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SCIENTIFIC ABSTRACT SMIRNOV, M.N. - SMIRNOV, M.S.

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CIA-RDP86-00513R001651520019-1
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S
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100
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August 25, 2000
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December 31, 1967
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SCIENTIFIC ABSTRACT
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U.S.SA. 67,916, F increase the yield of AlA ill thC Bayrr promb,%. there a, Added to the leached Wp a smill quatitity of org. 11tattef, bitch as utono- at polyhydrk ak., dibAc Acid. by-frov it"(JUcC h tUtL% - , a,.jd. muno- or polywebaritle, UMA. j)kCt traw ur ll l u vr. s protein or its deSmIlAtiatt prLutuct, or Lv ~ -trm-1 llo~e COO coo see *so f I I in AT tei j~1.1-,SLA NLIALLOCKAL LITERATURE CLASSIFICATION 410.0 11W.4191. so* 441,04; -A %41,44 L. 04. CAI iiiiiiii air 5%. ist man u n 1tv SID a" ;~p 1w It x a W, .1 A, (It An I I v 1w 0 0 w I w a ft I I * * * IV *;,; 0 0 0 0 0 0 0 0 * 0 0 0 0 9 0 * 0 a 0.0 0 0 0 0 0 0 * 0 0 0.0 0 0 0 0 0-4W 0 0 0 * 9 0 0 0 * 0 0 0 49-0000 0 0 41 0.0 0 so W, 0 *44-'e"'44 * 0 0 gal I 1 0 to If 11 to 14 t$ to a a x a It u If Ad x M 9 Is IT a If 41 All 44 , a a i A L -a-A.-P.- 1k.. M 90 JU A- W --A. d---j- 1- liv 4 X-- A k -L-Tt' 0 f- - II 60 4 P MiRNOV papgo$ - i M ( R%. 1 ~ , *0 -A Ced"d reks" betwe" Mblis t4wild seals. S. Karpachev and M. Smirnov (Und Breach. Aced. Sti. U.S.S.R.. Swrillovsk).7-J.-PhyS. CA#m. (U.S.S.R.) 21. JM5-12(1947)(in Ruitollan).-TIfe rullent i 1wrol 1 * " -00 01IMi. 1 l1ralcol W luallovill coll""Ir and now iff two) in't. 1 , ' .00 *to- a vat"U11% 00 111-1 unn. Its slej%ru.6 on life vilitadc I to the ctu accowdins to S - bj( v + va) end i k the 2 anondes From thm mealevements .0 x ! . - V is caled V It Is 0 23 v K id f li . . i . 1 l id willd Fb at 300% 0.42 v. for solid go mod or qu solid Pi, at rcmtn temp.. wed 0.1& 0.30. and 0.40 v. ( HIM (330') and 8"M (420 % Pb t 4W or Uquid Goa . a . ). rest#. , The contact ptxrntw differewe Y, is allnost equal Go to the differvoce between the giolentisills corresponding 1u x the electrucapillary was. of tbese metals in molten electrt)- Irfest. The e.m.l. of a cell is III - $'I plus the potentia14 if the difference tortween the electrolyte In conen. one to lhe_ 9 too to" and the rone1w rorr"Itividing to rtiviriyeor4ftry Insit. J, Ilibeffil'On qq sandal j $did*j it 4.C 44it Lw a.- sti ISOM F , 1 0 - ; i;; An I 1 4 ftd a a I IN It -3 63 a 3 6 u 9 AV 00 its ; a It 0 to to to a a st a 1111 a 9 :F9 of 000 0 000-0 0 00 000 0 0 0 OL Ot 0 OL 0 e 0 0 4, 0 0 0 0 CFI * III I,, IISJ;Ljc4~r4~rjg Fuml,,,rietitr D-,eratinns of DeriVing Cryolite b-, the Alk?JAno Iletbod V-11), Leiii-rigrad, 1954. No 1, C,arwl Tech Sm , All-Union. A-I~rd-trmr. R2.-nesium Inst (11. (RZh.Yliim, J.-)n 55) urve~, of Scentific and Tecli-ac:,l Disser'ations Defended at USSR Tir-her E~Ncational Tnstituticns (13) SO. siza. lio. 593, ')9 JiLl 55 SOV/ 13 7 - 58- 10 - 20698 T ranslation f rom: Ref erativn yy zhu rnal, Metallu rgi ya, 1958, Nr 10, p 52 (USSR) AUTHOlt: l(atsenclenbogen, P.D., Krochevskiv, V.A., Smirnov, M N. TITLE: Complex Utilization of Kola Nepheline Concentrate (Kompleks- noye ispol'zovaniye Kol'skogo nefelinovogo kontsentrata) PERIODICAL: V sb.: Legkiye metally. Nr 4. Leningrad, 1957, pp 37-43 ABSTRACT: Note is taken of a number of features of production engineer- ing and equipment found in the course of investigations of and development of a procedure at the Volkhov Aluminum Plant. Emphasis is given to the need for preparing the charge on the basis of extraction of alurninate caustics and Ca silicate. Per- missible maxima for impurities in the limestone and the nephe- line concentrate are established. It is recommended that sint- ering be done to a dense condition such as clinker. It is desir- able to combine grinding and leaching of the sinter at 68-700C. The concentration of aluminate solutions is 80-90 a A1203/ liter. The grain size of the ground clinker is from + I to -0.088 mm. The time required for silicon removal is 2-3 hours at 160-170'. It is desirable that carbonization be in 2 Card 1/2 stages, the residual A1203 contents being 4 a/liter in the first SOV/ 137-58- 10-20698 Co M'plex Utilization of Kola Nepheline Concentrate stage and 0.1-0.2 g/liter in the second. Equipment is chosen for each stage in the process, and a procedure for the employment thereof is developed. A high-output thickening filter, rendering contact between solids and fluids impossible (to avoid secondary reactions) is designed and perfected. L. P. I. NepheIiLe4 ores--Processing 2. Nephelite ores--Applicabions Card 2/2 137-58-6-11915 Translation frorn- Referativnyy zhurnal, MetallUrgiya, 1958, Nr 6, 1) 105 (USSR) AUTHOR Snurnov, M.N. TITLE- ~_`Th, gauss ~for th~e Differences in Degree of Extraction from Diaspore Bauxites on Leaching Without Addition of Activators (0 prichinakh razlichnoy vskryvayemosti diasporovykh boksitov pri vyshchelachivanii bez vvedeniya aktiviziruyushchikh veshch- est"') PERIODICAL: Tr. Vses. alyumin.-rnagn. in-ta, 1957, Nr 39, pp 24-35 ABSTRACT: The results of laboratory investigations in the extraction of A1203 relative to the content of various impurities in diaspore bauxites are set forth. The effects of the presence of CaC03 and Fe2+ and of thei e*venness of distribution of these impurities are investigated. The influence of organic impurities of the hurnic type (soluble in caustics) and of organic substances sol- uble in benzene are clarified. The effects of the size of the diaspore and the hydrate form of SiO2 are determined and the influence of length of storage is elucidated. The dependence of the degree of extraction of -4d2-03 upon these factors is set forth Card 1/2 in 9 tables showing that in each specific instance it is necessary 137-58-6-11915 The Causes for the Differences (cont.) to take into consideration the effect not of just one, but of two or more of these factors together. A.P. 1. Aliunimmi ores-Impurities 2. Aluminum ores--P:-ocessing Card 2/2 137-58-5-9273 Translation froni: Referativnyy zhurnal, Metalluraiya, 1958, Nr 5, p 70 (USSR) AUTHOR: Smi TITLE: Means of Increasing the Extraction of Aluminum Oxide in the Process of Leaching of Diaspore Bauxites Which are Difficult to Strip (Povysheniye izvlecheniya okisi alyuminiya pri vysh- chelachivanii trudno vskryvayushchikhsya diasporovykh bok- s itov) PERIODICAL: Tr. Vses. alyumin. -magn. in-ta. 1957, Nr 39, pp 36-43 ABSTRACT: Investigations were performed to evaluate the feasibility of increasing the intensity of the process of leaching of diaspore bauxites which are not readily leached by the standard process. It was established that - aching of these bauxites may be made more efficient by mean~~of simultaneously employing the follow- ing measures: increasing the consumption of lime by 5%, rais- ing the temperature to 2250C, grinding the material to 0.105 mrn particle size, and increasing the duration of the process. Better results are obtained if CaO is replaced by barium oxide. 1. Bauxite--Processing 2. Aluminum oxide--Production L. P. Card 1/1 3. Barium oxide--Applications 137-58-5-9270 Tran5lation from: Referativnyy zhurnal, Meralturgiya, 1958, Nr 5, p 70 (USSR) AUTHOR. Smirnov, M.N. TiTLE. Activating Effect of Certain Organic Substances in the Process of Leaching of Diaspore Bauxites (Aktiviziruyushcheye deystviye nekotorykh organicheskikhVeshc' .hchq'ach-v,-zd-' diasporovvkh pra v~s 1. boksitov) PERIODICAL: Tr. Vses. aLyurnin.-magn. in-ta, 1957, Nr 39, pp 44-51 ABSTRACT: In the course of studying the process of leaching of diaspore bauxites with synthetic and industri3i alurninate-lye solutions it has been established that the susceptibility to leaching is strong- ly influenced by organic impurities in a solution which contain alcohol groups. The activating influence of these organic sub- stances is manifested in the increased activity of time which, under these circumstances .. becomes more soluble in an alurn- inate-lye solution. In the process of leaching, the action of the organic substances varies owing to various contents of the acti- vating substances, such as compounds of Ca and ferrous Fe. When employing standard methods to determine the susceptibility Card 1/2 of bauxite to leaching, it is advisable to introduce appropriate 137-58-5-9270 Activating Effect of Certain (cont. ) organic SUbstances into the solution so as to avoid obtaining indices that would be lower than the true values. L.P. i. PaLLxite-Processir.a 2. Lye alumina-tes-Appi-ications 3. Orgar-ic anaterials-Applications Ca rd 2/2 137-58-5-9271 Translation from: Referativnyy zhurnal, IvIetallurgiya, 1958, Nr 5, p 70 (USSR) AUTHOR: Smirnov, M. N. TITLE: Activating Effect of Lime and Certain Other Compounds in the Process of Leaching of Diaspore Bauxites (Aktiviziruyushcheye deystviye izvesti i nekotorykh drugikh soypdineniy pri vysh- chelachivanii diasporovykh boksitov) PERIODICAL: Tr. Vses. alyumin. -magn. in-ta, 1957, Nr 39, pp 52-61 ABSTRACT: In the process of leaching of diasporic bauxites, activation is effected by a number of calcium compounds (apart from the activating influence of lime) which react with aluminate-lye Sol- utions and form tricalciurnhydroaluminate and Ca(OH)2. More powerful activation is obtained with Sr and Ba compounds. The leaching process is also activated by compounds of Fe2+ which react with hydroxyl ions of the solution to form Fe(OH)?; their activating properties are approximately one-half as strong as those of the CaO. Lime appears to be the most rational activat- ing agent. CaO should be introduced in amounts equivalent to 4~0 of bauxite by weight into bauxites which dissociate normally. Ca rd 112 This proportion may be reduced if the bauxite already contains 137-58-5-9271 Activatina Effect of Lime (cont. 0 activating ingredients. However, the total sum of Ca and Fe2f compounds in the charge, taking oxidation into account and taking one-half of the Fe2+ con- tent, must amount to 4% of bauxite by weight. N.P. I, Bauxite--Processing 2. Calcium compounds--Chemical reactions 3. Lye ahLmInates--Chemical reactions 4. Strontij-m compotinds--Chemical reactions 5 Barium comuounds--Chemical reactions Ga rd 2/2 SOV/ 137-58-7-14216 Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 7, p 36 (USSR) AUTHOR: Smirnov, M.N. TITLE; Or"Iphe-Ganwe;,bf-the Initial (at 500-5200C) Melting of Soda- Calcium Fluoride Mixtures in the Role of Active Additives as a Means of Combating This Phenomenon [0 prichine pervichnogo (pri 500-5200) plavteniya sodo-ftorkal'tsiyevykh shikht i roli aktivnykh dobavok kak sredstva bor'by s etim yavleniyen-il PERIODICAL: Tr.. Vses. n.-i. alyurnin.-rnagn. in-ta, 1957., Nr 40, pp 151-163 ABSTRACT: The.melting points of mixtures of the CaF?-Na?CO3type were determined by cryoscopic investigation of the melts and the variation of the melting temperature on the addition of sod-, ium silicate and si-licon dioxide. Observations of visible melt- ing oi mixtures ht. 5000C were made. It is determined that the CaF2-Na?C03 mixture has a eutectic of the composition 36% CaF2, 64% NaZ C03 which melts at 5550. Melting of mixtures composed of fluorite and soda is related to the eutectic melting Card 1/2 in the system CaF-2-Na ZC03_Na?SiO 3' The addition to the SOv/ 137-58-7-14216 On the Cause of the Initial (at 500-5200C) Melting of Soda-Calcium (cont.) soda-calcium fluoride mixture of a third constituent in the active form (SiO2, FeZ03) eliminates the visible melting of the mixture. Evidently, ow- ing to its high wettability, the third constituent, in the main, absorbs the liquid phase. The same results are produced by the addition of a third con- stituent in the inactive form but in considerably greater quantities. L. P. 1. Calcium-fluoride-sodium mixtures--Melting Card Z/Z SOV/137-58-7-14217 Translation from: Referativnyy zhurnal, lvfetallurgiya, 1958, Nr 7, p 36 (USSR) AUTHOR: Smirnov, M.N. '--=J-Mn- r TITLE: etiff TA_W_-P'o_ mation of Sodium Fluoride in the Re- action of Calcium Fluoride With Soda (Kinetika obrazovaniya ftoristogo natriya pri vzaimodeystvii ftoristogo kalltsiya s sodoy) PERIODICAL: Tr. Vses. n.-i. alyurnin.-magn. in-ta, 1957, Nr 40, pp 164-170 ABSTRACT: The yield of NaF from the sintering of mixtures under dif- ferent conditions is determined; the constants for the rate of reaction under these conditions are calculated. It is deter- mined that the formation of NaF from the reaction of CaF2 with soda in the liquid state proceeds according to the reaction: CaF? + Na2C03 -NaF + CaO +CO2. An equirnolecular mix- ture of GaF2 and Na2C03 melts at 5500C. Interaction in the melt goes on with considerable speed at > 9000. The reaction of the formation of NaF obeys a linear equation. The relation- ship between the constant ctkthe rate of reaction and the temp- Card 1/2 erature in the range 700-110 00 is subordinated to the SOV/ 137-58-7-14217 The Kinetics of the Formation of Sodium Fluoride (cont.) I Arrhenius equation. The activation energy of the formation of NaF is 14, 850 cal. A. P. 1. Sintering--Analysis 2. Sodium floride--Synthesis 3. Calcium fluoride--chemical reactions 4. Sodium--Chemical reactions Card 2/2 SOV/ 137-58-7-14535 Translation from. Referativriyy zhurnal, Metallurgiya, 1958, Nr 7, p 85 (USSR) kAUTHOR: Smirnov, TITLE: Rate of Formation of Sodium Fluoride on Sintering of Calcium Fluoride With Soda in the Presence of Silica in an Active Form, and the Nature of the Reactions Occurring Therein (Skorost' obrazovaniya ftoristogo natriya pri spekanii ftoristogo kalltsiya s sodoy v prisutstvii kremnezerna v aktivnoy forme i kharakter proiskhodyashchikh pri etorn vzaimodeystviy) PERIODICAL: Tr. Vses. n.-i. alyurnin.-rnagn. in-ta, 1957, Nr 40, pp 171-187 ABSTRACT: Experimental data are adduced on the kinetics of the forma- tion of NaF and Na silicate at various temperatures and mix compositions, as are reaction-rate constants arrived at in the course of mathematical analysis of these data. It is found that the formation of NaF in sintering is by the reaction of the CaF? with the Na silicate formed. The process attains a high rate at 800- 8500C. Under these conditions a mix with a 1: 1: 1 molecu- lar ratio between CaF?, Na2CO and SiO2 yields the best re- Card 1/2 suits. The yield of NaF is 85-84%; 10-1276 consists of losses SOV/ 137-58-7-14535 Rate of Formation of Sodium Fluoride on Sintering (cont.) of caustic in insoluble form due to the formation of sodium-calcium silicates. A 15% excess of Na2CO3 and a 20% excess of SiO? in the charge over the sto;cI!4ornetric molecular ra.tio raises the NaF yield to 95-96%. Equations are adduced characterizing the kinetics of NaF formation and the tempera- ture ratio of the reaction-rate constants, the latter being given for various temperature intervals. 2. Sod--;uni f-luoi-ides--Production. L.P. Ch-mical reactions--Ve-locity 4. Mathematies--Applications Card 2/2 SMIRNOV, M.N. i- ~ -~ "', ~ I " - - "I , ~ . ,w'. ~-;4, -,Producing activated aluminum oxide from carbonizer and decomDoser scale. Biul. THIN tsvet. met. no"- 7:27-29 158. (MIRA 11:7) (Aluminum oxides) S/136/60/000/011/006/013 E071/E433 Semi.-Industrial Testing of a Carbonator With a Top Gas Supply and air tube 25 mm in diameter. The gas distributor consisted of a two ring chamber 2 and six submerged grates 3 , placed over each other at a distance of 150 mm. Carbon dioxide was supplied- through Pipes 5 into the ring feeder and then through six vertical pipes into the ring chambers from which it is passed into the solution through comb-like channels 150 mm below the grate. The grates were made from rods 5 mm in diameter, forming a network with holes 5 x 10 mm. The total cross section of the holes was about 30% of the total surface area of the grate. Inside the carbonator there was a steam pipe, supplying direct steam for heating, and in the conical part there were four pipes supplying compressed air in order to preyent the formation of aluminium hydroxide deposits. It was expected that the duration of the process in the new 7~arbonator would remain at least the same as in the old, existing type ef apparatus. Tests of airlift as a stirrer indicated that it works satisfactorily at a consumption of 90 to 100 m3/hr of air. The type5 of carbon dioxide distributor tested, before the above des-sribed design was finally adopted, are shown in Figs.2 and 4. The dependence of the coefficient of utilization of carbon dioxide Card 2/4 S/136/6o/ooo/oli/oo6/013 E071/E433 Semi-.Industrial Testing of a Carbonator With a Top Glas Supply on the height of the layer through which it was bubbled is plotted in Fig-5 (broken line - extrapolation). During the test the height of the above layer was varied from 1200 to 176o mm. The experimental results are given in Table 1. Comparisons of size distribution of aluminium hydroxide produced in the tested and in an industrial carbonator are given in Table 2. The following conclusions are arrived atz 1. The airlift arrangement for stirring the solution can secure the necessary change of the liquid phase where it is in contact with the gas. 2. The gas bubbling arrangement worked satisfactorily and the carbonator with top gas supply can be recommended for industrial application. 3. The duration of the process does not exceed 10 hours. 4. The coefficient of utilization of carbon dioxide depends on the height of the layer through which the gas is bubbled and for a layer of 850 to 1500 mm varies from 50 to 62% respectively (in the present carbonators with the bottom supply of gas this coefficient amounts to 69%). 5. Low pressure blowers and high pressure fans can be used for the proposed type of carbonator. In the latter case the distance between the grates should be reduced to 100 mm. 6. Blocking of grates during Card 3/4 S/136/6o/ooo/011/006/013 E071/F,433 Semi-,Industrial Testing of a Carbonator With a Top Gas Supply the operation of the carbonator was not observed. 7. The size distribution of aluminium hydroxide produced in the carbonator was not materially different from that produced in the present type carbonators (in fact size distribution of the experimentally produced hydroxide was somewhat coarser - Table 2). 8. The introduction of carbonators with the top feed into the industry will reduce power requirements and, in the case of new plants, will somewhat reduce capital expenditure. The following participated in the experimental works G.G.Yeskina~ N.M.Kontorovich, M.A.Dudko, Ye.N.Tyuleneva, V.-_V.Borzenko, L._&jGana&pi. There are 5 figures, 2 tables and 4 Soviet references. Card 4/4 SMNOV, M.X.,__Kand.tekhn.nauk Cryolite formation process in the interaction of sodium fluoride with alumimim hydroxide. TSvet.met. 34 no-1015q-64 0 161. (MLU 14; 10) (Cryolite) (Aluminum hydroxide) (Sodium fluoride) SMIRNOV, M.N.; TSYMBAL, F.I. Investigating the crystallization process of sodium aluminate from thickened liquors in the Bayer process of alumina production. Tsvet. met. 35 no.1:59-66 Ja 162. (MIRA 16:7) (Aluminum-Metallurgy) SUMMOV, M.N.; TI NU MOV, N.N. Effect of agitation on the kinetics of aluminum oxide recovery during the autoclave-leaching of diasporous bawdtes. TSvet. met. 35 no.6-.46-51 Je 162 (MA 15:6) (BauxiL) (leaching) SIURNOV$ M.N.- - Chemism of the process and conposition of solid phases formed by the interaction of aluminum and sodium fluorides. TSvet. met. 35 no.9:61 67 S 162. (NIRA 16:1) (Aluminum fluoride) (Sodium fluoride) (Chemistry, Metallurgic) SMIRNOVY M.N. Metastable solubility of" silica in aluminate solu.uions. Zhur.prikl. khIm. 31, no.1:16-.22 Ja 164. (MIRA 17:2) P-i!d crz,) LI -r5~-t;intly -ntrOduc! corn 19~2. a z a 3 no) - ibrary o C,.,n,~ress, j,!I)te ribcr 1952. c, vki, Z" tv L. v a kc r (-l 'j"r. ro -~P- 7a 9Av t ~)c CC:C -Icic-i F C. IMIEAYEVk, V.G.; SI~IRIIGV, i--Ii.; YAh-b-BOV1%, A,I. Primary investigation of the po4ded erysi=., under cultivation, Trudy Bot. sad& "ap. Sib. f il -..) 'i1. All SSS-R no.1:27-31 156. (IME-L' 14:7) ysimum) (El- 31411UIOV, M.N. Cultivation of the thistle Pdlaponticum carthamoides. Trudy Bot. sada Zap.-Sib. fil. AN SSSR no.1:1,7-53 156. (MBA 14:7) (Thistle) SHIRNCV) M.N.; KOLESNIKOVA, S.M. Biomorphologic characteristics of alfalf-a Medicago tianschanica Vass. in its introduction in Western Siberia. Trudy TS&~S no.4: 87-94 160. (MIRA 15:4) (Siberia, We3tern-Alfalfa) ajIYMIOV~ Mikhail Pavlovich, polkovnik; VU1,MTYSHEV, Boris Vasillyevich) .----po1kovrdI; K011M, P.I.) pollcovnik, red.; SSOKOLOVA, G.F., tekhn. red. (Engineer support of tank operations] Inzhenernoe obespeche- nie deistvii tankov. Moskva) Voenizdat, 1962. 169 p. (MIRA 15:7) (Military field engineering) (Tar2c warfare) SMIRNOV, M.P. Automatic line for making asbestos cement products using ne-d molding mothods. Stroi.mat. 5 no.12:14-16 D '59- (MIR& 13:3) 1. Nachallnik nauctino-konstruktorskogo otdela Veasoyuznogo nauchno- issledovatellskogo instituta po mashinam dlya promyshlennosti stroitellnykb materialov. Stroi.mt. 5 no.12:14-16 D '59. (Asbestos cement) (Automation) (MIRA 13:3) SHAPIRO Mikhail Senenovich; SURNOVy Mikhail Prokofly�vic SAFONOV, N.T., inzh.9-r-eTs-e~-z-enR; -BERZON, E.M., kand. tekhn. nauk, red.; FOMICHEV, A.G., red. izd-va; SHCHETININA, L.V,, tekhn. red. [Equipment for asbestos-cement production] Oborudovanie as- bestotsementnogo proizvodstva. Noskva, Gos. nauchno-tekbn.- izd-vo mashinastroit. lit-ry, 1961. 155 p. (MIRA 15:3) (Asbestos cement) SMIRNOV.9 M.P. Studying subsoil runoff in the northern part of the Western Sayan Mountains, Yermakovskoye Permanent Field Station. Pochvovedenie no.4g93-100 Ap 163. - (MIRA 16:5) 1. Institut less, i drevesiny Sibirak4k-