SCIENTIFIC ABSTRACT TROSTYANSKAYA, YE.B. - TROSZKIEWICZ, Z.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001756730010-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 62
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 10
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

1/2 UDC: 678:539.4.019

T 'IS T
74- UVISK9A, NEFETO-11f., G.Z.
Insoluble pclyr~lectrclytes vith mobile Puncticnall gToupc..
Vysakom.soed. 7 no.10s!767-1770 0 165,
ONIIRA.
', Institut chi.stfkh roaktivov i osobo chistykh kbilnicheskikh
vep:lchostr.

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-AP5
622229

L -20375-66 DIT (d)/E%T (M)/E-.rp (v)/j4p(j)/T/EWF (t)/TEWP(k)/a1P(h)/EWP (-I-)/ETC (Im) -6
ACC NR: AP6006541 JD -SOURCE
(A) UR/0191/65/COO/011/0022/0027,
RM
Komarovq G. V.; Shishkint V. A*
AUTHORS. ~rostyanskaya, Ye. B.;
ORG: none
TITLE;i
-io-Lid of hardened plastics by the method of chemical weY -ig,
SOURCE: Plasticheskiy
e massy, no. il, 1965, 22-27
TOPIC TAGS: polymei-, -iflastic, ultrasonic welding, welding technology, we
Id
evali~ation, adhesive bonding
ABSTRACT: The object of the investigation was to test currently held theories on,
and to study the optimum conditions for, chemical, welding of hardened plastics Tbo
Kcycle)*welaing installa-~
welding was accomplished by~a high-frequency (1."i Kwt,.,?O-
tion and ultrasonic weld installation of type MP-1kAtilizing a generator of
type UZG-10. Microsections of the welds,*ireparel after V. bf. Gaterman, A. M.
Koganp and M. M.Notina (Plasto massy* Now 4P A 1960)t wore investigated by
mto~rophotography. The weld.strength of the various welds was detenainedp and the
increase in temperature in the weld during welding was measured. The experimental
results are presented graphically (see Fig, 1), aad-a table in which the strength
__._uDc:__.678.O29_-43J'

--20375-66
i. 'A.- Ap6oo6541
r
Fig. 1. Rate of temperature increase in zva -
the weld during the h~f-freq4enqy welding f8,0 -
ass-textolite KAST41"'of 1.5 Mm
of the gl
thickness (ar;a of welT-3 am") and 6 mm
1410-
(area of weld 8 cm2). Field strength:
KAST-Vj 1-5 mm thibk.- 1 ~-- 2.0 /Zo
IMAM; 2 - 2.9 kv/cm; 3 - 3-0 kvlcm; 4 fog
4-4 kVCm- ( ------ ) KAST-Vp'6 mm thick:
.25 kv/cm; 2 - 1-75 kv/cm; 3 2.0
1,-V/cm, 4 2-5 kv/cm-
timep sec.
lof welded and glued bonds is compared is,presented. It is concluded that at room
itemperatures'welded bonds are of the same strength as glued bonds ane. are superior
.~to the latter at high temperatures. Orig. art. hast I table a-~d 9 graphs.
'SO CODE: 13,111/ MM DATE: none/ ORIG REPS 016/ OTH Ws 006
-2 9 vib
T

TROSTYANS.KAYAO Ys.B.; POYMANOV, A.M.; SKOROVA A.V.
Chemical reactions on the surface of glass fibers used for
the production of glass reinforced plastics. Plast. massy
no.11:67-69 165. (MIRA 18:12)

V -_-1b5l&66,N
ACC NR: AP6001494 7 SOURCE CODE: UR/0191/65/000/=/0012/0014
AUTHORSt Trostyanskaya, ye, B.; Venkova, Ye. S.; Pav12n.L__A-P-
ORG: none
I TITLEs Structural pTasticization of epoxide resins6l
SOURCE:- Plasticheskiye maqsy, no. 12.. 1965., 12-14
TOPIC TAGS: epozy plastic., plasticizer,-copolymerp adhesive ED-6 epoxide resin
ABSTRACT: This article deals with the preparation of phorylic resins (molecular
-weight of 4 0
00--600) by polycondensati n of monophanylphosphate dichloroanhydride
-with - rbsorcinol lkydroq no-(II)-* p-p1-dihydroxydiphenV1w_thane,, and
-opropand.Adcording to a method described __(U. S.
ppp -~dihjydro_VdJpheny.11s -earlier
Pat..2616873;,Brit. Pat. 679834)., Preparation and pr9perties of bulk copolymer
obtained by.additio f or-II-to described.--The-
work- waa undertaken- in order- to improve the inipact-strenkthAhnd adhesive proper-
ties of polyepoxides. It was established that phorylic resins i~ bulk polymers
function as structural plasticizers, condiderably increasing impact and tensile
strength of cast products and of adhesivelfilms, at the same time lowering their
Card 1/2
ITDC: 678-6404205-678 04.9

TROS'"Y,kN5KAYA,q Y!3913*; WFEDOVA CIZ,
Iwolubl,- -780
polycmplezons. Zh=. anal -Vi: ~.,r. PO no.
165.
1. VsesDyuwi7y
r-3aktivov i osabo chl~itqkh (,!os,-cva.

CC NR: AV00009Y1.
SOURCE CqDE: UR102bb/65/000/022/00561005
15
INMiTOR: T ostyanskaya, Ye. B. Komarov, G. V.; Shishkin, V. A.
ORG: none
TITLE: Bondinj cured glass-reinforceq_RLSLtics. Class 39, No. 176388
SGUERCE- Byu_lleten' 22, 1965, 56
TOPIC TAGS:. glass.,reinforced plastic, chemical bonding, unsaturated polyester,,
Pali
ABSTRACT: An Author Certificate has been issued for a method for bonding glass-reinT
forced plastics based on. unsaturated polyesters or other binders which can be cureO
lyadditional - p-ol,rization.- The metbod-involves coating of the surfaces to-be bonded
,yme
-with- amonomer (e-g-, styrene) solution with added polymerization Initiator, joining
of the surfaces, and iligh-----fl~le-q--u--e-nc-y---oz~- ultrasonic- heating. -pr - --- ---
SUB CODE: .11 SUBM DATE: 24Sep62/ ATD PRESS-
6,u8.744.3-i34,622.0?9.42:621,3.023

RM
ACC W AP5026525 SOURCE COD32 -U-k/6-2-06-/65-/O-Cio--/Olow5~roo-O
AUTHORSi TrostyanBkaya, Te. B.; Shishkin, V. A.; Golovkin, G. S.; Nomarov, G. V.
ORGi none
TITLEt A method for vuloanizing. Glass 399 No._17$221
SOURCE: Byulletenl izoibretenly i toyarnykb- shakovg noo U99 196,50- 60-
TOPIG TAGS: vulcanization, rubtr.~'Wnomers initiator
ABSTRACTt This Author Certificate presents a method for vulcanizing* To increase.
the:strength and thermal stability of the unions the surfaces of the J'uzztion are
covered with a mixture of a proper monomer and an initiator or with a vulcanizing
agent. The surfaces are then brought into contact with one anathers and the zone of
contact is heated intensely,
SUB CODEs' is/ SUBM DATEs 05KAA
Card. 1/1 UIDC t
s621-9792*05

-(m)/EWA(d)/5JP(J)/T/L1TC(m)-6 WWIPIVWH
L 20382-66 EWF'.a)/tVn.
ACC NRt AP600650 (A) SOURCE COM UR/0191/65/000/01-1/0067/0069
AUTHORS: Trostyanskaya, Ye. B.; Poymanov, A. H.; Skorovap A* V.
7D
ORG: none
s used in the manufacture
TITLE: Chemical reactions on the surface of
of fiber-glas
s plastics/
SOME: Plasticheskiye massy, no. 11, 1965., 67-69
i TOPIC TAGS: fiber aass., polymer, epoxy plastic, silicon quartz surface active
agent, glass fiber, silicon, glass, quartz, cbemical reaction, surface ionization
ABSTRACT: It was the object,of this investigation to find uuitabl"onditions fort,
the modification of surfaceslor glass, siliconp and uarta fibers*J~The modifica-
q
i tion was carried out Vy the cherrdcal addition of organic radicals to the surface..
according to the schemes
C1
-S
~SJ-OH + SMIS jC1 + Sol + 14
-S C1 4- BrMgR -R + Mg8rcl
and
Card 1/2
um i 666.169.211&6-t7.862.

L 20382-66
ACC NRt AP6
0
E:SI-Cl + K-0-C-C=CH,
where R trimethylsilanes allYl, ethyls phe.V1, or methacryl respectively. The
contact angle of whetting and electrical surface conductivity of the modified
surfaces were determined after the method of Ye. B. Trostyanskeyal A. M. Poymanov.,;
and Yu. X. Kazanskiy (Plast. ma!ssyg No- 7., 1964). The experimental results are
tabulated. It was found that substitution of mono- and divalent ions by tri- ea.
he modified surfaces enhances the bydrophobic; nature of the
tetravalent ions on t
latter and eliminates the retarding action of the surface hydroxyl. groups on whn
rate of-hardening-of polycondensation type binders, thus improving, the qualities
of the fiber-glass plasttotif -Origbarti--hast 4 equations.
SUB COM 11/ SUBM DAM none/ ORIG REFt 008/ OTH FM t 007
_------------ ------
Ymb

~6~ EwT(x)/w(j)/T/F.TC(= .6 WwjRx
7"~
CC NRt rW008402 (A) SOURCE CODE: UR/03T4/66/ooo/ool/O067/OOT3
AUTHOR: Trostyanskaya,-Ye. B.; Novikov, V. U.; ~azanskiy,_Yu. N. 4Z
13
ORG: Moscow Aviation Technological Institute (Moskovskiy aviatsionno-tekhnologichesmy
institut)
TITLE: Effect of increased temperatures on the stren&th of solidified resins and
of materials of the same base. 1. Effect of increased temperatures on the strengt
of solidified phenolformaldehyde resins
SOURCE: Mekhanika polimerov. no. 1, 1966, 67-73
TOPIC TAGS: resin, phenolformaldehyde, temperature dependence, tensile strength,
compressive strength, thermal effect
ABSTRACT: An investigation of changes in tensile strength and of weight diminution
in phenolformaidehyde resins was carried out under high temperature conditions. It
was revealed that a spontaneous trannition from the first to the second and third
structural stages takes place with concomitant increase in the stabilization of
strength properties in the process of thermal destruction. In all the resins in-
vestigated and for every structural stage, the direct dependence between the relative
change of ultimate compression strength and the relative change of weight were
established irrespective of the conditions of thermal treatment. The investigation
was carried out on standard samples obtained by molding a mixture of hardened resin
and powder of the same, but preliminarily hardened, resin. Samples produccd in this
ard 112 upc: 678:539.4.oig.3

RM4
L20M.66.
ACC NRs M600402
way have better physical and mechanical properties in comparison with articles
made of molding powders with an inactive filler. The lowest w ght.diminution In
the process of transition from one stage to another is typical of the phenolic-
furfural-formaldehyde resins, and the highest degree of strength retention is typical
of the phenolic-aniline-formaldehyde resins. Orig. art. has: 9 figures and 2 tables.
[Baaedron authors' abstract.] ENT]
SLJB:CODE.-//,2,4/ SUBM DATE: 16Feb65/ ORIG REF: 0091 OTH RM 008/
Car ;212

V
L-Card
E61,
ACC M AP6023429 SOURCE CODE:
AUTHOR:'Trostyanskaya, Ye. B.; Venkovu, Ye. S.; Aristovskaya, L. V.
ORG: --scow Aviation Technology Institute (Moskovskiy aviatsionnyy tekhnologicheskiy
nstitut)
i
TITLE. Polycondensation of tris(hydroxymethyl)phosphine oxidelvith phenols
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 7, 1966, 1219-1225
TOPIC TAGS.: organic phosphorus compound, alkylphosphine oxide, polymerization rate,
polycondensation, catalytic polymerization, heat resistant plastic, thermosetting
material, phenolic plastic
ABSTRACT: Controversial data on the reaction of tris(hydroxymethyl)phosphine oxide
(TWO) with phenol prompted a study of the reactions of TM with phenol, resorcinol,
and phloroglucinol. The purpose of the study was to Prepare phosphorus containing
esistancelcn -the absence of a catalyst
_polvmers with increased heat and strength PI
the reac ion with phenol at 160-200C yielded only a phenol-formaldehyde type resini"'
with a low polycondensation rate because of predominant splitting of TMPO. In the
presence of a BF -phenol complex (in cat the rate of polycondensation was in-
L ed
creased and at 145C in 8 hr the reactio y ~11 30 wt% of an insoluble, thermosettinE
phenol-TMPO resin with high phosphorus I he polycondensation rate was further
increased in the reaction with resorcinol and even more so with phloroglucinol. Chem-
ical analysis of the reaction products at various stages of polycondensation indicatee
1/2 UDC: 541.64+678.86

L 35857-66
F,_ACE_14R_.._AP6023 t29
a nearly total polycondensation of TWO with resorcinol and total with phloroglucinol.
-Final polycondensation products with both resorcinol and phloroglucirol were insoluble
thermosetting resins with nearly theoretical phosphorus content (10.9-11.4% P).
Physicomechanical characteristics (Table 1) of the synthesized and hardened P-contain-
Ang polymers are comparable to those of the phenol-formaldehyde resins, but their
beat resistance is significantly higher. A sharp increase in deformation was observed
Table 1. Properties of compacted TMPO-resorcinol
0 900(14~ iar
ffeatrtsIstance at
4-)
Resin h H,
4) 0 CJ4-1 Coke
~4 bD-- W
type pidon, BurnIrg Flame residue,,
P' -4 7 see. time,
0,11 0 .. %
01 0 ~ 'see.,
20-25 52,6
TWO --xesoidm 4,46 0,~ 7-~
70 5,551
ng,
75D 5i62 4,68 0 191,16% 9
MMPO-phloro-
f glucinol
at 260-270C for TMPO-resorcinol resin and at 320-350C for TMPO-phlorogl:ucinol resin.
Orig. art. has: 6 tables. [JK)
SUB CODE: 07/ SUBM DATE: iijun65/ ORIG REF: 0061 'ORIG REF: 007/ ATD PRESS
Card 2/2 ~;_o 13

yjyA Ye.B.; V1140GO.M2V.14.; KAZANSKIY, Yu*No
TRCSTUW.~t~A Ounds based on hardening polyesters#
Molding c(=P Plaat-mas-Sy 40.1o:14-16
polygiter glass fibers* (KUU 15:11)
162. (cams afibers)
(F,sters)

LA0394-67 W(m) DSAK
SOURCE CODE: 0
A
cc 1414 03 175
A
AUTHOR t Makarova. S. B*
1~rostjMskayap
ORG3.
All-Union Scientific Research Institute of Chemical Reagents ar-1 Especially
ftie Chemical Sibstances (Voesoyuznyy nauchno-isslea6v~tellskiy in
kh#Acheakikh reaktivov i osobo chistykh khimicheakikh veshchestv)
longing to the class of onium compounds
TITIE: on-exchange resins
-SOURCE: Zhurnal prikladnoy i. v. 39,, no. 8. 19660 175471760
'TOPIC TAGS: anion exchange resin,, chromatography,, c
opolymer, styrene, vinyl compourA
ABSTRACT: Chroikt * phic'separation of ions from sait solutions requires that:
ogra
i Oe ion-wc6hange resin possess watifunctiopality., ~a high degree of ionization
i-in a broad range of pH valuesp and a high rate of establishment of equilibrium
"in the exchange reaction with ions of the solution, Copolymers of styrene with
divinylbonzene and styrene with divinyl with various -amounts of the bridge.
1:forming component in the copolpwr,, were used to synthesize anion-exchange
*luenco of structure of the macromolecules up 9.
resins for a study of the ini on th
ion-exchange properties of the, resins, The copolymers were chlorovothylated,
and then'the chlorine atom replaced by aminesp phosphines, or sulfidea. Anion.
exchange resins with su.1fonium, and phosphadum structural groups wer3 roadily
decomposed in solutions 6f alkal j anion-oxchanje r6ins tested with aui6niwi
functional groups acquired the.structure of basesq the degree,ofassociAtion of
'which was determined by the structure of the radicals on'the quaternary
Idtrogen. The therml.stability of the aidon-exchmge resins In the siai forn-
decreased In the aftlei &MMI= > phogizoniva > saradm cam As. The. -
uDc..-- 661.1a3-123
d 2
0 9"3,1-

L 10394-67
ACC NRI AP7003121

:degree of swelling of the ani6fi~-~hange "resins was detiritin~d by the stmcture'

of the briAge-4orming components with substantial2y greater mielling observed ;
-exchange resins produced on the basis of the styrene-divinyl
Aimong anion
copo3ytwr. The rate of exchange of ions fion salt solutions was found to be
determined by the macromolecular structure of the anion-exchange resin. For
ion-exchange equilibrium was established within 15
',ptyrene-avinyl polymers
,,
-whereas the-styrene-divinylbenzene anion-exchange resins were less
wanutes
*dtable for obromatographiq purposes,, estabUshmmt of ion-exchange -equi.Ubrl=~'
varied Uth2s ...within AbA, PH
'rnWrin five to 20 hours The exchange capacity
.
-"
'
ar
range 3
OAi-
b.! has: -3 figured' and 3 tables IJPRSI'
'. A9701
.

O 67 --"S= 4,
ORIG MW;.*,-
12Wu16
~.g= AM
4

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A

PHASE I BOO X EXPLA)ITATION
International symposium ots macromolecular chemistry. Moscow.
1960.
0
Kezhdu narodnyy aLopozium pa makromolokulyamoy khImI1. SSSR,
toreferaty
I a
k1
d
6 V1
.
v
a
0 S. ; do
Moskva, 14-18 ITunya 1�
y
Saktalya III. (International Symposium on Xacromole--alar
Chodstry Hold in Moscow, June 14-18, 2960; Papers a-d
Summaries) Section III. [Moscow, lzd_vo All SSSR, 19601
469 V. 55.000 copies printed.
Tech. Ed.: P. S. Kaah1na.
Sponsoring Aeoncys The International Union of Pure and Applied
ChesaLstry. Commission on M4cromolocular Chemistry.

PURPOSE: ThIs book in 1ntend6d fa r chemists Interested in poly-
marization reactions and the synthesis of high molecular
compounds.
cOVERAM Thin in section III or a majitivolume, work contain.
ins papers on macromoiecular chemistry. The articles in
general deal with the kinetics of polymerization reactlon
the synthesis of special-purpose polymers, e.g.. Lon *x-
::

change resins, semiconductor materials, etc., methods of
t
alYzIng P01"arization reactions, properties and chemIcal
Interactions

efr*cta
molecular
mater.-als, and the
of high
of
Various factors on polymerization and the degradation or
high molecular compounds. No personalities are ient-loned,
References given follow the articles.
ek T. I., and lo-Inatlon or
J~ Knn~.t (Poland). Ch
rhenol-Formaldshyde Resins 27
(ThLYanLa).
Zt.Zl and I
ropyl Ethers of Polyvinyl Alcohol 34
!Akubovlch, A. Yj- D.-TI-0221=1
Oasia lan an d
-9v3
tft.'Ch'em'ic'a1" 44
_Study-of Conversions of Polycarbonat*5
Do=dkin, J.A I M. 4. Polldshte , and X--X-_seI7AWa= (MR
Chemical Intars ion and Kechaninm of the Activating Action
-of Double-Syntems of Vulcanization Accelerators 65
Finm x I r. Voroblyeva. V,_A,
_�hIZAkari. and ?I, P~
130wehAveva. UiSRT----E-nt-e-r&--oTZalrurIc Acid and Polyvinyl
Alcohol 73

""h'r
TtLurT~ (Hangsry). The lnter~
I and 2~
,
0
t1on of ArematLen
noo and Yolyvinyl Chloride 79

chlev. ,nd R. n~~I;enKo
Kifi~
l
l
or
ion o Po
ymer c teria
s ch
-
Sealconductor Properties

5
XLk4&-J--A_ and L._jA-Xu4jURung4ry). chemicai Propertie s
Of Bipolar Ion-E=Fange Resins 93
X., and J. xoraviec (Poland). Effect or the Stru,.,-
tars or Organic Asirn-o-Co-opou-n-ds on.the Properties of Anion
From Po lys ty'rens
Saldadzt. K.. M. (USSR). The Problem of the Frfect of the
-
-
-
-
-Ttruc tu
ra
o
hi too on Ion-Fxchange"Proce5ses Bet.don
Fro
XonItes and Electrolyte Solutions 107 1
Bor"n
A- A.. (USSR).
,
rrd,. ron=nd Proportion of Som Aromatic Polymers IX5
Troaltyanskarix. Le. Y, , 1. P. v, A. S. Tevitna. S. 1j.
-
Ega

m
and
-jao (IROAJ. Chemical
"
R31 eo
B:k 17 -
Z1
C rolona
r ;
.
n, r
n-.olu I opolymerr, of Styrene
C
124
T-Ifte, man. J- jpol.~knd). Thermal Stability or Strongly- Bio-';;
-
F
Anion
U
F4"ge Rosins 146 WO

161

BUTOVSKAYAt Ye.M.; KON'KOV, M.; VERSESOV, I.L.; PAK, V.A.;
TROSTYANSKIY., G-D.-* ULOMOV, V.I.; SOKOLOVA$ A.A., red.;
~, Z.I., tekhn.red.
(Seismism of Uzbekistan] Seismichnost' Uzbekistana. Tashkent,,
Izd-vo Akad,nauk Uzbekskoi SSR. Vol.l. (The Fergana Valley]
Ferganskais. dolina. 1961. 97 p. (~MU 15:5)
1. Akademiya nauk Uzbekskoy SSR. Institut matematiki.
(Fergana-Seismology)

SEYDUZOVA, S.S.; GROSS, I.Ch.; YESINA, A.I.; TROSTYANSKIY, G.D.
Regularities in the attenuation with distance of the de"ity, of the.
energy flow of seismic vibrations at periods of 0.3 to ei9 seconds
in Central Asia. Trudy Inst. mat. AN Uz. SSR no.25:133-146 162.
(KMA 16:8)
(Soviet Central Asia-Seismology)

77,~ X-V'S
TROSZCZYNSKI, J.
From the Normandy beaches.
P. 4 (Zolnierz Polski) No. 22, Oct. 1957, Warszawa, Poland
SO: MONTHLY INDEX OF EAST FJROPEAN ACCES~-IONS (ELAI) LC, VU- 7, NO. 1, JIN. 1953

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h4ve Wfliiii,~4riA by the lictital of KSI1 till tile Lurre.;Xmiding .00
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IROSZKIEWICZ, Czeslaw; GOSZGZYNSKI, Stefan
Cyclization of benzylideneacetone and A --methylbenzylideneacetone
oximes to the quinoline nucleus. Rocz chemii 37 no. 7/8:919-920
163.
1. Depirtment of Organic Chemistry, Institute of Technology,
Gliwice.

GLINKA. Jadwiga; TROSZ~~GZ, Czealawa
Synthesis of quinoline nucleus by cyclization of oximez. Rocz
chem-li 37 no.12::L643-164/+ 163.
1. Department of Grganic Chemistry, Technical University, Gdansk.

PRAJSNAR., Bronislaw; TROSZKIEWICZ, Czeslaw
Alkylation-,of aromatic compounds with substituted amides
FMCQRt and other reactions of amides in the presence of
POC13. RoQz chamii 36 no.5:853-86~ 162.
1. Department of Organic Chemistry# Technical University,,
Gliwice.

PP4MNAR, Bronislaw; I~IOSZKIEWICZ, Czeslaw
Structure of the benzyl group structure of the amide
ArCMMCOC6H5 abd'Its influence upon the course of the
bensylation reaction of aromatic compounAs. Rocz chemii
36 no.5:843451 162.
1* Department of Organic Chemistry., Technical University..
Gliwice,

PWSNAR, Bronislaw; TROSZKIEWICZ, Czeslawa
influonce of the structure of the remaining acyl group in
C6H 5CH2flHC0R amide in the course of benzy1ation of aromatic
compounds. Rocz chemii 36 no.2:265-274 162.
1. Department of Organic Chemistry, Silesian Institute of
Technology, Gliwice.

8/0 81/62/000/021/06/069
B156/BIOI
AUrHORSt Prajanar, Bronislaw, Troszkiessioxf Czeslawo.
TITLEt Relationship between the ptoperties-of alkylating H-benzyl-
amides and the nature of the condensing agent
PERIODICALt Referativnyy zhurnal. Xhimiya, no. 21, 1962, 148, abstract
21Zh1O8 (Roczn. chem.0' ve 35, no. 6, 19619 1635 - 1639 LPol.;
summaries in Ruse. and Fng.]) . -
TEXTs When m-xylene (I) is benzylized by the action of C 6H 5CH 2NHCOC 6H5
(II) in the presence of dehydrating and condensing substances (DCS)
LP2 05 (111), POC1 3 (IV), PCI 51 PBr 5' PC139 SOC12 or A'C~13)1 products of
mono- and dibenzylizing, are only obtained ihen using III or IV. The by-
products are C 6H 5CH2C1 _'(Y)j C05" (VI) and KC1, their formation being
Sossible by the following schemes II + PC1 5 ---;YC6H5CH2 N-CClC6 H5 (VII)
+ POC1 3;- when heated, VII decomposes to form V and VI; VIII + H20
It C 6 H5CH3(VIII) and anisole (IX) have been bentylized by the action of
Card 1/3

S/081/62/000/021/016/069
Relationship between the... B156/B101
C6H5 CH2 NHCOCH3(X) in the presence of IV. According to Schotten-Baumann,
30 g C6H5 CH2 NH2 (XI) and 55 g 06H5COCI yield 95-3 % II, M-P- 106 - 107'C-
After 25 g XI and 30 g C6H 5 COOH have been heated at 160 - 1600C for 6 hrs,
the total yield of II from the melt is 79-1 %-* 0.1 moles 11, 100 ml I, and
a corresponding amount of DCS are heated for 3 hre at 1200C (reflux con-
denser; the P 2 05is added in two batchest 35 9 at the start, and a further
20 9 30 min later); when cool, it is dissociated with ice, and after a few
hours 20 ml I are drawn off with the water layert and the reaction products
separated from the combined organic layers. The DCS are given, also the
benzylizing products of I, the other reaction products, and the amount of
recovered II in 9s 55 9 111, 57.3 % monobenzy!-I (XII) and 9.8 % dibenzyl-
I (XIII), 5.7 g VI, -; 37 g IVt 71-5 % XII and 9.8 % XIII, 164 9 V, 9.2 g
V! and HCl, -; 42 g PCI 5t -, 5-76e;V,1-59 9 VI and H01, 11-5; 90 g PBr 5'
-, 44 9 of a liquid substance with a boilDig point of 70 - 90OC/16 mm, Bg coA-
(content of VI 6-4 9, content of Br 34.1 %) and HCI# 4.21 50 9 FC13' -,
0o15 9 Vs 0.1 g VI and HCl, 14; 71 jr SOC121 -t 1.32 g Y# 1.16 g VI and'Helt
Card 2/3

B/081/62/000/021/016/069
Relationship between the, B156/B101
13.2; 42 g AlCl3 (in toluene), solid unidentified produo.t, -. For 3 bra
25 g X, 66 g IV and 150 ml of It VIII or IX are heated at 12000; they are
dissociated with ice, and the products of the.reaction separated (the
initial substance and the reaction products are.given)t VIII, 45.6 %
benzyl toluene (b.p. 139 - 14100/1, mjn gg, 20 1.5715)9 7-05 A of di-
nb
benzyl toluene (-b.p. 215 - 235OC/ii mm-H9, n20 16955) and 11.8%-V; I,
20
46.1 % xii (b.p. 157 - 158OC/14 ma Hg, nD 1.5697), 3 % XIII (b.p. 235
20
2450C/12 mm Hg, nD 1-5972) and 9-4% V, b.p. 60 - 7000/11 am Hg; 111,
57-7 % benzyl anisole (b.p. 157 - 160OC/10 ma Hg, n 20 1.5773) and 8.3 %
20 D
dibenzyl anisole, b.p. 200 - 210OC/2 ma Hgt UD 1.6m. .[Abstracter's
notez Complete translation.]
Card 3/3
4

S/08 62/000/023/034/120
B166 lol
AUTHORS: Praj snar, Broni s37aw, o ~szki ~w~C~e a ~?aw a.
TITLE:. The effect of the structure of the acyl residue of
C6H5CH2NHCOR amide on the course o .f the reaction of aromatic
compound benzylation
PERIODICAL: Referativriyy zhurnal. Khimiyz! no. 23, 1962, 257, abstract
23Zh137 (Roczn. chem., v- 36 no. 29 19621 265-274 [Pol-i
summaries in ;Russ..and Eng.D
TEXT:. A study has been made of the reaction of toluene benz lation by the
action of C 6H5CH2NHCOR (la-k, where (a) R - H,.(b) R CH 39 ~c) R = C2 H51
(d) R = tert-C 4H9, (e) R - CH 2C1, (f) R = 6Cl 31 (g) R C6H51 (h) R= o-NO2Cel, 1/Z.
(i) R = p-NO 2C6H4' (k) R = p-CH 3OC6H 4); also by the action of N-benzyl
benzene sulfonamide (II) and of N-benzyl phthalimide (III) in the presence
of POC1 3' The dependence of benzyl toluene (IV) yield cn the structure
of the acyl residue of I-III is used to show that the reaction mechanism
Card 1/4

S/08 62/000/023/034/120
The effect of the structure of ... B1.66XBloi
is one of electrophilic substitution. A similar resection of Ig with C 6H6-9
toluene, m-xylene, anisole and C 6H5Br gave their mono- and dibenzyl
substitutes. The reaction b etween Ig and C 6H5 NO2does not go. The'method
of producing Ia, o1 d, e has been improved and Ih was synthesized. A
mixture of 25 9 C6H 5CH2NH2 (V) and 50 ml 90% HCOOH is boiled for 30 min,
the excess acid is removed by vacuum distillation the product is Ia,
yield 28-5 g, b.p. 169-1720/11 mm Hg, m.p. 63-640C (from gasoline-benzene
4:1), A mixture of 25 9 V and 70 g C 2 H5COOH is boiled for 5 hre, 55 9 of
fluid is distilled off, 40 9 C2 H5COOH are added to the residue, this is
boiled for a further 3 hrs, giving Ic, yield 89.2%, b.p. 180-1850C/14 mm Hg,
M.P. 54-550C (from gasoline-benzene). Id is produced by reacting 13 9
tert-C4H9COC1 with 12 g V; Id is C 12 H17 ON, the yield 16.5 9, m.p. 82-5-830C
(from gasoline~. 25 9 V is acylated in pyridine by the action of 43 9
CC13COU at,50 C, the mixture is diluted with water, the product is I f,
Card 2/4.

S/08 62/000/023/034/120
The effect of the structure of... B166YB101
yield 40.2 g, m.p. 93-940C (from alcohol). A mixture of 42 g o-N02C 6H4COOH
and 45 9 S0012 in 150 ml C6H6 is boiled for I hr, 80 ml 'of fluid is
distilled off and a solution of 54 9 V in 50 ml C H is added a drop at a
. 6 6
time to the residue, this mixture is boilb.d for 20-min diluted with water
fLnd the product is Ih, C H 0 N -yield 72A m.p. 124-1250C (from alcohol).
14 12 3.2'
A mixture of 0.1 g mole-1, 100 ml toluene and-37 g POC13 is heated for
3 hrs at 1200C, cooled, ice is added, this is then filtered and IV is
extracted with toluene (the I-III are given and the yield of IV as
Ia, 1.65.; Ib, 45.5; Ic, 25.2; Id, 46.7; Ie, 25.4; If, 0; Ig, 70.7; Ih,
60.5; 11, 70; Ik, 61; 11 (P 205 instead of POCl 36; 111, 0. A mixture of-
0.1 mole Ig, excess aromatic hydrocarbon and 37 9 POC13 is heated for
3 hrs at 1400C, cooled, ice is added and the appropriate mono- and dibenzyl
derivatives are separated (the following table gives the aromatic hydro-
carbon, quantity in g, the monoderivative produced, its yield %,
boiling point in Oc/mm Hg, n 20 , the di-derivative produced, its yield %I
D
Card 3/4

S/08 62/000/023/034/120
The.effect of the structure of... B166YB101
boiling point in Oc/mm 11g, a20). C H 70, diphenyl~methane, 36,
D 6 61
126-128.5/11, m.p. 26-270C, -, dibenzyl benzene, 11.6, 218-224/12,
m.p. 68-720C, -; toluene,_80, benzyl toluene, 70.7, 140-143/12, 1-5710,
dibenzyl toluene, 10, 220 235/12, i.6002; m-xylene, 90, benzyl-m-xyleno,
71.5, 148-152/11, 1,5694, dibenzyl-m-xylene, 0.1, 230-240/14, 1.5695;
anisole, 100, benzyl anisole, 78, 162-165/11, 1-5769, dibenzyl anisole,
11.1, 220-240/12, 1.6010; bromobenzene, 120, benzyl bromobenzene, 22.2,
163-167/12, 1.6041 (identifiect by transformation by the Grignard reaction
into p-C6H5CH2C6H4 COOH, m.p. 156-1590C), (Abstracter's note:
Complete translation.]
Card 4/4

3/001J63/000/004/020/051
B187/BiO2
Prajonari Bronis-rawg Troazkiewig
LUTHORSil,
TITLE: On the alkylation of aromatic co6pounde with substituted
amides RNHCORI and on other reactions of amidee in the
prepenci of Poel
PERIODICAL: -Referativnyy zhurnal. Xhimiya# no- 4t 1963P 242-2439
abstract 4Zh132 (Roozn. chemot v* 369 no. 51 1962t 853-864
Pol.1 summaries in Russ* and Engs
TEXT: The following particular facts can be astabliahed about the reactions
of the amidee having the general formula PJHCORI (1) with aromatic compounds
(ARV) in the presence of FOG1 3; (a) when R - (CnH2n+1'2-CH or
R a (CnH2n+1)3 C, R is easily broken offl this leads to the formation of
alkylation products of the ARVI unsaturated hydrocarbons, other
substitution products and corresponding nitriles. (b) when R w CnH2n+IC821
the C-N bond is considerably more stable and these amidea are not
subjected to deamination if they are influenced by POM 31 on the other hando
Card 1/7

5/081/63/000/004/020/051
Onthe al-kylation of ... B167/BI02
reactions come-about depending-on the kind.of acyl;.e*g., in
-case of H I RI C H ) (Ia). deaoylation comes about -witli the
C4 9 6 5
formation of.C 6H 5COC1. The reactions, both the alkylation and the
elimination, are apparently monomolecular with the usual stage of the
carbonium ion formation R+. As regards orientation both reactions
proceed according to the Zaitsev rule. Reducing 10 g of (CH 3)2CHCH-NOH
in 100 ml of alcohol with Na (50% excess) gives 40% (CH,)2CHCH2NH2, b.p.
67-690C, which is benzoylated by the Behotten-Baumann(methodi extraction
with ether and removal of the solvent yields I CR CH ) CHCH
2 3 2 29
RI = C H (Ib), b.p. 0
6 51 170-17'0C/11 mm, m-P- 56-5-67 C- 50 9 of C5 H11C(CH 3)
ITOH (b.p. 98-99OC/11 mm)* 55 9 of Na and 38 ml of alcohol are used to
synthesize 62fa C H CH,(IIH2)CH3, b.p. 139-1420C in an analogous manneri
5 11
0
I LR - C 5H11CH(CH3)v RI - CO 51 (IC)p M-P- 70-71 C is obtained from this
by the Schotten-Baumann method (from thinned alcohol). (CH COH (II)
3)3
is benzoylated up to I [R (CH 3)3 C, R' - 06H 519 (Id). 19.3 g of
Card 9/7 ~ - . - I.___.. ~ I - I

S/081/63/000/004/020/051
on the alkylation of W80102
concentrated H2S04 is added dropwise to 13 9 of (CH 3)3 COH (II) and 19.2 g
or C6H 5CN (III) over a period of 15 minutes at a temperature of less than
40 ; the mixture is heated at 40 0 for one hour, 150 9 of ice are added and
then 840/4 Id, m.p. 133-5-1340C are obtained (from benzene). If concentrated
H2504 is added to a mixture of I and II in glacial CH 3COOH at 50001 the
Yield of Id is 72%. For other I obtained by various methods R, R', b.p.
in OC/mm, m .P. in OC are given: cyclo-C 6H110 Cq (Is), 160-161/15,
3
104-104-5; CYclo-C6H11P C6H5 (IOP -, 149-1501 Ial 181-184/13, -; 20D
C2H5CH(CH 3), C6H5 (Ig), -1 83-86; C 6H 13f CH3(Ih), 141-142/10, -, n
1.44591 C6H 13' C6H5(11), 212-215/23, 44-45i.C7 H15' C113(1k), 151-153/11,
n20D 1-4468. Cyclo-C 6H11NHSOOC6H 5 (IV), m.p. 90-910 was also obtained.
0.1 moles of Id and 36 g of POG1 3 are heated 2-5 hours at 135' (bath
temperature) in 90 ml of M-xylol (V) (separation of Hcl), ice is added,
and the non-reacted V, containing oyclohexene (VI) yield 66%, determined
by bromination), CH 3C.9 and 3-6~o cyclohexyl-M-xylol ~VII), b.p. 130-1400CA3mm,
Card 3/7

510811631000100410201051
On the alkylation of B167/B102
20
n D 1-5250, is separated by fractional distillation of the solution.
-1 4 ~ This
1-!6 g of Br, are necesaary to saturate the fraction containing V.
--:c6rre4ponds.-td-&-Cycibhexene--yield-of c16. Po aniilogous-read-t-i-o-ns--of--I---
with ARV in the presence,of POC13j the initial substances, reaction
conditions# reaction products (in all oases separation of Hol) are now
0
given: 0.1 mole If and 36 g POC1 in 100 ml toluene# 120 Cs 2-5 hours,
3 0
4%4 cyclohexane (Vill), 23~4 cyclohexyl toluene (b.p. 253-255 C,
36-1380C/2 3mm, n'8D 1.5240) and 9.1 g 111; 0.1 mole If and 36 g POU 3 in
100 MI. V, 1400, 2-5 hours, 31-0 VIII, 35.6% VII (b.p. 135-139 0C112 mm,
16
n D 1.5253) and 6 g 111; 0.1 mole If and 36 g POC1 3 in 100 ml anisole
(IX), 1400C, 2-5 hours, 8.3~ VIiI, 67-8% cyclohexyl anisole (X) (b.p.
18
141-143'/1l mm, n D 1-53301 on letting it stand for a while, 1.42 g p-X,
M-P- 58-590C settlej When the filtrate is cooled down to -100, o-X is
-sepa m.-pe-9657270OCs n4OD 1-5305 together with 7.29 S 111; 11-45 9 Ic
ratedj
and 18.5 a POG1 in 50 ml IXt 3 hour' 9- 0 76% 111, 53-5A (1-methyl hexyl~
3~ 1-40 0
card~4/7

810811j31006100410201051
-On the alkylation of ... B187/BI02
an~ 20D
isole 14 1122 0, b.p. 133-136oc/ii. mm, n1-4970) and a certain amount
:of an unsaturated compoundi 20.3 g If and 25 9 Pool I hour, 150-1609C
31
bath-temperature) with distillation of the reaction products, 7M4 VI
b.p. 81-8200), a certain amount of III and chloro cyolohexane; 21.9 g Ic
and 30 g pool3 , as in preceding case; 67.41/4o heptene-2 (b.p. 97-1000C,
20 0
n D 1-40431 oxidation with KKnO 4 leada to 04H9COOH, b.p. 180-185 Ci
anilide, m.p.,60-610) a certain amount of III and 0-3 9 C a
0 20 5 11 ~HMCH3
'142-146 Cl n D 1.4273); 13-7 9 Ig and 36 9 POU in Pool in 90 ml
3 3
vi 3 hours$ 1200C(bath temperatu Ire), 64-5~ butene-2 (distilled off during
the reaction and absorbed in a solution of Br2 in CCI 4); (CH3 CHBr)2,
b. .-154.5-150 20 104-), 82 -III-and 6.8%*pec-butyl-M-xylene (b.p.
T-C, n--D-1-5 %
-0 20
-4.90-200 n- - D 1 -4975) 117-7,g Id and 36 g Pool in 100 ml toluene as in
3
-preceding case, 57--6% isobu.tylene absorbed in a solution of Dr 2 in CM 4;
CH2BrCBr(CH) 0 H b.p. 148-152 00, n20 D 1-5112), 77-5% 111 and 18% tert-
3 2 5
Card .51/7.
10 M -
4,
MmtMBPRMW~~ MORE

8/081/63/000/004/020/051
~On the alkylation of B187/B102
0 20
butyl-toluene (b.p. igo-i96.C, n D 1.4940);.17-7 9 Ia and 36 g POM 3 in
100-m1 toluenel--3,houral-120 0of-ae-beforn 2-4 9 C6HSCOP1 (b-P- 50-800C~4 mm;
a .,-14--g of~the'initial substanc
nilide, 'm-p, 1-61--1620C) e -la-(b*po
20
166-188'0/14 mmt n D 1-5360) and 202 g-of a substance which dissolves 0in
concentrated H250 4' 17.7 g Ib and 36 g Pool 3 in 100 ml Vt 3 hours, 140 C,
as before, 16~61 111, 6.8 g of the initial substance Ib (b.p. 165-175OC/13 mm,
-p. 56 zene))and 2.3 g of a substance soluble in
-570C (from bon
m
concentrated H so ; 20-5 g I and 36 g Pool in 100 ml toluenes 3 hours,
2 4 3
0
120 C (in the bath), 13 O-g of the initial substance Ii (b.p.
2W-21600/16 rimi m-P- 44-450 (from benzene)) and 5 9 of a substance
soluble in concentrated H2SO 41 from the reaction of Ih, k with Pool 3 in
toluene (3 hours, 1200C) no particular substances are obtained; in an
analogous reaction between 11.9 g IV and 18 g POM in 50 ml V (3 hours,
3
14000 HClie separatedi 7-1 g-of the initial substance IV are obtained,
---but alkylation -products of.V cannot.be established. If POW is replaced
3-
ard 6/7,

B/Osi./63/000/004/019/051
BIST/BIO2
~AUTHORS: Prajanar Bronisraw, Troszkiewicz Czeslawa
Influence-of the benzyl group structures of the amides
TITLE,
-X-C -H -CHR-NH- on the course of the benzylation of
6,15 GO-005
aromatic compounds
PERIODICAL: Referativnyy zhurnal, Khimiya, no- 4t 1963, 241-242,
abstract M131 (Roczn* chemal vo 36, no- 5, 1962, 843-851
Pol.1 aummaries in Russ. and Eng.
TEXT: In order to study the influence of the atructure of the ArCII(R)-
group on the course,o'f thereaction when aromatic compounds are subjected
to-benzy1ation with amides,of thegeneral formula ArCH(R)NHCOC6H5 in the
presence of POC1 toluene alkylation reactions were investigated under the
V
influence of 2~-R-3-RO-4-R"C CH HHCOC b, a# d where (a)
02 2 013 JII~
RWR"-H,_R!-q2H Oj--(b)-HWC_ff 0 R1WR"W'ffj (0) R-RI-H, R"-C H 01
2
5 5
---Card 1/6

-S/081/63/000/004/019/051
of-the benzy B187/B102
1 group ...
Jd),R-R-H, W-N02) and H G11(R)ffHCOG H (III where R C H (IIa) as
C6 5 6 5 2 5
.,well as'alkylation of benzene under the influence of II (R-C 6H5) (M).
Under tho influence of POCl the opening of the C-N bond and the breaking
31
off of the 0 H OC H CH -group in the cases Iat b, c take place easily with
2 5 6 4 2
a high yield of 0 H ON (III). On the other hand, the 0 H 0 group decreaaes
6 5 2
the yield of benzylation products of toluene, especially in case of its
ortho or pars, position in which it is linked with the CH.-group. At the
same timep it increases the relative yield of dibenzylation products for
the reaction with Ia
(apparently a mixture of 343f-02H 5 O_C6H4CH2)-4-
0H CH 0 H and 2-01-0 H OC H CH H 006H CH C H CH 4"). The NO
2 6 3 2 6 5 2 5 6 4 2)-5-C2 5 3 2 6 4 3- 2-
group counteracts the breaking off of the 4-NO.06H 4CH,-group so strongly
that the m:in reaction product obtained is the initial substance Id. The
0 H -group in IIb promotes the course of the benzy1ation reaction to a high
6 5
degree compared with the C B -group in Has When the latter was used,
2 5
Card 2/6

8/081/63/000/004/019/051
Influence of the benzyl group B187/B102
unsaturated hydrocarbons were found in the reaction products. 66 g
3-C,H OCA CHO (IV) (b.p. 117-1130C/11 mm) are boiled in 300 ml alcohol and
5 0 4
a golution of 85 a NH20H-0-5 H 2SO4in 300 ml of water and neutralized
Na CO for one hourt 200 ml of the solvent are driven off, 300 ml ---+er are
.2. 3
0
added and the oxime of IV is separated (IVa), C H NO
9 11 2F M.P. 60-61 C (from
benzene). 70 g of metallic Na is as quickly as possible added to 60 g of
IVa in 550 ml of absolute alcohol, the mixture is boiled for about 2 hours,
200 ml of water are added gradually, about 500 ml of the distillate are
dirven off with steam and from the rest is extracted with ether giving:
90% 3-G2H 5- OC6H4KH2(V)j b.p. 120-122OC/13 mm, n20D 1-5503; hydrochloride
(CaRt), C9 H14 CIBOt M-P- 134-1350C (from dioxane); picrate (PK), M.P.
.178-1790CI acetamide (AD)v 0 liff 15 N02 t b*p. 197-1980C/3 mm, M.P. 60, 5-610C
0
(from benzene). 60 g C 6H COU are added dropwise to the weighed quantity
of 40 9 V in 300 ml of I Na0H. This gives 69 g of Up 0 16U1711021 M.P.
Card 3/6

6/081/63/000/004/019/051
Influence of the benzyl group D167/B102
56-.5-70C-,(from-benzene-gasoline). The synthesis of I is analogous
a- 0
peoifications are I, empirical formula, m*p. in 0); b, C 16R17 U021
100-100.5 12-C H OC H NR yield 76',fa, b.p. 119-1220 C/14 mm, n20D 1-5294;
2 5 6 4 2' 0
ChHtj C H CINOt m.p. 164-1650; PK, m-p- 197-196 ; AD, CliH15"02' 'n-P-
0-9 14 8- 12 9005 w4v
65-86 J; b, C H NO H 0C H NH 12
16 17 29 98-99 (4-C2 5 6 4 V Yield 8&/0' m-P-
nd also Mb, m.p. 108-1090C [(;,H
a
5-CH(C2H5)NH 2, b.p. 94-950/19 mm]. A
Schotten-Baumann reaction on 4-N02C6R 4CH211H2 yields Igg m.p. 155-5-1560C
(from alcohol). To 0.1 moles of (C H CHOU and 0.1 moles of III in 60 ml
6 02
of glacial CH COOBvIl 'g of concentrated H so are added dropwise at 45 C
3 2 4
0
in the course of 20 minutes, the mixture is heated to 45 C for 1 hour and
then poured into 300 ml waterice mixture. This gives 91~a Ila, m.p. 171-172P
(from alcohol). 22 g of Iap ~, c, 90 ml of toluene and 33-5 9 of POCl 3 are
h
eated at 12090 for 3 hours; 1.69-1-74 moles of H01 are separated per mole
of I; ice is added and the procedure described in the preceding paper
(R.ZhKhimt 1960# no. 17, 26566) is carried outj the following substances
Card 4/6

s/oai/63/000/004/019/05i
Influence of the benzyl group B1870102
separate (specifications are I, monoalkylation product, empirical formulap
yield in ~, b.p. in OC/mm, yield of III in 4, residue in g): I&, tolyl-
(3-ethoxyphonyl methanep 0161f Ot 43.5, 100-182/13t 1.5625, di-(3-e'thoxy-
benzyl) -toluene., --C -_ 11 ---0 ~ 26?8- W-279/120 66-4v 31, Ib, tolyl-(2-
25 28 2, 0
'~ethoxyphenyl)-methane, C H 0, 15, 169-172/12, 1-5595, di-(2-ethoxy-
16 18
benzyl)-toluene, G25 H2602' 16.1j 220-226/19 92, 9. Ic gave 2 g of a
mixture of monoalkylation and dialkylation products, b.p. 160-2400/mm, 69YG
III and 7-3 a of residue. 19.2 g of Id, 90 ail of toluene and 28 g of
POC1 3are heated at 1200C for 3 hours; after ice has been added, 17-1 g of
the initial substance Id separate; distillation effects the-Separation.
9-of 3 am # f rom
4-90-0 H COC11-MOP-0 69-7-09op can be separated (from
~
2 6 4
alcohol). 18*3 g of I'Ibj 180 ml of C H and 24 9 of POCI are heated at
6 6 3
0
120-C for 4 hoursi after ice has been addedt 4.9 of (C H elf (VI)j M.P.
6 5 3
79-8200t are separated (from alcohol); distillation gives: 76% 111, b.pa
Card 5/6

-------------
5/061/63/000/004/019/051
Influence of the benzyl group B107/ 102
,-,CHC"L and 87%
74-7800 4 mn, 4 4 9 of a mixture consis-ting- of-- 13%
-o-tal--yie-1d-of--V1- -5%) 6 -3-5-4 g of~residuet from-vhich 290A
VI J~ -30 nd
-are se ro g -ial CH
4-;; [(C 9 C 6041-m.p. 1.1 64 16500 --,Darated--(-f m-- 1z COOR) ---------
6 5,2 2
I a,--10O-ml-of--to1 ne-~and-:37- -0 POC -are heated
a. t12OPC for
-ho iii -,toluene solution the presen
ce of 16.1% of an unsaturated
~rsf 0, the
-co-mpIound al culated with respect to-C6H MUCH ) is determined 'y means
5 3
of Br~l distillation gives 80% of III; bromination with a solution
of Br in, - CCI yields 1*5 9 of C H C11BrCHBrCH,0 M.P. 64-650, (from
2 4 6 5
20
alcohol). C H18, yield 45.2%, b.p. 16o-166,Dc/12 mm, n ~D 1-5682 is
16
0
oeparated from a higher fraction (9-5 g), b.p. 160-170 C113 mm~ ethylphenyl-
n-tolyl methane. Oxidizing the higberfraction with Ila Cr 0 in CH COOH
2 2 7 3
0
-,:gives A-C6 H5GOO6 H4000H, mop* 1190-192, Co Abstraclerto note,. Complete
translmtion
Card 6/6

TROSZKIMCZ, Czeslaw; GLIM, Jadwiga
New method of s7nthesis of quinoline nucleus by cyclization of
oximes. Rocz,ehomil 36 no.g.-1387-1388 162.
1. Department of Organic Chemistry., Siieaian Institute of
Technology, Gliwice.

TROSZK-EMCZ, Zygmunt,, mgr inz.
Unification and standardization of cranes and the economic
results. Przegl techn (84) no-44:5t6 4 N t62.

UQmMqqZ-~=7--
Tacbnical progress in the con3trucUon of crameso p-161
PMMAD MCMIMY.. (Stowarsysenie Inspierow i Toobnikow Mechanikow Poiskich)
Warszawa, Poland
Vol. 18, no. 6s Mar. 1959
Montbly List of East European Accessim (=) LC., Vol, 8s no.-A July 1959
uncle

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