SCIENTIFIC ABSTRACT SUVOROV, B.D. - SUVOROV, F.S.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001654020008-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

SUVOROV, B.D.
Acute gangreuvuzcho'~ecystitis in a 7-ye
14 ho.11:115-116 N '58.
5
1. Iz khlrurgicheskgo otdelenJva Tullfl'
noy 'hollnitsy (nach A.D. Verbovenko)
(CHOLECYSTI IS, in Inf. & child
I~I
ncute nnarenous in 7-Yem
1d child. Xhirurgiia, Moskm
(NM 12:1)
otdelencheskoy zhele
old (Rua))

V.S.,
Ti. Airs 50%.
KlUfk 1
,,.4 per-' me,
ji~Ejj StUdfr--3 cri t'np
ii n9 r:L L abil-I ~,,yo
Y -h b.
f !J Rj~ 9
r rlyi
o?. v:i
Li CL
-3C, 7.
P
-:"Va 0y shakhtrc-,g3 ~-ro~te-.I-
d
IS

SUVOROV, B.M.
Organizing cons I '.ori vork on gas-cdwdensate fields. Stroi.
I
truboprov. 9 no.26,24-26 F 164. (MIRA 17 % 3)
1. Stroitallhor
tov-na-Donv..
mlye Plo.5 tras~a Yuzhgazprovodstroy, Ros-

KOSSOV., V.V.; BARANOV., E.F.; VOIDDIN, L.N.; LEYD

~
IN
IND, Yu.R.;
MIKHALEVSKIY, B.N.; �!~OROV,__P.Fl DETN A, E.V.
(The interbranch b
distribution of an
proizvodstva i ras
raiona. Moskva, I
1. Akademiya nauk
skiy institut.
nce of production
onomic region] Me2
deleniia produktsi
vo "Nauaka," 1964.
TSentrallnyy
d production
traslevoi balans
ekonomicheskogo
209 p.
(MIRA 17:5)
omiko-matematiche-

I
LEYBKIND, Yuriy Rafailovich; XYOROV,., Borip-Pav,
L.s., red.; SLUTSKINk, TS.S., ml. ! red.
F
(Critical selectionlof design and plan
method of network slheduling] Kritiche
planovykh reshenii;lmetod setevogo pla
Moskva~ Ekonomika.* ;.965. 64 P*
ch; GIXAZER,
decisions; a
otbor proektno-
anlia. 2. izd.
(MIRA 18ao)

V U rco r)5.
14(10); 3(5) PHASE I BOOK EXPLOITATION SOV/2843
'Sloveshchaniye po rat5lonallnym sposobam findamentostroyenlya na
vechnomerzlykh gruntakh
Triidy... (Transactions of the Conferencel~n Efficient Methodsof
Building-Foundations on Permafrost Soi ) Moscow, Gosstroyizdat,
1959. 131 p. Errata slip inserted. 1 200 copies printed.
Ed. of Publishing House: N. M. Borshchevs aya; Tech. Ed.: Ye. L.
Temkina. 0
PURPOSE: This book is intended for const ction engineers, indus-
tri.al planners and builders. I
COVERAGE: This book contains reports orig:nally read In Vorkuta in
1958 on experience gained in planning atid building foundations
in permafrost regions of the USSR. The reports were prepared
for publication in the NIIOSP (Scientif---c Research Institute
for the Study of Foundations and Underground Structures). The
Introduction was written by Professor V G. Bulychev. No
references are given.
Card 1/4

Transactions of the Conference (Cont.) SOV/2843
TABLE OF CONTENTS:
Foreword
i 3
Kiselev" M. F. Basic Prin6iples of Designihg Natural
Foundations and Building S
i ubstructures on rozen Ground 6
Suvorov, B. T. Experiencel in the Construct Lon of Buildings
and S-~-Yqictures on Thawing Ground 18
Ushkalov, V. P. Computing
t the Bases of Fou idations on
Thawing Ground According o the Limiting C )nditions 27
Dokuchayev, V. P. Experi i nee in Designing Foundations
In Northern Permafrost Reg
1 ions 37
Bakanin, V. P. Constructs on Conditions ano the Exploi-
tation of Minin g Enterprig es in the Pecho# Coal Basin 47
Card 2/4

Tran6actions of the Confe ience (Cont.) sov/2843
r,
Zhilltsov, A. I. ConstrucItion of Industridl Plants on
Permanently Frozen Ground With Subsequent jettling 56
Markin, K. F. Designing P ile Foundations U nder Permafrost
Conditions 58
Pchelintsev, A. M. Specia l Characteristics of Foundation
Building in the City of Ig arka 64
Bakalov, S. A., and V. M. ] Vodolazkin. Meth ods of Restoring
the Deformed Pr incipal Bui dings in Vorkuta 67
Yegerev, K.-Ye. Analysis o f Work and Comput ing the Rein-
forced Concrete Frame Foun 4ations and Frame Works,Taking
Into Account Un even Settli ng of the Bearing Ground 75
Ushkalov, V. P. Computing the Depth of Thaw ing of Perma-
nently Frozen G round Under:!Building Foundat ions 83
Card 3/4

Transactions of the Conference (cont.) SOV/2843
Yegorov, V. M., and V. M. Sokolova. New Data on Frost
Heaving of Foundations 100
Shchelokov, V. K. Decreasing the Depth of oundation
Laying by Keeping the Ground in a Frozen St e log
Kravchenko, I. K. Frost Heaving of Ground aid Foundations
Idiscussion) 113
Chekotillo, A. M. Non-Soviet EiTerlence in Building
Foundations on Permanently Frozen Ground lig
Forkhayev, G. V. Maximum Thawing of Perenn~~ally Froten
Ground Under Heated Buildings (two-dimensio, al solution) 124
Boyko, I. V. Settling of the Foundations of Industrial
Structures of the Vorkutaugoll Combine 127
A17AILABLE: Library of Congress
MM/Tm4
1-18-6o
Card 4/4

BEZRUKOV, B.A., inzh.; PODQLITSEV, L.N., inzh.; SUVOROV. B.V... inzh.
Sinking reinforced c*crete sheUs with a diameter of 4 m. into fine-
grained Band. Transpotroi. lUl no-4: 1 Ap l6i. (MIRA 14:5)
(Archangel-Bridges-Found tions and piers)

7-~. ~ 2", V-CV, E, 11%
Tur-F-entine -, - -- ,
Catalytic oxidation of basic
82 no. 2, 1952 Institut
ts of turpentine inIthe vapor phase. Dck-l. AN SSSR
kikh Nauk- AkademiijNauk Kaz.SSR. rcd. 24 Oct. 1951
SO: Month List of Russian Acce4sions, Library of C'ngress, June 1952 1%#~, Uncl.
i ? -

M
^1
Madmism of thi catalytic *Madma of p-cyam" I the
r.M, ic!=rx7n~a Zhri "R:
R
82, 415-1709U).+(Juder cand,tions of wild oxida 'a of
Vajmr of )~Mftcf j4h4c on VA The main produ I, arr
I
p-MgCJI.C(hH. XMI14, bi~, and 11,0. )tber
tli)lt i
kientilled an -Ait(:0fic0,%fc, )~-Mecff 4-
Product
CHO. P-0: 1-4: IIC 0, and Porme Usti. lizOll, if.
NA)
, It
jD~-cJ14011 h, a P-1, H. A ; were er
C
"4*" 0
c
CIIC*H4c P-M 4CHO. Makic anh
06" W
1c,
(Mllh. fruf If. which am known to be it the
a HC
0
nd
oxidation of ": I#-.0 and of Cjf#, were nut found. Nor
MUM peruAkdfic mpd3,, be detected. A complete .. we
ty,
ne
of the oxidation proposed In whick the variety of 0M
FPM, T-0
I, detived from a prbnarfly formed IS 3t f..
- I~
LCIW
An interruedlate WCOC4H.Me can be o3cid-ited to thee in-
W , -
crumd'ate b operoxxide. p-1100CULCOW245lix". The
I ol
it, to detm be peroxides is due to their insug' Y and
3,401 further ion2. The main feature of the talytic
- in --
04(14941 attw!k on the iso-Pr group cun-
aellatiamu n anii
tra"t to 14, 1, P. nd
Slub)14. 6. tAYJ4) w1cfe the lwnduct,* we -%Ule'r
on
cliclif nd &-U*,ClICJfCHO. IN. bon

STJJ'/(')-ii(-ff , B . V . ; Rnffi!--~ov' 8 . R -
"Inve.'3ti.-atincr t-e Oxidation of Organic Compounds. R
1 .1 " t~
Oxidation of Ter.Denes"
Izv. AN Kazakh SSR, ser .. Khim., No 5, 1953, 85-90
Studied the catalytic oxJJatlon of alpha-pinene
h usin
the vapor D ase over V20 5 1~,
e~omospheric oxygen.
-tol n -toluic acid,
Products were : p y.Imethv e, p
p-quinone, C02, anl water. ~RZh im, No 3~ 1955)
III. The Mechanism of the
d dipentene in
he main oxidation
raphthalic acid,
SO: Sum-No 345, 7 Mar 56

,AOV, B.,V.; RAFIKOV, S.R.
SUVq
N"'INW
Investigation in the fie d of oxidiz r
ir#ic compounds. Report no.4.
Catalytic oxidation of t tralin and !=e the vapor phase. Izv.AN Ka
SSR no.118:82-89 '53. (MIRA 6:10)
(Oxidation) (Tetralin) (Decalin) I

SUVOROV, B.V.; RAFIKOY, B.R.
Oxidation of organic (
oxidation of vapor plu
Izv.AN Kazakh.SSR no.]
pounds. Part '. M hanism of catalytic
camphene, cinsol: and bornyl acetate.
:70-74 153. (MLRA 7:3)
(Oxidation~ (Terpenes)

isulmov,
Abst.
Vcd.. 48 No. 5
If, 1954
rr- t-_n~ Plant Equivu., and Unit
Cris
Me odsofproduction.ofhd _ ^generstorsofbal--
g ~cfto eri.
10 ypa. D.V.Sokam-Mlandl. , . veunilk
~l YI
Ako W, No- '7'(WWWWO. 100),
.d
6&_ gell~ratiorl of H2 in pjwi-S type gen-
prato is cfc:~cribed. The equation appem to he Si + 2HtO
iOk-- 4- 211.. The recommunded charge b FeSi:-
N-.iO I:H.Oratioofl:'.).75-.4,Nvhichmak-esibemethcxirnore
Qcon in;val and facilitates cleanlur the ann. G. M. K.

j
Mech "Iffm of the Y r ihase on"twu oljzge...
il,phal and WBTZI_ -
1. In the presence of -.waxmi~.
B. V. uv=v. R. Ralikavrand 1. G. AnuchinT
AcadlMi. Kazaic. S.S.M). vowMay
A ka-1. Na%#AZZZ.R ~-r2j lU6jT.=~UX1UaEi0n of PhMe -
in file temp. range 3ZI Iyields mainly CO~, 1-10. BzH,
Bz(,H, quirlone, maltic, a ydride, and anthraquinone, and
C'
s=dl amts. of PhOH ari" H M.p The process can, be
represented by the schem of th roducts, only VI %vas
Chemical Abst. co
HCHO CH/
Vol. 48 No. 4 Phh c - PhC11,0011 Pholl - PIC'U.03 0 c0, lizo
Feb. 25, 1954 CH /
\C0
Organic Gh6mistr-j (IV) M
-11101- Colt
PIICR OIL -11, Bzff BzOOH BzOH CsHo
(VII) (VIU) (IX) M
not detected. The sell me involves 2 intermediate per-
oxides, 11 and VM. A thraquinone (XI) was detected in
the oxidation of 1, but t in the oxidation of either VI or
u
V11. Theforniationof I evidently proceeds by way of I+
0% + C"Ur'. 0, . In the oxidatiott of 1, the total
amt. of V~'+ IX does ot exceed 4%; that this is due to
further reactions of VII ud IX follows from the observation
with a con act tule Shor eued by a factor of 4. the yield of

~M is ;iiig~as in of the original 'J In the oxidation of

in
thes
I
VII p. the ain products aie IX,
ame
W
d V
.
.
cti.,
c tfl'~i rots. P
,
Z
vtly
su I thrqgh max. A ON HIO in-

ke
es
es the total yields rn dl but ~vithout altering the
x

~
con tiveness of the ma (JAatio of VI also yields, in
:on
0
~

th
the n' the products of incomplqte ox ation. but in some-
VII
w
wha smaller arnts. than
t on of VII and of IX
ed
'b~ is=
p eds simultaneously; evidence that IX is
form not only from VII, but also direc ly from VI. over the

+0, -ILO
-0 P, h
co pondinghydroperoxide,vi Ph H(OH)OOH~
A.
IX. Adda. of RIO vapor again incre es the yields of the
e
ediate products, without altcrin the disposition of
ii~n
_
the n ax. N. Thou

Oxidatfo. of .,gaal. omprzmds. IN'. Catalytic IIA
e &nd decah-dronaphthal
tion of Ig',y I No
_'j.7 oi~ Lod S~ kov. lz~jf-
P
M. Y..k M -.Y. 'NZ!' No. 6.
10. 118.
"1963); cf. i&fd. No- St 1951) .-The cn~idaticn of tctra-
azd de=hvdA-,)naphtWOcnc in the vapor pILV-,e ov--r V oxides -
wasuai6d. The Istphiseof the m-a&-b3a%vss shown to be
dchydr W to C Ha The main reacdon products am
!noae, C,,lIt.j H-Q. and CO,.
Small ts. of 15-naphthociumone, Bz1f "d SzOH are
found :The overall reaction stheme can be(devetcped from
the pemife thearies exp 13-kh J. R=x. PkyT.
Chzin. Sm 29, 373(1897), e hypoth
sevuely ~critizcd for bring una e to prrdEc ~the actual !TC-L
tion pro4ucts. Kowlapci,31~

-1 CIV, 'j
DehvdroKenatlin and IrrevArsible ed-Wis itene-
an vanAas
1954).-r
absence of Os
4 300 to 50*
80
forma on
latter rises ito
Above 475
p-cymene drops;
isopropenyltolue
direct dehydroge
gir 13 admitted
ated Hi, no
ps from
t 4
ethylacetophei
a ve amt.)
n med
reactions of
hydro priative
of pure dipentent over Yoxide c
at OD-5W* gave the following resul
at
ther 13 a decline In the leld f
th-
to 37 ), and along with dliyd;,.Ovl U.",
7
enc. At higher temp. the yi
of
so 0d ment6ne=:t- in the 0
1301
,,I
deh genation pred . and th
menthane Is absent and the yi
ie and Hj rises, apparently as a
nation of the starting material.
J: ito the reaction tube to consume
,n Ian
me bane Is formed, and the kid of
0
to 50%; not all Hs Is MUM,'
th are found small amts. of MeC
ne. With a Vold excem of air
the 'eld of cymene drwos still lower, I
In ation of HO. Thus sIr Min
Irre ersible catalysts and favors the ;
r itctions. G. M. Ko.-
lyst in
from
urates
there
of the
te.
Tid of
of p-
rult of
le~
I all He
ses the
ely de-
apoff.

Nation vf l lc crjllmouarls. -I(- Innarin, 4iate
:3, 27iro-1, 7,-3-611le uioiio--!hY[Lc-nzk-.i cs in
Is - V, . alud A-
MM. rzf:'~
~ v Kfwf. 1955 ff. C-"' so,
uf, -'id.~-
'
tjoli C4 -'AkNI-r`2 :1.,Q -s'lown ivi, lit "
~'id'61.1 111~
k), v_;N at ;~04-451011 Wall o-o' i.
c I I Lillie. ~Mi-r"! ' Eff-il and cmaciw wErc- en LQttd.
of stq)v;jse n!ddl.ti,m :lr,2 Aown..
ibll! on""vic ni ImAllels: Arp.11, IIZCIIO' 13211, -
I,,;-,Of!, ClIf" -Ntoji and lnaleic iiii'!13dride
We'-e -io to ~llhy-
Lhida ulpf qu;ucmL~ "A - xi-, found tv llc-~ -abrIVnitially suble.
~~t te-aip. undor a~,O' : tjjilr~-;C t1itt Cinly pr(-.(jljet5; are rljqql~ of
Incomplete
Qliu~ in i:qtien.; Aw7 Iiii"Ilt-, minp. zhc~c 111.0fillc de-
thu-o-;idrdi-311 i' C!'Inplctc-

"The Kazakh Chemical Industry~" Promyshiennost' K
statey (The Industry of Kazakhstan DurIng the Last Forty Y
Alm- Ata., Kazgosizdat, 1957, 150 P 13,Q00 copies printed.
The article lists a number of1chemical enterpriseE,
fertilizers, and discusses some of thejr problems, Other
salt, borates, and synthetic rubber. I
hstana za 40 let; sbornik
Collection ofArticles)
mainly plants producing
items discussed are potash

15
M'T
c ytfc prq4rdw. d, 6-~14k fAt 73:--Y-51j~-
TAW

RAFIKOV, S.T.;SUVOROV, B.V.
Oxidation of organi
stages of incomplet
in the presence of
no.1:58-66 '57.
(Oxi
SOLOMIN, A.Y.
compounds. Report
oxidation of banze
n vanadate. Izv.All
(Benzene)
.14: Intermediate
in the vapor phase
7,zakh.S.S,R.3er.khim.
(MLRA 10:5)
vanadate)

AUTHOR �T!~~VOROV B ., RAMOV, S~R., W P Z WX "TX 1XI
._
KUDINOVA, V.S., KIRWRA, M I
~ 2D-a-3i/67
TITLE On the Mechanism of T
Oxida;i n ransfo
; zmations of Methyl Alcohol
Formaldhyde and For mic Acid in the Va jour phase in the Presence
of Tin Vanadate.
(0 mekhani zme okis itellnykh prevrash cheniy meti lovogo spirta
formaldegi da i mir ivlinoy kisloty v j arovoy faze v prisutstvii
vanadata alova
PERIODICAL Doklady Akademii Na ik SSSR, 1957, Vol 113, Nr 2~ PP 355-357,
(U.S.S.R.)
Received 6/1957 Reviewed 7/1957
ABSTRACT On the occasion of xidation of alkyl benzols in the vapour phase
on vanadium catalya ;s a considerable c' uantity of compounds of re-
latively small mole ules develops as l y-products. Formaldehyde,
carbon monoxide and -dioxide among the m 4evelop the main products.
The formation mecha lism and further t3 ansformations of these "spli
ters" are in suffic Lently investigated (methanol, formic acid and
others would be exp ected espectially o n the occasion of oxidation
of the benzol homol Dgie4uith an isoprc pyl group). The present
particulars indicat e that the lowest e liphate alcohols are the
most unsteady ones. Larger quantities of corresponding aldehydeB
and products of a c Dmplete combustion develop from them by oxida-
tion. The yield of cids is small, al
~ egely because of its unstea-
Card 1/3 diness under these ~ onditions. Oxidat on was carried out in a disv

On the Mechanism of Oxidation Transfor tionB
of Methyl Alcohol, Formaldehyde and Formic Acid in the Vapour
Phase in the Preserice of Tin Vnadate. 2D-2--M/67
drogen developed on this occasion, probably by formamide. Ammonia
(3-5 g per 1 g initial matter) did not effect any essential modi-
fications of the HCN CO does not react with ammoni*t the experi-
mental temperature elther. It is characteristic that on the occa-
sion of interaction 1~etween formic acid and ammonia under similar
conditioiis the HCN-yield does not exceei 50%- So the high HCN- yield
cannot be caused by !he intermediate formation of formic acid. The
results of these latler experime-zs thu onfirm (under the given
experimental conditi(ns% ! tral:rzations of methanol and
, the abovi
formaldehyde followiTg each other
(2 illustrations, 16 citations from publications)
ASSOCIATION
PRESENTED BY
SUBMITTED
AVAILABLE
Card 3/3
Institute for Chemicsl Science of the A
U.S.S.R.
ARBUZOV, B.A., Membei of the Academy.
29.9.1956
Library of Congress.
emy of Science of the

MAKAREVICH, V.G.; SUVOROV,
Oxidation of organi,
molecular oxygen in
zakh. SSR. Ser.khim
V.; RAFIKOV, S.R.
compounds. Liquid
the presence of inh
no.1:79-83 '58.
e) (Oxidati
ze oxidation of OL-pinene bv
tors. Part 18. Izv. AN Ka-
(MIRA 12--2)

KAGARLITSKIY, A.D.;;
Vapor phase ammonol
nium vannfla e. Izv.
(Benzaldehyde)
9 of benzaldehyde ~nd benzoic acid on tita-
Kazakh. SSR. Ser. im. no*1:84-go '58.
(MIRA 12:2)
(Benzoic acid) r(Ammonolysis)

KAGARLITSKIY', A.D.; SUVOROV,IB.V.
Ammonolysis of tran&
Trudy Inst.khim.nauk
(Cycloxexan
and cis-isomers oflk,4-dimethyleyelohaxane.
N Kazakh. SSR 2:112~115 158. (MIRA 12:2)
(Ammonollysis)

66358
SOV/81-59-19-68673
Translation from: Referativnyy zhu al. Kh1miya, 1959 Nr 19, PP 310 - 311 (USSR)
AUTHORS: Solomin,' A.V., Suvor , B.V., Rafikov, S.
TITLE: The Oxidation of Org ic Compounds. Co ication XVI. On the Effect
of the Structure of he Side Chain on th Vapor-Phase Oxidation of
Monoalkylbenzenes in the Presence of Van ium Catalysts
PERIODICAL: Tr. In-ta khim. nauk AN KazSSR, 1958, N 2, pp 182 - 187
ABSTRACT: The vapor-phase oxi tion has been stud i d of toluene M, ethylbenzene
(II), cumene (III), c( -methylstyrene ) and styrene (V) by moistened
air in the presence of Sn(VO ) (VI) alloy V205 : Sn02 1:1 (VII)
and V205" M003 : P 05 (1:034~0 003i Ij
I). The experiments are
carried out at a te perature of iOO - OOC, the time of contact
0.1 - 0.3 see, the eight ratio of the idized substance to air
1:75-1:85, and the upply rate of the itial substance and water
5-6 g/hr and 100 - 05 g/hr respectivel . The quantity of the side

reactions depe d 0 the structure of
-9 Of
of
e initial alkylbenzene and on
the conditions Of t e process conducted
: At the oxidation of I and III
Card 1/2 over TV at a t
mpe ature -,- 3400C princ pally C6H5COOH (IX), maleic

66358
SOV/81-59-19-68673
The Oxidation of Organic Compounds.1 Communication XVI On the Effc-ct of the Structure
of the Side Chain on the Vapor-Phas Oxidation of Mono kylbenzenes in the Presence of
Vanadium Catalysts 4
anhydride (X) and a small quantity ~f quinone are fome . At a temperature 4 340 0 C,
besides IX and X 3-5% benzaldehydelis formed from I an 3-5% acetophenone from III.
I
The oxidation of I, II and III ov:rr'VV' and of II and I I over VIII proceeds in an
analogous way to the oxidation 0v I, but the optimum conditions'lie in the region
of higher temperatures. In all exporiments the presene of phenol, hydroquinone and
formaldehyde has been proved, VIII is inactive in the eaction of the oxidation of I.
The oxidation of IV and V proceeds analogously to the oxidation of monoalkylbenzenes.
A diagram of the reaction and its possible trends, depending on the intermediate pro-
ducts, has been proposed. Communicztion XV see RZhKhim, 1959, Nr 11, 39570.
T. Sladkova LK
Card 2/2

mANnorsKAYA, L.G.; SUVOROV, ~.V.; RAFIEDV, S.R.
Oxidation Lf,.dorg compounds. Report Nol-17: Autoxidation of
n ten aldehvde and_p-tolua~dehyde. Trutr Inst.
-butyrald e, C~a
khim.nauk AN Kazakh. SR 2:188-196.5 (MIRA 12:2)
1 8. ~B)
(Oxidatio ) (A dehyd

C_
jo I 0jr 'j IAV
AUTHORS 1 11 Suvoro%r, T1. Ra i"'ov, 3. a. 7 CY-1-20/6 3
TITLE: The Oxidation o.'
soyedineniy). X*.
Vapor-Phase Sta
etilbenzola na --anadate
PERIODICAL: Zhurnal Obshche
(USSR).
OrCanic Compoundol (01-ifileniy')
On the Oxidationlof Ethyl Benzene in the
e Over Tin Vanadat~ (XV.. 0 parofaznom ol_-'_-islen~~i
olova). I
Khimii. 1958, Voll. 28, Nr 1: PP. 133-138
ABSTRACT: The oxidation of alkyl benzenes with a secondary x-carbon
atom in the vapor-phase state had not been sufficiently in-
vesti-ated. Only one paper had been published on this subject
in which it is Pointed out that or passage of ethylbenzene
vapors in a mix-,ure with air only benzoic acid is formed. The
yield. at 270-26)0 C amounted to 0. The aim of the present
paper was an exict investigation cf the fundamental rules
governing this reaction, special Ettention in the oxidation be-
ing paid to the intermediate and final producta. Some of the
intermediate prDducts were oxidiZEd under equal conditions.
The obtained ex erlmental results show that the vapor-phase
oxidation of e lbenzene with a' lakes a very c mpl-cated
t
U
course arid according to the 1 0
Card 1/0 preva, ing conditions leads to

The Oxidation of Organic Compo~nds, XV. On the OAidation of 7 Q-1~ -28/" 3
Ethyl Benzene in the~Vapor-Phake State Over Tin Manadate.
the formation o' different oxygen-containing compounds. Thus
the authors bes.de benzoic acid also found benzaldehyde.
acetophenone, qiinone, maleic anlij-dride.. CO and C02 and quanti-
tativ.ely determned their amounts. The dependence of the
yield, of some o' the enumerated rEaction products on tempera-
ture is represeated in diagram,l. A scheme of the fundamental
direction of tha vapor-phase oxidtion of ethylbenzeyle o'~rer
till vanadate was suggested which is based on the data of the
peroxide theory and on the theory of the radical-chain pro-
cessd,s. The assimption was uttered that the oxidation of
ethyl,'benzene might simultaneously proceed in several parallel
diredtions, in nain as well as in side directions. Each of
those represents a multistage prodess of a gradual decomposit-
ion or the carbon skeleton, with L subsequent formation of a
larger number of by-products. The final stage of each of these
directions consists of the formation of products of the com-
pleto d oxidation. There are 5 figares and 12 referencee, 10
of which are Slavic.
ASSOCIATION: Insti tute for Chemical Sciences Kazakh SSR (Institut
Card 2/ khimicheskikh Iauk Akademii naulcI azakhskoy SSR),

u v-'q /t C) V
v
jai
-3
z IV
A
1-k i
8-
j jn V. 'aj
H - a t Nr
m, n V
84
-- I 'a *a 10
Is Z
';!%
A
ai!ls
A All Zo 4 s
i~-
All
.4 6 an's t4
A j
Tj
I I
:1
a zus 14- R I A, 1; -111 1 Hit.
v ni 2i lie I
'c
01:11111A
'd
xv A A
n s Ila v
J_
It 13,
A5 lag 13 as
ZV3

-17
. 0,
R~ IKOV, S.R.; SUVOROV, B.V.; KAGARLITSKIY, A.D.
Dehydrogena:l::,:,fOj":z7lamine on titanium vanadat,e under conditions
of oxidativ -I is. Izv,Al-I Kazakh. SR.Ser.khim. uo.1:77-79
'59. (MRA 13:6)
(Benzylamine) (Dghydrogenation) ~Titanium vanadate)

SUVOROV, B.V.;,nFIKOV, S.R.;
- --- - ----
Oxidation of organic
oxidation of P-cymene
no.1:80-84 '59-
(Gymene)
, M.I.
ompounds. Report JUor3: Vapor phase catalytic
by humid air. Izv.A Kazakh.SSRiSer.khim.
(WRA 13:6)

Translation fromi Referativnyy hurnal, Khimiya, I
AUTHORS: Rafikov,;' S. R., 8 rov B. V.
uv~
TITLE- On the P!roblem of t e Mechanism of Inh
:)f t e Me,
6
by Moledular Oxygen.,
PERIODICAL: V sb.: i0kislenlye levodorodov v zhi
1959, p~. 94-100
TEXT: At the 6xidation o cyclohexene ( at 40
quinone, 0.05% phenoio, 0.05% n aminc-phenol, 0.0255
aniline, 0.05% diphenyl amine, dded at the beginni
to an.induction period of 5-7 h urs duration; add,
reaction process dec6lerate the process when 2-leo
ed in the system. At -the oxida ion of C6H 5C2115 (at
hydroquinone, the-latter is.,-con~erted into quinone
At 50-180'c$ 02 doesinot oxidiz essentially hydroq
H2SO4 (0 -05, ) strongly inhibitsithe, oxidation of i-
87670
s/`081/6Q,/0OO/O2l/Oo3/O18
AOO5/AOOI
No.21,.p. 47, T'r 83966
tor Action on the Oxidation
faze. Moscow, AN SSSR,
E_' additions of 0.1% hydre-
phnylene diamine, 0.6% -
of-the process, give rise
ions introduced during the
drogen peroxide are accumulatr
0
~50 C) in the presence of
uring~the induction period.
inone, phen6l, and pyrogallol.
ropylbenzene and benzaldehyde,
Card 112

87670
S/081/60/000/021/003/Oi8
A005/A00l
On the Problem of the-Meahanism..ot Inhibitor Action, on -the Oxidation by Molecular
Oxygen
in the-authorsl.opirLion, in conse uence.of the.format-en of phenol at the inter-
action of H2SO4 with the hydrogen peroxide of i-propy benzene. The,action mechan-
ism,of inhibitors of different ch mical nature is disiu8sed.
R. Milyutinskaya
Translator's note: This is the n 11 translation of tle briginal Russian abstract.
Card 2/2

MANUKOVSKAYA, L.G.; RAFIKUV, q.R.; bUVWLOV, B.V.
Oxidation of organic
catalytic oxidation
tive.a by molecular o
62-67 '59.
ompounde. Report Nc
n-toluic acid and a
gen. Izv.AN Kazakh.
(Toluic 4cid) (Oxidat
wajz~%
-- -__I
21: Liquid-phase
~e of its deriva- '
R-Ser.khim. no.2:
(MIRL 12:8)

5(1,3) SOV/153-2-4-27/32
AUTHORS: Raf--;'r,-ov, S. R., Kh-ura, 1-1. 1., Kudinova, V. S.,
Kostromin, A. S
I
TITLE: Direct S,,.nthesi of Dinitriles of the Aromatic Sequence From
Dialkyl Benzene and Terijene Hydr carbons
PERIODICAL: Izvestiya vyssh~kh achebnykh zaveqeniy. Khimiya i khimicheskaya
tekhnologiya, 1059, Vol 2, Nr 4, j1p 614 - 618 (USSR)
ABSTRACT: Aromatic dinitrliles are promising1raw materials for the produc-
tion of phth 1': acids and di :m!;J7 of the aliphatic-aroma tic
and a licyclIc equence. Thes n are the initial products
for the p 0du c *on of polye:t s ~nd polyamides (Ref 1). The
v 11 ly
latter, howe e , can be dir Zr ttained from dinitriles by
their interactfon with secondary nd tertiary highly molecular
s f
alcohol (Re Hence the gr eat interest in the new ways of
di
producing .ni rilee of vari ous s~ra:tures. After giving a sur-
vey of publioapthons (Refs 3,4) t - t hors state that they have
been dealing the catalytic 0
+monolysis of organic compound
for years (~ef~ 5-7). With rega d to their task of synthesizi
dinitriles th4 pay special atte tion to the ammonolysis of
Card 1/ 3 dialkyl benzenps especially in t~e presence of air. The apparat~

Direct Synthesis of Dinitrile~ of the Aromatic Sequence SOV/133-2-4-27/32
e
-From Dialkyl Benzenes an ler, ne Hydrocarbons
used for this pa pose is filled with a granulated catalyst.
Mixed catalysts f oxides of vanadiam, tin, titanium, and some
other elements w th varying valence proved to be most effective.
p-Xylene is the ost accessible and promising raw material in
the synthesis of dinitrile of terepithalic acid. Hence its
transformations ere investigated m)st thoroughly. Figure 1
shows the qualit tive composition arid the quantitative condi-
tions of the rea tion products of a characteristic experimental
series. Hence it appear8 that oxida;ive ammonolysis yields a
very complicated scale of substance;. The main prc.-lacts, how-
ever, are the dNitrile and p-tolunitrile required. The compo-
sition of the realction products greltly depends on the reaction
conditions. The process can be dire,ted to the special fOrMa-
tion of any prod ct by the choice (f the respective reaction
products The t ture of the ini'k:al product is also of im-
portance: In asdditLCion to p-xylene, (ther p-dialkyl benzenes as
well as hydroaromttic and terpene h,,drocarbons underwent the
reaction mentioneid. All of them yie ded terephthalic-acid
dinitrile, and mal thus be consider,d a source of reserve raw
Card 2/3 materials . Dinitrrile's of isophthali and o-phthalic acid are

Direct Synthesis of Dinitrilc-3 of the Aromatic Jequence
From-Dialkyl B(~nzenes and Terpene Hydrocarbons
very interesting. In addition to x~lylene
production of hi,yh-aieltin~, fiber-forming
U
valuable compoun Is can be obtained;
cyanine dyes (Rer 9), for refractoiy
Their yield excepded 50'~O. Thi- a.,,,imorolysis
take place -nitho4t oxy,~,en (Ref 3),tut
rev.,ains small (5~105,,) (Fig 2). Aroratic
react readily with ammonia under similar
nitr0e yields c ose to theorctical
0
!1.1i -, abovt_ )a ) or :.,,.a griveri at. the Al
~;trntiesd;s oCIc_itLl Iuctsfo-.-the Prodaction
from SC-PtEaber
There are 2 figu es and 11 referenc~es,
ASSOCIATION: Institut khialic4skikh nauk AN Kaz
Sciences of the jAcademy of Scienc
SOV/153-2-4-27/32
diaLuines (fox the
- other
polyamides),
orthoisomer (for phthalo-
varnishes and glasses).
i:ientioned can also
-the yield of dinitriles
aldehydes and acids
conditions and give
ones (Ref lo). 1, report on
1-Union Conf erence on "Ways of
of High Polymers" -,.1hich
29 to October 2, 1958.
8 of which are Soviet.
(Institute of Chemical
Kazakh SSR)
Card 3/3

SOV/79-29-1-34/74
A.UTHORS: Kagarlitskiy, A. D., Suvoroll, B.1V. Rafikov, S. R.
'et phenone it h
,#TITLE: On the Reacti n of Acetophenone ith Gaseous Ammonia Over
, 7e aimo
tsii v
Titanium Vana ate (0 reaktsii v aimodeystviya atsetofenona s
na n ate
ammiakom v ga ovoy faze na vana ate titana)
PERIODICAL: Zhur ey khimii, 1959, o1 29, Nr 1, PP 157-158 (USSR)
.i 95 9 1 2
ABSTRACT: On the baaisio:e the synthesis tT thl trimethyl pyridine from
acetone and Immonia accord ng Ch chibabin (Ref 1) it couldl
be expected 1hat in the ammo:ol,Sl s of acetophenone a 2,4,6-.
triphenyl py4idine were form d. it was the objective of the
present pape, to Drove that th r:a:htion can really take
place Molte t itanium vanadat!~'a osen as a catalyst
which as pr~_i ously establisheld (Ref 7), has no bad de-
hydrating qu lities. Already t ~e first ammonolysis experiment
of ace ph have shown tha in t his case really 2,4,6-tri
phenylt;yrTndpnn: results as thelmainproduct. This was obtaine
under op!imu conditions at 37VY80' in a 35% yield, referred
to the t ans itted, and in a 9 eld referred to the aceto
phenone reacted which may easi y be seen from the diagram. At
Card 1/2 4000 and mode the yield,decrea ed as crack reactions took p1 oe

SOV/79-29-1-34/74
On the Reaction of Acetophe one With Gas~ .eous Ammonia Over Titanium Vanadate
r~r'o
under the for ation of low-mole(ular products. In the ex-
periments per ormed below,'3500 1he resinous products were
separated on he surface bf the catalyst, whereby its aotivi
was reduced. It was howev'er posEible to restore its activity
0
in the air current at 400 . The catalyst was made by melting
titanium dioxLde with vanadium jentoxide according to the
formula Ti(VO 04 . There are 1 figure and 9 references, 5 of
which are Sovtet.
ASSOCIATION: Institut khimtcheskikh nauk Akajemii nauk Kazakhskoy SSR
(Institute oflChemical Sciences f the Academy of Sciences,
Kazakhskaya S$R)
SUBMITTED: November 22, 1957
Card 2/2

SOV/79-29-1-35/74
'AUTHORS: Manukovskaya, G., Suvorov, B. V., Rafikov, S. R.
TITLE: Oxidation of 0 ganic Gompounds (,kisleniye organicheskikh
soytadineniy) X X. On the Gatalyt c Oxidation of p-Xylene With
Molecular Oxyg n in the Liquid,P ase (XIX. 0 zhiakofaznom
katalitichesko okislenii p-ksil la molekulyarnym kislorodom)
PERIODICAL: Zhurnal. ubshcf~ey khimii, 1959, V~l 29, Nr 1, PP 158-165 (USSR)
A-BSTRACT: The oxidationlof the alkyl benze#es with molecular oxygen is
one of the mo t comfortable synt es.s of noble'oxygen-contain-
ing a . lompounds. At p;aineft. ;adetophenone Iand methyl-
phenyl,- carbi~lol- are thus 0b J,_,from ethyl benzene (Ref 1),
as well as th~ hydrogen peroxidel,of cumene from cumene (Ref`~)
the p-tertiary, butylbenzoie aci.d1from p-tertiary butyl. toluene
(Ref 3),- ete,iIn the last!years many s imilar methods of
synthesizing-the terephthalie,aeLd from p-xyleue. were dev1sed
fram. amo-pg,. wh4iqh.that having~ fo=?.,stages, (Ref 4) proveE to' be
the cheapesto.!Although many scientists investigated the
Ion in...ihe liqui I phase (Refs 5-8) and de~~
satalytic oxidat.
scribed the t ichnological scheme of the process in publication
Card 1/3 (Ref 4), some1questions regard-InK the reacti-on mechanism re-

SOV/79-29-1-35/74
Oxidation of Organic Compoun S. XIX* On the Cat lytic Oxidation of p-Xylene
'Nith Molecular Oxygen in. thelLiquid Phase
mained unsolvdd2 e. g, tha I '~e nature of the catalytic
I
on, on th' dependence t 0%e re acticn ra-e and the yield
acti. Of
of ox -Lous tions as well as the
ida.tion-~roducts on va~ Iccncentra
question of tl~e nature and succe~s~zjf the transformation
of the p-xyle~e itself based on xi a ion, etc. The solution
of some of th1se problems was th purpose of this paper. It
was establish d that the oxidati n of p-xylene without catalys
proceeds very slowlyg wherein a so the aromatic acids are
s
y
formed in neg igible quantities only. In the presence of
0
g
cobalt acetat below 13001the o 3'dation proceeds at a very low
t
rate as well. For this rea son, 11 following experiments with
the catalyst ere carried, 0u, t a 133-1350. Thus, the oxidatio
lys
of p-Xylene i n molecular oxyg(n in the presence of cobalt
acetate in ti e liquid phase .-tar, investigated, -o-toluic and
terephthalic acid-resultin'tr as he main products. In figure I
the results f two experimental z)er-les with 0.1 and 1% cobalt
acetate arep esEnted in order to determine t1he influence
e dd
exerted by t e duration of the xperiment upon the oxidation f
p-xylene. Fi re 3 illustrates ~.he dependence of the yield of
Card 2/3 the ii ation products of -xylene on. the concentration

SOV/79-29-1-35/74
Cxidation of Organic Compouilds. XIX. On the-Catalytic Oxidation of D-Y-yiene
With Molecular Oxygen in the Liquid Phase
of the catalyst. There are 5 firrures,'l table, and 21 ref-
erences, 14 of which are Soviet.
ASSOCIATION: Institut 1zhimicheskikh nauk Akademii nauk Kazakhskoy SSR
(Institute of Chemical Sciences of the Academy of Sciences
Kazakhskaya, :;SR)
SUBMITTED: December 11, 1957
3

SOV/80-32-2-27/56
AUTHORS:
TITLE:
PERIODICAL:
ABSTRACT:
ASSOCIATION:
SUBMITTED:
Kagarlitskiy, ~.D., SuvoroY, B.V.1, Rafikov, S.R.
Ammonolysis of Benzaldehyde on M xed Oxide Catalysts
(Aimmonoliz ben~alldegida ~ lannykh okisnykh katalizat
Zhurnal priklalnqrkbimii, 10,59, N
pp 388-391 (US)R)
During the int3raction of benzald
presence of ti;anium vanadate and
formed with an output of 67 -
small amounts y a side reaction.
the hydration of benzaldehyde to
There is 1 graph and 11 reference
6 American, 2 j1nglish, -'and 1 Gerip
Institut khimicheskikh nauk Akade
Chemical Scien es of the Academy
June 12, 1957
1 XXXII, Nr 2,
hyde with ammonia in the
tin vanadate benzonitrile is
Lophine is produced in
Another side reaction is
oluene.
, 2 of which are Soviet,
n.
ii nauk KazSSR (Institute of
f Sciences of the Kazakh SSR
Card 1/1

5 (3)
AUTHORS: Rafikov, S.R , Suvorov B. V.2 -SOV/20-126-6-39/67
Zhubanov, B. A., Khmura, M. I.$
Pro.koflyeva, M. V.
TITLE: Synthesis of Nicotinic AC:id and Its Amides by Way of Nicotino.
-nitrile (Sir tez nikotino'voy kii loty i yeye amida cherez
nikotinonitrJ l)
PERIODICAL: Doklady Akad( mii nauk SSSR, 195) , Vol 126, Nr 6, pp 1286 -1281
(USSR)
ABSTRACT: In spite of a n increasing deman( of the substances mentioned
in the title (Refs 1,2) the metl ods of production applied, gi- e
only low yiel ds (Refs 3-5). The authors produced these two suli -
stances by sa ponification of nic otinic acid nitrile which is
formed in hie h yields in~an oxi( ative
ammonolysis of the P-pic -
oline on vana dium catalysts (Re, s 6,7 - P-picoline was isolat(
) a
from the corr esponding in~dustri lly produced fraction. The mer, -
tioned ammono lysis was carried c ut in a continuous flow appars -
tus. Granulat ed tin-vanadate se3 ved as catalyst, air was used
as oxidizer. Ammonia was~introdt ced into the reaction zone in
the form of a 20~ aqueous soluti on. The duration of contact wa s.
Card 1/3 0.2 - 0.6 sec . Nicotino nitrile and the P-picoline which was

Synthesis of Nicotinic Aci and Its Anddes by Way SOV/20-126-6-39/67
of Nicotino-nitrile
not reacted ere extracted by s lphuric ether, the extract wa
dried asted sodium oulph te and fractionated. In the
over r su p
saponificati n by means of wat under pressure (with some
drops of wat r - ammonia.) nico inic acid amide (melting point
f-
c
12q!-713Z0O)T nicotinic acid ( 32-2340) were formed. Their yi,
depends on t e reaction P Ondit Ono of saponification. By chan
ing these co ditions either th acid or the amide may be obta.n-
ed with quan itative yields. T e duration of contact is withoLt
importance i the temperature ange investigated for the P-pi!-
oline ammono ysis. Figui e I oh wo that if the reaction temper
ture is inor ased from 310 to 700 the nicotino-nitrile yield
is increased. A further:Umper ture increase up to 4000 reduc
this yield. In this connection the C02 formation increases ri
idly. It may therefore ~e assu ed that at temperatures )370'
reactions of an intensive oxidation take place besides the o3
.dative ammorolyRis of P-picolize. Since the maximum yield of
nicotino-nitrile (65% of the theoretically computed yield) W
the minimum C02 formation were attained in the case of a 20-
Card 2/3 fold ammoni excess the'processes of intensive oxidation are

Synthesis of Nicotinic Acid and Its Amides by SOV/20-126-6-39/67
of Nicotino-nitrile
ASSOCIATION:
PRESENTED:
SUBMITTED:
(jammonia. Thus,
suppr;,,,:,,,d by th
high do ver 65~) of nicot
60%) wi:hgr
ag 0:1~ect to the initia
.short are not used.Sta
There are I f gure and 9 refere
Institut khim cheskikh nauk Akd
Chemical Scie~ces of theAcadem
October 20, 11958, by M. M. Shem~akinq
October 23, 11956
mentioned ammonolysis produce
ic acid or nicotinamide (over
product. Oxidizers which are
ard. apparatus is necessary.
es, 6 of which are Soviet.
ii nauk KazSSR (Institute of
of Sciences of the KazakhSSR)
Academician
Card 3/3

5-. J 6 /0
2J 0 0 (4.)

AUTHORSs Suvorov.9 B.V. 67274

nd Rafiko*, S.R.

OV/31~-60-1-~-6/20
TITLE: New Method tc
am
Synthesize,Diamin
n

T s and Dibasic Carboxylic

a

n
Acids for thE Production~of Hi
f
H Pollmer

'

0
P
1

PERIODICAL., Vestnik Akad~
k

sk
mii nauk Kazakhsko
h
0

S
SSR, 1960 '
Nr 1,
R
pp 44-50 A
ABSTRACT3 This is a st

n
l
s
dy - the 25th inst
d
r
t lment of the serialized

1

n
m
report on the "Oxidation of Org
of Org nic Compounds" - of
n
3-c
oxidizing amm nolysis reaction
tl_on f aromatic hydrocarbons..
f ar

e
In their expe
"I _h wer
iments, which wer carried out with the help
0ar
of M.I. Khmur V.S. Kudinova,
~nova9
A S
A.S. Kostromin, A.D,
Kaizarlitski-Y- B.A-.--Z =uanov an
ov an M.V. Prokoflyeva, the
M V

authors paid '1j
pecial attention
o the study of the

mechanism of 0 01 v
atalytic ammn
onoly j_s0
is of alkyl benzenes and
the effect of different factors on the yield of nitrileso'l
The reaction vas carried~out wit h an installation of the
flow-through ;ype with a metalli c reaction tube. of 1100 mm
in length and an inner.diameter of 21 mm. With the aid
Card 1/4 of dosing dev Lces hydrogarbon, a queous ammonia solution

67274
SOV/31-60.-lw6/20
New Method to Synthesize Dtines and Dibasic Carboxylic Acids for
the Production of High Poly ers I
and,,,in most cases, air were inlroduced into the upper
part of the reactor. The photograph gives the outer
aspect of the installation. The reaction tube was filled
with granulated catalyzer. During their experiments the
authors testei a great number ol different catalyzers.
The results siowed that cataly34B of the mixed type, pre-
pared on the oasis of oxides of vanadium, tin, titanium
and some other elements of chaneing valency, are most
efficient. Vie basic particulais of the reaction mechanism
of oxidizing immonolysis of aromatic hydrocarbons were
particularly iscertained in the experiments with monoalkyl
benzenes fRef 1g, which transform into benzonitrile with
a nearly theoretical yield. Dinitrile synthesis was
studied on su,,h objects as isomeric xylenes, p~cymene,
p-diethylene 3.nd p-diisopropyl benzene and also on the
example of terpene hydrocarbons _/Ref 17, 20, 217. For
Card 2/4 the synthesis of terephthalia d nitrile by means of

67274
SGV/3-1-60-1-6/20
New Method to Synthesize Dtamines and Dibasic Carboxylic Acids for
the Production of High Pol mere I
catalytic ammonolysis of hydrocELrbon the authors consider
p-xylene as the most easily obt:Linable and pTrispective
raw materiall Its transformation, therefore, under the
given conditions was an object Df a particularlyspecified
:5tudy. The authors investigatei within large limits the
effect of mu-ual correlation ani volumetric feeding rate
of the initLl materials, of th~ time of contact, reaction
temperature, catalyzers etc. Tae clata shows that as a
result of ox:dizing ammonolysis of p-xylene a very great
number of different substances vill be obtained. The
basic produc-s of the reaction, however, are terephthalic
dinitrile an p-tolunitrile. In the reaction products
terephthalic acid is always prepent in the form of an
ammonium salt. In experiments with comparatively 'Low
reaction temlerature the formation of p-toluamide and
terephthali-I diamide can be observed. Gaseous reaction
Card 3/4 products are carbon monoxide, h drogen cyanide, carbon

67276
SOV/31-60-1-6/20
New Method to Synthesize D:amines arid Dibasic Carboxylic Acids for
the Production of High Polymers
dioxide. Their yield increases with rising temperature
and may be ccrisiderable at 430-500 C. in addition to
p-xylene a number of other mateftals (other p-dialkyl
benzenes, sone hydroaromatic an( terpene hydrocarbons)
were subjected to oxidizing amm4nolysis. The reaction
was called so by the authors be ause the process of
nitrile formation develops undei the simultaneous action
of ammonia and oxygen on the in:tial substance. There
are 1 pho'tograph and 33 referen(es, 30 of which are
Soviet and 3.pnglish.
Card 4/4

5.3400
AUTHORS.
TITLE:
PERIODICAL:
ABSTRACTt
%.lard 1/12
I:)- f
T
SOV/80-33-1-36/4~
Rafikov, S. R., Suvorov, B. I., Makarevich, V. G.
The L qui - ase Oxidation o~- Cyclohexene With Mole-
cular Oxygen in the Presence of Inhibitors. Communi-
cation XXIV I
Zhurnal pricladnoy khimli, 1)60, Vol 33, Nr 1, pp 201-
209 (USSR)
Auto-oxidatLon of cyclohexena in the presence of phenol,
hydroquinon3, p-benzoquinone, quinhydrone, dimethyl
ether of hy1roquinone, p-, and o-aminophenols, p-phenyl-
enediamine, aniline, diphenylamine, ~nd dimethyl-
aniline was investigated. It was established that all
the above c)mpounds except dLmethyl ether of hydro-
quinone are inhibitors of thD reaction. Antioxidizing
properties )f the investigat?d compounds depend on
their compo3ition and on-the structure, The degree of
activity is as follows: phenol < hydroquinone < amino-
phenol < plienylenediamine _> aniline. Dimethylaniline
and dipheny~amine occupy a pLace between aniline and

The Liqui-d-Phase Oxidation'of Cyclohexene
With Molecular Oxygen in the Presence of
Inhibitors. Conununlcation'XXIV
P-Phenylenediamine. The tot
depends not'~only on the indi
but also on'its concentratio
inhibitors are capable of re
of cyclohexene. The inhibit
having phenolic character is
of a mobile.hydrogen atom of
aromatic amine3, not only th
amino group take part in the
the unshared electron pair o
oxidation are given below in
in all figure3 A = yield of
Rn %); B = time (in hr); 1
-752-(
SOV/80-33-i-36/49
I antioxidizing effect
idual activity of inhibitor
Most of the above
cting with hydroperoxide
ng action of compounds.
connected with the presence
the hydroxyl group. In
hydrogen atoms of the
process, but also, possibly
nitrogen. The results Qf
the following figuresi
the mentioned products
without inhibitor).
Card 2/12

The Liquid-Phase Oxidation of Cyclohexene
T,,Iith Molecular Ox,,,,rgen in the Fresence of
Inhibitors. Communication XXIV
527
SOVI/80-33-1-36/49
Fig. 1. Oxiqation of cyclohe.;-ene (I) in the presence
of phenol. Amounts are given in % of the corresponding
inhibitors.12 = 0.02, 3'~'= O-C5; 4 = 0.1, 5 = 0.2;
Card 3/12 6 = 0.25; 71 =0.5; 8 = 5.0, S = 10-0.

The Liquid-Phatic, OxicWt,.Lon
h~C C~,rclohexene
t pr
-11th Molecular Oxyf,,,en in t esellc,-e of, OV/80-33-1-36/49
Inhibit'"oru. CommunIcation .1
v IA
Fig. 2. Oxi
2 0.05; 3
Card 4/12 5.0; 8
J
e-
4 -
0 4
tion of T in tr
0.1; It = 0.25;
10.0.
presence of hydroquinone:
0.5; 6 = 1.0;

.
The Liclutd-Pir:- 0'-' k 1 u I i
With M01E!cular O;cyf-.-;-,r, irl
Inhibitor'.3. CON-CAU1~1LOP ti,onl
of ct; c. 1 k21 I t::4.1
~
3-1-3
0149
kdv ~F
M
Fig. 3. Oxl~
quinhydrone:
Card 5/12 quinhydrone.
C, 4 8
ion of -1 In the.p_v-sence of quinone and
0.1; 3,= 0-22; 11 = 1.0; 5 = 0.1, of

-2'(, "0'.1 ~'-' ' 33 ' 'S /49
/00-3 -J---)c/
17
Fig. 4. Oxidation of I in tht, pre3ence of anilinez
Card 6/12 0 - 1; 3 0. 2; 4 0. 3; 5 0- 6.

A
-_~27, S011/80-33-1-36/49
Fig. 5. Oxidation of I in the presence of p-phenylene-
-1= 5
dicai'mine: 2 = 0.001; -" 0 00 4 = 0.05; 5 = 0.2c:;
Card 7/.1'e? 6 = 0 .5; 7 = 15 - 0; 8= io.o.

"(1-27, SSOV/8'--33-1-36
4
Fig. 6. Oxidation of I in the presence of p- and o-
aminophenols: 2 0.001' 3 = (.005, and 4 = 0.025 for
p-aminophenol; 5 0.005 and 0.025 for o-aminophen-
Card 8/12 0l.

t )" C, (Y ~ '%') - /,49
S
fl
F i g- 'T. Oxidation of i in th presence of dimethyl
ether of 4ydroquinone - 2 = 0 1; 3 = 0.5; 4 = 11.0;
Card 9/12 1
5 = 5.0. 1

4 -------
SUV/ -1 - 19
4 J
Fig. 8. Oxi(lation of I in th, presence of diphenyla-
mine: 2 = 01001; 3 = 0.01; 41= 0.05; 5 = o.1; 6 = 1.o
Card 1.0/12

V-
0 -3 3 - I - 3 15/4 9
9. Oxi( ation of I in thl presence of dimethylani-
Card 11/12 line: 2 = 0ll~ 3 = 0,2; 4 = ( , ; ~ = i.0; 6 = 5.0.
0 ,

7 75 2
SUVA 0 - 3 31 -1 --3)('W4 9
There are c.) figures; 1 table; and 2'-.') references, 12
Soviet, 3 aerman, 6 U.S., 2 UK. The 5 most re:~ent
rl.~Cevences aro~ R. If. Rogenwald, Ind.
Eng. ~' 'hil -L62 (191JO); G. 3. Barruiond, J. Am. Chem.
Soc. '77, 32 (1955), C. E. 3oozer, et al., J. Am.
Chem. Soc., 3233 (1955)~- ' J. Peder3en Ind. Eng.
ch., 48, 188. 4956); L. F. F eser, A. E. Oxford, J,.
A.m. Chern. So,,.' 64, 206o (194-h.
SUBMITTE'D;
May 25, 1959
Card 12/12

KAGARLITSKIY, A.D.; SUVORCV, B.V.; RAFIKOV,, S.R,
Oxidation of organic compounds. Report N6.25: Oxidative
ammonolysis of some inonoalkylbenzenes. Trudy Inst.khim.nauk
All Key-akh.SSR 7:57-67 161. (14IRA 15:8)
(Benzene) (A-m nolysi

S/85o/62/008/000/003/004
AUTEORS: Suvorov, B. V., Rafikov, S.B., Kag-arlitskiy, A. D.,
Sa irova, A. A., Svetasheval V. A,
TITLE: Oxidation of organic compounds. Communication XXXIII.
Oxidizine ammonolysis of n- and m-xylene mixtures
SOURCE: Akademiya nauk !Kazakhskoy SSR. Jnstitut khimicheskikh
nauk. Trudy. iV. 8. Alma-Ata, 1~62. Kataliticheskiy
sintez monomero . 109-114
TEXT: The synthesis of terep hthalic dinitrile (I) and isophthalic
dinitrile (II) was investigated by reaction of Eixtures of D- and
,m-xylene of various molar ratios in amounts Q1 0-70 g with 120-175 g of
N'H31350-500 g of H20, and 2400-4800 liters of ir Der hour and per liter
of catalyst, with contact times of C.2 - 0-5 se , at 350-4100C. I.Mo1ten ___1
lead vanadate served as catal st. The contents1of I and II ir the
reaction Droduct were determined by polarograpn4 - Results: The yields
of I and II were only slightly affected by a c1a nge in the con'ac' time
and in*the rate of adding the reaction mixture.T When the react6ion
%.lard 1/2

/000/003/0 04'
... S1 5yo-2/008
.-anic
Oxidation of orr, co=Dound B 9 101
temperature is raised thc; yie d of I + II,reaohEs a maximum between
0 ;---h. v
3'0 and 3900C, 41a, the iel of Caseous substances increases steadily.
The formation of I and II deppnds essentially or 'Uha molar ratio of. the
xylene isomers used: under o herwise equal reaction conditions, the
yields of I aere - 39, --,,3, ind -52- , w1h.ilst those of II were -35,
- 3, and over SCFI..~ respectivel r, at the ratios m~xylene ; p-xylene
= 4:1, 1:1, and lig (referring to the theolretic 1 maximum yield). There
are 5 figures.
Card 2/2

IIANUKOVSI,LkYA,- L. G~; SOLOI-I~ N, A. V.; SUVMV, 1. V.; ROFIKOV., S. R.
Continuous methcd of prod-action of -terepitha-lic acid by the
liquid phase oxidation of m-mylene. NeftEkhimia 2 no.4:531-535,
JI-A,g '62. (MIRA 15:10)
1. Yzzakhakiy gosudarstvenn-yy sellskokho2yaystvennyy institut
i Institut, khimicheskikh nauk AN KazSSR, Alma-Ata.
(Terepht] Lalic acid) (Xylem)

RAFIKOV, S.R.; SEMBAYEV, 1) ;,jqpVOROV, B.V.
Oxidation of org:c* compoun .ds. .--. Par
28: Oxidative ammonolysis
of acrolein. Zhu'r.ob.khim. 32 no. t839-841 Mr 162.
1. Institut khi~cheskikh naifk AN Ka akhskoy SSR. (MIRA 15:3)
1 (Acrolein) (icrylonitrile)

PROKOFIYEVAJ. M.V.; RAFIKOV, S.R.; SUVOROV, BJ-j
Interaction of aromatic acid nitriles u
of hydrogen chloride. Zhur.ob.khim. 3
1. Institut ~himicheskikh nauk AN Kazak
(Nitriles) (
th alcohols in the presence
no.4:1318-1323 Ap 162.
(MIRA 15:4)
skoy SSR.
lcohols)

ARKHIPOVA, I.A~; RAFIKOV, S.R.; SUVOROV,;B.V.
Production of nicotinic and isonicotinii
I
by the hydrolysis of nitriles. Zhur.pr:
393 F 162.
.1. Institut khimiche'skikh nauk AN MzSSI
(Nicotinic a4d) (Isonicotin:
acids and their amides
1-khim. 35 m.2:389-
WIRA 15:2)
acid) (Nitriles)

KOINOVA, V.S.; RP.FIKGV, S.R.; SAGINTAYEV,A, K.D. SUVOROV, Bev.
Role of water vapors in the reactions of the vapor-phase
cataly-tic oxidation Df aromatic dompoundi. Zhur.prikl.khim.
35 no.lOz2313-23113 Oi'62. (MIRA 15:12)
1. Institut khimicheakikh nat*:AN Kazakh4koy SSR.
(Aromatic colopounds) ~Oxida:ti~n)- (WAter vapor)

~i ~. ~z--,%,J ;! --v kawm
.SU.VOROV,___0.y,.;, RAFIKOV, S.R. KAGARLITSKIY9 A.D. SAJIROVA, A.A.;
SVETAScHEVA, V.A.
Oxidation or organielcompounds. Report
ammonolysis of a mix ure or p- and m-x
nauk AN la2;akh.SSR 8 109-114 162.
(Xylene~il (Ammonolysis)
.33s (bcidative
aes. Trudy Inst.khim.
(MA 15:12)
(Oxidation)

Uk7i
XUDINOVA, V.S.; SUVOROVO B.Vj.; UMAROVA, R.U.
Oxidation of org :1, compounds. Report
tion On
phase oxida r propylbenzene, n-b
or their derivativefi, Trudy Inst,khJxf.:
162 162.
(Benzene) (Oxidat
.341 Catalytic va 4r
lbenzene,, and so 4 ':'
k AN Kazakh.SSIk 8:1157-
(KIRk 15:12)

IZELISCNI Ya.Z.; RAFIKOV, S
Nidation of organi
vinad.1117.1 Dentoxilt-i,
no.10-1~1.-, 163.
.,,.S7VOR.O.V, B.V.
compounds. Report
Izv.AN Kazakh. son.
o.34: Dissociation of
khim.nai&
(MIRA 170)

S/)79/63/033/002/007/009
D2010307
AUTHORSj Arkh1pova, I*A., Rafiko-, S#R, and Suvorovp B. V
TITLE: Hydrolysis of terephthaLodinitrile with aqueous
annoria, under pressure
PERIODICALt Zhurnal obshchey khimii, v. 33, no. 2, 1963,
637 641
TEXT: The above reaction was 3tudied to determine the
possibility of selectively preparing the d.-aired.intermediate products*
Terephthalodinitrile(TIN), prepared by th.- oxidative ammonolyeie of
p-xylene of Pb vanadate, was reacted ith Llueous ammonia (taken.in
Various TDNs ammonia:water molar ratios, i at 200-3000C, in a stain-
less steel autoclave under pressures from to 40atm., over 3 hours. A
For n - 1:14W09 the yields of the~diammoiium salt of terephthalic
acid M inoreased fko'm - 30 ~6 at 2000C t) - 100 % at 300000 whilst
the yields of NR COOC CONH (11): f ell f -0m -J 50 % at 2000C to Irv 10%
4' A 2,
at 2500C. At 20000, witY, TDNtH20 - 1:210,,~ncreasing the molar ratio
of NH3sTDN to >6 favored the formation of and II, whilat 30-40 % 0
Card 1A

S/079/63/()33/002/007/009
Hydrolysis of terephthalodinitrile..'~.. D204/D307
each of NH COC iN and IM COC H4qowl vas formed at WH ME 1-2,
2 04C 2 6 2 3
A small amount of ammonium p-cyanobenzoate was aleo'formed with low
concentrations of M A; 2500C, increased concentrations of water.
3'
promoted the rate of reaction and favored the formation of the final-
products of hydrolysis. During the formation of -1 CONH2 from CH9 A
the ammonia behaved only as a cataly'st; in the conversion of OONH
to COONH however, consi erably higher-concentrations of NH were
e
4 3,
required. There are 3 fi res.
AS:XCIATIOVs Inst tut khimich6skikh Uk Akademii nauk
t t
Kaz hakoy SSR, Instit te of Chemical
~
h
Scie coo of the Aoademy-of Soienoes of the
Kazalh SSR)
SUMUTTEDs makci 14, 1962
Card 2/2

,SUVOROV, B.V.;.RAF.IKOV, S.~.; ZHUBANOV, B.A.; STROMIN, A.S.; KUDINOVA, V.S.;
KAGARLITSKIY, A.Dj.; KHMURA, M.I. r
Catalytic synthes s of the dinitrile ~f terephthalic acid.
Zhur. prikl. khim,~ 36 no.8:1837-1847 ~g '63. (MIRA 16:11)

KAGARLITSKIYI A.D.; SINOROV, B.V.; RAFIKOV, S.R.; KOSTROMIN, A.S.
Catalytic synthesis of benzonitrile by neans of the oxidative
ammonolysis of aromatic compounds. Zhur. prikl. khim. 36
no.8:1848-1852 Ag 163. i (MIRA 16:11)

SFkIRAYEV , D. Kh.; SIJVOROV_,_ RAFIKOV, S.-R., ak demik
Oxidizing ammonolysis of methyl vinyl,ketone Dokl. AN SSSR 155
no. 4:868-871 Ap 164 . I (14MA 17:5)
1. lnstitut khimiclieskik4 nauk AN Kazakhskoy SSR. 2. AN Kazakhskoy
SSSR (for Rafikov). I r

'V. RA
FOLTMBETOVA, F.A. F 1KO V ,S i C, A F 'L.JI'S K 1 Y AD
BOGDANOV11'.1
Some results of reseaich on the syr4 thenis and tests of the growth
ikazin". Vest AN KIzakh. SsR. 20 no.7:3-10
promoting substance A
il 164. (MIRA 1?: 11)

I i --~v r 4-- ~-
SUVOROV
,_B,V,- RAMN, S.R.1 KAGARLITSKlY, A.D.
Oxidative a=onolysis of organic c
154.9 S '65.
. Usp. khim. 34 no.9:1526-
(MMA 18: 10)
1. Institut ktduLicheskikh nauk AN KazSSR

-ItI
vr,,O[Wfj
IfIL"l, (fo), K T-F sul~wlf,
th~ reaLong for FO,,ut-1,3.chf~et weldin d.ring
I.- vrit~CUv cOme _,,I
vW%vq Aro ali% aliced, As it
ir"Id,--d tilipt, to rmmmi-,~ weidiaz, th, danur
b.sirig ro)l,,d, flic, jJgr-,---r should F,~ the rp!) t*rnper4ture -anl
erflr~cr,
-9-~TM .1

t2l~~----- ----
!~.V,
Sull0foll) 11 -
Automatic diffracto eters for studying jingle crystals. (PBview).
Nauch. truey TashGU no.262 Fiz. nauki n .2202-102 164. (MIRA 18:5)

I
I
SOGRISHIN, Yu.P.; SUVOROV,
High-speed-ballio
1135 '63.
1. Fksperimentall
kuznechno-pressov
G.; KOBYAKOVSKIY, NI.F.
impact tester. Za . lab. 29 no.9:1134-
(MIRA 17:1)
nauchno-issledova~ellskiy institut
mashinostroyeniya.

/I
E;
L 1 5 d E Mk d /E LI /E4r P - (Q/113 - - (h /-VU /FWP (I Pf -4
(ki h),
_T77PSF_I7N NR: Jb 3000 4/066[605/0043/0057
A U1711011: -A
,~jiM!jsLitn,)Lq. 11% k H:Iatej o techn"Call scienc S); SuV (Engi -
sl~ruv
%-'-r, ; -ab - (E'ngineer
V~
TITI.E: Oetermination of the basic parar~cters -of machines fo hi velocity deformation
u, metals 19
S OU FIC E -Moscow. EksperimentalIrly*y h'au6hno~issledovatell kiy in-stitut kianechno-
voye-v kuznechho-~-~
pl'Ossovogo machinostroyeniya. Nauchn3i*ye trudy*, no. 8, 19 4. No
stitanipovochnom proizvodstve (Latest developments in for ing industry), 43-57
'11*01)IC TAGS: metal deformation, cold pressing, hot pressing ram velocity,: impact
elficiency
ect a e'
ABSTRACT: The paper discuSses the risults -of an inJestigati n of how to sel
a-machiAe for bir -,-velocitv-de wmation'of t
construction and parameters of h nietal.2-.j
special experimental instrument was designed with a dri d -by exploding
-nine thavLpe enc~e of the velocity of
powder charge. The machine was used ~o deteri .1
' investigate the stability o the ram velocity (im-
the ram on the gas pressure, and also t~ 'f
pact energy) for constant charging condi.tions and to'determinel the impact efficiency.
Advantages and shortcomings of theexp osion drive- ai&f t1fe efi eet-of hjgh~--velocity impact-__~~_.'.*'_~_-__`
on the durability of the instrument were examined. Cold and ot pressincr,was employed, -
1/2

166ah-65
ACCEISSION NII: AT4048351
and various alloys and steels were teste at deformation rates of 25, 5& and 100 ni/s'ec.-
simultaneous y
Ram velocities before impact and gas pressures were-~m asurPd
mn
recorded oil oscillograms. The special ;ethodq for in neasurements are
ot's crib(,d. A ram weighing ~ kg and quiltably suspended on ro s having a shear strength of
71'0, 1350 and 2600 kg, and ~runpowdcr cliarges weighing 3, 5 116, 8 and 10 grams were
wied. The experinitints; showed that tile velocity of tile rarn in(treases almost proportionally
111, 01 c gunpowder charVe. 'Illus, the rani velocities varied fL-orr, 90-30 m/sec to 100
TI f -impowder charge's; increL tile g~ p'ressure varied within the
o r sing from 3 to 10 g
m, ii )1 15- 180 atm. The impact efficiency was found to b~~: Within the intervai 0. 82-0. 98.
En". ji ,c i- V: NI. Stepanov, Engineer V. Ya. INIoroz and Technician 1. Ye. Beloya also
took j-,i-t in the work." Orig. art. il~~s: 5 figures, I table ar. 6 formulas.
ASSOC'! AITION- Ekspe rim ental I ny* y nauOhno-is sledov4tel I ski institut kuznechno-pressovogo
mashin4-.oroyeniya, Moscow (Experimental Scientific Ilese*arcInstitute of Fordng_
Alachit ez-0

L 11'i 9 va
5, U-65 Tr (m) /aIA (d .4 Tip
IP( C
=SD(_mY_-3 JD/FiV
ACCESSION NR: AT4048354 i S1300 /64/000!008/0130/0135
A-_
AUTHOR: Sogrishin, Yu. 12. (Candidate of technical sci nces); Suvorov, F. G..
(Enc:iineer); Koroz_'__V. Ya. (Engineer)
TITLE: High-velocity sheet metal stamping using rubber
SOURCE: Moscow. EksperimentalIny&V nauchno-issledovat4i'skiy institut kuznechno-
pre550VO-gO C_.aShInostroyeniya. Nauchny*ye trudy-.'z, no, 8, 1964. Novoye v kuznechno-
-i -v eLa t e--,t d ev Lopme rLt I ntfv_ginq i-ndu
shtampovochnom proizvods -130-435-'
-Ale
664 M- 4tu tnun'tLaUck
OL 'm
forging, stalMess steel forging 1
ABSTRACT: The auth-ors briefly lint, the advantages and di"-dvantages-of stamping
sheet-metal stock using rubber. They note that in thelmajority of cases the
rubber pads have to be shaped by hand. The resuits of an investigation carried out
In crder to assess the t(!shnologi(:al potentialities of hi h- d stamping of
sheet-metal blanks using rubber are then described. Alum! u . alloy and stainless
steel sheets were used. The rubber employed was In thi form of a disk 0-207 m in
jq diameter and 0.07 m in thickness. The velocities of diformation for forming opera-
tions were 15-20 m/sec and the energy of :mpact was about 5880 joules. In punching
operations, the velocities used were equal to B-10 and 15-20 m/sec; the impact
Card 1/3
0 V'~ ME

--------- -i-
:r, 3.5161-65
ACCESSION NR: AT4M354
energy was, on the average, 1420 iz-~,nd 5690 joules, respi,tively. The mechanical
properties of the rubber used in the experiments are t'abulated and photographs of
some stamped specimens are shown. The edges of the cOntour and of the punched
holes were smooth. The following formring operations ;here then investigated:
flanging, extrusion and extraction. The main purposepf these tests was to com-
pare the degree of folding, the accuracy of relief shaping, and the magnitudes
of the flanging and extrusion factors for various deformation velocities. The
features of high-speed stampinq using rubber are as follows., during impact, high
!.Pecific pressures are ceveloped b,iefly (they are greater the smaller the degree
of deformation for the same impact energy). Tne high value of the specific pres-
sires obtained decreases flanging, thus improving the relief and the accuracy of
P. stampiig. At the same time, the high impact velocities make it impossible to con-
centrate folds in separate places an the blank, leadiqg instead to the formation of
numerous shallow, uniformly distributed, foils. High,.velocity pressing using
r,
rubber makes it easier to shape the blank, to obtain higher borders and relatively
~n,
r
complex configuration of' detall as well as a high accL racy of the stamped parts.
In cutting operations, the high specific pressures obtained make it possible to
obtain small chamfering radii In the corners. The durability of the,rubber disk
was found to be satisfactory. The increased velocity of deformation using rubber
makes it possible to widen the technological potentialities of stamping operations.;
rig. art. has: 3 figures and 3 tables.
01
0
'Card. 2/3

wag
L 15161-65
ACCE6SSION NR: AT4048354
ASSOCIATION: Eksperimentalinle-y hauchno- I ss I ed o4atel #Fkly I nst I tut:,kuz,nechno-.
pressovoga mashinostroyenlya, Moscow (Experimental tific- Research Institute
of Forging Machinery) - -----

AR Sh.; GILUOVSKIT, V.A.; IVASKOV, Abp.*o
AT,A INSXIY, P.I.; , ONSKIHD,,~S
OV, LV., redaktorg. BASWOT9 T.Acg
SHMANE
redaktor-, S YIVA, A., redaktor; MANI U. M.P., teklmichaskly
redaktor
[Results of th organ sation and w;:k ore-dressing laboratory)
,at:,, , O:fi
1
Opyt organij r~boty obogati 1 0 laboratorit. Trudy lab.
geol.upr. no.3:3-57 9 22. [Kicrofilal (HLRA 7:11)
(ore dressing)

"l-le'uh.od's and Rati-na 1, 0',~eaa-c of Concentr--i in - i'Lan, -~anese Ores
rrcra Jort"em "mi Tech "ferl-Ilovsk 'dninc.
inst V. 74. Vakhrusr-v, i~-in lli~er Sverdlovsk,
(1'L, -Ao 10, ,'~-r
SO: su:-l. ',o. '070,29 Seri 55-survey of Scientilfic nal Technical
Dissertations Defenj!~,d al '.13,31, Hi.,Iher alucat#,nal Institutions (15)