FOIA
SCIENTIFIC ABSTRACT URBANSKI, T. - URBANSKI, T.
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CIA-RDP86-00513R001858020015-1
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RIF
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S
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100
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April 3, 2001
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15
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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POLAND / Organic Chemistry--Synthetic Organic 0-2
Chemistry
Abs Jour: Ref Zhur-Khimiya, No 8, 1959, 27503
Abstract: CH3CH(NO2)CH20H (X). The reaction of IX with
RCH2NO2 leads to the synthesis of the HC of VII.
0.1 mol III is treated with 0.15 mol IV, 0.5 gm
NaHC 03 , and 0.1 mol II; at the termination of the
exothermic reaction the solution is heated for 3
hrs at 60-650 and the resinous mass is washed with
water; I are obtained (the product, yield in
mp In OC (from a1c), and the mp in OC of the
hydrochloride (HC) are listed in that order): Ia,
^~/30, 50-51, 182 decomp); b 55 5?-6o, 187
(decomp); c, 60, 4-70, 179 Idecolmp). 2 gms of
I in 200 ml 80% alcohol are treated with 10 ml
cone HC1, the solution Is heated to boiling, and
the solvent is distilled off, the last part of
Card 3/6
Ila
POLAND / Organic CheM18try--Synthetic Organic G-2
Chemistry
Abs Jour: Ref Zhur-Khlmiya, No 8, 1959, 27503
Abstract: the di5tillatlon bting gatried out under vacuum;
the HC of V is obtained; One gm of the EC of
V in 15 ml water is treated with a calculated
amount of NaHCO, and V is isolated (the product,
mp in CIC (from ale), and the mp, In OC (fro-m 3:1
ale-acetone) of the HC and of the dibenzoyl
derivative (from aqueous ale) are listed in
that order): a, 68-70, 169(decomp);_106-107; b,
77-79, 170 (decomp), 101-102; c, 79 81, 167
(decomp), 140-142. One gm of V is treated with
a calculated amount of 2% VI and then with
an excess of alcoholic HC1 at 00, the solvent
is distilled off under vaccum In the cold, and tYe
HC of VII is isolated (the product and the mp
in OC (decomp) are given): Ma. 148; VIlb, 160;
Card 4/6
POLAND / Organic Chemistry--Synthetic Organic G-2
Chemistry
AbB Jour: Ref Zhur-lailmiya, No 8, 1959, 27503
Abstract: VIIc, 162. 0.5 gm of the HC of VII is treated
with a small quantity of water and a calculated
amount of NaHC03, is added; VIII is separated
(crystallization from ether) (the product and mp
In OC (decomp) are given): VIIIa, 61-63; b,
95-97; c, 97-99. The action of 1 ml cone HC1
on 0.1 gm VIII liberates NO - evaporation to
dryness yields the HC of VI~Il. 5 mmols VII in
50$ ale are treated with 15 mmols IV, the Golu-
tion is made alkaline with NaHC03, and allowed
to stand a few days; I is obtained. 0.03 mol Ma
or Mb Is treated with 2 ml CH30H or dioxane,
0.03 mol II is added, and the solution is
allowed to stand a few days at-200; Vb or Vc is
Card 5/6
POLAND / Organic Chemistry--Synthetic Organic G-2
ChemAstry
Abs Jour; Ref Zhur-Khimiya, No 8, 1959, 27503
Abstract: obtained, yield 80;90%1 0.01 mol X in CH30H
is treated with a alcidated amount oV IX and the
solution is allowed to stand in the cold for
a few hours; Va is obtained, yield/-200 (sic].
0;05 mol IX and 0.05 mol nitroparaffin In 5 ml
dioxane are allowed to stand for several hrs at
^-1200, the solvent is evaporated, the residue is
dissolved in acetone, and alcoholic HC1 Is added;
the HC of VII is obtained In yields of"80-85%.
V. Skorodumov
Card 6/6
UhBAU5KI To - PIOTROWSKI, A.,
Y
. FluiltalaK.1
On Aliphatic Hitrocompounas, Part XLEVII by ~ - i z,11d t - I
Page 455, Przemysl Cheminny, No. 8, 1957.
UFWANSKIp T.
J. Alkievicz, Z. Eckstein, H. Halweg, P. Krakowka, T. URBANSKI: 'Tungistatic Activity of
Scuie 91droxamic Acids," Nattwe, Vol. 160, Ho- 4596, (London) 30 November 1957,
pp. 1204-1205. Published from the Department of Dermatology, Municipal Hospital
No. 1, Poznan; Department of Chemistry) Institute of Technology, Warsaw; and,
Iaboratory of Mycology, Institute of Tuberculosis, Warsaw.
He,ANUI, TADLUSZ.
Tl,:CifNOLWI
UIRBAISSKI, TADLUZ. Chemic a technologie vybusin. Prel. Zdenek Dolezel a Lusan
Jakes. Fraha, Statni nakl. technicke literatury. Vol. 2, 1958. 285 p-
Monthly List of East European Accessions (ELAI) LC; Vol. 8, no. 3, Yiarc',,i, 1959. Uncl.
Distri 41,;2cW/4B3d 7
V Infainolecala bydrolien bandim la o-nI
Urbonslo and U. Da I (Polish Acad. "saw).1
e
'O
'tion spectra of the a Isomeric NOAMN14 if) In I % *
~Mf soln. In the frequency ran es 2. "'V ( - I stretchF!
stre tcfdv g vibrations) were eu
and 7
0
synt
"
6 (NO i
.
.
.
t
j
N
CI
-beam spectrophotometer with
&
with a single gm
psi
11t has previously been shown that in aliphatic nitro compds.
ithe H bonds reduce both tri-quencles of the nitro group
s for the a isomerk I were
ib
e
ti
Th
i
f
ra
ons.
e
e
quenc
r
Iv
;:S2 N-H, and NOs syrA. (requencles In cm.*7' given); o-,
510, SM; 1350, w-, 3516, 3450: ISM; P-. 3510, 3460;~
1340, Since the frequencies of the N-11 stretching vibrA:-.
dons agree with those reported and those of the nitro cromp
sym. vibrationsi with data for a free, unbanded n]" Imp,
there 6 no evidence of a If bond between the, amino and
q1tra groups of o-1. Blanche ID. White-..'
~;V
Distr:' 4E2a(j)~4E3d
'tereothemlll"- lof some 1.5-djus dee,
arsAw L all
WC71111i").-MC(Cilloll X NO,)Clf loll (is
tv -2-
and 34 W. 25% aq. N11, kept I lir. I tile Mr-ki-I t-ach, C
solid sepd., and df".Oved in ule. IICI Ogalve tile lChs-SAJI. Iralls-
in. 172,1*
decouipn.) and 0.07 g. nF the niore-sol. cis hydroOdaride'
ill. 160-71* (decompnj. I in 11,0 neutralized with nil.
rCaOll Vive the base, in. 94-5'. 1 (0.2 g.) in sict. IICI and
NaNOI gave 0.1 g. N-nilroyo ronspd., in, IWAO (RtOll).
Tile stere(wheuils-try of thesw clompoundsIq diicus.4ed. f.
I farry L. Vt&- .
Distri Wc(j)
a A1--d njtroparaffins~ T. Urba6ski Unit.
1- 1~ . - I
T ' Ft ., Warsaw). Tdraheilron 2, MWVMF~-A716,-
1-alti.11-h! presence of basic cAtalysts pituary nitrD-
4
paraffins are iscnnertztd und" the influence (if Ac~O or
112C:CO into hydroxionic acids. Practical applications
of this Isomerism were investigated. Concd. 141SO. (3.5 g-)
stirred at 100" with portionivise adda, of 2 g. 1,1-dinltru-
ethane (1) (cf. Levy, ri al., CA . 41, 0388a) an'l the mist.
cooled to 5-10% dild. with 8~10 mi. a1c. and the product
washed with a1c. and Et,,O gave 79% (HONJ[ft~.H.-SO4 [c(.
Polish 40.008 (1956)]. AcOH (10 g.) and 10 W. I added
dropwise in 20 rain. to 35 g. concd. HISO. at 1W-V (bath
ttmp., 1209) end the mixt. treated dropwise with 12-5 g.
cyclobexanone In 24 inin. at 120', excess AcOlf cvapd. wid
theresidue neutralized below50" withcohlari.295%NJI1011,
the or&. layer taken up iri EtiO and the dried (anhy,
S04) ext. evapd. yielded 727a caprolactain? bit.&
I 1FL-.T'?Y!4 iNWL95-64! :7777-7177:~.' !Wdiuall-
e-!v m1tv
W unsymnistrical isomerk derivatives a( tetran tro-
7
azozybe"enO _U and 1. UrbaiLAI (Poll' h"'
to
j!5re 1195SXt~ Englisb); d. priceding abs
.99 t ,
'Ut
tosyl chloritle, nltrobtnme, and diethylanilin at
witV
the product nitrated at 80* with 2:1 11NOrlisPOI save 4-
&Aoro-41-metboxy-3,3',6,6'.tctrunitroazoxybenztne, in.
which hydrcJyzed with aq. HBr In AcOH at 1100
afforded 4-chloro-4'-hydroxy-3,3'.5,5'-.tetrunitrmLzaxy-
benzene (1), m. 198-200. 1 was treated with McOlj,
NaOH,~ and MOM and the product treated with toxyl
chictride, nitrobenzere, and diethylaniline to give 4-ineth-
l-
oxy-4'-chloro-3,3',5,5'-teimnitmizoxybenzcne, in, 203-40,
which hydrolyzed with HBr In AcOff at 120* gave 4-hy.
droxy-l'-clilloro-3,3',5,5'-tetraiiitroazoxyhetizenc. m. 214-
IM Existence of these different isomers Is a proof of tlic
Lj I 1i Angeli theory of the asym. azoxy group. The 4'-MeO
group (in ring adj4eeut to azoxy group) fis more reactive
thu, n the 4-MrO mup.
Distr.- V20(j)AE-3d
D1 A r 4E2c?
iV4E3d
,
"*Pro'duz~s tit'altzatio
eno,7 T. tfiFf-tW n of 4N-bla(dime
Urba4skl
Saw BUM Ir I
o;rdthA,,307-8(1 Xin Enstlah); d. preceding abstr,-'!
.4 -B6(4iruethylantiLojazoxybentene was nitrated to 4.4'-;
'
3'
3
i
1
t
l
b
i
-tetrun
troam
no)-
troazoxy
enzent (
b
,
,5,8
~byla
),
"Me'
"
l
th
f
l1
i
20
d
d
b
8-0
o
ow
,
e
ng sequence,
.
ecatuprt.), a
so prep
y
(
of metions. Tetritaltroazotyanloole (cf. 2nd precedlug,
'
4'
2'
d)
4
bi
l
i
-tetfanitro-
-azoxy
an
so
e) was treate
abott.) (~,
,0,6
.
,
with HEr and AcOH to give
IF= MAwwo, tn. 186-7", which treated with tosyY
We" dtro~~--
yj, illne afforded thal
chlot 0 j.LqqdLAI
_
414khtera derip.,. ru. M-8', This was treated with
4
,
MeNH* 1A Moll to give the
m. 2&~V,whkh nitrated afforded 1. On Cl for MrNH
group exchange the 4 NH deriv, m. 206
produced. Owing to greater C1 mobility
the MeNH group
,
'1411 was substituted into the CoUs rint attached to awxy group
..
L
V,~ z
Stric 4F,2c(j Y.1E?XXV Infrared-also%flon
oun
Ida
J'adcu~z U 0-,A i Warsaw). Rocz-
CM.-- - U41
6U, Summary 251-4);
cf. C.A. $2, W45h. WIL-Infrared absorption spectra
were examd. of tetra liydro-5-ctliyt-5-nitro-1,3.oxazlnt-IICI
(1). Its 3-C2-etliyl-2-ititro-i-ii)-drox~,pi~pyl) deriv. (11). 5.7-
(M) bis(2-ethyl-2-nitro-l-h)rdroxypropyl)ammotittim chlo-
rid, (IV), bisf)-!ijetliyl.2-nitropropyl)ammonitim chloride
pholine (VI).' Ali the compds. oil
M, and mor ow strong
bands of.theXII-Xroup stretching vibratinns at 3 A, and de-
formation vibrations P (in the B-A re
,41on). There is no free
NH group band in the spectrum of I audV. Thiscnnfirms
t there exist
the! preXious hypothesis (C.A. 51, 12650d) tha
~~s between N11 and NO, groups. The C-N stretch-
ing s, seem to lie at 1209--11901 (1, 11, IV), and 1047-1031
'and 1224-1215 cm. I (all comptis.). It is su gested that
strong bands 3448 and M cm.-I In 11 and IA, and 6891, -
7143 and M cm.-t In U, M, and IV, reo. are due to OH
groups, and at 1016 cm.-I to C-0 stretching or 0-11 defor-
mation. The C-O-C stretching r of 1, 11, and III is finuid
to lie at 1111 cm."'. and that corresponding to cyclic ether
bond at 1042, 1053, and 1034 am -1 M with overtone P
at 4000, SM. snd 3M cm.-I, rjsp~. RI; was proved by
"amn. of morphiline, showing bands at 1099, 1942, and
4000 ern.-I, and confirms the structure of V1 and M derivs.
The values of o, found in the 6.4-p region correspond to free
'0% graup, or that bonded with only one Oll or Nit group
V). Thty are little affmited by 1-1 boods as in n1troak.
CIO uoei The stretchl g P bctwcen r, and N of the
NO~ Krnup may be amigx(j to 1087 (1), 1075 (H and IV),,
.1073 (in), nod 1058 cm.-F (in ;rqWent with previ..
A. KnOmw
Distr: IIE2c(,,)
I Nitration with dilute nitric acid. Tadeusz UrbafiW
ktecfi-.-, Warsaw~. R"sniki Chem -IfMUM
~P~o
H dro . --I (I)
iglish summary .-8- Hin -' can be
ith 25% H NO, LIM U2,2U, dull, M of I
to Y
nitrated if to y
(C.A.48.4546h). The same product can beobtaifted with
25% H N03 on 8-hydroxyquinoline-5-sulfonle acid (M) or 8-
hydroxy-5-(hydroxyamino)quinor3ne-N-sWfonic acid (IV).
The preseent expm show that I and IV may be nitrated with
15, 10, or even 7.b% HNO~. The rate oUnitration decreased
with low,!jingof cooca. The yield of P was 07-87%. Ithas
so far ben noticed that prior to'll6imation of 11, *4% is
evolved, This suggests that NO, il an essentia, inter-,
mediate (similar to nitration of pheuols). A. Krqglew3kL-
I
URBANSKI, T.
"The chemotherapy of tuberculosis"
P. 225 (Kosmost Seria B; Przyroda Nieozywiona, Journal on natural sciences
with the exception of biology issued by the Copernicus Society of
Polish Naturalists, Vol* 4, no. 3. 1958, Warsaw, Poland)
Monthly Index of East European Accessions (EEAI) LC, Vol* 8, No. 1, Jan. 59.
POLIJID/Organic ChordAry. Organic Synthesis, G-2
Abs Jour f. Rof Zhur-Khimiyal No 9p 1959p 31392
Author :Szyc-Levanska, K,, Urbanski, T,
Inst ;AS Poland.
Title :Contribution to Chumistry of Cyclonito, On
Nitration of Haxarlothylonatriparoxidadiariina
(MATDI-J.,
Orig Pub :Bull. Lead, polon. sci, Setd sci. chin.,
gool. ot geogrej 1958, 67 No 37 165-1677
XIII.
Abstract : With a View to confirn the as6timption
concerning tho formation of trimathylano-
trinitrar.iino (cyclonite) (1) in the nitro-
lysis of compounds containing the CHO groupq
a similar reaction vins carried out v th hoxa-
Card 1/3
POLOD/Organic Chemistry. Organic Synthesis. G-2
Abs Jour : Rof Zhur-Khimiyaj No 9, 1959, 31392
mathylenetriparoxidodianino (II). CH20
(III) and HCOOH. (IV) together with I viorc
revealed in the products of nitrolysis of
III an~, the absenco Of 02 vias proved. ;-c-
cordingly, the surit- 'lary reaction equation
must be as follows: II + ITH,4,NO M + 2N02
--.:- I + III + IV + 2H20~ 2o5 ~- of II and
4.~ g of V are added in snall amounts to the
soliiltlt'~M . of 3, -) 9 of II in 25 g of HN03 (d
= 1,5), the mixture is alloved to stand (so-
veral ninutes at 80-820 and 12 hours at 00)
anc! I is filteroc! off- yicV. of 1 26 percent,
molt. p, 203-2050. 111 anO IV are separated
from the filtrate as the 2 4-dinitrophenylhy-
drazono anC banzy1thiouronle salt respectively.
Card 2/3
POLOD/Organic ChcEiistry. Organic Synthesis* &.2
I,bs Jour : Rof Zhur-KhiniYaj No 99 19599 31392
0 Tho absohce Of 92 in the separating gases
ib clotornined by thl negative reaction with
sc-Ltraninole ~6 So Gtirvich
Card : 3/3
POLAND/Chemical Technology. Chemical Products H
and Their Applications. Pesticides.
Abs Jour ; Ref Zhur-Khimiya, No 69 19597 20704
Author :Eckstein, Z., Halweg, H., Krak-ovika, P.,
Urbanski T.
Inst :AS Polana.
Title :The Fungistatic Activity of 3,4-Dichloro-
phenoxyacethydroxamic Acid on Pathcgenic
Fungi in Vitro.
Orig Ptfo :Bull. Acad. polon. sci. Ser. sci. chi.-.I
geol. et geogr., 1956, 6, No 4, 235-23i)
XVIII
Abstract : Tests of the fungicidal activity of hydroxa-
mic acids by the 1--iethod of 11cylinders" with
Candid'a albicans 102, Cryptock.=us neofor-
Card :1/3
POLOD/Chemical Technology. Chemical Products H
and Their Applications. Pesticides.
Abs Jou2 Ref Zlhur-Khimiya, N-b 6~ 19592 20704
mans 3US Trichophyton gypseum 7682 T. rub-
rum 3da, T. violaceum 3905, T. schoenloini
111 1 F and Penicillium 45 showed that 2,4-
and 2,5-dichlorphenoxy- and 2-methyl-4-chlor-
phenoxvacethydroxamic acids inhibit t'in. grovith
of all tested species except C. albicans; al-
pha and beta-naphtoxyacethydroyamic acids sup-
presed the groi~th of fungi o-f the Trichophy-
ton family; 5-nitro-2,4-dichlorphenoxyacou-
hydroxatuic acid is activc a.,7ainst tho latter
three s-pecies; 21416-trichlorphenoxyacothy-
droxamic acid is non-active. 3,4-dichloruheno-
xyacethydroxamic acid (I) in concentrations
of 0.005-0.25 ml/g suppresses the gro-th of
Card 2/3
1~ -93
Pnr.
POLAND / Organic Chemistry. Synthesis.
Abs Jour: Ref Zhar-laiimiya, No 7, 1059, 23268
Author : Urbanski, T.; Tarantowicz, W.
Inst :-Xc-a~ --~6iences, Poland
Title On the Preparation and Some Properties of Butyne-
2-Diol-1,4-Dinitrate.
Orig Pub: Bulli Acad. polon. sci. Ser. sci. chim., geol. et
geogr., 1958, 6, No 5, 289-292, XXIII.
Abstract: N020CH2C CCH20NO2 (II) was synthetized by nitrating
OHCH2C CCH20H (1) and converted into I acetate (III).
20 g of I is added to 83 ml of the mixture (2 : 3)
of-HNO3 (d = 1.50) and concentrated H2SO4 at
18 220; 20 min. later it is cooled to 50 and poured
into 750 g of ine, and II is extracted with ether,
yield 70-75%, n25D = 1-4732, d20 = 1.4o8. 6 g of
Card 1/2
POLAND / Organic Chemistry. Synthesis. G
Abs Jour: Ref Zhur-Kh1miya, No 7, 1959, 23268
40 Abstract: Zn dust is added to 2 g of II in 25 ml of (CH3CO)2O
in the duration of 45-60 min. letting dry HCI to
pass through, all is poured out on ice, and III is
obtained, melt. p. 300 (from ether). 11 causes a
strong headache, and it explodes if stricken or if
it gets on a hot surface (245-3800); as far as the
force of explosion is concerned, III does not dif-
fer from nitrates containing the same relative
amount Of 02- -- V. Tynyankina
Card 2/2 6_1
~C,7,jtry
(;?.tc-,;Ory
tic organic
pOL;LND 53
orge-nic Ijo 5 33) 9
1959;
No 5,
larbarmkip
I -PLZOILIan'Sole
Polish JO of 14itration Of ppp
products
geol.
Sol. Chim.,
,Sol. Ser. XXIII 0
Acad polo,,.) )C)9.3039 116
0 00i958j &V No 5, 12-318 (1) , m
et geogr I -azown 31 5;~ Cs3coo"'I
fl-,p L%ture of 40% 003' j-djultro-
sitratIOTI * 0 to 3p
studied* rates I at1j.2001d 60%, M.P. 210-
'14as
and 5% water xdt' le (11)* C11 Gooli and 20'
-anIBO , 34 3 0-
_4F4, 64100 trinitroa7
mixtu-ro Of 1 Zo 3x5pY n.p. 179-
at 850 nltratOs old 60%, 1 85% ?k
water (111), 75- yid
41-anisole (d ti - 50) 8,,d
j4jxtu a of 11903 111 1 lield
12S jtrates I 01troazolcy-4,41 misols I ;
0
at 3 I-tetran
at 85 oto 315,31,5
Abs. jour
Au,,,bor
Inati-tilt.
ILti 0 ,
1, ?ub.
or
Ab5trOLIL
istiv Ijng O.Fv obta
cc t UZe xxx a Inecq *
O-r -S
the
POLAND / Organic Chemistry. Synthesis. G
Abs Jour: Ref Zhur-Miimiya, No 7, 1959, 23335
AkiL_T.; Urbanski, Js
Author : Urban
Inst :kcademyo-f Sciences, Poland
Title :On Some New Unsymmetrical Isomeric Derivatives of
Tetranitroazoxybenzene.
Orig Pub: Bull. Acad,,polon. sci. Ser. sci. chim., geol. et
geogr., 19 , 6, No 5, 305-306, XXIV
Abstract: The preparation of two pairs of isomeric asymmetric
derivatives of 3,5,31,51-tetranitroazoxybenzene
RRI(NO2)-C6H2N(O)=NC6H2(NO2)2R" (I. R = 5-NO21
a RI = OCH3, R" = Cl; b RI = Cl) R" OCH3;
c RI = OH, R" = Cl; d R1 = Cl, R" OH) is
described. Their existence is a new confirmation
of the theory of An eli ~Angeli A., Jazz. chim.
ital., 1916, 46, (2~, 67 concerning the asymmetric
Card 1/3
POLAND / Organic Chemistry. Synthesis. G
Abs Jour: Ref Zhur-Khimiya, No 7, 1959, 23335
Abstract: structure of the azoxy group. I (R = 5-H, RI
OCH3, R" = OH) is treated with P-CH3C6H4So2C' in
the presence Of C6H5NO2 and C6H5N-(C2H 5)21 the
produced I (R = 5-H, RI = OCH3, R" = Cl) (Ie) is
nitrated (800) with a mixture of HN03 and H3PO4
(2:1), and la (melt. p. 185-1860) is obtained. By
the saponification (HBr acid, CH3COOH, 1100) of la,
Ic is produced melt. p. 198-2010. lc is treated
with NaOH solution in CH30H in the presence of
ethylacetate, and Ib (melt. P. 203-2o40) Is ob-
tained from the produced I (R = 5-N02, RI = OH,
R" = OCH3) similarly to Ie. Id, melt. p. 214-
2170, is obtained by saponification of Ib similarly
Card 2/3 6-6
,nthesis,
ernistry' S ;cj335
rOLAND / organic Ch Vo 7, 1959,
iie r ,j,,r_njmjyas cafzcitl or t,,e
Abs J011r: , great reaction -lb is 'noted
to The -red Wita
8 compa
Abstract 00114,,group in :La a
Zaretskiy
0
Card 3/3
URBANSKI T . URBANSKIgJ.
On products of nitration of bia-4,4'-(dimthylanine)-azoxybenzene.
Bul Ac Pol chin 6 no..5:)07-308 058. MAI 9:7)
(Biedimthylaninoazoxybenzens)
(Nitration)
---------------------------------------
POUND / Organic Chemistry. Synthesis.
Abs Jour: Ref Zhur-'~iimziya, i%-o 7j, 1959., 2' )323
Author : Semenezuk, A.; jjrbaaski,, T.
Inst :Academy of Sciences, Poland
Title :On Preparation of N,2,4,6-Tetranitromethylaniline
with Fuming Nitric Acid in Presence of Inert
Organic Solvents.
Orig Pub: Bull. Acad;,polon. sci. Ser. sci. chim., geol., et
geogr., 19 j 6j No 5, 309-311, XXIV.
Abstract: The nitration of C6H 5N(CH3)2 (I) by the action of
HN03 (d = 1.52) (11) in the presence of the sol-
vents CHC13, CH2CI2, CC14 Or C2H2Cl4 proceeds
smoothly and results in 11,2,4,6-tetranitromethyl-
aniline (III). The solution of 6 g of I In 75 g
of CHC13 is added dropwise to the solution of 75 9
Card 1/2
POLAND / Organic Chemistry. Synthesis. G
Abs Jour: Ref Zhur-KhImiya, No 7, 1959, 23323
Abstract: of II In 75 9 of CHC13 and the mixture is heated
to 400. After the separation of N02 has discon-
tinued, the temperature is raised to 610 and, after
the distillation of the solvent, to 800 (until the
color of the substance becomes light-orange). 50
ml of water Is added and III Is obtained, yield
98%, melt. P. 1290. If the nitration has been
carried out in C02C14, the solution of III in II
is separated by decanthtion, yield of III = 92%.
-- V. ZEtretskiy
Card 2/2
POLAND/Physical Chemisti~ - Molecule. Chemical Bond. B-I+
Abs Jour: Referat Zhdr - Xhim) NOa 9, 19599 30152
Author : Eckstein, Z., ktaczkiewicz, T., Sacha, A.,
Urbanski, T.
Inst : Polish Academy of Sciences
Title Note on the absorption Spectra of 2-Nitro-2-
(11-cyolohexonyl)- and 2-Nitro-2-(Il-eyclohepte-
nyl)-l-p-chlorophenylethylene
Orig Pub: Bull Acad Polon Sci, Ser Sci Chim, Geol, et
Geograph, 19584No 5, 313-318, XXIV-XXV
Abstract: The absorption spectra of 2-nitro-2-(Ilcyclo-
hexenyl)- (I) anJ 2-nitro-2-(It-cycloheptenyl)-
1-p-chlorophenylethylene (II) have been inves-
tigated in the LIV region (2000-4500 A) and in
the IR region (2-14/,~). The spectra of I and
II are very similar. The 3030 (2985) cm-1
Card 1/3
POIAND/Physical Chemistry - Molecule. Chemical Bohd. B-4
Abs Jour: Referat Zhur - Khim, Wo-' 9t 1959, 30152
has been g4elated with the intraplanar deforma-
tion yit*at o4o of the ethylenic CH group. The
826 en-I bahdjjVhidh ib dbaracteristic for the
deformation ~ibiotiohs of the CH group in tri.-
substituted cis-e'thylenesq confirms the cis-
configuration of I and II.; This configuration
is apparently stabilized by the presence of the
olefinic rings in both molecules. The synthesis
of II is described. -- V. Koryazhkin
Card 3/3
SLOPIX,S.; MORMARSU. H.; MORDARSXI,M.-, URBANSKI,T.; SKOWRONSKA-SZWIB.B.;
DABROWSXA,H.
04 antiDOOPlaatic activity of some guanidine derivatives in
vitro. Bul Ac Pol chim. 6 no.6:355-359 '56. (MAI 9:6)
1. Institute of Imimunology and Uperimental Therapy, Polish
Academy of Scieaces. Institute of Organic synthesis (Warsaw),
Polish Academy of Sciences, Institut of Tuberculosis. Warsaw.
Frosented by T.Urbanski.
(Guanidine) (Antigens and antibodies)
(Tumors) (Cello)
SLORK.S.; XORDARSEA.H.; 1KORDA=I*Me-# URB-ANSKI,T.;.GURN1,D.
On antineoplastic activity of sow 1,3-oxazlne derivatives In
vitro. Bul Ac Pol chis. 6 no.6:361-363 158. (INAZ 9:6)
1. Institute of Iwmanology and Irperimental Therapy (Wroclaw),
Polish Academy of Sciences. Institute of Organic Synthesis (Ware"),
Polish Academy of Sciences. Institute of Tuberculosis, Warsaw.
Presented by T.Urbanaki.
(Oxatine) (Antigens and antibodies)
(Tumors) (Cells)
n#g�L42~, SKOWRONSEA-MMA IN,B.; STRYANIAK.L.; VESULIBT,J.; JANOWINCeN.;
JAKD(OVSKA~K.; URIBA SU,A.
on too-alcotinoylbydrazone of ethyl acetylacetate and Its anti-
tuberculous activity. Bul Ac Pol chiu. 6 no.8:475-A79 '58.
(INAI 9:6)
1. Institute of Taberculosts. Warsaw. Technical University
(Politechnika), Warsaw. Comunicated by T.Urbanski.
(loonicotinoylhydrazons) (Stbyl acetoacetate)
(Tuberculosis)
LMANSIrl . SIKORBXA,A-
On the sensitiveness of 2,4,6-trinitrotoluene to impact. ftl Ac
Pol chin 6 no.10:617-620 158. OMAI 9:6)
1. Department of Organic Technology, Technical University
(Politechnika), Warsaw. Presented by T.Urbanski.
(Trinitrotoluene) (Ixplogivee)
ECESTEIN,Z; SACHA,A.; SOBOTICS.W.; Urbanaki,T.
On preparation and properties of 1-cyclooctenylnltromethane. Bul
Ac Pol chin 6 no.10:621-624 '58, (xui 9:6)
L Institute of Organic Synthesis, Pblish Academy of Sciences.
Institute of Pharmacy, Warsaw. Presented by T.Urbanski.
(Nitromethane) (Cyclooctene)
(Cyclooctanone) (Olefins)
ci 7594'1
1: D ill :Eckstein, Z., iialweg, H., Krakowka, P., andlfc
:7
-~le !)or gmler
Oti the Fungistatic Activitty of 3,14-d,.chlorophenoxy
-aceto'rjdruxam'lc Acid on Patnogenic Moldii in vit.-o
:Meri Lor-%viad i V.jkrobLol, 10, No it, 48?-492 (1-958)
:,tee ?Z~Xfijjz, ,i-959, 6, 20704.
Urbanski, T.
240
POLAn/Physical Chemistry - Molecule. Chemical Bond. B
Abs Jour : Ref Zhur Khimiyn, Ho 19, 1959, 67057
Auth~)r : Urbanski, Tadeusz
Inst ;
Title : Aliphatic Nitro Compounds. XXXV. ConcerninG the
Infrared Spectra of Amina Nitra Compounds Derived from
Nitroparaffins.
Orir, Pub : Roc=i. chem., 1958, 32, No 2, 241-254
Abstract : Infrared absorptioi, spectra of certain derivatives of
1- and 2-nitropropane containing sec- and tert-amino
gToups and hydrixyl groups. Study of the valencc-vibra-
tion absorptiDa reC;ion of N-H b:Dnds confirms the earlier
stated assumption that a hydroGea bond my arise between
the nitr3 and amino C~raups. The latter hydriGm:i-bond
Card 1/2
6
C: st -Y Bj.-.d.
B
Abs Jour Ref Zhur Khimiya, No 19, 1959, 67057
forratlan hns little effect on the frequency )f asyra-
metric and symetric valence vibrations of 1102. The
small decrease in the NOP (sym.) is exp1niiied by ste-
ric factDrs, A bmid if the C-0-C Grjup at 1111 cra-1
was identified ii,. tho spectra of compui4a coiitni;.i-.,.r
the 1,3-3xazille or the I-)Xa-3-azacYcl.)-)ctane rin(;.
See Comnunication XXXIII in RzhKhira, 1959, Na 8, 27503.
V. Aleksanyan
Card 2/2
Colintry
I Gat--~.;ry
j-.ba. Jcur
Iti thjr
Tn3tli-Ut.
Title
or i-~ -4-'uh.
POLAND G
organic Chomistry. Synthetic Orgafte Chem stry
Ref 7Ju= - Katz., No 5, 1959, so. 15351
-Mikulski, J.; Eckstein, Z.; Urbanski, T.
:
: On tho Problem of' Synthesis of Herbicides Vi.
Synthesis of 2-Aryloxyethylamines and Theix 11
Derivatives
:Roezn. chem., 1958, 32, No 3, 661-666
~;Ibstract :As a result of further search of active herb-R-
cides (report V, see Rof Zhur-Kh1m, 1958,
32402), a series of ArOCH2CH2NHCOR (I) was
synthesized. By the interaction of ArOFa and
BrCH2CH2Br (II), ArOC112CH2Br (III) is obtained.
By the urotropine method, III is transformed
into ArOCH2CH2NR2 (IV); under the influence of
RGOOC2H5 M, I is obtained from IV. 1.1 moles
of NaOH In 180 ml. of water are slowly poured
Card: 1/6
C at c:-.- o ry
Aba. Jour Ref Zhur - 70da., No 5, 1959, No. 15351
Au'- ho r
institut.
Or X,; Pu b.
A b 3 t' r F.- c tinto 1.1 moles of 2p5-Gl2c6H3GH in 400 ml. of
cont'd. water and 1.2 moles of J1 during boiling, and
boiled for five hours; III is extracted with
other, Ar=2,5-C 206H3 (IlIa), yield b.p.
1 1
150-1520/3 rm. III is obtaine,d analwv-sl~,
(Ar, yield in %, b.p. in 0C./mm-, n D, d arf
given): C6H , 42, 112-11,1/4, 1.5525, 1-3555;
2-CH C H (~Jjb), 61, 118-120/3, 1-5444,
3 p 40.4 138-140/31
1.290 ~-CH~-4-ClVi- 6o, 147- ,
1.5600, 1.31 6; 2,4-cf' 4A,
2c6H31
C Ant r,,
ry
G
15351
J,:.nr Ref Zir-Ar KWA., ho 51 1959, No.
u t ho r
Titla
Orir~ .-Iul~.
!,il:Mtract
leont'd.
C.-,rd:
:1-5785, 1.5929; 2,4.5-c13
C6H2, 45, 158-160/2,
1.05 Moles of Ijjb in 200 ml. of CE01
are idded to 1.1 Moler of (CH ) N~ M) in 3
2 6
600 mi. of CHC1 at 500, and heat d for four
hours at 1~5% 98% of IIIb-VI is separated out,
M,P. 172-173 (from chloroform). Similarly,
with slight alterations IjIa*VI is obtained,
yield 80~, m-P. 176-179 6 (from chloroform).
0.56 mole of IIIb*VI is poured into 460 g. of
concentrated HU and 700 ml. of CH30H, mixed
3/6
Country G
lAbs. Jour I'lef Zhur - JoAm., No 5, 1959, ziD - 3.5351
Author
lnst4tut.
Oriz, Pub.
Ab3tra a L
cont'd.
at 40 0 for four hours, the solvent Is distillel
off, the residue is alkalized by NaOH and IV in
extracted with ether, Ar =2-CH 62%,1
&HIL, Yield
bj3,~290-910/2 mn.; hydrooblori e (11C), m.p.
2 - 130. Analogously, from the corresponding
IIIO*V V Is synthegized (Ar, yield in %# b.p.
in Ci.~Mmi., m.p. in C. of HC are given): C6H511
45 101-103/4, 215-216; 2-CH3-4-clC6H 58
1-1~-138/2, 165; 2,4-01206H3, 51, 16VW3,
188-191; 2,5-Cl2C6H3' 42, 162-164/4, 253-254;
Countrir
Ref Zhar MUm., ]No 5, 1959,
G
No. 1.5351
1r13t!'U',A.
Titla
Or1r, Pub.
nbstroct :2,4,5-C13 C61 168-171/5, 244-246. 0.02 mole
1~ '21 49
cont'd. I . of alcohol,
Of Vm R =C120H or Cl C in 5 ml
is added to 0.015 moie'of IV in 5 ml. of alco-
hol, heated at 60-70 for two hours, and I is
separated out (Ar, R, yield in % m P in Oc.
are given); G6H5, CH012, 75, 85-66; *C~H5, CC139
17, 63-64; -CH3G6H41 ClIC12, 90, 93-94; 2-CH3-
C6H41 CC131 90' 74-75; 2-CH3-4-ClC03, CC131
67, 86-87; 2,4-012C6H3, ClIC12, 70, 106-107;
5/6
Couiltry G
Jour Ref Zbur - KUM., No 5, 1959, No- 153%
AULM2,
11194,
T I t
Orl, Pub.
Abstract 2,14-C12CO31 CC13, 75, 67-68; 2,5-Cl2C6H3,
cont'd. ClIC12, 90, 120-121; 2,5-Cl2r,6H3& CC13, 95,
97-98; 2,4,5-Cl AH2, CHC12, 8o, 137-138;
2,4.#5-Cl3C6H20 C013, 78, 116-117, V. Sko-
rodumov
r i C-f-tiric Ch-..,t1stry
7 r
lli-bj~fl:IiLjl Ta~~t,1;3Z
7:
t
Ycto
t!
0*1 "'l,
3 o-f' b)~Ilin, i.-- ft.-ded
0.1 --?'6 4
(IT-) in 10 of alloohol. Thq milx-
licur.- a dr.,-)T)s
nt
5 TR, R I po
~Ilcoh,-,'L) ,s follo -:s):
1/6
C -)unt ry G
,r; ry Or t c i t ry. L; Yn Ii e t I c (!illailc Y
j,~ljr,
i !:-li, - r
itut.
A
r at
IT; 01 85 1f49 (decomposition); CH30,
H,6, 75, 16.3-164 kcc_Om-r~osition); li'l T C 21lq I
"OlY -63:15
65, 102 (-4ccnm-osi~klion) 1. C211~,l;
(doccray,osition) CT-~C', ~32H5, 1 1-124
(ducom'p~ositior.) 3 5 :121 '(d'
ecomposi- L
tion)- CH IT 2 148 221, -215 (def3ol-nc.lit, on)
2
NF2, i 8 ~lal, 5'lo, C1130, 3,~
~2,
0.1 mola 4-NO2c6H4ct~'!-2r,'(_nC2TT5 in 5no rd. of
r_bsulute CH-,CIT hy,:rog(;,--itel fo-r 1, ]--li.rs ol!er I
0- 3 Y't62 " 40-45"; 'h,! ffltr~-lc i s
-try
'
R f 1959, I'c,.L ~375
NC.12
. ,
lilu"
,
e
t 0,f
to 5'D; 50 rJ
-
'
NIaC-H are 51,:f,
'
-
,
t -L
Cj r,
r
TI
1 '1 8 2 the iicl-
2, j
v
. .
yield boiling!
-132
175 Tlic 7ixture 04,
11
.
5 1 e 0-5 f Seb~'Cic
3/6
C;.,.mtry Po I i. nd G
try
C,-.. t c.; try. ti c orl-Inic lu!,
No.12, No-42375
Zo-,t'ior
it t, .
cri- Pub.
r c t
:polyanhydridc is poured into the 3USrension
J- / 32 at 0-50; t~,e tomnlezR--
Of in C:
A
t'.Ir-- is zai3c~l t~ 'ibc,"t 400; Mixturt! is
stirred for hour5 an,' then set out for 48
3
h1wirs At ,-bout 200; the Ari.act~-c,;, proftct is de-
compooed with ice -,-a.-d MCI; t1w I~i (~is-
3""-Ivt--cl in 70 g of 110.11C03 in 1.2 lir~--ra f -;-iter;
tht~ flltrite is lif-,idified --lit"i the re-
sidue i-,, br)il,.d for 15 ninutes -.-ith 200 rd. of
10-:4 50 ml. of satur.,ited GINa t-,rL3 added
I. M
G
It,.; i.-~try. C',,ntrjf!Ljc 0;*f,,,, A(,
Ref No.12, No-4~'375
T
:?'-=H, n:z8
r 0
ben civ (1) prrd4ucts In the connen-
z
tr ions (if 1. 5-11"-' - 5A riF, ~;,,e t'~Z L jVt3 fl "I 1"4
T3""G ar H37Rv, but !tr,,! i:,:icrllve
tuborculnot,itic %ctiv-
ity Of co!,powic"a cdnta-*;iirl~~ the C'13C- P-r~"~r' is
t~)%;; T-,:if,~ tu3urculOntatic actlv-
'-'-e ITH2 grriup. he
i'vy containIng T
lij%gth of the ali:;iatic (.,!lrdn a-pnrently lia3 no
5/6
--an t rr
1959,
I-, t !-I:-.; r
s~ v;- 'Howt!,jur la , b )uive a
t, Cue r iln, C t I V tT --n o f
'bl-I I o .-I ta r .13
III CO
1/"3(;C) the tie actIvity in 'litro*
See report I in Ref ".~-,ur-Ehir-dya, 1515F, 1-10-10,
32371.
collAtry Fol3nd G-2
Gatel.lory
liba. Jour h 588-5
Author Belzecki, C. and Ur1ranski, T.
Institut, Not piven
Titla : Thioremicarbazories of Leto Acids. 111. Thlo-
fienicarbazonen of I-,Lhyi Estern of Aroylaretic
Acl-(Iz and Thoir DeriV;1LJV(-,F;.
Crib; Alub. : Roczniki Chem, 3.2, 1-.o 4, 779-787 (195"')
1~bstract : Tn the cource of the search for new antitubercular
apents the authors havv synt'hecized a series of
compounds having the f3tructure PC11jN1fJ1=C(R)Ci~ C00-
C-2 11~ ( I ) .When I are hcated or dissolved in 11H,.OH
cyclization to 1-thioformamido-3-aryl-5-pyrazo~-
lones (H) occurs. A numoer of 3-aryl-5-parazo-
10neU (TIO anti 3-aryl-5-isooxazoloner (IV) have
also been prepired. 0.1 1101 RCOCi;C(YJCzk; M in
hot n1cohol, is treated rapidly with 0.1 mol
jiH2(;ShH1;h, (VI) in 10 mol. water, the solution is
Card: l/8
COUI-Ary I Poland
0 -1 t o1y ri ry
'j-2
Abs. Jour J-1
Author
Inatitut.
Title
Orig Ilub.
Abstract refluxed O.r,-n' hr- witt. the actclition of ctverai
drops of 01 (acia), !~titj ~he Y which cefinrates
is recrystallized from alcohol (method A). A
mixture of V ind VI (0.1 mol cach) is gmund in
tnr, fo~aminr
a mortar, fUSed at JOL_jj~l- 111,ti'
stops, the relt in a-,Ixed rith water, and the
precipitate is recrystallized fror. alcolhol (meth-
od 13). The foiloalrip, I -stere obtninfw (it. the
me"hod vaed, -Uld EhP dOCOMr. t-mp in *G are given
in that orL!er)! f-NO-j C6 !14, , A, 1170-17;7; Ii-l~,4C6 ik
Card: 210"
country Folund
Catogory
Abe,. Jour 45885
Au6hor
institut.
Title
l
Orig.Pub.
Abatract B, 162; 4-03 c0h~~;6114 B, 152: 4-r-~E~ OG6
A, 123-124-, 4-BrC6H, (1h), A. 1'IP-I?j; -pyri-
dyl, A, 155; -pyrid-il, A, 169-1t'o. V and 41
(0.1 mol eacO &rr: rr.)und and ru;-,-ed ny m,~th-)d A,
at firat. at 10-',' Firld Lhen, when the foaming has
ceased, thtt temperaturp ir raised to 10-15* below
the mp of II.Le !-tven 1; the increacie in terpera-
ture ia accompaniud by reziewdd foaminr; the
temperature is raived an additional 10-20' and
maintained at that level until the complete
Card: 3/8
Country Poland 0-2
Catcqory
Ab31 Jour 45`85
Author
Institut.
T It Llc
OrIg Pub4
Abstract ceceation of -ind the melt in tround wit.
waLer ond II nd --ecrystalli7ed trom
MheL met:ioa 3 j.3 use.1, 0.1 mA I in a t,~n-fold
excezF3 of liqlij-d paraffin is beated LO a tenipera
ture 5-100 acove the mp of tap 64-ven r; rit the
complction of the reltin7, of I and thr, t,rmina-
tion of the r-2acticn, 11 reanzater- otit; Ui
laLter is isoiated ana warhed with othe- ..L.
h e
aryl group, method, and clecoi.ip temp in arc,
given that order for the :ollowing I.::
Country Poland G-2
Catc;gcry
Abs. Jol~w
Authur
Inatitut.
Titlo
GrIff Pub.
,Abstract 4-YO2 C6 H4 B, 264-;,66 "ti-Nd, G& H, A, 224-226;
4-CE4 CONHG6 N A, ;-759-2611: 4-CH3 CC6 i,. , B, 165;
4-Brr.(, if, , B, 251: f, -pyridyl, A, 2--'6; r -pyridyl
A, 222-223. U.1 nol V in a ten-fold excess of
alconol is treated w--th 0.5 mol N2H4-H70 and
heated for 15 win to Five III, yield 50-75% (the
aryl jrrolm and the decomp temp in OG (!rom a1c)
arc! in that order): 4-NO., C& 14 . 238-21;,9;
C6 i4 23.5-2.56; 4-CH3 CONFC6 H4 , 261-265;
4-CiI3 OC; 222-22 3; 4-BrC; ilk, 246-;!49; ~ -pyridyl.
Card: 51,4
Country Polarid
Abs. Jour
Author
Inatitut.
T ILI(,
45K~5
Or ig Pub.
Abstract 1 259-260; de'-pyridyl, 27S-279. 0.1 mol V in 100 ml
CJ30H ic refilixed and G.Vli nul 'IH20H in IGO Lni
CH.Off are added quickly, tre nolutinn ib allowcd
to stand 21; n-s in tfic rcfri~reraxr, t?iv Nli salt
of the enoll-ANY-m of TV io wa-hed dir-
eilved in viater, ~,nd the rolnti~,n ;-5 acidif~rd
with rAll C14 COCH '~o ;7,ive _230-400Z IV (the aryl
group and de~omp tomp jil 'C '%from ab;) are ,ivell)-
4-NO2 C6 114 (;6 H" WNIiC, 1~
1~)O -, 4-C1 OC, H,. ,
j _, 1143-.
(Doulitry Poland
Catosory
Abs. Jour
Author
Institut.
Tit1c
I
C-1.,
. _; Pub.
G-2
45885
Abstract dyl, 151-153; ('-pyridyl, 199. The re5ults from
the tests of the tubercuLontatic activity (TSA)
in vitro on 1-1. tuaerclilosir., stra-ine If3?Rv and
FiGg as viell az on M. omcgmat-a are reported,
Among the I prepared, la and Ib were found to be
most accurate. The cGnponnds Ha, b were found
to be more active than the correspondingly sub-
stituted 1. A decrease in TSA is on6erved when
the NH?CS group is removed; No correlation could
be made between the effect of the p-sub8tituent
Card: 7/8
voul~t ry Poland
Abe. Jour
Ruthor i
Institiat.
Titlr-
Orig Pub,
45b8=
Abstract and the T3A of 111. Th,3 activity of IV ie analc-
gaus to thnt of 111. Far Comrunication II see
RZhKhim, No ta, 1999, 42375.
Skorudumov
Cou;itry Poland G-2
Gate-ory
C
Abe. Jour 45876
Author brhajLski, T., Serafino-ma, 2-1., and Stefariiak, L.
Institut. Not given
T it1c.- The.Preparation of DiacyllliydraiUnes from Acyl-
hydraz.-Lnes
OrI3 Fub. I Roczaiki Chem, 32, lio 4, 1)57-961 Uqj8)
Abstract t The hydrazone RCOKJ1Nr-C(C1~)CH2COOC,,Hq (I, R
-r -CSHAN), obtained by the reaction of isonico-
tinio acid hydrazide (11) with acetoacetic ester
(III), on refluxing in water (2 ors) is converted
to 1'2-~diisunicotinoyliqdrazire (IV), YiOld 93".1
mp 26o-261*; the rnaction in accompinied Uy the
~~ormation of small ouantities of 41,51-dimethyl-
A
pYrazo1o-(4',3'-5,0- 0(-pyroae, my, 245-2460
(from a1c), III J.9 also prepneed in 70-78% yields
by refluxinr an equimolar mixture of 11,ard IN
112 -* h1'LLjtO'-rqkj'y
it ry G
Poland
OrC.;ini.c Chev~intry. Yn'll tt
Ref Z~h-ur-l"Mill 7-a No.12 .1959, 11.1o.1,2379
,C) M) ~$lL k,
;.,,t j., -
0 t
;ynth,~sizing
Uontribution ttlo ",!'e Pr 0Qrlf
cetic
r '
i c A
IT
.
.
e
lljcf!, 32, INTo.4, 9'3-970
The follo-viing thl'(-(3 flr0u.5 (;f t" of
-, Y0 r1iri"Llico hols
r j -
.
'H2
t 5-C13'6lT2-0r;H,)WOC
o
2
!',02 (TI (1) io obt,i~,,,flc,
,
t R=
ction Of
b
y
in
5-:"l 3C6"2('!'a) 2C 02) V'
r,f -,yrL~lne r.-~?thod
by -IV 3
the !~'n r. thc corres
r
.
in ;vricine B).
1)r
f5,D
llo.12, 1959, NO.42379
jour. Rt~f
o r
it
J-r
T11 c%nnot be obt,-.ilrl-~.! by nI, T-3 but
is fc,n.c,*, by *!;y "II) with
LT T
N02(;H2,C1i0,C13)OF k A. i 1
of alcoh~
-wn(,c-r thf;
H GCH
2 14 5-r.13
HC1 o-pen-s the :`-rig, for~-,'-nr 6 2 -,' 2
-CuC,11,'k2"(1YO (CH-,:~0H)2 0-0,') nr)lp V !,rd
C. 01, r. le 4a irl 45 r,.L 6 of '074cli :w.~i 12 r-1. of
0 1 -1
C5H5N -rY hc-~tcd tt~ 50 30 M~inutes; the
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