SCIENTIFIC ABSTRACT STAROBINETS, G.L. - STAROBINETS, I.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001652920014-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 25, 2000
• Sequence Number: 14
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

9Sr,"F6--.Tr7S2:WrW, 40.- 1054, No:
303M.-It is asisutned, that the deviations of the dielm,
co"9t.-(4t) and the activity coeff. (Ait) of solns@ Scompare4*
Zt standard state should be exprcs@iblc bysiQA functiont
of the compn. Furthtrutocc. tlkqi relation betweca Acand
A-tj should be linear. To tat this assumptioti, the diike.
consts. of mixts. AIeOHj HtOH,' PrOH, and -DuOH wIth
C#H4F were detd. by the pulsation taethod, at 25* and a wide
range of cozwn. The resulting d2ta were compared with the
activity coeffs. of the same mitts. previously obtained (Gia-. -L-
calone, C.A. 38, 193P). , At concns. of 15 to 70-W mol.. %
:atc. the ratio of is coust. within the limits of 0.11-
0.1-3. At small concas. cfalc. Nvhen.yi practically equals I
A-rjlAe decreasc3, and at very high coucns-' it i&reases.
On the basis of these established linear relations it is con-
eluded that the Kirkwowl equation for dielce. polarization -
shouldexprests the changes in the activitycoefl. of a oonpolar
solvent with the concn. of'the mist. M. Hoach-;

STARUBIK@TS, G.L.; FISIDER, I.Z.; MILICHINA, M.G.
Surface demixing. Kolloid. Zhur. 15, 219-22 153. (MIRA 6:5)
(CA 47 no.18:9103 '53)
- , -11., 5V
. ::@-- - 11 @-A @ ffW

STAR OBINETS, _ C@. L.; KOIAAFOVI V. S.
2. ussR 6oo
It. Rubber
7. Equilibrium between rubber and binar7 alcohol-benzene solutions, Noll. zhur,
15, No. 1, 1953.
9. Monthly List of Russian Accessions, Librvxy of Congress, APril 1953, Uncle

een ruVocr and alcohol-benzene, soluttons&
467h. lquilibr#n etw
QLJO.Stambi"ta and.V: So KomaMXt Kc.11oid Zhur., 1953, 15,
1953, 47 51.53. Vulcanised natural rubber
ed Lin thf,,. vapour for 10 days "L and the amounts q L and
vian,suspend
Ribber Abstract Q2g* of 'alcohol ah& Wn zone- taken- up -by I- g -of , rubber.-at-20*
Vol. 31 were deterrdned Interf eromr-trically. - Over pure benzene, @ Qp, was_*'@
November 1953 0.16* Over- pure alcohol, Ql increa%ed f r*om methyl alcohol to
Vulcanised hexanal, and (at-00*) octadecanol. I Over be ,nzene containing,
flatural Rubber little alcohol, Q1 was:Frvzter, and over alcohol cont@*On_ing litt.1 I8@
benzene, Q2 was greater, the smaller the mol CCII),71- "]It of Ule.
Over the intermediate solutionsp the III
alcohol. mole racti
of an alcohol in the rubber varied with th4,- composition of the
in the
saine manner as the mole f rac tion, n3 t1l,
liquid (n2)
_
.
vapourl betwetm n2, 0.2 and 0 8 n wa approxim;;tely equal to"
l

d 4 d
3n-X. At n2, 0.C9 of meLh@l alcoho
Q2 an Q1
through a maximum; this maximum war, less T)r3Pouncf-.j for ethyl,-
C
alcohol, and prooyl al ohol, and absent for buty! a1cohol,
hexanol --nd octadeca at ji@ 0.5
t101, 01 + f'2 had a minimun

Remarks on interface separation (answer to the article by G.L.Sta-
robinets, I.Z.Fisher, and X.G.Millehins. OInterface separation.8)
Xoll.ihur. 16 no.4:309-311 JI-Ag 154. (NLBA 7:7)
1. Khlulcheskly institut in. A.Ye.Arbuzova, Xazanskly filial
kkadeall nau SSSR.
(Surface chamistrr) (Starobinsts, G.L.) (71sher. I.Z.)
(Millchlus, M.G.)

STAROBInTS, G.L.
[Once more about interface separation (Answer to the article of
B.TA.Teitellbaun "Remarka on interface separationg.) Zoll.shur.
16 no.4:312 R-Ag 154. (KLRA 7:7)
1. Belorueekly gosudaretvannyy universitet In. T.I.Lenlas, Minsk.
(Surface chemistry) (Teltellbsum, B-IA)

@-@ @ i -@) , ,--,I / /Y - iz:@ - ,
- -f , - / - @, - -- , - r4,
79

ST@FO:KLNTS, Grigroriy Lazarevich
Acadenic degree oil Doctor of Chemical Sciences, based on his defense,
20 May 1055, in the Council of the Belorussian State U imeni Lenin,
of his dissertation entitled: "Absorption o-f Binary IIixtur-3s of
Saturated Steam by Rubberlike High Polymers and Adsorption on the
Solution-Air Boundary in Solvents-Non-Solvent Solutions."
Academic degree and/or title: Doctor of Sciences
SO: Decisions of VAK, List no. 25, 10 Dee 55, Byulleten' MVO SSSR,
Uncl. JPRSAIY 548

315. Distribution -"01 eompone* 0
nledis between solnum gild pdlymile, ph&$& W. (ke
Oil swelling proms. 3. L.- 9 Rom sAd L N,

-i B isi GO&
7 .3
U
-
Unio. ini. V. J, Lmi"a, -5er Khim-, 105b. X6,14,

41"7; Cheyn, Abs, 1957, 51, A456, Thoxwe
IU4 of
l
di
ml
d
bb
d
t OUT I
m
-
er- wart atu
u
q
ac
ru
o
a
n, pa

180-butyl alcohol iwd;'xa-,mo ethyl a"0111I.-
i
l
T
t
d
hq qv-vtW6.of "Anat
o a
cohol a
6
turm
i
wert, t4@-
aroinatic tompotmfhq M both phils" UWO4d
at DO end 360,hr-,' Diagranunatic rvprmn(JWohs
M
, the
are glyon for the distribution of compontints In
swolltin rubber " a function of tho composition of
the tiqqid phl!zi-z'

r) r F,

cti@e sorption of sot1jr.1ted binary vapor's, Vd-
of natur ar Ll,hh-. G. 11,
ji-
W
it --C --b -@fin -Imuf
'0 sej@ctivc sorpG&,t A lin@@r . bij a---
l
ene a id tiaturul mbb(.," wa@. studitd, wiLh uttentiou
d
oil @olvcnt-aonsolvtnt typts, In which the k-orptive
I'Mille ('fthe is pa;ticltLtf@ nromounced, The
binary SyMems %Ycre the noripolar solvents CsIL. CYd&-
bex@.' CCI,. and p-C@H401; solvents with a small dipole
i winent-toluene; nod the pufar solvents CHCJ" C11,12 t

i HcBr- The iionolvent compomrits were fatty alc'.
:
I
A !i,. i.I-,,:Jertc, be-@zuic, md salicyli, acids, 14@,CO.
M; @ i)l't ".10A." PLIA]. P11-m. 11,1ane., and dio@-Unr
Iv f, "f I., cir, 1:Ubh'i-I. The '-.wth ... I "f
rii I b,.- --bm,ts i-I K- ......
J-1 'ZII
19 :. St"Ilb'rg

STARDBINSTS, G.L.
", -.,. .
1-_@ Selective sorption of binary solutions by rubb^r type high,
polymer,. Uch.za BOU no.29:151-174 156. (min 11:11)
(Sorption) fiolution (Chemistry)) (Polymers)

STAROBIMS, G.L.-, RUBLINCHIK, K.F.
Jet-e.lectrochemical method for determining the thickness of
electr-6plating. Uch.zap. BGU no-29:175-177 156. (XIIIA 11:11)
jlectroplating--Testing) (Thickness measurement)
(F

STARC-BI-NETS, G.L.: TIKAVTY, V.P.
- = -
Effective sorption of binary solutions by rubber in relation to
the degree of its vulcanization and filling. Uch.zap. BOU no.29:
17B-188 '56, (14IRA 11:11)
(Rabber) (Sorption)

STAROBDWS. G.L. I
Uch.@Sp. Bau nOO29:277-281 56.
N.turs of Shreder effect- (MIRA litil)
(Polymers) (sorption)

J
USSR/Si;rface Phenomena. Adsorption. Chromatography. Ion Interchange B-13
Abs Jour : Ref Zhur - Kh1mlya, No 8, 1957, 26377
Author : G.L. Starobinets, V.S. Komarov
Title : Sorption-o-r-BUiWy Solutions by Vulcanized Natural and Syn-
thetic Rubbers. II. Application of laws of D.P. Konovalov
and Rule of M.S. Vrevskiy to Equilibriun Polymer - Binary
Solution.
Orig Pub : Zh. fiz. khimli, 1956, 30, No 8, 1771-1775
Abstract : The analogy between the azeotropism in binary systems and
the appearance of extremums on isotherms of general sorption
(IGS) by high polymers (HP), for example, vulcanised rubbers,
was noted. It is shown that the properties of IGS are des-
cribed by the laws of D.P. Konovalov and the rule of M.S.
Vrevskiy; the total amount of the substance sorbed by the HP
rises with the concentration rise of the solution component,
which is richer in HP-s; the composition of the solution in
the phase of HP-s is equal to the composition of the equill-
brium binary solution at points corresponding to the exremums
of IGS; with a rise of the temperature, the maximum on IGS
shifts to the side of the component, the heat of evaporation
Card - 1/2

STAROBINXTS, G.L.
Sorption of binary solutions by natural and synthetic rubber
vulcanizates. Fart 3, Model analysis of the systemtjolymer-
solvent-non-solvent [with English summary in inner Zhur.fiz.
khim. 30 noo9:2029-2038 S 156. (=A 902)
1. Belorueskly gosudarstvannyy universitat iment V.I. Lenin&,
Minsk.
(Rubber) (Sorption)

SOV/81-59-12-44604
Translation froms Referativnyy zhurnal. Xhimiya, 1959, Nr 12, P 534 (USSR)
AUTHORS: Starobinets, G.L., Komarov, V.S.
TITLE: The Modelling of the Systemsz Rubber-Like High-Polymer-Binary
Mixture of Low-Molecular Components
PERIODICAL: Sb. nauchn. rabot. In-t khimii AS BSSR, 1958, Nr 6, PP 154-162
ABSTRACTs The distribution in the systems high-polymer-binary mixture of
low-molecular components has been studied for vuleanizates of na-
tural rubber and mixtures of chloroform-acetone, chloroform-ethyl
alcohol, CC14-methyl alcohol, ethyl chloride-heptane and benzene-
chloroform. The curves of equilibrium between the polymer and
binary solutions have been calculated by the method of modelling.
They agree with the experiment.
From the authors' summary
Card 1/1

Dbtermination of Normal Hydrocarbons JLn Paraffinzl by 1,10,1"lo of 75-13-2-151/27
the Adsorption Analysis
paraffins end ir clearly expreased horizontal lines. which
correspond to the complete adsorption of the disPolved paraffin.
The isothermal curves of the commercial paraffins, on the
contrary run out on the 3ame conditions into lines,, which are
i.Aclined towards the abscisse and which indicate the fact
that the adsorption process in this case represents the sum
of 2 processes; The adsorpt.-ion of the normal hydrocarbons
and the adsorption of the iso-hydrocarbons. It was shown that
the ordinate, which was obtained by extrapolation of the
inclined final line on an urea content of zero, represents a
measure for the percentage of normal hydrocarbons in the
paraffin which is to be examined. The result of the analysis
obtained this way, J_s independent of the nature of the solvent.
This fact proves the reliability of the method.
3) The methods, described in publications, for the determin-
ation of normal hydrocarbons by means of urea in general
give too low results. These methods correspond in their
essence to the investigation of only one point of the iso-
thermal curve, while a unique conclusion on the percentage
of normal hydrocarbons in commercial samples is possible
Card 2/3 only because of the examination of the whole isothermal

Determination of i1ormal Hydrocarbons in Paraffins by Yeans of 75-13-2-15/27
the Adsorption Analysis
t.-sorption curve, which is concluded from the results of this
paper.
4) This method, worked out by the authors, in simple in an
experimental respect and can be performed with small substance
quantities. It is based upon the analysis of the solutions,
which are in equilibrium, and therefore it is free from
errors, which aro caused by tranafer, viaohing Qut, and
decomposition of the complox compound of urea Yrith the
hydrocarbons.
There are 5 figures, 1 table, and 22 references, 11 of which
are Soviet.
ASSOCIATION: Belorusskiy -osudarstvennyy universitet im. V. I. Lenina,
Minsk (Llinsk,Belorussian State University imeni V. I. Lenin)
SUB;'.'IITTED z may 31, 1957
1. Methanes--Analysis 2. Hydrocarbons--Adsorption 3. Hydrocarbons
--Determination
Card 3/3

AUTHORS: Starobinets, G. L., Pikulik, V. A. 76-32-4-3/43
TITLE: The Structure of the Adsorption Layer at the Interface Between
, Air and Concentrated Solution. II. (Stroyeniye adsorbtsionnogo
sloya na granitse kontsentrirovannyy nevodnyy rastvor
vozdukh. II.)
PERIODICAL: Zhurnal Fizicheskoy Khimii, 1958, Vol. 32, Nr 4,
PP- 756-759 (USSR)
ABSTRACT: In a previous paper it was shown that the possibility of the
formation of a polymolecular adsorption layer is greatest in
two cases; When the energy of the intermolecular interactions
1-2 is relatively small compared to those between 1-1 or
2-2. When the molecules of the active surface component form
groups with parallel oriented dipoles. In order to investigate
the first case the authors investigated in this paper the
system benzene-polar derivatives of benzene (benzyl alcoholp
phenol, nitrobenzene and chlorobenzene) with the active
benzene acting as surface component. The thermodynamic benzene
activity as well as the dielectric permeability and density
(at 7000 were determined for this system by Martin (ref. 2).
Card 1/3 A table of the additional measurements of the surface tensions

The Structure of the Adsorption Layer at the Interface 76--32-4-3/43
Between Air and Concentrated Solution. II.
at 7000 as well as of the calculated adsorption in the air-
-solution interface, and of the dielectric polarization
according to Onsager-Kirkwood and of the correlation para-
meter of the polar component according to Kirkwood is given.
From the graphically given results it can be seen that the
maximum adsorption of benzene in benzyl-alcohol is abnormally
great and decreases according to the series of solvents
phenol-nitrobenzene-ohlo.robenzene. The diagrams of the thermo-
dynamic benzene activity co-position show that the deviation
from the ideal case as well as the maximum quantity of
benzene adsorption take place sympathetically. The abnormally
great benzene adsorption is explained by the group formation
of molecules of the surface-inactive components. Investigations
of the correlation parameter of the polar components showed
that the concentration of dimers in the system benzylalcohol-
-benzene is greater than in phenol-benzene, in the former
the depth of the zone of negative adsorption of the polar
components being greater. The distribution coefficients of
benzene between the surface and the center of the solvent
were calculated according to the theory by A. A. Zhukovitskiy,
Card 2/3 and were represented graphically. It is shown that the

The Structure of the Adsorption Layer at the Interface 76-32-4-3/43
Between Air and Concentrated Solution. II.
adsorption layer of benzene in nitrobenzene and chloro-
benzene is monomolecular,and in phenol and benzylalcohol
polymolecular. Finally the authors state that the abnormal
properties of the adsorption layers found are to be traced
back to a polymolecular character as well as a conditioned
adsorption depth which is determined by the mean length of
the molecular groups.
There are 4 figures, 2 tables, and 5 references, 3 of
which are Soviet.
ASSOCIATION: Belorusskiy gosudarstvennyy universitet im. V. 1. Lehina
Minsk (Minsk 'i Belorussian State University imeni V. I.
Lenin)
SUBMITTED: May 21, 1956
AVAILABLE: Library of Congress.
1. Adsorption--Theory 2. Benzene derivatives--Adsorptive
Card 3/3 properties 3. Benzene--Adsorptive properties

SOV/81-59-5-1481o
Translation from- Referativnyy zhurnal, Khimiya, 1959, Nr 5, p 88 (USSR)
AUTHOR- -Star-obinets, G.L.
TITLEx The Structure of,Adsorption Layers-at the Solution-Air Interface
in the Solvent-Uc;n-Solvent-Type Systems of Rubber
PERIODICAL: Uch. zap. Belorussk. in-t, 1958, Nr 42, Pp 139 - 150
ABSTRACT: In a summary the results of a systematic investigation are given
conducted by the author (RZbKhim, 1956, 18926), on the proper-
ties of adsorption layers-on the interface between solution-air
in binary systems, consisting of non-polar (benzene, dichloro-
benzene) and polar (lower fatty alcohols and-acids, nitrobenzene
and others) components and models of the system: rubber-solution.
It is established that all the systems containing alcohols, have
anomalous properties, which lead to the fact that the adsorption
layers in them have a polymolecular thickness, and the maximum
values of adsorption are reached, in contrast to aqueous solutions,
Card 1/2 at very slight decreases in the surface tension. In systems con-

STAROBINETS, G.L.
Nat ra of sy
.stems of latticed nibberlike high polymers with binary
nixtures of low molecular weight conrponents. Uch.zap.BGU no.42:151-158
58. OCRA 12:1)
(Macromolecular compounds)
(Solvents)

PHASE I DDOK WWITATION SOT/3TT9
Starobinets, Grigoriy Lazwevich,, anaVladbdr Stepanovich Koxam
KauchukopodobnM polinery - sorbenty i khromatograficheskiy materialy
(Elastomers as Sorbents and Chromatographic Materials) Minsk., Izd-vo
Belgosuniversiteta,, 1959. 127 P. 1.,500 copies printed.
Sponsoring Agencies: Minsk. Beloi-iasski@ gosudarstvennyy universitet imeni
V.I. Lenina; Akademiya nauk BSSR. Institut obshchey I neorganicheakoy WWI;
BSSR. Ministerstvo vysshego, srednego spetaialtnogo i professionallnogo
obrazovaniya.
Ed.: N.D. G691; Tech. Ed.: I.Te. Belenskaya.
PURPOSE: This book is Intended for researchers studying the physicochemical
properties of polymers., and for persons interested in the theory and practical
application of sorption and chromatographic processes.
Card 1/4

Elastomers; as Sorbents and Chromatographic Materials SOV/3779
TABXX OF CONTMM:
Foreword 3
Ch. I. Selective Sorption of Binary Solutions by ElsOtOmeric Hi&
Plolymers
1. Review of data from the literature 5
2. Selective sorption and thermodynandc properties of solutions 12
3- Predicting selective sorption 22
Ch. II. Sorption Isotherm of Binary Mixtures of Saturated Vapors
and Binary Solutions .,
1. Techniques of studying sorption 25
2. Coefficients of the distribution of low-molecular components
between polymer and binary solution. Pblymer-solution
equilibrium curves 41
3. Interpr@tation of the sorption process according to the theories
of D.P. Konovalov and U.S. Vrevskiy 50
4. Zffective sorption isotherms 58
Card 3/4

3/081/60/000/007/001/012
Aoo6/Aooi
Translation from: Referativnyy zhurnal, Khimiya, 1960, No. 7, P. 54, # 25669
AUTHORS: Starobinets G L Ariko. P. 0.
M
TITLE: Thermodynamic Pronerties0'and Structure of High-Molecular Para-ffini-
Hydrocarbon Solutions in Benzene
PERIODICAL: V sb.: Thermodinamika i stroyeniye rastvorov, Moscow, AS USSR,
1959, pp. 207-210
TEKT-. The method of gas saturation at 49, 55, 58.3 0C was used to det-ermir_-
the benzene vapor pressure over solutions of two fractions of high-molecular
hydrocarbons separated from technical paraffin of 270 and 340 mol. weight
respectively. The activities and partial values of free energy, enthalpy and
entropy of the components were calculated. Deviations from the Raoult law and
excessive changes in the free energy of the solutions arre negative and increase
in their absolute values with increasing molecular weight of paraffin and with
raising temperatures. The formation of solutions occurs at a diminished entropy,
It is concluded that the thermodynamic properties of high-molecular hydrocarbon
solutions are one of the factors for their stability, In benzene solutions
Card 1/2

STAROBIOTS, G.L. [Starobinets, H.L.]; ALEKSAI'IDROVICII, Kh.M.
Mikhail 14ikbailavich Pauliuchanka; on his 50th birtbday.
Vestai AN BSSR.Ser.fiz.-teldi.nuv. no.2:132-135 '59-
(14IRA 12:11)
(Pauliuchonka. Mikhail 14ikhailavich, 1909- )

ISTAROBIVETS. G.L.: TIKAVYY, V.F.
-
Dielectric permeab-flity of systeme composed of a rubberlike high
polymer, a sol-went, and a nonsolvent. Dokl. AN BSSR 3 no.6:249-25Z
JS 159. . (MIRA 12:10)
I.Prodstavlonr akademikom AN 13SSR X.F. Yermolenko.
(Polymerg-Blectric prop'orties)

AUTUORS 0. 11: 3OV/75-14-4-50/,'D
TITLX. 000tion of konlytt sa Chemistry of the 7111 Mandeloyev
A
a r
CoAgr.m an '. moral &:: Applied Chemistry
L
,
PULOULCAL. Zh.-I .-Iltich.skil khL.Ii, 1959, Vol 14, Mr 4, Pp 511-512 '1
(133n) I
L53TRACTs Approximately 300 persons participated in the work of the
Department or An^Iyti..1 Chemistry, -A@; them representatives
of iario" 8.i.otlfic -worth institutes, higher so boils and

from Ins,
Im4%strI
p Ch
t
r
SU14's"Lo Po nd Hungary IIt. 7. Aypmxl-t-IY TO
j,
,
@,::
report. .... board. In him opining speech 1. r@jilimarla-r*portod
an the mableved result, and on "darn problems of analytical
U
oheftimtr
"
'
hyal Q-
1h
Y1 It
J@Y* reportoll 0
4p
l" U
.
s.
:
p
%.
:.
L
ch ALL &1 mg." to f rtt o ut n f a
;.
:
is* of problems of amlytLcal oheal.try.&'T. Z. rutno toov
r.portod an modern &Los in too use of organi`o-r-d-&-Uea-V"wj
& at the of halid. and thiOay.oato
so and
betv. on the stability of c
tica
rr I
pl
o:
m
:
the position of th: "a P-nding central tome In t, p rIodic
:Q
Card 114- z7vt .. t-K-ZoAbk2_yA and _r-X_AqjtjkS= lectured an the stability
of GMat.s of Cu. Co. and 21, A. d.;.Qag on the st@ctur. of
tb. art" molecule. J.Ott.r.d on the double

obarect
t
of reaction cf
em.
pound. Ja
h.
formation of
r
,
:
.
r
m
easspI.X The probl an th: :9 licit ion4tompolynaide I
;
4"Irt". :i chemistry - dealt with In ch. I..turo. of
,kh*v& and oe-wmitro, vA XokqXin and A.
Alarge number of lactums dealt with the us; of
.E
amQrganic "agents In knaly.1st ALJ_JLtamx-end W-I-IYA@tia
reported on the application of diaLkyj and diLryl dithlo- I
pboophorl sold for th sop4ratloa of eleadato
ar7l =14 "Id and :171 pboaphinic acid. R.
his SoLeafters treated .00,0 properties of ... ot.pl.xo... Th.
is 'turmo
tar9E an J--I, Konononki
4
tLi
:r
:

.
.4rL.. . rio..ts
,;L
j
= If F- -
&*&It mi the photometric @
t
"Inc fluorlas drl,.t... A2_X. Ch.rk..cr l.itured on the us. of i
Wochromation in mosslyti oil We and 1, 9,
Us,
loot red on the do roinati.. of tentAlum Ag
1
'@
x
Vf
f
.
..tilt .
yactraphotometry. Yu, V. ItorachovokiX And, JAa
I - to naly.i. we thods
ported an ". highly sensitive .
Z
!
___
r
rn
atr.liol.t
microscope. Several lecture. dealt with
Cord-A&L.. C 64
Methodical and theoretical probl... of p*ctrun analyst.
and G.-A'MLjMA.j 3, Vs. Yqyn.b%oYD and
% PoTu-ektov &M X. X. 31konova treated the
part otlon of fl@ photometry. 3*Toral lecture* dealt I th the
desezzatIon of elements by polamdTlp @2. 1. Sin-k ...1 1
jtf.!@@ a a an& 1. P. Go haTht ties
Itatrod.s w.rv
AC filed
re to In usi@
jtj@@ and J@@. S. Lyollkov and co-warkers. The loctur. of
I y1trosted the use of ampero-tric
.tjjov
11trats.. with t ro:;j. a the ch.wtstr7 of cranium and
ftorium. M.N. Uoyalin showed poo.ibilit! f predicting the
covAiti.amt or: hro.at.graphic separation :; :1. cents based in
their pool 1. 1. the pariodle system. T A. aolylio"y reportedi
obe of Inn exchange in the In,*. tiget I.. ;f than .tat* of
Zbst-n in solutions. A".@dub and V_J@YtraahepL
Isatured on the chromatographic separation of a series o
.24mant'. ', C' ftlyanskiil reported on adapting the proportion
of .on rewin*, 7 . K. M-yakin and as.. tat.. -prt.d
the ch proof of ouTf-anil"ide pr:p.ratton. in
nro"tag"'phlo
I
Card 314 7,Nds of the associates tr.4 tod
the opplioatip of high pol7mers in chromatographic analysis.
The lecture a &,A@ZhMkhujj&jy and 41,[e-mail] G.Sb^L
domit .1th go. chromatography. Several lectures treated the use r
r"Joactlyt isotopes for the chromatographic Investigation of
.onplos forostio. (ZA_ja @aqy and a.s..Latoo), for the
Solostication of the nmoth rdm of lots of rare
so 'I! t .d fterm . .
-t&ls with sulfide )'Do. or'do I mi nd r
.-to - -a.- fi:otopa dilution '.1. F,_"jgrLn, C,jL.
IUI@. . th: I d @f clomotary rj@nlc micro.nsly.i.
_;11L. fI
,;.LeIfr:a* GF4 Y- A Kli@ with
th:o.l.co-ures C.
at. - h T. to he d. :h-.utr-.t*d the ol.VaWCI@.. of
t.-%:th.d. far th!ic1..lt to . d to minstion of .... -1
element& fma,orte -iGhed p4rtLqr. of boron, fluorine end
sillatum-C-1. YY

5 (4)
AUTHORS: Starobinets, G. L., Tikayyy, V. F. SOV/20-i28-2-31/59
TITLE: Dielectric Properties of Reticulate Rubberli)ce Hig@ Polymers
Swollen in Binary Solvent - Nonsolvent Mixtures
PERIODICAL: Doklady Akademii nauk SSSR, 1959@ Vol 128, Nr 2, PP 333-336 (UM)
ABSTRACT: The d�eleotrie constant and the dielectric polarization of a
vulcanized cc-polymeric but-adiene-styrene is investigated at
250, swollen in benzene or oarbon tetrachloride, mixed with
a nonsolvent fluid, in this case with low alcohols. Further
the partial isothermal line of the sorption of the low-molecular
components of the polymer was determined as well as its distri-
bution *between both phases. Figure 1 shows the carve of the
dielectric constant in a system polymer-benzene-m'ethyl alcohol,
figure 2 shows the relation betwean the isothermal line of the
dielectric constant ana the isothermal line of the partial
sorption of the alcohol in the system polymer-carboxx tetrachlo-
ride-ethyl alcohol. In 6111 studied systems both isothermal
lines pass a maximum in the same direction. It is confirmed
that the dependence of the dielectric polarization , in the
combination of the swollen polymer agrees with the theory due
CaXd 1/2 to Onsager-Kirkwood (Ref 4) for the solution -if polarized

Dielectric Properties of Reticulate Rubberlike High SOI@120-1 28-2-31/59
Polymero Swollen in Binary Solvent - Nonsol-Tent Mixtures
mclectulas in nonpolarrized solvents. Aa ehown on figuxe 3 the
specifto. polariza t 4ons in system high polymer. - banzene - n-
butyl alcohol are placed ),a the line calculated in reference
to Unsager-Kirkwood. An orientation of the d4p0jZ In the
allr.lchol molecule pare-Ilel to the double bond of the polymer
cacurs. The alcohol molecules form dimers with double bonds.
There are 3 figures and 9 i-eferances. 6 of which are Soviet.
ASSOCIATION; Belorusskly gosudarstveary-j unlvezsitat im. V. I. Lenina
(Belorassian State University ime-a-4 V. 1. Lenin)
PRESENTED. may 4, 1359@ by V. N. Kargin, Academi-,ign
SUBMITTED- Mlav 2. '1959
Card 2/2

S/081/60/000/022/001/016
AOO5/AOO1
Translation from: Referativnyy zhurnal, Kh1miya, 1960, No. 22, p. 78, #8788,r-
AUTHOR- Starobinets G.
TIrLE: The Structure.of the Adsorption Layers at the Solution - Air Inter-
face in Systems of the Caoutchour., Solvent - Non-Solvent Type
PERIODICAL: Tr. Khim. fakt. Belorussk. un-t. Minsk, 1960, pp. 45-52
TEXT: On the basis of measu.-emerts of the dielectric sonstant and densit3
of solutions, the values of the dielectric polarization were calculated in accor-
dance with the Onsager-Kirkwood theory as well as the values of the Kirkwood
correlation parameter for the solutions of CH OH, C OH n-CP7TH, n-C H OH,
3 05 I-hloro Denze 4 ?t
iso-C411 OH iso C H110H, and C,HjjOH in benzene and a-di, ne, turned
values- 5
out tha correla i6h parameter of about 3 correspond to the maxi,.rr=
of the V
of alcohol adsorption, from which results that the surface layer of an alcohol
solution and pure alcohol in liquid state have the saine structure. It is shown
that the surface layers of systems conitalnin_g alcohol5 as Surface active subst-an@-s
consist of linear-polymerized alcohol groups. The dependence o-f th- correlation
Card 1/2

s/o8i/6o/boo/022/01,5/bi6
A005/AO01
Translation from: Referativnyy zhurnal, Khimlya, 1960, No. 22, P. 566, #91066
AUTHORZ: Starobinets, G. L., Povarkov, E. V.
TITLE.- The Dynamical Sorption of Binary Solutions by the Vulcanized Rubber
of Sodium Butadiene Caoutchoue
PERIODICAL: Tr. khIm- fak. Belorussk. un-t, Minsk, 1960, pp. 65-73
A dynamical method was developed forstudying the distribution of a
binary mixture of the solvent - non-solvent type between a polymer and a solut-ion
The polymer powder is placed into a column and saturated by the solvent. Then
from above the non-solvent is poured over, and the composition of the fractions,
sampled successively, of the solvent coming out from the column is determined. Ti-le
equations are derived for calculating the equilibrium curves. The method is
checked at the following systems: vulcanized rubber of sodium butta-die-ne caoutchouc
- benzene - etkyl-alcohol and vulcanized rubber - benzene- n-butyl-alcohol. The
equilibrium curves obtained agree with the curves obtained earlier (RZhKhim, 1955,
No. 14, # 28699) by the static method, The dynamic method is somewhat less precise
Card 1/2

S/081/6Q/000/022/Oi5/0i6
A0051AOOI
The Dynamical Sorption of Binary Solutions by the Vulcanized Rubber of Sodium
Butadiene Caoulk-lchouc
than the static one, but It makes It possible to est:tmate qillckly the dislu'ribution
of low-molecular components between the polymer and the bij@ary solution,
I
L., slonim
Translatorts note- Thi6 _ii --ne full translation of -the original Fussiar abs-tract.
Card 212

86151
S/065/60/000/009/005/006/Xi
1114 E19VE1811t-
AUTHORS: Starobinets, G.L.@ and Tikavyy, V.F.
--Mixtures of Aromatic and Aliphatic
TITLE: The Separation of
Hydrocarbons by Means of Butadiene-NitrilelCo-polymers
PERIODICAL,, a.,imi i tekhnologiya topliv i masel, 196d-@'No. 9,
pp @ 1r,_19
TEXT: Previous work has shown that rubberlike polymers and
co-P,Aymers may find. extensive application as selective sorbents
and t:qey may be used in several kinds of distributive and
adsorption chromatography In order to study the influence of
the chemical c-omposition A rubberlike polymertlon the sorption
propert, Les work was done with resins based on butadiene-nitri.le
0.0--polymers ctontaining 18, 26 and 40% nitrile acrylic acid.
The binary solutions were of the type solvent/polar non-solventq
the specific energy of cohesion.of which was greater than that of
the DOlymer (in the present work benzene-aliphatic alcohols), and
sy3tems of the type solvent./non-polar non-solvent, the specific
energy of cohesion of which is less than that of the polymer
(benzene-aliphatic hydrocarbons). Experimental data obtained for
Card. l/ 3

86151
S/06 5/60/000/009/005/006/XX
E194/E184
The Separation of Mixtures of A-romatic and Aliphatic Hydrocarbons
by Means of Butadlene-Nitrile Co-polymers
typical. systems of benzene-methanol and benzene-hexane are given
In Figs 1-3 as equilibrium curves. Fig.1 shows that as the content
Df nitrile 4n the polymer increases the asymmetry of the
equilibrium I-,UTve decreases in the system polymer-benzene.-,methanol.
Fig.- shows that in the benzene-hexane system there is also a
clearly expressed selective sorption of benzene. In this system
as the nit-rile content is increased in the co-polymer the sorption
potential of benzene increased; this is explained by reference to
Fig,3 which shows curves of partial sorption of hexane and
methanol from the systems benzene-hexane and benzene-methanol.
Various theoretical considerations are given. It is concluded
that nitrile co-polymers with a high nitrile content are
excellent sorbents .Lor various kinds of separation of mixtures of
aromatic and aliphatic hydrocarbons. Increase in the molecular
weight of the aliphati,-. hydrocarbons should increase @:the efficiency
of separation, The conclusion is confirmed by the experimental
da ta . It is to be concluded. that butadiene-nitrile no-polymers
C a. r JA 2/3

86151
s/o65/6o/ooo/ooq/oo.5/O06/XX
E194/B1'8L-
The Sepa-zation of Mixtures of Aromatic and Aliphatic Hydrocarbons
by Means o-f But-adiene-Nit'l-ri-le Co-polymers
should be used to separate aromatic hydrocarbons from petroleum
d.istillates and. for their quantJtative determination.
There a','-e 3 figures and 8 references; 1+ Soviet and 4non-Soviet.
ASSOCIATION; Institut nefti i gaza, AN UzSSR
(Instttute of Petroleum and Gas. AS Uz8SR),
Card

S/075/60/015/004/006/030/xx
B02O/BO64
AUTHORS: Starobinets, G. L. and Povarkov, E. V.
TITLE: Partition Chromatographyqof Aromatic Hydrocarbonsion
Rubber-like Polymers I
PERIODICAL: Zhurnal analiticheskoy khimii, 1960, Vol. 15, No. 4,
Pp. 405 - 408
TEXT: Hydrophobic carrier substances, such as crude and vulcanized
rubberv as well as benzene and n-heptane were successfully used as steady
phases in partition chromatography for separating some mixtures of polar
organic compounds (sebacic acids, nitrotoluenes, etc). Since it is
difficult to find a carrier whose adsorption may be entirely neglectedi
the attempt was made to use polymers as steady phases; in
this connection it was found .-ha!; the latter are selective solvents for
hydrocarbons, and that equilibriam. is quickly established, especially
when loosely linked and unfillee- polymers are used. In the present
investigation, the chromatographic method of separating mixtures of
aromatic hydrocarbons is iLqed, which is based upon the distribution of the
Card 1/4

Partition Chromatography of Aromatic Hydro- S/075/60/015/004/006/030/XX
carbons on Rubber-like Polymers B020/BO64
constant volume concentration of alcohol. These diagrams are straight
lines for the system methanol - water - toluene whose angle of inclination
depends on the volume concentration of alcohol in the ternary mixture.
The calibration diagram:angle of inclination of the straight line as a
function of the volume concentration of alcohol is also plotted. All
calibration diagrams (Fig. 2)were plotted at 22 + 0.5 0. Fig. 3 shows the
calibration diagrams characteristic of a benzene7toluene-n-xylol-mesi-
tylene mixture. The mean error of determination is not higher than 5%.
Table 2 gives the mobility of the hydrocarbons and also the distribution
coefficients for benzene and toluene determined therefrom. A considerably
higher ratio of the cross sections for the steady and mobile phases can
be attained as compared with silica gel and other carriers when polymers
are the steady phase; thus, an increase in the selectivity of separation
is possible. The method suggested is suited for analyzing hydrocarbons in
petroleum distillates. This paper was read in the Section of Analysis of
the VIII Mendeleyevskiy sl'yezd (VIII Mendeleyev Congress) on March 21,
1959. There are 3 figures, 2 tables, and 7 references: 2 Soviet, 2 USj
1 British, 1 Polish, and I Dutch.
Card 3/4

1.
Partition Chromatography of Aromatic Hydro- S/075/60/015/004/006/030/XX
carbons on Rubber-like Polymers B020/BO64
ASSOCIATION: Belorusskiy gosudarstvennyy universitet im,, V. I, Lenina,
Minsk (Belorussian State University imeni V. I. Lenin,
Minsk)
SUBMITTED: June 2, 1959
Card 4/4

5( S/069/60/022/02/023/024
D034/DOO2
AUTHORS.@ Starobinets, G.L., Barkan, A.S.
TITLE. Nikolay Fedorovich Yermolenko (60 Years Old and 36
Years of -Scientific9 Pedagogical and Social Work).
PERIODICAL-. Kolloidnyy zhurnal, 1960, Vol T.XII, Nr 2, pp 259-260
(USSR)
ABSTRACT.- This article was written on occasion of the sixtieth
birthday (January 2% 1960) and the thirty-sixth
anniversary of the beginning of the scientific, peda-
gogical and public career of Nikolay Fedorovich
Yermolenko. From 1930 the scientist is the h6ad of
the Kafedra obshchey i neorganicheskoy khimii Belo-
russkogo universiteta (Chair of General and Inorgau-
ic Chemistry of the Belorusskiy UniverLsity). In 1932
he organized the Kolloidnaya laboratoriy (Colloidal
Laboratory) at the Akademiya nauk BSSR (AS7of the
Card 1/4

S/069/60/022/02/023/024
D034/DOO2
Nikolay Fedorovich..Yermolenko (60 Years Old and 36 Years of Scienti-
fic, Pedagogical and Social Work).
Belorusskaya SSR), which is also under his guidance
up to the present day. The scientific interests of
N.F. Yermolenko comprise a wide range of subjects.
In addition to works on colloidal Ghemistr_y,@ the
physical chemistry of high polymersland the adsorp-
tion from solutions - the article gives more de-
tailed information on the achievements in these fields
which were the main object of interest to the scien-
tist-9 N.F. Yermolenko and his followers carried out
investigations on general, inorganic and applied
chemistry, and also on the history of chemistry -
in all more than 200 works. The scientist also took
part in the development of a number of branches of the
chemical industry of the Belorusskaya SSR. N.F.
2/4 Yermolenko trained many scientists and founded a

S/069/60/022/02/023/024
D034/DOO2
Nikolay Fedorovich Yermolenko (60 Years Old and 36 Years of Scienti-
fic, Pedagogical and Social Work).
scientific school, whose representatives teach and
develop the chemical science at the Akademy of
Sciences of the BSSR, the Belorusskiy University and
a number of other scientific research institutes and
vuzes of the republic. The public activites of the
scientist are also remarkable. For many years he
has had the leading position at the Minskoye otdelen-
iye Mendeleyevskog6 obshchestva (Minsk Section of the
Mendeleyev Society), and he is a permanent member
of the Minsk Oblastnoy Sovet deputatov trudyashchikh-
sya (Minsk Oblast9 Council of the Worker Deputies)
of the last four convocations. N.F. Yermolenko
was awarded the Order of Lenin, two orders of the
Trudovoye Kras-noye Znamya (Red Banner of Labor), the
medal "Za doblest-nyy trud v Velikoy Otechestvennoy
3/4

S/069/60/022/02/023/024
D034/-0002
Nikolay Fedorovich Yermolenko (60 Years Old and 36 Years of Scienti-
fic, Pedagogical and Social Work).
voyne" ("For valiant labor in the Great Patriotic
War"), and the Pochetnaya gramota Verkhovnogo Soveta
BSSR (Diploma of the Supreme Council of the Belo-
russkaya SSR). He also received the honorary title
of Zasluzhennyy deyatel9 nauki BSSR (Honored Scien-
tist of the Belorusskaya SSR), There is 1 photo-
graph.
Card 4/4

Sulfo Cation Exchangers Based on 78230
Polybutadienes SOV/80-33-3-31/'17
ASSOCIATION:
SUBMITTED:
elution column.
ences, 1 U.S., 1
reference is: J.
Minsk, The V. I.
(Minsk, Belorusskiy
V. I. Lenina)
June 24, 1959
There are 4 figures; and 9 refer-
German, and 7 Soviet, The U.S.
Phys. Chem., 58, 456 (1954).
Lenin Belorussian State University
gosudarstvennyy universitet imeni
Card 2/2

i
I.STAROBINTS,, G.L., prof., red.; NAYDOVICH, A.N., red.; BEIMOKAYA, I.Ye.,
t @e. r @e. @
[Sorption from solutions by high polymers and carbons] Sorbtsiia iz
rastvorov vysokopolimerami i ugliami. Minsk, Izd-vo Belgosuniv.,
19614 151 p. (MBA 14.9)
(sorption) (Polymers) (carbon)

BOLISHOVA, T.A.; STAROBIRETS, G.L.
Parti,tim chromatography of hydrocarbons from solid petroleum
paraffins or -carbamift. Khim. i tekh. topl. i masel 6 no.-5:17-21
My 161* - (MIRA 14:5)
1. Belorusskiy gosudaretvannyy universitet im. V.I. Lenina.
(Hydrocarbons-Analysis) (Urea)

STAROBINETS, G.I.; KEGIIKOVSKIY, S.A.
Chromatographic separation of halide ions. Zhur.anal.khim. 16
no.3:319-322 My-Je 161. (MIRA 14:6)
1, V. I. Lenin Byelorussian State University, Minsk.
Palides)

STAROBINETS, G.L.; RARTINCHIK, G.S.
Separation of mixtures of alkali metal ions and isolation of
magnesium by eluent chromatography. Zhur.anal.khim. 16
no-5:538-543 S-0 '61. (I-MIA 14:9)
1. Institut of General and Inorganic Chemistry, Academy of
Sciences, Byelorussian S.S.R., Minsk.
(Alkali metals--Analysis) (Magnesium--Analysis)

S/069/61/023/001/007/009
B124/204
AUTHORS3 Starobinets, G. L. and Tikavyyq V. F.
TITLEg Sorption of binary solutions by butadiene nitrile copolymers
PERIAICALs Y,)lloidnyy zhurnal, v. 23, no- 1, 1961, 112-117
TEM The sorptive properties of rubber on the basis of butadiene nitrile
copolymers containing )8, 26, and 4CF/5 acrylonitrile were studied. The
butadlene nitrile copolymers contained 2%, sulfur,, 1-5% stearic acid,
1.5% Captax, and 5@ ZnO per IOLY/6 by weight of the copolymera Vulcanization
at 1430C and 3 atm. lasted for 40 minutes. The authors used as binery
sysiemsi 1) a system of a solvent and a polar non-solvent with higher
specific cohesion energy than that of the polymer; 2) a system of a .
solvent and a non-polar non-solvent with a apecific cohesion energy lower
than that of the polymer. To the first kind of systems belong mixtures
of aromatic hydrocarbons with aliphatic alcohols, to the second kind
mixtures of aromatic hydrocarbons with aliphatic hydrocarbons. The systems
of the first kind were analyzed by extraction of the samples, study of
the total and of the partial sorption isothermal 1.1nes of the components,
Card 1/7

S/069/61/023/001/007/009
Sorption of binary solutions B124/204
and by means of an interferometric. technique, whereas the systems of the
VP,e@'-23 (IRF-23)-tYPe
second kind were analyzed with the help of an
refractometer. The experimental data obtained for typical systems are
shown in Figs. 1-3 in the form of curves of the molar fraction of the
non-solvent in the polymeric phase (NP), of the molar fraction of the non-
2
solvent in the equilibrium binary solution (N 2) , and in the form of curves
of the total sorption Q - f(N2) and of the partial-sorption of the non-
solvent Q f(N.). The experiments were carried out in an air thermostat
with a propeller mixer and a contact thermometer; temperaturr, fluctuations
did not exceed +0.50C. The distribution coefficients of the'components
between the polymeric and the solution phase were calculated from the
initial slopes of the equilibrium curvess
K ; K (dNP/01
(dNp/dNl)N ->O 2
1 1 2 2)N 2___'@ 0
in the same way, the sorption potentials of the components in calories per
mole were calculated3 RT lnK.,; T2 - RT lnK2. The results obtained
Card 2/7

S/ 023/001/007/009.
Sorption of binary solutions ... B
for the system beniene-methanol at 25 and 500C were used as an example
The distribution coefficient of the solvent and its sorption potential in
the system of solvent and polar non-solvent are determined by the flexibili
ty of the polymer chain.. '.-he latter decreases when going over from
butadiene rubber to a copolymer with a nitrile content of 40/14t whereas in
a system of a solvent and a non-polar non-solvent the sorption potential
of.benzene rises with the concentration of the nitrile groups in the co-
polymer. Konovalov and Vrevskiy are mentioned. There are 3 figures,
I table, and 8 references: 5 Soviet-bloc and non-Soviet-bloc.
ASSOCIATION: Belorusskiy universitet im. V. I. Lenina, Khimicheskiy
fakulltet, Minsk (Belorussian University imeni V. I. Lenin,
Division of Chemistry, Minsk)
SUBMITTED: July 1,1959
Card 3/7

STAFOBINETS, G.L.; SEDNEV, M.P.
Use of the reaction isotherm in elution chromatography. Dokl. AN
BSSR 6 no.3:172-176 Mr '62. (MIRA 150)
1. Institut obshchey i neorganicheskoy khimii AN BSSR. Predstavleno
akademikom AN BSSR M.M.Paviyuchenko.
(Chromatographic analysis)

STAROBINETS, G.L. [Starobinets, H.L.]; SOLDATOV, V.S. (SaldRtau.. V.S.
Thermodynamic function of Ion-exchange equilibria. Vestai
AN BSSR. Ser. fiz.-tekh. nav. no.3g69-74 162. (MIRA 180)

STAROBIVEIB, G.L@; SOMATGVj V.S.
Thermodynamics of ion exchange. Dokl.AN BSSR 6 no-4:233-236
Ap 162. (NUA .154)
1. Belorusakiy gomidarstvennYY univer8itOt imeni V.I.Lenina.
Rredstavleno, akademikom AN BSSR N.F.Yermolenko.
(Ion exchange) (Thermodynamics)

ACCESSION NR: AT4001413 S/3029/63/000/000/0020/0024
AUTHOR: Martinchik, G. S.; Starobinets, G. L
TITLE: Sorption of alkali metals by ion-exchan9d in'zirconium polyphosphate
SOURCE: lonoobmen I sorbtsiya iz @astvorov. Minsk, _1963, 20-24
TOPIC TAGS: chromatographic analysis, column chromatography, ion exchange,
cation exchange, adsorption, sorption, selective adsorpt'l'oh,-cation separation,
alkali met6I cation, syntheti@ cation exchanger, in'rganic
0 caiion exchanger,
zirconium polyphosphates, inorganic polymer,. preparation, Ion exchange equillbriull;
equilibrium constant, temperature dependence,-ion exch6nger composition
ABSTRACT: In view of the lack of information In the literatur@& on ion exchange
on,inorganic cation-exchange resins, the authors studied the effect of tempera-
tu@e on the selectivity of-the equilibrium exchanqe between ammonium ions and the
'alkali metals (Li, Na, K) between 0 and-90C, at W- 0.1, on zirconium polyphos-
phate obtained from either zirconyl nitrate or zi'rconyl chloride by the method
of Larsen (J. Phys. Chem. v. 64, no. 11, 1960)'..*t-Ne polyfunctional resins ob-
tained from the nitrate and the chloride had molar %atios (ZrO2/P205) of 1.3 and
1.24, and exchange c6pacitles of 4 and 3.24 meq/g, respectively. The results
presented in Figs. 1, 2 and 3 of the Enclosure show that the selectivity Co-
Card 1/6

ACCESSION NR: AT4W413
lefficients were significantly affected by'both the temperature and the compositlon:
of the ion-exchange phi3se; both the selectivity-@oefflcient per se and the effect
of temperature were greater for the resin obtained from the chloride. The resulm
indicate that the ammonium form of zirconium polyphqsphate @@y be useful in the
chromatographic separation of the alkali metals. Or 19. art.... has. 3 figures.
ASSOCIATION: none
ENCL: d4
SUBMITTED' 00 DATE ACQ: 21kov63
NO REF SOV: 002' OTHER: 005'
SUB CODE: MA, CH
2/6
Cord

STAROBINETS, G.L. [Starobineig, R.L.]j DUBOVIK, T.L.
- . .. .
I
Selectivity of aqion exchange on hi W -exchange resins.
. @ y basic Ion
Vestsi AN BSSR. Ser. Fia.-tekh. nav'.",*no.2:48-52 163. (MIRA 17sl)

L 11054-63 EWT(m)/BDS-ASD-RM
ACCWSIGN'Ms AP3000473 S10153163100610011006810(Y71
AUTHOR: B-oldatty, Ve-Se SWobinets, G.-L.
MLEs. Investigating the temperature dependence of the apparent equilibrium
constants of ion exchange processes
SOURCEs Izv. TUM Rhimiya I khimo t ologiya., vo 6, no* 1., 1963, 68--71
TOPIC TAGSs- ion exchange equilibriums ion exchange resins., thermodynamic constants.,
apparent equilibrium constants, M separation., alkali-metals., ion exchange
ABSTBACTs The ion exchange equilibrium was studied in sulfonated styrene ion exr-
change resins containing 6o5j, 10#5,, and 25% divinylbenzene (DVB) at- 0*1., 25j, 60 and
90 degrees for M-H and Ca-H ions; the thermodynamic and apparent-equilibrium con-
stants vv e calculated. These were found dependent on temperature degree of resin
netting and phase of the ion exchanger* For Ca the equilibri= constant decreased
with temperature Increase and increased with DVB increase., k always greater than-l;
for Li decreases noticeably with temperature decrease., k a1ways less than 1. For
example., at 90 degrees in resin containing 605% DVBJ, the apparent equilibrium con-
stants for Cs and M., k = 2,6 and 0a,81 respectivelyj at 0 degrees.. 25% DVB., the
g@sparation Is more than 200 to I* This phenomenon offers a means of separating I&
04-v-@k -- 'ex
Card 112
17-/
_0
7:@

SOLDAMV, V.S.; STARODINEI'S, G.L.
Study of the thermodynamic functions of ion exchange processes.
Izv. vys. ucheb. zav.; khim. i khim. tekh. 6 no-3:420-424 163.
(MIRA 16:8)
1. Belorusskiy gosudarstvennyy universitat imeni Lenina, kafedra
analiticheskoy khimii.
.,(Ion exchange) (Thermodynamics)

S/250/63/007/002/007/008
A059/A126
AUTHORS:
TITLE:
Starobinets, G. L., Novitskaya, L. V.
The swelling pressure of ionites
PERIODICAL: Doklady Akademil nauk BSSR, v. 7, no. 2, 1963, 103 105
TEXT: A systematic investigation was performed on the swelling properties
of sulfonated polystyrene ionites with different degrees of crosslinking which
contain Ht, Li+, Nat, e, Rb+, Cs+, Ag+, and Tl+ as the opposed ions in-the
binary mixtures water - acetone, water - methanol, and water - dioxane. The
isotherms of total swelling and those of the sorption of water and the organic
component were determined as well as the distribution of the components between
the phase of the ionite and that of the solution in the whole system character-
ized by the curves: molar portion of the organic component in the ionite phase
(Nb) - molar portion of the same component in the equilibrium solution phase (N2).
The asymmetry of the distribution curve and, consequently, the selective sorption
of water increase with the Increasing degree of crosslinking of the ionite, and
the selective water absorption decreases with the increasing degree of hydration
Card 1/3

The swelling pressure of ionites
S/250/63/007/002/007/008
A059/A126
of the opposed ion. The swelling pressure can be calculated from thermodynamic
values using the equation:
TrV = RT ln n ln aw, (1)
Po
where p/p. is the relative tension of water vapor (or the activity of water) in
the external solution, aw the activity of water in the ionite phase, -jr the swel-
ling pressure, and V the partial molar volume of water. Since the activity of
water in the ionite phase is unknown, the simplified equation:
- RT ln P1, (2)
V p
was used, where p' Is the vapor tension above the ionite with a low degree of
crosslinking. The value of @7calculated from equation (2) represents therefore
not the total swelling pressure, but only its component due to the lattice
stress. The calculated boundary values of the swelling pressures for the ca-
tionites HY-2 (KU-2) show linear variation with the degree of crosslinking,
being 2,000 atm for its hydrogen form, and the zeroth degree of crosslinking in-
Card 2/3

The swelling pressure of ionites
S/250/63/007/002/007/008
A059/A126
creasing by 70 atm when the styrene content in the polymer is raised by 1%. Thus,
the total swelling pressure is found to be equal to the sum of two components,
one due to the primary hydration of the moving ions and the other to the stress
in the lattice. There are 2 figures.
ASSOCIATION: Belorusskiy gosudarstvennyy universitet im. V. I. Lenina (Belo-
russian State University imeni V. I. Lenin)
PRESENTED: by N. F. Yermolenko, Academician of the AS BSSR
SMUTTED: June 27, 1962
Card 3/3

- I :,,! ...... .. . . ' ! " 'XTY
'I, @ . , ME,,*f;KDV,, I I S.ii.
Partiz'-on chromatography on -@t-,n exchp-nge.rs. RepsrL flo.2:
Sepa-ation of halogenate and @;a-@olvcnide ions. Zhur. aml.
@Illm. 18 no.2:--";:-)-260 F 163.
(MIE-4 -17:1011
Ic Lenin Whtte lliassian State ftivers-ity, Minsk.
.L

AFOB@!-',ETIS, Cr.L-- M-;:CI;',OV:'!,`Y
"T
Partit 1 on chromp-".@ography on ion e-xchangers. Report No.!;
,'@eparation of anions oxidizers. Zhur. -anal. khim. 18
@@ , i z 5
rio.3;298-303 ?,',r'63. (mm, - -
1. Belorusskj.y gosirdarstvermyy universitet Imerif- l.er-ina,
Mdrsk.

STAROBINETS, G.L.; NOVITSKAYA, L,V.
Swelling of ion exchapgars in binary..s*lutions. Part 1- Factors iiiflu-
encing tl@t'aelectivo sorption of water.' Koll.zhur. 25 no.6:0'89-694 N-D
,63. (MIRA 17.-l)
1. Belorusskiy universitet imeni V.I.Lenina, Minsk. . I

S/076/63/037/002/005/018
Thermodynamics of the ion ... B101/B186
by the "negazive near hydration" of these ions leading to a stronger
binding between cation and ionite and to the formation of ion pairs. This
is also confirmed by the different coefficient of selectivity
0 +
K11+ with poor filling. Viith 0.1 filling anq 0 C, K is for Cs
+
Rb+ -5.0,' K+ -3.0, Na 1-5, and Li (vO.S. 'With 0.9 tilling, all-Im
K
H+
approach the value -1 .6, exce lot Li+ (- 0-5)- In dilute solutiofii the
+
activity coefficients are for k-+,.Rb+,.Cs+ lower than@fbr Li and Ne..
moylov (struktura vodnykh rastvorov elektrolitov i
concept of 0. Ya. Sa
gidratatsiya ionov [structure of aqueous electrolyte,aolutions and
hydration of ions], Izd-vo All SSSR, M., 1957, 76) on the hydration of the
ions as statistic process is import-ant for the interpretation of the.
selectivity of the ion exchange. There are 4 figures and I table.
ASSOCIATION: Belorusskiy gosudarstvennyy universitet im. V. 1. Lenina
(Belorussian State-University imeni V. I. Lenin)
SUBMITTED: July.20, 1961
Card 2/4

Thermodynamics of the ion
Rb+- H+
213,3 2,84, -568
298,2 2,05 -424
333,2 1,65 -333
363,2 1,44 -263
C,+- H+
273.3., 3,23 -647
298,2 2,30 -495
333,2 1,90 -378
363,2 1,61 -344
Card 4/4
-1972
-1601
'-12SIA
-1184
-1997
-t568
-1300
-1200
S/076/63/037/002/005/018
Blol/B186
-14041 -512
-1177 -4.0
- 953 -2,9
- 921 -2,6
-1350 -5,1
-1073 3,7
- 922 --.!.2,9
- 856 -2,5

P"*VDS
L 017 5-66 j ) /E7,3(m) Z@j U /oofi-/Wa@019/s
ACC NR, AR6ol4535
vik T.
0. L.; PubO d ion
arobinets.4 .1 the derive
EUTHORS2 �@t@_' propert4 8
structure upon selective
TITLE2 Effect of the polymer
exchan e.r Pibs- 19S506 Sh. ghlrol-AP
SO,URCF,z Ref. 2h. Khimiya) sposobnost'- MI'sk' Vys
Sen. realctsli I reakts-
Sb, Getero
REF SOURCZ.
sulrC'j-_r'tioa
1964, 14-19 synthetic rubber)
n exchange -resinj,
TOpIC TAGS2 polymer structure, io Ldert@@en by: 1) sulfonation
,change resins was ur, limit and main-
aSTRACT- The preparation of ion :)prene rubber stretched to the
at 97--96C of chlori I mbber!&pt at 150C for 3 days
chlorosul*%tl
with 98% li,,SO4 and of .@j@rene
2 months if onation With
ttained at this state for -ju-bber)' and 2) su
onth (annealed Exchange
and cooled to -20C for 1 m, -ntained in a stretched state.
; of chloroprene rubber ma:L i produced samples Of ion
fonic acid at -20( le of al
and NaOjj and degree of swellir change of
of the equilibrium Ox
capacities for NaCl stigated. The selectivity ion of Polymerswith 98%
exchangers were inve 4+ on resins obtained by sulfOnat. e on the resin
U+-Ne, e- --lie exchaxig
--Li* 3, . acid*
also Studied.V aswas the selectivity of the IC@ with chlorosulfOnic
H,S04 was no rubber by sulfonation
obtained from stretched chloropre
It Was shown that selectivity of ionic
Polymer from which the exchanger Was Dr exchange is related to the structure of the
uncrystallized exchanger. epared. Selectivity is poorer
Of the in the case orl
stretched and Of the annealed chlo ion exchange resins prepared by sulfonat,on of
roprene rubber, the stretched iL the
Xhibited better
05hellorctsiuviity0noof exchange- Exchange selectivity of ion exchanger obtained by
I
acid sulfOnatiOn of rubber maintained in a stretched state cOrrespond4'
bto all Practical PurPOsGs. with the selectivity exhibited
y 112504 sulfonation of that rubber by exchange resin produced
N. Shamis CTranslation of abltracg
M CODE: 11 ) 07

EIVY(M) RM/DS
ACC N.R-. SOURCE CODE: UR/0081/65/000/024/3073/SO731
AR6016970
AUTHOR:, Sednev', M. P.; Starobinets, G. L.
ITITLE: Effeat of beat treatment on selective properties of
sull'oeattionites
SOURCE: Ref. zh. Xhimiya, Abs. 243511
REF SOURCE: Sb. Geterogen. reaktsii i reakts. sposobnost'. Minaks
Vyssh. shkola, 1964, 20-25
TOPIC TAGS: ion exchange resin, polymer structure, desulfurization,
hsat resistamee SUAe',--
ABSTRACT: A method was iiorked out for thermally desulfurizing ion
exchange resins under conditions of rigid thermostatic control and
continuous removal of the desulfurization products with a stream of
superheated steam in the absence of contacting the ionite with
atmospberic oxygen. This makes it possible to obtain an ionite with a
specified sulfo group content with maximum retention of all other
properties. It was observed that the exchange capacity and the degree
of swelling decrease in the beat treating process but the bound sulfur
content increases, apparently due to the formation of sulfone bridges,
C"d

L 40963@6
ACC NR: AR6016970
0
T- was shown that cationite KU-2x6 has greater beat stability than
cationite KU- ffranslator's Note: Latter part of designation
illegibl2e. Cationite KU-2x6 in the Na-form is completely stable to
225-2300. The density of the ionite decreases during desulfurizing
whIle the density, in relation to the same number of sulfo groups in
the original and beat treated cationite, increases. This indicates
packing of the ionite structure during beat treatment. N. Sbamis.
Zx7ranslation of abstrac-t7.
SUB CODE: 11@01

STAR OBINETS, G.L.; NOVITSKAYA, L.V.
Swelling of ion exchangers in binary 3olut-Ions. Part 2: Swelling
pressure of ion exchangers. Koll.zhur. 215 no.1:105-109 Ja-F
,64. (MIRA 17:4)
1. Belorusskiy universitet Lment lanina. Minsk.

Of iOr, ex--@-.-anqge on cope-l-mers of
3 tyr - ne ir-IIA7,'jn..rlbe-,7ene. 'art 4. Zhur. fiz. khim. 38 no 6-'-
1523-1529 Je-164.
1 Belorus@kiy- j6i@diiiit- v--eilii@Y uindiv-eri i7tet sk.

STAROBINETS, G.L.; SOLDATIOV, V.S.
Thermodynamics of ion exchange on sulfonated copolymers of
styrene and divinylbenzene. Part 3. Zhur. fiz. khim. 38
no.4:992-995 Ap 164. (MIRA 17:611
1. Belorusskiy gosudarstvennyy universitet.

suEmTm. i8,Tun63
MICL: 00
MM CODEE: IC, TD NO MW SOV: 007 01UM: 005

of

ACCESSION NRi Ap5oo4352
resin by metallic ions the coeffloient@ of ac tivity change considerably and
tho gh consteat. -Prom the
T6 _U witbln the group, differs A,
ion f or lithium and- 80 I= QW-4 -@1he,exchange -Q:f _qilvej'@'and thalli= n
un-t :16a
depends on their properties of strong-polarizers and on -:-the powiar__ of--h:Vdration-
uhich is strong In silver and weak -in thallium. The exchanges o silver and-,
hydrogen ions on reeinu of medium and high network densities depend on some factor
which favors t1io decrease of apparent equilibrium constants with the saturation of
-the ionite by metallic Ions,, On low density- networks this factor,is practically
absent. The binding Is not erytirely Ionic -,uad the interactions are not entirely
a the interactions of
coulombic. Decreases of dielec@ri6 permeability increas
':ions. Ohanges of entropy are weakly negative or positive during silver hydrogen
rexchange. Thallium-hydrogen exchange is similar to the silver-b7drogen exchange,
with a slight difference caused by the lack of hydration in thallium. In the
ionite phase) lithium and sodium do not enter, in-to ionic interaction., while
,pobassiumi rubidium.and cesium are partially bound to short ionid'couples) and-
and thallium ions are bound to couples c1loselr relat6d to nondissociated-
Lzolecules. Orig. art. has: 3 Woles and 2 formulas,
4S30GIATIONi JAkademiya nauk BSSR@Jnstitut ftshchey i neorganicheskoy khimii
B
(AcadeW of Sciences SM,, Institute of Generaland Inorganio Ghemis:try)
Card 2/3

CE 5c Flo Yll i
+C,
z. of

SOLDATOV-, V.S.; STAROBINEM,,, G.L.. (Minsk)
Thermodynamics of ion exchange on sulfonated styrene and
divinylbenzene copolymers. Report No. 5. Zhur. fiz. khiln.
39 no. 100-34 Ja 165 6an 19a)
Thermodynamics oi ion exchange on sulfunated styrene and
divinylbensene copolymers. Report 6. Ibid.%35-39,
Surfacemolecular properties of alPba-elkYltbiophanese
Ibid.t168-vo.
1. Ihstitut obahchey i neorganicheskoy khi-ii AN Belorusskoy
SS& Sutmitted December 10t 1963.

STOC-13INEI" i'3 -1 - SEDNEV, M.P.; DUBOVIK, T.L.
(--once-ritration and separation of small amounts of elements by eluent
chromat,ograpkv. Trudy Kom. anal. khiim. 1-023-330 t65@ (MIRA 18--.7)
-1 @,

STAROBINETS,_P@Lq_ WCHKOV9,IY, S.A.
Concentration of electrolyte impurities by means of salting-out reversed
chromatography. Trudy Kom. anal. khim. 15:346-352 165. (MIRA 18-.7)

STAROBIRTS, G.L.qq hTiRTMG11) O.F.
Sme chareatfriorlexi c-,f trol6cijlar sorpticn cr. ion exci4n e
I g, r? . Dck I.
Py BSSR 9 nr@,8?5J&-51.9 Ag 165. (M-IPA 18?10)
I. Tnstitut obshchey i neorganicheakly kMrill AN BSSR,

veak or@;an5.,z fiz. le-hLm. 39
8- -19,
n-:@cpganinlleok,:@,v kh ANN BSSR.
-ML

SER117, M.P.; STAROBINSTS, G.L.; AKUIOVICff, A.M.
-- - --- I-'__-__I_-I__
Separation of strontium from calcium and magnesium by ion-exchange
chromatography. Zhur. anal. khim. 21 no, 1:23-27 t66
(MIRA 19:1)
1. Belorusakiy Aaqudars Lvennyy univervi-tet imeni Lenina i In-
stitut obohchey I neoria-in-re-h-Wek-o-yihimil Ali BSSR, Minisk.

ZIATOPOLISKAYA., R.D.; @T SHULICHENKO, A.I.; ROMASHKO;
Yu.V.; KWOVITSKAYA, A.M.
Experience in cupping foci of epidemic hepatitis in-children's
preschool establishments. Vop.virus. 7 no.6:724-725 N-P 162,
(MIR& 16:4)
1. Kharlkovskiy nauchno-losledovatellskiv institut vaktoln i
syvorotok imeni Mechniko* Ukrainskiy institut-usoverahenstvo-
vaniya vrachey i Khartkov.ikaya gorodskaya sanitarno-epidemilogi-
cheskaya stantsiya.
(BEPATITIS, INFECTIOUS) (GAMMA GLOBULIN)

DIKENSHTEYN, G.Kh.; KUTUZOVA, V.V.; MASRIYKOV, K.K.; BABAYEV, A.G.;
POLISTER, L.A.; YUFEREV, R.F.; SHISHnVA, A.I.; BAREYEVp
R.A.; MAKAROVA, L.N.; @W-ADOV, K.; PYANOVSKA-YA, I.A.;
SENIOV, V.N.; SIROTIUAI Ye.A.; TURKRIA, I.S.; FELIEDRAN,
S.L.; KHON, A.V.; KUNITSKAYA, T.N.; GOLENKOVA, N.P.;
ROSHINA, V.M.; FARTUKOV, M.M.; SHCHUTSKAYA, Ye.K.;
ALTAYEVA, N.V.; DYKADOROVp V.A.; KOTOVA, FI.S.; S/LIRNOV,
L.M.; IBRAGIMOV, M.S.; KRAVCHENKO,, M.F.j MARKOVA, L.P.;
ROZY17EVA, T.R.; UZAKOV., 0.; SLAVIN, P.S.; NIKITINAI Ye.A.;
MILOGRADOVA, M.V.; BARTASHEVICH, O.V.; 4TXI@OBDIETS, I.S.;
KARIMOV., A.K.
(Splicing of the wires of overhead power transmission lines]
Soedinenie provodov vozdushnykh linii elektroperedachi. Mo-
skva, Energila,, 1964. 69 p. (Biblioteka elektromonterat
no.132) (MIRA 17:9)

S'MROBINETM, I. S.
"Ibe Application of the Chromitographic Technique to Lumenescence-Capillary
Analysts of Crude Oils and Asphalts" (Chexhistry: Analytical) Izv. An Turlm.
SSR, No- 5, 1953
Abs
W-31146, 1 Feb 55

M
VWWAMMMIM,
F-T S
USSR/ Cosmochemistry. Geochemistry. Hydrochemistry
Abs Jour Referat Zhur - Khimiya, No 4, 1957, 11536
Author Starobinets I.S.
Inst We-a-demyof Sciences Turkmen SSR
Title On Some Geochemical Characteristics of Petroleum of the Pribalkhanskiy
Rayon
Orig Pub Izv. AN Turkm SSR, 1956, No 1, 35-41
Abstract Petroleum-bearing matter, conditions of sedimentation basin, rock litho-
logy had no, or little effect upon the formation of different types of
petroleum of the fields of the Priballib"skiy Rayon. This diffei6ntiW-
tion is connected primarily i4lth -secondary changes. Study of ciffferen-
ces in properties of fluids of various tectonic units of.the same field
supports the possibility Of the o6curence of oxidative pro6esses Under
subterranean conditions, As a result-of which the more cyclic bitumi-
nous and oxidized petroleum is formed from those higber in methine.
Discovery of oz6cerite in districts'of the-occurence of practically pa-
raffin-free Petroleum in Western Tuikm6ni:@a in the-forii-of'stratified
deposits supports the assumption that paraffin petroleum from vhich
1/2
D.

Y,
STAROBINETS, I.S.
., -I-
Role of the oxi&qtlea factor in the formatioR of awl& petroleum types
of the Balkan region lit western TurkwRia. Hof t.khes-34 so-8:54-57 Alt
156. (Balkhan--Petrelcum) (KIRA 9:10)
=17

SMODIMMS, I.S.; PARPIYNV. A.
Bqulllbrl= cout"to of mis petrolem ItKrocarbons. law. AN
Tmrk. MM no.1-161-103 15?. (UK lo: 4)
lo Turkmenakly flltal Tessoynsnogo usuabno-loolodovatellskogo
imt1tuta.
(4drocarbons)

STA I. S. Doc jand Chem Sci -- (diss) "Main types
,:,) i ROBINETS I
of petroleum of ft?ibalkhaiiskiy-@Rajoh-Abm@641%9, ca (Viest Turk-
a q- P @n @ih@
meniya geoEchemical characteristics of their distribution."
Zlshkhaba@/, 1956. 12 pp 19 cm. (All-Unionketie@ ScientI4&ke
Pro
Re @&;@@fn_d`tbm3p@_
Tur@mien Affiliate of the
All-Union Petroleum and Gas Jcientific Research Instj_TF VNII)
(KL, 21-57, 99)