SCIENTIFIC ABSTRACT SHISHKINA, E.I. - SHISHKINA, M.V.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001549610008-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

111-9-13/28
AUTHOR: Shishkina, E.I., Chief' Engineer of the TsY.T~i Industrial Labor-
a ory
TITLE: The Organization of the Technical Operation in the Line Control
Room of the Interurban Telephone Network (Organizatsiya tek hni-
cheskoy ekspluatatsii v lineyno-apparatnom zale MTS)
FERIODICAL: Vestnik Svyazi, 1957, No 9~ pp 19-22 (USSR)
ABSTRACT: This description is based on the experience obtained in organ-
izing and coordinating the activity of technicians and engine-
ers by means of a definite distribution of duties and utilization
of their professional capacities and time in a line control
room of a central interurban telephone'exchange. It is
suggested to assign the maintenance of channels or systems in-
dividually to a determined technician, in order to increase
the personal responsibility for the quality of tests performed
by him. The statistics of communication disturbances for
January and May of 1956, Figure 1, show that a great number of
channels which technicians had to check upon request of tele-
phone operatorsp did not require any adjustment of electric
Card 113 characteristics; the requests were made because the telephone

111-9-13/26
The Organization of the Technical Operation in the Line Control Room of the
Interurban Telephone Network
operators were overworked. Besides, the diagram, Figure 1,
shows that, in a certain line control room, most of adjust-
ments were performed beyond the limits of the first repeating
section, i.e. beyond the main station. For this reason, a
group of engineers and technicians devised a dispatcher control
system which receives requests for channel tests from opera-
tors, the telegraph control room, the broadcasting control
rogm and from individual telephone exchanges used by enter-
.prises. The dispatcher's room has two-way service communicat-
ionines with all work sites of the technicians. The curves
of the monthly average of man hours spent in a line control
room in January and May 1956, are shown by Figure 2. These
curves are almost the same as those of the number of channels
handled by the telephone operators. Figure 3 shows the mcnth-
ly average of the man hours spent for servicing channels with
repeating systems having open air lines at one of the'operating
points. Figure 4 shows the man hours spent at another opera-
ting point where cable lines are used. It is to be noted that
Card2/3 the curves of Figures 2, 3 and 4 are of the same nature. The

DEMIYANCHENKO. Georgiy Vasillyevich; KIRITIOV, Yevgeniy Vladimirovich:
. red.; KONDRASHIKA's N*M.P red.; SHEM9
G.I., tekhn.red.
[Measuring apparatus used in wire conmunica'u:Lon systems]
Izmeritellnaia apparatura, primeniaemais v -provodnoi sviazi.
Mosk7a, Gos.izd-vo lit-ry po voprosam sviazi i radio, 1960.
101 P. (mTRA 14:3)
(Electronic measurements) (Telephone lines)

FARBER, Tuliy Davidovich; SHISMINA, E.I., otv.red.; PETROVA, V.Ta.,
red.; MA OCR, K.G., tekhn.rod.
[Measuring and tuning of multichannel symmetric multiplexed
communication cables] Izmereniia i nastroika mnogokanalinykh
sistem uplotneniia simmetrichnykh kabelei sviazi. MoBkva, Goa.
izd-vo lit-ry po voprosam sviazi i radio, 1960. 238 p.
(MIRA 13:6)
(Electronic measurements) (Electric cables)

MEDVEDOVSKAYA, B.I., inzh.; SHASTINA, Ye.A., inzh.; GORDON, Ye.Yu., inzh.;
PROTSENKO, I.Ye., inzh.; LITVINOV, V.P., inzh.;_SHISHKjJIA.--&I-,
inzh.; POPOVA, H.E., otv.red.; SALITAN, L.S., red-.; KARABILOVA,
S.F., tekhn.red.
[11andbook for the certification of multiplexing channels in domestic
cable and overhead line communication systems] Rukovodstvo po paspor-
tizataii kanalov otechestvennykh sistem uplotneniia vozdushnykh i
kabelInykh linii sviazi. Moskva, Gosjzd-vo lit-ry po voprosam
sviazi i radio, 1960. 261 p. (MIRA 13:9)
1. Russia (1923- U.S.S.R.) Glavnoye upravleniye mezhdugorodnoy
telefonno-telegrafnoy Bvyazi.
(Telecommunication)

AGEKYAN, T.A.; KAVRAYSKAYA, K.Y.; PLYUGIN. G.A.; STRUGATSKIY, B.N.;
SHISHKINA, G.A.
"-, -
--- . ~ -V
An indication of tho interaction of starivand diffuse matter.
Astron.zhur. 33 no.5:679-681 S-0 '56. (MLRA 9:12)
1. Astronomichaskaya observatoriya Leningradskogo gosudarstvennogo
universitata.
(Stars) (Interstellar matter)

k,7)

LEVITSKAY.A. L.A., SHISHKIIIA, I.D., KONDRATOYDVA, F.I., SUPKO, N.S.
HematoloFicil f:Actore in artificinl circulition [with gummnry in English]
Eksper.khir. I no.9:4---47 MY-JP '58 (MM 11:8)
1. 17, iiiiiirhno-igglpdovntL-liskoe,,o inatitutq okgi,'Iri'.qPntRl'noy
khirurgicheskoy npparatury i instrumentov (dir. M.U. Ananlyev)
Ministerstva zdrnvookhrnneniya SSSR.
(MRART, ~4rtif.
extrncorporenl nirc., off. of heparin & protamine sulfate
on blood coagulntion (Rus))
(IMPARIN, off.
on 'blood coagulntion in extracorporeal circ. in open heart
surg. (Rus))
(M()T
- AMINES, eff.
qulfnte, on blood conguIntion in extracorporeal circ.
in open heart surg. (Rus))
(BLOOD COAGULATION, off. of drugs on
in extracorporeal circ. in open henrt surg. (Rus))

MM~-',17KOV, A.G.; SHISHKINA, I.D.; LEVITSKAYA, L.A.
Freezing of bone marrow for its preservation atu low tLe--perature
Report no.l. Probl. gemat. i perel. krori 8 no-5:16-22 11,~,163-
OURA 16:7)
1. Iz TSentrallpogo ordena Lenina instituta gematologii i
perelivaniya krovi (direktor - dotsent A.Ye.Kiselev) i Nauchno-
issledovatells.ko.-o instituta eksperimentallnoy lchirurgicheskoy
apparatury i instrumentov. (direktor M.G.Ananlyev).
(T ISS UES-EMERVAT ION) (MU1,W)

ACC
'C\1-6031737 SOURCE CODE: UR/0299/66/000/009/,V1029/M029
I HOR: Shishkina, L D. ; Levitskaya, L. A. ; Lipovetskiy, G. S.
TITLE: Hematological research on transplanting extremitie~Lin dogs
SOURCE: Ref. zh. Biologiya, Part II, Abs. 9M167
REF SOURCE: Tr. 1-go Alosk.mcd. in-ta,--V. 42, 1965, 148-152
TOPIC TAGS: trans plantation, extremity transplantation, dog transplant
A53TRACT: The blood of a dog was studied whose rear extremities had been
30-90 rninutcs after amputation, after -preserving the
extrernity ' r 24 and 48 hours at +2C, +4C after transplantation with 1-45 days and
10
after every 6 months. The changes in the blood pattern during autotrans plantation
Ln both the nonpreserved and in the preserved extremity in 24 and 48 hours were
analogous. During the transplantation of the extremity the blood composition
showed a chan,-e all a somewhat later time and both qualitative and quantitative
~,;cre o'bserved. The author explains this by the immunobiological
reaction of the oraanism to the transplant of foreign tissue and by the effect of the
Card 1 / 2 UDC: 577. 99

-- L-_,-jd:,Q-7--C")7 --- - -- - .--
ACC INR: AR-6031737
6-mercaptopurine, used for inhibiting this reaction. The amputation of extremities
in dogs was accompanied by a decrease of heparin in the blood, an increase of
fibrinogen content and sometimes an increase of the prothrombin index. Theuse
of anticoagulants according to a given procedure made it possible to prevent and
actively conduct therapy of clotting already in process. , [Translation of abstract]
SUB CODE: 06

.C*!-!!

SHISILKINAY I.S~
Carbohydrate-amylase complex in the grain of some varieties
of winter wheat tested at the variety testing stations of
southern Kazakhstan. Trudy Inst. bot. AN Kazakh. SSR. 12:152-160
162. MTRA 15: 5)
(Kazakilstan--2.4heat--Varieties)
(Carbohydrates) -71~ (Amylase)

DARKANBAYEV, T.B.; XAPMSHINAJ G.A.; SHISHKINA,--I.S-.
Baking quality of some varieties of winter wheat of Ka2akhstan.
Izv.AN Kazakh.SSR.Ser.bot.i pochv. no.3162-65 162.
(MM 15--12)
(Kazakhstan-Wheat)

DAFY-~,NBAYEEEVY T.B.; KAPTYUSHINA, G.A.; SHISHKINA, I.S.; AKEMETOVA, N. Ya.
Biochemical and scme technological indices of the grain of the
winter wheats of Kazakhstan. Trudy Inst. bot. MT Ka2mkh.SSR 16:
3-37 163 04IRA 17t8)

GE,LIFPULN, Ya. A., kand. tekhri. nauk; IVANGVA, N. I., inzh.;
SHISHKINA I V.
Manufacturing polyvinyl, chloride finishing and decorative
films. Sbor. trud. VITIRISM no.5:3-24 '61.
(MIRA 15: 10)
(Vinyl compound polymers)

GELIFMAN, Ya.A.; SHISHKINA, I.V..; IVANOVA, N.N.
Extending the life of finishing and ornamental polyvinyl chloride
films. Plast. massy no.12:69-70 162. -(MIRA 16:1)
(Plastic films) (Vinyl compound polymers)

GEL',F!,.'Y't1;, 'Ya.A.., kard, tekhn. nauk; SHISTiXT~,11,, I.V., inzh.
Cc
C -Ioring matter for finishing ara aecorative polyvinyl chloride
films. Sbor. trud. V771INSIM no.7:29-34 163.
"Ini.ohing poi.-,riny! chloride films with a layer of glue. i1bid.:
~ 51 - 1-0 163. (M IRA 17: 11)

!~~ - : z.-. F. ~,- 1.1; '. ? 4 ii, ~~ - - ~--; - ,-, -, : !~. E-14 I , f .1"r, ',~ I M~1~51t~~,-Va*.

SHIS11FINA, K.A., Gand 4et Sci -- (diss) "Data-f-rw.
experimental study of tbe biological prqi--erties of bhe
~,q J,
virus IEV of horses and this
s- ~ -.. --
ic ness.11 Kazan' 1958, 16 i~a. (Min o'L Agr LISSR. Kazan'
State Zoo-Vet Inst im N.E. aauman) 150 conies (KL, 32-58, 110)
- 50 -

c, taued fluorescent, antibcdies fcr d---,ecti::z z-e ~rirus c-F'
!nf,f~zticus ericephalcmyt~Htlss in the brain of rabbits. Uch. zaps
EVI 89:35-41 16,2 .
U s ec. f t he m e L h ,:; d o fI i Lo, re s c e n t an t i bc d les for detecting the
v I - i i s of i n ft i,) u s a q ~ i i n a e n c e pha 1 orry el -; t i 0 il n ir --) s qu J-1 t C e s of
Wit, genu.)
vivas cT Inforl"cun equ~-ne encephalmyelif..3 in
LA
S(FAle cobjects tho e;'Lornal envimnment uning tho ' uorescant
antibody method. lbid.-.95-102 (~-LTRA 18:8)
1. Virusol~).--', :,li;~sFaya labor-atc-4-va (zav. - uref. ~ Z,.Al.'lI'.,,aLrov)
Kazahskcgo vetk--inarnego inst, tu4a.

ka:ld.veterin.nauk; GU-MkTUTDiNCjVA, starshiiy iab,~rant.
the v-4rus of Jnfectlou6 equlnnn- en-ha-,C=le~-Js In Z'-e
L
ticks Dermacentor marginatus and hil-ralorna detri-tum, by the mez' od
of fluorescent antibodies. Uch. zap. iOlI 89:55-59 162.
(MIF-A 18-8)
3. Virusologicheskaya labratoriya (zav. - prof. F.Z.Ainfl-teatrov)
Kazariskogo veteriparnogo instituta.

a, RAMIT IN*, UV K V"') K, Y! G , VS I i i ~' I I k I N A , K . A
p
InLibitive effc~ct ol" somr -rganoi.hoc-phorus co".-Pounds or I.
foot-and-mouth disease virus. trudy Kaz. gos. med.
inst. 14:14--l-14.2 164. ("-apu~ 1,0:9)
1. Virusologicheskay-a laboratoriva (zav. - prof. F.Z.Am'Liteatrov)
Kazanskogo veterinarnogo instituta i kafedra farmakologii (--av. -
dotsent T.V.Raspopova) Kazanskogo me-3--itsinskogo instituta.

L 1036 EVIr ';L)jgWA
-0-
ACC NRt APS028191 SOURCE CODE: UR/0346/65/000/009/0017/0019.
AUTHOR: Shishkina, K. A. (Candidate of veterinary sciences) w
ORG: Kazan' Veterinary Institute (Kazanskiy veterinarnyy institut).
TITLE: Tissue cultivation of foot and mouth disease'v'irus
SOURCE: Veterinariya, no. 9, 1965, 17-19
TOPIC TAGS: foot and mouth disease, veterinary medicine, fluorescence, virology,
antigen
ABSTRACT: Five strains of foot and mouth disease virus isolated in the Tatar ASSR in
1962-1963 (strains 1, 5, 14, and 15 obtained from cattle and strain 12 obtained from
swine) produced a cytopathogenic effect in cultures of swine and bovine renal epi-
thelium. Strains 1 and 5 grew vigorously in a renal tissue culture from rabbits 10-
-24 hours old. The indirect method of fluorescing antibodies permitted visual detec-
tion of the fluorescing viral antigent2after 10-18 hours in cells of all the afore-
mentioned tissue cultures. Observation of the interaction of the virus and the cells
under the luminescence microscope for 120 hours revealed that the v:L-,us antigen gra-
dually accumulates in certain parts of the cells, an indication of the strict speci-
ficity of the luminescence.
SUB CODE: 06/ SUBM DATE: W ORIG REF: 002/ OTH REF: 002
UDC: 619 : 616.988.43=093.35
Card

SHISHKINA, L.A.
Effect of the cover crop on the water cycle, growth, and development
of red clovar during its first year of life. Izv. Kazan. fil. AN SSSR.
Bar. biol. nauk no,5110-34 156. (MIRA IOt6)
(Tatar A.S.S.A.-Glover)

SHL-;riKIDIA, L.A.
I Mezlidu
hYarOlOgical profile.-, in jie region of Tuapse. nar
geofiz.god no-3:126-134 161. O-IFRA 14:10)
1. Tuapse Marine Hydrometeorological Statioh,
(Black Sea-Hydrology)

SOV/180-59-3-17/43
AUTHORS; Savitskiyr. Ye.M_ Tylkinag M.A. and Shishkina, L.L.
(Mosc3w)
TITLE: The Phase Diagram of the Tungsten-Rhenium System and
Properties of its Alloys
PERIODICAL; Izvesfiya Akademii nauk SSSR, otdeleniye tekhnicheskikh
nauk, Metallurgiya i toplivo, 1959, Nr 3, pp 99-107(USSR)
ABSTRACT: Microstructural and X-ray investigations were used as
a basis for constructing the phase diagrams Nlelting
points, hardness and microhardness of the various
constituents were measured. The resulting pliase
diagram is given in Fig 1. Microstructures are shown
in Fig 2 and 3 and X-ray photographs in Fig 4. There is
a solid solution (a) up to 45% Re near the alloy melting
point, falling to 321,0; at 1100"C. In this region
hardness increases with increasing Re content to 420 kg/
mm2 at 2550* Re~ A peritectic reaction takes place at
28900C. Liquid The a phase has a complex tetra-,
0.52.
gnal lattice with a =-9-53A, c = 4.95A and c/a =
a
This phase extends from 40 to 66 wt % Re at 1100 C and
from 45 to 66% at 20000C. It is very brittle and has a
hardness of 2000 kg/mm2. The solid solution of tungsten
Card 1/3 in rheniLm extends to 15M W near the melting point and

sov/18o-59-3-17/43
The Phase Diagram of the Tungsten-Rhenium System and Properties of
i-ts Alloys
127; at 1100'C. There is a eutsetic between.the a phase
and the P solid solution at 75% Re and 2815 C. The
microhardness of the eutectic is 800 kg/mm2. The two
phase region (P + a) is very narrow. There is a
peritectoid reaction as follows, a + The X phase
has parameter a = 9,57A and is of the a-Mn type. Its
micr-ohardness is 1500 kg/mm2. Alloys with up to 20% Re
have high electri-cal -resistance, strength and plasticity,
Fig 1 shows the influence of temperature on prdperties
and Fig 5 the influence of Re on strength. W-Re alloys
could be used in the electrical industry. Fig 6 shows
the external appearance of electrical contacts after
corrosion in moisture. Re after 50 days (a) is in much
better condition than If after 30 days and (b) W-Re alloys
could also be used in industry where high mechanical
properties and close tolerances are required. There are
Card 2/3 6 figures.. I table and 11 references. 3 of which are

SOV/180-59- 3-17/43
The Phase Diagram of the Tungsteri-Rhenium System and Properties of
its Alloys
English, I German, I Polish and 6 Soviet.
SUBMITTED: February 7, 1959
Card 3/3

Determination of the solubW4 of =hydrawmeiminbiter, j
/,"If the alkali meLds by meaas 01 MF
ged aU)U--5.Tti, V 2,
rf,

LAPITSKIT, A.Y.; SHISHKINA, L.N.; PCH91KINA, M.A.; STZPANDV, B.A.
Tracer study of the solubility of anhydrous metaniobates of
alkali metals. Zhur. ob. khim. 25 no.10:1862-1866 S 155.
(MIRA 9:2)
l.Mookovskiy gosudarstvennyy universitat.
(Solubility) (Alkali metal metaniobates) (Radioactive tracers)

L.V-~Jllf~HXI::A, L : NIYY and T I DEITNA
"Develoment of Gas Absorbers for -agmetrons" froT Annotations of
',,7orks Comleted in lc')55_at the State Union Sci, Res, lust: I/dn. of Radio Engineerin
Tncl.
So: B-3,080,r,64

ACC NR: AP5027179 SOURCE CODE:
UY q L/
AUTHOR: Shishkina, L. N. Berezin, I. V.'
ORG: Mosco
universitet
7
gosudarstvennyy
TITLE: Relative reactivity and kinetic isotope effect of the hydroxyl hydro en atom
of 2,4,6- utylphenollin the reaction with free methyl radicals "j-9
SOURCE: Zhurnal fizicheskay khimii, v. 39, no. 10, 1965, 2547-2552
TOPIC TAGS: tritium, hydrogen, free radical, hydroxyl group, heptane, phenol,
methane, chemical reaction
ABSTRACT: Using the method of competing reactions, the authors studied the relative
reactivity of the hydroxyl hydrogen atom of 2,4,6-tri-tegt-butylphenol in the rea-
ction with methyl radicals in n-heptane. The standariTera-ction chosen was the
well-known system kCH
CH3 + C7Hl6 CH4 + C7H,5',
CH3' + C7Hl5T CH3T + C7"115.
In addition, the following reaction took place:
CH* + R & OH CH + RO'.
where R stands for 3 OH--4 4
1

L 10509-66
ACC NR: AP5027179 C(CH3)3 -0
(CH3)3 C
C(CH3)3
Values were obtained for the relative rate constants of the reactions involving the
detachment of hydroxyl hydrogen atoms (kOH/kCii) and tritium atoms (kOT/[-.CH) of 2 4AU
6-tri-tgmD-butylphenol by the methyl radical in a-heptane. It is shown that kffl~k""
and Or/10 are independent of the extent of decomposition of acetyl peroxide and of
the concentration of the butylphenol. The temperature dependence of kOH/kCH shows a
deviation from the Arrhenius law. The value of the hydrogen-tritium kinetic isotope
effect kOH/kOT of the hydroxyl hydrogen atom of the butylphenol in the reaction with
the methyl radical was determined. Orig. art. has: 2 figures, 4 tables, and 6
formulas.
SUB CODE: 07 / SUBM DATE: 09Feb65 / ORT.G REF: 010 / OTH REF*. 011
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SHISHMI A, f nu
USSR/Cl=istry - Hydrogen B=d Jun 49
Chemi.--try - Dispersion
~Tcnbimtlcr, Disilersien of Light in 11.14-ghor XWW~ols and the Problan of the Hydrogen
%indain V. T. !"Plyohav, ShloWna., Mys In k-enl Lebedev, Acad &ai USSR, 3 3/4pp
'Inulk SOOR" V(.,.l L'~.TV, NO 5
i:Sioz: cc-bln-.~tion opcctx~-, cif to~m monatcnic alechols ft-om metby2 tc. cetyl
.--tcohol I_c'r vn-T-ioun results. Sult-Itted- by 'cad G. E. UmidsLvrg,
13 '!:x 49.
1-1 51-0/49-T26

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j T, IK I V
50
the '-ssociatilon --f 3~_ries of Satvratp_,J, Alcohol:-, by t'~e Vet~ord
of Col-abinatic-n Scatterimp- of Li~ht," V. I. I!alyslhev, Shishkina, inst ir-Ic-n!
Acad Sci USSR, 7 rT,
"'hur Eks-,er i T~ore~ Fiz" Vol
Io4
Fresentus r.C- S-,jIl S tT!,' 4 `nn sca of rnonoat=ic alcohol
I~es orl srectra of combinat- _tter1
for various tc-2~peratures. Cbser--.-es that, in spectra of tul-ese alcohols, oscillation
I)nrd of GE r-rour I-osses~-,es two maacirlmms ,,ith frc_~ ,uencies 3, 40C/cm and 3,63G/cm
ascribed to assoca".1on ard d-1--sociation molecular spectra. Sl~ows relative Intersity
C-1 t'!--.e~_e maximumz i-leien(Js upor. temt7~rature, ard upon magrnitucie and structure of
nydrocarbor, z--.rt of,"' m-lecule. Submitted 20 Arr 49
FA 15-)TI)S

tr Istillation essolin f
Jmvestigation of s t-(I! rout SUak-
han-petroleum. ~G-D.Gal'pern-&CV.Shishkina andM.-
1
2
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I
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.
x
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co.
rV
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Ptrerabalke 26'effi, -Baku. Sept
Aj ~4 A=-
ig5z,: k4d. Yaw
Md.-has. S.S.R.~ 1053, 123-35;- ~ Referal. ~ zhur" Xhim.
-
1954
No
27935
Aromati
il
dr
c
b
fi
d
t
.
.
.
c
o
ar
ons were
rs
,
remove
. .
y
givi: IA n
byzij cg. formnlite friction (Nastyukov
melliod, CA. 20, 498). j7hip fra~tjoas tion of the ga~ollne
iwus catfltd out ill a !I-ni. coluimi,provided with a Levin
head, and d. n. (at various wave lengths), and the spectra of.
combined scatterinj were detd.-da the fractions. Part of,
thefractions were dehydrogenateda4dfreed fro m-ar-orn-atic-s-,
and the coacn. of napht her es, and paraffins was detd, reffacto-.
t
ll
h
me
rica
y. T
e ratio of dimethyleyclollexanes was cheeked
by delydtogenation of the corresponding fractions. by the'
Zelinskff and Kazanskil method (C.A.-26, 77) followed byspti-_
tro
ra
hic anal
is of the
tal
tic-
t
Ana
l
l d
h
d
rc~
ca
es~ -
a
ys
i
e
yza
g
p
y
y
genation . was carried out so as to suppress hydrogenolysis
of cyclopentanes by using Pt-coated C (with~ admixt. of Fe)~
prepd, without pr~dinlinsry,pptn. of the Pt- with HCHO.
The content of aromatk. hidrocarbons in - the. catalYzateS
was detd. by specific dispersion. Theresultsoftbisinvesti-
gation showed the ratio'of naphthenic to praffinic, hydro-
carbons to, be; Co 0.2, CS I.., C1 4.8. Cp 3;5, and Co 10.
-f
b
d
-
e
oun
to,
main components of the, gasoline wem
methylcycldhcxane, srars-dimethyley-dollexane, CYC!Ohex-~
ane, methylcyclopentaue, and trans-dimethyleyclopentanes.
A considerable ripantity 0t hydrindene was belleved.to. be
tpre~ent, M. Hosch

USSR/Chemistry - Petroleum Dee 53
"Raman Spectra of Thianthrene (I), Phenylcyclohexyl-
sulfide (II), and 2,5-Dimethylthiophene (III),"
M. V. Shishkina, Petroleum Inst (Moscow)i Acad Sci
USSR
Zhur Fiz Khim, Vol 27, No 12, Pp 1877-81
The characteristic frequencies of the Raman spectra
of I (in a carbon tetrachloride soln), II, and III
were detd -- those of II and III for the first time.
275T17

SHISHKINA, i,?'. V.
USSR/Chemistry - Petroleum 1 Aug 53
"Individual Aromatic fl~drocarbons of the Gasoline Fraction From Petroleum Occuring
in the Red-Colored (1) Stratum of Nebit-Dag", Acad A.V. Topchiyev, I.A. Musayev',
M.V. ShishkinaY G. D. Galpern, Petroleum Inst, Acad Sci USSR
DAN SSSR., Vol 91, No 4~, pp 869-871.
Investigated the chemical composition of Nebit-Dag petroleum in order to compare it
C,
with that of other Caspian crudes, Found that in the gasoline fraction boiling up
to 1750 , 1, 2, !-,- trimethylbenzene, ethylvenzene, o-xYlene" and m-xylene comprise
52,8% of the total content of aromatics.
272T7

TOPCHIYEV, A.V,, akademik; MUSAYEV, I.A.; SHISHKINA, M.V.; GALIPEO, G.D.
Investigation in the composition of Ifebit-Dag petroleum, Report 2.
Trudy Inst. nefti 4:10-17 '54. (MIRA 8:1)
(Nebit-Dag--Petroleum--Analysis) (Nebit-10ag-Ebrdrocarbons)

TOPCHIYEV,A.V.; MUSAYEV,I.A.; GALIPFM,G.D.; SHISHKINA,M.V.
Analysis of the composition of Nebit-Dag petroleum. Trudy Inst.
nefti no.6:3-11 '55. (MLRA 8:12)
(Nebit-Dag--Patroleum--Analysis)

KUSAKOV, M.M.; NIFONTOVA, S.S.: POKROVSKAYA, Ye.S.; ROZENBRE. L.M.;
TOPCHIM, A.V.; SHISEXIlUp MoVe
Absorption spectrum study in the near ultraviolet region of the
structure and group composition of the kerosene fraction. Piz.
abor, no,30,321-326 157., (MIRA 11:8)
1. Institut nefti AN SSSR.
(Kerosene Spectra)

GALIPERN, G.D.; TISLINSKIY, A.N.; MUSAYN7, I.A.; TOPCHIUV, Aj,; SHISEKINA,
M.V,
Raman spectrum study of gasoline-ligroine fractions. Piz. sbor.
no.3:329-333 157. (MIRA 11:8)
(Gasoline--Spectra) (Ligroine--Spectra)

TOPCHIYEV. A.V.; KUSAKOV. M.N.; KIFONTOVA, S.S.; SUCHKOVA, A.A.; SHISHKINA,
KOVO _ I-- - ~~
Investigating condensed aromatic hydrocarbons from the kerosene
fraction of Romashkino oil. Khim. i tekh. topl. i masel no-9:1-7
S.'57. 10-.11)
1. Institut nefti AN SSER.
(Chkalov Province-~-Petroleum) (Hydrocarbons--Analysis)

GALIPERN, G-D.; SHISHKIIIA, M.V.; SHCRETSKO, M.I.
-,-, ~ '
naphtE6n'6-
and paraffin hydrocarbons in
Light
petroleum. Trudy inst..nefti. 10:59-73 157.
(Surakhany 'reg'ion--Petroleum)
(Paraffins); (Naphthene)
ordinary Surakhany
(HIRA 11:4)

1 60V/65_5S_q_1-/16
-2 ~' 0 -1 SI~Jir~;.ZGV, A. I,'; Vakhabo~ra, Kh; Sbishkina, LI. V.
T I ~_'IE Mondensation of Aronatic Hydrocarbons witE a oily
racLion o-' Cheleken Petroleum. CILCondersirovannyye
romatichesk-iye uglevodorody legkoy maslyanoy fra~-tsii
6hele'.-ensl,wy ne-I ti)
P-~,'-,TODjCAL: Xhimiya i Tel:hnologiya Topliv i Easel, 1958, iir
A- A . 9,
pp 13 - 18, (USI;R)
,~-DSTRACT- The possibility of using the p~-crate method for separa'Cing
the c o mde n s ed aromatic hydrocarbons from the light oily
'Paction (300 - 37000) of Cheleken petroleum was investigated,
well as the utilization cf thte obtained analysis data
__JLnd ultra violet absorption spectra. A number of tricyclic
and ~ri-substituted dicyclic aromatic hydr6c~Lrbons were
separated. The method described by T. Cosciug (Ref-B) and
improved by S. S. Nametkib et al. (Ref. 9 a-ad 10) wt~ks used.
6.8 kg of the oil,separated from the crude petroleum of
two oil wells (67 and 60) from the Cheleken region,was used
as raw miterial; its boiling point was within the limits
of 300 - 3700C. The oil was distilled into ten-grade frac-'
tions and each narrow fraction was treated with picric acid.
The separated p~crate aas dried on a filter paper, re-
Cr.trd 1/3 crystallized several times from ethyl alcohol and weil-hed.

Aroni,)~tic llyd-r rbons -.,-7ith a Li!7h'L Oily Fraction of
11-ion o~
lel: e -o Petroleum.
Results o-'-" this process are ~-iyen in Table 1. Dh.- -,Jcrates
,-;e- L
- ce t'ien decomposed -:1th A 3;~i~ alkali. s' o 1u t i o n
ard the separated oil extracted with ethyl ether. sifter
sev--tration of the ether the oil was distilled two to
three times over metallic sodium and narrow 1~'r,_-..ct ions
t_-,1:en off. The physico-chemical constants of the sepa-
rated aromatic hydrocarbons were then defined. The ultra-
violet alo-sorption spectra (2,900 - 3,800 AO) of some
ractions nere investif-ated in a quartz spectro-raph
I rarils ol-f,
and recorded on a microphotometer; micropnotof,-
those fr-tctions are shown In Figs. 1 and 2. The phvsico-
ol-,emi-cal constants of the fractions are ta-,)ul-,.ted M.,)Ie
2 -.3: mic-cophotograri of the absor- )tion spectruc,
o-f tne ~,rthracene. During, the recrystailiza'L;ion o--f'
~Pic-rates of" -Cractions a LTum-forminr- mass sefj5,r,--71'ted.
IL is possible tnat t-1-iis is due to the ps~rtial oxidation
or decomposition of the picrates. It is 'Kno-.i n t hL -. t
antt'cracene and its derivatives are comparatively easily
oxidised and tnat anthraquinone and othe-r substances
-:1.re formed. The aut'cjors concluded Mcc~t t!L-~e picc,_--te
met1-od is suit'able for sep-:,.ratin- tricyclic condensed
kjard 2/3 L,

Conden-"ML-ion of "'rom Lic -Yd~,oca,`, ons Oily 2r.tetion
t ic hy.Troc, cbon, 'ro!.i
~Po 'L r C lou,"'! ne presorcc~ of,
~_-,-jd a1sc of t-i-substlt-u~,-ed
The ultra_- .-viol.-- t spectra
ur,,,~sonce o-T an-1-.1,raccrie and
r,,.c t j- n - .TI-lepe a77e
3
riz-140h, 10 6oviet fLrid
"-lie licht oil~T `r- c t 1 o-,,- o-'
p1lier.'anth-rere, ---n.1 it-s hwolo u, o s,
miphthaleiiej ~Ia,.- coziCir:~.ed.
e used for ecta-blishin.- - the
n -U_ S
Lt-s ho, oloj. in some 0-r t,tle
2 Tal)les an~ 14 -n-
1 Germen.
Tnstitut Khimii Tur',I-mens.coy 6SR (Inst;itvte o-f 'hemistry
of 'Ll-Le Tur'4:m;en SSR)
I.. Petroleum--Fractionation 2. Hydrocarbons--Separation
3. Picric acid--Performance 4. Spectrographic analysis
C~a-rd 313

139
M. V.

T T of -,!~Ie Hydr
_O,;arDCzs of, the Indan

4 C"a 1,
_--a ol e Range
P-R7 ~D7 CAL: T-V~Z_~4ya A' SSSR. Se-,,-*Ya fi,icheskaya, 1959,
nau:_
7ol 23, :7-- 10, 1 2r-1 (USSR)

A CT 3y raeans of infrared and Raman analysis indan. and ita me-,hyl-
ated hoDmologues were fcuqd in a number of petroleur. fra,,tiots.
in order to obtain eyao' -harac-'Ieristic-g of the indan 1-O.Tao-
'~~---ues, th,~ hyd~-:,.2a_rbcr._s --f indan were 3ynthetized with one,
- I
I
-vc, and 3ub5-,i-.u,~nts of various Structuresa' the
'~himll*. r..=f--' Ins`tuta ii-eftekhimicheskogo sl-'eza
AY SSSR (Laboratcry I-r PPP-.roleu.,..i Chemistry op 'he Instlt,_-t~-
v
Lor The Petrel eum-chemical Synthesis of the kS USSR) . By means
of a -ohotoelectr! , spectr,-Dhct:)me-.er the absor-ot4.on spectra of
.he solutions of indan and 141 of its derivatives in isooctane
re invest4gated. The absorFtion spectra of ethyl-, .'scDro--
terrar,, lcuty2-., -i-soam-yl-, and 2-ethyl-hexyl
pyll-
isobutyl-
,
,
indan all had bands w~lth maxima at 2_76r, 2710, 2660, and 2630
This shoTed that the speot_ra rere practically indezendent of
d I
the structure of the subst't,,~_en- if the latter was saturated.

~-_b s o rt i o n S o e c i ra o f t h e Hyd ro r; a rb on s o f t h eSOV/,48-23-1 0-31139
ir.dan Series in the !.ear Uitraviolet RasnSe
The absorption. spectrum of oy3lopentyl-indan was found to b--
shifted in the direction of longer wave lengths by 110 - 1: 2 as
compared to that of ;i.-alkyl indans, which is a consequence of
"he naphthene characte.:- -)-F* tile substituent. The spectra of the
2--hexyl indan and isobutyl iadai-- are practically equal, tc that
of 1-methyl indan (maxima at 2735, 2665, 2605, and 2545 1)- in
the following the spectra of the di-substituted indans with
ethyl--, isopropyl- and isobut-yl groups in the benzene ring, as
well as -rhose of the trisubEzitute d 4ndans are briefly d~s-
cussed. In conclusi'~Dn -3 -a4 d that the distribution of the
intensities in the absoTpt
tiz)n bands does not depend on the
structure of the substituting groups. There are 9 reference3,
6 of which are Soviet.
ASSOCIATION: Institut neftekhimiche3kogo sinteza Akademii nauk SSSR (Insti-
tute for Fetroleum-3hemi3al Synthesis o--:' the Academy of
Sciences, USSR)
Card 2/2

50)
AUTHORS: Topchiyev, A. V., Academician, SOV/20-125-2-28/64
Mamedaliyev, G. M. I Shishkina, M. V.,
-
-
Anikina, G. N., Kisll-
n
skiy,
TITLEi Catalytic Conversion of Cyclohexene Into Tetra-Alkyl-Benzene-
and Dimethyl-Naphthalene Hydrocarbons (Katalicheskoye
prevrashcheniye tsiklogeksena v tetraalkilbenzolInyye i
dimetilnaftalinovyye uglevodorody)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 2, PP 341-344
(USSR)
ABSTRACT: Several investigations have been made into the monomeric
fraction of the reaction products of the reaction mentioned
in the title (Refs 1-7), the polymeric products, however,
have neither been studied, nor has been elucidated the
reaction mechanism by which they are formed. In the paper
under consideration the authors present the results obtained
on the dehydration of cyclohexanal and on the catalytic
conversion of the resulting cyclohexene on alumo-silicates.
The work consists entirely of an experimental Dart. From
the results it was obvious that there is no essential
Card 1/3 difference between the conversion products of cyclohexanol

Catalytic Conversion of Cyclohexene Into SOV/20-125-2-28/64
Tetra-Alkyl-Benzene-and Dimethyl-Naphthalene
Hydrocarbons
and cyclohexene. At 2000 the dehydration of the former
occurs without any noticeable transformation of the
cyclohexene thus produced. A further temperature increase
directs the process towards isomerization, cyclohexene
polymerization, and the reaction of hydrogen redistribution.
The catalyzed substances from experiments at 3500 and
atmospheric pressure vare separated into a monomeric and a
polymeric fraction. The monomeric product boils out at
46-1000 (Tables 1, 2). The unsaturated hydrocarbons account
for 20.2% of it. About 76% of the fraction boils out at
70-730. The product (according to the Raman spectrum)
consists of more than 75% methyl-cyclopentaneq some
20% methyl-cyclopentenes, 4-5% cyclohexanev and 2-3% 0
cyclohexene. The polymeric product boils out at 190-300.1
(Table 3). The main component of the 240-2700 fraction is
1,2-dimeth.yl-naphthalene with admixture of 296-and
1,3-dimethyl-naphthalene. from the*data obtained~ the most
probable reaction patterns (I-VII) are given. The unsaturated
Card 2/3 compounds contained in the polymeric products are incompletely

Catalytic Conversion of Cyclohexene Into SOV/20-125-2-28/64
Tetra-Alkyl-Benzene-and Dimethyl-Naphthalene
Hydrocarbons
dehydrated analogues of the hydrocarbons with a decalin
structure as well as of other alkyl-substituted cyclenes.
They are formed as intermediates in the conversion mentioned
in the title. The results obtained permit the assumption
that the cyclene conversion established in this investigation
may assume vital importance in the processes of the thermo-
catalytic processing of petroleum products and in the formation
of aromatic hydrocarbons. There are 5 figures, 3 tables, and
13 references, 9 of which are Soviet.
SUBMITTED: December 13, 1958
Card 3/3

50)
AUTHORS: Pokrovskaya, Ye. S., Shishkina, M. V. SGV/20-125-6-26/61
TITLE: On Some Alkyl-cyclopentyl-benzenes (0 nekotorykh
alkiltsiklopentilbenzolakh)
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 125, Nr 6, pp 1269-1271
(USSR)
ABSTRACT: It was proved (Refs 1-3) that complex polyalkyl-benzenes which
contain besides alkyl radicals also cycloalkyl radicals can be
produced by the alkylation of methyl- and polymethyl benzenes
with cyclopentene or cyclohexene in the presence of anhydrous
aluminum chloride. The synthesis of' dimethyl-isopropyl-benzene
is described in the present paper. The authors proceeded from
p-xylene and propylene in the presence of the same catalyst;
furthermore, the obtained trialkyl-I)enzene-isopropyl-p-xylene
is alkylated by cyclopentene. The position of the side chains
was determined according to the abs,.,)rption spectra in the
ultraviolet range as far as an i3omerization is possible in the
presence of aluminum chloride. The constants of isopropyl-p-
xylene agree with those listed in reference 4. A reaction
prescription and the properties of p-xylene as initial substance
Card 1/4 are given. A substance with the boiling point of 75' (at 11 torr)
0 %

On Some Alkyl-cyclopentyl-benzenes SOV/20-125-6-26/61
was obtained by fractional distillation at atmospheric pressure.
It does not freeze at -700, The refractive index and the
density correspond completely to those of 1,4-dimethyl-2-
isopropyl-benzene (Ref 4). Figure 1 shows the spectrum of
if3opropyl-p-xylene (Figs 1: 1) with maxima at 2755 and 2670
The spectrum of pseudOGumene (Ref 6) is plotted for comparison,
The rather similar values of the lengthe of the absorption
0
maxima waves and their intensities in both spectra as well as
the total character of the absorption point out that the
position of the side chains in isopropyl-p-xylene is a 1,2,4
one. A condensation of p-xylene with propylene (in equimolar
quantities) leads to the formation of the above-described
1,4-dimethyl-2-isopropyl-benzene with a certain quantity of
the fraction with the boiling point 225-235 0 which has frozen.
The crystals recrystallized from alcohol had a melting point of
36-370 and an empirical formula C. H accordin,, to the analysis~
14 22 0
In the ultraviolet range the preparation obtained was very
similar to the character of the absorption spectrum of durene
(Fig 1: 11). 1,4-dimethyl-2-isop:ropyl-be-izene was introduced
into the reaction with cyclopentene in the presence of aluminum
Card 2/4 chloride which took place under weak heating. Cyclopentene did

On Some Alkyl-cyclopentyl-benzenes SOV120-125-6-26161
not enter completely the reaction. Among other methods,
repeated recrystallizations from alcohol yielded two substances:
(a) (spectrum see Fig 1), melting point 29-5-30-50, empirical
formula C16H24 as fine needles; (b) fine-crystalline substance,
melting point 80 0~ The substance (a) corresponds spectroscopical-
ly to durene. The same type of -the absorption bands of
cyclopentyl-p-xylene and durene is indicative of a structure
of the hydrocarbons produced as follows: 1,4-dimethyl-2-
isoPropYl-5-c.vclopentyl-benzene.0 It is assumed that the hydro-
carbon with the melting point 80 corresponds to penta-
substituted benzene with two methyl-, two cyclopentyl-, and
one isopropyl group. It was, however, found that the spectrum
of the aforesaid substance corresponds to that of dicyclopentyl-
p-xylene (Ref 7). An empirical formula C18H26 was analytically
detected for the latter. It is quite obvious that this is
dicyclopent.yl-p-xylene. It is produced by the interaction
between 1,4-dimethyl-2-isopropyl-benzene and cyclopentene under
the given conditions and with the separation of the isopropyl
group which is replaced by the cyclopentyl radical. The theory
Card 3/4 of the considerable difficulties met in the production of

On Some Alkyl-cyclopentyl-benzenes SOV/20-125-6-26/61
penta-substitutea benzenes containing relatively heavy side
chains is thus confirmed. There are 1 figure and 8 references,
5 of which are Soviet.
ASSOCIATION: Institut neftekhimicheskogo sinteza Akademii nauk SSSR
(Institute of Petroleum-chemical Synthesis of the Academy of
Sciences USSR)
PRESENTLD: January 6, 1959, by A. V. Topchiyev, Academician
SUBMITTED: November 25, 1958
Card 4/4

S/06 60/000/006/019/025/XX
B020YB060
AUTHORS: 1~opchiyev, A. V , 'Mamedaliyev, G. M., Shishkina, DI. V.~
Anikina, G. U., and Kislinskiy, A. IT.
TITLE: Conversion of Cyclenes an Aluwinosilicates. Communication 1.
Conversion of CyclohexenelInto Tetraalkyl Benzene- and
Dimethyl Naphthalene Hydrocarbons
PERIODICAL: Izvestiya Akademii nauk SSSR.. Otdeleniye khimicheskikh rauk,
!960. No. 6, pp. 1084-1093
TEXT: The mDnomeric fraction of the cyclohexene conversion products has
been more or less thoroughly studied in papers by N. D. Zelinskiy and
Yu. A. Arbuzov (Ref. 2), A. F. Plate (Ref. 3), A. V. Frost (Ref- 4), M. V.
Yushkevich-Gaverdovskaya., K. P. Lavrovsk-,y, and others (Ref. 7), A~ A.
Petrov and V. V. Shci.,ekin (Ref. 8), as well as I. A. Musayev and V. V.
Shchekin (Ref. 10)~ These studies have not covered the polymers and their
formation. The article under consideration discusses the results obtained
from the study of the catalytic cyclohexene conversion on aluminosilicates.
Card 114 1

Conversion of Cyclenes on Aluminosilicates. S/062/60/000/006/019/025/XX
Communication 1. Conversion of B020/BO60
Cyclchexene Into Tetraal.kyl Benzene - and
Dimethyl Naphthalene Hydrocarbors
The main factors of the prooes~~ and the chara-3teristics of the reaction
products are indicated in. Table 1~ The apparatus used for the experiments
has been described in Ref. !I. No basic difference was observed between the
conversion producrs cf cyclohexavol- and cy--."ohexene. The total yield of the
monomeric fraction referred to the hydrocarbon fraction of the catalyzate
w-a.,z 57 -- 59%, and that of the polymeric fraction was 40 - 41%. The effects
of temperature, feeding rate of the initial material,, pressjxe~ etc. were
examined. The characteristi~,s of the monomeric fraction are indicated in
Tables 2 and 3. Table 4 gives the characteristics of the polymeric fraction.
The absorption spel-trum. of the fraction boiling between 1900 and 2400C is
shown in Fig. 1, the ultraviolet absor-tion spectrum of the fraction
boiling between 2600 and 2700C in Fig. 2., and,, finally, the absorption
spectra of the fractions boiling at 2400 - 2500C, 2500 - 26ooc, and
2600 - 2700C are 3hown in Fio-. 3. At atmospheric pressure and temperatures
of 3000 - 350CC about 60% of cy~lohexene is isomerized to methyl
cyclrpent,-nes. which are then larSely hydrogenized to methyl cyclopentane.
Card 214

Conversion of Cyclenes on Aluminosilicates, 310621601000100610!910251XX
Communication 1. Conversion of B020/BO60
Cyclohexene Into Tetraalky]. Benzene - and
Dimethyl..Naphthaler-e Hydrocarbcns
About 40% of cy--Iohexene is isomerized, over a dimer, to hydrocarbons of
the decalin- and octalin. series, which are further isomerized,
hydrogenc2ized and dehydrogenized,,, with tetraalkyl benzenes and dialkyl
naphthalenes being obtained as the end products. Basing on the example of
cyclohexene conversion the authors believe t'hat in the refining process of
petroleum products on aluminosilicates the conversion of cyclic,
unsaturated hydrccarbons plays,an important part in the formation of
aromatic and naphthenic hydrocarbons besides other aromatizing reactions.
50 t0.55% of the hydrogen consumed in the conversion process of
cyclohexene serves for hydrogenizing pQlymeric compounds into aromatic and
naphthenic hydrcoarbQns, and 4~fla for the formation of coke-like .
condensation products, There are 3 figures, 4 Tables,, and 24 references:
18 Soviet, ! Japanese, 3 US,, and 2 German,
Card 3,114
Cqj

SHISHKINA, YI.V.; PROKOFIYEVA, Ye.A.; PETROV, Al.A.
tiectron absorption spec of some high molecular weight
aromatic hydrocafbons. Trudy Inst. nefti 14:187-197 6o.
NIRA 14: 5)
(Hydrocarbons-Spectra)

C'.'1 I - 0
AU THOIJ Prokof" yolr% , Yo- A - and" ~,hiLh~,ina
I-L TLE 31actronic i%bso,-ptjon I-, poet C'Jof 11'.~Ianlllolioloruo-~z
11~1110-AG-t- Out'i":1 1 1~)W' 1101 8, 1 W-*"~-5
-2 3 T FLT Tho authork; ro-)ort th~iir iiiaarmremotit.,; of '.h.,) alo(;tronic. ilbsorAiou
spectra of indan and 15 of Its, dari~iati-~Tei. Thoise ~:,Pactr;L were
o~tain3d urzinu- a "Uvispak" spectrophotmao3tor at w.t vale n --ths
2-200 and Z85001~ at rocm. AmonG the indan doerivatives there
---iere ton (~ionosubstitutecd, three disubstitut&d and two trisub3tituted
indans The results are shown in Figs 1-6, in the form of
log where F, is the molar extinction coefficient, po-sitions
0
of the absorption iiia-ima and i..,inima of these. compound2 are liste~l in
Tables 1-4z TI--3 snactrwii of nach ccx;,,%ound i~ diz;c-.-zssod briefly.
There are 6 fit;uros , 4 tables and 32 references , 13 of ahich -are Soviot,
~3 U_`~ T TED July 15, 1937D
-z-

SHISHKINA, M.V.
I-.- -Im*-j ~ddbsorption spectra of n-heptanols. Neftekhimiia 1
no.2:255-~59 1-127-ILP 161. (M-HM 15:2)
1. Inatitut neftekhimicheakogo sinteza AN SSSR.
(Heptanol--Spectra)

KUSAKOV, M.M.; SHISHKINA, M.V.; PROKOFIYEVA, Ye.A.; KISLINSKIY, A.N.;
SANIN, P.I.; TERENTIYEVA, Ye.M.; STEPANTSEVA, T.G.
Investigation of the oscillation spectra of hydrocarbons
of the 1,1-di'phenylethane series. Neftekhimia 1 no.3:317-
328 My-Je 161. (MA 16: 11)
1. Institut neftekhimicheskogo sinteza AN SSSR.

S/048/621'02'/010/005/013
BI 17//Bi 86
AUTHORS. Kusakov, 14. Shimanko, N. A. , Shishkina, M. V. ,
Zimina, K. I., and Siryuk, JL. G. ' "-- -
TIT1,17., III travi olet absorp tion spectra of aromatics
PERIODICAL: Akademiya nauk SSSR. Izvestiya. Seriya fizicheskaya,
v. 26, no. 10, 1962, 1249-1252
TEXT: This paper deals with the rules governing the effect of saturated
substituting groups on the absorption spectra of a number of mono- and
b-;.cyclic aromatics. it has been found that, according to the number and
position of' substitutes, the absorption spectrub of alkyl benzenes is
shifted towards the Ion&-wave region, and the absorption intensity maxima
are intensified. In the case of cycloallcyl-benzenes (naphthene-aromatic
hydrocarbons) with a simil-ar spectrum this shift is related to the sub-
stitution of cyclopentyl groups for the alkyl groups. The structure of
indanes (hydrindenes), wLch show absorption spectra'and which absorb
2-3 times more strongly thar, benzene, can be determinbd by comparing their
spectra -kith those of corresponding alkyl-substituted:benzenes and simple
homologs of indane. The ultraviolet spectra of tetrahydronaphthalenes
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3/04p/62/026/010/005/0'13.
Ultraviolet absorption spectra... B117/B186
(tetraliries) follo-.-i the same. laws its alkyl benzenes, cycloalkyl benzenes,
and indanuL;. Diphunyls and; benzones have different spectra. I-lost m- arid
p-substituted diphenyl hoiriologs are characterized by strong absorption and
by the absence of' L, fine structure in'the bands. The spectra of ortho-
substituted diphenyl are subject to considerable changes. Diphenyl
alkanes and alkyl diphenyl alkanes: The absorption,spectre. of several
diphenyl methanes are similar to those of benzene. -The spectra of aromatics
with condensed rinEs show a specific character. Naphthalene has an
absorption spectrum covering the ran6c 2100-3300 3 and is characteristic
of all naphthalene homolo.gs. As the absorption spectra characteristic of
polycyclic aroma ics are hardly affected by substituting groups these are
suitable"Lor analytical purposes. An atlas (M. M. Kusakov, N. A. Shimanko,
M. V. Shishkina, Ul'traviol~tovyye spektry pogloshcheniya aromaticheskikh
uglevodorodov (Ultraviolet absorption spectra of aromatics), Izd. AN SSSR,
1962) was compiled for the practical application of ultraviolet
spectroscopy. The ultraviolet spectra of mono- and bicyolic aromatics,
I-raphicall, represented on the srume scale and in terms of E = f(?,) or
Y
logr_ = f(,O, were partly recorded by the present authors and partly taken
from publications (;,~7,erican Petroleum Institute Research ProjeA 44,
Ultraviolet Spectre' Data, 1958).
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S/046,/62/O26/oio/oo6/o1,:
B117/B186
AUTHORS; Shimanko, N. A., Shishkina, M. V., Kusakov,-M. M., and
Sidorenko, V. I.
TITLE; Absorption spectra of diphenyl alkane series OAVtrocarbansiin
the near ultraviolet
PERIODICAL: Akademiya nauk SSSR. 'Izvestiya. Sekiya fizicheskaya,
v. 26, no. 10, 1962, 1252-1256,
TEXT: Absorption spectra of isooctane solu6ions of several polycyclic
aromatic and naphthene-aromatic hydrocarbons, C - C -th isolated
.14 321 Wi
benzene rings, were examined at room temperature using an "Uvispek"
spectrophbtometer,, the compounds being as.synihesized by Ye. M. Terentlyeva
et al. (Neftekhimiya, 1, no. 2, 141 (1961)), M. G. Rudenko and Al. A.'
Petrov (Zh. prikl. khimii. 54, 613 (1961)). All the'spectra except that
of 1,1-diphenyl ethane were obtained for the first~time (Figs. 1-4). It is
shown that the spectra of hydrocarbons belonging to the 1,1-diphenyl ethane
series can be well simulated by adding the absorption spectrum of mono-
substituted benzene to that of the corresponding poljsubstituted benzene.
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S/048 62/026/o1o/oo6/o13-
Absorption spectra of diphenyl ... B1 YB1186
The total curves so obtained, representing characteristic spectra of
complex molecules, indicate the number and position:qf each absorption
minimum and maximum. This method is proposed for the structural analysis
1'
of the components of bicyclic hydrocarbons. There are 4 figures.
Figs. 1-4. Absorption spectra in the near ultrAViOlet.
Legend to Fig. 1: (1) 1,1-diphenyl ethane; (2) 1,2.-diphenyl propane;
(a) isopropyl benzene; (3) 1,1-di44-isopropyl-phenyl~-hexane; (6) 1-methyl-
4-isopropyl benzene.
Legend to Fig. 2: (4) 1,2-di-(paraxyIj,~-):--propane; (a) 1,2,4-trimethyl
benzene; (5) 1-phenyl-l-(Daratolyl)-ethane; (6) 1-phenyl-l-(paraethyl-
-phenyl)-ethane; (E~) isopropylbenzene t 1-methyl-4-isopropyl benzene.
Legend to Fig. 3: (7) 1-phenyl-l-(2,5-dimethyl-phenyl)-ethane; (8) 1-phenyl-
1-(2,4,5-trimethyl-phenyl)-ethane; (9) i-phenyl-l-(2,4,6-trimethyl-phenyl)-
ethane; (a) isopropyl benzene + 1,2,4-trimethyl benzene; (10) 1-(paraxylyl)-
2-hexyl-4-phenyl butane.
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S/046/62/026/010/008/013
B117/B186
AUTHORS: Shishkina,-..-M.J.,
Kusakov, 14. M. , and Tsyt ovich, W. E.
TITLEi Infrared absorption spectra of indane series hydrocarbons
PERIODICAL: Akademiya nauk SSSR. Izvestiya. -Seriya fizicheskaya,
v. 26, no. 10, 1962, 126o-1263
TEXT: Infrared absorption spectra'of indane derivatives were analyzed
within the range 5-15 9. Ultraviolet spectra of these derivatives have
been described in earlier papers (14. M. Kusakov, Ye. A. Prokoflyeva,
M. V. Shishkina, Optika i spektroskopiya, 8, 27 (1960)). Spectra of these
compounds from one to three C I - C10 substituting groups displayed several
characteristics that distinguish indanes from benzenes substituted
correspondingly, and which allow of determinin*lk them within the range*
mentioned. Conclusions: The indane spectrum obtained here agreed with
Yublished data (J. Entel, C. H. Rouf, H. C. Howard,"Anal. Chem., 25,
1303 (1953)). The spectra of 1-isopropylene indane And*l-cyclopentyl
indane are similar to that of 1-methyl indane (same reference) but do not
exclude the presence of an i9omer substituted in pod"Ition 2. A comparison
C. Card 1/2 ~ I I I

KRENTSELIV B.A.; SIDOROVA, L.G.; SHISHKINA, M.V.;. KUSAKOV, M.M.; KORENEVSKAYA,
F.V.;.SHCHEKIN, V.V.,
Conversion polymerization of 0~-olefins. Neftekhimiia 2 no.5:
705-708 S-0 162. (MMA 16:1)
1. Institut neftekhimicheskogolinteza AN SSSR.
(Olefins) (Polymerization)

CHERTKOV, Ya.B.;~~HIS4QHA V.; AFANASIYEVA, N.A.
HydroxVl-containing compounds in the middle distillate petroleum
fuels. Zhur.prikl.lchim. 35 no.11:2460-2466 N 162. (KRA 15:12)
(Petroleum 4 'fuel) (Rydroxyl gro-6p--Spec4
tra)

SEMIDOP G. Ye.; ILIINA, D. Ye.; SHISHKINA, M. V.; KRENTSELI, B. A.
Polymerization of trichloroacetal"e n6inlhe presence of
an organometallic catalyst. Dok.I. A 7 no,6.1386-1388
D 162. (MIRA 16:1)
1. Institut neftekhimicheskogo sinteza AN SSSR. Predstavleno
akademikom A. V. Topchiyevym.
(Acetaldeby,de) (Polvmerization)
(Catalys a

KUSAKOV', Mikhail Mikhaylovich; S11IMANKO, Nina Aleksandrovna;,�_~IS~KINA,
'Margarita VladimixD-Yna; BAZHULINY P.A., doktor fiziko-mai~~K._-___
nauk, otv. red.; LOSKUTOVA, I.P., red.; POLYAKOVA, T.V., tekhn.
red.
[Ultraviolet absorption spectra of aromatic hydrocarbonsln Itra-
fioletovye spektry pogloshcheniia aromaticheskikh uglevodor;)dov.
Moskva, Izd-vo Akad. nauk SSSR, 1963. 269 p. (MIRA 16:2)
(Hydrocarbons--Absorption spectra)

SHISWINA, M. V.
"Issledovaniye infrakrasnykh spektrov polistoksonov."
report submitted for the VIIth European Congress on Molecular Spectroscopy, Budapest,
22-27 jul 1963

ADILOV, S.A.; LESHChEVA, I.F.; ILtINA, D.Ye.; SHISHKINA, M.V.; OENTSELI, B.A.
Ghemical-structure of some chlorinated polyolefins. Feftekhiriift
3 no.1:82-89 Ja-F 163. (MIRA 16:2)
1. Institut neftekhimicheskogo sinteza All SSSR.
(Olef ins) (Chlorimtion)
(Chemical structure)

POPOV., Yu.A.; DAVYDOV, B.E.; SHISHKINA, M.V.; KRENTSELI, B.A.
Thermal conversions of polymeric Schiff bases. Izv. AN SSSR.
Ser. khim. no.11:2014-2019 N 163. (MIRA 17:1)
1. Institut neftekhimicheakogo sinteza AN SSSR.

05/003/003/024
S119016310
AUTHORSj Adylovj S# Ajr Illina, D. Ye.# Krentoelto Bo A.j Shiahkinat
M& V*
TIT Yr. i Interaction of chlorinated polyethylene with amines and
ammonia
PERIODICALs Vysokomolekulyarnyye soyedinenila, v- 5, no- 3, 1963, ~16-320:
TEXT3 A study was,made of the reaction of chlorinated polyethylene 9)M-
as
pended in toluene with aniline or di-n-butylamine at 50 - 7000P as well
of the reaction of chlorinated polyethylene. with aqueous ammonia solution
in glass ampuls in nitrogen'atmosphere at 700C. The chlorination of the
high-density polyethylene (m.p. 1320 13500)'was
C (I - 4-15 in decalin at i
made accor ii
ding to a method devised for e chlorination of poLypropylene
(Zh. prikl. khimiis 32p 1404, 1959). Resultes the IR spectra of the
chlorinated polyethylene showed the presence of C-Cl bonds. Chlorinated
products of different chlorine -content were obtained. The intrinsic vis- i
cosity decreased as the chlorine content increased. It was 4-1 at 10% 01
and 0-7 at 60.9% _61* X-ray analysis-showed that the crystalline structures'
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77-j

~8/190/63/005/004/014/020
B101/B220
AUTHORS: Kxentsell, B. A.~ Semenido, G. Ye., Iltina, D. Ye4.,Shishkina,
TITLE: Degradation of polymers containing chlorine. II. Dehydro-
chlorination mechanism of chlorinated polypropyleite
PERIODICAL: Vysokomolekulyarnyye soyedineniyat v- 5, no. 4, 1963, 564-567
TEXT: The IR spectra of chlorinated polypropylene were studied after
thermal treatment at 120 and 2380C. A comparison with the IR.spectrum of
polypropylene shows that chlorine substitutes mainly the H atoms bound to
the tertiary C atoms. Thermal treatment at 1200C had almost no effect,on
the IR sDectrum. At 2380C, however, several bands were observed which con-
firmed crosslinking by intermolecular dehydrochlorination. A discussion of,
the possible reaction processes shows that a radical mechanism is improbahlf,,
since its activation energy, B = 36-5 kcal/mole, is higher than the activa-
tion energy of dehydrochlorinationp E = 8 kcal/mole, and the radical
process sets in only above 1400C- Hence an ionic mechanism is assumed.
The polarizing effect of chlorine induces popit~ive charges at the a ands
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S/19 63/0'05/004/014/020
Degradation of polymers BIOIYB220
C-atoms so that protons are knocked out and crosslinking sets in. There
is 1 figure.
ASSOCIATION: Institut neftekhimioheakogo sinteza, AN."SSSR ~(Institute of
Petrochemical Synthesis of AS USSR)
SUBMITTED: October 2, ig6i
Card 2/2

ALIYEV i A.D.~ ARBATSKI*~`, AV, ";IJISHKINA, M."%: KRENTSELI, B.A,
Sterecsp~lc-.-'f--'-~ r_;'-
-, -.;- -2 -~ ~ !; r,;~ ; . ( K: RA -11 6: 1 -~ )
D o k I ~ All S S M I :: 3 n o . --- ~ , I I - - . .
1. Institut nef'--7,khirp-.!~h~--Aopro -4-jiteza AN SSSR. Predstavleno
ak a&wrp ik or, V . A ~ Ha r , -. n, ym.

TL
L17086-65 DjT(m)/EPF(c)/EWP(J)/t Pc-44/Pn-4 RM
!ACCESSION NR: AP4047685 S/0204/64/004/005~035/07V
AUTHOR: ~T~opchi~yey, A~.V, (Deceased) ;14ushina, Ye. A.; Pete IrjAn- AA'i.S Lih 11-
77-
~TITLE* Relative activity of some monomers in the polymerization eaction on a
chromium oxide catalyst
ISOURCE: Neftekhimlya, v. 4., no. 5, 1964. 735-740
TOPIC TAGS: vinylcyclohexane ally1cyclo-hexane, allylbenzene, phenylbutene,
phenyl pentene, polymerization catalyst.' chrom,iuM,L9xide catalyst', aromatic polymer.
l
JABSTRACT: The polymerizability of monomers containing n~!~hene7and other aromatic-.
!rings in the presence of a chromium oxide catalyst was investigated in relation to T."
t
their structure. The polymerization rate at different emperatures at a monomer
1concentration of 0.0022-0.0024-mole/ml in haptane, and with 10% catalyst by weight?
Iwas plotted in relation to the total amount of monomer and solvent. On the basis
lof these curves, the velocity constants and initial velocities Were.determined.
;The total activation energy was found to be about 12,5 kcal for all monomers even
ithough the velocity values vary over a wide range. -According to the kinetic
.characteristics, the relative activity of the monomer decreases if the naphthene -
ring is replaced by benzene and the vinyl group a proaches the ring: allyleyclo--
p
hexane > vinylcyclohexane > 5-phenyl-l-pentene > 4-phenyl-l-butene > allyl
Card 1/2

a
L 17086-65
1ACCESSION NR: AP4047685
benzene. The relative activity of the monomers is increased by.the removal of the.
vinyl group from the ring because the side chain becomes more flexible and the
orientation of the monomer molecules on the surface of the catalyst favors the
reaction of the vinyl group with the surface of the catalyst. The properties of
the resulting,polymers are tabulated. The relative activity was also increased in
the presence of a chromium oxide catalyst or by the replacement of the benzene ring,~.
with cyclohexane. The isomerization of the monomer, proceeding as a side reaction
parallel to the polymerization in the presence of a chromium oxide catalyst, was
also investigated. The structure of the monomers before:and after polymerization
was investigated by their infra e spectra. With increasing temperature of poly-
merization of vinvicyclohexane the isomerizing effect of the chromium oxide'
catalyst increased. "The authoks express-the-ir gratitude to 1. Yu. Tsarev! t~Ma for
the determination of the glass transition and melting points aC the polymers and.
to A. T. Svvatoshenko.for determining the composition of the isomerization product.
a
by capillary chromatography. T..A. Komov also.took part in the experimental work.
Orig. art. has: 2 figures and 5 tables.
ASSOCIATION: Institut.neftekhimicheskogo sinteza Im.-A. V. Topchiyeva AN SSSR
F(Institute 6f Petrochemical Svnthesis AN SSSR)
1SURMITTED: 02oct63 E N - WAY SUB CODE: GG, OC
!&PF SOV- 007 OTHER: 008

-L 49311-65 EirrWATe(i) pe-4 Rm
IACCESSION NR: AR5012257 UR/0058/65/000/00$/D034/PN914
SOURCE: Ref. zh. Fizika, Abs. 3D254
AUTHOR: Kusakov, M. M.; Niyazov, A. M.; SLdore 0. V. I.; Shimanko.'N. A, iL
Sh.shkina, M. V.
rITLE: Some properties of the. infrared and ul traviolet absorption spectra of
naphthene-aromatic ketones
"ITED SOURCE: Tr. Komis. p6 spektroskovii.
_ALSSSR, vyp. 1, 1964, 370-381
rOPIC TAGS: ir absorption spectra, ultraviolet absorption spectra, naphthene
-aromatic ketone
FRANSLATION: It is shown that-the frequency.157S cm-1 of the.val.ent number for the,
::arbonyl ketone group keeps its value when the 5-member, naphthene cycle is changed
to a 6-member cycle and during the injection of varlous numbers of alkyls -into
iaph-thene and benzene cyclic compounds. The cai~bon~l group affects the freqjency
Df the deficiency number of C-H aromatic nuclei bonds. . In the infrared absorption
spectra a series of characteristic bands was found, which made it possible to dis-
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[A'CCESSION NR: AR5012257
~tinguish between the spectra of these ketones with-5- and 6-member.cycledand,to
identify naphthene-aromat-ic ketones derived from naphthenic acids-. :Three speci-
fied absorption r egions were found in the ultraviolet absorption spectra: 3600-
3500, 2400-2800 and 2200-2400 A. the second region charactterize's the number, posi-,
tion and nature of substituents in the aromatic ketone compound., and the, third--
the presence of a carbonyl group,.the nature~of.the aromatic nucleus and its 'ub-
stituents, and also their nunler and position. This latter-region can be used-for
characteristics of the degree of reduction of ketones to.corr~esponding hydrocarbonsol
SUB CODE: OP ENCL:--00

I.L.; SHISHKINA, M.V.
Structure of the product of silvan polymerization in the presence
of a complex metallo-organic catalyst. Izv. AN SSSR. Ser. khim.
no.6:1095-1101 Je 164. (MIRA 17:11)
1. Institut neftekhimicheskogo sinteza im. A.V. Topchiyeva AN SSSR.

T,TOV , 9,F
Ser, kh,,n.
Izv. AN T,
(MIRRA 18:5)
SSSF
im. V.Topcliyeva AN
za