SCIENTIFIC ABSTRACT SERGIENKO, S.R. - SERGIYENKO, S.R.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 11
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

or Chemical nature of high molplar weight hydro~irbon
cwtiko and A. A. INIfilkhnnov
Petroleum S. R
DOklady ~ k&.-*Nanz X.. "', i?. 9 1, T aim -nxamn.
4 of IFe-
.Z~trolemn fractioni, 1). over 2W*, derived from
in.,. 1e by chromatographic adsorp-;
doit on sillcit gel with pei ether, benlenc, and benzene-
H toll solvents. 'rite nia(eiial, b. 200-370*,contained49%
itht-ne by(Itocarbom, 13.87o motiocyclic
of paraffin and napi
aromatic hydrocarbon4, 17.1% bicyclic and 17.4% poly-
cyclic aromatic hydrocarbons, and 2.6% tars and losses.
The kerosine cuts contain 75% of paraffin and naphthene
hydrocarbons and I I% monocyclic and 10.5% bicyclic aro-
matic hydrocarbons. The light oil contained 40% of patal
fin and naplithene hydrocarbons, 10% monocYclic, 8.14
27.7 % bicyclic arotna tic hyd rocarbous. G.M.Kosolapoff
7 q J4 r4

I
SERGI-TRIKO, S.R.; ZH11ANOVA. N.V.; TOPGHIYEV, A.V.. akademik.
- - - - - - - -
- ------
Conversions of methvl-2-butadiene-1,3 over an aluminosilicate cutalyst.
Dokl.AN SSSR 91 no.5:1147-1150 Ag '53. OaRA 6:8)
1. Akademi,,a nailk SSSR (for Topchiyev). 2. Institut nefti Akademii nauk
SSSR (for Sergienko and Zhdanova). (Butadiene)

'56'?q / .yevA-,c, -~ R.
VOLIFKOVICH, S.I.. akademik; SEROIYENKO. S.R.. doktor khimicheakikh nauk
professor; KAUFMAN, i3F.,--r-9AM6--,,iwrANsxIT. I.P., takhnicheskly
redaktor
[Russian chemists; annotated reading list] Rueskie khimiki; anno-
tirovanrqi ukazatell literaturv. Vvodnaia stattia i biograficheskie
ocherki S.R.Sergienko. Pod red. S.I.Vollfkovicha. Moskva, 1954. 145 P.
(Chto chitat' o v7daiushchikhala deiateliakh otechestvennoi nauki i
tekhniki. rn.5)
(Chemists)

SERGIYENKQ.-S.R-, professor, otvetatvannyy redaktor; IOMV, S.M., re-
daktor; NEVRAYEVA, N.A.. tekhnicheskiy redaktor.
[Problems of hydrocarbon oxidation] Problemy okieleniia ugle-
vodorodov. Moskva, Izd-vo Akademii nauk SSSR, 1954. 221 p.
(MI-'RA 8:2)
1. Akademiya nw1k SSSR. Institut nefti.
(Hydrocarbons) (Oxidation)

/( (-- / L A' A C, 'Z~' /~ -
AR-BUX4 A. Te., otvetstvennyy
otvetstvennyy redaktor;
tekhAicheskiy redaktor.
redaktor; SFMIYICNKO, S.R., professor,
LOKTEV, or,'SDMINA, Ye.H.,
[Academician Sergei Vasillevich Lebedev; for his eightieth birthday]
Akademlk Sergei Vasillevich lebedev; k voolmidesiatiletiiu so dnia
rozhdeniia. Moskva, lzd-vo Alkademii nauk SSSR, 1954. 263 P-(MLRk 7:11)
1. Akademiya nauk SSSR.
(lebedev, Sergei Vasillevich, 1874-1934)

7'~-7elopm,;Wt of -ga~.Yaie#i!Aj_
bf-h- s from petroleum
Okiskniya UghexftWor A a
NA. 54,4
-40-In the introductory remarks made I
osmw All-Union meeting on 14-18 May 1951, an
increase in the use of petroleum in chemical industry was
advocated. A brief summary wm given o
f the achieve-
ments in this field in U.S.S.R. during the Last 10 years.
Development In the theory of chain oxidation of hydrocar-
bons. N. N. Stmenov. Ibid. 13-39.-A comprehensive
review cdTV-In-g'TFF I=owmg topics was given: direct rcac-
tion between two saturated hydrocarbonsvchain length and.
r acti'vity of, free radicals; effect of biradicals on the chain
rd ag t 0; competition betwee,i the chain reaction and
p r:7',
~.thepd rtaction among the mots.; branching of chain
reactions and limiting phenornena; decay of chain reactiqns;
oxid*IW~-.n of simple paraffins; wall effects in chain reactions.
47#d kences. Mechanism of negative catalysis in oxidation
VI b IV. H. Nrerninn-
,~ r1ocar ons. -Eleffiento Ibid. 40-50.-A review
witit 12 refor-ences. try reactions of simple hydro-
c
'bons with atomic oiygen
ar ., L. 1. Avrameuko and R. V.
Kolesnikova. iota, J)" xtuatioll 01 metuaMe. efliame,
M.- _.-4j0!js reviewed.
17 references. Oxids-
.)a of
hydrocarbons in the presence of hydrogen bromide.
Z. K. MaTzus anti N. M~ Fninnupl- ThU. 6G-77.-A-;t&.
`-VXVTr7metjcs. 4 references. Investigation of oxidAtion
of CII-labeled propylene. A F. Lukoviiikov. - Ibid. 7P-88.
-Synthesis of CII-propyleui~, 1M MIUM J11, ~ 11`01nat0glapiliC
sepri., and dctn. of radioactivity of the mcdou pnRlucts
are reviewed. I I ref~renctts. Mcclianism. of oxidation of
propane. V. Yn~ Shtmw Ibid. 89-1113-A review with
52, references. Unique features of Wdation of
hydrocarbons In ~Iqufd phase-. A. N. Bashkircv,aud-.
B. Chertkov. Ibid. IN-3;
cl.-V~. Zo. IVS-~A review.,
XMI a MEW=vs. The ;--edt, a effea oU dav
en on hydrocarbons of ration strucwe ~ in fiquid
base. K. 1. Ivanor.
rb~d. 11 1-23-Fleparationa of -the]
Itillowing peroxio'esare fully revi-iOtU4 - heptane 2-hydra-
peroxide, bsn 38', 111? 1.4305, dii '0M72 -a - (sr'-_.,
nc)/d 101 - N.C. MRD 3748,~ 2qaL!;i9"e_2-h3'jM~-
10. ' "I
~perozide, bon 21% n,? 1.4270, dw OS9,54. MR6 37.9
'! ' -
2,9,4-trimethyl,3-pentanone 4-hydmperoxide, b..gj ~ 21*6
~m. 73% cyclohexatie hydroperoxide. in. -20', 001 1.4C380
du 1.013, MRD 31-50; I-ethylcyclohexanc 1-hydrnperoxide 7
bean 34% Me 1.4078, d2o 0.0907, S 85.4. JIRI) 40.45; - I-
propylcyclopentane . I-hydroperoxide. ba. . 34.50 , nV.
.1.4566, dsp 0.9581, 3 85.9, 2rRD 40.96; iudan 4-hydrow-
oxide, bo.1 75*; 1-metliyl-IL,3,4-tetmh)-drotiaphthalene*
I
I-hydroperoxide, ba-t 09-100'. ni? 1-5iMS, d. 1.1114,.
fluorene 9-hydropcromidc. m. 03*-. 1.4-dihydronaphthul-e-
1-hydroperoxide, bo-t 1-20-5', n.' 1.5685, d:s LIM; lil-
diphenylctltane I-hytimperoxide, in. &10; PhICOOII, in.;
81*. 1) references. Peroxides from autoxidation of Some'r
alkanes and cycloalkanes. K.l.lvanov,V..K.-&%,inova,!
and V. P. ZhaLbovsk-aya. N.I. l24-3j7=TT;p='Uonj;
and phys. properLu:s are revielyea and discussed in -dctail,'~..
15 refetences. Oxidation products of Tetridla. A -i
d L. A. Uniin. ]bid- 140-4-The A"Jec!
,~.tnneva an bl-
of tar foJ*m`aTto_n_-wa-s-s ZMed by analyzing the autoxi&; i
flan products of Tetratin. The fraction extd. kith 60% uq':-i
aq,
NaHeo, contained enols of 3,4-dihydro-1(2H)-naphthaI
one and diftydronaphtlitiquitione. Among the sidatitonn I
'A
products were: l~'.3,4-tttratil-dro-l-naphthyI hydroper- I
toxide; 3,,I-diliydro-I(ZH)-naphthalcnonc;,3.4-dih-.- _:t
exo-~
2(lH)-naplitbak-rinne; dihydronaphthoquiriont; o-HO;Cc)~_l
11.04CILCO111; and lmlymerization products.
Syntht
:of 1,1-dipbenytothanol-hydropero3dde and thermal dectml~'.
position of tertiary hydroperoxides. T. 1. Yurzhenko,
K. Tolopko.- and V., A. I'lichin, [b'r_RF3M.7._,.C

~45, Oxidation of petroleum ZRTeros Wiff -*0
air and HMOs. 11 Losev and R.
Smirnov. Ibid. 2~_
152-06~A review. bitsdation of higif-m fecuLar eight
hydrocarbons and petroleum oils In lintild phase- N T.
Chernozliukov. Ibid. 167-74.-A review with 10 refer-
eacts. Industrial. methods of oxidation of petroleum hy-
drocarbons In liquid phase. V. K.' Tsyskovskil. Ibid.
177-M.-A review with 17 'rejercuces. fixiallffba of,
paraffin wax. - D. A. Chemynty N. S. Mkyshinik-aya' -
and G. P. DoUravol'skil. Ibid. lb+-W~-Prepn. of 155-
denting 0- from P- "t is d,
w, h Zgar
in d.
scribed th diagram% *J , tpruent. Conditions
for the ortimuni yields are gistif 1AiTd 0-dussed at leng-.h.
Fatty ac ds from paraffins. '..A.. Yn. Rabigovich. Ibid.
c
200-7-Discussion of technological processes. No refer-
MCC:. Use of hydroxy acids from oxidation of petroleum
hydrocarbons as Min-forining materials. P. V.
Serh-
Serbin. JUd. 208-2l.--Compn., sepil., ailn properties 01.
11U =ds from oxidation of solid and liquid petroleum frae-
tions are extensively di3ctm%ed and the prelin. of vartitshes:
on laboratory and plant scales is reviewed. A_Ej,;,,_~

SERGIW S.R.; IIELONS, 1.0.; IkVYDOV, B.N.; TETFAIUA. M.P.
Composition andpropertles of the bituminous portion of Mori petroleum.
Report 1. Trudy Inat.neftl 4:18-30 '54. (MLRA 8:1)
(Mori--Bitumen)

JOMa ewive 1 1 butvl Olo-ide with oxide catalvsts.
_Oas of b
d
S
S
-AICICCI (1) t, touly converted into dimer and trimer of
bobutylene over CaO durini 20 hrs. at 100 and 51 atru.
Npressure. Under the swne conditions with a mixt. of I*
rith fsobutylcne, I is converted into isobutylene oniv; -with
isopropyl chloride, I Is hydrolyzed, form . 9, Ifftcoft. ~ In-'
creasing the pressure provokes an increaLa f dimer forma-
tion, while the amt. of Nfe.COH decreases. I with Cao"
or ZnO is converted Into d1mer and trimer; ;sDbutyl chloride
form-A the saine products over ZnO only. The velocity of
conversions of I with ZnO at 100' is almost twiqe-th3l of;~
isol,utyl chloride. M. Charra

lyne cunverilin of 2-heren.i

an 'Y
N
~
. -
S.
M
AlCla In a rou
added dropwise
nitroethane, 10
After stirring I
The mixt. of l
I.-I) at 0* and
16-175r0 beryl
Polymers Of he3
hexyl chlorides
f
qnormal p
ride does
-
-
7
t
h
prene in
P*-eriz-,'

-92
nd-bottop
9e'
sppropyl
q--ae
l
1954).-Ti, 4 F.. oT we-cooled:anhyd.
Bask, with reflux condenser, is..
whileftirring 2.67 IF. of a mixt. of 35%
f-nitropropane, ana 859p' 2-nitropropane.
~hr., the mixt. forms a viscous liclaid (1).
chloride and 2-hezene (mol. ratio
al premm form in the presence of I
rides, and 32-W% dimer3 and alkyl.
WO
during 3--4 hrs. Ile major part of the
t 0* and
b. 123.4% is 2-chlorobexane.- A
lation of hezene with Isopropyl chlo-
:k Under the same conditions Iso-
lsopropyl chloride spontaneously
M armandarlig.
Ch
6P

Nk'O)
.-T-e--raj- -W 14';$Ewjj:jh "Ad on:
YTE!--- ahi- 0
Hue oxide. A mi~ljpgv'l ap, and R.
V -=Frnj~. Tr Akad. Nauk 5.S.S.R. 4,
93--lof)(1954).-Isopropyl chlonde,(I) is almost completely
ropylene in the presence of ZnO, at 2.&-
327' and atm. ~rewure. Under 40 atm.. the polymerivt-
tlonofloco-r3andthe5-7 dimer34% trimer and 20%
high polymer are ronne, t-nder the sawe conditions (I
atm.). 2,Ultnethyl-l-buteue or 2-hutene did not poly-
werize but: reacted with isopropyl chiorlde. At the higher.
pressure, 2;3-dimethyl-2-butene pardy (5%) isomerized to
2,3-dimethyl-l-butene. It was concluded that inttrmedl-
ate formati-on of dimethylbutene from isopropyl chloride
did not take place. , It is found that a method of analysis,
based on the adsorption of butylents and propylene by Hj-
S04 of conca. 69 and 85%, resp., Is not accurate for gas rich
In propylene, because It Is highly adsorbed by 68% HtSO,.
M. Charrnandar4a_
_i wim --a
TIM i-M4

SERGiYENKO, Zi.li.
WChemistry Analysis methods
Card tlA Rib. 40 - 21/27
Autbors iSergienko, S. R., Bedov, Yu. A.,, and Teterina, 14. P.
Title l Investigation of high-molecular petroleum compounds, part J.,_ Use of
color Photography for the characteristics of the luminescence chart
PerlodIcal Izv, AN SSSR. Otd. khim. nauk 4. 716 - 721, July - August 1954
Abstract s The advantages derived by fixing the luminescence chart for various
COMOnents of high-molecular tarry--petroleum cornpounds, with the aid of
color photography, are listed. Lead glass was found to be the moat
satisfactory and convenient filter capable of intercepting ultraviolet
rays and thus eliminating their effect on the photo-film. A
luminescence analysis completed with color photography becomes an
objective method for qualitative evaluation of chemical changes in the
components of high-molecular tarx7-petroleum substances. Eight USSR
referencea-(1925 - 1953). Graphs; drawingej illustrations.
Institution : Aced. of Sc. USSR, Petroleum Institute
Submitted : September 20, 1953

STEPANOV, B.I..SMGIYMO, V.A,.
Analysis of indophenols by titration with ascorbid. acid.
Trudy Kom.anal.khim. 5:274-278 154. (MI.PA 8:6)
(Indophenol) (Volumetric analysis) (Ascorbic acid)

V_ /Y L,
USSR/Chemistry - Industrial products
Card 1/1 t Pub. 86 - 10/38
Authors : Sergiyenko, S. R., Prof.
Title : Chemistry and the chemical industry in the People's Poland
reriodical : Priroda 43/12j, 71-74., Dec 1954
Abstract : The claim is made that the industrial production of Poland
in 1954 was four times as great-as in the prewar period,, the
advance being noted particularly in the field of chemistry, as
is shown by the fact that in 1951, 62 new chemical-products were
manufactured; 109 in 1952; and 206 in 1953. An account is given
of expanding research work in chemistry and names of institutes
and outstanding research workers are given.
Institution
SuLudtted

-9. R.
UUM/Chamistri - Hydrocarbons
-card 1/1 Pub. 22 - 13/41
Af4tbors Bedov., Yu. A., and Sergianko, S. Ii.
Title Parachors of six-membered cyclic compounds with two hetero-atoms in.:
the ring
FariodIcaI t Dok. AN SSSR 98/2, 2197222, Sep 11, 1954
Abstract The structure of iix-membered,heterocyclic compound .9withAwo hate.r'o-
atoms in 1,4-positipn.and some of their.derivatives') wa's inveatigati~..
The-basic physical, c6nstarits and the parachor values of the.Ahveati-t.
gated-het6rocyclie compounds; are listed in tables..'The surface ten -1.
sion of the compoundswas date .rmined by thb P. A, Rebinder m6th6d;-o_f
maximum blister pressure#'7 Thirteen.referelices: 6-us,99; 54SA iM"Z-
German (1890-1950). Tables.
Institution Academy of Sciences, USSR, Petroleum Institute
Presented by Academician A. A. Balandin,. March 1, 1954

SERGI-MKO. S.R.; DAVYDOV, B.E.; DELONA, 1.0..; TETER114A, M.P.
LCOmPosition and properties of high molecular petroleum com-
pnundal Snstav i svoistva vyaokomolekuliarrffkh soadinenii
nnfti; doklady na IV MAzhdunarodnom naftianom knngresse v
Rime. Mowkva, Izd-vo Akad.nauk SSSR, 1955. 57 P. (WAA 8:9)
(Petroinum)

SERGITENKO, S.R.; TOPCH= , A.V., akademik, redaktor; TIKRONFUVOV, N.V.,
- -r
1--Ye-dik-or; ASTAFITEVA, G.A., tekhnicheski7 redaktor.
[Outline of the developnent of the chemistr7 and processing cf petrs-
leum] Ocherk razvitiia khimii i pererabotki nefti. Moskva, IvI-vo
Akad-nauk SSSR, 1955. 309 P- (MLRL 8-.4)
(Petroleum)

lcju1d-pba-q4 Lon of 1%-Ur dpceie,

n i and
'llepty1cyclohelune,
=
I
aa(
P. N. LiWtca.
atr ~;~gem. sgien
Gid W=14.
SiS.R., Trudy Ron/, loss, ~nm-m-~f I I' id h " ir

1
T p ast it
- hrS., tho Ist
oxidation of hydrozarboqs at 150" for 10
I
stage is the formation-of pcrox-i6s; which reaches a mal. Ja
10 hrs. anti declints to ucafly 0 by WO hri. Me kinctli:
.
. 1w
carves of time v-'I.- gcid no,, bromine va,j vipon. 1. no.
oxide content and 0 content are shown for is-undece e, n-
4
heptylberizene, 71-hentyleyelobexane. and 1-wethy1dicaby-
dronaplithalene. The tendency to form tars duringoXida-
tion declines in order: undect.-ne. 1-methyIdccahydr6naph-
thalene, hepty1cyclobexafte, heptylkmzene. Tar formation
begins to be noticeable after stime.W brs.. The gradual
decline of the rate of oxidation v%,;;d its practical ccssaeou in
Oic prezence of as yet unreacted materials is ascribed.Wthe
neg. catalytic activity cf the tan Nvbfch act as antioxidants.

SERGIYENKO~ L . R.
"Again About More Thorough Petroleum Refining," Neft. Khoz., No.2., pp 71-78,
1955.
Translation D 306428, 10 Aug 55

01
4,f)k-Ity(Itogenation 'Of ctl~~~oa zin chroninte.
14, 1~4-r6vn6I and 1, 7imly 1pist. Nefti, Akad.
on Zitl) cim N
tvwd t-, d,-hyd1,)j:cn:ttc UtPh.
s It: t ct, velfwi(v Icatk to VreMly incrc:md :wcoadary re:116
of shrenc, flo- rate of which incre.vt-s Lister with r~~inj,
tk%l I It I la Ilvlwdro~;coafion rc~.oltijig in mildl c"ke (A-Ilt
loc., io 3 11~,,sj dept-itimi ,it the vat:tlyst, However, the
cnf'~~l-vst It,taills activity foy Inole than 20 lirs. abiwe C(N),
;nA CM1 litt mictivated by a stream of air aL rjOl' for 2-3
,I T11C WithSt.1105 lle;Ltiot; to 700* without loss
'If nctivity. Fitergy of activation for catalytic dchydro-
J~vtialioo of I-F-01i mis caled. as 20,531) cal./mole; energy (if
activatimi fur pyrolysis of Fin asIS,100 mi./mole.
n Kro

Sf f~.
ne-hydrocarb-o-n-s
p-'Transformations of die
wWa conjokated
c
tam of double boads on n~ ~a and ait"Illaft-
TrNI
OrM;t
exomate catAIVII. on 213 LWOMYI
--.~113-butadiene. b. R Se k0 and N. 13. Zhdanova.
, , , k -r, W-01- -- - -
I May , UDO).-
KIS) rsxpts. were conducted at 20( with alurnina-silicate
and at 250-300* with alumina-chramate catalysts. Reac- c- C) Z,
tion proceeds essentially in sainc direction on both catalysts;
action of alumiua-silicatt catalyst is more aggressive and
destructive. Prlrnary reactions proceed in the following
directions: (a) d1werizAllon svith the formation of cyclic
cornpda. having a 6-membered ring as a basis and subte-
quent redistribution of H. accompanied by the dehydro-
genation of one portion of the hexamethylene rings to ben-
zene rings and hydrogenation of another portion of unsatd.
6-membered rings to satd. hexamethylene rings; (b) hydro-
genation of the original diene system into a monoolefinic or
completely satd. system;. and (c) dehydropoly7nerization
with the formation of a solid. polycyclic(penta-hexarner)
hydrocarbon which is deposited on the catalyst. All the*
above transformations are conjugated among themselves,
since the H which is liberated in the reactions serves as a
source of satn. of the unsatd. hydrocarbons. The basic
reactions am complicated by secondary reactions which
should include, above all. dealkylation. After 2-3 hrs.,
them is a sharp loss in activity of catalysts due to deposition
of condensation products of original diene. The product
on al-1--silicate catalyst had a mol. wt. of 442 and
corresponded to a penta-hexamer of the original diene.
Formation of catalyst poisons can be considerably retarded
or completely suppressed by reducing contad time, feeding'
H or inert gas into reaction zone, or conducting the reac-
tioninvacuum. A diagram of the general course bf primary'.
reactions is giveh. B, Z. KMich

SERGIYENKO,S.R.; DSWNE,I.O.; DAVYDOV,B.B.; TIKTERINA,M.P.
p'
Analysis of the composition and properties of the part of petroleum
having a high molecular weight. Trudy 1nst.nefti no.6:71-78 '55.
(Petroleum--Analysis) (MLRA 8:12)

1 7-
USSR/Cheoical Technology Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants,
1-13
Abst Journal: Referat Zhur - Khimiya,No 19, 1956., 62577
Author: Sergiyenko, S. R_,, Mikhnovskaya, A. A.
Institution: None
Title: Investigation of Group Composition of High Molecular Petroleum
Hydrocarbons by Adsorption Chromatography
Original
Periodical: Tr. komis. po analit. khimii AN SSSR, 1955, 6, 162-170
Abstract: By means of adsorption chromatography on ASK silicagel was investi-
gated group composition of the hydrocarbons of dekerosenized Romash-
kin petroleum of Devonian deposits distilling over above 3250 and
also of catalyzates distilling over above 2000, obtained by cracking
over alumosilicate catalyst of paraffinc-naphthene (PNP) and aro-
matic portions (AP) of petroleum residue distilling over at >3250-
Separation of residue into PNP and AP was effected on silicagel.
Card V2

C i\j k
USSR/Chemical Technology - Chemical Products and Their Application. Treatment of
Natural Gases and Petroleum. Motor Fuels. Lubricants,
1-13
Abst Journal: Referat Zhur - Khimiya, No 19, 1956, 62576
Author: Bedov, Yu. A., Teterina, M. P., Delone, 1. 0.,
Davydov, B. E.
Institution: None
Title: Use of the Adsorption Chromatography Method for the Separation and
Investigation of Tarry Substances of Petroleum
Original
Periodical: Tr. Komis. po analit. kbimii AN SSSR, 1955, 6, 171-181
Abstract: A separation and investigation of the tarry substances of Georgian,
Nebit dag, Tuymazin and Romashkin petroleum have been carried out.
First by dilution with a 40-fold volume of pentane were separated
the asphaltenes and the solution of tars and hydrocarbons was passed
through the adsorbent. The best adsorbent was found to be ASK silica-
gel of particle size 0.37-0.20 imm. Adsorbed tars were displaced
Card 1/2
-------- --------- ----------------------------------------------------------------------------------------------------

~qn IYKUKO, S-R.; IZRAYLOV, N.A.; SPIVAK, L.I.; GALICH, P.N.
Petentiometric methode of i-avestigatiox of high-molecular weight
c*mpouxds in petrele=. Zhur.anal.khim.10 se-5:315-322 S-0 155.
(HLRA 9:1)
l.Inatitut nefti IN SSSR, Moskva I Kharlkovokiy gesudaretyeayy
universitet imeni Gerlkogo.
(Poteatiometric analysis) (Acidity) (Petroleum)

Subject USSR/Chemistry AID P - 3572
Card 1/1 Pub. 152 - 9/20
Authors Sergiyenko, S. R. and N. P. Galich
Title Tar formation during the oxidation of hydrocarbons
Periodical Zhur. prikl. khim., 28, 7, 735-744, 1955
Abstract The mechanism of oxidation of Cll-C13 hydrocarbons at
1500C has been studied. The oxidation products of
n-heptyl benzene contained 13% tar and 27% asphaltenes,
and those of n-undecene-1, 85% tar and no asphaltenes.
Four tables, one diagram, 8 references, 4 Russian (1937-
1955).
Institution : None
Submitted : D 25, 1954

us"CR/Minerals Petroleum
Card 1/1 Pub. 86 - 5/37
Authors I Sergienko., S, R,J Prof.
Title I Petroleum and its utilization
Periodical t Priroda 44/4, 41 503 Apr 1955
Abstract I A short history of the extraction of petroleum is presented.. The
composition of petroleum is discussed,'as well as the methods of
working it. Under the heading of modern petroleum refining such
points are taken up as the removal of salt, atmDspheric distillation.,
vacuum distillation., atmospheric-vacuam distillation., thermal .
cracking, catalytic cracking, removal of asphalt., separation of
gases'. catalytic alkalization and others. An analysis is also made
of the uses to which petroleum oducts are put. Two references:
1 Soviet and 1 USA (1941 - 1953 . Diagrams,*
Institution *0900
Submitted 0000*

F-- Nf
USS/Chemistry - Organic chemistry
Card 1/1 Pub. 22 - 25/49
Authors I Sergienko, S. R.; Bedov, Yu. A.; and Hatnikova, L*.V.
Title I Relation between the tendency of vi.trification at low temperatures and
the structure of molecules of certain morpholine derivatives
Periodical t Dok. AN SSM 102/1, 101-104, May 1, 1955
Abstract I Experiments were conducted to determine the Zreezing point of morpholine.
derivatives.and to establish its relation to the molecular structure.of
the compound. The effect of individual structural elements,on the proper-
ties of the molecules is explained. It is evident that all compounds
capable of conversion into vitreous (freezing) state have general str'uctur-
al elements like the NCH CH OR group where R is the hydrocarbon radical.
e gf 2
The presence or absenc a double bondin the hydrocarbon radial was
found.to be of no importance just as unimpoAant as the structure of .nitro-
gen bound radicals. Ten references: 3 USSR, 5 USA and 2 English (1938-
1954). Table; graphs;*drawing.
Institution :
Presented by : Academician A. V, Topchiev, December 7, 1954

>
- --- ----------
"9140 Investigat-Ion of Propertfes of Macro-Molecular Corn-
un From Petroleum. logledovanle synistv vysokotnole- 1 2
ulflykh sovd[nenli nefel. (Russina.) S. R. Sergfenko and 1:7
K
D, E 'Davydov, Doklady okademil nauk SSSR, v. 104, no. 4,
Oct, 1, 195r), p. 555-558.
9tiady of mal.-surface properties and dielectric permeability of
petroleum tars; and their component parts in soluLlons of
".heptane, cyclobeaane, nnd benzene. Tables, graphs. 9.ref.

SERGIYENKO, S.R.; ZHDANDVA, N.V.
Conversion of 1,3 butadiene over an aluminosilicate catalyst.
Dokl.AN SSS4 104 no.5:737-740 0 '55. (MIRA 9:2)
1.Institut nefti Akademii nauk SSSR. Predstavleno Ak-PAemikom
A.A.Balandinym.
(]Butadiene)

PETROV, Al.A.; SERGIYENKO, S.R.; TSEDILINA, A.L.; YEGOROV, Yu.P.
Izomerization ef unsaturated C12-C16 hydrocarb*ns. Xhim. i takh.
topl. no.1:26-32 Ja 156. (MI,'RA 9:7)
(Hydrocarbons)

USSR/rhemical TechnoloLrj ChemLcal Products and M7.eir 1-13
Application. Treatment of natural gases and petrolF-IUM.
Motor fuels. Lubricants.
Abs Jour Referat Zhur - 1,11miya, 1,1o 4, 1957, 12924
Author Sergiyenko S.R.
Inst AcacTemy of Sciencez Kazaldi SSR
Title New Problens in the Field of Chemistry and Chemical
Processing of Petroleum,
Orig Pub Vestn. All KazSSR, 1956, No 8, 25-43
Abstract Review of the trends of research-on petroleum and chemi-
zation of petrolem-. industry during the Sixth five-year
period.
Card 1/1 - 236 -

SERGIYENKO.. S.R.,,-, DELONVE, 1.0.; DAVYDOV, B.B.; TETERINR, M.P.
--_ --il'
Composition and properties of petroleum high molecular weight
compounds. Article 4: Study of the composition and properties
of the tarry portion of Romashkinskiy (Devonian) petroleum.
Trudy Inst.neft. 8:42-46 '56. (MLRA 9:10)
(Romashkinskiy--Petroleum--Analysis)
(High molecijlar weight compounds)

SERGIYENKO, S.R.; DBLONE, 1.0.-, DAVYDOV, B.E.; TETERINA, M.P.
Composition and properties of petroleum high molecular weight
compounds. Article 5: Study of the composition and properties
of the tarry portion of Bavly (Devonian) petroleum. Trudy Inst.
neft. 8:117-51 156. (MIRA 9:10)
(Bavly--Petroleum--Analysis)
Oligh molecular weight compounds)

SERGIYENKO S R - CHAYKO, V.P.; RU~ffAIITSEVA, Z.A.
- wja*Q~~
Study of the petroleum high molecular weight compounds. Article
6: Composition and properties of the tarry portioa of Kzyl-
Tumsbukskiy petroleum. Trudy Inst.aeft. 8:52-59 '56.
(KLRA 9:10)
(Kzyl-Ttimabukakiy--Petrolnum--Analysis)
(High molecular weight compounds)

- - -- -------------- -------
0
_J'SS;'i/Chemic,-il Tochroj~)ty. GI-e .,,i*-cal PrGducts md Their 1-14
a-- d
.9:it of ratural gases
pe tr o le LLi. `IoLor fue.'-s- Lubricants.
Abs-jour: Ref Zhur-_K1himij,-a) flo Z, 1.957, 9277Q
A u ta o r Sara.~~~ ~'LlY~Lr, V. T.
inst 1-nstitut.-3 f ti-_c Academy of Sciences
USS)
Title Eydrocarbon Co-stitut'-on of B-it'.-ovo and Radchen-
kovo Petrolaura
Crig Pub: Tr. in-ta nafti -1-1, z';,';SR, 191-6, Vol 8, 191-198
Abstract: Lit,'--ovo and 'ia6c'r.,er.0-Dvo uils belong to the low-
sul_,"i,.r mi.-ed-base W_It~L a nredomination of
naplitherlic-paraffinic h,,.,-drocnr~ons in the fractions
boiling belua 3.100. 1-1adchenkovo crude Is light,
low in resins md Paraffinic; Bitkovo crude is
vy, q2gh in ra--Aiis, and paraffinic. The solid
hea
hydrocarberis in bitkovo crude have been observed
to er~fstallize easLIj and to be easily separable
card 1/2
Abstract: frorm the oil. 2h0 clusa of this plianoraenon ap-
poar, to ba the LlbsIonce of noticeable arLounts ot'
bi-inchad _;,R.m.fff-nic h~ dr oclirb oils and t'le high-
C,Oilzen"' of asJ)haltic niate,-ial. The corqbinad ap-
Pli,.;ation of carbamide extVaction and double recti-
fication to the Bitkovo crude fraction boiling be-
t'aeen 150 and 2000 has r_1VQn quantituttive yields
011 C9 Tj " Zl' C 11 t~ #T: - Presmiably paraffins,
C-h 1-2 0_7 -10--22, -11124
n Tt is ti,,at the use of dichloro-
Othane is preferable t---, that of petroleurl ether
or tsooctilla i-, t','.6 carbamide separati-m of thr,
paraffin h,jdrocarbons. of t-b
e
paraffine hydrocarbons separated from various
crude fractions investiga_t3d are Presente~'.
Card 2/2

SERGIYENKO, S.R.. doktor khimicheskikh nauk.
L7zm;
- ~ -.i
Now problems in the chemistry and chemical processing of
petroleum. Vest.-All Kazakb.SSR 12 no.8:25-43 Ag 156. (MLRA 9:12)
(Petroleum-Rafining)

KO
N
_
`
,-L!~, NiN
5

_N
3604. TAR FOWT
TRIHG 9
I ON D L A I DAT% Ct; OF IL EFFMT, OF.
K
HYDROC,'JtBCN I GROUP CCHPOSITIM OF DILSEL RUA W THE 13IRZCTIW OF OXIDA-TICtl
Sergiewco. S.R. and Gallch. P,N. (Zh. Priki. Knim. (J. appl. Chem.. hoscow),
-
-
19
56, Vol. 29, 1568-I_r401 abscr, in Chinzi. fibstr., 1957, Vol- 5 986).
3, 60 Ter
-
was removed f
om
MO-365P fraction of diesel f
SIM) b
h
r
a
ue
c
romatography
y
on silica gel and was separated, r0 Into fractions or aromatic
spectIvely,
hArocarbons (1), 20.7% and paraff ins-cycloparaff ins. The latter.fmation
was treated with urea and separated into n-paraf f Ins (11), 12. LA and
IwE frins-c
ioparafri a (M), 62. In leaving a residue (TV),' Each
!-rract~
r
on via. 0'1n 2 parallel ces. 'Md Oropertles
9 0 1 d Ized - by. aFr at 15) tdi;ffa
of the products Wvr- - f met to,
plotted as ns of the-oltdation time.. The properties
of I did not wange appreciably; a slight darkening Indicated a slow
condensation.- Those'of IV changed a little more.. The plots of.ir and III
gaie similar functions. , The proportion of peroildes rose abruptly to a
MaXIMUM Within 2 hours for III and .9 hours forJI' Beyond thIs"maxImu3
the acid number, the saponification number, and the proportion of oMen-
containing substances Increased continuously.,Tar%formation became notled-
able in 50 hours with III and in 75 hours with=. Oildagion or aiesei-ruel,ts
..retarded no,t-so much.by I as by'the Products of cleavaae.of the peroxides
formed.

in the oxit4tion 6t
tic hydrocaj~boas an the
on o ydro firbon mixtures.- it.
9.
e~"In air oxiINtion (if (III' Ilyttr(j-
carlx)ns front the is(jrdkanc-cyc1opj4rqfrjjl fraction -if jjlj~,hLq
fuel, tile iuitiul stage involves tile formation of pcrmidv.~
W t'i luj; Ufter'WhiLlf tile pur-
Which maches a lIUI_X. ill a u
,cma% itundily. Peroxide formation pr-
oxide wsitcnt (it . es s
cedes tile formation of uddic, hydrolyzable, and Oil conl-
Pds. Addu..of 1070 or less of'dilsopropylbenzeneLto OIL:
I Charge does not affcct tile oxichitioll kinctics, but 25% or
more abuost,completely stops oxidation. The retarding
effect is not pirGducW by dilsopropylbenzene itself, but by the,
-turdation is
products bf decompit. of its peroxides. Max.rt
caused by addit. of.20-5% arontatic tomptis. _Cu_BLJ~
f'YK
-7

TERPIGMV, A.M.. akademtk, redaktor- SIMGIIENKO, S.R., doktor khimtcheskikh
naak, otvetstvennyy redo Ict or:-#O-LES tekhnicheakiy
redak t or
LFuel terminology for internal combustion engines] Terminologita
topliva d1ta dvtgatelei vnutreanego agoranita. Moskva, 1957.
28 P. (Sborntki rekomenduemykh termtnov, no.44) (MLRA 10:6)
1. Akademiya nauk SSSR. Komitet tekhatcheskoy terminologii.
(Gas and oil engines--Terminology)
(Liquid fuels--Terminology)
(RocketB--YUel)

KUSAKOV, M.M., prof., otvetstvennyy redaktor; PLATE, A.F., prof., otvetstvennyy
redaktor; NIKOLAYEVA, V.G., kand.tekhn.nauk, otvetstvennyy redaktor;
TOPCHIYEV, A.V., akademik, redaktor; KAZANSKIY, B.A., akademik,
redaktor; SERGIXRKO., S.R., prof., redaktor; NEKRASOV, A.S., redaktor
izdatel'stva; LOXTEV, S.K-., redaktor izdatel'stva; NOVICHKOVA, N.D.,
tekhnicheskiy redaktor.
[Composition and properties of Detroleums and gasoline-kerosene
fractions; a collection of naDers on the study of the composition
of netroleums and petroleum products] Sostav i evoistva neftei i.
benzino-keroeinovykh fraktsii; sbornik rabot po izucheniiu. sostnva
i svoistv neftei i nefteproduktov. Moskva, Izd-vo Akad.nauk SSSR,
1957. 518 P. (MIRA 10:11)
1. Akademiya nauk SSSR. Institut nefti.
(Petroleum)

SER(',IYF.IIKO, S.R.; DAVYDOV, B.E.; GALICH, P.N.
Molecular and surface properties of petroleum tars. Part 7.
Article No.7. , I -, 7 ('ej-ft 0 -/ (;aRk i1:4)
OVS, " I ~ , ,
/ ( etroloum) (Surface*chomistry)

SKRGIYENKO, S.R., prof.
- Stndies of Academician S.S. Nametkin in the field of chemistry
and petrolem refining (on his 80th birthday). Trudy inst. nefti.
10:5-15 157. (MIRA. 3-1:4)
(Nametkin, Sergei Semenovich 1876-1950)

SF,RGIYF,NY,O, S.R.; TETERIU, M.P.; BEDOV, Tu.A.
Infrared spectrum technique for determining the composition of
cx,' -and /,? -methylnaphthalene mixtures. Trudy inst. nefti. 10:
92-95 157. (MIRA 11:4)
(Naphthalene-Spectra)

SERGITENKO, S.R.; SYLLYAR, V.T.; TETERI11A, M.P.
Analysis of macromolecular fractions of 33rtkov petroleum.
Article N6.8j Trudy inst. nefti. 10:117-138 157. (MIRA 11:4)
(Bytkov region-Petroleum-Cracking)
(Macromolecular compounds)

SERGIYENKO, S.R.
Analysis of macromolecular compounds of Sagaydak petroleum.
Article no.9. Trudy inst. nefti. 10:139-152 157. (miRA 11:4)
(Sagaydak- region--Petroleum--Cracking)
(Macromolecular compounds)

SERGI,YEITKO. S.R.; TETERINA, M.P.; MIKOOVSKAYA, A.A.
,.-- --
Infrared spectrum anal7sis of macromolecular hydrocarbons and reffinir.
article No.10. Part 10. Trudy inst. nefti. 10:153-160 157.
(MIRA 11:4)
(Macromolecular compounds) (Hydrocarbons--Spectra)
(Petroleum--Spectra)

SERGIYENKO, S.R.; TETERINA, M.P.; ROZETTIERG, L.M.
Infrared spectrum analysis of macromolecular paraffins from
petroleum. Trudy inst. nefti. 10:161-169 '57. (MIRA 11:4)
(Macromolecular compounds)
(Paraffins--Spectra)

SERGIYENKO, S.R-4,,:qjQRD&SH, YL,.T.
Chemical nature and compostijon of condensed bicyclic compounds
from macromolecular fraction of Radchenkovo petroleum. Article
No.12. Trudy Inst. nefti. 10:170-180 '57. (MIRA 11:4)
(Petroleum) (Condensation product (Chemistry))

SERGIYENKO,.S-...&,-, ~IKffOVSKAYAP A.A.
Comparative study of chemical nature of macromolecular petroleum
hydrocarbons. Article NO.13. Trudy inst. nefti. 10:181-187 '57.
(MIRA 11:4)
(Petroleum) (Macromolecular compounds)

SERGIYENKO, S.R.; &-RASAVCHE?TKO, P.I.; PUSTILITIKOVA, S.D.
Influence of the temperature on the prolongness of heating and
the depth of conversion of the residual products of Romashkino
petroleum. Report No.l. Trud7 inst. nefti. 10:188-210 '57.
(MIRA 11:4)
(Romashkino region-Petroleum-Analysis)
(Distillation, Fractional)

SMIYENKO, S.R.; KRASAVCHEITKO, M.I.
Effect of the chemical nature of petroleum and the concentration of
resinous asphalt substances in the products on the character of their
chemical conversions. Report No.2. Trudy inst. nefti 10:211-233 '57.
(MIRA 11:4)
(Petroleum) (Distillation, Fractional)
(Asphalt)

-A- I I !
-D /

SLFRGIYENKO, S.R.; CHAYKO, V.P.
Studying the high-molecular-weight fraction of petroleum. Dokl. AN
Tadzh. SSR no.21:83-91 '57. (MIRA 11:7)
I.Predstavleno Institutom khImIi AN Tadzhikskoy SSR.
(Petroleum products)

Distri 4E3d/4E4f
vCeuies of depsit Ocrmtfoa In Rim, ("I du'
& R. Sugienko and P. N. Clatich, ZRII,
13% romatlc hydioc"W6-and'cyr
and iropwaffin fractions obtained from Di6cl oil by chro-
matograpw Iftethods (cf. C.A. 50,8196s) as wellas Die-sel oil
wat kept 2-5 y=s in ope glass vessels- at room temp.
IThe aromatia hydrocarbou~';re inust susceptible to dL~
sit lorination. 0.20,-01 of asplialtemeg ~ad
. .111L The c~clo- and I-oparaff-ins showed an e%teuded
r
Induction pejicd so, that after 2 years deposits were absent
-but a high cvncn. of peroxides vms found. DepoFit forma-
'tluu was at ft.-st rapid, reached a rnax., and decreased subsL-
quently, appirently retarded by oxidation products.

AUTHOR SERGIYENK0 S.R., CHERMYAK ff.Ya.
TITLE -K-1-n-ell-ceAnd Mechanism of the Liquid
Dioyalohexylethane.
(Kinetika i mekhanizm zhidkofaznogo
geksletana -Russian)
PERIODICAL Doklady kkademii Nauk SSS-R,1957,Vol
Received 6/1957
MMUM.&A
Phase Oxidation of Dibenzyl And
2D-2-M/67
ikislenya dibenzila i ditsikle-
113,Nr 2,pp 351-354 (U.S.S.R.)
Reviewed 7/1957
ABSTRACT The oxidation of the liquid hydrocarbons was carried out by means
of oxygen being blown through them. The absorbed quantity of oxygen
wasascertained from the pressure diorease in the closed circulation
plant and the measured quatities were periodioally replenished. The
residual quantity ofthe initial product as well as the quantities of
superoxicest aoids, e-thers and alcohols were then determined. Di-
benzyloxydation was carried out at 11o030,140, and 150*. The 3-sha-
pe of the ourve (ill.1) and the fact that the semi-logarithmie ana-
morphism of its initial parts are straight lines,giyo evidence of a
reaction process according to a chain mechanism with d:generated bran-
ches. In the initial phase practically only superoxide ( monohydre-)
develop. Otaer oxydation products are produced by the deoay of the
hydrosuperoxide with later oxydation of the products developed. Af-
ter a retardation ofthe oxygen absorption its consumption proceeds
with a steady, very small velocity. The dibenzyl replenishment on the
initial quantity inthis phase did not accelerate the oxygen absorp-
Card 1/3 tion. It follows from this that the oxidation delay does not origi-

S. R.
Composition and Properties of the High Molecular (Cont.) 647
Wal-Mit Fraction of Petroleum; collection of Papers., Moscow., Izd-vo AN 880/370PP.
products which were determined to be hydrocarbons (high paraffin content
and low resin content) and noniuminescent reddish-blue products (nitro-
gen containing compounds). Evidently, the high molecular weight compounds
contain aromatic rings and other structures of low thermal stability,
which fact can be regarded as confirmation of the low-temperature forma-
tion of petroleum. There are 2 tables and 19 references of which 14 are
Soviet and 5 English.
PART V. RESINOUS-ASPHALTIC SUBSTANCES. COMPOSITION, PROPERTIES,
AND RESEARCH METHODS.
;3ergiyenko,~P,,'R_, Davydov, B.E. Physical Properties of Petroleum
Resinous Substances 245
Resinous substances from the Romashkino crude and from the Gyurgyany
crude were taken for this study. The increase of the amount of acid
and neutral saponifiable substances is directly proportional to the
increase of the amount of hetero-atoms they contain (OS,N). All
resinous substances are characterized by considerable surface activity.
They can be separated into fractions of increasing surface activity
CarU3]4M:X 2nd Collection of Papw is publ. by AU Conf. Jan 56, Moscov.

run I boot MUITMOK MY/IT65
AkMexlys. nauk SSSR. Institut nauchnoy informatail
BLImira nerti I gas& Chealstry of Petroleum and OLs) NoAcow, lad-
An am, 19 T4 p. (34kriest Itogi nauki; Idtisichasklye nauklo,
2) Jtrrata allp inverted. 3,000 copies printed.
Bd.s G.D. Gallpern, Doctor of Ch*Wcsl Sciences; Rd. of Publisring
Nauss I I.?. Lookutoyal T*ch. &d.t To. V. Rakuni.
rURPOSZt This took Is intended for tbo specialist working in the
field of petroleum chemistry and for the orgunla chemist working In
"lated fields.
COVIRAOIs This is the first volume of the aerie@ devoted to the pro-
gress made In petroleum and gas chentstr7. The first part or this
eoll&atlon contains survey articles compiled by the staff of the
Petroleum Institute, AS USSR. The authors are Specialists working
an methods for the Isolation, separation, and Identification of
salrar organic compounds In petroleum. The articles give k survey
card 116
of literature up to 1956 with lose coverage of recent research up
to 1958. The second part to c4nearned with the characterlotica of
bIgh molecular weight compounds and methods ror the study of their
somponition. There are 124 references.
TAMS OP OOWMPr3t
3,r ~Jyattko__&R. , and V.11. P.r4hankxt. Study or the Chemical
WaTure or Sulfur Organic Comv*unds in Petroleum by Keane
of Catalytic flydrogenation 113
The authors review papers on the methods for the hydrogenation
at sulfur organic compounds. The method or astaly-tic hydro-
S*natlon promises to be very effective In the study of the
structure of sulfur organic compounds. There are 9 tables
and 29 rerarenceso 11 or which are Soviets 3 English,
4 (Mman, and I ft-anch.
1'sn
Iz:-MIQR Nown" VMxr COWOM" 6p MTNDLAW
Nigh Nolecular Weight Compounds of Petroleum
.4ra the study of the composition of high-
boll" WrOISUN fractions. It Inclufto much of the
eather a own research. several or the points are debatable
rw 4I Irl t:n of organic compounds Into one lane
L r a Irld I regarded by the editor a$ improper.
rableft I h not yet been solved, namely, the
g
lata"Ret n manomere and polymers In , crudes
to 6160 trogt6d. It to assumed that there am'two basic
types of polymers In crudest the primary and the secondary
polymers . 5.V. Zelinakly Y-P. Larravokly Indicated

SERGIYEITKO~ S.R.; CHAYKO, V.P.
Chemical nature of high molecular hydrocarbons in Khaudag petroleum.
Izv. Otd. est. nauk AN Tadzh. SSR no.1:73-80 '58- (MIRA 12:1)
I.Institut khimil AN Tadzhtkokoy SSR.
(Khaudag-Petroleum-Analysis)

I
S.H.; Yu.T.
".~Ml ~,
3homic-~tl miturs) and convormion of high-mLecular homologs of
pitrolaum naphthalene. Dal-1. All BSSR 2 no-7:294-298 M 158.
(mifu. 11:10)
1. Pri-.dstavlpno aluidemil-orn All BSSR B.V.Y(irfoyevym.
Olaphtalene)

62 - -) 9 --"
2
A U T "'C' -2 3 TeLrov, 11. ii., S. R., Tseiilina, A. L.,
Totcrin, I' T* Kislinskiy, A. !.., Gall-
J. - j _ ern, G. D.
TITLE: of Sati,rated 1'Ydrac.-.r',,ons (Iso-.lerizatsiya
.."syshc:.,enny',:h u-levodorocloov). C,):~T:'7lnic_.t-_;Oll 1 : I:30---eriC
Con-,,ercions of Ail-nes 71it'! C, - C Str,,ct7_,,a
0
1:I~-.oracrny.,e _~revr!~fi"ic'ieniya C c
PERIOXCAL: Iiwesti-ra S_'.3R,O+delcniYe K'J.-:Jc'-skV:i
lir 4, r371 - 445 (USSIZ)
A _R ST A F,'T_ Dirin- Vic laf3t n,.-.~er of it vms ~-oirltei
0-t t'l__'l S~.Au_-,a'ed h-.ldroc~Lrbons are stthJect to a rc,-.,ar::"ble
i-omcri:-.ation ( Rc~fL:renccs 1-4.) under hydro-en pressure
i.- tlie of catalYsts (alimosilic-tes) . Tl,.is hetero-
,~_-no-!S i.,,07eri-.~-tion re~ic+ion of sTti,_rated hydroc-.rbons
fovind already use at lnnr~-est
is Lttc7,ti3n laid to tl~e pre-aration of catLAysts
t*,C!--e Llile, however, r-r-latively few vicri--s dealin- t-e
Card 1 /3 in,,u-sti--,."-;on of L":c reaction of in-lividual hydroc,-.-_~bono

6 2 - 5 3 - , - 93, ~3 2
s
lz=cri~~aticn of Sat,:rlted Tl,-3rocarb~ns. Co:-~-.!= ati )n I
Conversions of Al'.-ancs 71ith C 6 - C8 Structure
(on the sa...,e conditions). On'y 'lie works 13y ChJa.etta and
Kl~,-_-:,.ter Oiefcr-ence J) are ~~n exce-tion 'here. As the in-
ve~3t_J.,-L_ti.:)n of ior.,:.~ric cunver~;iono of the i.,-.d 4 V iic~
Aydrocarbons of dif-'erent r-~'Lr~lcture is of :-reatert i:itere3t
t',-c decided to carry ort a :3ystematic in-.resti.-:_tion
of the isomerina! ion reaction of t,e all:anes wit'n C C
s t r! - c 1-1 1 - r e . T i e e x - c::- i r ~~- i i t -.v -- s c,; r r ie d o ,, t a c c o rI' o t'.e
flo..,-;n--- sy~:Lem on S-ecial cO:-.,Jt;nn3 ilil all i.-_-en t s
of t ~ U i 3 atio" of tj.,C 41 ..-e e
.-erfar-red ~.t lo atmo:~,Ivres excess
The obt-ined e.Cl~e,,47-jelltal data were comr--rel 7,it*, t,--e
calcul-Tte.1 tI-.erLojj,rnf1m_ic vallies.
A new mec:ianism of isomeric conversions of s_--ti-_,-ated hy1ro-
carbons in the Presonce of polyfunctional catal.-s-ts was
su-Zested. Accordi-n~; to this mec:ianism tne first; ot~~,-e of
Card 2/13 reaction leads to the fornation of olefines. Also a -reat

62-58-4-8/32
I7omerization of Satiirated Hydrocarbons. Communication 1: Isomeric
Conversions of Alkanes With C 6 - Ca Structure
number of new data were determined which offer new ideas
as to the binding connection, the structure and the
0
reactivity of hydrocarbons.Thel-c are 4 tables, and 17
references, 11 of which are Soviet.
ASSOCIATION: Institilt n.-fti Akademii nauk SSISR (Petroleum Institute,
AS USSR)
SUBMITTED: November 19, 1956
AVAILABLE: Library of Congress
1. Hydrecarbons-Saturated-Isomerizatim 2. AUanes
C6 - C8 -Isoneris conversions
Card 3/3

AUTHORS: Petrov, Al., A. '~)2-5c-5-10/27
Tsedflina, A. L. , Teterina, P,
TITLE: Isomerization of Satu-cated Hydrocarbons (Izomerizzatsi,'a
nasyshchennykh uglevodorodov) Coiiij.-iunic~.tion 2. Isomeric Conver-
3ions of the Alkanes of the C12 - C16-Structure (Scobshcheniye
2. Izomernyye prevrashcheniya alkanov sostava C12 - C 16)
PERIODICAL: Izvestiya Akademii Nauk S33R Otdeleriiye Khinicheski':h 7"aUk,
1958, Nr 5, pp, 575-583 (USS10
ABSTRACT% The use of polyfunctional cataljsts _akes the successful inve-
stigation of thefisomerization of saturated hydrocarbons with a
boiling-point up to 1500C possible. Nevertheless, it is very
difficult to achieve the isomerization of paraffins (with a
boiling-point above 2oooC) in the preoence of heturogeneous
catalysts. The purpose of this work was the investif:&tion of
the structure and of the properties of the iso::,'erizates. Above
all, the isomerization of a series of alkanes (structure C12-
-C16) was investigated in the presence of polyfunctional cata-
lysts. It was found that ramified hydroc.,._rbons, --iairly with 2
Card 1/2 -nethyl-secondary-groups are formed due to tlie isc-;:!e_-iz_-tio-i of

isomerization of Saturated Hydrocarbons. Communication 62-56-5-5/27
2. Isomeric Conversions of the Alkanes of' the C12 - C16-structure
the alkanes. Yloreover, a catalyst with lower fisoi--a-properties
was found in the isomerization of high-boilin.-
A thermodyna-mic calculation.bf the real equi libriu:.-.- c o;.-,po sit ions
of the alkaaes of the C12 - C16 %,,,as carried cut. *21_~re are 5
tables and 12 references, 8 of which are l';oviet.
ASSOCIATION: Institut nefti Akademii nauk 3S311 ( Poti-olcurl t i t ut e,7
AS USSR)
SUBMITTEDs November 19, 1956
1. Hydrocarbons-jsomerism 2. Catalysts--Applications 3. Methanes
--Applications 1". Hydroca--bons--Test methods
Card 2/2

AU T 11 GIR S Petrov, Al. A., Sexjj
, S. R.,, SOV162- 58 - 6 - 13/37
Z~~nko
.
..
Tnedilina, A. L~j KialiRsI:Ey-,'Y~ N,, Ga-11pern, C. D,
TITLE: The Isomerization of Saturated Hydrocarbons (Izomerizatsiya
nasyshchennykh uglevodorodov) Communication 3. The Isomeric
Transformation of Cyclanes (Soobshcheniye 3. Izomernyje prevra-
shcheniya tsiklanov)
PERIOD7CAL; Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh nauk,
1958, Nr 61 pp~ 730 - 738 (USSR)
ABST'RIACT: In various earlier papers the isomeric transformations of
alkanes are discussed, which develop in the presence of poly-
functional catalysts under hydro.-en pressure (Refs 1,2). The
main purpose of this paper is the investi-~ution of the rules
governing the isomerization of hydrocarbons and of the connection
between structure on the one hand and kinetic and therm-odynamic
parameters on the other, The catalytic isomerination of the
cycloparaffin hydroc-arbons C - C in the presence of a poly-
~
ro,-e~ presoure was carried out.
functional catalyst under hy
Furthermore, it was found that the isonerization products of
the cycloparaffins C and C correspond with res.-ect to -Gheir
'
Card 1/2 conposition to the thIrmodynt2mic values obta
ined by calculation.

-The of Saturated Hydrc3arbons- S%'a7/62-`P--6-13 '37
Communication 3. The Isorieric Tra%rforrlation of Cycla-res
A mechanism for the isomeriz-Aior, of cyclo;)araffins was
ou,-,,- according- to which t~ie for:-,ation of unsatur"ted
LI ested,
hydrocarbons fi!-Ures as the first sta:-e of reaction. Furtherr-7ore
the influence exercised by pre:i~itre and temperatiro u'~on the
direction of the reactions of cyclopraff"ins in V,.e ~.-esence of
a polyfunctional catalyst wns shown- T'.erc are 5 tables and 17
references, 0 of which are Soviet,.
ASSOCIATIOIT: Inst-itut nefti Akademii nauk SSSR (Petroleum Izstitute AS USSR)
SUB,."ITTED: November 19, 1950'
1. Hydrocarbons-Isomerisir. 2. Ce-ta2,ysts-Performance 3.
--Chemdcal effe(As 4, Temmerature-Chemfeal effects
Card 2/12

SERGIYENKO, S.R.; SEWACHKO, R.Ta.; DAVrWV, B.Z.
Studying the composition and properties of high-molecular-weight 1.
hydrocarbons and tars of Gy-urgyanakiy petroleum. Article NO-13. Trudy
Inst.nefti 12:65-75 158. (MIRA 12:3)
(Hydrocarbons-Analysis)
i

SERGIYENKO, S.R.; MVTDOV, B.B.; LITRAIMICH, A.D.: SHAKHRAY, V.A.
Some physicochemical properties of petroleum asphaltenes and tars
in 961irtIon. Article No.14. Trudy Inst.nefti 12:76-82 '58.
(MRA 12:3)
(Tar) (AsphalteneB)

SERGIYP,IIKO, S.R. -, GORDASH, Yu.T.
Compositinn and pronerties of the tar fraction of Radchenkovo petro-
leum. Article No. 15. Trudy Inst.nefti 12:83-87 '58. (MIRA 12:3)
(Tar)

SKRGIYERKO, S.R.; GORDASH, Ye.T.
Low-temperature conversions of high-molecular-weigh~ aromatic hydro-
carbons of Radchenkovo petroleum. Article N6.16. TruAk-Inst.nefti 12:
88-101 158. (KRA 120)
(Hydrocafbons)

SFJIGIYENKO, S.R.; LKBRDEV, Te.V.
Chemical nature of saturated high-molecular-veight hydrocarbons
of Romashkino (Devonian) petroleum. Article 10-17. TrucLv Inst.
nefti 12:102-116 '58. (MIRA 12:3)
(Hydrocarbons)

SERGIYENKO, S.R. ; LIBNW, Ye.V.
~ -0
Chemical nature of naturated high-molecular-weight hydrocarbons of
Romasbkino (Devonian) petroleum. Article N6.18. Trudy Inst.nefti
12:117-135 '58. (MIRA 1-2:3)
(Hydrocarbons)

SERGIYF,NKO, S.R.; MIIMWVSKA.YA, A.A.
Chemical nature of high-molecular-weigbt monocyclic aromatic hydro-
carbons of Romaehkino (Devonian) petroleum. Article No.19. Trudy Inst.
nefti 12:116-146 '58. (WRA 12:3)
(Hydrocarbons)

SERGIYEI&O, S.R.; IMMKINA, I.A.; NOURINA, Ys.V.
Study of the chemical nature of high-molecular-weight bicyclic aromatic
condensation compounds of Romashkino petroleum by the method of cataly-
tic hydrogenation in the presence of Raney nickel. Article NO.20.
Tnidy Inst.nofti 12:147-155 '58. (MIRA 12:3)
(Aromatic compounds) (Hydrogenation) (Catalysis)

SERGIYENKO, S.R. ; WZDRINA, Ye.V.; 1XVIKINA, I.A.
Hydrogenation of high-molecular-weight bicyclic aromatic condensation
compounds of Romashkino petroleum carried out under mild conditions
in the presence of the catalyst WS2-NiS-Al2O3. Article N6.21. Trud7
Inst.nefti 12:156-167 '58. (MIRA 12:3)
(Hydrogenation) (Catalysts) (Hydrocarbon)
I'll, .1

SERGIYE14KO, S.R.: MMKII-1h. I.A. -, NOURINA, Ye.V.
--------------
ffydrogenation of tare extracted from Romashkino petroleum. Article No.
22. Tnidy Inst.nefti 12:168-174 '58. (NIRA 12:3)
(Hydrogenation) (Tar)

SERGIYENKO, S.R.; KORCHAGINA, V.I.; GALICH,P.N.; RUTMAN, L.I.; DAVTDOV, B.B.;
KRASAVCHENKO, M. I.
Effect of the depth of sampling on the composition and properties of
heavy residual stock. Article N6.23. Trudy Inst.nefti 12:175-186
1 58. (141RA 12:3)
(Petroleum products-AnalysiB)

SERGIYENKO, S.R.; YORCIIAGINA, V.I.; GALICH, P.N.; RUTMAH, L.I.; DAVYDOV, B.B.;
rMASAVCHENKO, 14. 1.
Effect of the nature of food stock and the duration of oxidation on
the composition and properties of oxidized bitumens. Article No.24.
Trudy Inst.nefti 12:187-199 158. (MIRA 12:3)
(Bitumen) (Petroleum-Refining)

t
I I
T.
xMTOA.'T: 2 L e.".e t I v f- a On,., 0-- 1 v I dun.- ny o -
a!,.! thei---., and w~s'--S
of
Ii-L LVS
o f 1,-, --11, z, s t e 1, J,,:r.j2.-oc!-rbon:3.
At -i~ve-rnt the examination oil t 1 i c, c- o n. o c 1 0' 1
t e S t 1-11 ct u o i-c ".1-Orert -i r'S of 'L h o t : r:r. 0 f:(~ ra
"te wc- J. t` `!m
t ~ ng n,,ore than f -----ude
o ; 1 -'n tlnis case f. vh,,rsical and chemicv! txm be
enim' oyed, that I s to say, inethods for the determlination ot.
,.-rd. 1/3
t'e auantitativ,, dei!enlences of the bas--c ipiysicr~l ~p:.o...erties

'67
Th-L of Hieri--.1olecular Hydrocarbons of -!,Ii-xe:l 3-tructure
f t I ve er, t i I -e ~,- -DM, pl- --c&t a' I Sys t cr. I -p-0, A 1c
ition. or th!-s rjurpuoe it is necessary to in,,-rtigatk:
the said depindence -imultancously -;,ith nn'tural
7 rj-~4
systems ,Uii as ".iti, (fvt4f4c-1:-1 mixtures of - .,--.idual
comilounds. he rnolccule3 of Ili -h -r.-Iolecll lar 0",
Poun,~v .-Id a Ove) aecordin6, to the
2 0 "L
recent years exhibit a mixed (hybrid) st-ructi~-i-~!. -l'i othc~:-
wor,1s, str;.-ctural rnernbers of different ho,:!ol.,-),,r t~:.Jke
;)Prt In t'le composition of the molecule. The ra-tio betv:eer.
-tructure elements of aliphatic P-nd cyclic na-ture var'ec r'th-
In wide iimlto according to the che,-iic;.---! nature of the rrinpral
oil. It was decided --n t,,is connection to a number
o!' hit-nerto r..-,)t described hydrocarbons with -- structure rar-ing
0- 0
from c", to C, with a different proportion o~' carbon atoms
In The Stl."Ucullral elements of the molecule. The i)roduced
hydrocnrbons together with their properties are --iven in
table 1. -t contains 15 compounds. Finally some particulars
Card 2/3 concernin..- the synthesis are given. Thpre -is 1 table.

9 07/1 -_' c, - 1 71
The :..~Ynflhesis of High-:oleeular Hydrocarbons of 111imed .'.tructure
AS 3 OC AY 1 ON : Tri:.Hf?1j. 4,
1 ~ 'wkti .*,`-.d_n_-di nauk Ss:~J?
(Petroleum Institute, AS USSR)
FRES-1~;NT--I'D
:-3 U B114! !T111 " 1)
J-.!-.uLrY 4, 4.91';S, by 3. 1.. zxbuzov, 'Ier-nber, '.calemy of
'.'ciences, USSR
"')O.Ceriber 17, 1915 7
i
1. Hydrocarbons--Synthesis 2. Hydrocarbons--Spectrographic
analysis
Card 3/3

5( 7 ) I
AUTHORS: j$er,:iyerkQ, S. R. , Lobed ev, Y.:. 11. , SOV 2o-i27-~-36/_3
0v , A
TITLE: Sel~ctive C-talvytic DehyOroge-ition of Saturated HiEh-11olecl-,-lar
Hydroca:-bons in Li:,," -11--e (I-"ra~el Inaya
de,~idr3--e!~i~:atsiya p-rc'!elln7lk h u.-',evo~orodov
v zhiakoy faze)
PEKODIC2"L Doklaly Akadeaii nauk SSSi, 1957, V:~l 123,
PP 704 - 706 (USSR)
- I (Ref 1 h-, s not yet
.,BSTRACT: The reaction discovered by Zelirz;'-iy G , -
been used for the purpose mentioned in the title, as far as
it can be judEed from references. Itsusefulness in stulying
the structure of hiEh-molecular petroleum hydrocarbons had
to be checked by the authors. Synthetic hydrocarbons C 2o-C 32
cyclohe,-ane-, 2-Dekalin-, 1-cyclo-
were used v,,hich cont-in 1-3
pentane nuclei ---.-nd 1 paraffin hydrocarbon of Structure.
First , the o,-.t -imum cord it ions of t, -- de'-y'l-ro~7enat ion ment --; one,2
in t-,e title ;.,ere letormined -nd .".e -.~S re zas
Card 1/3 co,.~.--,t rt-.ct ed F-i,.7 1Pt on ch-. rc oal rao ed IS '2, tyst

I
Selective Catalyt-ic De'-ydro-enation of Saturatc-d ~,-J.-h- '307 2 o - 13 6/5 3
Molecular Hy.-Irocarbons in Li--Mid Ph;tse
(accordinj:,,- to Ref 2). To expl-An tho behaviour of the -n-I%1ro-
carbons of v,"rious strt~cure tho followi-~r in~--ividual comonounds
were s:rnt-e-,-4zed: n-tetracos~--:e,
7-( oct a do--are , I Ov.-1C'hOxY`;.-~-hO;:,'-y1 an C-,
methyl cyclohexyl)ethane, 2,11-di-Oecahyr!ro na,;hthyl doiecane,
in ti,.e invc-ottigation the author
1 , 1-licyclohexyl (todo-cane
found th-zt tI.e dchydroge-1-tion of thc il--lividual hy,-roca-rbons,
-v.-h'ch ---re the ho:ioloZs of cycl-Dhexanie ard Decalin, takes :)lace
2 50 0. T
lrea,ly at 21 -n th-:? 1i'--4 "la L-e the t ture i s
315-~20'. At tlZit tei.-erature the de',Ylro,--er:;~tion of all in-
vesti:----ted hy~!rocarbons c,)nt-ir; isol--ted as viell as con-
dlenl-ed hex--.:-ivthvlc-ne structures, is ns a fi:A~'-e4 -4"-in
-6 hours, ;-.-ith practicall.,.- nc ta?kin-- place. Fi~-re, 2
sho,rs the ch-=-e of t;:e se-aration and of itS tot--!-
ar~ount _i- =::-ze of ti-e. Tho r action tem:~er~.tu--e -n=ounted
in --l! cases tc 315(). Tal-1-- I s~lcws the results o-4~' +.;-.-- catz.-
1,-Lic --chy-,ro.-enat-ion -,--F the -and
~
V-e increase of the number c-.:' nuclei
Card 2/3 occurrence of grouDs in 'U..e:: has o.--1-, !it"-c:

Selective Catalytic D,?hy~rogen_ntion --f Sz_:t-._=atG,-_7 Hl*,~h-
Molec,,.,.lar Hdroctrbons in Liqi;id ?h,~oe
ASSOCIATION:
PRESENTED:
SUTHTTED:
,on the, R-hydrojet-ation. Two no:;I-lenred haxanet-.ylene 6--oups
render thi,~ proces.- riore di'fficnlt. By interrupting this ex-
per-iment it was rol.-A thjit ti-ie dehy.,IlroCeration of. the cyclo-
lie.,,,yl nuclei tLl-cs place in both directions it the sa:.-~e ti:ne:
a) Of both nuclei. b) Of only one nuclous. The r,.)Ie of the
cyclizn.tion by dehydro~e:iation is unimportant. The above in-
ve.sti.-,.tion has th-1-t the method of investi,,.-ating fractions
of the -i~-.tioned ~)etr,.)I_._-um h-.,-3roc-,-.rbo!,s ,,.,ith c,ycloparaffin
nrclei as nt_,_ntione,! in tl:e title may be used successf4lly for
the det---iled characterization of t,.e-Lr c-e_~-_'Ical structiLre.
There are 2 fimires, 1 table and 2 Soviet references.
Institut nefti Ak2dlemii nauk SSSR, (Patrole= Inst-itutte,Acalemy
of SciencesJussn)
July 15, 1958, b~,- A. A. Balnnrlin, Ac_ade-licfa-
June 17, 1~15,9
Card 3/13

T
Alpw
0 crpyhTyFE "hICONOM0.1EXY.19FIFLU
MIE803OP0,108 FIEOTX
C.P.Cop-*.- ILIL A@ itx,k A. ALM as,
PPII~d cbmals"
fW OWARSI mal A
cloulawy 8" cums"I fteboLow of Fo*U,
!=
901. 19"
Ira
11
I"
b.%,Wu at " SON*"" to be p oba" mustland fampow,

A
HIM,

RI
U
w
k
aft

Egg[ Inn,
>
c r,
MO.
go
sit

PHASE I BOOK EXPLOITATION SOV/33~0'_
rglyeitko, .--men Romanovich
--.1'ysokomoleiculyarnyye soyedineniya nefti (High-molecular ComDounds
of Petroleum) Moscow, Gostoptekilizdat, 1959. 412 p. 2,~00
-:!optes printed.
_"xer~ Ed- L. A. Llvova; Tech. Ed.: A. V. Trofimov.
P'J'RNSE~' This monograph is Intended for s,,Ientifi.- workers
ao.d aspirants specializing in chemistry, petroleum technology
and pel'roleum chemical synthesis. It may also be useful to
eng-ineers and teennicians of the pptroleum-reflning and petroleum
industry.
COVERAGE4 An at-Itempt Is made to analyze theoretical studies of
bigh.-molecular components of petroleum a--%d to summarize experience
~~f -the refining Industry gained in dealing with resinous or
crudes a-rid with heavy petroleum products. Composition,
properties and structure of high-molecular hydrocarbons from
tz~
C a r d 1, /9

High-Molec.u.1ar Compounds (cont.) SOV/3330'-
petr,:~leum are reviewed along w1th chara,~"',eristlcs of petroleum
paraffin and ceresin wax. Chemical properties of hfgh-inolecular
hydrocacbons of some Americaa and Soviet crudes are analyzed, and
the applicatlon of adsorption. ohromatography, Infrared spectro-
scopy, ~';at_--aiytl~ hydrogenation and dehydrogenation In the study
c.f chemical structure of high-m(,Ie..-;ular petroleum components
I's disf-ussed. Petranleusm carboxylic and napthenic acids, their
origin and cause of formation are s-~udied, and pet.roleu-M sulfurous
organic ?~~ompoundo, resins, asphaltenes and bitumens -are analyzed.
Me author also considers condensed polycyclic hydrocarbons as a
possIble source of cancer and suggests mpasures to reduce risk to
refiners. Structures of various types of hydrocarbons and the
~oipposltl-ion of high-molecular hydroctarbons contained in crudes
different regions of the Soviet UrIon are illustrated in
nuji,erous tables. The author thanks V. T. Sklyara, Yu. T. Gordash,
1. S. Mayorov, N. V. Zhdanova. B. E. Davydov., Ye. V. Lebedev and
I.L. r. Te"erina for their participation in writing certain secticrI4
he also f.hanks L. V. Ratnllcova,, S. E. Kreyn and V. A. Sokolov for
theAr help. References, the majority of which are Soviet, appear
at the end of chapters.
rd 2

Compou_rids (Can't.) SOV/3336
~ABII_E OF IONTENTS.
3
ductL~n 5
p.A,R*T- r. PROPERTIES COMMON TO DIFFERENT HIGH-MOLECULAR PETROLEUM
COMPOUNDS AND METHODS USED TO STUDY THEM
'.h. 7(.. Diqtin~.tive Features of Properties and Composition-
of High-Molecular Petroleum Compounds 13
B-ast",% fr-eatures of high-molecular petroleum compounds 14
11"auses of diversity of high-molecular petroleum com-
p * ix,~d s. 17
B.,,bl lography 23
Me~-hods of Separat!-ng High-Mole-ular Petroleum
Compounds 25
Ads,)_rptl-lon ohromatography 26
Mc,-A:%,aLar distillat-Lon 38
Bib.`.i~~,graphy 47
Card 3/9

High-M,-.1ecular Compounds (Cont. ) 3-0V/3336
PART 11. COMPOSITION, PROPERTIES AND REACTIONS OF HIGH-
MOLECULAR HYDROCARBONS OF PETROLEUM
Ch. IIT. Paraffinic Hydrocarbons 55
Basic proDerties of different type3 of paraffin wax
and their dependence on wax structure 56
Ohemic--al properties and reac--tjons of different types
of paraffin v-,rax 78
Orystal.1.1.ne form -)f paraffin wax and its dependence
upon the chemical structure of hydrocarbons and
,.rystallization conditions
95
-Chara?.:~-',--eristios of petroleum paraffin and ceresin wax -97
1%-:,r-.tent of paraffin wax In crudes from Soviet oil fields 115
Bib.-Liography 118
Ch. TIV. Hydrocarbons With Hybrid or Mixed Structure 122
of compounds with hybrid (mixed) structure
in petr-:~Ieum
C a,,7 d 4/9

Compounds (Cont.) 3 OV/3 3 3 6,
J 'Y' ~&
Dependeneu, or properties of high-molecular hybrid hydro-
carbons on their structure 125
ChemIcal nature of high-molecular hydrocarbons of some
American crudes 145
Data on chemical structure of hydrocarbons of lube oil
frac'.-ions in some Soviet crudes 151
Study of the chemical nature of high-molecular hydro-
carbons of crudes 167
App--_'Ication o~ methods of selective catalytic hydro-
genation or dehydrogenation to the study of the chemical
structure of high-molecular petroleum hydrocarbons 1.73
Application of infrared spectrosaopy to the study of
high-molecullar petroleum hydrocarbons 191
Bibliography 201
Ch. V. High-Molecular Aromatic Hydrocarbons of Petroleum 204
Content of condensed aromatic hydrocarbons in crude
oil 204
Card 5/9

1f1gh--Mo!_ei7-ular Compounds (Cont.) SOV/3336
Dependence of properties of condensed aromatic hydro-
C-arbons on their ehemical structure 206
Effect of distillatio-, on the carcinogenic activity
of high-molecular petroleum products 213
Prs,,~esses of thermocatalytic condensation of aromatic
nuclei 216
Bibl"Loigraphy 221
PART III. COMPOSITION, PROPERTIES, OWD REACTIONS OF
HIGH-MOT-FOULAR HETERORGANIC COMPOUNDS OF
PETROLEUM
Gh. VI. Carboxilic Acids from Petroleum 227
Early investigations 227
Distribution of carboxilic acids in pet.-oleum. 228
Chemi.~:al reactions and properties of pe"Droleum car-
boxilic acids 231
Salts of napthenic acids, their pro-Derties and utili-
zation 234
Oai-d 6/9

0
..Igh-M t~-.ular Oampounds (Cont. SOV/3335
Da'a -z.!: t"he chemi.,,al features of petroleum a,ids of ultrahigh
weight 237
OrIgtn and cause of petroleum aoid forma-"Aon 243
Bibli-graphy 245
VTT. Sulfurous Organic Compounds in Petroleum 247
,7harar-ter of distribution of sulfur in crudes 247
C~iara%-~,-er of distribution of sulfur in petroleum
f ra,-, -.ions 249
-~hazta;,..ter of distribution of sulfur in high-molecular
-_.omponentls of petroleum 251
Nature of high-molecular sulfurous compounds in
p e r- ol e .in 258
P-r-pt. '.
r4 �es and rear.:tions
of sulfurous organic compounds
261
Me"_-.hods of separating and analyzing sulfurous organic
267
Selec-~ive catalytic hydro genation as a method of demon-
strating the structure of sulfurous organic compounds
In petbroleum 279
Card 7/9

Ili gh-Mo..~'e Compounds SOV/3-336
Blbli,~,4graphy 291
Ch. V11*1. Petroleum Resins 293
General" olharacteristles of resinous--asphaltenic
substances of petroleum 293
Prinr-,iDal trends in their utilization 294
Geneval principles of analyzing and classifying bitumens
and resins 295
Or-,,mposition, properties and distribution of resins In
p e 1 e um 300
Met-nodo of extraction and separation 302
S-udy of resins from Soviet crudes 307
Ch-em�j-al nature of resins 313
Applioation of infrared spectra to the study of
pe-.ro.Lewn resins and bitumens 332
Appl-ication of luminescence analysis to the study of
pe,~~roleum resins and bitumens 336
Bibliography 343
Ca-rd 8/9

=~~.ular ComDou-nds (Contl-.
SOV/3336
"'h. IX. Petroleum Asphaltenes
Pr,~perties of asphaltenes
Molecular weight of asphaltenes
Chemic.al composition and structure of asphaltenes
Bibliography
Gn. X. Physical Properties of Resins and Asphaltenes
Mc-lecular surface properties
Dependence of molecular surface properties of resins
on -N,heir composition and structure
Pc-larization properties of high-molecular petroleum
r
.~cmpounds
Bib'_.Iography
C C) n ~ "! -1, U S ic. n
BiA.3'egraphy
AVAILABLE: Library of Congress
Card 9/9
346
346
350
362
376
378
378
382
391
403
406
411
tWMnk,
4-25-6o

3/165/59/000/04/02/026
AUTHORS,. Sergiyenkc,, S.R., Lebedev, Ye.V. and MtklrLnovskaya, A,A.
TITLE,,, On -:~he 9-_r-.~ct.ure of High Molecular Hydrocarbons in
PERIODICAL- Izvest-1-ya Akademil. nauk Tiirlunenskoy SSR, 10,59, No. h, pp. 10 - 23
IM-T, The article reviews the chemical priperties of high molecular
hyd-rocarb-c-ris In petrsleum as presented in the Secfion of Chemistry and Tech:nology
of Puel at the 8th Mendeleyev Congress n March 17, 1959 In Moscn-w, investigation
of chemi.--al and -~;ecnnlcal pr:.perties of these hydrocarbons is impcrteLrit in view of
their proposed use as raw materials for synthetic pr--ductS during the current
Seven-Year Plan, Data ccntained herein have. been obta-Inedfrom 15 different types
of Soviet petroleum. The Romashkin T%ymazin, Bavlin, ri3rargyan and c-ther petroleums
contain aboLzt 40% h-igh molecular hydrocarbons, in heav:ier petroleum they frequent-
ly exceed 50%. To elimInate chemical changes, vacuum was used for distillation
of fractions up t~~ -525-3500C, at a maximum. temperature of 2500C, Cbromatographis
fractionation was carried out with coars6-vored activa-led silica gel (A3K). me
group compositl-_)n of high molecular hydrccarbons and their paraffin-cyclopar-affinic
(PCP), mcnocycloar3matic (,MCA) and bicyclsaroma-.-I~_- (BCA) hydrocaYbon cc-ntents in
various types :)f petr:)Ae~= Is shc-wn in Table 1. The main ccmpcnents of high
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OP -the Str-ac.-Vare of High Molecular FlydrocaZ-bons In Petroleum
I
molecular hydrocarbons are Paraffin-cycloparaffinic hydrocarbons with high hydrogen
content (40-60%), bicycloarcmatic hydrocarbons with low hydrogen content; and
the medium group are definitely monoayclcaromatic hydrocarbons, The differences
in chemical properties of petroleum are particularly evidertin composition and
properties of paraffin-cycloparaffinic hydrocarbons, as far as the determination
of their chemical properties remains limited to their reaction in forming a complex
compound with cartamide. Distribution of carbon atoms of various chemical prop-
erties in similar groups of hydrocarbcns extracted from Soviet petroleum is shown.
in Table 2. The question about chemical properties of cycloparaffinic rings and
the relation of hexamethylene and pentamethylene rings in the molecules of
par,affin-cycloparaffinio hybridic structures remained unsolved. Number of cyclo-
paraffinic and benzene rings in paraffin cycloparaffinic, monocyclo-a-romatic and
bicyclo-aromatic hydrocarbons extracted from various types of petroleum is shown
in Table 3. Groups and Droperties of paraffin-cycioparaffinic hydrocarbow; mono-
cyclic aromatic petroleurr. and bicyclic ccndensed arcmat-1-- hydrocarbons are shcwr-
in Tables 4, 5 and 6. Results of a th-ree-stage fracticnated de-hydrogenation are
given In Table 7. It shows that 'Lhe relat-ion of hexaff.,ethylene and pentamethylene
rings In tile Roma-shkin (Devon) petroleum varies from 1-1.5. Properties and
structure of paraffin-cycloparaffinic hydrocarbons ex-tract-ed fr= 3 fractions,//
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On the Structijre of High Molecular Hydro:arbons in Petrolelam
of paraffin cycloparaffinic hydrocarb:,ns ar,~- shown In Tattle 8. Oxidation of
benzene homologues in 30 hours at 97-9qoC is sh,:;wn in Table 9 and oxidation of
hybrldlc hydr~~carbcns C20-C24 in 100 hours at 97-990C iT given in Table 10. The
degree of oxidat-lon of benzenecarbonic acids i.e. oxallic and carb--nic acids in
30 hours at 97-990C is shown in Table 11. -The oxidaticn and infra-red spectroscopy
method showed that among high molecular monocyclic hydrocarbons of the Romashkin
(Devon) petroleum triBubstituted benzenes are predominant. Tests proved that
sulphur contained in high molecular fractions is constitutionally coi-nected with
aromatic compoLnds accompanying bicycloaromatis hydrocarbons. There are 10
tables and 1. diagram,
ASSOCIATICNN~
Institut geologil I razrobotki gVyu,chikh iskropayemykla Akademil
nauk SSSR (Institute of Geol3gy and Prccessing of CombuStible
Minerals at the AS USSR.) V11,
SUBMI=- July 11~ 1959
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SERGITERKO, S.R.
D.1. Mendeleev and problems in stud-Ang and utilizing petroleum.
I7v. All Turk. SSR no.5:3-15 '59. . (MIRA 13:3)
(Petroleum) (Mendeleev, Dmitrii Ivanovich, 1834-1907)