SCIENTIFIC ABSTRACT SPACINSKY, S. - SPACU, G.
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CIA-RDP86-00513R001652620019-9
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RIF
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S
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100
Document Creation Date:
November 2, 2016
Document Release Date:
August 23, 2000
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19
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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RUBESKA, Ivan; SPACKOVA, Alena; ZENLICKA, -Tan
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Praguse ?aeogiv or,) Firi-rolat!'i a 1~1 i, Vrl *111, Vo 2,
-Copyright& -I'0lAPhW hauum. Of the Cnschomlwak Aca4v -
once@ fttelstvi Ces%oaltmerie;&& ak&Ae--
my of s i tNakl.
1. -Estimating the Vollme of Ihe individut. I fiimeral a in
:Bar-andistaza Oret'" Otto Pp 121-129.
2. -Re-arks -on: the ~Piftd
dilts rq~of thi
I;p 13 C-1,31.
1. -rlim-ralca of ClAmium in a VO Pa Nposite in I.Orth Viet-
=.. :donsk J~HAII of.thc Cz-3 zvolarch 2rstitute (Vst.27
pro "4-,zk= rud). E-LLPAOI pr 1-52-l'o2.
4. "New Finds of 7haetonallur D=twval,~s (Ncval-. !E90)In
the 3arramdlen,= moar.todcnlcm,," i1ri.L11:2, ;P 13,~_144.
-Zowirk~ on the Algonquin Yor.-,.tion o, he Northern For-
%'-On 0" t%" Vltuvs-Z Avel P.Q.HLICKI pp 145-
157,
6. nocal Spe opgrachic ltt:roanallyvis f ~I!zeralotical _tI
:van riximn and IonbL 3N.L:i.W;. of a Central Gaolor_
L r~dni .1 V-11-1 _i
Cal rnws a -Icky) , 2r",naj p-~ 15c -
7. on the ;Iozrdei~ tttween the 11..'tddle and Uojer Do.
vomlwx Ia 'he 1.4chamtrm 'laanive." TAUG.L% ana
21we'. 101MICE; pp 165-175,
6. "Vessiliud Coaim taxat *,Ieu:. !IrtnIc"g Moruvia," juroolov
_TYRA= of the Central Go.~Io~.~tc&2 Inatit-ate, rrLru!i
r
P lc-la5.
P
9. "Zoolorj and Salanolos~y," ro=pd 3=3; pp
10. "Bacteris in the Mcent Sea Sed~Lv!rjts#" " denjk rLr:UL;
PP IM-192.
11. "Idjustment of Comp%rr.*I,:e Bpectr-.ia Tablec for Another
Type of spectrorraph t:sinj- the ~_xwnpls of Zalinin'a
Atl&m for the Q-24 3pectrorrmph," Ardolf iLC32; pp IS3-
194.
12. ':;ote on the Yvl'-Ow Eclybdic Ochre -rem I:rupka in Bohe-
eia," Prsntia�*A !;BM of 'he N.Lneralogleal Irtititute,
ee,UMverallmy NilliRc2~.iZI-T I:azlcva Un!.,,,Qr-
1/2
SPACKM, Alena,, dr. (Preha I. Hmdebni 9, Czechoslovakia);~
KR---JCI, E., SPACKOVA, A.; Balneological Institute of Karls Univer:sity,
?rague and Ce-_6E_ralGe616`gica1 Institute, -Prague, CSSR [origizial language
vers.on not given]
"Determination of Gold in Various Solvents by Spectrography
Budapest, Acta Chimica Academiae Scientiarm Hungaric V01 38. No 2,~ 1963p9
ae
pagges 103-113.
Absi"*ract: [Ge-,man article, authors' Enalish summa Two ~methods have been
ry]
developed for the spectrographic determination of minute amounts of gold
in various liquid, mainly serum and urine samples. The:r first method is based
on the analysis of the ash obtained by combustion of the aaziple*. The second
method measures the amount of gold in the biologicalliquidi dropped on'~th6
,-ra-chite electrodes, by direct spectrography. This latter ~io~edu:~e is- es_~
pecially suitable for routine serial analyses. 4 Easteim Euribpean,refeir'encies.
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+ For higher omens. 5 is pptd. and the other products nlosidation
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a 1-~alats *3det& "w m& w., Ot Wq =146 8"ad i"Vikoei: oltak imen"Ing
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The study uf the storwturv of pot"w"m "dillonlate.
A nrw ela" of sointined The ho"hylifosmitinlomy.
millingil, alid C. M'A'uh'wtk~~ ~t~miw.
liinhart~t, Rimm-M.0-1cid. Not, Aplht'r mo*djrr.
himj~ A' 1. -11 N194S).-Six tiew bevillydrip,ty.
arillnumptinnines "r pTcr4l. ill prove thr rhviii, sinicturr
of K11,14010.1 by IVI)LIcilig The K * With Co. Cr, Aliff CII
of kil"wil "'.1stitilliow
A 114).
II,;'Co.(.I.."II,(-J, (Ind Mf
410111V QJ. In JI'D al rwito fritilf.: ill bill 110 lber
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Th If L4 actory but COW re"1116~could: be'ob
fifterins. tained by pptg.
In an aliquot lain of the and deta. the Clem loi-
filtrate, adifin 0
'j()
and titrating, the 11j)",t, K I and If,,
d It th Xii-~,Oi- -rbe .4 0
PARIS were liti'l. pw
00 satisfactory. U1. p4"1101-trkway and the results were
goal, jud. in, 2Z"I(IM).46"nshistims Cd J;
dctd- by adding a jnown to, a, Kjo, L,' Him Th. can awe
d d be
.!Mx(,nt, To obtah, Cc); Ian ttg threxcess
0 a it E-6 11 nplete ppt.. Of the L
"Y that tbc Solo. Should conjah, a,:. !1ast"i
0 z Of 2 reudts resiorted, one 6 d 111C
an
of her is about too hiSh.
W.-T. flail
as
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o its aciil,~In. with KIO. asul K1, it 6 oxidized to dchydro-
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zoo
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fTALl.U$rKA1. LITIEPAUoPt CLASSWICATION
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m 'I' t, It a. 10i N IN YVI, is. 1:
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Papsul'Ifir Ramooli'le, flul. Moinj A. 1, 14:1 51i liti9j; If. Poid/. me a IdjiL. IV. Isimccentributioas to the study
,ewt see Iliad. ow-apost 27. 1:1.14C liM I 0t the structure of taftar elliatic! .1"'Abli'Awd Rep P.-Ph~'
1-111ftOl- "Os I-Irl"I it, Wdre- N$ Intor Or %lion'Mir /'I" R O'llse,
f,~ (Alms. A.
ell W.41.1 I Ile, ".. 7,
NO,. lito-A , cor;jIlgr rjjhvT %lable. 421) (C.0, lisc lognink x1ml I') 11.1111,1114ml 11.4il dl".v Is,
inailar fie fin larrin vIlletio. it, U111"ll . 11,4 Inol.
110. NjC,,(XI0,j( He(%) ;111,4 1. ~infllaf Re, ily. 141 tc,cl.- A L., 11"I sees fir ~h Ill; I -c-1-141, ..nd P, 'Ilegie. 4
if
411,1). dlva,enp. in mis,. 11,0,
A, r%elfrin-v that the ll~o I i, sells Nmnd;t"~ 1kat 11
Is 1we. . wMiumni Jf, I C'I 1. 1 I'Sh! ~ 11?;, 1 '711,41 %:4.:
I-Fel.1 : it .~17114 e lin-Irl ta6lom It li-to events ill
qnq~rlltv .4, 1110- wle'.11 Iffli4d %villsAWL'I. it _z.
~ilh 1crol NIL sr(:Ii! (rntii, 1:0:
110,0411,ShNIC(of Nils QCL-1114Y! i. '11,1 sigh M.
N64 i0mnmL : Few-
in'Ithal lot the 111~ ighikwia of all
tht, tlisilliird Anll,ff,-r
A 44W class of AMOW". TbW numme
thlocyammes, Q,t4qx~u Aski F- -;4)wu (Uttivt 11twhar"t,
Rumania). Aojzd, .4i ". s"p-ropuldrr kaw4m, 30q.
Alai.. lkx. A. 2.
Mitmile twis Ckfim.. Afem. 12. 30 pp.(1969)
(Flcllch ojnnLmy).-Uy enwintl aq. mahts, 0 their Wts
with phtluktalise (111stli) anil then with NH6WN. Fre: cu.
01, Zn. and Ni kirtu MlPb1:,#~4SV%h Ph larm PbPbd:-
(.ScN6, Un fotm-. Muphs Rj0Il)9CN.MsftUASCN),.-.
and co 'Thc
Mn and Xi saks have 3 of 11A, dat eibns at ittit:
hydcou4- The Fe compicz is sol. in sciatic arg. sAtent's
id,mity Imtoii, kntO; all 11w uthers we either In".
d,yomjk~ its vic ~Ilvvms. MI diNvulp, In atiwtial vieW,
uml lmw~. Aji mmijpk- of the ast-ahml of P#vPn. It: tivul
0.7 g. ZnSA)..7114.) itt 10 itti. 11,0 witho.7 g. phlbAUsime in
3 itil. 10) an,l 0 1 s. NII.SC,%', In 10 1111. jfj(), MA&hLt be
abitt, I)Pt. with A on" itsilt. 1110. MW dry
pla e he vww at Tom tmp. ()mhavil Mftvirkt~~
j
Clt
L&
A.
Fit Cum
PAPPS"ro, Room". J 00 v
2. Now. 22. 20 pp.( 940)(
94ructum of the
e
h
OH)sIll 11101 HC1) P117'"!
icu.-2ii.o
1. J()jj
,T,Ad.(IICI 0 -WOll
"0
(.V"d,- msm Oil,
0 IM u
U'Al,k) 41,01), weiv pgpd, by tirating 4-0K
ummat,r with the chimideb and "WAtts Of lwfilllne ~A"
Ai.jine (1-V) and by tzpmdnd m 84- 90im- the K
am
10 tht action of morne metsianumboa (VI-TM). Tbry
dimmolve in dil. IIC1 with deconsPe. ejxvlA M MA V.
16"ved only to 1119 p"Onmt of tartmic mm.
tins the ben&by*"Y-
hydrolysee In 111#0 -6t- I II
:1*11mmic, achl. which 6=7 LVOI-4*01 W60 416d. ~ Wb-"
armemd to the dehydratirg action of Cach - Hs" all
con*ds. um 1.5-3 mols. H.O. G. Audqw
;"iv,
ROMAtn'. MJ~ 'Thiffilo, pit, CU." Sm
%trill 24, lit pll.(l%iIXFltudI
-ul(at,s of Itcuchtine and tolidine and ccuopl~% met.d.11W
minc-4 are added to K stannsite to v"pi
,,new
Sn(Oll" broL, 31
(WS11,6111k). Tile? arc all ctjmt. COMIXIS.. MA. ill icalli
till. Itcl. U1141AISIC its hot 11,0. 111suns)IM of 111clul:
O."A 0. K,~41(01114 and t.2m licitridi"CAICI am, Submit 114:11
oil a to,prw " Iii1r. :6'5 4-t-, I #to is Added %trilwi.... filterni afte"
I0 Illisk willinut na-Idnic. dri,,I gin ligynmi% little, at rtillft
tellip.. Allafrild mit er. V-1 111.4, (.Sn by the Ijklientlid .14-1114i.1
liCuAtlint-N kY KjadAhl). (5) to 19, K StAlln4tr th,s,oltit'i
in 6 cc. water
+ 4 cc. colml. Nif.011 1.5g. Cu(,Nii,),.*) 'i~
ad'itil, vvsixv~l. mull vwAvif tilt ilmr. , Aftrv W min. the bill.,
rtystalt stv filtered. titut wwArtf twim:witlt Ftoll %.,61
-illi X16.16q.1 mvrwlitl .144011 its ad-i-aror ill N118'stin
[,-r lhcli 61,11.11)FICII. TJIV (InI311114 14W K 31AIIIIAW i
(011)6), lilla L
'llown 1-1 Iw KsIsn fintLil by flehavi und I'ani-
Vtno C-erbard Aullects,";I
ftzl DOWSOM of cart" from Csibuism
And Cot
and
'Runtania),
starips Crilitem
Aedd. Rep. Polmlose Romiiilm, Ya:.. Yij.,j,
Milt. 2. 487-MI00:(Preach sussimary)."Trtal thc';jij~
--ohi. contg Ca wW Cd with a %light mrss of R.S0. and
X11.80C.N. 'Tbe Am grftuish plit. of CfsSC%, turn, ~hkr.
Filter thraticb a filtercriacible A..
H10111, mW fiaWly withi shm, HttO. ilry AwIll min, in nUmd,
:101weilb. RWI the dltrole until OCA iq rentavell Atilt th't
-01n. is only Illotly Amic. Cant the 1)(HIP Mi. (JI'miln,
contg. only Cd and tseat with 0.5-1 g. SH.SCS and 11-1
W
YrWi & dropwise until a ppt~ formit. fleat until the pin.
'i.a= and adc! one timme nil. of pyiWine. Stir, miil.
k
;s I filter tbnmigb a filter enicitile At atilt WTLA the Ppt.with
a Wn. Ca"t4.3 g. N1164C.*4 + 6 MI. Pyrkline In 1(0) fill. 1110.
then 4-h thimes with I MI, of 2'%)1. (entax, '25 1111.451;',
PtOll.73sul
twice with I'ml. of a 10% ~mlst. of pWaline In All. Mill,
ithe plit., CclPyr MN)t is slightlY -0. in xhq~ Moll? ilml
timilly with a -4n. rosilm. 2 slrup-s of 1wrioline 1;1 10 Fill. alk.
rthm Dly Illul welith. 6erhard An"viger
Z:
Rapid m*dWd
fm god daigamilaing CoWl and
_glt and t.l'jliv
.4cod. Rep. Pepulare Momolor, 111.1,
Seri: Mat., Fig.. CkimN'2'.T13
marylI. -*tmt the all. -%Ali. "mag. Cumd Cil witha %1~~hl
eu-ims o( 111.40t and SIUSCS" adding the Wirt 1froll"I.-C
under 4-mulnuall, slilring., Fill" off he while lips I sit
Cto.'K:N, wtA with UP. F101f,and finally with all%. FiAl,
few I0 mirs. in a vacutsm, ti-kcalor milit wrists. 1 6nil
filmotir ontil all S(h 1% removeil, owfl, and ltrat Isith
11.5 1 a. NII.SCN and these with ron"Ifth livriditir tit iirnliil-
ire it an't leave I Int. in exce". The 171111WASION ~!; (hr
I-pt. is fincly tv"i. Filter Aft" IS inin.~ tiA,h with o "it
rmta. :I g. NH.WS + 5 nil. pyridiote in [ION) iisl.~ thvil
Kith it *Aft. Coma. 13 tsil. 0,57C P.W11 + PCP.5 nil. 1114 1! -f
1.5 lilt. pyridiur + 10.1 g~ N11.1'kN, theft with 1 2 lilt. .41e, q
I-MIll I'milt. 1f)% plifidline lulul filially." A. lim" i. ills k-16.1; z
2 llssit~ of joytidini: in 01 n1l. Div Ow, l'i'l.
fill 1.1 111111. In it VAC1111211 414-si'x~lot at 1,N,Ill and
4i
A new, rapid and
Opmadma at QPPW =i-b= 111216
*Ad tim. G. S d r~viina. Pirtea (irniv.
litteliamt, kurniulijL)-R5v,R, Paptlurf Rttmdmr,-
,tittimary).-To the miln. amig. Cu and Sh sonsadd 0.7~*, P.
virtaric acid firw each 0.1-40.3 g. W- Dil. to 7111-19) nil.,
asiol nil. pytiolineand 0.5 g. m)lid MI.SC.N gr~jdmillv
whilemirring.
metfiately. When the ppt. hat, filtef thrmigh a
filter crucible As. Wails the plit. with a ~oln. of 11.75 g. J
+ 0.75 C. tartaric acid + 2,5 nil. pyridigie ~- :t`tll
nd. HrO anti then 7-8 tinics with 2 -3 till. -f J Will- M11K.
1). 13 g. Nff.SC.*4 + 2 mJ. pyridine + 48 ml. 11,0 in '-0) till.
'Al%E1011. Finally wash with abs. HtOff and Etiormax, A
%moll atilt. of ftymille and dry filr'-N) min. in vacito at "~m
temp. If Di, Sb, and Sn are livesent In the Cu -tlN#y,w
Mineral, treat with bot,coned. IICI, introduce a few nil,
IIA dropwisc, heat until all metals are ditisolved anti the e~-
cessiWirenwited. Add 0.75 X. tartaric acid, dilute to 75.r
fill., anti nil() r? mi. pyridine anti f).5g. x)I,SCx withstirritiR.
W.-l-h a* dt~cnljcd above. Gerhard Aullegrr
i~~ , O~w
, . I I ; 1 , i :,!I ~- -: f 7 :; , '! ~ I : , I : :., L : *, L %I A,
? : . . : . ; " ; ;i I . ~ i. 1; ;
, I t-
,
77
a H f
7 ~T 177-
i!, I. .- -
A
6jld and convenient procedure F
4
4
C6 r add lq#A, ari!d-m px~clse
.0 S- , -1-C
f of (mila w H I
se Ovo
-enients!.,~ ~.C 1u I n IL it. M
PAR. mm
Arad "Ware P 71,
"T t,, I
4. a. a (.qj ti A n h N! ~Jid
in the co*d with NHjCNS and fl-so.;; - Alux ofri tlie~
washr with mater, ale., and abs. ~thEx,~ -)w ~6j all
CuCINS. Evap. em IC~ L
-mil N
weigh as C CES.. If SOOrt
';7
tie ~t
filtrate, neutralize with: -r* -ocit o
P~ ittitte; and 4";MM
crystals (;f Nipy,(~3CNI). Filter -thrpugfi`~ ~rucjhloi
Fit
-Cft 'r[; 4:
t he, pp t,~'
-im-111C idW jyiflia I; 6f:jaieric~~j~;A-)~,:t
and,6 g; pyridin-c; -was i isitli I(
I )o all ;Wiifer
It
'ale., 1.5 sfil.-pyrWiue; axid 0.1 g. NIWNSI-ilitiii ~th~11
rA. abs. el.her mutj ; 10 drops of pyriditie; dry nit rtfota tem -T. i F-I
~z D6
vI
Ti!
u
T!
t RVI MI,
-7
law microm. and- raft roch US SRI e C:Md
bll'utw
-d-eterffininatt n, G
Z
A-wd.-74~. Popular, -, Rait-Ij
-Chuys,4; 425-31(1',
)9~)-~nimdh -J-13 based*d# the f
H
0 , P-:; new cf
tioti J f implex7j* Nl~,
tbafl-thi:Bi; ;! -I!- -,,, : v.
Wts -Ni:
~mo
prp-viaugy~u,&
'BI fif,
6,1:361 0 :,-The salt -,st dlss6lved in a s o
0l
N,-
..-,j6rra KBllj,;- troittneat: 6f -this %,with- (Cr,(O%eQ 4 a -A
llow~ ppt;.
IVCS a ye The ppti; is rbis#,d*Itk-*a#ili
find isn then 060" ale-and. Wier; anti &k(1 i thlgii~
T
Ov heov,
P 0
A b accuimNiAnd rTe~41reSiV.,
v;
f
_t;"Tj6
acp AoIh
-1-di
777r7777
MIM 1
j~-
"At IF?
R,~
,j
I J-
M--
t
........ . ..
"Mill!
it
ILI'
n We" rm
Or f 11
ltd
Rep, pa~ C! AMU%
am: (C.
vv;tw
~py
yridiiiie mo
7 1' tt, ~11' t l&; 1k h
Win sal C
'a Cu fro"ITO~
tif*,rk~ idd AS;79M).!qTbd I
I I A,
en 1drox tilt
Wi fgtrl~ te~ 4, Rh
ki lh 0014. fmq
FM
41 !i".
i~J
ol
ji
ol~
j
j
Coater from
4 method. for thi Soparation d: "1611b
Coint
R U denum and their determimition 411ta
'13
d
Re
h
(U
i
"
11c
.
n
v-
p.'
m Oco
Populare - Romint, Sludfil Cemrs1ri :Ckiw.111. 7713(1954
1
umary).-Two, mahods- art, desiiribiih IL
(French - sur -
7
o1n. it 60", dropWlse with',
treat the neutral or slightlj~ igid s
it
H.SOs and- NJ14SCN Flltir;the~ USCN;;.
in excess of,
through a filter- cruciblej~ wash. ~ vitl; ~ H&O. ~ HtOlffi~
'
'
'
'
weigh.
vaima and
dry for 10 min. in
finally with abs. HtA
WWI thc
Bull the filtme 603-free, udd hot colird. IINO&'
saim Is Colorless. and boll off thc~exccm idd., -The Tdo coW
now be detd. volumaricalIv by mducklax with dectroMw
Cd in the presence of Fas i snd subsequent KMnO4 thraiw;
ravimetricall
or
t
y,
, g
in
I
-
'c1
k:bW
i
I
A
111
%o
n.
s
nr
e
) unt
(
!
throurli kk i Was
tile gret!n
[CUPY46MA ih,
1 (0.15 Mkitill 0,11 IlAsrvi
"all
with 't Collig
.
taric addin 250 ml-1110, en:3 times with 2 M.-of i1
soln. eontg. EtOH (200,rni.)i 1120 (484ni.), 1 (0.13
: e
9
ith 5 MI
I
ll
w
h
.
onct! Ca
t W
c
as
and III (_
MI.);. flua
y
, Et
O:
: D~A
o
o
d
I
h
i
i
0
o of Ill
ne,
ro
.
.
cac
c
n
T, tOff ant
M
g.
1
j
its vacuo anti %veigh. Der. Mai in filtrate as~abovd~
J it
A~
N
M fN'.vi ~1~
-X
N
-A!
_
1
7
Z~
on
Ise,
s.
,
W%
.
_7 ..AllighUylhlic ~nrfz,.ij
Ut -Addh
a, K, Cq Ila, hr~
q. 7
-_A - t: 4. i
fill
i4iltz;;-, lu
J;
U
ram
4 J
IX- - -
ea
4 As is .4
7
COMPIti'sak
Of the'itio[d Cu SOW a1d
25730r~llil Of let thei6 tve-gre~sl
Ip settle, _foil sl
ith 20~'
EEOH ~6**i a &V of and; finMl~V4106011
'tO; drylif: i~dciia": and !ig ai;y
of abs; 1, ;V
-teak:
-do uOtimpfrep.
and m
7'r'
pz--
D".
if
tw F
tip
T
XI
i!J
_j
fill
J i
:j:
obd I 4mn
of -c;ob t 1,~#n
G~, CU
exid at
-UT ~v RD,
Acad-~ rep-~ P477FM ~v RD,-If no'. 7-73:
W
th!
while-.At' sb1a,'
p
HSC W 1,11" isoln.1 k3U i
.. 4 " - I ::. .1. i.- ;,':-, , -. .,. ;7
1144MJ1
'A ;Ildd" ex as; 'paudi wtcr- IM:0;
6t.,
O-rl 1-1m Cto Ill Ai:
19, It
La to A and F -throul 44
dine! rA an(f. A jiter:
A-4 6r Ail!
fact lcrlkW~( L
i
(7 ml.VELXS~ml 1, tin 6i.
Eitog lWill
timep With C -nolrti: con.
ca;
contg,,Mfl: int.)j6:251 idWfEtqff-~ 6 8-
times wit imall aw4it -T tioliontelut
St Wt
are sco, Atid dctd 4 si ~~il io r
i "A
t"N
Ijii
-W,
i !j
p
~Vt
~j
-44i~
W q,
ti,
-J
J_
7,1N
r e an a,
gtr
lot"?
re
fop
sit M ltd 4$-MaOM~"
.(French-
Cloj,'a~ stnble st. cowpVr.i, -i) Ah~
acidjc' (HCI) i6 n~t 4d 10.3 41w`1N1LCi
andl ail; C'f ah - t It
(I) in dil. 11C1-(1:4)*. "Me, didAi'ailt. C- ~i
y6log-Me =
.. ; -f .
. -. !I, '~ t
Agitate'vit4j)uS1~1de rvn!dti.;~ 16c- We Or, c~`
cced 75 Mi.
so4r) filtm outl4l j!
'Wit (40'fii br
in tvjlua to CIA15t, %-It,z 4411. PL614'-;-
tate- ions do: fiat iliterilrTel 1410, ou 01~ ths~ )eti-lencei 4 nietAk J'~ :I":!: --~l
from the 2n rTou
5,
A
:j
jli
f
A
f
El: