SCIENTIFIC ABSTRACT SMOLIN, A.N. - SMOLIN, M.D.
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CIA-RDP86-00513R001651720001-8
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S
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100
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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Body:
USSR / Farm knira-als. Silkworm.
Abs Sour: Ref Zhur-Biol., No 9, 1956, 40569.
Author Zhizhina, Ye. I.
Inst :Not given.
Title :The Distribution of Phosphorus in Various
Fractions During the Period of the Develop-
ment of the Cocoon of Oak-FeedinIT Silkworm.
.3
Orig Pub: Uch. zap. Ilosk. gos. ped. in-t, Ic)57, 98,
119-128.
Abstract: The changes in the content of the various P
fractions in the body of the cocoons of males
and females of the oak-edtihg: silkworm was
studied. The content of the total. P in the
dry tissue during the whole poriad of devel-
opment is high. The considerable P content
of proteins and fats at the beginning of the
cocoon phase decreases sharply before long,
Card 1/2 75
USSP / Farm Animals. Silkworm.
Abs Tour: Ref Zhur-Biol., No 9, 1958, 40569.
Abstract: and on the third day drops to zero; from the
7th day on, and up to the moment of the emer-
gence of the moth, it gradually increases.
In accordance with a decrease of the P of
proteins and fats the amount of inorganic P
during th-_:, first days increases sharply, and
from the 7th day on, drops abruptly. Around
the 7th day of the cocoon phase, synthetic
processes begin to develop; this is accom-
panied by a cohtinuous increase in the amount
of the organic soluble P which only slightly
decreases during the last days. A detailed
description of the technique used in the an-
alyses is given;
Card 2/2
U1,13,31, / Fut-m i~niFiio Us. "', ! 1 1, -Jo o r m .
Abs Jour: Ref Zhur-Biol., No 9, 1956, 40590.
Author : SffiQlj_a,,~~ Gudalina, N. G.
r
_Lnst :Not given.
Title :Glycogen in the Tissues of the Cocoon of the
Oak-Feeding Silkworm During the Period of
Metamorphosis.
Orig Pub: Uch. zap. Mosk. gos. ped. in-t, 1957, 98,
129-135.
Abstract: The regularities of the change of the content
of glycogen in the tissues of tho cocoons of
males and females of the oak-feedin-a silkworm
during metamorphosis were determined. The
high content of glycogen on the first day of
life of cocoon (up to 6%) drops in the first
one third of this phase to 1/4-1/5 of the
original amount; from, the 7th through the 15th
Card 1/2 76
SHOLIN, A.N., FRAVDINA, W.F.
Interrelation of carbohydrate and nitrogen metabolism in tussah
moth pupite during metamorphosis [with summar7 :Ln Englishl'
Biokhimiia 23 no;69819-823 N-I) 158 (Mig 11:12)
1; Laboratoriya organichaskoy I biologicheskoy kh1mii Hoskovskogo
gosudarstvennog pedagogicheakogo institute imeni V.I. Lenin&.
(SIL&ORKS
(INSECTS--DMLOPMP,NT)
(METABOLISM)
PRAVDINA, N.F.; SMOLIN, A. N.'_~
Synthesis and decomposition of glycogen in the organism
of the chrysalis of Chinese tussah moth during meta-
morphosis. Uch. zap. MGPI 140:255-26o '58. (MIRA 16:8)
1. Iz laboratorii organicheskoy i biologicheskoy khimii
Moskovskogo gosudarstvennogo pedagogicheskogo instituta
imeni Lenina.
YEGOROVA, T.A.; SFDLIN, A.N.
Trehalose in the body of the tussah moth at various stages of its
development. Biokhimiia 27 no.3:476-480 My-Je 162. (MMA 15:8)
1. Chair of Organic and Biological Chemistry, State Pedagogical
Institute, Moscow. (MTHS) (TRERALOSE)
-YEG(ROVA, T.A.; SMOLIN, A.K.
Localization and sources of trehalose biosynthesis in the
organism of the oak silkworm. Dokl. AN SSW 347 no.1:22.4-226
N 162. (MIRA 15:11)
1. Moskovskiy gosudarstvennyy pedagogicheskiy institut
im. V.I. Lenina, Predstavleno akademiko-m N.M. Sisakyanom.
(SADworms) (Trehalose)
SMOLIN, A.N.; SMOLIN, Yu.N.
Using zircon paint at Chelyabinsk foundries. u,. proizv. no.6:
37-38 is 164. (MII~ 18:5)
SMOLIN,A.P., inzhener
Experience In operating and repairing the F,505 excavator. Mekh.
stroi. 12 no.8:13-18 Ag'55. (MLRA 8:10)
(Excavating machinery)
SMOLIN, Aleksandr Fetro,~A%h DuNOVICH. S.V., inzh., retsenzent;
; SH
X:RlKH3W,, k.N.. Inzh., red.; TIKWOV, A.Ya., tekhn. red.
11&-505 and 4-505A (39-651) power shovels; design, operatioi, and
repair] Acskavatory Z-505 .11-505k (*-651); konstru-ktsiia,
ekspluatatsiia i remont. Koskva, Obs. nauchno-tekhn. izd-vo
mashinostroit. lit-%7, 1958. 258 po (HUM 11:9)
(Shoveling machines)
-'UTHOR: Smolin, A.P_, Engineer S0V./l 18 -58 -1-14/106
TITLE: The BuildinJ of a Railroad Dam Across the Great Salt Lake
(Stroitel'stvo zheleznodorozhroy damby cherez Bol'shoys So-
ienoye ozerc)
PERIODICAL: Yekhanizatsiya. trudoydmkikh i tyazhblykh rabot, 1958, Nr 15
pp 45-46 (USSR)
AB3TR.',CT.- This is a short d03Cription of the building of the new rail-
road dam across the Great Salt Lake in the USA.
Viere are 2 drawings.
1. Dams--Construction 2. Tracks (Railroad)
Card 1/1
SMOLIN, A. P., and MIKIIAE, MIKHAILOVICH VOITKEVICH.
Rukovodstvo po tekhnicheskoi eksploatatsii samoletov i motorov
dlia aeroklubov i shkol Osoaviakhima; Moskva, Osoaviakhim SSSR, 1936.
180 p., illus., tables, diagrs.
Title tr.: Manual of aircraft and engine operation.
TL670.V562
SO: Aeronautical Sciences and Aviation in the Soviet Union, Library of
Congress, 1955.
frc-
0 r I
SIVOLIM, A. P.
Nekotorye voprosy eksploatatsii saroletnykh lyzh. (Vestnik vozdushnogo
flota, 1936, no. 11, p.67-77, illus.)
Title tr.: Some problems in the use of airplane skis.
TL50h-V45 1938
SO: Aeronautical Sci !nces and Aviation in the Soviet Union, Library of
Congress, 1955.
86-1-30/30
AUTHOR: Smolin, A.P., Engr Col in the reserves
TITLE: The Aircraft of the French Air Force (Samolety VVS
Frantsii)
PERIODICAL: Vestnik Vozdushnogo Flota, 1958, Nr 1, pp. 91-96 (USSR)
ABSTRACT: This is a review of the types of combat and training
planes, helicopters, and guided missiles the French
Air Force is equipped with. Six photos.
AVAILABLE: Library of Congress
Card 1/1
SMOLIN, AjP.j- IVASHUTIN, L.R., retsenzent; OTDELINOV, P.V., inzh.,red.
-Yz-d--va; MODELt, B.I., tekhn.red.
(E-652 and F,651 excavators; design, operation and repair]
Ekskavatory E-652 i E-651; konstruktsiia, ekspluatatsiia i
remont. Izd.2., perer.1 dop. Moskva, Mashgiz, 1963, 338 p,
(MIRA 16:6)
(Excavating machinery)
M,PLIIT, A. V.
Smalin, A. V.
"Themountplr Schools of the ~,kltua:~ In t.he 1.81~h
Ac-~der-~j, of PedagoglLcal Sciences HS11SR. inst- of
of Pedagogy. Kemerovo, !l)"6. (Dissertatudon for
in Pcda-ogllcal)
at~d 19th centur--:-es.$t
t,e H';story and Theorv
the Degrte~ of Cand"ate
Kiiizhna-..rp letools'
~T 1956. '-Ioscow.
LIO. 21,
SMULI14'j, D. D.
"Recherches dans le domaine da la. synthese dans la scrie des derives du 7-0yycomiarine".
Nesmejanov, A. N., Vompe, A. F., Zarevitch, T. S., Smoline, D. D. (p. 2767).
SO: Journal of General Chemistry (Zhurnal Obshchei KUaii). 1937, Volme 7, No. 22.
00
cl
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oil. and bldil'og 00 -Cm (2 1-2 mi v.56, 1cT;6).
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ill lip It
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yellov, OAP) 01t010i)_ Do - le (froo'
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tid 00CAY ,I. I.P) J-1i"ItAn. . S_
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St 20 s .4101f, to
(Ifowt 51;00~',01'10 "
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11'0)~M' ~0 tni- JW ~nd andasi WItd- d
in 15 g.
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tier g-& 1160.
ve tion. %c
01. IWJ -!~~- - St, 40% .
3w -- utiony, c .8-j-
comp. ;,~~ 30 -10, C'. of its
Anthi,qui, after 77.510
as sbovc Cd ficl, ;~-rjy Over -
NA Illo nil - COO - e"C'It. to
do _t - v,,ry d,., qtb IS
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mot 1-2 11k;1
- Z.
]AP) - , -1 filt I n.,.n
ftom 4.,Utw%qw t 40 41j"10011
1. - cdbYsalur.i.
WIT. Ito. 1.11,
Coding gave Sa,
ovrf bat
witb It Sur-90 0t Of it,
acids - wtt
5-V ulin 'm tit) CO
It Itied on VaM - Ott. 16 as 96-1
1( Et
~~.Cbqa . lip.
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lic'. fill. -~) I. *vc,*. ''CA I;~ 47%
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ad - 10 'Jig 0%1 e te'l Shcr -tried rcT-Cc~,jjhSXf*_
9 YtIW* edics, fit
d va-um derilr" 11ASS
til~vinlldEtOil,$ bcdist0"' F
an Wt Of t &Oil Ntf-Co~d -itb h
water .01120. -'0 treat 'a..
kid of jjgCI2 -30 90~01 I'l NICX , Wd 0`1
'Cocap - tot b~~zcl letjtt rA the
Up, d :;;~coded b Itot Et - 1.
"t, 2 5 g. Cu
VAL ;~~ wit ca, 9.8 g. C91
od k)"cd-
t Pt.
_,W;thvc'~~ a
product (in. 1313-44% Purified fly 44, firs! extn. with hot -
xyl ne and conen. until it lit. TW-*)' (it was still implifel.
eatn. (or 5 days with cold E[oil rave satne
skraquis"e, lit. 243% while the residue contained fig and
Cl. Irratnient of the xyltne exon. residue with 30% 111NO.
12 firs.andwashingAith 1130auld hot PUOI I Save 27%1,5-
(11. Thi% (1.0 g.) sus-
lictuled In 15 ml. KOII in 00) till. dry McOlf and redu%al 0
hr*. JrAVC a brown-black ppt. (W.4%) of 1.5-C14HA-
WCOH)tin~iL lit the uu4isalvents. This (0.58.) added
to 10 till. %ttrr"I corml. If'W. at W, fiftcrtA. and carefully
dild. to 3 %-a[%. with HgO fravr 95.5%
11),. sol. only in weak tileum. I is, rrrov"rd unchanged
t after LS-2 firs. in 50; olcurn at 15% but 10% oleum gives
upon treatment with Ice water M~'q of a mixed salt.
apprently an (HjC1)(11g5OJ1) derm, decamp. IW*.
lo olcum 6 hri. at MO gave 94,5% or the di-(ffS_W&ff)
diaror., which is obtained Ili K3.9% Yield with 15% okum 8
bri. Wow roorn temp. The prwfuct (4 S.) treated
with 12 g. ID"* olruin;P) min. at 140' and milled out witb
KC1 gave O.M x. salt ol' a disulfonic acid, which yielded
1,15-dichloroanthraquinone, in. 241 *, and 2 8 g. Hg dcriv.
was recovered; 4.4 g. 25% oleurn 1.5 hr*: at IW gave
10.05 g. crude anthrAquinone (Invil.) and the mother
liquor on saltinx out save 2 jr. dl-K anthrequinossediflulto.
natc, yielditist purr 1.3,dichloroanthraquitsone (Identifyisig
- the and as the 1,54somer). XV1. 1.111-Marturli ~v-
4dvvs Ot anthra%ufx~ws* (Dissymmetric). 1"d. so".
cf. Diniloy and Kat'nuna. C.A. 43. 63701c.-Vi--Na IA-
(1.04 g.) In W r"j. 0.1 N NaOff
added to 6 X. IIXC)g lit :0) in). hot 11,0, boiled 3 Isrs., with
a4dn. of 0.1 X NaOff until the soft%. Is clear Initially, gave
2.87 g. 1eN-bis(cAhwoswcjsrs)ax1Ara
.piaow, R(IMA,
whkh(lg.)3uspeadcdial5c.KOIIInSDml.dfy cOll
and refluxed 6 hr*. gave 86.16% of the (bykoxymereapt)
a'
--a . VrCCG`gMY POMIrr. The IAIICf (0,5 tj I*
10 M1. coacd. IIPS06 mized at 0' and catrefutly ditd.
ith 3 VOIS. III0 VAVe 88% 1,S-CJ1A(1jjSOff),
:: infusible solid. further diln. of the filtrate gve
game authraquinout; the mine sulfAte is obtained in %
yield upon keeping the HgOdcriv, in Ifl- okum 6 hr%. at.
or in IS" olcum d hri. In the
The sulfate (4 g.) treated with 1,21 K. I0% Olean: at 140'
0.5 hr. jrAve 0.!~J g. I -anthraq0tionesulfortic acid (as the
chry"ditic salt). and 0.45 g. t.8-anthraquintinedislattonic
acid (isolated as file di-K salt by s2itingout), whileetra. of
the residue with AcOff gave 2 S. unre3cted eallate and 0,3
g. of appurently 1-talfoaWkraquinowy(werrary salfase (as-
sumcd to be the 84%omer). broarrij darkening at 3250
(from dil. AcOH). Sulfowf !on with 25% oleurn at I 1s)"
1.5 hrs. pvc 0.04 g. I-anthraquittonconlionic acid. 0.19 S.
dl-K t,S-disulrtinatc, and 1.7t C. di-K 1,11-disadfonate; the
insol. residue was frre of fig and gave pure anthraquitione
ondistri. I fence, the 1.8 4 bismercury sulfate) gives, a idet
variety of product,& an taillonatkitt than the 1,54somer,
because of greater thermal [ability a( the 11S intermediate.
G. M. Kooolatialf
I)MIGLIN, D. D.
USSR/Chemistry - Production of Ketene May 51
"Brief Communication- Large-Scale Laboratory
Apparatus for Production of Ketene," D. D, Smolin,
F. R. Kravtsov, A~ P. Skoldinov, Sci Res Lab Exptl
Chemotherapy, Min Public Health USSR
"Zhur Prik Khim" Vol XXIV, No 5, pp 547-551
Describes new large-scale lab ketene generator,
made entirely of metal, yielding 200-400 g/hr
of ketene, depending on regime. It is based on
principle of pyrolysis of acetone on open elec
heating elements (spirals) placed in atm of acetone.
18w4 i
SMIRNOVA, F.V., ARMfDARUK, A.P., SMOLIN, D.D., SKOLDINOV, A.P.
Esters of N-(nrylallrvl)-4-phenylisonipecotic acid. Med.prom.12 no.?
31-35 JI '58 1 (KIU 11:8)
1. Irintitut farmakologii i kliimioternpli AW SSSR.
(IIDTCOTIC' ACID)
MIKHAISY, V.A.; DOROKHOVA, R.I.; SMOLIHA, N.Ye.,, ZIDIWKHOVTSEVA, A.M.; IVANOV,
A.I.; AiWTDARUK, A.P.; GAWIMUKO, M.I.; 5K0AOffMOYt V.A,; SMOLIN, D.D.
Styrene as rpw material for the production of synthomycin and levorq-
cetin. Part 1: Synthesis of p-nitro-t(--aejlaminoacetophenones. Anti-.
oiotiki, 4 no.2:21-24 Mr-Ap 159. (MIRA 12:7)
1'. 'IsesoyuzW rLiuchno-issle'dovatellskly khimiko-farmatsevticheskiy
ingtitut, imeni S. Ordzhonikidze (for Mildialev, Dorokhova, Smolina,
Zhelokhovtseva). 2. Institut farmakologii i khimioterapii AM SSSR
(for Skoldinov, Ivanov, Arendarul,,, Galchenko, Skorodumov, Smolin).
(CHLORAMPIOUCOL, prep. of.
synthesis from styrene through p-nitro--ot,-acylamino-
(VI acetonhenones (-Ibis))
NYL COMPOUNIS
styrene,-uBe in chlorarrohenicol synthesis through p-nitro-
Ok-acylamirioacetophenones (Rus))
(TWOTIM
p-nitro-4(-.acylaininoaceto-ohenones, intermediate in chlor-
amhenicol synthesis from styrene (Rns))
5-/)'7 0.)- / Al -D D.
MIKULEV, V.A.; DOROKHOIIJL, M.I.; SMOLINA, N.Ye.; ZHBLOKHOVTSEVA, A.M.;
T1191011OVIi, O.Ya.; SKOLDINOV, A.P.; ARENDARUK, A.P.; SHOLIN, D.D.;
GOLOVKIN&, T.V.; SLOITOVA, L.A.
Styrene as an initial prodnet for synthomycetin and levomycetin
production. Part 2: Synthesis of p-nitroacetophenone and
p-nitro-X-bromacetophenone. Antibiottki 4 no.4:21-24 Jl-Ag
'59. (MI-U 12: 11)
1. Vsesq-.mzn,:y naiiehno-issledovatellskiv khimiko-farmatsevticheskly
institiit imeni S.Ordzhonikidze (for Mikhalev, Dorokhovat Smolina,
Zhelalchovtseva, Tikhonova). 2. Institut farmakologii i khi-mio-
terapil jUD SSSR (for Skoldinov, Arendaruk, Smolin, Golovkina,
Slonova).
(CHLOMMpIr"ICOL
MTOIT."!-S chem)
V079J60/030/012/006/027
BODI/Bo64
AUTHORS: Yashunskiy, V. G., Smolin D D. Yermolayeva, V. G~,
an3 Shchukinn, M. 14.
TITLE: Substances Capable of Complex Formation. V. 2,21-Diamino-
diethyl Ether-N,N,Nf,NI-tetraacetic Acid
PERIODICAL: Zhurnal obshchey khimii, 196o, vol. 30, No. 12,
pp. 3916-3918
TEXT: The authors continue their studies (Ref. 2) of the synthesis of com-
plexons by synthesizing 2,21-diamino-diethyl ether-tetraacetic acid; this
synthesis has hitherto not been described. It may, however, be assumed
that this complex was obtained on the basis of data of an English patent
(Ref. 3) from 2,21-diamino-diethyl ether by carboxymethylation. Several ex-
periments had failed before the complex was obtained by reacting 2,21-di-
amino-diethyl ether. The diamino ether was obtained from 2,21-dichloro di-
ethyl ether with the diphthalimide derivative by the reaction of Gabriel
(Ref. 4), however, the 2,21-di(phthalimido)-diethyl ether was split off by
boiling with an alcohol solution of hydrazine hydrate and subsequent treat-
ment with hydrochloric acid which simplified the reaction and led to an
Card 1/2
Substances Capable of Complex Formation. S/079/60/030/012/008/027
V. 2,21-Diamino-diethyl E'Uher-N,11,!J',N'- 3001/B064
tetraacetic Acid
abruptly increasing yield, The diamine was separated as dichloro hydrate
and reacted with monochloro acetic acid. The reaction %as normal and took
place in alkaline medium (Ref. 2). Since it vas not possible to precipitate
tetra acid by acidifying the reaction mass, which is the case with some
other complexons, two methods of precipitation were applied. The cationile
KU-2 was used for the first one applied in the study of Ref. 5. By the
latter method the reaction mixture was acidified until the acid reaction
toward Congo red as indicator had been reached and, after the separation of
sodium chloride fromthe solution, the monosodium salt of the complexon pre-
cipitated with methanol and purified by repeated precipitation with
methanol from water. There are 6 references: 2 Soviet, 1 US4 1 Swissq
1 German, and 1 British.
ASSOCIATION: Vsesoyuznyy nauchno-issledovatellakiy khimiko-farmatsevti-
cheskiy institut imeni S. Ordzhonikidze (All-Union Chemical
and Pharmaceutical Scientific Research Institute imeni S.
Ordzhonikidze)
SUBMITTED: January 11, 1960
Card 2/2
wa
, V.A . ; ~ 1 -,'.1 *f. ", " r!'(", !' ", Ill TS [-A' Ycl.F.; O":11LIAN, ii.O.; SCHOLOVA, G.N.
. 4--; 6~ - y
-: , , -, os-' rion ol I'ver !I,, d fractions In anilpAl-
-,n cc,-,.pI ~ -1 ~. I - --
I
I
exposed to radiation. 'iadlo*biclogl~ia 4 no.',1:3'f'E--"180 164. kl'AIJ?j~ 17:11)
SMOLIN, D.D.; RAZBITNAYA, L.M.; VIKTOROV, Yu.M.
2.2tit.-Diaminodiethylsulfide of N,N,lT',,11*-tet,raace+i , acid and
some inner-compleoc compounds. Zhur. ob. khimo 34 no.lls
3713-3715 N r64 (MIRA 1881)
- . ..G. . - I - -.-. 11 1 1, 1 _._ .__1 .. . - .-. - - " .1 1
.~ :~. , " _- h' )
~1_ .~ _., - "I-1, ; ... - L,-:, " ) . . : . ; ~ ;~ ;, L. _'_2 V J V . A . ; - I-A, L, -,-i I u . u .k :;,C;S3'
" Investigation of turbulent plasma and real gas jets"
rerort preserted at the 2nd All-Union Congress of Theoretical
and ~ T, 1. b 6 4
.,lied Eecharics, Moscow, fKoscow 29 Jar. - 5 Fe
A . r
L 32842-66 ENP(m)/EWT(1)/EWTW/T DJ
ACC Nit: AP6008831 SOURCE CODE: UR/0294/66/004/001/0073/0079
AU`ITI0R:_Kukin. 1. K. (Moscow); Smolln, G. G. (Moscow)
ORG- None
TITLE: Two-dimensional isothermal flow of an e1 ectroconduc Ling fluid and gas in a
channel in the presence of an electrical and a magnetic fields
SOURCE- Teplofizika vysokikh temperatur, v. 4, no. 1, 1966, 73-79
TOPIC TAGS: fluid flow, conducting fluid, gas flow, isothermal flow, plane flow,
electroconductive fluid, electric field, re-agnetic field
ABSTRACT: The authors investigate two-dimensional, stabilized, isothermal flow of an
electroconducting compressible fluid In a plane channel in the presence of crossed electri-!,
cal. and magnetic fields. Use is made of -an approximate equation system, analogous in
form to boundary-layer equations. Self-similar solutions are derived and presented by
means of the Jacobi elliptical functions. The eidstence conditions for these solutions are
examined. As a particular case, the authors obtain relationships for the velocity profile
and pressure variations along the aids of the channel applicable to the flow of an incom-
Card 1/2 UDC: 532.542:538.6:537.29
L 32842-66
ACC NR: AP6008831
pressible fluid\, Orig. art. has: 24 formulas and 4 figures.
SUB CODE: 20 / SUBM DATE: 13Jan65 / OTH REF: 003
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56023
S10201601135100310011039
CII1/C222
An Approximate Method of Constructing Cauchy Function
x
(3) 'U(X) - Z(X)+~ Wi(x's)~f(s)-L!Fz(s)"
a
of the equation (1) then there holds the estimation; if lf(x)-L[z(x)l
-~!LJX-S)vR, then 21 1
R V. P 11C, ! (Q 9! )- (2'- 1 1 +~ik+t+ 1
.k k -a)
(4) 4"U"(') (x) -u (') (X)', (x
C f (21-1 ) (A+1
L
As WO(Xgs) it is recommended e.g.
wO(X,S) - (X-S) n-1 + (X-S) n gn-I(s),
n!
Card 3/4
86023
S/020 60/135/00'3/001/039
C 111 lyC222
An Approximate Method of Constructing Cauchy Function
Some properties of the considered sequence are given.. Therefrom there
result the conditions given in (Ref.3,5) that K(k)(x,s),::,O (k-t n),~
There are 5 Soviet references,
ASSOCIATIONs Izhevskiy mekhanicheskiy institut (Izhevsk Mechanical
Institute)
PRESEYTIED% June 17, 1960, by S,L,Sobolev, Academician
SUBYITTED~ june 14, 1960
Card 4/4
3MOLIN, Kalman
Properties of cooling agents applied In hardening. Gepgyartastechn 1
no-3:87-91 Je 161.
1. Forgacsolo Szerszamok Gyara.
SOLOVIYEV, V.N.; SMOLIN, L.N.
Method for determining the latent period of the defense reflex
In white rate and nice. Biul.eksp.blol. I mad. 40 no-10:75-77
Oct.'55. (MLRA 9:1)
1. Iz laboratorii eksperimentallnoy terapii (zav.-kandidat
meditainakikh nauk A.M.Chernukh) Instituta patofizologii I
eksperimentallnoy terapii (dir.--akademik A.D.Speranskiy)
AMN SSSR, ?4oskva.
(REFLEX,
defense reflex, determ. oflatent period in white
rats & mice)
SOLOVITAY, V.N.; SHOLIN, L.N.
Effect of dimedrol on the central nervous system. Yarm.i toks. 19
no.5:29-34 S-0 156. (MLRA 10:3)
1. Iaboratoriya okeperimentalinoy torapti (zav. kandidat meditsin-
skikh nauk A.M.Chernukh) Instituta aormallnoy i. patologichaskoy
fiziologii AKN SSSR.
(DIPHINHYDMINB, effects,
on US in animals (Rue))
(CESTRAL MVOUS SYSTIN, effect of drugs on.
diphenb.vdra mine in animals (Rua))
L.K. (Hookwa)
Role of experimental neuritis of the vs&ms nerve in the pathogenesis
of aspiration pne=onis, Pat,fisiols t eksp.terAp. 2 no.3-049
my-je 158 (MIRA 11:7)
1. Is laboratorli eksDertmentallnoy terapii (sav, - dotktor mod.
nauk A.M. Chernukh) Inatituts normalluoy I pqtologleheskoy fiziologil
UN SSSR (direktor - daystvitellnyy chlen ANN SSSR prof. V.N.
Chernigovskly).
(VAGUS r-%-(VR--DTSXAST]Sj
(PREUROU 1A)
SMOLIN, L.N.
Apnearance of electroancephalographic asymmetry following unilateral
liing injury.. Biul. eksp. biol. mod. 47 no.5.'47-51 My 159. (MIRA 12:7)
1. Iz laboratorii sravnitellnoy patologii nervnoy sistemy (zav. - Drof.
S. 1. Frankshteyn) otdela fiziologii i patologii nervnoy sinteav (zav. -
Prof. A.A. Volokhov) Institute. normallnoy, i patologicheskoy fiziologii
(dir. - deystvitellnyv chlen ANN SSSR V.11. Chernigovskiy), Moskva. Pred-
stavlena, deystvitelInym chlenom AMII SSSR V.N. Chernigovskiy), Mosk7a.
Predstavlena. deystvitelinym chlenom AMN SSSR V.11. Chernigovskim.
(LUNGS, physiol.
exper. unilateral thermal led on inducing MG asymmetry
(Ras))
(ELMTROETICEPHAWGRAPHY.
as,,mmetry induced by exper. unilateral thermal lesion
of lung Obis))
SMOLIN, L.N.
Origin of "spontaneous" electrical activity of the frog brain.
Biul. eksp. biol. i med. 52 no.12:17-22 D 161. (141-RA 14;12)
1. Iz laboratorii eksperinentallgoy patologii nervnoy sistemy (zav. -
prof. S.I.Frankshteyn) Instituta normallnoy i patologicheskoy fiziologii
(dir. - deystviteltnyy chlen AM SSSR V.V.ParinY A1414 SSSR, Moskva.
Predstavlena deystvitellnym chlenonn MI SSSR V.V.Parinym.
(BRAIN) (EUCTROPHYSIOLOGY)
FRANKSHTEBI, S.I.; GAYDRIA, G.A.; GORMIOVA, T.I.; SERGEYEVA, Z.N.;
SMOL121 ) L.N.
Mechanism of dyspnea in lung injury in the light of electro-
physiological studies. Trudy Inst. norm. i pat. fiziol. A14N
SSS.R - 6:102-104 16~1 (MIRA 17:1)
1. Taboratoriya eksperimentallnoy patologii nervnoy sistemy
(zav. - prof. S.I.Frankshteyn) Instituta normallnoy i pato-
logicheskoy fiziologii MIN SSSR.
SMDE-TN, L,-N.
Fac;i1itatirm cf prim77 corticAL resporses under thp influi-nae of
fy-om inflammatory fvti. Trudy Inst.nom.i pat.flziol.
M4 SSSR -~:86,37' (1-URA 18:6)
1. LiOoratarlya ekaper-tattntallnoy patol--Y,il nermoy sist-e-w (zav. -
r)-r ~%.T.Prdakziliteytt) 'r,-titi-tiAn I pAtQl)glcheskOy
,I AMN SSSR.
pvi~f.i- B.IYA5REVA, SMOLEN, 1,N.
f !canoe of Inhibitory synarses in the mechaniBzi of
,;,-rrx,p,env,ation of fu-notional disorders. Biul.eksp.biol. i
mad. 59 no. 5,.27-31-1 165- (KNU 1.8.-11)
a
laboratoriya eksperimantallnoy patolctgii, n-3rvnoy sistemy
prof. S.I.Frankshteyn)- Institut'a normallnoy i
p~2A,cOng:~cbBBkcy ftzA-ol4-,gIl ldl-Atrur - deyetvitellnyy chlen
AMN SSSR prof. V.V.Farin) AMN SSSIR, Moskva. Submitted May
1611 1964.
2 1 - 5 fl 12 /,'~ 7
-AUTHORS Frantsevich, 1,11t, Correspording Member of the AS Uk:SER,
Kalinovich, D.P., Klovenskiy, 1.1., Pen7kovskiy, V.V. and
TITLE: Electrodiffusion of Tungsten in an Iron - Tungsten Alloy
( Ele'Ktrodiffuziya vollframa v splave zhelezo - vollfram
PERIODICAL. Dopovidi Akademii nauk Ukrains,koi ROR, 1958, hr 7,
pp 736-739 (Us'O'R)
ABSTRACT: The role which is played in highly heat-resistant alloys
by the increase in the strength of interatomic bonds in
metal solid solutions is well known. The strength of in-
teratomic bonds is es-entialyy increased by the donor-
acceptor interaction between the atoms of elements which
compose the alloy. The availability of information on
this interaction makes it possible to theoretically base
the selection of a comDosition with optimum characteris-
tics of heat resistance. The electrotransfer method is
the best for studying the donor or acceptor ability of
the alloy components. This article describes an invest-
igation of tungsten mi,gration in its solid solution in
Card 1/3 iron being. subiected to a constant electric field, w~lich
Blectrodiflusion of Tungsten in an iron - Tungsten Alloy
21 - 58-7-12/2 7
carried out by raeans of the radioactive isotope
Experiments on electrotransfer were conducted at 900; 950;
1,000; 1,C50; 1,100 and 1,1500C, and at exposure times
from 40 to 110 hours, It has been established that in the
solid metal solution of tungsten in iron, the former mig-
rates, under the action of a constant electric field, tow-
irds the cathode, On the basis of experimental data, ve-
locities of the tungsten atom displacements have been com-
puted, as well as the charges of tungsten ions and trans-
fer ratios at all investigated temperatures. It has been
shown that the migration speed and transfer ratio values
increase with an increase of temDerature from 900 to
Card 2/3 1,0000C while the charge remains'corstant. At a further
Electrodifrusion of Turasten in an Iron - Tungsten Alloy
U
21-58-7-121/27
rise of temnerature all these quantities decrease and
0
reach zero at 1,150 C. There are 2 graphs, 1 table and
Soviet references.
ASSOCIATION: Institut metallokeramiki i spetsiallnykh splavov A.E, 1.11krSSR
(institute of' 1.1etalloceramics and Special Alloys of the
AS UkrSSR)
ql
S77B.1.171*11D: February 15, 1958
NOTE Russian title and Russian names of individuals and in-
stitutions appearing in this article have been used in
the transliteration
1, Iron-tungsten alloys--Diffusioxi 2. Iron-tungsten alloys--Temper-
ature factors 3. Tungsten isotopes (Radioactive)--kDplications
Card 3/3
FRANTSHVICH. I.N.; KALOOVICH, D.F.; KOMSKT-r, T.J.: S~JOLIN, M.D.
Some quantitative relationships of donor-acceptor interactions in
alloys. Fiz.tver.tela 1 no.i:62--66 -Ta '59. WRA 12:4)
(Alloys) (Electrons)
SOV1180 59-1-13/29
AUTHORS: Kalinovich D,F,. Ko,,renskiy I,I,,, Smolin M.D. and
Frantsevich I.N,, (Kiyev)
TITLE: Investigation of' the Migration of the Components of an
Iron-Tungsten Alloy in a Constant Electric Field
(Issledovaniye migratsii komponentov splava zhelezo-
vollfram v Dostoyannom elektricheskom pole)
PERIODICAL: Izvestiya Akademii nauk SSSRj Otdeleniye tekhnicheskikh
nauk, Metallurgiya i toplivo, 1.91 2 Nr 1, pp 71-74 (USSR)
J9
ABSTRACT: The authors point out that one of the best methods for
studying the donor-acceptor electron interaction in alloys
is to study the migration of the components under the
e.
action of an el .:~t-zJc! fields In the published data for
solid metal alloys, however, only one component is
consideied and the possibility of donor-acceptor inter-
action is n6t exam.1ned. The authors describe their own
w-ork on the transfer of the components of a solid solution
of 5 wt~ % tungsten in -iron, For studying the diffusion-
of tungsten W1 5 was introduced by difflasion, into the
central part of an eiectrolytic.~-iro_q wlLre 60 mm long and
Card 1/3 0.6 mm In diamete:~,. The actijity was determined along
the test piece bef--re and aftaz its heating by the
Investigation of the Migration of the G~mp~cnants of an Iron-Tungsten
Alloy in a Constant Field
passaga of a djirsz~t --.uri-ent, Foi studying the mobility
of irons the j,.):.--.Tial isotope of tU.'q sten was introduced by
diffusic,n int.D a similay- spe,,~Ime__ fdiameter 0.65 mm) over
it's Whole. langth, Fe:,;) was then deposited electrolytically
on tLe cent-ral zone of t,he spe;~imens and the distribution
of t~ii_s radioe.ctive lsotope over t >_ cross-section was
secured ty annealing, Afte:r- heating by the passage of a
direct the wi.re was -j-ut into sections whose
activi wera de~Cermjlne'-'~. The heating temperatures
were 900.,
- '. 950 1-000, 1050s 1100 and 1150oC t 5-j'OG. the
t1mes - i A. 1. L.
L tie. ng ho;i~ns the tungsten mobility and
10 - !-'10 .1"of the ~.iron mobility experiments. Fig J1 shows
4-
dis~L,.j-"*L-!~tL",~.-,i-oLis of ac,tivity along tbie I.eng,,h of the
spz)raimen f Dr Fe - Wft~_'5 (9500Ci 40 hours); Fig 2 the
distr.1j.b-ut'!.ons for Fe - W - Fe59~ The distribution
otitained when an t. rnating arrent was used is shown
L Fig 3~ The aut~,,_:iis det?rmine the transfer numbers of
n U
t.ingst.-3'a and L:,on fop ',.-,he va-Lious temperatuTes on the
Card 2/3 basis of eq-latlions deduced (Ref 1) and
published d-ats. D~a r.,:effi~tients (Ref 2).
SOV/180 -59-1-13/29
Investigation of the Migration of the Components of an Iron-Tungsten
Alloy in a Constant Electric Field
They conclude that it has been shown that at 900-11000C
the valency electrons contributed by tungsten atoms go
to fill the vacant 3d-levels of iron atoms, producing a
Card 3/3 donor-acceptor interaction,
There are 3 figures, 1 table and 3 Soviet references.
SUBMITTED: June 4, 1958
(Vesju r1i .41 3. .1.11T TvT..dR put, %*%.It
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.zl '401-4. ;a ; 0 .... J.J.4 6 put Slq.i a I"dt.v a AV PANUA
00011t
:P.Iqov04 0. t 4, p U 01 00 ..;111 . U.2
..a.2
oil, 'A.R.% J.N~I.jj uoa%*.T% 1D.0011t Vt O'Atm
01 fulli.q U.4l put 01 00 *64;
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7V
;o jjn- III ..ql... I, 4.1,d %u ... j! *qZ
2-3 11MIRZY
ig 11,ulmi,
,Xo;g 4 j.0jj%*.j-j mo
wt..,IT z ~l 1 mul
_ MOR.AT
vi
06567
180)
SOV/170-59-9-8/18
AUTHORS: Frantsevich, I.N., Kalinovich, D.F., Kovenskiy, I.I., Smolin, M.D.
TITLE; On the Donor-Acceptor Interaction of Components in a Binary Iron-Chromium
Alloy
PERIODICAL: Inzhenerno-fizicheskiy zhurnal, 1959, Nr 9, pp 62-68 (USSR)
ABSTRACT--. Electric transfer of components in solid metallic solutions furnishes
important Information for the development of the electronic theory of
alloys. The purpose of the present investigation was to study the be-
havior of the components of the solid solution of chromium In iran. in a
constant electric field. Radioactive isotopes cr5l and Fe59 were em-
ployed for marking atoms migrating in the process of electric transfer.
It was established by experiments that the chrome-plated zone in all
samples was shifted towards the cathode; hence it is concluded that
chromium in its solid solution with iron is a donor of electrons. The
study of electric transfer was carried out at temperatures of 1,000,
1, 050, 1100 and 1, 1500C and at various durations. It turned out that
the electric transfer of chromium ions Increases with an increase in
temperature and duration of experiments. This relationship is shown in
Card 1/3 Figure 2. The study of the electric transfer of iron ions was carried
06567
SOV/170-59-9-8/18
on the Donor-Acceptor Interaction of Components in a Binary Iron-Chromium Alloy
out at temperatures from 900 to 1,2000C and various durations. The rate
of migration of iron ions grows with an increase of temperature until
lt05OOC and then falls down to 1,2000C. At a fixed temperature, the
effect of electric transfer increases linearly with the duration of ex-
periments. This is shown in Figure 4. The experimental data obtained
made it possible to determine the charges and numbers of transferred ions
of chromium and iron at various temperatures. These data are presented in
Tqble'1. Thus the existence of a donor-acceptor Interaction in the iron-
chromium aiioy has been established; it diminishes with an increase of
temperature above 1,0500C. This finding agrees with a conclusion.by P.L.
Gruzin /Ref 177 that chromium strengthens interatomic interaction in the
Card a/3 iron lattice at temperatures below 1,1000C.
06567
SOV/170-59-9-8/18
On the Donor-Acceptor Interaction of Components in a Binary Iron-Chromium Alloy
There aret 4 graphs, 1 table and 17 references, 8 of which are Soviet,
6 German, I French, I Indian and i. unidentified.
ASSOCIATION-, Institut metallokeramiki i spetsialln'Vkh splavov AN USSR (Institute of
Ceramics and Special Alloys of the AS UkrSSR), Kiyev. t
Card 3/3
If 3
5/17 60/003/008/009/014
B019Y8054
AUTHORS: Glinchuk, M. D., Kalinovich, D, F., Kovenskiy, I. I.,
1. ~go'lin, M._D,_ lq~
TITLE: A Method of Determining -Diffusion Coefficients in Solids
PERIODICAL: Inzhenerno-fizicheskiy zhurnal, 1960, Vol~ 3, No. 8,
Pp. 78 - 61 lef-
TEXTt The authors investigate diffusion along an infinitely long
cylinder with the radius R. It is assumed that at the beginning the
diffusing substance is distributed at one end of the cylinder in a thick-
ness AR and a width of 21. The authors proceed from the diffusion
equation (1) and obtain the approximate equation (4) for the distribution
of concentration along the cylinder. Equation (5) indicates the concentra-
tion distribution of the diffusing substance after diffusion at the
temperatures Ti and T for the durations t and t , and the diffusion
1 2 1 2
coefficients D 1 and D2 are calculated from (4) and (5)~ Formula (7) gives
the quantity of the substance diffused, By the method suggested here, the
Card 1/2
A Method of Determining Diffusion Coefficients B/170/60/003/006/009/014
in Solids B019/BO54
authors determined the diffusion coefficient of chromium in nickel,
Table 1 gives the mean values of the diffusion coefficients for various
temperatures. The diffusion coefficients were calculated by formula (9).
Fig. 2 graphically shows the diffusion coefficient of;~~hromium inAickel-
as a temperature function. The method suggested allows the determination
of diffusion coefficients for various temperatures on a sample. The
accuracy is designated to be satisfactory. There are 2 figures, I table,
and 2 Soviet references.
ASSOCIATION: Institut metallokeramiki i spetssplavov AN USSR, g., Kiyev
(Institute of Powder Metallurgy and Special Alloys of the
AS UkrSSR, Kiev)
SUBMITTED: March 8. 1959
Card 212
819oz-
S/126/60/010/01/004/019
Elll/E335
AUTHORSt Kalinovich, D.F., Kovenskiy, I.I., Smolin, M.D. and
Frantsevich, I.N.
TITLE; Mobility of Chromium Atoms in a Nickel-c romium Alloy
Under the Action of a Direct Ele~_tric Field
PERIODICAL. Fizika metallov i metallovedeniye, 1960, Vol.10,
No. 1, pp 42 - 46
TEXT~ The authors point out that the study of migration of ions
in alloys can give indications of the high-temperature stabi-
lizing role of alloying elements. They describe their work on
the migration of chromium in a 0.63 diameter, 60 mm long wire
containing 4.360,6/bry weight. The oentral part of the specimens
was electrolytically coated with a 5-micron thick layer of
Cr 51~ After annealing at 1200 0 C for 60 hours, the specimens
were electrolytically etched to remove the surface layer.
Longitudinal radioactivity distribution was measured with an
MST-17 counter. Specimens were then placed in an argon
atmosphere and a direct current passed through them. Activity-
versus-.position plots before and after passage of current at
-, 0 C,,for 120 hours (Figl) and for 950, 1.000, 1050 and 1100 0C Vr
81902
qIIg_6/_60/010/01/004/01 9
Mobility of Chromium Atoms in a Nic e ~21clromium Alloy Under the
Action of a Direct Electric Field
showed appreciable migration of chromium towards the cathode.
Allowing for diffusion the authors calculate the speed of
migration of chromium (average values rise from 2.70 x 10
at 950 to 29.71 x 10-8 cm/sec at 1100 OC). By removing the
outer layer of treated specimens and repeating the activity
measurements (Figure 2), migration within the spec;kmen was
found to be less than near the surface (7.20 x 10 -7-
1.55 -, .10-8 cm/sec). For both there was a linear relation between
the average di-splacement of the chromized-zone boundary and
duration of experiment.. Using Einstein;s equation (Ref-4) the
authors calculate effective chromium-ion charge values in solid
solution in nickel to be 57.6v 42.5, 34.7 and 27.6 at 950, 1000,
1050 and '11000C, -respectively, which is in line with Wever's
values for higher temperatures (Ref.6).
There are 2 figures. 2 tables and 6 references-.~ 2 Soiriet,
2 English and 2 German. V~
Card 2/3
SMOLIN M D - FRANTSEVICH, I.N.
~ - I- Y P I
Application of the electric transfer method In the study of the
electronic structure of metals and alloys. Fiz.tver.tela 3
no.7:2115-2122 J1 161. (MIRA 14:8)
1. Institut metallokeramiki I spetsiallnykh splavov AN USSR,
Kiyev.
(Ions-1-%gration and velocity) (14etals--Electric properties)
-,j B
AUTHORS: Kalinovich, D. F., Kovenski-, 1. 1., and Smolin, M. D.
:E:ining partial
TITLEt A contribution to the problem of
velocities of electrical transfer wifh tagged atoms
PERIODICALs Fizika tverdogo tela, V. 3, no, 111, '1961, 3367-3370
TEXT: To determine the velocity of motion of a tagged ion during electrical
transfer it is necessary to have a coordinate system firmly connected
with a fixed point. The origin of coordinates can be put at one end of the
sample or at a mark which is located in a nonheated area (the mark can be
obtained by the impression of a microhardriess teit). When investigating
the electrical transfer of each alloy component, it is possible to tag the
components to be studied either along the whole z3ample or only along a
narrow part in the center of the heated zone with a radioisotope. In the
first case, a new distribution of the concentrati.---n of the component in
question is observed, while in the other case ci-,e motion of atoms of this
component during electrical transfer is obser--~ directly. Under such
Card 1/4
S/!,~!/61/0011/011/019/056
A contribution to the problem of ... B C'
conditions, the temperature distribution 7,ii-I pass through two
symmetrical points in regions with a stronlo d-t-_ieas,_ along the sample. In
these points, the mobility of atoms is practic,lly zero. The following
two cases were investigated: (1) If migraticri cff atcuis of all components
in one direction is observed, ions of all will arrive at the
boundary surface of the mass flux which is located in the direction of
transfer. New lattice planes are formed, Sim~zltaneously, atomic planes
are removed at the boundary of the heated zoz-.e loc.-ated on the opposite side.
Therefore, all atomic planes located in the he.ted region are shifted
opposite to the direction of transfer by the wiftt-In of the built-up or
removed zone. The equation of displacement is gi ien by iui (1)
where 6x/t vjyj(2). U denotes the totEl number; uit Vil and
J/i denote partial transfer numbers, velocit3~, and molar share of the i-th
component; Ax denotes the width of the built-ur (remcved) zone; t denotes
the duration of test. Ax/t may be regarded as the total transfer
velocity. The shift measured during electrical transfer for a tagged
Card 2/4
/003/011/019/056
~A
A contribution to the problem of ... ~))2-;l
atom in the heated zone is equal to the srra o -,.ft,; due to partial and
total transfert v v + W (3), where v velocity determined
experimentally from the shift of the tagged Lt.~~m In the case studied, a
transfer of matter will always take place. (2) Atoms of the components
will migrate in both directions. In both reglGns limiting the flux, atoms
of one type are supplied and atoms of the other type are removed. Under
these conditions, Eqs. (1) and (2) will al,_-~-- ief=ibe the total mass
transfer in general. When determining partial -,--locities of electrical
transfer with tagged atoms, the motion of t,-.Lese has to be considered.
The method of tagged atoms shows various ad-.,_azitatie--~ cver the method of V/
fixed marks. Especially, a chemical analysis of p_Iate and cathode space
of the sample is not required. All conclu,~icns ~n this paper are only
valid if the geometrical shape of samples dre6 rct change during the tests.
There are 3 non-Soviet references. The referen- -.* the English-language
publication reads as follows: R. P. Johnsort~ Phj-;. Rev., a, 459, 1938.
Card 3/4
S, e, /---1/00.31011/01 9/O~::6
A contribution to the problem of ...
ASSOCIATIONs Institut metallokeramiki i sj.,ii ~~Ilriykh splavov AN USSR
Kiyev (Institute of Powder rind Special Alloys
AS UkrSSR, Kiyev)
SUBMITTED: June 5, 1961
Card 4/4
22826
S/170/61/004/00=/1012./Cir,
00 Bi 1173214
AUTHORS: Kalinovich, D. F. Kov--r-.;kiy, I. I. , Smolin, It. D. ,
':rant3evich, I. 'N.
TITLE. The diffusicn or nickel in a nickeil xe~lyb,lenum alln~- in an
electric fiel-i
PERIODICAL: Irzhenerno-fi.-AcherlA~- ---h,trnal, v. 4, n). 5, 1961, loa-110
TEXT: The electric fic-ld ~rodlzces a directed displacement of the atocio
chell ir. the crystal lattice of a pure netal and solid solutions. Two
forces act on the ions: the electric field and a force depending on the
nociontum transition bet-weer, ions and the condnetion electrons or hole3. The
electrotzanspo-rtation of Ni ions in a solid solution of molybdenum in nickel
is investif;atgd in this paper (molyl:denum content 9.24% by weight). The
tracer was Ili 3 which was measured by a counter of the type T25-6~A(T25-137a
The temDerature of the sanDle was measured by a pyrometer of the type
xr-mm ZKhGI,1.fIP). The direction and rate of electrotransportation could be
determined from the diaplacer7ent of '.he boundary of the radioactive zone.
The diffusion was eliminated by relating the rate of electro transportation
Card 1/3
22826
S/17 61 /C(;4/005/012/01 5
The diffusion ... BIIIYB214
to the arithmetic nrean ~lf rh~ ~f the bonniary.of the active
z0n". The farce actinG ,>n an Ion riay b~ writtw~n as
F - Ee(z - n CY I ~ n d-l'),
I 1 1 2 e e j
wherc., E is t"rie ~w~t-~~ntiiil; e the elv-!~tronlc charCr.; v~ tI.v nf thp. Ion
in multiples of e; n, concentration ~,f the conduction c1.. the
scatterin.- cross section of the cordli-ti~n nr, tht.- migratinj ion;
and I the mean free path of the ole,,~trons on thp Fcr-,ri surface. The
irld X';'denotes hole ccniuctivity. Thq quantity z - n1a,11 + n q . z
2(Y2'-
is the effective charCe w-hich is equal to the trui, (-~.arge in the abcence of
the effect of electrons and hilez. Applying Zinst-7in's for-Aula one may
write for the effective charge zK: Z" - 300 v4qkTf/IDe (2), where v is
the rate of electrotran3portation; X, q the eloctrical conductivity and
area of the cross section of the samp2ej f - 0.78 (for a face centered
lattice); I the current strenath; and D the diffuelon coeffi-2ient. The
derivation of the diffusion coefficient has been given in IFZh, No. 8, 76,
1960. The value fowid 1; D - 2.68 exp (-65600/RT). The experimental
conditions, the rates of electrotranBportation, and the effective charges
Card 2/3
22326
311701611004100510721075
The diffusion B111/B214
calculated accordinf; to (2.) are collected in Table 1. All the experiments
phowed 'hat nickel mij;rates to theanode. There are-1 table and 10 refer-
encen: 6 3oviet-bloc and.4 non-Soviet-bloc. The three most recent reffer-
ences to English-lan,-uag-e publicatiom read as fOllOWS: 1) Coripaan, X.,
Haven C.: Trans. Faraday Soc., 52, 7861 1956; 2) Waver H.: PrQc. of Symp.
No. 9 of Phys..Chem., 21, 2, 1958.
ASSOCIATION: Institut metallokeramiki i spetsiallnykh splavov All USSR Z.
Kiyev (Institute of Powder Metallurgy and Special Alloys AS
UkrSSR , Kiyev)
S'd 3 1 TT 'ED September 30, 1960
Legend to Table 1:
- 3
1 - Temnoraturd in' C)C; Teunepwa. -C Bpeus on~Ta.
2 - exuprimental time
.10
36 25,7
e1of
in hours; 3 rat 1150 . 0.
22 1
2 20.9
electrotran3portation .1200 150 416 10-0 18,0
in~cm/sec; 4
eff4ctive
1250 100
100
7 36:10-6 150
charGe. ?
Card 313
25349
S/O~ 61/000/007/006/011
D20DYD306
AUTHOR3: Frantsevych, I.M., Member of ASUkrRSR, and Smolin, M.D.
TITLE: Dene2~fdence of electrotransportation of the components
of Ni-Cr alloy on concentration
PERIODICAL: Akademiya nauk Ukrayinslkoyi RSRI Dopovidi,* no. 7,
1961, 908 - 910
TEXT: An ion which is migrating in the process-of electrotransport~
is influenced, apart from the force of a constant electric field,
also by the resultant force of interaction between the ion and'the'
conductivity electrons and holes. The charge of the ion calculated,
according to Einstein's formula (Ref. 1: Ann. d. Phys., 17, 549t
1905) on the basis of experimental data is therefore not its true
charge but some effective one. The theory gives for the latter
z - n cr +:-n -
z being the true charge of the ion, n d C and n+o'+t+ the concen-
Card 1/5
25349
5/021/61/000/007/006/011
Dependence of ... -D205/D306
tration, scattering cross section, mean free path of the electrolis,
and, the holes respectively. To transform (1).one can use'
8
n e- (2)
which is deduced in approximate two-band theory of metals. In.(2)
A is electrical conductivityp 1 and n - mean free path and concen-
tration of current carriers, e the elementary charge, h - Planck's-
constant. From (1) aand (2) substituting the values of the constaii~s
and taking into account A = A + A one gets.
+ ~46
10,nil3a~-j- + 1,3. 104n+113_ (3)
z* z 1.3. +
is hole conductivity and electron conductivity). Experimen_~
tal determination of z, d+ and a' is particularly complicated. In'
IS
the pr6sent paper the authors.try to determine z, n n etc. -40rom:
+
Card 2/5
25349 1. ." ,
Dependence of ... $/02 X61/000/007/006/011
D20- 306
the data of temperature dependence (c cO-.n-st) and temperai"lur6del
-in the approximation
pendence (T = const).of electrotransportation
given by the theory bf"electro-transpor ation and the two7,band the-'
ory of metals. The authors investigated the concentration dependan-
cero.-'L' electrotransport-ation in the alloys Ni-Cr with the follovhng
concentrations of Cr: 4.76, 7.56, 10.28, 15-49, 19.66, 22.12, 25-07
31-01 (atomic %) at 12500C. The experimental methods are described
in D.F. Kalinovich, I.!. Kovenskiy, M.D. Smolin, and I.N. Frantse-
vich (Ref. 5: Izv. AIT SSR, OTN, metallurgiya i 'UOPl_JVO, 1, 719
1959). To increase accuracy all necessary quantities were determi-
ned experimentally for each specimen. Two specimens were investiga-
4.
Ued for each concentration. Radioactive isotoDes cr5l and Ni63 were
used as indicators. In the concentration interval 4.76.- 19.66 at
percent Cr where the dependence of ?I on c 1 c) is linear the
following equations are valid
('I - C) + 0,011 1,7 C(l C) + 0,0 11 + 13,0; (6
Card 3/5
25) /49
S/021/61/000/007/006/011
Dependence of ... D205/D306
1,0
IC(I-C)+0,011 C 0 -0~ +0,011
M3.-
These have been obtained by adjus"t-ing and the parameters deter J
ned with the aid of the method of averages. Since temperature de-
pendence was not investigated the calculation of z, or-, Cl+.was
approximate, wituh the assumption that these do not depehd on the
concentration in the interval 4.76 - 19.66 at percent Cr. Values
.of n n and the mobilities u , Ii were taken from H.-Schmidt
+ I- +
(Ref. 6: Z.F. Metualikunde, 49, 3, 113, 1958). All results are*gi-
ven in the Table. There are 1 table and 6 references: 4 Soviet-bloc.
and 2 non-Soviet-bloc.
ASSOCIATION: Instytut metalokeramiky JL s~etsiallnykh splaviv AN.'.
URSR (Institute of Metalloceramics and Special All-;oys
AS UkrRSR)
SUBMITTED: March 23,1961
Card 4/5
zz~_
S/126/61/011/002/020/025
E021/E435
AUTIIORS~l Kali-novich, 1),F,, Kovenskiy. I,I, and Smolin, IM.D.
TITLE' Diffusion and Electrotransfer of Chromium into
-rl 11M
PERIODICAL. Fizika metallov x inetallovedenlye, 1961, Vol.11, No.2,
pp,307-309
TEXT- The electrotransfer of chromium into molybdenum in the
solid state was investigated, Pure molybdenum wire samples,
O~5 mm diametex and 60 mm length. were saturated with the stable
isotope of r--hrojnium by d-iffuslon to a chromium content of 9.92 wtA.
The central 3 mm of wire were covered wi.th a thin film of
rad3oactive Cr:)I, The wire was then annealed in a protective
atmosphere at 1400"C to gi-ve viniform d.Lstrrtbut-ion across the
section, The distribution of Cr5l along the length of the wire
was then found by measuring the activicy of portions 0.1 mm in
width, A direct current was then passed through the wire which
was surrounded by argon, This heated the wire to a chosen
temperature., measured by an optical pyrometer, Then the
distribution of Cr5l was again measured- The graph shows the
Card 1/3
Diffusion and ...
S/126/61/011/002/020/025
E021/E435
distribution beforjs and after heating, Experiments were carried
out at 1200,; 1250., 1300 and 135CC and in all cases migration of
the chromium occurred towards the cathode, The amount of
electrotransfer depended linearly on ihe length of the experiment
and increased with increase in temperature. The rates were as
f 011OXTS ~
Temperature, 'C
Rate of eler-tro-
transfer: (cm/sez
1200 1250 1300 1350
8
-8 10'8 11.2 x 10-8 7.1 x 10-
5 x 10'
The coeffic-Lent of diffusion was found and it obeyed the
following relationships'
D z 4.3 exP ( -.72700/RT) cm2/sec.
The rate of transfer was measured -with an accuracy of + 5 to 8% and
t1le c0effickent of diff-3-on witli 8~,.. There are 1 figure and
2 Soviet referenc-es,
ASSOCIATION,, Institut. metallokeramiki i spetsial-nykh splavov
AN UkrSSR (Institute of Powd6r Metallurgy and Special
Card 2/3 Alloys AS UkrSSR)
Diffusion and ...
s/i26/61/oll/002/020/025
E021/E435
SUBMITTED: June 3, 1960
Figure. ftsplacement of the Radioactive zone during heating by a
direct current to 13000C for 150 h in the 11,1o-Cr5lsystem,
imp/min vs mm,
left of diagram - anode; right of diagram cathode.
uHnImaH
3.00
204
Card 3/3
2
'
-
.11 3214H
02
29
7
V.1
28
ClIcTelan MO-Cr.". cmeukeffsle rpaH[ILX PaRROUTHBHOA 3OHN nPH Harpese o6-
pama noCTORHHUM TOKOM nPIT 1300' C H Te4emie 150 qacois:
1-;Io Itarpena: 2-naune Harpesa.
S/020/61/136/00 1/015/037
B01 9/BO56
AUT~'ORS: Smolin, M. D. and Frantsevich, I. N.
TITLE: Investigation of the Teniperature Dependence of the Electro-
phoresis in Alloys on the Basis of High-melting Metals
PERIODICAL: Doklady Akademii nauk SSSR, 1961, Vol. 136, No.1, pp. 81- 83
TEXT; In the introduction, the authors give some formulas which were set
up within the framework of the development of the electrophoresis theory in
recent years. Denotations for the resulting force and the effective charge
of a migrating ion are given. Next, a report is given on experiments made
with Mo, alloyed with 25 '/',' 74, and with W, alloyed with 25 ~c' Mo. The experi-
ments were carried out on specimens of 0.5 mm diameter and 60 mm length.
The powder-metallurgical production of the specimens is desetibed, the
radioactive isotoues Mo99 and W185 being used as traces elements. The ex-
Deriment,- were carried out within the temperature range of from 1500 to
25000C according to the alloy. In all experiments a migration of Mo-ions
under the effect of a direct (constant) field to the anode and a migration
of the `7-ions to the cathode was observed. On the basis of the data ob-
Card 1/'~
Inve~:tiF,,-,tion of 'he Te-perature Dependence of S/020/61/136//001/015/037
the Electro,,)horesis in Alloys or. the Basis of
HiE-'~_-.-!eltin,c-,- Met-,ils
tained, the effective cLarge of a migration ion may be described as
z* = z + k(-T--+1 (4). T is the absolute temcerature, ~, the resistivity,
)o C\1
and !N the temperature coefficient of the electrical resistance, k is a pro-
port4o.nal factor. Knowing the charge and the atomic concentrations of both
alloy components the electron concentration in both alloys can be cal-
culated. The results are given in Table 1. There are 1 figure, 1 table, and_
4 Soviet ref-=rences.
,~SSOCIAT701-1: Ins'itut metallokeramiki i spetsiallnykh splavov Akademii
U - -
nauk USSR (Institute of Powder Metallurgy and Special Alloys
of the Academy of Sciences, UkrSSR)
PRESENTED: July 15, 1960, by G. V. Kurdyumov, Academician
SUBMITTED: July 11, 1960
Card 214.
S/849/6P,/000/000/008/016
AOO6/A1O1
AUTHORS: Frantsevich, I. N., Kalinovich, D. F., Kovenskiy) I. I., Smolin,
M. D.
TITLE; On the behavior of components of metallic solid solutions in an
electric force field
SOURCE; Vysokotemperaturnyye metallokeramicheskiye materialy. InA. metallo-
ker. I spetu, spl. AN Ukr.SSR, Kiev7,'Izd-vo AN Ukr.SSR, 1962, 75
83
TM- The method of electric migration makes it possible to estimate di-~
rectly the donor-acceptor Interaction in metallic qolid solutions. Previous
studies were directed on the electric migration of the alloying component, with-
out investigating the behavior of the base metal atoms; in a constant electric,
field the possibility of a donor-acceptor ihteraction between the atoms of the ; .
components was not taken into account. In the present article the authors stu-j~
died the mutual electric migration of both components of some binary alloys,
such as Fe-C, Fe-Cr, Fe-W, Ni-W and Fe-Mo, using the method of radio-active'lso-~
Card 1/4
5/849/62/W000/008/016
On the behavior of components of... A006/A101
topes. 7he component under investigation was marked with the corresponding
radioactive isotope and introduced into the central section of wire specimens,
0.6 mm in diameter and 60 mm lorZ. The distribution of radioactivity over the
specimen length was measured prior_tq.ajm&,,i
-kftqr electric heating. Activity,
graphs were plotted to determine the orientd ion and dislocation of the ridio'-
active zone boundaries during the process of electric migration., It was found
that carbon, chromium and tungsten migrated under the effect of the electric
field towards the cathode.. Molybdenum migrates toward the anode and is, contra-
ry to C, Cr and W, an electron acceptor. The electric migration of Fe in binary
solutions of G, Cr and W in iron was found to be directed toward the anode, but
only a portion of Fe atoms, proportional to the amount of donor-atoms of the ad-
mixture component, participated in the migration. On the basis of experimental
data obtained, migration rates of the investigated components were calculated
and tabulated (Table). The experiments'show thikt a donor-acceptor interaction
exists between the components of the Fe-C, Pe-Cr and Fe-W systems. The donor or
acceptor nature of admixture atoms is predetermined by the mutual position of
energy levels of incomplete shell electron *s of the admixture atom, and the Fermi
level of the base electron spectrum. The appearance in the lattice of admixture
Card 2,/4
3/849/62/0w/OW/008/016
On the behavior of components of... A0061AI01
atoms with excess charge is connected with the deformation of,energy bands of
conductivity near these atoms, and the formation of a charge of the opposite
sign, screening the excess charge of the admixture. This screening charge is
partially distributed in the conductivity band, and partially in the band cor-
responding to the internal incomplete shell of the base atom. The temperature
dependence of the electric migration effect is explained by the dispersilig ef-
fect upon the electrons of the conductivity zone of atoms, which are ih a state
of thermal oscillation at the crystal lattice poifits, and also by changes in the
degree of the donor-acceptor interaction. It can be assumed that the magnitude
of the electric migration effect depends upon the correlation between the exter-
nal electric field forces and the forces resulting.from the transfer by conduc-
tivity electrons of oriented pulses to the ions. There are 4 figures and I
table.
Card 3/4
On the behavior of components of...
S/849/62/000/000/008/016
A006/AlOl
I
Table. Migration rates of metal alloy components under the effect of an elec-
tric field, in v-cm/sec
Migra -,id
investigated: element
850
C
Fe- C Fe
Fe - Cr Cr
Fe- Cr Fe
- w
F
c
w
fe-W Fe
NI - W w
Fe - Mo Mo
_~~__in 0C_
e
per
950 1000 1050 1100 1150 1200
- a-A 806-10-6
- 3.41.1 2:51-10-6
- - - -
- 3,00-10-1 4901-10-7
- 4172-10-76.31-10-7
'6161.10-4
- 1125-10-
1,25-10 2.78.1 -13,89-10-7
- - 4,40-10-1
11,67-10-6 14,44-10- 331,39. 10-6 39,14-10-6 -
1.39-10-6
10-1 0.57-10-0 0
8 .10-7,
5 .10-1-18
4 .10-712
9
6.8 .
87-10-1
4 .
,
.
6,26-10-1 5.35-10-144,4 - 10-" 2,18. 10-1
,
80.10-1
8 568-10-1 1135-10-1, 0
.
2.44.1 ~$
0 1:50.10-" 0.32-10-6 0
1,86-10-1 0,72-10 7 0
_ 5.63--1e .7,23-10-1 7,78. 10-1
Card 4/4
39765 -
S/126/62/013/006/014/olB
B193/E383'
AUTHORS: Kalinovich, D.F.', Kovenskiy, I.I. and Smolln M.D.
TITLE: Electrotransport of tungsten in cobalt
PERIODICAL: Fizika metallov i metallovedeniye, v.13, no 6,
1962, 930 - 931
TEXT: The mobility of metal ions in a metal in a constant
electrical field depends both on the diffusion mobility and on
the characteristics of interaction between the ions,on.the one
hand, and the electrons and holes,on the other. Useful
information on the mechanism of the diffusion and electrical
conduotioh* can therefore be obtained from stud-Jes of mobility
of ions and the object of the present investigation was to
study the electrotransport of-tungsten in a cobalt allo)r
containing 99.48% Co, 0.240,1 Ni, 0.03% C, 0.04% 0, 0-010' C,
-ras
0.020' Si and 0.14 50 Fe. Tungsten i introduced into the experi
mental specimens (60 mm long, e.62 mm in diameter) by diffusion-
annealing (150 hours at 1 20 C) in tungsten powder, dry argon
being'used as the protective atmosphere. This treatment was
followed by homogenizing annealing (80 hours at 1 350 0C),
Card 1/~
s/lz6/62/013/Oo6/ol4/ol8
Electrotransport .... E193/E383
after which the tungsten content of the alloy was ' 0.82 'wt.%'.
After electrodepositing a thin layer of the radioactive isotope
1%,185 around the circumference in the middle of a specimen, it
was sealed in an argon-filled tube and connected to A DC source,
the electric current serving both to heat the specimen to the
required temperature (in the 1 100 - 1 350 OCrange)-and to set
up an electrical field, each test lasting 150 hours. The sign
and extent of electrotransport was determined from the
distribution of radioactivity along the specimen before and
after each test. Typical results aiZe reproduced in Fig. 1, where
the radioactivity (pulses per minute) is plotted against the
distance (mm) from the anode end of the speci.,ne2-,.,. the circles
and crosses relating, respectively, to results obTained before
and-after the test i-jhich consisted of 120 hours at 1 200 OC,.
The absolute values of the rate of electrotransport of tungsten
in cobalt, calculated from the experimental results# increased
trom 2.84 x 10-9 at 1 100 OC 'to 1.56 x 10"7 em/see at 135 *C
Card 2/V
s/126/62/013/006/ol4/ol8
Electrotransport .... P,193/E383
The effective charge of the tungsten ions,-calculated from the
kno-i-n-i Einstein relationship, was found to be of the order of
tons of electron units, which indicated the predominant part
played by the hole "wind" in determining the sign of the
electrotransport in the case under consideration.
There is 1 figure.
ASSOCIATION: Institut metallokeramiki i spetsial'nykh splavov
AN Uku~*SSR (Institute of. Powder Metallurgy and
Special Alloys of the AS UkrSSR)
SUBMITTED: February 12, 1962
Card 3/4
L 11259-63 EWT W /BDS--k??M ASD
ACCWTON MR: AP3000~~ 81/63/0(,)5/005/1238/1242
AM2OR: Frantsevich, 1. Kalinovich D. F.; Novenakiy, L: I. Soolin D.
TMZ: Relative and total transfer of substance In metals under the influence of
direct current
SOURCE: Fizika tyerdogo tela, v. 5, no. 5, 1963, 1238-1242
MPIC TAGS: electrotransference, transference. numbers, alloys,. Ag, Zn
ABSTRACT: The total and fractional velocities of transference and the transference
numbers were determined forAg4n alloys., 14easurementswere made.on alloysi,vith-,-w-,
25, 35, and 50 atomic % zinc.- Bodo 1 mm in diameter and 70 mm long 'were used, the
two vith lowest zinc content being coated electrolytically with the radiois
sup 3.10 and the third being marked, in ~ the same manner witla Zia sup 65. Ali
were annealed to produce uniform distribution of the radioisotopes. The d 10 MV,
tion of radioactivity was then measured along'the length 6f the rods and was found
to be uniform over the entire length. Direct current was then'sent.through the'
rods, which were placed in a neutral atmosphere (argon); the rods were sinialtane-
ously heated to 550C, and the experiment continued for 280 hours- The results show
that in the first two alloys, belonging to the'Alphs. region, the velocity of elee-
trotransference is greater for silver than for zinc. In thethird eazople (the
Card 1/p
SMOLINY M.D.
Temperature dependence of electric transfer in totals.
Fiz. tver. tela 5 no.6:1586-1588 Je 163. (YM 16:7)
1. Institut metallokeramiki i spetaiallrWkh splavoy AN UkrSSR,
Kiyev.
L 18008-63. EWP(q)/kWT(a%/nD',~L-..AFFTCIASD----JD/;G.,..--
MY-
ACCESSIO14 NR.- AP3001298
I AUTHORSt Frantsevich, I. Ny; Kalinovichs Do F.; Kovenskiyp I. Smolin Me Do:
A
TITLEt Determining the degree of i6nization-,pf components,in Mo-W al 0y
1;''SOURCE: Fizika tverdogo telap v 5 no* 6,~ -16~ 3, 728-1730
IIv
.TOPIC TAdS; Ionization, alloy) Mo,, W, donor"acceptorp interaction, effect e-
ch~rge, radioactive isotope
ABSTRACTs The metal studied was Mo alloyed with 15 atomic % we Thin wire.
samples~ 0*5 mm in diameter and about 70 Mm. I ong y were prepared from this alloy
and In-the m'ddle part f each sample a thin layer,ofradioactive isotope.
0
.(14699 or W185) was deposited. The' length of-this.coated segment was.'about 3 me'-"
,The method of determining rate o
f movement of the.radioactive zone has been.
described previously by Do Fo Kalinovicho 1, 1. Kovenskiyy and Me Do Smolin.
(FT-To 39 33671'1961). Investigations e made in -173~
wer the temper ature ranges 1
2473K for W and 1973-25739 for Mo at 1000,-intervals. At all temperatures the
Mo ions migrated toward the anoldel'the W ionitoward the,cathode. The values
Ihat the,piedominart effect in.tr sf*r of W i
for effective charges indicate an ons
-A
FRANTSEVICII, I.N. [Frantsevyoh, I.M.1; KALINOVICH, D.F. [Kalynovych, D.F.)j
KOVENSKIY, I.I. (Kovenslkri, I.I.); SMOLIN, M.D.
Studying the diffusion of the components of a molybdenum-
tungsten alloy over a wide temperature range. Ukre fiz. zhure
8 no.9alO20-1025 S 163. (MIRA 17:8)
1. Institut metallokeramiki i spetsialInykh splavov AN URrSSRg
Kiyev.
S/l26/63/Ol5/OO3/O2l/U5_
E073/E333
AUTHOR:. Smolin M.D.
----------------
TITLE: Diffuslon of components into molybdenum-tungsten
Alloys
PERIODICAL: Fizika metalloy-i metallovedeniye, v." 15, no- 3.
- 473
1963. 472.
TEXT: The diffusion, of.both components into allo'yz of
Mo with 25 at.% W and of W with 25-at.% Mo was Inveatigated by
99 185
means of Mo and W .1 isotopes in the temperature ranges
1500 - 2200,-1700-- 2300, 1900 - 2500 and 2100 - 2600 C. Wire
specimens of 0.5 nun diameter and 60 mm length wer Ie electroplated
-on a length of about 3 mm with a thin layer of the isotope of the
element, the diffusion'of which was studied. - Since the layer was
very thin,- the' radioactivity of the bath was very high,'125 to
150 mc/litre, i.e. about 50 times the current value used in
similar experiments. The experimental Method was the same-as that
used in earlier work of the author., The diffusion coefficients,
determined'with a n error of the order.of 8 12%, are tabulated.
In all c4ses, the relation observed.between lgD and-1/T was
Card 1/3
Investigating self-diffils on 4n rae~als the use o4' radio-
active isotopes. Fiz. met. i netalloved. 16 nc.1:138-140 R 163.
(11IRA 16:9)
1. Irstirut rn,,,~tallokararaiki i spetsiallnykli splavov AN UkrSSR.
(Diffusion) (Ions-Rigration and velocity)
KALRIOVICHY D.F.; ROVENSPY, I.I.; ~4N. M.D.
Investigating electron transfer in binary metal alloys. Fiz.
met. i metalloved. 16 no.2:232-235 Ag 163. (VaRA 16:8)
1. Institut metallokeramiki i spetsiallnykh splavov AN UkrSSR.
(Iron-aluminum alloys) (Electrons)'
KILINOVICH, D.F.; XOVENSKIY, I.I.; SMOLIN, M.D.
Diffusion of the components of an iron-chromium alloy in a broad
range of composition. Fiz. met. i metalloved. 16 no.4:619-620
0 163. (NMA 16:12 )
1. Institut metal-lokeramiki i spetsiallnykh splavov AN UkrSSR.
I,ACCESSION NR: AT4045011 S/0000/64/000/000/0171/0176
IAUTHOR- Frantsevich, 1. N.; D. F., Kalinovich; 1. 1. Kovenskly; M. D. Smolin
TITLE. Study of the passage of electricity through metallic solid solutions
SOURCE: Soveshchanlye po, probleme lzpollzoyaniye atomnoy energii, Kiev, 1961.
Radiatsionnaya avtomatika, izotopy* I yaderny*ye izlucheniya v nauke I tekhnike (Radiation
automation control systems, isotopes, and nuclear radiation in science and technology);
doklady* soveshchanlya. Kiev, lzd-vo AN UkrSSR, 1964, 171-176
TOPIC TAGS: electroconductivity, solid solution, solid solution cc -Iductivity, metal solid
;solution, ion migration, electron density, electron vacancy, hole
ABSTRACT: The Institut metallokeramiki I spetsiallny*kh splavov AN R (Institute of
ed out a method for studying
Powder Metallurgy and Special Alloys, AN Ukr. SSR) has work
the passage of electricity through solids by means of radioactive isotopes. This method
makes It pDssible to study such passage not only in extrinsic elements but also in basic
alloys. Some of the binary systems studied were: iron-carbon, nickel-chromium, cobalt-
Jungsten-, nickel -tungsten, molybdenum --chromium, silver-palladium, etc. The radio-
$active isotopes used included carbon-14, iron-55, nickel-63, silver-110, etc. The experl-
mental method has been discussed in an earlier paper by the same authors. Accordingto
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Card J/~r
ACCESSION NR: AT4045011
a recently-developed theory, ions during migration through solids carry the following of-
ifective charge: Zo - z - a' _' a- I- n+a+l+.
where z* is the effective charge Z Is the true ton charge, n is the concentration of the con-
ducting electrons (holes), a- is the electron (hole) scattering cross-section, andA is the
I length of the electron (hole) free path In the alloy. Values with a minus sign refer to
electrons, those with a plus sign, to holes. For greater accuracy in determining the value
of the effective charge, all the quantities needed in the calculations by the well-known
Einstein formula were experimentally determined for each specimen. The first set of
experiments served to obtain the relationship between Z* and temperature; the next set was
aimed at obtaining the electron density as a function of the charges of the basic alloy mid the
admixture and of the concentration of the latter; and the third set yielded the electron and
hole cross-sections. The results of these experiments are tabulatcd, showing a linear
inverse relationship between temperature and effective charge, and a direct linear relation-
ship between electron density and both charge and concentration. Orig. art. has- 8
formulas and 3 tables.
ASSOCIATION: None
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