SCIENTIFIC ABSTRACT SOKOLSKIY, D.V. - SOKOLSKIY, D.V.

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• Collection: Scientific Abstracts
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

-,T- 3.2 () o SOVAW-7-22596
Translation from: Referativnyy zhurnal. Khimiya, 1959, Nr -1, p 73 (USSR)
AUTHORS: Sokolts iy, D.V., Shmonina, V.P., Skopin, Yu.A., Tverdokhlebova,
TITLE: The Investigation of the Liquid-Phase Hydration of Acetylenel
According to Kucherov. I. The Effect of the Composition of tile
Catalytic Solution on the Course of the Reaction
PERIODICAL: Tr. In-ta khim. nauk. AS KazSSR, 1958, Nr 2, PP 158 - 172
ABSTRACT: The hydration of C2H2 was studied by passing it through a sulfuricLl(
acid solution of HgO and Fe2(504)3 , depending on the composition
and the temperature of the solution, the rate and the duration of
passing C2H2 through the solution. The loss of catalytic activity
of mercury compounds in the course of the process is caused by re-
ducing them to mercury metal with its removal from the solution.
In the absence of oxide iron the deactivation of the catalyst takes
place more quickly, the introduction of Fe2(SC4)3, though pro-
moting the removal of mercury from a solution in a more disperZed
Card 1/2 state, inhibits its reduction, increasing the reaction rate. The

80308
sov/81-59-7-22596
The Investigation of the Liquid-Phase Hydration of Acetylene According to
Kucherov. I. The Effect of the Composition of the Catalytic Solution on the
Course of the Reaction
optimum passing rate of C2H.. at 960C is 4.3 ml/min per 1 ml of contact solution,
the optimum temperature is 50C. The presence of H2304 is necessary even in
the presence of an intermediate compound formed between C 2H2 and the catalyst.
In the case of a change in the concentration. of the contact solution, the yield
of acetaldehyde passes through a maximum corresponding at 960C to a composition
of 23.N, M04 and 10% Fe (304)3; the highest productivity is attained at 750C LK
and a composition of 13.~i H2S04 and 17% Fe2(304)3, The introduction of small
quantities of chlorine reduces the total yield of CH3CHO leading to a r-upture,
the addition of small quantities of CC14, C2C16, C2H4C12 increases the yield of
CH CHO; chloroorganic compounds, as well as NaCl taken in large quantities
Qrt a negative effect. In the beginning of the reaction the CH 11
3C 0 yield is
less than average, the maximum Tyield, exceeding 100%, is attained after 3
hours, which is due to the initial formation and the subsequent decomposition
of intermediate products; later on the yield decreases again due to the in-
tensification of side processes.
Card 2/2 S. Kiperman

ZHANALINOV.A, A.N.; SOKOLISM, D.V.
I 'IZw';p?,~
Rate of hydrogenation of unsaturated compounds in mixed solvents.
Trudy Inst.khim.nuak AN Kazakh. SSR 2:222-228 '58. (MIRA 12:2)
(Hydrogenation) (Unsaturated compounds)

.7 1
a; 7 The 'e.-,ca of' the H,,-dro-~-?nution Vcl,,)ci+ly on t'~e
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a t a 1z - t oa

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p
2 Fciit 4 oned veloc ty r. t-- id ace
io, accor to tuhp op-i ni on o' mo.7t sc-*e z

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dro;-n 'or 1 hour. in t--- of
iiexyne-l in n-!-.eot--.-,,.e and of tr~~S
_p4 3erl.-lene
i,. et-.-annol t1ae s~,-cific acti-viv, Of' t~,e ca~aiys~
a u a -,I
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ki e tf r.]- 4-led by tliree processes to each,
a)B7r tl-e hydro;rn~,:~-.J-ion of t'- -1C-s~c_-ce t-e
L u
expense o fl. t.e hydro -on of t,.
deh-"_Ir,:):*O!_.a'~Ion fro- c-~~ -1,%:t , and c; y e
s a 0 0 f c a I Y S t e T~-~~e 0- .:v.~ 1- o -e
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4
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f

of 1.~,e Hydro,enation Velocity or, t'le SOV/1
C Y t c6u Y
-:uvf:.tce by reactin molcettles. Tner are 0 zcs,
U-ties, nr-d 26 -cferencoo, 12 of which are Scviet.
A'SOCTATIO!': Institut !-h-i-%ichesI,:i-h nauk tIN K. oy SSIR
(Institute of Chomicz 1 Sciences,AS Kn-,i"-hs'4*Mya SSq'
Knfe-Ira kataliza i tekhnicheskoy khimii (Chair of
Catalysis and Technical Chemistry)
SUBMIT-~'ED: October 9, 1957
Card ')/,3

SOKOLISKIY, _D.V., SHMONINA, V-P.; POPOU, N.M.
_WOR
Investigation Of liquid-phase hydration of acetylene according to
Kucherov. Part 2: State of mercury in the acid catalyst. Trudy Inst.
khim.nauk AN Kazakh. SSR 3:173-181 '58. (MIRA 12:2)
(Mercury) (Catalysis)

AUTHORS: Fasman, A. B., Sokollsk-4y, D. V. SOV/156-58-4-5/49
TITLE: Velocity and Selectivity Dependence in Heterogeneous Catalytic
Reactions on the Catalyst Quantilty (0 zavisimosti skorosti
selekt-'vnost4 gaterogennykh kataliticheskikh reaktsiy ot
kolichestva katalizatora)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Khim--Iya i khimicheskaya
tekhnologiya, 1955, Nr 4, pp 630-634 (USSR)
ABSTRkCT: In the present paper the problem of the influence of the catalyst
quantity on the kinetics of the mono and bimolecular processes
in liquid phases was investigated. The equation (8) was sug-
gested for the determination of the rate of reaction:
K k1A S K k'S

(-
xp - - (8)
W
I
t)
V
+ kfS -Y +k1S
[
b
J
During the catalytic processes the selectivity was investigated
in dependence on the catalyst quantity in three systems. It
was found that with small differences in the adsorption prop-
Card 1/2 erties of the components the rate of reaction is not influenced

SOV/156-58-4-5/49
Velocity and Selectiv-ity Dependence in Heterogeneous Catalytic Reactions
on the Catalyst Q:-iant.-' tly
by ,;hange of the catalyst quantity. With d-ifferent adsorption
properties of the components the selectivity of the catalytic
process can be controlled by change of the catalyst quantity.
There are 28 references, 16 of which are Soviet.
ASSOCIATION: Kafedra kataliza i tekhnicheskoy khimii Kazakhskogo gosudarst-
-ennogo un-versL L
'te'a (Chair of Catalysis and Technical
Chemistry at che Ka---a%.h State UnIversity)
SUBMITTED: February 1-1, '1958
Card 2/2

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t DOIR T 0/000/0 1 '~f

PHASE I BOOK EXPLOITATION SOV/3537
Akademiva nauk Kazakhskoy SSR. Institut"khimicheskikh nauk
Trudy, t. 5 (Transactions of the Institute of Chemical Sciences.,
Kazakh SSR, Academy of Sciences, Vol 5) Alma-Ata, Izd-vo
Akademii nauk Kazakhskoy SSA, 1959. 154 p. 1,000 copies
printed.
Ed.: N.D. Zhukova; Tech. Ed.: Z.P. Rorokina; Editorial Board of
Series: D.V. Sokollskly (Res Ed.), V.G. Gutsalyuk, and
B.V. Suvorov (Resp. Secretary~.*
PURPOSE: This collection of articles is intended fw personnel of
scientific research laboratories,, laboratories of industrAl
enterprises, and faculty members of schools of higher education.
COVERAGE: The collection reviews problems of liquid-phase catalytic
hydrogenation to upgrade and reactivate various products. Hydro-
genation of unsaturated bonds of various types, adsorption of
hydrogen on different catalysts, chrom,tographic separation of
mixtures, and the effect of halogen saics of alkali metals on
the rate of hydrogenation reactions promoted by various skeleton
catalysts are described. Conditions of catalytic hydrogenation
Card 1/5

Transactions of the Institqte (Cont.) SOV/3537
of natural fat., sunflower oil, and such synthetic products as
esters of high-molecular fatty acids are set out. Dehydration
of the butane fraction carried out in combination with isomeri-
zation is analyzed. Principles of selecting catalysts and re-
generating them are reviewed and the formation of adsorption
potentials on metal catalysts is explained. Each article presents
conclusions drawn on the basis of experimental findings.
References accompany most of the articles.
TABLE OF CONTENTS:
Sokol'skiy, D.V., and G.D. Zakumbayeva. Reduction of n-Nitrophenol
Carried out Over the Skeleton Ni Catalyst in Presence of Potassium
Chloride, Potassium Bromide, and Potassium Iodide 3
Zakumbayeva, G.D., and P.V Sokollskiy. Effect of Alkali Metal
Halides on the Rate of Hy-d-r-og-e-n--at-i-o-n--af-AllyI Alcohol . 9
and N.M. Popova. Adsorption of Hydrogen on Ni/ZnO
catalysts 15
Card 2/5

Transactions of the Iristitute (Cont.) SOV/3537
Popova, N.M., and D.V. Sokollskiy. Hydrogenation of.Allyl Alcohol
-0
Over Ni/ZnO Catalysts
Shmonina, V.P., R N. Khasanova, and Q.V. Sokol'sIdy. Chroqiato-
graphic- Separation of Mixtures Of Nitr-obenzene-Aniline Products 28
Golodova, L.S., and D.V. Soko_j_1_ak4;r-. Study of Hydrogenation Reac-
tions of Natural Fats and Their Simplest Synthetic Analogues, the
Esters of High-Molecular-Fatty Acids 36
Golodcva, L.S., D.V. Soko , and Ye.A. Podlyacheva. Kinetics
~q2ls~~
and Mechanism of Hydrogenation of Sunflower Oil in Solutibns 44
Luklyanov, A*.,T. Problem of Formation.of Adsorption Potentials
on Metal Catalysts 50
Yerzhanov, A.I., and D.V.__a0k(zl'skiy. Potentiometric Study of
Hydrogenation of-Benzalacetune Over Skeleton Pd/Ni cataiyats 56
Buvalkina, L.A., G.V. Pavlova, Z.F. Prussakova, and D V. Sokoll-
skly._ Dehydroisomerization of the Commercial Fractiorr-b-f-n--BUta-n-e
6_v'~_r~Oxide Catalysts 64
Card 3/5

Transactions of the Institute (Cont.) SOV/3537
Shmonina) V.P., K.M. Vlasova, and.D_-Y-Sokol-~~-Catalytic Re-
duction of Aromatic Nitro Compounds. Part IX 72
Flili. R.M. (Moskovskly institut tonkoy kh1micheskoy tekhnologli
inewi M.V. Lomonosova- -Moscow Institute of Fine Chemical Tech-
nology imeni M.V.-Lomonosov]. Some Principles of Selecting Cata-
lysts for Liquid-Phase Hydration of Acetylene to Acetaidepyde 81
Shcheglov, N.I., and-D-V.-So-kal-laki-y- Some Methods of Reactivating
the Skeleton Nickel Ca~talyst 92
Shcheglov, N.I., and D.V. Sokol'skiy. Hydrogenation of Acetylene
in the Liquid Phase 97
Sokollskiy,,_D,V., and L.P. Dunina. Hydrogenation of a Sodium
Acid-Over Platinum
Sokollskaya, A.M., and D.V. Sokollskly. Hydrogenation of Cinnamic
Alcohol (Styrone) 110
V'-*ard 4/5

5 S,'-', V/ 1 51 9
AU -.3. Gr)!- S. , So',c~' D V
A F c, on i c _;r lnv,~S,i --ati
on ..-l -tion 0 f, T"a, s ir 1 v - %~t 1-tri 3- -,-'i c 1,.-S, 4
mc t Od s 1 edova~__ IL-a ~;e le:-. luivn, S ~i ~-,r` Eri r~)v
Ir raS t1ro 1--*
,_~:~_T: ')TCAL: -) -,P; c se Y zhl-c Y.
a c y y e d') 1 ad
.
r 1 1) 23 - `1 (7,3,;

A 33-11 "1 " C T omc ric
S uns at ul- a e P_ s d, C f n tic CS, 2 rs
cf fat'ly acid s prcv~~ d -at tl_~c,
sh ~c!::,~ositinn cliaiii:e b~r r-j-,-)-r2.-
des c-- or :astcrs --71 hyd_~-o ati-l-n. TI-e
-d on -a nic'-_cl siz-Icton catalyst in L:.bscluto
car-i
_
cf ti-e potc-tial ccur-res -.2re plc";,-,d
_in adIc'iticn, the ir -Le sa:rl;lcs wr~i-e a-nalyz-A.
,, ~,rtt ion selcctivol-Y as _i~; 'by t'--?
-:~c h
4
Of a ml;_--turo of -1-Inoleic ard
-1
C 0 1-1 0 .3 1 o v; c a - ram C,
ar

A 11o tc. x.'iomc et I iod for Inv -j - ti ti Se ' --.c; tj vi t,,.- '.-1-7 11
5 4
on Hydro:~c_ation of Pats in 31ol-vento
First, I.,- -orc. iz;
71hc oicic ac4r! con~-_~nt incr.~a:;es wlicl-cas "lic, -,.cid
cont._-.I~t only T11- h,,d-o~-iD-_-.`1_Jc.i, of cl_,i-
i. eL no r t, bt-.f c, --r0 t, 1~, 1 i n C. I -- i r, _- C i d 1 0 .)oe.L~
to dccl.C.2L 3
acii c~oiJoct; and
~,( _-U --re L11, -i
t~,bi- ki- ,oilfsc of V-,p
of -Iotl,yl est,= c" lino-lo,ic and, ol:,ic ncift.
A S 3 O'C-.1 K a r a b o i i K -a z ak s'-:D 0 -f.) s, U(I r, t V 0 'n 0 L- C; S i.,-_ S -
i ka-'aliza -i
iE,. S.
0- t!,-
c-f *,Pioc-,,_,_. -~~z,!` State Institute of Me-
dicine nnd C'iair of CatalYsis anc! Technical Chemistry of Kazakh
-j--01~i S.
D: juice !6,
Card 2, 2

SOKOLISKIY,-D.V~,; ZAKUMBAYEVA, G.D.
Effect of alkali metal halides onthe mechanism of hvdrogenation of
o.vclohexene on platinum black. Izv.AIT Kazakh.SSR.Ser.khim. no.l:
62-64 '59. 041PA 13:6)
(Alkali metal halides)
(Hydrogenation)
(Cyclohexene)

POFOVA, N.M.;,30KOLISKlY, D.V.
Hydrogenation of furfurole on Fli - ZnO catalysts. Izv.AII Kazakh.
SSR.Ser.khim. no.1:65-70 '59. (MIRA 13'6)
(Furaldehyde)
(Hydrogenation)

MELEXHINA. L.S.; SOKOL'SKIY, D.V.
Potentiometric investigation of the hydration of fats. Izv.
AN KazaId1.3:;R.Ser.khim. no.2:32-34 '59. (MIU 12:8)
I.,
1. Kafedra biokhimli laz46skogo meditsinskogo institute, i
Kafedra kataliza Kazakhek6go gosudarstvennogo universiteta.
(Hydration) (Oils and fats)
" j

MELAIMILL, L.J.; SOKOL'SKIY, D.V. . I - .
Kinetics of the hydration of methyl esters of oleic and lino-
leic acideand their mixtures. Izv.All Kazalch.SSR.Ser.khim.
no.2:35-40 '59. (MIRL 12:8)
(Oleic acid) (Linoleic acid) (Hydration)

GOLODOV, F.G.; SOKOL'SKIY, -D.V.
Hydration of v-.*Lnyl ethers. Izv.All Eazakh.SSR-Ser.khim. no.2:
41-50 '59. (141Rk 12:8)
(Hydration) (Ethers)

BEZVEIMIOVA, ;.T.; SUKOVSKIY. D.V.
Reduction of wqrgen by skeleton nickel catalysts. Izv.AI1 Kazakh.
SSU-Ser.lchim. no.2:51-55 '59. (14M& 1-2:8)
1. Kafedra Ichimii Kazakhakago sellskokhozyaystvennogo in'.Aituta
i Icafedra Icataliza Kazal:hskogo gosudarstvennogo universit6ta.
Oi,-.rgen) (Reduction, Chemical) (Catalysts, Nickel)

5(1,3,4) SOV/153-2-1-22/25
AUTHORS: Fasman, A. B., Khaldeyev, 0. D., Sokollskiy, D. V.
TITLE: Geiieistioa of - ectricity - .. During the Catalytic
iiyarogenation in iiu,i-conauctive hiedia (U vozniknovenii..tribo-
elektrichestva pri kataliticheBkoy gidrogeniZat8ii V
neprovodyashchikh sredakh)
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheekaya
tekhnologiya, 1959, Vol 2, Nr 1, pp 123-125 (USSR)
ABSTRACT: Static electricity with a potential of several kilovolts is
produced by the friction of dielectric liquids at the container-
or the tube walls of any shape (Refs 1-3). If conductive sub-
stances are added to hydrocarbon, the electric charge first in-
creases and is then reduced and ceases completely at specific
resistances of below-10 10 ohms.cm. Since during the catalytic
hydrogenation dielectric liquids (hydrocarbons, ether) are
employed by intensely stirring the reaction masi, it was inter-
esting to determine whether friction electrici:y is herein pro-
duced and how it affects the process of hydrogen-tion. Figure 1
shows an apparatus designed for measuring the eleLtrification
Card 1/3 potential. Figure 2 gives the charge curves foi n-heptane and

SOV/155-2-1-22/25
flunera-on of Triboelectricity During the Catalytic Hydrogenation in
iiva-uunuucti-ve wedia
its mixtures with absolute ethanol. The electrification attains
maximum velocity at a specific resistance P - 3 - 10 12 ohms.cm.
At p - 10 11 ohms.cm the electrification drops and ceases at
10 10 ohms.cm (in accordance with reference 4). Apparently, the
velocity of charge and discharge depend in various ways on the
resistance of the medium. The'voltage is rapidly increased,by
intense stirring. In the next experimental series a skeleton
nickel catalyst was employed additionally (method of reference 5)-
Also in this case maximum voltage occurred at p - 3 - 10 12 ohms.m
Consequently, the process of electric charge i s 4 tensified by
a fine-disperse powder with large surface (---70 m g). The action
on the course of the process is to be taken into account during
the hydrogenation in solvents with high specific resistance.
The extension of the interatomic distance by the electrostatic
field is bound to increase the reactivity of molecules of un-
saturated compounds. There are 2 figures and 7 references, 6 of
Card 2/3 which are Soviet.

SOV/153-2-1-22/25
Geaar-,t,lor. of Triboelectricity , *, - .- al-. During the Catalytic Hydrogenation in
ivon-conauctive ~iedi:,,
ASSOCIATION: Institut khimicheskikh nauk AN Kaz.SSR i Kazakhskiy
gosudaretvennyy universitet. (Institute of Chemical Sciences of
the Academy of Sciences of the Kazakh SSR and Kazakh State
University)
SUBMITTED: December 20, 1957
Card 3/3

5(2),, 5(4), 50) SOV/153-2-3-6/29
AUTHORS: Zakumbayeva, G. D., S okollskiy, D. V.
TITLE: The Effect of Potassium Iodide on the Catalytic Hydrogenation
of Some Organic Compounds
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, Nr 3, PP 340-344 (USSR)
ABSTRACT: At the beginning various results on investigations of the
effect mentioned in the title are quoted (Refs 1-7), The
following Soviet authors are mentioned2 Aykazyan and Fedorova
(Ref 4) and Pleskov (Ref 5). The hydrogenation process of
various organic compounds was investigated on a-skeleton
nickel catalyst (0.3 9) with 20, 30, and 400 in 50 ~6 ethyl
alcohol. The solutions were VN, 0.5 N, OJ N, and 0. 01 N of potassium
iodide. The kinetic and potential curves of the hydrogenation
were recorded, namely for the following substances: cyclohexene
(Fig 1), allyl alcohol (Fig 2 and Table), mesityl oxide (Fig 3),
and n-nitrophenol (Fig 4). The following was foundi The iodide
ion reduces the rate of hydrogenation of unsaturated compounds
and displaces the potential of the catalyst to the negative
Card 1/2 values. The inhibiting effect of the iodide is stronger than

The Effect of Potassium Iodide on the Catalytic SOV/153-2-3-6/29
Hydrogenation of Some Organic Compounds
that of the bromide; it still increases with the increasing
dipole moment of the hydrogenated substance-The rate of
hydrogenation depends on the fact to what degree the substance to
be hydrogenated may reach the surface of the catalyst.' There
are 4 figures, 1 table, and 11 references, 10 of which are
Soviet.
ASSOCIATION: Institut khimicheskikh nauk AN KazSSR i Kazakhokiy gosudarst-
vennyy universitet imeni S. M. Kirova - Kafedra kataliza i
tekhnicheskoy khimii (Institute of Chemical Sciences AS KazSSR
and Kazakh State University imani'S. H.Xirov - Chair of
Catalysis and Technicc-1 Chemistry)
SUBMITTED: March 14, 1958
Card 2/2

15-. //C/O
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
Card 1/4
Buvalkina, L.A.9 Pavlovq GoVaq
Sokol6sk
f 844.
S/153/59/002/o6/022/029
B115/BOOO
The Dehydroisomerization of n-Butanelon Mixed Chromous
Catalystalf
Izvestiya vysshikh uchebnykh zavedeniy. Khimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, Nr 6, PP 930-937 (USSR)
The present paper deals with the possibility of simultaneous
hydrogenation and isomerization of n-butane in the presence of
a number of oxide catalysts. This reaction is very important
in the production of high-octane components for motor fuels
as well as of synthetic nxbbex~ Cr203 -- A1203, an aluminosili-
oate catalyst worked-up by crackingg Cr203 on worked-up aluminotl/
silicate, and Cr203 on silica gel were used as catalysts for
the dehydroisomerization of u-butane. Experiments.were made in
a unit with continuous flowq and the initial raw materials
and reaction products were analyzed in a Podbillnyak apparatus.
The industrial a-butane fraction contained; in addition to
n-butane (about 70 to 85PP alsc butane (5~ at most'), isopen-
tane, and n-pentane (20~ and more). About 150 experiments were

The Dehydroisomerization ol" n-Butwie on 3/15Y59/002 '/06/022/029
Mixed Chromous Catalyste B 1 11 5BOOO
made with the oatalyst.-i mentioned, wbere the temperatures
(from 500 to 700 0 1) ang tha rates of flow ( from WO to 2,000 CM3
per minute per 100 am . of the catalyat) wcre varied, The oata-
lyst was recovered by air az 500 The yields of end products
(butene and isobutane) were re~Lated tc the quantity ci n-butane
reacted and passed~ and -to the raw material passed (sum of
n-butane and pentanes)~ The results of an experiment and the
calculation of the material balance for dehyt-iroisomerization
are given ~Ijab!e. as as I-ondit-Ions of catalytic isomeri-
k- -
zation and deanydrogenation of n-butane giving maximum yields of
isablatane and butene (Table 2.)'~ Tll--,s happened when the sum of
isobutane and butene was 37-45!, the rate of flow of the raw
- 6 0, 'When a
material 700 ,m3 rer minu-e, aand the t-eciperature 560
catalyat st-zi:~ .-;f 'l~o.-ked-uo aluv.nasilicate was used, the
total yield. -f i'~Obutane itid butenF was. for a rate of flow
of the raw niat-exial .2~f 2,00 0-ta..A per m4nute and a temperature
of 6od)~ 26~-P' (Table 3 Wher, Cr9c on wcrked-uD alumino-
isobu+~ane and butene was,
silicate' was itsed, the total yield. c~
for 1,000 c-m3 pez minute ana 5"0 32.~2',,~ (Tablez 4'), and,,
Card 2/4 finally, when CT203 on sL, -,a ge~ waa useet, at 600 cm3 per

The Dehydroisomerizatior. of n-Butane on
3 9/
/5 /002/06/022)029
Mixed Chromous Catalysts 3 115, BOC)0
minut-e and 600 the total Yield ~,f isobutane and butene was
56.6% (Table 1). In table 6, the dehydrogenation and iso-
meriz.-ing ;~h&rat~-teristics of the groups of oxide cataljstls are
compared,, Yz ia s1nown that,, at a low n-butane content (58.6~)
in the raw material. isobutare and butane may form on Cr201
on al-amin os-~ !--I cate at -the .9:rpqnss of the conversion of penianes.
The presence of more than 5% iscbutane and pentene in the raw
material. reduces the yields of these compounds or the dehydro-
~somexizaticn of industrial n-butane fractions, if Or 0 on
2 3
allaminosili!,,ate is us8d. A" tPmperatuz-9s above 700 b
-butane
is simultaneously pyrolyzed (in 1,1te dihydroiscme-=izalton cata-
lysts to give 01 to C~t When passed over the
catalysts investigated, 50 to 70A of n-butane is converted,
The low quantity of lilberat-ed hydrogen (2~, at most) is explained
by its oonsumption to reclu~.-e chromic oxide to lower oxides
which is not in disagreement w1th thfx resui-ts obtained by
Obolentsev (Ref 5), Ba.andin, Zalensk.'Ly and others (Hef 8).
This paper was lectured on t-he All-Uniom Conference on "Methods
Card 3/4 Used to Synthetize inft-fal Products for 'che Preparation of

6
6
7844
The Dehydroisomerization of n-Butane on s/iri3/59./002/06/022/029
Mixed Chromous Catalysts B115/BOOO
High Pol3mers" (Vsesoyuznaya konferentsiya "Puti sinteza
vysokopolimerov")
held
iskhodnykh produktov dlya polucheniya
in Yaroslavl' from September 29 to October 2, 1956. The
student Z.F.Prusakova took part in the experiments. There-
are 6 tables and 14 references, 12 of which are Soviet.
ASSOCIATION: Kazakhakiy gosudarstvennyy universitet imeni S.M.Kirova
(Kazakhakiy State University imeni S.M.Kirov)
Card 4/4

SOKOLISKIY, D.V.; ZAK074R&YEVA, G.D.
Reduction of p-nitrophenol an a nickel skeletal catalyst in the
presence of F~otassium chloride, bromide, and iodide. Trudy Inst.
khim.nauk AN Kazakh.SSR 5:3-8 159. (MIRA 13:6)
(Phenol) (Reduction)

7-AKUMIMYEVA, G.D.; SOKOLISKIT, D.V.
&feet of alkali metal halides on the rate of hydrogenation of
allyl alcohol. Trudy Inst.ldiim.nauk Aff Kazakt,,SSR 5:9-14 159. -
(MIRA 13W
(A1171 Alcohol)
(Alkali metal halides)
(Hydrogenation)

SOKOLISKIY, DI-V-- POPOVA, N.M.
Adsorption of hydrogen on Ni-ZuO catalysts. Trudy Inst.khim.nauk
AN Kazakh.SSR 5:15-19 '59. NEU 13 -.6)
(Hydrogen) (Adsorption) (Catalysts)

POPOVA, N.M.; SOKOLISKIY, D.V.
Hydrogenation of allyl, alcohol on 91-ZnO catalysts. Tr~dy Inst.
khim.nauk AN Kazakh.SSR 5:20-27 '59. (MIRA 13:6)
(AlIFI alcohol)
(Hydrogenation)
(Catalysts)

SIDIONINA, V.P.; MIASANOU, R.N.; SOKOLISKIY, D.V.
Chromatographic separation of mixtures of nitrobenzene - aailine
products. I!iudy Inst.khim.nauk AIT Kazakh.SSR 5:28-35 '59.
(MIRA 13:6)
(Benzene)
(Aniline)
(Cbromatographic anaJ-rsis)

GOLODOVA,'L.S.; SCKOLISKIY, D.Y.
Reactions of hydrogenation of natural fats and their simplest
synthetic analogs - esters of high molecular weight fatty acids.
Trudy Inst.khim.nauk AN Kazakh.SSR 5:36-43 '59. (MMA 13:6)
(Oils and fats)
(HydrogenatioN)
(Acids, Fatty)

GOLDDOVA, L.S.; SOKOLISKIY, D.Y.; FOD'YACHEVA, Ye.A.
Kinetics and mechanism of hydrogenation of sunflower seed oil In
solutions. Trudy Inst.khim.nauk All Xazakh.SSR 5:44-0 159.
(Sunflower seed oil) (MIRA 13:6)
(Hydrogenation)

YERZFWIGV, A.I.; SILOLLSKIY-j-D.V.,
Potentimetric study of benzalacetone hydrogenation on a Fa-Ni
skeletal catalyst. Trudy Inst.khim.nauk Alf lazakh.SSR 5:56-63
159. (MIRA 13:6)
(Hydrogenation) (Butenone)

BUVALKINA, L.A.; FAVLOV, G-V.; PRUSSAKOVA, Z.F.; SOKOLISKIY, D.V.
Dehydroisomerization of the industrial fraction of n-butane on
oxide catalysts. Trudy Inst.kUm.nauk AIT Kazakh.SSR 5:64-71
'59. (%une) (MIRA 13:6)
(Catalysts)

85h29
~z z 09 A006/Aco I
Translation from~ Referatlvnyy zhurnal, Khim'ya, 1960, Nc~ 16, P~ 73~ # 646;,:o
AUTHORS Shmonina, V.P... Vlass.--va, K.M., Sok--1;-='k-,y D.V~
T-T'r-- LE Red--jc-'.ion Arz..ma,.ic T-nf--rma-.i.--n FK.
alyt. I c
hyl Grcup on Reduct-iDn KinA-',i,:.z of .1-je N,*.r~,grc,.11
The Effect of E' 1- x
in Sk~E-'-,s-on Nickel and Platinum
PERIODICAL-, 1r. In-ta khtm. nauk, AN Kaz-'::SP, 1959- V--7- 5,~ P;:-. 72-80
TEXT, -The effect of the et,hyi radical intr-lur-ed in~lc the :;,Dmp,:~B-,+.'-:~n of
a nitr-.Crcmpound, -tn r= redu.-I-on. rate of 'he ni-=.grc-,.i-- del:end~, on, a ser.,.Es ~f
factnrZ, first c~f all on "e catalyst na,~ure, Vnen Tne Cn, Ske-
el~nn Ni, -,te an ettyl rad-1cqL2 en-,a'-Is an a::celartf,~ reao,~jon.
The et- 1 gr--,up -speeds up *.'--e reart.:,n mcr~~ L.-~ --rie or.,.,.-.-~*,a~- than in the para-
s-,at.e. ThIS is explained by -,he fa--,,, tt-a-, ~-qe cf +ne e!-ty.l grcup
causes a redused P~iscrptic~n of the nit-r-.,-c-rnpo,-ind, thus incr=-aS1-rjz the nvdr~gen
access ca,~aly-zt s-.zrfa.-e, Tln4.:~ redllstr'-'~--u-ior t-,--, --j~airzs- --irfa,e under
limiling the react.lon by a-+ival-~on, hal- a favl-ra*.-7--s effent
Card 112

851j29
3/,'81fj.60/CIOO/C 16 /005/C 12
A006/A001
Catalytic- Re.Jlllc~ion of Ar-ma-~Ac Nrtroccmpounds, 1:nf..-rfr.-i-l._,on DC. Tile Effeci.. of
~-,e Elhyl Group on Reduc*_J.._-_ Kineti~:_~ --,f Iths Ni-.r-_gr-uv. in Skele---ri N,,ck,~--~ and
Flatinam
or ~-re or~ce~S rate, A sltah- of the a~crp*.-n cf a on
P-k, cccuring during 'he intrcduzti:-, of I-te ethy-1 gr,:-.ip -in -he Fara-slal~e., _~cms_
wna,~. ac~eleratez whereaz a further de~-rea_ze of ads:~-_z*izn c~-jrl_ng
by ~;re of a _~-ut_=-,itllte -he cr,,hc__z*l.a-_.~.,
Inf.n_rma+ion VT_ see RZhIC-iinn, 1957; Nc~ 6, # 186_38~

Tra~n.slat~rls r~-t.e-. Tni~_ it- :7--in -_rani la~jcn. cf -.ne R,15_=.iaj,~
Card 212

Sf[CML