SCIENTIFIC ABSTRACT UKSHE, YE.A. - UKRAINTSEV, F.I.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001857910013-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: March 14, 2001
• Sequence Number: 13
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

UXSHE, Ye.A.; STEPANOV, So I.
Blectrode processes in fused salts. Occ13-lographic study of the
electrodeposition of mgnedlum in the presence of sulfates. Zhur.
fiz. khim. 34 no*3!559-364 W '60* (MIRA 13: :11)
(Baits) (KMwsium)

UKSHEO Te.A.; BUKUNv N.G.;. S, D,I.
tam
Capacity of the electric double layer in fused salts. DAL IN
SSSR 135 no :118 1196 D 160. OCM 13:12)
1. Institut lektrokhimii AN SSSR i Ber'.8mikovskiy filial Vsesoyw-,
alyuminiyevo-magniyevogo i9stituta. Predsfavlono akademikm A.H.
Fr=kinym. (Salts) (Electric double layer)

BUKUN, N.G.; UKSHE, Ye.A.
P,eaction of metallic maSnesium with fused chl6i-fdea. zhur.neorg.
khim. 6 Ap 161. (MIPA 14.4)
lo Bereznikovskij filial-Veesoyumogo alytudmiyovomagniyeg.9
instituta.
(Hagnesium) (Chlorides)

S/074/61/030/002/001/001
B124/B203
AUTHORSt Ukshe, Ye. A. and Bukun, N. G.
--------------------
TITLEt Dissolution of metals in molten halides
PERIODICAM Uspekhi khimii, v. 30, no. 2, 1~61, 243-273
TEXTs The present paper gives a survey of publications on dissolution
processes of metals in melts without making mention of new papers by the
authors. The dissolution of metals in salt melts is of great importance
to many electrometallurgical and thermal processes such as the production
of titanium, magnesium, aluminum, sodium, etc., as well. as to the purifica-
tion of metals. The solutions mentioned are most interesting also from a
theoretical point of view since they permit essential'conclusions to be
drawn on the interaction in ion media and on the liquid state. For the
formation of true solutions of metals in salt melts, three concepts can be
assumeds 1) Dissolution of the metal in the form of atoms evenly distributed
over the entire volume of the solution; 2) dissolution of the metal in salt
melts by chemical interaction of the electrolyte with the metal, with forma-
Card 1/9

V
S/074/61/030/002/001/001
Dissolution of metals in molten... B124/B203
tion of low-valency iopB (sub-ions); and 3) solutions of metals in salt
mefts may be regarded as struotural units whioh are identical with the color
centers (F oenters) so that these solutions might be called ion-electron
liquids. Data are given on the formation of i 'ons and compounds of low-va-
lency. The apparent valency n of a metal can be determined from the anodic
current yield of aqueous solutions of metals, and is generally very low
(Table 1). The iY values are not dependent on tho current density or the
concentration of the solution but they are determinea by the anodic poten-
tial (Table 2). The basic data for calculating the formation heats of sub-
halides are also given, namely I - ionization potential, 6- sublimation
temperature, 1/2 D - dissociation temperature, E - electron affinity, and
the ionic radii (Table 3). The calculated and experimentally found values
for the lattice energies and the formation heats of sublialides are given
(Table 4), the difference not exceeding VY~. The color centers in ion crys-
tals are described, studied, and characterized. The solubility of alkali-,
alkaline-earth-, amphoteric, and other metals in halide melts9 as well as in
dependence on the type of halide, was also studied, as well as the effect of
secondary cations on the solubility of metals. The solutions of metals in
Card 2/9

S/074/6 1 /0 ',0/0-'-2/0-0 1 /-jr, 11
Dissolution of metals in molten... B12111B-_105
salt melts were also studied cryoscopicali.y. The stractureG of sodium and
potassium dissolved in their halides (Table 12), and that of Bi in BiCl 3
(Fig. 7), were'atudied, where T f is the melting point of the pure solvent,
X, RT f14011000 I;f is the cryoscopic constant, L the melting heat of the
'pure solvent, M0 its molecular -aeight, and V the number of particles formed
on dissolution of a metal. Further items of this study are the effect of
,metal dissolution on the vapor pressure of molten salts, the vol,=e effects
on metal dissolution in salt melts, potentioimetric investigations of metal
solutions, and the electrical conductivity of metals dissolved in salt melts.
Finally, magnetic and spectroscopic studies of,metals dissolved in salt
melts, and the dissolution in electrochlemic?l processes, are described.
Ya. I. Ollshanskiy, S. A. Semenkovich, D. 77. :,Okoulina, V. B. Kabanov,
N. A. Belozerskiy, X. B. Yatsimirskiy, Kapustinskiy, A. 1. Ioffe, P. S.Tarta-
kovskiy, A. I. Zhurin, S. V. Karpachev, k. G. Stromberg, M. V. Smirrov,
N. Ya. Chukreyev, A. I. Bulkhbinder, L. N. Antipin and L. Suskiy are
mentioned. There are 10 figures, 16 tables, and 167 references: 53 Soviet-
Card 3/9

s/c74/61/01;0/002/001/001
Dissolution of metals in molten..; B124/B203
bloc and 71.1 non-Soviet-bloc.
ASSOCIATION: Bereznikovskiy filial Vsecoyuznogo alyuminiyovomagniyevogo
0
in-ta (Berezniki Branch of t,he All-Union Aluminum and iijagnesium
Institute)
Legend to Table 1:
Apparent valency H in
anodic dissolution of
pome metals in acueous
solutions.
a) Normal valency
Mo Do Af AW Z" G., tj In Mn Ha

HOPNI.

eHT-
3
HOM

W 1
31 1,7
,
Card 4/9

S/07 61/030/002/001/1C01
Dissolution of metals in molten... B124YB203
to Table'2:
Legendi
Depehdence of A on the type
of solution and the anodic
potential; a) solfition,
b) concentration in g-e-qu/1
TA&MUA 2
3auticusiocinb W om ripuro0a pacnicapa
u ont nornenquaAa allooa no 41. 11
-1,7 1
26,
I%I-,Br,: 0. I-I.U too -1,62 ,
30
1
.M"'S04 0,01--1,0 100 -1,155 ,
,NIS04, 1,0 NO -1.5 1
30
+K-CrO4 0.05 ,
J~uu~,, 1,5 11.4 1 13

S/07L/61/030/002/0C1/'V'01
Dissolution of metals in molten... B124/B20'3
Legend to Table 3:
Thermochemicall
characteristics of
ions, kdal/mole;
T ArJ7HLj A3
a) ion
Tep,toxtijumccKtic xaraKarepacmuicu UOU06, KKaJ/xO,1b

Mg~ 177,7 35,9 1,01 Z11, 216,() 31,0 1,27 F- 93,5 2 i,:M,
32
Ca- 14-9.2 A G, 0 2,16 Cd+ 20(),G 27,0 1,44 (-1- 88,2 28 9 1,81
:
sr~ 132,8 2,5:" 111~ 134,8 58,*2 1,49 Ba- "I U
' 21;,!) 1,111;
Ba' ILN. (; 42,1) -1,741 Ga 1 139,8 0.0 1,33 J- 6 2 5. 4 2. 2"
T1- 1142,3 44,51 1,49 Sit+ 140,0 72,0 1,62
M- 131) 5 75 0 1 1,1,11 Pb' 17-1.5 4,j.3 1,7(.'-j
I Ig ' 1 12 AE, 6 14:5 1 , 4A Sb- 100,7
1 W, 8 1,4(,
Bi- I
t
Card 6/9

S/074/6'/030/002/001 /00 1
'Dissolution of metals in moiten... B12413203
Legend to Table 4:
Lattice energies
and formation heats
of subhalides and of
normal salts (2960K):
a) subbalide,
b) kcal/mole,
0) halide
Card 7/9

vo

MgF I ~S 37, t I%igr._. 263 . 13-t
IF
A
,7 31.5 [ F.,'-
A 311

Mgcl t.", C I - 153:4 J
AC
I 173 .5
, 18
6 I
A
d, PRO

r
MgB
17
"A 1 g B
12:11
7 AJB
r
170 2
04
: l
A Br;y 1:)3.3

gj

78 0
fit,
~j
8(;, 0
AIJ
1
163:8
310
A IJ, 75,)

c
- (
7
8
C
~ 1.() nF. r)F j 913
,~ )
,

C.1c,
I i
,7: 0
2) 1 !0
!)
1 TICI 177 5
: 50,0
CaBr 1,57,() Ca L r 16t -
: I'IBr 175,5 It 3. 4
Caj 15(;,7 17,7 CnJ, 1'27,8 TIJ 171,5

IrF
I
I
f
I
SrF-. Z CI 210,7 23,0 Zi.Clt ',19-4
'
."C
, :.
,
r
j
j 1 cdcf*-.

SrBr '1
1:-,1,7 1. .7, t I'd

1
.,153,7 1
30j!)
j. GIC6
P-,It:. 128G 9 S,-.Cl. 173 *8 20,5 SrCI: 83.6
BaC12
;
vj: I)LCI 182,4 '22,9 PKI. s:-),s
P, a- B r 1!,/,, 1; BiBr,,
, 1804
"
1 SLCI

B"O
1.1410
1 29, 1; ,
IlIV)
MCI I
180, 1
MCI, 90's

S/074/61/030/002/001/001
Dissolution of metals in molten... B124/3203
Legend to Table 12;
Struc ture of dissolved
sodium and potassj4u,-i in
halides; a) salt,
b) kcal/mole
7*AB.,7HUA 12
Cnipyxmypa pacmeopennozo uampux u iccAuji a ziwzcnuc)ax
L -
*
L

C0.1h
7-1. -X I
irt,
Ai
OX lot x/ co"11,
Tf. -H
I if 3C
ATf.
KI
NaF 1268 7,8 5 2,5 IM 0,W KF 1131 6 75 9 45 18 8 0, GO -
NaCI 1073 6,7 5 2,1 18,5 0,73 KCI 1043 G: 34 is
1 10 26:G 0,54
NnBr 1020 0,24 7 2,0 33,2 0,72 KBr
1 1007 ("10 26 17 32,4 0,46
1
NaJ 933 5,61, 3 1,0 49,0 0,55 KJ 954 51,74 23 12
48,5 0,57
Card 3/9

Dissolubion of metals in molten...
Legend to Fig. 7:
Comparison of experirmntal data
on the melting-point lowering
of BiCl on dissolution of Bi
3
With the calculated values
obtained for various structural
% f
schemes of solutions, a) molep
of Di.
S/07 "1611 /0~30/C 02 1001 /00
OtC13
Jz_
ZC,3 atict,
14-
&3C13
M. Biz
ffVt4
iF I Iz 9 x 24 a
Card 9/9

TJKSIiF,l Ye.A.; BUKUN, N.G. (Berezniki)
Faradic impedance of lead in molten chlorides. ZImr.M.khim.
35 no.12:2689-2691+ D 161. (IMBA 14:12)
1. Boreznikovskiy filial Vsesoyuznogo alyuminiyevo-magniyevogo
inatituta.
(Lead chloride-Electric propertiea)

DEVYATKIN., V.N.; UKSHE, Ye.A.
Behavior of iron electrodes in molten thlorides. Zhur.prikl.)-.him.
35 no.6:1328-1333 Je 162. OURA 15:7)
1. Filial Vsesoyuznogo alyuminiyevo-magniyevogo inatituta.
(Electrodes, Iron) (Chlorides)

UKSHE, Ye.A.; BUKUN, N.G.; LEYKIS, D., .
Double electrical layer In fused salts. Zhur. fiz. k-him. 316
no.lls2322-2328 N162. (141RA 17 j 5)
1, Institut elektrokhimli AN SSSR i Bereznikovakiy filial
V;esoyuznogo alyuminlyevo-magniyevogo instituta.

RYABUKHIN, Yu.M.; UKSHE, Ye.A.
Diffusion coefficients of lead in fused chloridas. Dokl.AH SSSR
145 no.2s366-368 J3. 162. (KM 15:7)
1. Bereznikovskiy filial
alyuminiyevo-magniyevogo
A.N.Frumkinym.
(Diffusion) (Lead
Vaesoyuznogo nauchno-iseledovatellskogo
instituta. Predstavleno akademikom
compounds) (Fused salts)

S/062/63/000/001/005/025
B101/B186
AUTHORS: Ukahe, Ye. A., Bukun~ 11. G., and Leykia, D. I.
TITLE: Effect of the nature of the electrolyte on the capacity
of the double-layer in molten-salts
HRIODICAL; Akademiya nauk SSSR. Izvestiya. Otdeleniye
khiiiicheskikh nauk, no. 1, 19~iy 311-36
TEXT: ;%e capacity of the double layer of a molten lead electrode was
measured at 18-20 kc/s- The electrode was in a capillary tube and covered,
with molten alkali halide. The reference ele6trode used was: PbJ10~ by
weight'PbCl + electrolyte tested. The following compounds were studied
2
as electrolytes: Na!Cl; NaBr; XaI; NaCl + NaF 1:1; NaCl + KC1 1,:lj
NaCl +.Nal, KC1, KBrl KI, KC1 + KF; CsCl, CsI; LiClj LiCl + 20 Mole',e4 LiI.
The temperature was 8000C, with NaCl 8200C. Results-. The nature of the
electrolyte had a marked effect on the structure of the double layer,
The alkali halides can be subdivided into two groups. Na and Li halides
give high capacity, this being strongly dependbnt on the nature of-the
anion: Cmin (tLF/cm2) is for NaCl 43,. NaBr 52, Nal 75p LiCl 35,
Card 1/3

3/062/63/000/001/005/025,
Effect of the nature of the
LiCl + 20 mole~,4 UI 75; the potential is about -0-46 to -0-48 v, the
C_verBus-,~ curve rises sharply on both sides of the minimum. The
capacity produced by K and Cs-halides is lower And not much affected by
the nature of the anion (except F_): C io.for M and CsC1 28,
min
KBr 29, KI 32, CsI 33; 'ie about -0-55 to .1:0A0 v; the curve
T mio .1 -
0 f(T) is flatter. In bo~.hjgroups, addition of~F ions increases the
ca;acity proportionately to the F- concentration. Iodide addition to
NaCl and LiCl increases 0 min rapidly to the limiting value of Hal and Lil
respectively, which is reached already with 20 molec,o' iodide. The followin
9
assumptions are made to explain the results: (1) The thickness and
capacity of the double layer changes owing 'to deformation of the ions and
of the double layer; ~2) the 'surface activity of the anions increases in
the order F_< Cl- < Br ,-)si-:on n-haseF, ,n the ~an-aluri-selerl-irn svs~cm
TOPIC T-AGS: tantalum se lenium system, variable phase c :)mposition, ta-ntaluni
selenide, tantalurWdiselenide
ABSTRACT: The phase relationships irt the Ta-Se system In the composition
region TaSe 0 were investij-~ateci. Samples -,N ere Tirepared by heating the
ofiric- v- c4 and cr-sol inj rinwiv
-T-1 tijrf "-f-glo L,) lc~ X-.,a Lx~'-
ar, di -j a - It r, o (d, fc ar, s.
Card

ACCESSION NR: ApWW~816
i -s metastable in the TaSe the Qn,;d c5oluf ors b-epc--d therpor
98- 1 P7
Ac; e
SUBY[ITTED: 120ct63 ENCL: 00
SUR CoDi-- SS (,c
Ca,d 2 2

IRLICIMKO, V., inzh.; URRANSKY, P9, insh.
Making thermosite-concrate vall blocks vithout using cement. Stroi
mat. 4 n6-5:35-37 MY 158. (MIU 12:45
1. Nauchno-iseledovatellskiy ingtitut stroitelInVkh konstruktsiy
Akademii, itroitelletva i arkhitektur7 USSR (for Lelichenko). 2. Zavod
ii. Illicha v g. Zhdanove (for Ukrainskiy)e
(Concrete bloc1m)

27862-66 EW(d)/Dnf 1)/
i ACG'NR I EWPtb)/ZYA h f
AP5026531 Wxc(i4 Ult/b, 66/05/W0/020/0125/0125
IJF(b) it)/Ww/ 4 j
~'r AUTHORS-. Ukraip -ey _B.N. Fo
Vlkn-itis SArotenko.. _Gj' liforov, V, M,
ORa: none
~TITLEt Electromagnetic induction p
ump. Class 59 No. 175825 jainnounced by'Central;
I Project-Construction Bureau of Mechanization and Automation of the C
ouncil of
National Ec&60mi Of -CEe Lii;aWW
noye proyektno-konstruktorskoye
ovnarkhoza LAtviyskoy SSRY
SOURCE: Byulleten' izobreteniy i t~varnyi~h znak~vj no. 20, 1965p 125
TOPIC TAGS: electromagnetic pump, I pump"Imagnetic circuit# electrode
liquid metal
ABSTRACT-.
This Author Certificate presents an qlectrom~Zaetlc induction pump
containing a ma hetic circuitij an
-in ductor with coils, and oLactr owl osIocaLu din
slots in the body which has a passage for thu plu
Teq f UidNi3en, Fi~. 1). To
increase its operating temperature rango, the pumped liquid metalfis used as the
iinductor vinding material. This metal fil3a the inductor an(F-eleatrode slots
rd
,-ca mat 621.;689

4a,,

UKRAINTSEV, B. S. (Candidate of Philosophical Sciences)
"on the Possibilities of Cybernetics in View of the "roperty of
Representation of Matter."
Filosofskiye voprosy kibernetiki (Pbilosophical ?roblems of Cybernetics),
Publisi-ing House of Socio-Economic Literature, Moscow, 1961 392 p.

a~Ialoa - Illuciear Engineering and Power C-8
1VTnf- Y
Abot Jour : Rof Zhur Fizika, NO 1, 1958, 597.
Author : Isypunskiy, A. I., Blokhintsev, D. I., Aristarkhov, i. M.,
Bondarenko, 1. 1., Kazachkovskiy, 0. D., Pinkhasik, M. S.,
Stavieskly, Yu. Ya., Stumbur, E. A., Ukraintsev, F. I.,
Usachav, L. N.
Inst
Title Experimental Fast-Neutron]Reactor M-2
Or1g Pub Atom. energiya, 1957, 2, No 6, 497-5oo
ABstract Brief description of the arrangement of the experimental
operating reactor with fast neutrons and its basic expe-
rimental and auxiliary equipment. The reactor is inted-
ded for physical research with fast neutrons. The active
zone Of the reactor is made up of plutonium rods; the
lateral reflector is made of impoveri4ed uranium. The
heat is carried away from the active zone by mercury and
from the uranium reflected by air. The total nominal
p9wer of the reactor is 150 kv, of theses 100 kv are
liberated. in the active zone.

LuipurSKIJO A.I. [Leypunskiyp A.I.); BLOCKINCEVO D.I. [Blokhintsev, D.I.];
ARISTARCHOV, I.F. C istarkhov, I.R.1- BONDARIWO, I.I.;
KAZACKOVSKIJ,,O.D:. Kazakovskiy, O.D&J PIWCW3X, YI.S.;
STAVISAKIJf Ju Ja* Staviaskiy,, YuYa.j; SMMR, BIA.;
UKRAJINCEV, F.I. [Ukraintsev, F.I.1- USACEV, L*F. Weachev, L.W.1;
MEDONOS, S. [tranera-ro-rl- '='j-
Soviet experimental reactor with fast neutrons BI-2. Jaderna,
energie 3 no.8:231-233 Ag 157.

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