SCIENTIFIC ABSTRACT TRETYAKOV, YE.F. - TRETYAKOV, YU.D.

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SCIENTIFIC ABSTRACT
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VISHMSKIY, M.Ye.; LYUBIMOV, V.A.;,_TRITIYAKOV, Ye.F.; GRISHU, G.I. Investigation of polarization of internal conversion electrons follovine A-deca7 of heavy elemeats. Zhur.ekzp.i teor.fiz- 3b no-5:1424-1429 My 6o. (MIRA 1~--7) (Electrons) (Beta rays) 83~76 AUTHORS: S/056/60/038/005/009/050 B006JBO70 Viahnevskiy, M. Yo., Lnbimov, V. A., Tretlyakov je. F., Qrishuk. 0, 1. TITLE: Investigation of the Polarization of Internal Converslon Electrons Following the 0 -Deca of Heavy Elements PERIODICAL: Zhurnal okeperimentalinoy i teoreticheskoy fiziki, 1960, Vol. 38, No. 5, PP. 1424-1429 TEXT: The polarization of internal conversion electrons in transitions following P decays was predicted by A. I. Alikhanov and V. A. Lyubimov, and experimentally discovered by Lyubimov and Vishnevskiy. The theory of this effect was developed by V. B. Berestetskiy, A. P. Rudik, and B. V. Geshkenbeyn. The results of the present work were communicated to the International Conference on the Physics of High Energies (KiYev, July 1959~ The authors investigated the polarization of.gonversion electrons :L'or tran- sitions following the P_ decay of Tm170, Rel , Hg203, and Pa.233. The apparatus they used is schematically shown in Fig. 1. The arrangement and the method of the experiments are briefly discussed in the introduction. Card 1/3 83576 Investigation of the Polarizption of Internal 3/056/60/038/005/009/050 Conversion Eloctrons Pollowing the 13--Decay B006/BO70 of Heavy Elemontg The results are individually discusued for the various isotopes. The con- version electrons were found to be polarized in the direction of the emit- ted P-partiolve for Tm170 and Re186, and in the opposite direction for 203 233 Eg and Pa . The results obtained are compared in part with those of ather authors. Tm170: 2q - 0.1.9 � 0.03, and with a correction for the finite thickness of the scatterer according to Alikhanov, Lyubimov, and G. P. Yeliseyev: (2S)o=0.22+0.03. The polarization of the conversion elec- trons yiel ded e. O-partiales recorded being 0.18. The resultu are compared with the theory of Geehken*beynp which give' - (-0.048 � 0. 14) v*/c for an average value 235 v/c - 0.56. For the possible spin values in the ground state of Pa the theoretical results Card 2/3 I TRETIURV, To.?.; XONDHAT'7EV, L.H.; raLONIKOV, G.I.; GOLIDIN. L.L. S,pectrum of internal conversion electrons accompanying the CO-decay of Pu238 and pn240. Zhur.eksp. i teor.fiz. 36 no.2: 362-366 F t5q. (MXU 12:4) (Ilectrons-Spectra) (Plutonium--Decay) 21(7) AUTHORS; re t I yalcov. ID-,- F. 1, SOV156-36-2-3/63 Kondratlyevo L. N., Khlebnikov, G. I., Golldin, L. L. -TITLE: The Spectrum of Internal Conversion Electrons Accompanying OC-Decay of Pu 238 and Pu 240 (Spektr elektronov vnutrenney konversii.soprovozlidayushchikh Ot-raspad Pu 238 1 Pu 240) PERIODICAL; Zhurnal eksperimentallnoy i teoreticheskoy fiziki, 1959, Vol 36, Nr 2, Pp 362-366 (USSR) ABSTRACT: The investigation of the decay of even-even nonspherical nuclei and of the energy of excited levels, especially the cbL.-decay of Pu 238 and Pu 240, is of very great theoretical'importance. Investigation of the cK-decay of these nuclei and ofthe levels of doughter nuclei occurring in this decay is carried out either by the cx-spnctrometry method, by that of r-jl- coincidence, or, as in the present paper, by the analysis of the conversion electron spectrum accompanying this decay. Measurements were carried cut by meant; of a -apectrometer with toroidal magnetic field and a-e-coincidence circuit, The method has already been Card 1/3 described (Refs 1, 2). Scintillation counters with stilbene The Spectrum of Internal Conversion Electrons SOV156-36-2-3163 Accompanying M-Decay of Pu 238 and Pu 240 crystals were used for #-counting. Electron energy was determined by comparison with the conversion electron energy the transitions 2+-*0+ (43-5 kev) and 4+4 2+ (99.8 kev*) in U 234 the daughter nucleus of Pu 238. (These exact data were obtained by Perlman (Perelman)(Ref 3)~ For the investigation of the 238 conversion electron spectrum occurring in the o(-decay of Pu which therefore supplies data concerning the level of U 234 ' a source with I cm diameter and an intensity of 40,9C was used. The results obtained by the investigation are shown by figure 1 (course of the spectrum with assignation of individual peaks), figure 2 (scheme of U 234_levels: 499 'kev(8+), 295.9 kev(6+), 143-3 ke-V(4+), 43.5 kev(2+), containing data from references 3 and 4), and by table 1 (energy of U 234_levels and intensity of oc-lines of Pu236, containing data from references 3, 4, 5)0 Card 2/3 For the investigation of the conversion spectrum of Pu 240 The SpecttuaL,,of-jnternal Conversion Electrons BOV/56-36-2-3/63 Accompanying CC-Decay of Pu 238 and Pu 240 a source of only 5,9 C was used, and the spectrum was investigated within the range of 20 -220 kev. Figure 3 again shows the spectrum, figure 4 the level scheme of U 236 (daughter nucleus of PU 240 ): 309 kev (6+), 239 kev (3?)0 210 kev (1?), 148.9 kev (4+), 45.3 kev (2+). The lines with (?) are from reference 5, but were also observed by Kondratlyev et al.(Raf 6). Table 2 shows the intensities of the oe--linen (Pu 240 ) and the energies of the U236_ levels in comparison with the results obtained by other authors (Refs 3# 6, 7). The authors finally thank G. I. Grishuk, V. P. Konyayev and Yu. N. Chernov for helping to carry out experiments. There are 4 figures, 2 tables, and 7 references, 5'of which are Soviet. SUBMITTED: June 14, 1958 Card 3/3 I AUTHORS: --Trettyekov, Ye.F., Grinhuk, G. I., 56-34-.4-4/6o -a _0rrttn -1t TITLE; The Investigation of the Lower Excited Levels of U 235 on the Basis of the Electrons of the Internal Conversion (Izucheniye nizhnikh vozl)uzhdennykh uroyney U 235 pa elektronam vnutrenney konversii) PERIODICAL: Zhurnal ekaperimentallnoy i teoreticheskoy fiziki, 1956, Vol. 34, Nr 4, PP. 811 - 819 (USSR) ABSTRACT: This work investiCates the electrons of the internal conversion which are emitted from U 235-nuclei subsequent to the a-decay of Pu 239_nuclei. In the introduction a short report is given on previous papers dealing with the same subject. These internal conversion electrons were examined by a lar,~e iron-free 0-spectro- meter with a toroidal magnetic field. The first paragraph re- ports very shortly on the experimental technique. The authors investigated the conversion spectrum of the U27~ up to electron energies of 35o keV, but conversion lines with an energy which Card 113 considerably stirnounts the background were found only in the The Investiv,,ation of the Lower Exited Levele of U235 56-34-4-4/6o on the Basia of the Electrons of tho Internal Converuion range from 0 - 105 keV. Three different diagrams illustrate the ranGes of the conversion spectrum for 0 - 35 keV, 35 - 52 keV, 52 - 105 keV. The ener--ies of the electrons and the intensities of the conversion lines are compiled in a table. First the authors repoirt on tho levels I and 11 (13,0 and 51,7 keV). These two levels I and II are to be regarded as the first excited le- vels of the rotation band with K = 1/2. According to this inter- pretation the levels 0, 1 and II must possess the spins 1/2, 3/2 and 5/2 as well as the same parity. Almost all conversion lines which belong to the transitions 11-0, 11 - I and I - 0 clearly show up in the spectrum. The authors also determined the mul- tipole properties of these y-transitions. The level 83,8 keV is the third excited rotation level of thE! band with K = 1/2, On this occasion the spin must be equal to 7/2 and the parity must agree with the parity of the remaining levels of the aFLme band. The authors found only one transition starting from this level, the transition III - I with the energy 70,8 + 0,2 keV. Remark- able is also the absence of the transition YII - 0. From the Card 2/3 level IV (149,7 keV) transitions start, which is discussed in The Investigation of the LGwer Exited Levels of U 235 56-34-4-4/6o on the Basia of the Electrons of the Internal Conversion greater detail. From the level V (172,6 keV) some weak conversion lines start. This level seems to have the spin 7/2. Finally a short report is given on level VI with the energy 234 keV. The authors also looked for the electrons of an isomeric transition, but without success. The pu240-admixture in the investiGated samples allowed also the inlreatif-ation gf the conversion electrons emitted from its daughter-oubstance U23 . The results of this 235 work show without doubt that the levels 0,I#IIqIII and IV of U belone to the rote.tion band with K w 1/2. The investigation of the a-spectrum of pu239 speaks for the existence of a whole series of higher excited levels of U235, but.the electromagnetic transi- tions between these levels cannot be 'observed. At the end the authors thank L.N.Kondratlyev, I.I.Agapkin and C.Chornoy for their assistance in the moasmrementsf and L.L.Sliv for the information on the internal conversion coefficients on the L-shell. There are 4 fiCures, 2 tablesland 13 references, 4 of which are Soviet. SUBMITTED: Hovember 15, 1957 1. Alpha particles--Decay 2. Uranium--Production 3. Beta Card 3/3 particles--Detection AZARENKO, B.S.p kand. tekhn. nauk; AFANASIYEV, V.D., kand. tekhn. nauk; BROVYWI, M.Ya., inzh.; VAVILOV, M.P., inzb.; VE211K, A.B... inzh.; GOLUBKOV, K.A.; GUBKIN, akademik [decepsed); GTHEVICF, A.Ye., inzh.; DAVYDGV, V.I., kand. tekhn. nauk; DROO, V.G.., inzh.; YM,'OLLYEV, N.F., inzh.;'ZHUKEVICH-STOSHA, Ye.A., inzh.; KIRILIT,., N.M., kand. tekhn. nauk; KOV M V, M.V., inzh.; KOGOS, A.M., inzh.; KOROLEV, A.A.,, prof.; KUGAYENKO, H.Ye.., inz~.; LASK321, A.V., inzh.; IMITANSKIY, B.A., inzh.; LUGOVSKrY, V.M., inzh.; I-EY.1-20VICII, LIM.) kand. tekhn. nauk; OVCHAROV, M.S., inzh.; PASTERNAK, V.I., inzh.; PERLIN, I.L., doktor tekhn. nauk; POEEDIF, I.S., kand. tekhn. nauk; ROKOTIAN, Ye.S... doktor tekhn. nauk; SAFIYAN, M.M., kand. tekhn. nauk; SY.IIUIOV, V.V., 'kand. tekhn. nauk; SMIRIOV, V.S.; SOKOLOVSKIY, O.P.p lnzh.; SOLOVIYEV, O.P.p inzh.; SIDOU'.EVICH, M.A., inzh.; TLtqT'YA40L,-Ya.X.,-inzh.; TRISHROKIYj I.S., kand. tekhn. nauk; KHOKID, G.N., inzh.; TSELIKOV, A *I.; GORODINCIOIKO, V.M., red. izd-va; GOLUBCHIK, A.M., red. izd-va; R11MOV, V.A., red. izd-va; DODUZHINSKAYA) L.V.j tekhn, red. (Rolling; a handbook] Prokatnoe proizvodstvo, spravochnik. Pod red. E.S.Rokotian., , Mloskva, I-letallurgizdat. Vol.l. 1962. 743 p. (MIRA J5:4) 1. Akademiya nauk BSSR (for Gubkin). 2. Chlon-korrespon ant Akaderaft nauk SSSR (for Smirnov, TSelikov). (Rolling (1-letalwor))-Handbooksj manuals, etc.) KOWS, V.1.1 TRETIYAKOV, Ye.M. Determining the thicknessof a solidified layero Nuz*--ahtam. Proizv. 5 no.2t47-49 P"63- (KM 16t2) (Thickness measurement) TRETIYAPDV, Ye.m. Friction in supaetting with an effect of hardening. Kuz.-Bht:-a, proifv. 5 no.3:5-10 Mr 163. (KRA 16:4) (forging) (Friction) I ..~ TRETIYAKQVO Yu.D.; KACRANOV, I.N. 4isothermal so2ubillty diogram for the quaternary system f'eSO4-(NH4)2S94~- VPO,4!"Hn3o/,*(,W I go W'OONH4)2~047~240 at 1100" Zhur noorgokbU* 7 no~lz176&177i fl V6;-. - i MIRA 16',3) (Systems (Chemistry)) (Solubility) (SU.1fates) - PERELYGIN, V.P.; TRETIYkKOVA,_S.P._- SARANTSEVA, V.R., tekhn. red. [Half-life of a spontaneously fissionable isomer) Period poluraspada spontanno deliashchegosia izomera. Dubna, Ob"edinennyi in-t iadernykh issledovanii, 1963'. 6 p. (Isomers) (N)iclear fission) (MIRA 16:6) all R n 4; 3k 13 Ni 'gig a lilt if IlH i! !1 1,1 1 S/12 61/000/007/005/Od7 D209%304 AUTHORS: Tselikov, A.I., Lugovoskoy, V.M., and Tretlyakov,Ye.m. TITLE: Basic theory of diametrical rolling and cold rolling using two and three roller mills V 41 PERIODICAL: Vestnik mashinostroyeniyaq,,%Ao- 7, 1961, 49 54 TEXT: The authors elaborate the problem of using three roller mms as oppoved to two roller mills, for the cold rolling of metals. This method, they claim, can be used for the manufacture of cylin- drical objects with diameters ranging from 18 to 20 mm, giving a very low surface impurity product. The aiithors make the following assumptions: The contact between the cylindrical viork piece and the rollers takes place along a straight line, or in other words, the resultant displacement is the sum of the elementary rotations through an infinitely small angle. The plastic deformation of the material is shown in Fig. 1. The authors first consider rolling by using only two rollers, and then Fig. 1 will consist of a num- Card 1/6 S/122/61/000i'007/005/007 Basic theory of diametrical ... D209/D304 ber of triangles representing thevarious zones of plastic delfoirra- tion due to the Dressure exerted on Lhe work piece. They state that these zones of plastic deformation must satisfy the kinematic conditions existing at the boundaries of the plastic deformation zone. This approach is recommended by the authors since it gives the upper limit of the pressure at the contact points, as opposed to the static consideration of loading which viould only give the lower They consider the equilibrium of the right hand Dor- tion of Fig. 1 to obtain an expression for the contact, pressure. In the case of rolling with three rollers, and for section I-I _2k 11Y+ 2 1.08 In Y 2 (21) 3 -0,02) + 1,3 q7T- 0,1 + 0,261. (21) holds, where a - the pressure in I-I; k - plastic constant and '7 = 2r/b (b = Yheight of contact). To utilize the equations obtai- Card 2/6 S/122/61/000/007/005/007 Basic theory of diametrical ... D209/D304 ned, the area of contact has to be calculated. In the ca.)e of hot rolling this is given by / 21ir b where R - roller radius, r radius of the viork piece and Z-\r de- formation due to rolling. It is not valid for the cold rolling of metals because it does not take into account the elastic deforma- tion taking place between the rollers and the metal. Therefore, to obtain a value, for B, Fir,. 4 is used to illustrate the zones of deformation. _A 1 an d --"62are tile local radial elastic deformations of the roller and work piece respectively. In order that the work piece be compressed by all amount r its center 01 must move to po- sition 02 by a distance equal to I + 2' b = b + b + b + b (24) 1 2 R + r 2 2 Card 3/6 S/1 22/61 /01)cj/(')07/()05/007 Basic theory of diain(,,trical ... D209/'1)304 gives the resultant liength of contact taking into account clastic deformation. If the absence in symnetry is nerrlectod b ~_-._\/4q(kl + k fir (25) 2 2 It + r applies, where q is the presoure per unit length of the cylinder, and ki, k 2 are constants, depending on the material of the work piece and roller. q = 2b 2P shov's the relationship between p and q. By putting this value of a in 11'q- (25) b 8 (k + k ) Rr (26) 2 1 2 R + r v is obtained. The formation of' cavities in the center of the cylin- der could be attributed to the very large stresses developing at the boundaries of the plastic regLons. Also Y_2k III 'Ir -_L+1 7ja I* (19) Card 4/6 S/122/61/000/007/(105/007 Basic theory of diametrical D209/D304 shows that the maximum tensile stresses occur at the center of the work piece..Vlnen using three rollers a cavity of diameter A (Fig. 2) is lforrmed. The authors emphasize that that annular compression reduces the possibility of cavity formation in the center of the work piece, and, if enough tension is developed in the work piece, failure doc:a not occur. Peeling is a great disadvant , of the Cold rolling process, and this could be eliminated by using work pieces with smooth, surfaces. This method was successful when using steel t pes 20, 45, "77 X Y 1, (ShKh)9, ShKhl5, Y(U)12 and U8. The maximum Sur- face area reductLon was 75 ~a'- Cold rolling greatly increases the strength of metals. The percentage reduction in surface area and C~ are the yield stress of steels ShKh9 and U8. There are 10 figures, and 9 references: 8 Soviet-bloc and 1 non-6ovict-bloc. The referen- no to the !~riglish-language publication reads as followo: S. Jonson Identation and Forging and Action of Nasmith Anvil, "The 1,.'ngineer", 1958, v, 205, J115328. Card 5/6 TOMLEIqOV, A.D.; TKETIYAKOV, Ye.Y., red.; SI?,OTIN, A.I., red.izd- va; t6khn. red. (Mechanics of wtal-shaping processes] Nekhanika protses- sov obrabotki metallov davleniem. Moskva, Mashgiz, 19631. 234 P . OIIRA 16:12-) (Plasticity) (Sheet-pietal work) (Forging) S/182/62/000/005/005/007 D038/D113 AUTHOR: Tretlyakov, Ye. M. TITLL: The effect of temper rolling on the mechanical prcoerties of sheet steel PERIODICAL: Kuzneclino-slitampovochnoye proizvodstvo, no. 5, 1962, 20-23 TEX"r: To improve mechanical properties and prevent the formation of slip band S 4n the stress strain diagram of parts extruded from 0.3-2.0 rmi thick sheet steel, the steel must be tenper rolled. The distribution of deformation along the thickness of a terper rolled sheet is given as: 2 6 H - . 1-11, ~F rH2-4mL;V (12) where H is the thickness. Experimental investigations demonstrated that (1) the' correlation of plasticity with hardening %-ras sufficiently accurate under single and compound loads in tests for uniaxial tension or compression.; (2) the condition of plasticity permitted determining variations in the mechanical properties o-f a strip after temper rollin.-jand (3) the tension imtensity could be deterridned from C a r d 1/21 S/182/62/000/005/005/C07 The effect of temper rolling on ... D03S/D113 (a) the diagram of uniaxial tension and (b) the stress strain diagram. It is important to determine the residual stresses in a temper rolled sheet as they affect the nature of the stressed state of the part during extrusion, and max, buckle it later on. It is pointed out that E.J. Paliwoda and I.I. Bessen (,-,etal- lurgical Sociezy Conference, vol. 6, Chicago, 1960) had wrongly assimLed that the symbol of residual stress(s agrees with the defonnation symbol. Formulas for determining the factors of residual stresses durin- flat deformation of a strip are given. There are 4 figures. Card 2/2 TRETIYAKOV, Ye.M. 19ffect of temper rolling on the meehanical properties of sheet ateel. Kuz.-shtam. proizv. 4 no.5t20-23 My 162. (MIRA 16:5) (Metals-Finishing) (Drawing (Metalwork)) L-42305-6� f-.WT(d)/EWT(m)/EWP(w)/T/EIYP,(t)/ETI/EWP(k) IJP(C) iT-,/K!/EM ACC Nts AP6016308 SOURCE JODE: UR/0380/66/000/001/0107/01-l.4 AUTHOR: llyakovp Yes Me (Moscow); Yelenev) So A (Moscow) ORGt none TITLE: Analynis of the process of plastic compression of thin bi--.1ot. of bardened material OURCE: Meabinovedeni-yes no* 10 19660 107-119 TOPIG'TAqS-,,-,metal ardeningq compressive stress ABSTRACT: For many hardened materials, In the presence of Intens.!-. stresses wbich exceed the creep limits, the plastic conditions are approximated by an exponential relationship of the following form: Of =2 C44%, where C and n are parameters characterizing the mecbsnica~ -Proper' the deformed metal* A figure shows the effect of a change in n obaraoter of the above relationship. The article prooeed!3 to 2n mathematical treatment of the subject, ending with the derivati----- formula permitting the numerical determination of the contact fr~7t!~: with respect to the intensity of the stresses at the center an,~' 94; Card UDC: 13-':,,-, - ~ -.1 -1 L 423M-.bO [-A'tt -WR-'j6-6O-i6-3-0-8' edge of a metal band. Orig. art. boat 31 formulas,, ~J fl.gures and 4 tables, l SUB CODEI 11AVSUBM DATE: 09Jun65/ ORIG REF: 007/ OTH REF: 002 11-7 Cwd 2/2 , I Yt~. V. V k"! In, I TM,I" Y A K" Vi C. on s wap t -i or. f:n);t r rr-~ -'-T: S r 3 1; g4 Ukrp n' art kand.tekhn.nauk. TBL,T-IYAKOV,-Yq. Research by the Donetsk Branch of the Ukrainian Research Institute of Metals. Stall 22 no.7:605,621 n 62. (MIRA 15 - 7) (Steel--Metallurgy) LEVUSHKINO S.I.,- -je-.Y.4, Su=er studies of the karat group of the Labomtory of Hydrogeologic Problems of the Caucasus in 1960. Nov.kar.i apal. no.2:97 161. (HIRL 15:9) (Caucasus--Karst) S/133/6Z/000/007/001/014 A054/A127 AUTHOR: Tretlyakov, Y6.V.; Candidate of Technical Sciences TITLE: At the Donetskiy filial Ukrainskogo nauchno-issledovatel;skogo in- stituta' metallov (Donets Branch of the Ukrainian Scientific Re- search In6titute of Metals) PERIGDICAL: Stal', no. 11, 1962, 605 TEXT: The properties of zirconium-modified carbon steel grade 15 and 20 were investigated. The -Lests were carried out In a 200-kg induction furnace with -he addition of ferro-zirconium foundry alloy containing 25 - 35% Zr. When the ~'I,i.ndry alloy was idded to the ladle bottom, 47.5% of zirconium was adapted, wherit. - when it was added to the flow or the furnace, the figures were only 20.9 and 1 .6%, respectively. Zirconium considerably affects the crystallization of the z,-. al, 'Its grain size, the zone of acicular crystals. The number and dimeh- sions -,f oxide inclusions were reduced and the composition, shape and distribu- tior norurietallic ilaclusions changed as well. With a zirconium content of O.IL- 0.11% Zr02 inclusions are formed and distributed uniformly, while the Card-1/2 At Donetiskiy filial .... S/133/62/000/007/001/014 A054/A127 amo'_.it of corundum ln~,lusfons decreases. Upon adding zirconium In amounts of O-v~ - 3.42% the basic strength and plastic properties of low-carbon steels did not -nange. The threshold of cold brittleness was lowered, the corrosion re- sistance In water increased by a factor of .1.5 - 2. The total weight loss for steel grades containing 0.11 - 0.42% Zr amounted to 1.24 - 1.58.g after being tested for 500 h, while the corresponding values for control samples (without Zr) were 2.315 - 2.981 g. Card 2/2 BRONSHTAY11, Vladimir Markovich;'TRZTIYAKOV Ye.V., rod.; Lr.B;=V, A.I., red.izd-va; ISM 115YA '-r~- ~., xnn.reds (Reduction of waste staloplavillnom izd-vo lit-ry po, 140 p. (Steel--Metallurgy) in steel smelting] Snizhenie braka v proizvodstve. Moskva, Goa.nauchno-tokhn. chernoi i tovetnoi metallurgii, 1959. (HM 12:9) (Metallurgical plants--Quality control) L! Y:,']: GONG[DkRENKO* N.I., kand. tekhn. nauk; BABIYj A.S.; BAYDUK, V.F.; BAZILEVSKIY,, A.R.; MISHCHENKO, N.M.; MATINOVSKIY9 V.G.; BELEPAt V.I.; TOLISKIY, A.A.; TRETIYIKQV,, , _XS..V.? kand. tekhn. nauk; KHALIF, M.L.j PODMCIGORA, I.D. Smelting of steel in oxygen- and steam-blown converters with an acid lining. Met. i gornorud. prom. no.4:20-25 il-Ag 165. (MIRA 18:10) KULIKOV, V.O.; BORNATSKIY, I.I.; ZARUBIII, N.C.; DOROFEYLV, G.A.; KALUZHSKIY, Ye.A.; KAZAKOV, A.A.; KOVAL' , R.F.; KORNEVA, II.K.; TRIJIGV, Yo--.A,; Prinimali uchastiye: GORDIYENKO, V.V.; GPINEVICH, I.P.; GUBARI, V.F.; DOHLEIIKO, II.I.; ZHERNOVSKIY, V.S.; ZHIGALOVA, Z.I.; KOMOV, N.G.; KURUIN, B.S.; OLESHKEVICH, T.I.; PRI.KHOZffENKO, Ye. Mastering the operations of 650- and 900-ton (mega - gram) capacity open-hearth furnaces at the Illich metallurgical plant. Stall 25 no.8:805-807 S 165. (MIR-1.1 18:9) 1. DONNIICHERICT i Zhdanovskiy metallurgicheskiy zavod imeni Illicha. TMIYAZDV, Ye.V., insh.; OYXS, G.R., profe, doktor takhnnauk ~. 1'441~1)0 lfa- Conditions for accelerating slag formation and dephoaphorization. Ixv.vys.ucheb.zav.6, chern.met. no.8:21-30 Ag '38. (MIRA 11: 11) 1. Koskovskiy institut stalie (Smelting) Ohemlst'7, MOtsllurgic) I ROKASHKOWSW, Grigoriy Savvich; red.; R07M,TSVEYG, Ya.D., red.izd-va; DOBUZHINSXAYA, L.V., tekhn.red. [Inspector of the technical control division of an oper~-hearth p!ocessl Kontroler OTK martenovskogo tsekha. Moskva, Goo. nauchno-teklm.izd-vo lit-ry po chernoi i tovetnoi metallurgii, 1959.. 214 p. (MIRA 12:4) (Open-hearth process) TWITAXOT, Ye.V.; SMMOT, TA.A..; KOTIN, A.G, =~, "', - - - .Using fluxed briquets and sinter cakes in open-hearth furnaces, Biui. Tsmicmf no.4t6-12 158- Wn 11 W (Open-hearth process) .Nbairow, V.I., A. TXTLts RMOI-MOY f the U-. of Slater end briqu.ttes Inate.4 or Ore and Llx:stons In Open-hearth Purnacan (Mffkttwnomt- PrLm"emiya v iwartanorskikh pach-uh aglomer.t. I briketow, Womi= rudy I Iswestayadva) PMODICALs 3tOll, 1959, Xr 3. ip 400 - 407 (USSR) ABSTRACT9 In O"~ to conipmr. the officLeamy Of usimg fluxod -inter ot", Ako.. N.Z. . AIMMAS1 Darrell, A.G.. DubLno. TU.G.. w14 or"llsio briquettes Inatend of Ore and ilmoston. 1= !"s-b"rth tvJ'aacom as Wall am to 4.tas~vdx. the ptjc~ on Or the above Agglomerated "terials, expet-1. mantel boats were ca=rrir4 out In 370-ton ru~VMAOOS at the least D%"%U-oki7 Vo:tx daring 1957-X958 Altogathas 63 ft"t- -&in cr~qm%tes' 70 with &=term of Teri us compositions and 90 oopaxotil. boats using cre and Mamtons were made. All heats wore made in the :m* furnace* and during the sun* period- The compositionM t briquettes ad minters t..t.4 is given in Table I (bonlotty of briquettes ymrid from 0 - 3.4 &.4 or POO content in .2.9 in the 2.urs. of ...1ting Ora t~Qwn in Flsr.a L and 2, rospectiv-17, the -I- I -it":-0-Cptho ~parlmos&l. and ow.;,or.tiv. heats in Table 2: t On azi- a" of the mounts of C^O, SiO2 -4 Hero tranararr.4 to *lag from varlo" xronulw a,mt~rt Is - Table 3. changes In th. Sto2 content of &;ag in the :ours* of ameltim4 for wam." hosts - PlcurdA 3 &=d S. the '-a changes In '2^9 basicity - Fl5ure Ah. the - GhAng.$ '-U the P20., content figures !1 and 9. the j"s chanses in the Coo cost ant - Figure 6, the am* chsnzam '~n the JP.0 and C&O &" 47.0 the a- h h :on an . - Figures 7 a=d 11. f- , . t .at= or suzphux - Figure 10. It a c =-d ':at 4 of fl%Xod briquettes or *intern instead Of Ora &a4 limestone leads to a Gonaidorably faster formation of slag during the vo-ItIng down P--i*d, to an earlier slag r~~.2 and to a ..rrsopondInS decrease in the malting Cas,43/4 Period. 7ba uaa of tlus:.4 briquettes or inter of & basicity 2.0 - 2.5 without additions or with minimal dditions or or. &.4 limestone ..4. it pcn4Lbl.c 1) to decrees. the malting period I. 370-ton turma.- by 40-45 vain with &A Increase In the Curnsme productiwity of 6-7%j 2) to decrease the duration Of ho^t1" up somomealro layers of gr&nul~ materials during the harS.LwC Period " an On their heating after the cb&rging 1.8 "=4PXoto4 (wtLich Permitted a further decrease of 10-15 min In the duration of heats); 3, to soar.". slag basicity in the Gourn* *C smelting &s%4 to decrease the Peo content of slag at the begist"ag or the melting period ard to 1~emmo Its FoO content at the end or this pario4l 40 to Izaroam. the 4.pb..pbol.lnS and don.1pbuxialo, ability ci slag 4me '.4 -= ~-rji~r fo-eattan and hizhor basicity tbroughOut the whole cour.9 of malting asu~ 5) to ""lude blow-outo from the furtiacs du~rlng malting. Th. bri qutt.. and *Later* an l.. be Used with success during refining. The *rX&n.L.&tion of & Logo-scals prO4.ctlOn of r2".d briq..tt.. -A Later. for the upon- hearth furnaces and their wide application in xtoeX-"&"AS pre4tio ended. rh.r. are 11 fig-r.-, 3 table. 6 3: I:trocoom .ad vi rof.rava... ASSOCIATID Ukr*i-"y instit4t. ..zelj.~ lns~tltuto or x"Ma .) and Zov,.4 im.ni (i..ni D.-hinakiy Works) Card 4/4 0 Y A,',(-"I Y, of C(ov-r L-bor 149-5 TMItYAKOV, Y-11'. 7- "LIMIUKOV, IN.V., inshener; KAKOVSKIT, V.A., inshener. I ---- - -mplaw Reduction of high phosphorus pig iron in tilting open hearth furimces. Stall 17 no.6:517-519 Ja '57. (M1RA 10:7) 1. Zavod "Asoystall". (Open hearth furnaces) (Iron phosphides--Metallurgy) SHNFYEROV,- Ya.A., kand.tokhn.nauk; DERFELI, A.G., kand.tekhn.naukj KOTIN, A-G., kand.tekhn.nauk; Prinimali uchastiye.- ZAYTSEV, I.A.; KURAPIN, E.S.; LEVITASOV, Ya.M.; SUKAGREII, A.I.; TRETIYAKOV, Ye.V.: UKIEW, V.D.; SIIUYSTU'-"SKIY, I.B. Reducing the consumption of ferrombnganese in the making of open- hearth steel. Trudy Ukr. nauch.-issl. inst. met. no-7:103-114 161. (MIRA 14:11) (Steel--Metallurgy) (Ferromanganese) TRETIYAKOZ,-~., kand. tekhn. nauk; IMVALENKO, V*SOP itizh.; CHUMACHENKOY V.S., inzh.; KISELEV, I.M,, inzh. Using compacted addition alloys in the produatdun of low carbon steel with zirconium. Met. i gordarud. prom. na.6:29-30 N-D '62. (MIRA 17: 8) 1. Treat "Donbaostsvetmet" (for Tretlyakov, Kovalenko). 2. Donetskiy filial Ukrainskogo nauchno-issledovatellskogo instituta, metallov (for Chumachenko, Kiselev). POLYAK, Isaak Berkovich; T=IYAKQV, _)(4~ygeniy Vasil'yovich; LANOVSKAYA, M.R., red. izd-va; mkkitou,' m.', tel:hn. red. .(Open-hearth production of steel] Martenovskoe proizvodstvo 13tali. Moskva, Metallurgizdat, 1963. 161 p. (MIRA 16:6) (Steel--Metallurgy) (Open-hearth process) r;i~ r9A,SE I BWX EXPL01TkTT0V SOV/4893 ysonoyutnoy# soveshchanlye po fIzIke, .112lWo-khImicheskim EVOY*tv%z rerritov I fitlCheaklm osn*vmm Ikh PrImenenlYs. 3d. Minsk, 1959 ftrrIty; rl43ICjj&skIye I flziko-"Imlche3ktly;ro3vOy3tev&. DOk-ladY (Perritess ftysical and rhysicochemical perti a. Reports) Kinek. Ud-vo AN BSSR, 1960. 655 P. Zrrata allp Inserted. 4,000 copies printed. 3ponsoring kientlast. Nauchnyy sovat P~2 zagnatizzmU AN SSSR. Otdel Miki, tvtrdago tela 1 polupravodnikoy AN BSSR. XdLtorial B*u-d: Rasp. Xd.z 1. W. Sirota. Academician or the J, of Sciences SM; X. P. Below. troresaor. Ye. 1. KOndor SICTy"yrofe3sor: 1. 14. ftllV&nQV; ft'Of#3JOr-. R. V. Talesnin. Pr;. resaar: 0. A. Smolenskly, Professar; 1. X. Shollts. Candidate of Physical And riathematIcal 51: lances; Z. K. Smolywrenko-, and X.. L. Ushkirov. Zd. aff Publishing gouse: 3. Kholyavsklyj Tech. Zd.: 1. Volakhanovich. for physicist$. Physical . C.hIealsts radlO electronics engineers, and technical Personnel engaged In the Production and use a' ferr0cmEnst--c materials. It may also be used by students in Advanced courses In radio electronics. Ph"Ics. and physical cbenistr7. COVERA1214 The book Contains reports presented at the Third all. M%IOn COnftr*nC* On Forrltea hold In PUnsk, Belorussian SSX. The reports deal with magnetic transformations, electrical and 9WITImOMAgnstle ;mpertlos Of fe""O's- studies Of the growth or ferrite single cr~$%Als. Problem in the c"cical and ph7al- cOzh*slc&l 'analYzIs Of fOrrltcs. stud.'~S of f*rrites having rectangular hysteresis loops and culticamponent ferrite systems ftZhibiting spontaneous rectangularity, Problems in magnetic Attraction, highly coercive ferrite&. MAVnetic spectroscopy. rerrOdAgnatle resonance. MagnstO-Optlea, Physical Principles or using ferrite components In electrical Circuits, anl3ozropy~ of OlectrIC&I And Magnetic Properties. &to. The Committee or. ftg~ n4t1sDo AS USSR (5- V. VOMSOvskly, Chairman) organized th- Con- 9"'ence. References &4CCWpALny Individual Articles. SOVAS 93 AftLactropy of Suil. Crytat. ~.Il -o-~C bi r c FOrrites 95 d K a Kh kov. Mzparizent in 100 Be lc-- - r . A. P. raikin. 517'errItas Durjn--Eh-~ ard S. X. 51"ta. Formation ~I S oh of g alt, Ill pe I Investigation Or the ' t I e s 0ke'-Zlnc P*rrl"3 0? NOAr-StOichlOwetric C om P-15 t I l on and 1122QVTskQX Calorimetric D.- terwinatl~; 11.a Or J"r-,tlon of Ferrite$ 124 "M yl~ - I The Chemical Kature of 30" K3&netlc "~ I N. N ' the D's ft0-MCt-P*203- SP'n*lo with Rec- :rA" Ungular RY3t9r*sI . Lo p 129 Card 5/,B CAN 4A8 I ; % ; , -~ ~ I*,,. ~ - ! , I - . - . I "Investigation of the Structural Transformations of Certain Majpetic Alloys by the Method of the Real Heat Capacity," Moscow, 1958. (Dissertation preEented and appi7oved for the degree of Cand. Chem. Sci.) Moscow State Univ. fm M. V. Lomonosov. 5W .AUTHORS: Tretly-akov, Yu- ., Khomyakov, K. G. SOV/78-4-3-23/34 TITLE: Specific Heat of the Alloys FeM.Al and FeCoAl (Teployemkost' splavov PeNiAl i FeCoAl) PERIODICAL: Zhurnal neorgantcho3koy khimii, 1959, Vol 4, Nr 3, pp 645-650 (USSR) ABSTRACT: The true specific heat of the alloys FeNiAl and FeCoAl was investigated according to various methods of treatment of the alloys. For the production of the alloys electrolytic cobalt, nickel, Armco iron, and aluminum with a purity of 99.99 1fa were used. The melting of the alloys was carried out in the high-frequency furnace in argon atmosphere. The alloys were investigated as to their true specific heat and coercive force H . The curves of specific heat c of one and the same 0 p sample were plotted in softened state and after hardening at 800 and 1,2500 and are shown in figures 1 and 2. The course of the c p curve of the alloy FeCoAl shows a maximum at 7000 and of the alloy FeNiAl at 730-7350. The coercive force of the softened alloys amounts in the case of PeCoAl to Card 1/3 250oe and in the case of FeNiAl to 75 0e. 8pecific Heat of the Alloys FeNiLl and PeCoAll SOV/78-4-3-23/34 In hardened alloys at 8000 the 11c of FeCoAl -1 oe and of PeNiAl = 63 oe. The c P course in hardened qarriples (8000) 1-9 characterized by the occurrence of exothermic effects at low temperatures. The c p course in samples hardened at 1,2500 proceeds in a similar way. The limit of the exothermic effect is in the case of the alloy FeNiAl between 300-6000 with a cP minimum at 4600 and in the case of FeCoAl -at 400-6400 and a c p minimum at 5600. The nature of the exo- thermic effect at 300-6400 could not clearly be determined, it is presumably based upon the orientation of the /~ and A phase with a variation of the structural tension in the alloy. Alloys hardened at 1,2500 have also an exothermic effect at 640'and 6800. The considerable temperature effect increases the coercive force H.. There is no dependence between high-temperature transformation and magnetic hardening of the Pe-Ni-Al alloys. It was found that in the system Card 2/3 Pe-Co-Al the magnetic hardening process proceeds slogly. . Specific Heat of the Alloys FeN.4Al and FeCoAl SOV/78-4-3-23/34 At higher temperatures the cp curve proceeds 'A -shaped, independent of the thermal treatment of the alloys, with a maximum in FeCoAl at 7000 and in FeNiAl at 730-7350. This variation in the c p curve is connected with the occurrence of the magnetic transformation in the Curie point. There are 4 figures, I table, and 27 references, 19 of which are Soviet. SUBMITTED: November 16, 1957 Card 3/3 f \i~ TR P. T 1, YA- YO V, Y D - by 100 copic.;~ 2.1344 S/07 61/006/004/018/018 I C) 104S, 12-13,11"' B107YB218 AUTHOR: Tretlyakov, Yu. D. TITLE: Isothermal solubility diagram of the Zuaternary system MnSO 4(NH 4)2'04 -MgSO 4(NE 4)2SO 4 - FeSO4 NE 4)2S04-. H20 at 400C PERIODICA:bt Zhurnal neorganicheakoy khimii, v. 6., no. 4, 1961, 985-993 TEXT: The data obtained by the present study of the system may be used for the production of Mg-Mn ferrites which are of great importance in pulse technique. Double salts of the schoenite type (MgSO 4-K2So4 -6H 20), whare Mg may be replaced by Fe 2+ , Cc 2+ , Mn 2+ p Cu 2+ , Cd 2+ , and K+may be replaced 'by NH+, are usually isomorphous and form uninterrupted series of 4 mixed crystals. The initial substances weret MgSO 4* 7H2 0, chemically pure (NH 4)2SO4 and MnSO 4' synthetized from 99-95% electrolytic manganese. The method of "isothermal decrease of supers aturation" was used for establishing equilibrium between the liquid and the 3olid phase. It was developed by V. G. Xhlopin et al. and has been used successfully by G. I. Gorshteyn. Card 1/13 21344 S/078j'61/006/304/018/01 8 Isothermal solubility diagram of the ... B107/B218 By this method, equilibrium is established after a few hours, which distinguishee the method from others, e.g., the method of "recrystalliza- tion". The authors used a thermostat which enabled simultaneous experi- menting with 24 samples. Fe was titrimetrically determined by KMn04. Mn was titrated as oxalate with KKn04- Mg was bromatometrically determined as oxyquinolate. The ternary system MgSO 4' (NH 4)2504- MnSO 4' (NE 4)2S0 4- E'O was studied (Table 1). Apart from the different solubility of Mg and Mn salts, the system seems to be ideal over the entire range of concentrations of both components. The mean value of equilibrium distribution between Mg salt and Mn salt is 3.50. Based on the thermodynamic theory of activity (Ref- 3: G. I. Gorshteyn, N. I. Silantlyeva, Zh. obahch. khimii, 23, 1920, (1953)), the following holds for ideal ternary systemsi Df /Mg) , D w D In the present case, thiscondition is fully ,Fe ~e/Mn) (Mg/Mn)' satisfied.. Five inner cuts of the quaternary system were studied (Tables 2 and 3)- For evaluating the solubility diagrams, no tetrahedral model was used, but the curves were treated mathematically in rectangular coordinates. The solubilities of the individual components were plotted Card 2/1!i 21344 S/078/61/006/004/018/018 Isothermal solubility diagram of the... B107/.B218 on the axes x, y, z. The coordinate surfaces x-O-z, x-0-y, y-O-z cor- respond to the given ternary systems, and the total octant O-x-y-z cor- responds to the quaternary system. For any content of the solutions, the following equation must hold for the surface in the intercepts on the axis of coordinatess x/a + y/b + z/o w 1. a, b, and a are the solubilities of the individual salts, and x, y, z are the concentrations of the saturated solutions. Tables 2 and 3, column III, give the values for the sum x/a + y/b + z/c of the compounds investigated. Since the values are nearly equal to 1, it is possible to prove that there really exists an uninter- rupted series of mixed crystals in the quaternary system FeSO 4' (NH4 )2 s04 MnSO 4' (NH 4)2SO4 -MgSO4(NH 4)2SO4 -H20. It seems to be of special im- portance to establish an interrelation between the compositions of the liquid and solid phases, which enables quantitative calculations. The following relation holds for the relative concentration of the component A in the solid phase and in the mother lye: D . YA / XA equ(A/B) `yB x. Systems for which the value for Dequ remains constant are termed ideal Card 3/13 9.,-344 S/078/61/006/004/018/()18 Isothermal solubility diagram of the... B100218 systems. Their distribution curve assumes the form of a hyperbola following the equationt YA - -1 D-xA . XA and yA denote the concentrations of the xA(1-D) component A in the salt fraction of the mother lye and in the solid phase; D is the coefficient of equilibrium distribution of A as related to B. It seems possible to apply this coofficient also to quaternary systems. In this case, it holds: Dequ(A/B+C) = - YA XA . Tables 2 and 3 give experi- Y(B+C) x(B+C) mental results. The ratio Mn-salt concentration/total concentration of Mn and Mg may be seen from column VI. The change of the distribution coefficient as a function of the composition of the solution is given by; D f ( Mn ) in the salt fraction of the mother 'lye. By using (Mg/Fe+Mg) - Fe+Mn the method of least squares, the following values are obtainedt D(Fe/mn+mg)'0'633+0.0278x +1-389x 2, and D .963x2 1 1 (Xg/Kn+Fe)"1-580-0-3X3x2+1 2- X1 is the -atio of concentrations of the salts Rn/Mn+Mg, and x2 is the Card 4/15 S/078/61/00-6-7bO4/018/018 Isothermal solubility diagram of the ... B107/B218 ratio of concentrations of the salts Mn/Mn+Fe. Thus, to a mother lye consisting of 25 % Mg salt, 25 % Mn salt, and 50 % Mohr's salt, corresponds a solid phase of 36-04 % Mg, 14-11 % Mn, and 49-85 ~ Mohr's salt. Any poin t of the solubility diagrams of the system MgSO 4' (NH4)2SO4 MnSO 4* (NH4)2 so 4 -FeSO 4' (1111 4)2SO4R20 may be calculated analogously. There are 9 figures, 3 tables, and 9 references: 7 Soviet-bloc. SUBMITTED: February 20, 1960 PROTSENKO, P.I.; PROTSENKO, A.V.; TRETIYAKOV, Yu.D.; VENEROVSKAYA, L.N. Electric conductance of binary molten nitrite-nitrate systess. Dokl. AN SSSR 154 no.5:1171-1174 F164. (MIRA 17:2) 1. Rostovskiy-na-Donu gosudarstvennyy universitet. Predstavleno akademikom A.N. Frumkinym. KHOMYAKOV, K.G.; TRETIYAKOV, Yu.D.; REZNITSKIYI L.A.; FAVLOVA-VERMIIIA, L.A. Works on ferrates at the general chemistr7 department Over the last five years. Vest.Mosk.Un.Ser.2.;Khim. 16 n0,5:52-59 5-0 161. (MIU 14: 9) I.. Kafedra obehohey khiraii Mookovskogo universiteta. (Ferrates) TMITAKOT, Yu.D.; KwmrAKOV, K.G. Structural changes !z some mgUetic alloys, as studied by the method of true heat capacity. Zhur.raorg.khim 5 no.2:4io-414 F 16o. iMIRA 13W (Magnetic materials) (Alloys) (Heat capacity) ---- - -- --- i~~ -7: am~ --fiA&ietic soll 6 so-Iutions 4i 4 SOURCE- VI ~z ~z ~z FTzvestiva. georganicheskive materialy, v. 1, no. 2, 1965, 240-245 acllii solution T 4"1-p --~ ~ I I ACCES'~'IION NP A 0 () 9 ~ 7, 1 - 4 . 1 ~. , I ;: - , , 1, " Lem a a wall a M 16, 1 49?8A,-65 card 3/3 ~Wllqql M.-Mil ,)(4), 18(4) AUTHORS: Tretlyakov, Yu. D., Khomyakov, K. G. TITLE., The Specific Heat of the Intermetallic Compound CoAl After Various Thermal Treatments (Teployemkost' intermetal'Aiche3kogo soyedineniya CoAl posle razlichnykh termicheskikh obrabotok) PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4~ Nr 1, pp 13-16 (USSR) .ABSTRACT-. The real specific heat of the intermetallic compound CoAl of stoichiometric composition was investigated by the method of continuous adiabatic heating. For the production of the alloys CoAl electrolytically purest cobalt and aluminum (99.99~6) were used. The real specific heat c p was measured for the same sample in hardened and annealed state in dependence on tempera- ture. The c p value in the hardened samples rises slowly and shows a sudden rise at 7400. The sudden rise of the c p value depends on the order and disorder in the CoAl structure. By hardening the samples at 12500 a greater disorder is caused Card 1/2 than by hardening at 8000C. At temperatures above 8000 all I SOV/713-4-1-3/48 The Specific Heat of the Intermetallic Compound Con'l After Various Thermal . Treatments curves of the c p value show a sudden drop. There tire 2 figures and 13 references, 4 of which are Soviet. SUBMITTED: Lj, -ber 7, 1957 Card 2/2 7(0), 24(8) SGjV17,-,-4---211C- AUTHORS: Trettyakov, Yu. D., Trush~ina, 7. 1A.., Khomyakov, F. 0. TITLE: An Adiabatic Calorimeter Operating bn the PriheiplA of Contimious Heating (Adiabaticheskiy kalor--imetr, rabotayushchiy po printsi- pu nepreryvnogo nagrova) FERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 1; PP 5-12 (USSR) ABSTRACT: In order to investigate the structural change in magnetic alloys by the heat capacity method a new adiabatic calorimeter was constructed. The device is described in detail and the diagram shown in figures I and 2. The thermo-elements for the calori- metric system are indicated. By determining the real specific heat of cobalt and iron within long temperature ranges the calorimeter was tested. The specific heat c p of cobalt changes 4 suddenly within the temperature range 447-478' , Iron shows a maximum of specific heat c p within the temperELture range 745-7750 which corresponds to the transition from a-to P-phanc. Card 112 The c p determination of cobalt was compared to data obtained t;i_ SOV/78-4-1-2/48 An Adiabatic Calorimeter OperAting cn the Principla of- Cantinwu Beating from publications and it was found that the maximum error of the adiabatic calorimeter is + 1% at a heating rate of 0.2) to 1.00/min. Heat capacity uP-to 8500 can be moasured by of the new calorimeter. There are 7 figures, 2 tables,and 10 references. SUBMITTED: October 7, 1957 Card 2/2 68233 S/076J60/005/02/02 1/045, AUTHORS: Tret',yakov, Yu. D., Khonyakov, K. G. B004/BO06 TITLE: Investigation of the Structural Changes in Various M6,netir, .AlloyA'Sy the Method of Real Specific Heat-p\ PERIODICALs Zhurnal neorganicheskoy khimiij 1960, Vol 5P 11'r 2~ PP 410-414 (USSR) ABSTRACTt The authors investigated the industrial alloys ANKO-1 and ANKO-2. For ANKO-1 , the authors found the approximate ccm- position of lEr% 11i, 1VI. Al, 12% Co, Cu (roots Fe), and for ANKO-2, 2W. Ni, 9~ Al, 15% Co, 4% Cu (resti Fe), The au'~hors determined the real specific heat c by continuc-uz adiabatic heating in a calorimeter (Ref 11) , he alloys were heated to 12500 in an argon atmosphere and then hardened in ice water, Hardening was controlled by measuring the coe-rcivify Hc by tle ballistic method. The values obtained for c are _pven in the figures 1,2, those of H. are listed in a tatle. The findinCii were as follows: 1) tempering of hardened alloy5 a' low tempara- tures is accompanied by an exothermic effect. 2) This effecil is probably caused by the ma,-,netic transformation of the Card 1/2 magnetic P2-phase. On repeatedly heatinE the alloy, the effect 66233 Investigation of the Structural Changes in Various S107SV601005'0210271045 Magnetic Alloys by the Method of Real Specific B004/B0006 Heat SUBMITTED: disappears, since meanwhile a separation of the j3- and phase has occurred. 3) The exotheruLic effect occurring at 610 - 6600 is caused by the maj:netic hardloriine or tliv iillc%yo, since it is accompanicd by a sharp increase in H,,. The al-A,-,,..3 ATTKO-1 and ANKO-2 are distinguished from the al!Dy FeNiAl -Fjy their greater ma6,-netic force, 4) The endothermic eff,-,.:,t at 7'00':~ obsorved in the alloy A11KO-1 is probably due to the ti-anl-- fori;iation at the Curie point, Similar effects were obf-ior-red in FeCoAl (7000) and FelfiAl (7350), The transforaiation c--' ANKO-2 is above 8000 and thus beyond the ran~,,e There are 2 fi,-iires, I ta-b1c, ~lrd i----ferencez7, i-.,f w"!.4 are Soviet. October 26, 1958 Card 2/2 TRSTITAMV, Yu.D.; KHOMYAKOV. K.G. 11 - --., -- Heat capacitjr of the alloys FeRiAl and FeCoAl. Zhur. nourg. k-hiso 4 no-3-.641;-650 Mr '59. (XIU 12: 5) (Iron-nickel-aluminum alloyl) (Iron-oobalt-aluminUm alloys) (Heat capacity) -- - ITRIATIYAKOII, Tu-D.; 1HOWAKOVa-K.G. ft7sicochemical propertlen of oome ferrites obtained by different methodes Part 2: Solubillty lootheras for the eyotan (VkJ2504 - MVB04 - 78$04 INS04 - H;)O at 25, 40, and 55~ C- Vast- Xo,3]r- un- Ser. 2: Xhim. 75 no-5 251-55 B-0 160. (MIRA 13:11) 1. Moskovskiy gosudarstvennyy univereitet, kafedra obehchey Ichimli. (Sulfates) Oferrates) S/078/62/007/006/003/024 B124/B138 AUTHORS: Tretlyakov, Yu. D., Khomyakov, K. G. TITLE: Apparatus for measuring the dissociation pressure of ferrites and oxides at high temperatures PERIODICAL: Zhurnal neorganicheskoy khimii, v- 7, no. 6, 1962, 1219-1224 TEXT: The direct static method-is best suited for measuring the dissocia- tion pressu:rc of ferrites between 10- 2 mm Bg and I atm 0 2 corresponding to-"'- a temperature variation between'1100 and 15000C. The diagram of the apparatus (Fig, 1) and the heating system (Fig. 2) ard described in detail. Before the experiment the gas in the system is removed by heat- ing to 1500()C for 8 hrs until reaching a vacuum of 1o-5 mm Rg. The air- tightness of the system is checked by disconnecting the pump system and seeing that the vacuum must not fall below 10-3 mm Bg in one day. Complete expulsion of the Cases adsorbed to the apecimotin wan attained by 18 hr heating to 8000C. The specimen is heated to 11000C and the Card 1/f -7, -0/078/62/007/036/003/024 -Apparatus for measuring the ... B124/B138 manometer is read every two minute:i until the pressure does not ric-e any.. more. Equilibrium dissociation proosure is usually beached within 20-30 min. Then the furnace temperature is raised by 20-3boc, and the initial temperature is re-established after 5-10 min, while the pressures are noted. Measurements also are taken each 500C up to 15000C. The test substance in chemically pure Fe 0 produced by thermal decomposition of 2 3 Mohr's salt. In some cases analytically pure Fe 20 .3 has been uned. The fbllowinS relation holds for the dia.,;ociation pressure as a function Qf 1/T: log PO 2 (atm) - 23,330/T + 13.52; hence, for the reaction (2'3)Fe30 4 + (1/6)0 2~== Fe 203between 1100 and 1500 C, the formation heat t2ff - 17-80 + 0.20 kcal/mole of Fe 20,, arid the heat of formation of Fe 20 3 fvom its elements -,'H - -191.8 kcal/mole, which agrees very well with the _ublished value (-192-5 kcal/mole). The change in free energy of the 1: -eaction 4Fe 0 + 0 3 4 2 6Fe203 calculated as a function of temperature from che equation L Z -4-575 T log K A . -4-575.T log p0 2 is -106.200 C,ird 2/0 _> S/07 62/007/006/003/024 Apparatus for measuring- the ... B124YB1 38 + 61.51 T(kcal/mole of 02). There are 4 figures and I table. The three most important English-language references ares L. S. Darken, R.'W. Gurry, J. Amer. Chem. Soc. 68, 799 (1946); J. Smiltens, J. Amer* Chem. Soo, 791 4877 (1957); J. P. Coughlin, USA Bureau of Mines, Bull- 542 (1954)- SUBMITTED: June 1, 1961 Card 34 - . 7 T"~ :; ~ -r .. r ,d . A . . : .,k - . . - 1: 1 . I .? , ~ I ;,. I -! I ? . -.. :. . NO mf~ff ~ijv jr) rMi E R ffmoLume mi, IBM- o=-= mm I I 997 ACCESI- I li lt~ AP) G'3 Yj A 1~7F T 7~, v . re ak Yu. Y, y L, TIT i~E: Corri! kat ion between dt icn prc. and 47 manganese-cor!t-aining U F'- E ~tvi 2 TOPIC TAG:~~ mangant~se ferr:~e ABST A c- Tar i w r- so lutii on Mn w j.13 S t a!-, i'y f'r, dn' the floqrs at Card 1/2 L 5,;L91-~77-6-- ACCESSIT4 NF: AP501 i 13~- FeI2 04 solid solutions and mixtures of levrLtes were MiasuciC in "he a00-12001C I Mn ~ I -,r te~iperature range. There is an -irregularitv between compoWiDn and the change of ~lattice paramater a of the solid soAtions of magnetite (FfiO4) ~nd heusuannite it:Lte win Kn- and M, ions. in vie uvu- Eemi;-~rdtUM vilit2u Lart,= zo a ~ut- betkeen---fhe - smoazotlon- --pressure-~:of --th6--m--a--nE.,e.--nese-cat~ziining, di -multicormo, - - L-ifion -i s- independent- Htd�~-ajl e cry att.ce:parame. e -r i-- natut~.~of~ c ,Ctm'olementarv- CqOE~6ne tG~-Ivesent-in -t:iei~mang' 2,-A.e-containing-1er- System, th-e- lattice parameter a in--re-ases in provortion Ito renlacement of Fe3t ions (r= 0.6'7 A), in Fe3+FFe2+Fe34lo4 ta-iahedra with Fn2t ions (r= 0.91 X). ~ivs-em. the chanF,,~,S 'T, --e ~-t:re :~afarmeler -a are smali siv.~,e Fe io-ns in tl~ e Kln' L Fe 3 J~ __ -- - -- -- -- - - Z- ne- -placed with"Mn -ions - Ov=-G.:16-1). ~ Oiclgi --ar-L i has, --2 t6les' auid 3 figurii~-s. ASSOCIATT04- ".imicheskiy fakulltet Kosko,~--ikogo gosudarstvenn-j,- univor-s-iter-3 im. W SUBMITTED; DiFeL64 ENCL; 0-j S'S INO REF GOV: 006 U."HERs 108 [Room= L 54996--65 ~q-T (1 )1WG( WENT, (M)AFF c a.4 F I'M c ACCESSIOU UP: AP50119 3 (4 ,AUTHOR: Tret-1-jakov, Yu. D. TITLE: Thervadvnamid-determination of redox equilibrium in mang4me;3e ferrite SOURCE: All SSSR. 11-Vestiya. Neorganicheskiye materialy, v, 1, nr ,TOPIC TAGS: numganese ferrite, manganese, redox equilibrium. irjr distrlbut:cn, phase equilibr-.um ABSTRACT- Equilibrium ion distribution in manvanese ferritfiat 129')OC rs deter- *Jibrium t- zz-,r,,te i .,nj r.~rrl rained froui e)-pftrj'-,,e7rt;--1 data on phase eql'i, i v i ts a r -5-, -6 7 -3 and' I-e7* LCard 1/2 formu-3, -Orig. art. has: 12 formulas. ASSOCIATTON: Khimicheskiy fak-jl'tet M~-SkQVSK-gl-, gosjdarsl~~iennogc oiver~ it(-ta -h e mi s t r-1; -DW Ve M Card 2/2 TOM T7 AUMOR: Ole fnilkov, N. N. Saksanov, Yu. G.; lret'yakov, Yu. D. gy S O,)-K CE AIN -)SSR. zve st --7Z3- :7-e S, 7~i -era 2, !qF-5, 2-5- TOPTC TAGS., magnesium oxide, ferrous oxide ferrite phase dial(rLm, ferric oxide, phase equilibr,iiim, ternery -fe-r-rite sys'.-2 T'hP nurn--se -,f !his work was ARSTRA( the measir-ems-nts of Dhase eq,-iili- i -.Af I -Ti 'm -1) -1-M I ~A 1AnA Iv- iqot, L 55031-65 ACCESSION ~f~: AP5OOq376 sv-stem a~ variable presstff~-'s A -T. Vhj M! -~,p Ski V f 3k-~j Rrw9lidars tvennogo universi teta SUBMITTED~ 2Wui64 ENCL: 01 SUB CODE: 1c, M11 NO REF SOV: 004 0111ER: 01.7 M�RM -am gz-jmmm - mm ms I W-N Imammi Fe 2~'; I k 66Y-id 3/3 him a MEAN ice -mss a! !,AOOIC a- Pm 85753 B/iaq/6o/ooo/oo3/OO7/O13/XX fj 11.3 o o 0 ;_P3 , /a V-3 B003/W67 AUTHORSs Trptlyakov, Yu. D., Khomyakov, K. G~ ---------- TITLEi Study of the Physico.-chemical Properties of Certain ~N Ferrites Whch Were Obtaine( fferent Methods. I V _~ by Di I - 7r_o_d_u_c_tTon of the Perrites"'bf Manganeselind CoRpejrlby Thermal Decomposition of Isomorphous Solid Solutions of the Sulfates PERIODICAL: Vestnik Moskovskogo universiteta. Seriya 2, khimiya, 1960, No, J~ pp, 31-36 TEXT: The authors point to the insufficiencies of the ceram,-cally produced ferrites with respect to optimum electric and magnetic properties; the study of these properties is connected with great dif- ficulties. The shortcomings are due to the type of preparation which in all cases leads only to homogeneous mixtures of the initial substances. The authors made the following experiments for producing completely homogeneous ferrites: 1) production of solid isomorphous solutions of La and Fe sulfate (double salt) as well as Mn-, Fe- and Cu-sulfate by Card 1/4 85753 Study of the Physloo-chemical Propertititi of 3/1 fig/60/000/00 3/007/01 31XX Certain Ferrites Which Were Obtained by BOO3/BO67 Different Methods. I. Production of the Ferrites of Manganese and Copper by Thermal Decompositicn of Isomorphous Solid Solutions of the Sulfates Isothermal evaporation with constant salt concentrations in the solutions to be evaporated, The apparatus used for this purpose is schematically shown in Fig. 2. The original paper contains detailed theoretical explanations (Fig. 1),, An isomorphous mixture of the composition (1/3 Mn, 2/3 Pe) SO 4" (NH 4)2 so 4' 6H20 was necessary for preparing MnFe2o4bX Mohr's salt,, (NH 4)2SO4 and CuSO4(chemically pure) which were recrystal- lized from bidistilled water as well as MnSO obtained by dissolving 4 D electrolytic - Mn (99-95%) in 3ulfuric acid (chemically pure) served as initial sub:3tances. The content of foreign admixtures of the Purified substances (determined b~ spectrum analysis) was at the order of magnitude of jo-3 to 10- %(Table), 2) The thermal decomposition of the isomorphous mixtures was made on air at 800 and 9000C and in the C02- or N2 current at 8000C, Fig., 2 shows the curves of the thermal decomposition Card 2/4 85753 Study of the Physico--chemlcal Pro,,eities of S/189/60/000/003/007/013/Z). Certain Ferrites Which Were Obtainod Iny B003/BO67 Different Methods. I. Production of th:.- Ferrites of Manganese and Copper by Thermal Decomposition of Isomorphous Solid Solutions of the Sulfates of the isomo:rphous Mn-Fe sulfates in the air current at 800 and 900 0C (in the time - weight per cent diagram the weight of the m-'xtures men- tioned first rapidly decreases, then remains constant) as well as MnSO 4 at 800 C (flat decrease of weight with time), In the case of thermal decomposition in the air current a completely nonmagnetic oxide mixture was obtained according to the composition Fe2o 3+-Mn2o 3' A decomposition in the C02 current led to a strong magnetic mixture of the composition MnO+Fe2O 3(=MnFe204)., Hence the changes of the valence states of the metal ions can be controlled and completely homogeneous products can be obtained by using an isomorphous mixture. There are 3 figure3, 1 table, and 9 references: Ii Soviet, 1 US, 2 French, and 1 British,. Card 3/4 (35753 Study of the Physico-chemical Properties of S/189/60/000/00"/007/ /01 71XX Certain Ferrites Which Were Obtained by B003/Bo67 Different Methods., I, Production of the Ferrites of Manganese and Copper by Thermal Decomposition of Isomorphous Solid Solutions of the Sulfates ASSOCIATION: Moskovskiy universitet, Kafedra obshchey khimii (Moscow University, Chair of General Chemistry) SUBMITTED: June 30, 1959 Card 4/4 T RE T1AK912 J U.0. - SPIKSOIAW GUORDEYEV, I V. 41'hasp- diagrii.-i r;f' '~~a !3ystu-f---m F-c-0 ~b 3()4 - yX-PI IL- iind the theznriodynamlc of' coexistlrg phases. lz,,r. All V)SOOR. Neorg. ma~-- L n-;.3,413-418 I-b, '65. (14'a"l Moskovskiy g6sudar~itvenrjnr universitet imcni LCTOnO3OVa, 1,himic,he~3My frtkullti!t, Cry3tal t hu~rjl, -)n manganr;~o r f N r i~- rr c 'Mr 165, "Ly'y A N SSSIR. ro. no 7 1. MookovskJ.y khiridchask.ty fak-al I tet. At TRETIYAKOV Yu.D.; OLEYNIKOV, N.N. Estimation of the defectiveness of spinel structures based on chemical analysis data. Zhur.neorg.khim. 10 no.8:1940-1942 Ag 165. (IMIRA 19:1) 1. Submitted October 6, 1)64. -TRIMAKOV, Yu.D.; MIOMYAKOV, K.G. P~ M, Heat capacit7 of the intermetallic coarpound CoAl after various thermal treatments* Zhureneorgokhime 4 no.1:13-16 Ja '59- (MIRA 12:2) (Cobalt--Aluminum alloya) (Heat capacity) TRLPTIYAK(Z,ZRd,D.; TROSHKINA. V.A.; IHOMYAKOV, K.G. Adiabatic calorimeter working on the principle of continuous heating. Zhureneorge)(him. 4 no-1:5-12 -Ta '59. (MM 12:2) 1 (Calorimetera) TRET I YPI:OV. Yu.D. Synthesis of rare earth ferrites of predeterminaA composition. Vest.1look. un. Sar.2: Mim. 18 no.4:59-60 Jl-Ag 163. (MIRA 16:9) I. Kataclra obslichey kchimii Moskovskago univeruitata. (Rare earth ferrites) .TRET'YAXOyv_ju_.D.; KHOWAKOV, K.G. Apparatus for measuring the dissociation pressure of ferrites and oxides at high temperatures. Zhur.neorg.khim. 7 no.6: 1219-1224 Je 162. (MIRA 15:6) (Ferrates) L 17R29-4b--' E7,-:PqEWT m HDS ACCESSION' Nr: AP3004693 A=OR- -Trejr4yakov. Yu. TITLE: SyntheSiS of rare-earth ferrites of a predetermined composition SOME: Moscow. Universitet. Vestnik. Seriya II. Khimiya, no. 4, 1963, 59-60 TOPIC TAGS: garnet, ferrite, iron, yttrium, yttrium iron garnet, yttrium iron prnet synthe-sis, yttrium iron garnet stoichiometric composition, rare-earth Territe, mixed garnet, stoichiometric composition, garnet material, syntheais,, 4oprecipitation method r WTRACT: A neV Lcoprecipitation) method has been developed for synthesizing Aftrium. iron garnets of strictly stoichiomtric composition for re:;earch P-Irposes. The new process requires less time then other knawm mathods and utilizer. ialnim= quantities of starting materials. The Y20, Is dissolved in JR10 and vit t:ae same VLm, naebonyl ironis;dismlvedin ~,ot H,-S04 and then oxidlzed Ult~ H Ot. Thj,,~ tvo solutlons are mirxd at 10C or 10VC--3', and added tn -oncentrated NT-40H aB th'! MIX- tiwe. -5 subJected to intimate mechimical mixing. The resulting coprecipitated yttrium and Iron h-~dxroxidaas are centrifuged, triturated in the presence of a - nfLaf and dried at 100-150C for 24 hr. The product is aEaln triturated with water., card L 17829-63 AcxEssim im: Ap3oo4693 A yield of -ed, and 16 then bold at 1000C for seveial hours 96-99% was obtaii vith a composition as follows: Fe20~, 54.35%; Y203; 45.64,1',; and W', leso than 0.01%. The method describid may be used to obtain any rare earth ferrites desired. It is particularly valuable for preparing ferrite garnets which are strictly stoi- chio=etric in composition, and "mixed" garneets in uhich the additional ions must be uniformly dispersed throughout the solid. ASSOCIATION: Moskovskiy Universitet, Kafedra obshchey Ichirnii Department of General Chemistry) -~moscoy Uriversity, swu=: owov62 DATE ACQ: 06SeP63 SUB CODE; CH I NO REP SOV; 005 i- 7.- Co rd ~-'.2/2 ENCL: 00 OrHM: 007