SCIENTIFIC ABSTRACT SHVEDOV, N.YA. - SHVEDOV, V.P.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001550410003-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 3
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SWEDCV, N.Yu.
Treatment vtith~ myelosan ok'chronic myeloid leukemia. Sov. med.
25 no.2:11-17 F 162. (MIR-11 15;3)
1. Iz Glavriogo voyerLnogo. gospitalya i-meni pJ,4demika N.N. Burdenko
(nactiallnik -general-maypi modito-inokoy !jluzhby L.I. Lyalin).
(METHANESULF01,11C ACID)

n (4 PHkS1 I BOOK EXPLOTTATIO14 SOV, 25~1 1

Inrarnation3l Conference on t)j* peaccrt., Uses of Atomic Eng~rZY-
2nd
Geneva
1958.
,
,
Ocklady sav*tskIk1% uchonykch; y&dernyye re&ktOrY I yadernnYa onor-
eports at Soviet Scientists; Nuclear Reactors and
astika. (1t
r
Moscow, Atcattzdat, 1959 707 p. (Series: its:
Nuclear
power
Trudy.01. 2 R'rm ta slip 1-naerted. 8:000 copies printed.
e
l
General Ide.s N.A. Doll.zhal, Correapandl,ng Member, USSR Academy Of
Sciences, A.K. mrasta# Doctor of Physical and MathematIcal S,Ienc es
A.I. Leypunskiy, Member, ULcrairtan SSR Academy of Sciences, I.I.
NOvIkov# Corresponding Membisr, USSR Aesdowy of Sciences, and V.S.
Pu.rsov, Doctor of Physical and Mathematical Sciences; Rd.: A.?.
A1701yevs Tech. Zd.% Ye. 1. Maxell.
PURPOS51 ?his book is intended for scientists and engineers engaged
In reactor destgning, an well as for professors and students or
higher technical schoolm where reactor deoign in taught.
COVIXAOR, This le"s Seemed volmse of a six-volm. eallewtion 'Pa thopee"ful
-
-Use or,atomuc energy. The AIX volumes contain the reports
pro.
sonted by Soviet Scientist& at the Second International Conference
On Peaceful Uses Or Atomic Xnargy, held from September I to 13,
195B In Geneva. Volume 2 consists of three parts. The first to
devoted to atowic power plants under construction In the Soviet
ftlOn; the second to experimental and researrh reactors, the ex-
Periments carried out on them, and the -ark to Improve them; and
the third, which in predominantly theoretical, to probLesis of
-
nuclear reactor physics and construction
engineering. Yu. r.
lb?'79kin is the Science"editor or this volume. See SOV/2081
for title& of all volumes of the set. References appear at the
and of the articles.
-Dollmzhall~ N- A- A-r~ Kr"I-A, N.A. Nlk~LIAY&V, A.M. OrtZar'y!,
_
ace
,
an . .
hl'Skoq -
WsFrIbAth 'Of OpOrCting the PjrjFJ*tomj; PSWir
a a 'R-&M the Plant's Iffork Under 3011%71& Conditions
(Report No.. 2183) 15
DolLexhalf. X A., A. K-J[rA*Ls1, ?.I. AlOSIMUAMIMY.
'
~ri-._YemstrZakov, N.Xruguahey,
2~7# Florinmkly, X,TZ. NInaShIn,
*
'*
-
'
Xityayif-, and A QrapnLt`d-_-_
I
5h&rVaTj-jU.
o
j.X;:
araraun Raictor Ifst?rNigri-rreadure steam Superheat (Report No.
2139) 36

, ~ Aatav,* AT, Brandaus, A.T.- Brand~u*_
I.I. Afr.~k
-
-
:',
' V
d
i
Ya.
V And
n
eelri,
W.S. ja
tcpkii
_
_
_
wf
.r0 IdWbrW1M2r-.6nLr;1
Xf0
M*part No. 2140)7- 60
W
"
.Alx&"44*,_M. V. and V.Q_fCaOSI~dX. Radiation Safety system or
the Artesia Icebreaker tReport, No, 2518) 87

Tort%qTj,3jA. Water-water rover Reactors (VVILR) In the U33H
.
1sport No. 184)
1
I
.
A.M.
rqv# V.V. OQncharov, A.I. lavalov,
W
_
du_ -?
tandMAM.,ortao , Sea aIng itlements or Water-water-
;:
t%~
Reactors of Atowle Power Plants (Report go. 2196) 119
*P,3A..Q.N. and V.I. Subbotin. Cooling Vater-water Reactors
_fC
port no. 2T44) 134
V.S. and I.V. Ivanow. A Study or Unsteady Heat Trans.
4IN; a -producing Elements of Nuclear Reactors (Repor-
go. 2470) 153
Irenovoldy# X.M.p V.I. Subbotln~ and Z."ah43rar. High-speed
-i#mms at for CoffrLelent In the Pipe
(Report No. 2475) 166
3- , V-1- Subbotlp# v.N,- Borl,&UPAX y, and P. L.
IMt6
J9
4_1.1_G
'
I
4. ,at Z"1JJA 11" DUrjr
-flow or Liqu Metal 'fn_TV
t
ft
v. 00 ng the
R
-Mkl
Pipes uport no. 22,or 176
?
In Piker Power R*-
~Aa& SconoftLes of Nuclear Fuel
t go. 20.~B) Ise
rj=
v N' Jw`A--4-PG4I1J1kIY, &6A,.D.0QMv, and O.Y
l N
t
za="s
area
eu
`_
ran Density Distribution A On& the Radius o?
AosedbIlem of Mod-shaped Heat Producing Itleaents (Report
no. 2034)
- 1.- 199

BELKIN, V.F.; SVEDOV, O.V. [Shvedov, O.V.1
Thermal neutron density dis*ibution in channels of a heavy
water reactor model with rod-type fuel elements. Jaderna
energie 8 no.10:343-348 o 162.
1. Ustav teoreticke a experimentalni-fyziky AAWAftde yed
SSSR.
-Ir

S/089/63/014/003/006/020
B102/B186
AUTHORS: -Belkin, V. F., Shvedov, 0. V., Kochurov, B. P.
TITLE: Determination of the external blocking effect in heavy-water
moderated multiplying assemblies
?ZRI0DIC-'.L: Atomnaya energiya, v. 14, no- 3, 1963, 281 - 284
fEXT: The external blocking effect of a multiplying assembly was found by
measuring the thermal and.epitherm.al neutron density distributions in the
moderator. Discs of 0-42 cm diameter, made of Dy (r-3 mg/cm) and of In
(/V25 mg/cm2) coated with Cd, served as detectors for the thermal and epi-
thermal neutrons resDectively.. These detectors were arranged in radial
sections around*a 100/0.252 channel in a quadratic lattice (pitch 26 cm).
The channel w" 36.8an off the core axis. The blocking effect, character-
ized by IN I was-calculated also.by the usual formulas (Galanin).
mod 0
is the mean neutron density in the moderator and '11, is the mean themel
mod 0
neutron density at the outer surface of the caisson tube. Theresults were:
71 p = 1-514 and 71 1-504. Measurements and calculations were made
ex Cale
Card 1/2

~ S/089J63/014/003/006/020
Determination of the external ... B102/BI86
also for other channel types and other Ditch values, but for these only
the numerical results are given. '*'.,.e results agree with those published
in J. Nucl. Energy, 6, 79, 1957, or Ychoport CEA No. 740, Saclay 1957.
For eDithermal neutrons the blockinc efiect may become considerably
noticeable. There are 2 figures and 2 tables.
SUBIAITTED: April.q, 1962
Card 2/2

BELKIN., V.F.; KOCHUROV, B.P.; SHVEDOVI,.O.V.
Measuring the density distributim 9f thermal neutrons along the
radius of plug type fuel elements. Atom. energ. 15 no.5:377-381
N 163. (MIRA 16:12)

SHVEDOV, P.A.
South Korobkovo mine is already in operation. Shakht. stroi. no.7:
28 159. (MERA 12:10)
(Kursk 101agnetic Anomaly--Iron mines and mining)

SHVEDOV, P.M.
r-- ' - ~%-" '% , ,
Through t .he Meshchera territory, Zdorov's 1 no.7:22-24 Jl '55
(mLHA 9:5)
(NESHCHERA-DESCRIPTION AND TRAVEL)

SHVEDOV, P.M. (Moskva); AVSYUK, G.A. Frof. (~bskva)
- I
Hilly ranges on glaciers. Priroda 50 no*6:113 Je 162.
(KRA .14:5)
(Altai Territory~Glaciers)
j

NMUT
INZOMM
VE7 P Al -
USSIR/Engineering - Structure
Card 1/1 Pub. 70 - 10/11
Authors Berl A. E., and Shvedov, P. N.
Title Assembly of emblems and other decorative fixtures on the tall Moscow
University building
Periodical Mekh. stroi. 4, 29-31, Apr 1954
Abstract The methods and devices used in lifting and assembly of dome
sections and emblems on the 52-meter tall tower of the newly wected
Moscaw University buildingp are described. I]-lustrationsj drawhW.
Institution
Submitted

'C' SWEDOV,
VA Ko~ r'..
~Jrnyy
zcniyy
go--Y-2
S e I e c ri g a 0 00; in seams subject. to
(J~IFA 17:101
rock ITunps. I-gol I 3c)

Dri-ve for t',.,U durability and reliability of macnines in
enterprines of the Voronezh Economic'Council. Mashinostroitell
nQ.9:2 S 162. (14MA 14,
tcklmiclheskogo upravleniya `O*oronezhqI:ogo
-.ma~, - klioza.
(Vorors-,zh i1rovinco-Machinery industry)

-.iT
theises with 10'aft
fig
oltriFe F
~-X. ~C-k-dm--
Ge -.U.S-1. --
B M. R~
28d.
f
II'!- I It III z;14 1 'IL

-
4 X. Rwt:106 bf.ac lacetone [mine W th
1
v-11
l

(I
'( 0v. al
L
ve(o all
ail A. N, Crinevi
0
'ei
- y . Hichel
Lnt'eV (State WC
T
a
ltfg,-4T;-r C. 50, 4(xY.'f.---RCfluxiLlg 3~ jr. P-
(XII). Mt (1,05 C;) and OSS g. 11COtEt in 5 ml. 0 ,
ubs. 1't01 I added to a wurmsoln. of 0,:j g. ~V~j- it, 10
nit, Uh%.

J_w 1
E(Oil and tilt! aq. layer acidified gave 1914) itiq e1hy 4.
11.1-1. . ; I .
jotntyl-5-inelhux)oxhildole (XIII), tilt. 21f)'. X111 (b g.) and
10 nil. pure 800,1 heated to 60* give after vapu. and
crysin. from EtOlf 3 g.
oxyindale (XIV), tit.
beliw.tv-2-a.-cocycloijexylpicii.yiene)o.riiidole (XV), 6btaijied by
sintilar condensation to IV from XIV and H, in. 103';
selaicark--are,m.1W. XV(0.2g.)iscyclizedbyi,;ttrtniag
with 2 stil. 90% H:SO, 2 min. on steam bath, Evolution of
COi occurs. After treatment ivith ice and soln. in EtOAc
150 mg. yellow needles, in. 129-01, of
7oielliyle)i,,-6-?ticlho4ynaphthoslyriI (XVI) is obviiiijeed, XV
was i5olucrized with -1 rut. 35% If& solo. in MOH to a
emnIxt., nit 126*; jonic'arbawiie, in. XII (5 g.) in
70 nA. EtOll, 0.71 g. Na in 40 ml. EtOH, and 3.6 irA. Ph-
Clizo refluxed 2 firs. gave 2 g, 1-nie1hy1-5-ben3y1v;cY"inda1.
*
XVII
), in. 115-17
. With evets,; PhC1120 1-mcrhyl-3-
(
'
, is formed.
hen_-y1-5-bmzy1oxycrind(j1e (XVIII), m, 155

E)
X11 (5,g.) ik:11vxed with 25 nil. AcO and a f6w drops f
POCI) an(l the sala. evapd. gives 2.8 g. 1-tncthyl-5-a,~cloxy-
oxin
-dole (XIX), in 105'. X11 (5 g.) tl with 25 nil-
-
,i
0
d C
:j
2
1
th
!
Xdh
i[C
OEt)
1
-
an
s.
vvs
.
,nu
y
~~xy
g.
g.
V,
3 _
(
ittethy(cur-5-acecoxyoxindole (XX), in. I&II. X)((,%o itig.)
truated with 11C1 gives 100
hydfaryoxirdole (XXI), in. 185*. (~*nduniatjoll of 2 6'.
:ilV with 2.63 g. AcNHCH(C0X;t),and 0.4 g. K. in 10 nil
urf-BuOll gives probably
tn.

GRINEV. A.N.; SHVEDOV V I.; TEOR'YEV, A.P.
Rea*arch in the field of qixinones. Part 11. By-nthesis of certain
substituted indeles. Zhur.ob.1-him.26 no-5:1452-1453 MY 156.
(aRA 9:9)
1.Moskovskiy gesudarstvannvy uuiversitet.
(Indolm)

AUTHORS: 3rinev, A. N., Zaytsev, I. A.) Shvedov, V. I.j 7/5-2-37/6L
Terentlyev, P. P.
TITLE.' Investigations in the Field of the Quinones (Issledovan-iya v oblasti
khinonov).
XXII. Synthesis of Substituted Indoles (XXII. Sintez zameshchernykh
indolov).
PERIODICAL: Zhurnal obshchey Khimii, 195% Vol. 28,, Mr 2. pp. 447-452 (USSR).
ABSTRACT: It was aLready found that frow, the reaction of the imines of the ace=
tyl-acetone with P-ber-zoquinone either substituted indoles or benzo=
furanes are obtained. This reaction was increased and by the condensa=
tion of the ethylether of p-aminocroto-nic ac-id and of some of itus de=
riva'Llives with p-benzoquinone, 2,3-dichloro-p-benzoquincne, 2,5-dich=
loro-p-beazoquinone, and a-naphthoquirone the ethyl-ethers of: the
1-(o-tolyl)-2-.methyl-5-o.x-findol- -3-carboxylic acid, l-cyclohexy-7-2-
. tiiyl-5-oxyindol,3-carboxylic acid, 2-methyl--If,-oxy-6.7--ill,4~chicro-in=
rne
dole-3-carboxylic acid, 2-4--ethyl.~--,7-dichloro-5-,----cj-indole-3-carboxy=
lic acid, 1-ethyl-2-methyl-4,7~dichloro-5-o>-,-indole---,-carboxrlic acid
and 1-phen)rl-2-metryi-~-oxybenzindole-3-carbox-flic acid were obtained..
The methylization and benzoylization of the oxyindoles were izrresti=
Carr! 1/2 c7ated in this and previ us papers, as well as the reaction of 'he ethyl

Investi-at'ons in ~he rielt of the ruirionea. 77--Z-37/64
XXII. SyntLe-uis of Substituted indoles.
ether of 1.,2-.di-rnetliyl-',~-metoxyindole-3-carboxylic acid and magnesium
bromoethyl. The latter tuakes place evenly if a rrdxture of ether-ben=
zene is used as solvent and yields, 1,2-dimethyl-3-(pentene-2-il-3)-5
-metoxyindole. Preparative and specific data are given.
Thefe are 8 references, 51 of' which are Slavic.
.p.S.SOC 'fT 1,1: State !1-mi-vr--I-GitY (Yoskovskiy gosudarstvemnyy un-i%rersitet)-
-0 U
S113,11ITTED: December 2e, D56.
AVi-,. 11 LiLB -rE Library of Congress.
Card 2/2

SS-,
1, ~!7 I
1L
a1
r~y

r!

OUOT, A.N.; VIiOHMTIYNV, T.L.; SMDOV, V.I.; TIWMIYET, A.P.
(~uluones. Part 34: Condeasation of p-quinonat with acetyla-
cations imines. Zhur.ob.khim- 30 no-7:2311-?515 J1 'F60,
041M 1a: 71
Mosicoirskly gosudaretvennyy universitet.
(Pontanedlone) (Benzoquinons)

GWZV' A.N.; SlfVSDOV, V.I.; SUGROBOVA, 1.1'.
~~uinonos. Part 36: Condensation of acetylacetionle ipines with
zo(ju inone. Zhur.ob.khim. 31. no.7:2298-2303 JI 161:
~MIFA 14:7)
.1. Moskovksiy gosudarstvemyy universitet imeui-m,v.
iwomonosova.
(Pentanedione) (Ben"uinone) (Imines)

.~HVEDOV, ~.L.
Absorption of radioactive iodine by the thytoid gl&nd and dis-
brders of its function in chronic experimeiit4 qmd.itions. tied.
wad. no.6:38-41 "Ol. (MIRA 1-:1)
(IODITTE-ISOTOPES) (Th-fOID GW~4-AIATOGR.-,-PHY)

11 -
GRnEV, A.N.; 5~~
Quinones., Part 39: Mechanism of the condensation of p-quinones
with imines of 1,3-diketanes. Zhur.ob.khim. 32 no.8-2624,-2616
Ag 162-, (MIRA 15:9)
1. Moskovskiy gcsU&L~s-tvq=yy universitet imen'i M.V, Imonsova,
(BenzoqbUane im$m)

f~,TOII V~
Stflay of ftiwninaq, 'rart 2-C-4hydroxyarylation of enarrulnes of aliphatic
'Ideh,r,3,-a and cy~31ic Iet,--nns. Zhur, org, khim. 1
a 128 Je 165,
Of-RA 180)
1. V3,~noyuznyy
Irm-titut. lme.-i

WPM
t,-id,7 CT 41viln0~15. Rfir! 40; gYrUlgsis -,f
Zhux. cj,g. kialm. 1 41).11:2051-;105,5 N 16'5.
L tea I skiy Itbim:Lk*-farniats~-vticheskiy
insttiut Lbuli 9, Nc-ve-mber 11,
M~4~

-Y.1.; GRINE-Ar, AOTT.
','4i andneo. Part 3: SulAtIttted Z'rmr, Org- "--~ - 1
1~0. 12:2228-2231 0 165 (MIRA 19:1)
1. Vsesoyuz-tyy nauchno-l-idleatmatellskiy
X
r,lay inst.1tut, Subhilwt..sd ~emlmnbtr 25, 1964.

SOURCE CODE: --UR/0409/66/000/003/0395/0397
AUTHOR:. Grinev, A. A.; Shvedov, V. I.; PanLshevs, Yo-,, Ke
ORG., All-Un1on Chemical and Pharmaceutical Scientific Research.
Institute im. S..Ordzhonikifte, Moscow (Vsej3oyuznyy naurhno-i6s1edoVatel'akiy' I--
khimika-farmateevticheakiy inBtitut)
TITLEs Syntheiis of alkylamina derivatives of 1-aryl-5-hydroayindola
SOURCE:- KhLmiya Seterot~Lk1Lche~kLkh soyadLnenLy6 no,* 3,, 1966g 395-397
TOPIC TAGSs arylhydroxyindole alkylamino dert.vatLve., phenyls3thyl-
aminoethylmethoxyindole, anisylmethylaminoethylmethoxyindolog nemus
system drug, organic synthetic process, alkylamine, amine
ABSTRACT:
Some of the previously obt'a4:~ieii'alkylamine derivativ"es of I-alkyl-5-
hydroxyindoles-have found application as central nervous system stimu-
lants. In fh .is.connection, synthesis of alkylamine derivatives of 1-aryl-
5-hydroxyindoles was a.tudied. Condensation of substituted 1-aryl-5~hydroxy-
ind0les with bia(dimethylamino)methane in dry dioxane..on-a steam bath,
jollowed b~_~re~#tment.with.HC1, yielded eigbt previously unreported 4-alkyla&Lne,
Card I / 3 UDCt 50. 755

.ACC NRi AP6023582
derivatives of 1-aryl-5-hydroxyindole hydrochlorides;.reductiDh with Na in
eth-qnol of.the previously obtained oximes of I-phenyl-2-methyl-3-acetyl-5-
methoxyindole, (IX).and 1-(n-anisyl)-2-metliyl-3-ace.tyl-5-metholcyindole.(X)_.
yielded .1~p~e'n*yl-2-m.ethyl-'3-(l'-aminoethyl)-5-methoxyindole (Xj) and
.1-(n-anisyl)-2-.methyl.-3-(I'-aminoethyl)-5-methoxyindole (XII) which were
,toolatee a& hydrochlorides.
C
N(C" ."Cl,
If2 3)2
-no COOC3"$ COOC2"I.
_QCH2 [M(CH.)J2
1) "CI
N C"3
At
Ar'
-Off 'N"
N
C" C CHSO LU.-
Na'. CHs
CIN60"
10CM ~ICI!S
3
Ar
Table. 1. 4-AlkYlmlne deriva tives 'of. I-aryl-5-hydroxyladolo
hydrochlorides.
COW 213

Tabl e L 4-Alkyla mine de .rivati ves of-1-aryl-5-hydroxyindoLe hydrochlorides

Found 'J6 Gal4ated
N I Formula .
o. At. J
~e
nt
';
(U
or crystal-, C II N C H N. Mjft
Jzation)
I C81114 18.1-165 Cai HuNtOs ficl '64.45 6.5 .9 7.37 64.85 6,48 7,20 71
G-4,77 6.52 7.41
11 -0-CHx CoHa 156 157' Caji-12sN,102 HCI 65,54 6.74 6,93 65,55 6,75 6.95 6a
Fr" ac 65,41 6,86 7,12 -
l
III P-M-C*144 147.5-148. Cx2H3sN2Oa - H CI 65,751 6.83 6.71 65.55 6
.75
6.95
63
(I :1 10) 65.45 G.87 6.64
IV M-6-cji.. C11H23CINjO1 HCI 59.93 5.89 6.74 59,57 5.71 6,62 .66
59,57 5.85 GGS
V P-0-r4th 192.5-193 C21H22CIN201 HCI 59.64 5.53 6,51 59.57 5,71 6.62 67
V m-CHjO-C4H#
VI:j p-C.H,O-C~.Hs
ti
VIIII p-CHICON
--C4H4
Origj art. h,is:
SUB LODE: OFDqSUBM'DATEt
Card -3/3
(I : 10: 12) 59.56 5.66 6.42
177-178 CnH2.N,04 HCJ 62.94 6.34 6,51 63.07 6,4 6.68 74
(I t 10: IS) 63,28 6,34 16.74
18()-161 C"H2,NO, 1ICI 63,32 6.461 6,38 63.07 6,49 6 70
63.13 6.631 6.59
203--;-204 CsiHiYN304? IICI 61~91 6.38 19.40 61.94 6.18 9
.42
77
(1 10.. 10), 61,70 6.141 9,451
- I table. (W .A.-50; CBE No. 101
13Feb651 ORIG'REFs .006/-OTH REFt 001

ACC NRIAP603569i~ 8
OURCE C.ODr---.- U]1/01~13/66/000/019/0034/0034
~DANE~ITOR: Grinev, A. N.; Shvedov, V. I.; Altukhova L. B.
iORG: none
i
:TITLE: Proparationof I-aryl-2-methyl-5-methoxyindoles, Class 12, No.
i186487 (announced by All-Union Chemical and Pharmaceutical Scientific
,Researr!h Institute im-. S. Ordzhonilcidze (Vses0u2nyy nauchno-issledo--
~,vatellslciy 1d-UmJ1co-farmatsevticheskiy institutTl-`
SOURCE: Izobreteniya, promyshlennyye obraztsy tovarnyye znaki.. no, 19.,
34
,TOPIC TAGS% aryl PjvW~vwV;L:ndol e,
i1carboxylic acid
'ABSTRACT. In the proposed method,,, 1-aryl.-2-methyl-5-methoxyindoles
are-- obtained by heating 1-aryl-2-methy~-5-methoxyindole-g-
carboxylc i1cids at 2-10--~-245*cz
No.
[VIA-50 L41
(Psi
[SUB GODE'. 07/ SUBM DATE 050ct65
Card-i

BESPYATOV, M.P., kand.tekhn.nauk; POLSTTANOT, V.I., inzh.; VITSINKO,
I.S., inzh.; SUKHOBRUSOV, P.N., inzh.'# SHV=QV,-V~!~-_, inzh.;
KULIK, Yu.A., inzh.
Continuous contact splitting of fats. Maol.-zhire prom. 23
,n0,9:,22-23 '571 (MIRA 10:12)
I.Kharlkovskiy politakhnicheskiy institut (for Bespyatoiv).
2.Xhar-Okovskiy mylovarennyy kombinat (for Polstyanoy,71teenko,
4ukhobrusat, Shvedov, rulik).
(Oils wftd fats)

oHvroov L, A M D Ll F- D 3 C-,) "EFF[:GT OF r4ADIOAr.TIVE
10DINE THE ORGANISM IN A CNRONIC CXPEklMENTiy' MOSCOW#
1960 (SECOND MOSCOW 3TATE tA&D !NST IM He I PIROGOV)s
(KI-t -3-611 236;).
48S

SHVEWV, V.L.
P~rotecti-ft action of potassium iodid6 during the chronic adminis-
tration of radioactiva iodine. Med.rad. 5 no.7.-60-63 160..
- , '. ... - (MIIU 13:12)
-a,-, , ~SPTOPW- ) (RbIATIOII PRMCTION)
-~, . ~ (POTASSIUXIQDJDB) (1071~-.
. , - -AMEMPOW"
M

SHVEDOV, V.L.
Thyroid gland function during variaus initial condl-Itions o~
the nervous and neuroendocrine systems. Probl.endok.i gorm.
7 no.3:.61-67 161. NqRA 24:9)
1. Rukovoditell raboty f D I Zakutinskiyt
(THYROID GLaD~o(N*ERVOTJS SYSTDO -(ENDOCRIVE GW.V DS)

Juno l';5i4 S f
1 L i 3t

SMDUV V.N. 1whener.
FurnAture.polishing using nitrocellulose finishes. Der.Prome
4 no.1:26-28 Ja'55- (KIaL 8:3)
1. Gla*mebellprom.
(Y'Urld ture) (Poiiehea)

SIMSON, Ivan Iosifovich; NOVOZHILOV, V.I., retsenzent; FAUSTOV,.V.A.,
retsenzent- SHVEDOV, V.N., red.; SIDELINIKOVA, L.A., ;re
izd-va; iiiZKAN.' Te.Ta.-, tekhn.red.
[Safety engineering and fire prevention techniques at.--sawmills
and woodworking enterprises] Tekhnika bezopasnosti.l*~r~ottvo
pozharnaia tekhnika na lesop-*Lllnykh i derevoobrabatyvalu6hohikh.
predpriiatiiakh. Moskva, Goalasbumlzdat. 1958. 316 ]~. .'.11 . 1~ I I'
. (MI'RA 12:7)
(Woodworking industries--Safety measures),'

VFELA1,1ED, Lipa Ca-igorlyevich; SHVEDOV V N.,, red.; PLESHANOVA, M.I.,
red. izd-va; GRECHISOTWAO V.I.# tekhn. red.
[Technology of the manufacture of the basic assembliep~of frame
furniture] Tekhrologiia izgotovleniia osnovrWkh uzlov korpusnoi
mebeli. Moskva, Goslesbumizdat, 1961. 41 p* (MIRA 15:1)
(Furniture)

L 48119-65 EWT(m)/r-wP(t)/EWP(b) IJP(c) JD/JG
ACCESSION NR: AP5008485 '9/6078/65/010/03/t6g)/6696-,~-- 7
AUTHOR: Shveaov, V. P.; OrLov, Yu. F.
TIM: Extraction of rare-earth elements by butyl phenyl jdhos#hates
14
SOURCE: Zhurnal neorganicheskoy khimii, v. 10, no- 3, 1965, 693-696
TOPIC TAGS* cerium nitrate extraction cerium, cerium nitrate,, pras ~od~rmitm,. :!.a4-.
thenum, neoaymium extractant, triphenyl. phosphate, butyl phenyl pho'phate (111butyl
phenyl phosViate., aiphenyl butyl phosphate, tributyl phosphate, partition, extra,c_
rare earth element extraction
:tion rare earth element
ABSTRACT: Nitrates of Cr(13:i), Fr,, La, and Na have been extracted with dibityl.
~phenyl phosphate (DBPP) diphenyl. butyl phosphate(DPBP), ancl.the effect of sub-
stituting phenyl 'groups for butyl groups in tributyl. phosphate (TBP): on tiie extrac-
-separation of the nitrates has been studied. The .-esttlts show that-
tion and
.the extraction of Ce(III) and Pr drastically Ae6reases in the folloitrbig order:
TBP > DBIF? > DFBP, while the separation factors practically remain constant; and
2) the reparation factors of the La-Ce(III) and Pr-Nd pairs for extraction by DBPP
have the same value of 2 obtained for the extraction by TBP. The ~reaults exe IVIvert
'iin Table 1 of the Enclosure. Orig. art. has: 1 table.
[Card.
_j

SHVEDG-;, V.P.; CHLOY!, Yu.F.
Ex-,ractiln- of nitri c acid by 'phosphate and phosp-'-ona~ e
derivativ,-,s. Zhur.ntrorg.khim. 10 no.12:2774-2779 D '641.
. (LIRA 19:1)

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11ACt,purpulill, alit III agailA. alizitfilwyalline. ccruirin.
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-( I . T zo. PlUl, ltn,l,-r Ilntilir With
a jill?-mg. %milpir np-, ~i#~iflvsly is oblaitird by Ifir
!
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file to tit, %�A" ICKI'm 4 the The I,.
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fit . No,- i, ver% fight, while Al' ", SO, -, 10.--
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-t-illicter that h1w"s A 111AL11-114tical roAtiou of the
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PSM/Nedicine Indicators Apr 1947
Chemistry Analysis
"Radioactive Indicators and Their Application in
Analytical Chemistry," V. P. Shvedov, 17 PP
"Vestnik Leningradskogo Universiteta" No 4
Discussion of radioactive indicators (Geig3r counters)
and chemical formula for their use in chemistry.
Conclusions voice the opinion that the use of these
radioactl7e Indicators will increase as time goes on.
Can be used in analytical chemistry for determining
the periods of semi-d-isintegration of minute amounts
of one element in the presence of another, for
Judging the completeness of disintegration of
elements, determining the degree of solu'bility'
and A-or calculations in new methods of radio-
metric micro-analyeis.
16To,14

A
Its awfMism of formam of load oxyhaw". U.
V- P-at J. &4. C".,
(Leninuad State Inv.). 'and the original riatio fir in "it] phava, WOO
77-11(1947)(fa Russism).-I%lid PbRrr -:Df* 14 Win.
_-I.Ii 1: 1. the reaction equations are 2PbUr, + 4KDr* ~ 2K2-
Was treated at botifins temp. with a "a. of KBe (o -
1111-IMI-) coats. radioactive Be* (pcvpd, by the S"ion of 7 PbErshril, 2 Kilablirsfirs" + 2 N31,011 OE 2 KBt +
neutrom OR C-11413r, mold extra. by aut. K80. then irtAted f., 2KOrO + NIf4 W +.XI I.Hr'+ Pb(01 I)Rr + Pb(OH) fir'. Le.
with a definite Quantity of o.t)2 V aqI10011, which 1&vW S the devest of exchange is 23% and the mact"ki! of the
2
11PPt-011PIV(01011r. The d6tributictiol! Pc- between it, Pb(Otf)BrandAgfkppt4.shou$dbel:3. Thtp-*sibility
11%1- SPA the Asilt pistal. (torn the filtrate ("NiMor + of an cubanife between the consplex fortuad and tL- BrO
a rernaloing In the Kilt uAtt. I& d6rejartled. From capts
I i r) was dctd. by itirmuicnicrits of tberadjoEscilvity, End
,be results were col"Parell With those expectrst on the bull Ith lit: Hf* - 2: 1. 1 -, 1, und 1: 2. It follows that at 2:1
00 %1 1 of a merhanism tentatively asguarsed it, &4y&Me: thus. U th~e nimin intermediAtor cwtiplex Is KlIblirs. sumellines also see
00 0 the tom4tkm loclk PUCC lay way of IlIbUtl 1, as suggested 9,11bDr.. and thAt the 6tter fortwi mainly lit 1: 1 sind I A.
1 by Z. Kasoglanoviand D. Chavdacav (C-4. 24.31M). no On the basis of this finding. the nitchanixin of the rearlism
0o 13 exchAttlic of fir' betwren the molls. atul tile pp(. %ballif take 'if Kareafhallov land C1141VII400V (I r,) 14 lnl~Fpttltd 8%
IIIAVC; It I lit [later mediatir Iscoduvi is the cot, plans Kapblic, Ph(Ac-0), I- 2KIlr - + x90
flat) - III-1011111c f- Kilt i KA,-O 0 A,Off, the ev.
chanitc of labIlt, wills KI. Imultble It, Islam of Md,, is
listerWetc(I as jxroLveding through 91111,11r,11; The mAn. of
MS0j in NIIAcO ormrq through the intawmaediate cm-
pies (Nff&)jPh(Ac0)0j,. Lead liallides &*I o4yh&Wes
also readily disoolve In NHAcO. -N. Th"
~Ih*--SLA METALLURGICAL
.30.1 410.010 woe
;et ~40~
IMMY.4, 0.V 5-( 1JI me 11111,11 am on tat
Sit 1A I a nd o a 0 1 W a 4 3 9
pp p p IV a 4 K at It a it tt a it a ;~ 1-1~6
0 0 0 0 0 0 0 0 0 0 : * 9 9 0 0 9 0 0 0 9 0 0 0 0 0 0 0 0 6 0 o11
0 0 0 0 0 0 0 0 411-

jllLw~m W10 W W W w

Is 11 R 19 x it a a At A A x A' x 11 v Lj I. IS 11 11 a 41 42 a 4A n ro
r

it

8; - Downsination of I"d in the promence Of harlium.

-Mg
gk
C 00
he",
.
.4
(Letlittowl State Univ-). J- Gem-
0 x m L;;-70m7)(in Rtmitiatt); vi. C.A. 41, II11b.-The
J.-iltility'i Wpit. Ph *11(flou 11.1 'Illy lqng '11 11)(0100
.00
.%, 'howal try rapt'. with 11W rx.16W five 1% And
0: uteautfuld the - alld 0.16.1tAlloil ..1 the 11111morl It'.81 the
lvptu. Attempts to wriall the Wit -wet C 1,01 ~Utvr-ffll and
0 J
1
f
00
b
rom
, the best artmAytical rmdts were obtained in sepig. l
0 ~ I Alk. earths by WS. as Pb(01l)CJ. dis"ving the -.t,hed
00 a pipt. in hW. Qigbtly acidic Nlt.OAc mul pptj. &* 111,CrO.-
zoo
In I hi. -y fairly &I-Ate -ult.
C. M K-441-11 roe

too

Ilse
r -,-v
is A,I Io 11
it tv It CAP H a It 9 x of q tt It X
y
1 It 'A I t a nd 0 m
Mo 4 t Is
Ape-
e
e
s 000.0 0 0 0 o 0 900 gel* 06009 00 0000 00000
1W fit' 1,! : 11 .:1 0

517. The quantitative detorm nation of load In the presence of groupll
Cations. V.P. J1VtML)V E 0 WLDSHTEIN and N.I. Skliv.OVA (J Anal. Chas
U.S.S.R. 3, 109, 1948.~ T~e'suthora developed a method for the complete
quantitative sopmation of Pb in the form of oxybroodde or ozyiodide from
larger quantities of 88, 5r, Ca and Pg. It was found possible to determinst
Pb quantitatively after dissolving lead oxybromide or Ovyiodids in an @Omni=
acetate solution and then precipitating as lead chromate. The precipitation of
lead In the form of oxybromide, ox7iodide or oxychloride is reconimended a8
a convenient inothod ensurIng complete separation. (2 Tables.)

tun/ObAmd"m - Uwailva, MAO= Iva
3' ~ ' " Separation of
ChmIstry- - Calolva Oxalate
*Tbe SeWation of Calcine 7rom Magnesium. 1. Verl-
floatim, or the Ozalate Method With a Padloaatlv6
Udioator," V. P.'Shv*d6v, lmiiiWad State Ord at
Lenin, Chair or Analytical Ohm, PP
"Zhur Analit Khtmil" Val III, No
Jilftt& obtained show that vw4pesium precipitated Utth
mloiux axalate is directly proportional to omosm-
tration of mWesium found In solution. Results of
experiments conducted with aid of radioactive 166to"
Am
tM/Chmdstry - HiWeelum, (Contd) My/.Tun
Separation of
cf oalcium show that quantity of w4piesium. going In-
to CaC.004 precipitate, mid quantity of'calolua pro-
01PItAble together with MeNROOk are notable. ft!b.
mitted Jun 1947.
M-41

o 0 of,

09 Air

Ow"ratilm" of cak4wm Train mrsm"Ju. a. The S'J~
4 Ll fair KNAmmL (in Rumvian.) V. p, Sityl!
10v. Zhurnal
*
'heirkoi K ;mis
h V,
(Journsi of Ana ytical Chou.
,1
v try). v. 3, Sept.-()ct 194s, p, 29(~.294.
Ve-.-wrib*4 rapid and simple ffwthod involving prv-
vitlitation of Ca by rneamq of 11,S(i. in an
arclone medium.

9 ZVI? Lv. imir 0 X It
a All 10-10
zr a W
A I VA
a
a a a a 0.* 0 0 0.0'. 0 0
go

5(2); 21(5) MASE 1 BOOK EXPLOIT.WHON SOV/1900
Akademiya nauk QJS3R. Xomiss'Lya po analiticheskoy khimii
Primeneniye izotopov v analiticheskoy khimii
(Use of Radifoact'--ve isotopas in Analytical Chemistry) Moscow
Izd-vo An SSSR, 1958. 3066 p. (Series: Its: Trudy, t. 9 (12)]
Errata. sliP inaerted. 3,030 copies prin-t-e-il.
U
ResiD. Ed.: I.F. Covro3ponding Member, USSR Academy
Of Sciene_-s: o- f~IPublishing House: A.N. Yermakov; Tech.
Ed.: T.V.
PURPOSE: T~-,a bo2l- is _'xtanded for chentista and chemical
en-inae-s wit-h work in analytical chemistry.
COVERAGE: J."I'la b-oolk -'s a collection of the principal papers
pre3ented In Moacow at-, tiie Sacond Con-ference on the Use of
Radicacti-ve The rrobiams discussed at, th_~
Conference co-x:,cacizitation, aging, and solubility
of pre cin, 1. ",a-Ca s, =Lia tion of the instability constants
Card l/
'lc

Use of lsoi;o,,~as ) SOV/1900
of 00'ulplex, cr)- au:x1z, of rare earth metals, and
~c
ion-exuhan,~,e e',,1roi:tatoc-auhy. No personalities are mentioned.
75 n
There ax,2 I I _f wl;lclri are Soviet, 33 German,
J.
._i.3"i, 'Hw-garian, and 2 Czerh.
19 Frennh,
TABLE OF
Foreword
3
Lavrulchina 1, A. K. Sc),ae sties o' Radio-
cheirical knalys_JL; 5
Shvadov-,-V.P., and L.Y. Ivancri-. Separation of
Some Short-lived isotooes from Comvlex Ylix-
tures and Purification of the Isotopes 20
Rudenko, N.P., and 1. Stary. Determination of the
Complex Formation CQnstants of Indium. Acetyl
Acetonate by the F-ctraction Method 28
Card 2/ 10

Use of Radioactive Isotopes (Cont.) SOV/1900
Izmaylov, N.A., and V.S. Chernyy. Study of the Solubility
of Salts in Nonaqueous Solvents with the Aid of Tagged
Atoms 44
Busev, A.I., and V.M. Byr1ko. Determination of the
Activity Product of Cadmium Diethyldithiophosphate
by the Radioactive Indicator Method 59
Babko, A.K., and P.V. Marchenko. Study of the
Conditions for Precipitation of Microquantities of
Some Me~als in the Form of Halogen Compounds With
Basic Dyes 65
Yuznetsov, V.I., and G.V. Myasoyedov. Organic Copre-
cipitants. 9. Coprecipitation of Rare Earth Ele-
ments 76
'Kuznetsov, V.I., and G.V. Myasoyedov. Organic Copre-
cipitants. 1O.Coprecipitation of Molybdenum 89
Card 3/1O

Use of Radioactive Isotopes (cont.) SOV/1900
Kolltgof., I.M. Use of Radioactive Isotopes in Studying
Aging of Crystalline Precipitates' 98
Blerkulova, M.S.,, I.V. Melikhov, I.G. Mulyarova, and
B.VA Strizhkov. Study of Distribution of Lead and
Bismuth Isotopes Between the Solution and the
Crystals of Sodium Chlovide 115
Morachevsjciy, Yu. V., and A.I. Novikov. Copre-
cipitation of Some Elements in Low Concen-
trations with Metal Hydroxides 121
ftVachevskiy, Yu. V., and V.N. Zaytsev. Study
of the Coprecipitation, of Gallium, Indium, and
Thallium. with Calcium Phosphate 135
Slavedov, V.P., and N.A. Pavlova. Coprecipitation of
~~irconlum with Ce;,ium Oxalato in Nitric Acid
Medi= 144
Card 4/10

Use of Radloac'*-,.tve Isotopes (Cont.)- SOV/1900
Illyenko, Ye. I., B.P. Nikoltskiy, and A.M. Trofimov.
Study of the Adsorption of Ruthenium on Ion-exchanging
ILA
R~sirts rrom Aqueous Solutions
Pozdnyakov, A.A., and A.K. Lavrukhina. Use of Radio-
actIve Isotopes for Developing Methods for the
Se
paration of Elements with the Aid of Anionites 161
Yermakov, A.N., V.K. Belyayeva, And I.N. Marov,
Study of the Anion-exchange in the Complex For-
matio.n of Zirconium and Hafniuln with the Oxalate-
,ton 170
laVrukhina, A.K., K. Yung-Ping, and*V. Knoblokh.
Me of Trihydroxyglutaric Acid as a-Washing
Solution for the Chromatographio Separation of
Rare Earth Elements 179
Card ~/j a

Use of Radioactive Isotopes (Cont.) SOYMOO
TroitskiY, V.K. Ion-exchange - Radlochemical Method
for the Determination of Metal Traces 187
Yataimirskiy, K.B., and Ye. N. Roslyakova. Radio-'
metric Titration with Solutions of Complex co6o
Gompounds 194
Busev, A.I., and V.M. Byr1ko. Radiometric Titratlork
of Thallium Cadmium, and Zinc with Sodium Sal t of
J-Dithiocar~OxY-5-Methylpyrazoline 200
Iforenman, I.M., and F.R. Sheyanova. Non-isotopid
Indicators In Radiometric Titration 205
Allmarin, I.P., and V.S. Sotnikov. Gravimetric
and Radiometric Volumetric. Methods for De-
Uermining Iron with Ammonium Benzene Seleninate
and Ammohium Naphtaleneseleninate 213
filmarin, I.P., and G.N. Bilimovich. Use of the
Isotope Dilution Method for the Determination of.
Some Rare Elements 219
eard 6/j 0

Use oL' Radioactive Isotopes (Cont.) SOV/1900
Turl-e-vich, Yu. N.3 and G.G. Besproskurnov. Quantitative
Determination of an Element by Its Known Added
Quantity with the Aid of a Tagged Reagent 226
'Zlmakov, I. Ye., and G.S. Rozhavskly. Method of
Multiple Radioactive Dilution for the Deter-
mination of Small Quantities of Admixtures 231-
Gaydadymov, V.B., and L.I. Illina. Analysis of
Tantalumniobium Binary Alloys by the A-radiation
Reflection (Reverse Scattering) Method 240
Irving, G. Determination of Indium by the Radio-
activation Method N9
Starik, I. Ye., F. Ye. Starik, and A.N. Appollonova.
The Carbonate Method for Separation of Micro-
quantities of Uranium from Iron 264
-Card 7/1o

T;se 9r Radioactive Isotopes (Cont.) SOV/1900
Ifavrakhina, A.K., and S.S. Rodin. Study of the
Analytical Chemistry of Francium with the Aid
o.C Radioactive Isotope Fr212 '274
Nikolayev, A.V., A.A. Sorokina, and -A.S. Maslennikova -
Use of Radioactive Indicators in the Analysis of
liare Earth Elements '284
Korenman, 1,M., A.A. Tumanov, and Z.V. Kraynova.
Precipitation of Zlrconium Dihalooxinatee 288
I AnalysVs Ndj--) -294
Frivalova, M.M., and D.I. Ryabehikov. Extraction
Mechanism of Tri- and Pentavalent Antimony with
Tributylphosphate 301
Bykovskaya, Yu. I. Determination of Tungsten and.
Niobium, in High Alloys 323
Dykovskaya, Yu. I. Determination of Niobium in the
Presence of Large Quantities of Titanium 329
Card 8/10

Use oX liadioactive Isotopes (Cont.) SOV/19QO
Grizik, A.A., and I.I. Marunina. Methodology of
Using Radioactive Indicators for the Process
Oontrol in the Production of Rare Metals 333
Starik I. Ye., E.V. Sobotovich, G.P. Lovtsyus,
aiad-V.f. Nesterov. Pyrochemical Methods for the
Quantitative Recovery of Lead from Rocks with the
.Aid of Radioactive Control 341
KaTasev, K.I., and T.N. Mukhina. Use of the Tagged
Atom Method for the Determination of the
Btficiency of Fractionation of Gaseous Hydro-
carbons 34.9
grasnousov, L.A., Ye. V. Volkova, Ond P.V. Zimakov.
Use of the Chlorine Isotope m3b for the Quanti-
.tative Determination of the Content of Hexa-
chlorocyclohexane Isomers in Technical Grade Hexa-
chloran -356
9110

21('J';' SOV/-3 9- 51 -5--13/2 7
Ar, TIM S V. :,edeonov, L. I. , Ankudivol~,
Ye
TITLE: Radioact,--e Fall.-Out in the Neighborhood of Leningrad
(R,ad-Lo,qk`1-a.%rn.yye vypadeniya v okrestnoctZukh Lep-ingraila)
P4210D I C 1,'.- Ato.-,inaya
1958, Vol 5, -',T-r 5, Pr 577...582 (USSR)
ABSTRACT: The samples to be -*LiiveG,I.Lr,.qtpd weie obtained in the folloyting
nanner:
I A pi-ece of absorbent paper, oxi which the duat from the
-1recipitatiovi co1L9:,,ts, i3 placed 14pjqr~
atrunsphere and from .
the bottcm of a cuvetP with walls of 10 cm height and a
jr,--und surface of I rri-. Tha euvette is posted in a f~.t~c.
1)9ce a Peried of 24 hrura- Colleetive effectivity;
f-, 0
The as ;~cliected in a porcelain vessel yrith
h ijh wa'L Is , the b o t t om of whi c It is cover ad uy ac idif I LI-d
wa -.e-r . Co Ie -. t 1 v e ef f e-- L i verne s s - 100 5-
The cc.1 1c: ted ma~,ei:tl 'wat,i . snow, absorbent paper) is
0
s,raT;c-rat,~-- and 'the aahes are dried at 500 C. The aelvinri4ty
Pard of tre rr-c--id,.es --.a a r-,rnund state is measured by means Cf a

SOV/89-5-~-19/27
Radt4active Fall .0,.;t in the rei-h-borhocd of Lening-zad
Ti~nd,,.w-eounter.
In order to be able tc. draw conclusiona with respert 'to ab-
solute. activity from the impulses per minute measure4 b.,r
means of the couriter used, compara ive measuremehts wgile
carried ol;t. (A 4TE counter developed !~y 3~ A. Baeanov and
T
~ T
R
11. was used).
TI-Le density of fall-out is represented j~~raphically in the
log, r -,hm:Lc scale for the period of from Alril It 1954 to
a
De-emb-3r 5-: "',57 (daily measurements). The aniuta-l distri..
b-otion -i5 as follow5: 2
Density per day iii mc/krn
ime-an annual mean annual maximum value I number of"signal"
remperature background I with date If-all-outs
_T
0-31 19. 48 (10" XI. ~6.
~S
0. A, 0 93. 00~':'3:- 111,) 53
O~7
.0 0 45 :-D-A1.206,XI.
40
0 1_10 43 42(-!,)
IV.
94
'-95G1 42
Ju%e)
Cfite. !V'3

2OV/89-5-5-10/27
Z,5-1 -ilian UVq Fall-OU'r, In tho NO cf Leriir,6ra4i
Sw,tli.-ated acz-4vitles were c-q'Iculated as ammipting to:
mc/k.,a2 m 2
JulY 1; 1954 13 July 1, 1-966 68
Jun. 1, 11)1-5 ~b Jan-1, 1957 87
Jul~r 1, 1955 .37 July 1, 1957 142
Jan. 1, 1956 72 Jan. 1, 1958 151
A more detailed graphical representation of thesp values
is aiven in an affixed appendix. Th~eze are 5 figures, 2
tables, and 13 references, 3 of wh:Leh are Soviet.
SUNN'ImelE'D July 30; 1953

i 0 t t T-tcdu----s off
D-L,21ear ~'-,S lans,
Soviet Ei~lkt~rti6ts Concern4n~ t,.e Eanl,,rers of ',Iuc lear -Wearcr Teoti; p. 40,
Publl.%hinZ liolize of the Ma-ifj Adminstration for the Use (~Al A~V-omtc 111',wtl4;-7
ccunc'!! 1.W l4illi46stters USSR, "'Osco'w', -195'9-

~b.V-P-; ZHILKMA, M- 1-; ZIITOVIYEVA, T-1f,
)tdv method for the quantitative separatico 6T, %ntimony. Radio-
Mimiia, I no-D109-111 159- (LIRA 12:4)
(AutimonY--AnalYsis) (-'~Xtractlgo ~qhemistry))

SHV~OMfo V.P.; STEPANOV, A.V.
$eparation of rare earth elements by coutinuotas, eUctraphoresis.
jPArt 1: Separation by menns of citric acid. Raafa4ffiinita 1 no.l:
UZ-115 '59. - (MIRA 12:4)
(Rare earth metAle-Analysis) (Elea trqohioreos)
(Citric acid)

SMIX0. V.P.-, STNPkNOV, A.V.
Blectrical nigration method for the detervihatlon of the instabi-
Ilty constants of complex compounds of oln-ignta, present in micro-
.gfortce at rations. Part J! Determination of the instability constant
of gornplwx compounds of sone lanthanicles with the anion of ethylene-
dj%-Jw+.9traacetic acid. Radiokbimiia *,L no.2--i62-167 '59.
(MIFIA 12:7)
Oare- earth compounds) (,Mptle atid)

SMDOV, V.P.; 'PAVWVA, N.A.
Use of paper electrophoresis for dotermining the charge sign of
zirconium ions in cart&-in solutions. Radiokhimila 1 no.4:400-401
159. Raper electrophoresisjI, (Zirconium) (MIRA 13:1)

SHVEDOV, V.P., -MUSAYEV, Sh.A.
14o 147
Coprecipitation of la , PM , and T9' ith iodates of
quadrivalent cerim. Radiokhimi.ia 1 no.4:465-474 '59.
(MM 13:1)
(Yttrium)
(Cerium iodate) (Ionthanum) (Promethium)

ZINOVIYEVA, Y.K.; ZHILKIIIA, 14.1.; SINEWY, V.P.; YAKOIYIXVA, G.V.
Method of extracting strontium from the soil and the determination of
Sr90. Radiok-himiia 1 no-5:613-615 '59. (WRA 13:2)
(Strontium--Analysis)

-.,.S-H.VIEWV, V.F,.; MAKAROVA, T.P.; IVANOVA, L.M.; PAVIOVA, N.A.
Determination of radioactive strontium in water samples.
.Radiokhimiia 1 no-5:616-618 159. -.2)
(MIRA. 13
(Strontium--Analysis) (Water--Ana-17sis)

SIIVEDDV,. V.P.; STRIZHOV, S.G.; CHIN TSZF-KHBU [Ching TSe-houl
Preparation and some proportion of potassium Imnthanum selenate.
Ttadiokhimiia I no-5:622-623 '59. (MRA 13:2)
(Potassium lanthanum sellenate)
4w

STEPANOVr A.V.; SHVFMV, V.P.
Blectoromigration method off determining the inata1bility con-
stants of complex compounds of infinitely diluted elements.
Part 2: Determination of constants for complex formation be-
tween some lanthanides and citric acid. Radiokhimlia 1
no.6:668-673 '59. (1411Lk 13:4)
(Rare earth compounds) (Citric acid)

SOV/78-4-110-16/40
-717 qORS: Ryskinj Ya, I,, -ledov, V. P., *olo-~rlyeva, A. A.
qh
TITLE: Infrared Absorption Spectra of Solutions of Uranyl Nitrate in
Ethers and Ketones
PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 10,
pp 2268-2275 (USSR)
3 ST
-RACT: In this paper the IR-spectrum region of the inner vibrations
of the NO 3- ion in nonaqueous solutions of hydrated uranyl
nitrates is discusqed. The analf'8is of the absorption bands of
the ~;rystal water in such solutior,.s was dealt with in ref-
erence 10. The absorption spectra were taken by means of the
D-209 spectrometer of the firm Hilger under assistance of
N. D. Delektorskaya. The spectra of the concentrated solutions
of UO2 (NO3)2' nH20 (n - 2,3,6) in diethyl ether, acetone and
methyl-ethyl ketone are presented in figures 1-4, the frequen-
cies of the absorption maxima in table 1. In the discussion of
the results the authors point out the contradictory data in
publications lRefs 11, 13-16, among them A. N. Sevchenko and
ca--d 1/2 B. I. Stepanc-j, Refs 14,15). Tht maxima lying between

SOV/78-4- 1-3-16/40
I-,fTared Absorption Spectra of Solutions of Uranyl Nitrate in Ethers ar.,.'
1000 and 1515 cm-' are interpreted as vibraticns of. the anion
and this assumption is confirmed by comparison with thct spec-
trum of the-thorium nitrate (Table 3). From this the fellowing
charac-teristic features of the structure of nonaqueous anbrtiajs
of uranyl nitrate are derived: Irrespective of the content of
water of hydration ' 2+
.he ions UO and NO- are in direct contact
2 3
with one another whereat the anion is noticeably deformed. The
stability of the bonding of NO- to the cation was also found
in other nitrates, e.g. by Ye. 3F. Gross and V. A. Kolesova
(Ref 20) in calcium nitrate. In the inner coordination sphere
of the UO 2+ ion two water molecules are retained irrespective
2
of the degree of hydration. The central uranium atom is com-
bined with two molecules of the solvent by way of the ox-tgen
atoms. The authors express their gratitude to Yu. S. Samoylova
for assisting in the experiments and to V. I. Zemlyanukhin and
N. A. Derbeneva for advice and production of the preparations.
There are 6 figures, 3 tables, and 21 references; 4 of which
are Soviet.
SUBMITTED: june 27, 1958
Card 2/2

5(2),5(3)
UTHORS Shvedov, V. P., Rosyanov, 3. P. BOV/75-14-4-28/30
A
T
TITLE: Determination of Dibutyl --Phosphoric, 1410nobutyl Phosphoric and
21Y.osphoric Ac,-.ids 't-y Paper Chromatography
PERIODICAL: Zhurnal analiticheskoy khi-11-n 0 8
ii, 195./, Vol 14, 1'r 4, PP 507-50
(USSI?)
ABSTRACT: The separation of mixtures on chromatographic paper depends on
several f-ictors of which the most important ia the distribution
'betvaen the solvents. The proper choice of the solvent deteriRines
the success of chrornatot-,raphy. For the quantitative separatidn o-"
dibutyl phosphoric acid (DBA) and monobutyl phosphoric acid (IM)
chloroform and alcohols are used. To ensure the constancy of the
distribution coefficients the chromatography of acids is
generally conducteO, in media which contain either an acid or a
base (Ref 5). The authors used mixtures of bases with alcohols
as both DBA and 0A hydrolyse less in alkaline solutions (Ref 6).
To shorten t1he duration of chromatography the solving agent was
brought to a height of 15-20 cm. The device and the working
conditions of the chromato,-iraphy are described in detail. The
chroLiatoGraphic paper is that of the factory imeni Volodarskiy
Cp,rd 1 jl'~ (GOST 5621) and vras washed with 0.1 N oxalic acid, water, and

Determinationof Dibutyl Phosphoric, Monobutyl SOV/75-14-4-28/30
Phosphoric and Phosphoric Acids by Paper Chromatography
finally with alcohol. The chromatography was conducted for
3-4 hours in upward direction. The following 5 solvents were used
for the separation: butanol methanol - water (4:1:2);
isoamyl alcohol - pyridine 25% ammonia solution (6:14:20);
chloroform - methanol - water (4:5:1); propyl alcohol - 25"4v
ammonia solution - water (6:1:3)- For the development of the
spots they used a mixture of 5 ml of 60% perchloric acid, 10 ml
of I N hydrochloric aciA and 25 ml of a 4% ammonium molybdate
solution which was diluted with water to 100 ml (Ref 4). After
spraying the chromatogram with this mixture it w'as dried in -ffarm
air, heated to 850 for 7 minutes, then left in the air until it
was saturated with humidity and finally it was kept for 5-10
minutes in an H2S atmosphere. The developed spots were cut out
and they were burned iret in a mixture of concentrated sulfuric
acid and concentrated nit-ric acid (1-1). Subsequently, the formed
orthophosphate was quantitatively determined (Refs 6t 7). The
authors chrommatoZraphed a vixture of DBA, MBA and phosphoric acid,
and solutions of each conponent. Identification of the components
on the chromatogram was made by comparison with a pure substance
Card 2/3 sample which r7aa simultaneously chromatographed.

PHASE I BOOK EXPLOITATION SOV/5404
Murin,.A. N., V. D. Nefedov, and V. P. Shvedov, eds.
Radiokhimiya I khimlya yadernykh protsessov (Radiochemistry and
the Chemistry of Nuclear Processes) Leningrad, Goskhimizdat,
1960. 784 p. Errata slip inserted. 13,000 copies printed.
Ed.: F. Yu. Rachinskiy; Tech. Ed.: Ye. Ya. Erlikh.
PURPOSE This textbook is intended for students of physical
chemistry or radlochemistry at universities and schools of
higher education. It may also serve as a handbook for sci-
entific workers and technical personnel in the radlochemical
industries and other related branches.
COVERAGE: The textbook deals with problems In modern radio-
chemistry, including adsorption, cocrystallization, isotope
exchange in radioactive elements, the chemistry ol" nuclear
processes, and methods of preparing radioactive isotopes
and labeled compounds. Special attention has been given
to chemical processes caused by radioactive transformations
and radiation. In the main the book was compiled by person-
Card-1/1CD'-_ -

Radiochemistry and the Chemistry (Cont.) SOV/5404
nel of the Radiochemistry Department, Leningradskiy gos-
udarstvennyy universitet Imeni A. A. Zhdanova(Leningrad
State University Imeni A. A. Zhdanov), and the Department of
the Technology of Artificial Radioactive Isotopes, Lenin-
gradskiy tekhnologicheskiy institut imeni Lensoveta (Lenin-
grad Technological Institute imeni Lensovet). No person-
alities are mentioned. Referenaeq accompany individual
chapters.
TABLE OF CONTENTS:
Foreword
Introduction
9
11
Ch. I. Distribution of Substances Between the Solid Crystal-
line and the Liquid Phases. L. L. Makarov, V. D.
Nefedov, and Ye. N. Tekster
1. The importance of distribution processes in radlochem-
istry 17
Card 2/16.-

Radiochemistry and the Chemistry (Cont.) SOV/5404
9. Curium 538
10. Berkelium 541
11. Californium 542
12. Einsteinium 543
13. Fermium 544
14. Mendelevium 545
15. Nobellum 545
Ch. XV. Chemistry of the Fission Process of Nuclei of Heavy
Elements. A. N. Murin and V. P. Shvedov
1. Distribution of fission produc -bj="ij~a~=jnd charge 548
2. Basic propositions on radiochemical analysis 555
3. Brief characterization of methods of separating and
purifying individual isotopes formed during fission 566
4. Analysis of mixtures of fission products 599
Ch. YVI. Production and Processing of Nuclear Fuel. V. F.
Shvedo
LV
1. Tee n of the production of primary nuclear fuel 6o4
2. Production of PU?31 and U2-13 in reactors ~14
3 Te,clioology of the chemical processing of nuclear fuel 1
C arcl ~2/-ItL-

S/081/61/000/022/003/076
B102/BIOS
AUTHORS: Shvedo P., Petrzhak, K. A., Sedletskiy, R. V.,
Stepanov, A. V.
TITLE: Extraction of the rare-earth group from U 236 photofission
fragments by continuous electrophoresis-
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 22, 1961, 36, abstract
22B248 (Tr. Tashkentak. konferentsii po mirn. ispollzovaniyu
atomn. energii. Tashkent, AN UzSSR, v, 2, 196o, 325-326)
TEXT: Electrophoretic separation of rare-earth fission products is
preceded by the extraction of their sum. Recipe. dissolve I g of
irradiated U 3 0ain 2 ml of concentrated HNO 39 add Pb(NO 3)2 (20 mg with
respect to Pt) and Ce(NO ) (15 mg with respect to Ce) as carriers to
3 3
15 ml HNO 3 (sPec- wt. 1-5), and twice precipitate Pb(NO 3)2 to remove the
Ba and Sr isotopes~ Isolate the precipitates, boil down the solution to
2 ml, dilute with wat Ier to 15 ml and precipitate CeF 3 after adding Zr (NO~4
Card 1/3

S/08 61/000/022/003/076
Extraction of the rare-earth BI 02YBI 08
carrier (20 mg with respect to Zr) and a mixture of HF and NH 4F. The
precipitates are rinsed with water and dissolved in a mixture of H 3BO3 arid
HNO Then Ce 3+ is oxidized to Ce 4+ by bromate, 3 mg of Fe 3+ are
3'
introduced into the solution, and Ce(IO ) is precipitated by means of
3 4 3+
15-17 ml of an 0-35N HIO 3 solution. The solution containing Fe , K9
103-3 BrO_ and rare-earth elements (REE) i's heated, and Fe(OH) is
3 3 5 3
precipitated by a solution of concentrated NE 4OH. The Fe(OH) 3 precipitates
with the REE are rinsed with hot water and dissolved in 4 ml of
concentrated HC1. After cooling the obtained solution" Fe3+ is removed
by fourfold extraction with amyl acetate. The aqueous phase is evaporated,
the dry remainder is calcined and treated with HNO 3 and 30% H202- After
having removed the acids have been extracted by heating, dissolve the
remainder 'in 0.7 ml of 0.013~ Trilon B solution, Ce3+ (0.001 mg/ml) carrier
introduced, and subject the obtained solution to electrophoresis in an
-ro,_01% Trilon B solution (pH 1,.94) as an electrolyte. Separation is io
take place at- a potential gradient of -~10 v/cM. The flow rate into the
Card 2/3

S/081/61/000/022/003/076.
'Extraction. of the vire-earth B102/B106
cell of. the mixture to, be separated is 1 .5 ml/ht, By thismetho -d
1.41 1.40. 1 -14.5 149047, PM140, 150 91 93
la PIr NA and Y have 'been
extraoted. The*.separation time of the. total of R.EE was ~j2-5 hr, the.
time of electrophoresiewas 2 hr 26 min. [Abstracterl,a note; Complete
translation.j
Card 3/3

L e4 1' 0
6 1/ "CC, 1.." 009/022
A,'_!_57/ A! 29
AUTHORS: Shvedov, V.P.; Fu I-Pei
TITLE: Separaticn of radioactive Isotopes on a mer-oury catnode. 1. ST.Udy
of the e-lectro--hem4cal bellavior of europiu-~
PERIODICAL: Radiokhimiya, v. 'a, no. 1, 1960, 57 - 64
TEXT: The effect of various factors (coneentration cf substances,type of
complexes formed, nature of the added alkali met-1, fcrm of tllae depcsit, pH, tem-
perature, etc.) on the process of sepapat-lon of europium on a HS cathode was in-
vestigated using the iso*cpes Eu152-1Lc__,4 , c 137. Separation cf Fu by electrol-
and s
ysis had already been investigated by H.N. McCoy FRef. 1: J. Am. Chem. Sca., 63,
1622, 4432 (1941)], J.K. Marsh [Ref. 2: J. 9hem. Soc., 398, 523 (1942), 8, 531
(1943)], E.J. Onstott [Ref. 3: j. Am. Chem. Soc., 7-7 (8), 2129 (1955)j, and D.I.
Ryabchikov et al. rRef. 4: ZhNKh, 1, 9, 1954 (19501. Nevert!'ieless the nature
of the separation ~f rare earths is notu yet definitely explained. The main prob-
lem is the negative potential of separation laid the formation of non-soluble
hydroxides on the cathode. in the present experiments eurcpium ace',ate solutions
were used and the eur,plum conten-. In the electrolyte was controlled with a butt-
Card I

22458
I 86/60,/(X)2/G0 1/009/022
Separation of radicactive isotopes on a.... A() r,,"/ /A 121)
window counter LT-25 60A (T-25 BIFL) type]. A Pt-wire anode and a Hg-cathode (me-
cha-nically stirred) was used and tlie electrolyzer was thermostated. it is seen
from tabulated data that almcst no separat-I.Dri of eurr_r:_!um oc3urs w1thout alkali
admixtures. Considering data obtained b McCoy (Ref. 1) this indicates that sep-
aration (' rare earths is essentlally influenced by the nature ~f the alkali met-
al in the solution. Using Cs2CO-q (labelled with Cs!37) the effect of various
electrolytes on europlum separatfion was studied. Mu,:~h better separation of Eu V~
from acetate than from nitrate solutions was Qbservei. E-lecTroly5is oarri'~:d out
with admixtures of' L:,-, K-, Na-, and Cs-salTs proves that the yields correspond
to standard potentials, while the best yield is obtained with Li2CO3 additfcn.
The efficiency is correlated apparently with the potential difference between al-
kali metal and 'the separated element. Accer-ding -_'. in assumption of the present
authors in the case of formation of rate earth element complexes these diEsociate
and thus the electrolyte contains free ions Of rare eaVthE. Having a more posi-
t.ve potential these ions substitute the alkali metal In the amalgam forming rare
earth amalgam. This assumption is confirmed by the experimental results obtained
with the alkali metal Cs label-,e,; with Cs!37. in solutions riot containing Eu
already 10 min after the beginning of the elecLrolys1:i an equilibrium distribu-
tion of Cs between solution and amalgam is reached, while In the presence Of Eu
Card 2Y

22458
Separation of radioactive Isotopes on a....
S/186/60/002/001/00~/022
A057/A!29
the content of Cs in solution gradually increases with a decrease of Eu content
in solution.- Thus Cs is substituted by Eu in the amalgam.* The authors assume
that separation of Eu, Sm and Yb is due to a stable divalent state of these ele-
ments. Besides, ',on an amalgam with a-more negat~ive potential other rare earths
could be separated by electrolysis. Experiments in connection %,.,ith the'effect of
pH intlicate that the stability of amalgam grows with increasing pH. Europium
yield increases from pH 4.25 to'pll 10 and drops with a further Increase in pH.
According to the above-mentioned mechanism of curopium separation, the change in
europlum yield depends on the concen.tration of the alkali metal in amalgam. This
is experimentally veryfied. Different from data onytterbi:um separation (Ref. 4)
[Abstracter's note: erroneously printed yttrium in the original paper] no effect
of europium concentration (between 5 - 1o-5 - 3 r jo-3 m) on the yield was ob-
served. This was veiyfied in experiments without Eu. carrier. The difference be-
tween the present ob4ervations and those in Reference 4 i.s explained by the si-
multaneous decrease 4f Yb, concentration and increase in volume of the elec-
t 203
trolyte, resulting i lowering 6f the deposition rate, i.e., in yield. The ef-
feet of the concentrdtion of the complex-forming agent on the concentration of Cs
in amalgam and on europium separation demonstrates the dependence of europium
separation on cesium poncentration In the amalgam. An increase in citrate-ion
Card 3/~

'),I ,
S/186/60/002/001/009/022
Separation of Radioactive isotopes on a.... A057/A129
concentration primarily increases the europium yield, but with a further increase
in the citrate-concentration the yield decreases. The effect of various complex-
forming agents on Eu separation was investigated in dependence on the pK on the
molar ratio between-eurQpium and the agent (Fig. 2) and on the riature of the com-
plex-forming agent (Fig. ~).* Adco:rding to the results obtained.it can be stated
that for separation of europium.and other rare earths by electro*lysis on Hg cath-
ode succinic or tartaric acid instead of .-itric acid and under certain conditions
trilon B can be used. There are 3 figures, 8 tables and 6 referencesi 1 Soviet-
bloc and 5 non-Soviet-bloc.
too
SUBIMI'IT~D: May 7, 1959 0
so
Figure 1: Dependence of europfum yield on 70
pH. I - citric acid; 2 - succinic acid;
3 - tartaric acid; 4 - trilon B. U) so
'30
o 20
10
0
Card

1L) A. A" 2~~
(yo
AUTHORS: Shvedov, V.P.; Stepwiov, A.V-
TITLE: Separation cf rare earth c-1-emen*,s by the cf c-ritAnucts elec-
trophoresiS.
acid
PERIODICAL: Radiokhlrnlya, v. 2, 6;z
TEXT: Using trilan B (Na --f e-,'~iy*~-e,-,,i~dl-a--niz,.~-,~r-.~raaceti-- as ccm-
F,
plex-forming agent, a serara~,.-:j -.; - ('72~ Frn4 Y) I-;
continuous e1ectrophoreEii-~ -,:A!F n-L
vestigations concer7iinE ty Ti:~~----z .-:!Tc~.ex-f,--rrz-AnS
The principle of separat.!~-n 1-L baze-i --n -L~--- rar-e eartr.
complexes. In the previcus w(-,-k c1tx'--- ;vas used ae ~--rnp-ex-f--raling agent.
However, the Instability rcnztant~ :he K,,,. --5- ~rrp'exez -.r it-are
earths are less- differr-r-1, "!--;~~n EV'A 'ab'Le). 1hus
trilon B is more efficient in ty '1'ne preEerL experl-
ments were carried cut In an aocaratu~ frr. dessribed
in a previous paper FRef. i!2 5~.-.atzae cf ~heiow
Card I

221459
Separaticn of rare earth element. a lr-~-j -.nt- rr,~- 7,,'A 12
solubility, 0,01% trilon B w~r,~- uz-.-i. pH waz? hy a qu'nhydrone
electrode, the temperature was kep,: a_-, 2-~)-3 a~n'~ "'_-e ~01u-
tions at 0.017. Curve3 repregenting -,he zhif-- rf eqail!-trum. rf t'ie revers*_ble
reaction H+ + EM ental- i.-* m3+ + 11 enta3: ( 1) 'are given Ir. Firz~ire 1. Thie izicbii~
itles of the rM ental- and ~13+ lop= (;f 1nvez',lgatE-d rare ea.rtl- ar':- very ~irr-
ilar, therefore, the observeci effecr f zone Separa~tlcn r~irc- earths: :.ari Ue
explained only by the dlfferen.,e in ~he 1ristability of each rare earLh
element. Hence the icrrela-.lon t~eetween 'he _--eparaticii -if _,~,blllty Ix
constant is evident. The most effl!Aen". separati-_,n ~,s limI7;ed ~.2 a narr-_w pH
range. From Figure I the optlar.Lru separet.1cr, condlt!~~n5 for any c,_mb!nat1zn of tha
cerium group of rare earrhs can to determined. As a_ ',yplcal exanple -;-_-nditlons
f47 i It, 7 -1-F-2-154 _,~
for the separation of Nd FIT: ELI _,j tnq srt~lfi~ data
are given: 0.01% trilon B, Ionic at.rength 0.0i'1, ~,ampera!'_Ire PH, 1.88, Pc-
tential gradient 9.2 v' 1c.-m- rate of rupply int,~ t.hr-t --e_- :zt3r'ar.-1'!;!Cn time
86 min. Nd'47 and Eu152-1154 were n:-~, frc.:- ~,' th-~ car!-!-r. au4n~~rs ren:_%rk
that with citric acid, even at 3on:~iderably Ligher grail~n-,s, ,tis mix-
ture of rare earths could not be seplrated- Trr--re are 2 fiFures~ 1 table and
3 Soviet references.
SUBMMED: MaY 8, 1959
Card 2/4,

24395
S/186/60/002/002/014/022
E071/E433
AUTHORS: Shvedov, V.P. and Fu I-Pei
TITLE-' Th-e--s-e-pa-rf-a-f-lon of radioactive is,otopes/7, a-mercury
cathode. II. A study of the possibility of
separating rare earth elements not possessing a stable
divalent state
PERIODICAL: Radiolchimiya, 1960, Vol.2, No.2, pp.231-233
TEXT: The object of the work was to study the possibility of-
separating trivalent rare earth elements under conditions
preventing the precipitation of their hydroxides and to
investigate the applicabillty of the mechanism of the separation of'
europium, samarium andytterbium, presented'in Part I (Ref.6:
Radiol-,himiya, 2, 1, 57 (196o)) to the separation'of trivalent rare 1
earth elements. The experimental method7was described'in Part 1.
The experimental conditions were as follows: bath voltage 9V;'
2
current de7,sitY 3.98 tlA/cm quantity of mercury 177 9;
temperature 300C; volume of the solution Investigated'15 ml;
pH for lanthanum
7.85 - for other elements- 7.0; citric ion
concentration 1.33 X lo-3 m; concentration of carbonate of the
10-2;
alkali metal 6.95 x duration of an experiment for europium
Card 1/3
Orl

24395
S/186/60/002/002/014/022
The separation of radioactive ... E071/E433
30 min - for other elements 60 min. To compare the conditions of
separation on the mercury cathode of various rare eirth'blehients,
a
amalgams of lithium, potassium, cesium and sodium were used. it
was established that under certain conditions rare earth elements
(lanthanum, cerium, neodymium, prometium, yttrium, erbium,*and
lutecium)'which do not possess a stable divalent state can be 1
separated on a mercury cathode. It is assumed that the separation A
during the electrolysis process takes place due to the reduction of~
a
rzare earth element to the divalent state and then to metal with a.
sub-9equent exchange between the alkali metal of the mercury amalgam
and the rare earth elemei)t. A supposition is expressed that the
yield is influenced by the potential difference between the alkali.
metal and rare earth element entering into the composition of the
corresponding amalgams. Part III (Study of the separatlon of
cerium) is published in the same issue, PP-234-238. There are.
2 tables and 6 references: 1 Soviet-bloc and 5 non-Soviet-bloc.
The four references to English language publications read as follows;
H.N.McCoy, J.Am.Ch.Soc., 63, 1622, 3423 (1941);
J.Marsh, J.Chem.Soc., 523 (1942);
W.Noddak, A.Brul-cl, Angew. Chem., 50, 362 (1937);
Card 2/3'
40

21L395
.9/186/60/002/002/Olii/022
The separation of ra dioactive E071/E433
R.11.Leach, H.Terrey. Trans.Farad ay Soc., 33,400 (1937); W.R.Sherman,
G.Glockler, J.Ani.Che m.Soc., 70, 1342 (1948)l C.R.Eatee, G.Glockler',
J.Am.Chem.Soc., 70, 1344 (1948); A.W.Swesisen, G.Glockler, J.Am..
Chem.Soc., 71, 1641 (1949).
SUBMITTED: June 3, 1959

Card 3/3

2 43 9,'
s/186/60/002/002/015/022
E071/E433
0 0
V.P. and Fu I-Pei
AUTHORS: Shvedov,
TITLE:' The separation of p_p_a on a,mercury
cathode. III. A: study of the separation ?f cerium,~j
PE1110DICAL: Radiokhimiya, 1960, Vol.2, No.2, pp.234-238
TEXT: Part 11, dealing with the possibility of separating*rare
earth elements not possessing a stable divalent state,is
published in the same Issue, pp.231-233. In the present work'
optimum conditions for the separation of cerium on a lithium amalgam
were studied. Radioactive isotope Ce144 was used for the
experiments. The measurements of the radioactivity of the
solutions were carried out after attainin ilib ium of Ce144
praseodymig r
with its decomposition product um The following
optimum conditions for the separation of cerium*were established:
cur-.rent density 7 mA/cnir; quantity of mercury 13 ml; temperature
of the medium 300c; volume of the solution investigated 10 ml;
concentration of lithium carbonate
pH of the solution 7.0;
3.5 x 10-2 'M and-molar ratio of Ce3+ to cit3- 1:4. By means
of electrolysis under these conditions and a concentration of
ce3+ = 2.42 x 10-3 M, 99% of cerium can be separated in- 70 min.
Card 1/2

24396 "7-
The separation of radioactive s/i86/60/002/002/015/022
isotopes on a mercury cathode. III.. E071/E433
There are 8 tables, 1 figure and'7 references'. 3 Soviet-bloc and
4 non-Soviet-bloc. The two references to English language'
publications read as followsi
E.Jukkola, L.Audrieth, B.Hopkins, J.Am.Chem.Soc., 56* 303,.(193'4);
E.Julckola,,L.Audrieth, B.Hopkins, Inorganic Syntheses, 1,'15, (1959).
SUBMITTED: June 13, 1959 _1
Card 2/2
nci, A'~

SHVEDOV,--V.P.- STEI-ANOV, A.V.
More accurate values of the instability constants of certain complex
compounds formed between lanthanides and the ethylenecligminetetraacetate
ion. Radiokhimila 2 no.6:261-262 160. (MIFA .14:4)
Rare earth compounds)
etic.acid)
t

0 0
21'09
3/186/6o/oo2/oo6/o14/026
A0511AI29
AUT:,MQ1rp'--, Skiv-,lov, V. P.; K. A., Sedletsiciy, R. V., StepimovA.V.
TFILE 711i,~i ao -o.1 contin-.i- t oDhor=5i~ f~!,,r The sapara-
.rl :;llzs f1W r I I -
t-10- :f rhr:~, -aroun U2 P"ctozr*riratic- fragm-ants
PERIODICAL. v. 2, n~. 6, 1960, 711 - 714
TEXTi JmiL ..V - t,
ve .17, eettgated the possibility of applying the
elartropho~e~,-S Ir ~~ 'h--;J a-rid 5ubsequ,5:nt detemirel.cft of the yia]cLe
e fi
of t1h naFi~-z in the rpglon of th,:- rar;~ earth
ei~~memts. A J=s~ricz.,-on a~-,7=n ;7~f th-~ m-:!tkiod of tltr~e radiocheni-cal zs!~!pararion
of a 5um sf Wl-mn.-W.,-, ,:; ,;arrier from. the pr-,3du3ts of the photo-
separa:!Aon of It tz eL~-~rrc-pncresis for s,~tuarat-
inu g
; iv~-J ra- Tlie radincherrIcal zzepara-.ion of the s= of
that fare eartt gro,z-v i wes zlz~veloped for mea---uring the beta-acti-
vjji-~s of tha- rtts.!n~d The prfj:edur~- Is as follows:
Abour, 1 Lzram. cf c-side LF dissolvr-d in 2 ml of concen-
relr-iz 2+
trateA FW~3 ~j. 7g -f' Pb i3 add~~i -ro tne zolut~ion
-at
and 11 rqg --f C~;!I-,- ) in E:-- rm ra.,r The s~iu~.I-m i-_-; coo'Led. Pb(NC;)2
Card j/A