SCIENTIFIC ABSTRACT STERLIN, R.N. - STERMA, F.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001653310007-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 3, 2016
• Document Release Date: August 26, 2000
• Sequence Number: 7
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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D
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Irr' ed
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a

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,11-1 @WUp!io.;ph loll
with dr.i 11G11 Ilavc-,
L(Ad Go%; bp
c I., P L@j (C,, I J@, + 411C1 )CF,-, @CFPC1, + 2(C,11 11H - HC.1
5)2
Simllavly, the dc-uc)jflpoL;ltlc)ll ul, dI-(tI-j1'1L1UVt-,VlI1yj)-
pkuophinoilto dlQthylamide L@uvc, dl-(tv11,1uoI,,Qvl1lY1)-
(yleld 60%; bp C; jl@-,b 1 .116-5;
D .1
(CF 2- CF),PCI AIL;o Lit! iy ldl chlovopho:;phine (C 2If 5PCI 2)
wa@; -riit:ieL;Izcd. ThC CIM;t WO CI11Ul'OP1lQjP1IlILC3 III
1*t.@U,*-111-1-oi-, with aimlinon-ouL; i'luovide weve, trau;1'Gvmed into
L@w covvu@;pond III
11cluldi Va2ily LIP III all'. Per-
i'l~to.,ovii-i~,ldleiiloi-opliL)2piiiiiE.@ thu2 i@ave peri'luo lily I -
Cat'd 3/j.j dIt*1L1O1'OpI1OGOhI1Ie (yield 64%; bp 2-30 C)

I i ILI I C, p Ili J p I "1 -(7300
SOV,/'63-4-6-,'
34/37
3cr. 2- CFPC12+ 2SbF3 @NF2@ CFPF@D + 2SbC13
S111IL-larly, L;ave
d1,-(tr' L'IU01-ovilly 1cluo roplic)L;pi I I lie (CFO-CF).,-,PF
@lcld 50%; bp 63-650 C) - There are 3 referelicc's, 1
U.K;, I Gennan, I Soviet. The U.K. rel'erence is:
F. Bennett, If. EmeleLI3, R. Haszeldine, J. Chem. Soc.,
p 1565.
SUBMITTED: JL11Ie 11 1959
Card 4/4

5 (3)
AUTHORS: S_terlin, R. IT,, Li-Wei-Kang, SOV/62-59-8-37/42
Knunyants, I. L.
TITLE- PerfluoTodivinyl Mercury
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheakikh nauk,
1959, Nr 8, P 1506 (USSR)
ABSTRACT: It is reported that perfluorodivinyl mercury (C 4F6Hg) was obtained
from perfluorovinyl magnesium iodide and mercury chloride in an
ether solution at -10-50 as a colorless liquid with a dis-
agreeable odor (slightly soluble in water). C 4 FJg reacts rather
easily with iodine while perfluorovinyl iodide is formed. The
physical properties of C 4F6Hg differ considerably from those of
the perfluoroalkyl mercury derivatives. These have a high malting
point and are easily soluble in water. In comparison to the
compounds investigated they are considered to be halogene
derivatives of Hg whereas the former are designated vinyl
derivatives of mercury in which the pseudohalogenous character of
the perfluorovinyl radical is not prominent. There is
Card 1/W 1 reference.

JI @f
0 V/16 I_,2_Ii_)1
A 0 113 SI erl -in, R. N. Bo.-achev, V. E. , Yatsenko, R. D.
-rrrlri -ya FT -7, - f
TI "LE: 1',niz @)t' Fluo!-joleCins. Communication 10. Concerning
1111io Dcpendence of Chemical Pi-operIties of' Fluoro@,@Ieflns
-i P:)larity
PERIODICAL: iya Allademii nauk SSSR. Otdelenie "C'nimichesk-ildi
a Ili, 12, Lip 21`7,1-2155 (USSR)
A-3S 7HiC 1':
-P
at 1@ mm) was ottained by shaking perfluorovinyl
!!:,!TI I. d ea Idiethylamine, at)r(jorn temperature, for
."'Ju-S. On. ;iydrolysis of (I with water, the diethyl-
amL,je j"i 111-io-obromoacetic acid :bp 93o at 4 mm) was ob-
t e
a L.,I e dn IXO yield. It was shown that, ne reaction rat
-,f ajdi'.;.Dn of' diethy'amine to perfluorovinyl lial-des
increases -;-ri-h increasing polari-,y of the olefin, molecule.
reacts vigorously w-P.--1 diethylamide of
acid; almost fails :o react '...,ith the
I,'e*,;,.-!amIAe ch.-Io-oacetic acid, and reacts very slowly
C a., -:11L A

-, -, I - - 1@ -7 "7 2
F c a*,
2
Deperlence Chemical
p'! -)n Polarity
2
e am n 2 -r 4 I'lu, c rbl, omo - r
Tiere is I Ifigure; tal-Jles; an.-,
U.K., U.S. 7iie U.S.
I'e`e-en-es' "T'e:rmar,
',-'.K. -el'erences are: R. N. Haszeldine, j. Chem.
A. Giacomo, R. Saith, J. Am. Ciiem.
S:. G. Rigby, H. Schroeder, U.S.
.p a !9- Hurwitz, W. Miller, Abstracts of
46);
Meeting, J. Am. Chem. Soc. 41 (lq-48@
pa 0 e j .

SMLIN, R.N.; PINKIHh. L.N.; TATSMO, R.D.; KYJNY.4H'M, I.L.
PerfluorovimVl derivatives of arsenic and antimony. Khia.nauica
i prom. 4 no.6:800-Ml 159. (MIRA 13:8)
(Arsenic compounds)
(Antinow compounds)

STRUIN. R.N._; PINKIW, L.N.; KMNYANTS, I.L.; NEZGOVUROV, L.F.
Exchange of radicals in the series of perfluoroalkenyl derivatives
of magnesiu. Khim.nauka i prom. 4 no.6:809-810 159.
(NLRA 13:8)
(Magnesium organic compounds)
(Badicals (Ghemistry))

STERLIN, R.N.; YmTSMO, R.D.; PIRKII6, L.K.; KNMi.LMS, I.L.
Perfluorovizqlhalophomphines. Xhim.nauka i prom. 4 no.6:810-811
'59. (MIRA 13:8)
(Phosphine)

STJMDI,__4tH! . [translator]; KNUNYANTS, I.L., skademik, red.;
YITKOVSKIT, D.P.. red.; RABINOVICH, F.T., red.; ZASUGISEATA.
Y.F.. tekhn.red.
[Modern experimental methods in organic chemistry] Sovremennye
metody eksperimenta v organicheakoi khimii. Pod red. I.L.
Knuniantsa. Moskva, Goo.nauchno-tekhn.izd-vo khim.lit-ry, 1960.
627 P. (KIRA 14:1)
(Chemistry, Organic-Uperiments)

86479
11871 22-09" 1716C S/06 60/000/01i/co6ft16
B01 3XO78
AUTHORS: '-S@texjjR_L R. N., Yatsenko, R. D., Pinkina, L. N.,
Knunyants, I. L.
TITLE: Perfluoro Derivatives of Nonmetals
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdelcniye khimicheskikh
nauk, 1960, No. 11, pp. 1991 - 1997
TEXT: The preparation of perfluoro derivatives of phospho3zusa arsenic,
and antimony is described. From the reaction of perfluorc/IffAesium
iodide with AsCl 39 PC1 39 and SbC13 in ether solution only tertiary de-
rivatives were obtained: tri-(trifluorovinyl)arsine, tri-(trifluoro-
vinyl)phosphine, and tri-(trifluorovinyl)stibine. Primary and secondar
derivatives were not formed in this process. Perfluorovinyl dichloro-
arsine was obtained by splitting 10-alkyl-5,10-dihydrophenarsazine with
dry HC1 (Ref-4). A corresponding perfluorovinyl derivative was obtained
in a quantitative yield as a result of the reaction of perfluorovinyl
magnesium iodide with adamsite. Perfluorovinyl chloroarsine was
Card 1/3

8%79
Perfluoro Derivatives of Nonmetals S/062/60/000/011/006/016
B013/3078
isolated in a practically quantitative yield by the reaction of
CF2-CFAs(C6H4)2NH with liquid HC1. By treating the tetraethyldiamide of
phosphorous acid chloride 'and the totraethyldiamide of ethyl phosphinio
acid with dry, gaseous HCl in xylol solution, phosphorus trichloridep
and othyldiohlorophosphine, respectivelyl were obtained. From the reao-
tion of perfluorovinyl magnesium iodide with the tetraethyldiamide of
phosphorous acid chloride, the tetraethyldiamide of perfluorovinyl phos-
phinio acid was obtained. This was converted into trifluorovinyl dichlo-
rophosphine by reaction with dry HC1 in ethex solution. By treating the
latter with antimony trifluoridep perfluorovinyl difluorophosphine was
obtained. In a similar manner, the diethylamide of di-(trifluorovinyl)
phosphinic acid was obtained from (C 2H5)2NPC12 and perfluorovinyl mag-
nesium iodide. By decomposing it with dry HC'l, di-(trifluorovinyl)chloro-
phosphine was synthesized. By treating the latter with antimony trifluo-
ride, di-(trifluorovinyl)fluorophosphine was obtained. As opposed to the
trifluoromethyl derivatives of arsenic and phosphorus, the prepared
tr-.-(trifluorovinyl) arsine and tri-(trifluoi-ovinyl)phosphine do not
Card 2/3

86479
Perfluoro Derivatives of Nonmetals S106 60/oOc/CI1/oo6/o16
BOI 3Y3076
separate trifluor(ethylene when heated. Thus, the perfluorovinyl radical
in the said compounds does not show any properties of pseudohalogens.
Ye. P. Shcherbina and L. F. Razgovorov assisted in this work. There are
8 references: 2 Soviet.
SUBMITTED: June 4, 1959 j
Card 3/3

STERLINv R.Ne; LI VEY-GAN; KNUNYANTSP IsLe
Reactions of perfluorodivinylmercurya Zhur.VKHO 6 noolilOS-109
161. (KMA 14:3)
(Mercury)

6TERLIN, R.N.-; PUBOVj S.S.; LI VEX-GAN; VAKHO,'ICII'1Kp L.P.; kaTUNYANTIS, I.L.
Certain regularities in the series of perfluorovinyl derivatives
of the elements of groups IV and V of the periodic table.
Zhur.VKHO 6 no.1:110-111, 161. (MIRA 14:3)
(Vinyl compounds)

STERLIN, R.N.- LI VEY-GAN [Li Wei-Vanp.,J; KNUNYANTS, I.L., akademik
. -1-
Electronegativity of the perfluorovinyl radical. Dokl- AN SSSR
140 no.1:137-140 S-0 *61. (MBU 14:9)
(Vinyl compounds)

STERLIN, R.N.; DUBGV, S.S.
hifrared spectra of perfluorovinyl derivatives of elements. Zhur.
VKHO 7 no.1:117-118 162, (MIRA 15:3)
(Vinyl compounds-Spectra)

DUBOV, S. S.; CHELOBOV, F. R- N.
Mass spectrometric study of some vinyl and perfluorovinyl com-
pounds. Zhur. VKHO 7 no.5:585 162. (MIRA 15:10)
(Vinyl compounds-Spectra)

DUBOV, S.S.; TETELIBAUM, B.I.; PTERLIN R N
Nuclear uAgnetic resonance of some perfluorovinyl derivativeB.
-Zhur. VKHO 7 no.6:691-692 162. (MIRA 15:12)
(Vinyl compounds-Spectra)

KNUNTANTS, 1.L.; STERILIN, R.N.; TTULENEVA, V.V.; PINKINA, L.N.
Pseudohalide properties of perfluaroalkenyl radicals in esters of
perfluoroalkenylphosphinic acids. IzY. AN SSSR. Otd.khim.nauk
no.6:1123-1127 Je 163. (MIRA 16:7)
1. Institut elementoorganicheskikh soyedineniy AN SSSR.
(Phosphinic acid) (Radicals (Chemistry))

L-2@@65 EfiT(m)/E PF (c)/E PR/Etw(j )/ENA (c). PC-4/Fr-4/Ps-4 RPL RM/a
ACCESSION NR: APSOOSS21 S/0286/65/000/00610026/0026
AUTHOR: Gololobov, Yu. G. ; Dmi triyeva. T. F. ; Soborovskij, L. Z, ; @Inq
Yu.
TIT A met od for producing alkyltrifluorovinylalkyly 5phinatep Class 12,
Ho'LE1619118
'SOURCE: Byulleten' izobretenly I tovarnykh znakov, no. 6, 196S, 26
TOPIC TAGS: fluorine compound, phosphonic. acid, organo wallic compound, mercury
jorganic compound
ADSTRAM This Author's Certificate Introduces a method for producing alkyltri-
4
@ fluorovinylalkylphosphinates. Acid eaters of alkylphosphonic acids are Interacted
with perfluoro Imercury during heating. The Author's Certificate also covers a
?rfluoroviny
ication of Ma met In which a heating temperature of approximately 1000C
modir
ja uacd.
1ASSOCIATIONs none
@SUDMITTEM 20Feb64 ENCLi 00 SUB COM M, OC
no Ra my I - 000 ona 1 000
!Card-

- @1@
KNUNfANTS, !J.@ TYULEWEVA, V.V., PMVOVA,, Ye.Ya.: STERLIN, R.N.
Pseudophosphonium 2ompnunds from triethyl pho.9phite and
pcrfliicrc----clo--fIns. Izv. AN SSSR. Ser. khlm. no.M1797-
1801 0 lh4. (MIIRA 17:12)
.. Inat.ltuT, elemontoorganJcheskikh eoyedineniy AN SSSR.

V ERV E-K I IA y A. K. I i nz h. ; KO LC 11 11F,,K 1Y , Y u. L. , i n zl-... ; N I KCL.-Vi EVS )KIY
Ye.Ye., irizh.; -,ODIO@:OVA, inzh.; RTAMLM , A.F.,
inzh.; SOKOL T A.p nzh.; SrERLD'., S.L., lnzh.;
E-,'DEL11,ANT, L.B., inzh.; ORLOV, V.N., kLna. 'Uekhn. nauk,
retsenzent YUR2,EL11 inzh., retsenzent; FOFr*l , V.Ya.,
inzh., nauchn. red.; VOL11YA11SKE1, A.K., glav. red.; SUDAKOV,
C1.1111.1 zam. glav. red.; IOSELOVSKIY, I.V., red.; X.AHKOV, I.I..,
red.; MELINIK, V.I., red.; O!"KES, A.K., red.; STAROVEROV,.
I.G., red.; TUSI-1-1AKOV, M.D., red.; CH17,EEOV, A.V., eed.
(Engineering pipelines for industrial enterprises] Tekhno-
logicheskie truboprovody Fromyshlennykh predpriiatii. Mo-
skva, Stroiizdat, 10,64. 2 v. (MIM 17:12)

VERVEIKINA, A.K., inzh.; KOLCIIIHSKIY, Yu.L.,, inzh.; NIKOLAYEVSKIY,
Ye.Ya., Inzh.; RLODIONOVA, H.G., inzh.; RYAPOLOV, A.F., inzh.;
SOKOL, I.A., inzh.; STMIN L- inzh.; 17DELINANIT, L.B.,
inzh.; ORLOV.N.M.1 &E@, Ue T. 'I
nauk retsenzent4 YURGFV,B.I.j,
inzh.,retsenzent; FIDKIN,V.Ya., insborymmmobao red.; VOIliYANSK37r,A.K.
red.; MARKOV, I.I., red.; HELINIK, V.1., red.; ONKIN, A.K.,
red.; STAROVEROV, I.G., red.; TUSIR@IYAKOV, H.D., red.; CHERNOV,
A.V., red.; SUDAKOVIG.G., red.; IOSELOVSKIY,I.V., red.
[Technological pipings in industrial enterprises] Tekhnologi-
cheskie truboprovody promyshlennykh predprliatii. Moskva,
Stroiizdat. Pt.l. 1964. 784 p. (MIRA 18:9)

BOLTUKHIN, A.K.; STIRLIN. AN, L MUSHTAYIV. A.Y.; MOROZOV, I.I.; KUDINOV. V.A.:
MONAKHOV, G.A----KZARSTICH, G.M.; LAPIDUS. A.S.; PROKOPOVICH, A.Te.,
redaktor; RZ;@iIIISKIY, V-V., redaktor Ledatelletva; TIKHANOV, A.Ya..
tekhnicheskiy redaktor
[Modernization of knee and column type t2illing machines; instructions]
Modernizatsiia konsollno-frezernykh stankov; rukovodiashchis materialy.
Pod red. A.I.Prokopovicha. Moskva, Gos. nauchno-tekhn.izd-vo mashino-
stroit.lit-r7, 1957- 194 p. (MLRA 10:8)
1. Moscow. Usperimentallayy nauchno-Iseledovatellekly institut
metallorezhushchikh stankov
(Milling machines)

10=OV, Anatolly Pavlovich; TROFIMOV, Arkadiy Alekseyevich; ST-E41N,,-Ya.B.O-_
retsenzent; PESKOVA, L.N., red.; BOBROVA, Ye.N., tekhn. red.
[Journal-voucher accounting system on railroads] Zhurnallno-
ordernaia forma ucheta na zheleznvkh dorogakh. Moskva, Voes.
izdatellsko-poligr. ob"edinenie M-va putei soobshcheniia, 1961.
137 PiRailroads-Accounts, bookkeeping, etc.) (MIRA 14:7)

BOCHVAR, A.A... akadomik.. red.; MEL'YANOV, red.j ZVEREV, G.L., red.
toma; IVANOV, A.N., red. toma; SOKURSKU', Yu.N.,, red. toma; STEI@@.-
LIN) Ya,M., red. tomal PEREVERM, V*Vop red.j PCHELINTSEVA, G.M.,
red.; MAZELI, Ye.I., tekhn. red.
[Transactions of the International Conforence On The Peaceful Uses
of Atomic Energy) Trudy Vtoroy mezbdunazodnoy konferent9ii. po mir-
nomu ispoltzovaniyu atomnoy energii, 2d, Geneva., 1958. Iabrannye
Doklady inos rannykh uchenykh. Moskyap Izd-vo Glav. upravt po ispoll-
zovaniiu atomnoi energ. pri Sovete Mini3trov SSSR. Vol.6. Nuclear
fuel and ractor materials) lAdernoe gorluchee i reaktornye materialy.
Pod obshchei red. A.A.Bochyara i Emellianova V.S. 1959 702 p.
iMIRA 14210)
1. International Conference on The Peaceful Useo of Atomic Energy
2d, Geneva, 1958. 2. Chlen-korrespondent AN SSSR (for Yemel'7anovi.
(Nuclear fuels) (Nuclear reactora-Materials)

STERLI~~,-)I-akov.-11,,Usipl-Q-yich,k-nd.--tekhn. nauk; VOLISKIY, A.N., akademik,
red.; PAIIASENKOVA,Ye.I., red.1 POPOVA, S.M.,, tekhn. red.
(Metallurgy of uranium) Metallurgiia urana. Pod obahchei red.
A.N.Vollskogo. Moskva, Gosatomizdat,, 1962. 43.6 p.
(MIRA 15W
(Uranium--Metallurgy)

1. Y-E. A.
2. u ".R (60o)
4. Relis (Textile Machinery)
7. Methods for coraputim@ norms for rf-.eling atuom@@ts. Tekst.prom. 12 no. 11, 1952.
9. Monthly List -*or t@uqsian_Accecsiont3, Librnry of 6ongTess, February 1953, UncDtssified.

STMILIN Ye.A., kandidat tf3khnichoskikh nauk.
Weavers' work organization. Tekst.prom.16 no.1:10-11 Ja 156.
(Weaving) (MLRA 9:4)

START,-I-.-Yefim :LAW" ggjph; 7A?4AK14OVSKIY, L.I., retsonzent: DOXHMAN. Ya.4.,
retaqnzent; @11 -st', N.M., redgk-tor; DMITRMVA, N.I., takhnicheakiv
redz,ktor
[PrLwAnlea of angineering stanlarlization in 4-extile manufacturing-I
Osrovy tokhnicheskoeo normi.rovantia v takstillnom p-roizvodetvs),
Mos;'"a, Goo. naucliao-tekhn. tzd-vo lit-r7 po legkoi promyshl., 1957.
177 P - (Mllp@ 10-10)
(Textile Industry)

STERLIN. Ye.A.-,--Idots., kand.takhn.nauk
Division of labor on automatic looms, Tekst. prom, 18 no,6:7-8
Je '58, (MIRA 11:7)
(Looms)

OOLUBEV. H.. lawd.toklin.nauk; STOLIN, To., kand.toklin.nauk; FBOXTISTOV,
M.; BRIMIOV, A.; SIMAKIN. V.; KOZLOVA, L., tlatchikha;
NIKOJUVA, X.,- CHIRMY, L.; SLUTSKIN, S.; MINKYXV. I.. Inzh.
Introducing a now organiiation of work; letter to the
editor. Tokist.prom. 19 no.12:18 D '59. (MIRA 13:3)
1. Direktor Novo-Tkatakoy fabriki Glukhovsk-ogo kombinata imeni
V.I.Lenina (for Fooktistov). 2. Zaveduy-iishchiy 1-Y tkatakoy
fabrikoy kombinata "Vozhd' proletariata" (for Brekhov).
3. Nachal'nik tkatakogo, @roizvodstva fRbrIkI im.M.V.Prunze
(for Simkin). 4. Fabrika Im. Frunze (for Koxlova, Nikonova).
5. Zaveduyusbahly normativno-iseledovatellskay laboratoriyoy
po trudu fabriki Im. M.Y.Frunze (for Chartk-ov). 6. Zavedu-
shchiy normativno-iseledovatellskoy laboratoriyoy ramenskogo
kombinata "Krasnoye ZnaWall (for Slutakin).
(weavin,g)
Im

STERLDI, Yefir. Abramovich: POBEDIIIIISKIY, G.V., retsenzent; CHERrKOV, L.Ya..,
retsenzent; WAKHOVSKIY, L.I., spets.red.; KOFELEVICII, Ye.I.,
red.; SHAPENKOVA, T.A., tekbn, red*
[Establishment of production norms in cot-Wn spinning] Tekbnicheskoe
normirovanie v khlopkopriadenii. Moskvat Izd-vo nauchno-tekhn.lit-ry
ILSFSR, 1961. 257 p. (MIRA 14:12)
(Cotton mmnLfacture-Production standards)

,YW! n@A
(Work o:-ganiLnt,,;-; and the establi3r-ment of work n--, fnr
"hose who work at several machine Loo1r, in the textile
industry] Organizatslia i normircvanie truda raiognaLanoch-
nikov v teksl.fPrioi jj:-omy9hIormo;;fJ. 1,.-,d-vo
r.atn inciustriia," 197 (MIRA 19,7)

th@! -,c1(.ntjfjc organIzaTjon of fte work of vomen
A
:;jllnning mvchtne opurators. Tekat. prarr, 25 no.10,1-4 0 '65.
(MIRA 18jlO)
1- Kheroonskly filial Odesskogo tekhnologicheskogo instituta
4@
!,r.@,ni 1'orticnosova,

SIPFIRIIINJ Ya.N.
Role of chronic bacterial carrier states in the pathogenesis of
sporadic ty-phoid fever cases. Zhur. mikrobiol., epid. i im-rim. 40
no. 8:134-137 Ag 163. (MIRA 17:9)
1. Iz Mcskovskogo instituta vaktsin i syvurotok ir,.ent 1-i-ximikova.

POZHARSKIY,, B.G.; STERLINGOVA, T.N.; PETROVA, A.Ye.
Hydrolysis and complex formation of uranyl in mineral acid
solutions. Zhur. neorg. khim. 8 no.7:1594-1611 J1 163.
(MIRA 16:7)
(Uranyl compounds) (Hydrolysis)
(Acidep Inorganic)

YAK(VLEV$ Yu. V. ; S.
Deter.,:dna'lior. of ccritardnations in pure [e-mail] by -7.eans of
rie,.itron activation, using, X-ray s1pectrometry. Nukleon-k% 7 no-3:
141-151 162.
1. ImAitut geokhiraii i. annIlticheskoy khimii AN S33R, Dubria
( for Y.,!(oviev).
2@ T,i --I I @., @ @ y . - nikh i,l,- I r 1 , , -@-, ;.,,,,'"Cil, Varshava, Otdoleniya
analiticheskoy khimli (fcrr Sterlinskilt

67357
AUTHORS: Sosnowski, R,, __ glifiski, 5,j_ POL/45-1,9-6-3//5
TITLE: Isomeric Transition in Hg199
17
PERIODICAL: Acta Physics, Polonica, 1959, Vol 18, Nr 6, PP 573-580 (Poland)
ABSTRACT: It was the aim of the present paper to investi6ate the spectrum
of internal conversion electrons for the isomeric transition
in Hg199 from the i to the f level. This 370-kev
1312 5/2-
transition was investigated under conditions, which permitted
measurement of the ratio X/L and to estimate the S5 contribu-
tion. L.A@Sliv and A,M.Band had estimated the E5 admixture
to 90/0, Preparation of the Hg199 source is briefly described
and shown in figure 1. For measurement of the internal con-
version electron spectra, a magnetic spectrometer with a thick
lens was used. A G-M counter of the BAT-10 type with a mica
window (1-3 mz/cm 2 ) served as detector. The spectrometer had
a resolution of 3.3,01, the counting backL-round did not exceed
7
..' counts/min; the electron absorption in the window was
Card 112 negligibly small. @Ieusuring results are shown in several

199
Isomeric Transition in Hg
"3UC1A-10N:
SUBMITTED:
67351
POL/45-18-6-3/5
diagrams. They show good agreement with those calculated
theoretically for M4 transition in consideration of the finite
nuclear dimensions and nuclear field shielding by the electron
shell. The authors obtained: K:L(11+,'I) - 1:0-57�009):
:(0.12�0.07). The mixture ratio of L14 to E5 is shown in
figure 7. The maximum E5 admixture is found not to exceed 11@$
which is in aereement with what was found by Pound and Wertheim,
The authors finally thank Professor A.__qolt for his advice
jin
during construction of the spectrometer and for his keen
interest. There are 7 figures and 13 references, 4 of which
are Soviet.
Institute of Nuclear Research, Academy of Science,
"i'arsaw
April 25, 1959
Card 2/2

Gamma-spectroscopic ...
P/046 62/007/011./003/005
D256YD300
pulse-height analyzer. The two photoelectric peaks in the ga-an. a
spectrum corresponding to the 605 keV and 797 keV lines of CS134
were used in the analysis; the identification of the lines was in
addition verified by comparing the ratios of the areas under the
1_2
peaks and measuring the rate of decay. The feasibility of the quan-
titative analysis was tested using samples of synthetic NaC1 contain-
ing a knoim amount of CsCl, and the figure 2 :c 10-3 jjpm of Us is
quoted as the lowest amount which could be determined by this method
under given conditiowl of activation and in the absence of any other V
long-lived impurity. It is pointed out that changes of the neutron
flux in the reaction during the process of activation may produce
an appreciable uncertainty of the results. There are 6 figures and
I table.
ASSOCIATION: Instytut Badafi Jqdrowych PAN, Warszawa, Zaklad
Chemii Analitycznej (institute of Nuclear Research,
PAS Warsaw, Department of Analytical Chemistry)
SUBMITTLD: August, 1962
Card 2/2

L 13lia-63 BDS1FdT (m) AFFTC/ASD P/046/63/W8/001/003/00.'b
AUMCR: pterlibskio Srawomir
TIM: Optimal irradiation and messurpent conditions in an activation
analysis. Gamma-SR2atrometrid determination of trace contamination
in the presence of active matrix.
PERIODIML: Nukieonika, V. 8, no. 1, 1963, 57-67
TMM The aim to reduce analytic activities in an activation analysis
leads to a gradual reduction of chemical operations and to optimum utilization
of gum-spectroscopic method. 7his method is limited. by the fact that certain
matrices are activated during the irradiation of the sample. Active matrices
render the application of the gamma-spectroscopic method to direct sample analysis
impossible. In this paper, gunme-spectroscopic determination of trace amounts of
the element in presence of active matrix is considered. Formulae for relative
statistical fluctuation of the number of counts due to the trace amount is offered.
On the basis of these formul e optimal irradiation and measurement conditions are
described. Several graphs illustrating the mathematical problem are included.
Card 1#/ Asaociation; Nuclear Research Institute

OSTERLMSKI, Slawomir
Influence )f the analyzer channel width on t@e shape of the
photopeak of a monoenergetic gamma line. Mukleonika 8 no.10:
709-712 163.
1. Department of Analytical Chemistry, Institut of Nuclear
Research, Warsaw 9.

".. - - , , L'. Lfvopo'-.l i, lovoml r f Sterlinsk'
""um c t v v r., z, e n@ n t 4. r, '-'f i e F, r e e e n c e cL" a n
164.
Ft, I. ',-)kleonA@a 9 no.)-.697-703
Frr..I@ow rinn li r, .6 or
zl lasti-,,,ite of' o I; -;h
-,'c. r
F. rj c zi r-

f. 21932-66
Act-77"z-, 1-uUih464 SOURCE CODE: W/0046/65/010/011/0641/06591
AUTHOR: Sterlinski, Slawomir
ORG; Analytical Chemistry Department. Institute of Nucl2,~E_fipqgArq-bj_yarsaw-Zerant-
TITLE: Method *@Qr simultaneous counting of source nd background for short-lived
radioisotows near the determination limit
SOURCE: Nukleanika, v. 10, no. 11, 1965, 641-659
TOPIC TAGS: scintillation spectrometer, radioisotope
ABSTRACT: The problem of simultaneously counting source and background radiations
when determining trace amounts of short-lived radioisotopes by gamma scintillation
spectrometry is discussed. In the case of time-consuning measurements (of the
ordcr of hours) the evaluation of the background on the basis of its counting in
another time interval may prove to be false. because of daily fluctuations. The
error due-to this may be in many cases eliminated by estimating background under a
given photoelectric peak on the basis of the number of counts measured within
another energy range of the spectrum. A method of estimating background within
a measuring range is presented, the variance of the estimation is calculated,
and a condition is pointed out under which the optimum (the minimum) relative
accuracy is attained. The author thanks Mrs. Marecka and Mr. Kowalski for car ng
out numerical calculations. Orig. art. fia's: 7 figures and 31 form as* LNA1
SUB CODE: 18 / SUBM DATE: 2lJun65 / ORIG REF: 004 / OTH REF: 015
SOV REF: 003
Card 1/1

... minsvry, in.:,titillue of "'.-c"Car ac;--Cztrc*. ar=,l
ioiLoto @)apor rrcsontod
!;:ilz oz: Ceti--c-zlon Afor 5*.,'io- -liv- rn-'
'An tlemical A:.Z.Ay A
-c-,,@czvnco on A
20 .,,:o April 1906]
-.'.dconika, v. 11, no. 6, 1936, 441-1,53
car, c
ioactivity v, u r c il,'
0@ t`o 1110"nar 111-11: o,- dr-.,:oc!-;On,, @70-- sho-t-!-vm@cl
and t'lo- so-callocl 0@ t'.-.c.- r:a,.:C;Ctor
thar tl@,c limait Of C:O;;bct:ioi z-cac!-.c:; a for 1:'--,
is Zulf Of ti-'a 111c,","ar llmiz
ci ca-a bc calc-ullatcd zlccord-.r.@; Zo L::,Ic lach:00d Zor.-7,ulas.
by
3.75 min).
(de-
ilizy-cA.: on
D:.,. .'Z. fo:: (11--cu:.sions, on
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in, and calculation:;.

and 2 tzialcz.
v Rzr. C)OI 014
14jan66 003

SOURCE CODE: i,0/0046/66/011/07-*/0533/0553
7
n- Slawo-mirl; Byhezynski, taj-mund--D)rbch1n_qki R.
Dep@'ru'-Ionl: of Annlytical Chemistry, Institute of Nuclear Research,
TIT!.:@: DQtenilnation of cesima traces In mineral salts by means of
nouti-on activation-lon exchange chromatography method
SOUPOL: Null-leonika, v. 11, no. 7-8, 1966, 533-553
701,1C TAGS: cesim, neutron activation analysis, Ion exchinge chromatography@
irloimcr, chromatographic analysis, alkali metal, trace analysis
SUB COD-Z; 07,18
jV,Z"TjVX7: A neutron activation-chromatographic nothod for the deternim-Ition
of traces of cc.-;Iun that nalces use of the short-lived isomer 134nCs is presented.
Cesiu-1 was isolated from macro amounts (0.5 - sample) of lighter allcall metals
on tlie colu;tui with IM-3 cation exchnnget