SCIENTIFIC ABSTRACT SIDOROV, S.V. - SIDOROV, V.A.

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• Collection: Scientific Abstracts
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

ACCESSION N9t AP5020791 0%x
uR/bo48/65/b2q/bo8A3l7A- 32c)
AUTHORt Naboyking Yue Ve; Sidorovp S* Vo
TITLE: Polarization of the luminescenAR o"i rAphthalene in the bonsophonone
i lattice Aeport9,13th Confezv-nc--~-on Luminsectince hold in Kharlkov 25 June to 1
July 196V
1 SOURCES AN SSSR. Izvestiyas Seriya fisichook-ayap v* 29j, not 8.* 19652 1317-1320
1 TOPIC TAWS polarized luminescence., luminescent crystal, organic crystalp crystall
orientation, laser optic material
ABSTRACTS The polarization of the luminescence of naphthalene molecules in benso-1
phenone crystals was investigated in order to dete e e o entation of the fbr-~
eign molecule in the crystal lattice. The investigation was undertaken in part bow
cause of the possible technical importance of the material for use In laserse Thai
CLYSta13 were growni by the method of k.A.Chumakov (Sb. Rost kristallovp Tol.2,, Pe
109o Izda AN SSSRI M., 1959) from solutions of 30 g bensophanone and 3 g naphth-
j alene in 375 cc of isoooctans 9 Samples cut par-allel, to a nwdmr of different cry-
stallographic planes were investigated, The sample was illuminated obliquelyp end
the fluorescence leaving the sample at right angles to the wirface was oxemdned
.,Card

L 01280-66
ACCESSION NRt AP5020791 Z
with a polaroid analyzers a monochrometer and a photonultipliero The sanple
could be cooled to 800K. Correction was made for the polarization introduced by
the apparatus; this was determined by exaWning a piece of ground glass located at
the "le position and illuminated from bihinde Polarization Introduced by dou-
ble refraction In the sample was negligiblus From an analysis of the polarization
of the naphthalins luminescence in differently oriented crystals it was found
that the triplet-ainglet oscillator in the naphthalene molecule in the crystal is
parallel to the intersection of two glm*s of which one is perpendicular to the
(110) plane and makes an angle of 20 with the *4 direction and the other JA -
perpendicular to the (001) plane and makes a milumm angle of 520 with the W101
directions The oscillator is nearly perpendicular to the (001) plane* Them are
(undisclosed) indications that., contrary to) the opinion or aswillisms (je Chem,
Phys-P 309 233, 1959)p the oscillator for -bbe triplet-singlet,transition in naph-
thalene is perpendicular to the plans of t:3e molecules "in conclusions the auth-
ora express their gratitude to ~*N,DvchinnLkova for assistance with the workaff
OrIge art* hast 3 figures*
Card 2

SlJOROV, T. A., Engineer
"S'latJonary Depots." Sub 21 Doc 51, Hilitari Red B nrier EnOn erizv Acadenv Joeni
V. V. Kuytyshev
Dissertations presented for science and engineerlt4, dogrees in Moscow durir4~ 1951.
SO: Sum. No. 480, 9 Pay 55

SIDOROV. T.A.; SODOLEV, U-N.
Isotope shift and its structure in the infrared spectrum of
boric acid. Opt.1 spektr. 1 no.3:393-W2 JI 156. (WJA 9:11)
1. Fizicheskiy institut imeni P.W. Lebedeva AN SM.
(Boric acid-Spoctra)

24(7) ~3 PHASE I BOOX EXPLOITATION 307/1365

XOI*kUlYAMAY& (Papers of the 10th All-UniOn
Conferenco on Speotr,34cep:1. V01. Is Molecular Spectroscopy)
(Llvovj lxd-vo LIvevokogo unl't-ts, 1957. 499 P. 4 000 GOV1414
printed. (3arlost I'*% Plzychryy zblr.Vk. Typ.
Additional SponsorInj Agencis Alra enlys. nauk SWR. Koals*IYA PQ
spektrookopil, W4.! 3&zer, 3.L.j We%. Ed.t Baranyuko T.Y.s
Editorlma Boards Zwkistor4gi 0.3,, Academ1clan (Reap, Rd,v Deceased).
Reporent, B.S., Doctor of Physical end Plathematteal 3clencom.
Fabelinakly, I.L., Doctor of Ph7si4aX And Mathematical Sciences,
Yabrilmatt. V.A., Zvotor of Physical WA Mathematical Sciences.
Kormitsuls. V.0., Candidate of Technical Setoncoo. Raysicly. S.M.,
Candidate of rrqsiaal arA matAwastio" ftlences, KLIm*voldY, 4-19-#
Candidate or rtValoal and ftt;h*wAt.1o&j Sciences. VAILYAMIt". V.$.,
Candidate or Fh4sloal and ft'V"wAtIoal Science& w4 Glanbervem,
1
To., Cutdidete of Physleal NW Mathemstleal
41~6.
C&I'd 1/30
---- 11 As-md N.V. Sabel". %germ" 3wwe
ad 1111-stractims at nommetarms. ftemob-le "

BabushkIn, A.B., A.T. Ovarov, and L.A. Ignat-yeva.
infrared 3pectroscopia 3t&wy or the Adsorption
and Surface R*&o1.jQn* or Ithrl OW Methyl Alcohols
on Alunt" Oxide 161
Aldorov, A.M. Study of Adsorptlon on Porous Glass
by Means or Infrared Absorption Spectra ieT
belonskiy. L.I., M. To. WASAnskAls. Ot 41- SPGG%VG-
phatmetrle Study of Vat Solit ITO
"T.A* WA U.N. 3*bol*V. Isotopic Shift In
X
-Aq
g
b
structure 3peatrAm of Berta Aold, MA Its ITG
&*ynkor. YU. U. Spectra and Tom rim or uyieted
Hatorocyg1lo #AIrAffi 160
rostovskly 1. ,is., Yu. )t- Shoynker. am
fteetro:oopla Study or 9~-ovysr7lasridlws 163
Celd 19/30

In it
511;OROV, T. ' . , Cand of Pays-Math S-.I -- (dlsi~) lnfra-red specter& and
structure Df certain E-lass-oroducir,4 oxidizers." Moscow, 1 57, 1 p
- a jo
(PhysicsInstitute Im P. 14. Lebedev), 125 copies (K-L, 35-57,

AUTHOESs Sidorov, T. A. and Sobolev, 14. N.
TITUt Infrared Speatrum and Molecular Sti,ucture of Phosphorus
Trioxide. (Infrakrasny spektr i struktura molokuly
fosforistogo angidrJ T
PERIODICAL: Optika i 3pektrosk.opiya, 1957, Vol.II, Nr.6,
pp. 710-716. JUSSH)
ABSTRACT: Infrared spectrum of phosphorus trioxide (P203) was
studied in the region from 2,,5 to 24^ . The trioxide
was prepared usinj~ the method of Thorpe and Tutton
(Ref.1). During preparation the trioxide was placed
in a current of carbon dioxide to prevent attack by
oxygen and moisture of the atmosphere. The measure-
ments were made on liquid trioxide. The liquid was
prepared by meltIng a piece of trioxide between two
plates of KI. The spectrum was measured using a
double-beam infrExed speetrometer described in Ref.6.
A f8ilit? resistor heated to about 160000C was used as
the source of light. A blackened bismuth bolometer
Card 1/3 was used as a de-Dector. The measured infrared spectrum

61-6-5/26
Infrared Spectrum and Molecular Structure of Phosphorus Trioxide.
satisfactorily interpreted only by using a molecular
model of P406 belonging to the point-group Td-
These conclusions are in full agreement with eleetron
diffraction studies of phosphorus trioxide vapours
(Ref.2). There are 2 figures, 3 tables and 6 references,
2 of which are Slavic.
SUBMITTED: November 10, 1956.
AVAILABLE: Library of Congress.
Card 3/3

'77-4.
51-6-3/25
AUTHOM- Sidorov, T. A., and Sobolev, N. N.
---------------------------
TITLE: Infrared and Raman Srectra of 13oron Oxide.
(Infrakrasnyy i kombinatsionnyy spektry bornogo angidrida.)
II. infrared Spectrum and Structure of the Boron Oxide
Molecule. (II. Infrakrasnyy spektr i struktura molelm],T
bornogo angidrida.)
FERIODICAL: Optika i Spektroskopiya, 1957, Vol. III, Nr- 69
pp. 560-567. (USSR)
ABSTRACT: The preceding paper (Ref,l) reported the resultson the
Raman spectrum of glassy boron oxide. The present and
subsequent papers report measurements of the infrared
spectrum and interp3.N-,t the vibrational spectnim of the
same substance. The infrared spectrum was obtained
in the region 2.5 - 24 ~L for the usual glass-10bqron
oxide and for the same oxide enriched with B . using
a double-beam spectrometer described in Ref.3. A
monochromator of a WKC-11 spectrometer with NaG1 gnd
KBr prisms was used. A "Bilit" rod heated to 1000 C
Card 1/4 was used as the infrared source. The absorption

1 51-6-3/25
Infrared and Raman Spectra of Boron Oxide. II.
spectra were recorded using a blackened bismuth
bolometer. Chemically pure boron oxide was used.
Oxide enriched with R 10 was produced by prolonged
heating of enriched boric acid in vacuum. By drawing
thin layers from the melt a glassy substance was
obtained2 These layers were about 1 ji thick and
2 x 3 cm in area. The form of the spectrum depended
strongly on the time the layer (film) was kept in air.
Fig.3 shows six different absorption spectra obtained
after 0 - 48 hours in air. To avoid the effect of
atmospheric moisture end to make the samples as small
as possRle a differer-t method was used. After heating
to 1000 0 to remoge water, the oxide temperature was
ine3vased to 2000 C and a film of oxide was evaporated
on a KBr plate. To study weak absorption bands
0.02 mm films were irepared. Thq,usual boron oxide
studied had 18083ci.', B 0 and 81.17% B-L-L. The enriched
oxide had ?1% B10. The infrared spectra of these
oxides are given in Figs. 1 and 2 respectively. Boron
oxide (Fig.1 and Table 1) has three strong absorption
Card 2/4 bands at 1330, 1260 and ?18 cm--L. These bands exhibit

Infrared and Raman Spectra of Boron Oxide. II.
51-6-3/25
strong absorption even in I ~L f ilms. There are
also some frequencies at which absorption is noticeabl
only in layers 20 p thick. The 1260 and 718 cm
bands exhibit isotopic displacement by 21 and 6 cm7
respectively (Fig.2 and Table 1). The infrared spectra
of boron oxide films evaporatedin vacuum, and all
layers prepared by drawing from melt (not exposed to
air) were found to be almost identical. According
to Zachariasen (Ref.9), boron oxide has coordinational
structure in which there are no separate molecules,
but according to Fajans and Barber (Ref.10), this
oxide consists of molecules which are bound together
by considerable intermolecular forces. The present
authors favour the molecular structure h othesis.
Table 2 collects the Raman (cols. 1 and 21 and infrared
(cols. 3 and 4) spectri of boron oxide. Of these
1330, 1260 and 718 cm frequencies of the infrarea
spectrum are regarded as fundamental. In the Raman
spectrum the eight strong or medium frequencies are
Card 3/4 regarded as fundamental (470, 5089 670, 725, 8089

51-6-3/25
Infrared and Raman Spectra of Boron Oxide. I ir
1260p 1330 and 1500 am-1). Tables 3 and 4 give
various possible symmetry groups of the boron oxide
molecule. From the data of these two tables, the
authors conclude that only the B406 model of the
oxide molecule and Td symmetry agree reasonably well
with experiment. There are 3 figures,, 4 tables and
11 references, of which 6 are Russian, 4 English and
1 German.
ASSOCIATION: Physical Institute imeni P.N. Lebedev, Academy of
Sciences of the USSR. (Fizicheskiy institut im.
P.N. Labedeva AN-SSSR.)
SUBMITTED: February 28, 1957.
AVAILiLBLE: Library of Congress.
Card 4/4

ID r) r-, oT - f) -
AUTHORt None Given 3o- 58-4-3o/44
TITLE% Dissertations (Dissertatsii).
Branch of Physico-Mathematical Sciences
(Otdeleniye fiziko-matematicheskikh nauk).
July-December 1957 (Iyull-Dekabr' 1957)
PERIODICALs Vestnik Akademii Nauk SSSR, 1958, Nr 4,
pp. 116-116 (USSR)
A.BSTRAM 6) At the Institute for Physics imeni P. K. Lebedev
(Fizicheskiy Institut imeni P. N. Lebedeva) the following
dissertations were defendeds
a) for the degree of a Doctor of Physico-Mathematical
Sciences: B. M. Kozyrev - Experimental Investigations
in the Field of Paramagnetic Resonance. (Eksperimentalinyye
issledovaniya v oblasti paramagnitnogo rezonansa).
I. L. Rozentall - On Nuclear Interactions of Particles
With High Energy (0 yadernom vzaimodeystvii chastits
bol'shoy energiij.
b) for the degree of a Candidate of Physico-Mathemati-
Card 1/2- cal Sciencesg

Dissertations. Branch Of PhYsiCO-Mathematical 30-58-4-30/44
Sciences. July-December 1957
A. V. Antonov - Investigation of Diffusion Processes and
of Neutron Retardation in Different Milieus and of the
Multiplication of Neutrons in Heterogeneous Uranium-
Graphite Systems by Means of the Impulse Method.
(Is8ledovaniye protaessov diffuzii, i zamedleniya neytronov
v razlichnykh arodakh i mulltiplikstaii neytronov v uran.-
grafitovykh geterogennykh sistemakh s pomoshchlyu impull.
Bnogo metoda) .
T. A. Sidorov - Infrared Spectra and the Structure of Some
-VItrifying Oxides. (Infrakrasnyye spektry i strukturs. ne-
kotorykh stekloobrazuyushchikh okislov).
M. I, Tretlyakova - Determination of the Mass of Slow
Charged Particles in Photographic Plates. (Opredeleniye
massy medlennykh zaryazhennykh chastits v fotoplastinkakh),
1. Physics-Bibliography 2. Bibliography-ftsies
Card 212

51- 4 -.1-2/26
AUTIIOR~;: Sidorov, T. A. and Sobolev, 11. T,.
TITLE,: -The Infrared and Combination- Spectra of Boron -Oxide
III. Interpretation of ~he Vibrational Speatrum of
Boron Oxide and Calculation of the isotopic Effect.
(Infrakrasny-j i kombinatsionnyy spektry bornogo
angidrida. III. Interpretatsiya kolebatellnogo
spektra bornogo angidrida i raschet izotopicheskogo
effekta.)
PERIODICAL: Optika i Spektroskopiya, 1958, Vol. IV, Nr. 1,
pp. 9-16. (USSR)
ABSTRACT: In the preceding two parts (Ref.1) it was shown that
a molecule of boron oxide has the formula B406 and
belongs to the symmetry point-group Td* Structure
of such a molecule is shown in Fig.l. Atoms of
boron are at the vertices of a tetrahedron, and atoms
of oxy6en are on straight lines joining' the centre of
the tetrahedron with centres of the sides of the tetra-
hedron. Due to the hi,--h symmetry of the molecule,
Card 1/7 24 of its normal vibrations degenerate to 10. The

IA- 4--l--L,/26
'Llhc~ lnfvare~ Combination Spectra of Boron Oxide. III.
molecule .1aas two fully - ~~yiraio t- ri c and totally polarized
vibrations of the type A 1 -which are active only in
the Raman spectrum; two doubly de!--Onerate vibrations
of the type E rihich are also active bnly in the
Raain spectrum; two triply de,-enerato -Abrations-
L)
of tlie type F 1 which are forbidden both in the
Raman and in the infrared spectrum, and -four triply
de~;enerate vibrations of the type F 2 which are
active both in the Raman and tlLc infrared spectra.
Force constants '-4re- calculated -Cor a valence model
of EL~O6 on the assumption that, firstly, B 406
molecule belon~-;s to the Td point-6roup of symmetry
Card 2/7 and, secondly, that the -Ghree experiLnc;n-ally observed

51- -`rl -1-2/26
ii~
Tlle in--FrL~red and Combination Spectra of Boron Oxide.
frcqu-.Dncics at 103-~)~ 606 cm--' belan~; ;to
the I ILI, A, and E types of symraetr-j respect-i'vely.
The force constants v.-ere calcula 6ed -to be
2 , 105 d = 0.6411- x 10:~ and - = 0-590 ~, 105
f = '.852 :, I U
dy~w s/cm. JetaLls of calcula-,AcnF. of Lhe -force
const,wits and fxecluencies for boron oxide v,(-re repoited
in a t1isseitation by T. A. -"i-dorov. TJ---in,- these
force constants the frequencies of ill-le i-eriainin-
seven fundamerital vibratl o-ris of the moleculos were
found to be: type E: 1372 cia"'i type Fl; 1505,
383 crII-1 type P 2 1428, 1059, 671 and 671 cm-1
1-~omparison of the calculatc-d and ob-served frequoncies
is- ;7-ivDn in '-,able 1; -tlLe E;econu' rov.- in th,~tt table
Jves th,-, obc:-;vved ralues. One frec,uency, at 1260
Card 3/? cm-1 diffor-- by 16~' from th- cal3ulate,A vulue of

Ir 4~
ation Spca-V-ra of Bc-1,0z., Oxide. II.L.
Die Infrared andCombin
1059 cm- 1, but for other frec~i,~-nicies the difffer-3nce
between the calculated and experimental values does
not exceed 1C~)'. This is considured to be satisfactory
in view of the appro-ximations made. Seven strong.,est
Raman and three stronGes-t infrared bands are inter-
preted as fundamental (Table 2). Weak bands of the
infrared and Raman spectra may be represented as first
harmonics, sums, and differences of tlie fundamental
vibration. The observed departure from selection
rules and the hiL;l-L den-ree of depolarization of the
_1 C~
a 08 cm band is due to considerable intra-molecular
forces in boron oxide, To study vibraticnal spectra
of isotopic molecules, the in-frared s-)ectram cf boron
oxide enriched with B10 isotuape was mca.-,-ired. The
Card 4/7 enriched oxide had '711,~." of B10 and 29r,:' of B11, compared

'--I - ',. -1-2126
d UmbinatIon Sps-c-Ifza, of Boy.-,n Oxid~-:.'-- !-!-L.
The Infrared and
with natural composition Of 16,83', of B 10 and of
11 U -
B On enrichment of D 0, with B an isoto-11
1-~ U, 11 11
displacement was observed in t,.-.,0 bayidE- of the infrared
spectrum: 21 cril-i a -1 -1
at 1260 .-.m band and G ~,m
at ?18 cm-1 band. The 1330 cM--i ff'requency falls
in the viinr~, of the 1260 cm-1 line, and its --isull-cpic
displacement could not be observed. Both in the
usual boron oxide and in 'the exiriched oxide tile-re are
1' -.10
five different isotopic molecLies: B -0.-, B"B 0
11 10 11 10 10 11, 5 6'
B B 0 B B 061 B'I~ Or The per---entage content
2 2 61 3 a
of these isotopic molecules in natural and enriched
oxide is given in Table 3~ The calculated lzotopic
displacements between frequoncies of mclecules
B110 and 10 are -iven in Table 4. The absorp-
4 6 B4 06
Card 5/7 tion bands of t1he oxide may bc re, prc sente, d by means of

51-4 -1-2/26
The Inf rarod and Combinaltion Spectra of Boron Oxide. III.
five equidistant intensities propor-
tional to the p_-rcenta6;,c con:tuent of the isotopic
moleculcs of BL& (Fi~;.2)j where the upper part
represents natural B,~OC ano.1 t,'ie lo,,,ior part enriched
.3 Vrohl 'Vit,.2 the alltiiors calculate the displace-
406-
ment of the maximum of the absorption band. on enrich-
ment of "406 with B The results of such
calculations for the F2-type frequencies (Table 5,
the upper royi) and the experimental values (Table
5, the lowor row) are in satisfartoi-j agreement.
This agreement and the infrared and Raman spectra
of 61assy B,,06 can I),-, taken to zfupport the B,,o6
raodel and Td symiactry of the boron oxide molecule.
Card 6/7 This is in ai~;reement with i-'ajan-s -.,nd Barb-~r (Ref.11).
Co

51- 4 -1-2/26
The Infrared and Combination Spectra of Boron Oxide. III.
All the stroneezt 1?aman bands of -lassy B 0 were
L;l 4 6
observed in liquid B406 as -~,rell (Ref.1). The
very stronL; infrared band at 1260 cm-1 r,,as found
in the infrared spectrum of B 406 up to 10000C
(Ref.12). This shoris that the molecular structure
of boron oy-ide is similar in the glassy and liquid
states. The au-,hors thank F. I. Strizhevskaya
for holz) in calculationo. There are 2 fi,-~ures, 5
tables and 12 roferences, ol' which 5 are Russian,
5 EnClish and Am(trican, 1 German and 1 French.
Institute imeni P. 11. Lebodev, Academy of
Ociences of the USSR. (Fiziclieskiy institutu im.
P. N. Lebedeva AN SSSR.)
SUBMITTED: March 4, 195?.
AVAIiABLU- Library of Congress.
Card 7/7 1. Boron oxides-Molecular structure 2. Boron oxides-
Vibration-Spectrum

BOV/51-4-6-17/24
ATJ1HORs Sidorov, TA.
TITLEi Infrared Spectra at Low lemperatares and Structure of 42artz and
Cristobalite (Infrakrasnyye spektry pri nizicikh tmperatarakh i
atrukturs, kvartsa L kristobalits)
PERIODICAL; Optika i Spektroskopiya, 1958, Vol IV, Nr 6, pp 800-801 (USSR)
ABSTRAM X-ray crystallographic data indicate that que,rtz,cristobalito and
tridymite have coordinational structures (Ref 1), i.e. structures in
which molecules or complex ions are absent. Investigations of the
infrared spectra, however, show that various crystalline for= and
glasses of SiO2 have identical 4pectra. This fact may be explained
by the presence of identical molecules or complex ions in all
crystalline modifications Of SiO2 and in S102 glass (Rof 2). Recent
measurements of the infrared spectra of qaartz, tridymite, cristobalite
and faied cpartz (Refs 3, 4) show the presence, in addition to
absorption bands which are present in all these crystals and in glass,
of weak absorption bands characteristic of each crystalline
modifications 694 cm-1 for quartz, 5U ca-1 for tridynite and
615 cm-l for cristobalitet. Fused quartz does not possess a characteristic
Card 1/3 absorption band. It may be assumed that the bands present in the

-SOV/51-4-0-17/24
lLiff,Lred Spectra at Low Temperatures and Structure of Q*mrtz and CrlstobaliU
infrared spectra of all .,.rystallins, modifications and in glass are
due to internal vibrations in molecules or ecimplox ions. The bands,
characteristic of each c:rystallino modification are produced by
vibrations of molecules or cemplex Ions with respect to one another
or they may be due to combinations of intermolecular with Internal
molecular vibrations. This assumption may be verified by investiption
of the infrared spectra of SiO2 crystals at various Umperatures. The
absorption bands due to internal molecular vibrations are not affected
much by toaperature, while the bands due to intermolecular vibrations
are changed considerably when temperature is changed (Ref 2). The
samples used were in the form of mixtures of crystal powders
(I ?~diameter and smaller particles) with paraffin oil. Only tearts
and cristobalits were studied. Measurements were made using a
double-beam infrared spectrometer (Ref 7) with WaC1 and KBr priam.
It iias found that within the limits of experimental error temperature
does not affect the posiAon width and intimsity of absorption bands at
1150, 1070, 790, 520-460 ca-1 which are common to all crystal
modifications and glass. The figure on p. 800 show absorption bands
which are characteristic for cjaartz and cristobalite modifications
respectively. Both the ahape of the bands and positions of their
bard 2/3 maxima change on trausit!.ou from room temperature (dashed curvet) to

sox/81-4-6-1 144
Infrared Spectra at Low Temperatures and Structure of (4aartz an ristobaL0
liquid-nitrogen tompers.tare (continuous curves). For quartz the
maximua at room tqmpercture vas at 694 em-1 and at low temperatures
it vas at 697 cm-'s for cristobalite the maximum at rocm temperature
was at 615 cm-1, and at low temperature at 617 cm-1. The measurementa
carried out on the infisred spectra of quartz and cristobalito tfraa
show that the assumptices given above on the structure of these
substances and the orig;in of their absorption spectra are correct.
The ideas put formard in this note make it possible to explain the
temperature behaviour cif low-frequency bands in the Raman spectrum
of crystalline quartz (on increase of temperature theme bands broaden
and their frequency decreases). Thereat* 1 figure and 9 references,
4 of -which are Soviet, 2 American, 1 Belgian, 1 Gorman and 1 Indian.
ASSOGIATION iFizichosiciy institut im.. P.N. Lebedeva, AN SSSR ('P4y&dcg Institute
imeni P.N. Lebodev, Academy of Sciences of the U.S.S.R.)
SUMUTTED% December 4, 1957
Card 3/3

suv/4417
riviuk SSISP. Fizlcli~741,y irl~:tLtut
p- ~-Ttl-ke (Clti-s Reses~r:h) Mr;scm-, 19(Y). 273 p. (Its: TruAy, tcm 12)
nted.
T S kc te I I t2,
yn, Academlniq-q; Ed. of PublIching House: D.M. Alekseyev;
Tech,
Z Intr.-nded for re-ses-rchers in optics, physics, and chemistry.
-ains one, ebrldged tvo cm-plete texts of dissertations
-.f of Eire- W-01-hematicEr *-tv'Ji were defended by three
.3 k 41
st. t1he F i z! ch*-- - La,-: t;!. tur, imer-i F.W. Le tedeva AN SSSR
lmtnA P.N. Lel-sellev, A,~.sdemy of Scllen~,es USSR). Each disser-
c 11- i~-d Iny i cts of reftrenneq.
*e '7 x .'cn Energy ia Luminescent Solutions
risfer of E. 3
.--Xr~ of t-L-- authc;~-lq 0-issextation for the degree of
-f i~,- -ane. Ma-~,&mattcs, defL-r-dewd at them Physics Inst"tute, imeni.

scrv/.4417
P.N. The auf ,:hor t:.,:jnpares Th. F6rsterls quantim
f"_e cjmsj~al lntelvrtt.B'lA.:x-,. . He exuAinc-9 twn extreme
nil .3,e of rf averaging
j t rf Me!! '11F
the cceacer-tration _--e!sjje-S and hav t--Ly might be
4~' lt.-v t eory t taln-41,L-g tr-e zlimp i,:,n o 7!1 ~a an clus
t f r tqnt e
T, r'lArl, t,'r,.e uean tirnt-. ~~f r!-,X.::14;ed stqte In rt!leica to
'T~ -ftt relat,;~ to -n`--.j-~naraera in scluticras of lin"l-
quxor.,~.hfna~ sensit' 7vl in r.,-Allt-lons ener-gy
r. i rf 5 1. a t h r-~ r% h s; t,~ E e-! i s I t I i a t i o n o f
nt.
aztng Spe~c~tra St~ru,--ture r,~f Hydro2arbons 54
rjl,t~~ --tt" -r tt.-! d.F6x,!A. ,f of Ftysicr, gal
it e ime at P . N . Leb e de v un e 24,
ct ~tuldylng. cf6tlned
morhoft5 1'requenvy of mrAecules;
cf ar-ft ur.=6tu-ratr-l hydr-c-
_1 ce:m ed
74~

SOV/4417
1rifrdre-i SJX-,~,tra ar-A Stmc:ture of Certain Glass-Forming Ooddes 2215
author's dlesertation Vc-r the degree of Doctor of Physics and
dtfer-l~-,l at the Physics Inst"tute imeai P.N. Lebedev on
16, 1957. The author lescribes experimen-ts and presents experi.-
~a ir--fr-Axed 6pectra of glase-forming axLdes. He also presents
t;O-i or. tho- vil,raition spectrum and structure of phosphoric and
,IA/vbc/gnp

V-:") -tr" I A I - 1.,,i C
c'.. th, V1.t-L- "Id i., L-!, -"A:
1.4. ',, A:,' S~'.SR' P. lw.t" Inj
V.ri~ it.: 1-!y)
Lent--- o;tt,h..kty t.1tif It 11-1 --.1. V-111.-
Editorial 1,,Ard: t.l. Av-it1n1v_ V.P. Barzako.okly, X.A. O.F.. )1v1.%lr.Uo,
V.V.V^rdttl, A.G. VlftdVv, K.!I. X.A. left_'-, M.A. V.S.
R.L. Y,.A. N.A. Tore..,, V.A.
A.K. Yk]%kl,Aj E!. of IN. 6,Yo,~; T,ch. rl.:
V.r. awri.rr.
F%W~. 1: : Itts book to for resekrcherv In t%, sclr--e anl of
glazze*.
C0V)`X.'4 F ; Tn, book c,a,!ma t~.o m_.-ta &r.1 disr~-4v-s of the Tizird All-UmIc:i
cmf~r-.C' On the Viller~ t!~, li,l, In on I,_'19, 2)j?.
Tney dr&1 with t- w.1 -lta of "~yjng tt,e trv"ure *.* tlnac'.. to~'
rrlAtLm bttwen t.,.c strct,m A.~4 rro,,rt1c* of cid!-:, tht rat,-'m Cf L~.~
bend astd r~l- atrictiim. sod t;-.a cryAtA1lc,c:-.lnLry of glax- r"oj
111,.. of itrifi,mlon. olotical al 41"s .-roet"re. .a
tLe electrical rrolvrtles of glAs.t. 6" &1- dlat~6e!. JL tuxiber of %he re-
ports deal with the apa%,!v- of glass rro;~rt-ca on cQzrOaltim, thw tinting of
glaases and m4tatic, sfCcct.. and x-1..jjcA.j, technical, ahl r-ror-
ties of SIasmes. Other 1~6"m tmat glass scol. sxil Aca'. borcistlic.t,
gI ... A. Tne Cmle-i. .- by mo" via. P) delegates fr- Sod.t aal
!..~ I------ cftntirst Arennitattw-s. A_-aoir une y4rtlclj~lta In the 4144urstme
-r. V. Solociln ye V 1*4. ':t'
Z D.P. M-;.ylov. M Pe ro,. IA%&"V, D.I.
tilb: 0 P.
to rin.A.V. 5hatlI_. W.T. A.Ya. Kitzaetaos, Z-V. D-Ztys~reft. G.V.
by~i.,d.mskAj., A.A. W..*,. N.M. Skorayakov, P.U. Pokin, E.K. Zon.r. Ya.A.
ruln'too'. V.P. rozd"4~' B.S. SbomIsm1ch. EX. Plelker, ma 0.3. molchfia~&.
To* fIrAt session of the Conference vv,& Ldd~.a .. d by Pmfe ... r 2.1.
Amored Scl.nttat and Endl ... r. Doctor of Technical Sciences. Too follwing
Inativ,Lea %vr. titel fo; %!,,1r to t;,e de"lorrient of glass set.nc*
ec'. oiy
I t.-not : Go_Ihr.t-t,rj artlcnesviy Insti-at (state op-Icki lrstjt4--)j
I #tttqt kMllt --A On-tlt.t. of Silicate Ch-latrW, AS =ii).
rLIIth1st.ty AIN J.sttt.t. A:, U5r,.R),
inatit,It A119 ESLA JAstjjte A5 L=fl). lwtltj-. flylk, A,,: IZSR,
Moak Owxti-~te or Friyolt: , Ami~zy of Scivu-3, Felommgk~ya VSR. min,k).
I,Atora.W7 CC F.1.1yglCal Ch~t4trj of StIlCate. Of t-m l-tlt.t. 'k.me-1-Y I "ord-t-
ch-t.ol IL4t&tt KV Xl.~- (113ttt4te of iIeneral ant lnoreknic Cr.#Atatry,
Acal-Y of Scl-cl- CrR. Tri.tit.t
Oy dir..n,.y M er rug." mol.c4lar Carro"Is. JL3 =11).
:
YYQIA'%,tt~t Dtwklx (State lo~tlUte for Glaaa), Gw-4mr*t-nyy triutttIt stew;.
1""10)-- (State lAztltlt- r-1 ;I-*- Pitirs), r~~larstvemnyy inattt.~t elektrotel'-i.
.let, dk~ao stath (St.t' J.'titte for Electrical Glass), Sltirakiy filike-
t. chatcheakil th.titit, T,eiak Wltmrl&Ix Phy. I cote clinical ltatlt,ite,
skly i9OsA"t-;'.'Y ~fver~itrt ft&nlti~-I State Umiverulty). m,,sk,~xkjy khlettio-
inwt'- zn..!tjte Or C.11-1c.1
tWo-ol-31ch..'kly i-Sttt'At Im. l,,n5o,*t& (L-,inmi Toc."olozleml. Inatit,It tnerit
W.-s.kly I.Atlwt x1n.'k (Flelarv..I~l r4lyt-!~aig
InatItitte, Minsk), Ncvec-rk,-,k.1y pc,jltek~.ijc-;eskjy Jt&t!t%it
11olytecti4ic It'st1t4-cl, All CTvr4lrvb1L!y Follt~kt.nicteskly Institut (Svvrdlo~k
Fol,ytechnlc InNtit~t,i). Th, C-mfemnce vas spocso"! by t- ln$Lltut# of Silicate
cr'~%I,try &r, Uz'_h (A-Ltn-~ P.-~tor - A.S. r~tlib), th- Vo.6cf4t.oVe
I., D.J. M-A~J,,y-ft Cr...2f.1 Soci,ty I...t D.T.
to,n1. ley*v), arid tne r,.-!nr#twnny7 or-4o..m teeln& ortlch"kly LnstlWt Itrul
S.I, Va~ll- (St,t- '0",r or L-lh' (i t!, .1 1..rit 5.1. V-llm).
T1,e 15 of t!., C.nf-- WIO. re"-~fttlm. to rg-i:* .
C'Mer for tte T-.poie tf coorlinatimic W.e zes-rch An F.1"s, to S.,bll.l, a t-
parl-!t~&I hl~r t~." tttlv "FtIjkA I k.,tTiy% 9ttkIK" (111y6lCS -4 C!IC-littry Of
GI." ). and t. jo-rI th, C-.Itt.. On Class. Tnv CAnrmu-
AA 1.tt.--v. ke4irmicl1r., Froreator, at Cnaltman G., t4e or"'arillattvi of C-
.;tZ*.; Y..A. V,ray,r.;,.1t4. Doctor of ruy,lc. anl F..t1.-ttcs. R-ber of &!,e
0rjtWzAt1w.n1 C~=Xtt-; aril R.t. Ky,41ler, Doctor of Cn-lr-l Scl.ncr,, W-b,r
Or th. ord_..Istj~orul C_ltt-. The *34torial VAii! thaiks O.M. PKmenov,
.Vwk..Almy.. L.I. D.P. vol'yel't.. 6.F. Ntrcwo, V.A. Tort., ana
,:TV*. K01~1).tl. ac,cel,any lvill~id,.l report&.

147
Di- 4: " 1 155
CI tic, I fl~ I- t It. I: t~. G., n,
F'J.r I..:. L~ , V A, -1 A.S . r, - - , Qf cl- cry.--..,.!,-...*.!-,
k", ;ct' C.- t~.' ~J-: I ... t- :t_:lur'4 151
Florl-kay., V.P.. In!r-! ~~IllLtlll r,;-t- of 31"-
7-1~ to IT"
Al~k-y-, A.G. tt,i., or si- 0! t-
YuZO~SIQ2 by V,i: X I~y Mcthl
plob-Ic!" Y..S.. u1 'r.f. C_'Aulti- Sc--Lttert,,,- cr Ult-t
(K-- Sl-tr.] -4 ztro:t- cf 5- 01--
Kolez-%, V.A. Stuly cr tat f:tixtu;t ct Moll
by Tz,~I~ 20)
C.r'i 91-"'
vltm~ state (C~.t -
marki~' V.V. T.A. Sid-ov, W.N. 2~lool-, 4,-1 V-P-
Cherc.!.!~,C- %it-ratl~n M C.A4.z 1.
Cryst.Ilt"t ..11 vitw-. mf
Sjdaro~, T.A.. XTI*tol%r Ctr~-t~m ~il lr_-;~rtlca Q.- Crjsual-*~e ;~,rtz 21)
Drelthov.),W., S.M., an! V.P. Stu4y Or U-C or t"A
Bor&tc "a 1..Ic=qth Ic:^t, Gj~tcj W~,ttj %,,c Aid of Infoarel 219
Vlanovs A.G. q-t1tative CorzeJAtj- cf t%c Orda"I ~~!Msv--!rrvl
in Glenn 222
ji.eyk-ya,it.. G,O., -1 A.G. El,ctroc, Dlffr-'ti- St,:~4 of
VJt-o- SlIk. ~;~J I.a-1 S-Lclt, G18.1u.; 22-5
X.I.yall., A.I. A.-!-. -f U. :!,t 1- 01-13 230
VItftc'. St4t, scv/5035
, stltll~- 'Oo 11~1- of I.t,r-
I~t'rfzf_~ , In r Oi_ I In ft Sc4A B~r~'Ucatv
254
011 c".. I m 258
of Glax
Myull-. 1;.L. ir-t- ~r %:t"411#1 Scle.--). selility c: cxtto,.~j a,.1 v.#
Cu&p.~Ltlm cr ciati A, a yvrtc~. cr tc 1,1, 245
V.A.. V.1. G-=, -d L.M. Kl-llllnIk,,l. El.,trl,,l Comd-tt,ity
of Gl--~j t. HtG!~ str-,;t.~ El~ctrj~ Vj..,14 "e rmtjc~. of ~11- ,t,Qct,a 251
lelys-kAys, t.p.. rtoj, cr V,,.TjL&j a., GIajvz by the
Method of 254
Card

AUTHOR: Sidorov, T. A.
2903.;L
3/081/ 6 1 /000/0 18/001/027
B104/3101
TITLE: liolecular structure cnd pro-pertics of crystalline quartz
PERIODICAL: Roferativnyj zhurnal. Khimiyn, no. 18, 1961, 14-15, abstract
10B89 (3b. "Stakloob---azn. sostoyaniye". M.-L., AN OSSR,
?960, 213-218, Disk-iss. 238-242)
TEXT: On the basis of the similarities of the infrared absorption spectra
cf quartz, tridymite, cristobalite, and fused quartz glass and of the
Ram~n s2ectra of quartz and fused quartz glass it is assumed that all
these Sio2 modifications consist of molecules. It vias found that by means
of tho Si3 06 molocules with D 3h -;ymmetry, which have the structural
formula (I), X-ray diffraction data on the spatial location of the silicon
~-ttcmo may be explained. The structures ofal- in-' 19 -quartz, the cause of
the high rate of cu-p-transitions and the oriGin of Dauphine'e twins are
,:xplained by representation of t'ae electrostatic molecular interaction.
'~Unrtz 'miolecilles form right and left spirals b~, .,.,hich "'ne effects of
C-tral,

29031 S"Gal /"I/CCO/C16/001,,C27
Miolocular jtructur-2 and ... B1041B101
opti-al :--tivit.., are oxplained. The splitting of thc- fivP funda-.- 'ent-tl
frcquenci-eo into three Davydav componentj results from thc
reoonance interaction of quartz molecules. In the Raman
sp-rtrit,m %nd in tho infrared ipec:rum of quartz there are four groups
out oil t4e three closely situated components harmonize with theory
E.-, to th(--Ir actlvity In the infrared Raman spectra and as to the
ch-j.ractc~r of polarization. In coasequence of the electrostatic forces
actinG fro.-.-4 the side of the charged ends of neighboring molecules in a
Giver molc~cule, an electric dipole moment is induced. The value of this
di-Lolo moment changes -.,;ith a change of -.he distance between these
that is ith deformation. Taking into account the Symmetry of
the unit cell it is possible to say which of the piezoelectric constants
,)fct- and P-quartz differs from zero. The strong -polar bond Si"-O in
43 11lbstituted by the aeak polar bond Si-O during a transition
frDm q-uart-z to alkali-zilicate glass. This explains the decay of the
infrared spectrum intensity and the rise of the Ramar spectrum intensity
in alkalli glasses with increasinj; alkali content.

--trurture and ...
[Ab.-tr,c,cr's
+
0---S i ,/0
O-S i , ----0
note: Complete trarslation]
(1)
29031
S/oal/61/'000/018/001/027
3104 B101

or
S/072/60/000/011/005/005;
B021/BO58
AUTHORt Sidorov, T. A., Cand-idate of Physical and Mathematical
TITLEs Correlation Between the Structure of Oxides and Their
Vitrification Tendency
PERIODICALt Steklo i keramika, 1960, No. 11, PP. 43 - 46
TEXT: In the present paper, the author answers a number of readers'
questions dealing with the vitrification tendency of substances. The in-
vestigation of the vitrification tendency of oxides should be started by
examining the character of the chemical binding in the oxides and its
influence on their inner structure. Limit cases of the pure ionic and
homopolar bond are dealt with next. An ionic structural type of the
crystal is called coordination ccmpoundjand is distinguished by a high
melting temperature. All crystals of alkali haloids (such as NaF) with a
pure ion bond are called coordination crystals. Substances with homopolar
bond are normally gases, liquids, or molecular crystals with low melting
temperatures. Hydrocarbons and s=e inorganic compounds, such as F 2 belong
Card 1/3

Correlation Between the Structure of Oxides and S/07 60/000/011/005/005
Their Vitrification Tendency B0219058
to them. The problem of the influence of the character of the chemical
binding on the structure of the oxides in the crystalline state is dealt
with next. Modifications in the character of the chemical binding and the
structure of the oxides are traced, dependent on the position of the
element in the periodic system. In conclusion, the author states that all
oxides of elements can be divided into three groups according to the
character of chemical binding. Meial oxides, the bonds of which are mainly
given by ionic bonds, belong to the first group. Oxides of metalloida with
mainly covalent bonds belong to the second group. Oxides of elements which
take up an intermediate position between metals and metalloids and which
possess intermediate bonds, belong to the third group. The oxides of the
elements of the first group possess a coordination structure, and those of
the second group, a molecular structure. A molecular structure which forms
at the expense of the homopolar intermediate bond, is characteristic of
the third group oxides as well as a strong intermolecular interaction of
the electrostatic type, which is accomplished at the expense of the ion
part of the intermediate bond. The strong intermolecular interaction in
oxides of the third group warrants a moderate mobility of their oxides in
liquids, which explains the vitrification tendency of these oxides, The
Card 2/3

SIDOROV, T.A.
Infrared spectra and structure of some glass-forming oxides. Triady
Fiz.inst. 12:225-273 160. (HIRA 13:8)
(Oxides-Spectra)

4~ 0 0 81973 3107616010341071091009
B015/BO70
AUTHORS: Obukhov-Denieov, V. V., Sidorov, T. A., Fayzullov, F. S.,
Cheremiainov, V. P.
TITLE: The Vibration Spectrum of Vitreous Beryllium Fluoride
PERIODICAL: Zhurnal fizicheskoy khimii, 1960, Vol- 34, No. 7,
pp. 1622-1624
TEXT: The vibration spectrum of vitreous beryllium fluoride is investigat-
ed and the results are discussed. All investigations of Raman spectra were
made on a three prism spectrograph OCIT(ISP)-51 and the spectra were
photographed. No Raman spectrum, however, of vitreous beryllium fluoride
was observed. Infrared absor tion a ectrum was Investigated on a double
radiation speotrophotometer TRef, 2S and an intensive absorption band with
a maximum at 750 am-1 was established. It is assumed that the structure
of BeF2 is neither typically io-nic nor molecular. The high degree of
homopolarity of the Be - F bond shows that the valence electrons are for
most of the time between Be and F atoms and guarantee the formation of
Card 1/2 LIK

The Vibration Spectrum of Vitreous Beryllium S/076/60/034/07/09/009
Fluoride B015/BO70
81973
molecules or complicated ions. The ionic character of the bond on the
other hand shows that in BeF 2 molecule the atoms of Be and F possess
charges and a strong interatomic interaction is present. The authors thank
L. R. Bateanova and A* V. Novoselova for the BeF 2 sample and N. N. Sobolev
for advice. There are 1 figure and 8 references: 6 Soviet, 1 German, and
I American.
ASSOCIATION: Akademiya nauk SS3R Fizicheskiy institut im. P. X. Lebedeva
(Academy of sciences of the USSR, Physics Institute imeni
P. It. Lebedev)
SUBMITTED: October 31, 195e
LX1
Card 2/2

BREKHOVSKIKH, S. M., SIDOROV, T. A. and CHUBKM, N.I.
"Structure and Properties of Germanium Glasses"
report presented at the Sixth International Congress an Glass, 8-14 Jul 62,
Wash., D.C.
Hesearch Institute of Glass, Nbscou

KOWALIFY V.V.; KO,!A.'-.C)Vtf., L.I.; SIDOROV, T.A.
I -
Infr,Lrf-d Bpectra of orf-Lric complexes of beryllium. Izv. AN S~~`R.
f-,td.Jddm.nauI-. no-5:813-815 147 162. (MM 15:6)
1. Institut elementoor-ganichaskikh soyedinerdy AN SS.,R.
(Beryllium organic compounds-Spectra)

3/062/62/000/008/009/016
B1O1/B18O
AUTHORS: Korshak, V. V.p Vinogradova, So V.p Salazkin, S. N.f and
Sidorovt T. As
TITLE; Production of polyaryla based on phenol phthalein by inter-
phase polycondensation
PIRIODICAL: Akademiya nauk SSSR. Izvestiya. Otdeleniye khimicheskikh
nauk, no. Bt 1962# 106-1423
TEXT; This is the 47th report on heterochain polyesters. Interphase poly-
condensation of phenol phthalein (F) with chlorides of dicarboxylic acids
yielded.polymers of low intrinsic viscosity, NJ. Reacting P with '
isophthalic acid in this way in p-xylol solutio'np at initial reactant
concentrations of 0.1 mole/l, with 2M NaOH per M phenol phthalein,
resulted in DO< 0.23 (in tricresol) and yields of up to 8Wo. Higher
alkaline concentrations reduced both Eq] and yield. Nor did an emulsifier
(Nekal) or catalyst (triethylbenzyl ammoniumchloride) cause an
appreciable increase in &0. Polycondensatee from P and terephthallic
acid (T), and mixed polycondennates from P, 4-4#-dihydroxydiphenylpropane
Card 1/ 3

8/062V62/od0~608/009/6i,6
Production of polyaryls based BIOI/B180
Dian) and I or T all had a low [,q] (0.26-0.32). [,q] was. lower still
0.12-0.16) when the dichlorides of I and T were to-tally or partially
~
replaced by fumaryl dichloride, due to the slight hydrolysis caused by
the latter. These results are attributed to the slow rate of the
tautomeric transformation of P. In alkaline solution it is assumed that
there in equilibrium between the quinoid and the lactone forms. The
chloride of the dicarboxylic acid only reacts with the lactone. Since
transition from quinoid to lactone occurs alowlyt-hydrolysis of the acid
chloride sets in, and the molecular weight remains low. This is supportcd
by the absence of a band characterizing the quinoid structure at 1680 cm-1
in the IR spectra of the polycondens'atess The 1300 cm~l bandi attributed
bj S. Lo Elisabeth to the quinoid form (Industr. and Engng, Chem.) 52,
313 (1960)), was ascribed to the residue of I# since it wall alB? observed
in the polycondeneate of Dian and Is The doublet 1710-1760 cm- is
attributed to the different bonds of the carbonyl groups (eater and
laotone bonds)- There are 2 fisuffeO efid 4 t4111~02
ASSOCIATION: Institut elementoorga:nicheakikh soyedineniy Akademii nauk
SSSR (Institute of Elemental Organic Compounds of the AoadeaW
Card 213 of Sciences USSR)

KORSIIAK, V.V.; ROGOMIN, S.V.; SIDOROV, T.A.; CHMOU MUNit-PEY1 KOMAROVA, L.I.
Synthesis and structure of polymeric compounds from saturated
alkyl aromatic compounds. Izv.AN 9SSR Otd.khim.nauk no.5:
912-921 My 163. (MIRA 16-.8)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Polymers) (Arom tic compounds)

L 24839-65 EW(m)/9"(c)/EPR/WP(J)/T Pc-4/Pr-0641 ASNO-3/09MAM
ACCESSION NR: AP4047401
S/0062/641000101011881/1832 13
!1 AUTHOR: Zamyatina, V. A.; Oganesyan, R. M.; Sevostlyanova, V. V.;
Sidorov,_T. A.
TITLE: The reaction of nitroallyl with N-trimethylborazole
SOURCE: AN SSSR. Izvestiya. Seriya khimicheakaya, no. 10, 1964, 1881-1882
;.TOPIC TAGS: nitroallyl, trimethylborazole, nitroallyl trimethylborazole react-
ioniproduct, synthesis, polymerizaAion
A]3$TRACT.- The reaction of 3-nitropropen- I with N-trimethylborazole in ether
solution at reduced temperature gave a white crystalline product corresponding
to th' formula (N02CH2CH2CHZBNCH3)3. The material did not melt, but graduals
n1composed on heating from 181-300C. It exploded in a sealed capillary at
ly d
130-140C and was not reduced to the amine with Raney nickel. The material did
not form a complex with methanol at room temperature, but dissolved in boiling
benzene and on cooling separated as a powder insoluble in benzene or dimethyl-
formamide, probably due to po!Marizationj IR data and physical properties in-
1/2

4
0 2"65
27
'ACCESSION NR: APS006416 S/000/65A00/001/0146/0154
!AUTHOR: Korshak, V. V.*, Rogozhin, S,._ V.. Sidorov, T. Chou Jun-21eiL.~.
j
:Komarova, L.
JITLE: Preparation of polymer products from p-a1ene pseud:)cumene land ditolyl-
-ethane
:SOURCE: AN SSSR. Izvestiya. Seriya khlmicheskaya, noi 1, 1965, 146-154
TOPIC TAGS: polymer, xylene, pyrolysiE;, pyrolysis polymerization
:ABSTRACT: Polymer compounds were produced by thermal poXydebXdrocondensation of
p-xylene, pseudocumene, and ditolylethiLne. These hydrocarbons were pyrolized on an
.incandescent metal wire located in a 1J%quid monomer. The effect of temperature and
.time on the yield of polymers was inventigated and it was found that the,yield
~increased with both temperature and time * The structure of the polymers was
,investigated through analysis of their infrared spectra. The probable mechanism oft
the formation of polymer products was Jiscussed. It,,was assumed that the soluble.
,polymer of p-xylene is formed chiefly -by branching of linear molecules,- an a result[
of interaction with active radicals and-the recombination of macroradicals with
'each other or with radicals forming from monomers, dimers, etc. Orig. art. has*
i Card
7.
_7=_ 77 j.
;-.1 :- - ;~6J

i
~9 figures, 5 tables, 2 equations.
.ASSOCIATION: Institut elementoorganicbeskikb soyedineniy Akademii nauk SSSR
(Institute.of Elementoorganic Compoun Academy of Sciences SSSR)
-SUBMITTED: l9Feb63 'ENCh: 00 SUB CODE; CC, OC
:NO REF SOV: 001 CTHER: 002
f

'.'~ (, i ~: ~A' , t 4 , 11 . V. ; -'- -1 Lk, 'i u 7 , T . A . - 7V ' INCORY.. I;(,'; i, , -, . V , . FG;'V, I71'r-, I I,,I,-, -~, 7Y
9 1 -1.1 ~ - . I, ,
1, . M. ; I !-,, D E I d~ ~ 1A f A . J.
fleterochain complex polyesters. lReporL '&,,'o.c2: 1'etermir-a'~Iun c"
double bon(is In unsaturated polyarylates by -Infrared spectrc-
S~!Opy. Izv. All SF)SR St~r, 1chim. no.2:261-26F 165.
(MIRA 18:2')
1. Institut elementoorganicheskikh soyedineniy AN SSSR.

SIDOROV, T.A.
Cor"parativel,-, study oil the mclear magnetic resonance and
infrared spectra of scdium borate glasses. Cpt. i spektr.
18 no.3:384-387 Mr 165. (MIRA 18:5)

U
I*.~f" -~CL On z;D~.,czra Of ate
-n- 1 V. no
r L y r e --ilicate C;-"ass llithium
'rcr-2 Z;;~c C~ a 0 f - 4,1=1
C) Z; t a:-, C: ox
j Z _7 1 C.:.. 0 ur, tc f d c ~L d d c d"d g-lazzer, Crystal-
c: I.,c a-6 i- c~ -py ro c e s 1) were carried out
Of by O-4"-erG. The Com-,
of of of 'rra various- S=ples
or- Of --c zcL;=,~c. observed -nfrared
0..c of -C! Dlacc~ b
Z~.re CC)r~-014.~L'd W--*-."-. of d.-*--:frc:.-,-~ ~Jon"~z "d defin-Ite crystalline
c 0 ur, %-.A 5In ~.-.Q ru,io:. Of cxis~~Cnce Of S-*--G- londs in lithium
Cord

ACC
'.o be prcz(-~nt only in glazscs where
Ii-ifrared spectra of
to cryGcal:;, while t'-.c narrow band at '1020 cm-1.
c;-yztaII;, witi obtained by oth,ers.
C;" O~,Jel",ruck -k-A oil clo.,,c to spodiu..cnc and in
zi lica conton-.;; ~4o -t-.rijutc.- -Lo t,,c vazxcous naase. This
V to a -4,..-Lon clod;-:! -.o that of cl-a,,r-zz ~Iasz A p"-.Cze
'based o.-, the z--,cctra yielded, rezuIzo coincicking
-z ja co,-,c^uded that, cm advan-
oj7F.-,inCLL z)y x cy 62f"rr-c-z.-,on. i. %,
'f 'r -* 1, ty of
e 0 over x my --C,;ion 4a .4-1-
71Y
ccsc, T)"'ase of the pyrocera:. and avoroximate c=positi
~-n. ., :i-;-ures and 1 table
su~ CCJD---*:,.. 23/ SULX DATE: G2.Apr0"5/ 0.~.!G RL.F: 005/ 3--l. ;RZF: 002

ACC NRs AP6036793 SOURCE CODE- IR/0363166/002/011/2039/2044-
AUTHCR: Sidorov. T. A,; Tyullkin, V, A.
CRG: none
TITLE: Investigation of glass ceramics in the L-LzO-Al 2-03-S'02 system by the method of
electron paramagnetic resonance
SOLRCE: AN SSSR. Izvestiya. Neorganicheskiye materialy, Y. 2, no. 11, 1966,
2039-2044
TOPIC TAGS: metal ceramic material, lithium oxide, aluminum oxide, silicon dioxide.
electron paramagnetic resonance
ABSTRACT: The glass ceramics were investigated in a standard FZ-1301 unit with a
double modulated magnetic field. The composition of the glasses on the basis of which
the glass ceramics were obtained, is shown in Figure 1. TiO2 was used as a catalyst
the crystallization. Based on the experimental results, an extensive table gives the
g factors of the electron paramagnetic resonance lines. It was established that in the
crystallization of the glass, the neighborhood.of the centers determined by the
electron magnotic resonance line with g = 2.010 is ordered. This means that the end
oxygen atoms enter into the crystal lattice. 7his result agrees with data obtained
with an infrared spectroscope. The changes in the structure of the lines (during
Card 1/2 UDC: 666.1:542.65:538-113

ACC NR: AP6036793
crysta1lization), due to the electronic center in the titanium, indicates that in the
formation of glass ceramics, the titanium atom also enters the crystalline part of thel
glass ieramic. The series of electron magnetic resonance lines, which have a g factor
between 2.01 and 1.94,-iB related to centers in the crystalline 1ithium silicates.
Orig. art. hass 2 figures and I table.
SUBCODE: 11/ SUBM DATE: 12Fob66/ CRIG REFs 008/ OTH REFs 003
Card 212
Figure 1.

KOTYLIRA. V.A-. kand. vot.vAwk; SIMOT. T-L. vetvrach. YIRGAYIT, X.P.,
votyrach.
Coapmwd treatment of paratyphold fever in calvas. Totorluarlia 35
na.l.-M-.65 To 058. (NIMA llt2)
1. Nauchno-prol2yodstvannaya laboratorlya po borlbe a bolosayaod
moladnymim (for Kmyllna), 2. guybyshavskaya =zhsowkhotna^ vet.
baklAboratorlya (for 51dorov, Torgaqcv).
(Paratyphold favor) (Calven-Diseases and post@)

SIDOROV, V.
"Mobile 560-)-.va, 6-1010, 4-ky. Tranaf oritter Station." Tr. from the Russian. p. 131, Praha,
Vol. 4. no. 3. gar. 1954.
SO: East European Accessions List, Vol- 3, No- 9, September 1954, Lib. of Congress

6(6)
SOV/107-59-2-11/55
AUTHOR: Sidorov, V., Deputy
dr,
TITLE: 011 ComplaintE (Nashi pretenzii)
PERIODICAL: Radio, 1959, T1r 2, p 14 (USSR)
ABSTRACT: The author bluaes the bad service of television re-
pair shops. it is impossible for a television set
owner to obtain antennas, cable, voltmeters or auto-
transformerst it is 'evbn practically impossible to
purchase an o:?dinary 6afety fuse.
ASSOCIATION: Kirovskiy raysovet,g. Kopeysk (the Kirov Raysovet
at Kopeysk)
Card 1/1

80) SOV/25-5'1-4-29/44
AUTHORS: Azarkh, M., Sidorov, V~, Engineers
TITLE: "Elektronit" (Elektronit)
PERIODICAL; Nauka i zhizn', 1959, Nr 4, p 67 (USSR)
ABSTRACT: Recently a new material "elektronit" for electric insulation
was developed by Engineer F. Gorshkov of the "Dinamol' Plant
in cooperation with N. Dodonov, Engineer of the Teentrall-
naya nauchno-issiedovatellskaya laboratoriya asbesta (Central
Scientific Resea7ch Laboratory of Asbestos). The basic
materials usod for elektronit are asbestos fibres and syn-
thetic rubber. In comparison with the generally applied
micaceous material, elektronit possesses many advantages.
It has a very high electric strength and can be used in de-
vices operating under 600 volt and, as has been recently
proved in tests, even up to 3,000 volt. There are 3 photos.
Card 1/1

15(8) S'~V/25-59-7-27/53
AUTHORS: Azarkh, M., and Sidorov, V., Engineers
TITLE: Asbodin
PERIC;DICAL: Nauka i zhizn9, 1959, Nr ?, pp 66-67 (U6SM)
ABSTRACT: The article describes a new insulation plastic - asbo-
din (compound word derived from 11,isbest" and "Dinamo")
- developed by the Gorshkov brothersq Fedor 1jikola evich
and Dmitriyj of the Moscow "Dinamo",Plant Imeni S.~"'
Kirov, and Bagineer IT.Dodonov of the Vsesoyuznyy nZchno-
issledovatel9skiy institut asbestovykh tekhnicheskikh
izdeliy (All-Union Research Institute of Asbestos Goods
for Technical Purposes). Asbodin can be used in the
electrotechnical industry (FiGures 1 and 2), in building
construction, and in the household. It is made of asbes-
tos fiber, synthetic vubber, iron minium, and other
materials. Put first into press molds, asbodin is then
pressed to shape at a rather moderate teaperature, with
Card 1/2

S011/25-59-7-27/153
Asbodin
consecutive calcininG in an electric kiln. The new
plastic is economical insofar as it can replace such ex-
pensive materials as U-1ass textolite, various fibers,
and silicon-ovganic plastics. In 1958 alone, the new
plastic brought about a savin.,.; of as much as 500,000
rubles at the above plant. There are 2 photographs.
0
ASSOCI.A.TION: J~oskovshiy za-vod "Dinamo" imeni S.M. Kirova (MOSCOw
"Dinamo" Plant Imeni S.I.I.Kirov)
Card 2/2

AZARKH, M. , Inzh. ; SIDOROTI- 1'. 0 inzIl.
Safet7 control panel. flnuka i zhizn' 27 no-7:67 JI 160.
(KM 13*7)
1. Moskovskiy zavod 'Dinamo.0
(Cranes. derricks, *to.) (Antomatic control)

SIDDROVP V.; ZVMIEVI N.
For the boat production in the world. Vnesh. torg. 41 no,8:34
161. (MIRA 14:8)
(Moscow-Electric industries)
(Russia-Comerce)

MUHIMIEDUANOV, N., student; TURULINA, T., studentka; Pni'VLOVA, I..%
studentka; PARSHAKOVA, V., studentka; SUTBAYEV, S., student;
SIWROV, V., student; ANDRUSEVICH, V., student; BAVEIOV, A.,
stJdd_p_R--,7'Kr8RAMOVICH, B., student; IIALIlOVSKAYA, Ye., studentka-,
GUI)OCHKINA, L.M., assistent
Mineralogical characterisitcs of loess of Alma-Ata Province. Sbor.
naueb. trud. Kaz GKI no.19:i5g-163 I(c. 041RA 1.5:3)
(Alma-Ata Province--Loess)

I
SUZOROV, V.
Unilorm methods. Mot.ugl. 9 zosl2s4-3 D 160. (KLRA 13:12)
1. Sekretarl Artemoviskogo gorkous NommuMstichookoy partil
Sovetskogo Sayusao
(coal mines ad slalmd) (mine management)

SHONOROVP G... inah.; _PAPqROL__L, inzh.
Foamed polyurethan sheets, Na. stroi.Roo. D04:31 1p 161.
(KM UsO
(Urethanes) (Building materia2s)

SIDOROV, V,
For ri-at c~)op(-rnticn. Grazhd. a-,, 19 My 10~2.
( M i F."A I F . 6 .,
4. Chlen llrnnorskogo krayevogo komiteta Koramunisticheskoy
a
par,.-"i SrilleLokogo Soyuzu.

SIDOROV V sh.
-1-M!I - -IIAU~p
-~R , , to,
Create exemplai"j sanitary evnditions in the city of Sverdlovsk.
Zbtl,kam.kh'O~~ 9 no-7:28-29 - 159. 1 . (MM IZIII)
1. Upravlyuyushchly trestou ochistki, g.Byardlovska.
(Sverdlovok-Streat cleaulng)

si - *vropol')
Combined objective vith a bamboo tube. Sov. foto 19 no-5:60-61
YT 159. (KIRA 12:9)
(Telephotography)

SIDOROV, V. (Stavropol')
Inexpensive long-fucus lensen. Sov.foto 21 no-3:31-32 W 161.
OIRA 14W
(Leames, Photograpbic)
I

50) SOV/62-501-1-9/38
A"TTHORS: Sterlin, R. N., Sidorov, V. A., Fjiunyants, 1. L.
TITLE: Reactions of Fluoro 010fins ftorolefinov)
Comnunication IX. Action )f Anhydrous Aluminum Trichloride
on Fluoro Olefins (Soobshcheniye 9. Deystviye bezvod-iogo
trekhkhloristogo alyuminiya na ftorolefiny) .
PERIODICAL: Izvestiya Akadernii. nauk SSSR. Otdeleniye khimicheskikh nauk,
1959, Nr 1 , pp 62 - 64 (USSR)
ABSTRACT: In the preceLt paper the authors investiCated the effect
exercised by anhydrous AlCl 3 on fluorinated olefins and
especially on perfluoro propylene and 2-hydroperfluoro
propylene. A~-. a result of the interaction of CP 3- CH - CF2
with AM 3 pentachloro propc-ne cc'3- CH ~ CC12 is synthe-
sized as the only reaction prodnct in a CH 3COC1 solution
under pressure (yield 65.51",). Similar results were obtained
in the cold, at atmospheric pressure find in the substitution
of chloroform for chloro acetyl. The complete exchange of
Card 1/3 fluorine atoms for chlorine in fluorinated olefins takes

Reactions of Fluoro Olefins. Com7iunication U. Action SOVI/62-59-1-9/36
of Anhydrous Aluminum Trichloride on Flurro Ole-'ins
p1rice under extremely soft conditions. This exchani,,e
apparently is a rQstilt of the u,n conju~~ation in the
2-hydroperfluoro propylene molecule
F1 C11- CP2
PP
F
which determines the mobility of fluorineatoms of the CF 3
group ari,4 the levity of the rillyl regrouping. In the reaction
of AM 3 with perfluoro propylene, which was carried out
under equal conditions as in the caze of 2-hydroperfluoro pro-
pylene, the only reaction product obtained was a compound
with a C 3FC1 5composition. Its structure may be expressed by
one of the following formulae: CFC1 2- CC1 - CC1 29
Cel 3- CP ~ CC1 2 (Ref 3). The compounds obtained were
oxidized in order to determine their structure. Trichloro-
Card 2/3 acetic acid was synthesized as a result of the oxidation.

Reactions of Fluoro Olefinc. Comnunication IX. Action SOV/062-59-1-9/38
. of Anhydrous Aluminum Trichloride on Fluoro Olefins
This may be taken an a proof that 1,10,30-pentachloro-
2-fluoropr(ppylene-3 vas obtained as a result of the exchange.
There ar-e :; refet-ences, 1 of which is Soviet.
5 UB 71, 1 T-E D : i1pril 17, 1957
Card 3/3

S/020/60/132/04/21/064
B0140007
AUTHORS: Donaboday, A. T., Sidarov, V. A. Timarev, K. V.,
Torkhovskaya, Y_ I.
TITLE: The Relationto Between the Velocities of Simultaneous
Vertical Notions of the Zarth's Crust, the Gravitational
Fields, and the Elements of the Earth's Structure
PERIODICALt Doklady Akadenii nauk 353R, 1960, Vol. 132, No- 49 PP- 810-813
TEXTt In the introduction, the direct and indirect correlation between
the time-dependent changes of the gravitational field and the vertic:1
motion of the Earth's crust are discussed, and two symbolic relation
for this purpose are given. In the geophysical laboratory of the
Kompleksnaya yuzhnaya geologicheskaya ekspeditsiya Akademii nauk SSSR
(Geological Expedition to the South for Comprehensive Studies of the
A~ademy of Sciences, USSR), which was under the supervision of A. T.
Donabodov, systematic inv9stigations were carried out in 1957 ot the
indirect relations between the gravitational fields and the vertical
motions of the Earth's crust. At the same time, the characteristic
Card 1/2

The Relations Between the Velocities of S/020/60/132/04/21/064
Simultaneous Vertical Notion@ of the Earth's BO14/B0O7
Crust, the Gravitational Fields, and the Elements of the Zarth's Structure
features of the structural elements of the Earth's crust were investigat-
ed. From data, which were determined in the territory of the Caspian
Sea, relations between the gravitational anomalies and the vertical
motions were found to exist. Three main types of relations, via. a so-
called direct, an inverse, and an indefinite r*lation, were discussed.
From the diagrams of these measurements (Figs. 2-3) for the profiles
Rostov - Sallsk (Fig. 2) and Stalingrad - Krasnodar (Fig. 3) carried V/8
out in consideration of other profiles, several conclusions are drawn
and discussed in detail. There are 3 figures and I Soviet reference.
ASSOCIATIONs Inatitut g*ologii i rasrabotki goryuchikh iskopayesykh
Akademii nauk SSSR (Institute of Geology and for the
Exploitation of Combustible Minerals of the Ae&demy of
Sciences, USSR)
PHESENTEDt October 28, 1959, by I. P. Gerasizov, Academician
SUBMItTED: October 27, 1959
Card 2/2

5/0' 4/ 61/01~0/0
Biol
r
G Siaorol e On solid Stall
elegini VrOVIlen 1961 1 65 -61
1, M Istjo 'a of toluene by I no. ill lene in
NIM ,OMyqhjenIftO5t ' and vropy ) vith Sri 059
T -IT LF, 1 .08, toluene a ~5 go 5 its assohig
from. dism ter eig t 10 21
(tot Iera
(inne slay
roduced '", hZone llog ing
a big iesel9uhr I
,,,there 9 930 10 ' etiOn the fO id, on industris
The vessel' The res dL 0 ith ric So The 13a
T tee t ,,I e,r - f j.1 e"hospho 'P295total
Jertjeal a ta Ys -ts and alyst P lass rings - The
le cost I inse- of cat jg 9 pp5fle, let.
f immobI so 0 al age 5- 4~ s'26. 1g/tab immobile the
aed bY (2) 10 g) ( th Wf itis on to
to bou thic~Lnev I of, 2streng v Ith 010 ordiD9
.9 rin 8~ iste a see lene
to~ gl layer cont aiesl ties 0 bine
mm 1960 ee 6 f aroma be G M opg,,,e - pro?l in
(9 . 98.* m tion 0 ich Mayr9 ump e
Vol, cat&.lys* Sly h ane *a er S
Otivity 4. YIS nits V us jng
a g,dL for 'he in I %hen late& tolue Una
60-* u ,jo ma uTitl . calcu burette
Betw, tus gists 0 its P the . efrom a
"s
'P*e
Ppara ta con "and opylenet '03.9
0
pass.,. c teria- 30 PT a added &rOP
d
volume 'Stalls ra'P Ms M
seous
2 contain fractio
e
ive
the ct ective.
ctt01
degree frao hile ed to the
tct ~~
250-27
0
ature r, (V 1-9 - and at 250 - 27501. a
at
0 a., and
50C-a
mo
1
r,sr& 00 amol ara
t0of
Card 21 01500C red ar ratio of
rue
5 Cd ed thec0
-used -rlaie Yield to 70 O'~rn-e
0 a4uced the Conversion
_ 60%.
deer
higher Yield, f 0 Gradual e er
of .raI t mp r8
9adu
(591nItemper-
1%a
and lower
w

SIDCROV, V.A.; SHABURCV, M.A.; SOFRONENKO, Ye.D.
Analysis of a nixture of 2-methyl-2-butanol and
2-methyl-2-butene based on infrared spectra.
Zav.lab. 27 no. 7;826 161. (MIRA 14:7)
1. Novo-Kuybyshevrkiy filial Nauchno-isaledovatel'3kogo instituta
sinteticheskikh spirtov i organicheskikh produktov.
(Butanol--Spect?a) (Butene--Spectra)

OSADGHENKO, I.R., red.; MASLYANSKIY, G.N., red.; BUIRSIM, N.R.,
red.; POKORSKIY, V.N., red.; KLIMENKO, V,L., rod.;
-MLDAVSKIY, B.L., red.; S.~~ ~~.A.,red.; PORUNKOVI,
G.G., red.; TOMARCHENKO, S.L., red.; FONKMA, T.A., tekhn.
red.
(Production of benzene]Proizvodstvo bensola; po materialam
Vaesoiuznogo naitchbo-tekhnicheakogo soveshchanila, 1960 g.
Leningrad, Goskhimizdat, 1962. 275 P. OGRA 16:3)
1. Vsesoyuznyy iiauchno-isaledovatellakly Institut neftekhi-
micheskikh prot3espov. 2. VBesoyuznyy nauchno-issladovatiall-
skiy institut n-afiekhimicheskikh protsesBoy (for Maslyanakiy,
Klimenko). (Benzene)

5/064/62/000/007/001/003
B117/B101
AUTHORt Sidorovi V, A.
TITLEt Oxidation mechanism of paraffins in liquid phase 10
PERIODICALt Khimicheakays. promyshlennost', no- 7, 19629 ~4 -29
TEM This is a survey of' non-Soviet and Soviet papers 6n the oxidation
mechanism of paraffins in liquid phase. Problems discueseds location of.,
oxygen attack in the hydrccarbon chainj decomposition of peroxide com-
poundal conversions of perdxide decomposition products. The.study of the
kinetics of the formation of pure oxidation products is recommended,
particularly in the initiEtl stage of oxidation. There are 85 references.,..
Card I/I

SIDOROVj V.A.
Mochanin of the oxidation of paraffinic hydrocarbons in the
liquid phase. Khim.prom. no.7:490-,495 n 162. (KIRA 15:9)
(Paraffins) (09rdation)

$11911621000101010011010
C) B101/8186
AUT1101; t Ileyman. M. 13., Xovnrakaya, B. M., Lovantovakaya,.I. I., Dral-'
iO I G. V. A., X..h.tk.,, V.
Trovnm,in., G, L,, Tatovoolyan G. 0-.'q'TUTFe"rG-OV3, L Dd
TITLFs itibilization of p6lynmide films for agriculture
?%;1101jlt;, Lt Vl-natiche3,ciye masojo no.. 10, 1962, 6 - 8
TEATs P ,tection or polynijide films, type 54v as used in hothouses and
niloo, r vin erecto of photo- and thermo6xidation. was tented by trying
Vnrlala f, 41,11tivus under various test co-nditions.i The following were ndded
a:j ultrnt~jolot light n1sorborni 2-hydroxy-4-iaotboxy-tenzophanons Oh0q)
(OUBF) (.~), 2-hydroxy-L.-alkoxy-b nzophopona (a thixture. of tonzophenones
vjtj, vnelous nl%oxy Crt,ups of th:. typ 0C H OC H or 6C H ) (11), and
. 7 15 6 17t 9 19
a I
2-hydroxy-51-meti,yl-betizotriazol (Ti:uvin) (Iii~. As antioxidanta"KI
Una oop!)ur naphthenato and organic stabilizers of the following, ty3eweire
"Lliedt -0 derivatives (if aromstio amineal 2) phenol deriv ativ r m
oxU1.11neel I) 2,6-ditert-butYl-4-mothyl-phanyl-pyrooat*ohin ph:: philte (,I)oatot"
Card'1/2

~/191/62/000/010/001/oio
atfillili-'at toll of ... BIOI/B186
Polymaide rilm ')1%n1.r, prrduced b;r condensation, namely hexamethylene nAlvi-
nate -ind ~ -cni~rol ctam nt 2600C in an 14-atmoophero, were subjected to
therno- -%n,1 1Photoox1dnti%e action. LiCht sources were carbon-arc and
morcury,q1i,,Vtz inwila, tyie rl?K-2 (PRA-2). Temperature in the test chamber
vVin 70 ~ - C. Thormoozicntion measured by the drop In oxygen pressure was
elininat(~d woot officiently by the pyrocatechin asters and phenyl-p-naph-
thyl-amine. It fan fewint.. that stabilizers 'of the OMBF and Tuvin types not;
us antioxidrinto. j'hditoaxilation experimertte showed the followinr resultal
in moot cnaca the elon,a,ion at rupture dropped even on initial exposure. I
After 200 hru of exposuro time, breaking tenacity of both stabilized and
nonatribilized films fell by approximately 20 - 25%. AEeing time until
etabrittlument %-w,iu detern~ned. Without an inhibitor it began after 190 hre
of exposure to the litht of an arc lamp. Optimum results were obtained
with 1,.,roo,itochin asters (250 hro), KI + copper naphthenate (260 firs) and
(,inntovar) -1 ((2.6-di-tert-butyl-hydroquinbne)) (240 hre). Different so-
tion of the light from the aro lamp* and the mercury lamps was explained
by spectrum differences. Yurther field tests are recommended. Thor* are
3 firurce find I table.
Card 2/2

BORISOV, Ye.F., dots.; EREGELI , E.Ya., prof.; BUKH, Ye.M., dots.;
VASHENTSEVA, V.M., dots.,- GOLEVA, Yu.P., kand. ekon. nauk;
COLEVA, A.P., kand. ekon. nauk,- DEMOCHKIII, G.V., dots.;
DONABEDOV, G.T., kand. ekon. nauk; YEilMOLOVICH, I.I., dots.;
KALYUNRY., V.M., dots.; KORMEVA, K.G., dots.; KUZNETSOVA,
A.S.,, prof.; HIAOSHNICHENKO, V.S.# dots.; MYASNIKOV, I.Ya.,
k*W. ekon. nauk; PIKIN, A.S.,, dots.;-.PTDOROV,, V.A.; SMIRNOV,
A.D.,, dots.; 30LOVIYEVA, K.F.,, dots.; SOROKINA, I.F., dots.;
TARUNIN, A.F., kand. ekon. nauk; KHARAKPASHIYAN, G.M., prof.;
MENDELISON, A.S., red.; SITVEYTSER, Ye.K., red.; HOTOVA, R.S.,
red.; GARINA, T.D.., tekhn. red.
(Economics of socialism] Politicheskaia ekonomiia sotsializ-
ma. Moskva, Gos.izd-vo "Vysshaia shkola," 1963. 476 p.
(MIRA 17:2)

AT R V. V. A.
Thermodynazice of the process of cymene production. Khim. pros.
no-3:201-205 Mr 163. (MMA 1624)
(Cymne)

Nr 974ql 22 'May
-NOTTOW
SELF- EXTINGVISHING EIASTIC FOAMED POLYURETHANE (USSR)
Sidorov, V. A., 1. M. Zverev, V. P. Areflyev, and V. D. Samsonov.
Plastiche.skiye massy, no. 4, 1963, 69-70. S/191/63/000/004/014/015
Self- extinguishing elastic foamed polyurethane MY has been prepared by adding
up to 25 parts of tricresyl or trichloroethyl phosphate to 118 parts of the poly-.
urethane starting material. The new material can be produced with existing equip-
ment. The physical and me chani6al properties of experimental self- extinguishing
MY were shown to meet theTY35 XII-395-62 r. spec ifilcat ions,. but tidditioil 6f phos,
phates considerably lowers the heat resistance of filly. The self -extinguishing.
IIIIY is easier to make with tricresyl than with trichloroethyl phosphate, and the
product has better physical. and mechanical properties. [BAO)

ACCESSION NRt AR4036156 S/0282/64/00~0/004/0069/W69
SOURCEs Rof. Zh. Khimioh. i kholod. mashinostr. Otd. Vop., Abs4 3.47.545
AUTHOR: Sidorov, V. A.
TITLEj The SSK-l mixing chamber to produce polyurithane foam
CITED SOURCEt Vostn. tekhn. i ekon. iesled. N.-io in-t tekhne-ekon. isslede Goo*
kom-to khime i neft, prom-sti pri Gosplane SSSR, vy*po 7, 1963, 22-23
TOPIC TAGSs polyurithane foam, foam, foam plastic, plastic, foam rubber
Lio
MANSLATIOM The oonstruation of,tho SSK-l mixing chamber in described. Prelin
nary mixing in the chamber is done by spraying low viscosity produota through
special needle valves and fiaal mixing is done with a oroas shaped agitator.
Designs of installations whioh provide two methods of produoing polyurithane foam',
are given. Installation 1 produoea 16 kilograms per minute of foam material for a
velocity of rotation of the 3ross shaped agitator of 300-500 revolutions per
minute. Two illuatrationse By N. Milenina
DAM ACQs 17Apr84 BUD CODE & Mr INCL& 00
'Card 1/1

SIDORUVJ V.,..
1'roduction and possible means ci' processing cymt-nes. Knim.
pr~.,[A, no.7:481-488 JI 163. (MIRA 16:11)

TELEGIN, V.G.; SIDOROV, V.A.
Alkylation of toluene with acetylene in a reactor with a
screened electric motor. Khim. prom. no-8:567-570 Ag 163.
(M1RA 16:12)

1-65
-4
L 2307 EWT(M)/EWII(J) Po,
ACCkSSION NR.-- AR404M7- -~--S/0081/64/000/013/8053/053
SOURCE: Ref. zh. Khimiya, Abs. 13S335
AUTHOR: Kochetkov, V. 1.: Sidoro4, V.-A.; Morozove- N -V,,
TITLE: A study of the -affect of stabilizing additives an the a&tqjj__khysLcomech&n-;_.:__.~:
ical and optical properties of a poly&=Lde fLjm
CITP SOURCE: Nauchno-Issled. tr. Vsee~#- n-.--L. in-t plenochnt materialov L lskusatw__
koxhi, ob. 14, 1963, 92-110
TOPIC; TAGS: polyamide J!ilm, polyamide light -permeability, polyamide heae resL&t___,7
ance, polymer film stabi.lity, stabilizing additive
1r
TRANSLATION: The authore studi d the effect of the addition of stabilizing ad-
ditives (CuS04, CaHP04, TL02,!Y-naphtol, phenol, dipheny-lguanidine, resorcinoi,
maleic anhydride, phenot-formaldehyde resin, etc.) on the-physLcomechanical-and-
optical properties of pclyamide film. They found that the most effectivt stabLl-
izers are KIJ -naphth4l and phenol-formaldehyde resin; the greatest heat re-,
sistance was produced by the addition of.stabiliurs in amounts of 0.25-1%.
Card 1/2

TELEGIN, V.G.; SIDOROV, V.A.; KHARCHENK0, A.A.; ZPARKOVA, D.H.; TREYBSHO, Ye.I.
I------
Obtaining ditolyl ethane. fleftepc-. i neftek-him. no.l.-
34-39 164. (MIRA 17:6)
1. Vsesoyuzryy nauchno-issledovateliskiy institut neftekhim-
icheskikh protsessovp Leningrad.

ACCESSION NR: AP4033056 8/0147/64/000/001/0181/0186
AUTHOR: Sidorov, V. A.
TITLE: A vibration study of rods with apertures
SOURCE: IVUZ. Avlatslonnaya tekhnika, no. 1, 1964, 181-186
TOPIC TAGS: rod vibration, aircraft structure, aircraft vibration, vibration
frequency, equivalent rod method, flexure, bcnding, rod aperture
ABSTIIACT: Pointing out that many aircraft assemblies consist of parts with apcrituros
and slots, the author notes that there Is a lack of information in contemporary technical
literature concerning the vibrations of such structures. The present paper presents a
method for the calculation of the natural frequencies of the transverse vibrations of rods
with apertures. The "equivalent rod" method ir, employed. The equivalent rod must
have uniform strength along Its entire length and the same frequency as the rodwith
apertures. Onco the lengti of t1io equivalent rod is found, the following well-known.
simple formula can be used to determine its frequency
Card 1/4

ACCESSION NR: AP4033056
The length of the equivalent rod is determined In two,stages: first the length, equivalent
to the section with apertures, is found and, then, the length of the equivalent rod (see
Figure I of the Enclosure). Formulao are derived for the determination of the width of
a rod section equivalent to the section with apertures, vibrating around the node (both in
the case of n apertures of the same diameter, arranged in a section of length/ I? , an
in the case of apertures of various diameters). The derived expressions show that it Is
not the dimensions of the apertures, but their arrangement vvith respect to the node
which exercises the greatest effect on this parameter (that is, on b' - the width of the
equivalent rod section). During the vibrhtion process, tho rod section under considera-
tion is subject to flexure. Ilic author adduces formulas showing how to select a section
length 2 1 such that the section, with its former sectional profile (b x h) (where b and h
arc the width and height of thz! rod) will resist bending in the same way as the section of
cross-section (b' x h) of lcng~hj. The method proposed for determining the frequencies
of transverse rods with apertures Is applicable to apertures of any form. A verification
experiment was later performed which revealed the following details with respect to the
nature of the influence of the disposition of the apertures on the change of natural frequen-
cies: 1) the further from the nodal line the aperture is located, iho greater will be the
of frequency; 2) apertures arranged on internal nodal lines have a negligible
g effect on the natural frequencies; 3) apertures arranged on extreme nodal lines
=
have no effect on the natural 1requenoies 4) apertures arranged beyond the wareme nodal
2/4
Cord

ACCESSION NR: "4033056
lines increase the natural frequencies. Orig. art. has: 12 fomulas, 2 tables, and 3
figures.
ASSOCIATION: None
SUBMITTED: 21Jun63 DATE ACQ: 11MayG4 ENCL: 01
SUB CODE: AS No REr. SOV. 00~ OTHER; 000
3/4
Cord

ACCESSION NR: A-P4033056
ENCLOSURE: 01
Fig. I. I and 11 - sequential positions of a rod at vibrations corresponding
in the given case to a third frequenoy
card 4A

ixcimsiox xR: AP402684T 4(006-V6h/000/00k/0w310W6
AUDIO: Telegin, V. G.; Sidorov, V. A.; Zharkoysi D. R.; ftryukova,, L. N.;
Tokareva, A. A.
TITLE: Preparation of Individual vinyltoluenes, 4
SOURCE: 1(himiya I teldmloglya topliv I musel, noe 4, 1964j, 3-6
TOPIC TAGS: Vinyltoluene, preparation, synthesis, vinyltoluene Isomer,, separs""01
ethyltoluene, toluene ethylationp dehydragenation, Isomer separetlon,, frectum-
ation.. dealkylation., cracking, disproportio- rion
ABSTRACT: The study vas made to determined If It is possible to prepare IndIvIdual
vinyltoluenes or at least mixtures of the vinyltoluenes enriched In one of the
isomerz. Ethyltoluenes vere made by continuous vapor phase ethylation of toluaw I
vith phosphoric acid catalyst. Since it is difficult to separate the A*b_YdXVGM3AW-
'tion products of ethyltoluene, the ethyltol-en a were separated prior to dehy-
'drogenation. The ortho isomer vas fractionated and the remslnJ mIxture of meU
and para isomers was sulfonated and the ethyltoluene s~"d selds vere bydrolysede
The separated isomers vere then dehydrogenated in the presence of water (vater:
:hydrocarbon ratio of 22:1) at 580C at a flov rate of 0-T5 bro-I an a catalyst
Card 3~2

comprising 87% Fe20j) 8%. Cr203 and 5% K20' Used on ethyltoluene the y1eld Was
94-96%; exhaust gases comprIsbd 76-78% B2s 19-21% OD2 and 2-4.6% hArocarbons.
Products were fractionated at 8 mm. Hg. The purest vinyltoluene Isomer prepared
was the ortho, containing 5-7% para-isoner. The other two Isomers were contsmi-
natedwith larger-asiounts of mixed isomeft. In comparison to I IIM Of
ethylbenzene, dehydkogenation of ethyltoluene is accompained by amdesirable
dealkylation, cracking and disproportionktion reactions, and the catalypt activity
is rapidly lowered io it must be regeneriLted after each cycle. Further vork in
needed on the purificati6n of the individual etbyltoluenes and on their dehydro-
genation to obtain individual vinyltoluenes contallain a min"mum of contaminating
Isomers. Orig. art. haa; 3 tables.
ASSOCIATION: VNMeftekhim (All Union Scientific Reseamb M3stitute of Patro-
lchemical Processes)
suna=: 00 n= ACQ: 2aAprj~4_..__/ I ' Ta OD
StM CODE: CH NO. FM. SOV: 005 OTM: 007

L-62504~k5 --EPF(c)/EWP(J)/EWT(m)/T------.-W/RM:'
5 OW
A=.SlDlf DR i AR5
SOMCE Ref. zh. Khimiya, Ab s. - (64
90-
AUMOR., Sidorov V. A.; Troamn, G.M. jAleksandrov, K.
I TITLE; Self-extinguishinj( foam polyurethane
Ci SOME: Vestn. tekhn. i ekon. infom N-i. in-t tekha.-ekon.'Loaled. aas.
kom-ts khim. prom-stipri Gooplane BSSR., vYY- 71 1964P 11
TOPIC TAGS: polyurethaneo fcam plastic, polyvinyl chloride, flammability
TRAIMATION: In order to rvduce the inflammability of elastic foam polyurethane
up to 54 of polyvinylcliloride was added to the mixture before adding the, 2A. and"
2.6-isomers of toluylenediiaocyanate. The introduction of polyvinylehloride im-
i pairs some of the foam polyuretham characteristics, such as Ultimate tensile
;sbrtngth, melting point, elongation during the tensile test, and Increased weight
losses -with heating. Hoveve:r, the foam po3,,n=ethane also acquires desirable prop-
erties 6duced inflammability good veldability vith hf current, and ease of laold"~--,
Ivanan.
Ing into complex shapes). Z,
SUB
CODE: MTj 00 ENCL: 00
C d

~F,(p)/W(J)/T. Tc-
'T ,4/,Prs* &1- EN -777-4-
[A~6 RPq am 1 99.1 UR/ 11 6.51 /008/067/S66i~-"
SOURCE: Ref. zh. Khimiys. Abe. 8S390 12
AUTHOR: ~idorov, V. A.;; Trosmanp 0. M.; Rogov., V. M.; Aleksandrov, 9, N_.
TITLE: Improving the purformance characteristics of PK-4 po yamidefilm
CITED SOURCE: Vestn. tnkhn. i ekon. inform. N.-i in-t tekhn.-ekon. issled.,cos
kom-ta khim. prom-sti pii Gosplane SSSR, vyp. 7, 1964, 13-14
TOPIC TAGS: polyamide :,.*ilm, polymer film strength, polymer aging, stabilizer,,
protective coating, pol,rurethan lacquer, film transmittivity, phthalocyanin blue
TRANSIATION: To improva the performance characteristics of the PK-4 polyamide
film (PF) in agricultural applications, stabilizing admkxtures are added to the
composit4on, such as an-Lline-phenol-formaldehXll_EeLsin4~polyamide film of brand
PF-4FF)10or cre o1; the :?F to also coated with a protective layer of 201yuretha
c u~3 (PUL consistin:g of a mixture of glycerol toluylenedtisocyanate, a poly-
eater,,*chlorobenzenej, a,2d ethyl acetate. Accelerated aging of PF was studied
under a PRK-4 lamp for 10 hr.- It was found that-the properties of PF of brand
_;ard 112
34

ACC NR, AR6000275
SOURCE CODE: UR/0061
AUTHORS- Sidorov, V. A.; Pefer, I. P.
TITLE: Napped rolls made of elastic polyurethane foam materials 1/j
SOURCE-. Ref. zh. Khimiya, Abe. 14S396
REF SOURCE- Vestri. tekhn. i ekon. inform. n.-i. in-t tekhn-ekon. issled. Coe. kon-ta
khim. prom-sti pri Gosplane 3301 vyp. ill 1964, 15-16
dustrial
TUP.C TJQS: polyurethane, resint epoxy voei&, foam plastict adhesi
,a A6 -On epoxy W"Wine, Z-SKN
__ , &M. itrile rubber / IW-17 resin, ED-5 resin, E-40 MOM -26
nitrile rubber
ABSTRAM Experiments wore conducted in the application of cotton nap on polyurethane
foam roll in an electros-.atic field. It was established that the quality of the
produced material is determined by the nature of the adhesive, its application method,
and the method of the subsequent thermal treatment. Satisfactory reaulte were ob-
tained with adhesikes baoed/on polyurethanes (PU), polyvinylacetate emulsion with
addition of 17-17%nd ED-5 Sesins. To decrease toxicity and to increase the stability
of the adhesive ased on PU, nitrile rubber,