SCIENTIFIC ABSTRACT SHILOVA, A.I. - SHILOVA, S.A.
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CIA-RDP86-00513R001549510002-4
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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fAHILOVA, A.I.
Some gregarious tondipedid species (Dlptera, fendlpodld&*) of
the Amu Darya Basin. Znt.obot. 34:313-322 155. (NLRA 9:5)
1. Xafedra entomologii Moskawskogo gotudsretvannogo universitsta.
(Amu Darya Basin-Diptera)
--- ----- - -
vA-
Eliolow - Zoology
Card 1/1 Iub. 22 13V47
77
aw 34ilovis
I rc,- dtnL, or, CIA -Ir ce in connection ldth- thil
I'MA briss
truc turv of their T.-outh apparatus
Atriodica I ;x =zR 100/6, 1191-1193, Felp '21,1
Abstraot I TV- rrobIsms of feedini-, CrIc'itopuc Zilvectric F. larva6, taken
fr M tile "re;ads of thc- Volt-p-River ustitray, -because -of their peculiar--
mouth ztructxt;, 3re discunsed. S:.x USM refcrcnces (1926-19.510.
Ir.3titution Acadciq~, of Scienf,(.~s Vje rT.A Morozov Scientific Research
BioloCical Station "Dorok"..
Prec~;,ntQcl by Lcad=Ician E. N. Pavlovskiy, 11.7oveiabor 10, 1954
SHILOVA. A.I.
liltration method of feeding in midges (Diptera, Tandipedidae).
Doki.AN SSSR 105 no-3:596-598 N '55. ()(T,RA 9:3)
1. Nauchno-iseledovatel'skaya biologichaskaya stantsiya "Borok"
Akademii nauk SSSR. Predstavleno akademikom Ye.M. Favlovskim.
(Diptera) (Larvae)
SHILOVA, A.I.
Palearctic species of the subgenus Cazptochironomw Kieff.of the
genus Tandipas Mg (Diptera, Tondi-pedidael (with su=ary la Ger-
man] llnt.obox.36 no.1:224-230 a57. (MIak 10:4)
I-Institut biologiivodokhraniliahch Akademli nauk SSSR)Borok.
Ohironomidae)
SHILOVA, A.I.
Materials on the biologT of tendipedid larvae (Tendipes Mg.) in
Rybinsk Reservoir. Trudy Biol. sta. 'Borok' n0-3.-250-258 '58-
(MIRA nig)
(Rybinsk Reservoir-Chironomidas)
SHILOVA, A.I.
S73tomatics of the gennp Tordioss )L,-. (Dipt,-ra, Tery-Upedidas)
[with summgry In German]. Ent. ob(a. 37 n*o. 2,.434-L49 153.
(MIRA 11:7)
1. fnatitut biologii vodolochrantli-iL.: Akademii wific SSSR, Borok,
Taroslavokoy obl.
Ohlron-~-nidae)
SRIWYA, A. I.
Cryptochironomm ussourionsis Gootgh. ( Digridens Tochern.) and
some data on Ito biology. Trudy Inst.biol.,Yodokhran. no5.21
ioq~-i16 159. OGU 13:5)
(Rybinsk Reservoir-Ctironomidae)
SMWVAV A.l.
Sea,sona2 variati=s in the popu:Lations of Tandipes plumosus L. aqd
T. ter,tans F. In Rybins): Reservoir. Trudy lict. biol. vodokhran
no.3:129-~W 160. (KIRA 14:3)
(Rybinsk Reservoir--Chironomidae)
ShILOVAp A.I.
Hatamorphoolis of Cryptochlronomur burgaudimae Tahern. Trudy lzwt.
biol. vodochran.-no.3:143-149 161. * ' (MIRA 140)
(Chrinmidae) (Imeets-Deve3opment)
SHILOVA, A.I.
A new genus and species of midges (Diptera, Tendipedidae). Blul.
Inst.blol.vodokhran. no.11:19-23 161. (MM4 15:8)
1. Institut biolgoii vodokhranilishch AN SSSR.
(RYBINSK RESERVOIR-CHIP.0110MIDAE)
SHILOVA., A.I.
Dynamics of the 4undance and the biomass of Tendipes plumosus L.
in Rybinsk and Gorkiy Reservoirs. Vop. ekol. 5:246 162.
(MITLA 16:6)
1. Institut biologil vodokhranilishch AN SSSR, Borok.
(Rybinsk Reservoir--Chironomidae)
(Gorkiy Reservoir--Chironomidae)
SHILOVA, A.I.
Metamorphosis of Lipiniella arericola Shilova (Diptera,
Tendipedidae). Trudy Inst. biol. vodokhran. no.5371-80163.(14IRA 16:8)
(RYBI21SK iMFEVOIR-CHIRONOIODAL)
_S141 U.1,11A I A ~ I
17*~ +e,a
T
laxonomi,, Allcchiroro,~..US
Irondiredidael. ,,YLL. obcz. 43 no.3;"3'--7"ij 1'.
"ECHIFOR-WITKO., G.!.',.; TA-PRINA, G,M.; SHILOVA., A.K.; SKIC-7, A.Te.
M--ihanlsm of nitrogen f-4xaTica in the rea-iting aystem
-1 - L;4 ~ +
(G2H5) TMZ -- '-2!!5M,9Br- Drki. AN S~!SP. ' r.,~. 5!'.062-.' '26 1
0 165. k'V;RA 16010)
a. iristitut khLmlchaekc~y fizild AN SSSR. SubmItted March 2,'-,, 1965.
S/190/62/004/011/007/014
B106/B101
AUTHOR3: Shilov, A. Ye., Shilova, A. K., Babkov, B. N.
TITLE: Reaction of a-olefins %ith soluble complex Ziegler catalysts
and the mechanism of polymerization initiation
PERIODICAL: Vysoko-,Lolekulyarnyye soyedineniya, v. 4, no. 11, 1962~,,.'.
15ea - 1695
TEXT: In a previous paper %/Ref. 3: A. K. Zefirova, A. Ye. Shilov, Dokl. J.
AN SSSR, 136, 599, 1961) the hypothesis was put forward that the J
polymerization of ethylene is initiated by an ionic Laechanism in the
presence of a Ziegler catalyst obtained bybringing dicyclopentac'enyl
titanium into reaction with aluminum alkyls. This hypothesis was studied
experimentally on the basis of the catalytic system (C H ) TiCl Al(CH 'Cl.
5 5 2 2- 312
.Since the polymerization of ethylene coincides with the reduction of
4+ 3+
Ti to Ti , which is accompanied by a change in color, the process was
studied by spectrophotometry. Titanium is reduced by reaction of
(C5If5)2 TiCl2with Al(C11 3)2 Cl only in the presence of a-olefins (studied in
Card 1/3
S/190/62/004/011/007/014
Reaction of a-olefins ... B106/B101
a-heptene-1 as an example). The following course of reaction reaulted
from kinetic investigations:
(C H ) TiCl + Al(r,11,) 01 -- "(C If ) Ti(CII )Cl-Al(CII )CI (complex A);
5 5 2 2 ~' 2 5 5 2 3 3 2
2'C H ) Ti(CH )CI-Al(cif )Cl + Cif -CHR --,2(C If ) TiCl-Al(CH 3)Cl + CH 4
5 5 2 3 5 2 2 5 5 2 2
+ CH 2= C(CH 3)R. With a large Al(CH 3)2 C1 excess (AI:Ti> 20.1) further
conversions of complex A take place; the resulting compounds do not react
with a-olefins. The polymerization rate of ethylene in the
(C 5 H5)2 TiCl 2- Al(Cli3 )2 Cl system as well as the rate of titanium reduction
in this system in the presence of an a-olefin are directly proportional
to the increase in electrical conductivity due to the formation of the
complex A. These results confirm that the Ti reduction in the presence of
an a-olefin, as well as the initiation of po~ymerizations in the system
studied, have an ionic mechanism. This does not agree with the results
obtained by J. C. '11. Chien (J. Amer. Chem. Soc., 81, 86, 1959). The
mechanium of Ti reduction is analogou3 to that indicated in Ref. 3 for the
reduction of (C 5i[, ~-'TiCl2 by Al(C 2 H5 )2 Cl. The sole difference is that in
the case of Al(c 21,5 )2 Cl the intramolecular disorooortioning of the two
Card 2/3
5/190/62/00,',/'011/007/014
Reaction of a-olellins ... Blo6/B101
ethyl groups can start without preliminary incorporation of the olefin.
A roui!h estimate of the lior. concentration in the reaction studied (using
benzene as a solvent) hith the aid of the Waldep equation yielded
mole/l for melium concentrations of Complex A of -5-10- 3 mole/l.
Hence, the concentration of ions i:9 very low and their reactivity very
high. There are 5 fi",reu. The most important English-language references
are: W. P. Long, D. S. BreDlow, J. Amer. Chem. Soc., 82, 1953, ig6o; A. N.
Maki, E. IN. Randall, J. Amer. Chem. Soc., 62, 4109, 1960; G. Wilkinson,
J. Y. Birmingham, J. Amer. Chem. Soc., 76, 4281, 1954.
ASSOC11MON; Institut khimicheskoy fiziki AN'SSSR (Institute of Chemical
Physics AS 115SR)
SUBMITTED: June 30, 1961
Card 5/3
S/020/63/148/001/026/032
B101/B186
AUTHORS: Stepo vik, L. P., Sbi1,ovaj-Av-*rT--Ghilov, A. Ye.
TITLE: Kinetics and mec~ iism of the initiation of ethylene
polymerization on a soluble Ziegler-type complex catalyst
PERIODICAL: Akademiya nauk SSSR. Doklady, V. -148, no. 1, 1963, 122-125
TEXT. In a previouspaper (Vysokomolek. sayed., 4, no-11 (1962)) the
following reaction pattern was found for the polymerization of olefing
on a (n-C 5 H5)2 Ti C12 + Al(CH 3)2 C1 catalyst:
(C5if 5)2 Ti C12 + Al(CH 3)2C'_'~' (C5 H5)2 Ti(CH3 )C'1-AlCH3Cl2(complex A);
+ +_
A (C5H 5)2 TiCH3 + WCH 3 )CI3 ; (C5H 5)2 TJCH3+ RCH- CH 2
(C H T'CH2CH(R)CH+ ; (C5 H5)2T'CH2 CH(R)CH+ + AlCH Cl-
5 5)2 3 3 3 3
(C5If 5)2 TiCH2CH(R)CH 3Cl-Al(CH3)Cl2 (complex B);
(C5If5 )2 TiCH2CH(R)CH3Cl-Al(CH 3)Cl2 --+-(d5H 5)2 TiCl-AlCH 3C12 (complex C).
Card 1/3
S/020/63/148/001/026/032
Kinetics and mechanism of the B101/B186
The reduced titanium in complex C is no longer-active. In the present
paper a direct proof of this orkler of reaction for ethylene is given,
based on determining spectroscopicall~ the variations in concentration of
the complexes A, R (in the present, case R - 11) and C from the variations
in optical density of the solution at 660 and 61o m~t for A and B, and a7t
720 and 520 mp for C. The determination of the concentration of C on the
basis of the e.p.r. spectrum agreed well with optical data. It was found
that the sum A+B+C remained constant and that the reaction occurred in the
order A B i C. This is the first direct proof that the olefin
molecule is added to the Ti-C bond. The kinetic equation for complex B
is: (dILBI/dt)o S k['A_J 112 The following data were found by experi-
j EC2:4 j
ments: k 22 toC-103, 11/2. mole- 1/2. see-1 equaled 4.9�0.2 for C 2H V 1.7�0.1.
for C 3H61 0.5110-04 for C 7H14" and 0.037 for C 2H3Cl. The specific effect
which the catalyst investigated exerts on the ethylene polymerization is
explained by the fact that in this case the linear C 3H7 radical is formed
from C 11 whereas the branched group -CH CH(CH )R is formed from the
2 40 2- 3
Card 2/3
3/020J63/148/001/026/032
Kinetics and mechanism cf the ... B101/B186
a-olefins of the formula RCH-CH2 ; this group is easily converteJ to the
isoolefin C92-c(cn )R, with the titanium being reduced and termination
31
occurring. This generally holds for Ziegler catalysts by which ethylene,
but no other a-olefins, can be polymerized. An*active B complex is formed
only with C2H4. The'ratio k2/kl between the constant k2 for,chain
propagation and k, for initiation was found to be 18.9, in good'agreement
with the value, 19, found from the rallio between maximum rate of poly-
merization at constant and the -.*nitial rate of complex formation.
z . PC2H4
Tbese results do not confirm the assumptions made by J.S.W. Chien (J.Am.
Chem.Soc., 81, 86 (1959)) and C.L.Karapinka, W.L.Carrick (J.Polym.Sai.,
55, 145 (1961)). There are 3 figures and 1 table
ASSOCIATION: Institut khimicheskoy fizik~ Akadem;i nauk SSSR 'Institute
of Chemical Physics of the Academy of Sciences USSR)
PRESENTEDi July 23, 1962, by N.K. Semenov, Academician
SUBMITTED: July 23, 1962
Card 3/3
TSYNKAIDVSKIY, I.B., dotsent; SHILOVA, D.A., vrach
Capillary resistance of the mucosa of the cervix uteri and sk-lb
in Bothn's disease. -Akush.i gin. nosWO-62 161*
(MIRA 14112)
1. Iz Kiniki infektsionnykh bolemey (zav. - prof, A.G.
Podvarko) i kafedry patologicheakoy fiziologii (zav. - prof.
I,A. C7vin) Kubanskogo meditainakogo instituta.
(HEPATITIS, IWECTIOUS) (UTERUS.-MOD SUPPLY)
(SKIN-BLOOD SUPPLY) (CAPILLARIES)
SHILOVAt G. B., CAND MED SCIt OFUNCTIONAL VALUE OF
THE MASTICATORY APPARATUS RESTORED BY PROSTHESES OF
VARIOUS DESIGNS# to KHAR'KOVj 1960o (KHARIKOV MEO INST)o
(KL, 3-61, 237).
487
SHILOVA, G.B.
Ff,'nctiveness of mastication in subjects using dental roothemis.
TrA,Iy LSGMI 63-109-120 160. f~UA 1521)
b (DEUTAL PiiOSTHrSIS) (MASTICATION)
SHILOVA, G.B. (Miartkov)
CharacteriBtics of the adaptation to dental beridges and arched
prostheoes. Ymbl.stom. 6:291-296 162. (MIRA 160)
(DENTAL PROSTHESIS) 1,A
1. e
I-WIFUTDA, 7.1.; .1)01.0'IIYFVA, G.I.; EGLIT, L.V.; HDIVIAN, I.V.; S4ILCVA, G.I.;
ZA"IPIA, F.Ya.; CHAMM, L.,.; FILICILEVA, T.B.
Highly d'3persed pigmnts for stock dyeing of v1scose fiboers. Khim.
voick. n:)."1-6-0-62 165. (MIRA 18:7)
-1. 'T,.i-,,.4oyuznyy nnuchno-Issledovatellskiy iskus--tvernogo volOkna (for
f-'.ayL,Qrodrt, Solov'yeva, Eglit). 2. qauchno-iss2 riovatell'skiy institut
rr.-,mlcn-3r,kikh'poluprodultov i krasiteley (for 1-~diman, Shilova).
3. Klimmiy kombinat iskliss-tvannogo i sinteti, heskogo volckna (for Urina,
Chanova, Filicheva).
69970
3/039/60/051/002/005/005
11,4900 C111/C333
AUTHORs Shilova, G.I. (Gorlkiy)
TITLEs Existence of an absolute minimum of the multiple integrals
of the calculus of variations in non-parameter form
PERIODICALt Matematicheakiy abornik, v. 51, no. 2, 1960, 253-272
TEXTs Let be a closed bounded domain of the Euclidean
R n(X 1~x2g...'X n) , n.*2, with the boundary GO, where it is assumed that
a S70 exists such that every sphere, the radius of which is smaller
than d, contains no component of 01 In the interior (i.e. the
boundary is uniformly regular).
f(X), X=(x 19 X2'.' .,,n),- 5is calied absolutely continuous in the sense
of Tonelli, if it is continuous in U relative to x 19-1Z n, absolutely
continuous for n-1, and for n >1 inductively described as followat
1) f(x) is absolutely continuous in the sense of Tonelli relative to
1 2 i-I i+1 n i
X 'X "'.'M X X for almost all values z (ift1,29..,n)*
i af
2) 1 p'1 d 11 /2, with
uniformly regular boundary. Let Le(z) be defined and continuous on
jyj< M. Let the functions F(Xf,P), F pi(xJ,P) (i-1,2,..,n) be defined
for xC-5, Ifl-4 9 and arb1trary p, be continuous relative to all
arguments, and satisfy the conditionst
1) There exist T-.,-O, C>O such that for every xE~E it follows%
(P,)2] '2 If,< M~ n
F(x,f,p)-, Z (p i)2;~'- C2
from
n
2) E(x,p.,T)= F(x,f,p)-F(xj,'p)- (p P )p i(x,f,p):~/,O for all xFj,
p
jfj-,~'V and arbitrary p and
3).There exists a continuous convex function if(p) and constants 11,A2
Card 3/4
89970
3/039/60/051/002/005/005
Existence of an absolute minimum... C111/C333
such that A, y(p),