SCIENTIFIC ABSTRACT SHOGAM, S.M. - SHOKIN, I.N.

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SCIENTIFIC ABSTRACT
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SHDGkM, S.M. Mechanism of the preparation of powder-type insecticides and ways of intensifying their production. [Trudy] NIUIF no-156: 5-18 '55. (%9RA 9: 10) (Insecticides) SHOGAM, S.N. -, BEZZUB, K.Ye. Basic factors determining the quality of DDr dusta. [Trudy] NIUIF no.1506:18-22 155. (.19AA 9: 10 ) (DDT (Insecticide)) SHOGAM, S.M. Degree of dispersion in DDT and hexachloro-cyclohexane powders and dusts. Fractional distribution of the active principle in dusts. [Trudy] 1TIUIF no.156:22-30 '55. (MLRA 9:10) (DDT (Instbeticide)) (Benzene he*xachloride) Devel of a klVed-, jmWiad for dcfenaicatiQn cf -I- 'o W-E-fac'ELI'm ~-I~ il dusts &ad emiched prepdraffor's. M. R" ad F. I., Fen'kava, Trudy, Nauch. Inst. No. two O.IOM CiCU6 m? of 95% RtOH, by Lorliag &tfttly'15-20 tmia4- (2) bath soIns. m cooked and pl.,ictd for 21 hrs. In ke, toptfier wit~i 2 tm lubt% cath cotag, 10 mi. of 0. IN ale, F.'OH. previou-sly freed froal carbMiates by long standiog and c=iuj tion; (3) tha BHC " KOH satns. art snized and both -sly rcir F Ritaken catitinw MO mim.; thm mmptc I i3diAlcn perlodirAy foran addni. 7-5inln.. sampte2farza addni. 4-1-40 min.. without r,=ovias thrun &c.-i Ice. Then 10 :nI. of d2d. (1:3) HKOS is added- t' z--;& samptr- aad the fiberated Cl Ida Is The -isotner 13 from the cq~aiatlarz ~4muw '70 -x 25~3 .74) - 14A wh--l I b the in!. cl O.IA' A-ZINOt Sala, used up in bin-ding Cl ion in sample 2: b being the -a= for mrnple 1. Deviations from thit. data cbWned chrotuato- craphic--ify are 0.2-1.5% for umh. RPIC, 0.5-2.5% for ea- riched prepus., and 0.01--0.167o fuz dtLsm. When ""-ts am rich in CO (> 50%), the equation -y-L-emer % - 24.4 (r-b) - 17 t3 used. 2 referencts. 1. vehm "Idethods of Obtaining Powdered Poisonous Chemicals," by S. M. Shogam and V. 1. Orlov, Khimicheskaya Promyshlennost', NFUT Dec PP 474-VT6- I The authors ran tests on a laboratory scale to determine optimum con-., ditions for pulverizing insecticide materials consisting of the chemical agent and a filler (clay, tale, etc.). The chemical agents used were DDT in combination with chlorotene or with hexachlorocyclohexane. If rod mills are used in place of ball mills, the pulverization proc- ess is intensified and there is less lumping of the product even when liquids are used. The use of rod mills also makes it possible to prepare concentrated powders for use as aqueous suspensions without the necessity of adding expensive surface-active agents such as sulfonol or OP-7. It is only necessary to add 15% sulfite liquor to obtain satisfactory powders containing up to 30% technical grade hexachlorocyclohexane. Preparation of dusts containing agglomerizing fillers such as kaolin can be carried out in rod mills without separation of the product. SHOGAMY S.M.; FENIKOVA, Ye.I.; GAR, K.A.; POSLAVSKIY, YU.M.; GOLUBEVA, Z.Z. ... -- Investigation of fillers and selecticn of appropriate machinery for the production of new organic powder insecticides. [Trudy] , NIUIF no.164:3-5 '59. (MIRA 15:5) (Insecticides) X SHOGAM, S.-M-..; F,NIKOVA, Ye.I.; EPSIITEEYN, T.B. Physicochemical methods for dotermining the _~ -isomer of hexachlorocyclohexane in various preparations. (Trudy] NIUIF no.164:35-36 159. (MIRA 15:5) (Benzene hexachloride) SHOGAM, S.M. - ORLOV, V. I. ; EPSHTEYN, T.B. ; SIDOROVA, S. V. ; YM'KOVA, I.Te. I I Fillers for insecticidal dusts and methods of studying them. [Trudy] NIUIF no-165:36-45 159. (MIRA 13:8) (Insecticides) SHOGAM, S. M. ; OUOV, V. I - Efficient system of producing DDT and GKhTsG dusts. [Trudy] NIUIF no.165:46-51 159. (MIRA 13:8) (Insecticides) 6HOGIU1, s.M.; ToMiclovA, M.V.; LEZINA, T.A.; SUKHANOVA, Ye.N.; KOROBOVA9 I-V-; MAKHNEV, Yu-A- Introducing the kinetic method of determining gamm&-isomers of hexa- chlorocyclohexane in dusts of hexachlorocyclohexane. [Trudy],NIUIY no.165:52-62 '59. (MIRA 13:8) 1. Predpriyatiye khimicheskoy promyshlennosti. (Cyclohexane) SHOGAM S.M-1 SIDOROVA, S.V- DIatribution of the dimensions of particle diameters In povders and the diepersity of dusts by means of air duoting. Eft-U-171 RIUIF no.165;63-67 1599, (MIU 13:8) (Insecticides) T.3. Insecticide powders, duts z;md ~,ranulated insecticic.-~;3. ZhLr. 5 nc. 3:312-317 "CO. (-4:L2. 14:2) (Ins~,-ctic-J&--s) SHOGAM, S- M. _ __ ____ _ Chemistry and technology of calcium arsenate. [Trad-A -VIU17 no.167.-43- 72 16o. (MIRA 13:8) (Calcium arsenates) (Insecticides) SHOGAM, S.M.; VOLIFSON, L.G.; YEFIMENKO, I.A. Method for determining heptachlor in a technical product. (Trudy] NIUIF no.171:49-51 161. (MIRA 15:7) (Heptachlor) SHOGAM, SJI.; YEFIPTENKO, I.A.; AIKIFOROVA, MEPNICHENN, E,L. Chromatographic analysis of heptachlor. Lhur.anal.khim. 17 no.2!260-262 Mr-Ap '62. (MIRA 1r,:4) 1. Nauchny U ,,v instit t po udobreniyam i insektofungisidam imeni Ya.V. Samoylova, Moskva. (Heptachlor) (Chromatographic analysis) SHOGAM, S.M.; ORLOV, V.I.; FFN'KOVA, Ye.l. Mineral substances used as fillers for uowdered insecticides. Trudy IGEM no-95:113-119 163. (MIRA 16:12) _~HOGENQV,,_A.,_ Business accounting in the Office of Grain Procurement. Muk.-elev. prom. 22 no.4:12-16 4 156. (HLRL q: 8) 1. Zamestitell upravlyayushchego Kabardinskoy reepublikanskoy kontoroy Zagotzerno. (Grain trade--Accounting) SHOGIZ6* V.A Some problems in labor organizetion at grain procurement stntiona. Unk.-elev.prom. 23 no.5:8-'.'2 My '57. (MRA 10:9) 1, Kabardino-Balkarskaya respublikanskaya kontora Rosglavzerno, (Grain handling) U F4=TUL, M.A.,, prof.; VASILIYEV, T.V.; IrMROV, G.I.; MASLOV, P.Ye.; RAKBMANOVA, N.V.; KHARAGANOV-4, A.V.; SHOGINA, M.P. Bici-Ilin-3 in the treatment~of syphilis. Vest.derm.i ven. no.11:35-39 161. (MIRA 14:11) 1e Iz otdela sifilidologii (zav. - prof. M.A. Rozentul) TSentrall- nogo nauchno-issledovatellskogo kozhno-venerologicheskogo insti- tuta (dir. - dotsent N.M. Turanov) Kinisterstva zdravookbraneniya RSFSR. (SIPHILIS) (BICILLIN-THKUMTIC USE) BALKAIND2JIIIEV, Rosen, inzh.; SHOILEV, Glora, inzh. Analysis of circuits for decreasing electric-power consumption of welding converters. Tekhnika Bulg 12 no. 10:15-18 '63. SHOILEV, 1. Cabinets for agrotechnic, and zotechnic propa-anda, p.)1. (MA,q-;T',.IT-ZjU~N0 ZM-!E~)ELTE, Vol. 8, no. 5, May 1957, Sofia, Bulgaria.) SO: Monthly List of East Eurooean Accessions (FEAL) LC, Vol. 6, no. 12, Deceraber 1957 Uncl. T r "They 7ntrocluceci Com.~-,Iete ~-.e-hnndzatirn for Cle-n~n--,, Weighinr,, 2nd Transpor-i-7 the Ura-in from the -G(-vfI--ines." P. 37 ('~'coneratilm-o Zemedelip, No. 7, July 111Q, Sofiia, Eulgaria) i:cnthly index of East -1,uropean Accessions (E&AI) LC, Vol. 7, 'No. 11 N I o%r. 19758 ROZHNOV, Vladimir Yev&-onlyevich, kandidat meditsinakikh nauk; BM,IM40V, O.R., redaktor; SHOK, M.M., redaktor; DMITRIYEVA, R.Y., takhnicheskiy redak-tor [Hypnosis and suggestion in medicine] Gipnoz i vnushenie v meaitsine. Moskva, Izd-vo "~nanie," 1955. 31 P- (Vsesoiuznoo obahchestva po raspro!3tranenilu politicheskikh i nauchrqkh znanii. Ser. 3, no. 28) (MLRA 8:10) (RTPffOTISY--THSRkP3CUTIC USX) (THIRAPBUTICS, SUGGESTIVE) SHOKALISKAYA, Z. Yu. DECEASED 1963/1 - -. c. lo,61 GEOMWff -11 SHOKALISKIY, B.V. Projection of a complex image in perspective. Trudy IPI no.18:191-197 163. Solution of certain problems in perspective on an inclinad plane. Ibid.:198-203 (MIRA 17:6) SHOKAN, Menek V. MUDr Kadelungova deformita. Prakt. lek., Praha 35 no.5:115-116 5 Mar 55. 1. Z roentganol. odd. Statni fakultni nemocnice v Praza XII. Pradnosta, doe. Dr. RomAn Blaha (RADIUS, diseases Madelung's deformity) L 21948-66 ACC NRt AP6014628 SOURCE CODE: UR/0242/65/000/008TOO56/0051 AUTHOR: Shokanbaye-~~,',A. N. (Aspirant) ORG: Department of Pathological Physiology /headed,by Prof# I, Ps Mishchenko/, Samarkand Medical Institute (Kafedra patologicheskoy fiziologii Sama kAndskogo meditsInskogo, inst�tuta) TITLE: Tim lapses before the appearance of serological activity after burns SOURCE: 14editsinskiy zhurnal Uzbekistana, no. 8, 1965, 50-51 TOPIC TAGS: antibody, injury, antigen ABSTRACT; The article contains a study of various laboratory animals with experi- mental burns over 9-11% of the body and 10 patlents with second and third degree burn-c (over 10-20% of the body)* Complement-fixing antibodies which reacted non-specifical. 3,y with tissue antigens appeared in the blood in most cases within 3-4 hours after tht burn was inflicted, Selectivity to antigen from the burned skin appeared 4-7 days later. fJ-PR_S7 SUB CODE: o6 suBm DATr!,: 3oNov6t+ ORIG REF: 00_1 Card 11, 2-- NAYMARK, L.E.; CHALYCH, P.N.; SHOKANOV, A. Quantitative apectrographic determination of beryllium and Beandium in products of the treatment of beryllium-bsaring ores. Izv.AN KAzakh.SSR.Ser.met.obog.i og-neup. no.1:85-89 159. (MRA 13:4) (Beryllium-spectra) (Scandium-Spactra) - SHOKAY-)-V,--N. ;-.SHOIY%KOV, Sh. Some Droblems in ensiling feed in Kazakhstan. Vest. 10. AN Kazakh.SSR 16 no.6:8-i,, is 16 (MIRA 13:7) J (Kazakhstan--Ensilage) S/137/62/000/004/029/201 A006/A101 AUTFORS: Yudelevich, I. G.,_ghokar_e_v, JM_ M., Sosnovskaya, T. I., Stanevich, V_ V., Alontseva, N. T. TIME: 3pectrographic control of tellurium production PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 4, 1962, 28, abstract 4G178 (V sb. "Nekotoryye vopr. emission. i molekulyarn. spektroskopii", Krasnoyarsk, 1,060, 126-133) T=: Detailed information is presented on methods of determining Te in semi-products of Pb-manufacture and admixtures in commercial Te. For products containing 0.01 - 0.0%, Te, the' are method of exciting the spectra is recomm,~nded with admixture of 7% Bi(N03)3. To determine high Te contents (up to 10%) spark excitation of spectra is used on a mixture of samples wiP Cu powder in a I : 3 ratio, after briquetting under a pressure of 3,000 kg/cm . To determine admixtures in Te, it is evaporated without a buffer from a carbon electrode crater of 5 mm depth and 4 mm in diameter, Graduation graphs are given. There are 5 references. rAbstracter's note: Complete translation] A. Tseydler I Card 1/1 S/081/62/000/013/009/054 BI58/B144 A 0 3 Yudelevich, 1: G., Shokarev, M. 14., Sosnovskaya, T. I., lt)tanevich, V. V. , ATWnrs-ev-a, ~1. T. TITLE: 1Jjectro.-'raphic control of tellurium production R(!fer,.,tivnyy zhurnal. Khiniya, no. 154, abstract 13, 1962, 13D150 (Sb. "Nekotoryye vopr. emission. i molekulyarn. spektrookopii".. Kras-noyarslk., 1960, 126-133) TzXT: The determination of Te in intermediate products from lead Production and of impurities in tellurium is described. A strong ef ect of the overall compositIon of the samples on the results of the analyses was eotablished. As a result, several sets of synthetic standards are bein,~~ prepz~red . At a Te concentration of 0.01-0.0501fal the sample is diluted by double the amount of carbon dust, 7~'V' Bi bein.- introduced as'Bi(110 3)31 anc. is evaporated from the crater of a carbon electrode 4 mm in diameter and in depth. The spectra are excited for 60 sec in an alternating current arc at 8 amp with an are gap of 3 mm and are photographed on an Vir,!;-28 (ISe-26) spectrograph with'an aperture of 211. For deterimination of Card 1 /3 S10811621000/01310091054 Sj~ectro,:,rLt-111C Control of tellurium ... B158 B144 the ,3ample is -mixed witii copper dust (1:3) and is briquetted 2. C a, The briquette of 4 mm dia. and A -im i n un~ier i pre,,;sure of 3000 kj 0 lit-i'-11-it i.'; Clamped in ton's. The spectra are excited in a high vol take 0 e, I conderised sp~_rl, from ar, qr-2 (IG-2) aenerator at a current of 1.6 amp, self-induction of O.V- im;,,, capacity 0.01 jifarad, ~Luxiliary and an_nlyticai ~;a,, 5mii; the upper electrode is carbon. Industrial samples are used as stE-ndar(lz~. Graphs are constructed in co diriates L-S, log C for low concentlr6.Liono along lines Te 2385-Bi24vf "for high concentrations Tl 2585-Cu 2556 QA. Tile mean analytical error is Impurities in the ' lluriu:,i are determined by lines: Cu 3274, Al 3082, Fe 3057, Si 2a81, and te_ Pb 2B73 ~ ,,iith a line of comparison Bi 2898 ~, Se 2062 with line Te 2070 10L an6 Na 50-a4 with the bac-kground. For the determindtion of Se, type 3 11spectral" t, .plates are used. An exposure of 90 sec is made up from 3 i-M.-itions of the oamples in the channel of the electrode at a current of 16 aulp. For the remainin,~ elements, type" I or 2 "spectral" plates are uued and at the same time a '!Panachromell for Na. The standards and samples are mixed iAth carbon duet (1:1) and evaporated from a Oarbon electrode with an alternatin6 current arc-discharge. The mean analytical error is Card 2/3 S/081/62/000/013/009/054 j 6pectrographic control of tellurium ... B158/B144 I !Abstracter's note: Complete translation 6-ioo -1 I I .. i !I -. Card 3/5 VRUBLEVSKIT, V.I., inzh.; KRYZHANOV-SKIT9 O.M., inzh.; fANASYUK, L.S., linzh.; RAVICH, K.S., inzh.; SHCHUR, A.G., in*.; GARNAZHENKO, ::1-.0.., inzh.; LEBEDEV, Te.I., inzh.5 FSAREV, A.M., inzh.; SAIATSINSKIY, VS. . inzh.; SHOUREV, V.A., inzh. Over-all mechanization and automation of the compsition of charge. Mashinostroep#e no.6W-47 N-D 162. (MIRA 16:2) 1. Institut liteynogo proizvodetva,AN UkrSSR (for Vrublevskiy,Kryzhanovskiy,, Panasyuk, Ravich, Shchur). 2. Toretskiy mashinostroitel'nY.V zavod' (for Garnazhenko., Lebedev Psarev, Salateinskiy, Shokarev), (Cast iron-Metallurgy~ (Automation) SHOKH, B.P. Strentococcal antihyaluronidase in rheumntic fever in certain other disenses in children. [with sunmnry in English] Pediatriia 36 no-7 38-43 Je 158 (MIRA 11:7) 1. Iz kafedry fakulltetskoy pedintrii (zav. prof. P.A. Ponomareva) II-go Hookovokogo moditainskogo Inatitutn imoni N.I. Pirogova (dir. prof. O.V. Kerbikov). (RHEUMATIC FFVF,11, blood in, streDtoc, antihynluronidnee (Run)) (PURPURA, in lnfnnt nnd child, blood strentoc. antihyaluronidase (Rua)) (TONSILLITIS, blood in streptoc. antihyaluronidnse activity (Rua)) (HYALURONIDASE, antagonists. blood streptoc. antihyaluronidase activity in rheum. SHOMAN, N. Training is a pledge of victory. Kryl. rod. 15 no. 4:13 Ap 164. (MIRA 17:5) 1. Starshiy inspektor-letchik UP-avleniya aviatsionnoy podgota,.rki i aviatsionnogo sporta TSentralluogo komiteta Vsesoyuznogo do~'-,-ovollnogo obshchestva sodey.Lviya armii, aviataii i flotu Sm. SHOKW, N. A hard nut. Kryl. rod. 15 no-5:21 MV 164. (MIRA 17:8) 1. Starshiy inspektor Upravleniya aviatsionnoy podgotovki i aviatsionnogo sporta TSentrallnogo komiteta Vsesoy-uznogo dobrovollnogo obshchestva sodeystv-iya armii, aviatsii i flotu. SHOOPON, N. Under the banner of the All-Union Volunteer Society for Assistance to the .4--my, Navy and Air Force. !Cryl. rod. 15 no.12~-17-18 D 164. NIIRA 180) AT6034090 SOURCE CODE: HU/2502/65/044/003/0327/0340 r, AUTHOR: Kormendy, Karoly--Kermendi, K. (Doctor); Sohar, Pa --Shokhar, P. (Doctor) 5' ORG: Institute of Organic Chemistry, Eotvos Lorand Unive~~,,Y-_Tlro~tvos Zrand 6_0 Tudomanyegyetem, Szerves Kemiai Intezet); Pharmaceutical Research Institute, Budapes (Gyogyszeripari Kutato Intezet) TITLE: Heterocyclic spiro compounds IV. Pfeparation of 2-N-alkyl-, and aryl- spiroxazone derivatives SOURCE: Acta chimica academiae scientiarum Hungaricae, v. 44, no. 3, 1965, 327-340 TOPIC TAGS: alkylation, heterocyclic baue compound - . t;, ABSTRACT: (English article, authors' English summary modified] When treated with primary and secondary alkyl-halogenides in the presence of an equi- valent amount of sodium ethoxide, a 2-11-alkyl derivative is formed from .~.piroxazone~ a compound of acidic character, with a loss of solubility in alkaline media. Alkylation does not take place with tertiary butyl bromide .or ethylene bromide because of a predominance of a side reaction whicfi consumes sodium ethylate. On treatment with tetramethylene bromide, sodium spiroxazonate yields 2-N-bromo-butyl-, and cL,~-tetramethylene-bis-spiroxazone.. On nitrosation, the NH group of the oxazolidine ring undergoes reaction to :form 3'-nitrosamine. 2-N-Alkyl-(aryl)-spiroxazone is converted into the 4-0-mono-acylated when acylated in pyridine,and yields the 3'.;N,4-0- diacetate when boiled with acetic anhydride. The products obtained by 'the'alkylation of spiroxazone and by synthesis from the mono-substituted hyd razine were found to be identical. Orig. art. has: 4 tables. [dylis: 33,5401 SUB CODE: 07 / SUBM DATE: 160ct64 / ORIG PEF: 007 Card 1/1. 1- 7, NIKITIN, A.N.; HIMI, Yu.S.; SHODUREVA, V.I. Pb,ngocytic index in c"mbinad therapy of dysentery. Zhur. m1krobiol.epid. i irman. -no.11:67-69 N '55- (MLRA 9:1) 1. Iz Vologodskago oblastnogo otdeleniya perelivaniya krovi (nach-zasluzhezuqy vrach RSnR A.N.Nikitin), Vologodskoy gorodskoy ob"edinennoy bol'nitsy (glavmyy vrach S.F.Shvarer) i Vologodskoy gorodsko.ir infektsionnoy bolln'Ltsy (glaviW vrach N.D.Denisyuk) (DYSFMMff, BACILIART, therapy, chemother, combined, eff. on phagocytic index) (PHAGOGYTOSIS, in various diseases. dysentery, bacillary, eff. of combined chemother) 'jlV'.K!'AT, L. A. ind A. 3. lll,lebhods of Anal-zing &)c-eri:.riental Data", Izdatellstvo InoStrannoy Literatury, 364 PI, 195'0. r a f F r. A a 6 F F ir so 3326. LONG DISTANCE Hlt'&T SUPPLY. Cite tve riche nko, A. and Shok- .40 Of a. hat, S. (!.a Ekon. Topliva (Fuel July 1961, 6-10). The chief it-vas -00 a to b-e considered In planning thermal powur plants for supplying large 00 r towns are stated to be site and coal;storetee space, ash disposal arranre- .00 00 X manta, return water utilization anti sulphur saparqtion e4ulpmont. It is *0 j concludod that whore coal of high aah and sulphur content has to bo u.,iad '00 go 0 the oowur z)ltknt should be situated well outside thm toym. P:1wor should J - 0 ee j be raised io 260C,00 k.w., and heat supply increased to lUkk =9 a go o P:Q f Do A 1 9 1 t A 41 1 At t bgt6k &t U I I OA I UM I CLOWK A I WN UO 41 it Y- 71 W 6t -N it 1 4 0 0 0 4 0 0 0 0 H01(lHAT, S. A. LS Fuel Abstraots June 1954 Steam Raising and Steam Engines CI) ShOWt, S,A; (Mela. Sta. (pVjr SC8., MoscCAA, Aug. 1953, Val. 2h, 13-171:-Tood rater tempurature for all CYPQs Of high Pressure boilers irrespective or the turbine type should be Y11thIn the range 15(~-19CPC. -At *the feed water tomperatura of 150PC cxlrrlnr, high pressure boilers should pmVIdO the ncm1nal evaporating value preaerying the vxjnlnal sream paremattrs. 11hen FiodIfyInP, a medium preizura power plant for extra high steam parameteiS the feed uater ta,11crature for the extra b101 pressure bollcirs must retain the Value It had In the nedlun pressuro plant. D.E.A- -MCKHINA,Q.-I.; LUCHITSKIY, I.V., doktor geol.-min.nauk, otv.red.; SHALINA, L.V., red.; MAZUROVA, A.F., tekhn.red. [Alkali rocks of the Bulan-kull massif (Krasnoyarok Territory)] Shchelochnye porody Bulan-Kullskogo massiva (Krasnoiarskii krai). Novosibirsk, Izd-vo Sib. otd. AN SSSR. 1961. 68 p. (Akademiia nauk SSSR. Sibirskoe otdelenie. Institut geologii i geofiziki. Trudy, no.10). (MIRA 15:11) 1. Zaveduyuahchiy Krasnoyarskoy kompleksnoy laboratoriyey Institute. geologii i geofiziki Sibirskogo otdeleniya AN SSSR (for Luchitskiy). (Bulan-kull Lake region-Rocks, Igneous) SHOMAN, Ya.D., kand.med,nasak Compression fmcture of five thoracic vertebrae in a -.,:: child with tetanua. Vast. khir. 93 no.12:94-95 D 164. (MIRA 281")) 1. 1z filiala Novosibirsko o nauchno-issledovatallskov(, ,)rf.opeiii i tramatologii Mr. - K.G.Nirenburg). ZUA~,NOVI NJI..ola-v latrovleh; SIKA(TEV, V.A., rot-senzent;-SHOKIN, _;3, F. . red. [Shutters for aerial photography cameras] Zatvory aerofoto- apparatov. Mloskvao Nedra, 1965. 84 P. (MIFLk 18:8) 7" *,'I! T, ......._, -1 . ~-,:Jf,! -, iir,,~7 phv~~ I corri,~chaz-.Acal prrjpert_itoo rf the common sa L t, -,f Lhe Ptokurich6: doposit. Sbar. naucl-_ tmid. UkrllIISol " . - 2~-2(-, 164 (,'-111 18-1) no. I - -v, PROTSEMKOY P.I.; SHONINA., O.N. Specific gravities and molar volumes of the ternary system consisting of the nitrites of-sodium, potassium, barium. Zhur. fiz. khim. 36 no.3:474.--/,.79 Mr 162. (MIRA 17.8) 1. Rostovskiy gosudarstve,-myy universitet. Sq'i I ZASLAVSKIY, David Josifovich; KOVTU11, Yu., red.; PROTSM., L.., mladshiy red.; %IIRNOV, G. tekhn. red. .j I--------- [International significance of the Soviet seven-year plan] Mezhdu- narodnoe znachenie sovetskoi semiletki. Moskva, Izd-vo sotsiallno- ekon. lit-ry 1961. 69 p. (MIRA 14:12) Nussia-Economic policy) BESSONOV, S,A,; VASIL~KOV, N,P,, kand. ekon. nauk; VLASOV, V.A., kand. ekon. nauk;; GLUKHAREV, L,I,, ka-nd.ekon. nauk; DANILEVICH, M.V,, doktor ekon. nauk; ZHAN9N, V.A,, doktor ekon. nauk, prof.* ZAKHMATOV, M,I', kand. ekon. nauk; KURAKIN, N.A., kand. ekon. nauk; PANOV. V,P.1. 5M1RNQY,-ja-V,, kand, ekon. nauk, dots.; TRIFONOV, V-1_ kand. ekon. naukz TYAGAY.,Ye,Ya.; FAMINSKIY, LP., KHODOV L.G., SI-24IDT, G.A., k'and. ekon. nauk dots., SRXIGOLI, N.N., kand. 8kon. nauk, dots., MATSUK, R.V- red.; GARINA, T,D,,, ~ekhn. red., (The asonomy of foreign countries,! the capitalistic system of Y the world economy after the Second World War-)Ekonomika zaru- bezhnykh stran; kapitalistich6skala sistema mirovogo khoziai- stva posle Vtozo:t Mirovoi voiny. Pod red. V.A.Zhamina. Mo- sk-.7a, Vyssbaia shkola, 1962. 632 p. (MIRA 16:1) (Economic history) ZHAMIN, V.A., prof.; GLUEIW?EV, L.I., kand. ekonom. nauk; FUCHKOV, A.N., 6.otsent, kand. ekonom. nauk; FAMINSKIY, I.P.; KURAKIN, N.A., kand. ekono:~. neuk; IVANOV, N.N., kcand. ekonom. nauk; S-JRNOV G..V., dotsent, kand. ekonom. nauk.; VASILIKOV, N.P., kand. ekonom. nauk; VASILIKOV, N.P., kand. ekonom. nauk; LUKIYANOVA, M.I., prof., doktor ekonom. nauk; OZIRA, V.Yu., red.; LAZLREVA, L.V., tekhr.. red. [Characteristics of developing industrial production in capitalist countries] Osobennosti razvitiia promyshlennogo pro- izvodstva v kapitalisticheskikh stranakh. Pod red. V.A.Zhamina. 1,03k-w!, Izd-vo N.osk. univ., 1961. 239 p. (MIRA 15:2) 1. L-loscow. Universitet. Ekonomicheskiy fakulltet. Kafedra ekonomiki zaruoezluVk-h stran. (Industry) is o * ot o * o--q- , 0 0 0 0 0 0 0 0 0 * 0 0 0 0 0 4r-10 0 0 0,10 0 0 0 I I . ; q 1, 1* " 1) 111 it JU )) J7 a x Z$ 26 zy is h III P ij JI 14 Is u j/ a it 4v It 41 41 a C A I. L L t 6 11 4 A. L it It P U Y I It A I I cc IV E( I the fOTia IC&UizAtiOu Aud im i f d h TU e t mt O Demai na t P 4 hhoklim and N A A Wi 1 S f N -00 . . . . . . n, quality o ..d 1939, No. I Kkj"j. Reftral. Zhm,. 1940. No, 5 mt-tea- it, lemp. In parts A a Ital-1; t"i. vw .1vi'l. by liwan, ill Olvilm-mi'l Il Allou, J."int, ill the g~.I-I-- I It.- vulcallixell at 1,541, for 12 mill. The illml It.111, .) flit, gal-sh'. mich the wmp. for Villeallifitioll lully 0 dilting the loll 3 mill, I .his I, ill~mll;,ivlll fin vmli I'lor vilh-111111'a I!,") ililb 1111-1 Ittlilrattl Accelritititt% A 110-1111-1 114,44 drViblItid 14)F Vill zoo W -InitilIK (11c 1111ICT 1141tric imitr%. K 1:1 aud so K-15 at low temps. ( M.'). Aftrr a.3-mm. vulvaou.ittion at 12W the ruhher tuixt. with K-45 mcclerAtor was well The meth.1 irrd,!-, the vAtl-i ii,atimi time .-he. (urmll f2 to I; ill It R. Will, ago Zoo :3*0 clov An I 1 3 'or 14 v 'It a I It 1 AI . - SH OK, H I N mummmmm Z, n. ~ Nature of the structural changes in butadiene rubbers by the action of high temperatures. A. S. Kuz'ininskil, 1. A. Sholchin 'ind R. N(. Belltskay-a. Dokladv Akad. Nauk - k IV-709M.-Undcr c,inditi' S-MT.- -74, 711 on, of rigorous exclu,ion of 0 on hcutins In u high vacuunt ;it '24)11*, the douhle bond content 1) in the lateral chain, (all% linestly with time. the fa,trr the higher the initial D; in 2 different samples of butadirne rubbers, D fell in 122 firs. front M to .A)%, and from 50 to 40 %, ris p. On heating in N* at 13) .and '-M*, the inhibitor (phenyl-0-naphthylatnini-) is con- ~umed only in the initial stages. That this initiale.,oustinij, tion dnei rint depend on the different reictivitio of the dmible hondn in the inain end the side chains is drinonstratt'l hy the identity of its kinetic curves for samples with dif. ferent dioributimis of the dniabe bonds betiveen the nuin and side chains. (hi the other hand, ndUlk!iiOn of U Small anit. of 0 after the consumption of the inhibitor has. cione to a halt gives; rise to renewed fall of the Inhibitor content. Consequently. the initial cnitsuniption of the inhibitor is ([no tn the presence of traces of 0 in the rubber. The linear increase in the modulus of elasticity with time of heating goes on far beyord the ccssatinn of the consumptitm of the inhibitor. N. Thon -N, i ~ "Inv,iostigntion of Structural Chnneet. of RiCober at TpTffp8rtRturp:, of 10!',- 2000.11 Sub ? :,!!iy ~)l, Mosc-ow Inst-of Fine Clic;,licql Tocluiolopy Imeml Lorao-iosov. "issertationn nresente.,l for sclfmnp. and er,~,xlrieering de6r--,PS in Mosnow 19"1. SO: Sum. 'To- 55 stadu of the ruhher tompwent in M sholkbl~ 31-141 'G& ~io~aNsk-ya. I't-udy- Much 17 Rff~ M t: Zhur., KUrn- 1956, Abstr. No.'14291 ~~T=Grtiaa' of, sul. and i~W: fractions obtained from tion. and ,of rubber in rubber materials caa serve as' regeneration- indicator, of, the intcask ' f th Existing mithx. 79 C procem- of detn. of the CHClx ext. are not suitable for this purpose since the calcu. is made on the initial wt. of the regener-ite .0~ ._1 (R) bb fulmixts. A methodl is prvo-ned for, ~ -on- o'% .1 asb 'de(n. aclu by meaat of exti. with CHClj satd. with Ns~ ter a total ellminatio~n of nonrubber-admixtd. Since 4hedt. methods are Inadequate owiuW-t6 the presenct, of C. the kinetics and the legree of swelling vf exe studied for the get traction as well as modulus a-. elasticity. Practically applicable R were Investigated. The results obtained by the --dissoln." -method, ixt higher in ash fraction (40-46%),tltan those obtalneA for R.by th6. method (,f thir~aoswelllng (10-26%),, , from indication the., tire ptbber from SKS,10 ii easier to -re.-werate thrui that: from SKB ~6histous tar bu a 8ttroug reivicrating actlo i trichloratidophenal, a good actlvut6r. mcreases the azntl~? 'the ash fruction with m lower amt. of --ofteners and a e. creased devulkahization tijne~ In the ash fraction remains' :65-70% of the: theor etical no. of double bonds present in the initial rubber. material, - meaning that-imly an insignificant no. of double bonds is *uscd up during regenerition. _~ This'~- has a strong bearing the behavior of R during the f6t lowing vulcanizationj4proctSS- Favestintions; of. fraction TaMica"fMat the spatial net- k' preserved' M" th rubber coin ponent and that the degree of 'qoo=Wg'1 of thO-. net depead'son-thestrerigth-of the attack-during regenem-' Con. P ' Eav 'on of. the technological qojier~tieof reclaimeA i V -1:7- and L. B~- q A. Shokbin a ono, b b ' --h. -Issled"Ied. Insl. Re--sn. royn. 2, 146- - Kb-* -D i 1956 t N &M Zh Ab ur ng; o. n . s r.. . ur., 64; , 500) ! li l d bb k f i th?t on o rec me ru er olf warm o a s (to ' : and, its, elastic. recovery its softness increases up to 30% deri ses up to 80%. The major change &ctirs in thC ea first 10 min. of mastication, being aided by low temps. A: stepwise mastication is recommended or a fast, nninterruptcd,~ blending with simultaneous addn. of plasticizers and di%~- Persing agents. ThIs process aids the mLdng, luiproves'. th-- homogeneity, the uniformity, and the plasticity of thti rubber-rodaini mixts., aud decreases their shrinkago an& mutual adhesion. This change of properties is noted in the! - ; ~ recUms of both natural aud synthetic rubbl~r B. ParaUel J ? %vith the destruction of adso n bonds during the Masti- ~ n r , of inteliual. bondsd ti cation on I le rolLi, u breaki m (gef-_ka "e.- u i In= i9murs, which Is a c6tit' tion. on started of the dc~~ = z at ave., !In the a~utoc The 16s the destruction in. the nutoc LL ve,; fiftensive-is the -masticatlot, Ake, A _ e -a ,-P Jul eneist princl le%4 "i" Vha g' , or ulation G# r-Aubjjg~~ Ining red -'.e T Conta kina. A. L. Untmra. Trudy 1 55, No. 2, 165- 89; Referaf~ Zhur- KU;~i'0956, Abstr. No. SM.-The re- -CL-timcd fflbber (1) ir con~ldefOL43 ft inixti contg. m-bber. do Therubber and 'RWIltniticral fillers, asu in rubb4cr and C black 3 siulilar to the Qf,Vlr& diinto the the W4fal filter is chalk. I= th ' 3-3.5% S'and 1.5-2% org. accelenator.' The C black added to I has the %-.une effect as in naxts, with ortaidal, for- tic rubber. For preservation. ofAhe synthe mulationi the corre"riding Phys.,dictu. ch. uracterisdes :and the technological properties of the mixts., it is r ecom. 4__ mended~ivhen introducing I to talze into consideration its omponents In a ratio 1 * 1. Itil'thIS type:'Of fartiilation',_. I ral rubber for static deformations. When lnulv..to natu the ribber- differ,. the properties of the vulmni~tr_-- :appear to be practically additive d -ding on. their ratio. Nortnally, the expd. values am sUgh y lower than-the calcd. - 'eladtic :This is explained by the fact that the stable and. -tdy- cc th~ i gels of I do not comple imbinc with the rubbei ,causin.-loi~erizigottlietv.~ch.properti6. -Ford, and effincimc fortuations, the mech. propcrtje~s Y_ 13er-1 mixts. are lowered because -of nonho V mat Irom'semp - ' rrno - II A. Stalmovi Skoftv makrialy r-M-M --Txmltc tilm = made by fm't - it lw-lgo*. a mixt. tit aii , i = wute,'15 rcgeaeri~cd Tubber, 6 grQUAd $, iud n - A ~ -mi6cdas Ins- of vulcaalatlaa aticelcratcc- - CorrosiiM t 145--I&Ov 26-W% ~Z sheets W. manuld. by. mixing a - ' 7-12 =% bfituiam and then ceendaina tha Mti ( itt , lar W c is ma& by dwl&- gFrC RellIs' which Is a subber linalaim, he abc~e propardons to 95-30% gMud-rubbef AMP, t1 woGd dma, 25-30 sYu- bitumen, 25-30 asbestos or thetk rubbal Pvop~zrfiea of th.14 mAtULWA ue given. F Sl.,(Ii,TZTII , I. I T 71-'-r -r.'7-,,77; -1 - I . . ~L "Tnv--s'-;~,ation o4' tile technolc :-icLl oualities of reclaimied nbber.,, p. 2L (Leka Pro, -ishlenost, Vol. 6, no. !'-;, 1-9-57, Sofii-a, Bi.,L-aria.) -.o,it,I,,�v Index of East European accessions (7-AI) Vol. 7, 'No. b, June 1958. ROGOV, Nikoley Alekseyevich, ' nKRIII-L-Amommadia-~tor; SIIPAK, Ya.G., tekhnicheskiy radaktor LProceBsing of reclaimed rubber] Proizvodstvo regenerate. Moskva, Qos.nauchno-tekhn.izd-vo khim. lit-ry. 1957. 246 D. (MLRA 10:8) (Rubber) SHDKHIN,_I-., kand.khim.nauk (Moskva); Rubber linoleum. -Prom. koop. (Linoleum) SMIRROV, inzh. (Moskva) 12 no.9:27-28 S '58. (MIRA 11:10) SOV/1718-59-3-8/16 I. A. and Kaplunov, Ya. 'T 12 IL riLlivo-Stage Preparation of Homogeneous _;degenerated Rubber Mi-xtures in a High S~jeed Rubber I-Aixer ( 1"'etod dvukhstad- iYno-o izr-ouovleniya odnorodnykh rezino-regeneratnykh 0 0 Smesey v skorostnom rezinosm-3sitele) PE.LtIUDICAL: Kauchuk i rezina, 1959, Nr 3, PP 33 - 38 (USS~q) aBSTR&CT:Th_e possibility of preDaring homogeneous re-enerat--ed 0 rubber mixtures in a covered rubber mixer b-v chan-ing LD the conditions of iAxin, were investi-.ted art of the e,c-perimen-Us v-.,ere carri ea ouU by O.L. shak)o Glu It was assumed that the-non-homogeneity of rubber mixtures CD containinG regenerated rubber is due to the incorrect mixing of the components. Experiments were carried out on mixtures of tyre rubber prepared from SKS-30A and SY,B-NK mi-,ctures; their composition is given in Table 1. Re~g,enerated rubber prepared from tyre rubbers was added to this mixture (Table 2) in quantities of 0, 15, 30 and 45~6 (Table 3). The rubber-regenerated rubber mixtures were prepared in a 2 litre laboratory mixer. The speed of the rotor of the mixer was '03 rev/min, the friction Card 1/3 1 : 1.19, and a pressure of 6 atm was applied to the SOV/1381 -5Q -3-8/16 Two-Sta~;e _-,areparation of Homogeneous Regenerated Rubber Liixtures in a Hig~_q-Speed Rubber Uixer plunger. Tyre mixtures based on SIKS-30A and regenerated rubber R-3-' were prepared by a one-stagge method. The c ompo sit i,_~n of four different mixtures is r-iven in Table 0 4. Three mixtures based on SKS-30A rubbers con-ta-d-nin- carbon black and batuches pre-oared from these mix- tures, ha-%rin-' similar plu-Stic and elast-ic proDerties as the regenerated rubber R-3~), were tested (Table 6). The comoosit-ion o-f rubbers prepared from these mixtures i_ sho..n in Table 7 and identical ex-Derim-ents urere ca-cried out on rubbar mixtares ba.,--,ed on SIG-11K rubbers,, The -ohysical and mech.~nical characteristics of all tyre rubber mixtures, ~,Ath varyin,,-:, quantities of added regenerated rubber and various m-Ahods of addition, are listed in Table 8. The mixtures tend to become more rigid during the two-sta6-e process than --barin- the one-stage process. 0 Car,_1 2/3 Thi-- is probably due to the better distribution o-f the SOV/1 7;8-~W- -5-8/IG TLvo-Stage PreparaII-ion of HomoCenous Regcneratlled Rubber Mixtures in a I-ligh-Opeed 1--L'ubber Uixer re::,enerated rubber in the mix-tbure. IAicro-ph6tographs confirm that the two-staSe process of mixing produces moie homogenous distribiAuion of the regenerated rubber in tyre rub-Lers. The two-sta,,,e process increases the workability durin-- repeated deformation; this is obvious- ly of :,-reat import.,ince when considering the quality of C~ car tyres. the effect of the addition of various quan- tities of rep-tjnerated rubber R-33 and R-33NB and the iaethod of introducin- them into the mixtures affects the quality of tyre rubbers (Figures 1 and 2). The two-stage method is most suitable when the rigidity of 0 the carbon-black-containin- master batch i~; considerably 0 higher than the rigidity of the uEed regenerated rubber. C.) 'h U ere are 2 figures, 8 tables and 6 Soviet references. ,bard 3/3 SHOKHIN, I.A., kand.tekhn.nauk; KUTSEITOK, B.I. Corrosion-resistant ebonite floor tiles impermeable to mercury. Xhim.prom. no-5:430 Jl-Ag 160. (MIRA 13:9) 1. Nauchno-iseledavatellskiy institut shinnoy promyshleanosti i TSentral'naya naucbno-issledovatellskaya laboratoriya "TSnilkh- imstroy." (Tiles) (Rubber goods) S/138/60/000/012/008/009 A051/AO27 AUTHORS: Tsvetayeva, Ye. M., Sidorova, R.I., Drugovskaya, M.N., Shokhin, I.A. TITLE: Synthetic Softeners for the Reclaiming of Rubber Produced From the Products of Its Pyrolysis PERIODICAL: Kauchuk i rezina, 1960, No.12, PP. 31-34 TEXT: The authors have developed a method for the production of a polymer from rubber oil, which can serve as an active softener in rubber reclaiming. The method also helps to deodorize the rubber oil. Mention is. made of the method presently used in the USSR for the production of rubber oil, containing 90% of compcurids, which react with strong H2SO4 (Ref.2) (Fig. 1). The medium and heavy fractions of the oil contain more of these compounds than -the light ones. Since the oil contains 8011o of medium and heavy fractions with the greater unsaturation, this product can be processed without preLiminary fractionating. The method developed by the authors is described as follows: 98% H2SO4 (12 w.p.) is poured into an apparatus Card 1 / 6 S/138/60/000/012/008/009 A051/AO27 Synthetic Softeners for the Reclaiming of Rubber Produced From the Products of Its Pyrolysis equipped with a mixer and a jacket in which the rubber oil (100 W.P.) is vigorously mixed for 20-30 min, at a temperature of 10-250C in small portians, Then the mixing continues for 2-3 hours more at the same temperature. After holding 4-5 hours the acidic petroleum asphalt is let out of the apparatus and the remaining oil is processed a second time with H2SO4 (10 w.p. based on ache initial oil). The second asphalt let out after holding of 16-20 hours is mixed with the -Pirst one. The purified oil is washed with hot water 3-4 times and is neutralized with a 0.5~o solution of NaOH at 60-700C. Then a second washing with water is done. Due to "this processing an oil is pro- duced with an odor of kerosene. The water is separated from the oil by heating for 2-3 hours at 80-950C. The formed acidic asphalt is washed 4-5 times with hot water and is then neutralized with a le. solution of NaOH at 60-700C, whereby the alkali solution is introduced in 4-5 portions. Each portion is about one quarter of the asphalt volume. The reaction of the last rinsing water should be neutral or weakly acidic. The obtained organic Card 2/6 S/138/60/000/012/008/009 A051/AO27 Synthetic Softeners for the Reclaiming of Rubber Produced From the Products of Its Pyrolysis mass (subsequently called polymer) contains up to 4001fo of emulsion water, the main quantity of which can be separated after heating for 3-4 hours at 90-950C. In order to produce a well-deodorized polymer, it is suggested distilling the volatile components at 130-1400C. The described method can be recommended for industrial use. The polymer yield was 46% and the deo- dorized oil 43% of the initial oil. The deodorized oil as compared to the non-processed one has a lower iodine number and contains less sulfur. The increase in the molecular weightq viscosity, specific gravity and relative content of heavy fractions when processed with sulfuric acid points to the fact that the deodorized oil contains also polymers in addition to unchanged components of the non-processed oil. The latter differ from polymers passed into the asphalt by lesser polarity and unsaturation. A conclusion is drawn that when processing rubber oil with sulfuric acid together with other processes dehydro- and hydropolymerization take place (Ref.3). It was also seen that the deodorized oil contrary to the initial oil contains sulfur in the form of odorless compounds. When heated under atmospheric Card 3/ 6 311381601''0001012100811009 A051/AO27 Synthetic Softeners for the Reclaimin-- of Rubber Produced From the Products of Its Pyrolysis pressure, these sulfur compounds begin to decompose at a t,~mperature of 1500C forming substances with an unpleasant odor. When heating the oil mixture with rubber and rubber chunks even at 1900C no odor is noted. The polymer obtained from the asphalt is found to contain more hetero-atoms (especially sulfur and oxygen) than the non-processed and deodorized oil. In thedeodorizing process the quantity of oxygen in the oil even increases somewhat. It is concluded that the increase in the quantity of the hetero- -atoms in the polymer can take place as a result of the extraction of com- pounds with hetero-atoms from the oil with sulfuric acid and the formation of new polar compounds by sulfurization of certain components of the oil. Due to a lower iodine number the deodorized oil differs from the non-pro- cessed oil by a lowered masticating action. Both oils do not have sufficient intensifying action due to a low content of polar compounds in them (Ref-4). It is pointed out, therefore, that these oils can be used in rubber reclaim- ing only in combination with more polar softeners. The polymer is said to Card 4/ 6 S/138/60/000/012/008/009 A05l/A027 Synthetic Softeners for the Reclaiming of Rubber Produced From the Product's Of TtS Pyrolysis be -a very ac ti-~--o -reclaiming agent, easily used wi- thout any addition of other softeners. The --eclaimed rubbe:- thiis obtained has good physico-mechanical indices and an elevated chloroform extract. It also has a lowered acetone ex tr -ac The noly.:,.er samples and the deOaOr4Zed oil were tested at the r1hekhovski-Y rel-eneratnyy za-vod (Chekhov Reclaiming Plant) under semi-;ndus- ~ri al concli~ t4 ons i n recla4 mi ng lire rubber by the .,rater-reutral method. U -;ie results corresponded well with laboratory findings. it is pointed out U-at the deodorized rubber oil is not recommended as a universal softener, as .4'~ is aoplicable only to 'he reclamation. of =bber not requiring very lar,-e amounts of softener. An estimation of the cost showed that the pbly- Mer would be twice as lo,.,,, in cost (1,000 rubles/ton) as the applied com- bined softener in most plants based on J~~rkhangellsk pine resin and fuel oil. There are 5 tables and 4 Soviet references. ASSOCIAT'01T: 1-.'auchno-i-ssiedovatellskiy.institut shinnoy promyshlennost-i i Chekhovskiy regeneratornyy zavod ( Scientific Research insti- Tute of the Tire Industry and Chekhov Reclaiming Plant). Card 5A S/138/60/000/012/006/009 A051/AO27 Synthetic Softeners for 'the Reclaiming of Rubber Produced Prom the Products of Its Pyrolysis Fig. 1 Relationship betaeen the unsaturation of the rubber oil fraction and the molecular weight. zo :3 4~ 0 0 -H -i to C) 'n ~:f ~SL CU Q 5:: 7-4 4-4 0 0 1~0 2,00 J1,70 400 Cd0 "1 E~ average molecular weight of the fraction Card 6/6 23765 S/190/61/003/006/008/019 B',IG/B216 AUTHORS: Drozdovskiy,. V. F., Shokhin, I. A., Klauzen. N. A. TITLE: Deoomposition of butyl rubber and its vulcanizates under the influence of CobO 7--radiation PERIODICAL: Vysokomolakulyarnyye soyedineniya, v. 3, no. 6, 1961, 852-860 TEXT: In the absence of clcygen, butyl rubber ard ts vulcanizatea decom- pose under the influence cf ionizing radiation (Co~O y-radiation) similarly to polyisobutylene. The -present study deals with the decomposition of btity-L rubber -arid its filled sulfuric.. and unfilled sulfur-free vulcanizates under the action cf Coco y-radiation in presence and absence of oxygen, the influen,~e of radi-al acceptors on this process and the plastic-elastic uh ' ysz come-chanical properties of the radiation regenerate. Irradiation Tia.,:*. performed at 25oC in air and in va0U0 in flat ampOLI.IeS (,150'14*1 mm) by a method desf%ribed by the last-mentioned author (Ref. 8: K-lloidn, zh_ 20. 2160, 191~8`. Comuosition and properties of the vulnanizates s'uudiTd are listed in Tabi-? 1 , Sulfurle --u!.-lani2ed rubber vgas swelled in solut,,ons cartalnina 0.238 phenyl P-naphthylamine and m-dinitro I Card 1/1 23765 S/"; 90 6 1 /003 '006/008/019 De,7cmnosi~i~:n cf bLif"i-I rllbbw~r and iks' B I '01B" ben-,ene, 0.258 ri%d Cl.-2 mo,! 'i", 1 buTylphenyl disulfide, 0.17 mole/1 tri- di-9U,flll~ hnd 10.12 r.,iole/l tetramethylthiuram disulfide.. The sulfar-free vul-anqza~e was sweiled in benzene :ontaining 0.134 mole/l butylphi4nyi disulfide D~:,.omi)osition was determined by measurement of the relative viscosity change in 0.~; 1P benzene solutions, Infrared spectra 6 in the 10-13 p ran~,e were taken before and after irradiatior with 50~10 r in rair anl ,n %a~.ull 'fter -rradlation, -uthors carried out osmot4c .) -A the a ;3nd Vigr-os molel--!,lar -Neight ,.,ieqsiiremarts. and determined the modulus at 300 and ',00 ~,o -lcn~~-ation, the break resistanna, relative e1 -nuation, and tKe Swell ifig,maximum, in m-xylene and chlcroform extract. t~ 100 r, ff-.-e sulfuric -ulcan4zed rubber, w4th and After irradiati-cr, %ith 20- 1 - .Yith~ut b,)tylphenyl Jisiilfide. 1~ 11 was extracted v;ith a-etone and anal-zed quaz~tltatively fc)--,- bound 3UI'LLIr. The quality of the regenerate 'Was tested 0 by means of C'6() y-radiation. after swelling, and its plastic-elastic properties by rolling f,7.r 2 min each in refining and mixing rolls. The value of IsDe~ /,,, decreases during irradiation of benzenic rubber solutions 6 in air and in vacuo (Fig, 1.). Irradiation with 20-10 r reduces the viscosime"ric molecular we ight, calculated accordir.- to Fox (Ref. 10: T - G, Fo-.~ , P ~ J. Flo rly -. J- Phys. Coll. Chem,,, 53, 197, 19401)~ from Card 21-11 2 S/ I go/ 0 ;0 03/0006/008/019 Denompouition of butyl rublir,,er and its B1 10/B216 264,000 to 41tOOO In pra~tj~,(', the decomnosition of butyl rubber does not differ from th 'stL in oxyger~. Irradiaticn6cf tllf"led sulfuric and sul- fur-free vulcani?"itps with 10, 15. and 20-10 r lohers their break resistance and somewhat increases their relative elongation. The sulfur- free vulcanizate is decomposed more rapidly than the sulfuric vulcanizate. Irradiation of filled vulcani-.at~jFi '.ead.9 to a lower modulus, break re- sistan_-e and slightly lo-Ner relative elongation, The swelling maximum in m-xylene and chloroform extract increases. The property changes during radiation of the sulfur-fr-ee vulranizate are very rappid, Butylphenyl disulfide had a Preater intlupri-ce on the decom:,Olsition of the sulfuric -j--_i1caniaate than on that of the sulfur.-free vulcanizate. The presence of oxyun affects all the nrcperties of the filled sulfuric vulcanizate more than the vacuum. In the presence ef 0.238 mole/! sulf1de, the sulfur nontent nf gulfuric vulcanizate irradiated with 20,1C6 r increased by 0.35 % relative to, villealilzate irr-adiated in the absence of sulfide.. A ieLffenerate with good plastic-elastic and physicomechanic-al properties was -air --'ed,in a salut~on contain-ing 0-238 mole/1 b I ed from vulcanizat--~ s-,,,P- - I u sulfide 3nd irradiatea ;%if!, 2':~10 and 49-100 r In practice. oxygen does not accplorate decom-,-o3ition, but only affe-ts the chemical character Card 3,/, 2.3765 S,/190/0'1/003/oo6/oos/oI9 De,~omocsition of buty! and its... '31II()/B2I6 of the decomposit-'~~n to fcrmati-on of virylidene groups, the ey-hlbat--~d a band at 11.,2,~ ~L, The leromposit-ion mechan-~sm of butyl rubber by ionizing radiation resembles .-hat of polylsobutyiene 31111'Ur-free vu!:7finizates de.-,omrose faster than sulfuric vulcanizates. arA unfilled vulcanizates much mnre rapidly than filled cries. The presen-E, of frPe-radical ar;:-eptrrs (e..g. disulfides) accelerates the decom!~t:'sltion of filled vulcanizates. The increased co,!rert of bou-A sulfur --ihc;-Ns that addition of sulfur atoms to irradiated vIllcanizate take.9 place The sulfide rPnct9 more erfectively with ra3~icals possessing free electrons at the sulfur atcms instead of the c,;rbon atoms.. Oxy.-en ha,-, Li slight influence on the decomposition of !3u!furi(-, vulcanizates by De~-rens!~!d formation of branched 9tructures in the preser,-7e of disulfide (free-radical acceptor) is assumed to be the catise of 'the difference in the physicomechanical properties, astic properties. of regenerates subjected to varying at equal plastic-el~ radiation doses. Irradiatinn~3 -~,iere performed by V. T.. KLzlov, coworker physics and ohemical laboratory of the NIIShP, in the K-18000 "K-18000) apparatus of the Institute imeni Karpov. M, -i. Aric.:iangellskaya carried out t;ie osmotic molecular weight deiermi-rations., There Lire 7 figures, 3 tables, C a rd 4 /'-? 2 3765 511901611003100610081019 Decomposition of butyl rubber and itus... 311~)/B216 and 10 references: 2 Soviet-bloc and 8 non-Soviet-bloc. The three references t1o Engiish-lan6-uage publications read as folllozs: Re.'. 4: 0 ~ R. -!a-rin,7tor Nucleonics 14, 110 9~ 70, 1056. Re'. 5: 11. L. Johnson, H. A d a:. i Y. Barzan, I -ef. 06 Rubber World, 137, 73, 835, 91, 1957. R. Harrin-ton Rubber Age, 83, 472, 19'58. '.SSOCIA'-1'1ON,T Nauchno-i~-sledovatellskiy institut shinnoy promys 1 nno ti (Scientific Research Institute of Tire industry) STj--71j.'ITTED July 28, 1960 Table 1: Composition and nroperties of unfilled and -filled butuyl rubber - -oer'ies of the vulcanizates; 2) Sul - vulcanizates. 1) composition and pro. 4- -,uric vulcaniza'es; 3) sulfur-free vulcanizatues: 4) unfilled; 5) filled; 6) butyl rubber3 7) stack soot; 8) furnace soot; 0) zinc oxide; 1.0j) Petrolatum; 11) stearic acid; 12) tetrnme'hylthiuram distilfide; I,`;) mercanto benzothiazole; 1A) p-q11iinone dioxime; 15) dibenzothiazole di- sulfide; 16) -ulfu-,; 17) vulcanization at 1510C min; 18) modulus e-t 500 Tll elon-Eition, kE/C-,!2; 10) break -resi~st~~nce, k- cm~ 20) relat-1ve elongation, C~ 21~ s-,,ellinS maximum in m-xylene, %; 22) ::ax3.--7= inbenzene, Card 5/7 DOGADKINI, B.A.; MCHESOVA, G.N.; SHOMIN, I.A. Reclaiming of rubber by the dispersing method. Kauch. i rez. 9Q no.22;15v-21 D 161. (MEU a 5.-'1) 1. Nauchno-issledovatellskiy ins#tut shinnoy promyshlennosti, (Rubber., Reclaimed) 4 DROZDOVSKIY, V,F, ~ SOKOLOV, S.A,; SHOMIN, I.A, - EYTINGON, I I. y - I A(.Aivators of rubber reclaiming process. Kauch. i rez, 20 no.12:222-25 D 361, (MIRA 15;1) 1, Nauchno-issledovatel'skiy institut shirmoy promyshlennosti, (Rubber, RecdaLmed) S106 61/023/002/001/008 BI 01 YB208 AUTHORS: Dogadkin, B. A., Zachesova, G. N., and Shokhin, I. A. TITLE: Preparation and properties of aqueous suspensions of vulcan- ized natural and synthetic rubber PERIODICAL: Kolloidnyy zhurnal, v. 23, no. 2, 1961, 150-156 TEXT: The purpose of this study was to investigate the regeneration of used waste rubber by dispersion in aqueous medium. The authors applied the method devised by B. A. Dogadkin and D. M. Pevzner (Ref- 4: 'Author's certificate no. 29973, 30AV 1933), in which an oleophilic emulsifier insoluble in water (fatty acid, resinic acid), and then gradually a saponifier (alkali) are added to the hydrocarbon (rubber, plastic, vulcanizate). The reclaimed product is obtained by electrolytic coagulation from'the aqueous suspension. The following was studied in the present paper; 1) The effectsof the emulsifiers oleic acid, colophony, P-naphthalene sulfonic acid, P-di- naphthyl-methane sulfonic acid and their sodium salts. The optimum dose was 5-10% of the rubber weight. The authors determined the particle size by means of N. A. Figurovskiyfs sedimentation balance in coarse dispersions, Card 1/6 S/069/61/023/002/001/008 Preparation and ... B101/B208 and by means of an electron microscope in fine dispersions (carried out by S. A. Simanovskaya). The following results were obtained: Emulsifier a/100 a rubber Darticle radius colophony 10 0.241 oleic acid 10 0-514 P-naphthalene sulfonic acid 5 2.045 P-dinaphthyl-methane-sulfonic acid 5 3.14 dto. 10 4.41 2) Effect of saponifier: NaOH KOH KOH NH 4OH NH 4OH conc.entration, % 5 5 7 5 10 average particle radius, g 0.24 0.22 0.20 is not dispersed No Dhase inversion (dispersion of the organic phase in water) occurred in NH4OH owing to its volati1ity. The same result was obtained for Na 2B40 V but this is able to replace.2/3 of the alkali, a particle radius of 0.59 g being obtained. 3) The concentration of the alkali solution exerted the Card 2/6 Preparation and ... following effect on dispersion: S/069/61/023/002/001/ooa B101/B208 concentration, ~- 2 5 10 time of dispersion 90 50 35 min amount (glloo g rubber) required for phase inversion 67-83 33 25 particle radius, g 0.249 0.241 0-555- 4) Large particles were formed when the alkali solution was added too quickly (30 min). Slow addition (90 min) gave a fine emulsion. This is stable if the pH of dispersion is not.less than 11.5-12-0. 5) The clearance between the rolls had the following effect: clearance, mm 0.3 0-5 0.8 1.2 particle radius, p 0.241 0.539 Moi 0.785 6)The consumption of electric energy during disperdion is compared in Fig. 6 with the amount required to plasticize the mixture. It decreasesafter adding the alkali solution, and approaches the no-load consumption during phase inversion. 7) Fig. 7 shows the effect of a plasticizing activator, i.e., Renatsite 2, (a preparation containing 42.50i'2 trichloro thiophenol). Card 3/6 S/069/61/023/002/001/008 Preparation and ... B101/B208 8) the behavior of various types of rubber with highly active carbon black as filler was tested on HK (NK, natural rubber); CKW (SKI, synthetic cis- polyisoprene rubber); CKC-30APM (SKS-30ARM, divinyl styrene rubber), and CKS (SKB, sodium butadiene rubber). Two groups of samples were used for the purpose: 1) samples prepared according to industrial formulas for tire rubber, 2) samples prepared according to a unified formula so that they differed only in the polymer. Table 3 presents the results. The particle radius was found to depend less on the type of polymer than on the density of the vulcanization network. However, the properties of the reclaimed products obtained by dispersion differ in the individual polymers. The authors will later report on this subject. It is mentioned that the disper- sion method described has been used in 1938 at the zavod (plant) "Krasnyy treugollnik" for the regeneration of used rubber. From 1941 onward, this method has not been applied any longer. Mention is made of F. F. Koshelev and I. A. Tartakovskiy. There are 7 figures, 3tables, and 7 Soviet-bloc references. ASSOCIATION: Nauchno-issledovatellskiy institut shinnoy promyshlennosti (Scientific Research Institute of the Tire Industry) Card 4/6 7~rei;aration and s/o69/61/023/002/001/008 B101/B208 SUB.,'ITTED: October 26, 1960 Le.-end to Fit;. 6: 1) plasticizing; 2). dispersion; 3)'idling; a) power consumption, w; b) min. LeCend to Fi~5- 7: a) content of Renatsite 2, wt~6; b) mean particle diameter, Card 5/6 0 4 e P ti d 6 Y6 023/002/001/008 / r on an para ... 131 1320 8 V Tun rmmHmepa :KC-30APM (DcKr. HK CKH rpynnL4 onimn 1 1 2 1 1 2 1 1 2 1 2 q)LIUCAO YMOR 8 eAURIUM cdtwa 4,03 4.68 3,99 4,80 1,65 4,01. 2,39 4.28 BYAK3111133T11 X 10-9, AIA-1 (D A1O.1eKYAF1PHUr1 uec ytlaMa wit M M 6M 0450 W 200 7050 It 550 M &C,ny.qKamt3aTa KV11111r, P3A11YC 43MILL AHCflep- 0,428' 0,388 0,279 0,30-9 0,241 0,306 0,270 0,328 gy elm. !tCAbliall flowpX11GM, 'faCTMI 6,16 7.46 8.90 7.45 t0,82 8.7 9,86 8,31 401 Pglicilepcillf, 41210 pa3onaiwe "CXOA 911ePFUH iia o6 9.5 - 5,44 - 5.90 CA1111111tu YACAMOR nOUePXHG- CT" AllcnePcHOR 4)a3b[ X 10-4, KOM - q Legend to Table 3: 1) polymer; 2) NK; 3) Syl; 4~ SKS-30AIal; 5) SY.B; 6)e,-roup of experiments; 7) number of lattice points x 10 per unit volume of the vulcanizate, m1-1; 8) molecular w eight of the section of the vulcanizate chain; 9) mean radius of disperse particles, p; 10) specific surface olC disperse particles, m2/g; 11) power consumption per unit of specific surface of the disperse phase xio-4, kw.hr/(m2/g). Card 6/6 SHOKFIN, I.A.; STRONGIN, M.A. Valuable initiative of the ChekJiov ReclAimed Rubber Plant. Kauch. i rez. 20 no.9:58-59 S 161, (14IRA 15;2) (Rubber., Reclaimed) V 8/1" 62100010WI0051QOT A051/Ai26 A11MORSt Berlin, R. L., Dogadkin, B. A., Zaahesova, 0. H., Koratkova, A. A., Linicheako, A. I., Shokhin, 1. A. TITLE: Production of foam rubber articles from latex using aqueous rubber dispersions 1101110DICALt Kauchuk i rezina, no. 8, 1962, A - 16 TZKT: A method has been developed for the production of foam rubber articles with partial replacement of the latex by aqueous dispersions of old rubber or olante products from foam rubber production. The technique of old rubber dispersion was developed at the 111511M (NII&P), whereby the aqueous dispersion of the rub- hor is a polydispersed colloidal system. Dispersions prepared with colophony as the disperser and 3% aqueous solution of NaOH, as the soaping agent, were used in developing tho production method of the latex mix for the foam rubber articles. Trte iaLex mix of the foam rubber, based on "revertex-standard" and CHC -50 [1 r WKS-50PG) latex, using various types of aqueous rubber dispersions, contained POLaL51UM paraffinate, vaseline oil or its emulsion, as the foa:nIng agent, or Card 1/2 s/i3B/62/000/008/005/007 Praduction of foam rubber articles from... AO5lAi26 dispersion of vulcanized substances (sulfur, diphenylguanidine, eymate, zinc mereaptabenzothiazol, zinc oxide). The quantity Gf vulcanizing agents In the mixe3 was calculated adcording to the rubber substance of the latex. They also contuined a LclatiniZing ZolutiOn (10 - 20% solution of aillmonlum chloride, 10,15 solution of ammunta and triethanolumine), Tile o 'btained articles flet the coffoler- clal requirements. The cutting-out proLess caused no change In the phlsico- mecLanleal 1~ropertirs of the foan rubber articles. The latter retain ChLir color whvn unlnj~ d-'--persiavs produced fron foarn rubber wastf, preducts. it is coriclud,-Li that by replacinF 20 - 3C1% of tile synthetic and natural latvx with vqtjeuu3 cil:iper- L;Ivris of rubbr, thu quaiity uf the fowu rubber prorlueed by the foanjln,; IrmAhUd. fi-'~ Aeccrding to preliminary calculattons, the use o!' aquL-oun tl!~- 1;161S!-~lls of ruju-ir Ir. tile production W' foam rubber articles should offer con- - ',rub' .A -e a-id aconcinLe advantnges. There are 2 tables. V.90CIATION: institut, vezinovykh 1 1at,-1.z:nykii lzdelly I Instittit. zhinnuy promystilei--nontL .1tesuarch institute at' Rubbr and U-tex Arr.!c',,n and 2~ it! P.TAf le Razearch Institute of the Tire Industry) -ca 2/2 ,L 15669-63---.- ---EWP4)~/EWT(M) S---~A4 4- .ACCESSION HR: AP3004257 0138163100010071603310035- 4UTHORSi Drozdo vskiX, V. F.; Shokhin, I. I~TITLE: Destruction of monosulfide bonds of sulfur: vuldanizates iSOURCE: Kauchuk i rezinap no. 7, 1963,- 733~35, JOPIC TAGS: sulfur vulcanizate regen.eratio4_thiuram,vuleanizate, zinc'oteara.tal - ;monosulfide bond :'ABSTRACT.- An attempt was made to disc.over the..,origin, of the, sulfur.:-which appears. ;as zinc sulfide in the.reclamation process of vulcanized tubber. To this end the ,ireactions taking place in theiabsence of oxygen between'zinc~stearate 9r.zinc !oxide and the ethyl ether of dibutyldithi ocarbaminio acid. (EDTGA),, dipi~opylmono- sulfide (DPMS), and diallylmonosulfide'~ ~(DAMS) were Stu-died. 11mAules with zin,c istearate and EDTCA were heated at 180C.for 0-5-20 hours.and at 200C for 5hours., I M :then the compounds were analyzed for sulfide sulfur. At.180C only an iniigni i- :cant quantity of ZnS was formed, while at-200q the yield of sulfide sulfx~,r amounted I ~to 2%. The reaction of zinc stearate :ith DPM&was eoiducted at 2Mand 1220C without any ZnS being formed, As to D91S, it.was reacted with 2no at 143, 18o, Card 112 L 14398-65 ACCESSION M AP4045697 trichlorobenzenethiol were added-to the mixturee The-extent of the~~ modification was evaluated from.the change in weiRht of-the reclaim, Portion insoluble In acetone and -chloroform*' It,-was showd that vulcanizates are not modified in' the. __1 ca'se ---a fpolyisobuty-lene - and.--._.- polychloroprene. In the -case of poly,(mdthyl methacrylate) the-veigh of vulcanizates increased, independently,'of their molecular veightv:_ by 12-14%, which corresponds to the chemical-.addLtion.of 45-51%,_0f,_ the polymer charifed, Reclaims of HAVc -arbon black-filled vulcAnizate d contain unreacted poly(methyl methacrylate an, are, ve,ry. kLgLd.,.:. VuLcanizateis of these reclaims exhibit- enhanced hardness, and resis-: tance to swelling in hydrocarbons.. but.4 lowered. wear- and tear-- resistance, tensile stretigth, an d I ow- tempe ca ture re a f a t at&, cei* ~t Origo, art. has: I tdble~ ASSOCIATIONs Nauchno-Lestedovat.o. rowy*~hienn*-l ~~Lyjnstitut 8 Unoy V~ the Viri-:4nlui try ti (Scientific Research-Inati-tutg .2 f--- (W SUBHITTEDs 00 ... ........ t NO REP SM 003 __--,-_-Ii-0TH 2 SARAYEV, I.Ya.; SHOKIN, I.N.; KRASHENINNIKOV, S.A. ,Extraction of nhosphoric acid by n-butyl and isoamyl alcohols. Zhur. prikl. Id-lim. 37 no. 4:874-880 Ap 164. (MIRA 17.5) BABITSKIY, B.L.; VINITSKIY, L.Ye.; DROZDOIISKIY, V.P.; DYUBKO, L.D.; KAPLUNOV, Ya.N.; MELE14TIYEFTA, Z.G.; SHOKU11'11,~J,,A.; Prinimali uchastiye: ZHILITSOVA, A.A.; LEVIT, R.G.; YAKovL"wi, D.e. Effect of filling reclaimed rubber on the dielectrical properties of the reclaimed product. Kauch. i rez. 24 no.5:22-25 Mly 165. (MIRA 18:9) y nauchno-issledava'uellskiy institut zheleznodorozhrogo 1. Vsesoyuzny- transporta i Nfauchno-issledovatellskiy institut shinnoy promyshiennosti. ROZER! , A.M.; SARAYEV, I.Ya.; 9110KE, 1.11. Detemination of the degree of hydration of extracted sub- stances. Zhur. neorg. khim. 9 no.6.-1455-146.4 Je 163 OTIRA 17:8) 1. I-loskovskiy khimiko-tekhnologicheskdy institut imeni Mendele- ye va . BEIG L("." , b ~Yl, . -',~-ICK 7 N L N , r,i:.l:".I~:i!~'NINl~,l~~,'~l: , L".~-t. ': - .'. _ ~,-j 1 -im !,-- arlrb,,Dn,~ ' e . U -'r. . kh 1 m. zhiir . 8 no . ~- . .-l' -0: 1:1 - 11 5- ,-'(3 1 ~- " RL A I B -, 4 " 1. Yn-sl&c,,-.,rskty institilt. BEGLOV, IHIFIV, T.e4.; ',S, F . -1 ' ~; ~ 1 *,,~ 1, ~ Ij -. - . KR. ~V, :~,. A. FrOCC-SS 0~ of arr,,,,-jn-ur-. ltlica-rboriate. Uzb.khimn.zhur. .4 -- ---- - 6 no.5:1-C-!-'/ '~,4. (MRAl 18:5) 1. Ncski-vz3kiy irstitout i-:-,ien--- Viendeleyeva. KUKURECHENKO, I.S.; SUM 'i HEV, N.G.; SHOKIN, I.N.; KRASqENINNIK(J--'V., PODOSINKIN, P.A.; POSTOROIIKO, 'A.T.-; TAOYNIK, G.G. Decarbonization of sodium bicarbonate in a semi-industrIal column with submerged packing. Trudy MKHTI no-40:186-190 163. (1,ERA 18:12) , H", - - .. I ,1 15 rl I B I.j . ~ I -anizatsiyu Yeteorologicheskoy Sluz~by. 'Glav. 22/,15. :110i'liTI: . V. Orr k Botan. ad) D.,nulleteril Glav. Botan. F.~oda, IJYF. 2, 1949, S. -28-30. SCI: Letopis' No. 30, 1949