SCIENTIFIC ABSTRACT SAPOZHNIKOV, YU. P. - SAPOZHNIKOVA, R.G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001447130014-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: July 13, 2001
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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L 51844-65 EWVm)/FWG(m)/EWP(t)/EWP(b) IJP(c) RDVI/JD/JG
ACCES-SION NR: AP50liBO9 I-rP/'008()/65t'038/004/0717/0720
546.23+546.65
AUTHOR: Markovskiy, L. Ya.; Soboleva, M. S.;
,a2zhnikov, Yu. P.
TITLE- Preparation of rare earth selenides by reduction of selenites
SOURCE: Zhurnal prikladnoy khimi
v. 38, no. 4, 1965, 717-720
TOPIC TAGS: rare earth compound, selenide, lanthanum compound, cerium compound,
praseadymium compound, gadolinium compound, neodymium compound, reduction method
k
ABSTRACT: Selenites of lanthanum, cerium, praseodymium, neodymium, samarium, and
were reduced with a mixture of hydrogen and hydrogen selenide at 600-C,
5-lenides of the general formula M2Se3, Hydrogen selenide was used to
the F-~r7o_ti-_)n of oxyselenides, which were present In the reaction products
W-11 11. 11_1~_Igen al-ne was used. X-ray phase analysis of all products sbowe~ .ra-if-us
I an t han, im
s~ Phases 'in the czwe of each rare metal. The powder figures for
i-arium palvselenides had the same system of lines and nearly the same inten-
t -a" Jlffe:,ed in nterplanar dist-3nces. Such J15taTICeS f,.-r the'pcwder pat-
--rr~F - :lolyselenides of cerium and the other rare earth elements occupy an inter-
Card 1/2

25(6)
AUTHOR:
TITLE-
PERIODICAL:
ABSTRACT:
11-larJ 1/2
SOV/9--59-5-19/27
Sapozhnikov, Yu.M., Engineer
On Thermal Efficiency of.Steam--Poi,.,er.Installati6ns
of ST Type (0 teplovoy ekonomichnosti parosilovykh
ustanovok tipa ST)
Energetik, 1059, 1Tr 5, pp 32-33 (USSR)
In small enterprises not conneoted with outside
thermnl and electric networksi the themofication
aggregates of 5T type work in accordance vith
electric chart and their efficiency direG-tly depends
upon parameters of used steam and the graphs of
steam loads. The author examines how to find the
most economi--al consumption of steam by means of
a U"' balance equation
(.T
N c-r-( int t n-is' C'L r-K -Nlr~v. (int-
K
wb-erein --AM!"i-c' the utuillzod heat oC used steam,

SOV/92 -.qg-5-19/27
On Thermal Efficiency of Steam-Power Installations of ST Type
and d are specific expenditures of steam.
d
or ST anti 'K In kg/e.'.s./hour; N., ancl IT are
ck
viers of ST and SK h%"r-slopo --11;
p C,
.0k
n. r7. -re temperaturel- of fead wat-'r
El. - e,,
of tho boiler amd locomobiles ST anal SK in 0;
i is the cont-ent of heat in overheated steam
K
of both locomobiles in large calories per kg; 1j, is
the content of heat of saturated steam from
the boiler, in large cal'ories per kg. The Lyud-J--
novskiy loicomobil'nyy zavod (Lyudinovo Locomobile
Plant) is mentioned in the texct.
Card 2/2

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Wal L
Wation W. Mde. &AL.R.

85622
IZO% IZIS, 110%5 B/078/60/005/012/003/016
13017/3064
AUTHORSs Markovskiyq L. Yu., Sapozhnikov, Yu. P.
TITLEj Some Properties of Lead Selonite
PERIODICALt Zhurnal neorganicheskoy khimii, 1960, Vol- 5, No- 12,
pp. 2655-2661
TEXT: Lead Belenites were prepared by the following m,-.thods:
a) Reaction of lead nitrate or lead acetate with potassium selenite
in the stoichiometric ratio,
b~ reaction of lead acetate with a solution of seleniousacid,
c reaction of lead nitrate with an excess o f selenious acidq
d) reactiorL of lead-carbonate with selenious acid.
Acid lead selenite Pb(HSeO 3)2,was formed by the methods b), c),'and. d).
Lead biselenite PbSe 0 was prepared by heating Pb(HSeO The
215 3)2 to 130oC
best method of synthesizing lead selenite is that of precipitating from
a solution of lead acetate with selenious acid or potassium selenite.
After the synthesis, the following compoundB were separatedt PbSeO37
Card 1/3

85622
Some Properties of Lead Selenite S/07 8/60/005/012/003/016
BO17/B064
Pb(HSeO and PbSe 0 Moreoverythe double salt PbSeO Pb(NO was
3 2 2 5* 3* 3 2
separatedv and its occurrence confirmed by chemical and X-ray phase
analyses. The lattice parameters of the compounds are given.,Microphoto-
graphs were taken of the individual forms of lead selenites. The thermal
stability of lead aelenites was studied.,The-differential-the=al curves
.were determined with an EIIV-09 (UP-09) recording electronio potentio-
meter, and with an OK-54 (-FPK-54) Kurnakov pyrometer. The thermograms
of PbSeO show two endothermic effectst the melting point lies at
3
675�1000, and SeO2 Iforms at 790-8300C. At 4-10OCp a strong endothermic
effect appears on the thermograms of the double salt? indicating the de-,
composition of this compound. When further.heatedp the reaction product
melts, and at 690-7000C Se02~vapors form in a considerable amount. An,
endothermic effect appears at 110-1200C on the Pb(HSeO 3)2 thermogram, cor-
responding to the dehydration of this compound. On further heating of the
dehydrated product, SeO vapor is generated at 3800C. There are 6 figu.'resg
2
3 tables$ and 17 referenceag 9 Soviet.
Card 2A

m

20020
S/081/61/000/002/006/023,
2L,1 o 11 AOO5/A1O5
Translationifrom: Referativnyy zhurnal,,Khimiya, 1961, No. 2, p. 320, 2K101
AUTHORS: Markovskiy, L.Ya., Sapozhnikov, Yu.P.
TITLE: The Development of Cathode P=osph~�rson~ Basis of-Certain Metal
Oxides
PERIODICAL: "Sb.tr.Gos. in-ta prikl. khimii" 1960, No. 43, pp. 92 100
TEXT: The expediency.of the application of mineralizers to the synthesis
of the lum:Lneseenoecomposition MgO.-Cr:LiC1 is shown. It is found out that the
composition MgO:Cr:LiCl has.relatively low emission intensity in thevisible spec-
trum range and is of importance only as an i.r.-emitter. The lumineseerm compo-
sition Al 20 -Cr has high emission intensity in the visible spectrum range (X max
690 mt) ana*does not yield to the lumineseerxe composition Zn Mn with res-
(P04)2:
0
peat o the-magnitude of the relative emission brightness. 2:b sh6wn that it is
possible to obtain new luminescerm compositions with.a. wide emission band, a large
part of which lies in the red spectrum region by mixing oxides of Zn and Mg. There
are-13 references. R.A.
Translator's note: This is the full translation of the original Russian abstract.
Card 1/1

29532
S/078/61/006/011/010/013
BIOI/B147
AUTHORS: Sapozhaikov,---Yu. P., Kondrashev, Yu.~D.f Markovskiyj L. Ya.,
Omellchenko, Yu. A.
TITLE: Study of phase composition and luminescence properties of
the system ZnO -MgO,,ac'bivated by chromium
PERIODICAL: Zhurnal.neorganicheakoy.khimii, v. 6, no. lit 19611, 2550-2 557
TEXT; On the ba sis of.A.paper by A. L. Smith (see beio'#) who at udied
the luminescence of nonactivated MgO 'and ZnO miktures,-the authors
examined the syst.em MgO -ZnO activated with 0.5 ~.of Cr (added as
ammonium bichromate). The mineralizer added was 3 % LiCl. Samples were
produced at 1100 and 13000C. ~ Powder patterns were taken by.a YPC-50-~4
(URS-50-I) apparatus. Two limited solid solutions were found: Zn(Mg)0
and Mg(Zn)O with the structure of the.initial components. The unity cell
volume of the solid solution Mg(Zn)O increases continuously. The
,incorporation of Mg ions into the hexagonal structure of ZnO causes a
slight increase of parameter a and a considerable decrease of parameter c;
thus, the unit cell volume is reduced. The upper limits of existence of
Card 1/3
Chromiura i Sq

S/078/6i/006/011/010/013
Study of phase composition and.i.
activator of ZnO and of solid Zn(Mg)0 solutions. A paper by
G. S. Zhdanov, V. A. Pospelov (Dokl, AN SSSR, lit 97 (1953)) is mentioned.
There are 4 figures, 2 tablest and 10 references: 4 Soviet and 6 non-
Soviet. The two most recent references to English-language publications
,read as follows.~ A. L. Smith, J. Electrochem, Soc,, 55, 155 (1952);
W. A. Runciman. US Patent no. 2736712, February 28, IT56.
ASSOCIATION: Gosudarstvennyy institut prikladnoy khimii (State Institute
of Applied Chemistry)
SMUTTED September 30, 1960
Card 3/3

ACCESSION URt AP4029185 9/0076/64/009/004/0856/0866
oir
I'AUTHOR: Markovskiyp L. Ya.; Sagjqrhn.Lk Boyev X. Is
TITLE: Bismuth Selenites
SOURCE: zhurnal neorganicheskoy khimii, v. 9, no. 4, 1964, 856-866
lenite, synthe is, composition, the Bi sub'V
TOPIC TAGS: bismuth se s rmal stability,
(Seo sub 3) sub 3, bismuth selenite, bismuth selenite monohydrate, Ri sub 2
(Seo sub 3) sub 3,11 sub 2 0, Bi sub 2(SeO, sub 3) sub 3.H sub 2SeO sub 3, Bi sub 2-1
(SeO, sub 3) sub 3 SeO sub 2, BL sub 2 0 sub 3.SeO sub 2, Bi(NO, sub 3)SaO sub 3,
Ai sub Z(SO sub 4; (SeO sub 3) sub 2, Bi(CH sub 3COO)SeO sub 3. thermogramm V
bismuth s ous acid, crystal mLcroph
elenide, BiSe, Bi sub 2Se sub 3, seleni oto-
graph, x ray analysis
ABSTRACT: The conditions for synthesizing bismuth selenites, their phase composi-i
tion and thermal stability were investigated., Reaction between H2SC03 and
bismuth nitrate, sulfate, acetate, chloride, susp nsion: of bismuth oxidesp hydroxi.
I ide, basic carbonate and,cLtrate were run. The Matence of the neutral selanits
BL2 its monobydr&teAL2(3603)3-H2O and its crystalline acid "it
(Se03)3,
i Ca'd

r
1 ACCESSION NR: AP4029185
is best prepared~b
Bii(Se63)3.H,SeO was confirmed.* BL2(SeO )3 y.reaction, of~
c,3 bes
se enLous ac d with bismuth nitrate or trate. Two new selenites Bi
2(SeOj eO3
and B12O3.SeO2 were identified, as well as selenite double salts with nitric,
i sulfuric and acetic acids: Bi(NO3)SeO3, B12(SO4) (SeO3)2d' Bi(CH3COO)SeO3- Hicro-IL
photographs of these various selenites are shown. X-ray at& is given. The
thermal stability of these selenites was investigated (thermograms; are shown in
figs. 1-6) and explanations are given for the various endothermic and exothermic,
effects observed. The bismuth selenides:BLSe and Bi2Je are formed on heating 4.
the.noutral or acid bismuth selenitee in hydrogen or calbon monoxide:
Bit (560s)o + 914 2BiSe + 911g0
~vw
Big (SeNt + I)CO Dlfse~ + FA
Orige art@ has: 8 figures, 4.tables and 2 equations*
2/8

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ACCESSION~ NRt AP4029185 INCLOSURE 1 01
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Card 4/8

L 1-0532-4~ EWT(m,)/ (b) 'r ct
EWP
ACCESSION NR: AT4044996
AUTHOlk SaiDozhnftv, Yu. P*
TITLE- The crystal'bydrates of neutral cadmium selenite and their thermal
decomposition
SOURCE: Leningrad. Goi;udarstvenny*y,inbUtUtprMadwykMmll, TA**---n* 51 -100C
1 1. . 0 & - P , -
Khimiya I teldmologlya lyuminoforov (Chemistry and technology of lundu9j*rs) 3449.'~
TOPIC TAGS: luminophor, cadmium'selenh
fe,leadmium selenite, ned'racidmium.
selenite, crystal hydrate, cadmium selent Trieduction
ABSTRACT: Since the usual method of preparing CdSe lunitni6phors involvios the high-
temperature reduction of cadmium selenite by hydrogen, it appeared Important to
the thermal stability of the various pbases of cadmium selenite and Its hydrates. In the
present paper, the crystal hydrates were obtained by reacting a solution of eadmimn
sulfate with a stoichlometric amount of sodium or potassium aelenite after the preliminant
i-11 nf I // 10 Vie statchlometric amount of selenious acid. After 10- 15 days, colorless

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ACCESSION NR: AT4044995
obtained, which are attable at rdom t6inperature. The lattied parameters and chemical
romposition of these crystals and of a(-CdSe03 are tabulated. Heating of these crystals
t 1 ()0- 11 QC fo r one hour also did not change thel r phase or chemical composition. At
higher temperatures, however, endothermic dehydration took place, witi, acdgeOLL-2-HY12L
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MARKHININ, Ye.K.; PAPOZENIKOVA, A.M.

1. Vaesoyuznyy institut zashchity rasteniy, Leningrad.

BEKHTEPMA, M.N.; MEDVEDEVA, G.A.; POaFZCVA M.N. i SAPOZHNIK Up G.A.,-~~,:-
FEOFILOVA, Ye.P*
Rapid method of detecting bacterial Infection in culture fl
during.the produetio of treptomycin, Prikl. biokhim. I
n
(MIRA
mikrobiol. 1 no. 6:726-730 N-D 165.
1. Institut mi ohiologii AN SSSR., Submitted Dec. 24y 19(40
-Z
W
-k,

SAPOZHNIKOVA, L. V.; YEGORSHPIA, L. A.; EBERTS, V. L.; SBEROVEROVA, L. P.

SAP07.HNIKOVA, M.A. (MoRkva)
ORteonalacia in a man with Iranconifs syndrome [with summary in English].
Arkh. pat-20 no.4:81-86 158. (MIRA 11:5)
1. Iz patologonnatimicheakogo otdeleniyn (zAv.-prof. A.V. ISmollyannikov),
Nnuchno-issledovatel'skogo institutR imeni N.V. Sklifosovskogo (dir.-
zasluzhenW vrach USSR N.M. Tarasov)
(METABOLIC DISEASES, case reports
Fanconi's rachitic synd. with osteomnlacia, postmortem
pathol. (Rus)
(OSTBOKALACIA,
in Fanconi's rnehitic synd., postmortem -pathol. (Rua),

Cancer of the esophagus developing after Imrns caused by caustic
soda. Vop. onk. 9 no.11:91-,95 163. (MIPP 18:2)
1. Iz patologoanatomicheskogo otdeleniya (zav.- daktor med. na-A
N.K. Permyako-v) Ilauchno-issledovatellskogo instituta skoroy
pomeshchi imeni Sk-Lifosovskogt) (gla-myy khlrurg instituta-
chlen-korres-pondent AM B.A. Pal.-rov, dir.- zasluzhemlyy vrach
UlrSSR M.M. Taraz~ov). Adres avtora; Mo8kva, I-101 B. Kolkhoznaya
ploshchead', 3, Nauchno-iasledovatellskiy institut skoroy
p0moshchl imeni Sklifosovskogo.

KPMEVSlaY, N.A., pro".;
Proceedings of the Mosco-4 Society of Pathologists for the First
half of 1.964. krkh. pat, 27 nc,5987-94 165.
(MIRA 18-- 5)
3. Frodsedatell Moskovskogo obsbahestva patologoanatomov (for
Krayevskly). 2. &-krotarl Mos~ovskvgo obahchestva patologo.-
anat,~mov (for 9apczbn-4k,-,va).

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...

S/53/60/003/003/019/036/XX
Bo16/BO58,
AUTHORS: Dariyenkos N. I~, Sapozhnikova
TITLE: Kinetios of the Nuc~lecphilic Substituti-cr. of Halogens in
Halcgen-substituted A,,etates and the Influence of Halogen
A-;cumulation a' the Place of Subst.f.tution on- the Mobility
Df the Halogsn
PERIODICAL: Izvestiya vysshikh uchs4bnyk-h zavederify. Khimiya i
khi-micheskaya tekhnologiya, 1960,,Vol~ 34 No- 3,
PPz 46+1 46r-
TEXT: it was the aim of the authore to characterize the inf luence of
the halogen a coumulating a' the substitut`cn pla,,e in a comp-letely
quantitative way. They -~~ve a similar characterist-to of the. influence
C
of the haloge
r~_ on its mobillty in r e a c t fc, n
n natu s of nucleophilic
sunstitution during the interaction ---)f the halcgen aceltatea with
hydroxyl ion, and ammcmia. Sinciz the corresponding data by c-ther Ecien-
'-istls for the reantion: CH HalCOO OH CH 'OH)COO'- + Hal- (1) differ
9 9
Card '/4

I Nucieop~-_'Ilc Subst"u'
K4ns',fts c S/1:~3 6010034100310191036AX
9 n - .5 u b s t it e d c;;)3
f Halog-~nB ~n Halo-
Acetate5 ana the Influence.cf Halo.-an Acrum-ulation EL' -the P I a
SutstitT.-ztioa or the Mcbiltty of the Halcgen
Mor
widely, -,he authors determined fo-- this reaotion ""he ratty constants
0
Several tqmperature val--aes bstw,;.,!~n 6o qnd 96 C. Or, the basis cf -~he
Fituno halogert iv~etatonl the ron,t.ion wan atudie(l wli,h- anotshor nualoar
reagens, i.9. ,.-iqup, 4 a d 600C. The number of
-ous ammoniac betwo(ar, ^5 r,
c.hargss remains unshanged in phaae (I ) which determines the rea3tion
rat;--- bu~ a new di4stz:I'but-_'o,-t of the ~~harges in "'he intermediate complex
:~ccura, One r_~harge -~_f the hydrcxyl-ion is t.ransferred here to the
ha-loger: H-0 + GH 2CICOO H-O.... C .... C1. H0I'H coo (2)
O-C__0
At the ammonc~lyais; partial -charges in the antermi2di-,ate comr-lex:
H H
454- +
ITH + CH CI (31
3 2 'COO H N....C~ ... C-1 H N CH-COO + ei
3 1
Card 2/4

Kinetics of the Nucleophilic Substitution S/153/60/003/003/019/036/xx
of Halogens in Halogen-substituted B016/BO-8
Acetates and the Influence of Halogen Accumulation at the Place of
Substitution on the Mobility of the Halogen
develop in the phase which determines the reaction rate. On. the basis
of these data, the authors characterize the kineti,-'s of nuclear Bubsti-
tution of the halcgens in mono-substituted acetates in dependence on
the nature of "he halogen concerned, in the following way: 1) In the.
reaotions with the hydroxyl-ion and ammonia, greatly differing with re-
gard to their mechanism, iodine is much less mobile than bromide
(Table 1). 2) The authors proved that tbe.ammoi.o1.ys1s reaction is
ateadily SIC-Wed down by the acoumulation of .,-.hlorine -r. the chlo_~Jlne
aoetates, since the activation energyincreases (Table.3)- 3) The
periodicity" by P. Pet-renke-Kritohenko (Refs. 5,6) concerning the in
flaer---%e of halogen accumulation in chlorine acetates on.the mobility of
this halogen in the reaction with alkali, was confirmed.(Table 4). The
authors presume that the lincreased reactivity of chlorine in. trichloro-s-
a~7;etate is connected with''the change of the reaction mechanism, They
did nc-t succeed yet in studying the nature of this reaction (its pro-
dvt~ts, phases) more closelyi The authors drew the above conclusion from
the aralogy with the data by J. Hine (Ref.7) on the increased reactivity
Card 3/4

Kineti3s of the Nusleophlliz~ Substitw.ion S/153j6O/OO3/003/019/036/XX
of Halogenz in Halogen-substituted BO-,6/BO58
Acetates and that Influsni,;e of Halogen Accumulation at the Place of
Subatitution on the Mobility of the Halogen
of +,he chlorofoi-m in the rea,-tion. with alkali. They mention the paper by
M. B. Neyman~ V. B. Miller, and Yu. M. Shapovalov (Ref.8). Thsre are
4 t-ab'_11-pa and 11 references: 5Soviet, 2 US, British, and 3 German.
ASSOCIATION: Urallskiy politekha-icheskiy institut im. S. M. Kirova;
Kafedra fizicheskoy i kolloidncy khimil (Ur-al PolytechnIc
Institute imeni S. M. Kirov; Chair of Physical and Colloid
SUBMITTED: October 2,1, 1958
Card 4/4

I
. . . . . . . . .. . ..
ACC NR. Ap70081J3 SOURCE CODE: ~_R/6620/67/172/00L~1083 7_/0840~ 7,
AUTHOR: Androyev, S. N. V.
ORG; leningrad Institute of Textile and Light Industry in. S. X. Kirov (Leningrad-
s
kiy institut tekstillnoy i legkoy promyshlezinosti)
TITLE: Coordination equilibria in the system Cu~"'-aq HC1 H20
SOURCE: AN SSSR. Dokla 67, ~37-840
dy, v. 172, no. 4, 196
TOPIC TAGS; copper compound,, absomtion spect coordination chemistry, chemical.;..
rum
equilibrium
OUC14
.ABSTRACT: Electronic absorption spectra of the crystals, Cs2CUM4, 1(CF,3)41112-
th
and 1(C2H5)41N12CuCl4, which differ in the size of the cations located outside e
a iu
coordination sphere, were studied. Thespectra showed that a decrease in the r d S!,
2
of the cation outside the sDhere causes a shift of thb absorption bands of [Cu
C141
ions into the high-frequency range, the form of the spectral absorption' curves re-a
maining the same. This leads to the assumDtion that the electronic absorption
spectrum of the system Cu?-+.aq - HC1 - H26.at-C ~-12 M is due to the formation
HCl
of tetrahedral complexes [CuC1412- in the solution. 'A change in HCl concentration
from 10-4 to 20 M in.solutions of salts of divalent copper involves the following
processes: ?
ICU (H20),113+- ICU (Hj0J13 C11+ - (CU(1TM0hC1.21:;t ICU (H20)3C131-
ICU (H2OhC41"-tr'"S +_
(CUC141t -i-IfIA114-1 ... CUCI$..
Card 1 /2 13nc *. Aj e. A4

0

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- I I - . - I I - -
li

MW/ Chemistry Spectral ar~,:-
..........
Card 1/1
Authors
Title
Submitted

SAPOZHNIK
Hicroclimate of the classroom and its significance for the condition
of students. Pediatriia 39 no.1:45-49 Js-F 156. (MM l0a)
1. Iz otdela gigiyV Hauchno-icaledovatellskogo pediatrichookogo
institute RSFSR.
(CLIMATZ,
microolimate of class-rooms, determ of @ff. on students)
(VINTILATION
class-rooms, eff. of microclimate on students)