SCIENTIFIC ABSTRACT STETSENKO, A.I. - STETSENKO. N.D.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001653310015-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 3, 2016
• Document Release Date: August 26, 2000
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

26873
S/081/61/000/013/006/028
B105/B201
AUTHORSs Stetsenko A. I., Tverdovskiy I. P.
TITLE: Overvoltage of hydrogen formation on disperse Pd - Pt and
Pd - Rh alloys
PERIODICALt Referativnyy zhurnal. Khimiyal no. 13, 1961, 87, abstract
136663Xb. tr. Gos. in-ta prikl. khimii, 1960. vYP- 46,
221-22
TEXT: With the aid of a previously described method (RZhKhim, 1960, No.
15, 60716; 60717) it was shown that, unlike what is the case with Pt, the
overvoltage of hydrogen formation on disperse Pd depends largely on the
pH value. For the Pd electrode, the transition of 1 n H 2so4 to 2 n NaOR
is accompanied by an increase of the absolute value of and by an increaLej,,
of the coefficient b of Tafel's equation from 0.020 to Z-152 v.
Dissolution of Pt or Rh in Pd results in a rapid decrease of the value of
in alkaline solutions. An addition of 25% of Pt to Pd lowers /I to values
O%tained on pure Pt. For Pd - Rh alloys, @ is rendered independent of the
composition by adding @40A of Rh. It was shown that the change of q and
Card 1/2

26,573
S/081/61/000/013/006/028
Overvoltage of hydrogen formation on ... B105/B201
of the solubility of hydrogen are qualitatively similar functions of the
composition of the systems investigated (Stetsenko A. I., Tverdovskiy 1.
P. "Zh. fiz. khim.", 1951 1 26, 647; "Dokl. Ali SSSRII, 1952, PA, 997).
Various assumptions were made concerning the possible causes of the
decrease of:i as a function -1 of the composition of the alloy. [Abstracter,;i
notej Complete translation.
Card 2/2

GiLI i DAL, A. A. ; -A : ".' ) - ." , .". - I- -
"o-1), IGI-,.
j.
L -@ ! * i.." i ! t,.*%:"j LIC-1, l.; of [P., ('A,) ("r -
I . 1 .1. :10.1;111-119 Iclol: It"U. 'A ': /.,; - i
zlluf. Itnor . ':' 1 ..
(?-. .tt -.V:.l zc;-.."CjA-.-

sq'rmr@lr), i'@.I, A
Method f@ir preparing Alexander base [Pt0IH20'Q4j(OF)2 and LosEen
01oride [ROOF20041012. Zhur.neorr.k@ir. 6 no.8:1769-*1770
Af-I 10 . (MIRA 14:8)
(Platinum compounds)

GRIMMG, A.A., akademikj,STETSERN09 A.I.; INIKOVA9 Ye.N.
Acidic properties of cis- and traw-isomers of [Pt( lh) (IM3)21 C12.
Dok:L, All SSM 136 no,41821-823 F 061a 12 14: 1)
1, leningradakiy tekbnologicheskiy institat imeni Lenoovetae
02atim- compounds)

GRINBERG, A.A.; STETSENKO, A.I.
Acidic properties of cis- and trans-isomers of [Pt(NH20H) (PYWC12-
Zhur.neorg.khim. 7 no.12s2678-2684 D 162. (MIRA K12)
(Platinum compounds) (Isomerization)

ia648-61 SD JD/HW-2
ACCESSION M: AMOOZ599 S10060/63/036/005/1040/1045
THOR: Tvardovaklys I# Pq Vert$ Zh. Le; MarpoTal R. A.; Mosevich, I#_A* and
tetaen3mp Ao I*
f
PITIE: glectrochazical. extraction of dispersed binary aUOY@ of palladium-with
vetals of groups 8 and ID
f
j SOURCE: Zhurnal prikladnoy kbimllp ve 360 noo 5, 1953, 1040-1043
:TOPIC TAGS% palladiumv binary alloy# Ptp Rht Aug Nip Cu# Co. Pe
ABSTHACT: In examining the phyaico-chemioal and catalj&lo properties of panadium-!
base binary alloysi eleotrolytio methods ,of extractiouldr mixed dispersed predipi-
@tations of systems Pd-Ptj jd_Rh' U used@ Abnormal results were obtained
only for the system Pd-Ki ;en%vnt;7uczion of niok3l in pallad!um at @0-35%
was not accompanied by a change in lattice oonstanto In the zone of richer neckel
the sizes of she elementary oell of dispersed alloys ooinaided approximately with
parameters of the 6ompaot forms nooording to data of Mltg.*en and Zapfe (Tranne
A*,TXo3* 133, 1939v5B)o Use of soluti on @j bas4ld6f nitri" group of pall"
olp d
Pd-N
dium permitted extracting alloys Pd-Mvv_
I -Go, d Pd-E!@*,% only by joint
:V
electrolysis, but also by, chemioal precipitation by-re'ana of-reduetion of metal
ions by formate or sodium hypophosphite, hydrazine salts, etc* Orige art* has:
Card Associationt St; Instj of Applied Chemistz7

Lens
L :T

STZT-S 0, A.K., inzhener; DANILOY, V.I., inzhener.
Dry nitrogen used for protection of machines and instruments.
Vest.mqsh. 37 no.6:32-33 Je 157. (KLU 10:7)
(Frotective atmospheres) Olitrogen)

@N lu A.M.; 1,111LOV,
Scale forration dur-rig t-@- heaLing Of wiroe2r, n heat treatirIg
ring furnaces. rzv,,rf5.u-@!-.eb.zav.; chern.met. 3 no.6:159-162
165.
-1
I. Dnepropet-ovskiy -,@'.uliurgicheskiy inotitut.

UYAGINTSEN, A.F.; IVANOV, Yu.N.; KA7AKOV, V.E.; STETSENK0, A.M.;
SOLOMVICH, M.Ya.; KORZ11, V.1.; DASIHEVICH, A.A.; Prinimali
uchastiye: LIPTSENO S.Kh.; RY7HIKOVv A.P.; STALINCITITSM,
V.N.; U-SMETS, L.Ye.; MOGILA, V.A.; KOVAL', A.A.; VLASOV, V.F.;
ROSHCHIN., A.G.; PLAYKO, V.P.; KOPNIYENKO, V.G.; PANTYUSHKIN, N.V.
Investigating the possibility of
electric locomotive wheels with
proizv. 5 no.11:11-14 11 163.
manufacturing all-rolled
existing equipment. Kuz.-shtam.
(MIW.. 17: 1)

L 43852-65 D1T(M)/D1P(t)/D1P(b) Pad IJKC) JD/W'
ACUF5,91ON Nit: AP4048779 S/0126/64/0111/004/0632/0634
AUTHOR: 'Palatnik. L. S.; Ravlik, A. G.; Stetaenko, A. N.
TITLE: On phase composition ofxacuum condensates of cobalt
SOURCE: Fizika metallov i metallcrvedeniye v. 18, no. 4, 1964, 632- 634
TOPIC TAGS: phase composition, cobalt, vacuum cobalt deposition, alpha coba
beta cobalt, polymorphic cobalt modification
ABSTRACT: The authors have experimentally investigated the influence of tem-
perature and the nature of the substrate on the phase composition of vacuum
deposited cobalt. The substrates (carbon film, condensate of NaCl, or glass)
had a measured temperature gradient. The composition of the films was analyz-
ed with the x-ray diffraction method. At was found that of lower temperatures
(in the 20 to 200 C range) the bt Co is formed (hexagonal closely packed lattice),
and at higher temperatures (206 to 450 C)- the o(Co is lormed (cubic face center-
ed lattice). It is possible thatXphase which is formed at lower temperatures is
I_cardl/2

L 4.3852-65
ACCESSION NR: AP4048779
transformed intooc-phase through the action of dislocation centers.. This trans-
formation is impeded at higher temperatures. Orig. art. has: 1 figure and I
table.
ASSOCIATION: Kharlkovskiy politekhnicheskiy inatttut im. V. 1. Lenina Kharl-
kov Polytechnic Institute)
GUBMITTED: 02Aug63 ENCL: 00 Sun CODE: MM ss
NR REF SOV: 006 OTHER: 007
.card-,

STE-TS.ElO.U. A. V.
Dissertation: "Cyanine Dyes Containing L.,luinone Nuclei. 0 Cand Chem Sci, Kiev State
U, Kiev, 1953
W-30928
SO: Referativnyy Zhumal, Nol 5, Dec 1953, Moscow, AN USSR (N-91,RPg)

... . ......
d'6., V. stelsmko, U4 Ato.
Us b.H
qksit=*J2,3-dJthiAwlc (11) wtre syntlittLifil III urdef to
t,t;tainitlyeroti(i.aqiiii,.oitefcsiducinit%iTial. Igaid1larn
Al
Rt
(IIIA)

mud P-toh.Z-tcj. U.EtCl (Ul) wu synthesized
as a;r similar salts of bcuzthUzok. BOilin9Mi=uk--cO"-
verted It into a methylcvc base. From 111 were obtahzed
the following 111a (R given): A (s 0. R' - mci, (IV), H
1. R' - H) (V), B (m - 1, R' Me) (VI), A (x - 1,
R, - FO WI), 2-11-mthyl-2
(61.HYqulnolyIldtn-JttbyIl-
dene (VIII), (x - 2, R' - 11 ( ), jp-hfC.NCH,CJ1:
11I)i lleptamethinec7autnt could not be isolated. The
% city of V was .1.32 moks/I., while the baskity of diethyl-
WbocyAninc was 2.64 molts/l. (The haskity Is rel erred to
Aa the cuticn. of IICI fit a mixt. of 15 mi. ale. mid 10 ml. 11,0
required to reduce by hatf the color of the dye dissolved in
this mixt.) All the vaplithoquinonothiz-zoles absorb at
longer wavelength.4 than the derivs. of naphtho[2,3.dlthia-
zolc, except VLI, in which a hypsochrome shift of 6.5
mp is caused by a differmce iA the baskIty of the bctero-
cyrlcs. A still greater difference In the basicity of hetero-
CYL!eJ and consequently a greater hypsochrome shift is'
found In VELI In which can it is 18 rus. Namflon of di-
Mabyl ether of hydroquimme in glacial AcOH yielded the
mono-1-1.11; deriv. MD. m. 71*. X1 was reduced by SnClj
.W" IICI to aminodimrthythydroquinane (XU). m. 81*.

j
Orr
-T"s
'Its Ac deriv.. m. 91'. was fused on a water bath with Pjh..
leached with an 8% MOII sol * C(h td N 11140mill
pnx
ineth Y14,741metlimybemothinob M. 101 . Boil.
;lug XJV In Q5!jHs1SO,, sapood. the MadmIr r
0@
2-aAA1tyl4,7 gro
dibenithlasole (XV). as.
(6. g.1 dissoircil I in]. of 63% HoW, and to it added
drogwIse 2.6 a. XsCrgh In IOD mi. HtO, gave 60% 1. m..
IAO . Sulfonatlon at 801 converted at-naphthol'Into "a-,
maphtholsulfoulc acid" from which by the action of HCI and
KCIO, was obtained 2"ichloro-1.4-naphthoquincate (XVI).'
m. I.W. To XVI dWolved In ale. was dropwise added
concd. NHoOH. Bening for I hr. produced 2-chlcro4l-
arnino
-1.4-caphthocininone (XVII), M. 190'. XVU (I a.)
dimulytil In 18 ml-ofatc., toltadded 1.15S. MarS InOwl.91,
LIG, the inixt. boiled tojr 3U mtn filtered and the MM.
boiled in 6 mi. of AcxO Yielded , M. 190 . fill
Mab wpa-silso
produced from the Ac deriv. of m.2196,*4Mvso1v6W
@I g..of,the substance In 80 ml. of We.. adding 40AS 4. -of
a -1 d. NatS.. @bolllnqi 4 hn. dift. 09 Aid. Of ak..
d1ij*j, the Midue with H80 iltegz
1. yJag with dfl.
P ,and xe=jr d U Add* Frof a 33% &k.
,win. of St ;AZ of 6 a. 1W is, 20 mi. J...
tN . to OL
gild cooling Ia M4,0%-Wbd 100% 24dorb-34thyll-,
iamino-1,4-asphthotitsinods (XM), w. 116*. IMI was
transformed into 1Uby2 methods: (a 1.114XV1111ol-S
g. NasS and 12 ml. of H%O was boUe2 for win., 20 mi.
C.11. V&d. the mist. "Wed with AcOH, shabo, the
CIIIlayer sepd.. dried over NsM.*W treated with Ia. al
AcCl In 5 mt, CjH4 to ykM III, m. 2481 (decompo.
IJ (4M
A #--

ST,@ r.y"r-Aj)(6
and A. vimill. Mine.
USSR Bar.- IV, Jki*. 1954, NO.
(1)@ I.Mecl
M, mW lXd Ma) wen s"thesixed: H and UA Wmedsed
to metbylem bases (M). I is a weak base. but strvngu
than 2-weth]d u1notiothhumle and 2-meth 0..
!
labtalne.4 the cHowing a (R and X A
2q1-methyl-2(1H)-quludrlld V.-).
g ; 3
11n;th CM. I (V
yl-2-4cozothLuollarlidenc. I 0-meoNcal
(Vn); P-bfeoNCJf4N:. I Then ON
*#N
(A)

.lwiw " ve lQgths thAn do the dyes derived from anthra.
thiftinle. 'Me 9-ster ba%i6ty of I as compared with 0-
mcthv-luaphLhoqWnonothiz.zolc is confirmed also by a com.
p2rLum of the hypsochromic shift of V (2.5 mo) with that
cbarurtt@ristic of dyet having naptithoquinouothiazole and
quitioline nuclei in th-t mot. (18 MLO). From 3-Chloroanthm.
qaiaone And 21% NH3 kept 4 firs. in an autoclave at 21&
was obtained 2@xmi%wmLnthMqUivmnr (W. in. 301, (d,
Votmbtaov and ShItitin. C.A. 32, 53W). IX was acetylated
by the action of AtjO aud chlorinated (junglians, C.A. 7
.3743).
thas obWued. was sapond. with STo KOH. t%crtbv pro-
ducing I-chloro-3-krninamuthraquinme (X), m. =1. X
.(3 g.) distiolved iu 41c. and, bmkd for I hr. with 4 z. Na.S
and I C. S in 4 ml- HjO produced 100% Na salt of I-mer-
capto4-.aWummthraquiuon2 (XI). ]a (3 C.) and U tal.
Ar.0 builed for,2 hrs- produced 35% 1, ta-2-W'. I(O.76g.)
and 0.8 S. Mr2SO& heated 30 min. at Ifin-56. th@., product
Waslied with C.H. and ether and dimAvtd in 14*0. the solo.
treated with C and fil'tered. KCI udded to the flitratt. pro-
duced 53% 11. m. =*. Ila m. =* (decompri.). 110.0.6
C.). 0.3 C. NaOH in 5 mi. HrO, and.10 mi. Me'CO, sh2ket; 10
min.. filtered, and the filtrate dild - with HzO guvt 94c" IU,
m. 173*, Mating M with dil. IlCJ produced 11. IfIO33
g.). 0.33 C. orthoformic caero and 2 ral-ActO boiled 45 min.
gave 79% IV. M. 34"* 1%d-ompia-L 10--. 64f) toji (in
.AcOH). U (0.33@g.). 0.43 C. 2-w-acetaidlidaricylquino-
Line-Mel and 0 '3 Z. anhyd. NaO.Ac. heated 15 min. with 2
mi. AcjO at l0q* care 90% V. m. 233-4 * (decompa.). ".
(12D tax (in ak.). 11 (D-56 C.). 0.62 g. 2-tuetljylmcrr&pto-
beimxhizzole-Mc.SO.. 0.32 z - atilt yd. Na art-tate. and ft mi.
r.b;. sk. L"icd i hr. Irive 1-IC/0 W, M. 1103" X- 490 MA
(in :,Ic.). U (0.33 g.) and 0-15 K. jo-Mc.14C.H.C.110 tri
Ac,O, swd replacement of Cl by iodine with KI gave lh&'
VII, m. 2A* Wccomtxn@). )-. &.45 ins. (in Av.j. 13 i;.31
jr.). 0,15 a. p-Mc.NCJl.NO, and 2 nil. abs. u1c. boiled 50
ruin. gave 43% VM. M. 196* (devomp.), N_ QO n." (in
M. Mrch-)

t
o1`j7@e1h-Yleri_eUi_W6(1 R-WTW'ji-h-'-Co@ -rm-rff;G,-O iirra
nd A. V. Steten o ev, g. Lyer treat-d with 0.21 W, p-henznquinnIne In CJ14 A
'I liazzil
zhur. C c K0717-23-17MMIXI s ken I hr. gare 14!70 2-(J.lne1hjd-J1-bt4ro1A in ylide ne-
J. C.f
@"' '-- 17-1,4: Vimin. Khi,". Zhur. 19, violet, tn. 237* (from CIICW. ah-
X,, 'd '-.;ti ; which are inner-ionic dyes of the; sorption nil%. W trip [it Cl IC4. W-10 In WIN let. silllillrl@
-,ol-i fiilo, were obtained by the reiction of qui-' 1,4-naphthoquinorte gave F.R.3% I-
.' 0 @: Waes of X heterocyclm The ab- violet, decolnu. LW
,;f ;ill the5c dyei nre not
n sharp and thelfrom C1114), absorption rrax.610in EtOll, 615 in CHOI.
I ow -re nithur broad. The max. shift to-- 570tripinEtOMIC1. 'rhisindil.110treatedwilli NXIO,
1. 1 Ilb- '-I- when the solvent h changtd toonelgave a red Pefirklerafe 165%), m. 2300, that i.-1 ralli'lly
rollitant. The prol,111cu form mlts. @ Irolyzed by 11-0 ot aq. MOIL Th mi on
I'llt of JlC1 to luch a 3n1n. shifti; the abi. max.'formsadivzij#j*(33%), m. 73* (from dil. &31131.
The dyei are readily reduced to'none deriv. heated in F'tOH withSti0jrnd tICl pvc Sjl'iv'
,0-faricm, fornting corresponding derivs. of
lgmef.kyl) -
lidsid, linve the propertlej of vat dyci, since @ droquinasie, colorlesi, m. 107' (fro dil. HLOII), which with'
!-)p "n expO411re to MIT, Chlorination of: ActO gave the di-Ac de,iv.. m. 1419 (from dil, EtOll). the:
hi AcOll gave i reduction can be made also with MatS04. rhe, hydrnqui-@
@7'1', red needim I-Naphthasulfortic acid'none deriv. with hwo, in NA011 gain. save the 'U.Ard
-4 '@ @' I; @'
C10, III'l lfCl gave 2.3-dich1oro-j,4-Fts#41ho- elker, y-ellowr m. 64* (from EtOll). Treatment, aq ribove.
v. Ill. 1W. 2-MethVilientnthLazole, of 2-methylbetizoth4vi't methyl mciluutd(litt- with It
I !!F It- (0.2)7 g;) in 2 ml. 11.0 treated with 0.21
M.

;vt 4) jl- (frogrit C.1 1. mai. IlDin Irto.1171W 16 CTICL, 01,
(3 - pmr1hyl - beas(vh;ased;n -inak
yUde es i
u
A1
;
rhjort@1,4
ftaphlh@juinc
nc, blue, in. 194 (fruin C
4),
-
lm
w
6
0 l
H
M
(M
i
CHC
hl UYIRHLOII-HCL-
-i
43
l-
11-meth
t-fil
ulf-
vi, 811
blue 4
-(
etr
'O
i
t
ti
in inux.
irl.
,
it
I
itralo
mij
n
h: perc
,
,
.% ellusv, ill - 233 4 ' (I'min alic EtOJI ). Similarly the re", i
.
m
ull
e alict
in
uF
,
2
l)
e v
a
y
Om Save 32% 4+I.mrlhy14- 172', at--oarptluti ulug. 00 Ili 1.1011, file) ill CIICI.. W) mp
lwn,, Itione, blue, Ili. In VtOTI.-HU metlivi
Or-urptluti tnux. 640 lit Mfi. 112(i in CHU., 430 till& lit inctimulfate und 1.4 4w lixt'll till vul iv vtk%v vit'let
T('H-J:L I. 'I lit rtactimi with I v1suilarly guve 231,1, 4 $.

@
'
i imiyar, deemilp. 209', vh?i9rpt1un ItIlO.Y. Ujo wilpi In clicl,
vl
1
1

11m
t,om tit. IN
(frnm CHICII),11 Itt I
ql In 0 1.
A@)Isiopj)t Im inax. U.
-1
f1f, Itik, ill ('1101, 420 Ill Etol Sinilarly 2-inctiv% - t use of KA1g- 44
, little 11-0-
It
@
-6,7 -it: vNitylidt it, nicithyl) - 1,4 - iml-n-
invitkyl , - Lett. -hi vdiu.
4.7 Ill jjy tit k@tjjj I ill int- glive 501 'Yg blue J-(.V.me1ky1.4- ' nbsurption 111111,040 Ill Pit 011, 0:40 Ill C I I -
iflapimpmr.m.21il'

V torWhIlVidinyiiiii tit till .2-P ;1-4,7 - brnwilk ill 3olisili-
Asyl) lldh
C 6 "19, 1 1 list ill I'Mil .1 icl. QaNkLiffive I twl I ly I muill'if I, if I%'. c
I
'
now, tit. 4H -5' (Irmu LoW, ithliorpliantnax.11180niplit CIA- , bl,,. 34 1 -sm 'k W-" -qu iftl4jti-
uad 17 r,
U,. @;Imilw rmct im, W ctida-
"O.4hy' 041111110i'lclW6.
i
A
lit: pipisait. red, tit. v
(
rt
-
pi:ulk visn - !@10 mp fit Cl ](As. 2-?wIctlq-j.4Wj. M Ili 1, t lit. o ill In CI C
jam, . tit. 17W, att@tqj,Limj imtv, A
methlOdidC HIM J,4-n1%jJl1tIl(KI1fI- URI 11111 tit I'tDINICI; rcil, 2tr'
'V" 1:-1 wev" U43 mt tkyl-d-divir1hyla in inn- Ornill l"1011). ki. N1, l."'oklull
sit, 210'
NMI--- mw

USHKNKO, I.K.; STETSZNKO, A.V.; RUBTSOVA,'Te.N.
Investigations in the chemistry of,cyanine dyes. Part 8. 3,3'-
diaryl-6.7.6'.7'.-dibenzothiacyanines. Ulcr.khim.zhnr. 20 no.5:
530-534 154. (KLRA 8:1)
.0
1. Inatitut organichookoy khImil Almdem'A nauk USSR.
(Thiacyanines)

r
tl@_!:
Wide!
':rthy
2 bew
Man),
10
3-meti
25 1 ::
2fa
CaNCf[,Clf:
Varn the Wmark WK
d H, U*
'A' 1. KiPT ;!t tot==
raim. Kkim.
in
(C
Cl
31.
all
Z74RA 1!11 , ).CIL:R
in Tax given
'i,
pti;i=ylk (1), 3-cilly -
m"Wylldcat 11), 0, 273", 440; 1, I-ethy -
3olylklme (1111), 0, -, 445' 1, 3-ttljyWnetbyM
lAbi3thlasulinylidene (IV). j ')61* W-
1-benzoXasolinylidem, 1, 2LO': 0. 1. V.
; .I. 3-ethyl-2-njaphtho la2ollnylldene,
LH, 1, 204-, OW; 213*, 680, 1.
(V), 0. 234% W; 3-ethyl-0-inethyl-S.,
(VI), 3-16fe analog of 11, 0,
;W_4 . C12; V1- Us-
thiaziAhtylidene (VU), I (VIII), 2701, rj7d; V1. vil, z,
'145', 670, VI. VU. 3, 212'. 794; V1, 3-ethyl-r@Vbcnyl-2-
benzothis"nNnyWcue, 1. VG', 582;. V1, 3-ctt-yl-&jS-uapb-
thyl-2-bcuit,tlLLt"nylklcnc, 1, 25d . Mi. 11, 3-tchyl-12-
tLaftiffi(I-1.1 jonuilinylidene' 1 273* &14, V1 11. 1, 27330,
570,
V11 In. 1.' 2110', 5M; VI, V, 0,' 2155', 540. V111 inuthylAitcA
Lu the mittal snethine poup gave a 41mulul., m. 2871, X'
5.59 itip.; Et analog, in. 207 , X FM mo. 3.7-131ethyl-2k
b1s(2 -p - (IlinctliyL-tatinophenylyinyl)beurA) I 1,2AMbistbW
zolium diiWitte OX), Im. AW, X 612 S"'O. TILC bCn2OjI,2,-
4,5)b61h1,j sole (X) dcrivs. have 15-10 ukq ITruter than the
Ismeric benzuj1,2,5,4JlAstldazvk derivs.; the latter, how-
ever, are obtAlned u3w]ly in bLtter yk!hW. lsoum.4 of IX

or of the centrally alkylated derivs. W Nla were not ub-
taiatil In the X series. "-?btcthy)4acetAu~dob4rnzothL-tiole
and PA at 1.30-V In Ph,%Ie fonn the thkincilaruldo miipq..
in. 2ON', which with K,Fe(CN), In alk. aq. F tOll sobi. yicldg
2,fl-ititiiethylbenzo[1,2.441bisth6zole (XI), in. 121*. XI
and p-?.fcC4II.Wt form a toono-Et deriv. in 3 Urs. at 130'
nod a di-Et deriv. (isDUted as the Iodide. tv. Vg') on beat-
ingl3hrs.;Ltl3Wandlhr.atl5O*. "ADimetItylbeazo-
11.2,5,41biithiazole tatthiodide. to. 23W; ethiodide. in.
2384. 2,f;-L)itnethylf)entoll,2,5,41bisthiazi)le Et p-toluenc-
sulfqnate and PhN:CHNHI,h in ClHIN forin RCII.--
CII,NfIPhJlOvSCsll,Ntc-p (R - 1). in. 259". Cyanhic dyes.
from the i3omeric pyridothluolov. S. G. Pidnian and A. L
KiriAnov. Ibid. 767-7t.-The followirtg R'(CII:CH),
C, are reported (R', R", N. x. X, in.p,, and A in
nio fivcn): 1,4-dicmthyl-2-thiaiolu[5,44olpyridyI (XII),
1,4-dunctftyl-2(ill)-thLtxuloi5,4-61piridyi~tene. 1, T. 1-1
286'. 570; XU, V. 0. 2. 004 MS; 3,&-ditutthyl-2-
111,0), 419 (423 in ale.); XLU, 3@Witucthyl-2(31f)-thLazolo.
4,541pyridylidenc (MY), 1. S. V, ZM* (2 11#0), &12;
1

7

XM. V, 0. 1. 11 -, 220,-3* 2 140), 5"Aln Ilk.] I 54ce"m 0- ,
3-tatthyl-2-tJ
yl, 644etamido,3-methyl-2-
b PYM
Bf
Vai- I
ridy"(M), &uetaxnidZ,4-dimethWK3H)-,hl-- tc-%
"ylideat, J, C104 -, 270% W2 (M5 III
alc

:,cJOJ-,iA4.,mq. Th4ccutrWJ @
k
yctby!&tediV
m. 2S" , X 570 In mic. R'CH: CHCMe: C 9
R11
=3*
Xul
h
xtV
X 00
2
1f OUR"
4
hb
6
1
-
-
.
et
,
,
:
,
idi
l
bl
lt
tkA -
LZO
1-
t
01
4% Th
M
-
d-to
ne
uumsu
mate, tn.
i(e
e
pyr
!
nwuoctbyl P-tolutuesullocate of It1d*soWj4,fkj-
dLue. mt. 137% don nat give a dye and so the
yri
r
3t i presuiaNy on the pytidlut and not The thlagoI4 N
L
morn. ne bis(Me inetho"Ate HtO, m. 72-3% - It
-2
1
541,
d
fo
i
A
t
id
4
tb
6
t
i
ltbb
l
(4
-
-
ye-
ng..
rm
ce
wn
o
mt
tzo
o
r
~
y
.
,
3yridinium hLi(methosulfate), cu. 1724% 6-Acctamid,,
@
-nltrbeuzene-sulfo_
nate, m. 236411. yanino d 4 611 the "*th*dWtI&z*Is-
V
-series. A. V. Stetseuko and
1. l#anovit (T. G.. Shcv-
l
i
d. 772-b.--The followin
chen
ro Sute Unly.0 Kiev). [b
R'(Cli.CH).CH:R" Iodides- are reported W. It'
-illmethyl-2-naphthol 1.2
m.
, "Ok in ruo plyca).
p 3.7 g
bl, ti,
,
14iotyl (XVU). Me. analog of U, 0 330-40', 44
XVIT
L
-ditrietliyl-2-nalitilholl.2.ri,oibisih
zoiin)riwe", j,!
A7
247'. OW; XVII 11, 1 2101. M; XM, Me analog of 11.:
54r
2(9
1
XVH
,
,
;
1810' tm- xvu
241-2
&M
C
If
1
0
1
V
&:A
NIQ
.
c
,
j
m
c.
1
,
,
,
,
M'
1494
uua PA lottli the thiotwetusuklo cotalml
3n
M
.
.,
.,
,
,
convertct, bY
(KiF CN)t In Wk. mola. to 2.7-dhijettill-
th
272* (
l
6 t
l
d
tbl
M
270
2
ll
i
o
au
me
a
i
c, in.
e, m.
nap
.
,
,
Julio 11uwc *(AL-,

STETS'TO, A.V.-, IVANOU. V.I.
=Wftt
Cyanlnm dyes of the nanhthodithissole series, UkrAhlm.zhur. 22
rv@.6:772-775 '56. (KLRA 10:?)
1. Kiyevskly gosudm?stvennyy univerattet im, T.G. Shevehenkc,
knfedra organ5chookoy khtinit.
(Cyanino dyes)

8MS=KO. Alsksey Vasillyevich L@tetsenko, O.V.j.k9nd.khim.nauk; POCHINKO,
kand.khim.nouk, red.; TIPLTAKOVA, A.S.
[Tepliskova, A.S.], red.
LHigh molecular weight compounds and their importance for the
national economy] Vysokomolskalierni spoluky ta Uch snachennia
dlia narodnoho hospodarstva. KYiv. 1958. 30 P. (Tovarystvo dlia
poshyrennia politychnykh I. naukovykh xnan' UR.9R. Ser.4, no.11)
(Gums and resins, Synthetic) (Polymers) (MIRA 12:2)

-MI-XHNUVSXATA. N.D.; RDTMISTRDV, M.N., doktor biologichookikh nauk;
STITSINKD. A.V., kand. khtm. nauk; XULIX, G.V.
Studying the fungicidal properties of chlorine derivatives of
salicylanilide and carvacrol. Dokl. aked. sellkhoz. 23 no-9:35-38
158, (mm 11:10)
1*Xlyevskly gosudarstvennyy universitst Imeni T.G. Shevchenke. j
Predstavlena akademikom S.N. Muromtoevym
(Fungicides) (Salicylanilioe3 (Carvacrol)

YlJRBATOVA, A.D.
Cyanine dyes of 2-math7lacenaphthothiazole. Ukr. kh1m. zhur,
24 no.3.-354-357 158. (MIRA 11:9)
l.Kiyevskiy gosudaretvennyyuniversitet im. T.G. Shavehanko, kafedra
organicheako.r khimii.
(Dyes and d7eing) (Ilaphthothiazole)

ROTMISTROV, 11.11. [Rotmistrov, H.M.] ; STETSTIMO, A.V. [Stetsenko. U-V-1; KMIK, G.V.
CKI,lyk. H.V.]; VASILEVSKAYA. I.A. [Vasylevs1ka, 1.0.]; KHARCHMKO. S.N.
EXhurchenko, S-14.1
Study of now synthetic antimicrobial substances. Mikrobiol.
zhur. 21 no.3:31-35 '59. (MIBA 12:10)
1. Z kufedri mikrobiologii Kiivslkogo derzhavnogo universitatu.
(SALICYLIC ACID rel cpda)
(ANTIBIOTICS chem)

S/073/60/026/ooi/014/021
B004/BO54
AUTHORSt Stetsenko, A. V. and Bogodist, Yu I-
11-ft ------------- w----
TITLE: Cyanine Dyes From 2-Methyl--4,5,7-trichlorobenzimidazole
PERIODICAL; Ukrainskiy khtmichesk"y zhurnal, 1960, Vol@ 26, No,. 1
pp 92-95
TEXT: The authors report on the synthes13 of imido carbocyanines con-
taining three chlorine atoms on the benzimidazole radical They proceeded
from 2-methyl-4,5,7-trichlorobenzimldazole.. The latter was converted to
the quaternary salts of 1,2-dimethyl-4,5,7-b,?nzimidazole by means of
dialkyl sulfates or halogen alkyls From these salts, six dyes cf th,@
Cl 2H3
general structure It", w.=-- unthesizal. Th,@ authcr3
+- C-CH-CH-Z
Cl V/
@1 6H3
determined the absorption maxima, and calculated the hypsoch-.0mic- sh-'ft
according to A, 1, Ki-prianov. The latter is def4ned a-= the difference
Card 1/4

Cyanine Dye3 Fr= 2-'4e-hy--,-4,5 7-trichloro- S/073/60/026/001/0@4/02!
benzimidazole B004/BO54
between the arithmetical mean of the absorption maxima of thtl two sym-
metrical dyes synthesized from the same heterocy-,les, and the absorption
maximumof the asymmetri., dye. Table 7. gives thpse data
Dye Z. : m hyp9cchr-cm- sh1fr
AM a It m
r. H C I
3
I CH@C,, 520
L
C1
II CH=C 480
H
S
III CH=C
H
2 5
Card 214

Cyanine Dyes From 2-,Mp-thy1-4,5,7-trich1Drc- S/07 "60/C 2 6/00 1 /04
benzimidazole B004@BO5't
Dye Z. aX, M@A hyp r, n, c h ro m 41 c s hll
Am M
IV C11=C 536 22.5
)9
t2H5
V CH= r
N)O
62 H5
557
5--5
VI IT(CH 3)2
Further, the authors determined
imido carbocyanines with 2, 4,
435
the absorption riaxima ok the symm.=trical-
and 6 chlorine alsms. Table 2 indicates,
Card 3/4

Cyanine Dyes From 2-Methyl-4,5,11-trichio.rc 3/07 3 1601026 ' 0 '0 @/'02 1
/0 4
benzimidazole B000054
general structure
Dye
2
3
4
There are
2 Italian,
R H CHj R
R11 @4'1-1 N R1
+ O-CH=CH-CH-Cl.
R2 %@" R 2
subst'.-tuents:
R R.1 R2 R3 maic, M'U
H H H H 489
H Cl H H 507
H Cl Cl H
C1 H Cl C1 520
2 tables and 7 referencesi 4 Sclv@-?' US, G@@,r.-.Ian, 2 Fr-:-I:h
anJ ' Swi63
ASSOCIATION @ Kafedra crLari--,,-@hc-skoy kh-.m4.1- Klyo-jokc-go pcLudvr5tvennogr7'
liniversiteta 4m. T G. Sh(,vjh.:lrko (Departmert :,f 0-ganle.
Chemistry Of the Fiyev S@ate Univers'.ty --meni T.G Shev;h,@-nkc,)
SUBMITTED, October 2q, 1956
Card 4/"4

ROFTMISTROV, M.N. j. STETSENKO. A.V ; KULIK, G@V.; VASILEVSKAYL, I.A.; RAYSHEVA,
V.G.; GAMALEYA, N.F.
Antimicrobial properties of some acenaphthene derivatives,. Mikro-
biologiia 29 no.5$757-761 S-0 160. (MDLA 13tll)
1. Kiyevskiy gosudarstvennyy univorsitet.
(AGEf1APHTHF11E)' (ANTISEPTICS)

STETSENK09 A,Y.; CHEIUqAVOKIYI G.V.
Cyanine dyes, derivatives of 2--mothylanthraquinon-(If, 21954)-
imidazole. Ukr.khim. zhur. 27 no.2:237-240 161. (MIPA .14-3)
.LKiyevskiy gosudarotvennyy universitat im. T.G. Shevchenkot kafedra
organicheskoy khimii.
(Cyanine dyes)
.1
i

STETSENKO, A.V.; LISHKO, V.K.
--@7 - - - -- - -
Imidocyanines containing elvctronegative substitutes. Ukr.khim.
zhur. 28 no.2:218-222 162. (MM .15:3)
1. Kiyevskiy gosudarstvennyy universitet im. T.G.Sheveheriko.
(Cyanines)

M
STETSENKO, A.V.; KPAVETS, L.I.
Cyanine dyes from 2-methylacenaphtheno-41,51 ; 4,5-thiazole.
Ukr. khim. zhur. 30 no.1-75-80 164. (MIRA 1716)
1. Kiyevskiy gosuiarstvenny-I aniversitet imeni Shevchenko.

STETSFNKO, A.Ye.
riesearch work of a young in.-;tit,.:te. Tekcsl@. pro=. 25 ro.12:FZ--e9
D 1651. OMIF,,.@ 19:11)

s iv"anldizalic'n n on tin uOus fumace. A. M.
ML:111 ). A. pul-c-lika, I't-51nik A1a,hijins1rn!-)1Tw,
r
!Ili,, www*AO"wmwle gc-ari maile (A 0.
3
C, 0.11:3 %fit 0"
.,I,';Cf
"1 :1 stream of -I A rIQ of 2 1.
r. atid Nll@ introduced 'it -I ratc of 9 atirl'21-
111113. thirl, was pri'milit-eLl. F@rjjl:r C.j@Qi 'M@r(: form'-d
fit tile 0 L/lir. r.1te. The C cantent rcial'siticit
III I)t)tlv cam.s. Thuir wear rc@i-t;mcc much greatvt
thatt ef carl-ttrind aml Ima-irv.0-1 Cr-M-Nf,s stvO gcir-
G.It

Sr_rrSiE Ntco, B. A -
WSRA41scellansous
Card 1/1 t Pub. 12 - 8115
Authors t Tarasov,, A. M.., and Stetsenko.. B. A.
Title I Use of kerosene as a carburizing agent for gaseous cementation
Periodical j Avto tra". prom. 2., 25-28p Feb 1954
Abstract I The use of lighting kerosene (standard GOST 4753-49) in the.role
of carburizing agent for gaseous cementation in coutinuous-operation
furnaces, with direct feeoing of the liquid carburizing madium and
in shaft furnaces, is described. The vtrength of details cemented
with lighting kerosene and pyro benzenop is identical. YAthods of
reducing the soot formation and improving the circulAtion of the
carburizing agent between the treated details, are presented. Tables;
graphs; drawings; illustrations.
Institution t The V. M. Molotov Automobile Plant,, Gorkiy
Submitted *0**9

SuT, "-VC, " '
I!', ... .-)* .1.
USSRI Engineering - Metal hardening
Card 1 1/1 Pub. 128 - 14/32
Authors i Tarasov, A. M. and Stetsenko, B. A.
Title t Hardening of metal by a diffusion process with high frequency,heating of
components.
Periodical I Vest. Mash. 34/7, 50 - 52, Ju1Y' 1954
Abstract I Hardening of metal by gas diffusion with high frequency heating of compo-
nent3, is described. General information is given on diffusion processes,
hardening, cyanization) temperatures, and types of steel. Illustrations;
drawing.
Institution :
Submitted :

,ISTf-@T-S- F,-NKUT
- - - - -. . . . .
&OIrsd=Md PwDedim md Weu Midues of Clu ftwlW:
AutdmoWle Parb. A. M. Tarmoy and 13, A. Stetooako.
(A 'twya i Trakfornaya
(]ear tooth and rear axles are conmiderO and cyaniding
conditions aro given said fatigue or ntatin load testa @abnlatcd
Hardness, ease depth and ultituate breaking loatti dre xb)wn
and wear-rmistance memureq. 4P,4%4 and liquid opudding are
_,@fbty precautions are j e tiq
ared. n.n. ru4

'J
UM/ Engineering - Processing metal
Card 1/1 Pub. 128 - 22/35
Authors i Tarasov., A. M.., and Stetsenke.. B. A.v Engineers
Title Defects of cementation in a hard carbonizer
Periodical i Vest. mash. 3513, 70 - 73p May 1955
Abstract i A description is given of experiments conducted in cementation in'a hard
carbonizer in place of gas cementation. The method of operation, materi-
ale used, temperatures applied, rates of heating and cooling and other
points are examined as to their effect on the finished product. The dis-
advantages of the use of a hard carbonizer In place of gas are pointed out.
Four USSR references (1949-1953). Illustrations; diagrams; graphs; table.
Institution
Submitted I

3 -1-E 7-
USSR / Mechanical Properties of CrystLls an@', Polycryt,-taili-L., E-9
Compounds.
Abs Jour Ref Zhur - Fizika, No It, 195,, No 9462
Grig Pub Stetsenko -1"4-
Inst :-OM-Nry- 'Automobile Plant
Title :Causes of Formation of Irreversible Temper Brittleness
Orig Pub :Metallovedeniye i obrabotka metallov, 1956), 110 7, 38-35
Abstract :The existing hypothesis explain the irreversible temper
brittleness of hardened steel (a) by the decay of the re-
sidual austenite and (b) by the seperation of disperse
carbides. The author investigated the @ause of temper
brittleness of 40xh steel (0-38 -- 0.43% C)- Polished
specimens 10 x 10 mm with a notch were quenched from 8200
in oil, and then tempered in saltpeter bath in the 200 --
5500 range. Second hardening increase sharply the impact
viscosity, although the zone of increased brittleness
(275 -- 3500) remained. It is possible to assume that in
Card 1/2

USSR / Mechanical Properties of Crystals and Polycrystallic E-9
Compounds.
Abs Jour Ref Zhur - Fizika, 11o 4, 1957, rio 9462
Abstract the 40Kh steel, as in the 20 KhM steel, the amount of re-
sidual austenite after the second hardening decreases. This
should influence the course of the curve of the impact vis-
cosity towards increasin,- the interval of temper brittleness
Me same effec should be seen in the increase of rate of coo-
ling upon hardening. However, experiments have shown that
cooling of water gives a more pronounchd interval of increa-
sed temper brittleness.'The results obtained show that the
decay of the residual austenite in steels which are contai-
ned in an insignificant amount after hardeninF is not a prin-
cipal factor causinG the temper brittleness. The author be-
lieves a more acceptable cause to be the separation of dis-
perse carbides from the solid solution or the separation of
compounds that reduce the impact viscosity of steel.
card 2/2

AUTHOR: -r.;tetse.ako B.A. Engineer. 129-4-10/17
TITLE: -6n high speed heating during heat treatment. (0 skorostnom,
magreve pri termicheskoy obrabotka.)
PS,RIODICAL: "bletallovedenie i Obrabotka Metallov" (Metallurgy and
tal Treatment) 1957, No. , pp. 47 - 50 (U.S.S.R.)
AESTRACT: For studying the possibility of application of high
speed heating during hardening and tempering of steel
experiments were carried out involving heating of steel
in ordinary furnaces, the temperature of which considerably
exceeded thi required temperatures. The effect was studied
on cylindrical specimens consisting of fine grain 40K steel
of 60 miji dia. 180 mm length, composition: 0.35-0.45% C,
1
1
'
C
6
1
r. MRX.
1 Mn, 0.80 - 1.10%
0.17 - 0.3?%
, 0.50 - 0-80
;.
0*400/a' Ni. For measuring the temperature one of the speci-
mens was provided with a 10 mm, dia. 90 mm, deep hole into
which a thermo-couple was inserted. The specimen with the
thermo-c8uple was subjected to high speed heating at 1 000
and 850 C in an electrically-heatod chamber furnace. The
results are plotted in graphs and entered in a table. It
can 8e seen from the curves, Fig. 1, that a temperature of
870 C in the core of the specimen is reached after 11 mins
in the case of a furnace teRperature of 1 000 0 and for a
Card 1/3 furnace temperature of 850 0 the core of the specimen is

On high speed heating durinr- heat tre-atment. (Cont.)
D 129-4-10/17
heated to 540 OC in 8 minn. The proporties are compared
of specimens wtich were heated for 1 112 hours and hard-
ened from 850 C in oil, whereby one of the sSecimens was
subsequently tefmpered for 1 1/2 hours at'540 C, with
specimens0heated for 8 mins in a furnace of a tempemtuie
of 1 000 C; in the latter case one of the specimens was
tempered in a furnace at 850 C for 11 mins. In the case
of high speed heating the micro-structure of the surface
zones of the hardened specimens consists of troostite-
martensite and the core of sorbite and ferrite. High
speed hardening followed by high .9peed tempering brought
about a considerable improvement in the impact strength of
the steel. It is concluded that high speed heating enables
to r6duce considerably the duration of heat treatment and
to improve the strength of the steel. During rapid heating
it is very difficult to control the temperatuie of the
furnace and of the components pyrometrically; the temper-
ature of the components increases rapidly and for ensuring
uniform heating and preventing over-heating of the steel
the heating has to be stopped in time.. In flow production
processes such heat treatment can be effected in automated
Card 2/3 high

AUTnOR: Stetzenko, B.A. 129-10-10/12
On industrial utilia-ition of gas cyaniding. (0 promy-
shlennom qt,-nenii gazovogo tsianirovaniya)
priL
Pz;RIODIUAL: "Inetallovedeni-ye i Obra-botka Yietallov" (bletallur and
Lietal Treatment), 1957, No.10, pp. 43-48 (UOS.S%E)
ABST.L-LiCT: All the gear box gcarS Droduced by the Gorki Automobile
@@W@orks are made of 40X steel containine 0.38 - 0.43 and 0.36 -
0.41@,- @, and subj%@cted to liquid cyaniding to a depth of 0.18
and 0.25 mm, followed directly by hardening in oil. These
sear.s -Droved sutisfactory in service and technologically. A
more proLa--ssive Liethod is gas cyaniding; it ensures good
properties of sui.,face-hardened components,as was confirmed by
compai-ative fatiL@pe tests with gear boxes of the Pobeda car
which were cyanided in a ,-aseous medium and in a liquid medium
to a depth of 0.18 mm. In spite of the advantages, gas cyani-
din- is not bein- adequately used in industry owin:1- to techno-
lorl-ical difficulties and due to the fact that available infor-
Liation is not adequately disseminated. Due to the relatively
low process tem-pe-rature (800 - 850 C), it is advisable to use
zor L;as eyanidin,,,-- iaediuia c---jrbon steels since fov such steels,
Ui,e temDerature of the cyamling process can be made equal to
Card 1/2 the har-doning temperature, ensuring adequate haidening depth

129-10-10/12
In industrial utilisation of gas cyaniding. (Cont.)
and strength after the hardening process. Practical problems
of E',as cyaniding are discussed on the basis of practical
C>
experience and some literary data. It is mentioned that cyanide
hardened layers have a characteristic feature, namely, no
excess cementite in the fonn of a lattice or grains was ever
observed in the micro-structure, not even in cases in which the
surrounding zone of the layer is strongly saturated with carbon.
The author eiqphasises the importance of introduction on a wide
scale of @@as cyaniding.
There are 2 tables and 4 Slavic references.
ASSOCIATION: Gorki Automobile Works (Gorkovskiy Avtozavod)
AVAILABLE:- Library of Congress
Card 2/2

STWSUKO, B.A.
NVANNEEW
Determining the Miss of the austenite grain by high-temperature gas
cyanidation. Zav. lab. 23 no.3:326-)27 157. WRA 10W
1. Gorlkoveiriy avtomobillnyy sayod in. V,,N. Molotov&.
(Austenite--Ustallography)

A@MfOR: Stetsenko, B.A. SOV/113-59-2-12/15
TITLE: Increasing the Service Period of the "ain Gear of a GAZ-63
Automobile (Povysheniye sroka sluzhby glavnoy peredachi av-
tomobilya. GV-63)
r7-RIODICAL: Avtomobillnaya promyshlennost;, 1958, Nr 21 Pp 40 - 42
(USSF)
ABSTRACT: The resistance to wear of gears is increased by using small-
grained steel type 207MIM. Several gears were tested on
a special stand driven by a 90-kv electromotor at 940 rpm.
Table 1 shows that the Kears processed by carbonization in
a solid carburizing agen' lasted 3.5-37 hours on the stand,
the majoritO, being betwuen 3-5-13.5 hours, Figure I sbows
the type of wear on the cogs of the tested gears, The re-
sults of the chemical analysis layer by layer are riven in
Table 2. A partial decarbanization of the carbonized layer
and its saturation by nitrogen takes place during heating
for tempering (Figure 2). The data of Table 2 shows that
Card 1/2 steel processed b.,., gas carbonization has an increased

SOV/113-55-2-12/15
Increasing the Service Period of the L-lain Gear of a GA3-63 Automobile
bending resistance and resilience. There are 2 tables,
2 graphs, 4 photos, and 3 Soviet references.
ASS-1-CIATION: Gor1kovskiy avtozavod (Gor'kiy Automobile Plant).
1. Gears--Life expectancy 2. Gears--Carbonization 3. Gears
--Heat treatment 4, Gears--Testing equipment 5. Gears--Test
results
Card 212

2 4 0
852ol
s/129/6o/ooo/oll/012/016
E073/E535
AUTHOR: -Stetsenko, B. A., Engineer
TITLE: Increasing the Strength of Cyanided Steel
PERIODICAL:Metallovedeniye i termicheskaya obrabotka metallov,
ig6o, No.11, pp. 46-47
TEXT: III y(iew of the possibility of controlling the process of
gas cyaniding,@Athe author sttidied the influence on the strength
of cyanided steel of feeding into the furnace kerosene and
ammonia. For this purpose, the gears of the M-20 motor car gear-
box, notch-free 10 x 10 x 55 mm impact test specimens and
10 x 12 x 80 min bending test specimens were used. In testing for
static bending the distance between the supports was 60 mm. For
layer by layer chemical analysis of the cyanided layer, specimens
of 35 min diameter, 120 min length were used, from each of which 3 to
4 batches of chips were taken, the thickness of the first batch
being 0.05 min and that of the subsequent ones being 0.10 mm. The
specimens were subjected to gas cyaniding in a laboratory shaft
furnace (300 min diameter, 650 min deep) at 815*C for 90 min with
various speeds of feeding the kerosene and the ammonia. Following
that, the gears and the specimens were quenched in oil and
Card 1/3

852ol
S/129/6o/ooo/oil/012/016
E073/E535
Increasing the Strength of CYanided Steel
tempered at 200*C@ Then, the bending strength of the gear teeth
was tested by means of a press, breaking 3 to 4 teeth in each gear.
The strength depended on the mechanical properties of the cyanided
layer, since tinder all gas cyaniding regimes the temperature, the
duration of the process and the method of quenching were identical.
The results (which are tabiilated and graphed) lead to the
following conclusions:
1) The kerosene/ammonia ratio influences the contents of carbon
.A@d nitrogen in the cyanided layer and also -the strength of the
cyanided steel,
2) The hardness of the cyanided surface is high enough and
practically equal for all the gas cyaniding regimes tried in the
experiments .
3) The best combination of bending and impact strength is obtained
under the regime No-5, which consists of feeding into the furnace
25 to 30 drops/min of kerosene, 2 1/min of ammonia, The speed of
diffusion of carbon and nitrogen is relatively high; at a depth of
0.25 mm the layer contained 0.78% C and 0,25% N. This compared with
o.61-o-72%N andO.02-0.16% N for specimens subjected to the other
Card 2/3

85201
S/129/60/000/011/012/016
E073/E535
Increasing the Strength of Cyanided Steel
regimes. At the surface the carbon concentration is nIar to its
eutectoidal value. The bending strength was 247 kg/mm and the
impact strength was 2.06 kgm. The breaking force of the teeth
was 5075 kg. There are 1 figure and 1 table.
ASSOCIATION: Gorlkovskiy avtomobillnyy zavod
(Gorlkiy Automobile Works)
Card 3/3

1. 1 rl 10
88370
S/129/61/000/001/012/013
E073/9135
AUTHOR: Stetseriko, B.A., Engineer
TITLE: Application of D@uble Quenching
PERIODICAL: Metallovedeniye i termicheskaya obrabotka metallov,
1961, No. 1, pp. 62-63
TEXT: The authors investigated the influence of double
quenching on the strength properties of 4OX NOW, 20)(MM
(20KhNM) and 18,Av4vA(18KhNVA) steels. The strengths in static
and dynamic tests were determined on 10 X 12 x 80 mm specimens.
The distance between the supporting points in bend tests of
prismatic specimens was 60 mm. The specimens were heat treated
under shop conditions. The impact strengths of cyanided and of
case hardened steels were determined on notch-free specimens.
The bending strengths of gears were tested and these were also
tested in rear axles and gear boxes of motor cars. The impact and
bending strengths of all these steels increased considerably after
double quenching. In the core and in the diffusion layer of the
specimens the structure was fine grained; the quantity of residual
austenite decreased considerably in the diffusion layer. For
Card 1/3

88370
S/129/61/000/001/012/013
9073/EI35
Application of Double Quenching
verifying the effectiveness of double quenching, 7 gear blocks were
quenched and 1+ of these were quenched for a second time* These
blocks as well as standard gears were used in gear boxes. The
gears with the standard gears were subjected to shot peening.
The results of stand fatigue tests of the gear boxes were as
follows:
Torque, kgm Service life (until tee th failure), hrs.
Primary Secondary 1 quenching 2 quenchings
shaft shaft
22 39 78 48
22 39 65 16
22 39 65 11
22 39 - 8
The results show that the fatigue strength was considerably lower
Card 2/3

88370
S/129/61/000/001/012/013
E073/E135
Application of Double Quenching
after double quenching. This is attributed to increased
deformation of the gear teeth after repeated quenching which
disturbs correct meshing. As a result of heat treatment of the
rear axles the driven pinions suffered considerable deformation.
The following conclusions were arrived at: 1) Double quenching
increases the strength of steel; 2) For components that are
not prone to considerable deformations during quenching, double
quenching can be effective for increasing the strength and service
life; 3) For components which suffer a high degree of
deformation during the first quenching, a second quenching is not
recommended.
There is 1 table.
ASSOCIATION: Gorlkovskiy avtomobillnyy zavod
(Gorlkiy Automobile Works)
Card 3/3

GLADKIKH, A.14., kand.tekhn.nauk; ST'--'Ta'-II',KO, B.A.; GITELISOU, lq*L.I.
Improvin& the quality of the sta--l used for cold upaetting.
Stall 21 no.8:758-761 Ag 161. (MI-'U 14:9)
1. Gorlkovskiy politeklinicheskiy institut i iro)-ektno-tekhnolo-
gicheskiy i nauchno-tekhnicheskiy institut Gorlkovskogo sov-
narkhoza.
(Stool--Metallorgri-Ahy) (Forgirg)

GLA,DKIKII, A.N.; STETSE14KO, B.A.
Quality of steel for cold upsetting. Metallurg 8 no 7:29-30
ii t63. ilURA 16:8)
1. Zavod "Krasnaya Etna."
(Forging)

7 ' 7'77
'rn /J3 "A -
i ACC NR, AA010640 (.A) SOURCE CODE: (J,1/0422/66/000/005/0087/0~87~,'
,ALT-MOR: Arone, R. G.; Balakina, 1. A., Bochkareva nko, B. A.; Sokolov-
Stetse
iskiy, P.
'ORG: none
!TITIX: A itandard for lovi-alloy structural ateel ;i
SOURCE: Standarty i kachestvo, no. 5, 1966, 07
TOPIC TAGS: construction material, structural steel, alloy steel, welding evaWation,
I
mechanical property / IGGS steel, 09G2S steel, lOG2Sl steel
iABSTRACT: A series of innovations in low-alloy structural steels (GOST 5058-65) based
Ion recent work done at the Central Scientific Research Institute for Ferrous Metallurgy,
is described. Nineteen new gr@jqes of high st-rength low-alloy steel ning small
!amounts of carbide and nitrid6L forming e ements (Ti, V, Zr, 11b) were developed. Higher!
quality and performance are c aimed for the new naterials and suitable applications are@
mccmmended. The steels were melted in, standard Martens furnaces and oxygen- conviefted.:
While the majority are used In the hq4rolled condition, they may be heat-treatedito
yield strengths of 40-50 kg/cm2 with fa 3aving of 20-30% in material. The heat--Tr-eated
steels possess lower brittle fracture@ 6ndencies and slight aging sensitivity. Phos-
phorus and sulfur contents oF the-steels were maintained within strict linits (below

Category USSR/Oprtics Photometry, colorimetry, and illunination engineerinz K-10
Abs Jour Ref Zhur - Fizika, No 1, 1957 No 2613
1
Author Kondilenko, I.I., Stetsenko, B.N.
Title Luminescent Hetero@@Ru@s @try in the Ultraviolet
Orig Pub Nauch. zap. Kyivslk. in:-ta, 1955, 14, No 8, 137-14o
Abstract L.N. Ananlyeva's and A.A. Shishlovskiy's method (Dokl. AN SSSI@ 1937, 17,
183) for the measurement of the distribution of energy in the spectrum of a
source of light in the UV region was m6cUfied and simplified. Instead of a
luminescent plate, brought in contact with the photographic emulsion, the
authors coated a layer of luminophor in the form of a viscous mass (mixture
of 1.5 cc alcohol solution of Na salycilate with a concentration 0.5 g/cc and
3 cc of aqueous solution of agar-agar with a con,:entration 0.15 g/cc) directly
on the photographic emulsion. After photograptdnf the luminescence occuring
when the photographic layer is illuminated by the investigated source in the
spectrograph, the layer was washed off in warm water. This layer is suitable
for accurate measurements only at?\> 210 mp; at smaller wavelengths there is
some absorption of *ght by the agar-agar, which, however, does not prevent a
qualitative study of the spectrum in this region. The energy distribution
in the spectrum of the SVDSh-250 mercury lamp measured with the above method
in the 248--365 r# region is giWn.

L 2843' 66 FBDIEWT(l )/EEC; (0-2/T/EWF (k) IjP(c) WG/G D,
ACC NRt AT6015147 SOURCE CODE: UR/0000/66/000/000/0322,10326
AUTHOR: Yatsenko, A. F.; Kulyupin, Yu. A.; Stetsenko,
_B, V.
ORG: Institute of Physics LN UkrSSR (Institut fiziki All UkrSSR)
TITLE: Using _jilsers f studying the kinetics of photoelectric field emission
7
SOURCE: -Respublikanskiy seminar po kvantovoy elektronike. Kvantovaya elektron.ika
(Quantum ile-&fr-onf@) --tr-a-d Kii. - ' o_@a-dj@_
y sem nara. -"iik
I ev, ca, 1966, 322-326
TOPIC TAGS: pbotoelectric effect, field emission, laser application, silicon, laser,
pulse generator
ABSTRACT: A method is proposed for using a continuous-duty helium-neon laser to pro-
duce short iniense light pulses. An example is given illustrating use of 'these light
pulses for stu@iying the kinetics of photoelectric field emission from high-resistance
silicon. Two methods were used in this study: 1. measur4--ment of the drop in photo-
electric field emission under pulsed illumination, and 2. determination of the vari-
able and constant ccxnponents of field emission current under illumination by a sinu-
soidally modulated light. The short light pulses were Fri7oduced by a mechanical --ys-
tem with a rotating rIsMatic mirror (see figure), The light source was an LAK-1
Ile-Me laser (A=6328 K, power 100-300 ow, divergence angle less than 10'). The instal-"
lation gave a pulse duration of 2.10-7 see with a I cm light spot at the pickup. The
1/2

L 284'132-!'@t
Mechanical generator of short light pulses: 1--prismatic mirror;
2--light source; 3--light receiver
distance between pulse generator and receiver may be increased by i
an order of magnitude and a long-focus lens may be used to reAuce :
the spot diameter to 0.1 cm or less. These measures would make it@
possible to reduce the pulse duration to 10-9 sec. The variable
and constant component of photoelectric field emission produced by'
exposing an emitter to light modulated with a frequency of 4.6 Mc
were measured to study the fast component of relaxation. The
modulating element was a KDP crystal placed between the laser and a polarization
pr1sme A block diagram of the experimental installation is given. An attempt was
made to establish the upper limit of frequencies which may be recorded by a photoelec-
tric field emitter. The experiments yielded satisfactory agreement between calculat-
ed and observed frequencies although the photoelectric fifeld emitter was not able to
record a signal at 67 Mc, apparently due to inperfections in the method. Further at-
tempts in this direction are being made. Orig. art. has: 3 figures. [14] L
SUB CODE% 20/ SUBM DATE: 12reb66/ ORIG REF: 002/ OTH REF: 008/
ATD PRESS:,.$-.40@'
Card 2/2

L 2@4@Z-@61 EWG Q)/RWA(k)/FBD/LW(j)/PM W@LWW /SEC W -2/&C W/T/8EC
ZW?(k)/&WA(m)!2/ZWA(h) Fn-4/Fo-4/Pr.4/Feb/Fi-4/P1-4 IJP(o) WG/WH
I of - -- - .,- -
ACCESSION NKj AP5000631 S/0185/614/009/011/1267/1268
AUTHORS Broude, V. Lz;.Fogoryelyyt 0 H.,g @ookLn,'-H, -9,1 Statseako,
it. V.; Ya nko,, 0, F.
TITLEt 'Radiation fluctuations of a pulsed laser
SOURCE: Ukruyins'kyy fixy4ihnyy zhurnal, ve 9,, no. llv 1964,
1267-1268
TOPIC.TAGSt laserp pulsed laserp laser ra'diation intensity~ r@bj
crystal, neodymium glass
AHSTRAM An investigation' is made of the relationship betveen-the
intensities of "np@kes!' radiated from two ends of a pulsed laser. A
-.-special laboratory setup was used for the measurement of laser
rndiationo The measurements consisted in photographing the flashes
'from both ends of the.crystal. The intensitLeti of "spikes" ,
4ere.m e.a a u r a d (with an accuracy of 5--IOZ) and their ratios
calculated. The ratios of radiation intensities from two resonator
ends for different "spikes" within..the same flash differed by as much
as'20 to 40 percent, Other regularitiesp such its the dependence of
Card 1/2

L 23457-65
ACCES$ION NRs AP5000631
scattering on intensity and the moment of "spike" radiation vithin
the flash were not observed. Noncorrelation of laser radiation
intensity with ruby crystal and neodymium glass in the case of di-
electric mirrors with a reflection coefficient close to 100 percent
was approximately identical. Scattering decreases when pumping is
increased above the threshold. OrLgs art* has: 2 figures; JKHI
ASSOCIATIONt Instytut fiiyky AN URSR#Kiev- (Institute of Physics,
AN UKrSSR)
SUBMITTEDs 25Jun64 ENCLt 00 SUB CODEs EC
NO REP SoVi 005 OTHERt, 001 ATD PRMS: 3174
Cord
.2/2

zcne servt-,-i b-.-
In
r-;:,.en+lgl Station. 7rakt. i
r .14'.4 Ja 16-5.
axty,
stantsiya.

-s,mrsmw, G. 1. , inzh.
Investipting corncob cleaners. Tzrakt. i sel'khozmash. 33 no.12:
33 D '63. OURA 17:2)
1. Ktummikaya mashinoispytatol'ruiya BUint.,siya.

STETSENKO, G. F.
F. K. Borisovich reviewed an article by G. P. Stateenko., *On the Problem of
the Therapy and Prophylaxis of Fowl Plague," in which he states that for treatment
of chicken ill with plague, and for propbylaxis of this illness, the author
(Stetsenko) tested a number of preparations, such as: camphor serum (according
to I. I. Kadykov) in 0-5 - 2 cc dose.
SO: Yeterinariya; Vol. 23; No- 8-9; 16/18; August/ftptt=ber 1946 Uncisasified.
Trans. #312 by L. Lulich

STITSIM. G.Ye., kandidat tekhnichookikh nauk.
Grinding the conical alide block plunger. 2hel.der.transp. 37
no .10:?1-72 0 155. (KLIA 9:1)
(Locomotives-Telve-gears)

GUBMATORUVA, V.D., T.GNATOVSK.A.YA, L.I.1 N, L.N.; SMSENKO. I.A.
(Ryaza.nl) ; ---, Ir_-
Diagnostic impwtanca @f the erL.j.bpj'u-rc:,,,riase titor I'D
rhoumati2 favor. Nauih. trudy RJ.!i-.. impd. !nmt. 14-222-227 163.
(MJR!- 171:5)

PANASLUKO), G.P.; PI-IANIJUNIKOV, V.Ye.; 5T-i'TU-LNKO, I.P.; GROPIKAJHVILI, M.A.
Some test results of cast core bits. R&sved.i okh.nedr 28
no.3.22-26 ',Ir 162. (ME1 15.,4)
1. Vol.Co-Donakoya geologicheskoye upravleniye.
(Borine. machinery-Testing)

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11. Oils and Fats
7. Problem of breaking down fats with high initial acidiky.
Masl. zhir. prom. 17. no, 7- 1952.
9. Monthly List of Russian Accessions, Library of Congress, -1953. Unclassified.

/V A o" -L-.
:)f in )n@,, :@Ilbra C-@!i:lz-,---3:,

SaMBKO, I.P.; SHTERN, R.M.
Producing glycerol without using a reagent. Yasio-zhir.proma
20 no.1:15-19 155. (MMA 8:3)
1. Nevskly mylovarennyy zavod.
(Glycerol)

STETSENKO, I.P., lnzh.; 14IRDITOV, H.A.
,,-, - ''' @ ' ' Screw press for tollat soap. %al.-zhir. prom. 24 no.10:
39-41 '58. (MIBA 11:10)
1. linvakly mylovarennyy zavod.
(Power presses) (.Soap)

-ST&SIMID, M., inxh.
Smll univereal feed mill. Tekh. v sellkhoz. 20 no.6:35-36 is 160.
(MM 13:10)
(Feed mills)

STMMO, M.
Fire-proof casing of cOmInAtiou chambers in dryer furnace@ of
corn-procesaing plants. Muk.-elev. prom. 26 no.6:19-20 Je 160,
(MIU 13 i 12 )
1. Tekhnicheskove upravleniye Ministerstva khleboprodukotv RSFM
(Furnaces) (corn (Maize)--Drving)

STETSINKO, M.,.INZH.
Disk feeder for slow-flowing materials. Muko-elev. prom&
26 no. 12:16-17 D '60. (MMA 13:12)
1. Ministerstvo khleboproduktov RSFSR.
(Feed mills)

ST-`T6h;N!'.OY M., ihzh
Stamp for labeling paper bags. ',%uk.-elev. prom. 27 no.7:13 Jl 161.
(MJRA 14:7)
1. Te;'--dM-'cheskoye upravleniyo Ministarstva zagotr-vok M?S3R.
- (Marking devices)
C@s?@
@j

STETPZNKO, N.A.; PALIMIN. B.A., kand.ekonom.nauk. otv.red.; ITSKOVSKIY.
M.B., red',izd-va; GORIKOVAYA, Z.P., takhn.red.
[Combining farming branches on cotton-growing collective farms]
Sochetanis otraelei v khlopkoseiushchikh kolkhozakh. Tashkent,
Izd-vo Akad.nAk Uzb.SSR. 1959. 156 p. (MM 12:7)
(Uzbekistan-Cotton growing)

STETSENKO, M.D.
Affect of rectolinear impulses of rectified. current on the central
nervous system In dogs. Fiziol.zhur. [Ukr.] I no.2:30-37 Xr-Ap 155.
1. Institut firtologit iment akademika O.O.Bogomolitaya Akademil
nauk URSR.
(NUCTRIC ANESTHNSIA) (ELICTROPHYSIOLOGY)
,(IMRVOUS SYSTEM)

USSR/Hurnn nnd A;iimal Physi3l@@gy - The Nervous System. T
Ab.; j)ur : Ref 7-hur Biol-, N--) 3o 1959, 13150
Author : Stetsenko, M.D.
Title Changes in the Temperature of the Brain with Application
of Alternate nnd Direct Currents as CDmpared to the
Effect of S-me Riarmcologidal Agents.
Orig Fiziol. zh., 1957, 3, Na 6, 91-lol
Abstract When the brain cortex of rabbits was stimulated by means
Df electrodes forced into the frontal and occipital re-
Gions, three types of temperature chan6es were ibeerved
in the brain with alternate currents of 10, 40, and 100
inpulses/second: cooling, heatin(;, or coaling followed
by heatine. With the action of a current of 100 impul-
ses/sec-)nd in 70% of the experiments sleep was induced
by electricity, and the condition was accippanied by an
elevated temperature of the brain. This reaction
Card 1/2

USSR/Hur.nn and Aniriai PhysiolDgy - Ve Ncrv@us 'System. T
Abs Jour Ref Zhur Biol., U.) 3, 1959, 13150
explaina the stimulation of the hyp@Ahalamic region.
Therral reacti,)ns of the brain rose with reduced fre-
quency of the current and prolongation of each impulse.
Direct current influenced the temperature of the brain
tj a lesser degree. With the action of phenamine pa-
rallel phase changes were ;1oted in the temperature of
the brain and the body. Chloral hydrate caused a lowe-
ring of the brain temperature, and the effect of morphi-
ne was varied in different experimnts. It is suggested
that a c-minectixi exists between stimulation and inhibi-
tion and the chan,-.0s in the brain temperaturej and that
it can have a mDsatc and phase character. -- K.S. Ratner
Card 2/2
94 -

KRUFSKIY, N.K.; ALEMANDROVA, A,M.; STETSE940, M.V.
Determination of chlorine ion in cloudy @md colored soil extracts,
Pochvovedenie no.2:-Ur@@-113 F 162. (MIRA 15:34)
1. Ukrainskiy nauchno-issledovatellskiy iastitut pochvovedeniya.
(Soils-.-Chlorine content)

L7 I-- '_1'
133-10-23/26
AUTUOR: Yulin, S. I., and Stetsenko, N. A. EnE3ineers.
TIT11@: The Influence of the Reduction Rat on Destruction 6f
Carbide Lattice In the X12 and X121 Steels,
(Vliyani-ye Stepeni Ukovki Na Razrusheniye Karbidnoy
Setki v Stalyakh X12 i X124@.)
P!@RIODICAL: Stall, 1957, No-10, PP. 948-950 (USSR).
ABSi:RACTI: During-forging of ingots of X12 and X12