SCIENTIFIC ABSTRACT SHILOVSKAYA, O. - SHILTSEV, A.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549510004-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SHIIAYVSKAXA-,-D= I uchenitsa o klassa.
On a tortoise and a guinea pig. Nauka i zhiznl 28 no.11:109
N 161. (MIRA 14: 12
1. 3-12-ya shkola FrunzensIkogo rayona g. Moskvye
(Animal's. Habits and behavior of)

. . , - , . rlz~. .
I. ~-: -,i .,- .7., L .~', ("'I I ~ , ll~. .
:nrluetr-.al :io2m-',iondu-tor m~tillter for suipplying
rcwr.r tc clectrl,~ transportation systems. Elektrcteki'..r.!-k~a
-15 n o . 3 '. 3 0 - 11, ~, iel~- (MIRA !?:5,

VAI

SHILOVSKIT, I.A., Inzhener.
Problem of beat engineering applied to roofs and iron roof
maintenance. Gor.khoz.Hosk. 24 no.2:38-39 7 150.(MM 7:11)
(Roofs) (Roofing, Iron and steel)

SHILOYSLIT, I.A.. inshener.
Heat insulation and cooling attics an countermeasu2ve to condensation
and ice layers on roofs. Gor.k:hoz.Xosk.28 no.2t27-30 7 154. Off-RA 7:5)
(Insulation (Heat)) (Attics-Tantilation)

SHNIP, O.A.; DANCHEV, V.I.; SHILOVSKIY, P.P.
Cretaceous structural features of southeastern Fergana and
their paleogeographic importance. Trudy MIPMHiOP no.25:328-341
159. (MIRA 15:5)
(Fergana-Petrology)

r 7 1
-",A. JA

VICHEWIN,A.Te.; GUIXV,ya.p.; VACHUK,L.Ta.; MROBIUSKIT,V.A.; KRYLOT9
S.K.; SHLDUR,L.A.; SHILOVSKIT,V.A.; CMMNYSHNV,V.1., redaktor;
VIRINA,G.P., tekhniMfftfflr~~r
[Railroad fundamentals) Oanovy zheleznodorozhnogo dala. Moskva,
Gos.transp.zhel-dor. Izd-yo, 1955. 400 p. (MM 9:3)
(Railroads)

DOBROSILISKIY, Konstantin Mikhaylovich. kandidat, takhnichookikh nauk;
NIKOIAYNY, Ivan Ivanovich, doktor takhuichaskikh nauk; CHXRNYSHEY.
Mikhail Andreyevich, kandidat takhatchookikh nauk;
Ukt2" I ovi, kandidat tekhnichaskikh nauk; NIKOLAYST, I.I.,
orofes
rofessor., r9i!ktor62; YSAKHZON. 3.B., kandidat takhnicheakikh nauk,
p
recLqktor; VERINA. G.P., tekhnicheekly rodaktor
[A general railroad course] Obahchil kurs zhelsznykh dorog. Pod
obahchei red. I.I.Nikolseva. Moskva, Goo. transposhal-dor. izd-yo,
1956. 382 P. (MIRA 10:2)
1. Chlen-korraspadent Akademii nauk SSSA (for Nikolaeyv, I.I., rodaktor)
(Railroads--Management)

PONORARINKO. Panteleymon Londratlyevich; RAKOV, Vitally Aleksandroviobi
SHILOVSKIT, V.A. , redaktor; T7JDZCN, D.M., tekhnicheekiy redaktor
(Electric locomotives] Xlektrovoz. Izd. 5-oe, parer. Moskva, Gos.
transp.zhel-dor. izd-vo. 1956. 627 P. (MLRA 9:11)
(Electric locomotives)

SHIIOVSKIT, V.A.-
To be published in 1958. Xlek. i tePl- tiaga, 2 no.1:4748 Ja '58.
1.Zamestitell nachallnika Tramssholdorisdata.
(Bibliography--Railroads)

SHILOVSKI-TI-Viktor Anatoll~e~,ich, kand.tekhn.nauk; BOVE. Te.G,kand.
--- r-V -
---E60in.nauk, re
(Modern electric locomotives] Sovremennye elektrovosy. Moskva,
1959. 109 P. (MIRA 12:9)
(Electric locomotives)

BLANTER, Solomon Grigorlyevich; SHILOVSKIY, V.A., red.; RACHEYS&AYA, H.I.,
rod.izd-va; WMIKHT,
[Ourrent converters for traction substations] Proobrazovnteli
taka tiagovykh -podstantaii. Moskva, Izd-vo X-va ko=Mkhoz
RSr.Mq 1959. 238 P. 13--4)
(Blectria current converters)

SHIWVSM, V.A.
Literature on electric and diesel locomotives to be published
during 1959. Blek. i tepl-tiaga 3 no.2:47-48 F '59-
(MIRA 12:4)
1. Zameatitell nachalinika Tranesholdorisdata*
(Bibliography-Locomotives)

Stractural steel processing for -,-ielding and riveting
1949. 85 P. (50-15902)
1
Yos'eva, Gos. izd-vo stroit. Ut-rf,
1 TS".50- S5

SH-1-LOWWL.A.-P.; RTABOV, A.F., inzhener, nauchnyy redaktor-, BEGAK, '3.A.,
redAktor; PFRSON. M.N., tekhnicheekly redaktor.
[Technology of factory-made steel structures] Takhnologita to-
Yodakogo lzgotoyleniia stallnykh konstruktail. Xoskva, Goa. Izd-
vo lit-ry po stroit. i arkhitakture, 1954. 246 p. (MI.RA 8:1)
(Building, Iron and steel) (Building materials industry)

amn moknrafemmuwfm mwQw4Iw=Iw-:~
-S5
1955
Iz.-gotovIeniye svarny?h i klepanykh stalinykh konstru~tsiy (The production
of welded and r'veted steel structures) Izd. 2. dop. i perer. Moskva, Gos.
Izd-vo Literattinj po Stroitellstvu i Arkhitekture, 1555-
19h p. i3lus., diag-rs., tables.

AKULOV, I.A.t kand. tekhn.nauk,dets.; ALEKSEYEV, Te.K., inzh.; GUiMI,
N.D., inzh.[deceased]; MaTRIYEV, I.S., kand.tekhn.nauk.,dots.;
YEVSEYEV, R.Ye., inzh.; ZILIBERBERG, A.L., inzh.; LIVSHITS, L.S.,
kand.tekhn.nauk; MEMINUK, V.I., inzh.; RAZUM.OVA, E.D., inzb.;
TAIWIJ, V.D., prof., doktor tek-hn.nauk; FALIMICH, A.S., kand.tekhn.
nauk; TSECELISKIY, V.L., inzh.; CHE104YAK, V.S., inzh.; SHUMTSEN,
D.P.J. inzh.; ZVEGETSEVA, K.V., inzh., nauchn-yy red.; TYURIN, V.F..,
-I-nzH-.,nauchrjyy red.; VOIrYANSM A.K.,glav.red.; SOKO1DV,D.V.,zam.
glav.red.; SEUBREMIKOVIS.S., red.; MIK1UZLGV,K.A.1red.-
STAROMOV, I.G., red.; VOLODII-,, V.Ye., red.; NIKOLkYEVSKIY,
Ye.la...red.; LYTKDIA,L. S. red. izd-va; PE1i6VkLYUK,X..V. red. izd-va;
RUDAKOVA, N.I.? tekhn. red.
(Welding o:erations in building]Svaroclmye raboty v stroitellstve. Mo-
skva,Gosstroiizdat,l962. 783 p. (MIRA 15:6)
(Welding-Handbooks, manuals, etc.) (Buildlng)

AYDAROV, G.A., Inzh.; BELYAYEV, B.I-, Inzh.;-LEVIN, L.I., inzh.;
RYABOV, A.F., inzh.; SAKHNOVSKIY, K.M., kand. tekhn.
nauk; CHESNOKOV, A.S.j SHILOVTSEV, D.P.; GAY, A.F., kand.
tekhn.nauk,, nauchn. red.; GORDEYEV, P.A., red.; GOLIEERG,
T.M., tekhn. red.; RODIONOVA, V.M., tekhn. red.
(Manufacture of
konstruktaii.
(Steel, Structural)
steel structures] Isgotovlenia stalinykh
Moskvap poostroiizdat, 1963. 401 p.
(MIRA 16:8)

inzb,-, sill lOVT.9EV p D,P.y inzh.
oml.ra~,-tlori on ad'ety vvwjrov~ In t~,n manufacture of
swal structural elements) Instruktalla po tokhnike bu-z-
-r,;)gnof-)'.i pri izgotovlenii stallnykh konstruk-tsii VSN
Vonkva, Strolizdat,1965. 13F p.
2. Hus.31a (1-923.. U.S.S.il.) Gla-~rUo upravleniye po prolmd-
stvu i montazim stallnykh i s1azhrWkk, ~helezobetonnykh kor,
struktsli.

.I ~~ "I -IV - j:~ Y jp k, i
"Zmcheniye vitaminov v khirurgii," Sovetskaya reditsina, 1939., No 21, pp. 10-14.

Prac
Arti-le,
'ocent
",he ~erm,)n -c

11C I'lo. 1, 174r). Pn-,pc~!cutic
e t. Xhir-ur.
Stab- Inst., -cl9l,,9-.

SHILOVTSIV. S.
(Traumatic aneurysm; classification, diagnosis, clinical aspect
and surgical treatment] Traymaticheskie ansyrizar; klassifi-
katojia, diagnostika, kdinichaskaia kartina i khirurgicheskos
lechente. Leningrad, Medgis, 1950. 119 P. Illus. (KLIIA 8:12)
(ANEMSM)

-"-N. M1119M. 1~ --
SHIWVTSBV. S.P., professor; )MGOLID. D.P., doteent.
Prevention of surgical shock. Xhirurgiia uo.10:33-35 0 153. (XUtA 6:11)
1. Is propedevticheskoy khirurgicheskoy kliniki Uybyshevskogo medItsinskogo
instituta (direktor professor S.P.Shilovtoov). (Operations, Surgical)

professor
Surgery in postoperative herniss 'by subaposurotic transplantation
of the cutaneous scar. Xhirurgiia, 33 no.2:10-t6 7 157. MRA 10:6)
1. Iz propedevticheskoy khirurgicheakoy kliniki (zav. - prof. S.P.
Shilovtsev) Kaybyshavokogo weditainsicogo institute.
(HKRNIA, VIRML, surg.
technic subaponeurotic transpl. of cutaneous scar in
postop. hernias (RuB))

SHILOVTSEV, S.P., professor (Xyubyehey)
"WXWOM-WOMMID
Life and scientific activity of Tol.lamovskil; on the 100th
anniversary of his birth. fest,,khtro 78 no.5:131-138 Jtr '57.
,(XLRA 10:7)
(RAZUHOVSXII, VASILII IVANOVICH. 1857-1935)

SHILOWSBY, S.P,, prof. (Kwbyehey)
~ .
"Readings on the his tor7 of surgery," no.1, by B*M. Xhromov. Rerieved
by S.P* Shilovtsev Nov khir. arch. nool:81-82 J&-F '58 (MM 11:11)
(StMGMU5 0
(MOMOV, B.H.)

AMINEV, A.14.j, prof.,- BEREEZOV, Ye.L., 1rof.; BISENKOV, N.P., lumd. med.
nauk; BRAYTSEV, V.R., prof.; DEYNEKA, I.Ya.,, prof.; DYSKIti,
Ye.A.,, kand. mod. nauk KAZARSKI7.1, V.I., prof.; KARAVANOV, G.G.,
prof.; LEVIN, M.M... prof.; MAKS110;KOV., A.N.., prof.; YMAT, V.S.,
prof.; NAPALKOVO P.H., prof.,- ROZPIIGV, B.S., prof.; RUSANOV, A.A.,
prof.,- RUSANOV, G.A., kand.zed. mauk; FILATOV,, A.11., prof.;
CHUKERIYENKO, D.P.., prof.; %MIJ USEV -I.P.., prof.; PMOVSKIY,
B*V,, prof., otv, red.; YELIKKOVI A.V.,, Prof.,, red. toma;
SUVOROVA. T.A.j dots., red.; MIROTVORTSEVA, K.S., red.; RULEVA,
14.S... tekhn. red.
(Multivolume manual on surgery] Mnogotomnoe rukovodstvo po
Ichirurgii. Moskva, Nedgiz, Vol.7. ISurgery of the abdominal
wall and organs of the abdordwLl cavity, the stor-ach and
intesUnes) Khirurgiia briushnoi stenki, organov briushnoi po-
losti-zholudka i kishechr-tka. 1960. 746 p. (14DU 15:3)
1. Deystviteltnyy chlen Akademii meditsinskikh nuuk SSSR (for
Braytsev, Petrovskiyj Ylellnikov). 2. Chlen-korresSondent Akaderii
meditsinakikh nauk SSSR (for Itakstmenkov, Filat4
(ABDOWN-4THGERY)

~- 49WWOVO-11I.P.-
A few words on the intestinal suture; in defense of the double-
row suture. MLU-Lwgiia 36 no.ltl26-129 Ja 960. (MM 13slO)
(MWTMm--SURGSU)

SHIIDVTSNvt SOFG# prof@
low surgical method for the treatment of cysts of the eav@
Ybotekbire 85 no*108134-:L37 0 160v (MM"13t22)
1. Is obishchey khirargichookoy kljin4Ir4 ($&r, - p=f, 8,P, Shi].OVUOV)
Kuybyshevskogo maditaiwkogo ivistituta.
(PANCRIAI-TUMM) (CISTS)

A
SHM~VTSKVJ 3.11., prrL,.; B--S:ltU)V, G.S., doktor med. nauk; SH'IfjVT3"'.'A,
ned. nauk; SHHOLIIiIKOVA, 3.A.; n-JC'17-iS'FIY, A.L.
Preventive and therapeutic effc.--ts of magnesium and calcium salts
and of bromides in mal!giant tutors. Vest. khir. no.12:14-22 162.
(IAJRA 17: 11)
1. Iz kliniki obahchey khirurgil (zav. - prof. S.F. Shliovtsev)
Kuybyshevskogo meditsinskogo instituta. Adres avtorov; Kuybyshev,
meditsinskly institut, klinika obshchey khirurgii.

,SHIWVTSE7, S.P., prof.; SHILOVTS97A, I.S., kand. med. nauk; SHKMINIKCTA.,
S.A.; KRICHEMMY, A.L., aspirmt
Prophylactic and therapeutic action of magneaJun and caloium
salts and bromides m malignvnI, tumors. Trudy Kuib. mod. inst.
24:11-31 163 (MM 17s4)
1. Tz kafedry obshchey khirurgii ( zav. - masluzbeanyy doyatell
nauki prof. S.P. Shilovtsev) Kuybyshevskogo meditainokogo Insti-
tuta.

SHILOWSET, S.P. prof. zasluzhemyy deyatell nauki RSFSR
In memory of Professor Efim Vvovich Berezox,1895-1958; on
the fifth anniversary of his death. Trudy Xuib. zed. inst. 24t
245-250 163 (MnU 3.714)

"I V E'Elt& rnin
t u v) Len rant vubtropical zone
the exi-,,.,.:!n,7 ot' tl
of t1ic Azorbayllzhan 27 PP, (17in of I-.c2-;Mndglg'e
georgian Crder of Labor Ited Banner
150 CoDien. (Y-L, 38-58,

SHILOVTSEVA, A.S.
Experimental prevention of malignant tumors (with summary in English].
liksper.khir. 2 no.4:53-58 JJ-Ag 157. (MIRA 10:11)
1. Iz kafedry obahchey khirargii (zav. - prof. S.P.Shiloytapv)
Kuybyshevskogo meditsiaskogo institute.
(KHOPIASMS. exper.
prev. & control of growth by salts of calcium,
magnesium & bromine)
(CALCIUM, off.
calcium salts, prey. & control of neoplasm growth)
(HAGIESIUH, eff.
magnesium salts, prev. & control of neoplasm growth)
(BROMINE, eff.
bromine salts, preT. & control of neoplasm growth)

S~iTLOVTSEVA, A.S., C.-aid *,'ed ici -- (diss) "On tne vroblem of
cancer orophylaxIs in exneriment.11 Kuybyshev, 1958, 16 -F)
(Fuybystiiev Aate -ed 1115t) 3`00 CoOies (KL, 131)
- 159 -

SHILOVTSEVA Jq A. S., kand. mad. nauk
Recovery of a patient vith suppurative ze6mtiritiz flollowing
conservative treatment. Vest. otorim. no.4:qS-99 161.
(MIRA .15:2)
1. Iz kafedry bolezney ukha, gorla 1, nova (zar. - prof. B. N.
Lukov(doceasedl) Kuybyahevskollo zeditainakogo instituta.
(MEDIASTINUM-D.-LSMES)

dokt or Med. naul-
I A YT I CHT-'V~', K li
kand. rlau~;
prciveritive and thrrapeutic c~fects Of MagrIss 'dm ~-nci c-' c: t
nc,
and of bromideo in mvilfgiant. tumors. Vest. khir.
1. Iz kliniki obshchey khlnxgii (zav. - prof. S.F. ShilwtOev)
F,uybysliev-.kogo meditsinakogo instituta. Adres avtorov: FIllybYshelry
meditsinskiy institut, klin:'-ka obshchey khim;rgli.

SHIIAYVTSLT, S.P., prof.; SHIWVTSEVA, A.S., kand. med. nauk; SHKOLINIK(WA,
S.A.; KRICHEVSM, A. *,, asp-ran
Prophylactic and therapeutic action of magnesiun and calcium
salts and bromides cn malignant tumors. Trudy Kuib* med. inst.
24:11-31 163 (MIRA 1714)
1. Iz kafedry obshchey khirurgii ( zatr. - moluzhenny7 deyatell
nauki prof. S.P. Shilovtser) Kuybyshevskogo meditainakogo Insti-
tuta.

SHILOVTSEVAJ, A.S.
Atelectasis -of a lung follow-Ing tonsillectamV. Zhur. uBh.,
nos i gorl. bol. 23 no-4a 82-83 Jl-.Agt63. (KnU 16S10)
1, 1z kliniki bolezney ukha, gorla I nosa (zav. - prof. 1.B.
Soldatov) Kuybyahevakogo meditsinskogo instituta.
(MIGS - CULOSE) (IMMIS - SURGERY)

S111LOTIS.HVI" A.S., kand. med. nFaik
Effe~~t of mal7tesi= and calcium salts and bromides c-n the
("Llu!'J, Of riqJ110maa; an 6AperJr-Lmta1 azid clinical stud7.
rug t.
'14 C[08 (MIRA 17:4)
1. 'Iz kava&-y obsh,~;hey khi:-.-urgii zuv. - zasluzhermy-t
nauki RSFSR prof. S.P. Shilavt-sr.7) I kafedry otorinolar `.~ g,;-
(zav. - I-Jrof. 1.B. S61datx,r) Kuyby-nhovskogo mojdlt-Onskl-g~~
tuta.

NIKOLMHIX, N.; SEVE VTMA, L.
A matted, of great governmental impoitance. T pom.profaktiva 14 no.16:
26-29 Ag '53. OnAi 6:7)
(Zabor and laboring clasece-Dwellings)

f
IVANOV, Igor' Vladimirovich, shofor 2-go avtobusnogo parka g. Xogkvy;
SHILOVTS17A, LeX.V redaktor; RALIKOVA, I.V., takhnicheekly redak-
[More than 600,000 kilometers of travel without major repairs] Za
600 tysiach kilometrov probege. bez kapital'Logo remonta. Moskva,
Hauchno-tekhn. izd-vo avtotransportnot lit-ry. 1954. 26 p.
(Motorbuses) (HLRL 8--7)

kati.i. clol-?hoz. nauk, glav.
red.; :31LOU, I.F., kano. I.A. nauk, glav. red.;
T.M. rAuk. eirtc..
'1:0, Y.I.I. [5,4yakoo I.M. J), red. ; TA7, ARINOV K. A.
va.
S
(Tatarvnov. K.A.I. kand.--bf4.'naukj dots., red.;
SI'DIANSYMA, V.O.[Sh~L4~Aka, V.0.1, rei.
(Materials on the study of the natural resour,:es of
Podolia] Faterialy do vyvehennia pryrodnykl, remarsiv
PotAllia. Kremenets', Kremenotalkyi derzha-myi pedagog.
!I,,-t, 1963. 199 P. (IMIRA 17:7)
1. Mizhvuzivs'ka konferentsiya po v)-v--hennyu pryrodnykh
resursiv Fcdillya. 1963. 2. Kremenetalkiy pedfigogicheskiy
institut (for Tatarinav, Farisova).

E:
MSR/ Chemistry
Card .1/1 Pub. 22 - 3.1/62
Authors t Nesmeyanov, A. N.p Academician; Perevalova, E. G.; Golovnya, R. V.; and
Shilov-tseva, L. S.
Title i AUM arjurMMN s and forrocenylamine
Periodical I Dok. PJ? SSSR 10213, 535-538p May 211 1955
Abstract I Using various diazo-compounds the authors synthesized m-nitropheny1ferr"
and p-ferrocenylphenol and then utilized the m-nitrophenylpheny1ferrocene
and a previously described p-isomer fcr the synthesis of a and p-ferracenyl-
antlines. The ferrocenylamine was established to be an orange colored crys-
talline substance well soluble in organic solvent and when distilled In
vacuo, it offers acetylene and benzoyl derivatives. Perrocenylamine chloride
is soluble in water but not in hydrochloric acid. Four references: 3USSR
and 1 USA (194.1-1955). Grarbs.
Institution : The M. V. Lomonosov State Univ.,, Moscow
Submitted : March 22, 1955

SCV/20-12 I - 1

1 S 77.:.~,
F E~ -.-,i c) va c

TITLE: The Synthesis of 14etlh~jl Ferrocene (Sintez octilferzotsena)
~I;RIODICAL: Doklady Akadeiaii nauk SSSR, 1958, Vol- 121, Hr 1, pp. 117-118
(JSS,q)
A35rRACT: In r,~cent vzrious mono- and 6ia11kL,1 ferrocenz-. were de-
1' i r c; c ti...i I a t i cz o f
-::ice of ride (.,Lf:: 1-,'" or
b, redL,--tiuL of the -.Ltones (,Icf 3) o:.- acids
(Ref 6). In the prejert paper the authors acnieved the syn-
thesis mentioned in the title by two Aays: a) by reduction of
methjl ether of ferrocene carbonic acid (yield 83;j) by means
of lithium alumohjdrate and b) by reduction of the -Jodine
methylate of the X 111-dimethyl-amino-methyl-fzerrocene (Refs 7,0)
by means of sodium amalSam (yield 9,i~a'). In the letter caze a
3.:iall quantity of nono-ferrocenyl carbinol ether
(C H Fec H CH is produced. In an e;t-leri:aental oart the re-
0 1
)
2
5 5 5 4 2
Card 1/2 actions a) and b) are described. The infrared and ultraviolet

The 6~-nthesis of Methlyl Ferrocene SUV/I2U-1 2 1 -1 -32/33
spectra of the methjl ferrocene which -,%as produced according to
the reactions a) and b ) are correspondingly identical. They
were taken in the laboratoriya molek-ulyarnoy spektrookopii
kafedry organicheskoy khimii (Laboratory of Molecular Spectrcs-
copy of the Facultj of Organic Chemistry of the Moscow State
University). In a paper on ferrocene ald1lation (Ref 2) methyl
fcrr(~cunk~ with a mtlting point of 110 - 1190 was des(.,ribed. The
1-1-roduceed product has a meltir.,~ te.al .,r3ture oi' 33, 5 -. 36,5)0.
These last d-.ta ar-., undoibted. The reascrs for the Lv!ntioned
diver;,ence are ex.~laincd later. There are 9 referEnces, 6 of
which are Soviet.
ASSOCIATION: Lliosk:~vskij C;osudarstvennyy universitet im. M. V. Lomonosova
(L:oscow State University imeni K. V. Lomonosov)
SUBEITTLD: March 12, 1958
1. Methyl feiTocene.--Synthesis 2. 14ethyl ethers-Redue-Lion
3. Lithium aluminum hydrates--Chemical reactions 4. Me-~.~yi
iodide-Reduction 5. Sodium-Chemical reactions
Card 2/2

50)
AUTHORS: Neemeyanov, A. N.p Perevalove., E. G., BOT/20-124-'2-25/71
ShjjQyjjt!~~ ~stynyukf Yu.*A6
TITLEs Synthesis of Perrocene.Derivatives by Means of the
RIX-Dimethyl-Aminomethyl Forrooone Mothiodide (Sintez
proizvodnykh ferrotsona.s pomoshoh'yu yodmetilats.
N,N-&imetilaminometilferrotsona)
PERIODICALs Doklady Akademii nauk SSSRj 1959, Vol 124t Ir 2. PP 331-334
(USSR)
ABSTRACTs The compound.last mentioned in the title was earlier used by
the authors (Ref 5) for the synthesis of metfiyl forrocons. It
proved to be a suitable reagent for the introduction of the
ferrooonyl-mothyl group (Refs 2 -8)# In the present paper some

'botitution reactions of the climethyl-amino group were carried
u
o
out, furthe rmore 4 m94hYJx4ftr2aQ4.= was aminomethylated and
forrooone aminoothylated. It was thus possiblo to obtain the
sodium salt of forrocenyl-mothane sulfonic soid by theinteraotion
between the compound mentioned in the title and sodium sulfite.
By the influence of potassium thiocyanate ferrooonyl-mothyl
thiocyanate was formede Sodium phenolate and -fl-naphtholate
Card 1/3 yielded the phenyl- and Pnapbthyl other of the forrocenecarbinole

Synthesis of Ferrocene Derivatives SOV/20-124-2-25/71
by Means of the N,N-Dinethyl-Aminonethyl Ferrocene Methio(lido
By ferrocenyl methylation of the p-oxy-azo benzene an azo
compound was formed containing a ferrocenyl group. This had
hitherto not been possible. On the aminomethylation of the
methyl ferrocene (Ref 5) with a mixture of NtH,N I'N 1-tetramethyl-
diamino methane and paraform a homoannular (N,N, dimeth.71-amino
methyl) methyl ferrocene was obtained in a 60% yield. The
aminomethylation of the methyl ferrocene was carried out in the
substituted cyclopentadiene ring in a yield which was somewhat
higher than for ferrocene (51%, Ref 2). The addition of
phosphoric acid increased the yield up to 80%. Besides,
diaminomethylated meihyl ferrocene is formed (10% yield). Thus
the methyl group in the methyl ferrocene considerably activates
the ferrocene nucleus against electrophilic attacks. The
formation of the homoannular compound suggests that the ring to
which the methyl group is bound, is activated to a more
considerable degree. The successful production of the diamino-
methylated methyl feTracene further proves that the influence
exerted by the substituents is transferred from one
cyclopentadienyl ring to the other one by means of the iron atom
Card 2/3 (Ref 9). From the compound mentioned in the title the authors

Synthesis of Ferrocene Derivatives SOV/20-124-2;.25/71
by 111,eanB of the N,N-Dimethyl-Abinomethyl Ferrocene lethiodide
synthe.sized the homoannular.dimethyl ferrocene. It may be
assumed from the comparison.of infrared spectra that the
alkyl groups are in a 1.3-position. There are 12 references,
2 of which are Soviet,
ASSOCIATION: koskovskiy gosudarstvennyy universitet im. M. V. Lomonosova
(Hosco.w State University.imeni Lf..V. Lomonosov)
SUBMITTED: October 14, 1958
Card 3/3

NESIREYANOV, A."I.; PFREVALOVA, E.Go; SHI.LOVTSEVA, L.S.
Reactions between organomagnesium compounds " (Ferrocenylmethyl)
trialkylamy,onium salts. Izv.AI4 SSSR.Otd.khim.nauk no.11:1982-1983
N 61. (MIRA 14:11)
1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosova.
(Magnesium organic compounds) (Ammonium compounds)

2
4C82506/61/1 3Y/004/Oi 6/025
2 IL'3/B2C6
AMIOR31 5escoyanov, A. N., Acado=ician, re.sva:oya, Z. G., Gubin, J.
2., :iikitina, T. V.f Pono-Mareelo, ani Shiloytieva,
.17LEs kroporties of pheryl forracene
kI.ilODICALe Akademiya nauk SSSR. Dokl.&4y, v. 4. 1961, 888-891
TBXTe The auzhcra investigatede 1~ the am..no ccz.~'V_~~.".~.'Qn' 2) sulfona-
t1on, 3) concurrent (with forrocono) acetylation. az,' 4) nitration of
ph.jr,:Il forroceno. They established that the slky'l tj-~up' if lielod with
th-i forrocar.9 ring, facilitates the suboojuent elect lic substitution.
in this case, the cyclopontadianyl ring to which the %Llkjl group to b9nde4,
is rare strongly activated. In relation to the f9rrc;oN,-l group. the
phenyl group is an electron-aoceptor rroup (A. it. Ne4zdyanov st al. 39f.
51 DAN, 101, 81 (1955)). Those data by the authors were confirmed by U.
Roaonbl~~J. Am. Choz. Sao-, OIP4530 (1959)), The ).notroDhilic substi-
tution of the hydrnger, Atoze -in-the forrocons rins is deactivated by the
phony! group. 1) Amino motbjlation. To a mixture of 70 z1 of glacial
Cardl/6

n V,~, -AmV-,NW
25856
S1001671139100410161025
?rc;,ertisa of ph*nyl fezrocene B103,(B206
acetic acid and 4 9 of H 3PO 41 coolod to 100C, ~.25 9 (0-01-9 mole) of
I
.6tramethIldiamineathano is gradually added, and then 4 S (0.015 mole) of
phorVI farrocene. Thi reaction =as& 7an stirred for I hr at room
toz~oraturo and for 10 hr at 110 - 115 C in a nl:rogon currant and sub-
soluantly diluted with water to the double amount. The fe=rocerts (1-5 Z)
vhich had not entered into reao%ion was extracted with berzona. 4VP ",au
solution was added to the acidic solution, azd the formed (N, V-dizothyl-
arzino:~ethyl)-phanyl ferrocona was extracted with other. After distilling
off the other, 2.6 g of the abovo-mentioned compound w.o obtained an a
viscous, dar&j reddish-brown oil. The yiold ozounted to 54~0' of the
theoretical ore (related. to phanyl, forrocona) and to 96A of the phenyl
forrocano reacted. The final product was distilled In vacuo.1ta boiling point
was 150-1600C/3 cc HgI 20 1.6315- In the Infrared s2ectrum of the final
nD I
product, week absorption bands oxistod In the range 1000 and 1100 cc-
From this, the authors asouno the for=ation of a mixture from the hatoro-
and hozoannular laomers. The latter seems to form in s=all quantities.
The zathlodide of the final product was produced loy adCLtioa of CH 31 to
Card 2/6

3/020J61/139/004/016/025
Pro;trties of Phanyl forro0sno 2103/3206
a solution of 3.2 g In absolute Ch OR (or In benzene) wItb procipitaflon
aftor 15 min by a-;reat a=ojnt of anhydrous other. An 41=04 t.quentit&tive
(4-3 9) amount oftzethicdidi was produced. It is a yellow, c.7&t*&Ilta*
,substance with 'he decompoaition point 70 - 750C. gince In the Wrared
spectrum of the methiodide ihich was produced froA the distilled fipal
produot# absorption at 1000 and 1100 ass -1 Is missing, the authors conclude
that the substituting groups art in various cyclopents4ionyl rings.'
Through reduction of the mothlodIds I)y sodium ozalgan, theAfTeraimilar.
1, 1-nothy-phenyl lirrooone was obtained (at's rarction no. 1).
COH. CAU
0100.
4,
/-C"0
1YK I
Card, 316

/61/1'39/004/3 5
S/020 ~qw
V
,
.
Propert1~3 of phonyl ferrocens, B103/3206

The yield was 1-8 9(71',?- of the theoretical one). Absorption At 000 trA.,
1100 ca"I was missing in itslnO~xrsd spoctrux. A frire cyolopantadlenyl.
rtng *an only be proved spootrcecoyically In the substance which was
iaolstad fr-~.n the.rother liquor. ".he authors ooze to the con4celco that.
the hateroannular Isomer wao the ritn cozycn4nt of the xIxtur# produced 'by
amino methylation. Therofnral.th.11 reaction ssalnlr coctro In 1bj free,
cyclopentadienyl ring. 2) To a,,e;-IutIon of 10 8 (0.08 0014)'0f phollyl
'
of troehly
forroceng I~ 100 al of dichloroaths!Ao6o .10 S (0.060 mole/
propardd dloxant sulfatrioxide.wc-1.4dded whil* cooling with $a*. 'Under
the conditions of formation of jfGz-:?o4en*.nonosulfanl* acid; I I, I V~04Y.L
ferrocone sulfoale acid was obtaln7:14.
50 -dloxane
1
C H C OC x C H C 74~
7 -H 50 3 This sold was Isolated
6 5 5Y' 5 5 6 3 5~4
: 5 .4 3
.
as lead *&It, which crystallizeawl.016'. .vatler molecules. Absorptioz~ at
1000 and 1100 am- I ias ~sra ale p. mlisirs; the phenyl and sulto grou3t are
therefore in different cyalopvnti~isrxyl rings. The forastion of kettre-
annular sulfcAic acid is also proo,t.of a lover reactivity of theyinj
Card 4h __ j

5/020/61/13)/C,04/016/025
Proportios of phenj1 ferrocano BIOVB2C6
lin],.ed -with phenol. 3) The deactivating effect of the yhcr%yt Src.-p
on the forroco-41 ring is spociLlly marked during the Friedel-Cr&ft
reaction. A solutio-I of 1.4 =1 of acetyl chlcride And 2.66 g of AICI 3
in 10 ml of absolute ether vvis added in th4 course of 20 z.4n to a
solution of ferrocene (14.72 Z) and phenjl terrocone (5.42 S~ in 100 =1 of
CS2. All components were ujed at a molar ratio of 10,10. The authors
obtained acotyl ferrocene only with a yield of 25~; of the theoretical oAo,,
and a mixture of acc*jI phenyl ferroceres of only 5%, i4l,~ of ykenyl
for.rocene and 3Dv" of fcxrocene being re~~,overed unchaneed. From this# the
authors conclude that ferroceno may be &cotylated more easily then 'phenyl
ferroceno. 4) Phanyl forracene was nitrated by means of ethyl nitrato
in CS2 in the proserco ~f AlCl 5' The authors obtaftee a 13% yiold (of the,
theoretical one) of p-nitro-phenyl ferroc9ne (see reaction no. 2).
NO.
Fe 640". \/-
- Fe
!AICZJ
Card 5/6

3/02 0/61/139/004/01�/025
Properties of pher4l forrocene B103/B206
The main quantity of this final product is 13OlatOd together with part of
"-a nonreacted phonyl ferrocene in nonoxidizoe stato (ar.-A not as a cation).
The authors pre3*.;=o that nitrat4on does not take place with the phonyl
lorrocene cation but with pheul ferrocene. The continuanci of the ferro-,
ccn.-1 ring under tho5e ccnditions is not'iceab,16, probably as a consoquente
of a reduced capability of being oxidi=ed to - cation as co=p&rod with
ferrocer.o.' Ferroceno itself cannot he nitrated under those conditions.
Attempts of the authors to nitrate ferrocene with varloua bther reagents
(e. g., nitroniu= borofluoride) also failed. Onl:- oxidation of farrocene
to the cation which is inert in reactions of the olrctrophilic oubatitution,
was brought about. There are 9 references: 7 Soviot-bloc and 3 Aon-
SovieZ-bloc. One re:rerencs to Znglish-lan6uage publications in given In'the
body of 'he abstract, the another one readst M. 2o3enblum. R. B. Woodward,
J. Am. Cho=. Sac., 8-0, 5443 0958))-
ASSOCIATIONs Maskovskiy Cosudarutvenny;r universitetim. U. V. Lomanoaov&
(Sloocow State University imeni X. Y.-Lomonosov)
SUB-1ITTEDt April 19, 1961
Card 616

51062
,/62/000/010/001/003
B144/B186
AUT~Qlqs: Nesmeyanov, A. 4., Perevalovat Ft. Gov and Shilovtoevap L. S.
TITLE: Aminomethylation of phenyl, tolylp and'chloro ferrocenes
Pr;;(10"ICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. 10, 1962, 1767 - 1772
TZ'AT: Phenyl, p-tolyl, and qjhloro ferrocenes were aminomethylated with
N,N,N1,Nl-tetramethyl diamino-methane in glacial 0acetic acid In the
presence of H PO by heating between 110 and 115 C in an N stream for
3 4 2 .
12 hr. The mixture was then diluted with the same amount of H , the
2
non-converted initial products were extracted with benzene, and the
solution was alkalized with 40~ NaOH. The end products were extracted with
ether and chromatographed on Al 0 impregnated with formamide. The
2 3 .
quantitative composition of N,N-dimethyl-amino-methyl ferrocenee were
determined by paper chromatography.
Card 1/3

S10621621000161010011003
Aminomethylation of phenyl,... B144/BI86
!Initial ferrocene Amino isomers lodine methylates
number, type R in benzenei% of totallm.P6 in IR spectrum
f
amines C 1000- 1100
pheny! 1hetemcyclic 0.14 82 90-95 -
homocyclic 0.38; 15 143-145 1004; 1104
0.81 3 167-170 ~1103; 1106
:P-tolyl 1heterocyclic 0.26 83 95-99 -
1 homocyclic 0.57 17 172-175 1004,1106
Ichloro Ihetrrocyclic *0.22 eo 185-190 -
Ihomocyclic. *0.32 11 -W-166 loo61 1104
1mixed 2
CHC13:C6H 6 1:1
Thus the aminomethylation was effected mainly (, 50) in the non-substituted
cyclopentane dienyl ring; this w.- shown also by the IR spectra of iodo-
methylate of the substances obtained. The spectra of heterocyclic isomers
showed no 1000-1100 cm-1 bands. iodomethylates were obtained by converting
amines with twice the methyl iodide excess in benzene; their compositions
and gross formulas are given. An excess of 1,11-methyl-p-tolyl ferrocene,
Card 2/3

3/062/62/000/010/001/003
Aminomethylation of phenyl,... B144/Bla6
CJBHI~Fe (m.p. 93 - 950C) was obtained from the iodomethylate of
1,11- N,N-dimethyl aminomethyl)-p-tolyl ferrocene by reduction with-
sodium amalgam. There are 2 tables.
ASSOCIATION: Monkovskiy eosudarstvennyy universitet im. M. V. Lomonosova
(Moncow State University imeni M. V.- Lomonosov)
SUB!JITTED: March 7, 1962
Card 3/3

3/062/62/000/011/006/021
B101/B144
AUTHORS$ Nesmeyanov, A. N., Perevalova, E. G., Shilovtoeva, L. 5.0
and Tyurin, V. D. -----------
TITLEt Ferrocenyl methylation by means of N.N-dimethyl aminomethyl
ferrocene and its iodo methylate '
PFRIODICALs Akademiya nauk SSSR. Izvestiya. Otdeleniye khimi'cheskikh
nauk, no. 11, 1962, 1997 - 2001
TEXTt The following syntheses were-made with N,N-dimethyl sminomethyl
ferrocene (A), trimethyl(ferrocenyl-metkiyl) ammonium iodide (B), and di-
methyl-ethyl(ferrocenyl-methyl) ammonium bromide (C)s- (1) Reaction of B
with Na 2S-10H 20 on a boiling water bath and ex traction with ether pro duced
di-(ferrocenyl-methyl) sulfide, yield 54~, M.P. 107 - 1080C (with decom-
position). The IR spectrum contained absorption bands at 1000 and
1104 cm- 1. (2) Di-(ferrocenyl methyl) disulfide, yield 53%, m.p. 125-1270C
(with decomposition), was obtained from B and NaSH, the latter being pro-
duced by bubbling H 25 through XaOH solution. (3) The synthesis of ferro-
Card 1/4

S/062/62/000/011/006/021
Ferrocenyl methylatic;j by means of ... B100144
cenyl methyl acetate was made in three wayst (a) Reaction of B with
glacial acetic acid at 90 - 950C in N2 atmosphere, yieid 25%, m-P. 74-760C,
IR absorption bands at 997, 1104, and 1740 cm- 1. A compound soluble in
benzene,(gross formula C 12H12 Fe, m.p. 115-1350C) formed at 110-150OC; it
was not further investigated. (b) Reaction of C with sodium acetate at
150-1550C in vacuum (7 mm Hg), yield 59~, m-P- 75-760C. (c).Reaction of A
with acotic anhydride, yield 69~. The compound obtained by (c) was, as to
m.p. and IR spectrum, identical with the compounds obtained by reactions
(a) and (b). (4) Reaction of A with methyl benzoate in N2 atmosphere at
150 - 1350C, and extraction with benzene, produced ferroceny1methyl.
benzoate, yield 507-1"o Z-P- 132-1330C, IR bands at 1003, 1098, 1700 CM
(5) Peaction of A with methyl anthranilate produced ferrocenyl methyl 1
anthranilate, yield 46~;, m.p. 123-1240C, IR bands at 996, 1102, 1666 cm-
(6) Heating of B with ethyl acetate at 120-1250C produced, instead of the
expected ferrocenyl methyl acetate, ferrocenyl carbinol ethyl ether, yield
42~;, b.p. 66-70OC/0-3 am Hg, n20 1-5840. The IR bands at 1002, 1106 cm-
D
Card 2/4

S/062j62/000/011/006/021
Ferrocenyl methylation by means of... B101/B144
proved the existence of a nonsubstituted oyclopentadienyl ring. Bands.of
an ester carbonyl group were not observed. (7) B with butyl acetate pro-
duced ferrocenyl carbinol butyl other, yield 351;, M-P- 31-5-32-50C, b.p.
105-1060C/2 mm, Hg, n20 1.5695. 1R bands at 1004 and 1104 cm-1. (8) Heat-
D
ing of B with piperidine at 1100C produced N-(forrocenyi-methyl) piperidine,
Yield 94~v, m-P. 64.5 - 85-50C, IR bands at 1002, 1103, 1505 cm -1 ; Reaction
of A with piperidine did not lead to a subst-itution of the dimethyl amino
radical. (9) N-(ferzocenyl-methyl) morpholine was obtained from B and
morpholine at 120-1300C, Yield 95%, M.P. 74-750C, IR bands at 1006,
1104 cm- 1. (10) N-(ferrocenyl-methyl) anilinewas obtained from B and
aniline in boiling aqueous solution, yield 75cl, m-P- 84-64-50C, IR bands at
looo, 11o6, 1602, 1552-1566, 3930 cm~ 1. (1'1) N-(ferrocenyl-methyl) phthali-
mide was obtained from B and potassium phthalimide in dimethyl formamide
solution at 130-1400C, yield 97~6, m.p. 209-2100C (with decomposition), IR
bands at 1000, 1102, 1706, 1758 cm (12) Ferrocenyl methyl amine was ob-
tained from N-(ferrocenyi-methyl) phthalimide and hydrazine hydrate heated
at 80-900C in N2atmosphere, by precipitation with NaOH, b.p.
Card 3/4

Ferrocenyl methylati4ftn by means of...
8/062/62/000/011/006/021
B100144
20
108-110OC/0.5 mm Hg, n D 1.6310, 1R bands at 1002, 11%, 5288, 3366 cm-
This compound decomposes in air. Bubbling of HCI through its bonzene solu-
tion yielded ferrocenyl methyl amine hydrochloride, decomposition tempera-
ture 235-2550C.
ASSOCIATIONt Moskovskiy gosudarstvennyy universitet im. 9. V. Lomonosova
(Moscow State University imeni bl. V. Lomonosov)
S UB14ITTED s April 2, 1962
Card 4/4

0 k a -18 1,1 9 h i I aT t O"s
Y,:harie- of th- ligane In rap,A(nd ferrocenes
P,
a 9tran, inliuence an the exchanx-ie of Liquida. in the reaet'-Cm wl-= meal'Ulmr4
iron.

--------------------
A-P5007066
-Me.#4 tyl,?,Tle r~~,rT
.11t 'ract4on betwqc-n ack-tyl-ferrocene &nd
mri .1 -Y TDen t ad
t. ar~7-lLn--nty, AkAdemii nAuk cS_"?
SM CODS: oc, Gc
-TB 21 000
-
Card

MP'Si-i yll~
::Xchallre 0i l-,J!nnJ:; .111*1,~31'jt;A~~i! ft";*:, 'J.-I, 4~
10 no.6:111~7-1330
I n 3 t i t i i L e I t!no n t, o c) rgn i i i e i z,-~yt-A I v,: 1.

__r'%CC__NPt_ AV7013160 -----------------SOURCE -CODE-.- - UV0062/66i000-012'-*2239. 2240--
AUTHOR; Shilovtseva, L. St; Parevalova, E.; Nefedov, V. A.; Nesneyanov, A. N.
oRG: ~joscow State University in. ~1. V. Lononosov (1-toskovskiy gosudarstvennyy
universitet)
TITLE: Aminomethylation of ethy1ferroceno
SOURCE: AN SSSR. Izvestiya. Sartya khtmicheskayal no, 12, 1966, 2239-2240
TOPIC TAGS: methylation, ferrocene
SUB CODE: 07
ABSTRACT: ' Mie dimethylamin' i6y ion- of eihylferx-locene wai'~onductedvjth
ame
ii,N,N',N'-tetrar.iethyldiaminon-ethane. 1,2-,1,3-, and ill,_(N,N-direthylaminom-
e'vhyl)ethylferrocenes (total yield approximately 70% of the theoretical) and 1,
11-di(li,N-dimethylaminomethyl)-2-,ethylferrocene and 1,1--di(N.,X-dimethylaminom-
ethyl)-3-ethylferrocene (total yie1A about V,9) were isolated from the reaction
products. The products were characterized, and thei 'r structures studied accord-,
.ing to their absorption capacity and infmred spectra. Me yield of the how-
annul-ir isomers was approximately four times as great'as that of the hatero-
annular isomers. Me ratio Of 1,3-isomerr, to 1,2-isomers was'approximately
3:1, both for the mono-and for the diamines. ~f.values for the isomers obtained
Card 1/2 UDCg 542.958.3 + 547.1113 + 546.72
9 02r76

ACC NR: AP7013160
i
are cited for chromatography on alumina Impregnated with formamide.
Orig. art. has: 1 table. IfT!1PRS: 40,42
27

STIILOZBIMG. Ju.A., inzhener.
Some Droblems in general automation of industrial machiner7.
Prom.energ. 12 no.9:1-3 S '57. (MIRA 10:10)
(Automation)

__ BLAJITLIR, H.S.: FINMISHMN, B.M.; SHILISHTM, S.Sh.
Thermodynamics of binary alloYso Izvoy7souchob.say.; chern.
mete- n0-3:10-12 160. (MM 13:4)
1. Hoskovskiy institut siati.
(Alloys-Thermal properties)

4 1110
AUTHORS;
TITLE:
PERIODICAL:
86235
S/032/60/026/008/035/046/XX
B020/BO52
Bogorodskiy, 0. V. and Shillshteyn, S. 3h.
Goniome%er Head for X-Ray Stru-,,tural Analysis by a
Double-crystal Spectrometer
Zavodskaya laboratoriya, 1960) Vol. 26, No. 8,
pp. 1012 - 1013
TEXT: The double-crystal X-ray spectrometer detects errors in the struc-
ture of single- and polycrystal samples, exactly determines The stress
distribution in wide single-crystal regions, and the lattice periods of
single- and polycrystal materials. The device type YPC-50M (URS-500
used at present does not permit sufficiently rapid and exact studies.
The goniometer head designed by the author (Fig.!) simplifies the fixa-
tion of the objects to be studied in a position which corresponds to the
reflection of X-rayB from every crystallographic plane. Thus, an ac-
curacy of UP to 0.5" is attained. The double-crystal spectrometer is at-
tached to the device URS-50I. The first crystal is put into the clamp
Card 1/2

86235
Goniometer Head for X-Ray Structural S/032j6O/O26/008/035/046/XX
Analysis by a Double-crystal Spectrometer B020/BO52
cf the menochromator, the second one into the goniometer head. The
widths of the rotation curves of a natural calcite crystal (201) and a
germanium single crystal (111) were determined by she above grniometer
head attached t,:~ the device URS-50I (Fig.2). The theoretical width cf
reflecTion of an ideal calsite crystal is 5.8". In the given case, a
width of 1111 was obtained due to the insufficient quality of the crys--
tal. The experiments show9d that the band width of a germanium crystal
_'2 -2
with a dislocatic-n density ef 10 cm IS ZOII, and of a crystal with a
dislocation dengity of 104 cm- 2 it is 40". The rotation curves thus
have two maxima which is due to the presence of blocks in the germanium
aingle crystal, with disorientation angles of approximately 20". The
theoretical width of the rotation curve of the ideal germanium arystal
is 15.8". There are 2 figures and 1 non-Soviet, reference- 1 German,
Card 2

83560
5/02q6o/i34/001/012/021
f,q3l B004/BO6O
AUTHORS: Bogorodskiy, 0. V., Umanskiy, Ya. S. S1hil1sht#Z!y S. Sh
TITLE: On the Nature of the Mosaic Structur:'~f -
of Germani um and Silicon
-0
PERIODICAL: Doklady Akademit nauk SSSR, 1960, Vol. 134, No. 1,
PP~ 114 - 116 VV
TEXT: The authors wanted to check the dislocation character of the
mosaic structure (Fig. 1), and studied single crystals of germanium and
silicon that were drawn from the melt along the (III)-axis. The samples
used were 2-3 mm thick foils out perpendicular to the (Ill)-axis. It
was established by etching that almost all of the dislocations exhibited
the Burgers vector a/2 (lfO). In some cases2 the authors observed lines
which corresponded to small-angle boundaries. The densi y of 9-irface
dislocations was 102 _ 106 cd,4 for germanium, 102 _ 101 cm-2 for
silicon. The principle of the X-ray analysis is described (Fig. 2). The
monochromatic X-ray beam is reflected from the crystal I, and hits on
crystal II whi4,,h is rotated around small angles. The authors used the
Card 1/3

83560
On the Nature of the Mosaic Structure of S/02o/60/134/001/012/021
Single Crystals of Germanium and Silicon B004/BO60
JPC-50H (URS-50I) apparatus with Geiger counter.The curve of the in-
tensity of double reflection of I as a function of the angle of rotationp
is defined ae rotation curve. The authors constructed a special gonioa
meter head which allowed rotations around small angles with an accuracy
of Oa5". The rotation curves obtained experimentally-are shown in Fig-39
the data are given in Table 1. The distances between the iaaxima equal
the disorientation angle of the crystal blooks. Experimental data show
that the Ge single crystals have a mosaic structure with all disloca-
tion densities, while the disorientation angles of the blocks change
-littlo,'although the dislocation densities diffei by four orders of
magnitude. This cannot be explained by the Burgere m6del. In silicon,
the blocks are considerably smaller, which likewise contradioti-the
Burgere model, since the lattice constants of Ge and Si are little
different. The germanium crystals with small-angle boundary.showed
fragment structure. The authors arrived at the conclusion that the block
boundaries in Ge and Si may be connected -with dislocations, but not ac-
cording to the meohaniBm of the small-angle boundary. Also structural
defects might play a role here. The interfaces between the fragments,
on the other hand, consist of dislocation-a in agreement with the
Card 2/3

_9_V_ - -70VODOVA~--k-V---POGORODSKIY,-O-.V--~~
FOMIN G.~,
Some features of the crystallization of germanium-silicon alloys
in zone melting. Kristallografiia 6 no.2:256-260 Mr-Ap '61.
(MIRA 14:9)
1. Gosudarstvennyy nauchno-issledovatel'skiy i proektnyy institut
redkometallicheskoy promyshlenno5ti.
(Germanium-silicon alloys) (Dislocations in crystals)
(Melting)

/A
FF! AP4946(749 9-/tU70/64/009/005/0727/0729
A7,TICR: Shil'shteyn_, S. Sh.
r-.,.,estiqation of the structucal perfection of germanium
V:- I
q I !I a f 1, v. 9. -n-. 5, 1964, 7 27- 7 2 9
QS gerff%anium, jingle crystal, crystal lattice structure,
x -ay diffraction, x ray scattering, disloca-
coet f
ABSTRACT: The perfection of the germanium crystal structure was in-
.,*,sti,qated with a two-cvratal x-ray spectrometer based an the URS-501
Installation. The principles of the method are described In detail
staidard books (R. W. James, Optical Principles of the Diffractlon
Bell, Loondon, 1948: A. H. Compton and S. K. Allison, X-
7. e( ry and Eyper Lrent, van Nostrand, New York, 1935) ne

ACCESS [ON NR: AP4346049
i-~ t--p Pr-crii;r- fnr plotting the oscillation curve are
.1 1 ,-w, ~:,- -.zE~e os--illation curves were --_iKen for
~'ts 'Dr) eM-h ;; -'MP! eThe width of the osc,llation
-urver it half the height and the integrated reflectLon
:,;-ag,,ired. The test results indicat2 that germanium crystals
-islocation density frcrn zero to 10 am 2 scatter x-rays in
the dynamic scattering theory of Darwin
ry a-(g r e eme n t w, th I
When the dislocation density reaches 105 am-2, consid(ir-
1,roadering of the oscillation curves is observed, and the intf~-
-7ral reflecti-or COeffiCiEmt increases. It is concluded that at the
-!,slocation eersity the germanium crystals behave in somf?
:Pspe-1 -is _f t-hey had ar appreciable mosaic structure. Orig. art.
'nas: 1 fcrmula and I table.
V-q~- ?kT'ONL- ',,osu-iarstvenny*y nauchno~igsledovatal'skiy i proyekt-
avcv i bral-nl~ki ts-,/etny*kh metallov (State Sc-,en-
1~~stlt%ite for A.1loys and the Processing.of NonferroliE.

.iwjc,3; wag I t-T I tr".%Qw5m, mqml*~
ACCESSION NR: AP4046049
SUBMJl'rFD: 06Feb64 ENCL: 00
SUB CODE: Ss UR REP SOlft 003 OTHER: 009
3/3

R.I.; ~,~OWLERTPIVJKAYAP Y-.~.; ~~",RILISMTNY S,9h,
Vrjr-'..nis I.ypas cf stih pltq in jrlrg's aryistals of )--j.#17-type
I -
r.r -a no,2038-
Trudy 41 165a
(M'&'Rk 18i11)

1: ^r3
A LrR/',-; 0 7 -'/6 5/0 1 C/('04/0 5 6 21 56 5
ATMIORS! Pet r1i gevi ch,R L Shi'.1shtnen G. 9h.
--r --t inn of qall ium arseni-de s i nq :e
4-
~~)f'RCE- Kristalloqrafiya, v. 10, no. 4, 1965, 562-565
T A S s!r,ile crystal qro%~ri,vg, crystal imperfection, cralli-Im
r, crys~*-al dislocation
-ifection of GaAs -ad
c single crystals1was investigat
.;''4 nq cmuer Ka radi atioti A qP
ac; mon:D-h--)--iator. In view of the closenes-z of
-th-- - I
-tion duei tu-disperslorf-At~biot 4L'Ijileed d t
in thc-. (1, -1) and 3, -Y positions. The 1-2 mm thick
1- he Bri dq-,an or the Czoc-iralsku

614793-t'5
ACCESSION NR: AP5018727
method along the J111) plane, and
whose density was identified with
of etched and cheinically polished
pits had no effect on the shape of
'~')P f f i c- i on iF
irilli,-m arseni-~t~ -r--
(111) and (333) ref:ections
:
12 -1
etched-to-exhibit dislocations--
th6 etch-opit dens-itya--.-Ccraparitio-n-.----
crystals indicated that the etch
the reflection nor on the inte-
r small dislocation donsities I.he
stal. Broadenirg of the reflection
observed on some portions
-ji--atinq that the -nain reason 'or
it.iori caused_by the mosaiL: stric-
f 5 x 104 cm 2 the reflection
-hs but the
especially for the
f 1
:ot-fticient. -N 5., s-

~',()sudarst-vennyy nau --hno-issledovatel'skiy i proyektnyy
-,:l-.-e-:nykh metallov (State Scientific
~-D b r a b o tr-I y
,I I Dvs and Processing of Nonferrous
00 SUB CODE: SS
OTH!,"R: 006
31/3

A AN NF AP'~0187---2 UR/0070/65/010/004/0580/0582
548.4
AU MORS: Shil'shteyn, S.SI.M.7 Simonova, T.I. -7
T'. e~)roblem of the nature of the nondisloca*ion et-h pits
7- 1
SOUFCE: Kristaliografiya, v. 10, no, 4, 1965, 580-582
TOPIC TAGS: germanium, etched M,stal
ABSTRACT- New data were obtal-ned on the nature of the "'Little" -itch
pi.ts --n :zermanlwn. 7he i-estiqa, ~--)n showed that these etch pill-t
i rile
solution r)~ 14
is iricreased, to 5 or f~ nin,
to b-, I f-)r s--.,-~ral rn.,
112

N;~ AP:~UI8732
-ttle" p)-ts appear extremely elor.gated if the orientation is 4-50
nff jIll) and do not appear for laiger deviations. Unlike disloca-
the "little" ts reach a maximum with increasin4g etch:ng
A, !Isappear.P~This f-i-, ~oqether with comparLSOr. ':J
f &-nd comp a rtaon of
ities before and after quencIving and _ann4ajLI:r4,__ ie'd to
that the "little" pits are due to accumulations of point defects.
Ori-T. has: 3 fiqures and 1 table.
-AT TN: -~.s,ilarstv.-~rinyy issledovatel 'skiy i p--,Dyektn,,ry
metal lov (Stalle Sci-ent 1 f ie-
07HEF
212

,L 18847-66 EwT'z)/T/ZWP(t). - NP(o) JD
NX: ATbUUb471 SOURCE CODE: UR#,f2680/65/000/024/0038/0043
iAUTHOR:
Petrusevich, R. P.; Sollertinskaya, Ye. S.; Shil'shteXB, S. Sb.
State Scientific-Research Planning Institute of Allo
:ORG: _ys and the Processing of
--------,Nonferrous Metals (Gosudarstvennyy--nauch-40--issledovateltskiy i proyektnyy institut
,splavov i obrabortki tsvetnykh metallov)
JITLE.- Various kinds of etch pitting insingle crystal compounds of the type
~A B
III V
.SOURCE: Moscow. Gosudarstvannyy nauchno-issledovatel'skiy-i pmyektnyy institut
splavov i obrabotki tsvetnykh metallov. Trudy, no. 24, 1965. Metallovedeniye i obra:
!botka tsvetnykh metallov i splavov (Metal science and the treatment of nonferrous
metals and alloys), 38-43
:TOPIC TAGS: gallium arsenide, indium antimonide, single crystal, etched crystal,
:dislocation effect, defect structure, metallographic examination, semiconducting
material
;ABSTRACT: Etch pitting was studied in single crystals of GaAs and InSb~~ Ae fbrma~*
Aion oi small pitta on (311) surfaces and their redistribit-1;n-upori-Iiiiing weft
Card

L 18647-66
'ACC NR: AT6006471
!dissociated from the larger dislocation t1ch pits which generally form after chemi-I
Ical polishing. The etching conditions for obtaining the'small pits were as follow
!GaAs--the polishing solution was 1 part HF, 3 parts HN03, 2 parts H20 (polished-ai
f
Iroom temperature for 2 to 3 min) and the etchant for small pits was 1 part HM03 3
to
Iparts H20, 0.5% AgH03 (at boiling point 1.5 to 2 min); InSb--1 part HF, 2 par
'HN03 (polish at room temperature for 30 sec) and I part HF, 1 part H202, 8 parts
iH20, 0.5% AgNO3 (etch 3 min at room temperature). Mtcrographs (200-and 440x).show-I
,ed that the small pits became larger and formed terrace-like steps and subsequently
;became flat and eventually disappeared. After repolishing and etching, they,reap-
Ipeared in about the same number indicatirg that they are caused by defects extend-
ing deep into the crystals. Some crystals were heat treated at 1100 and 4000C (60
,hr), cooled slowly U day), repolished and etched. Small pitting reappeared except.
for randomly depleted areas. Within the depleted zones, the larger dislocation
tetch pits could still be observed. These data indicated that the small pits were
;not caused by dislocations but by clusters of point defects. Only the point de-
,fects could have been affected by the heat treatment. Orig. art. has: 3 figures,
i
i1 table.
SUB CODE: 20/ SUBM DATE: 00/ ORIG REF: 003/ OTH REF: 007
lCard 2/2 vab

SHILIT, B.A.; LTUBAH, A.F.; HARCHINSKIT, V.G.
Rate of interaction among the hard components of bl"t furnace
slags. Stall 16 no.4:303-307 AP 153. (KM 9:7)
l.Leningradaki.r politekhnichookiy institut,
(Blast furnaces) (Slag)

'r I - ity - ~ ~.- Y -&-
1~ - ''. - .-. . I '. .-..
I
--r
I
I

ACCESSION NR: -AP3007869 S/0197/63/000/008/0057/00W
Amms: xunin., F., Taksar,, I.; Shiltere,, M.; &d.1ter., E.
TrUE: On enerey spectra and oscillator forces in single valence atoms
SOURM AN Lat=* Izvestiyaj, no# 8s 1963s 57-&
TOPIC TAGS: Shr8ding6r equation,, single valence atom., potential field,, noutral
ato.m, single charge ion, lithium atom, sodium itoms pewazed-M atom
ABSTRACTL: The ~hrking'er equation has been solved for single-valence, atoms in two
effective potential fields given by
B
U= + -2r5-
where B - I for neutral.atams, B 2 for single-cbarge ions, etc.. and by a second,
itore complicated, gne given by
:U=-2r-'--:-2ar+s(s4-1)b (2)
Card
.1/2

ACCESSION NR; Al"1007069
I" el
A closed form solution is obtained for (1) and a three-term recurrence formula.,
represented by a series, for (2), Detailed numerical computations on an electronic'
computt-or are obtained for 31thium, sodium., w-A potassium atoms and in isoolectron
series of lithium, The various parameters oppoaring in the equations for various
.enerMr levels are determined Irom experimental data. All computations vare, per-
A. or,;- -.1 on the BEM-1-2 Vrs- computer at Latviyak4 gosudar"vennogo universitst Ime
P. Stuchki (Latvian'State University)& Orig. *rt. hass 12 formulas and 1 table,-
ASSOCIATION: none
SUBMTTED: 26DecQ DATE ACQ: 220ct63 MCL: 00
SUB CODE: PH NO MW SOV 1 003 OTIMRs 000
Cmd 2A

FUNINP P.; TAKSAR, I.; SHILTER, E. (Silters, E.]
Effective potential method for determining the modium
atom. Izv. AN Latv. SM no.10:49-53 163. (MIRA 171l)

i
Ar.JESSION' NR: A?3007869 S/0197/63/000/008/0057/0062
ALUHORS: xunins P.; Tak5sr, I.-, Shiltere, 11.; Sbilter,. E.
TrUE: On energy spectra and oscillator forcoa in single valence atoms
WORCE: All LztSSR. Izvestiya,, no. 8, 1963.p 57-U
TOPIC UGS: ShAdingir equation,, single valence atom, potential field,, neutral
atom, single clxrge ions, lithium, atom, sodium itoms, potassium atom
ABSTRACT: The &hr9dinjer equation has been solved for single-vaUnce atoms in two
effective potential fields given by
B S(S+1)
U= -+ (1)
r 2r'
where B - 1 for neutral atomss B 2 for single-charge ionst ate., acd by a seconds
more complicate4 pne given by
U. (2)
Card 1/2

ACCESSION NR: AP~007869
A closed form solution is obtained for (1) and a three-tam recurrence fomulas
represented by a series, for (2), Detailed nvzWrical computations on an electrorda;'
computer are obtained for lithium,, sodium., and potassium atoms and in Isoolectron
series of lithium. The various parameters appearing in the equations for various
enerMr levels are determined from mcperimental 'data. All computations were per-
Lormed. on the BFZZ-1-2 VTs'computer at litviyski~ gosudarstvannogo universitat Im,
P. Stuch1d (4tvian* State University)* Origo art* bass 12 formulas aqd 1 table.-
AS=IATION: none
SUBMTED: 26DecQ DATE ACQ: 220ct,63 =Ls 00
SUB CODE: PH NO. MW SOVs 003 OTHMS 000
CWd

POPOVKIN&, Ritta Aleksandrovna; Ya.L.,
red.; ATROSHCHIM, L. ., tekl=. red.
AGambodial rambodzha. Moskva, lmd-vo "Zimlanie,m 1958- 31 Po
4Vsesoiumnoe obahchestvo po rasprostrananiiu politichookikh i
~a.hnvl&-'z-j--41. Ser.7, no 17). (MTRA JI.-g)
iCamhodia)

GIEBOVA, I.I.,[tran*slator]; ZELENTSOV, V..A. (translator]; IVANOT. Y.Y.
[translator]; NORDYINOV, Y.F. [translator]; UMLIN, N.I.
[tranalatorl;_ZHLUMU..A,Z..I.t;saslatorl; TRIMMOV, V., red.;
DA11ILIKA, A., tekhno red.
[Progress in the restoration of Una national economy of the
Democratic Republic of Vietnam. 1955-1956] Uspekhi voestanovleaiia
narodnogo khoziaistva Denokratichaskoi Respubliki Vletnam
(1955-1956 gg). Moskva, Goo. izd-vo polit. lit-ry, 1958. 271 P,
(MIRA 11:5)
(Vietnam, North--Economic conditions)

JUBOVA. Ivota Ivanovna,- 2UNNUOY. Vaevolod Alekseyevich; IYANOV,
Vladimir Vladimirovich; NIKULII, Nikoley Ivanovich;.gATffAj_
Alln Pe-~rqyua~-OWNIN. I.M., prof. , red.; YU DANG AT, red.;
SPEKTOROT, L.D., red.; ZMENTSOVA, Ye.B., red.; SOBOLETMU,
H.S., takhn.red.
[Vietnamse-Russian dictionary] TletnBmsko-rusakii slaver'.
Sost. I.I.Glebova i dr. Pod red. I.M.Oshanina i Vu Deng Ate.
Okolo 36000 slov. Moskva, Gos.izd-vo inostr.i natsionallnykh
slovarei, 1961. 616 p. (MIRA 14:4)
1. Vostochnaye redaktaiya Gosudarstvennogo izdatelletva ino-
strannykh i natsionallnykh slovarey (for Te.B.7elentsova,
Spektorov).
(Annamese language--Dictionaries--Russian)

SHIFILOV. I.7., pelkovnik; �#4~!'TSXV, A.S., polkoynik, redaktor; IMNDVAWVA.,
TB.I., tokhnichaskiy r' 0
(our country's aviation; a collection of articles frog the perledizal
OVestnik vosdushnago flota* (Review of the Air Yorceli Avlataiia n&-
shai rodiny; abornik statel shurnala "Yestulk vosdusl*ogo flotas.
Moskva. Voon.isd-vo Mintsterstya obor. SSSR, 1955. 365 p. (KLU 9:6)
(Aeronautics--History)