SCIENTIFIC ABSTRACT SHYVAYEV, L.K. - SHUYKIN, N.I.
Document Type:
Collection:
Document Number (FOIA) /ESDN (CREST):
CIA-RDP86-00513R001550320008-7
Release Decision:
RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
August 31, 2001
Sequence Number:
8
Case Number:
Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
File:
Attachment | Size |
---|---|
![]() | 2.65 MB |
Body:
:1
7D.
i I . I - I - -
. ..:-: :'~ ; . , . , ~ . - I .
i
2. U~w"~;R ( 600 j
4. i; -.!ui [)
7. 1J)e,),--r),Ience c,!' f"bin- c,tjality in i.emr. h~vbridj on conditions) Sel.i sem. ZO no. 5
195~ -
9. Monthly List of Russian Accessions, Library of Congress, - 1953. Unclassified.
SAMY,;W, L. L
USMANuclear Fh-vsics - Cosmic Rays 21 Nov 49
Particles, Elementary
"Absorption Spectrum of Penetrating Particle Currents of wide Atmospheric Showers in Cosmic
Rays," G. T. Zatsepin, I. L. Rozentall, S. A. Slavatinskiy, G. Be Khristiansenp L. A*
Shyvayev., Phys Inst imeni Lebedev, Acad Sci USSR, 3 pp
I'Dok Ak Nauk SSSRII Vol LUX, No 3
Employed usual Tethod of variation of area of counters connected in coincidence scheme.,
and method of vakiation of "coincidence multiplespli to determine subject spectrum and
clarify nature of penetrating particles. Submitted 22 Jul 1949 by Acad D. V. Skobelstsyno
158T76
SOV/124-58-2-1539
TranSlatior-, from- Referrat",-nvy zhurnal, Mekhanika, 1958, Nr 2, p 7 (USSR)
AUTHOR: ShLl`-dyeV, N. A
VT I,E - 'rile E-q-u-,trrmr-of Motion for the Center of Mass of a System of
Particle!, Having a Variable Mass. General Case. (Uravnenive
d, izhewya tsentra mass sisternv tochek peremennoy massy v
obsilcilen-i sluchaye)
PERIODICAL: Uch. zap Gor1kovsk.. un-ta, 1955, Nr 28. pp 56-69
ABSTRACT: The article presents the equations of motion for the center of
mass of a system under the assumption that the system mass
varies through to the simultaneous joining Iand separation of
particles without consideration of their relative motion, The
equations of motion of the center of mass are developed both for
the absolute reference system and for a coordinate system the
axes of which have an arbitrary motion. The article considers
some laws of particle radiation, The equations of motion for
the center of mass pertaining to the radiating particles have a
sitripler form.
Card I/I At 1. Zenkin
A.
nono
cL-,:;:; of majL
S 1, C !',UZ Aviatslornaya torchnika. no. 2,
-oli -LJ on, qu~ nt-x.% mc;char,~ cs
va r
--y.3tC'.7iS Of on.. G~ Z-, vzl-l-*L~."10 and
C, f -1 z s Y, c'
to
c '&--t ore,::-. f3r -c~*-~ J. of of Y:; t f'~ m
of tho-
of tho nazz contor. --~~.:;cia clas-- of masz
~'-e -'7'a:'z'jz C,
0- Of -:0
`-e- of t'-e
aro Or.:lzLl- y vand
n3
of var~,a-blo mas5qs. cj~ t h 3 !.~6'ic,
2~j SU ~E: 2Z';o-,r641 CRI.--i aZ*.,'. 033/ 0-,:H,
caru I
124-1957-1-75 D
Tr.in~.-I'aGon from: Refer -Aivnyy zhurna!, Mekh:inika. lq57, Nr 1. p 8 (USSR)
AUTFIOR- Sliuvaycq,,. N_ A.
TITLE-. Critical' HiEtorical Analysij of the Developments of the Funda-
nientals of Vatriable-Ma-_s Mechanic6 (Istoriko-kriticheskiy
analiz razvitiya asnov mekhaniki peremennykh mass)
ABSTRACT: Bibliogr-:tphic entry of the auther's dissertation for the
Degree of C-Andidate of Phytic-A-Mathernatical Sciences. In-t
i~-torii yestel~tvozn. i tekhr, AN SSSR (Institute of the History
of NYWI'31. SCienCec Ind Tech-~-,'.cwy, USSR Academyof Sciences),
M.-O'Cow
ASSOCIATION- In t i:,t(2rii ye-Ae,.tvcsr, i tekhr. AN SSSR (Institute of the
Hi-tory of the N~Atijr-fl Science5 and T(-chnology, USSR Academy
of Science.-), Mc~cov,,
1- Variable mass mechanics--Fundamentals--Critic
CArd i /i
ALEESANDROV., V.K.; SHUVAYLV, N.A.
Automatic record of the lines of flow of a fluid. Sudostroenie *29
no.4:54-55 Ap 163. (,4I.-,A 16.4)
(Recording instruments)(Aerodynamics--Llectromechanica1 analogies)
BOGOSLOVSKIY) I.M., inzh.; SHUVAYEV,_P.N.
Manufacturing parts of the nflanged ring" type of sheet steel. Khim.
mash. no. 3:33-34 My-Je 160, (MIRA 14:5)
(Chemical engineering-Equipment and supplies)
FERAYONTOV, A.D.,, starshiy laborant; SIIUVAYEV, P.N., slesarl
Flat specimens with thread for mechanical tensile tests. Sbor.st.
NIIKHIMMASH no.33sl33-134 160. WRA 15:5)
(Testing machines)
SVECIWIKOV, S.V., kand. tekhn. nauk,-, SHUVAYEV, V.A.
Photoconverter controlled by the v:)ltage function. Art. i
prib. no.4.,51-54 O-D 164 (MIRA 2JRa2)
~
K
0
:ACCESSION NR: APS009042
, V1010/001/0061/0064
3 .4 1.
AUTHOR: Borovskiy, V. P.; Partala, 0. N. 1, Shuvayev; V. A.
TITLE: Generation of FM oscillations in a wide range bmulti;;Tratore
y
:SOURCE: Avtomatika i priborostroyeniye, no. Is 1965, 61-64
TOPIC TAGS: FM oscillation, rnultivibratoz, FM signal generator
!ABSTRACT: As phantastron FM. signal generators. easily develop spurious Am
and present difficulties in filtering the I et harmonic, a symmetrical electron-tube'l.
RC multivibrator is proposed for this purpose. these experimental results are
claimed: frequency range, 1 00 150; frequency drift on tube replacement, :t 1. 25%;
!-frequency drift on t 10fe heater-voltage variation,.t 0. 4%; the frequency was
ipractically constant witl*an anode-voltage variation of tlO%. Or'1g. art.' has:
14 figures and 5 formulas,
ASSOCIATION: none
iSUBbUTTEM-00 ENCLI. .00. SUB CODE: EG
NO REF SOYS 002 OTHER:.~000
Card
T
-ACC
FZSIOX NR; AP50017". S103021 00/00-
V -W
'A
AU~HOR: Svechnikov, ;9._Y..'-4.-Candidate of fachnical sciinces); Sh
TITLE
Voltage -function ph(itoconverter
SOURCE: Avtomatika I-priboron0ayeni e~ Imo. 4. 1964,- 51" 54'-
Y
TOPIC TAGS: photoconverter, voltage hl~nAioh.convertar
AB.9TRACT: An analog -to -analog photoconverier is proposed. a substiWti i6i'--
M-~chanical sliding-contact potentiometers. The converter consists of a,
transistor with the input voltage applied between, its -emitter and.bas oft
a and a ga
fill ed*old- cathode lamp connected into its vollectair'idircuit. 'An thelanip
luminescence intensity is propoitional to its current in k*w1d6 ran at a
(selenium-cadmium) photovaristor placed near the laxnp w=,j~& a a current'l
proportidnal, to the input voltage. Temperature stabilizing resistors ar6.j
in the circuit. The'inertia of both tho lamap and photovaristor*is. tot or &
ip~_asibt&.f
C~,d I/Z
. . ..... .....................
L 6961-66 0dT(1)/9dA(h)
AM NR: AP5020931 SOURCE CODE: UR/0142/65/008/003/0366/0368
AUTHOR: Vollerner, N. F. (Prof.); Borovskiy, V. P.; Shuyayev, V. A.
ORG: none
TITLE: A generator of video pulses of arbitrary shape
SOURCE: IVUZ. Radiotekhnika, v. 8, no. 3, 1965, 366-368
TOPIC TAGS: pulse shaper, RC circuit, pulse generator
ABSTRACT: In contrast to the complex arbitrary function generators described in
the literature, a comparatively simple scheme for obtaining pulses of arbitrary
shape is described. The method is basically the following: 1) the creation of a
step function of n quantizing pulses of identical duration and amplitudes propor-
tional to the instantaneous values of the function at successive instants; 2) smooth-
ing the step function with a low-frequency filter such as an integrating RC circuit.
A commutator based on cold-cathode thyratrons operating on the principle of a count-
ing circuit is proposed since it is simpler and more.reliable than comutators. If
UDC: 621.373.53
Card 1/2
L 6961-66
ACC NR: AP5020931
a symmetrical pulse shaper is desired, the number of commutator cells can be halved.
A generator with a capacity of 64 quantizing pulses is capable of generating func-
tions from 5 microseconds to several seconds in duration. The functions generated
are within 2-3% of the theoretical estimates. The arbitrary function generator
should find wide use in analog computer technology, modeling 'of systws, and produc-
tion of AN and FM oscillations with arbitrary modulations. Orig. art. has: 4
figures.
ZA(,rljT,yjtyp,vi..l A. I., riatichnyy notrudnik; SHUVAYEV, V.14.
Rarid method for manufacturing leathor from vhale skin.
Y,o'zh.-obuv.prom. no.12:7-9 D 159. 04IRk 13:5)
1. Tikhookeanskiy riauchno-isaledovatellskiy institut morskogo
rybnogo I:hozyaystva I okeatiografii (for Zugulyayeva).
(Whale) (Leather)
L 14498-65 OdT(m)/W,(J)/T Pc-4 IJP(c)/AFVQ3SD/LSD( RM
~&)JFSD(t)
SIO 48/64/028/010/1725/1727
ACCESSION NR: AP4048648
AUTHOR: Kocharov, G.Ye.; Kaydenov, V.O.; Shuvayev, V. M.
TITLE: A proportional counter illed with a mixture of xenon,and is-oPentaneq./1Fe--.,'-.
port Fourteenth Annual Conference on Nuclear Spectroscopy held in.Tbilisi 14722
Feb ~964-1
SOURCE: AN SSSR. Izv. Seriya fizicheskaya, v.28, no.10, 1964,.1725-1727
TOPIC TAGSs proportionQ1 counter, xenon,--Isopantane, Samma rQ spectrum, bariurA
ABSTRACT: The coefficients Kand U that characterize agas, according to:the
ory of proportional 'counters (R.17.Kiser' Appl.Sci. Res. 8,183,1960; G.Ye.Kocharov
.and G.A.Korolev,Izv.AN SSSR,Ser.fiz.27,301,1963), were measured f or',a xenon is o.-
pontane mixture by the method of Kocharov and Korolev,(loc.cit.). A.27.4 cin long
counter with n 4.6 cm diameter.cathodc and a 50 micron diameteranode containing-,
xenon at 650 mm Hg and isopentane at 10 mm fig was employed with 5.07 MeV Cf-paritfc3xs::~-~.,.
and 30.6 and 41.9 keV -y-rays. The values,of K,and U were found to.be 64.5 V/cm mm-~':%l'-'.
Hg and 23 V, respectively~' Itfollows from these data that the cross section-of
xenon for ionization by electrons is 3.2 x 10-16-cm2. t.Pontecorvo~(Helv.i?hys.,Aci-a,.,~--~:--,~",,*~
1/3
L 14498-65
ACCESSION NR: AP4048648
23,Suppl.3,97,1949) showed that the eneigy~resolution of a proportional counter: is_~
reduced by space-charge effects when the gas amplification exceedsa certain criti--~".
cal value, and that the product of this, critical amplificatiori and the energy . re-
leased in the working volume of the counter is constant. Working with x-rays pona~
tecorvo found this product to..be 3 x 108 ev. This product was measured with 5.07,.
MeV U-particles and 30.6 keV 7-rays and was found to.be 1.7 x 108 and 1. 5 x -108 eV.
in the two respective cases. The reduction in energy resolution when the critical
amplifkcation is exceeded is,illustrated.with Ba133 yl-ray spectra recorded at.anode._.~_--
potentials of 1.9 and 2.0 kV. The /-ray.'spectrum of Bal*3 was recorded at energies~'~.-.
8
from 30 to 80 keV. Three lines were obseirved at 30.6 approximatel'
y 50, and 7 .6
keV. From the relative intensities and known internal conversion coefficients it-
is concluded that the L to X capture rati.o.is .1.1. This Is in'good agreement-with,'_~,;~,-~-.
the finding of R.K.Gupta, S.Iha, M~Joshi and B.K.Madan (Nuovo cimento 8, 48 1958
and in disagreement with the result of U.Langevin (Compt.rend-240,289,1955).
art.has: 4 figures.
2/3
IOAZHIN, J3.X.l SIMVA!nv, V.P.
Electric conductivity of polyetyrene solutions. Vysokom. soed, 7
no.6s962-965 Jo 165. (MMA 18 19)
1, Nauchno-issledovatellakiy institut polimerizatsionnykh plantmaes*
SHITVAYEV, V.F.; ANIKOVICH, V.F., kand. seltskakhoz. nauk
Fall tillage of sail. Zemledelie 27 no.8:35-39 A 165.
IMIRA 18:11)
1. Orenburgskaya oblastnaya seliskokhozyaystvennaya opytnaya
stantsiya (for Anikovich).
SkZIIIN, B.I.; SIMAYEV, V.P.; VESELOVSKAIA, L.N.
Determining the molecular weights of polymers by the electric
resistance of their solutions. Plast. massy no.11:48-50
165. (MIRA 18:12)
SIIUVAYLV, V.S.; VISI ICIUKOV, F.Ya.
Using graphs to solve some transportation problems. Izv.vys,uck.-
zav-; stroi. i a--kh-,*t. 5 no-4:1003-116 162. (MT-ra 15tg)
1. Kuybyshevskiy inzhenerno-stroitellnyy institut imeni ',,Ukoyana. 1.:1
(Transportation, Automotive)
DOMANSKIY, V.-Ye., prof.; SHUVAYEV, V.S., dotsent; ARNGOLID, A.V.
"Design and operation of a tallinge storage department of an
ore dressing plant" by P.D.Evdokimoya. Reviewed ty IA.A.
Rubinchik. Remarks on the book review ty V.E.Dozanskii,. V.S.
Shuvaev, A.V.Arngolld. Reviewers' response. TSvet.uet. 35
no.1243-77 D 162. (MRA 1682)
1. XiWbyshervBkIy inzhenerno-stroitelln7y institut for Doianakiv).
2. Kuybyshevaldy lnzhenerno-stioitelln~y Institut ifor Shuwayev
3. Vaesoyuznyy institut po proyektIrov4Iyu organizately
energeticheskogo stroitelletya (for Arngolid).
(Tailings (Metallurgy)) (Evdokinova, P.D.)
USSR/Farm AninrlB. Cattle Q-2
Abo Jour ; Rof Zhur - Biol., No 8, 1958, No 35624
Author k 8huveyov V.T
Inst I-N-OrGiva
Title : The Methods Used for the Inprovenent of the Dairy Hord of
the Rod Steppe Broad in the Severo-Lyubinskiy Sovkhoz of the
Onsk Oblast'
Orig Fub : Tr. Novosib. s.-kh. in-tc, b. g., 11, 92-109
Abstract S The fixation end improvonent of highly productive milk end
fet-typo streins of thoprogeny of four bulls, the crossing
of those strnins with other strains, end their inbreeding
with the Shorthcrns, constituted the basic mothods of roising
Red Steppe cattle rt the Sovero-Lyubinskiy sovkhoz of the
Wsk Oblast'. The breciing wns carried out accordine to
strrIns and ferilies, md individual selection. A series of
orgenizetioncl end econcricel nonsures were adopted. The
live wiight of the tertiporse cows incrersod tp to 514 kg.,
their cverrge nilk yield rugnented by 931 kg. (up to 4,719 kg.),
Card 1/2
UGSR / r-arm Anijmair, 1.1 1 ~,-- -.I... Q-2
Abs Jour Ref Zhur - Biol., No 10. 1958, No 45161
Author
Inst Not given
Title Methods for the Improvement of the Dairj Cattle of the Red
Steppe Breed.
Orig Pub S. kh. Sibiri, 1957, uo. 8, 45-49.
Abstract The formation and improvement of the herd of the Severo-
Lyublinskiy sovkhoz of the Omsk Oblast' is described.
Card 1/1
SHWAY-N, V. T. : Mastor A,--ric Sci (diss) -- "Incr--asin., Llia productivity and
V^Vm-?w
stock qualities of ral steppe, canle in the hord of the north Lyubinskiy sovkhoz,
Om,4' Oblast". Omsk, 1956. 24 pp (Min Agric USSR, Abstracts of Dissertations
Pr~!sent,A at- tli~2 Omsk A.~lric Inst im S. 'M. Kirov), 150 copies (KL, fllo 10, 1959,
127)
KIRPATOVSKIY, I.D.; SHUVAYhV, V.V. (Moskva)
Some special problems of transplantation, based on =aterials of the
scicntific conference of the Laboratory forT ransplantation of
Organs and Tissues at the Academy of Medica2 3ciences of the U.S.S.R.
Vest. AMN SSSR 18 no.12:89-90 163. 011RA 17:7)
T K
o-' an exf.rfmity in doco. udv
~-2.11 42:2;~:-29
JrAravi.*a! lympto- and we.Cof-,raplay in a repll-tr-.ted extreralty;
pr, 19:2
po td.
SHU11"AYI.-N] V.V.
Oerve s,.',Urc- and its use in the replantation of an extremity;
, p
a revlew of the literature. Trudy !-go 42:101-111 165.
19:2)
1. Labor:Ltoi-iya po peresadke organov .1 tkaney 1'MN SSSR.
Ti-i%-'-- 1-vo MMI 4':119~-128 165.
ibr,,,-a va po peresadke orpnow i
1. - tori~
-.,.!I-w~l ar-utlom, i eriri-i
(-f' ar. extrtmltv;
in w.
I imi nary r- or T-I! 42 153- 59 1
Laboratt.orirt po pereea(ike i tkaney A.M SSSR.
- - -1
I I F 1 $1 -
WPENKO, V. I,;SHUVATRY, Ye.11, --
length of blavout of a system by Inert gas. 9him. I tekh. topl. i
masel No.2:58-60 F '57. (MlaA 10:4)
(Petroleum industry-Squipment and supplies)
(GaBes. rare)
9
S/06
/60/000/009/004/006/XX
1
3030 U 2
,
AUTHORS: P,331yaftskiZ, G.N., Dur3lan, 5. ., rAmusher, G.D.,
2ETrxan, 3.A., a v .4.5,
4 ~r"l
L
__
I _ __W
-c~~ ytic Rarorn
;2tin -fFact-ror.
TITM 1., .1 on a
Platinum C.-.1" I
PERIODICALt Xhimi" I tow2noicein topltv i masol, 1960, No. 9t
.
pp. 1-9
TXXTt FUII-scale plant studies have been conlu:ted on
reforming Listern and Southern crudes on 2 platinu=/alumir~
catalyst. RumanianI rirkuk, and E-yptlan crudes hiv4 also been
investigated, To types of plant Eave been developed with reactor
Crs38UrO3 around z0 arrI 40 atmospheres rej;octivelyt the former
0 ng better for producing high octane jpirlt and aromatics for
or;anlc synthesis. With a 60-L20 cC str2,
,ght-r= fraction at
" OC, the aromatic yield falls from Z7Z weight to K1, and at
505 OC from 36 to 3z%, on Incra,13ing the pressure from ZO to LO
Hoveverj coking of trio c%taly3t and deactivation
atmo:ih
er9%
h
om;
by 3 p ur r=13 bO=nd troubleaome at the lower pr93~UX43.
especially Vith Ca and heavier fractions. If *he sulphur content
Card 1/3
t4,yt-.c Reforming of Ber,:Inj F.-t-ticra ~n a Plitlm= Cata I73t
or the crude rises from 0.01% to O.Z-.%. 'he actar.9 number f&1'3
from 77.3 to 70.3t the aromatic yield falls 1.7 tin-, and th') gas
7Laid increases 1.5 times. The sulphur content of tho feedstock
should be less than O.OZ%, e3p41!ftl_1Y' at 20 AtmOsPht-93 OPe-~tlc'n-
rer -'cw sulph-ir crudes (0.05-0.7% Sul-hur feel), 'he H"I '-a qm,)vO,I
r-.c.m the circulating gas with eth&n,)Ia=I-no, an! fr hll~e, sulphur
foods (greater than 0.-?% weight sulphur) hF!r:fI.,%1ng
,.u_
The catalyst can be reGonaratal by exl1daticn for stout
300.450 OC, with 0.8-1.5% of ox7jen In the gas hiah cirlulats at
10-20 atmospheres After 2,ibsaq,4a-t rejenoration, the arcmatLC
yield falls by 30:-0x. OxIdatic,n at higher -,~=peraturej (around
550 cC) Is Impracticable te~ause the -.Ata'73t be:=03 del~tlatel.
7ho most important crude fa-tor detar=.::,-e the yield of high
)ctans spirits. and arc=ztlos is the naphthone c~ztont. Scuthern
rMs (containtng st~~t ~Oj raphthone3) 1.5 times rare
c
ar,matics than Pastern cr.Aea (-omtjini-=;- &!,cut 2~,% ra;htheres),
th. difference bocc='Ing g-e.,Ite.- as higher t~I_'!ng fo~d3t0z;,3 &-,G
Used. At 90 0.%, sover!ty. the ~,C :uts yields 81:C motor
Card 2/3
spirit from Mastirn cruiii, and 91% frm S-"tharn crules.
o
participated In the wc-k.
v!
-
`Igura3, 4 tables and 17 references: 5 Soviet and
12 non-Soviet.
ASSOCIATION1 Vl;llnqrtakhlm, Glpron.fti:&,r~!d7
(VNIlneftekhim, 01proneft Wjrks)
Card 3/3
AbStracts
Vol- 48 NO. 5
10, 1954
and Physical Chemistry
ChMMOSIMMIff ICAM 101 So Jklm"exide 61 Ain-
=Miym 'K'C,,,'
Akad. Namb S.S.S.R.. OS". Min. SmA 1050. 41-5.
(Pb! 19M); cf. C-4. 43. 7956W, 44, M&~The use of jui
vnt - named sluminate oside of Al. in which the active
group appears to be AJOsNa, and which Is prepd. by treat-
ment of 2% No aluminate with COs. washing the pptd.
hydroxide. drying at 100-MO. and calcining at WO" 10
min., is discussed (cf. pece sibar.) - The applicability
and the 1= properties of this adsorbent an the own as
i those of juterm prepd. meardirig to Brockmann and
Scb6dder (C.A. 3S. 2X". G. M. Kew" -
0k 041
vo
r, -t1,
VO 1
1 1 L
I ~ 4 4 . ~ .
0 a a
34 a It
I mot a
t,
1 0 0 0 0 0 0 a
61
U It 0 a 0 a
1-.L- -� -,ff- -
1.
MMUS OXMS CONTAMING AUMIPIATK MR
CUROMATMMPNW w APALvAl. L N. G,#.. and
G. 0. SEIM& Oak* AM& 14" 70,1007-lo
it.
A compairskive study of a atephar af AIA pfprd",,, Wd
1
,b
f
l1
0
,
o
oe"m -0-6 albommits, Imitebts
A)r chrowAftr
bl
00 e ituphretwe of hate. AMM). te jwp.
o
CIP144,04 by M from a TwOrA solution a fthlo. JOW&I"d
TOP 111111-111141111 M So 16 WS "w" 004011IM). Me pregiptalte,
(Al
MO
0j
Ilh
d
a
.
to a chrom~hOk camteu, jkW
.
^
pwomobw sepwaft edbom 111rank mejective Ow"Ifte
- 10
0
'"9h Us No' km 111hem dantlawd for the separstims, of muouti.
It Is Previously treated &I* IN WWI, triumfor" it imo ago
(AJo0*)"AIO.IKI,, whkb "parake eakwo through Atelft"wo
aftharAp With So NO; kim. All Me magerstloom Awro very
matisfactorY. and Of ordwr Am wkbgh varifts Itmus are
Admortmed In that established by *hwab of a].
546. M It 937)). ?b~ letter authors used morch 'a prop -
AVAIIJUR of AISOA (&I=" COOftiMiNg MR) as stmodardleed by
Brochimman (later dmrftd by Brocksm et &I. in Bar_-74,
7341941)).
L A a S L A 41TALLUIMICAL LIT INOW C""ICATPON
a lo~ SI.,411W. all
51 &A 0--
0-1 IIIIAll w9l
rw 0 AT IN 5 Al a
1 1 IrA All L
U is a T. -.- I 'r I a I IS
0 U AV 43 TV TV IV IT is to it w It 9 4 a 41 at 0 61110 0
0
g I
0 0 a 0 0 0 : : : : : : : : S A db a a a
000000000000
0
'akademik, otvatstvennyy recialctor; GAPON, Te.N.; G'.InN, T.3.
ZHYPjMIITA, Ye.S.; RACHINSKIY, V.V.; BEMIKAYA, I.M.; SHUV"'Y-~'.'
ROGINSKIT, S.Z.; TANOVSKIT, N.I.; PUM. N.A.; KISIMZV' I. Ye.
SLINYAKOVA. I.B.; LHATSW. F.I.; LGSJIV'. I.P.; TROSTYARSKAYA, Te.B.;
TZVLDTA, A.S.; DAVANIOV, A.B.; SALDAM, K.M.; BRUIBEEID, Ye.K.; IHIDKOVA.
Z.V.; V=RnWA. N.Ye.; NAPOL'SKIT, S.A.; MIKHATLOVA, Te.A.; KAZANSKIY, B.A.;
RYABCHIKOV. D.I.; SHIKTAKIN, P.M.; KRITOVICH, V.L.;BUNDILI. A.A.: SAVINOV.
B.G.; YEW, V.P.; IPSHMN, Ya.A.
[I'lesearch in the field of chromatography transactions of the All-Union
Conference on Chromatography. November 21-24, 19501 Iseledovaniia v oblasti
khromatografti; trudy Vsesoinznogo soveshchaniia po khromatografii, 21-24
nolabria 1950 g. Moskva, Izd-vo Akademil rawJc SSSR. 1952. 225 -p.
(KI,'RA 6:5)
1. Akademiya nauk SSSR. Otdolonie khimicheskikh nauk.
(Chromatographi,! analysis)
Brit. Abst.
Sept. 1953
General Technique
Laboratoz7 Apparatus
2656. SeCondary adsorption of ions orn aluminated sk
aluminium oxide. G. M. Shuvieve and E. "N - 'Gjan
(J. anal, 'Chem., USMP 1953P 9, 50-52).--
Adsorption of cations on cation-exchange,41203 is
known (Schwab and Jockers, Angew. Ghem.9 1937p 50, 546)1~~,
to be accompanied by simultaneous adsorption ofanions-,:
when tile cations are multivalent. It is now
shown that simultaneous adsorption of cations occurs
on anion-exchange- Al 0 when the anions are
multivalent. An exp j 3
anation of these phenomena is
given, and examples of their occurrence in
chromatographic Vork are described. G. S. Smith.
-SHUVAYEVA, N.I. (Moskva)
I -
Pregnancy, birth and puerperium In certain Infectious diseases;
Felld. I akush, 22 no,937-14 S157 (MIRA 11:10)
(PMUNCT, CON]PLICATIOINS)
(LABM, COMPLICA"W)
SHUTAYEVA, V.I.
Courae of pregnancy and labor in women with pulmonary tuberculosis*'
Sov,med. 22 no*8:78-84 Ag 158 (KM n:10)
1. Is kafedry akusherstva i ginskologii (sav. - prof. Jr.N. Zhuak1n)
I Mookovskogo ordena Lenina neditsinskogo Instituta Isent leMoSechanovai
(PRZGNANCY, in rerioue die.
puls. tuberc.. prolM. (Rue))
(TUMCUU)SIS, PUIMOWART, in pregn.
pregn. (Rue))
SIMAYEVA, N. I.1 Candidate tied Sci (diss) -- "The course of pregnancy, birth,
Und the postnatal pericyl In tuberculosis patients". Moscow, 1959. 18 pp (Firdt
Moscow Order of Lenin Med Tnet im I. M. Sechenov), 200 copies (KLP No 24, 1959, 153)
An' , "mr~:d In thp n(nitron
of* enr.ched
nt- 3
('M::R,A IF:3)
S1fUVAYEVA, V.I.
Mechanical jaundice according to materials of the surgical
clinics of the Moscow Prov-Incial Scientific Research Cli-
nical Institute. Trudy mol. nauch. sotr. MCNIKI no.1950-54
r59 (KM 16:11)
1. Iz 1-y khirurgicheskoy kliniki Moskovskogo oblastnogo
nauchno-ioBledovatelli3kogo klJnicheskogo instituta imeni
Vladimirskogo.
4-
SFIUVAYEVAJ. V.I.
Cancer of the pancreas according to data from MUTIKI suz-
gical clinics. Vop. klin. pat. no.22103-107 161
(MM 16:12)
1. Iz 1-y kh-irurgicheskoy kliniki (zav. - dotsent N.I.
Makhov) Moskovskogo oblastnogo nauchno-issledovatel'skogo
klinicheskoeo instituta imeni Viadimirskogoo
?r CPF L I N I K o V 1, , Z , P. -, '-,~ f P I V A Yll", V A, Y P . F .
Dimorcaprol aL.- an against hexcnal. Natch. , - iy Hiraz.
med. inst, 15:41-42 162. 'URA 17-5)
1. Kafcdra farmakologii (zav, kafodroy - dotsent A.il-NIkulin)
Ryazariskogo mo-dl to I risk rgc Instit,ate irneni Pavlova.
SHUVCHIVSKIY, L.
Rapid repair of hearth bottoirs. Diul. TSIICR;,' nr,.2:33 161.
(MIKA 14:9)
1. Zavod IlAzovstall ".
(Open-hearth furnaces-Maintenance and
repair)
SHUVAYEVA, V. I.
Technic, indications, and diagnostic value 'of transhepatic
cholangiograpby. Khirurgiia 37 no.7:61-64- -T1 161.
(MIRA 15:4)
1. Iz 1-y khirurgicheskoy kliniki. (zav. - doktor meditsinskikh
nauk N. I. Malchov) Moskovskogo oblastnogo nauchno-issledovatell-
sko"o klinicheskogo instituta imeni M. F. Vladimirskogo.
(BILE DUCTS-IL4,DIOGRAPHY) (JAUNDICE)
SHUVYRIN, D., general-mayor
Types of security. Voen.-znan. 41 no.12:24 D 165. (WRA 18:12)
SHAKHOV, P.N.; SHUYER, A.M.
Standardization of column appar-a-tus of by-product coking plants*
Koko i khIm. no.5:32-39 '57. (MLRA 10:5)
1. Kharikovskiy filial Asuchno-Iseledovatel'skogo Inotituts,
khtmichookogo mashinostroyonlya.
(Distillation apparatus)
T I
AUTHORS: Shakhov, F.9. and Shuer, AI.M. 68-5-7/14
TITLE: Standardisation of column apparatus for coke oven works.
(Tipizatsiya kolonnykh apparatov koksokhimicheskikh
zavodov).
PERIODICAL: "Koks i Khimiyall (Coke and Chemistry), 1957, NO-5,
pp .37--79-M-. 5. S . 11. ) .
The anthors point out that some distillation equipment
used at present on coke ovens should be redesigned in the
light of modern knowledge of the hydrodynamics of a bubble
cup plate. As an example lime-ammonia and benzole distill-
ation columns are quoted. A review of various types of
cup bubble plates, types of overflow, their performancev
types of columns and methods of their assembly aud criter-
ia for the choice of diameter of steel and caft-:1ran col-
umns are given. Standardisation of distillation plates on
coke oven works and particularly on new works is recommen-
ded. This will lead to standardisation of the distillation
columns which will simplify trainimg of personnel with a
general improvement in operation. There are 13 figures and
3 references including 2 Slavic.
ASSOCIATION: Kharkov's branch of NIIKhIWASh. (Kharlkovskiy Filial
NIIKhIMMASh)..
AVAILABLE:
Card 1/1
TAVANETS, S.M., inzh.; SIRL)M,. L.A., inzh.; REMENNIK, L.M., inzh.; APANASHCHENKOI
V.G., inzh.; BRUSNITSYN, M.I., inzh.
Results of relaying railroad tracks in strip mines. Bezop. truda
v prom. 8 no-10:30-31 0 164. (MIRA 1?:11)
SHUYEV, M.T. [Shuiev, M.T.], mekhanik
Vacuum-regulator on a tractor. Makh. nAl'. honp. 14 no.6:23
Je 163. (MIRA 170)
1. Belokurakinskogo otdeleniya "Sillgoaptekhnikill Luganskoy oblasti.
KGZYULVP G.I., iqzh.; -. . ,
-7-7Z-'
Utilization of the he,-.--t of scaverging water. Prom. energ. 18
no.11:6-7 14 163. (MIM 16:12)
S/229/63/000/002/002/002
E081/E14l
AUTHORS: .3huygin, F.P., Engineer, and
!�hchukina, Ye.N., Candidate of Technical Sciences
TITLE: Fatigue characteristics of aluminium alloys used in
ship construction
PERIODICAL: Sudostroyeniye, no.2, 1963, 47-51
TEXT: Fatigue tests'up to about lo7 cycles on the aluminium
alloys AM9-5B, AM9-61 and Al-Zn-Mg. are described and discussed.
The results are compared with those of previous workers to ones*
the effect of various types of welded joint on the fatigue :trength.
,The effect of exposure to sea water on the fatigue strength in also!
measured. Conclusions: the alloy Al-Zn-l,,Ig has most favorable I
fatigue properties, both welded and unwelded; the best type of
angle welded construction investigated was a double aided
continuous seam; welded construction in aluminium alloy is
particularly sensitive to stress concentration; coatings which
protect aluminium in ships against sea water also prevent any
iadverse effects on fatigue properties.
There are 6 figures and 2 tables.
Card 1/1
A . . . . .
o-4-4-0- . .
4-w-w- 4v w-S-w--w--
I G of Ij I) W 11 16 11 0 3% MvMA11911 Uji bin hill N III Ali 41 4W U Ai 45
'A t L 0 L I G-11 A A 1 1- AA
L __L_ a N F 9 4 T. L I UP V. UP t& k d A 4
W,
f
"_
1011. mum ad ift I to 6 7011*06
1*
el -1, JUSS, Phys.-CAWM_1 4
_.u low,. I
Mu -84 19M)
cf. C. A.
-6=t
i~~
f
As
bt
i
d1h
d
di
k
1
1
t
l (
-
-
o
cvc
o o
a
n
roxy
)ptn
v
cyc
.
y
y
M
t5 to obbin
the attem
I
"
w
A
tim
Sk 76)
I
)
.
.
M
NNOW
.
JANUCY~
p
p
P
W
-
*O taftwe phow (1) by oxidation with Br%H, air to
i
h
i
i
TU
I
M
0
00
R
_ enewt I into do
k~ ve re-vu
ts.
4. ve aw) met w
NS
V1
t
negat
9
at rt-C produard a said. hyd boo difterent frows the .
-00
aim
I nttv results b-vv led to an laves4lipstian of
0
wft
ed W120-1W, 1;
;by:.&ryZ;iF;C t= r v
)
L
00
%. .W The w". refract
. - ion .1 JiMb I
ALK at SM1. b; wiffest
dm*v has 111 sbmscomAdevablit op*W decstwit. Tbrb1Sbcu*ff.u1;k;z;;); .
age
*0 jt almsany, 11 ft thats comaid"ble put of Ul is Present in tautancric (Mul) tam
d b
c
f M
d I
b
f
dd
t
d
f U
b
&
f tM
t
JU
kd =00
go'. %-
e
eive . o
ructures o
an
e e
u
a
e
w
om c
s
n
my
y
y
Sam 0d M in UK I of 1% wbmb instead of suboitution of H. for N at dm C
-
_*6
I
0, b way of an intermediate pyfatokisw to a
iE
FFCFW
C"
I
S
=100
.
.-
. (Clux-CI
.M.
~
u
tsk, icepiro-by4fticarbon' goo
H_ Cf a00
o0 (CHI).C 13-Tetramethylentbicyclobesaw (Y) teach with
ZIctf.m. goo
N- coo
aw4d.I and with 9z0#H Do& at &U. By antelytic
9,
b
l
fi
b
l& b
C
i
d
C
(016)
A
99
a Au
o
rrant.
racU
M
rucyc
Stow
& sP
e
I
,
y J15
R -
-
;-
_ W
Tfll;'
5~1647
~~
iG
i
JENiK
;~
KW5FW
W
w
.
i
,
,
.
E
o
ft
mw
bm
y no
n -I of IV, anif peady diffemnt from thow of IL Expd. Part.-The prem. of
air
said KOH
mu as a1c
EtON* (Wallach)
KOH
at
M ken IT with mKb a
-
.
.
.
.
g
AS* ~L A ItIALL
S 1,PfKAL 1.11tNAT"t CLASSIFICATICh Ef
wcm u is IT 14)
fig I I I I i I I I I I Ili
00
of
90
00
of
00
SO
of
00
00
00
00
00
90
00
*0
90
00
00
00
00
0 0 0 0 0 0 0 0 0 0 0
0 0 0 40 0 a 0 0 0
KCN-V up to *Mat kf#bcf Coadmationg-prudiKu, While pwfting vis 41V
om A of XW rusilps In a 410 yirld of I *11b ~kvfly no fommtr'"j by.
pn*-t& A milL of M &W ;C;~t sk. Koll Is allowed to) co;A' then borat"I 1.5 bit
as dw Water both, trailed with HA the olly Jay" estd. with 11103. dfW with OW
KOH, the 91*0 capriled. awl dWd. im; smociso. too. 116- a', a". 1.3211. 4:" 1.017.2; GLIM
m. 12""; sunkarbammum mL 167-70* (Avomww); bydnuumv, ML 1111-404" (dricamPL).
M abbilmed by bNaft IV 4 hIL UM 10% MuNd KCN. sof 1.510. 4? IAIM his
Is. W"'. The 11100ims hsop M-00" oom siminymms. from Wit us. 61-4'
th. L P. 76.1". amd wo
by dim". 110 Ito W 1u is
V L"1111
of KOJI =d M bousting with 4M. AcOK wa%bWg wilb 11.0 to & NrWd W
gift KA)Q6 Wd Wift digs. am �WWW Na. adedsms lhemiiL ~ We
aft KNOD, Mid Dr. bwo M-00". 4 LMK dV 0.9011. V p -11- WM KMMU
W Pk~ML 11141114011180 MM VIM 010M. BY Imaging V 3 timme mow PI-C of 1110-
mid -bwqmmdy dft- WVW NO IN 416111imid VIL bm 134-b". Alf 1.4701, is,* IAMI.
dof OWK which neft wift KU*% vary dMy. and on &hydmpmtka gross, ptc_
at 30D* shows; no she I-Clodom -Wk
hydrad-mg =atajw. (M. was obtalmed by dr
RW. by ftdmtiou of M with xe in sq.
_4V= boo., IM41". as,* 1.4054% dr OAM& rwb with XMno, and ar, ow wbm
MCIUM am PI-C 84 190" givm EL C*cbmpmIVI-2.cycIoSmnj&ouw& M, chmiud
*Issm 35 6. of m Is mbw vrft ND cc of 00 Ad)H. to which is added 17 g. of CvOs
imaDeLookliP.&M bob bbowd 30 wift dw water bath. dild. wkh IlsO. time 44y
layer wvd.. washed with MO. dried with ca&dwd KiC(N. ¬ ndkd,. tho 111-3';
W1116cWhAmm. M. 210". W 01rioid. 8',' IAM. Prepe. of U. The hydruspne was
Pena. by heating on at WSW bob = a. ut K wish 11 5 a. of NfI14. 11#0 in *I&. tow
on&& portmidect was Armawd. with KOH in Primmer of lot "(kr. drioxf with Cos"
and over Na. how IN-W.60, 418 ojM spt.' t.*m CIVAIL RLAWe
0 0 0
00
00
00
00
so
so
so
00
00
00
00
00
09
00
*0
00
00
00
0
0 0 0 0 0 0 0 0 9 0 0 0 9 0 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 9 0 0 0 0 a 0 0 0 0 0 0
IN ~lv;
P 0 P me 1~ 'y 11 14 1$ 14 $1 Is )l V;2172 DUB 26)7n)9 Lp 1;1) Ma Mr m om
4 V Y T L %A 44 W if
'~q *
4
a orba" cyd"""MgFdWi~iio~o MW bkyg""?L M. 1)
7
:
.
tutflamAmLILY&Tmw. J.roM.CAoIL(U.S.&k.)J,d71-M)
ZoLtsmal.N.
-sa
OW32); -t- C. A. 23, 2M-11 ow shown 1 0, - dot the by4mimt algeJaprotyl- i-00
idruecjclopentAWW.CW(CjW -C -(CMa)%-CHaM.brdKampiLwnbpowd.Pt
L Lf! -00
AM KOJI gives not the rspwttd cTchwop -0 0
bicyclabessar. A simikr nuction with the *00
(U) proceeds ourinally wM do I
oo
P
M
i
I f
ulse
ett.
peewiarevar
,
sab md Gari
(C
A
d hi
h
h
d f
"" bli
d i
.
.
e two
nwt
d
m c
r
ow
n t
s
a
219-31 -
X17-8- and
h
h
3W
d
i
l
W d W
4
Mi
al- e
n
ot
) owpixte
t
oo
im
,
19.
gM
,
l
JS
IM
A
) =00
Mu
=&I . lowing IhaW -chodou an do am, d ftom (
W. as.
M
W
MAI(CTM"I). HAtML &Vd& (C. A.S6,2112) tfi~d that by6diptindowal
ZOO
stoma go" is ftmed I
L -7-7.
-
'
-00
sche I
w
ith I cd an
ppwftd. WWBh is
16
0 cyck"tar. The latur aim by bamw! 0 lkc
0 & a tWbt 3 ponadaluMM d IV d K Md CL to do dthYdrotim
4"S
h
Y
k
b
=
go Mor
4
a
). wit
ldw
(
d-:-owA
ith ft Z"J 1
clAw
deftsdow M)
c
d
difi
t t
i
i ~2: -
S
~ -
tren
lat
m a
,
a
ype w
y
y
y
i -
o0
0*
*
*
9 -h au nbuiord by ddWdmdm of wt (VIM). with
wh
.
I I-OMMO-1-C tram of
-
KHSO~ VI by redurflixi
'
-
-
-
0
t h
uiw
d
tyY W
aVwb (C. A. 1.
which prawat is IV w0 depIm its PbYL conaft F"
0
l 1116) by heating V with Ml dmms vary low p&vL coulft, bm 225.3~7 ', or 1.4701, d.**
o 14SWI. as compared with the meow al Cjlw obluitiod by the mum to"W. b,. 236.&
-lbcami%t.cllVwithitsp"__-
ucts of immerintion, IV was obtained by debydrsticts al i-cydo4vxykydoA#xaxol JM)
abd"ductimoltherandfing
ffifT ALLIJPGKAL LITFRAT601 tMOO
lee
ami
j;75
It;
.1. J:- I A I --r 11 ~11
'
r
F
l u
b
Al I I " ;
'
'
- i ' -
1 If " Oj
I e OW a a
rp cy It 0- 44 K a W a tr if it at n I so
0 0 0 0 0 * e & 0 0 0 0 0 0 0 010 0 0 0 0 0 a 0 0 a a 0 0 0 0 0 0 0 0 0 9i
0 0 0 0000 0 00 0 # 00 0 0 O's 0 00 0 0000 go 000 *,oggo,-,
0 0 0 0 0 0 a a 0 0 o a a 4 0
30W-1). b. 2U*. %V 1.4-.K Ar O.M7. Timm do Pnowtift of the 3 tinvas. of IV
obijuned by different methadS. and Ow rvmdta of IL mod N. (L c.) do not amem to te
the exiamm of Ste twimommit k I of IV. Howam tkm wm obtWwd 2 .4d
IV differing com&krW* Immmi tbow dewribed Omm whith "a Pos. =7 'j.
pom4ble eximem of mWiall immmaim, w IT. by dry 00
00 WM 0% RON. ba 14$-M'. a%? 1.308k 41.1 LUM.
00
00 nsol, rdr. W.W. cmk,& 8174- - ' I _ , eL 1"'. SK pnV& 6m the by-
dranow of n by repated iW& 09W 5% 00 1909 in war pnwnm a# pletimind
$
=64'
lum
li
b
1
4N
A
i
m.
.
is
O
k in
IOV. Md. Nk. 10.40. cmkd. 62.78. V saw Pr"d.
, W~ 90
117 Mducing wil or cychlimmomme, bw *V IAM. in tbriedwe im the
CO group of n is reduced to sk- bdm the now al the dmbk boad, witli Comatim of a- 00
cyclobesylidenecyclohexamoll. bw IW4** ~V 1.3M, d9a4 1.0014. mol. Mr. 63.75. caled. 00
5427. Tim atswu of /I/ In T do marmimme how.-(a) A mixt. ol 25 C. noway . V and
*
3vokollil(d li)*I)
b
d26b
O
00
00 was
~ntt
t~-10
matl
inowak tube. then the Wide ww
treated in the cold with Zu dust in the onsence of Hl. and broiled. the hvdroeattxm distd. 00
00 of
00 00
00 of
00 00
00 00
00 0
00 00
00
00 00
00 00
00 00
0
L 000000000000000000090ooooosooogoosoooooooo
0 * 0 q 9 9 * a 0 0 0 0 o 0 * 0 0 0 0 0 0 0 0
:000000*900000099909
mond
~
~ ro
i
~
4
i
wa
I
a ad a 16 J7 A A
m
OU111,1111611
9 j 3
1 it 0 a .1 40 4n@
.
fj -.1 -1 "g.r.
60.0
00, pi
rr.listii.ov"Ns*Vasw4owfPt-&OPMO$in flat ""*'&g`ds It
00 - 'botl 4.vf Na. Its .12. . ism 23111.44. . sit 1.4w. do% 0 '114112 a" Mr 6,136, Va"- Ing
l
h
l
;~
ih
d
41
s"re sms o
-
-V I
&1 dr
r
-
r
C'.11. (IV) U, Z1. 'IV wtookil"S WHIA "IN (d. 1
T
00 a
III
oW, (b) A mist. Of 4o S. cryAI. V mW 4 wok. (to
phis, vytau figorit sk-. In. 00-
*
j
0 witimput a rumst. on. p.,
in 6 stated tube, Y--
heat"I 9 Ism. at 3WiO
relf
IAW d" 0 low
now
2
Ar
)
.
.
SI-
.
. OV
rve 1.5 S.. b. I Ow.
which. rrpratedly irdisid.4
14,; M411wr free-
2W 4
Car.
M.54, and to S. h.
M - AT I- . PM suu-
l
2
w" at -
1
gum crysta
=5-7 '
iled
d
m
i
A PI
I
d6Wd I
C
00 ji- -
an
a
m
V
s.
t
duced chivily no, the a n
.
Ivir C.211". =. "I Vow hosted 9 brig. St:p0-m*
(c) A inixt. of 3M a, life
I andetpe tedly redistd., 3 kwdm.- 3 S.. b. ODO-21 *. wV 1.4477. 16 #.. h. Z0-
'
- '
0! torshaustivedehydn*cm-
X',mW 1.472?1, awl III? 1.4M. X
j
I .
00. a! uKbm~K wWk the other 2. coafg. co-iiier-
tion over 14-C, the lot fise
'
00
1 . and the
able IV. gave good Yields of Pho. urbick NU I am mw Ghend n# at -10
'
. . then ftPMt d.. giving 3 fractions: I a.,
residue passed over PI-C at 210-20
001 I and 5 a., b. 2M" 5'. mV d:'
l free
0,97)8, nwl. a 5.3.4.,,, Now of the tioussubdifiedst-W. Theprolmoirlitsoltbe
~ Alitnethylbk7elo-
ion 1). 220-85* indicate its interignerfigItc position betoreen 3,1-
e
I :o: Arrityl. 1). 21341'. mW JAW. d:1 Amm, end IV, mW is considered as consisting ChiedY
. macrixat~m of some
a pmduct of a profound im
ts**
S L A .1 1FALLLIPLAC-L LITCO.ftlif C:tAjj6FAC4rtCM
'41, 3.1
Is AV .3
I
1
Ago A
(#ft
;
"
It '904 in't "It
.
t
1. a I
1
0 0 0 0
0*
VII wasobtaliard 1,.,W S. 041 t"Vtbrf with other "Mdessatino
tf
&mi Cjl,,141 p: Vll b. III,.. %.
, I 40K., d'.
Wtfraled with KIISO
St jpm;~qij- 00
0 .
havil Vill, Iv 1.4M=d 8 0.00. mini. gdr. &l.06. C&". lm C,.Iil. 52
Vll"ffAumd ovrr Pt.C at Ar.
r
d VW
dl
d 00
00
0
0 o
si
, re
p
. ever No. &-V. or 1.470 1.
d:-01*44I.fistil frk.Un. VtU dm suit M'JWIfY at -- 20". atid k,-Iv r~wtnlil" tlw 00
* traction it. WO X*oMaltaidtly theislossirtkimiallfaimill Ill at
00 4 at 210" ovw P44alimptatim, at a MI@ of 4 -S,InV~ 1W..b,d IV, 00
00
k c4mvrrtcd tit Phs by dehydrigitimatim with Pd-asbintim; at 305'in a umh cumnt al H 90
0 .
11 Was Obtaiwd by interwtimis of Cimt%MfBr and cyckilwittoonte. FfunslWaAwativio- 00
00 cyriabexamic resulted 50 ji. M, be.. 136-5 . his,* 1211-9*. anti 14 g. IV, h. _117.5 M% m.
" 00
Os -12
. mi? 14942 dl* OW14 tool. Mr. A3.115. M heat"I with KIISO.sl
produredl. b. zwfli~ths_s 105"and 4& I(M)"
19*014W
mit' 141010
f
41
4
5
00
.
nu
rr
r
0
2:
.
eakNI. ftw C,.Ilto W.75. I redwed &I 221~-6'ovvr It-C pr;~lucvd IV: 1, 2375'
' 90
tit 3 A 4
. at: LAM. d:' 0.141147. inol. rrfr. 53 -14. CHAIV BLANC
00
09 00
*0 00
go 00
00 00
of 00
00 00
00 00
00 *0
00 00
a
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
0 0 0 0 9 0 * 9 0 0 0 0 0 0 0 0 0 0 0 0 0 0
IV
'
'
N
69 0 O - W W
10 1 0
0 0 0 6 0 0 0 0 6 0 9 0
0
Op 60
14 if
811111111114
U
A A L -11- L I _k a I L -I
.p ... ...
.09
0.60441 1 __
peoctstit ..D .6001-fles, .Del -00
M_ Radom - I - - , id tosses Sam asnums Catalysc
I
d
d
C
d
m
o -00
~ "t,
..ka
~
amp. fea
1). Zrhoa
l an
N I
M
r
.00
oo . I , -German64-5)~Hydro-
06 sefttionalfwmmWksdmlv AntleavagowphoserrithNi .00
coulyKe opeast the rime And fulmis stics. And mid. hydr.s.
is "aced with
est the vin
r
en
At hi
h
b
.00
e
tr
ons.
car
g
p
g
thorulty. CH in MIS a adlable catalyst (ow norlear rellut.- -00
0 IkX1 With reituerd
2-
prnlww-I
&nitd b
ale
acetm
ll
far
l
h
d
.00
,
ru
.
.
to tetro
ur
y
p
y
y
dial. prataset-1,3-diol aml pratax-l-ol. With the aid ,f
.00
to IM-chercoal CAllaMill,011 has been reduced to C.11,
100' 3t)% Pt-activated cbermal or
0H
M
00
00 a ass
.
4
19% Pt-ambewas have very little effect onsylvam (1) in the
*
over 20% Pt-
vapm pluses. A 4-fuld reWtition at If3O
ist. of tetrohydroturan. tetrishydrosyl-
chwcoW
00 3
VAN, bu Anti protan-2-al. Furfural was con-
2.r
=
00 vetted According to the method of Wolff (C. A. 7. 790)
join 1. whit* ddfrr dialn. gave C6140. 1,,a G1 4', if:*
zoo
s,
w
00 0.0"), aV I.,L141, At. It. W-141 (called. X1.41). 1 w
*
d
V
) Moo
oo
0
00
0 --
vAP*w
At
A
and carried at the rate of 4-5 thops per S
min. in a stream of it over a 25-cm. I&M of kmecly pacjwd
00
::
0 23% OB-Obbeetap 1111 AN &-asse. glass tube. The redeced
material Was collected in a chNird recivrr. It alsolmd
Ii zoo
ftle cleaw of a an a reprtitioa 0( the feduclit)a procev..
"00
Me PnAtwt &flew distn. over No S&vr trl,Ahyj1r_yjvAn.
Call-0- bm 714.4-40)-. Q- OAW. aV I U. K. 24,-,J 00
I"Ak'41- 24-78). Thus 0% i, A unique catmayso f,w the
smooth hydrollessation of furen &givv. in lip.- vapor pim,,
without ring Cgravolle.
C. K. Addinall
s
4-
1
;
A I i L ot CLASSIFICATION
-~?ALLUQGKAL LITEMAI 1 moo
~
i
------------------
It i
-
-
e0
U
a AV AD ASI;
p
'
" -AAL Selma malmosAll a
-
- T
9
o
4
0::::::i
7
l
o ; z a ; o
o
o
o i
f goo
. 00 o 000600*0000 0
t
.0
I o o 0 0.
/
o
*oo*oooo000
o
o
o
4
lo 00000*00*0006000*oofooll
a W-IV-W- IV 16~
0
0 0 0 0 1
I W) 11 1) m
JL -I.- a -J, -
0 0 ~A A L 9 A-1.
00 ja
00 cyde
96 A. I
V. A
00 it rileth
040 fori'll
12,11
ke #-
00 romp
00 the t
00 tactii
-fight
00 1 calall
*0 drivil
20M)
000
00 1
.!;
00 it
1-1
00 ri
*-- 0
9 UP V W w
;T-N
; 0
0 0 6 0 4 e 0 0
0
0 0
-
we
1
0
it it l
e 13, 30 V A N * 11 U U 11 11 11 11 m U it mit*
l
R I 'U. a (X I EK --I t', - - -!--r Ad 040
..v
im) ..0f.$
mell ad the =
"t!r of meftyl.
4=0S:
.,
nimmist soi a W C."St. A.
.
Wriglin and N. 1. Shuikin. Aria : -00
r. S. 1. 210-11(10,14)(in- GertnanI.-By the tame .00
as for diturthyleyclohexame ((. .1. ZS. 71'--7#t ih,
Of MictivOlitill! for rol%[%. with 04414-C Inflictor it -00
rat. and the value of lit In the equation tit k
' .400
/7
is 5.9 x login the temp. range 29(W) 851. L)C.
with embamme farmation is negligible e%rrpt in .00
ene-rkb mixts. The toluene half period .4 &,1- 11160
in gmster than that for methyle)-clohe-sne and
d
h 00
erreaws t
e rate of dehydr,wenati-m The =
was prepil. by reduction of the inktil oxiolr%
' zoo
120
(Zelin%k! and Rommatevski, C. A. 18,
*
6i
d
h
d oo
rst
e
rating at 2Y)
and then slowly rai-ing
F
y z
to 350' liver a perinif of 30 hm Thr artivity '00
Alyst it slightly 1"% 111#411 that of little Ni Iftilit'"i
tout r"Altl% i14 at-livili, moth li-ogel. 'Ihe
it rmcfioti is slightly greater lliAn for cyclo-
F. It. RAthmann
'
i
1
P
t
WW I
j
00 S
00 t ;44Y.; vv -!,A
4"a
761 U " d3 it It it N Of Is it q U it r, - 666664 see 4
0 0 0 0 0, a 4
0 0000000
fG000000001,01,0006000000 0000000000000
R
0 1 1 4 1 1 a Ii it 11 14 is 16 it If If a b - M P
LI A go
of A
A a L-I AA JL-j-L-L a 11"r .0
fj- I L d -s-
Ye 0
paccessit .%a F's s
0
T -
0
A
,
s
"
Mal WO 6 ml~. I~fkft Oc"
14 cl "
i
It
ft 11
*
"
4 ades of 2 -cyd"tykydapra&mw.
F !a
t
N-I~ftmffift-
i. Rep
is. mos"m _u4se U.M. 19", N..
.3. 197-21)2.-2-CyckpmtykTcjopentanaI awl ZnCl, (1t#)-.
0
hrs.) yield a'.'-amt A"-witthydrtmisplathalcur J).
;I.kb with IfOr YieWs 9-brumudecabytirmplathaktw .00
KI this yield* pure I when ImAled with EtOH-KOH. -00
B. C. A.
.00
,
00 'j Zoo
Os 400
00 see
00
Os I free
zoo
see
see
see
1114110
a SITALLUQGKAL LITINATLOR CLAS%IPKAIIC& 800
lei
; I Slow
-
1
-- - --0
a-- ant see
-A
1.0moso
U U AV 00 It
; I Wa
; It a -1 a a No
,
0 0 0 0 0 0 0 0 0 0 0 0 0 a ; 0
-
1% W W Iff jr Iff JUX INF
W
a I G itivilliliku4ils Ify
J a it J? u if a a At Is p a do u a
.Er
00"
a. I I LA-A
LM a GIC K a
it- &_
1,
1 1. 1- '.
. too "age,
A plic"M CONT"ON of cychlbouse In, the pivistift" of 0
0 swami calostylve N. I), Min't it 411.1 'N 1-hulkin. -00
9 CoNspe. FrOd. a. LsJ. 1.$. 11. R. S. S. J. 2153 Nill (Actillan.
1 -00
0)(11M). -its the pfcanii %4 4 NI VAWY-t 11111d. 1111
2.
'
9411
midrisr,"
Affoll is. eveUentins, (1) in 11 wits. mat Alt )-&) .
V. &vLnvrri-OO with the bwo 4 11
= see
hOrtinvi-Evist. Ahmom wills a debyd
I
*
- 14ke' PISIV Willi IbC tWMS-
-11 Clegy
1
1
1
W
C
H
4
00 1
1
-
00
O1
s Is
0
.
1
lion td trew CHO sitlikvis. rhe- we, to awt. rRvivivia #,,
Cffs Alfid In PdFt (IMMINIME Willi file COIL MOM the 1111001CM1
ee
I t., Awns CALcue. xylene. til,thvieviclahirvact, wed di- S s
C. R. Addiusill go*
see
LITIOLL11,8C CLASSWKAItGw
44,
j a- J-9-4-1
b u s AV so
000.0 so
0 0 0 *:6 0 0 : : 4
00
01
Joe*
00
woo
goo
DIALli-aw E.- ill
&
: 0,
0 0 0 0 0 0
0 0 0 0 0 9 0 0 * 0 0 * 0 0
a 0 a 0 0 0 0 0 0 0 a a a 0 also Sim a~ff,~ABI&AG a a it a
0 6 0 0 0 0 a 0 a 0 0 a 1 11 0 0 4 0 0 0 0 0 0 0 a,
j I I)& to 116IIIJI)IJ it fy is It a a ails jivapiall LIU its itu Jose it
L A_L_f-_fi_A A _A_L 4,11 r 9 1 1 V -1 -1-A-M 111 9 4.1-A 1 ~ I.-A. t . g 1~ I A-9 -1.
yi~ - "1 0 a t ..t. ... ". qa~t~! - - - I- t 0
00
00 CIA-"
00 '40** aragaidsadw of XWO-Sepadwa (ittabla) 9. 4 the naothis frwtiOR was p-d 3 times tbrol*b the -*a
tube at XW in very dil. Its at 0.5 cc./min. NO Oidko
00 1: N~PbMa. N. D Zelinakil and - N I 'Slkiuaia i Goo. The issrollossoorts '00
CA#". W. S. 8 R.) 4. 'n.* wirrop fiwwr4l. Itifech. klaws
plithe the several Itartkinis vejq%t friars &A to, 10.071. -so
hawti-in (1) .4 N.w-Kostailulah twitiWoruso, atumust. to, in It in
the Ifilsest lollsorivird twills with the frarlisou 11, %ill 111)
00 a Vol, lot thr vindor tell. A lasuiple lot I was desoull"liahl , the let -00
Still 11SCil. drwd ,veff CoU. and Iractlostoosted over No Ih-hpltusenallcorl 111111% INSCIK-4117 V-411911"t" &fit
so or passage. The mine frwtkms Ifulls I were aliks dchydros- -00
00 r lmt,,t ith 4o S. Ni (&) cm.) an A" (Zefirtakit and 0^ gas
slumn. Arnmatic compsis. (U) well, Komarevskil, C. A. 18. 21045) in a &I&" tube lit Internal
00 j deld."Its"nod"CacutlZ by two metticklm. in The fractions 3 dill,1111. 16 mm- Usid"s' the agme ezPd' con't"t"ase se 'a the
**a The variusup fract I ptun-C expt. The catalyst diried at 130" bell high
b. VU~- 175% U ammuted to (11111.4%. Uns thyl. Goo
In- I SIM dehydriyornated covirr Pt an activated C activity after reductinn in a stream Of Its at 330". we
sea e being complortely debYtirugfmtfd Oft" Ow 411141111111111
00%) in a Cu tube of Internet diam. 21) mm. The tube cycwhtzw
00 fifted mccessoi.otly swith 10 a. catalyst (14 con.) to palossage. N. alefins, were produt . Mork. k="
amosuntedtolli-10%. The Yields of U seem 1-2.5% high"
oe lemsive I races Of S. a *ral of As wit e (4 cm.). and 21) g
catalyst (2111 cm.) far the l1rhydrioxcluitif"l. Furly-fiv with the Ni catalvvt. The neAllsoo rwooplookilaing after ror see
so oll"Val If 11 PIMISICed fly calalw-in hall a Ism" TolshossoCtione are 0
food" NMI h. I.- than Woolf. Irhv,fr,.~ i ikon The It
I "Mtents a# somw Otw nsphth" -wre lnr"al"l Inx" 1% ;so*
toy treatment with the Ni Catalyst in a C11 00
tutte. Tsillesoftiostis are given. Novo-PAWlivAksawbe
is rK hydrtsisrusnatic rtsing"Ps. than other varieties. :011111
it tConn. smar" f'xr It. I elpriss W. Puts
i,
.1=
es
-206
A I a - S L A &I WALLUROCAL LITIRATOF CLAISSIPICATION see
-An -t is a. is a is I OF a 9 a a 9
I ism
1~. ~.01'81 So,
0
:900010000000000*000 Is 9 0 0 0 0 0 0 0 0 0 9 011114111411041111
4- -o- 0-6 4-0 _6 CP
a a 00 a0
14 to if 4 It M
-
L!!-jLn
-PA IN Q M? ILI 0 b V 0 P 6 41 41 AA
- - . .
:- ; , . - , 00
-,.
600101 --
VIC
111% ..Q #I. -Uj.,
C1
Isis
06
The scope.
Ive astlow of mixed catalysts In the simultaneous
t
00 si-
dehydration of
thyl alcohol and asmoula,2.1. ShU41M, A.A. Balandin
-00
00 and Z.1. Plo e J, Gos* Chose (U.SeSeRe) 4. 1444-60 (1934).- The
.00
0 0 dehydrating me cm at mixed catalysts ecstg. A1203 with one other -00
oxide was canp d with that of Pure A1203. The dehydration of 1&1 .00
Sol. Sixt. of I # studied. The alzod catalysts contained
ad NR3 on
00 j - io% re2ol, 20% 10% SnO and 10% 260- reap. the reaction temps.
r203
.
were 300 . 330 ,
$60 , and 400% The resotion vessel was a glass tube
00
000 18 sm. In dime oontgo a layer of catalyst, dried at 1600, 30 on. lose
The NH3 088 In used at a rate of 66 -60 cc./ min. and the ale t
e
1.6 0000 &in. oxPt
In each expt. 20 cc of ale. was passed. In 2 . C5
H&V derive. we reemed. W"k A1203 "203 at 3600 and 4WO the yield
j"69
of smines was GGIND 66 with A120 In the sees of all the other
t
d U
l '00
mixed catalysts s ro
s
ormation me lower an
a rate of mine ~,Oe
!DqJ
of ale. dobvdra an higkor. The properties of the aixed eatalvats as" t use
be regarded as summation of the properties or the component oxides.
1
e o'
0
g
J, I j L A TALiIJRGKAL L1799.1 CLASIWKATIGO- w
w
0:
a
T
a A, a
,
it
t
`t0
0, 0 0 0 0 0 0 0 0 0 0 0
4 U r9 It V
0 0 0 0 0 10
-------- -- go
1--V-74- ; -0
1A A s 4 ad a 4 8 1 w so 9 &a 4 3
ia A I in do I
0 a 94 0 0 0 0 0 0 a 0 0 0 0 0 a 0 0 0 all
~
00
4
0000414100
go 00000 go 0 0 0 0 0 0 0
4
0
00
so
of The data are
00
00
of
00
09
go
so
90
00
&0
4
00
0 0
00
00
00
00
00
00
00
0*49000*09900
0*00*00*00000
*000 0 9 see* 00000 ego** go**
00
00
ifcuf$sd frm the vlenolnt of the sultiplet thoorp t:
00
Lawls W. But&.
90
00
00
00
00
00
90
00
00
00
00
00
9
0
0
00000&S90&969090009000900000
:1 h4 1
L a k j a j L Q
The comparative actlai
so othyl alcohol and aniline.
00 Z Shulidn. A. A. Balandin, i
00 (1934'--fto dehydration ad
00 the dome catalyst* " veri
*0 In addn. with A;LOO(95%) -
*0 ale. soln. was 1-ntroduced
" * Results folim"
00
00 Catalyst
00
00-
00 AILO J
00 F%k.0.3~
Sno
AN
JWWO
.0
Cr
:
Ak
0-1
it %
A]&
~ C
O;ZnO
A~
,
PhMN,!Ith ale. to d
00 t
00 4
M or a
0
IP
11 jb :7 :3 h
U y I A& ft W U P
-~V
of mixed catal"to in the simItanscum dehydration of .00
The catalytic proper tirns of othylantliniv. W. 1. 60
P. T. Vulmov. J. Gen. Chow. (u. s. s. n.) 4. IU51-7 ~
a 2:2.9 mol. mixt. of PbOxand ale. was studied with -00
00
us" for ale. said IM (cf. preceding abstract) and
NIO (5%). The tempe were 350* and 4000. fte PhV- .00
nto the reaction vabool at the rate of 12 cc./hr. The
. of max. PMJ6 Yield yield
MY
rsion ofPhJ1H Converted of of
67.5 &-3 3.2 .00
52.9 2.2 0-7
~ 4*0
50.2
8.7 1.5 AO
4
43.2 3.2 traces
35.5 38.4 0.1 ;~Oe,
31.6 31-6 true0d,
ted at a hieher rats, than IM under the sems condition.
Lewis. W. Buts.
;g
74
4 4
4
0 0 0 0 o o 0 0 o
8
I u 4
0 I
V 1! 11. ~1.1
~
I.. A. Feder. J. Applid
U. S. S aii) T. I IW
26(l
Ww).-Ihbf. is hydragegi.
ps'"Ne lowher with I..'1011 vapo" at 1;0-210*
ated by
I
I
mr NI ppid. on A4(),. W"bY um hykychihcuo,, is
wild. amd RION The boo pruftm
umnP' 'a Igo' NW..Ib~.*W of Methytrychohrlimine is Shgo
of of the tbm, ~4 W"y&_KM. .,W
iJ 1 0
Sillidw 1 1
"1 444ird
IMIMI 'be dthy4rQ h drtqcmgso I
1
1
sho Pill:
9
1:1
4- Iltli
00
66
00
0=0
00
66.1
-00
~
14"
t tAlt J-40C.L LMN.Tto! -A-WFICAUCh
~
-
1
PC It
_
"
, oil,
III-
An I 1 0 cw a
"
~
114
a it Do If a q
1
0
v
9
6
~
19
IM
0909000060;90;
0
: oo~
: :
06
00000,0 6
0
o
0000000-0004 S
0
0
;o 0 0 0 o o o 0 Is o o 0 o 0 00 i
4 , 6 , 8 11 14 is 16 1? N AVA29 X), 1211 3415 MU 1619 a 41 41 41 d 1:10
00 -A, A-C a I I f, a I I L A-M r- g R I I u 0
00
00
00.,
00
Ropwft d im ft dome m is out by W. D. Z~MskU
dw, M-1-MemmidiRs"OffIG&WOVIIIIIII. P.P.Bori!A)v
00 d N. 1. Shuikin. Neflysisim Kbocwkaw 26. No. 3.
::
00 myrrint Z.'s fA Yesr%' rewsurch se-
tiviticq. including #Avmc 4-4 hiq unpublinhelf warks.
00 A. A. 11-htlingk
-00
X00
-00
.00
.00
00 a '00
as
lea
ts 00
Is LA ALLURGICAL LITINATLOt CLASSIFOCATICIO
$#nos* -j %vilillp., .1 4.. a.(
T
~
!
r
, two oll 1111wellad 29 .
0
a a 416 j a j I a g S
: 4 000000000 000
: :!A
a
!0 0000 0 4 06 0 0 0 0 0 0 0 0 0 0!0 0 000000 161010 0 0 0
&OCOMPGastas. 00081 fur 1 10 31 12 s k V J's it a 41 v At do 0
It Co AV v Ts
;1R 99
fee
so
*oil 00
00
0
j-00
IP oe
Go= Au"ff akl" IMISM IH.144a aqp PIM 00
009 .1 roe
-"I p--pd -9 3nq -)ua"sd 9 jo saow) aql aA-31
00, SISAMW aqL '16MAMR3 so ld in to" an IN S"G .0w,
iv H qi!s asvmM Aq *"W- 311- ol pa)-OojpAq
&p Aplaidum lomis an Otl-fll I pw jZt-qt q *oO!i
%q (%09 1"9) 'NA-P m p- -mrQpA3
00
'N Pen Fl-.,Oz a -N 'Sillpsw (SWR
re go
00- 00
'L to.
oor-1 -; I A I
030 - nzy its"ll am apt
a n if of ii-M -R~w a it fz it f? a &I It it Of 11 44 C. r. a,
0 '90 0-0 0 0 0 0 9 0 0 Go 0 0 0 0 0 0 0 0 0 0
A 0 0 0 00 00 0 0 0 st 0 0 0 0 0 0
a 0 0
M 0
,
- 0 W 0, -4-
S WI
"
it it if 0 14 It
it U Is "if W,
dl
5 U11 Ida flu
iinai
41 46-a-
A A.-c- a IF IF r. 0 1 a L 4
-A
l
L
V.09.1
-PC< I)SO I ..c OcIf."j,
/Catalytic desulturization of dismounts letain Barg.s.
00 propelit" Grid Kashpirs shalsm at ordistairy presswAr.
- N
l
"I
kil
l
ik
A V
F
I
il
I
00
Ov f
Ill
.
.
atil
~ffllfl
-
til AI
.
tp
ff
N. Fitt, N
KA..z%jiti- S111.1:i5i, Jim armAlturtlAtItaf
- .
K4"IlMII%AI,ftftkIl4.I6t in flit pfewo%vol
.4 flit
a0*
wkichwasprelid. froni
freating Prit It caustic soila to slishtlv alk. reaction 111) lips.
The ll)Aroxides). The product W24 Wahed Willi W.Iftr
3 nd ( ticed in a I-., of H,, The destilfurization wj~
"d
~k
-
of v erf ,,b
,
ga~olinr cuntil. up to S~ A
X..."911tte desulturisation was obtained with ga~nliue, It---
00 a to S. while those high in S needed a repeated treatint-tit.
~he catalv&t was poi%orted after a compar"fivelv 4116wt
400"
t
t
Thi
b
l
h
h
d
h
it vau,r
t
e
nor.
est
emp. wit,
t
~
. a
oug
formation of un4ard. rotriptis. and a lrm% in the i;2~lin,-
'Irld. A. A. l1nehrlinxii
j;
A A MITALLUAIGICAL LITIERAUNE CLASSIMATIOM I Z_
S4804,p .41 k~, ON( qjjsiiii~c7 .9111, d., M
31
U a AV .0 is 0 IV III P, Of It III n I ~14
0 0 0 0* '*a 0* "
0 0 0 0 0 0 0 0 0 111 0 0 0 0
1111-ii 00 ~O 0 0 0 000 00 0900011.90 0 0 ii a a 0 0 0 0 6 4 le, 0 0 * v 0 9 0 0-
w w Is Is 9 0 0 9 0 0 0 0 0 0 0 0
we*** see to 0 0 go::::: :'11918-041 M,** i live 40 1** ~Og go Oe 0 0 * * 0 0 0 0 0 0 o O's
''1 11 11 11 w it it I? to If L JI J) a JI a JS V a P 1, U 11 w 0 a U a if 41 a 41 a a CO
1 4 L 0 f 9 if I I w I A I -I AA to OL I U
91 ' - - ... .41.
A
so
00
-d Ukhd 411"I"is Pdoe"d
WINS Ishillubmw Wb. 1. N. Th
Shoftj
KWaWYA pptd. as At,% MA Poiwwd in the drsul-
00 oil furitation a# the beraww hwilon hm fablenberw c"We _41111111
06 1! oil (hiSh In 5) with N wasoxidind with Oa!3S0-"*=d
tedumd with H at 3304ID'. A bk part of its s -00
00 activity swas regabord. 7U r"IttirratbM pix with 000
00 j greater ease with cam" low im Ni. The ems don of
HIS during the demilfurimthin cut out in the
00 of a regenerated catalyst arts its go- Zee
00 %man" amt. of heroarse its comparison Oft a
preM. catalyst. Five efeest A. A. Bmbtkftk
00
00 zoo
00 9 BOO
0 g 00
too
"'go
A 1 0 - I L ASITALLURCKAL UttRAIUSt CLOUPKA7100 Ut too
bl~ $amt,.
to*
I.n0f.3 -0 441091 -67 Ij4II'3.i #fill' d-f 0- 4�1
a Vo
a I I I Od 0 a 5 1 0 a 0 As d J~
U If AV 00 It KIIII II; a . I. 'A
0 0 0 's ~Oeev~
: : : : : 0 9 0 a 0 0 0 0 4 o 0 0 o 0 6 a a 0 0 0
01 : : :1
-All a 0 9 5
0, to
Ott
JOA A I AM
~46 At (if left jkv 000flo
IRS All J? 11!
00
06
c0,
00 ir~
00
4 0
so I
so
5V=**Z "T V
R.) 0, 2M NJ( 1936).-Teirabydruturan (1)
ir4ultrd in 1U0% yipid by a 2-stagr hydragirnatigm r4 fumn
ill [be presence of 35% cat,slyst at M 7W. 1.
A1.12 (valcit.), pown-d in a weak ruffir"t lot It w C490,1vVir
Pit Swid. '"S active C %or 0.1w.14)1 tat fu,w.,i it-,
traces A debydrutteriatitm. I failed to Tract will%:$ imstv
lit 15,A) amill 41111% HAO, by le!dUltilig Of br-Atillt the 111INtS.
ill wakd lubn at 1100 for 0 hm Chits. Mine
0 Ole 0
00
roe
-00
i
goo
Joe
!ago
A 1 0 - 5 1 A -1 TALL L1*r KAL, LITINJIMS1 CI AS11 IFICATION
goo
00
U a IV MD is It & a ITT 1 0 Al a I IT a 2 A a 3 0
1 0 0 0 0 0 0 0 0 0 :;0 0 0 0 0 6 0 0 0 0 0 0
0 0 0 0 0 0 e 0 * 0 Is**.,$ 60 o q 0 0 to to 0 *
0 0 0 0 0 0 0 0 a
'its at u 41 ad 41
a r-, I L a 11 P. Q~ 1.
*MISM plot.($ J-1.
sold,*
40 dyda~
OW N. 1. SbWbim. A. A.
00 10". No. 0, 3"4'm Sd- Irim'. jfomm Sisk
"I n' w0irify 44 11rhydroarm.
210-1101- I-VI-AWk rainfroti
-lishily nutre than mat A
g:
fe
zoo
Joe
00
es
doe
~e0
.4,W
of
j v am L i a Od a
ate ItOMMA 194
I 14 is u11w15 a 9 a
f .1 a 41
L L Al Is P .4 Is 3 1 Is I -1 T I AA 0 U W U
41
00 -so
A*Z!sd- ad awilifts; Im dw presissece at nlistj ca tml y% is
Ul. Thsr
411111AW N . -00
11!10 J. Gira. ('40m, (C :-.1 11, MIA I
I Of. PhNII.1-aIhvId1t.I *lilt ..I
1,11011m Moil hy6lin.11"lillf thritim .,%.I AI'll., I
0
W
to suistio. ut A kh Ill talv's, Fc.(k at d RAI'M I"
W
1
0 -'fill 3
~
and - 5% The catalysts jut- pt Iftl, by ppli;
00 AISOW8. vvskh or their ladilti. with 23% folill-
il
a
d
o
i -00
n ws
ia
w
ppia.
"to Ibis, -duttlist-.4 and Its-ind *I
"
00 011
to 0 ninsit. all. A1'(1. j~ Ow 1114AI 0, site q 41.41Y.I. 1*0
Kivists a Inks. 44 ""mo. and .11411,V611111m. Wish it., 0
os 1
111. 44 101 PTIA16 Ow F.Allwhocl .4 1.
00 :
1
I11110116-il, fit% all-I she Itowd im,li'm I oll.-I, 14.11,111.
x i-00
it -silly lilt- '01VI..11"ll 1.1--k ~oo
06 j: a,a &$water rate than The 1whylalitill, 1,111 1, Ac-sulmlli'd
0 _i
large k;.4 tif air. lm-auw ut the dritstliatitmi And tic 0
hy'llimsenatkul. Max. NIO.t. we N.im-t J 45.1 ..W ~00
00
4
43.8% PhN1iMc with lssixt,. of i: -( AlAl. alld
'qual lull,
0
Fr". will arml 57.5% 11h.Nill't lilt 161, Athl
* ~00
Fe.09 at 3:k1
and 373'. re-+. ChA.. ItUttv 06
00
90
0
00
Do
00
.......
- too
bLO-
1 1
71 m L I w SO 5 is 3
S
0
0
74 .
it, 0,
0 0
0000000000000 00 0040000000600000
1 13
0000
49
/
0
0
000
4 000~00 goo 000000 006
000,0000000000600 0 oeooq_.~,/
L I w I . V A I I AP PA It
00 catalytic aguatallastwe W martioul fiectidall of Nuttill
b&u*d Alad bak*h~"W bealibes. N. 1). ZOIuAil And
00
.4. 1 ~ Mulkin. J. Applied Chem. (U. S. S. It.) 9.
I
ill (;Crnlan 12v1s)(19M); cf. C. A. 20. 272016, 62141.
I'll.- drilydr,wenathin -)I bwnxhw fractiam at NO-lo' be
00 I 1w lueth-1 previously dvwfibed in the prilwwre of Pt ,%%
livisle4l C wid N1 wt A40, pf.wvvsl% its-ibly in gl*-,
as lWows'll" "t it...
00 .."1 1111
h VI V Its Ill., vir-WO.- :-I
1
41W.1 At AW* g." .4 OJVO~ .."lie M. 410 UP4 00
iiq. I 1... .1. livOwli'lloilbul Ill, 0
th, Ni milli ttwiss'.11t :
bligh "altmt. tut, W&I%) of wunialle rtullpti- 'fill, 1,
o4plained by the prewnce under tbase canditions uf a
v pro,*" of armistisadw as a remit, probably.
-,-iid
t
ti"I of thurtmith 6minierisation with (ornistion 44
z
jvn,,IhvI~rw ringi. Chas. 11141w
I,
OID
00
60
0 0 0 0 a 04 a
a : 0 600 0 0
-
We -
G
e 0 0 *
0 to 4-4~i 0 6 0 4 0 0 0 0 0 0 0 0 0
A
1l L Q L
6 8 It It W It 4 It 1$ " m
?
I
1 In a ji a It a a 0 .1
1' it At is
~v
a (x u a are
-1
0
r
4 At-A. A- L a 11"
- M_ 7
-1
-_ -M
0 a.,- 111 4
._Q a I
_60
-409
00
-00
0e Z 1-00
of 2 00
00 all. The peculim cOMM-CaWjr1k bramidannatims of hydra.
0o a I:: carbas W dpmml A Aw. N.J. an. J. (,ex.
" -00
P S. R.) 7, IUIN-21(1937
.r. C. .4. Is.
oe
: I
Under the mate conditions as previou-Jy urd. -490
00 and dimuctityl-cyclabexames over Ni at X04W
3
00 Kivr p-xylene and C#IU[r~. mp., iss well as underguing
. normal dthydroscustiou. mad splitting off of MC KFUUIIS =00
00 to foirin C.H. and With. The splitting maction Ittr.
dognimattm ovrr the synthetic om. At 373* cyclobeiLant
faints StrPh, but no xy1me. " it do" at luwvr tempo. i
This is duc to kos of activity by the catalyst due to fixtua- 7 re 0
tion no it of a C Qn. At 4(N)* cyclobexamw splits curn. -
:0 pIrarlyIqjgawmspmlucts. 0vtra Pt catalyst at 3;Jll-75* ii goo
. iu~ synthetic rractious omur. and the products froin cycloi- 2 see
Itemanc ore CJI,arul Phs. Ilmlithealicyclicatmisrumatic -
so ring% cian undergo the syntli,lic reaction. If. Nf. 11. zoo
goo
WOO
ttoo
go
&I-ILA
-
1: META LUPIGICAL LSTINATWW CLASSIVOICATOGO
: T
t1
-4 1810.j 0.. Q.t
6 a IF
AV '0 L,
u All a I a ad 0 a I a Is 9 m 1 9
It a a a m a a at it ar it I I&A 9 dim,
0 0 10 0 0 ap
4: 60000000600
g If 40 0 0 0
0 0 0 fee
4 L It I-
k' I l" It it it
f
4
'OK lots ..t'
09
-00
00 .00
00 -00
00 N!, The hydrogenation of furan mad its alkil derivatives in
palladium catalyst. S. Nitilkiii.V-1.
the amacm ofs
r
00
,,
w ul"I A.S1.4yar-na, J.6ro.Chem. I-S.
.Ntk
R.) 411%37~. --f. C. .1, 30, INX0 I.m.111 [tilt
'
~h-Me -Alpt ,-Vl 41cm, hi.1logrimil.
-Itle. n".
I., thr ttilailvdi., C.41,141" %hol I'l-I %lilt It
I-
I'd
th
m
A
A
d
7
-( mi
l.At-
tt
,it ;&
wm-.
c
( l%vt
dc jk
NICS Anwiltda. SUC laistdcr to II)druge"Alu fluff fill, 11111r1%,
;llyl till- calalytt faligil"I ollfrific fit, if ll.*Jtll.l fit. zoo
It call ra-kily Im. Willi If. 100
1,400
00
00
It
&46 0
0
20
'00
MIS-SLA StIALLLWGKAL UT1041k.441 CLASUPOCATICk '00
i"o 0
t.jq.;P to
u
11 AT 10 it It It it it 13 ft An
0 0 0 0 O's 0 to o 0 o o 0 0 0 0 0 0 0 0
'p
0 0 0 0 of* o 0 o o o o 0 o o 0 0 0.0 0 0 0 0 0 0 0 0!
0 0 0 0 0 0 0 0 0
4 It It 11
* 14 15 A) It It IN m
i
,
t
TY
M 1.1 a F~ C 41 a r
:
0 L a a A
F -li , A ,
-
-
. I t - -
- , , . a `7~1
00 hy""Wition of Irylese 4nd Sol.
'J. it pplied Ckem
S
(U
.
.
.
h !*
F
*9)~l9:1T
I
65
h
E
(in F
)
.--
.
renc
,
-Oc
-
q, wcfr
%p
i
..00
0 wf in ithe prc%nk-c of It in a glA%s tulw iinnrr
L in l
- pr'-k- If ;
:0 dia I Into.) placed in an Ore. furnace 01,,ralm, and
16 .--) p -1 in a. -**
a
61 with A, eat., t
61 with a eataly%t (451) Veit.). C.11I.Me, MAS introduced
0 the reaction chamber with a velocity of
0
hrough the upper end of the tube and the product was .00
8
00 collected at the ctoled rtxvivtr attached to the lower end
of the tube. The
wai 33t)-4tX)*
trinp
of the cipts '00
.
.
.
.
M. deposited on AIA
Ni on silic-A and Ni on asbestos
40
0 .
ssm umd m catal
sts
the Lwst catal
st Wa
Ni d =
e.
,
y
y
ll '00
ed on A". yielditiff at 375* -14-9-0 of C.H.-Ph%le
=
in (from CV"
m
)
d
i
d
lk
-00
an
caut
'
"
ng
ra
ylation Of Am.
malle brdranubms present in the h. ;,69
l5*-2M) ). Destructive hydrogrenatinn oil C*lf,Nfes
usider the above cmWitions consisted in a onwelltive,le-
meth
lation with th
f
i
f
e
ortnat
on o
y
PbMe, C.11, mn,l
CH
T
..
welve refermces. A. A. Podxorny
L a elIALLURGOCAL LITIOATLAt CL&SSIP KAT ION
G.. Qot
AV .0 Is
is I; 4r 8 41 It a " a
0 0 9 o
0 0 0 ojo 0 0 0 0 0 0 0 4 0 0 * 0 0
000
00
.2j.. J.0.
q..t .1"', at( J.- 't.
to 04 0 m Is IJ a a 3 4
:4 : 0 a 0 000000 0 0 0 0 0
4 0 a * 0 9 0 0 0 a 0 0 0 0 0
0 o 0
4 mm o
0
wu uh Nil k J,
4~ m III Cc ip U. v 41
H, P60CMIS Awl poclour'll
00 1 . --,- -
so
00
00 Camlytic laydifoenation of fuma and sylvan in the
N. 1. shillkal
lumisum Catalyst
I
1
f
I
A
.
-f
a D
C
0
r prescop o
00 S. R8, 669 73
1 31. S% Fislalt Atul
S,
tiv.11"
th
I
v
1
1
e
'
A
1
V to
IL'twe mu-4
I Willi It At 120 -1-1 ",wrl .1
'*
' N"A It
Ni o- 73% AD actmol-A by ti,Atlawnt -III I"
lbe C~AIAIY%t showed tit) sign' o( fAttilli: ;'(fit
00 Ilillt
00
04
00
00
T'
jj
S L I411TALL1106KAL, U118ATtAll CLASIMPKAtION
a%- NO a
141J., 5"
-
U 0 Al1 11
-1 v I "'I"Ang SHOW o a- st '-
i -
j A
4 1
Wp 1, lp
0
at n
w
s
sor an #t
* mma n t
a
o
e
e
0 0
o
0 0 00 0 0 0 0 0 0 ;q o a 0 o 0 0 0 0 000 0 0
0
0 0 0 q 0 0 0 o 0 o 6 0 * o 0 0
we
-0-
--v
0- 0-- 0- w-6-6
w
61111111i
sm to 4 it -
4r
-
6
0
, 0
U 1`1 4 at one it 411411044
-A--A--A-Ji A A 0 P 4 R
it, liww 01plaas 1 0 - a -a - 1--A.6 .
00..,
00
00 LOS
of S%tillivais or organic I unities by idislotic hardirdailwas
than it tho furan nucleus N 1. 1.
-
00 ,m Cke., 0 S 14
(m.4 j 1,
a S. 1."I Wall EnAli'll
-00
mti.m it( F(C( )CI and falls" "it to AICI, Ira cs.. 1.
00 4 all. JIM.;'U.5% Ift S6.2"; m. 177 S , -00
A miV. of 44a g. I in M) nil. of alys. air. with 2-4 jr. -,f
.00
lh)% 11INS111.1flO in 40 ml. ale. was relillit') on a walvar
),silt hor 4 liti. und life ale. saws dets.1, -Il. 'I If.- lisAY.- age
1444% 1111101111-41. I,v- hratillil 11 will) 1.,') 4, "1 14vt%J,
tel'.
i k
1
i
00 a"
allmin
111. p"i"t
III $fill A little p
1
1 II
J* j 11"O
S!46
IA
4
1
I
A 0
410 .
.
.
,
n.
%
:
M. It. MI.W. Passing is imall 11 liver Id ,,a
oo
` al gave la;~ 132 :1
1
l
oill
. .1. It. ;11.-ks. A.Cl .#fil
S. 4 1? 1.421- s
9 wifinan willi A10, in CS, gav. ~N~3-
'
'
' 1
11:
) 7
74
all 0
,
. ml.
N 1%
0
.
, 1]
.
. Fix hydiamne *IwPI Jt-mj.j~ visib
fit. 171.
S99
kOll "fail Ill forill"I 511.11% 1." -00
III'. 11Y.It-PlIvii-
;,I,.l A* JIMIVV. it fAvr see
1% iW, J." WK1,211. Doi," 1.414 1. \I. It. :11 ~!?-. lite
J! -.1%, .1 flat IM vtil.klv~t 1, utelvd-I I.v tire plr~ tm~ A
k1)11 11111,111114- 144'.
oo
t..90
ASS-%LA, "TALtURGKAL LITINATUNIE CLASSIVICAT-CO
woo
$.now* -1
I.
affair
3- fit
0 AV PO Al -a --l
lieveleptoom
~~ -r-4 w
oasis strict It 0
WW at I Is
m:
age 4
6 0
0
00000 0 a
0 0 010 0 0 0 0 0 0 0 0 0 9 0 9 6 0 0 0 0 0'
0 Oesti, 00 0 6 0 0 0900 111111111 0 0
W
go
goo'
oo
90,
SAL!
(
CaWydc hydriallawAtime of covitswessm. N. 1. Shulkj!~,
I .1. Ihilitlwv suit U 1'. I%'Intitkind.
.,4.
t
. S. R.) 10. IkU
inatroar (1) was "tried on by the nicibud and with the
catalysts pritiviowaly described (C. A. SJ. 13161-J).
Uiuk;
all the tniahlitinsis used the reaction IT acconspanied by par-
tifil cledvage of the turn" ring stut The irmnation at 3-
.-thyli-vulohrasirwil (11) and ale. (111)
N-Minii I with It over I'd 41rift-Wed 4041 GIIIIett,w at 176'
I.KnOrd lip "no
III In & shnilar traction whit, the MI vaimly.4 the yisig
a 4
Ill if wa lictrisani to ributit WI, itud that CA IV
If) 21-21. rh. liquid-phavir be.4jenailiat 44 1 It. =01
.1 W-111) and mini. pressure In I pgrwwv us fit black atml
1,41111ised rharrual lirticMis allakwouply, total with 11W in
Mittediate locittatiott of cocionaran (IU.Iihydrolsento-
furAn). IV. 1". 170-:21', d!* (PARIM. air 1.44M. M. K.
:41A.
Ill. N. !X13 it'. d:- OMM2, -IV 1.41MI. Chas. Illane
f%t v.
7= ----'=7 7.'-'--,
41,1- SI.I.All.
Re
~v
U AT 00 is I a a a I F W 0 a
0 IT to 0 a a a 111 a of a It It a 4 in
0 0 0 0 Via
000060006000000064
~D ~-tp ~, o -
I-so
-00
200
goo
900
14
goo
goo
lbal" Most"
a" &i9
FA I S a rw Or is 0 1 0 a 9 a a 3 0 w
I a 11 u u m 'I v
0 t a I A
.40 #lot 449141
!$94S Am~ 049PIST181 MOIS
slow
abiftim. OEM.
*OA sci. V. AM-
I
C a low-W.
the an woo
- F^ Z' Pt-o
tmmdt Vifto. *,.-W
!b-"d.A=vwv. A
wbm
eddy*, ee-
004 see
00-
goo
we
wee
lei ;it&"- 410.09d I1 3 0
b 0 0 0 0 0
000 o
Mar"
tv /V, -F
USSR/Organic Chumistry, Synthetic Organic Chemistry. E-2
Abs Jourt Rof Zhur-Khimiya, Ho 6t 1957, 19046.
.-I.uthor iFlokrasova V. A., ;~hufykin 11. 1.
!not
Titlr-. The Problem of Chlorination of Alkanos in the Presence
of Nitrogen Dioxide.
Orig Pubt Izv. AN SSSR, Otd. Xhim, N., 1946, No 5, 583-586.
A bul. rt;.,:; t: Investigated arc products obtained of the gaseous (265-
4000) and liquid Z123-2130) phases of chlorination of
n- alkanus from n-C61' 4 to CgH26 at molar proportion
of the alkan0s: C12= 1:1, Vii a catalyst -N02(-"%.), and
in thu Droooncc; of 1% unsaturated hydrocarbons initiat-
ing tliv chain reaction. Chlorination in tho gascou3
phaso is carried out with the velocity of passing C121.2
liters/hours. The reaction proccuds uniformly and yields
mainly primary chlorides and some secondary. At the
Card 1/2
- !'I -j-
.1 ': 7 -j!, 7.
":A.~ -~jrc por-AnnDt.-I on o Vethyl. Froup.,--. Jn X.vlene-Bernzene ryrtc-m effected b-.- A--~-=in=
Chloride.' b.% N. -1. Sli~wkin and ?... L. "rokhorova (p. Fla)
1~ 1 6 ,~ 7C, 'I U_
I ,.C, I," lic . 6
S(.-: Jourm,l of Gene-al. Chemistry (Zhurnal ( 6FLel:ei Kh'm.1i) I., I ri N
,ydrombons on the dehydro.
F"P.Ming prop6lies oT*iTt-tini-i-m-c-a-t.,tl;~sts. -.4 1 1;1...
ri !~It. acy Jci iiii'le, -set. chtipt.
.- U.R.S.S., z
de-
a-mallizol p-miline fraction 1b. 98-101", n2r,~ 1 10f),3,
It)) -ith lin,;atd. hydrocarNais, in tile lit. vitio
1:10, were subjectLA to pro-
0 dt at WJ-305' oil 1 5'-1; Pt calaiv5f
I; C, 50 crn. hirit, -18 g.. raft: (if flow I nil.jalin~
+ -!-~Iv -V-), and the activity if tile cataly:ik
'Ittrititz, and aftrr the itins wa, tested I)v the
W04. lly'thu I
of w ._m tlyLatc). Cyclollcxvitz ha.% ao efft-cl mt v
v-. lbws 17"t afIvet tile activity alld Stat6ilitV Of thV
"AiLIN"A. I-('1ctcue, 1-heptene, a!!,! 1 oidy
.1 very Might inat:tivating viTtet. Mark-A illaclivatioll is
brought aboul. by I-etityl-I -6-clopctitelic (Y falling front
fit).,; to 5S Cycloilexclic alolle, in i1 slow 11,
,Iri-afff, t
he'activity of tile cat.-tlyst unchmiged.
ill a Arclull of fit or of CO, causcs only a slight
1w.,titim, of ill-, the jir-Itwf% art-, in file Ist-
I L;c, 11"xaltv, with it litile I-hexciw, lit tile 2nd case, 2-
fww,v.. 18.5 g., in a stream of
CO:, 93Vc ll-'~ K. 1:~italyzate. fractimatted into f)T&l 9l[i-
103~ 40.8 g~), M3-V (4 g.), 104-5.J5* (4-5 g.). residite
,s).9 l*.; tile,. lit a!al 2aft fraction, tre~ated ivith micil.
I I'SQ1. F,~.lvo 'L Ity'lro-tbo" "ith cnllqt%. close to those ~f
tile activity Of the Lakalyst 11:15
t-th yl~l-ryctopelltcae; Iltalit,, 10 g.. in a stX-M,
fAIICn to y . Ally]CYCIDIA
10 catalyl.1te; its fraction bm u9-111"
of CO." gAve pyleyclopeaLlat;
:1,-e to those of prol
Since
,Ictivit) f t1p, c;jtaly5t hai; decreased markmily
tile
!gMI 011VIcyclOllctitene anti ally1cY clol;rutalle are hytiro-
hSerice Of Ht 11111(jer Co.), this call only
grilatcd ill tile A
. 11, liberated ill tile tic-
pellse. of the
I'llce place at tilt! Cx
hydrogtoltt,on of other t"ols. to the corresponding Cyclo-
Iwil uldi. 'Iles - CycInprittaflien,' itelf, ii., -ixcd
n of If:.
with 15-181 g. ilk:ptaiic, at 30(il, under a streat
Ravi: 16 t, g, catalyzate of Which 1).s g. was vrrv C105C to
tile C,%talyst has fallen to V
~yr!tipcjtuoir; the:lcti6itYf)fl N. Tholl
SHTYKIIII, 1.
"Stability of the Catal.,~tic Properties and of the 6tructure of Platinized Carbon
in Heat-Treatment.,11 by S. S. 'No-rikov, A. 1M. Rubenshteyn, and 11. 1. ShuCrkin. Dokl.
Ak. Nauk SSSR, 62, pp 345-348, 1946.
Constancy of the catalytic activity f a 20% Pt catalyst on active C, independently
of the lenCth of heat-treatment at 3j, up to 639 hrs., was ascertained by dehydro-
genation of cyclohexane to C6116 at 3000, space velocity 0.4 l./1/ cataly-st/hr.
Under the same c~)nditions, both the crystal lattice constant and the grain size of the
Ft (-56A.) remain practicallg unchanged. Regeneration of a catalyst, heat-treated
for 639 hrs.,, and used at 300 for 120 hrs... at well over 3000, restored the original
activity and left the crystal size unchanged, i.e. no rec.-ystn. took place even at
red glow. Inasmuch as highly disperse Pt without carrier recrystalizexs easily even at
room temp., it follows that, on the carrier, Pt is not distributed unfoxro_y, but the
grains are localized in pores and completely isolated from one another.
11. Thon
K tq, pt.
Q B I T 10 Y 29. f 30 8-19-
YMS INDEX
enation Of 0 on Olifinized carbon of I*vr
'LIT, V.4 VA;-
m
ir
~
~
Cmon
m
t
PRAU
Nauk S.S.S.R.
series oil Cata ysts naide under.identi-I
carldit onis but with tire Pt cootent decirtaalit, by steps.
con,
showed
to 0
1
d
.
rwa
.
0,
+om 20% (sundatril catalyst)
diNnitpeAlTulco of high-injej
In dellyogmm, 'systerniatic,
the Pt, the -(222)
'reffectiong. L With
ne Etflection disappears rst, followed, In that order
l
a
-nIj (002), the'rellection call the (111
plane pernists throughout, and is only weakened at the
'
r
yst
it proves illat the t
Iowest pt content.
i all olpor.-
preserved evert at very high Ellin. 61 the Man
-r. The activities of thWictics of cata[Yst-,,~
*
phous carrit
expressed in percentage of conversion In hydrogenation at
tualit coast.'- 100% with 4-1% Pt, and decrease
re
C411s
,
only slightly (to aboUtL 00%) iriih 0.5-0.1% 'Pt. This
erved persistence of the (111)
1
findiri 2 g with the obs
)
9 i
!
hp catalytic activity of Pt
Jonr,, indicates that t
i
1
1
plane
c
la
r
6 (111
i!Rk
ii,i
p
on.active C resides
r
i
in,
bither,index: e
'
catalysis. It is consistent with Bolarriffir
s location of thet,
hYdrogenation-dellydrogettation catalytic activity at octi--
faces of the anJ1 'Villi bh- 3"tet MC,,jel Of"L:
I1edJAI
r -sha *IS.
plane orientation 6 fing ped rn all those fac".
N. Thou
M 5 L AP XrTALLk-ICAL LITERAJURE CLASSIFICATIGO,
SRTJYKIN, N. I.
Blocking of the active centers of vlatinized carbon by products of deep decomposition
of hydrocarbons. A. M. Rubinshteyn, 1h. M. Minachev, and N. I. Shuykin, Doklady Akad.
Nauk S.S.S.R. 637, 287-90 (1949); cf. C.A. 43, 1249g, in the hydrogenation of C6H in
excess H2 at 170-20 at the space velocity 0.06 1./1. catalyst/hr., on catalysts co-ntg.
from 4.0 down to 0.03% Pt, corresponding to passing velocities from 5.5 to 540.0 mi./hr./g,
Pt, some reaction took place even at the smallest Pt content; with 4.0-1.0, 0.5, 0.10,
0.09,0.06, and 0.03',t Pt, the initial degrees of conversion were, resP-, 100, 88.5, 88.4,
11.2, 9.0, and 1.01,. The fall of the initial rate during the run is in inverse ratio
to the Pt content. Similarly, in the dehydrogenation of cyclohexane, in a weak stream
of H2, at 300-20 and 0.3 1. cyclohexane/l. catalyst/hr., the activity of catalysts with
4.0-0.251? Pt showed no marked differences; from 0.25% Pt down, the activity falls sharply,
but even at 0.00% it still is 5% dehydrogenation. The stability of the catalysts falls
sharply from Ft