SCIENTIFIC ABSTRACT SOBOLEWSKI, H. - SOBOROVSKIY, L.Z.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001651910010-7
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 26, 2000
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SOPOLDISKI, 9.
A study on the traffic safety of trains with two locomotives on curves. p.201
(PRZFGLAD K0LFJOVf, Vol. 9. No. 6, June 1957, Warsaw, Poland)
SO: Monthly List of East European Accessions (EEAL) w, vol. 6, No. 9, Sept. 1957, Uncl.

PHASE I BOOK EXPLOITATION POL/5033
Czaplinski, Stefan, Master in Engineering, Jan Dyduszynski,
Professor, Master in Engineering,'Jan Sobolewski, Docent,
Master in Engineering, Zbigniew Szanlawski, Master in En-
gineering, and Zdzislaw ZioZkowski, Professor, Master in
Engineering.
Najnowsze rozwikizania konstrukcyjne w budowie aparatury chemicznej
1959/1960; praca zbiorowa (Latest Design Developments in the
Construction of Chemical ApparAtus 1959/60; a Collective
Work) Warsaw, Patfstwowe Wydawn. Techniczne, 196o. 127 P.
Errata slip inserted. 1,b90 copies printed. (Series: Nowa
technika, zesz. 32)
Coordinator: Jan Dyduszynfaki, Professor, Master in Engineering;
Scientific Ed. PWT: Irena Gajewska, Master in Science; Tech.
Ed.: I. Milewska.
PURPOSE: This book is intended for chemists, engineers, and
designers of chemical equipment for research and industry.
It may also be used by students In higher technical schools.
Card=a/51__

Latest Design (Cont.)
POL/5033
COVERAGE: The book discusses the latest (up to 1959) trends in
the development of some designs for chemical equipment. The
authors deal specifically with progress In the design of ab-
sorption and distillation equipment, and latest developments in
the design of gas compressors arid sedimentation separators
used in the chemical Industry. No personalities are mentioned.
References accompany each section.
TABLE OF CONTENTS:
I. Progress in the Field of Absorption EqiApment Design 5
1. Introduction 5
2. General review of progress in absorption-tower design 6
3. New types of packing 8
a. Solid-wall packings 8
b. Grid-and mesh-type packings 18
c. Packings consisting of parallel layers 32
Ca

I ! I 1 .11 . I . . fli f , , -4; i 1 :'. . ;so
tit iVX ot , ' I i !,:; I -i w , ii;;- r 1 nz, . ; K I I, .,~ ' ~n i , " "ti()I,Fw:"I-l ,
-1 J)rz..,,
Of 3-L' labOr"Itory cement
tf-, F. '. -1, ntr I-z " blid 21 nn, . l-, ; "u- IF '- ', 4- .
1 ~ ~, - -, ---~ ; i : n a S- i -, I-- c I o i' Erl I * i n e f ~ -- ~ n z , F -,* a I %,, s t, )'r: .
I

juzef
On the role of Sor,~- endogenous factors in the etiopathogenesis
of perdodonto S4S in the light of recent studies. Pol. tyg. lek.
19 no.7:269-270 10 F 164.
1. Z Zaklladu Stornatclogii ZacI:cyw&4czej Akademii 14edycznej w
Lcd-.-I (kit~rovnik: -.-rof. dr ',!ieczvsla:,: Fuchsi

SOBOLEWSKI, L. (:,:ngr.):
Zarys Chlodniczych Urzadzen AbsorpcyJnych. (Sketch of Absorbing Agents in Refrigeration).In
M
Vol. V. Wspolazesne Problemy Inzynierii Chemiczned (Common Problems of Chemical Engineering)
Pages 551-558, Warsaw, 1950.

peretraL-ing
r~g vapor Q',
3 !,ooz cj--i 1, rv-, 4 44-1-466 164.
of Gbamica-- Engineering anj Apparatus Design,
1
C".i the Fsli3h d' 3cie=09, Giiwi~--e. 3ubmi-r,~.edl
Sopteml)cir 21, 1964.

SoBou-7--mi, m.
SOBOLEWSKI, M. Vibrators, modern equipment for driving piles into the
ground. P. 418. (10SPODARKA WODNA. Warszawa, Poland. Vol. 15, No. 10, Oct. 1955
SOURCE: East European Accessions List (ERAL) LC Vol. 5, No. 6, June 1956

iY Poland 11;-32
--",&TEGOYff Chemical TecIlinology - Artificial and
~ynt'.hetic Fibers
P-1pS. jOUP,. 11-12-Kbim, no. 24 1959.- 0. 88616
AUTHOR
T-IT.::;'T.
T ITLE'
Gobolewski, M.-
De-.relopment of the Industry of Chemical
Fibers
C) R I ~-T Chemik, 1959, 129 No 4, 13-1-139
AB.--.TRACT A review of the technical and economic
d-v~?Ioj)-me.nt. of the industry of chemical fibers in various
I
cou.-QIU-r--ILn-s and in the Polish People'S Republic.
T. Bud-kevich
RD:

III
"Olome rToblems of the rubber industry." D. 221. (Chemik. Vol. 6, no. 7/8,
July/Aug. 1953. K-itowice.)
SO: Monthly List of Eist European Aftessions, Vol. 3, No. 2, Ubrary of Congress,
Feb. 1954, Uncl.

SOBOIEWSKI, Marian, mgr inz.
The Polish synthetic fiber industr-f in the prospective plan up
to 1980. Chemik 15 no.5.-156-160 )OV 162.
1. Zjednoczenie Przemyslu Wlokien Sztucznych, Lodz.

S/ 081/62/000/024/045 /052
B106/B186
AUTHORS: Kraul, Emil, Clapinski, Jan, Sopiela, Waclaw, SRY9Lew!jki,
I
.4azia7rk-, Rybicki, Zbigniew
TITLE: Methods for Droducing a fiber from polyvinyl alcohol
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 24 (11), 1962, 953,
abstract 24P1034 (Pol. patent 44511, June 10, 1961)
TEXT: A method is described for the production of a fiber from polyvinyl
alcohol by coagulation from aqueous solutions in a bath, dehydration and
simultaneous-stretching of the deposited fiber, removal of part of the
salt contained in the fiber by washing, drying of the fiber, thermal
treatment and acetalation. The method distinguishing features of this are
as follows: the spinning solution flowo from the spinneret into the
coagulating bath at a velocity of 12 - 13 m/min. It then follows its
course at an angle of 900. The fiber leaves the coagulating bath a%
15 m/min; th,.--e is a distance'.of 130 - 150 cm between the exit of the
spinning solution from the spinneret and the point at which the fiber
changes its direction in the bath. The excess from this bath is removed
Card 1/2

S/08 62/000/024/045/052
Methods for Droducing a fiber from ... Bio6yBi86
and the fiber is passed through a washing bath which consists of an aqueous
solution of sodium sulfate (concentration 140 - 155 g1l). The pH value of
the spinning solution and coagulating bath is adjusted to 7 as to yield a
spinning solution of polyvinyl alcohol containing 40.2% by weight of ashes.
The maximum moisture of the dried fiber is 3% and the maximum dr '
ying
temperature is 1200C. Before it is dried the fiber ought to contain
35-37% by weight of polyvinyl alcohol, 58 - 60% by weight of water, and
5-7% by weight of salt. The temperature of the washing bath is
25 - 290C, the washing time of the fiber is -1 min. [Abstracter's note:
Complete translation.]
Card 2/2

SOBOLEWSKI, Marian,
-- ----!
Fifty years of the Polish chemical fiber induBtr7. Przegl w1ol-den 16
no.6:348-350 je t62,,

SOBOMrWSKI, Marian, MU -tn27.
The photocheri-PI indusi..rv in FoLand aud ~r the world.
wm"k-,16 ia"32: - Supplftmat ro;34- Lin" Jvso

SOBoL7,,q,SKI, S.
110r-a-mz;~Aizon of mech%.;mIzed &penwork *-nd -planks ')y using single-ohovel
excavators workirg above the ground level." p. 320. (1-:kTMIALY BUDMMUNT-13
Vol. 0. No. 12, Dec. 19f;Ii. Warszawa. Pol-and)
SO: MwitAy List of .2ast European 'Accessions. M-IkL). LO. Vol. 4. No. h.
April Uncl.

~Ilcladca &Ufl s a upnm rod
and Gr-sa K=durds. T~'SoWew*i &ad P. wajda~
lg22),7
62 methA SL_ G==
M~ 116 =ad
gave, tcr COs. MCO, aad NaCUd=d=d resufts, and far Fcv%
+ AW. 0.195;*o and D.21%, cup. - By thm~ASTM aiethcd
t~~h=, IfIG 0.04, CcLQ 32.43,
s0a 45,81. + L~A Vda. HCI Q.85%-. by th
DIN.z4ethod tUa resp.*-r~40'.wae,20.60. ~.Otl. 321.11,

rOLAND / Chemical Technology. Chemical FroduCts and K-13
0 L~
Their Application-Ceramics. Glass. Binding
Materials. Concrete
Abs Jour: 'Ref Zhur-Yhimiya, No 39 19595 9108
Author Sobolewski, T.
Inst Not given
Title Chemical Analysis of Gypseous Stone by German
and American 3tandards
Orig Pub* Cement. Wapno. Gips, 1958, 142 No 4, 79-82
Abstract: A comparison of methods of chemical analysis of
gypseous stones by ASTM C 26-52 and DIN-1168
standar,s was conducted on two samples of known
chemical composition. Close conformity of results
Card 1/2

SOBOLEWSKI, Taususz (Wroclaw)
"A general map of Germany 1 : 200 000." Reviewed by Tadeusz
Sobolewski. Czasop geograf 33 no.2:270-271 162.

SOBOLEWSKI. Tadeusz
"Germany and Europe. The Great Shell Atlas." Reviewed by Tadeusz
Sobolewski. Czasop geograf 34 no.l-.92 163.

Tl-.,-z dcvelo,-;m?,n'U of th,!~ sy-nthctic fib!~r.,; Indu-,,try. p. h7l.
'HE~-'J (Minisuerstwo Przt.,;-i-,7slu ChnmicznnEo i Stowarzyszenic llauko-,ve-Tec~miczne
Inzyni-~ro%-, i Technikow Frzc,-nyslu Chemdeznego) Ijar3zawa. Poland. Vol. 12, no.
1050.
Monthly Ust of EaSt European Accessions (EZA1) LC. Vol. 3. no. 8, Auost 1q59.
Uncl.

SOBOLICJ P.
11 A few notes on 'the tectordes of the Pezinok-Pernek crystalline rocks".
GEEOLOGICKE MWE; ZPRAVY, (Slovenska akademia vied, Geologicky ustav
D-Jonyza Stura) Bratislave, Czechoslovakia, No. 15, 1959.
Yonthly List of East European Accession3 (E:EAI), LC, Vol 8, No. 0', August 1959.

- p . ~
EYDMAN, I.Ye.; ROMANOVA, V.G.; SOBOLKIN, S.Ya.
Evaluating the aalinitfV-UTWground waters on the basis of
hydrogeological well logging. Ra2Ved.1 prom.geofiz.no.17:79-83 '57.
(MIRA 10:12)
(Borings) (Water, Underground)

SOBCLCT3Y,-,Y,I.
2079. l(inatics and inechanism of the 0:01~`
mcrisa(iion_~f vinylchloride and viulidene chloride.
A. 1). K .S--hWSrF.DVHM.V, 1'. M. KHOMIKOVSKIII
and Y. J. 11hys. Chem. U.SZ.H.~
. ait ,
1053,27, Imn 2 KaW., IN-4, 1, 45- I'lle
bumoyl I'Vroxide Catalysed, suspension pelymeri%a-
tion of Ilmsystem ha:% been investigated,at 60', GO';
re
.in([ 701 C. Conchisions are drawn on the activity
of eich monomer. 3S21121MILU4"

; ~-:. ~-, , ! ~ ~:. ~. t. J.!! I -,, :I !~, ~- i "; ~ - lc U.-I ti:, Ft - -, -- ~ :: I
- : "! ~ t, -~, ~- ~~ I :~ .- 1- 11 - F I*Ia- -' I L ,
., I I . - ~:~
., , ~ , C z , t, f : ~ ! ~ C ,. - , i I t i ~ ~, - 1- ~ a "'.4 r!na I --I ~; L I i~~. ~-~ S711C~I! t1i"~-I'l- -1~7,1- ~- - ,:, ~1-1% 1 F
: . 1, 4 - -- -, I- .., .
- .1

303OLOV, V. 3 -
T-achr'010T[
3uilding and maintenance of backlinz, machines in the hemp and jute ;ndustrr, ~Ioskva,
Gizlegprom, 1,052.
~d ~"VY, Uncl.
9. Monthl List of Russian Accessions, Library of Congress, December p

S0136LOVA, V. Technicl:n qpoluprace A. Kudrnova
'Tffect of thermal factors on working performance and on the course of
the recovery lohase, Cesk. fysiol. 8 no.3:245-2h6 Apr 59.
1. Yatedra lekarskych ved ITVS, fakulta telesne v-ychovy, Praha. Predneseno
na III. fysiologick,7ch dnech v Brne dne 14. 1, 1959.
(MAT, eff.
on working Derformance (Cz))
(WORK, physiol.
eff. of heat on performance (CZ))

SOBOLOVA, V.;SKORPIL, V.
Participation of the striate muscles in restoration processes in
animals adapted to low environmental temperatwe. Cask. fysiol.
9 -ao.1:51-52 Ja 60.
1. 1TVS-Fakulta teleane vychovy, Fysiologicky ustav CSAV, Praha.
(ACCLIMATIZATION)
(MUSCLAS phys iol. )

SOBOLOVA,V.
Effect of thermoregulation. and of motor adaptation on the work
performance and on the recovery phase. Cesk.fysiol. 9 no-3:
265-66 my l6o.
1. Katadra lek. ved ITYS, fak. KU Praha.
(ADAPTATION PHTSIOLOGICAL)
(BODT TIM M ATURB)
(MOVIIMT)
(EMTION)

SOBOLSKI., Konstan~y, dr
I ineers and technicians, facilitaip the way of living for
t-abled veteransol Przegl techn 84" no.1:6 6 Ja '63.
k
~'t'

_601~OLSKIY R.y prof., mgr., inz.; IIAWRYIAK, 11.0 Zastepea prof., dre, inz,;
STRYCZEK, S., adiunkt, mgr., inz.; TESIOROVSKIY, J., adiunkt, mgr.,
inz-.
Investigation of the d7namic coefficient of crane steel supporting
structures. Mechanika Wroclaw 6 no.43:65-108 161.
1. Katedra Maszyn Dzwigowych i Urzadzen Transportowych Politechniki
Vroclawskiej.

SoB()LsKI, Roman, prof.; HAjjRyLAK, Henryk, dr., inz.
Analysis of the needs and possibilities of domestic machinery
production, essential for open cut mining of brown coal.
Przegl mech 21 no.7:193-197 Ap 162.
1. Politechnika Wroclawska.

WROBM4SKI, Teodor, prof.; SOEOLSKI, Forian, prof.
On the fate of the cair of machine des-igninf; in teclinical
colleges. F-rzegl mech 21 no.12:357-359. 25 Je 162.
1. Politechnika.- Wroclaw.

-SOB0146KI, RomaE, prof. inz.; HAWRYLAK, Henryk, dr inz.
On some dynamic phenomena in the operation of a multibucket
dredger excavators on wheels. Przegl mech 21 no.18.549-552
25 S 162.
1. Politechnika, Wroclaw.

SOBOLSKI, Roman, prof.
Hydraulic power systetis, their application and development prospects.
Przegl mechan 21 no.23%713-714 10 D 162.
1. Rzeczoznawaf Stowarzyszenia Inzynierow Mechznikow Polskich,
przewodniczacy Oddzialu Stowarzyszenia Inzynierow Mechanikow
Pol$kich~ Wroclaw.

SOBOISKI, Roman, prof.
Scientific and Technologiced Conference on the Construction.
Utilization and Teating of Pumps,, Przegl mech 22 no.14'1+25-~-
426 25 J1 ~'t63.
1. Przewodniczacy Oddzialu Stowarzyszenia Inzynierow Mechanikow
Polskich, Wroclaw, oraz kierownik Katedry Maszyn Dzwigowych i
Urzadzen Transportowych, Politechnikag Wroclaw.

.0:1.aIll prof. ::igi-. inz., HAWitYLAK ar., ill:,,.
L
3-rcalcdown correlation of machaine sets in opencast miln-m*.
Przc.,~l mech 22 no.19:535-591 10 0 163.
1. Kierovmil: Katedry i Za,dadu :,as-"yri D-.-,.,i--o,,rych J-
~ ych, 11olitecimilca, I.,!rocla-7., or 3obolz;.:i'
Urzadsc~n Transportow
2. lw,lykladoirca, Katedra ~'-~szyn Dztiigo,..ryc,'l i Urzadzcn
Politc,clImika, ldroclau (for llam-ylak).

SOBOV, Janina
Cooperation of the Upper Silesian Field Station of the
Geological Institute with institutions abroad. Przegl geol
11 no.5%239-240 My 163.

S CBON, J.
Schedule of sessions of the Upper Silesian Field Station of
the Geological Institute. Przegl geol 11 no.5:249-250 MY 763.

SOBOIRP~ J.
Special libirary of the Uprer Silesian Field Station. Przegl
geol 1.1 no.5:250 My 063.

BACA, Ferenc. inz.arch. (Backa Topola, Dare Saiaja 1)3 SOB(FiJ.A.,-Petar,
tehL (Backs. Topola).
Industrial method of building at the Prvi Maj Building
Enterprise, Backa Topola. Tehnika Jug 18 no.109.Supplement*,
Gradevinarstvo 17 no.10.,1842-1844a 0163.

ACCESSION'NR: AP46T6TzC-- sNj6i"A 0667F0i760'WW8"""
AUTHOR: Sobornikov, Yu. P.; Kravets, P. N.;: Yanik, A F
TITLE: Capacitance parametrons with pulse -type -junction diodes
SOURCE: Avtomatika i priborostroyeniye, no. 2, 1964, 25-28
TOPIC TAGS: semiconductor diode, parametrorY, capaci.tance parametron,
junction. diode, junction diode pa.rametron,: digital bomputer
i' ABSTRACT: The details of a new des*lgn of C-pa:rametron using quick-pulge-
response Ge junction diodes are reported. The diodes have a base resistivity of
3 -5. ohms and a barrier capacitance of 6 -28 pf at - 1 v bias; they are used in the
simplest self-biased series-supplied circuit which permits a substantial diode-
parameter spread. Clock frequencies of 200 and 300 kc are selected for 3-cycle
and 2-cycle h-f purnping'systems,, respectively, the parametrons are intended for.
industrial computers. A 3-input parametron rridy have 6 logical couplings (with
Card 1/2

AGC;ESSION NR: AP4040426
R = ZO kohms); a 5-input parametron, 10. logical couplings. Other details *are
given. Orig. art. has: 2 figures, 2 formulas, a'nd 1 table.
ASSOCIATION.- Institut avtornatiki gosudarstvennogo komiteta. po
ittee for Instrurri~nts)
priborostroyeniyu (Institute of Automation, State Gomrr
SUBMITTED: 00 DATE ACQ: 24Jun64 ENGL: 00
SUB CODE: DF, EC NO REF,SOV: 002 OTFIER:~ 001
Card

ACCESSION NR: AP404Z955 S/OIOZ/64/000/004/0037/0048
AUTHOR: Doly*ns'ka, N. 0. (Dolinskaya, N. A.) (Kiev); Maralin, V. G. (Kiev);
Sobornikov,- Yu. P. (Kiev); Yany*k, A. F. (Yanik, A. F.) (Kiev)
I TITLE: High-frequen6y- pumping systems in parametron digital computers
SOURCE: Avtomaty*ka, no. 4, 1964, 37-48
TOPIC TAGS: digital computer, parametron, parametron digital computer,
industrial digital computer
ABSTRACT: A 3-cycle pumping system is considered which permits synthesizin
9
industrial digital computers with parametrons operating at an excitation frequency-,
4-30 'Mc, with 20-30 oscillations per packet (clock frequencies, 100-500 kc).
-synchronizing and ring 3 tion-oscillator schemes
Hard-closed self -phase relaxa
for 3-cycle semiconductor submodulators are described, as well as mixed and
purely semiconductor h-f.supply schemes which have a pulse-amplitude pumping '7
Card I /Z

i
i
i
I
i
i

Ro
L 22140-65 EPF(n)-2/`EWT(d)/DJF(1) Pg-4/Fk-h/P1-h/Fo-h/Pq-b/Fu,-4/Pae-2 SSD/ASDA-5
AEDC(.-a7A-Ff4dC/AFETRAFTC(p)AAEi%[&/iU M/ESDI)(p) LJP(c) WWOWAG
ACCESSION NR: AP5001746 S/0302/64/000/004/0056/0059
AUTHOR: Dolinskaya, N. A.; Repnin, V. N., Sobornikov, Yu. P.
TITLE: Device for comparing parameters with several set points
SOURCE: Avtomatika i priborostroyeniye, no. 4, 1964, 56-59
TOPIC TAGS: automatic control, automatic controldesign, automatic control
systern, automatic control theory
ABSTRACT: In digital systems of automatic industrial -proc es s control, the
current value of a process parameter is automatically compared with one or more
set points. As existing synchronous comparison devices are too complicated, a
new asynchronous device has been developed in which the code of each set point,
coincides, in the storage unit, with its numerical value. An additional indicant is,
introduced to identify the next-in-line set point of the same parameter. A
functional diagram of the new device is briefly described. A Z56-point laboratory
_Cord 112

,L 56526-6
;ACCESSION NR: AP5009401 S/0208/65/005/002/0366/0369
681.142.2
jAUTHOR.- Soborniko P. (Kiev)
ITITIX: On a method of division and determination of multiplicative overflow for
computers operating in a system of residue classes
'SOURCE: Zhurnal vychislitellnoy matematiki i matematicheskoy fiziki, v. 5, no. 2
1965S 366-369
;TOPIC TAGS: computer theory, computer programming
In connection with the,unsolvability in.thegeneral case of the con-
gruence YZ _= X mod m. , an indirect machine method for the division of integers in a
tsystem of residue classes is developed. It is based on the decomposition of exact
W or of rounded W) into residue representations of degree 21- (i= 01 it... , k;
'12 S z). The method is free of the limitation of digital division in residue numbers.
isystems, possible only for integral quotients. Given a non-redundant system of
:residue classes having the numerical range
+
Card 1/2 J

SOBOTTIKOV, YU.":, MY
-mir.Ltion of ~-,,i-,i~,-licative o-rflolj
lethod of cii-vision and deter "I - -- I -
-n residue number systems.
for electronic computern oper-ating L
Zhur. v~ch. mat. I fiz. 5 no.2:3~,6-369 --r-Ap 165.
4 mat. J. M
12:5)

L ()0916-66
iACCESSION NR: APS014215 UP./'0102/65/000/002/00115/0053
:AUTHOR: Sobornikov, Yu. P.)-"(KieV
!TITLE: Tbree-valued pAramptron logic in.Post's algebra
~SOURCE: Avtomatyka, no. 2, 1965, 45-53
~TOPIC TAGS: ternary logic Arcuit, computer logic, logic.element, ternary parame-
tron, computer component 1,
;ABSTRACT: Ternary notation offers many advantages over binary and other systems of'
a
,coding information; discrete automata based on three-valued logical elements offer
;much greater speed than analogous automata with binary elements. The possibility of
!using autoparametric resonance of the third type in a nonlinear oscillating circuits
!to construct logical elements with three stable phase states is discussed. It is J
.
' emonstrated that the design of any three-valued ODerator of the basic logical s
d YS-
;tem ban'be achieved with a single ternary parametron if use is made of the simplest'
;lines of complex inter-parametron linking% The construction of a ternary parametric
ogic in Post's algebra is based on the principle of the linear vector addition of
,input information signals and the parametron's capacity for phase discrimination.
Orig. art. has: 5 Tigures, 3 tables, and 9 formulas. [14] i
Card l/.1,

L 009-1(i-60'
IACCESSION NR: AP5014215
~ASSOCIATION: none
i
~SUBMITTED: 10Ju164
INO REF SOV: 003
Card 2/2
ENCL: 00
OTHER: 002
SUB CODE: DP, EC
ATD PRESS: 116417

L -3q9-56--66 0.,IT(d) IJP(c)
AGC NR: AP6027353 SOURCE CODE: UR/0102/66/000/002/0017/0025
AUTHOR: Sobornikov. Yu. P. (Kiev)
ORG: none
TITLE: Arithmeticqperations with integers of arbitrary sign in a system of residual
classes and their circuit realization
SOURCE: Avtomatyka, no. 2, 1966, 17-25
TOPIC TAGS: arithmetic, integer, computer circuit
ABSTRACT: Arithmetic operations with integers of arbitrary sign in a non-
redundant residual class counting system (NRRCCS) are considered; this in-
cludes the operations of microprogrammed division, determination of additive and
multiplicative redundancy for the case where the overall range of the NRRCCS is
partitioned into equal subranges representing positive and negative numbers.
The author proposes the structure of an arithmetic device (AD) consisting of
addition-subtraction and multiplication circuits in NRRCCS, a "conveyer"
circuit for conversion to a combined-base code (CBC) and a comparison circuit
in CBC.' The AD performs the operations of addition, subtraction, multiplication,
microprogrammed division, raising to the n-th power, determination of additive
and multiplicative redundancy, and universal group operation -- all pertaining
to integers of arbitrary sign in NRRCCS; and also conversion to CBC, scaling
.with respect to one or more NRRCCS moduli or to a constant that is relatively
Card 1/~

ACC NN AP6024362 SOURCE CODE: UR/0280/66/000/002/0049/00581,
AUTHOR: Sobornikov, Yub P.
ORG: none
TITLE: Synthesis of combinational iietwoiks realizing arithmetic operations W& oysteni 01f
residual classes.
.2 1966,
SOURCE: AN SSSR. Iziestiya. Tekhniche'skaya kibernetika~ no.
TOPIC TAGS: Boolean algeb 'computer matrix
ra -circuit, circuit design, circuit theory,
element
kBSTRACT: The concept of the output function of adding, subtracting and multiplying networjls:'.~
is introduced. The properties of the diagonal symmetry and repetitiveness of the equivalent
elements of the square m-matrices of these networks are defined and the method of their equi-.
valent transformation to a finite set of Boolean matrices is described. It is shown that the
synthesis of logic networks realizing modulo-m arithmetic operations can be reduced to the
synthesis of a finite set of Boolean combinational networks with a single output term1W and
multiple input terminals. The combinatibnal network itself consists of logic elements realizing
C,,d 1/2

SOBORNIKOVA, I.G.
Effect of irrigation on Ciscaucasian terrace Chernozems of Rostov
Province [with summarv in English]. Pochvodedenie no.2;65-74 F '59.
(MIRA, 12:3)
l.Rostovskiy-na-Denu gosudarstvenny7 universitet.
.(Rostov Province--Irrigation)
(Chernozem soils)
jo u

L 29277-66 --EWP(J)/EWT(m)/T RM
ACC NRs AP6019321 SOURCE CODE: UR/0079/65/035/008/14-60/1463
AUTHOR: Gololobov, Yu. G.; Dmitr Tva, To ~; Zinovfy2v, Yus M.; Soboroyskiy, L. A" f;
ORG none
TITLEs ViWl esters of phosphorus acids. IV. Virql chlorgt sphatesl
SOURCE: Zhurnal obshchey khimii, ve 35, no. 8, 1965, 11160-1463
TOPIC TAGS: phosphate ester, acetaldoliyde, organic synthetic process
ABSTRACT: _1n the reaction of POM with acetaldehyde at 80-1000
in an autoolave at about 2 atm In 2he presence of triethylamine,
vinyl dichlorophosphate(I)or divinyl chlorophosphate (11) formed
depending on the molar ratio of the Initial substances; MeCHO +
+ Et3N`CH2=CH0P(0)Cl2 (1); 21fieCHO + POC13 + 2 Et3N"
JCH - P(O)C1,(II). (I) had been prepared for the first time.
2~00)2
By the reaction of (1) with dimethylamine, vinyl dime6hylamidoonlor
rophosphate (111) was prepared. (I) could be used as a starting
-material for the synthesis of phosphates with two different a.
alkenyl ester groups - e.g., the reaction of (1) with butyraldehyde-
:in the presence of Et.~NVielded vinyl - but6nvl-l chlorophosphate
(IV). Bjv treating-(TITWith aeatylacetone in the presence of
St N# the compound
ZW2
L MCI

L 29277-66
ACC NN, Ap6o19321
MeC(O)CH=C(Me)
EtCH=CHO 0 (V)
CH2WCHO
.was obtained, which Is the first phosphoric acid ester with thrie
.different alpha-alkenyl groups that has ever been prepared. The
reaction of POM with acetone proceeded with greatdr difficulty
ithan that with agetaldehyde; isopropenyl dichlorophosphate
~CH2=CO(Me)-POC12 (VI) formed with a small yield. The new compounds,
'that have been synthesIze6iad the following boiling points: 1,
36-400/30 MM; Ills 60-660/1-0 MM,- IV,-57-610/2.0 mm; V, 96-1ozo/
,~to'3 MM; Vis 69-700/30 MM-/ Orig. aft. has, 3 formulas and 1 table* fjPR-S7'
SUB CODEt, 07 SUEM DATM 16Jul64 4 ORIG-REF: 003
Card 2/2 o

,0 *0 0, ** *0 0*
A L A L --I A- A J__L__L
4! -I
00
09
00
00
00
00"
j
0
00
00 Si
we
0 0 0 00 4 4-0 ov--Gif-4v v w- a
A 14 AI I v IF I T -1 , A.. 1. AA a cc 1 .12 -1 Is
. .1 1 .111 ..
Ovdation of hydrilhalic salits of plamythydraxints in the
Presence M clowr "Its. A,11.111rultirran,
,h it- ,I Gov. Ck,-r. 11.1. s. s.,R.) S. IlUTNITILTS3
f-.Alf t- '. _4 01412
7-" it alkI Ifelsic in". 23. 11). .,I,l4iIjV.j
g'..1 Ir .4 144:1. 1114111 And Pill toy Ow ..%lilathin .4
W 11.1p. by.h.-IsAw %ttfq 14 PhNIINII, (1) Willi I is ... I,. d
11
c.st).. Tr-ti.ix CuCl, in 12% HO in tljV cold, Willi
Niltillig, %Vill nit "JuillIC4. amt. 04 1 F"Ilit'd in a C-topicte
4 the An. %not iptn. .4 .1itw. ct"t.
1.11CLOiCt 011. The traction 6 utnuviv"I a, -, sowlsA
of I Will% 11w I-mosti.its "t Coact whii'll react.
Thk llivisiv 6 millixtittil liv A livativ
%I Is givilig It.
11,44sillell Ily the hilvirsictiml lot CtICI allit
'fight vaiwilim its 111C vlxlljlsl~ 111 11 "I'laitIM ate
A by it, In'tal'ility Is, issfill. ills. Thil" 11 ill IICI at
v%j-%ljv 1'. 41, 'n ad.ln~ .1 CUCI, i~ Capidlyd".."111.1 with
1 li. I~n 111.0, Inst 'All lw ln~f ve.1 [.of llmllkll~ I,v
4-1-11ill to In It, InA.
InIVIIA1111-11 -,( tile 111111olti'MI Of I ill IICI tO I'liCt Will%
all --~N sit Cis" 4AIti C0114i,itj CA IltelittlinAlY (01MAtio'll
.4 11 ,it Itivilarr oxidalimi hAm, I'I%N,Ci All.1 lilt-
Willi Clocl Ks", I'llclamwiling to tile Satuillievef IVA'.
IllAnc
u "
1
MOO
9
Igoe
41111o
t2 0 0
o o 0 0 o o o o o o 0 0 0 0 0 :io 0 0 0
00006006*000000000 1606400

SOBORNSKII, L.
"Chemi6tr-j and Technoloa of Poisonous Plil itary -Substances," Par - 15, B-81482
and Par. six,, B-841216. (A131)
B-84689, 21 Apr 55

Formation of a phosphorus Carbon bond in the co
blood reaction of hydrc)cgfbons, rn-
lool'10411111101-us trichlorido.
and allysion x1 /Ill-Wev. '411.1
M A, Iiiijorbis, S " A.M, 07. ~Ul
--j R44JI1-111 file olllph Iv ali'villo. "1 0. Pcl, thwi, flat
rr-ct (.lilt 4 A C - I- I"",J) ,Ill
I'llaffill.,
I-Irffim,. i,r their iwlllw 4MI 4110-
Ill, %be Imwe'. 1, 1111.411"1"1 fly irrailicits... (lift lAmpi.
Sifullarly the ,,, $-I Ir-I wo tto 1, 1
In I be lwvwnm at t h- a1_11ce of Oc I rif live
131 11A
.4 11cl, mid 0 wl tilt. Ilvd-ml.m. %tdd-
RI'00, atid NICI, (A, %ell -%it IICII With I`iIr-itr1II-- while
olffin, ttfiilVrg,, add,... vi'Ming
dichkoridv~ awl POCI~~ The rt-ji-Imil I, bw lime'l I-
r Rif ~- 0! RPOCI- * POCI, ' IICI, .,",I
"PCI,
RCII.Cil. + 2m), () . Rc,.If,cll,(ICI' - pficit.
re,j). smer I fir par.aliti, trc -alit t;illv %immilelittl tivil
'1111.1 fill tem-II'm I, I.wK.Mv Ititt'st-f
P0, mi-Imi.m. 'I ..... ItV-.- I, i, Oh
fit, 1.,41-1
Im"A Ilm"1111, I platv -Ih
.1114,111 Irml, It,%- 1., 411 70 ; K-mi, hvd-
p.-A 'imoll(.Imml ,Iv. fifth (I mto IVI I?w., A Ill.
mmt, K.%%,- A5 10" Vold, if 1, N
Imt.01114 III-l ...44 "'. Ih, IIV.11- .."IV
,IV I-I Vivid I he b4h-.'r ., 1,
J:-, And NJ* m1wil, fv,p~l~ Iw-
I. 1., ?4 L'.401, I lfwwf. C.11"I'01,1Z (from tw"
if 10111, CM.P04 -010
ji-AvIt".
off"J".1
snr~. b, to :I',) IW, ; (WIF.J'(FO, k,t
IhW S". 1. 11v,2, I AX;V; (*.11,vjo0! I
~,elk v/pv-NM;vr?dqSI L".1 13'.h$j Or//.
(Imm C-11.1. IV, "j;-5 7 41 1 M IG. I pt!ts, c,ff.cirr.,-
Of 11111911 C,11.1. b. 1C. 7, . I Ilit.5. I liki(f.
thOlit ll~kkj,
ii(rom tor(Atict t.;(Ild row I.- tric-I It ... it I-11,11t,
vleneFVt)lYI?Irf,).1,,7S -At', -,-. ,;imil..fIy.cIcII:cIICj
:11111 C)ICI, give I'm vitihiii If the P detiv.
Noiiilw, Nt,CN MeN( I. wavt,ii ami I-ih 4 th.-m Tmtif,t
.m.laff"If It 110, ti. 11twi.. 1-1 thrr J.- '-f pto--w ?h.
KmA I"'cli'm .4 $111- A.-
Vill. J- I-t N. It"l,
IWtillvill if Our tol.irtril I,v- C1.4irt."I :,,fit 1-1~11 IC .1
43. 131W). Stirfortie mid w1mic drtiv~. me 1P.Mly .-fill-

S
~Ld- Vo Xt and NI, A. I iighn. livkh1dy
S -%..% A.' 73. :;:;.1 lit 19.*All ; cf. C-1 . 44, 1 lott.
AliPILIt"' 0111-fid- -o t vith PCI. and 0 an~h,jcvu,,Iy t,,
tilt- Ily'llot-'al.m. and 110
11 Cite c'utell-loling Ith'.101milirl
'v, luixt4. It [Ile jxm~ilde i'murr'.
lFactill"all-11 'If file Ilro,lucts fruin DuCl yjcI,jcj Lail
4 1w,-Olle i-no. I
olole If t"Tal I'll. " ditrilklition, expressed as toole'l
howli in lNtrcnlllc-w3;
110-13' d" 1 395"
Ill.'S. J.,
1010; (ji'llt Ill It 7,11"
Ol 111 .1:, 1 1 Is"wit I It-- 11"ll-I
6m, 4", V1.1.1 1-loct ... lkt,. And (Ile olubilily .,I tile I-
I'l-n-vtI It muill, L, deducible from tile vicl,6 of the cut-
re'l-oldins i ... tilerie I'll, I,1.110110 dichlorides; in stinlic,
it "., '1"', 11 0-1. tile P-C link is most
f.,joled.'t ti,ele"i-try C a t oul. follo-ed by secondary
'"d le"'t " `111" 11 1 Ile PT i'll-41 v C AtIll, - Tile following
el .1"t'llon ...... f.mod.
C.11, rav, Air,.
1.*_'Jl',~.J. J: 1.174,611.
Ili,* 1.46311: 1
7.1; Saw'. ol. I All,l
of "'el""Alion 010031,110 -organic cornpottrids by a reaction
Posphotus tFichlotide and oxygen with h)
an th-ir balotion degilativelt and with the rilrocartions
Z.
ts.
I I t 1, 1 1 It r I
I, ed by Iq .1. .tv,h lu.1 f, 1. . 1- 1. 1
MvIcl 11, t.,t% C 111.11 IN Aff, CH 'I I'l h 1. 1 Met. N h I -, 1 #1
d' * 1. ISIV, nV 1. 17'_114. aud OAK! Jfrj CHCH -Ile 0/,P( it I.,
tions With the
th S.Y-7'. 11.1 1.17,96, mi: 1.17,20. Real'
c Illot it Iv, " -it tile f - yields 1,eing
ividt oit-mill,l pfe.luct, ( lit
th- 4 ulilt,. t-li'le i-nict's: (toul IC111CD1.
.1 1(7,. Ill 70 ;."; ftmo FtCl. A I";
( )(7,. Ili 65 75 V, CL -*-. :11
ill 65-Ohl"; In'to Xle'ClIcl. C'11,C11-ilk-l" I., -J)
I
P.1% fruln But'] 17.2"; C.11.17i'lich. 1" .10, )'-'W; Itoul
Nlc,CIICIISCI. I., "it lilt)*, 'Ntelccl
K.'ve It, 73 '; MeJOW.Cilict Kave
4:1 "q (*.J/,,t,'jl,Oc'/,. 1), 1 ;it 7W. Tile miction -ill% ether-
6 ;n~;c complex and re.1clium, with I;I,0 And U140 KANT
lylm-4 of pro,luvi,: dichlmi&4
ItOll 1111,0 ton- Itucl waq
11"'ll";1liclau'l PCI.(3umI-1
ii~,- It 1:1 lloill'tIt'l. old W-' u-I.,
ju-lu~l -fih-
t Ile 1,,lmv t'. 1'.u.4
PCVhYOorair; the i, imt, km A
this little), alipmently bv a-idn. of 0 to fortil A high?%- lctiv,
pcrO%idc-lyj,C Ill.tving frer ta.lie'll pr.1-Ttiv, .1ad
o-I,
fell 9)mof P 411,10"'NAl u.!
1.111) lival.. rr.p.; t
-4 ) - - I hi, pro,lo.-I re'o-ling .1111 Pct. vie!'l, II()CI. 41 IK
117 kcal.). Ili ttic pre~etlcc of I-dow.0-- ~,,, dm_
the radictil reacts with the Litter, rielding ne- radival

vallach yield %ell 11-11% U I I( ok~ I,,,, Vmmus ratille-Al fc-tiott~,
-mv "t " laida + R I I - vocl, + ii + 611
_'1 Ila A I PCI, i R fiaw.r,t toy RI-Cl, +
m.1 (UP0,111 RITI, I tic[-
I
It 1*1 WI, . 1" .4
kPIA,la I I ha .kIk A it." kalwil I, mIjFjkCtVd I.,
C."IV Ims'. I-VrII ~.t W'. Ilk' If
RCI III i,.ta:tka- ,I jib PC4411.1
(I Ahs~ 1,10,06 a~ 'h'al'tt toy ~ I "'it Roll. RMI +
14K'I~ - R110it 1~ , llk~l. RohWI, IICI, - HC1 I-
110POCII) . t tha t-I.,tk.jk ,I I" Ijj,L*j ,,,I i, .11111,001
frnut I Iw iv.., I t,-ta , 111, 1- t,lilc i to toy -Ic,je!jjCv
4 Ow Rif I-v $11 1" 'Ith", N14 and Mr,clicifoll
1, md %I~ act III I III
twilill"I nk,l. .1 .,1" ludalcd It"Ill tile rc"Cli"ll; e.g.,
MePh Ylvid. C"11". b. I., "4h..,4 lim fierix at - mr.
Ill,llcjtlllg f,.,111 C,11,. to( R1114KA,
111 lravtlllla~ If "Iwl~ I~ mat C..tled toy Collar 'Ic.,vage its"Irr
tile CMI'Iilillk~ A' IlCithet %.11 the RIO IjWd 111111deoi
bylIV-dilitt-0 1701 With POCI,Ut PCII 711117~. ill-Alk-Ituloov,
mar Iiot airy I ICI p~-ctl into tile ether as itaorn temp. *I br-
imise miy chaftFv. The evacti(in may Im expt4invi by:-
Ittil)IIII )it lot'sIll 1 11110: ItISO f lil"(1
lialtill -,kl, VVIIII NK1. TIVI'l ... g
WhIlt. Illa- t."ll'A .3, 1,01-tv,11 a-mliot
vu-bit"g III, ph-ph"Ilvi 1,10: a thj~ I;j,Isa-A III.,v A-
m- lov: cl.~ (1 4" 1- 11,1,4) - Nocl, j- of -I
Itilt ICJ I.. The pi,.liki- fr ... I. Ft,O w Hulot
I., 7h
ss 111'. 1:, 1.'_"Sll~
nja` 1-131A, boom
he pr,.hact, b,, 53 4 % W." mi.*
A".d:* L~111,69 " V 1.1460~
C., %I. kaw-Lij.,If

Oboffav(skl*( 2.2_
Y'j
US-5-R/Chemistry - Reaction nroccssps
Gard 1/1 Pub. 151 - 37/38
Authors Zinovyev, Yu. M.; M,uler, L, I.; and Soborovskiy, L. Z.
Title Synthesis of organo-nhosphorus comnounds from hydrocarbons and their deriva-
tives. Part 3, Reaction of acetylene hydrocarbons with phosphorus trichlo-
ride rand oxypen
Periodical : Zhur. ob. khim. 21~/2, 380-385, Feb 1954
Abstract t The reaction of formation of oraano-r)hosnhorus compounds, which takes place
during the reaction between acetylene hydrocarbons and their derivatives and
phosphorus trichloride and oxygen, is described. The products obtained from
such reaction, their structure and -irorp_rties are listed. The effect of the
ox-jgen on the reaction process is explained. Nine references: 4-MA; 3-USSH
and 2-German (1932-1951). Tables.
Institution : ...
Submitted July 29, 1953
:- B - 7L7 7 4-, 7 44,

USSR/Chezrdl; Synthesis
Card 1/1 Pub. 151 - 24/37
Authors Soborovskiy, L. Z., and Zinovyev, Yu, M,
Title ~tffe-sis Wf--oFja~o--phosphorus compounds from hydrocarbons and their
derivatives. Part 4.-Formation of dialkylphosphinic acid derivatives from
alkyldichlarophosphines, hydrocarbons and oxygen
Periodical Zhur. ob. khim. 24/3, 516-519, Mar 1954
Abstract
Institution
The formation of a 0 - P boiid during the reaction of aliphatic hydro-
carbons or their chloro-derivativeo, with oxygen and alkyldichlorophos-
phines, was establishied.=-parimentally. The synthesis of secondary (mixed)
diallcylphosphinic acid chlorides is described, The reaction between
methyl- or ethyldichlorophosphines and propane, cyclohexane and allyl
chloride i-ras investiLmted and the products obtained are listed. Seven
references: 3-USSR; 2-U3A and 2-German (1880-1954)- Table.
Submitted July 29, 1953

ZINOVIYEV, Yu.M.; SOBUROVSKrY, L.Z.
Synthesis of arganophosphoric compunds form hydrocarbons and their
derivatives. Pitrt 6. Oxidizing chlorophosphinntion of cyclohemane and
propylene by phenyldichlbrop~osphine. Zhur.ob.khim.26 no-11:3030-3032
N '56. t; (~tw 10: 1)
(Propylene) ( yelohexane) (Phosphine)

"Oxidative ChlorophoWhowtion of Chlorine Substituted Ole-
fins," by L. Z. Soborovskiy, Yu. M. Zinoviyev, and L. I.
Muler, DokTa_d_y_A_9_de_m__r1_Na_U L_59R_--V~ Jul 36,
9~,Ko 1,
Oxidative chlorophosphonation is defined as the reaction between hy-
drocarbons (or their derivatives), oxygen, and phosphorous trichloride
(or products where part of the chlorine is substituted by organic groups,
e.g., PC12R or PClR2). In the case of vinyl chloride, this reaction was
found to proceed in two different directions:
CHC12CH2POC12 (30-35%)
CH2 =CH Cl 2 Pcl3-t-02 + POC13
CH2C'CHC'M'2 (65-70%)
The yield of the reaction product in the oxidative chlorophosphonation
of allyl chloride was too low to say for sure that the reaction proceeded
in one direction only. (U)

T tr
Rl. is Ileitted- in a-
2,r 1957. Ain xt- a. by the,
Iroducts are Set),
toclave at 100-10a inii that
j
~
(til
ee
S
-RS
4P

_25, 0 A
- - - - - - - - - -
Tp-
V-1 N.
.02
.7 PK
I
PCI, hi 3W ird. C;Ht at 20 f 0 b. of.
I~rt the prodzk~~ two wack-mbk d iel
3 CGIV
POC4; ti6atment d the - a HC) left
rammly p
X. P axfd I k.
hind but I Z. CHiCICHC4. , Read
CHvtC Un autodave 12 hrs.'a
vei 31 % CRC6
RC
C"Sa and 33.6% (Cm2CIjrCqTf)* (I i tha 200". d2o
1.4477. aV 1.4995. Heating 3-5 C. Cff2-CHCVand 62 g-.:
15'hm. at 1100 P%re 18% CHC4-
50t.Cla in an autoclave
CUtC]. Tseatmegt d 20 gj with 13 c. KOH in MOR in 2
(H), bot 54_50.436~
mieZ;;.. took Place- wheit, Cat-C
1.3630i 1.490. No, r,
CffjCl und. PCIG iiem ftirred in, CHt 12 firs 'at'rooin t=p. -
M g;_ HU in id aat()-.
ting 16.3-C.-CU -CHCHICI aA4
_l20--20`gav_-54.1 k. pmduc f
cla, 14 hrs~ at ts Coni-which
ve
t44 . . . . - - - ::, r~:. z L~~
a sed" of fractions ba to 130!; from these wa~.
Was S04
-e bi 94-jC4!.-,dw-
isolated s
1 4m, 10,2 1.6136. Heating PCI, "'ith cffi-cc~ a hrS. ixt,
11~5' gave Un"acted FC4 and viaylideve chtaride
polynter..
Passage of. CtHs: through . PCIj suspcaded ln.C4H4 until no
CN rred gwre after eirapa.. of* the %otveA
146 g. emcle, &IeCHClCH;E'c4' Which witi,heated, ill (L
darkiai. ~ The, liquid potlibn was shown'to be maijily.,T
C
_aud,ClCfItCHCMTe along with some
Aexarc, b, 80% d-o- I.SS29, ul? t-5233.' The formation of
chloma!Lwnes of double the chair. langth bf 41itw orefing is
explainable by initW foinlation of the I _11-acMud, of
PC14 at the tilefinic bowl, followed by-dCL - CIE tile a4-7
dUct to the of 4ouble chain leagil., aloug
tea" U CI e-
With VC4 dad Kit, with a CumPefing
'dirwly to-A dcriv. and to
Coartmilig the p A tuie
ghown,

s - - - - - - --------------- ----

Z=fl=
-
-
i1 sifd L. Z. ov6rA
N
v
RAIII-MIN.
4

-dl
d b
i
h i
i
ii
C
j W
owe
c
coo
w
t
HsO n
Jo 34.711. FCH3
y
s b#
co
90 L, F
av 7
ted ROH
!

Distrz 4E3d/"4j/ .
o
unrcu
g
g
0
Ibl
i

4E20(j) e. two
189-71
70
, d= 1.1116, nV IAO It was
rup
Na ft~lcoholW~a of FOH
CHICH
late th4t
G
M
.
.
-
.

AY-HORS: A. Ya. L. Z. 11uler, L. 1. , Flaye-ruar-!,:,
V. S.
12 IT" L E S.vntheses of Vinylidonomers. 1. U,-Substtitutad Derivativc-o ol' Vill.yl-
phoophinic Acid (Sintezy vinilovylkh imono~3erov. 1. r/--za~:c;21-.,cNennyye
proizvodn~;ye vinilfosf-ino%,oy 1-i0laty)
PERIODICAL: Zhurnal Obs'.'.Clleir Khii,iii 1055 Vol. 23, N2 2, ,op. 317-31~) (USSR)

ABSYRACT: Of t1ie derivatives t'le
acio, (reference 1), the dietilylether of d--car'jo;~~cttiox-jvinylphos-
phinic acid reference 2 and the diethylet,-,er of cy-Movinylphos-
~
-,)hinic acid
refcrcnce 3~ are. lmoirn. The unthors -.it'i-asized come
11--rivativcs ulnalo,--ous to the aloov--t-,:.untiored c(-:,I~Culndts b.." the -ucth-
od of phosphinoxidation. In the oxidati on of th4~ .:'-fxture of uc-thyl
acrYlate and phos,-bovuu trichloride bj means oZ oxy'~~cn the chlorine
anTh,,dride of acid for%i- The at-
t--,.v)ts to ~roOuce -an a:i~,Jo' --ous c '1or4rio-.vbstitutc,.1 -!,~rIvative of
vinylp'.-iosphinic acij, w'-.ich was not describeC in pizblicutons, ac-
cordin~; to the iaetl-~od by Puciiovik (refercnce 6) fro-! -,inylidene chlo-
ride and dialkylphos.-,)hite fdiled. Ctiloiocyano~~tiyi-niio~,.,-,~!iy:e ~eri-
vatives 'b"), wliosc d chydrocialori na ti oil the cou-,pcur~z of c.-Tanovinyl-
Card 112 p"'Loophine c,ui be obtained were s..,othesized bj of pbou.-phinoxi-

T) - 2) - -) / ~- ",
SYrthescs of Vinyl-,.iono:~,crs. I . cC-Sm?)Stituted Deri-mtives of Vji-,Jyll~hos:~hinic A,-id
6,-~tion of v-i,,.,-rl oyanide. The liquild isouer under thc- influence of
tric thyl,-;:iinea eu oild" oc parate s the hydro:ran-cliloride L lemcn ts and
foraj tu~,-ie di:.'c',hylejter of cyanovinyl.-hlosphinlc acid; tt`lz Iosition
of tne cyano-en -roup has not yet been determined fo-o this -o-..,-
pound. The attempts of syntzlenizin.;-- the
` , h
dcrivatives by addi--~tion of phoso orus pentaclaloride to vinyl cy-
anide did not yic.:ld any po-3itive results. Thqchlorinlution of Vcrylo-
nitr7,1 wit':, the formation of dinliloropropion tryl can even be ob-
served at 200C). Thai di;:ieth
-:1c~her of vinylpho~.,jhinic acid,
.
not dz=ibed c-ari-Jer, syn"urvesized. accordin.-- to Lhe ust~~,-l --lethod.
'2ht3 et.crs o:-' t'~i~ o!IbSti-tuted vinylpho~~phinic -acid forn! polymers
-ith oth~-r vJn-7,i.ionomers. Summary. 1) By :~hosphin-
and cL J~
oxid,-tion of me t hylacr,, late and acrylonitryl, chlorine ar,7111,id ride s
of the corie:j)ondin-~~, chlorocarbomethcxy- and clyanochloro---~ubstituted
cthylphosphinic acids were obtained. On treatment 0-L-' the latter
thQ-ir ether was obtained. 2) By Jeh.,,,drochlorination o~' t1hL above-
-Lujntionud ethers the cyanogen chloride and carbon chloride i.~ieth-
ra.,~y-culj.2ti tit ted ethers of vinylphosphinic acids -were synthesized.
*2here are ,") rdferences, 4 of which are Slavic.
SUBUIT-IED-z April 25, 1957
AVAILABLE: Library of Con.-ress
Card 212

S f) b C, IQ V

A 11 I'l 10 li S Bri, i3 A. B.

In 1, .3 tl:;
, ReW, i ZIE lila'
in t:~ of Alu_iini~.i

t5ji
~-.ltrekhldiloristym I'llo

PERIODI'J'! L: Z" 1 C'') i 1 1, 5 ~2 , V k) 1 . 2,, 2 0 US 3R
.1 B O"T R. tW'T In r-_~ n io r;: c tl~, t !I o rs r v,~, Z -tu r,_- c 0~1 uf tri -
r s,-; n i c i tq t rafl u o ro c
c, L~n~ un- t-,zrl tA cow oi~r ]z j Gn-I rr .-.`4~;ated
0, ro;-'ion
- _.: I -
in
D. i.3 R_-.1.3'!ou, Uor
- . ru j v L3z~vration of tri-
L s, -~!L
n
t',,e Of
c- ,loride, un,,',,ar ut,au~sijhi2ric prL:Li.~,ure and _t .n
tl:~,~ for,~,,_,Ljon of ~2.i_-ll Aeld
s j c z, aittllors GrJ* jnall,, tvi~l "o pci-for.-A intt~_-rac4di on
L,, _L Y -
b i t % v c c n f I t -, o r a z c z a i -, -1 t 4. c'- 11 o r c s c n L,. i C- r c o n (I i t i o n 3
in -.-Tit'A et',iylcr-_,
t ivk2 - J u a n t iv .3 roa t h e a t t c-,.i -k~t s ul I i c_'I wc! r e rf Orla~~ d in
Card 1/4 -in autccl_-~ve_ biult-, Wit".011t &Iorida. Upon

-/6 !
7
__Cnic in the
,j-
T.V, j
o-' latrafi!oro-th~~lEn~~ With Tric:iloroa-
Preo--mce of 1 n u Ch 1 c _- I de
c I o 2 c. r Df -this re;_iction it -,.,-ts found t".,lal. in the irter-
ac ti on batwee-, tr-c';1crourzeric an-l in the pre-
z~,,mcc of almjihu~n c.Jk~Adc l SLC~i'~~tLVICC ij DroOucud wli.,icli contains
i t c, r 1 n,_, , C 'a .0. r 111 C C, "I r r i c . :211 i_ ~3 2 -t i b a t cc wa-,, i d a n t i -
~icd t 1, 1 i 01 c :, t (, it n',-n o w - ~ ~: n t nf I L; o ro p tl ty 1 d i el 11 o ron r:.-- i n u . Be s i d e
ic _..,,ot~,or 4:iz !!liii~natod Cvo!.i tli,,~ r,~!action ahich
dcscldbed in rub-
lic-,tions (r_,fcr~.nc(~ 10). '21iie cli,!urut-ical of .,!-t.:ifluovCethyl-
tc th~_ tric*i1orours--mic rt~ ctid t",row,h
usc!d in t h c
0 accardin, tc th, t~ztrafluoroethylciiie
,..,Cj;,ntj to 70
v(.,._,cLion to ")(11-60
-CI -2
+ 2ASCl..
2 3 )A- 2 + C 2 = Ccl 2
a re
~w-i_ticn of ac a r-3ult
,.Ctlon 0 '!1,- L
inj_`-~at,~d th:a dliffcrorcc of this nrocess fro-,,i the usu-
:11 redaction in v1iic'-4 tric'hlo2o,:ir_-2en_ic is Lidded to unZaturatod co:.i-
-,ound s. '2hc: 1 t i ^_ n f o r i 1 i e c i r. tbc ca o7 aliminum
~jl to- h f lr or~ nz~-. d or 4 c by-
.:, ,-[i L
Ulc! dularin.~ t. L - I.J
~lrcc~.a.-~)ons ainot flitorinz! (rcf;_-rellces 11-15). It sca-Ina probabl-e
Card 2/4 'L!, t in L`i,: observed caa~~ ~_t fir' -,,;l i~xchan-a cir loallides ll)~A%Teen

Inv~~ s t tion o -,' 'hc- Re action o 2 T'ctraf 1* uori.)c t",-..y lcm~ 11-2, t:.. Tric:,411,.-,~.-C, ic in the
PrcsencL of Alu.-ainvm C',)lcj.-itR!
tctrdfluoructh,~lun.s and aluminuii c~;lcride L-,1--to id-cc
cy, + Alcl Alp Cl 4- CY, = CC!
2 2
.s o-' thin i-ia, ~ju con:!idercd -ic f,-ct -fiat in all
L
ti~,J-30 tustj wit'), di-
a--s s,--p,:~rated in a ratio to
h a t in .-~ qu a
t t ion Lz r t hic r -he f oU on o~ p,~ n v o ro c t hyl d i -
c:i1oroLrsinc --nd alinninun f luorodichlori des ryl.,,Ic:r irtlt~raction of
tetrafluoroc;t~,,--rl,~r~a .-iith trichlorcarscnic an6 aluuinuij difluoro-
chlor4de t-,4!~ej -,~lacc,
AM
Cr, C-2,AsIC1, + AlFC1 (3)
2 + Ascl
CF = CF,. + AIF, 3 3 2
rejultin aliu.-iinum fluorudic:iloriCe
may also ~:nt-~r Zan inter-
ucLiori with tetr~.fluoru~~thylcne and u.-ain forim alu--iintim difluoro-
C:.lori-d a .
CF 2 = CF, + 2AlFCl 2 C F2 =Ccl 2 + 2AlF 2 cl (4)
2'i, :3c,,L~nes -,iven Jufficic--ntly .chow that comDuratively cz,-mill aiounts
of alunimum are z3u--P.-"ic-ient for conv,-rtin;,, conSiderable
c--* to i.,,e-itafluoroet'~lylez)edic'-,loroarsine
Card -,nl~ ji-fluorodichlorout'ier ~---ble). 6tuxiary: 1) T.ie ~,,vthors

I _,, tion o" t1m, F-action o' aitli in the
Inv- t i -a
Presence of -.11u,inti-I Cl~-',Gride
rcaizi~j 6~.,o reaction of tetralLli-,oroc,Ul.!,;!cne with turi-c'.11oruart-i-enic
4n thl- prc-ercc of uluminuia c-,loride at elevated tcr,i-.ocratureo and
un,-~er pre3-jurc. '21ic, c-~~Vrej-~Qld their opinion on th-:
y
proe,.-o-l. --,lh~~ --ntjfjj,,orok~l"jyjd4 ciiloroarsine -,Ct ~,OjCr4 bad
was z(-~_parated -s tmin -roducti. -1) Pc:itafluoroet'.q~,ldifluoroarsine,
and pentftflUOrOethylarsenic ucid hitherto
icre produced ~-Lnd characterized.
not discri1jud in -,-.ublicationo
~,re I tz-L le, and 16 references, 1 of which is Slavic.
SUBHITTED: Febrikary 2, l(,:57
AVAILIBLE: Libr,-,r,-~r of Congzes;:!
Card 4/4

AUTHORS: Zinov'yev, Yu. M., Kulakova-, V. 11., 30';/ 79-26-6-25/63
SoborovGkiy, L. Z.
TITLE: __Di~eyn~esis ~of 6r.anophosphorus Compounds of Hydrocarbons and
Their Derivmtives (Sintez fosfororganicheskikh soyedineniy iz
uglevodorodov i ikh proizvodnykh) VII. Oxidizing Chlorophosphi-
nation With Alkoxy- and Dialkylamidadichlorophosphines (VII.
Okislitellnoye khlorfoofinirovaniye alkoksi-i dialkilamidodi-
khlorfosfinami)
PERIODICAL: Zhurnal obshchey khimii, 1958, Vol. 28, Nr 6,
pp. 1551 - 1554 (USSR)
ABSTRACT: Contrary to the method (Ref 1) employed in an earlier paper by
the authors they now prove that alkoxydichlorophosphines and
dialkylamidodichlorophosphines can be used as phosphination
agents, i.e. compounds in which the hydrocarbon radical is com-
bined with the phosphorus by means of a third element:
RH+2R'XPC12+0 2 RP(O)(XRI)Cl+RIXP(O)Ci 2+HC1, where R and R1
are hydrocarbon radicals and where X is equal to 0 or to N. By
means of the mentioned reagents the oxidizing chlorophosphination
Card 1/~ of cyclohexane with ethoxydichlorophosphine and vinylchloride

The Synthesis of Organophosphorus Compounds of joy/79-28-6-25/63
Hydrocarbons and Their Derivatives. VII. Oxidizing Chlorophosphination With
Alkoxy- and Dialkylamidodichlorophosphines
with methoxydichlorophosphine and dimethylamidodichlorophosphine
was carried out. The corresponding chlorine anhydrides containing
a phosphorushydrocarbon bond were separated as final products.
The chlorophosphination of cyclohexane with ethoxydichlorophosphine
lead to a mixture of compounds the separation of which by
fractionation was difficult. In order to prove that this reaction
actually takes place according to the above mentioned scheme the
mass obtained was hydrolized and the cyclohexanephosphinic acid
was separated from the products of hydrolyBis. Also with the
compounds of the ethylene series oxidizing chlorophosphination
with alkoxydichlorophosphines takes place in a manner similar to
the reaction carried out with phosphorus trichloride; the vinyl
chloride was used for this purpose. The chlorine anhydride and
the ethyl ester of dimethylamidodichloroethanephosphinic acid,
the dimethyl ester of dichloroethanephosphinic acid and the methyl
ester of dichloroethanechloronhosphinic acid were synthetized.
There are 3 references, which are Soviet.
SUBMITTED: May 12, 1957
Card 2/'3"

3OV/ 79-28-6-45/63
ine Synthesis of Orgaqophosphorua Compoarzkd,,3 F,7-m flydr,),~arbons and Their
Derivatives, VIII. The Investigation of Ox-ldation of Phcoph~;ruatrichlcride
With Oxygen
ary4. -, and alkyl radicala, alk~,xy.,-, dialkylamine- and other
Mor-ovalent orcvxi,~ groups) w-.",.h a sj.n~;Ie passaSe of gaseous
oxygen or air can be by meanr, of the mentioned re--
agents, Earlier the assumption was roade that "he oxidation
chlorophosphination. as well. as the oxidation of phosphorus
trichloride have radi~:al chara,3~-,r. A--cording to this assump-
tion in the oxidatlori of phospharkis trichloride first the
binding cf ox)gen to this substa:n!le takes place. The formed
compound can be either regarded aE birad-iial (C1 POO) or as
---> Ci
biDolar ion (C1
~08)-Pcl
+ 0
POO. This adduct
2
3
3
3
conv,;~rts immediately with a -,et~rjnd moleQuie PC1 and forms
phosphoroxychlorid-.- Cl POO + PC! -),-2POCI . hen a hydro-
'

~Von mixt,,J-e it can be
ca--rbaa (RH) is art. 3n the e
p:1,s
included. in the rea,-Aioxt. The biradical Cl POO forms the
organic radical R* and the radical OH:Cl,A6 + RH -->Pocl +
j 3
-
R'+ OH on the occasion of the collisio-i with the molecule
RH. Either of these radicalq can lead to the formation of
the chlorine anhydride's of the c;~rr-:~sponding alkanephosphinic
Card 2/3 acids. The initial stage of the oxidation, of phosphorus tri-

SOV/79-28-6-45/63
The Synthesis of Organophosphorus Compounds Prom Hydrocarbons and Their
Derivatives. VIII. The Investigation of Oxidation of Phosphorustrichloride
With Oxygen
SUBMITTED:
chloride with oxygen is a heterogeneous process dependent
on the velocity of solution of the oxygen. The oxidation
velocity of phosphorus trichloride with gaseous oxygen does
in no case depend on the temperature. The activation energy
of this oxidation is very small which fact points to the
assumed free-radical character of this process. There are
4 figures and 11 references, lo of which are Soviet.
May 29, 1957
1. Phosphorus chlorides--Oxidation
Card 3/3

SOV/79-28-7-30/64
AUTHORS: Soborovskiy, L. Z. Gladshteyn, B. M., Kiseleva, M. I.,
TITLE: Investigation in the Series of Organosulfur Compounds
(Issledovaniye v ryadu organicheskikh soyedineniy sery)
I. The Synthesis of the Pluoranhydrides of Alkanesulfo Acids
and Their Halogen Derivatives (I.Sintez ftorangidridov al-
kansullfokislot i ikh galoidoproizvodnykh)
PERIODICAL: Zhurnal obshchey khimii, 1958, Vol. 28, Nr 7, Pr. 1866-1870
(USSR)
ABSTRACT: The fluoranhydrides of aliphatic sulfo acids are little in-
vestigated. Some of them are of practical value, as, for
instance, methane sulfofluoride which is an effective in-
secticide. In the present paper the authors realized the
synthesis of some alkane sulfofluorides and their halogen
derivatives (comprising some not yet described in publica-
tions); they do so according to the general scheme
RF, Zn-F2
Card 1 RSO2C1 RSO2F. The synthesis of the first member,

SOV/79-28-7-30/64
Investigation in the Series of Organosulfur Compounds. 1. The Synthesis of
the Fluoranhydrides of Alkanesulfo Acids an ITheir Halogen Derivatives
of methane sulfofluoride, according to the method by Davis,
Dick (Devis, Dik) cannot be carried out. The authors suc-
ceeded in obtaining in good yield methane sulfofluoride
from methane sulfochloride by the action of potassium fluoride
on it; the fluoride could be distilled off by means of steam
without any admixtures. The same way the authoissynthesized
the hitherto unknown n, and isopropane sulfofluorides, as
well as the iodomethane sulfofluoride which could not be ob-
tained according to the method by Davis. Thus the authors,
synthesized the hitherto unknown fluoranhydrides n-propane-,
isopropane-, iodomethane, P-fluorethane-, P-chlorethane-;
0-bromethane-, P-nitroethane- and P,P-dichlorethane'sulfo
acids. It was shown that the heating of the methane-, n.-pro-
pane-, isopropane- and iodomethane sulfochlorides with a
saturated solution of potassium fluoride and with uninter-
rupted distillation of the forming sulfofluoride by means
of steam represents a convenient preparatiftmethod for the
synthesis of the above mentioned compounds. There are 14
~Iard 2/1 references, 6 of which are Soviet.
71~ S_

SO V/79 -28- 7- 51 1 /64
AUTHORS: S borovqkiy,,~,,.4_:Z., Gladshteyn, 3. K., Chernetskiy, V.
Kiseleva, M. 1.
TITLF: Inveotigatioyt~in the Series of Organic SuYur Compoiindo
(Insledovaniya v ryadu organicheskikh soyedineniy gery)
II. The Synthesis of the Fluoranhydrides of Alkenepulfo ?..cid!i
and Their Halogen Derivatives (II. Sintez ftorangidridov
alkensullfokislot i ikh gcloidoproizvodnyI:h)
011, Vol. 28, Nr 7, Pf. 1870-1873
I~IRIODICAL: Zhurnal obshchey khimii, 1958,
(USSR)
ABSTRACT: Continuing the previous paper (Ref 1) on the effect of po-
tassium fluoride on some alknne sulfochloridezi under the
convenient preparative production of alkane- end halogen-
alkane sulfofluorides the authors carried out tl--- investi-
gation of the reaction of potassium fluoride with halogen
substituted ethanesulfochlorides; it was found 'that besides
the substitution of the chlorine anhydride by fluorine an-
other dehydration and dehalogenation takes place with un--
Card 1/3 saturated sulfo chlorides being obtained as final producto

SOV/79-26-7-311 /64
Inveztigatiom in the Series of Organic Sulfur Compounds. II. The Synthenis
of the Fluoranhydrides of Alkenesulfo Acids and Their Halogen Derivatives
(see scheme 1). The property of potassium fluoride to cleave
off the hydrogen halide from two adjacent carbon atoms made
-it possible to realize the direct transition from the halogen
derivatives of alkane sulfochloride to the sulfo fluorides
of the unsaturated series in one stage in good yields. Hither-
to only one such representative has been known, the vinyl
sulfofluoride (Ref 3). This reaction was used for the synthesis
of the fluoranhydrides of the unsaturated aliphatic sulfo
acids and their halogen derivatives, the constants of which
are given in table 1. The halogenalkane sulfochlorides (as
given in scheme 2) served.as initial products for the syn-
thesis of the.sulfofluorides of the unsaturated type and
their halogen derivatives, although the yield of the obtained
P-chlorethane stilfochloride--was small. Concluding it may
be said that the vinyl sulfofluoride and the 0-chlorovinyl
sulfofluoride (in two stereoisomeric forms) were synthezized
in the way described. Ther6---are 11 references, 4 of which
Ca.-d 2/3 are Soviet.

GLADSHTNYti, B.H.;CHERMETSKIY, V.N.;KISEMVA. M.I.;SUBOROVSKIY, L.Z.
I
Sulfur organic compounds. Part 3: Properties of haloalkene, alkene
and haloalkenesulfofluorides. Zhur. ob. khim. 28 no. 8:2107-2111
Ag '58. (KIRA 11:10)
(Sulfur organic compounds)

BRUKER, A.B.; FlUENIM', R.I.; SOBOROVSKIY, L.Z. --
Preparation of esters of fluoantimonic and fluotitanic acids by
reacting antimony trifluoride with complete esters of these acids.
Zhur.ob.khim. 28 no.9:2413-2416 S '58. (MIRA 11:11)
(Titanic acids) (Antimony fluorides)

GLADSHTEIN, B.M.; KULYULIN, I.P.; SOBOROV,9KIY, L.Z.
Sulfur or,-,anic compounds. Fort 4: Synthesis of chloroethane-
chlorosulfonate. Zlrar.ob.kMm.. 28 no.9:2417.;2419 S 158.
(Chlorosulfonates) (MIRA 11:11)

;AUTHORS: Zinov'yev, Ya. M., Soborovskiy, L_ Z. SOV/79-29-2-55/71
TITLE: Synthesis of Phospho-organic Compounds From Hydrocarbons and
Their Derivatives (Sintez fosfororganicheskikh soyedineriiy iz
uglevadorodov i ikh proizvodnykh). IX. Oxidizing Chloro-
phosphination of Butene-l.. Butene-2, and Cyclohexene (IX,, Okis,
litel~noye khlorfosfinirovani-ye butena-1. butena-2 i tsiklo-
geksena)
PERIODICAL, '"hurnal obshchey khimii, 19599 Vol 29~ Nr 2, pp 615-619 (USSR)
ABSRACT- In their earlier paper dealino with the reaction of hydro-
carbons .vith PC13and oxy.-en the authors pointed out that
butene --- 1 i3 transformed by the reaction into chloric
anhydride of the chlorobutane phosphinie acid (Ref 1) with
the structure remaining open. In the present paper this
anhydride is shown to be a mixture of isomeric compounds.
On expelling relatively large amounts of this product
(500 9r) fractions ivere separated having the same composition
but different boiling temperature3, 0-cidizin.- chlorophosphi-
nation of butene-2 led to the same chloric anhydride.
However, it boiled within narrow limit~ss Constants and
Card 1/3

Synthesis of Phospho-organic Compounds From Hydro- SOV/79-29-2--55/71
carbons and Their Derivatives. IX. Oxidizing Chloropho-op'nination of Butene-1,
Butene-2, and Cyclohexene
probably apply to it. For this reason in these compounds the
structure of chloric anhydride must be ascribed to 2-chloro-
butane phosphinic acid-3. Thus in the oxidizing chlorophosphin,-
ation if butene-I the above compound may form only accordin.-
to scheme 2. The other fraction is apparently a mixture from
the chloric anhydrides of 2-chlorophosphine-1 and 1-chloro-
phosphinic acid-2- forming according to scheme 1. The table
shows that reaction 2 predominates. Also isomeric chloric
anhydrides of cyclohexene-and chl--rohexane phosphinic acid
were synthesized~ There are I table and 7 references, 5 of
which are Soviet,
SUIA1.1ITTED: January 3, 1953
Card 3/3

Synthesis of Organo-phosphorus Compounds From SOV79-29-4-21/77
Hydrocarbons and Their Derivatives. X, 03ddativn-:
Chlorophosphination of Some Ethylene Derivatives
of vinyl chloride under the formation of isomers which
differ from one another by the relative position of
chlorine and the radical POCI 2(Ref 2). These acid
chlorides synthesized in this paper apparently form also
a mixture of two isomers of the structure CH 2 ClCHXP(O)C12
and COUCH 2P(O)C1 2* In particular for the product of the
reaction of vinyl fluoride with phosphorus trichloride and
oxygen expeximental data are available on the occurrence of
isomers, the separation of which will be the subject of
a special report. The reaction product of the
oxido-chlorophosphination of vinyl bromide was divided
by fractionation into two fractions which differ not only
by the boiling temperature but also by their composition.
The low-boiling fraction proved to be the acid chloride
of bromo-vinyl-phosphinic acid, while the higher boiling
one was the acid chloride of chloro-bromo-ethane phosphinic
Card 2/3 acid. The formation of the first compound probably results

Synthesis of Organo-phosphorus Compounds From SOY/79-29-4-21/77
Hydrocarbons and Their Derivatives. X. Oxidation
Chlorophosphination of Some Ethylene Derivatives
from the second dehydrogenation reaction of the acid
chloride of chloro-bromo-othane phosphinic acid in the
distillation, Reference 2 confirms that the low-boiling
product is the 2-bromine-substituted substance, while
forms the higher boiling one the 1-chloro-2-bmathx-derivative,
and accordingly their formulae are BrCH--CHP(0)Cl 2 and
CH2BrCHClP(O)Cl2 (Table), As by-product of the reaction of
chlor.ine with vinyl bromide the 1,2-dichlorobromide ethane
hitherto unknown was obtained. Consequently, the synthesis
covered the acid chlorides of 1-chloro-2-bromo-,1,2,2,-
trichloro-, fluorochloro-, fluorodichloro- and chloro-
(fluor08UlfO)-ethane phosphinic acid. There are 1 table
and 5 Soviet references.
SUBMITTED: March 3, 1958
Card 3/3

-n

n C. Cr
n t rj n t ii
'i t and!,
%
ire.
IC"D I G, T, v
ST IltT Ll~
ij
already -in I no-I Y C~ T 0 ee n
6~scj~ibc.,Ii in deiail, Onl-v i c ~r--lasllormr.ll ion into
tta t ri,l I thyl ~- lie (-H*~12) nn-,! -'h-2 c;` fluoro'orra
. L L
b:~- ito r,aaction .vith a t t c. e, 7n n i-~ r:a ', iern ovi n
I t
.
is goner~~Ilv ac,~3umcd th~lt t h,-~ & o 11 z2 0 n 1;~~ m -D
~lifiuor monochlor methani~ a r e 1: 7r
f ror
p .I the
Loal point of view'. The floun-~ th~it 'he
chlorine? itom In the mci c---u-., e of d luor 1-waoc-hicir methane is
comparati,.ely mobile, it coiz--Ld be seen thr-t froon-22 macts
Card 114, alroady -it r---ori temper:illurc- w lih

:;C'r 17
Dif luor '4'onoch Lor :-:ethane q.3 +
'-22/77
Agent. !, Reactlon of Difluor `13no--hior 7:1nt!
_ ( F r -,.-i -) n - 2 2 71' 1 -~'h ~ I o h o I a t e s
and Sodium Illercaptides
mer,apt`d~,.,3 in ~nhydvou.5 i o ~ld i n u, ra n- et e
j-
and fluorilnati---d -u-i',cie.-. ',Iinr, h
clip Ill + -.a.,DTZ ---4
A,
2
Lons procoed
ver', smoothly -hroliEh alcoholi.-,
5olutions of sodlum T. n n 4 !,.v in e T:
cliflucis,ome~l*!- --.na -the- -,,,re
o b n e d In th~, rn:~,,,Oon LLMI
with f~c-c~n-22 in ;,,r (S A -
dif luorometh-l -al` hi-Oi&r v; eld
'y n J.
ac,:~Ordin& to the itlt eC 1 1 ~7
j,~.-F SCH CH C j -L
2 2
h~~ r n f the ac~ tG s c f-:
s yn t h e, s i z ts!d lo y G I Vo 1 11- --j r n,,, rt~,--c%~-nce 'as"
sch--~iae There are 4 1 -~nl-
Card 2/A

5
AUT."OF--": 3obo-rovskiy, L. Z. , 3ziina, 7
2 /77
T I T 1, -j -4chloromethine as Dif luorome thy! atins A-ent
10
kak '-if torn, etiliruyushchiy ~~,!,-cnt- II. Reaction of Difluor
:~'onocalor -lethane 'Uith So..-I-i-u!!i-di.,3.lkyl-!)hophi-tt,s -Z~n.ktsiya
--J`to.r!-~hlormetana s natri~rditil!cilfol
FE, R iD 'J., CL :~!,urvial obshchey khimii, 195~,~, Vol. 2Q, -71-7-
~`.BSTRACT: In thc T:rcsf.,nt paper the attctint is mw4e uso rji.rjuor
nonoc,hlor methane in the reaction of "ichac1is---3cc!rc- .-.,.i-th the
;!o-;.ium derivatives of dialkyl-phosphorous acizls in c-Ior to
obt-in the corresponding difluoronathyl phosphinates.
Di-luor flonochlor methane was found to -eac,
of lialkyl-phosphorous acids in ,n incrt sGivent
'ho
"ormation of dif1uoro--ie1hirjphosDhina'cs:
OR
CHF -P +
+ -L-P.OP(O7,02 2
0-11
This r0. ction Droceed3 the most roadily i- `I-o soniu-m
Car'l 1/3 derLvativ-s of the hiGhest dialkyl-phoophorous in,

D i c ~i I o I-) r. ra, i f 1 - V, n --,, 0 " i (-, t i I ,;- 1i nC n t- 707.-,.~-7 01 _ T %/77
IT, R---netb-i -~f' Dif1!7.0L- "onocinlor
rtic,,,.I:~r in Mif? c-se of dibutyl phos-,hite ~ahic'- is 1-noWn
I;o bn in liquid li~:,drocarbonn (7ef 4). On t!i:,-
P-s--in.- (-.,f -n,)nc)chlor methane throu-,h the benzine
soluti----n of Jibutyl phosphito th~i diloutyl-lifluolo-
aas thus formed (70 Yield). In 'he so.,ne
!,he ~Iizathyl- and diisopropyl-difluorometh-1
ty L U
pho3n'hina.te -.7ere obtr--ined. The anomaly observed in the
rel"Lction of' difluor monochlor methane with sodium dimethyl
phosphite, where instead of the dimethyl-difluoro methyl
T)hosphinate to be expected dimethyl phosphite and a small
P,111 unt o" the ex-oected ester are separated, is due to the
L U
fact that the system sodium-dimethyl phosphite in the
methanol sollution is equilibrated with sodium dimethyl
Phosi)hite and methanol (Scheme 2). The equilibrium is usually
shifted to the right and the reaction proceeds according to
scheme 7. The reaction of dibutyl difluormethyl phosphinn-to
with phos-phorus pentachloriie yielded the hitherto unknown
acid dichloride of difluoromethyl phosphinic acid. A cleRvage
of the P-0-bord was thus found to take place due to the
Card 2/3 influence exercised by PC1 5 upon difluoromethyl phosphinates

Dichloromethane as DiCluoromet-hylating A~ent. , SOV/79-29-1-23/77
II. Reaction of Difluor .,lonochlor '.Iethane Iffith Sodium-dialkyl-phosphitf~s
in adilition '..o the formation of the acid dichloride of
difluoro--iethyl nhosphinic acid,with the formation of the
carrespondinl- :?X,-yl T)hosphates. There are 5 references, 1 of
which is Soviet.
SUB,JITTED: 'jarch 6, 195--3
Card 3/3

JIUTHORS: Bystrova, R. I., Zinov?yev, Yu. Y., SOV/79-29-6-68/72
Soborovskiy~ L. Z.
TITLE- Synthesis of Organo-phosphoric Compounds From Hydrocarbons and
Their Derivatives (Sintez fosfororganicheskikh soyedineniy iz
uglevodorodov i ikh proizvodny~h). XI. Oxidizing Chlorophosphi-
nation of Nitriles (XI. Okislitellnoye khlorfosfinirovaniye
nitrilov)
PERIODICAL: Zhurnal obshchey Ichiraii, 1959, Vol 29, Nr 6. pp 2088-2092 (USSR)
ABSTRACT: In the reaction of the oxidizin.1, chlorophosphination of hydrd-
carbons and their derivatives the C-P-linkage results; at the
same time acid chlorides of corresponding alkane-phosphinic
acids are formed. The reaction was carried out by halogen
substituted paraffin hydrocarbons and by halogen olefins. The
oxidizing chlorophosphination of alkoxy substituted hydro-
carbons of ethers (Refs 1,,2) is also possible. In the present
pal;er the authors analyzed the reaction of phosphorus tri-
chloride and oxygen with cyano substituted paraffins (nitriles
of carboxylic acids). It was shown,that the oxidizin '- chloro-
phosphination of nitriles may proceed in two directions. The
Card 1/3 acid nitriles with 4 an" more C-atoms per molecule form acid

Synthesis of Organo-phosphoric Compounds From Hydro- SOV/79-29-6-68/72
carbons and Their Derivatives. XI. Oxidizing Chlorophosphination of Nitriles
chlorides of the cyan alkane phosphinic acids C nH2n (CN)p(O)Cl 22
i.e. of compounds containing a C-P-linkage. The first links of
0
the nitrile series (acetonitrile, propionitrile), as well as
benzonitrile, form in the reaction with PC1 3 and 029 compounds
which contain the P-11--linka--e., i.e. derivatives of acid chlo-
rides of the imido-N-phosphoric acids, which cozrespond to the
formula RCC1~11P(O)cl 2' Acid chlorides of the cyanopropane and
the cyanobutane-phosphinic acids have been synthesized. Two
acid chlorides of the imido-11-phosphoric acid have been obtadned
whose structure corresponds protably to the formulas
C2H.5 Ccl~NP(O)Cl2 and C 6I-T5ccl~_NP(0)ci2. The acid chloride
of the imido-11-phosphoric acid, which is formed from ageto-
nitrile, could not be separated in pure state. For the nitriles
of carboxylic acids, which contain more than three C-atoms? the
oxidizing chlorophosphination is carried out according to
scheme (1). and for the acetonitrile, propionitrile; and benzo-
nitrile aocording to scheme (2), and leads to the P-N-linkage.
Card 2/3 The spectrosooDic analyses have been carried out by

Synthesis of Organo-phosphoric Compounds Prom Hydro- SOV//79-29-6-68/72
carbons and Their Derivatives. XI. Oxidizing Chilorophosphination of Nitriles
N. P. Rodionova, S. S. Dubov, and V. V. Fedotova- There are
1 table ana 5 Soviet references.
SUBMITTED: March 3, 1958
Card 3/3

50)
AUTHORS: Soborovskiy, L. Z., Zinov'yev, Yu. M. SOV/79-29-7-10/83

TITLE- Allyl Esters of Some Alkane-, Alkene-, and Chloroalkane
Phosphinic Acids (Allilovyye efilry nekotorykh alkan-, alken- i
khloralkanfosfinovyk,h kislot)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Nr 7, pp 2152-2154 (USSR)
ABSTRACT: Allyl alkane phosphinates are of importance as initial products
for the synthesis of vario,.is polymer products. Up to nor, some
alkane and alkene phosphinates have been obtained by causing
allyl alcohol to react with acid chlorides of the corresponding
phosphinic acids (Refs 1, 2) or, according to Arbuzov (Ref 3),
from triallylphosphite and alkane halides. Ally! octane
phosphinate Tras synthesized according to reference 4- Kamay and
Kukhtin (Ref 5) described allyl chloroalkane phosphinates. In
the present paper some allyl alkane, allyl alkene, and allyl
chloroalkane pho8phinates were synthesized. The acid dichlorides
of the corresponding acids rhich had been obtained by oxidizing
chlorophosphination of paraffin and olefin hydrocarbons
(heptane, cyclohexane, propylene, butene-1) Ttere used as initial
Card 1/2 substances. As far as some acid dichlorides obtained by this

Allyl Esters of Some Alkane-, Alkene-, and SOV/79-29-7-10/83
Chloroalkane Phosphinic Acids
method were mixtures of isomeric compounds, the resultant
esters also consisted of isomers which 'differed by the position
of the phosphorus-containing residue in the hydrocarbon radical
(Refs 7, 8). Moreover, the acid chloride of propene phosphinic
acid was obtained by dehydrochlorination of the acid chloride
of chloropropane phosphinic acid. This acid chloride could be
transformed into allyl propene phosphinate which probably
contains an admixture of isomeric compounds. The constants of
the compounds synthesized are tabulated. There are 1 table and
8 references, 6 of which are Soviet.
SUBMITTED: May 15, 1957
Card 2/2