SCIENTIFIC ABSTRACT SHABALINA, O.K. - SHABALINA, Z.S.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001548230003-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 49
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

The Effect of Boeirilte and Maspore Addition on 77626
the Rate of Decomposition of Aluminate Solutions SOV/80-.33-2-1/52
A a)
so
40
jo I
20- z
f0 -
0 __O
B
20 Q so go
4 b)
JO
zo -
10-
0 0
-fo
zo ~0- 80 m
Card 6/ 9 See Card 7/9 for caption

The Effect of Boemite and Diaspore AdditLon on 77626
the Rate of D4--composition of Alwninate Solutions SOV/80-33-2-1/52
Card 7/9
Fig. 3. Decomposition kineticsof aluminate solution
with different amounts of seed crystals from incomplete
recrystallization.product of boemite into diaspore:
a -without organic admixtures; b - with organic
admixtures, 1% based on Na 20gen; A -degree of the
solution decomposition (in %); B - duration of the
decomposition (hours). The seeding ratiot 1 - 0.05;
2 - 0.1; 3 - 0.2; It - 0.5. The seeding ratio In Fig.
3b Is in the range 0.05-0-5.
Decomposition of the aluminate solutions containing
seed crystals of thermal boemite results in
precipitation of the comparatively large hydroxide
crystals, most of which are +50-100 A very fine
precipitate of the hydroxide crystaUL--4qL up to

The Effect of Boemite and Diaspore Addition on 77626
the Rate of Decomposition of Aluminate Solutions SOV/80-33-2-1/52
46-55% was observed when seed crystals of the
hydrothermal beomite were used. The solution in thIs
case did not contained any organic.admixtures. The
small amount of seed crystals (the seeding ratio 0.05
-0.1) facilitates the precipitation of fine crystals.
Analysis of the hydroxide crystals indicated that
%they are composed-of hydrargillite and seed crystals
and the precent of the hydrargillite is higher than
could be expected from decomposition of the solution..
It means that part of the seed crystals undergo
transformation into hydrargillite. X-ray phase analy-
sis of the precipitates obtained during the decomposition
of aluminate solution containing seed crystals of
hydrothermal boemite showed that they also contain
bayerite, I. e., that hydrothermal boemite on mixing
with aluminate solutuion Is transformed first into -
bayerite and then into hydrargillite. The high seeding
activity of the product of Incomplete recrystalliza-
Card 8/9

The Effect of Boemite and Diaopore Addition on 77626
the Rate of' DecompOs1tion of Aluitililate Solutions SOV/80-33-2-1/52
ASSOCIATIONt
tion of boemite into diaspore, compared to hydro-
thermal boomite, ILi due to the partially distorted
crystalline lattice of unrecrystallized boemite, the
outer layer of which is transformed at first into . ,
bayerite and then into hydrargillite. Tne induction
periods (as it is shown on the decomposition kinetics
curves) is due to the recrystallization of the outer
layer of boemite into hydrargillite. Microphotographs
of the formed crystals taken with an electron microscope
are given. It was concluded that diaspore is inactive
as a seeding agent for the decomposition of the
aluminate solutuions. Ther,-~ are 9 figures; and 6
references, 2 Soviet, 3 German, and 1 U.S. The U.S.
reference ist Iaubengayer, A., Weisz, R., J. Am. Chem.
soc., 65, 247 (1943).
Ural Polytechnic Inst-Itute, Sverdlovsk (Urallskiy
politekhnicheskiy institut, Sverdlovsk)
SUBMITTED: April 11, 1959 Card 9/9

5.4220 782o6
SOV/80-33-3-7/47
AUTHORS; Kuznetsov, S. I., Derevyankln, V. A., ShabalIna, 0. K.

TITLE: The Effect of Added -Alumina and Corundum on the
Rate of Decomposition of Aluminate Solutions
PERIODICAL: ZhUrnal prikladnoy khimli, 1960, Vol 33, Nr 3,
PP 547-552 (USSR)
ABSTRACT: This is a contihuation of studies (Abstract 77626) on
the rate of decomposition of aluminate solutions under
the influence of added aluminum-oxide grains. This time,
the authors used ' -alumina and corundum seedsand the
transitional products between the two, to accelerate
aluminate decomposition by growing crystals. The
three types of seeds were produced on annealing
hydrargillite at 8ooo C for 4 hr, diaspore at 1,2000 C
for 5 hr, and hydrargillite at 1,1000 C for 12 hr,
respectively. Figures 1 and 2 illustrate the seeds of
Card 1/6 alumina and its transitional products to corundum

The Effect of Added - -Alumina and 782o6
Corundum on the Rate of Decomposition SOV/80-33-3-7/47
of Aluminate Solutions
effectively accelerate the decomposition of dis-
solved sodium aluminate after a certain period of
induction, while corundum does not affect the
aluminate decomposition during any duration. The
induction period decreases with the increasing
quantity of the seeds relative to that of the alu-
minate solution, i.e., with the seeding ratio.
Organic impurities first reduce the decomposing power
of ..'-alumina, but later increase it considerably.
The decomposition of' aluminates by -alumina gives
rise to the precipitation of extremely fine aluminum
hyd'roxide. UP to 30% of the grains remain smaller
than 40 - .' Small amounts of organic impurities
increase this fraction up to even 70%. However, the
higher contents of organic substances make the hydroxide
slightly coarser. Larger quantities of seeds (seeding
ratios 0.2-0-5) also reduce the grain size of the
hydroxide. The precipitate, generated by the
transitional products from --alumina to corundum,
Card 2/6 consists of up to 25% of the fraction under 40 -- ,

The Effect of Added '-Alumina and '(8206
Corundum on the Rate of Decomposition SOV//-30-33-3-7/47
of Aluminate Solutions
Card _3/6
in which the majority of grains vary from
across. X-ray diffraction data proved that all the
precipitates consist of hydrargillite and the surface
layers of the seeds themselves also turn into hydrar-
gillite during the initial period of induction. Perhaps
-alumina first turns into boel-nnite, then into
bayerite found in the X-ray diffraction photographs,
then into hydrargillite. Electron microscopic data
disclosed the composition of '7"-alumina of amorphous
minute particles, whose porous aggregates have large
surfaces per minute volume. During the induction period
they become covered with dendritic crystals of boehmite
and hydrargillite, 0.1-0.5 ' long and 0.11 across,
whose crushing off at stirring of the solution produces
numerous new crystallization centers. Some of the fine
grains of . -alumina recrystallize into hydrargillite
completely and form pseudohexagonal Dlatelets. In
conclusion, the authors state that the seeding capa-
city of boehmite and ".,*-alumina is related to their
instability in the presence of hydrargillite.

The Effect of Added '"'t,-Alumina and 782o6
Corundum on the Rate of Decomposition SOV/80-7113-3-7/-417
of Aluminate Solutions
ASSOCIATION:
SUBMITTED:
During the Induction
i-n.t.o hy-drargillite.
because of the Very
into hydrargillite,
aluminate solutions.
true for corundum.
1 Soviet reference.
period, theiv surface layers turn
Diaspore ts zlw unstable but
low rate of Its recrystallization
does not cause decomposition of
The same reason is likely to be
There are 8 figures; 1 table; and
Ural Polytechnic Institute, Sverdlovsk (Urallskiy
politekhnicheskiy institut. Sverdlovsk)
April 11, 1959
Card 4/6

30
fill
40 2
.10 jo
10
fo
2 a
-10
-2,9 ~O so
2d ;0 450 10 40
Fli-:. 1 Doe:oinposlt ion b.-Ineties of' aluminate solutions
contalnini~- Jillf'erent (luantities of '/-alumina seeds.
0
(a) Without rganic impur i ties; (b) with 1% 0,) of
impur,ities (,-on.;idering* total Na2O 100%; (c)
with _~% 0,,-) ol' organic impurities; (A) degree of solu-
tLon decomposition (%); (B) duration of the decomposi-
tion (1ir). Seeding ratio: 1-0.01; 2-0-05; 3-0-07;
11-0.1; 5-0.2; 6-o.L7.
Card 5,16

7822o6 sov/80-33-3-7/47
Fig. 2. Decomposition kinetics of aluminate solutions
containing different quantities of the seeds produced
by an incomplete recrystallization of '/-alumina
into corundu-n. (a) Without organic impurities; (b)
1% 0, of organic impurities considering total Na20
100,0v'; (A) degree of the solution decomposition (%); (B)
duration of the decomposition (hr). Seeding ratio:
1-0-05; 2-0.1; 3-0.2; 4-o-5.
Card 6/6

BOGOSLOVSKIY, V.N., SHABALINA, O.K.
Alectron microfractography of ferrates. Fiz.met.i metalloved. 10
no.1:153-156 J1 160. (KM 13:8)
1. Institut metallurgii Ura"skogo filiala AN SSSR i Urallskiy
politekhnicheakiy institut im. S.M.-Kirova.
(Ferrates) (BlectroNn microscopy)

LEREVMIKHlt V.A.; KUZUETSOV9 S.I.;- SRABALINA2 O.K.
Investigating the processes of dissolving and crystal growth
of aluminim hydroxide in alk-aline aluminate solutions. Trydy
Ural.politekh. inst. no. 98:10&-U5 160. (MIRA 14:3)
(ALluminum crystals- Growth)
(Electron iieroscopy)

S/126/61/012/005/010/028
E111/E435
AUTHORS,* Shabalinal. O.K., Chufarov, G.I.
TITLE. Mechanism and kinetics of the decomposition of
wustite, I
PERIODICAL: Fizika metallov 1 metallovedenlye, v.12, no.5, 1961,
697-702
TEXT.~, WiUstite decomposition below 570"C is important in both
scaling and iron-oxide reduction. The authors have therefore
carried out an investigation in which special attention was paid to
changes in the microstructure of the free W"Ustite surface during
deco.;rnsition and to the kinetics of the process as a whole. The
process taKes place in two stages:
(l - 4y)Fe 1-X 0-:0 (l - 4x)Fe 1-Y 0 + (x- y)Fe 301 ; x > y .... (1)
4Fe 1-Y 0--)#Fe3 04+ (I - 4y)Fe a .... '(2)
Wustite was prepared by oxidation of armco iron with a CO-CO2
atmosphere (2..'3) at 10400C cooling to 8000C and quenching. The
Card 1/4

Mechanism and kinetics of
S/126/61/012/005/010/028
EIII/E435
1.
wustite scale was chipped off to give 4 x 10 x 0.3 mm coarsely
crystalline plate specimens. These plates were -vacuum annealed at
350'C for -rarious periods., Decomposition was studied by
qualitative X-ray structural phase analysis on the powdered scales
in a high-.resolution camera. The lattice parameter of Vomstite and
its decomposition products were determined, Magnetic analysis
(Ref.10.~ Kifer, I.I. and Pantyushin, V.S., Testing of
Ferromagnetic Materials,Gosenergoizdat, M~-L., 1955) was used for
following the process quantitatively, the specific magnetization
being determined with the &id of a standard nickel specimen, An
electron microscope with a resolution of 100 A was used to study
decomposition on the free surface, The inner and outer faces of
the scale were studied by X-ray structural analysis; rapid
photography with focusing on the strongest structural lines of the
phases was used for phase analysis-, the parameter was determined
by back reflection. KaCo radiation was used in all the X-ray work.
Powder X ray patterns showed the initial specimens to be FeO.9250
but there were signs of the start of decomposition on the
outer side of the scale, The lattice parameter there was 4.299
that on the inside having the average value of 4,302 Xo A multi-
Card 2/4

s/i26/61/012/005/010/028
Nechanism and kinetics of ... Elll/E435
step relief was found electron microscopically on the outer
sitrface, that on the inside being typical of crystal cleavage.
Observations oil the decomposition at 3500C shoured that within
15 111inutes the procelss bad spread to the inner face. At the outer
face there was more metastable than original Iw'ustite. Vi th
ftirther decomposition, llv'ustite disappeared first from the outer
and then the inner face; the hypoeutectoidal formation of
magnet-ite was accompanied by the appearance of fairly dense
formations at both the inner and outer faces. The course of the
process is shoim by Fig.11 (specific saturation magnetization as
as function of' time (lop, scale) in hours): in about I to 1.5 hours
the first-stage reaction M.is completed. This enables a. to
be checked by calculation, values of x and y being obtained
f.ror- varainetevs of. the original and metastable i'lustite (Ref -3:.
k;arion M.P. Doc. metallurg., no.24, 1955, 87) and using the
tabulated as value for magnetite. Satisfactory agreement was
obtained. After 2 hours holding at 3500C, the second
eutectoidal-decotaposition stage of the process begins, iron being
detected on the outer side of the scale and, after 5 hours, on the
Card 3/ 11

Mechanism and kinetics ok oe.
Institut metallurgii UFAN (Institute of
Metallurgy UFAN)
inner side. On both sides, numerous pores about 0.1 micron in
size appeared. This porosity is more pronounced ttian that in the
first stage. Pore formation is due to coagulation of vacancies
caused by diffusion of iron ions, which in the U'rustite lattice
occurs more rapidly than tdiffusion of oxygen ions. There are
7 figures and 13 references: 7 Soviet-bloc and 6 non-Soviet-bloc.
ASSOCIATION:
SUBMITTED:
Card 4/4
March 6, 1961
B'10
S/126/6i/012/Orj5/010/028
Elli/E435
'V0
Fig.4.
20
01~
0,25 0,S I 1,S2 3 4,,~ 147 IJ 20 90
8pemp, Yacw t'.w01C-r

S/08 60/033/'012/'048/024
D209%30'5
AUTHORS: Sh.abalinai M., Derevyankin, V-* and Kuzneteov, S.I.
TITLE: Experimental investigation of aluminum -tnd hydroxides
and oxides by means of the electron mio-roscope
PERIODICAL: Zhi4rnal prikladnoy khimii, v. 33, no. 12, 1960,
2774 -- 2777
TEXT: The elec-'ron microscope is being increasingly used as a
means of assessing the properties of aluminum hydroxide& and oxi
4
des, so the authors studied var ous aspects of the preparation of
samples for this purpose. SomewhaT modified versions of the stan---
dard procedure were tested to try and surmount certain difficul-
Tiesg The Dresence of soluble alkali impurities; the existence of
readily-hyarolyzable subsTanceRs, such as the titanium compounds
noted by M.V. P.1ironov et al (Ref. 2: Izv. Vuzov, Tsvet. met, 1, 83,
1959); and the occurrence of large crystals with dimensions of 101i
and more. Benzene appears io be the best liquid for preparing sus-
Card 1/4

S/080/60,/033/'012/018/024
Experimental investigation of ... D209/D305
pens"Lons.,, Pthyl alcohol is unsuitable in view of the damage incur-
red by the collodion backing on desiccationo Carbon can also be
employed as a film-backing in addition%~o collodion. It is made by
evaporating a polystyrene - benzene solution on glass, after which
the residue is dusted with carbon. The softened polystyrene is
then dissolved in ethyl bromide, and the residual carbon-film is
again washed in benzene and dried on the carrier-g4pting. Collodion
and carbon fillm-backings react different-ly to concentra-Ued NaOH
and aluminate solutions: with NaOH the former ma-,erial is loosened
and fractured and evaporation of the solution, whereas the carbon
backing is not affected in this way. A dense, raggedi coagulated
layer obscuring all details is also formed when an aluminate solu-
tion is evaporated on the collodion film-ba'eking. Investigation of
crystals contaminated by alkali- discloses the presence of halos or
branching folds of alkaline film around them wLch distorts the
true surface picture and gives rise to the illusion of numerous
offshoots near diaspore crystals. But previous work by S.I. Kuznet-
sov et al (Ref. 4: Yietallurglya NDVSh, 4, 87, 1958; Kohaszati La-
Card 2/4

S,,,`080;'60 /'033 '012/01-3/024
Experimentai. inves-Lligation of ... D209/D3Y5) '
pok, 14, 79 29, 1959) and V.A. Derevyankin et al (Ref. 5: ITDVSh,
Eetallurg4ya, 42, 19~;q; Tr~ Ural'skogo politekh. inst. im. S.M.
K-1rova, 98, 106, 1960) has sho,.-in that diaspore, unlike bemite and
gibbsite, does not form dendrites. If these alkali-clntaining cry-
stals are applied to carbon film-backing, however, they preserve
their clear outlines since alkali will not deliouesce on it. As re-
gards the questiorl of large crystalst the very rigidity of the car-
'I'm 4
bon L.L~ Impedes the application of the technique used by the au-
thcrs for turning crystals in order to appraise their three-dimen-
slorial form,, the film fractures and turns with -the crystals. This
does not happen with collodion backings. and the authors have been
able to employ such a method in much of their research. In view of
this fact, and taking -into account the need for rapidity and sim-
plicity when preparing large numbers of samples for electron-mi-
croscope analys-4sj the standard procedure involving the use of col-
lodion film_baoking 3.s recommended-. although the expediency of
ui'Llizing the other mod'Lfi~:at'ions is also noted by the authors.
There _s -re 3 figures arim 5 references: 4 Soviet.-blo.- and 1 non-
Soviie-t-bloc, The reference to the Engli-sh.-language publication
Card 5/4

S/'080/60/033/012/018/1024
ExperInuental invest.1'.gation of ... D209/D305
reads as follovis.- D.E, Bradle Appl~ Phys.. 27, 12~ 1399, 195
Y, 6./
ASSOCIATION: Ural"skiy pol-l-tekhnicheskiy institut im. S.M. Kirova
(Ura7 Polytechnic- Institu-te im. S.M. Kirov)
SUBMITTED: Dlarsh 9, 1-960
Card 4/4

SHABALINA, O.K.; CHUFAROV., G.,L,
M
1
,3,.,hanJ.,.jL, and kinet-Ics of' the decomposition of wustite. Fiz.
niet. i irietallcwed. 12 nr,.5.,677-702 N 161, (141RA 14: 12))
1. Insbitut metallurgiJ. Urallskogo filiala AN SSSR.
Nustite)

2432
1) 0 D S7 S/080/61 034/007/006/016
D223/D305
AUTHORS: Derevyankinp V.A., Kuznetsov, S.I., and Shabalina, O.K.
TITLE: Effect of additiens of titaniUm oxide and silica on
the leaching rate of aluminum hydr~qkide
PERIODICAL3 Zhurnal prikladnoy khimiiq v. 34, no. 7, 1961t
1456 - 1461
TEXT: The main part of this article deals with tl* study of kine-
tics and the nature of dissolving pure aluminum hydroxide in the
presence of titanium and silicon oxides. To establish the nature
of dissolving thearystals of hydroxide use was made of electron
microscopy, by which means data was obtained on the formation of
protective surface films on hydroxide crystals and also on the
-C.
.Lorm of traces of chemical compounda, developed by the reaction of
Ti and Si oxide with an alkaline solution of aluminum during leach-
ing. The composition of these compounds were not studied. For
leaching experiments following aluminum hydroxides were used: 1)
Card 1/4

22432 016
S/080/61/034/007/006/
Effect of additions of ... D22VD305
Hydrargilite, obtained under control conditions; 2) Bemite, prepa-
red by the reorystallization hydroargilite under hydro-thermal
conditions at 3000C and for 8 hours; 3) Diaspor, prepared by the
method of A.VV Laubengayer and R.S. Weisz (Ref. 6: J. Am. Chem.
Soc. 6q, 247,
W _943)q i6e. by heating bemite in presence of water
at temperature 350-375 C with 2 % of diaspor seed. The results of
the experiments confirmed that titanium oxide appreciably lowers
the leaching rate of diaspor and bemite, but has no effect on the
dissolving rate of hydroargalate. It was also confirmed that tita-
nium oxide inhibition at a temperature of 150'C and higher pre-
vents the leaching of bemite and diaspor"but on reaching 230" it
no longer prevents the leaching rate of bemite while the solution
of diaspor is still inhibited. In this respect, Ti02 gel and ru-
thile differ, the latter being less active. In the presence of
waste (3-4 % of the initial weight of solid phase), the inhibiting
action of titanium oxide is much smaller and at temperatures above
1750 becomes practically zero. The oxides of silicon also deter
the leaching of aluminum hydroxide, but to a lesser extent than ti-
Card 2/4

22432
S/080/61/034/007/006/016
Effect'. of additions of D223/D305
tanium oxide. The bes-c Inhibitors are silica gel and opal. Elec-
tron microscopy has confirmed N.K. Druzhinina's suggestion on the
mechanism of the inhibitive action of titanium oxides, I.e. the
formation of protective films on aluminum hydroxide. The thinness
of film is appreciably less than 100 X and on the addition of
waste films were not formed. With an increase in leaching timet
the protective films crystallize into needle-shaped crystals which
still form protective layersp but now these are porous and alka-
lies diffuse to aluminum hydroxide and the dissolving rate is high-
er. Additions of silicon oxides form crystalline protecting films
of zodium aluminum silicates on aluminum hydroxide insulating it
from alkaline attack. The formation of aluminum silicates on the
surface of aluminum hydroxide crystals can be explained in the
following mariner: Silicon compounds contained in bauxite react
with alkaline aluminum solution to form sodium silicate which. in
turn, reacts with sodium aluminate to form a complex compound qa20-
A120~-2SiO2.2H20. The form of reaction, state the authors, is pro-
babl
Card 5/ 4

S/020/61/140/006/029/030
B10-'/BlOl
AUTHORS: Chufarov, G. I., Corresponding Member AS USSR, and
Shabalina, 0. K.
TITLE, Mechanism and kinetics of wustite decomposition
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 140, no. 6,1961, 1392-1393
TEXT: The decomposition of vustite on its free surface and the quantitative
characteristics of the decomposition kinetics were studied. Wustite
produced by oxidation of Armoo iron in CO-CO 2 atmosphere was chipped off
and temDered in vacuo at 3500C. Phase composition and parameter were
determined by x-ray structural analysis. Polystyrene carbon replicas of
the free surface of the specimens were examined electron microscopically.
The magnetic saturation moment was measured by means of magnetic analysis
in a ballistic apparatus. Wustite had a parameter of 4.295 1 in its
original state. This corresponds to the formula Fe 0.907 0. It bas been
found that decomposition begins an the outer surface of the scale and is
here more intensive, since this surface is richer in 0 2* Primar~, magnetit6
Card 1/4

S*102q/61/140/006/029/0~-O
Meohanism and kinetics of.. B103/B101
forms on both surfaces ae hin and flat formations according t~. the
reaction: (1 -4Y)Fe 1-x 0 --* (1 - 4X)Fe 1-Y 0 + (x - Y)Fe3 04; x> y (!). 'he
resulting metastable wustite contains much less oxygen in the surfar,~
layers (Fe 0.9840 ) -than in the center (Fe 0.9630 ). This is indicative of
strong decomposition on thu free surface, where crystallochemical
oonversion is much easier. Eutectoid decomposition is determined based on
the occurrence of --','ron and the constancy of the parameter of metastable
wuaiite,, It proceeds according to the reaction: 4Fe 1-Y 0 ----PFe304
+ (1-4Y)Fea (2), This decomposition is accompanied by a chRracteristic
change of the surface microstructure. Numerous fine pores (of about 0.1 ~L)
are formed. The mechanism of this process is: On leaving the wustite
lattice iron ions leave vacanciez. coagLlate to micropores which
are not overgrown by the magnetitr - ivnating from vustite. Additional
annealing of the specimens (at )UOOC) nf;er decomposition reduced the
porosity and revealed clearly the microstructure. Both the large primary
magnetite c_rystals and the eutectoid could be easily distinguished.
Microcrystals (of about 0.5 g) of the secondary magnetite became visible
Card 2/4

Mechanism and kineticF. of...
8/020/61/140/ 006/029/030
B103/B101
in the eutectoid. Presumabl,,f the iron content of the eutectoid is
insignificant (about 13 ~5 by volume). Probably, Fe forms intermediate
layers between the magnetite microcrystals. The curve as(t) wag plotted
(Fig. 4) as a result of magnetic analysis and shows that the specific
intensity of saturation magnetization of wustite specimens is a func':ion
of the annealing time at 3500C. The experimental values of as could be'
used to determine the decomposition degree in any intermediate stage and
to estimate the decomposition rate in different periods. This became
possible owing to the constancy of the quantitative interrelations
b,etween the phases formed. The rate during the first period (pre-eutectold
separation of magnetite) exceeds that of the second period (eutectoid
de^~omposition) by a factor of about seven. There are 4 figures and
6 references: 3 Soviet and 3 non-Soviet.
ASSOCIATION: Institut metallurgii Urallskogo filiala Akademii nauk SSSR
(rnstitute of Metallurgy of the Ural Branch of the Academy
of Sciences USSR),' Urallskiy politekhnicheskiy institut im.
S. M. Kirova (Ural Polytechnic Institute imeni S. M. Kiro-v)

DEREVYANKIN, V.A., kand. tel-Jri. nauk; KUZNETSOV, S.I., prof., etoktor
tekhn. nauk-; SHABALIN'.. 0.K., inzh.
i Nk
Effect of titanium and sil~-.-on oxide admJ~ t~Tes on the leaching
rate of aluminum hydroxides. Sbor. nauch.,,trud. Ural. politekh.
Inst. no.122:102-110 161. (MIRA 17:12)

S/126/62/013/005/020/031
Elll/E435
AUTHORS: -Shabalina, O.K., Chufarov, G.I.
TITLE: Mechanism and kine:ics of the decomposition of
wustite. II
PERIODICAL: Fizika metallov i metallovedeniye, 7.13, no-5, 1962,
766-768
TEXT: In an earlier paper (MM, v.12, no.5, 1961, 697) work on
wustite decomposition at 350% was reported. In this paper
wustite decomposition at 400 and 500*C was studied. In the
present work the same batch of wustite was used in the form of
platc!3 _T scale 0.3 mm thick with a.lattice parameter of ~--302
to Fe3.9250- AnTiealing was carried out in vacuo
(10-4 mm Hg). The saturation magnetization was determined an a
function of annealing time, the same specimen being used for
constructing a complete curve. X-ray patterns were taken from
the same specimen to obtain the phase analysis of the inside and
outside of the scale. A separate specimen, which had undergone
the same treatment as the other specimen, was used for the X-ray
Card 1/2

s/126/62/013/005/020/031
Mechanism and ki~!etics Elll/E435
powder method deterwir)ation of lattice parameter. Changes in
the surface'microstructure during decomposition weize followed with
the aid of an electron microscope (resolution 100 A). The work
suggested that in addition to the iron + magnetic eutectoid
the surface contains primary magnetite crystalw. The decomposition
must follow the equation
4Fe 1- X0 -. Fe304+ (1 - 4x)Fe, (x = 0.075)
The process at 5000C is much slower than at 350
OC and is
different in ocher ways. This is explicable on the basis of the
two-stage mechanism. There are 2 figures.
ASSOCIATION: Urallskiy politekhnicheskiy institut im. S.M.Kirova
Institut meta-llurgii Urallskogo filiala AN SSSR
(Ural Polytechiiical Institute imeni S.M.Kirov.
Metallurgy Institute of the Ural Branch AS USSR)
SUBMITTED' September 23, 1961
r d 2 1/21

S/020/62/142/002/028/029
B101/B144
AUTHORS: S a i2i-.,L,_0
'~h__bj K., and Chufarov, G. I., Corresponding Member
AS USSR
TITLE: The maximum rate of decomnosition of wustite
411-412
PERIODICAL: Akademiya nauk SSSR. Doklady, v. 142, no. 2, 1962
TEXT: The rate o' tnermal decornosition of wustite at 400 and 500 0C was
investigated. The decomposition products were subjected to X-ray
structurELl and electron-microscopir.; examinations, and the kinetics of the
process was clarified by measuring the variation in specific magnetization
saturation us during heating. Decomposition follows the reaction
4Fel-x 0 ->Fe504 + (I - 4x)Fe; x = 0.093. Details of the process; The
preeutectoid sep~tration of Fe 3()4and eutectoid decomposition are caused
by diffusion of iron ions out of lattiee points; coagulation of vacancies
to pores which are not immediately filled with Fe 304" This porosity
facilitates the tran9formation of neighboring sections. Recrystallization,
however, is also accelaratea with increasing temperature. The pores are
Card 1/2

S/020/62/142/002/028/029
The maximum rate -,,f t ion.. B1O?,1B!44
closed, and the total rate of the process decreases, There are " figure
and 3 references: 1 S,,-viet dni 2 rion-SovieT.,
ASSOCIATION: ffral'.ikiy pij'l!fekhniche3kiy institut im. S. M. Kirova
(Ural Polytpnhiiic Lpstitute imeni S, M. Kirov); Institut
metallur,rii Ural;skogo filiala Akademii nauk SSSR (Institute
of M-,allarg, of the Ural 'Branch of the Academy of Sciences
SUBMITTED: 3ept=mber 22, !961
Card 2/2

8/020/63/146/604/024/025
W92/3101
AUTHORS: Shabalinap 0. K.1 Chuf aroy G. ~-1. 66r"iespondivg. *dxber'.*
TITLEs Decomposition kinetics of- wastite-..
PERIODICAL: Akademiya n auk SSSR. boklady, v. I no."..
46- -4.190v 90-18~Z, -
TEXTs The decomposition kinetics of wdstite was. a tudied. by ~, m!eaa urJ4 the,
ncti' _441: anplei
specific saturation magnetization d (t) as afu on*of.time.
with a lattice constant of 4,032 R'be'tween 2000C and. 50 .00C* fti.meati urs-4
.curves show that two succeseive -reactions,. take place beldw400001
pre-eutectic separation of ma&Otitei and - (2) a.- eut'dotic dedostpon ition or.
metastable.wlAstite;while there is,,only'one A00001': (3):. otic do--
above
-the con-
composition of the original wUstite. The.iiolak f ri6tioi-,Qc(t) -of
verted material was calculated-. from the, e:~periiientad- diLta,;,_Th6,b9ha*ior -of,-,
a(t) is determined by the number N of pores - For d 1/2-, -
the measured points satisfy the equation C!/ -a)- 6411 (Ict.1- ",era - k.
and b are constantsi th6 equation is valid on. the aseuiiptio.n! that~ W
Ca'rd 112

8/02Q/63/148/W4/04/02~
Decomposition kinetics of Ytistite Bipjmll
proportional to a. For ix.9ri/2, the measured- P'Ointa'foilov tfie,ieiition
.1/2 /,3/2
a/(1 - a) - exp(b 2ht' e n -.k' D an& b 4re Cia nit ai nts-.
2 Wher
.2
V2
This equition is ,ralid on the assumption that N. i.s: pTopbrt iona 1'.t oa
where D denotes th#.~ diffusion coefficient of
U' -,W -1ui
(1) and (2), k increases with the temperAture P to a,' as Ur n a 0~a.
'44000C and decreases in reaction.(5). In 611 three, tia~tioiii, .-u is'.-practi-;
cally equal and independent of temperaturej b inc,r'ses6i. bil".4000C., and
decreases above this temperature. There'.are -fi*ur,ao
9
A' :;: OC I AT I U11 sInstitut metallUrgii ljralfskogq~,- ~ia
(Listitute of Metallurgy'of ~he Ural..Branch of ilit A~.ade*':-.
(if 14ciences USSR)
SMAITTE'Di October 1, 1962

L 19397-63 F.JT Wl&ip (q)/&iT (m)/RiVP (B)/BDS AFFTG
JD
ACCESSION NR: AT3001931 S/29.12/62/000/000/03?1/03 6
AUTHORS:~ Kuznetsov, S.1.6, Derevyankin, V. A.; Shabalina,_ 0. K.
TITLE: Some observations of the processes of dis 9 olution and g rovAh of c rys tals .
~of Alumiiium hydroxi in alkaline alumina solutions
SOURCE: Kris tallizatsiya i fazoYyye perekhody. Minsk, Izd-vo AN BSSR,
,1962, 321-326
-.TOPIC TAGS., crystal, crystallization, crystallography, soludon, dissolution,
-growth, Alt hydroxide, precipitation, leaching, dendrite, dendritic, lamellar,
acicular, bemite, diaspore, hydrargillite, Ti
ABSTRACT: This paper is a progress report on the long-term project at the
Urallskiy polite khaiche ski' institut (Ural Polytechnical Institute) on the character
Y
of the dissolution and growth of crystals of alumina in alkaline Al solution's vrith
ayer method. The, laboratory work was primarily done
especial reference to the B
at the Institute; indusIrial experpnents were performed by the Aluminum industry.',
Investigation methods employed:Mlectron microscope, X-ray diffraction, crystal-,
optical and.chemical methods of'i-naly-sis. Ea-iffir stages of the authors' work we:ie~__
published in cite6 references. The present paper is a concentrat6d,- informative;
Card I ~3

L 19397-063
ACCESSION NR: AT3001931
on the mos tin~te resting data on the dis,solution and growth of Al-hydroxide
crystals. (1) Procqsves of dissolution (leaching). Hydrargillite crystals in tinsat-1
urate alumina solutions, when heated to nearjb. p., breakup into fragments. Upon:
this initial commint~tion, they dissolve prorr~ptly. Diaspore crystals usually dis-.-
,solve at the faces$ )V#h the formation of fissures and perforations. At times, 'the
r
holes in bernite o. dja~spore exhibit a sharply defined hexagonal shape. When Al
hydroxides with addMons of Si oxides are leached, growths of fairly equiaxial
crystalline formations of Na hydroalurno silicate (sorxie'bf'l.6_-~_rnicron diam) form on
the dissolving particles. Upon full dissolution of the hydroxide crystals or- which
these spherical part~Oe% had formed the latt~'r exhibit apertures. Experiments
show the presence of -films of Ti compounds on the dissolving boirmite and diaspore
crystals. During leaching these films cryst.allize into acicular crystals visible
under an optical microscope. Photographs of these formations are shown in the
article. (Z) Crystallization processes (separation of Al solutions). Without stirring,
alumina solutions foym practically only antiskeletal forms of crystalline growth, so
that crystals of hyd;argillite grow primarily.in the form of lamellar dendrites.
-Lamellar growths form an the plane of the pinacoid. There are virtually no pris-
matic growths. Thoroughly stirred alumina solutions, ex~ecially withprimer, give
rise to a greater probability of the deforma~i6n of growths and, hence, various de-
fects. When, in a lam'jella.r growth, spiral dislocation occurs, it may grow into a
Card Z13

iI,.19j97-63
'ACCESSION NR: AT3001931
:prism. Growing dendrites undergo deformations which increase the numblOrof
~:directions of growth. The dendrites lose their SC structure and assume a fairly
;equiaxial form. The decomposition products of alumina soluotions. a-re--mrifally well
crystallized; hence theyjepd_ themselves well, to-dleiit-ron-micros cope and X-ray;-
:diffraction anarysi's.-tlie various crystalline products and the sequence of their
-precipitation by various agents are described. The best precipitation of alumiria
under the action of nonhydrargillitic P*rimers for industrial purposes is
obtained with the use of a bemite primer obtained by 2500C roasting of hydrargyl-
lite. Optimal primer ratio: 0.2-0.3. A brief survey is also given on the process, of.
::rccrystallization of hydrargillite into bemite',and diaspore in water and alumina-
~solutions, including ~he layerwise s tructure,a rising from the.-p~-riodic "wave-lik6l'
~character of the crystallization. Orig. art. -has 5 figq.
ASSOCIATION: none
ACQF I ENCL: 00,
64pr63
SUBMITTED: 00
0"
SUB CODE: CH, PH,* MA#f1-EI;::. !NO REF SOV: 006, -` OTHER-.' 000.
Card 3/3

SHABALINA9 O.K., CHUFAROV, G.I.
I
Meehan--lsm and kinetics of the decomposition of WU"Stite.
Fiz. twt. i metalloved. 15 no.5t690-696 My 163. (MM 16a8)
1. Urallskiy politekhnicheskiy institut im. S.M. Kirova i
Institut meta2-lurgii Urallskogo filiala AN SSSR.
(Wustite)

LAKERMY M.M.; LAVROV, L.G.; SHABALINA, R.I.
Condensing zinc into a liquid metal in a lead-sprayed con-
densator during the electrothermal treatment of intermediate
products from complex metal ores. Sbor. nauch. trud. Gin-
tSV8tMet4L no.19:387-396 162. (MIRA 16:7)
(Nonferrous metals-Electrcmetallurgy)
(condensation products(Cheinistry))

..rj ~,~rietics c)," an fr-ot ---a,:-~ alll~-- Li 2icpuild mattes.
f3;et.met. '8 no.3:3~--15 Ir'15. (MILRA 18!(,)

NOSKOV, S.K., kand.tekhn.nauk; ODINOKOV, S.D., kand.tekhn.nauk; SIROTYLINA,
O.V., starshiy tekhnik; KRETOVA, L.V., starshiy tekhnik. Priaimala
uchastiya SHABALINAr-Y.J., mladshiy nauchnyy sotrudnik. SKVORTSOVI,
I.F., red.izd-va; TEMKINA, Ye.L., tekhn.red.
[Album of technological schemes and drawings of the equipment,
instruments. and devices to be used in covering roofs with rolled
materials] Allbom. takhnologichaskikh skhem i chertezhei oborado-
vaniia, instrumentov i prisposoblenii dlia ustroistva krovell iz
rulonnykh materialov. Moskva, Gos.izd-vo lit-ry po stroit., arkhit.
i stroit.materialam, 196o. 48 p. (MIRA 13:6)
1. Akademiya stroitel'stva i arkhitektury SSSR. Institut organi-
zataii, makhanizataii i tekhnichaskoy pomoshchi stroitellstvu.
(Roof ing-Equipment and supplies)

UMKOVO V.F.9 kand.tekhn.naulc [deceased]; BOGATYREV, I.I., kand.tekhn.
nauk; DODIN, V.Z., inzh.; GORDIYRiKOp N.A.# inzb.; MUKHAt V,Mot inzbo;
BEREZOVSILU, B.I... inzh.; KOVALEVSKIY9 r.I.p inzh.; ROGOVSKUq L,V.,
inzh.;-_SIIABALINA, V.I.; PETROVA, V.V., red.izd-va; ABRAMOVA, V.H.,
tekhn.red-~~
(Temporary instructions for carx-,'-,ng out building and assembly
operations in the Par North and in permafrost regions) Vrememiye
ukazaniia po, proizvodetva stroitellno-montazhnykh rabot, v usloviiakh
Krainego Severa i raionov rasprost-rorn niia nnogoletnei merz1oty.
VU 2-60, Maskvav Gos.izd-vo lit-ry po stroit.9 arkhit. i stroit.
materia:1sms ~ 1960. 59 p. (HIU ~ 24:6)
1. Akademiya stroitellstva i arkhitektury SSSR.-,Listitut organi-
zataiij, mekbanizataii i tekhnicheakoy- pomosheld stroi-bellsbv
(Ruasiag Northern-43uilding-Cold weather conditions)

SHABALINA, V.I., inzh.
Mechanization of gluing of roll roofing materials. Makh. stroi.
20 no.10:6-8 0 163. (MA 16:10)

SIIABALn[A, v.i.; EmBrTSKIY, A.D.; GORYAYEI, M.I.
Isomerization of d--sabinene to 1- ck --thujene. Zhur. ob. khim.
34 no.110855 N 164 (MIRA 18:1)
1. Institut khimicheakikh nauk All Kazakhskoy SSR.

GORYAYEV, M.I., akademilr; S11ABALTNA, V.I.; D.E1,11BITSKIY, A.D.
Acid isomeri2mtion of saWmne.Dok'!. Ali SSSF . 58 no.1:155-156
S~4) 164 0-11RA 17:8)
1. fnqtl.tut khimicheskikh nauk All Yaz,-'S* . 2. AN KazSSR
(for Gorynyov).

SHEVCHWO) F.F*, otarehiy nauohnyy ootrudniki,�H~~ ~IWA,~ZS... starshiy
nauclutyy sotrudnik
Noctuid moths as corn pests in the Altai. Zashch.rast.ot vred.i
bol. 7 no.6:29-30 Je r62. (MIRA 15:12)
1. Altayskiy nauchno-issledovatellskiy institut sel'skogo khozyayst7a.
(Altai Territory6--Corn (Maize)-Diseases and pests)
(Altai Territory-Owlet moths)

DANCHEVSKIY, V.I.; SAVEL'YEV, B.I., BORISOV, V.V., red.;
SHABALINA, Z.S., red.-leksikograf
(Ital-ian-RusBian military dictionary] Italliansko-russkii
vaennyi slovar'. Moskva, Voenizdat, 1965. 404 p.
(MIRA 18:6)

I