SCIENTIFIC ABSTRACT SRYVALIN, I.T. - STABNIKOV, M.V.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

AUTHORS: ,Sryvalin SOV/JL@9-58-4-9/26
ynf
Nikitin? YU.P.
TITLE: Thermodynamic Characteristics of Molten Copper-Nickel-
Sulphur Alloys (Termodinamicheskiye svoystva rasplavov
sistemy med' -nikell -sera)
PERIUDICAL:Izvestiya Vysshikh Uchebnykh Zavedeniy Tsvetnaya
Metallurgiya, 1958, Nr 4, pp 66-72 (US6R)
AB@3TRACT: The object of the present investigation was to obtain
data on deviation of the Cu-Ni-S melts from the ideal
solutions. This was done by measuring the emf of the
concentration cell formed by solid nickel (99.9% purity)
on one side, and molten Ni-Cu or Ni-S alloy on the other.
Molten acid slag containing 2Wo CaO, 300,75 Na20, 33% Si02,
151,1,@ A1203and 20,@ NiO was used as the electrolyte. The
experimehLts were carried out in a fused magnesia vessel
shown on Fig.l. The metal electrodes were contained in
two vertical channels connected at the -too by a central
compartment filled with the electrolyte. The lower ends
Card 1/3 of the vertical channels led to two inclined channels

8o V/ i 1@9- 58-4-9/26
Thermodynamic Characteristics of Molten Copper-Niclwl-Sulphur Alloys
housing graphite leads and filled with a neutral slag
protecting the metal electrodes from oxidation. The
results of the measurements taken at 1340 - 13600C are
givea.in Table 1, for the Cu-Ni alloys and,in Table 2
for the Ni-S alloys. From these data the activity of
Ni-Cu and S in the Cu-Ni and Ni-S melts was calculated.
The calculated activity values were in good agreement
withthose obtained by Vollskiy (Ref.2) in his
investigation of chemical equilibrium and with.the
published data on the equilibrium..diagrams..of--the Gu-Ni
and Ni-S systems. It is shown that the equations of the
ideal solutions are not applicable to the Ni-S melts
which however can be adequately described by the
expressions derived by the Authors (equations 10 and 11)
in which non-additive character of the bond between
dissimilar atoms had been taken into account. It is
shown by comparison with literary data that the
activity values of Ni, Cu and S, determined by the emf.
Card 2/3 method, are iia good agreement with those determined by

@j
SHITALIN, I. T. ; i 0. A.
0 ipimenenii prosteyshikh popravok k formulam regulyarnykh
rastvorov d1ya metallurgicheskikh shlakov.
report submitted for the 5th Physical Chemical Conference on
Steel Production.
M G -, r- C) w () J@jj 1353
- 3

SOV11 6 )3-58-1-8/53
AUTHORS: Nikitin, Yu. P., Yesin, 0. A., Sryvalin, I. T.
TITLE: The Capacity of the Double Layer at the Boundary Between the
Aluminum and the Cryolite-Alumina Melt (Yemkost' dvoynogo
sloya na grardse alyuminiya s kriolito-glinozemnym rasplavom)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Metallurgiya, 1958,
Nr 1, PP 37-39 (USSR)
ABSTRACT: The capacity of the double layer at the boundary between
the aluminum and the cryolite-alumina melt was determined
by direct measurements at different composition of the alu-
mina melt. From the result may be seen that a decrease of the
cryolite ratio to 6 - 1,9 does not at all influence the
capacity, whereas an increase of the aluminum oxide content
considerably increases the capacity of the boundary layer.
The dielectric constant E of the boundary layer was measured
(see Table). In addition to the capaaity the resistance and
the diffusion were also measured.
When the cryolite content is changed no considerable change
Card 1/2 of the diffusion coefficient takes place; a change in the

SOV/163-58-1-8/53
The Capacity of the Double Layer at the BoundaW Between the Aluminum and
the Cryolite-Alumina Melt
Al203 content, however, increases the diffusion coefficient.
There are 2 figures, I table, and 12 references, 12 of
which are Soviet.
ASSOCIATION: Ural'skiy politekhnicheskiy institut
(Ural Polytechnical Institute)
SUBMITTED: October 4, 1957
Card 2/2

24(8) PHASE T BOOK 4@:FLOTTATION SOV12809
Akademlya nauk SSSR. Otdeleniye kbimichaskIka n&Uk
T@rmOdLn&Mika t Atroy4niy;ur1%stvorov; trudynzoveahchaniya...
(ThermodynsalLs and St oture of Solutio ; Transactions of the
Cottr4ronce He January 27-30, 1958) Moscow. lzd-vo AN SSSR,
1959. 295 p. 3,000 copies printed.
Id. I N. 1. Shaktipamnov, Doctor or Chemical Sciencea; Ed. of Publishing
Houses N. 0. Yogorovj Tisch. Ed.: T. V. Polyakova.
FURFOSZ; Thla book Is Intended :or physicists, chemists, "d
chemical engineers.
COVZRAQX: ThIs collection of papers was originally presented at the
CoiLrer4mas an Thermodynamics and Structure of Solutions sponsored
b the Section of Chemical Sciences of the academy of Sciences,
%SR' and the D"wrtment of Chemistry of Moscow State University,
and hold Lit Moscow on January 27-30, 1958. Officers of the
are given. Among the problems treated In this work aret.
*I*Qtvol7tic 501utiOnAt ultrasonic measurements dielectric
and thermodynamic properties of various mixtures, spectro-
scovic analysis, *to. Reference& accompany Individual
if-the IF
I M I Present Prc@imms hormodyn a
ry q.%tJ Mok or Momolectrolytes 36
JkZ1bQX--Y--2- Fluctuation of Xnargy in Solutions and Their
-Ul-atLeato deat Capacity 43
Fisher 1 3 and 1. 1. nsstiah. ftleavlar Theor7 of
iiiaikii-=A 48
ahavakir. 1. IL. and Critical Ph&maona
In Bin"7 Uquid Systews 49
_AQzdmt-X-Y- Study of the Critical Stated of Individual
Componads and of Their Mixtures With the Aid Or V!t-vsonio
methods 56
end rS a jLt- Phase Tranaltlons in
LIU I
if.,
.-SIMpla systems and Their C&& a as on 6T
US* of '01100sonic Measurements In the
T2
and K. 1. Zemborsk. Transformation of
Binary Rotero;i9otrop-is Int-G-To-m-0-a-z-oo-Cr-opes and Homoz*OtroPes 79
and A. 0. Moraoh@@ Applicability of
KDnovslov-d " VrovaRI-Y'd-LU-4to-Torna" Solutions 87
aud.-?,-MZhuLM&- Relation of Thermo.
dynamic Properties of Saturated and Wearly Saturated Ternary
Solutions to Their Composition 93
Mj&h%b&%kor46-4P. Thermodynamic Proportles of Water in
-Bolutions of Ilectrolytes 9T
j!1'Wqy_j_A__pismociatLcu or lisotroi7tes in Nonsqueous
4"Lons 105
3- and-U.-P. Ivano-va Thermodynamic Proper-
Nankausous Solutions--or-110-at-rolytes-,-,
V. A Kronor L. M. ftt$yna, and Yo. ;r.?Ito..
Study of the Iffect ci Solvents on the Strength of Acids by
Reams Of Optical Methods 122
M
jkqjjnkIx,-S-P- Dissociation of Aolds &W Complex Compound~
6114 Methods of Studying It 126
K
1jA-JQL Change la ThArobodynamia Pumotlono in
S
So I
OOLMLOn of Zone In Solutions 133
in"@@ Thermodynamic& or eAquacomplexaso 140
-Wawal-And- Study or ipartial J;@jjsqrs of golvont In
A"Ov" solutions or 9140trolytes
144
Inn UtGracti0fts Of FrOtOft VIth MOl6GUlQS (Water.
ant
152

3tyrikovich,
M., A. Study 0.1 SolubIll-ty OV Low @Glatlllty
.
Compounds In Water Vapor Under High Projaure 151
3hchukarov_S--A-, L. @S. aml V. r. Timorezicy. Change
T"he Isobaric Potential When Salts Are Dissolvdd In Wator r@7
Jlarkw,-L-3@ 1freat of Additional Components on the
Solubility or Compounds In Mixed Media 172
Akouftov and YjL.V.Pylkova. Solubility and Super-
@Xs, I. #
Saturation IR the System SoEta-Su-Irste - water at High
Temporaturen 176
and 0 A YeaLn. Application Of the ThOcrY Of
-
@
ra@oltls
i
Ideal Solutions to 140 179
ar4(0.--k@Y,&wIn. 3yatwo With Positive-
SCOMLIn
X
T
...
@
@
142T59199MIons 7rom Ideal Solutions 182
gajbwQVoa_j_A_ Thgraodynamias of Ionic Solutions With an
186
Arbitrary Number or Anions
T&IklL#. D. S. Solutions or Monalectrolytes at Superhigh
Prowmares Igo
Torr4osove. Q. D. Solubluty of Gans@ In Liquids Under Pressure 198
@, and Y_,Z--TIk&vyV-The Relationship
Dis. metric and Thermodynamic Properties of Binary
jjg@
RLatures of Polar end Monpalar Compounds 203
q@ L.,and _q_a-Arlka.- Thermodynamic Properties
7(ftarabinotj,
-
j
ions, of High-Moleaular Paraffin Hydro-
a"7SE-n-ictures of Solui
"Awas in Bensose, 20T
Z Viscosity and Structure of Solutions of Man-
215
Ilkv A. Z. Viscosity =0 Structure of Solutions of
-
7'"
-
3170et"VF%F6@ 219
SkOkAPA""v, 1 1, Polarization " Structures of Solutions 224

y
@% trU*tUM And Crystallization Nochaniza of
ft
j? -3
d
t4F;t
U: 228
Molecular Dispersion of Light La Solutions
or somisetrolytes 233
P and-M. 1. thakhparomov. Verification of the
of Moledular DIapors1o-n--or7Zrgff-Vy Means Of Binary,
Solutions 239
Take N F AnisotPuple Dispersion of Light and Its Use in
-0
quid. and Solutions 242
Mlahah*nko. K. P., and A-N.-2=az&rsva. Partial Nol&l
troples In Sys ons koeti-6 -Acid---irAf-er and Pormla Acid -
Water and the Structure of-Th-o.&* Solutions
-
-@ 246

in M.
@-W
. Spectroscopic Methods &F -Studyl,, tab
Mrn@.wj% .1 so
251
SVO0tPO06OPI6 Nothads for Studying Complexes In
258
id V V kova.
-"11RMF
M , -T-E-9010-kov, W4 L-1-Romd

ullf
*It ORA
&P7Bii *On glectroal-rAbSorption SV8-Gf-r&-A=d
Radiation of Solutions of org&TAO CaRpounds And the chemical
Bats" of solvents i 262
31 and r. 1. Aq Study of
0ail.al
$or. 0"; Nhath;., M
Absorption ftestra 266
Atudy of the Effect or the
earro ng US ON the 3tate of the Chrome ran by Means
SPOGtPa Of Solutions and alum Crystal*
-
-
-
-
- 270
Ch
em
w
ya
okays, and N
trs ei V. Chornaya.
porm
Id
"
e, 273
T vao L- D. Darkaohova, and
4242M
Rw-
" -
C-
..
IX
so by z Assoc"trOn -CVnUftTV%td
Me Of Ab&019tisu And LIA"n .... ace

2?5
low L arreat. or 1OnI2&tLOA and Association on
of Complex organic MOI.Oule,
28r-

1,9(6)
AJTHORS - Sryvalin, I. T., Yesin, 0. A. SOV/163-59-1-2/50
:'LTLE: On the Most Simple Corrections to the Equations for Regular
Solutions (0 prosteyshikh popravkakh k formulam regulyarnykh
rastvorov)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Metallurgiya, 1959, Nr '19
PP 5-10 (U35R)
ABSTRACT: In this paper an attempt is made to find simple extensions of
the formulas from the theory of regular solutions, which would
permit to extend the range of applicability of these formulas
considerably. At first the influence of temperature is investi-
gated. Formulas (2,1), (3,1); (4,1), and (50) are obtained
for the heat of mixture a H, for the excess entropya S', and
the excess isobaric potential 6 z'. From these formulas it
can be seen thatA@@jzl is linearly dependent upon temperature,
and that the relationship betweenA H,Anzl, & S' and the
composition of the solution is also linear@ Subsequently the
consideration of the deviation from the additivity of the
bindings is in*vestigated. Formula (1,2) for the energy of
mixture,a E is written down for one mole of solution ac-
Card 1/4 cording to the theory of regular solutions. In this instance

On the Most Simple Corrections to the Equations for SOV/163-59-1-2/50
Regular Solutions
it is assumed that the atoms interact by means of short range
order forces. It is further assumed that the atoms are in a
state of statistical disorder and that in the calculation of
the energy of mixture the rule concerning the additivity of
bonds is applicable. Attempts are made to estimate the influ-
ence of small deviations from the rule of mixture for indi-
vidual bonds. Pormula (4,2) is derived. In this fcrmula,
denotes similar as for reCular solutions the "energy of
mutual exchange", whereas q denotes the deviation from, the
additivity of the binding energy between different atoms.
Assuming that the entropy of mixture is identical with that
of an ideal solution, formula (5r2) for A z' is written down.
This formula specifies satisfactorily the thermodynamic
characteristics of the isothermal lines of a number of
silicate melts and of sulfide and metallic solutions (Ref 1O)v
rihich are characterized not only by asymmetric curves for
,(Azi, but also by deviations with change of sign. This
formula does, however, not express the dependence of A z'
upon temperature. It is assumed that temperature takes a linear
Card 2/4 course and thus formulas (6,2), (7@2), (8,2), (9,2), and (10,2)

On the Most Simple Corrections to the Equations for SOV1163 -59-1-2/50
Regular Solutions
are obtained. In order to elucidate the practical use of
these formulas, the three systems tin-thallium, tin-zinc, and
sodium-cadmium are investigated. The excess isobaric potential
for the first system follows a linear relationship, that of
the second is described by an asymmetric curve5 the las!
system is characterized by deviations from the ideal solution
with change of sign. Q and q were determined with the help of
activities of one component of two mixtures found experimen-
tally, whereas for the coefficient k (a constant which depends
upon the nature of the constituents of the mixture) the
experimental data for A z' at different temperatures were used.
From a comparison of the experimental and the theoretical
data follows that the system tin-thallium is an example of a
solution, for which -A S' differs noticeably from zero,
although the isothermal lines of the activities follow the
rules of regular solutions. The system tin-zinc exhibits a
close agreement between the activities of the components and
those of the enthalpy of mixture, which were computed according
to the formulas (4,3) and (8.3), presented in this papers; and
Card 3/4 the experimental data. For the system sodium-cadmium the

On the Most Simple Corrections to the Equations for SOV/16)--59-1-2/50
Regular Solutions
computed values for A z' coinaide with the experimental
values, whereas considerable deviations in the values appear
forzN H. There are 3 figures, 2 tables, and 13 references,
7 of which are Soviet.
ASSOCIATION: Urallskiy politekhnicheskiy institut (Ural Polytechnical
Institute)
SUBMITTED: May 15, 1958
Card 4/4

SOV/78-4-4-28/44
AUTHORS: Sryvalin, I. T.; Yesiii, 0. A., Kh-,,yriov, V. V.
TITLE: On the Deviations cf Molter Silicates From ideal Solutions
(Ob otkloneniyakh rasplaviennykh silikatov ot ideallrykh
@-astvc-rcv)
PERIODICAL: Z@urnal neorgariicheskoy kl,,im-"-'* , -1 0,59, Vol 4, Nr 4, PP 877-383
(USSR)
ABSTRACT: The deviations of molten silicates frcm ideal solutions as
well as the acti-;-tty coefficients were compute-- by
the follo-Aring sem-i- empiri oa 1 equatiors:
RT 3-r (2Q-q)N2 (2q-.2Q)113p and
2 2
2
RT 1-r (2q-Q)N (2q--2Q'N@-

where T denc'es the ab s o l"It. etemperature, R = gas zonstant,
-- trcle fractior.3, Qq = coefficient-s of certain physical
r
2
@
l
importarce and N VN2 = number of the a-@oms A and B. The
Gard 1i'; silicate melts of the systems FeO-SiO PbO-S-:O,, and
21 4 Cao-S'02

SOV/78-A-4-28/44
On %he Doviations of Molten Sil@ca@es From Ideal Sou.,ions
- were 'nvest-igated bi, means of the@3e eauations. The
1.1ge.-SJ O,@ V -
aLti -@y @::f Sio2and FeO at 16000 was calculazed and I's listed
--D tlable 1. The values agree well with publications. In the
.-M PbO-S-*0 he activity at 0000 was calculated and is
2
repr@-sented in figure 3. in this system t"he authors observed
posi-,--'ve and negatilve deviations from the ideal solution, wi--.h
P',-- 0 ; -,v, -"*-le @hey found only positive deviat-ions --*n the cas-= of
S.,-O.;. The system-s CaO-S--'O2and MgO-SiO2were the-=Tody-.,-ar�cal-'y
by detezminatfons of the activity cf CaC and YgO
-3-'; and "700:-'- Figure 4 shows the negative deviatic"a of
the mel" Cao-s-*.O, from the ideal solution at '16000. For tho
higo-s-io Lhe authors computed Q and q according to the
2
0.
G-F @-.he corresponding liquid phases a' 17100 Th@
app'-f-ed and the results of the .3omputatfon-
nf and q, in a table. There are 4
alb I c U.
., - -r.;, and 14 referenr;es; 11 of which are Soviet
SUBMITTED: JanuaTy 17, 19,58
Card 2/19

5 (2)
AUTHORS: Bratchikov, S. G., Yesin, 0. A., SOV/1631-59-2-6/48
Sryvalin, _L,-T-._
TITLE: The Thermochemistry of Melted Lead Silicates (K termokhimii
rasplavlennykh silikatov svintsa)
PERIODICAL: Nauchnyye doklady vysshey shkoly. Metallurgiya, 1959,
Nr 2, pp 32-37 (USSR)
ABSTRACT: The specific heat in the PbO-SiO 2 melts was measured in the
0
temperature interval of 550 -9600 in solid and liquid state.
The average molar specific heat and enthalpy for melts of
different compositions are given in tables 1 and 2. The
dependence of the melting heat (L) and enthalpy (6 H T
298
on the composition of the samples of the system was investigated
and is given in figure 1. It is concluded from the results
that stable compounds with the group Pb-O-Si exist in the
melts. The experimentally measured c P-values are higher than
the additively detected ones. The results concerning the
enthalpy, off the specific- and melting heats confirm the fact
Card 1/2 that the melts represent compounds with the structures

The Thermochemistry of Melted Lead Silicates SOV/163-59-2-6/48
PbSiO3and Pb2SO 4* Several thermodynamic parameters
(characteristic values) for the melts PbO-S'02, as e. g. the
heat (& Hx), entropy (& Sx), and the isobaric potential
(& z.) Were computed (Table 3). The dependence of heat
and entropy (6 sx) on the isobaric potential ( 6zX) of the
composition of the melt PbO-SiO2 ras investigated at 12230K
and the results are given in table 3. Stable ag)mmetrical groups
like Pb-O-Si exist in the melt. The Laboratory Assistant
B. T. Kadnikov and the Students S. !@ Andrianov and V. I.
Sokolov assisted in the measurements, There are 3 figures,
3 tables, and 10 references, 7 of which are Soviet,
A @';30 0'1 A TT03 -UrAllskiy pDli'1qkhnicheskiy institut (Ural- Polytechnic
In" fJ, ttl tq)
SUBMITTED: JulY 4, 1958
Card 2/2

SRYV'.aLIN. I.T., kand.tekhn.nauk, dots.; YESIN, O.A.. dokt.teldin.
nauk, prof.
Component activity of molten CaO - Al20 SIO2 systems.
Izv.vya.ucheb.zav.: chern.mat. 2 no-8:9-16 Ag 159.
(MIRA 13:4)
1. Urullakiy politektnicheskiy institu'.k. Rekomendovano kafodroy
teorii metallurgicheskikli proteassov UrAllskogo politekhniche-
skogo instituta.
(Chemistry, Physical ana theoretical)

SRYVALIN, I.T.; YISIN, O.A.; KHLYNOV, V.V.
Deviation of fused silicates from ideal solutions. Zhur. neorg.
khim. 4 no.4:877-883 Ap 159. - (MM 12:3)
(Silicates) (Solution (Chedistry)')

Stt,kl.@t .--.ops
16-20 19,3,) (Vitr-J, Statc; of u... T."Irl Cv.'.-
fe,r,laae c,., the Vitrco,iv State, vicla it, 1959)
Iz4- AN Sj3fi, 2@,-;G. 5Yi P. Errata rllp 1r;ffertcd. %2C,0 coplea rrlr,--td.
Series: Its: T-dy)
Spont,oriny, hgeneiecz Inatitut Vt!-i JIij,.fttov Ak.d-il ,.,.k S`@R. Vacloyuznoye
blil.ich"k.ye obith,-h-t- inzc@@! D.] . M-delcy-. and G.-durat,e.,,yy orldenm
Leftinu optichcc@ly inAtitut !-sli 5.1. VQv7IIov".
Editorial Board: A.r. Aviru3tinlk, V.P. bartriko-kly, M.A. Bczborodnv, O.K. Bottrialln,
V.V.Vargiu, A.G. Vlftsov, r.S. Ye-troplyvi, A.A. Ecb@d-, X.A. M.t,cyc@, V.S.
HOIch-W, R.L. Myiller, Ye.A. Poray-Kt,vdiits, Cnalmrn, N.A. Toropov, V.A.
Florlilakaya, A.K. Yakhkind; Ed. of NbIlohing Ho,,=c: I.V. Suvorov; 71"h. Ed.:
V.T. Dochever.
PURPWE: This bocilt Is Intended for researchers in the science and technoloa of
glosses.
COVE31!4E: The booL contains the rel4rts wd diac"aloan of the Third &11-Urlion
Conference "i the Vitrcojo State, held In Lenin4red otl Noveta-har 1(-19, 19"9.
'nicy deal with 'the methodn and result- Or utudyIng the &tr"ctum of glaccea, tile
"Ifttlan between the atructure and prop.-rtles or rlaso", the nott,re, of the
chcul.%) boill and glass 0tr,lct.re, end the cryetlillecit-Intry of' el"a. Fused
ttillea, mocha.als:ll of r1trIfleation, optical proptrtlea and gloat: structure, and
the electrical properties of eltizuen are also 41Gctissed. A liclaber of 'the re.
porto deal with the dependenca of ellian propertle5 - cocir=ition, the tinting of
glances slid radiation trfactn, and mechanical, tecrnical, and chectical. proper.
ties of glituses. Other 1xil-ra treat Claas xcmiccud@ctora and see- boroAllicate
glasses. Th. Conference was attenied by more than 500 dul@&&tea from Soviet and
East German scientific or6railtations. Apong the particij@at3 In the d1scustions
were ff.V. Solmin, Ye. V. Vuvithinclay, Yu.A. Gmatev, V.P. J@ryrnlahlillctv, Yu. To.
Gatlib, O.P. Mchedlov-Petrocyan, G.F. Milchtlylov, S.M. P.tron,, A.N. Iazalrev, D.I.
14@1n' A.V. Shatilov, N.T. PlosbehInskly, A.Ya. Kulzlletnov, E.V. Degtycrom, G.V.
Byurganovskaya, A.A. Y@Icnov* X.M. P.Yk. DOO%ln, E.K. rxl3er, Ya.k.
Kaziu,tilov, V.P. Po--dn-ev, R.S. Shavelevich, Z.G. Pla@ker, and O.S. Molcbmo@a.
The final cession or the Conference was addreatcd by Profelizor I.I. KiteyZerad.1cly,
Hanorel Sclentlat and Engineer, Doctor at Techrlc&l Sciences. Tile rollavInC
Inatitutcs w@re cited ror their contribition to the davelap-caL of gims science
and tecilnolo,.y: Gosudaratvennyy optiche;kly inlititut (State OpLlCft3. IntititUte),
lustitut k@"I=il silikAtov A" SSSR (Inativite Of Silicate Cha,zistry, AS USSR)a
rizicheskly ltlatit,lt An SSSR (Physlca InAtItute AL USSR),
instittit AN SSSR (FhY@Icotechulcftl institute. AS USSR), Inatitut fiziki ArI IiSSR,
KII&II: (Insti-tite of Ftlysirs, Academy of Scjra"a, "lortiazV4ya SSE, Minsk),
TAlloratory of Jnylijaal C)n,mititry or Silicates Of tre Inttltwt obahchey I nacr@-J-
che.kw khi=il AN L@SF!@ '!task (Inatit,ite of Cafteral end Inor@;mlc Chemlatry,
,2"czy of Sciences, Btlor,1531.aya SSH, Kinsk.), InstItut vyGokcs,oIakul)@l-nyjlh
Ioyedlntnty &H or Hie, Molecular Corp"zids, AS U=), Gosudrat-
nYY ltlatitut ztekla (Stt-te Itatitute for Glass), Goliudarstye-yy inatitut otlk- .
lovololma (state institute for Glans Fibtrc), ColludaraLvennyy Intititut. eicktrotekh-
niche"I"),30 staklit (Stult, Institute ror ElOctrical GIvza), SIbIrAkil, fIzIkc-
techniche-k1l' In.tltut, T-k (51berian Phycle0taChalca.1 ImatItute, T@ak),Lealngrz,'-
day univeraiLet (LenIngrud. State University), moskovaitly Llosijka-
toklinologIchr,skly inatitul, (HoT-cvj Institute Or Chc=ical.
teklinOlujicilctlkly institut I. . Lsnooecta, (14nint;raa Technolz,;Ical InAtttut Imcill
I,nao@et), licloraskly poll t,kbnl c%ttakly 1.stttut Hinak (Belo-aill" Pol@ytocWa
Institute, MInall), Wovocnarkasekly politekliniViesidy inwtut
Polytechnic find Siterdlovaldy poll tekhn ichea ki y Institut (SvcxdJt;ntsk
Polytechnic In'titute). Tne Conference was sponsored by ".c Institute or Silicate
Cnezi,try I-S USSR (A1,tI.Z Director - A.S. :;otlib), the Vaesc7u-noye khtiche.ky.
obzhct,ezLvo lm. D.I. Meadelpyeva (ALI-thilan Crmaical Society i-ni D.1 . '
Y ndeleyev), und tile rma@!arvtvenrqy ordena rAnIns optichrekly Inctitut 1=cnl
S.I. Vuvilcvn (State 'Order or Lenin" optical Institute imelli S.I. Va%-Ilov).
Via 15 resolutinns of the Cmferance Include recceumendations to orannite a
CL-nter for %he purpotie of coordinatino tile research on glass, to pzbIlth a new
periolt,al -ler the title "Fizik. I khtlya otchl-" (Phy.1c. and ChenlDtry or
Glass), slid to join the Cot-Itt- on Glass. The Ccelrc@-na. thank.
A A,.L4bca'v, Artidenician, Professor, end Chniman of' the Org,nilZaLlOn of Con.
.;t el Yv.?,. F-@ruy-Koshlts, Doctor of physics and Math-a-les, Me,ab,,r of tile
Org-lt.tlotliil Cm-,Itt,-e; anid R.L. Kyuller, Doctor or Chenical. Sclenceb, Member
or tile. Ordanizlitlontil Cavrlittee. Tile editorial board thanla G.M. Flart,ne,,t.
N.V. 1"I. De,.kttin, D.P. Llrbychlti, S.K. Dilbrovil, V.A. loff., &I
B.T. XO1ccdyt,ti,. Reft,re.... acco'pany indi@llhial reports.

Vitreois State (Calt. ) SCIV/5055
Rl,latl.,l llctve- tte Str,.ture -a Prc;,rtlc@ or @]--
Yev3tr@plycv, E.S. C@-rsl of Structu-rt- und. Fro;@rtlca or Gln-ca 31)
L. I. hddAtivity of Silica Glu@@ Proj@rtica -n C@-cctlan WlUl
Tncllr Str.ct--.-. 48
Bczborc@!.,, M.A. Vitree- Sly.t-@ -d t!.c Proble= of Glaze SL-ct,lr,. 55
Nature of U,e Ch-leal Ecid will Stvzct@r,-- of Glr=er,
Hyulle.r, R.L. lnc@tor of Cn-icAi scieqcenl. Ch-I-1 I'zo;@--,rtlea of Polyv.@rlc
Giaav-Fornin,; Subowcca arld the sature or Vitrifl-ti- 61
Gory-oyao N.A., and B.T. Vol-:yeti,. Problem of VIL-Iricatioi rtej:ularitl@
In Chlc.F-Ide 71
T@@, V.V. Gl- a. a Fll)r@cr V
Curd 61122
vit"0=1 state (Coilt.) BOV/5055
eCryzta1I0thcv.I*trj or Glea,"
-Bolov, N.V. [Academician]. GlIxid Stmct,we in the LICht of the Cryatai. ch c@.,otry
of Silicate. 91
Discan.lon 98
PMED 52LICA. KrUANIER OF N7IT:'UFIC;VrI(%1
Puzed 61.11ca
AvKwtln4k, A.1, On the Ylr@blez Of CTYAL51 Ft@e Pmlition Prc= Ftued
,
' ,
Silica 115
@@Tin@.4nk O.K. VIt.-irIcatLon Frocecs "I Cl-5 Struct'@ 120
On tm Prbl,, of F,rrlda, ttlle Claso rLructuro DwIng
the I!eltln& Frocela 125
Lepincklich, N.M,, O.A. YP.3111@ and. V.I. [e-mail]. Amillotropy of Flectrien.1
Condactl,,ity of Y-ca st item ..d Por--tc. I., Fl@, 125
r-rd
vitrvouu, state (Coat.) SOV/5055
@emol.nlco, N.N. Oil the Proble.. of Gla.,s F,@-Icg 129
CbeChUlin, V.A., and C.A. YeDin. Electrolycia of Liquid Aluilnoolli-lea 129
ST It
-jvmJ1a, I.T., and O.A. T..in. Tlaermodyr-lc Prcpertieo or fNaurd Silica
-d C.0-AIP05-sioz syllt-. 130
Discu"I on 131
M.Chaftic. or Vitrifle.ti-
V010kenwhtcyn, @I.V. On tile ct"ctural ".d rl'Detic Charucturl.tIcs of tile
vit"ous state 1@2
AoufriYeYD, Yd-V., and M.V. Vob-ahtm@- On the LuclInebecace Method or
ttudYina the Vitriricattea of Pol),mpro 138
kolotinAl I.A. Optical Artivity end Vitrifice.-Ion 142
Card 0/22

85454
3/149/60/000/005/002/015
ICIC6/A001
AUTHORS- Nikitin, Yu.P. and Sr-yvalin, I.T.
T17LE-. lnvestigati,-n of Pr:Per".1sa Of Ni-cu-SLr, Ni-Cu-S and Ni-Fe-S
Melted Systems by the Metb.:@d of.Ele,:@tromotive Forces
19
FERIODICAL-,, lzvestiya vysshikh uchetrykja zavE-_eniy, Tsve+.naya m-31'allur-giya,
1960,, No. 5, pp. 4-3-48
A S-udy was made in order t- c@-mole'e exis";I_rg data on the devia-
tion fr3m ideal acluti.@ns of melts of the Ni-C-u-SrI.. Ni-Cu-S and Ni-Fe-S -ternary
sy_@tems ujing th,_@ emf me'II_,_-,d, Moreover, an &ttempt was m&de to apply formulae
descriting the bshavior of binary systems -.' tlte inves"Igited ternary systems.
Tne ex'-,,@!r'fments were made at. 1,,340-.1,36000 and z-h,-_%w nAiceable deviatims of the
_=ys-_e_Ms fr----m the Raoul- s law, Rela-n�vely ILw negative deviations of Ni in the
Ni-Cu-S melts are. explained by the exietance in the liquid of cybotaxis groupings
cif @@._-Tper ani s-iilfur in. [e-mail]!@,.,_-ls ex,@eedilng mean statistical valueE. Thermo-
dynan!_-al dala @f binary sys-zemS are uEed t,-- der.-_,ve fcrmulae for- the analytical
d@s-@rlr-licn of prcrerties cf thel deszr�b-=d @_ernary systems, 1) Based on Yaj.
Gera_zlm,:@Vs data-, rickel actIvity at, i,35()@C in the NI-Ca--Sb ay_--tem is expressed
car-.;. 1/2

85-454
s.11 49/6o/ooo/oo5/oo 2/0 15
A006./AOO 1
invez- r. -@ga4l !-.-- nof Prc-.Lertiee of Ni-C-a-3b, Ni-C-u-S and Ni.-Fe-S Melted SystemS by
th--, Me-@hcld of Eloe.@trjz-mc--Ive Forces
'8
f srmu 1. 2
'1! 0 , 1-2 x + 2 4x xSI)
Cu (1 - xNI.) - -3x,9b -r-NI' + Sb @'N G-i
8x x2
I'%zr-r,---dYnain-Ical data given by A.N. Vol Skiy serve I.-- d--trive the following
for Ni activity in 4. YZ7 .1
th@= 1,3) 2
1 0@12x (l - xN,@ - 4xS i- 6.88xcu@c s.
9f.\IIL Cu + -3.05x,,
i 4-rS (l xN,) 2-x,,, x_ 'tta---@-d on Chipman's dat, a, dL---
Fc:rrrr-lia (15@',,Igflu
-- *r'@- C-@@-LlClent %L k
@-rih- I;f -@Io el as-tivity in ?5 NI-Fe--S sys4 Exzerimental
values rf activities are in a sa-Ilisfactory ag-re-emen4.-. with data calculated. a@@cord-
@ng - formulae, reflec-i--Ing in 'the firs, appr-.-xImation the effect of thE
@he given
z-:-r- --ire V-
r 11 E-. -= tie heat of mixing, Th=-rs are "a-Cs and 7 r=ferencesg 6
S-vle@ an-d 1 Engll-=b,
ASS:',:;T TT@-,N@ Uraskly polilekhm- esk'-y lnztit t. (Ura! Polyteshnic Institute)
A.- I --h
Kaf ed-ra teorili metallurgicheskilch pr:o@-9esscv Devaxtment o t
T -
I@n@@cry of Metailurga-@a-
S U-:'V-"' TED March 8, 1960
r-.ard 2/2

s/18o/60/000/oo6/021/030
EIII/E335
AUTHORS: Yesin, O.A. and Sryvalin, I.T. (Sverdlovsk)
TITLE: Thermodynamic Properties of Metallic Alloys and
Phase Diagrams
PERIODICAL: Izvestiya Akademil nauk SSSR, Otdeleniye
tekhnicheskikh nauk, Metallurgiya i toplivo,
196o, No. 6, pp. n6 - liB
TEXT: The authors give a critical survey of investigations
of thermodynamic properties of alloys (mainly binary metallic)
in relation to the corresponding phase diagrams. Deviations
of solution from ideality form the major part of the survey.
For systems with continuous solid solution deviations are
usually slightly negative or zero. An example of the rare
system where positive deviation in the liquid accompanies
complete miscibility in the solid could be Au-Ni but the
authors doubt the evidence (Refs. 2, 3). Most such systems
obey regular-solution laws. Simple eutectic. alloys generally
show positive deviation; those that show a negative deviation,
such as Bi-Pb, are specially interesting. Negative deviations
Card 1/3

s/i8o/6o/ooo/oo6/02l/030
EIII/E335
Thermodynamic Properties of Metallic Alloys and Phase Diagrams
also occur when unstable compounds, decomposing below the
melting point, are formed. Especially large negative
deviations occur in alloys of iron with nonmetallics. E.m.f.
measurements (Ref. 5) indicate the existence of stable FeSi.
These results are in line with those of other methods
(Refs. 6, 7, 8, 9). The e.m.f. method has also been used
(Ref. 10) for carbon-saturated ferro-alloys: Fe2P was
detected in Fe-P-C (Ref. 12). Positive deviations are suggested
if there is an immiscibility "dome" on the phase diagram;
other links between e.m.f. results and phase diagrams have
been reported (Refs. 16, 17). The submicro heterogeneity of
eutectoid liquid alloys is suggested by X-ray (Ref. 18),
centrifuging (Ref. 19) and thermal (Refs. 20-22) experiments.
The authors doubt the valLdity of Bartenev's views (Ref. 23)
Card 2/3

s/l8o/6o/ooo/oo6/O21/03O
Elll/E335
Thermodynamic Properties of Metallic Alloys and Phase Diagrams
on liquid-solid relationships. Of the authors, Yesin has
cooperated in many contributions in this field, e.g. Refs. 5,
10, 11, 12, 13, 16, 17, 24.
There are 24 references: 18 Soviet and 6 non-Soviet.
SUBMITTED: August 26, 1960
Card 3/3

SYAO CHZHI-TSAYN [Hsiao Chih-tsangl,- SMIRWOV, V.I.; SRYVALINq I.T.
Thermodynamics of the sulfatizing roast processes of converter
slags in a fluidized bed. Trudy Ural.politekh. inst. no.ge:67-71
16o. (MIRA 14:3)
(Nonferrous metals-Metallurgy) (Slag)
(Fluidization)

- I -SPYVALIP, I.T.; YESIM, O.A.
Thermodynamic properties of silicate melts in the system
FeO - CeO - SiO 2. Izv.vys.ucheb.zav; khim.i khim.tekh. 4 no.5:
....... '.., 825-831 161. (MIRA 14:11)
1
1. Urallskiy politekhnicheskdy institut, kafedra teorii metall-
urgicheskikh protsessov.
I (Silicates)

SRYVALIN I.T.- YESIN, O.A.
---- --
Dependence of the heat of mixing on composition. Izv.vya.ucheb.
zav.; chern.met. 4 no.9:13-20 161. (MM 14:10)
1. Urallskiy politekhnicheskiy institut.
(Liquid metals-TbprmLl properties)
(Heat of mixIng)

SRYVALINJ, I.T.; YESIN, U.A.
Using quasi-chemical methods for metallurgical system -vith ternary
compounds. Izv.vys. ucheb. zav.; chern.met. 5:10-16 162. (MIRA 15;10)
1. Urallskiy politekhnicheskiy institut.
(Systems (Chemistry))

s/14q/6P_/boo/bo6/ool/bo8
AOO6/A1O1
AUTHORS: _�_r7yalin, I. T. Yesin, 0. A.
TITLE: 'On the temperature dependence of thermodynamical properties of
metal solutions
PERIODICAL: Izvestiya vysshikh uchebnykh zavedenly,,Tsvetnaya -metallurgiya,
no. 6, 1962,, 41 - 49
TEXT: In the theory of regular solutions.and In the �uasi-chemical method,
the interchange energy W is usually considered to be indepefidentof tempera Iture.
As a result, the excess isobaric potential of mixingA.F'J, does, not depend,at all
or very slightly upon the temperature. In fact, according to Soviet, Americ6ii) ,V/
and English -data, W. is a complicated function of temperature. The slinplest.W4 of
improving the theory is to consider W as a linear function of tempera ture:
w + T @W_
0 dT
Card 1/2

S/i 4@/62/06o/06/boi/W8
On the temperature dependece of... A006/AJOI'-,-
Several examples are given for binary metallic alloys which sh6w-the-adequady ;-of..
this function to describe quantitatively the experimental.data. on heats and free.
energies of mixing. Variants of the existing,theory.are Proposed which show the,
effect of local surrounding and the composition upon the-energy of,the'Interacti.on
between particles. The correlations derived show well.the behavior of.variou.s '. :-'. @ *'. 1
metal solutions with both low and high energy ef fects A quantitative descriptiori`@.'._-
is given of the thermodynamics of metal melts of Sn7T1, Fe-Sni,,Na-Sn Na-Pb-and'
Ni-Si systems. System Sn-Tl is related to the type of regu@ar sygtems the iso-
baric potential of Pe-Sn is described by an asymmetric curve; systems Na-Pb, Na-
an(' Ni-Si obey the quasichemical formulae where ternary compounds are taken into
account. In all the systems a noticeable temperature dependence of the excess
baric potential of mixing A F' is observed; it can be well considered by the lin-
ear course of the interchange energy W with temperature. The predicted thermody-
namical properties of the systems investigated are in a satisfactory'agreement
with experimental data. There are 5 tables.@
P
ASSOCIATION: Permskiy politekhnicheskly institut (Perm olytechnic Instituti) .
Kafedra fizicheskoy i analiticheskoy khimil (Department of Physical,
and Analytical Chemistry)
SU34ITTP: March 17, 1962
Card 2/2

SRY'VALIN I T.; YSSIN, O.A.
Using the quasi-chemic4lmethod for liquid iron-silicon alloys.
Izv. vys. ucheb. zav.;'dbern. met. 6 no.5:5-9 163. (KRA 16:7)
1. Permskiy politekhnicheskiy institut. -
(Iron-sillcon alloys-Thermal properties)

SRYVALIN, I.T.; YESIN, O.A.; LEP.INSKIKH, B.M.
Thermodynamic properties of magnesiiun solutions in nickel,
lead, and silicon, Zhur, f1z. kbim, 38 no.5;1166-1172 My 164.
(MIRA 18:12)
1. Institut metallurgiJ Urallskogo filiala AN SSSR, UralskJy
politekhnicheskiy institut i Permskly politekhnicheskiy institut.
Submitted May 23, 1963.

SMALIN, T.T. I YESMY O.A.
Application of the quasichemical theory -to calculate the activity
of silicate melt components. 1zv. v-fs. ucheb. zav.; Chern. met.
8 no.10:14-21 165. (NIRA 18:9)
1. Permskiy politekhnicheskiy institut- i Urallskiy politekhnicheskiy
institut.

1, 1T UE N , C! F G -rd) A 0 -, i r,-,,y V c 01 o
-ul
i-.Lt,ng "ria Mat of oxf-de M'
@.,)r,s .1@ oc)sing Jjem@ I2r,-. vyz-. ucheb. zav.; -harn.
n-,).11:9--I-'3 165. 1@14YRA J8-jl,Lj
-1. Urallskiy politakhrolchaski-y i Parms'KA.y p.,'i._"-
I
taldm@-Iheskiy institlit.

SPAVALIN, I.T.; YESIN, O.A.; KORPACHEV, V.G.
Evaluation of the beats of mixing of salt solutions according
to ionic characteristics. Usp. khim. 35 no.1:3-20 ja 166.
(141FU@ 19: 1)
1. Urallskiy politekhnicheskiy Institut imeni S.M. Kirova i
Pez-msl-,iy politekhnicheskiy inBtitut.

L 08191-67 FdT(m)/E-rIP(t)/ETI IjP(c)' JD/WW/J',[/JG/jli
ACC NRI AP6030498 (A-) SOURCE CODE. UR/0149/66/000/004/0022/00271
MR: 7'11(hdmirov, A. A.; @@alin. I. T.; Yesin, 0. A.; le inskikh, B. M.
p
Perm Polytechnic Institute, Department of Physical Chemistry (Permskiy
Itekhnicheskiy institut, Kafedra fizichoskoy khimii)
LE: Thermodynamic properties of liqu solutions of the aluminum-tin system
IVUZ. Tsvetnaya me .tallIurgiya, no. 4, 1966, 22-27
TAGS: solution property, aluminum, tin, thermodynamic property
ABSTRACT: The investi.aation was made by the method of electromotive force. One of the
electrodeswas liquid aluminum, and the other a liquid alloy of Al-Sn of varying
composition. The electrolyte was a mixturg of anhydrous sodium and potassium chlorides
in equimolar proportion, with an addition of AICI 3* The electrolytic Coll was mado of
a lump of magnesite brick with blind openings for the electrodes and the thermocouplo.
The current carrier,- 'were tungsten vj.ros protected by alundum. jackets. The cell was
placed at the bottom of a quartz test tube with a diameter of 50-60 mm. The
exper:Lments were carried out in.an electric re'sistance furnace. The experimental
results are given in tabular form. The &'allowing conlusions were drawn: ' 0
1) 1-11'easuroment of tho electromotive force was made at temperatures from 700 to 850
2) the system studied e)diibited. measurable positive deviations from Raoult's law.
Card 1/2 uc. 669.715+669.65

L 08191-67
ACC IIR@ AFF6030498
0
evicientiy due to the presence of -Large ae-va-ations o--- tifte neaT, capac,-ty rrom. Yopp's J-aw;
3) the dependence of the activities of the components on the composition, to a kno,@m
approximation, can be described by the formulas for regular solutions; 4) the
thermodynamic data obtained agree satisfactorily with the results of calorimetric and
glectronographic investigations. Grig. art. has: 5 formulas, 5 figures and 3 tables*
SUB CODE: 07, 20/ SUMI D@TE-.,- 2'f,@LarW ORIG REF: 008/ 011H REFt 001
q
dda
Card 2/2

POLYAKOV, A. I., inzh.
I
I.
Adjustment of boilers operating on Nazarovo coal. Energetik
12 no.4:2-1+ Ap 164. (MdRA 17:7)

NEMCFERKO, V.V., inzh.; SRYVKIOV, S.V., inh.; 111z'n.
Burning of Nazarov coals in boiler systems wil7l, small evaporat4ve
capacity. Prom. energ. 19 no.12:22-23 D 164.
(I-IMA 18: 3)

GERLIKII, Ye. [Gorlich, Ej; SUEDN *I-TSKIXt--Zh, [Srzedniaki, J.1;
KOVALISKIYY Z. (Kowa )
4
Multicycle oscillographic polarograply with two streaming
mercury electrodes in differential circuit. Zhur. fiz. khim. 36
no-3:449-454 Mr 162. (MIRA 17:8)
1. Gornaya Akademiya, Krakov.

THOK, R.; GLOWACKI, J.;_SRZEDRICKA, W.
Purification of dairy sewage by means of the active precipitation
method. Acta Kicrob.polon. 8:175-179 1959.
1. Z Instytutu Przemyslu Mleczarskiego w Warazawie.
(DAIRYING)
(SF,WAGB)

/C- 7 'k@
EXCERPTA MEDIC& Sea 12 Vol 13/4 hthalmol@ogy Apr