SCIENTIFIC ABSTRACT SPASOKUKOTSKIY, YU.A. - SPASOV, KH.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652630006-2
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 23, 2000
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


SPASOMOTSKIY, Yu.A., prof.; YUDINA, N.D., prof.; S&RNITSKIY, I.P., Icand.

- !, - . I ~ , I i ~~ " ~- ~: ~- . ; i
--- ~ I-, . 1. , : , -

. a. MMKILlogulml - 'M

F'FF~WTtPVfilPMffW,IllMF IIMMIHHIS LITIMIMEJUJI0111111M

3PASOLOWIKAYA, A. Ye.

fly!m

, I . 11

s-P.n.buy i~-lelr-sanqur
Bulgaria
Dn:~,"ZdC3 iot ind cated
Teacher at the ~,-ricultuxal Technological School
(Sels'n-ostopanski Teldmikrum) in:Pazardzhik
Sofia, Biologiya i nimiya, No 21 1961, pp 50-52

I If if to 0 14 it to if f# I it JA is x it A u It N m v v if v 61 o .1 m or*
-1-A-ift x WSW
f
00 t -00
br''
00
addidto of Sir kvmkw". lvamyv Sol A'~
vp
00 a1! Athiff 118m, Fwve. 0, WAMW Vltf*'h fl) -00
00
-00
Is M alul 111"'D
041 a yiel.1, rem...- wondind twilla equatko, 2phcll(5lKx)-' .00
9no*
CO.Na +,O#-2PbCH(Ougx)cobxa-21$Clt(Oll)~,
00 a
000 COJI fulml l'hCll(OMSX)C%N& + Pbcn(mxx)m.:: -00
NQ - (PhOic"Oh + ugo + ugx.,: mp.
0o
wi'l is fisawd MA at the fammur thm:0-4kibenyboijechmic zoo
00 and is obirshmed Is 22% M fxCuldimil ID Obo equal":,
Lee
00 l'hcll(mxx)c(*hN& + of - rbcmbrCOoNa + Ug-
X Hir and MCM]WINX)COWS + I% - (ftCHCOIN&V
+ Mgxv + MRSTI. temp. ftan Opbenylketic mcldti~
substituted in the rutcle we not found. 1. Ktkl"a
00
roe
1:9041
A AITALLUPGKAL LITINATILAR CLAIWICATtO
m
An a ad 11
p It all 019 a CT It a *4 a I us
"i" ;'. ~4010-
ogle '00
-~O 4o 0 0 0 0 0 0 to 0 0 0 0 0 0 See 0 0 0.0 0 i

aW, ~Ogw--M
9 v. A is a a e e e a @ a
4 1W 0 we

193
J
p 41 Q 43 U A;C Q
A ,
0 1
A. -r-ji 1, 1 k
,DID
Some new applications of "10441rolnol In Iljn~ 00
thesis. III; AcyletWe of ph4nols In the pressam of
Go

: malgaesium anti ligeparadon of phanulic
0 =axe_ip4Wv__AMx. unit. 51fia. /1,
Math.. Livve 2. 35, 21110,41(in Gtrntan, Z$4-51(IM44(9);
c(. C. A. 32, 1243O."The realction of phenok willilivid

e chloridtil takes Place more smoothly in Call. boln': in tile
presence of NIS, which does not, howevet, trout oith all
of the IICI foraned as In the act-fallool of kcrtiary -11".
The phtm4 (O.t tuol.) in 20-25 It. C.M. NIg turnuirs
(1.2 it. for each 110 grouls) end 0.1-0.12inni. acyl vithititile
*

04 were heated hr. at 90
in a round tla,,i, the re-
r and the ethrr .)III
action product was dild. with c1he
0 111

06 al dt-tanlrd from file unchanged bich was then wa4hcd
'
Z

00 13 v%k wa% treated With
wtth ether.
rhe tcsidue in the 1
llsOmnd the mixt, filtered intotht through

00 a wire Saute. After shaking succemively with water.
goo
dil. caustic alkali and water, the soln. was dried 46ver
NatSO4 awl the ether rLmoved by di;tn. ' The residue.
if liquid, was distilled its vaciao; if solid, it wus crv,.%t(l
,
N

A front a suitable solvent. Yields of esters -vre: AcO
II
9--- LtCO-Ph OM: PrCW"h, W%* 1111C I IC(Wj I'll:
"JiT
- H
(111
%I
A
0k
A
OC
l1
O
-
z
%; o-
c
c, A-
c
.
..
,a
,
3
4)
t1-A
C
11
INCO
C
H
Nl
11
4
98%
95%
GJ
see
-
so-
,
v
.
c.
; o
u
e,
4
.
.
;
,
C,11*31c-iso-Pr, 9777o: O,tl-PrC(hCgH&Alc+K;-Pr, 07%; Zee
(OAO., 95176; I,3.5-C,IIg(OAc)o, 710-v;!,..Ac0Colfr.
zoo
Oftntle Avcfq

t ,jIA11.1W11 1.11111111URE CLASSIFKATICx

77-
'
see
v law a3 min-
4- C.C
0

is IV IC Is
0 an i t 0 Od' 01 0

pro ra
-1
2 do a a vl~
:000 :10 0 0 00 000 0 0 4 0 0 0 0 0 0: 0 0 0 : 0 : 0, 00 W 0 0 0 0 0 0 0

,
'
I
I
00 wt 0 0 0 0 0 000 0 0 0 0 0 0 0 0 0 W *
9
f 0 4 We el G
190 0 0 0 0 0

VIP 0 0 0 9 6 0 1 0
A It P X A U 0 X JO 0 43 4 40 MOV-47MW
00 -3 flame N-conderiamition products ofars-6im&-avait" in Lit ) give
66 1
.
0 1with Otoral hydrate of diplisaylsicallsildshyde and AM- Z N0k), in. 101-4". Under thit-tv"donstji-fANC.H.-
i
d
k
-
an sue
ng Pin
00 Amon~fri. Alck."adr Simmm and Irmi Khr. lvanur, Ami- CHO (in Coll.) gives while Cry"sh trail
xuaire A. Livre 2. &&- int. scpd. by hot Colts into spirizigly IC4. cry"'ll
t 7
go a126(11141-42)(in fl utprian).-(I) The fortrIatioa of, I-N NO"jCll.-N)tCjj(p_C4tf.NO.) ro. 1541., and I
09 '(IjeiizylidelIC4niino)
6'I(
t
8
) -2.LI,2-trichiomethat" (1). M. 138- 1
remidil sol. jP-ChN`C4l1.Cff:NCli(OH)CC16. to.
of X
and
11
0 Nit
l
f
CC4010
W a
ii
i
t
0
015
k
i
k
rout
wozene
.
t
d .
i
tom
.
s
.,il
v. mul
s,
s O
,
,
l
equ
1
,
, 4 (
)
f
th
atio
01
NCH (011)
s
&iZ~(Gtfh + CC3
i
C
11
0
11
01
IO
C
"
010
e
00
can reerm .
n
VeS
:
1y
e equ
-
im
N-
8
6
4K
4
6
,
"
(&1)-W%). (WAttemptedsocylationolibe
,
N11 C , L,1(011)NII, U) + HjO, aRd U + PhCHO CC16.m-,l29
go )-PhCll:NCII(Ofl)cclil
)+IlsOorhy3PbCHO+ HO Schiff 6.-4s of type I with AcCl. AcrO, and Ds#O, gives
0& A Milo - (PhCli:N).CI]Pb (M) + MUO amil M + products of the type PhCJf(NliA0(N:CllPh) (IV),
.400
too C21CCUCII (011). - 21 + PhCHO; the latter sysithesslim orm PbC1l(NHAc), (V), and a substance ComflaOiNs. The .
actually carried out. adding I g. CCfqCHO to I s. M in mactimselstmeis: I-PkCH:N1l+CCUClfO-. -00

Za 0-8 cc. CJ16: the reuction takes pitice only in the I - M + NIL: M + HzO
presence
0
0
00'

*0
1
a- ol 11,0 and does not omir with absolutely dry Is (N:CIIPh) + PhCHO. PbCll1(NHJ(N:CHPh) + AcCl
r
'00 '
00
-
+ PkCffO
o - Plitli(Nil
I lCl
Mi
IV
Ul
w
)
A =00
g
+ -
s
;
+'
,
even on very long manding; this is crid b
+
l
;
y
.N1
000 lfjO - PhClfO + 2PhCff: Nil and Ph 14: NH + CC4- PhCH(Ntla), + MCI ~ V + 2110. Essimples of re-

go"
0
aIHO - 1. From 1.64 g. H and 1.06 g. 8111 in 10 6. C011%. actions. 1 (3 g.) Is shaken with 4 C. anhyd. NA.CO, and

o0
2.4 g.
00 ;3D dry ether for 4-5 hrs
; during theist 21) min.
~
i
d i
20
i
*kf
bt
15
in 80%
M (3
)
.
-
,
was o
n.
.
a
ne
n
m
F.
y
I
`
ether in added by portions; the ppi. is washed
00 Lf
a in 3g
Wdh
11fr
l5
Cjl
2vCl(64%)i"2Omin
ith 15
too
.
w
..
i
C.
g.
Gg
'
OH
i
i
I A
- j
v
ng
00 further awls. ppig. during filtr2tion, probably owrin T= 70% Me
' g
.
ipe
Alm.misfure. (2) Conf lensat ion of p-McCJ4010 with , 2.0 ji- IV, M. 13".5 , immill. In H&O, little ad. ilk cam Other
a
0,
:
CCLCIIO.11,0 and Nil, (in equiv. arsits.) gives 10-Me. 41'~Wtd Colo, WHY ad. in bill 411c.; the ether solim. PpIts. a
' 4
# " giving no with
CJf.Cff:NCll(Oli)CCl,, in. 144-15' (firom product m. WJO-
'M
A
%
it
O r authentim: Y. Similarly. I with H(KH
H
L
W%; tb;r- -1 obtained f JW
Lfw
f PhCZCHCHO
CHPb)
l
i
h (N
=
e
w
:
on o
t
rni
rr.,
d
.
and U. y.
CCI.CI(0.11,0 and Nil. jrivesPhCH:CHCH:NCH(OH)_ BuO, 04 g. HlO, and 10 g. etber ptimioss 10-12 Ims.
5"
221 ' (StOll).
s *M 4502~ MeO- I standin
OJ2 g
bi
dl
(W%) PhCH m
'
137-7
h
M
See
.
.
c nee
e
.
om
g.
s. m.
, r
sampended in 3 g. Et.O. treated with 3 g. AcYO
Cll:'NCH(O
In
IV (1.6 S.)
O-&tCOCjf
if
cilo
ives
C
w&
.
,
.
'
o
o
g
'
141-2' (68%); o_ljOC4lf4CHO gives u_HOC4H4CH._ 6 converted into V. 1(2.6g.), with 3g. AcjI MW I
t XCH(OH)CCI., in. 12-3-4* (t)(117"); 0-. M-. and! p-ON- and 12 g. ether. on stanitfina 12-1.5 hm, pon. 6 ambeftwe
:2 QHoC110 give o-. m-, and p-~DjNCjf#Cll:NCH(OF1)C- C4GHwOwN# (VI). m.p. rising floor ~178- to 2011*,(27%).

41
tie*
Cis. in. 1181, 113% and 123.5-4'. rimp.; with the aitro- AD 3 products. TV. V, and Vill are obtained in the FtAlCtiM
bentaidellydes. an excess of 3 moles CCA.CHO.HgO per between M and AcgO: 111 (3 S.) in 15S. ether, ftea"dwith no*
niole QNC.H.CJJO is indicated, the fractions am cam- 1 If. Ac%O %M 0.2 jr. HiO and left standing:l(f-12 brs.,
:9
pleted in 24 hrs., the yields being over 111)%: equiv.amt3_7 pqts.1V,im35% yield; thesalwatrit.ofMantlethmer.witis

~
0

1.2-1.4 s. V1 ud soomm:
,, and N I I. , 2L.5 z. Acq "it 0.4 g. 11,0, gve
of m-ONC*H4CHO. qC4010.160
U (2_1~ - at A
"
t I 1
0

000
i .
to to IF -to is it
s In OCR or st.111,411 En, lim
IN 0 0 0 0 64 too 0 -10 0 0 0 e 0 0 o w 010 #0 ve
90 4! 0 0 0 o Io 0 q 000-000.0
05"

00
00
00
0-
00
00
00
00
00
00
00
00
00
00
so
09
00
0 Oil 2 8 0 6 A 9 S 0 A 8 N 0 B M A A 9IN A 0 A A A J) 4% A J1 !I
0 0 9 0 0 0 0 0 0 0 0 0

00

IV. (4) The baws of tnw k'are suitable lot Purpose, of I 00
4knillication of aromatic ablehydet and their Melts. fiven
00
aliphatic aldthydes. which form no crist- podw s Vkh
CCICIIO and NHs; thus, PhCHO can be detected is the 00
Presence of a 7:1 excem of EtClIO iM a 4:1 eicess of Pr-
Clio.
caffect v-4lues only in low-malting solvents (e.g.. PliNlifes.
the vahus are distiactly too lm in hisba-weltitair
Phllqt)~)
,
uAvents WhiNfl. Cialls, jacnanthrem); this may be
awribed to a d6sacm. I - l'hCII:NtI + CCJ#CIIO.
Lxww out by the twe CAW; thu"
con,1111. dapende

an Af of 245.257. anil
CwHs. 0.7.2.5, and 4.5 7g. gives
raw. (true MX119).

0
t9. Without solves4 VU 4 If.. PhCHO 3.1 g..,wW

*
03
O
d
PNC
011
) 0
'
.
M
:
0 W
gave
H.Oll 1.6 (0 (12
C) W .. In c5l. (is 6.).
IMICII:Cphe
H
S
NH
5
AR
Ph 0. and
IMve,
5.8 g. VU, 3.1 S
a
&?
N Mime
PbClf
(&
i
l
X
M
:
n
besides some V
, ma
y
2'
little ad
in
l
In MID
i
131
i
36%)
-
.
.
mo
td
cs, m.
,
.
(
ether with 6 g
AcjO and
) in 6
d
1c
M (2
th
.
.
er an
a
c.
g.
e
1 S I to giM after :14 bes., PbwC:CHNH., m. 163-4*
(5 g.) with 10 cc. 23% NIfoH gives VM.
-
witb3
CCI
CHO
C
2
IO
H
VII(2
)i 00

00
.
.
g.
n
s
g.
X.
~
e
IfsO and I g. courd. NH.OH pptd.. after 15-21) ntin-. a
*
MOAO, which is hydrolyzed by lICI
net. m. 109-11
V
to CCIsCII0, Nils. and V111, and is thus assumed to be
'
&
N. Tbott
CC4CII:NCIi(OH1CHftt
.00
00
06
0 0 0 0 0 0 0 0 0 0 0 0 0
L1* 0-9 Wo 0 * 0 We WO-wo
3
0 0 0 0 ex: 0*4 0, 0, 0 0 P;
0.0 0 0 10 0 * 0 o * 0:0. wo I go -0
0:0,0 0:

""Fatima of Stanek
smohydoo is 0114W00 aim serbommyl Gooppeoft by
fillwal 11041116" OW sow"W~ AIrl,W10*1 Nkoi,olv iolod
IWall Chg. Immolov, 'Immossfo
Y".
MaL 41j, Line 2. 1046). 4 1, C;. 1, 41. 21-`Ws.
,fill friwts, with CcItcol(Oll)o AM NIL At go' if)
illicit *NCI4(0ll)ccl.. Umw thew
11011"16 lOkmf 0614thA60 Alkl Aft-40444' krimWit liot 11411 frooct
atki milikAAW 61,6-hydei dIVV lmllwt~md. t1olulhic llrit~t6
the m-Wtkits kwa lir U-WA its det"t -x WI). atotmitit! Alc-~l
hy-k,i. Hill vAn lw dirfectral elmoto it mointw6et
14 A 111111. With H14:110, 14.017C with VIC110, 1110-0 "11h;t,
I-PIC114). with M40, d.2,;C, with I-r,ct
.1111 NIC1111CO. with A1641 5,11' With (I'b-"
P-WC411.010 givemi, all a 1,411m 6-1,111INI, its.
111 -5.4', log "hich the Ati- 2-ts.b.
17-2. 110.2. IUA. M.U. 14.3. 74. 14.7~ Fill C.11.41CII.SCH
(011)CCI.. on. 1211'. thL W'AILV~ are 12.1, It.7, It.7. 17.1'
6.5, ".2. 5.5. 73: for ftcIi:cIlCII-.NcII(ojI)ccI"'
9n. 13--7.5', 12.4. 10.3. 10.0. 10.2.01.11, 0.1. 4.9, 5.4-
fiv p-MK)c.IfcII:NCII(C)II)ccI' tit, 111-21% L-sA:
17.3. 21,2 10.4, 8.4. V.3. A.5. 9.7. AtkI IU( -I (A:.Il-
I
CII'.\CI1j(JII)CCIs. its. I'MA', 34-1 3n.,. 20.C.,
21.1. 10,2.

The rewdom of: pbessylby with 0-hytilisity
carboxyLic uAills. U. Aleksand'r Spasov aud Bogdan I
Kurtev. Axintatiopir 43,
Livre 2. 147-Q(190-1947); cf., C.A. 39. Zr.W.-Mo%t
0-H0 intriboxylic itrids form plianylkydruaides with Ph.
NUNIII (1). but in a 541C reaction I glecon1p. to CjIG,-
VhNlit. Nth. and No. and sorsatimirs tbb metion piv-
vents detection ad the phenythydratidei. PrIC10110CIII.
CO,H and I form the sak, In. 9"", at irount It
heated at 140-5* they give 45% of the phem-
73-41*. NIIj anti PhNifs am lounil in i mixt. Ph-
(PITCHIMON)CHICO'iff (9) and I COM the Jdk. In.
105-7 *. anti on healing give the tn. 1411 -
7.5'. as well as the N11, jish. in. 363:5'. anti the PAN11,
MeCH(OH)CHMcCOJJ1*nd1'
give only the OtayiApiraeW, III. W."'. EtCll!(Oli)w
ClfMcC(Mi gives 3."% of Its pWAydmik, in. 101-
1.5*. SIcIC(OH)CIA[McC0.111 ithres Its I San. M. 110.5--
11.5% und from the reactitm mist. only the Nil. salt, m. I
MeNIC(OH)CHIRtco'll !gives nn definite
ucts. MeftC(0lI)CHMeC(Vf, m. 65-7% gives the'
r
salt. tn. 133~1.5% N114 s4k. in. I(0" PhNih
1,111. in. 116-17'. and ilk 124"1". Mt--
i;~, suit. in. 12-5.5-
V. anti the. Nits jak, in. IrJ-,Il* (decoutpIt.). Phx.
(OH)CHAlfccchil gives imly driwinpll. product.,# 14 1.
I1rIC(OII)CIIphCOIII gives Duly PhellCON'llPh. sit.
117 Nf. Lcierster

I* am& 41
and mumemia. Akk~~j4#~,Sj%wv and IvAn:
Ivanow AlowNaire xxiv. SitAs, FacWM ui. U. Livre 2,:1
_V1S7,-4IjIlM7-49).-It h. bcn "tabl6bed that ClCII_,1
-TARO (1) my he condensed with mromfic nWlmk-* and
to ftwm mized alikitycle-NFIs conitob. with the strUc.
ture AtCIl:NCli(0Il)CHCIj (H).. Their compla. ji
grM,
with this struct
Ure ; tb2Y bth&Vt W 1. ChIMAI hYdIAtC,
and PbCHCHO, which form ScIN 110 bears with aro_!
inatic aldehyda wo INHs, This btbavior 01 the above:!
aldchydes drpm& perlispe ulme the seg.~ Cl atom or the i i
Ph groulp t. ~ The U werelprqW. by treatment of
equiv. quantities of the 2 abkbydrs in Coils with sq. Nlls~
wtth codiftf- Tbry an hard, cryst., unstable substances
decOmps. RAW a few hn. at the usual tinnp, Only a~
lower temps. do they remain undetompd. for a Inapt time.
The furforylidiene ~ompd. is relsti
vely mom Stable.
The U were quantitativwly bv&olymd to it spli
Itinig ff
the ar(nnatic aldchycle and NH,.' by dill JICI. .. Phcll-
UNHOCCUji, from A~,O In at.0 soln., M. =S*. '],he
following n were prepd. (ArCH Siwn)
btsSA&ne, M.
tY3-7'- cixasmyl6kne,
m. 97."'; jurfaryJidexe, rn.,'
I 11-12 Anid-ldebY& and P-McCJWHO give under
Simil;;; conditions OWY viwwa, -o-cwtallizable conden.
sation producu. F. S. Bois

P
U
j
_:"Ifto Isaalvd~ L~ at
'
I
IT
ftuay nis Sti RU
auction of bewil otiotutraia I,
-id. bulgare cf.
Bull. insf. chint. ~c.
47,2154a 4W
In 3 ral ThINHNI-11 wazi.ls-aited tot-21M..and thL- infxt~ dild;
with &011 tn :give crystals
:'
pt

in. Z10-2", Redtiction
ist 1.0 W. t in Ito i6l. Ltib:
' ,
C
-by shaklug 0.5 fir. with,0A g. P&O
Vir V4~% (III
-
-
'
~
b
k
--nx;
16
iole
tr
d
tri
A
(M),
toM as~zdlmt :.'ii% fl.ffihd 48%
LtOlf-RiO (10.

*
was obt:suied; 0 hirs, shak is
'
f
9
w."' Rdadl"
a Ituall 4mt; of p)
IH With d
O
S
f
,
dwpunded In 25 ml. PtOH with 5 sial of .50% a
:1U17o KOH coat:4. I g. Z. dwit pit 6.4 PWiisil ai lital
If.
-
ted"Aian
41 ~ under Uniet coW
of 0
r R
111
il
i
f I
itloiiiiL faUd
l

.
iv
tict
on o
3M)
glvv
'04 i
zft
11
11
t
d M
l - -
"04 14 So
i bi
i
bbLd
en
iv
x
t
so wi
' i-
fide a
, aa
.
P-1
bL-
Ahrouglia soln-of I ia WOUcktirifisix coca 143.hssl'~
"
~
i
1
1
11
"
IV
U
%nd
3
sides #4
1 a 6 contig. am
4
i C2Iffj4
) W
(
=
trilued; when HIS was bub
f" on!Y 3-3 intm, a Lirv,;~:
aint. of TV, ("up. crystals,: at. 12041, stepd. 1 Y treai* 4
vrith (NII4)rs pvc M after kkliflcadn Mth 190 ; 1 rtdii c~
tion of IV with Za wW AcOH also gAve M.'.- V~:~ T h6 "d il-
zatfou of a- da4 "eaA phadylasasniss ft 2A.S&WMAII.

K,
U;:

L
Z~ t.. ~l f:

A

H

;i;j -C,,6jj;ratfoa ts ad out
16 fit, -:1(j, CXP C;Irr
AcIO, EtD~I~, Cilli, and RtOH-CIIClrH%( with. Pit
rvu of litilzil
ovL~r c:hamoat as catalyst 3hmied that the P-la

- ibereforn t4e :P- and wfcmw
than thL t4-furm, M.. 219',
must mpr~eut me,iya Euid axis arm, rest). ~ The catIlYst
(0.25-0-5 g.) vru "uspemded in asoln.'of
rul. scAvent, the mixt. refluxed froin 311 to 48 brg-the prod-
t~c- was ijl~crcd hot, lc filtrate evapoi. to dryness, aod.Ahe
d
C
taken up with the Av6f lddir~olve tbc trinvil
bills the unreactiml 11 nainitil insol. Meguerian
G.

_NAY, .5,

H

5,

ONE

Ham 19-11
View pos
V F T
and n,
now Voiad Itobe
'A

051
yucw&, Add$.' Al 7i

C
KWU-1-
g. I.
d N
?
C
d Acoll in

N11,
tt
.
.
(;f~_d,jcd) is idde&2Z 9-,~P'j
d 10 m 11; t' a-
of Xylem
c
1)
c
-
1
. Id We infit. hote
15 cc. x1lole. at
widn.o(0-04 l0tia"an"I'AtCl 1 C41..
n
th Iter the
0 (150
d 41
b
a
.
A
is continucd 3~4 firs.- With C.
-wakhect.: w6t
"
to
,
and the t
TheacfY1jatLo1d(VAfCJl: It
tiyt& froth
r
i
s
l
ful
ppt(l. alul
Art, Til-P-
o Ar
,
Hr
Given
L
c
30
010_'ll 'hie
132

j. ji ~~i

,
-
o-clollb
i0a,
p, Ill, 21MA"Aal
1.
e
Tile r4r.1

k.

'ti

6-4
55 -61(1054
Lo,N
Ph'.,,. added
Lq dis~6WW In

the
PP,t-:
e0d. in 6L5%
4ad
'
if the
Xll;
cHphcrtpfi-

e-jhe dlliydro
A
i
-
'
-
iul 14
g.
A
a la fh~
RtIon pr6duct,

:ahd acidified

:
A
a taAtli p1)- in'. J

_op iy
a
n
!ihsl., chins..
Akad.::-Nduk
f ~O 022."tuble
,was treated

q.,

I
~
i

-7-

~'ATF.N

-J.
"s

i:
B U
In the presence of NaMs And 4ridei ief!Ux;` When the i 6

,, 'i
fit Ctlfi 4'
sion W almost disioptued (10-15inio. r d N i. I'.
,
.

th
to e truxt.;~
RtjO), 100 g. i66 cuid 20'C.-NFrAC1!w4 dddw
the filtered, su~peuded in2 HgO and, treated. vvitfi'ixoti,~
')CHR'CO
V
l
R
H
1
) wal.
- (
l. - COH; - the pptd "
CU(NH:R
d
s
' "
(R
~-recrystd. from ale. The (WaWl were prod"
-
21 '4iP'
R'
-A 'A
i
nd Ph 171
ld
-
e
s
are
, a
j
ftbm.PhCH:NPhi(HC
from -P-
Q%CI1iNA?;' 0101-
1814*
5217
m
CI1 ---- ---
.
t
,
s
,
Ph. tn. 189--00., 56 % froin Ph(.H. A. : ar.
' N
h
l
i
h
168-400% ;
3in PhCH
Kap
eljf%(~
t
Ph, ;fr
y
CHCI 0'. Megiler
M.

SPASOV, Al-.-L ROBEV, St.

::G
COUNTRY
CATEGORY Orgaric Craemlatry. Synthetic,oi~gani6 .6mmistry
AB-5. JOUR. Az,4,,Uh tia 1~0. 23 193~,
U 7 a c A. Parlwro tova, B.
It , t
Iril'o-rar" tion, o f t anui and 6rc-an6vi to. es ilu~l-
Lac

ORIG. YJB. CrodisAaalk Sof un- t Piz.'44aa tem f ak.
~ ~3 -' 8
7-101,
195'-191 7: (1 9
-
1
u 'of P:~~l ac t
11, 4tilh 0 - b o 111 rug : 1. 3 ho ra j ma -of or
OITI piian~!:) Cunllnut~xi6p ionic acid
wl-lulh 2 mclas-of~~C6HcV:TgBr, a :0,,*Axt,u- t9;, of an
10 Oll I ub d-MuTude;
ke tone Cl( 11 . t - Z)
(G-6E~ 0006 P
f45
"
1.47
0 fb
p.

:,`
a 1 pea, id ~tlqal~ to
~;w y L,~~ Ga corap6iiiiii 15,
l
vionsl,yr obta ln6d -conideapaqbj-olli r,~bp bbiazy.
ideiieplniline 'kid.--benzyl-phop, --tono (II

R I
G
C' T2G C, Z'
ADS. JONJR. No. 23 1959, VF-o. 8~308

I
l ,
I U
i
HL 0 IR
T "~',S T .
T I Tr L T
ORD'7. PUB.
AESTRACT with !V in X-Y101 it. gives urcftiaz~lne, zr,:.
cont d
1'5.5-1570 (from
aqueous
C'~ D. Vit-
~13COO
1)
Ic~ V'~'~Jy ;

Ji T.
jj

U~y
-j'-TR.
T "IOR
i
iPBST-PbOT
cont Id.
C A RD -
G
FOY91im-41 Flo. 196o) No. 1258
(decomp. and dinitro3o derivative, M.P. 136-
1-3-10 (dea(ZIP.; f2on, ether); -upo'n h6ating- up-to
2000. 1 i,-: decomposed into aniline :and. II; on
ho ale
ting (1.5 hours) vT-Ith YSCY4 In aq. ohol
acidified v~ith HCly a thioureide derivative, is
0
obtained, ra.p. 193-1950, cyclizingiat 220-225
IM-A, to :1
"dth SplittLig of f of 3,4,~5,6-penta.-
phenylhexahydro-1,3,-~?'-trfazi-yi6~th-loii-2, ri.P.,
236-237' (froya alcohol-CO14). ,On the Ir. asis of
2/5
G-29

. i -I!Y
c
c U.T
k,, J. GMY
1960 No. 12~58
JMUR. RMLim.,
OR !G. PUB.
ABSTRACT Is poured into a 3olution of:6.02 mole of
t1d G f
Con CH2GO011 in 30 ill Of C6H6 and, then~heabad d 101,
min, 0.01 rnole of Il is added:: and: heated aga in
-er is added arid2 frbr~ t1 1 oov-E;anic
for 3 hours, wat
layer I Is separated, m.p. 176-177,9; (froi
hol I vmol e of III 1 0, 01 mo'16 of L C611r~NH2: and
22 mmoles of IM21,71a in 30 ml Of C6 heated
r
for 3 hours, 0.02 mole of II I n 1 ml oi. C.,Z~~
CARD
4/5
J0

Distrz-':~.4ml (J)j 40d

-aldlehy es.and
d
romal with'aromatic
;,oCondensation of b
.
-
mmonift. d ~ Iv.; Ivandv. :Rsdgar.'Akad.
au
~V
~-
6. lurOMM).-To OA mole
d
.
Xauk. I;.

aldch;de and OA mot bromal Is added 4 m1.25% aq. NHa
e
1
:
) ,-.
Idropwise and the solid filtered off after 24 hrz. to gi7e RCH:-

i'
NCH(OH)CBra (1), crystd.- from Cal-Ta. The following 1:
or, pr (R. m.p.. and % yield given): ph (u), ui-ww"
0'
119-206 a- I
129-31% 44* o-MeOC4114
eCA
,
" 10
1.9 g') In
fury . 125-6*,.-; o-HOC
4M: 135%
*
ml H th tif 2
tjo with I C.AcCl in reswce F 3C gives
anYi aen up In Rj~'
lefUtered off
a one hr
1,
which after
t
A
.
.
.
e fly layer, then solblifiei In a few
t7
1
1 H:O; it Ist forms nn ol
hrs.; crystd. from 70% MOR it gives -N-be-myliden

J acetylbenzaidiamine, m. 134.5% AThe~ Et:O Mbmte yields,

'I
235-7!'
Similarly :
benzylidenediacetamidO m
on evapn
.
-
. ,
.
149- and;Ms-
veg trie eawyl analogs
M
BzC1
1
~7 Fi
!csp
.
.
,
9
:
-Me
~G.

-Y

,
J
.
f-
:tji 'i" T!..,
! u I...

IMMI-mi.- - . - ''. mmm~~

SPASOV) A.; GOLOVINSKIY, Ye.

i',EDVEDEV, I.A.; BELIGOLI,9KIY,-B.P.; GLIKW, E~S.,,
TOLSTOPYAT, A.A. . I .-1 . I

e. f - .3 ~mWj

e-o
Iff
Lfic

%E 16

1
F- `4 NO

Tzl
i, AJ
V
Icki '331')
'
l "r
�

hi 0
und Margadtm
Affv- !p(mva G14ki
ya

it
1058) -Electrol
tic
bjjCu;
,
y
,
phases: .4-
were Combined below 400q-to fonu Abe folluivink
"
ith of
Sit.; Thigra,
Sit' and.,, 380,
5. 32.5% Sit. ~60.69,
1
i
ti8fic I
i
h

'
-:
i
t
e c phase pro,~eeds accor Jing, to thit par.1
v (Y 4,t
fludependeli&:61 th~:Ltiffusiou On
2pl). Front the exponend
'
'
~
fir
ni
dctd. (Q: -x
temp...the actimdon: ener Y W thc*a phuse
,
'.
T?
~
v
P
l
b
22
5W
6
d
.a
o
e
tiergy
al) he- correspon
t
ca
, t
./g
~ a
ng
,
400- is 14.Z czil~/g~.afrna- This Aiscreparicy isin arr
'
-
949i
ment with Bugak-ov
o?: 'bv:APjdh and Alloys I
(DjjAh
1). 149 (C.A. 47, ijMlfflaud Scith and Loptimfin (CC:47.:~
'
'
Wetals. J~.
8-1b) who studied the -roctl
ve diflui0ii of o0er
:
plidei and 0~4,40& is~
in actl
renct: vattowenergy
Tile difre

8
~il
,
"
l'th
hii5is
d
61
th
e
bqm6r
th
tu
,
,
ue
e na
o
1 Iinge in.
r
e
e ~
,
y
p
N
_jt
Ji

:
:
:
t 14
;'

-3
S 1 7/62-/000/003/112/191
~A;6601AIOI
AUTHOR: Spasov, A. V.
TITLE: Effect of pressure upon aging of aluminum-co1pperalloys
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no, 3, 1962, .13, abstract 3184
("Godishnik Sofiysk. un-t. Fiz.-matem. fak'.!!, 1959-196o (1961);
54, no. 3, 55-506, Bulgarian; German summary)
TEXT: Alloys of Al with 5% Cu were investigated. 'Spec imens in the:for%m of
cylinders 10 mm diameter and 6 mm high were subjected to~hardening in water from
0
a temperature of 520 C. The aging occurred at a pressure of 10.~'tons/cm?- and
temperatures 150, 200, and 250 C for a period of I to 56~hours.' It was establ-
lished that pressure accelerates the process of formation of Guignet-Preston
zones, and that in alloys aging under pressure the hardness is greater than In
alloys aging under ordinary conditions. The quantity of~cu settled in the form
of CuA12 under aging at 250 0C is greater in specimens ag" under pressure. The
X-ray structure analysis of duraluThin specimens aging under pressure has :indi-
cated that in that case the pressure inhibits the procesises of formation and-
Card 1/2

V137/62/000/008/037/065
1~0061-4101
AUTHORS: Spasov, Al. V., Dekov, Il. D.
TI=,,: The effect of pressure uponthe aging of aluminum-zine alloys
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no.'8, 1562, 311~abstract 8121b,,
("Godishnik Sofiysk. un-t, Viz.,-matem* fak 1955 1960 (1961)3
v. 54, no. 3, 75 93, B~lgarian; summary &~German)
TFJT: The authors studied the effect of 10 t/cm2 pressure upon aging!of
an Al-Zn.alloy containing 30% Zn. The-Investigations were'~made in three direc-1
tions, namely to determine 1) the effect of pressure upon natural and artificial
aging at 100, 150, 200 and 2500C; 2) the effect of pressui~e upon Ithe formation'
of zones in artificial aging at 100 and 1500C and bone growth when'there is no
pressure; 3) the effect of pressure upon the growth of zones obtained without
pressure. It was found that*in natural aging the hardness chang6s,insignifi_
cantly with time; in artificial aging hardness decreases-with time. The hard-
ness of specimens, aging under pressure, is below the.hardness of specimens
aging without pressure. Thus, pressure inhibits the aging, procesrvin. AI-Zn allots.
[Abstracter's note: Complete translation] V.:;Srednogorska
Card 1/1

:~., - I
"S3tablisiment of the RaLionalization Fund -in Same C(muneric&I Enterprises

S/081/62/000/024/001/052
BIOS/B186
AUTHORS Gerasimov, Mikhail, Petrova, Yelisaveta,i;Dobroyski' Ivan,
Spasov, Groadanp V111chev, Dimit"r
TITLE: Bulgarian oilt composition with regardto str tural Sioupst
uc
and properties
PERIODICALs Referativnyy zhurnal. Khimiya, no. 241 1962
:114, abstract!, I
24M129 (Nauchni tr. Viesh. in-t mekhaniz' - i elektrif. sslskoto~
stop.-Ruse, v. 4, 1961 (11)62), 185 - 19.7'[Bulg.; summaries i
32
Russ. and Engj)
TEXT: The methods of Van Nee - Van Weeten, Cornelison Wat orman, Kura~-
Ward, Robert, UmstAtter, Gilyazetdinov, and Dineley -Karlov wore used to
determine the composition with regard to structural groups'of the 5,..fr
%
tions of Tyuleniy island ortide oil, which is a typical hea* oil. It was
vy,
found that none of the above methods is superior to the others.. It is
shown.that the Tyuleniy island crude oil is rich in high-molecular paraffin'!
hydrocarbons. (Abstracteres notes Complete*translation~
Card 1/1

S/081J62/006/024/003/05 2
B108/BW
AUTHORS: Drenchevo Nedelcho, Spasovp Grozdanq Lyubenov;, SLavi
anufactured ~~troM
TITLE: The performance of gas oils m Tjruleniy crude*, oil::
PIMIODICAL; Referativnyy zhurnal. Xhimiyat no. 24, 1'962, 714," abstract
24M131 (Nauchni tr. Viash. in-t:mekhaniz '.i el!ktrif Selskoto*
6 n~
stop.-Ruse, v. 4, 19 1 (1962), 199 -~209.~[ Bulgj sumaries i
Russ. and Ger.3)
TEXT: The kerosene - gas oil fraction of Tyuleniy crude oii:,(FTO) hax~:a4ow
cetane rating (CR) (^a35 - 38). Every 10% of~high-cetane RW~anian gami oil
added to the FTO increases its CR by ^j2 units. The 4dolcentrition of'~butyl 7
nitrate required to increase the CR to 42, - 46 is 0.5
PTO produced,
by vacuum distillation has a slight teniency to formation of:scale and
lacquer. The turbidity temperature of the*FTO is