SCIENTIFIC ABSTRACT SAMSONOV, G.A. - SAMSONOV, G.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001447010019-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 22, 2000
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AT.RVSAlMR(YV, P.A., kand.arkhitektury; GROMOVA, N.M.. kand.farmatsevtichaskikh
nauk; KAPITSA, N.K., arkhitaktor- SAMNOV G.A. arkhitaktor;
DANOVSKIT, V.F., arkhitektor, nauchnyy,red.; 0 5, Z.K., red,
izd-va; GILOSON, P.G., tekhn.red.
[Auxiliary therapeutic departments of general hospitals; manual on
the planning of pharmacies. laboratories. and physical therapy
departments] Lechabno-yapomogatelinye otdeleniia.bolinits obe,heho-.
go tips; posobie dlia proektirovaniia aptekq laboratorii, fizio-
terapevticheakikh otdalenii. Koskva, Gos.izd-vo lit-ry po stroit.,
arkhit. i stroit.materialem. 196o. 122 p. Wu 14:2)
(HOSPITALS-CONSTRUCTICK)

SAMSONOV, G.I.
*Stamping parts from sheet metal without and with small waste.0
V.A.Volosatov. Reviewed by G.I.Samsonov. Avt.trakt.prom. no.9:32-
33 S '54. O(T-RA.7:10)
1. Moskovskiy avtozavod imeni Stalina.
(Volosatov, V.A.) (Sheet-metal work)

-ZVYAGINTSEV.? Yu.Ye.;-q"-%Q&LV'-G.I-_, inzh., retsenzent; LIBERMAN,
Ye.G., doktor ekon..nauk, red.; SALYANSKIY), A.A., red.
izd-va; DEMKINA, N.F., tekhn.red..
(Operational planning in pressworking shops] Operativnoe
planirovanie v pressovykh tsekhakh. Moskva, Mashgiz, 1963.
136 P. (MIRA 16:7)
(Machinery industry-Management)
(Sheet-metal work)

BRUK, Ya.S,; SAMSOITOV, G.N.; SOKOLOV, A.I.
Sets of equipment with the K-52M narrow-range cutter-loaders.
Biul. tekh.-ekon. inform. Gos. nauch.-issl. inst. nauch. i
tekh. inform. 17 no.3;13-15 164. (14IRA 17:5)

- SAM~~SO~N~Y=Y-14-IL2Lo_=b; ELIKIN, Iosif Lazarevich; MiRKULOV,
Nikolay Yakovlevich; BOGUTSKIY, Nikolay Vasillyevich; KAZAKOV,
Stanislav Semenovich; IVANOV, Ivan Konstantinovich; AER.LMOV,
V.I., inzh., otv. red.
[The K-529 (IK-52M) narrow-cut cutter-loader) Uzkozakhvatnyi
kompleks K-52M (1K - 52M). Moskva, Wedra, 1964. 207 p.
(KIRA 18:4)

MANZHULA, N.G.; SAVELIM, I.P.; GUDYRIN, Yu.N.; qA~O_FVP G.N.
Testing the IK-52sh cutter-loader with the M-87 support. Ugoll
40 no.209-43 F 165. (MIRA 18SO
1. Shakhtoupravleniya No.1 "Znanya ko=unizma" tresta Krasnoluchugoll
kcmbinata Donbassantratsit (for Manzhula). 2. Luganskiy sektor-Gosudarat--
vennogo proyektno-konstruktorskogo i eksperimentallnogo instituta ugollnogo,
mashinostroyeniya (for Savellyev, Gudyrin). 3. Gosudarstvennyy proyektno-
konatruktarskiy i eksperimentalInyy institut ugoltnago mashinostroyeni~a
(for Samsonov).

DOMningdon at fm Carbim to Won OWN&. Tr. A.
26trersim and 0. V, Santxwov (SI. 1. Kalinin. Inst. Sa3
Ferrous Metals aridlrokj.~ Sfo~c;*). ze"dikays U6. 16,
41-1-OK 1951).-m-The rate of amidst ion of 8 carbide Is cmist.
t const. temp. Independently of the srain Are, when 0 or
chromate soln, yme word. Tbe'rate Is less Than that cif
MpItit sidation A man of CrOo In H.0 In "led at too*
Co
#&Mple.fona- bylipSOo.andtherroultiviggasessre
Ow q4 by a cunreat of 4tiod air tbrmgb the CwO &bomber.
followw by the drying tnin ol POD% follo"I by Naolil
aboorbem CaCls tuber asot! a afety vesed. The abmwbtrt
are pe. ically vehOsed. The results am piatted and thi!
value of free C is detd. as dw difference between the total C,
m6d d p I
gthe &cn Instant and the product of the titne
r
s
teoluxidationotc(prrmin'). 0%irlatiml
can be done with 0 at WD-10M, pmvidcd Out the. samilk
is well po". (324 mesh or better). Accuracy a( 0.6%. kf~
clainwd.
n. M. Koactspor

Isr"dea ad dw** crpotils of hagc~s emblde. 1. L.
zasymiaW, G, V. Sonsonor, and N, V. Popova. DoAkid
Akaj. crystals ~
R,C, up to 10 mm. long. 0.25-0.5 mm. thick. am obtained
in an clec. furnace from a mixt. of HA and tarnphlack,
under ronditious of slow cooling. if B bt allowed to diffuse
Aomly into the C-rich liquM around the etectmle. X-my
Alatirm of amm of the sansples taek~[ the. line with J
e 3.39 A.. umally attributed to D.C. but tvhlcntly due to all
limpurity, rhably graphite. Absence of that fine can.
v. so -ation of the purity of DjC.
,conseeluent y. serve as an indic
S. Thou

SIAVINSKIY' M.P., professor, doktor [deceased); 1FILIN, N.A., professor,
doktor, retsenzent. SHFICHINETSKIY, Imndidat takhnicheskikh nauk-,
ratsenzeat; ROGELIBM, I.L., inzhener, retsenzent,4, SARSONOV, G.V
radaktor; KARAYEVA, O.M., redaktor; MIMTLOVA, V.1r.
redaktor
[Physical and chemical properties of elements] J?iziko-khimicheskie
evoistva elementov. Koskya, Goo. nauchno-takha. izil-vo lit-ry PO
chernoi i tsvetnoi metallurgii, 1952. 763 p. (ML'RA 9: 12)
(Chemistry, Metallurgic) (Chemical elemeate)

<
~n
0.3 ,

USSR/Cheii,str tirc6nlun

in -a, Vacuum,
"Obtaining Zirconium Carbide G.
Meye3~son~PG. B. Samsonov_,Z~Moscow Ins't of Nonferrous,
Metals a~d G61d im -M. I. Kalinin

Zhur Prik Xhim, Vol 25, No 7, pp 744-748
By observing the rate of increase of CO given off~in
calciting of a mixture of ZrO2 and carbon black,,lit.
s'
was found that the reacti.qn'Zr02 + 3C'= ZrC + 2C0 i
.
additive and is composed of successive reactions',in~
which Zr203 and ZrO are formed. The practical teW
ZI
range in which the reaction with formation of
will.proceed in a vacuum was established and: the
263T44~'.

intermediate reactions were.discovered. It .1s pq~s
i
l
ble to obtain by the vac~mm process ZrC which con-
tains no N or 0 admixtures. A fundamental errorl.was
found in the work of Prescott and Hincke.(J. Chdm.:Soc.,,
V61 49)-who suggest equil coexistence of Zr02 and.
ZrC in the same reaction.
263T44

tal High-*itin ~,Xetals-_
9y,- 9
"Microhardness.of the, Borides I and Nitridei.of
High-Melting Metals," G. V. Samsonov, Moscow
148t of ]Nonferrous Metals an'd',Gold imeni M.' 1.
Kalinin.
Dok Ak Nauk SSSR" Vol'86., No 2, PP 329-332
Ketsures microbard ness,of TiB2, ZrB VB
Th B, -B, - WB2, TiN,I ;ZrN and, W. 2-1 CbBV
2, Cr
examn ajad-X-ray analAis showed, single-phase
s
btructuie of all Specimens. Tabulates physi-
to6hem properties of borides and nitrides., StiLtes.,
conclusion that' borideG sere formed by intrusion
235T62
1of:B atoms into lattices of high-melting meUls
Ind by wedging slip:.planes of these metals.
'This con~radictb assumption accepted in.:tech
liierat=6 that borides do. not, belong to in-
trusive phases. Includes several miciogiaphs.
Submitted by Acad'G. G~ Uragov 18 Jul 52.
235T62

FILYAND, M.A.; SEMOVA, Ye.I.; POGODIN, S.A., 2asluzhennyy deyatell
nauki i tekhniki, professor,-doktor, retsenzent; NZYNBSON, G.A.,
professor, doktor, laureat Stalinskoy premii; SAMSONOV G.V.,
redaktor; KAKATEVA, O.M., redaktor; MIKHAYWYA, e n
cheskiy redaktor.
[Properties of rare elements; handbook] Svoistva. rodkikh elemeatoy;
spravochnik. Moskva, Gos. nauchno-tekhn. izd-vo lit-ry po chernoi
i tsvetnoi metallurgii, 1953. 414 p. (MLHA 7:11)
(Chemical elements)

V.
.)c -ca:L A-iiiial,- sis
-in. F -rfj 111' SSSR Vol. 2", "53,
DV. ru.- Analiza -om
pp 92-103
Sansonc~v, G. V.
o- Fuc-*- D-1.~,c-rams of the 51'ste,". Boror.-Carbon and the 1"~--twre o-," the
PI-ases in This S-Tsten,
S-*Uud'-ed ~abcr~re s-,~-stem and deterraUied Its ph-ysic-~I constants.
SO: Zl-..urn--:L -Ko. 2, 1954 (T.-T-300,07)

-C7T-CT
ZELIKKAN, A.M.; SAMSONOT. G.V.; MYN, O.Ye.; STIPANOT, I.S., inshener.
retsenzenl",- V.. reteenzent; FMDIW, S.A., professor,
aoktor, zaalusheaW de7atell nauki i tekhniki, reteeni,ent; 110~3,
Ye.Ye., professor, doktor, reteensent; AIMIXOSOV, IfAh, daktoi
khimicheskikh nauk, retsenzent; SHAMRAY, M. doktor khinicheoklkh
nauk, retsenzent; XCROZOV, I.S., kawUdat "icheakikh nauk.
retsenzent; BOOK, Te.A.,.kandidat khImicheskikh nauk, retsbnsent;
NIKOLOXV, N.S.. kandidat khimicheskikh nauk, retsenzent; ZVORTKIN,
A.Ta, kandidat khimichaskikh nauk, reteenzent; BASHILOVA, N.I..
kandidat khimicheakikh nank, retsenzent; TYSOTSKATA, V.N., redaktor;
KAKAYEVA, O.M., redaktor; ATTOPOTICH, M.K., takhnichaskiy redaktor
[Metallurgy of rare metals] Metallurgiia redkikh'motallov. Noskya,
Gos. nauc)mo-tekhn. izd-vo lit-r7 po chernol i tsvetnoi metallurgit,
1954. 414 p. (MLRA 7:9)
1. Chlen-korrespondent Akademil nank SSSR (for TaasnVev)
(Metals, Rare-Ketallurgy)

(78-2 B
0 ea.
Fesos Wt
3- 3 0_1
03,
rkwa4fo Owed
ROL I obtalhed
wslu~s
i.342kc
.=aT538-k
P24, , with-,
24
NN
eon to,-
;B
fie/.
ho~VC6~ty' Of
.obtained b a
2.4 _:d U.",

_~)'q / VI !'~i C /V U V
Category :.USSR/dolid State Physics - Pb,~ase transformations in solid bodies E-5
Abs Jour : Ref Zhur - Fizika, No 1, 1957, No 1186
Author : Samsonov, G.V., Tseytina, N.YL
Title :-C-6n_c_e_r_n_IHg-Tffe- Mechanism of Sb~ace Saturation of Iron and Sterel by Bo;on
Orig Fltfb Fiz. metallov i metall ovedenie, 1955, 1, No'2,,'303-306
Abstract Based on the investigations of the microstructure and the microhardness of
specimens of ArAco-iron and of steel No -.3, subjected to_ZA~uration by Boron
from the solid phase at various temperatures (700 -- 1-2000) And-at various,
soakings (I -- 17 hours), the authors believe that in pure iron there is a
diffusion reaction of 'boron with formation of iron boride FeB, canstLng re-
latively high micro-hardness of the saturated layer (on the order of'730 -- 790
kg/mm2), and that in the presence of carbonthe reaction consists mostly of
diffusion on the boundaries of the grain of the solid solution of complicated
/mm, the high hardness of the saturated layer (on the order
carbo borides, c7in
of 14oo --.9loo

C7
Al 5
USSR/Solid State Physics Structural Crystallography, E-3
Abst Journal: Referat Zhur - F:Lzika, No 12, 1956, 34654
Author: SamsCmov, G. V., Zhuravlev, N. N.
Iostitutien: Nore
Title: On Aluminum Boride AlB12
Original Periodical: FU. meetallov i metallovedeniye, 1955, 1, No 3, 5&-566
Abstract: AlBip crystals were obtained by aluminum-thermal reduction of boric an-,
hydride in crucibles. The contents of boron in the beads obtained during the melt-
ing amounted to 82.5 - 82.8%. Almost all the AlB:L2 crystals were double growths.
X-ray structural investigation has shown that AlB12 belcogs to the tetragonal syngony;
and has the following periods: a 10.1 � 0.1; C 14.3 � 0.4 A and c/a = 1.41, P 2.79 � :
0.02, number of atoms per elementary cell approximtely 200. The electric rdsistiv-
ity of the pressed powder of A1312 is related to the density as follows: In
7.588 y - 15.03; where jp is -the resistivity (ohms/cm), and y the density of tre
pressed briquette. The electric resistivity of the specimens of AlB12 in compact
state, prepared by hot pressing, amounts to approximately 103 ohms/cm, the thermal
coefficient of electric resistivity is 0.4%/deg. The micro-hardness of AlB12 is
close to the micro-hardness of B.

wtit=*
C, Q Imm'n
Mg
bodde my Mte. G. V 11'ap"
~ N 4.- .91 24
Bruicner F7 in-datiun No 3~3761 -The -. i Fs, was Prod It
~v the v;~r -therinsl and l: liv
-na- T li,
Sz-
mate
off taut at a
pure.,_
within expEl- error, hitcroe3caratt. showed that the at-
toys were 2-phoe before atmeall
q; but those coutC. 3 to 8
after -Wiu* ne
--olicrohardtless.6, e,##,04 the 2 bA
'Pam
R~ PU AW Z,
bii t Y.;
tff
aliftbo
expansm was
ditivitle li~~ to-a ir~. at 90 more M. suppertinC
the Ides of limited solsr. of Tt% 62 TiN. Tests of oxiclatiou
resistan4m at 700 to 10004 showed that the 40 mete % TiN
most resistant. The soly. of TJE6 in TiN was
compn. was
judgedtobeg mcte%; that of T%N in Tillt was slight.
4M

-------

borides of lZr,,,VUb, Ta. omit W, and the blry systeMs
of certain Id ere studied. Briqueti of metal olkie
134C, and C black %vere charged kato a vacuum dec-resisthi;
furnace. The aptitual conditions of boride production wc-c
found from tensiornetric data. X-ray analysis of the Po4-
der% of borides Ti. Zr. V, Nb. and Ta showed lattice coast 5.
agreeing with those in the literature. Theds.oftheborides
detd. by micropycaometer nnetj with the caW. ds. AV
bdMe. an account of volatility -of W drUo. was obtained
at intich lowgr temp. with the emcess of VVOj: it has the
approx. compa. WIRt with the Uttice coasts. a - 3.00 Al
"M
a ZrB,, and Tillic t preod-
M
c W subsequent ng*o an WM Motm
%naeff,
and thek lattice cousts. were =Fly to their
tin, Woporticual
campus. The alloys were can4ara i corro6lon-Mist-
ti ly
ant, this resistance chmgiag gradually with the cozalm.
Th-fe-robardn graph of the Ultem changes continuously,.
in of compa. vs. dec. ccad. is a continuous curve,,
id=
i~
ttpwmrd Wj iadimtes that the borWes B.
tam a coutiattolts of OW Solm. A. N. PeKtaff
sets
.2

ks
-.3
if
arm
fat odufe'slti~s.'6f l9wor v Biiipj-
oxid
MOO,
owovr
"Kifos'~
-.46,14575r,"Tholita -con ft 0
TI A GUMQ~ly' actAT,
sm
equil. temp"d ~a&'A _Qf- thaf ~o
" -'W-
mpodds-tolbir bv&tk-jn-th-" 'itryi -P-
'wxpt
e c
imlcd. AH of ThOl audTIO 110'and ia;i~
at 880'1153ifi4.91042338 re*" M46 "t, 'o
ues tbat it is platu~le t
4 wsum~ e$
are- taft
'In' -Mi ~WW
d -it '
-otlicr han -T C
ef I
-a
-Ing.
-14231) Es'low's thli'61,i IlD lei7
aid- qcp-gf,
u 8649) th
j r I mV ~t -'(CL4; ...
a riBj,z+;4CO
7. zi;
C)
u Wof

o Is and Nb boride
ho aU Y ts ;iis
O
j=d7M%d. -at 14013-1;0
tftei
for 30 min, to 32 hrs.. followed by w x-tay examn. of Otte
amptes. ne iWiva(Wh enefly wits fivad by cat-an. to
equid 20,100 cal./molailio DiRt % M UIUCIt 113 WU Pre-
O
h
ff"
In
Ml
r-
e mu d
the Ti
e sys-
viously found In t
n
-j rot US
that the-principal t
tem (42AW, cat./inole)jhdicatin

h d*IT occs56 d- Isciii It borw
e I usma pr a e satid- sbl~s, is
t

' vs. -~ tie atmnis are concladed also
due to the.met4d aw T a
to nilgrite during the nultual barldes diffuslon. contrary to -
lik'(Powder A14
t lie vorichudons of Gkisi~ AM t vi,
B0
6

1 .
.
-
.
1260053)). A uniform solid Kin. and a cantinumts change

-
1
! in har(incss in the Tin,-NbI3, v ~xevu ~,,Ls fr~ttnd in miet4110-

1
" gy,iplti, And rtiirr-jlwdues~ anti the crystal g-rciw!h

c
Y during th, intr~,ng oI the At,v, -,- f-,u-i i fun,!-,.
kit~,I xr,i:gIh in 'he ~11 :1 ~P- Utfi- zftt, --t
11 1::!! U'U 0

0 4A
uSWvGhSmistz7 -m mtLuvr
card:3
hb*
.22 30151~

Authors t i~d We
Sand liar, Go S*ii., ~`V. 6:
21t3m Hatutal diffusion of titanium and doblum boriddim.
'Nriodical I '_ ~Dok. AN Sm 5q-
stract I

TIB2-_NbB"--"`$uM:".. - VAG%a-ii
ti
and niobL; b6idda 6: at' bigh tei tures- leads ~Ao he formation: a, a
-para
.
I&BO was I -to, bo -to
'
-

'lainad
nolvent: and this
U 94 1 7. f iiiatii b nd
existing
_euergyl,
between _thi~.Imcteallo_ ttoms -and A 6,~iistal atdimil"irid LA,

he. Ti, iwi, $46 -M Gred:Id, poissai
Id
of TO thin Lfil6AW
_4
f6it: th
?ii- Ao
tr6
i
IeW d
A Ab
re
r
f

-~
10
a
c
e
an
x -,
U
e
e
grea
A
nces.
.
4 1 Germn and, Im -(1904054). - Graphil,,,'.....".
Initit*ution s The H, I*' Ulimjh~jfij of ffon~ IF
t. arrow Metals &nd, 1d Moscow
Pree G-uWd bys Academdcian A 9' Frm*ih-_ OoU)b_er,92j 19!4.'*,
6

1~ -,~~7~7 :- ;:~ -* ~, ; , -- ~~ : , '-t- -I-- - , - - .--- -
Z - - p -- , ~- -.- - - . ~ :=- - Z-
a 4=pccc4th(Uty of pagiforgd bodd
1~ &"T..ftl- .1 --f. f~ " . ') "

--i -

FAZMIN, Vasiliy Aleksandrovich; FISHER, AlekBandr Yakovlevich; KRBSTOVKKOV,
A.N., professor, doktor. retsenzent; MIC11MON, G.A., professor, doktor,
retsenzent; ZIMOVSKIY, Te.I., professor, doktor, retsentent; MINISHI-
KOVg M.I., kaudidat tekhnichaskikh nauk, retsenzent; SAMSONOV,.GJ-9
kandidat tekhnicheakikh nauk, retsenzent; KESHCH1931YAK&T'*' S*it-,'- i;~t
tekhniches)rikh nauk, reteenzent; SAMSONOY, G.V., redaktor; ARKHANGBLI-
UiYA, M.S., redaktor izdatellstva; BIRLOV, A.P., tekhnicheskiy redaktor
[Vacuum in metallurgy] Vakuum v metallurgii. Moskva, Goo. nauchno-
tekhn. izd-vo lit-ry po chernoi i tsvetnoi metallurgit.1956. 520 p.
(Vacuum) (Metallurgy) (nn 9: 12)

SAMBONOV, G. V.
Samsonov, G. V.
I'Some physicochemical propertied of compounds of the transition metals
with boron, carbon, nitrogen and silicon." Min Higher Education LISSR.
Moscow Inst of Nonferrous Metals and Gold imeni M. I. Kalinin. Chair
of Metallurgy of Rare Metals, Moscow, 1956. (Dissertation for the
Degree of Doctor in Technical Sciences).
So: Knizhnaa letopis'
Nu. 25, 1956. Moscow

C-~
Category : USSR/Sclid State Physics - Systern
Abe Jour : Ref Zhur -' 1, 1957
Ftzika., M No n58
Author : Samsonov G.V., Neshpnz,, V.S., Lange, L.N.
E-4
Inst. Moscow MatitUte for Nonferrous Metals &td Gold
Title Laws of Formation of Blaa:ry Alloys of Titanium
Orig Pub Metallovedeniye i cbrabotka metallov, 1956, No 11~, 30-39
Abstract When Ti interacts witia metals that, have a similax electron shell str'ucture and
a small d-iffe-,r,pzce in atamic diameters (Liot more than 18%), the additive (Zr)
may have aa utlimitel solubility in the cx. andl? modification of Ti, or else Con_
tinuous series of solid s.- are f~:irmed with/? titanium with a limited
Vil .-a
solubility ino( Ti (Mo. V~ Kb, Ta'I' Elements having-a. different e:Lectron-
shell character anA a differe---4t atomic diameter interact with'titaniim to forM
solid solutir-a-s with a1imit.4ed- solubility iil'the,~d and-Ok-titaniuft- and- with dia-
grams of state with c-iteabic'cr eatectzid'tramsformations (M,, Fe, Cr, -Sil Ni,
Cu) or with pe:7-itectic or~pi-,:,ite6tLid-trar~if6-mati-oni (C, N., ~1)-. When Ti is
smelted with elleme~,.ts of the' tramsition'groups, ame observes an expansion in
the region of t-he s:,Iid solutio=s vithQ(-Ti.
Card 1/1

7
. . . ......

/A;PlRavfew of iho* BbLay of Titn' ands",
for Their MmWaHon. N
Lor
`--Reviews the jkluffibrioni dia
tua dia ui
gm
~
.Vilffiffied for- bhvixy Was f Ti *&.Cu;'A#,-Ax4`

Be
~ ON
Fb' Z
-V
AL SL P
S
rb
0
S
.-AL
n
r
; go. e
,
, U
.
C4 No, W. U. Hi-Mn.-_Fe~ -C6;i6Ud-Nj;iad.th6auggmuo
P
b."'Iff . th,
that have been mads for c I '1W i MmL-
Q T

Al
"T

11 qjgkiV ki , "
I Ar &I. d _pl in chenlical indUSErY-
MEL

Pill (; A,, 0 t
USSR/Inorganic Chemistry - Complex Compoundsa cc
Abs Jour Ref Zhur - Khiziya, No 9, 1957) 30277
Author Samsonov., G.V., Zorina,, M.
Inst
Title Preparation and Some Properties of Thorium Emboride
Orig Pub Zh. neorgLn. W-1i, 1956, 1, No 10, 226o.2253
Ab5t Borides of Th were obtained by the method of va=ft.
thermal reduction of Th oxide with carbon of boron car-
bide and carbon black, according to the reactica 2ThO9-+
3B4C + C -4 2nai6(t) -+- 4co. At 13oo-14ooo the process
takes.place very slowly while at 18000 it comes to com-
pletion. within 35-45 minutes. If the reaction is Icou-
ducted in such a Ynnner as to obtain MB4, that is ac-
cording to the scheme Th -f- B4(; + C -3~ ThB4 + 200 the-
. 02
re is formed at 1250-13000 a product of composition
'Xhx]3yCz- (11). Density of 11 is 7.552. 11 has a teragonal
Card 1/2

USSR/Inorganic Chemistry - Complex Compounds. C.
Abe Jour Ref Zhur - Khimiya, No 9, 1957, 30277 1
.lattice, a 5.80, a 3.80 At, Povdered II sinters at
22300 to a compact state; melting point of II is about
24000 while the meltin _T
k~ ~iabout 21500.
ess of I is Ig PZi"23'
Microhardn 1.7 ' '12 k Ivetric-, resis
tance 37 . 10-6 OEM cm efficient of therml esm*,f.,
when coupled with Cu, is~2 5 zv/degree in the :Wterval
20 - 600, work function n thermoemission 2.86 W, coef-
ficient of radiation 0.69 0-70-
CsLrd 2/2

USSRZCvystals.
B-5
Abs Jour Referat Zhur - Khimiya, No 6, 1957, 18248
Author G.V. Samsonov, N.N. Zuravlev, I.G. Amnuell.
Title ~~oncerning the ouestion of Physico-Chemical Properties
of Boron-Carbon Alloys.
Orig Pub Fiz. metallov i metallovedeniya, 1956, 3, No 2, 309-313
Abstract An x-ray and microscopical study, as well as the measure-
ment of the electrical specific resistance and of the den-
8ity of B and C alloys within the limits of C content
from 5 to 72-5% by weight were carried out.. It was found
that at >
5% of C, an imperfect structure,of the carbi-
de B13C2 developed, which structure wascharacterized.by
vacaj.L. p-.az:es on the c axis in the B13C2 lattice. The va-
cant places were occupied by C atoms at 14 to 16% of C
r,,aking the line -C-B-C-, which transformed later into the
line -C-C-0- of-boron carbide B12C3 B40' A1.1.0ya
with the imperfect lattice possess the,electron
B13C2
Card 1/2 53
Card 2/2 54

R"d jdqjo wab a Rol Q
mtribution of thr"'gafti" Pftl&ftr fhe Manuftetm of
riaV -9D"77 ~Rsnd
Abrasive Kate j
7:777-Tra-TT,-ni- 3-SS. R , 19M. [Tek~.
T R -4W Ne cond.,t.oiti nf pr-pn )i~p~
in zmn~iiria rif iuat-ri;. projf.~ns it
r"utancIN- !1-rm-f 'r; A 01' he
fi~, rta nctier Lrz i o ThA- t --pe of atructurt
E. B.
-- ~M~tX
.7
.................
P

L
p4f4S9- New Refradon, Altvrial~ for Smd!!B& dhd CAQ,
of :gh-Aletting let-le Navye Odneuponfe materidly
iu-l-~ -1w
plav m1w gdDTavkikh metatlov. (Rtrisian.) C. V. Sam-
sonov. Ogrieupory, it. 21, m % 1956, p. 12:1,la5. -
A survey of various refractory materials for grospective use in
SmeltT of high-111-Ating inetals. Quate. a Parge bibli ntph)
of lwAtly foreign st,urces (in the subimt. Ta bles. 53 rt(!T

SA~SONOV, G. V., and CHISTUMV, Yu. D.
"Metal-Reduction (IMetallothermic') Methods in Chemistry and
Technology," by &.'and Yu. D. Chistyakovl, Uspekhi
Khimii, Vol 25, 'NO 10P Oct 5pp 1223
Work on the reduction of metals and some nonmetals (31) with metals
is reviewed. Reference is made to the use of metal hydrides as reducing
agents in processes of this type. The physicochemical aspects of the
processes involved are discussed in detail.. The heats of formation of
sow oxides and halides (including CdC12, ZrC14, UCL4, RaC12, LiCl, CeF 3)
LaF , and LiF) are listed. The free energies of formation of halides in-
cluaing CeF ThF Zr F4, Ce C13,,Th C14, and Zr C14 are given. Frac-
p1j, 4;
tically ap ied reduction processes are listed under the subdivisions of
processes conducted in vacuum, processes carried out under atmospheric
pressure., and processes conducted in an atmosphere.of inert,.gases or re-
ducing gases. The authors say that methods of this type are extensively~
) CrAw-,".
used at present for the production of'pire metals, primarily Ba
and'some light and rare metals (e.g.. Li, Be Ti, Zr I va)
an

Nhile in the metal-reduction processes described above the oxide
of the metal being reduced functions as the oxidant, oxidants in pyro'-
technics are selected on the following basis: (a) the oxidant must con-.
tain the maximum quantityof oxygen and furnish it readily during the
combustion of the mixture, and,(b) the oxidant must represent a rela-
tively stable, nonhygroscopic compound, at least in the temperature
range minus 600 - plus 600."
The subject matter of the article is based to a considerable ex-
tent on data taken from"GSSR publications: out of 45 references in them
bibliography, 26 are USSR.
[Comment: Some of the information given in thislarticle has a bear-
ing an the production of materials that are of importance in nuclear tech-
nology (e.g., U,, Th) LIJI Cd. Be. Zr), The discussion of, the properties,
of metal fuels used in pyrotechnics is of', importance fron the standpoint
of the potential use of such fuels'as propellanti in reaction motors.]

The following processes are described, among others: production Of
1ithium by the reduction of lithium oxide or ofspodwnene I n vacuum with
Al Si, or Mg; production of Be by reduction of BeFL> in vacuum. with Ca
or Mg; production of Ti, Zr, Ta, and other metals by the reduction of
their halides with Mg or Na; and production of Zr, Tt, and Ta by the re-
duction of their complex fluorides. The use of oxidizing agents to raise
the temperature during the process is mentioned and the proper-ties of sow
oxidizing agents including Ba(KO Sr (NO KNO NaNo KCIO Ba(
21 3.1 .9 3 C'03)2,
KCID BaO Us 0 Cas and Na' are discussed from tais standpoint. 7.
42 T,1 t~e-21 04, 2 4
In conclus on application of metal-reduction processes in pyrotechnics,
specifically in military pyrotechnics, is discussed on the basis of inform-,
tion given in two USSR hand-books on the subject.
The section on pyrotechnics includes the following passage:
"Among metals which can be potentially applied as metal fuels one
may mention Be, Al, B, Li, Mg, Ca, Si,.Ti, V, Zr, and their alloys. The
highest temperatures during combustion.must be developed by Zr, Al, Ca,
and MS. At present, no metals except Mg, Al, and their alloys are ap-,
plied for this purpose, although some metals which are extensively used.
in contemporary metallurgy would be suitable for this application either
in the pure state or in the form of their alloys.
"To obtain the*maximum effect from a metal,entering into the composi-I
tion of a pyrotechnic mixture,.the oxidant must be appropriately selecte-a.'~

M S N N/.
USSR/ Physical Chemistry - Thermodynamics. Thermochemistry. Equilibrium. B-8
Physicochemical, analysis. Phase transitions
Abs Jour : Referat Zhur - Xhimiya, No 4, 1957, 11277
Author : Saxasonov G.V.
Inst : Institute of General and Inorganic Chemistry, AcadezW of Sciences USSR
Title : Some Physicochemical Properties of Compounds of High-Melting Transition
Metals with Boron, Carbon and Nitrogen and Particularly of Their
Binary Alloys,
Orig Pub : Izv. sektora fiz.. -khim. smaliza IONIh AN SSSR, 1956, 27, 97-125
Abstract : Review of work concerned with interaction of high-melting transition me-
tals of groups Iv, V and Vi of the Periodic System, with boron, carbon
and nitrogeA. An attempt is made to interprete some properties of the
compounds thus formed in the light of modern concepts of the theory of
structure and chemical bonds. Biblography 47 references.
Card 1/1

~~ ------ -------
()7 5C; A/0 V i'~
C&tegox5;-, USSR / Physical Chemistry - Crystals
Abs Jour: Referat Zhur-Khimiya, No 9, 1957, 29770
B-5
Author Samsonov G. V.
Inst not~~~
Title Electric Conductivity of Some Compounds of Transition Metals with
Boran, Carbon and Nitrogen, and Their Alloys
Orig Pub: Zh. tekhn. fizilU, 1956, 26, No 4, 716-722
Abstract: Determirtation of electric resistance (g' ) of carbides, borides and
nitrides of a number of transition metals (Ti, Zr, Nb, Ta, V, Hf,
Mo, W, La, Ce) -- compounds of the type of implantation phues satur-
ated with metalloid. The5 of carbides is higher than of the
corresponding metals. This is an indication of the fact that for-
mation of carbides results in an increase of the unfilled state of
d-band and, correspondingly, of probability of scattering of carriers.
-In borides of Ti, V, Zr, Hf, Ce, I&,_P is lower then, and in borides
of Cr, Nb, Mo, Ta, W, it is.higber than the _~ of the corresponding
metal. Borides of 2-nd group are, apparently, similar to carbides
Card 1/2 -48-

USSR/~hermodynamics - Thermochemistry. Equilibria. B-8
Phyaical-Chemical Analysis. Phase-Transitions.
Abs Jour Referat Zhur - Khimiya, No 6, 1957, 18498
Author G.V. Samsonov,_NS. Rozinova.
Inst : -1-n-st-MR5 -of Organic and Inorganic Chemistry of Academy
of Sciences of USSR*
Title : Some Physical-Chemical Properties of Zirconium and Carbon
Alloys.
Orig Pub : Izv. Sektors; fiz.-khim. analiza IONKh M1 SSSR, 1956, 27,
126-132
Abstra,t It was established on the basis of roentgenographic and
metallographic research and the study of the microhard-
ness and electric conductivity of Zr and Clalloys that
the alloys containing 0.64 to 3.12% of C by weight were
two-p-hase alloys* The--basic, (hexagonal) phase is a so-
lid solution of C in Zr, and the~second (cubic) phase is
a Zr carbide. Alloys containing 3.50 to 11.62% of C by
Card 1/2 179
loys decreases from 3.16 A of pure ~r -to G 0.0cyp
of C by weight, after which it rises from 4682 A at
3.50% of C by weight to 4.683 A at 11.62% of C by weight.

)~d
t
r
d
th
h
id
b
b
E
C
L
e
-
ne
em
ov
es d
a. and
e were PrCP
a.
a.
T
-
1-
1n P4.tilm "el CE!td.,. UAI.
I2

428 -E 0.01, 4.16 :1: 0.01, 4.14 *
SMTb .1
1
0.02, 4.25 � O.M. 4-79- :L- 0-02,
;
microhairdness (2740 :1-- 220. 30(0 ~i- 290, MO 4: 160,
3140 t: 190 kK /5q mm-); cOeff- il Unear exPaas'an (5-2 :L-
10- :,= 6%. 6.1 x 10- z!z 6%, oj o )< VIO, 8.2 X
10 - t. f~% /degree 1: %peecffic clec. r --sistance (123.5. 306.
17 4, W.5 rmu,,h-m =.), The teat al famation of CeB-
was found to be 91 -L 16 kcal 'it 10le The prope~tias are
related to the electron structure f tfc hexaborides.
I~ovvu Leach

ME .. iju

rum 4 "d;w. I
-Z
-,ow *W.
et,4
Tbc at sAtim isotherms ime allzined Ld
n,
,t~
c. the Ist i3 curred cad
thc ~~Is a Stra4ht. Ulte. 7 for TiLh obeys the
Ale F*. The pidde ==vc fonned "Cir
and by clectrou'lif-
by dMusion of
a
k of the oxidation for 13N
it the Lsotherm) Is tfm f"-
D at rlCeZO fdbwcd by
a loom layer of the h4.hdr
Madan 6 bmught about
of bwates tItAt is formed
Rovtar 18

1-11. -111 .1 . I

CftL%JQUQEWAMW of bcridds of same trarssjt-~;n meEais
-l'i C Paw 7~-r~
;6L - -1
-~q ZP
pp,

Categoyy: USSR Physical Chemistry - Crystals B-5
Abs Jour: Referat Zhur-Khimiya, No 9. 1957, 29711
Author : Samsonov G. V., latysheva V. P.
Inst : -Academy of Sciences USSR
Title : Diffusion of Boron, Carbon and Nitrogen Into Transition Metals of
Groups IV, V A1,[D V! of the Periodic System
Orig Pub: Dokl. AN SSSR., 1956., log, 1110 3., 582-585
Abstract: Reaction diffusion of B and C into Ti, Zr, Nb, Ta, Mo and W is uti-
lized to elucidate the effect of vacant d-electron sites of metals
and of ionization potential of B and C on the diffusion constants D
and Q. Reaction diffusion results in the formation of.the compounds
TiC, ZrC, Ta,_C, Nb C, W C, Mo C, TiB- -, TaB,, NbB , Mo- Band,V,B.
Values of Q on diffusion of B, C and N (from another paper) into trans-
ition metals of groups IV, V AND VI, reveal the fo" owing regularities:
1) in the same group of the periodic systerp Q increases with atomic
number of the metal; for the given metal, Q increases in the series B,
C, N. Low values of Q in the case of B are attributed to the low ioni-
Card 1/2 -22-

Category: USSR / Physical Chemistry - Crystals B-5
Abs Jour: Referat Zhur-Rhimiya, No 9, 1957) 29711
zation potential of B; 3) on transition from metals of groups IV and
V to those of group VI, Q increases slightly in the case of B and
sharply in the case of C. This is interpreted on the basis of the
theory of Pauling (Pauling L., Phys. Rev., 1938, 54, 899). Differences
in values of Q on diffusion of B into metals of groups IV, V AWD VI,_
level off in comparison with C; the authors attribute this to decreas-
ing effect ofdeficiency of d-sublevel as a result of the formation of
structure elements from atoms of B (chains, layers and framework, con-
nected by covalent bonds).

SAKSONOV. (6orgiy Valeatinovich- PIOTICIN. Semen Takovlaviah; OLIKHOV, I.I.,-
or;' redaktor isdatellstva, WASSON. I.M.0
tekhnieh*eakiy redaktor
LProduction of iron powdarj Proizvodstvo zheleznogo porashka.
Koskva, Gos.neuAno-takhn.lzd-vo lit-ry po ahernoi i tevetnoi
metallurgil, 1957. 348 p. (MIaA 10:7)
(Powder setallura)
'(P, bl, ~j

SKIY, Yakov Semenovich; RASTORGUYST,
5V_ 12aliAlolt F%"=0_ WOPOPM 14. , rodaktor izdatellstva; ORMORT*9 B.F.,
professor-doktor, reteenzent; TRFT'YAKOV, V.I. kandidat tekhrLi-
cheskikh nauk, retsenzent '~hnicheskiy redaktor.
;MIKHAYLOVA, V.V., te
[Hard compounds of metals irith high melting-point] Tverdye soedi-
neniia tugoplavkikh metallov. Moukva, Gos~nauchno-tekhn.izd-vo
lit-ry po chernoi i tsvetnoi metallurgii, i957. 388 Pe
(MIRA 10:4)
(Heat-resistant alloys)

c
LARM 1K, ffqrk Moiseyevich: SMYUKOV, Nikolay Nikolayevich; BELTAYEV, A.I.,
prof., dokt.; retsenzent; VFJJM, R.L., kand.tekhn.nau)c; reteenzent;
VANYUKOV, A.V., retsenzent; XROL', L.Ya., retsenzent;.A
retsenzent; LRONIDGV, N.K., lnzh., retsenzent; ZflD1CHUZHIffA,,Ye.A.
red.; BLIKINA, L.M., red.izdatelletva; MIKHAYLOVA, V.V., tekhn.red.
[Metallurgy of nonferrous metals] Metallurglia tsvetnvkh.metallov.
Moskva, Gos.nauchno-tekhn.izd-vo lit-ry po chernoi i tsvetnoi
metallurgil, 1957. 535 p. (MIRA 11:1)
(Nonferrous metalg--Metallurgy)

of na,,comrounds he transid(m
n -eir melts
Lq#~~d th
Ai- 'h ,1 6, 76
V
:,-,57 F[igtuh tr
Inst : Institute of Metal Ceramic and Special Alloys, Academy-of
Sciences, Ukrainian, SSR.
Title : 14icrohardness and Tantanlum Carbide in the Region Where
they are Homogeneous.
Orig Pub Dopovidl AN MR, 1957, ITO 3, 247-250
Abstract Experimental data ara given on the measurement of the mi-
crohardness andthe electric resistivity ofalloys in
the system Ta-C In the region vhere the carbides Ta2C and
TaC are homogeneous. It is porposed to treat the results
on the basis of the electron structure of the atoms Ta
and C.
Card 1/1

i Sd

122-3-6/3b
AUTHOR: Samsonov, G.V. , Candidate of Technical Sciences, Dotsent.
- -d - ' '' - e
TITLE: ompon nts made of Boron Carbide (Izdeliya iz karbida bora)
PERIODICAL: Vestnik Mashinostroyeniya, 1957, Bb-3, PP. 24 28
(USSR)
ABSTRACT: The properties of bo= carbide compared with other hard
materials are stated in a numerical table. The preparation of
components of boron carbide by hot sintering under-pressure is
discussed and described with the help of drawings and numerical
data7 taken mainly from foreign periodicals and patent litera-
ture. Some applications are discussed; original applications
are mainly those for diamondless dressing of grinding wheels.
Tests carried out at the First National Ball Bearing Factory
(lGPZ imeni L.M. Kaganovicha) with the internal grinding of holes.
showed that a dressing pencil of boron carbide of 18 mm diameter
and a height 23 mm stood up under shop conditions to 168 hours
of service, and so ensured hole tolerances of between 8 and 10
microns. The ratio of volumes removed from the grinding wheel
and the dressing pencil varies between 800 and 8 000 ior boron
carbide whilst'.: for carborundum it varies between 200 and 60.
There are 4 figures, including 1 photograph, 4 tables,and
uardl/l 32 references, of which 9- are Slavic.
AVAILABLE- Library of Congress.

V,
5 V
ATJTI~DRS: Neshpor, V.S. and 5amsonov, G.V.(H.V.) 21-5-13/26
TITLE: New Borides of Rare-Earth Elements (Novyye boridy redkozemell-
nykh elementov)
PERIODICAL: Dopovidi Akademii Nauk Ukrainelkoi RSRp 19579 Nr 5f PP- 478-
479 (USSR)
ABSTRACT: The authors obtained the borides of dysprosium, holmium and
lutecium by means of the vacuum-thermal method. They were
subjected to X-ray and chemical analyses. Roentgenograms of
all these compounds are completely similar and indicate the
presence in each 9f them of two phases; cubic and tetragonal
so that the composition of these borides is as follows: DyB6,
DyB4, HoB6, HoB4, LuB6 and LuB The constants of their lat-
tices are cited in Table I of Ge article. The intensities of
the lines of the two phases in the roentgenograms are approx-
imately equal; most of the lines are ascribed to the phase of
MeB4. The article contains 1 roentgenogram, 1 table and 6.
Card 1/2 references, 2 of which are Slavic.

New Borides of Rare-Earth Elements 21-5-13/26
ASSOCIATION:
PRESENTED:
SUBMITTED:
AVAILABLE:
Card 2/2
Institute of Metalloceramics and Special Alloys of the AN
Ukrainian SSR (Instytut metalokeramiky i spetsaplaviv AN URSR)
By V.N. Syeahnikov(V.M. qvyechnikov), Member of the AN
Ukrainian SW
4 March 1957
Library of Congress

/I J-n S 0 Aj 0
ILP.,L'HOR SAIZONOV G.V.,NEC-HPOj V.S.,KU-INTSEVA G.A. 109-5-14/cr_
TfTLE -G-n-f H-P-1-e U-111 o ns hi _t_-;C
p Between Thermoemission Constants of' rans
.,.etals(and Their Compounds with Several Metalloids)and Electronic
Structure.
(0 svyazi termnoe-maissionnykh nostoyanrtykh perekhodnykh metall-7(i
itch soyedineniy s nekotorymi metalloidami)s elektronnoy strukturoy
- Russian)
P-LIHIODICAL Radiotekhnika i Ilektronika,1957,Vol 2, Nr 5,PP 631-636 N.S.S.R.)
ABSTRACT ZLn attemDt is made here to determine the relation between the elec-
tronic work function in thermoemission and the electronic structure
of transitive metals ( and their compounds with ~b'bron carbon
and nitrogen). It is shown that the work function depends on the
atomic structure of the metal and decreases with decreasing degree
of screening of the electrons of incompletely occupied d-atom shells
of transitive metals. The work function can be brought into connection
with the quantity of dispersive power of the atoms of transitive me-
tals which are characterized by the criterion 1/Nn. 11 - chief quantum
figure; n - the number of electrons in the incompletely occupied
d-shell, it decreases with increasing 1/Nn. In metalloid compounds
of transitive metals with bor6n ., c-arbon and nitrogen the work func-
tion should increase with increasing I/Nn for the corresponding
transitive metals.This is confirmed in the case of borides,but in
the case of carbides and nitrides it can not yetbe considerled to be,
Card 1/2 an established fact. The ionizing potential of the metalloid atom

On the Relationship Between Thermoemission Constants of 109-5--14,/22
Transitive Metals (and Their Compounds with Several -Yet-alloids) and
Electronic Structure.
exerts considerable influence on' the amount of the work function
of metalloid compounds. A reduction of the work function is to be
expected in the M02-MeC-HeN series, where Me is a transitive metal
of groups lVa, Va, or VIa. The work function is in most cases smal-
ler in the case of metalloid compounds th an in that of the corres-
ponding metals
1 table, 4 iilustrationg, 6 Slavic referonces).
~Tot
ASSOCIATION diven.
PRESENTED BY
5 UBiJITT ED 25.6.1956
AUILABLE Library of Congress.
Card 2/2

ri rl .-S 6 v, 6C- - V
AUTHOR: NeShpor, V.S. and Sams 126
'-',onov,--G.V.
TITLE: On the problem of brittleness of met-a-1-
.1o'fds compounds.
(K voprosu o khrupkosti metallopodobUkh soyedineniy.)
PERIODICAL:"Fizika Metallov-i Metallovedenie" (~hypics of Metals and
Metallurgy), 1957, Vol.IV, No.1 (10), pp.181-183 (U.S.S.R.)
ABSTRA.CT: The coefficients of linear expansion of a number of
metalloids were determined and their modulus of elasti.eity
was estimated on the basis of a formula proposed by I .
Ya. I. Frenkell (3). In a table, p.181, the coefficients
of linear expansion, the elasticity moduli, the mean square
displacements of the molecules in the crystalsand the
brittleness of these compounds are given, some of the data
being based on information published in literature. The
following compounds were investigated by the authors:. Mo2~
WC; TiC, ZrB 2 2 TiB 21 ZrC, TiN, CrB2. The values given in ...
the table for W C NbC TaC and VC are those given by Koster
(Zs. f. Metalli?Q'e. 1~48, 39, 111).
1 table, 1 graph, 7 references, 3 of which are Russian.
Institute of Metal Ceramics of
Special Alloys, Ac.Sc. Ukraine:
Piloscow Institute of'non-ferrous,
metals and gold imeni M.I. Kalinin. Recd. Mar.22, 1956..

.ALTEORS: Samsonov., P~,'_V,,,.and Solonnikova, L. A. 126-5-3-30/31
TITLE: Diffusion of Silicon in Transition Metals (Diffuziya
kremniya v perekhodnyye metally)
PERIODICAL: Fizika hletallov i Metallovedeniye, 1957, Vol 55 Nr 31
pp 565-566 (USSR)
ABSTRACT: Transition metals form compounds of high'electrical.-
conductivity with silicon (Ref.1), which can become
superconducting (Ref.2), which have a metallic lustre,
etc. Orystallograp'hically, silicides are substitutional
phases (Ref-3). unlike carbides and nitrides, which are
interstitial, or borides, which shov, some signs of being
insterstitial, as well as some layered features typical
of silicides. The metals used were Ti, Nb, Ta, Cr, M0,
W1, Fe. Co and Ni; the diffusion data were worked up to
give the activation energies of diffusion. The cY711ndrical
sDecimens were saturated with silicon in an oven while
'immersed in silicon powder containing activating additives,
The thicknesses of.the silicided layers were determined
from etched cross-cut sections. Wafers less thick than
the silicide layer were examined with X-rays and by
Card 1/3 chemical analysis; in all cases the layers were found

.Diffusion of Silicon in Transition Metals .126-5-3-30/31
to consist of disilicides. The results were worked up
in the normal-a-ay for reactive diffusion (Ref.4). The
activation energies (in cal/mole) given in the Table were
derived, and compared -with those for B, 0 and N in the
sqjne metals (Refs. 4, 51 7). The silicon was found to
give the lowest activation energyl although, formally,
speakinG, one would have expected it to give the
13rges since silicon has the largest atomic radius
(1.18 b, ,,,hile.B, C and N have 0.9, 0.77 and,0.71-i
respectively. The figure shows that the activation
energy is inversely proportional to the ionization
potential of the metalloid. The electronic properties,
rather than the radius, are therefore heredecisive.
Although silicon gives lowactivation energies, the
silicides have comparatively low values of the physical
-oarameters, relative to borides, carbides and nitrides.
his occurs because the high-melting carbides and
nitrides (Ref.8), and partially the borides, are inter-
stitial in typel %-.,hile the silicides are substitutional.
In the first three the shear deformation in hardness
Card 2/3 testing, and the general deformation in melting, are

Diffusion of Silicon in Transition Metals' 126-5-3-30/31
resisted by the cross-l-inkling action of the metals, while
the silicides, having graphite-like layers weakly bonded
together (Ref.10), deform comparatively readily. The
silicides therefore often melt even below the meltingpiint of
metcnls and S ~'licon7and the hardnesses do not exceed 1000-1500
kg/mm , while the borides nitrides and cai-bides give
values of 2000-3000 kg/mmt (Refs. 11, 12). In.Fig.1
relations are graphed of the activation energies for
metal-like phases to atomic radii and ion,~-zation potentials
of the metalloids. E, kcal/molevs..r., A i Ix~ eV.,
Note: This is a complete translation without including
the information contained in the table, lish.
P*' ~P
There is 1 figure 1 tablq and 12 referinc 'n
SDie
ASSOCIATION: Institut met~flokeramiki i spetsial nyUls'piavov
AN Ukr.SSR (Institute of Cermets and Special Alloys,
Ac.Sc., Ukr. SSR)
SUMITTED: January 22, 1957
1. Silicon--Diffusion 2. Metal si-licides--Preparation
Card 3/3 3. Metal silicides--Properties

129-12-2/11
AUTHORS: Bal'shin, M. Yu. and Samsonov, G.V., Candidates of
Technical Sciences.
TITLE: Forty years of powdermetallurgy in the Soviet Union.
(40 let Sovetskoy poroshkovoy metallurgii).
PERIODICAL: Metallovedeniye i Obrabotka Metallov, 1957, No.12,
pp-~ 15-25 (U.S.S.R.)
ABSTRACT: The first part of the paper deals with prewar and
pre-1917 developments, mentioning that in 1932 fifty tons
of "pobedite", thirty tons of I'vokar" and sixty-nine tons
of "stalinite" were produced and during that year these
cemented carbides were used in 1400 Soviet plants. An
All Union Scientific Research Institute for Cemented Carbides.
(Vsesoyuzniy Nauchno-Issledovatellskiy Institut Tverdykh
Splavov) was organised, the work of which determined to
a certain extent the development of the Soviet cemented
carbide producing industry during the post war years.
This Institute contributed a great deal to the development
of the process of manufacture of shaped cemented carbide
components. It is claimed that the Soviet Union is
In the forefront as regards production of cemented carbides
and this resulted in considerable successes in the fields
Card 1/5 of machining of metals, mining, oil and geological drilling.
Between 1949 and 1951 a highly efficient method of

Fort-y 'years of powder metallurgy in the Soviet Union. 129-12-2/11
producing pure borides of high melting point elements
was developed (Ref.8) and also methods of producing
silicides and a number of diagrams of state of carbides,
borides, silicides and nitrides were investigated (Refs.9-11).
Cemented carbides were used as substitutes for diamonds in
trueing grinding wheels and for machining hard watch and
instrument jewels of the type of rubies and leucosapphires.
New thermo-emitters for electronic,devices (lanthanum
boride) were developed and also high resistance resistors.
At the Institute of Metalloceramics of Special Alloys,
Ac.Sc. Ukraine (Institut Metallokeramiki Spetssplavov AN
Ukr.SSR) intensive investigations are proceeding relating
to cermets which consist of composition of oxides with
carbides and of metals with oxides; a considerable part
of this work was carried out by Ya. S. Umanskiy,
G. A. Meyerson, B. F. Ormont and V.V. Grigorlyev (Ref.12).
An important contribution to the theory of alloys of
hard, high melting point compounds was made by
I. I. Kornilov (Ref.13). The Soviet chemical industr7
developed methods of production of boron-silicate
Card 2/5 powders. F. I. Sham a and V. N. Yeremenko investigated

Forty years of powder metallurgy in the Soviet Union. 129-12-2/11
Card 4/5
alloys, P. I. Rebinder, V. I. Likhtman and I.N.Smirnova,
Institute of Physical Chemistry, Ac.Sc. (Institut
Fizicheskoy Khimii AN SSSR) contributed a great deal to
the study of the relations governing the structural
transformations in iron-graphite materials (Ref.16);
their results enable evolving a rational technology
for producing materials with an iron structure.
Bimetallic lead bronze liners on a steel strip base
and also trimetallic liners (steel base, powderedcopper-
nickel layer, tin babbite) were developed by
V. V. Saklinskiy, A. A. Kokorev, V. A. Khazov and
G. S. Konstantinov. Of great importance are welding
electrodes, the coatings of which contain waste steel
powders; their use simplifies welding and increases the
productivity by over 30%. A. S. Zaymovskiy and others
have developed sintered magnetic materials, particularly
the alloy alsifer (7.556 Al, 10% Si, 82.5/06 Fe~ The
technology of producing permanent magnets and pressed
magnets from alni and alnico alloys was developed by
Zaymovskiy, A. B. Alltman and others. Work on developing
magnetically soft cermet materials was carried out by
N. I. Frantsevich and his team in the Institute of

AUTHOR:-Samsonov, G. V. 73-3-1/24
TITLE: Intermediate Stages in the Formtion of Carbides of
Titanium, Zirconium, Vanadium, Niobium. and Tantalum.
(F.romezhutochnyye Stadii Reaktsiy 04razovaniya Karbidov
Titana, Tsirtoniya, Vanadiyaq Niobiya i Tantala.)
PERIODICAL: Ukrainskiy Rhimicheskiy Zhurnal, 1957, Vol.23, No-3,
pp. 287-296 (USSR).
ABSTRACT: Tensiometric measurementa were carried out on carbides
of the above listed metals in vacuum according to the
reaction:
MeX 0y + zC = Me XCz-Y + YCO.
X-Ray and chemical methods of analysis of the intermediate
and final products and the calculation of the approximate
values of their heat of f ormation verified the f orm~ation
of TiC and ZrC via the intermediate oxides Ti 2031 Ti 3059
TiO and Zr203 ZrO and also the formation of vanadium
carbides (from the V20 3 + 5C layer), of niobium and
tantalum carbides (from the Nb 205 + ?C and Ta 205 + 7C
layers) via the intermediate Aides VO, V 40 and TaO 22
Card 1/3

73-3-1/911-
Intermediate Stages in the Formation 6f darbides of Titanium,
Zirconium, Vanadium, Niobium. and TaAtalum.
Ta 0.,," The values of M~(=',chan e in heat content, cal/mole)
of T*
0 and TiO obtain4difrom' tensiometric. data are given
.2 3
in T, The tens 3*-Oil;.;;ric curve of the reaction
Oble 1.
Ti + 30 = TiC + 2C0 (d~ gram, Fi' . 1) shows not 3--but 4
9._
pre~-sure jumps. The fir.u occurs at 1.100 1 .150'0 $
the
se qpnd at approximate .' -. aef same tempe rature , the . %trd
betiHeen 1250 and 1300(,0 , id. the last at 1280 - 1320 C.
X-P-ay analy-sis of Iiven-in Table 2 confirm the
s= g
dada -obtained by eh m9cal analysis. Diagram,,Fig. 2
shQws the tensiometr cikrve of ZrO + ZrG = 2CO,
Wi't1h 3 Pressure jump TAe chemicai composition of the
lower Zr oxides is- gi'7en " Table 3. and line diagrams
obtaiiied-by X-ray- al"_-Lysis%hown in diagram, Fig. 3. It
is shqwn that ZrO a. cubical grid With an interval of
_..V ).-
4.63 X (viz. Table I Tensiometric investigations on
the conditions of fc nation of vanadium carbide were carried
oiA together wi-th G~.,, V. Moskalik (diagram, Fig. 4). The
heat of formation of vanadium carbides was calculated from
the co-ordinates of oints on the tensiometric curve
Card 2/3 (imTn diately precedi ig the pressure jumps) and are listed

F9
?3-3-1/24
Intermediate Stages in the Formation of Carbides of TitanWmf
Zirconium, Vanadium, Niobium, and Tantalum.
in Table 5- Further the formation of Niobium. carbide was
investigated and the relevant data are given in graph 5
and Table 6. Conditions for the formation of carbides of
niobium. and tantalum in vacuum are nearest in those having
the composition NbC and Ta0- Approximate values for LH of
the metal oxides are given. There are 6 diagrams, 8 tables
and 24 references, 12 of which are Slavic.
SUBMITTED: November, 23, 1956.
ASSOCIATION: Institut-hletallo?-Ce37dmie*.aiid-'-Special Alloys.
(Institut Metallokeramiki i Spetssplavov AN USSR)
AVAILABLE: Library of Congress.
Card 3/3

er
AUTHORS: Samsonov, G. V., and Popova.N. M. 439
TITLE: Preparation and Certain Properties of Thorium Sulfides
(Prigotovleniye i nekotoryye osobennosti. sullfidov toriya)
PERIODICAL: Zhurnal Obshchey Khimii, 1957, Vol. 27, No. 1) PP- 3-10 (U.S.S.R.)
ABSTRACT: Efforts were madelto improve the method of preparing thorium sul-
fides by direct combination of the thorium. with the sulfur.- A
thorium powder containing 99.8% of Th and thoroughly purified
sublimed sulfur were used as basic,matirial for the experimeints.
The first series of tests was conducted at temperatures ranging
from 400 to 8500 with intervals of 50 to 1000 with a running period
of about 30,min. Parts of the prodicts obtained were chilled in
the open airand parts in an H2S stream. During the ohilling of
reaction products in a hydrogen sulfide stream the sulfur content
increased sharply and the total.of Th+ S, reached 100%, especially
in experiments at 6000. The composition of procbets-obtained with
consideration of the abseme of free Th is Th 253- ThS-and Th2S,4
were observed to be the most stable sulfide phases in the Th-S
syztem. Results obtained by extending the reaction period from
Card 1/3

439
Preparation and Certain Properties of Tharium
Sulfides
30 to 240 min. are given in Fig. 2. Results obtained at ODOO
with a change in sulfur content in the initialbatch and 30join.
reaction time are presented in Fig- 3.- Certain physical,prvperties
of thorium sulfides were determined including their melting koint
which.was studied by direct meltirg of samples.
The melting of the sulfides at 2400 24500 and 23000 took place
without any noticeable decomposition. Special samples prepared by
calcination of the powder throulh hot molding were used for studying
the microstructure and microhardness of the thorium. sulfides. The
sulfides were seento react with the graphite of the molding forms
at temperatures much lower than those necessary for the conversion.
of the sample into solid state. Th 2S3 samples baked at 1960 20000
showed a diphase'structure. The Th2S3 'compound was alsdo found to
be a variable.composition phaae.,-extromely hcatogencouls and rangirg
from,-ThSI.22 to ThS, .59 The relation between the properties of
thorium. sulfides and ot~eranalogous compounds of intermediate
metals with metal-loidswas established. Attention is called to
Card 2/3

ASSOCIATION:
PRESENTED BY:
SUBMITTED:
AVAnAELE:
Card 3/3
Preparation and Certain Properties of Thorium 439
Sulfides
considerable stresses originating daring the calcinating by hot
molding which are slowly eliminated during ani following anneal-
ing of samples.
Three tables, four graphs and one illustration.
There are 20 references, of which 6 are Slavic.
Moscow Institute of Non-Ferrous Metals and Gold (Moskovskiy
Institut Tsvetnykh Metallov i Zolo.ta)
February 16, 1956

SOV/137-58-11-23268
iranslation from. Referativnyy zhurnal. Metallurgiya, 1958, Nr 11, p 203 (USSR)
AUTHOR: Samsonov,, G. V.
TITLE: Activation Energy During the Diffusion of Boron, Carbon, Nitr .ogen,
and Silicon Into Highmelting Transition Metals (Energii aktivatsil
pri diffuzii bora, ugleroda, azota i kremniya v tugoplavkiye
perekhodnyye metally)
PERIODICAL- Sb. nauchn. tr. Mosk. in-t tsvetn. met. i zolota, Nauchno-t~,khn.
o-vo tsvetn. metallurgii, 1957, Nr 30, pp 192-222
ABSTRACT- The process of diffusion of B in Ti, Nb, Ta, Cr, Mo, W, Fe, Go,
and grade-3 steellof C in Ti, Zr, Nb, Ta, Gr, Mo, W,, and Co, and
of Si in V and' in the original. Transl. Note) Ti was investigated.
Saturation of specimens.of the above metals* with B and Si was achieved
in a stream of purified H at various temperatures (from 1000 to 20000C
for 2 hours). it was established that the corresponding carbide, boride
and silicide phases are formed in the course of the diffusion. The cal-
culation of the coefficient of diffusion D was accomplished according
to the following formula: 'D(C' --C?) = C K where C is the amount of
1 0 h
Card I/Z B, Si, or C necessary for the transformation of I cm of the metal

SOV/137-58-11-23268
Activation Energy During the Diffusion of Boron, Carbon, (cont.
into the boride, silicide, or carbide phase, (CI-C?) is the difference of the concentra-
tions of the metalloid on the borders of the layers, and K is a quantity dependent on
the radius of the specimen, the thickness of.the diffusion layer, and the saturation
time. It was found that the activation energy of the diffusion of the metalloid into the
transition metals of a given group increases with increasing atomic number of the
metal. The activation energy increases during the transition from the borides to the
carbides and nitrides. These regularities are related to the magnitude of the ioniza-
tion potential of the metalloid and the degree of incompleteness of the CL -electron.
sublevels of the transition metals. The activation energies of the reactive diffusion
were compared with the crystalline lattice -energy of the corresponding carbide and
boride phases determined through calculations. The activation energy decreases
with the increase of the energy of the lattices which are formed upon the diffusion of
the phase.
L D.
Card 2/2
ips 1 10,11 ; I
A F_

SOV/ 137-58- 10,-Z0802
Translation from: Referativnyyzhurnal, Metallurgiya, 1958, Nr 10, p65(USSR)
AUTHORS: Sirota, N.N.-Eamsonov, G.V.. Strellnikova, N.S.
TITLE: Electrical Properties of Some Metalloid Compounds and Solid
Solutions Thereof (Elektricheskiye svoystva nekotorykh rnetal-
lopodobnykh soyedineniy i ikh tverdykh rastvorov)
PERIODICAL: Sb. nauchn. tr. Mosk. in-t tsvetn. met. i zolota, nauchno-
tekhn. o-vo tsvetn metallurgii, 1957, Nr 30, pp 368-374
ABSTRACT: The results of measurement of the electrical resistivity
and thermoelectrornotive force of a number of carbides,~ sili-
cides, borides, nitrides, and certain binary alloys thereof, all
Card I/ I
in a Cu-containing vapor, and of preliminary determination of
the magnetic susceptibility of a'number of two-component alloys
of these compounds are presented. The specimens for investi-
gation are made by hot extrusion. The electronic structure of
the objects of investigation is used as the basis for discussion
of certain results of the work. 1. Intermetallic cowpounds--Electricall~
properties 2. Alloys--Electr4cal properties R.A.

afloa (;i,) of ~iu
)
NbE6, nd th~iraltoy-_wesdetdi. by the increase in wt. ap,g
Sq. Cin I A specimens made of powdets, sint-xed and hot,
pressed, Annealed in If, and slqwly ei~iled in th-: furn"cr-
it wds rwalnized that the change-in-wl. inctlind was not ac-
cnrate but sufficlent fcc precAse, "lative values. Tile
'
r6utgenograAle d. of Nb% and 1113, used vrere 7.03 and
4.53 g./cr., resp. The plou of Ap vs. temp. were exponen-
tial functims: on semilog coOrdmatev they consisted of 2
Linear branches lotessmting at M*. Fbe rate o! oxidation z
above 6W* wns more raptd. This was attributed to a.
change in structure and a wcakeniog 4 the forces betiween,
the atom of thebody and the filnx. The plots of filat filick-1;

wide dilai it 59 6ql~ % NbBs an&TM.. The
0 Weft,
-
-
-
-
9 -2
12.9, X 10
X 10-1;
Zdox. X-.Io-- gjjsq.
,~m.
-
-
14
Th
ese resU
btdkate that the principles o oxidatiou
4
solid Wins. Of h"Wes am the.silne as those of carbides-

MEW.-.. A_~t- 5,

SAMSONOV. G.V., kandidat takhnicheskikh nPol , dotsent,
-1--
Boron carbide products. Vent.mash.37 no. 3:24-28 Mr 157.
(KIBA 10:4)
(Boron carOds)
m

V
AUTHOR SAMSONO-V _G.V. 20-6-:W5Z
TI TU Fe- the Tungsten-Boron System.
(Fazy sistemy vollfram - bor.- Russian)
PERIODICAL Doklady Akademii Nauk SSSR 1957, Vol 113# Nr 6, pp 1299-1301
(U.S.S.R.)
ABSTRACT On the occasion of the radiographical investigation of the
tungsten-boron system 3 borides were found in the beginning:
the tetragonal W23 and WB as well as the hexagonal W 2B5*
Later the existence of a high-temperature modification of
tungsten monoboride P-WB was determined. Aacording to publis-
hed data W2B ( I -Phase) kas very close homogeneity limits,
whereas (6-phase), has wider ones. The previously determine&
phase WB2 is probably identical with W 2B5 if there is a
deficiency of boron-atoms. For the purpose of a pricise de-
termination of the phase range of the tungsten-boron diagram,
the author investigated alloys of this system by the methods
of mioro-hardness as well as by methods of radiography and
metallography. The results obtained make it possible to sug-,
gest the following phase ranges of the tungsten-boron system:
CARD 1/2

The Phases of the Tungsten-Boron System. 20+Y459
1~ a-range of a very restricted solid boron solution in a-W.
2 two-phase range a plus 9,with the 9 -range having a very
restricted homogeneity range.
3) two-phase range g+ 6 (W 2B + WB)
4~ Homogeneity range of WB (6-phase)
5 two-phase range 6 + E (WB + W 2B
6) homogeneity range of W 2 B5which is probably very wide
which does not coincide with ZIESSLIWS data.
(1 table, 5 Slavic references)
ASSOCIATION: Moscow Institute for Non-Ferrous Metals and Gold "N.I.KLLININ"
PRESENTED BY: A.N. FRUMKIN, Member of the Academy.
SUBMITTED: 29.10. 1955
AVAILABLE: Library of Congress.
CARD 2/2

a Ive v
20-6-23/42
AU72HORSs Portnoy, K. I. , and Samsonov, G. V.
TITLEs Properties of Threefold Alloys TiB - CrB ZrB
2 2 2
(Svoystva troynykh splavov diboridov titana, khroma i tsirkoniya)
PERIODICALt Doklady All SSSRf 1957, Vol- 116, Nr 6, pp. 976 - 978 (USSR)
ABSTRACT: For the modern technical engineering of high mechanical stress at
high temperaturesborides of viscous rare metals are of interest,
because they show a strong hardness and resistance to abrasion as
well as stability toward acids. They shall be studied from systems
in which extreme values of these properties are to be expected
In literature data on the systems mentioned in ("he title are almost
entirely missed. Therefore the work under consideration has been
attempted on diboride alloys lying at a " beam cross section"
"luchdvoy razrez") TiB -CrB (50 z 50 mol.%) ZrB Since it was
(
'
K
known-t
and Zr form un-
hat borides of Ti and Cr, as well as of
interrupted series of solid solutions, meanwhile borides of Cr and
Zr are into one another soluble in a limited sense, it was inter-
esting to follow, how the solubility of CrB (?) in a solid solu
2
tion TiB 2- CrB compared to its limited solubility in CrB 2(? ) and
l
Card 1/2 its uniterrupie
d solubility in TiB22 and in reverse, vary itself.

20-6-23/42
a
- GrB
-ZrB
PtqXrtJAj of Threefold Alloys TiB
2
2
2
..Conclus-ion3i It has been state.d that the solubility of ZrB 2 in
E
, Cr)B 2 amounts to about 40 mol.%, whilst that one of (Tij Cr)B2
TI
in ZrB2 is below 10 md1%. The range of solubility of ZrB in CrB
raises at the decom
o
ition
t
fold b
id
f Z
B i
C
?Ti
)~
n a
s
o
r
wo
or
e
r
p
q
2*
Zirconiumboride forms together with a component of the latter .
(TiB2 ) an uninterrupted series of solid solutions. In the range of
the monophase of the solid 08 lutions of ZrB2 in (Ti,, Cr)B in a
d
l
h
f f
9
e uenc
e
o
rom 1900 there isamaximum of micro-
1rdnesss
samp
3900 kG~=2 (at 20 mol.% ZrB and a maximum'of electric resistance
(216/a /cm at 10 mol.% Zr%). There are 3 fig"resp and 6 re-
ferences, 5 of which are Slavic.
ASSOCIATIONt A3.1-Union Scientific Research Institute for Aircraft Materials
(Vsesoyuznyj, nauchno-issledovatellskiy institut aviatsionnykh ma-
terialov)
PRESENTEDs June la, 1957, by A. A. Bochyar, Academician
SUBMITTEDi June 7, 1957
AVAILABLE: Library of Congress
Card 2/2

CV Al .5 0 N -, \1
L
18(0,7) PHASE I BOOK EXPLOITATION SOV/2170
Alcademiya nauk Ukrainskoy SSR. InstItut metallokermiki i:spetsiall-
nykh splavov
V.oprosy poroshkovoy metall~rgii i prochnosti materialov, vyp. 5
(Problems in Powder Metallurgy arid Strength of Materials, Nr 5)
Kiyev, Izd-vo AN USSR, 1958. 172p. 2,000 copies printed.
Ed. of Publishing House: Ya. A. Samokhvalov; Tech. Ed.: V.Ye.
Sklyarova; Editorial Board: I.N. Frantsevich (Resp. Ed.), I.M.
Fedorchenko, G.S. Pisarenko, G.V.Samsonov, 6d V.V. Grigorlyeva.
PURPOSE: This collection of articles Is Intended for a wide circle
of scientists and engineers in the research.and production of pow-
der metallurgy. It may also be useful to~advanced students of,
metallurgical institutes.
COVERAGE: This collection of articles describes the results of in-
vestigations made at the Institut metallo keramikii spetsiallnykh
splavov, AN USSR (Institute of Powder Metallurgy and Special Al-
loys, Academy of Sciences, Ukrainian SSR). The physical and chem-
Card S?TN

Problems in Powder Metallurgy (Cont.) SOV/2170
ical properties of materials used in powder metallurgy are dis-
cussed. Materials described as new, production processes, and
methods and results of mechanical testing are described. No per-
sonalities are mentioned. References follow each article.
TABLE OF CONTENTS:
Samsonov, G.V., and V.S.Neshpor. Some Physical Characteristics of
Mefall--IlYe -Compounds.
The authors, describe results of investigations of microhardness.,
coefficient of thermal expansion, calculation of the inter-atomic
bond between the metal and the metaIloid, and factors affecting
this bond. They conclude that the hardness of the njetal-like com-
pounds is determined chiefly by the bonding forces between
the atoms of the metal and the metalloid.
Yeremenko, V.N., G.V.,Zudilova, and L.A. Gayevskaya, Chromium-
Niobium Structural Diagram 36
The authors describe the results of an investigation.of the
chromium-niobium system by thermal, metallographic, and radio-
graphic methods.
Card,*6

S-1/1-37/60/000/0 2/03/0 10
91ravislation from: Referativnyy zhurnal,. Metallurkiya, 1960, No 2, p -92, 2779 a,
AUTHORS: Meyerson,, G.A., Samsonov., G.V.
TITLE: On the Conditions of Obtaining Boron Carbide
PERIODICAL: V sb.. Bor. Tr. Konferentsii po khimii bora I yego soyedineni
Moscow, Goskhimizdat, 1958, PP 52 - 57
TM: The main condition for the preparation of high-quality B 4C powder
Is-the limitation of the temperature of the preparation process by the tempera-
ture of peritectic decomposition (2,200(?C)entailing-an increased amount.,of Cfre
in the B4C powder and reducing its,polishing capacity. The best industrial
method of B C production is the reduction of B,;,O3 with carbon in electric
resistance grnaces where the temperature of tRe process may be regulated. It
Is shown that fine-grained powder.of the theoretical composition may be obtained
by magnesium-:thermal reduction of B 203 at temperatures of 1,000- 1,4oo0c.
A.P.
Card 1/1

S/13T/60/000/02/04./olo
Translation from: Referativnyy zhurnal Metallurgiya, 1960, No 2, p 92, 2781
AUTHORS.- Meyerson, G.A., Samsonov G.V., Kotellnikov, E.B., V2povaL M.S.,
Yevte.yeva, I.P., 1Ta-snenk&V-a-. S.D.
Tl=: Some Properties of Alloys of High-Melting Transition Metal
Borides
PERIODICAL: V sb.: Bor. Tr. Konferentsii po khimii bora i yego soyedineniy,
Moscow, Goskhimizdat, 1958, pp 58 - 73
T-M-. Information is given on the production technology and results of
investigations into the phase composition and the structure of products of
diffusional interaction between initial borides of the TiB14 TiB2-W,,B,'l
- 2 C
anAr%-Cr, systems. The authors studied also microhardne phases, heat-
resigt-;-nce 0~ alloys and the structure of cinder of variouscomposition.
A.P.
Card 1/1

Translation from. ReferativnyY ahurnal. Khimiya, 1959, Nr 23, P 35 (USSR)
AUTHOR.
TITIE-.
PERIODICAL:
ABSTRACT-
Card 1/2
Sams ov, G.V.
\The Activation Energies of the Diffusion of Boron, Carbon, Nitrogen and
Silicon Into High-Melting Transition Metals
V sb.: Bor. Tr. Konferentsii po khimii bora. i yego soyedinenly. Moscow,
Goskhimizdat, 1958,, PP 74 - 89
Based on the roentgen- and chemical 'analyses as well as the measurements
of microhardness and weight change of,the samples, it has been established
that the diffusion of B into Ti, Nb, Ta, Cr, Mo, W, Fe and Co, of carbon
intd'hiPZr ANbY'1Ta,v1Cr,-1Mo,-1W andIlTo and of Silicon into Ti is an active
diffusion, i.e., it is accompanied by the formation of the pertaining
boride, carbide and silicide phases. Based on the microscopic investigation
of the thielmesses of the diffusion layers as well as on the data of the
regions of homogeneity of the pertaining phases and the results of the
chemical and roentgen-analyses,'the activation'energies have been calculated
and equations of the temperature dependence of the coefficients of diffusion
of B,, C and Si into some of the metals indicated were derived. It has been,--_,

SOV/81-59-23-81116
The Activation Energies of the Diffusion of Boron, Carbon, Nitrogen and Silicon Into
High-Melting Transition Metals
shown that the values of the activation energies of the diffusion of B, C and SI into
transition metals are connected with the value of ionization potential of the diffusing
metalloid and the degree of incomplete filling of the d-electronic sublevels of the
transition metals, and agree well with the physicalconstants ofthe transition metals
and the pertaining boride, carbide and silicide phases.
Authorls summary
Card 2/2

131-1-7/14
AUTHORS: Samsonov, G. V. , Neahpor, V. S.
TITLE: Production, Properties and Technical Use of Molybdenuri-Disilicide
(Polucheniye, svoystva i tekhnicheskoye primenenlye disilitsida
molibdena)
PERIODICAL: 06neupory, 1958, Nr 1, pp. 28 - 35 (USSR)
ABSTRACT: This is one of the most important difficultly fusible compounds
(:do Si 2) which in recent years are used at high temperatures. The
extremely high resistance to the influence of atmospheric oxygen
0
at a temperature of up to 1700 0 and other agressive gases, as
well as to acids and molten metals is to be considered its basic
property. Its properties and behavior at different temperatures
are described in detail; K. I. Portnyy also participated in these
tests. The behavior of Mo Si in the atmosphere of various gases
g
and in the air is represente
by the curves of figures 1 and 2 and
then exDlained. Molybdenum-disilicide is resistant to the action
of the following molten metalst sodium, lead, bismuth, tin, mer-
cury and other metals which do not form disilicides. Tabl- I shows
the resistance of I-JoSi to the oxidation in an oxygen flow at
12000C after Previous Keating in metal melts. h1oSi .
s inclined to
Card 1/3 .
creeping and is not sufficiently resistant to heat2shocRs ksee

131-1-7/14
Production, Properties and Technical Use of Molybdenum-Disilicide
table 2). The other mechanical and physical properties of MOM
are enumerated in detail and explained and its use at high temp
perature is described in, detail. Figure 3 shows a molybdenum heat-~
er with and without a MoSi 2-covering. There are many pos ,sibilities
of the preparation of Mosi -powder , the simplest one consists,of
a direct combination of mo~ybdenuat with silicon: Ho +23i = MoSi 2.
The tests of a direct synthesis were perforated together with N. M.
Popova. Up to a temperature of 1100 aC the tests were performed in
a laboratory furnace TK 30/200 in an argon atmosphere (figure 4),
at higher temperatures in a vacuum resistance furnace. In the La-
boratory of the Institute for Powder Metallurgy and-Special Alloys
AN Ukrainian SSR MoSi was prodwed at a temperature of 1000 0C and
one hour halt. I. D. Kadomysellskiy also participated in the ex-
periments. Figure 5 records the porosity dependence of the test
samples on the sintering temperature and figure 6 that on.the,.time
of sinterintr. Ficure 7 shows products of molybdenura-disilicide,o.f
the firm Plansee in Austria. Conclusions:
a) MoSi is ona of the compounds most resistant to scale' and chemi-
cal inHuences, which property is connected with its hi-h thermal
conductivity, hardness and stability. It is used for the produc-
tion of refractory products, heatproof alloys and covers for mo-
Card 213 lybdenuat products and for the solderinG of ceramics rrith metals;

. I . 131-1-7/14
Production, Properties and Technical Use of Mol-1-denum-Disilicide
b) the mozt suitable method of the production of -iiosi powder con-,
sists in the heating of briquettes of a mixture of mo~;bdenum- ana
s
Jlicon
L -povider in the course of 1 hour at a temperature of 1000 C
and the manufacture of products by hot preszing of LioSi -powder at
a temperature of 1900 0C. There are 9 fi-r-res', 2 tables,2and 27 re-
Q
ferences, 9 of which are Slavicv 7 German and-10 English.
ASSOCIATION: Institute for Powder Hetallurgy and Special Alloys AN Ukrainian
SSR
(Institut metallokeramik~i i spetsialtnykh splavov A111' USSR)
AVAILABLE: Library of Congress
1. Compounds-Properties
3. Compounds-Application
2. Compounds-Production
Card 3/3

129-1-8/14
AUTHOR: Samsonov, G.V., Candidate of Technical Sciences.
TITLE: -Ma-racterOf the Interaction of Titanium Boride- with
Metals of the Ferrous Group (Kharakter vzaimodeystviya
borida titana s metallami gruppy zheleza)
PERIODICAL: Metallovedeniye i Obrabotka Metallov, 1958, No.1)
pp. 35 - 38 (USSR).
ABSTRACT: Chromium carbides, although having a relatively high
chemical resistance interactwith titanium carbide forming
ternary phases C-Ref.2') and, for instance, for such systems as
TiC-Si a eutectic type of diagram has been observed which is
obviously linked with the low loss of free energy during Sic
formation. The author considered it of interest to investi-
gate the relation of other Ti compounds (borides, silicides,
nitrides) with metals of the ferrous group. In this paper, the
interaction was investigated of titanium boride with Fe, Co
and .6i. Since the work was not aimed at detailed investi-
gation of these systems~atechnique was applied which is des-
cribed in a paper by A.N. Zelikman and D.S. Bernshteyn [Ref.4-1,
utilising titanium boride powder produced by the vacuum thermal
method [fZef - 51 and containing 68. 90'16 Ti , 31- 02% B and 0. 02016 Cfre
Card 1/Snd powders of Fe, Co and Ni which have been reduced by hydrogen

129-1-8/14
Character of the Interaction of Titanium Borides with Metals of the
Ferrous Group.
titanium boride as compared to systems containing titanium
carbide. This is attributed to the presence of strong,
covalent bonds in titanium boride which levels out the diff-
erence in the behaviour of boride in its interaction with
metals of the ferrous group. It is possible, in principle, to
utilise titanium boride as the hard component of metallo-
ceramic sintered carbides. There are 5 f igures, 2 table s - and
5 references, 3 of which are Slavic.
ASSOCIATION: Institute of Metallo-Ceramics and Special Alloys,
Ac.Sc. Ukrainian SSR (Institut Metallokeramiki i
Spetsplavov,AN USSR)
AVAILABLE: Library of Congress.
uard 3/3
- --------- --- -

AUTHORS.- --Samsonov, G. V., Candidate of Technical 64-58-2-8/16
_
Sc7J
en_c-e.-,-Zr5-tTi-n, S. Ya., Candidate of
Technical Sciences
TITLE; Powder 1,,ietallurgical.Materials for Chemical Industry
(14letall.okeramicheskiye materialy dlya khimicheskoy
promyshlennosti)
PERIODICAL: Khimicheskaya Promyshlennostf, 1958, Nr 2, pp. 42-46 (ussa)
ABSTRACT: The present paper gives a survey.on the kinds of production
as well as on the various types of finished products of pow=
der metallurgy. It is mainly foreign processes and finished
products which are mentioned. In the production of powder
the authors point out the importance of structural charac=
teristics,as well as ofthe size of particles, with physi=
co-chemical and mechanical methods of production being men=
tioned. A~table of the characteristic features of metal
powders obtained-by different methods is given. The-Dres=
sing and sintering of metal.powder or powder mixtures re=
spectively are carried out either simultaneously or by
soaking the porous pressed article in liquid metal, or
Card 1/4 also by means of a pressing into bands and other forms