SCIENTIFIC ABSTRACT SEMENOVSKIY, A.V. - SEMENTINOVA, N.B.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001547910008-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

E N F- N C~~
,IV )~J-
AUTHORS: Nazarov', I. N., and--~--menovskiy, A. V. 62-1-14/21
TITLE: About the Tendency of the Chloromethylation Reaction (0 napravlennosti
reaktsii khlormetilirovaniya)
PERIODICAL: Izvestiya Akademii Nauk SSSR Otdeleniye Khimicheskikh Nauk., 1957,
No. 1, pp. 100-111 (U.S*S*Rq~
ABSTBACT: Various types of aromatic compounds were investigated to determine
the trend of the chloromethylation reaction. Employing the oxidation
method, a structural analysis was made of the products obtained from
chloromethylation of ethyl ester of phenylacetic acid benzyl chloride,
ethyl benzene, cumene, tertiary butyl benzene and all four monohalide
benzenes. All cases (with the exception of tertiary butyl benzene
showed the formation of mixtures of ortho-and para-isomers with a
quantitative ratio depending to a large exl;ent upon the nature of the
substitute. The results obtained (with respect to the trend of the
Card 1/2 reaction) were found to be analogous with results obtained during

62- -a
About the Tendency of the Chloromethylation Reaction 1 14/21
nitration. It was observed that, during tv chloromethylation of
toluene, ethyl benzene, cumene (isopropyl benzene) and tertiary
butyl benzene., the content of p-isomrs increases gradually in the
mixture, which is explained by the volumetric effect of the sub-
stitutes (steric factor). During the chloromethylation of benzene
halides., the amount of para-isomers decreases slowly during the
change from. fluoro- to iodobenzene., wh_Lch is determined by'ionizing
effect of the halogen atoms. It was concluded on the bases of obtained
results that the chloromethylation reaction belongs to the electro-
philic substitution type of reaction.
Tables. Thera are 15 referencesY of which 3 are Slavic
ASSOCIATION: Academy of Sciences of the USSR., Institute of Organic Chemistry
imeni N. D. Zelinskiy
MESENTED BY:
SUBNITTED: April 6, 1956
AVAILABLE: Library of Congress
Card 2/2

NAZAROV, I.N.; SEMENOVSKIY, A.V.
Bromomethylation of aromatic hydrocarbons. Ixv.AX SSSR. Otd.khim.
nauk no.2:212-216 F 157* (MLRA. 10:4)
1. institut organichaskoy khimli im. N.D. Zelingkogo Akademli
nauk SSSR.
(Hydrocarbons) (Ethylation)

- -11 - 14
-~,- le- /1-11, 47*~Y6 I'll -)- - - I V,
NAtARby, I.k.' rd..Z~dj;,w
The mechamism of the haloidmethylation reaction. Izv. AN SSSR. Otd.
khim. nauk no.8:972-975 Ag 157. (MIRA 11:2)
1. Institut organichaskoy khimii im. R.D. Zelinskogo AN SSSR.
(Chemical reaction--Mechapiam) (Mothylation)

NAZAROV, I. ~bdeceasedj; SEVINNOVSKIY, A.Y.; KARMWITSKIY, A.Y.
Prepamtive metho~A?d-~~e =yn~h~~ifis of nitr1les using acetoncyano-
hydrin. Izv. AN SSSR. Otd. khim. nauk no.8:976-979 Ag 157.
(MIRAL 1l-.2)
1. Institut organicheakoy khimii im. N.D. Zelinakogo AN SSSR.
(Iaobut.vzonitrile) (Acetonitrile) (Toluene)

NAZAROV, I.H.- SM-
Freparation of aromatic acids by oxidation side chains of aromatic
compounds with nitric acid. Report No.Z; I'zv. AN SSSR. Otd. khim.
nauk no.9:1101-1104 ff 147. (MIRA 10:12)
1. Institut orSauicheskoy khimii im. N.D. Zelinskogo AN SSSR.
(Aromatic compounds) (Nitric acid) (Oxidation)

NAZAROV, I.B.; SEMENOVSKTY, A.V.
Steric factor in electroph~lie substitutidareactione of aroratic
hFdrocarbons.,Izv. AN SSSR Otd. khim. nauk no.10:1229-1234 0 '57.
(MIRA 11:3)
1.Institu,t organicheakoy khimii im. N.D. Zeilinakogo AN SSSR.
(Stereochemi8try) (Substitution (Chemistr7))
(Aromatic compounds)

5(3) S07120-124 ~ 5-`31-6;
I
AUTHORS: Smit '~ V,, A , Semenovskiy, I.- V. ,
Medvedeva, V., M", 153cherov. 7-F,
TITLE, On the Cyclizattion Character of the Pseudo-ionon (0 kharaktere
tsiklizatsi-i p.,r-vdoionon%-%).. A New M'ethod of Producing the
CL-Ionon (Novyy metod polucheniya- (X-lonona)
PERIODICAL; Doklady Akademii nauk SSSR, 9,59, V,31 124~ Nr 5, pp 1080-1082
(USSR)
ABSTRACT: As has been proved in numerous publications (Refs 1-8)1 the
pseudc,iclnon is i~,onverted tc a m'L-xture of a- and P-ionor. under
the action of various acids~ The a~atio between the resulting a.-
and P-iscmers dapz~nds on the nature of the cyclizing agent, For
P-ionon concentiated sulphuric. acid in ether or in acetic acid
is the specific cyclizing agent whereas this role is played for
a-ionon by 60 ~of sulphuric or phosphoric ac.Jdq preferably by
boron trifluorlde. The statements made in Dublications seem to
that the a-somer forms the original reaction Droduct
almox3t in all ,,ases independently of the nature of the agent
(Refs 9-13) and*o-an be converted to the stabler conjugated
M
system of the P-isomer under the aution of acid agents. Thus,
card 1/3 the spectwfi-~ activity of various cyclizing agent is restricted

On the Cyclizatior. Character of the Pseud,:--Loilors SC.V/20-12A-5--33/62
A New Method of Producir,3 the a lonon
to thel"r 1--e-ater of smaller alhil-ity of isomerizin.- the initialLy
formed a-isomer.- In order to give experimental proof of this
assumption the s.lathors have studied the cyclization of t'he
pseaudo-ionon by 100 % H2 so4 be-~weeh +600and ~60c., 111-t-romeihane
or nitrc;Dropane were used as solvents. The destillate obtained
in a vacUum ras analyzed with the aid of its ultraviolet spec--
-rum lobtained w-~t.h the assistance of T, 'J,. Padeyeva)(Table 2).
It 's a-
pDarent 'Prom '.he results 'Table -1) That the ratic, be-
,ween the a~ anri ~-icnona fo-_-med is entirely determined by the
n conditJons, ramely., -the residence timej teMDerature,
and the amount of H2SO 4' This shovis clearly that the Dr_-alary
Drocess in the cYcliZation of the P::-,eudo,-ionon is the formation
Gf thi Depandim- or, the -:;onditiciis of the reac~tlon
th 4S is more cf less r 'somerizat~on to form the
onverted by i
P-ionon, Thus, the reactions whereby these isomers are formed
are sequential -nather than Darallel reantions. The specific
c,haxaic.ter of the cy3lizinG agent is restricted to the degree
of its isomerizing as-,,,ioity., The method described in the arti-
cle makea pos3ible a convenlent preparation of both lonons
Card 2/13 and may p-ro-e

On the Cyclization Character of the Pseudo-ionon. SOV/20-124-5-11,7/62
A New Method of Producing the a-.Ionon
valuable in the production of a-ionon. There are 2 tables
and 15 referenaes, 1 of which is Soviet,.
ASSOCIATION: Institut or-anicheskoy khimii im. N. D. Zelinskooo Akademii
0
nauk SSSR (Institute of Organic Chemistry imeni N. D. Zelinskiy
of the Academy of Sciences, USSR)
PRESENTED: October 30, 1958; by B. A. Kazanskiy, Academician
SUBMITTED: October 24, '1958
Card 3/3

FRASILINIKOVA, G.K... red.; hIJGATOVA, G.P., red.; UGMOV, V.F.,
doktor Ich" nauk., red.; LPTREANSKAS, G., red.; PETRAUSKAS., V.,
red. red. -, TOMITE, T.,, red.; FMMUGHMS, A.
tekhn. red.
[Chemistry of terpenes and terpenoids; papers presented at the
All-Un--on Conference on Problems in the Chemistry of Terpenes and
Terpenoids in Vilnius on June 4-6 19591 Trudy Vsesoiuznogo sove-
shchaniia po voprosam khimii terpenov i ter,enoidov, Villnius, Gos.
P
izd-vo polit. i nauchn. lit-ry Litovskoi SS-1, .1960. 21+7 p.
(1,11RA 15:7)
1. Vsesoyuznoye soveshchaniye po voprosam khimii terpenov i ter-
penoidov, Vilnius, 1950" 2. Zavediiyushchiy sektororn Instituta 1-hi-
mii i kbimicheskay tekhnologi:l AkaderAi nauk Litovskoy SER (for
Kugatova).
(Terpenes) (Terpenoids)

-SIMENOVSKIY, A.V.; SMIT, V.A.; KUCH3ROT. Y.F.
Mechanism of the cyclization of pseudoion,-.,ne. DDkl.0 SSSR 132
no-5:1107-1110 Je 160. (KIRA 13:6)
1. Institut organicheskoy khimii im. N.D.ZellaskDgo Akademii
nauk SSSR. Predstavleno akademikom B.A.Kazanskim.
(Psoudolonone) (Cyclization)

SMIT, V.A.; SMONOVSKIY, A.V.; KLJCHEROV, V.P.
Regularities and the cyclization mechanism of Isopronoids.
Repor-t No..2: Cyclization of din-and trans-gerazWlacetoneo-
Izv. AN SSSR.Otd- khim. nauk no-12:2103-2200 D 160. (MIRA 13--12)
1. Institut organicheakoy khimii im.I.D.Zelinskogo AN SSSR.
(Undecadienone) (Cyclization)

V.
-,:IER.~ V. F., VIT, V.
"The Structural and Spatial Orienti-Ji-on of Cyelization
Reaction of Isoprenoid Compounds. 11
Report p-esented at the 5th International Biociemstry Congress,
I
1.1,09cow, io-16 Au~~ust 1961

RUDENKO., B.A.; KUCHEROV,, V. F. ; SMIT, V.A.; SFM-EROVSK-IY,A.V.- --
Gas-2iquid chromatography of isoprenoid compounds. Izv.
AN SSSR Otd.khim.nauk no.2:236-243 F 162. (MIRA 15:2)
1. Institut organicheskoy Ichimi:L im. N.D*Zel-inskogo AN SSSR.
(Isoprenoids)
(Gas chromatography)

SMIT, V.A.; S12,IENOVSKIY., A.V,,- VIAD, P,F.; KUCHEROV, V.F.
Cyclization of isoprenoid compounds. Report NO-4: IOW
temperature cyclization, of geranic acid and its ester.
Izv. AN SSSR Otdikhim.nauk no.2012-317 F 162.
(MIRA 15:2)
1. Institut organicheskoy kbimli im. N.D.Zelinskogo AN SSSR.
(Geranic acid)
(Cyclization)

SMITP V.A.; ~E~~~MJCHEROV, V.F.
Cyclization of isoprenoid compounds. Report 110.5: Low tem-
perature cyclizatiun geraniol acetate. Izv.AN SSSR.Otd.khim.-
nauk no.3:470-476 Mr '62, (14IRA 15:3)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Geraniol) (Cyclization)

SMIT, V.A.; SEWNOVSKIY, A.V.; KUCHEROV, V.F.
Cyclization if isoprenoid compounds. Report No.6:
of Ok- and 0 -cyclogeranic a-cids under the effect
acid. Izv.AN SSSR.Otd.khim.nauk no.3:477-484 Mr
1. Institut organicheskoy khimii im. N.D.Zelinskogo
(Cyclohexenecarboxylic acid) (Lactones)
Conversions
of sulfuric
'62.
(NIRA 15:3)
AN SSSR.

SDENOVSKIYJ A.V.; SMIT, V.A.; KUCHEROV, V.F.
Configuration of -lactones formed during cyclization of
geranylacetic acid. Izv.AN SSSR.Otd.kbim.nalLk no.32558-560
Mr 163. (MIRA 16t4)
1. Institut organicheskoy khimii im. N.D.Zeldnskogo AN SSSR.
(Lactones) (Cyclohexenecaricoxylic acid)

SMIT, V.A.; SEMEII(YVSKIY, A.V.; KUCHEROV, V.F.
Cyclization of isoprenoid compounds. Report No.7: Low-temperature
cyclization of dihydro-o~-, dihydro-/Oi-, and dihydro-y-icinones.
Izv. MI SSSR. Ser.khizft. no.9-.16ol-1607 S 63. (MMA 16-9)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Ionone) (Cyclization)

SMIT, V.A.; SEIIENOVSKIY, A.V.; ~UGHEROV, V.F.
Dependence of the steric course of isoprenoid cyclization reaction
on the configuration of 6,7-double bond. 12,V. AN SSSR. Ser.khim.
no.9a1702 S 163. (MIRA 16:9)
1. Institut or anicheskoy khimii im. N.D.ZeUnskogo AN SSSR.
(Igsoprenoids) (Cyclization) (Elouble bonds)

SMITY V.A.; SEMENOVSKl.-YP-.,A.V.; RUDENKO, B.A.; KUCHEROIT, V.F.
(~vclization of isoprenoid compounds. Report No. 8: Mechanism of
the stereospecific cyclization of geranylacetone. Izv. AN SSSR
Ser.kbim. no.10.-1782-1789 0 163. (MIRA 1733)
1. Institut organicheskoy khimii im. N.D.Zelinskovo AN SSSR.

M
KUCHKHOVj V. F.j SMENOVSKITj A. V-1 SMITI V. A.
wA new route for the stereospecific cyclisation of isoprenoidB.01
Report presented for the 3rd Intl. Symposium on tlx- Chemistry of
Natural Products (ILTAC), Kyoto, Japan, 12-18 April 1964.

SEMENOVSKIY, A.V.; SNIT, V.A.; KUGHEROV, V.F.
Cyclization of isoprenoid compounds. Report No.9: Stereospedific
cycl-ization of geranylacetic acid, its methyl ester and monocyclic
analogs. Izv. AN SSSR. Ser.khhn. no.3:504-51.2 Mr 164.
(MIRA 17:4)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.

KJ
a t i on of
:65
All
Illy

L
ion cf v--ar-i -Lrd r.~:-oi ethers. 1z-.,.
C za
no.6:.-LC(;s'---,(Y/iD t65.
-e~3kvl khi:r.-*,! "el-n-kogo A'.T 'S~F.
o:-a.,ich I I- --- - - It 1; -

SL:M,,NOVSKIY, A.V.; smrr, V.A.; KUMEROV, II.F.
New path of the stereospecific cyclizat-'rin of isoprenoida. DokI.
AN SSSR 160 no.5:1097-1100 F 165.
04IFIA 18:2)
1. InstIt-at organicheskoy khimii im. N.D. Zelinskogo AN SSSR. Sub-
mitted July 28, 1964.

SMIT, V.A.Q a
7-_,j4U,.,NOVSK!Y, A.V.,~ CHERNOVA, T.N.~ HCHMOV, V.F.
I
Cyclization of isoprenoid conpounds. Report No.10t Depeendence of the
structural course of cyclization reaction of J.soprenoids on the configura-
tion of 6,7-doub'-e bcrid. in. AN SZSR. Ser. khim. no.7-.1229-1236 165.
(~aW. 180)
1. lnsii~-ut organikhe&kcy Uimii Lm. N,D.Zelinskcgo AN SSSR.

SEMENOVSKly'J'-A~.; SMIT, V.A.; KUCHEROT, V.F.
Cyclization of isoprenoid compounds. Report No.ll: CyclizaUon
of isomeric farnesenic esters and their monocyclic analogs.
Izv. AN SSSR Ser. khim. no.8:1-424-1433 165. (MIRA 18;9)
1. Institut organicheskoy khimii im. N.D. Zelinskogo AN SSSR.

SnENOVSKly, K. P.
TJM/Eleotriolty
Dielectrics - High Frequencies
Drying
Nor 48
"Comment on Engineer A. A. Chizhunor's High-
Frequency Installation for Drying of Dielectrics,"
K. P. Semen07skly, Engr, 2 pp
"Elektriche8tro" No 11
Heated discussion on the relative cost of drying
vood by steam or by high frequencies.
PA 27/49T46
AIL 27/4!)T46

SFNMOVSKIY, L.A.; MUDRIK, V.I., kandidat tekhnicheskUkh nauk.
Increasing the whiteness of pqper. Bum-prom. 32 no.4:22-23 AD '57.
(MLRA 10:7)
1. Glavnyy inzhener fabriki tekhnicheskikh bumrig "Ok-tyabr"' (for
Semenovskiy). 2. Moskovskiy filial Gosudarstvennogo instituta
po proyektirovaniyu tsellyulozno-bumazhnoy -promyshlennosti (for
Mudrik).
(Paper coatings)

N 0 V.S~ P~ I kil. L - F) ,
CCIUM/Chemical Technology Cellulose and Its DerivEitives.
Paper.
Abs Jour Ref Zhur - Khimiya., vo 16, 1958, 561cq
Author Semenovsky, L.A., Mud--ik) V.I,
Inst
Title Improvement of Paper Whiteness.
Orig Pub Tszaochzhi Gun-e, 1958, No 1) 41-42
Abstract Tremslation, see: Ref Zhur. Khim., 1957, 59216
H.
Card 1/1

ROZEDSHTRAUK119 L.S.; -_~~EITOVSM, M.L
Comparison of angio- and bronchographic data in the central form
of lung cancer. Vop. onk. 6 no. 10:46-51 0 160. Q4IRA 14:1)
(LUNGS-CANCER) (AMGIOGRAPHY) (BRONCHI-RADIOGRAPHY)

ROZEVSHTRAUKH L.S.;~-. SFMEkQj~KIY, M.L.
.9 -
Comparison of ang~io- and bronchoggraphic datua in a perilpheral fol--,
of pulmonary cancer. Vop. onk. 6 no. 11:33-38 N '60. (IFIRA 14:1)
(LUNGS-GAIICER) (AMIOGWBX)
.1

SEMENOVSKIYP M.k. .4t kv.10'.); KOSTASH9 G.A.
_(Moskvay Luchnikov per.j, d
Significance of selective angiography of the lungs in the evaluation
of operable possibilities in primary bronchial cancer. Vest. rent.
i rad. 35 no. /+:9-13 Jl-Ag 160. (MIRA 14:2)
1. Iz 2-y kafedry klinicheskoy khirurgii..(zav. - prof. B.K. Osipov)
i 2-y kafedry rentgenologii i meditsinskoy radiologii (zav. - prof.
YU.N. Sokolov) TSentrallnogo instituta usovershenstvovaniya vrachey
(direktor M.D. Kovrigina-) na baze gorodskoy klinicheskoy bollnitsy
No.50 (gla7nyy vrach N.P. .Brusova),
(BRONCHI-CANCER) (ANGIOGRAPHY)

'SMENOVSKIY9 M.L.
Angiography in primary cancer of the lungs. XhRurgiia 36 no, 5:119-
124 MY 160. (LUNGS-CANCER) (ANGIOGRAPHY) (MIRA 1/+:l)

W
SEMENOVSKIY, M. L.
Cand Med Sci - (diss) "Angiography in cancer of' the lung." Mos-
0
cow, 1961. 18 pp; including cover; (State SCiE!ntific Research
0
Roentgeno-Radiological Inst of the Ministry of Public Health RSFSR);
250 copies; price not given; (n, 10-61 sup, 226)

SEMOVSKY, M.L. ----
Angiographic picture in atelectasis. Trudy TSIU 2:54-77 161.
(NIRA 15:8)
(LUNGS-COLLAPSE) (MIGIOGRAPHY)

SEMENOVSKIY, M.L.; RYAPOLOVA, M.D.; LITVAKOIISKAYA, G.A.
Selective angiography in central cancer of the lungs. Vest.
rent. i rad. 37 no.5:14-16 S-0 162 (MMA 17:12)
1. Iz 2-y kafedry khirurgii (zaveduyushchiy - prof. B.K. Osipov)
i 2"y kafedry rentgenologii i meditsinskoy re.diologii (zaveduy-u-
shchiy - prof. Yu.N. Sokolov) T-Sentrallnogo instituts. usovershen-
stvnvaniya vrachey na baze Gorodskoy klinichE!skoy bollnitsy No.50
MoEkvy (glavnyy vrach N.P. Brusova). Adres ELvtora, Moskva,
LuchiAkov pereulok, dom 4, kvartira 10.

GUREVIGH, L. A. (Moskva, G-2, Karmanitskiy per., 3, kv. 3);
SEMENOVSKIY, M. L. (Moskva, TSentr, Luchnikov per., 4, kv. 10)
Possibilities of pneumomediastinography and angiography of the
lungs in determining the operability of lung cancer Vop. onk. 8
no.1:5-12 '62. ?MIRA 15:2)
1. Iz 2-y kafedry rentgenologii (zav. - prof. Yu. N. Sokolov) i
2-y kafedry klinicheskoy khirurgii (zar. - prof. B. K. Osipov)
TSentrallnogo instituta usovershenstvovaniya N-rachey (dir. -
M. D. Kovrigina) na baze Moskovskoy gorodskoy bol'nitsy No. 50
(glav. vrach - N. P. Brusova)
(LUNGS-CANCER) (ANGIOGRAPHY)
(MEDIASTII-RR,4-RADIOGRAPHY)

TSUKEWO, G.I., starshiy nauchnyy sotrudnik; SEMENOVSKIY, M.L.,kand.med.
nauk.
Surgical treatment of acquired heart failures. Med. sestra, 22.
no.1&19-24 ja 163. (MM 16:7)
1. Iz Instituta serdechno-sosudistoy khirurgii MIN SSSR, Moskva.
(1WRT-SURGMY)

ROZMETRAUKH, L.S.', prof.; SEMOVSKlY, M.L., kand.mEid. nauk
Comparative evalaation of contrast sA*tances for angiography.
Vest. rent. i rad. 28 no.2.-9--13 Mr-Ap'63. (MIRA 16:9)
1. Iz 2-jr kafedgy rentgenologli (zav. - prof. Yu.N. Sokolo,y) i
2-y kafedry khirurgii (2av.' - ~iof. B.K. Qsipov) Wentrallnogo
116
instituta uaovershenstvov#.niya vrach (dir. X.D.Kovrigina~).
(PULMONARY CIRGULTAIZ (AWGIOCARDIOGRAPHY)
(CONTRAST NEDIA)

OSIPOV, B.K., prof.; SEMENOVSKlY, M.L., kard.
Diagno3is and s~Lrgical tr-atment o~ 1--;ng
66-.15-21 164.

4h197
s/iog/62/007/012/017/021
D271/D308
~AUTHOR: Semenovskiy, V. K.
TITLE: Switching time of a tunnel diode when triggered by a
voltage pulse with inclined front
PERIODICAL: Radiotekhnika i elektronika~ v. '7, no. 12) 1~9629
2092-2094
TEXT: Tunnel diode switching time is analyzed assuming that modu-
lus of the mean negative diode impedance pm and series resistance
R are of the same-order of magnitude, and*that diode switching time,
and the rise time of the trigger pulse are comparable. The simplest
possible bistable circuit is considere'd which consists of a trigger
source, resistance R, stray inductance L and tunnel diode. Switch-
ing phenomena are analyzed on the basis of current-voltage charac-,
teristic approximated by rectilinear sectiona. pm is taken as pm