SCIENTIFIC ABSTRACT USUBAKUNOV, M. - USTYUZHANIN, G.YE.

Document Type: 
Document Number (FOIA) /ESDN (CREST): 
CIA-RDP86-00513R001858220015-9
Release Decision: 
RIF
Original Classification: 
S
Document Page Count: 
100
Document Creation Date: 
November 2, 2016
Document Release Date: 
April 3, 2001
Sequence Number: 
15
Case Number: 
Publication Date: 
December 31, 1967
Content Type: 
SCIENTIFIC ABSTRACT
File: 
AttachmentSize
PDF icon CIA-RDP86-00513R001858220015-9.pdf3.55 MB
Body: 
BLESHINSKIYR S.V.;__USVBAKUNOV, _~!- Determination of halide and thiocyanate ions by the use of merearbides. Izv.kN Kir.SSR.Ser.est.i tekh.nauk 4 no.9s47-51 162, (MIRA 16:4) (Halides) (Thiocyanates) (ion exchange) 88861 3/044/60/000/007/015/058 It .3 V00 C111/C222 AUTHORt Usubskunov, R. --------------------- TITLEs On a method for the estimation of the neighborliness of solutions of some differential equationa PERIODICAL: Referativnyy zhurnal. Matematika, no-7, 1960, 83. Abstract no-7563. In ab. Materialy 8-y Nauchn.konferentaii professorsko-prepodavat. sostava Piz.-matem.fak. (Kirg. un-t). Frunze, 1959, 43-46 TEXT: The solution of the Cauchy problem for the differential equation R(Y) f(X)1 R(Y)-= y(r;)+al(x)y (n-l)+...+an(x)y is replaced by the soluticm of the Cauchy problem for the equation Q(z) - z(n)+bl(x)z(n-l)+ *.o+bn(x)z - f(x), where Ibi (x) -ai (x) I e. F- , x r= [at b J, 1-1 9 2 p . * ., n. An eeiimation of the difference Y-z and its derivatives is given. fAbstraoter's notes The above text is a full translation of the original Soviet atratract.] Card 1/1 GRIGORYAN. Kh.A.; GO'FMLIK, M.L.; ALIYEV, Z.B.; PIEKIR, B.A.; USYNINA, T.P. Producing furnace black from gas rich In air by enriching the gasoline liquid hydrocarbons, Sbor.trud.AsKII NP no*2:362-372 Ag 158. (KIRA 12:6) (Carbon blacir) f,T, A 687 621.127.3-1.4 TAwlumacz-R_Thr 1prilestian in Liffhoing fleffeeLvIt Made by Eviparalin metals III a Vacuum, ,,Z!%Mo"lwnniP w irchtilre Awlethirl odblysk6w wyltoninich prim ot1pnrownrile mclisIl w prtSznI'*. 11'rzellIsid Elektrotrehniculy No 9-10 - H. 14rO. pp. 4111 -490, 1 fig.. 4 tntu. Thr urtirle cnntf~n,% all nwkr&imejli, of itnvingi In electric rnerry likely to accrup frouil rvilinclug, lanips IttLett with Aeparate r(!flectnr3 by I-Mill' with all Ilinpr reffect,ing coothir. The author dells with the mrthOds of nl)plyln,-' the roalinpr. the sob-Olon of mrinh for the I "Inkthir mid ilip Ithp;+ c-I the bulb. U')TYIIZI7CZq R. "A Con'versation About Fluorescent E-Defectology." p. 309 (HCRYZO::TY TECHIiIKI, Vol. 6, No. 7, July 1953) Warszawa SO: YonthTy List of Eav~t EW-opean Accessions, Library of Congress, Vol. 2, Uo. 1q# October 1953. Unclassified. USTYNOVICZ.- R.; SPIOWSKI, S. "New Problems of Radiant Drying.' p.2,15 "For More Collaboration of Technical Periodicals with Production Establishments.* P.239 "Meeting of the Laureates of State Prizes with the Capital's Technical 'dorkers.'r p.241 "Fulfillment of the Plan of Educational Lectures in 1952." p.241 "Yearly Meetings of the Provincial Branches of the Chief Technical Organization." u.243 "Nowa Hata, the Paramount Task of our Iluilding Industry." p.250 "We Produce New Types of Machines." p.250 (PRZEGLAD TECHNICZNY Vol. 74, no. 6, June 1953 Warszawa, Poland) SO: Monthly List of East Europea Accessions, LC, Vol. 3, no. 5, may i954/Uncl. 7- r /I/r 11 USSR Ahemical Teennuiogy. Chem-Leal Products T 2 and Their Application Food industry Abs Jour: Referat Zhur - Khimiya, No 9, 1957, 33020 Author : Ustynyuk A. Title : The Dairy Industry of the Polish People's Republic Orig Pub: Moloch. prom-st', 1956, No 8. 4o-42 Abstract: A review article. Card 1/1 PEREVALOVA, E.G.; USTYNYUK, Yu.A.;_~ ~TY",_L.A.; NESMEYANOV, A.N. Reactivity-of compounds containing a ferro,-.enylmethyl group. Report No.6t Steric effects in reactions of alkylation by quaternaz7 ammonium salts. Izv. AN SSSR. Ser. k-him. no.lls 1977-1985 N 163, (MIRA 17:1) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. 50) SOV/79-29-6-41/72 AUTHORSt Levina, R, Ya., Kostin, V, If. , Kim Djaj Gir, Ustyn~,-ak, T. K. TITLE: Reaction of Cyclopropane Hydrocar7oons With Mercuric Salts (Vzaimodeystviye taiklopropanovykh uglevodorodov s solyami okisi rtuti). X. Action of Mercury Acetate on (0,1,3)-Bicyclo- hexanes (X. Deystviye ataetata rtati na (0,1,3)-bitsiklogeksany) PBRIODICALs Zhurnal obshchey khimii, 1959, Vol 29, Nr 6, PP 1956 - 1960 (USSR) ABSTRACT: The products of the reactions described earlier (Refs 1-4) which are characteristic of the above hydrocarbons and which take place under the opening of the three-membered cycle i.e. the T- alcohols and their ethers were the products of the reaction with mercury acetate in aqueous and alcoholic solutions. Their investigation revealed the cleavage of the three-membered cycle between the hydrocarbon atoms which were the most strongly and the most weakly Bubstitute(i (Scheme 1). The forming crystalline organomercury compounds may be successfully for the identifica- tion of the cyclopropane hydrocarbons. In the present paper it was found that the above reaction is also characteristic Card 1/3 of the "bridge bicyclo hydrocarbons" in the system of which Reaction of Cyclopropano HydrocarbonB 'Kith Mercuric 507/79-29-6-41/72 Salts, X. Action of Mercury Acotate on (0,10'l-Bicyclohexanes the three-membered cycla is integrated. It was shown (Scheme 2) that the opening of the three-meLibered cycle in the homologues of (091,3)-bicyclohexane in the action of mercury acetate on these homologues in aqueous or mathanol solution does not take place at the bridge C-C-bond. The products of this reaction are cyclopentanolesj -mercurized in the side chain or their methyl ethers. The syn esis of the cry:3talline f -mercurized alcohols and their ethers may thus serve for the determination of 1,3- dimethyl-1,3,5-trimethyl and 1-methyl-3-o.hyl-(0,1,3)-bicyclo- hexana. The structure of the I -mercurized alcohols and their ethers is the following: RO CH2Hgx 1) from 1,3-diLlethyl-(0,1,3)-bicyclohexane CH ~3~C H3 Card 2/3 Reaction of Cyclopropane Hydrocarbons 'Kith Mercuric SOY/79-29-6;-41/72 Salts. X. Action of Mercury Acetate on (0,193)-Bicyclohexanes H H2Hgx 2) CH3 CH3 from 1,3,5-trimethyl-(0,1,3)-bicyclo- V3C hexane. H3 There are 3 tables and 7 Soviet references. ASSOCIATION: Mookovakiy gosudarstvennyy universitet (Moscow State University) SUBMITTEDt May 25, 1958 Card 3/3 AKHREM, A.A.; USTYNYUK, T.K. Rearrangement of 21.,21-dLbr o-184 - ..j9g'nen--17f -o1-3,, 20-dione acetate to isomeric 10 -pregnene-.17. 20 -diol-V-l-oic acids. Iz,;-. AN =R. Oted.khim. nauk no-4:768 96~- (141RA 16:3) 1* Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR. (Pregnonedione) (Pregnenoic acid) AKHREM, Afanesiy Alskse"vich; USTINYUK, T. K. "Rearrangement of 17-acetate-20,21-dibrono-®rwrw-3.7B-ol-3, 20-dione into isomeric &-pre gnerm-17B, 20 ~ -diol-21oic acTds.w Report presented for the 3rd Intl. Symposium on the Chemistry of Natural Products (IUPAC), Yvoto, Japan, 12-18 April 1964. 50) AUTHORS: Nesmeyanov, A. No, Perevalova, E. Go, SOY/20-124-2-25/71 Shilovtoeva, L. So, Ustynyuk, Yu. A@ TITLE: Synthesis of Ferrocene.Derivatives by Means of the N,N-Dimethyl-Aminomethyl Ferrocene Methiodide (Sintez proizvodnykh ferrotsena-s pomoshch'yu yodmetilata N,N-dimetilaminometilforrotsena) PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 124, Nr 2, PP 331-334 (USSR) ABSTRACT: The compound.last mentioned in the title was earlier used by the authors (Ref 5) for the synthesis of metfiyl ferrocene. It proved to be a suitable reagent for the introduction of the ferrocenyl-methyl group (Refs 2 -8). In the present paper some substitution reactions of the dimethyl-amino group were carried out,. furthermore-methyl-ferra".ne was aminomethylated and ferrocene aminoethylated. It was thus possible to obtain the sodium salt of ferrocenyl-methane aulfonic acid by theinteraction between the compound mentioned in the title and sodium sulfite. By the influence of potassium thiocyanate ferrocenyl-methyl thiocyanate was formed Sodium phenolate and -f-naphtholate Card 1/3 yielded the phenyl- an~ flnaphthyl ether of the ferrocenecarbinolo Synthesis of Ferrocene Derivatives SOY/20-.124-2-25/71 by Means of the N,N-Di-methylwAminomethyl Ferrocene Methiodide- By ferrocenyl methylation of the p-oxy-azo benzene an azo compound was formed containing a ferrocenyl group. This had hitherto not been possible. On the aminomethylation of the methyl ferrooene (Ref 5) with a mixture of NVN#K 1'V I- tetramethyl- diamino methane and paraform a homoannular (N,N, dimethyl-amino methyl) methyl ferrocene was obtained in a 60% yield. The aminomethylation of the methyl ferrocene was carried out in the substituted cyclopentadiene ring in a yield which was somewhat higher than for ferrocene (51%, Ref 2). The addition of phosphoric acid increased the yield up to 80%. Besides, diaminomethylated methyl ferrocene is formed (101A yield). Thus the methyl group in the methyl ferrocene considerably activates the ferrocene nucleus against electrophilic attacks. The formation of the homoannular compound suggests that the ring to which the methyl group is bound, is activated to a more considerable degree. The successful production of the diamino- methylated methyl ferrocene further proves that the influence exerted by the substituents 13 transferred from one Card 2/3 cyclopentadienyl ring to the other one by means of the iron atom (Ref 9Y. Prom the compound mentioned in the title the authors Synthesis of Ferrocene Derivatives SOV/20-124-2~-25/71 by Means of the Npff-Dimethyl-Aininomethyl Ferrocane Methiodide syntheAized the homoannular dimethyl ferrocene. It may be a'asumbd from the compaxison.of infrared spectra that the alkyl groups are in a.1-3-Position. There are 12 references, 2 of which are Soviet. ASSOCIATIOH: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova (Moscow State University-imeni M.N. Lomonosov) SUBMITTED: October 14, 1958 Card 3/3 83136 3 ? 0 0 AUTHORS: S/020/60/133/005/014/019 B016/BO60 Nesmeyanov, A. N., Academician, Perevalova, E. G., stvnv-uk- Yu. A- TITLE: Ferrocenyl Methyl Lithium PERIODICAL: Doklady Akademii nauk SSSR, 1960, Vol. 133, No- 5, PP- 1105-1107 TEXT: The authors previously described the production of ethers of ferrocenyl carbinol (Ref. 1). In the present study they used lithium to cleave ferrocenyl carbinol methyl ether dissolved in tetrahydrofuran. The resulting ferrocenyl methyl lithium was used to produce ferrocene derivatives. The authors proved furthermore that ferrocenyl carbinol ethers can 1-e readily obtained by heating ferrocenyl carbinol with the respective alcohols in the presence of acetic acid. In this way, the authors obtained methyl-, ethyl-, and benzyl ethers of ferrocenyl carbinol in yields of 73, 80, and 72%. The ready formation of these ethers is explained by the stability of the ferrocenyl methyl Card 1/2 83136 Ferrocenyl Methyl Lithium S/020/60/133/005/014/019 BO16/B06O carbonium ion (Ref. 2). The reaction conditions for the production of ferrocenyl methyl lithium are analogous to those indicated by H. Gilman et al. (Ref. 3) for the cleavage of benzyl ethers. Ferrocenyl methyl lithium smoothly reacts with trimethyl chlorosilane to give (ferrocenyl- meth.Yl)-trimethyl silane in a 68% yield. Under the action of anhydrous ferric chloride, ferrocenyl methyl lithium yields 1,2-diferrocenyl ethane. New data regarding diferrocenyl ethanes produced by condensation of formaldehyde and benzaldehyde with ferrocene (Ref. 5), as well as by Friedel-Krafts's reaction (Ref. 8), will be published at the same time. There are 8 references: 4 Soviet and 4 US. ASSOCIATION: Moskovskiy gosudarstvennyy universitet im. M. V. Lomonosova (Moscow State University imeni IA. V. Lomonosov) SUBMITTED: April 18, 1960 Card 2/2 L 1280~j;! J) PLUUM-5510N NH.' AP300: S/0 ~e;Fgfo_`44/ OA4/%6/1043 3 AUTHOR: Perevalova, E. 0 ; Usty*nyuk, Yu. A.; Nesme-yanov, A. M. TITLEs The reactivity of compounds containing the forrocanylaothy, 7group. Report 1. Hydrolytic cracking of tetravalent ammoniun salts SOURCEs . AN SSSR. Izv. Otdeleniye khimicheskikh nauk , no. 6, ia63, lo36-1045 TOPIC TAGS: tetravalent ammoniun salts, forrocanylmethyl group, hydrolytic crack- ing, rate of hydrolysis ABSTRACT: k series of tetravalent ammonium salts contaWng the farrocenjklmethyl group was synthesized, i.e. c,,=pounds of the type shown in the enclosure, where RCH sub 2 is methyl, ethyl, n-propyl, n-butyl, n-nonyl, benzyl, allyl, carboxymethyl, phenacyl or ferrocenyl methyl, and the anion X is chloro, bromo, iodo or picryl. Rydrolytic cracking of these compounds in alkaline, neutral and 50% aqueous dioxane solutions was studied: rate of hydrolysis was independent of anions and of solvent concentration, but increased with electron acceptor properties of the CH sub 2 R group. Hydrolysis proceeded according to the S sub N 1 iftechanism with the inter- mediate formation of the forrocanylmethyl cation. Orig. art. has: 9 tables, 8 formulas, and 1 figure. Card 101 0 t's Q_ 0 -'o RM rdljD SION NR: AP3002-a ~0 2 3/ 8 s 6M 00676bMt45/i84' + AUTHOR: Perevalova, E. G.j Usty*nyuk, Yu. A.; KeBmeyanov. A. M. TITLE: Reactivity of compounds containing a ferro 0~;11 roup. Report 2. Regeneration of tetravalent ammonium salts, containing ferroceny]Lmothyl radical, with sodium amal by Emde SOURCE: AN SSSR. Izv. Otdoleniye k"iimicheskikh nauk, no. 6, 1963, 1045-1049 TOPIC TAM ferr6canylmethyl group, trimethyl ferrocenylmethyl ammonium iodide, dimethy-lallyl ferroceny1methyl ammonium iodide, dAmethylbenzyl ferrocenylmethyl ammonium iodide, sodium amalgam ABSTRACT: The reduction of trimethyl-, dimethylallyl-, and dimethylbenzyl ferro- cenylmethyl ammonium iodide with sodium amalgaza by the method of Rude and co- workers (Arch.- Pharmi _v.. 1909, 333, 314, 351; v. 249, 19U, 111. 118, 166; Liebigs Ann. Chem. 391, 1912, 88) was investigated. The ferrocenylmethyl group split off from the N of the tat-ravalent ammonium much more readily than the methyl, much less readay than the benzyl, and at about the same rate as-the allyl group, Hence, ferrocene group stabilizes the neighboring radical center less than the benzyl, and more than the methyl radical, and about equally to the double bond of Card ilk PEREVALOVA, E.G.; USTYNYUK,.-.Yu.A. Reactivity of compounds containing a ferroceny1methyl, group. Report No-3: Reactions of quaternax7 ammium salts vith organomagnesium compounds In the presence of cobaltous chloride. Izv. AN SSSR Ser.khim. no.10sl?76-1782 0 163. (MIRA 170) 1. Institut elementoorganichaskikh uoyedinenly AN SSSR. PEREVALOVA, E.G.; USTYNYUK Yu.A.- NESMEYANOV, A.N. . Reactivity of compounds containing a ferrocenylmethyl group. Report No.4t Reaction of ferrocenylmethyllithium. Izv. AN SSSR.-Ser. khim. no.11:1967-1972 N 163. Reactivity of compounds containing a ferroceny1methyl iroup, R rt NO.5: Preparation of organo'lithium compounds with Zferrocenyl alkyl gr6ups. Ibid.:1972-1977 (MIRA 17:1) 1. Moskovskiy gosudarstvennyy universitet imeni Lomonosova. PEREVALOVA, E.G.; MTXNXLTK, Yu.A.; USTYNM,, L.A.; NESMEYANOV, A.N. Reactivity-of compounds containing a ferroceny1methyl group. Report N*.6: Steric effects in reactions of alkylation by quaternary ammonium salts. Izv. AN SSSR. Ser. khim. no.llt 1977-1985 N 163. (MIRA 17:1) 1. Moskovskiy goeudarstvennyy universitet imeni Lomonosova. ACCESSION NF: AP4010040 S1006216410001001loo62loo69 AUTHORS: Usty*nyuk, Yu. A.; Perevalova, Be Go TITLE: Reactivity of compounds containing the forrooenylmethyl group. 7. Rearrangement of the dimethylbenzyl(ferrocenyl- methyl)a=onium. ohlorlde under the aotiou of nuoleophillo reagents SOURCE: AN SSSR. Izvestiya. Ser. kh1m., no. 1, 1964, 62-69 TOPIC TAGS: ferrocenylmethyl compounds, reactivity, rearrangemen ferrocenylmethyl group, stabilizing action, Isomerization, intra- molecular reduotion, carbanion stabilization, nuoleo~hilio reagents dibutyllithium I ABSTRACT: The comparative stabilizing action of the benzyl and the ferrocanyl rings on an adjacent carbanion center was determined from the rearrangement products. Dimethylbenzyl(ferrooenylmethyl) ammonium chloride (1) rearranges in the presenoe of dibutyllithium to (alpha-phenyl-beta-farrooonylethyl)-dimethylamine (II)v 72% yield. In the presence of potassium amide, conversion in 50%,-with benzyl- i-Card ACOESSIOt'NR: AP4010040 Magnesiula chloride, 21%. C41ij FeC4H& CHs\A/CH& C4H&FeC*H&%,+/CH9_, 'N QUHI/ \CHo (KNHI, Collo GHv KRGO QltiUh/ C4116 - CH - CH* C6Ht FoC6Hs Thus.the benzene ring stabilizes the adjacent anion center more than the ferrocenyl ring does. A n .ev type of isomerization was observed In the reaction with dibutyllithium; N,N,Nl, N'-tetramethyl- alpha,beta-diphonyleth.vlene diamine and 1,2-diferrocenylethane were :, produced in addition to 11, the amount of 11 decreasing on prolonging~ the reaction. The following intramoleoular reduction of the ammonium~, nitrogen Is suggesteds Card .2/3-- - ---------------- - -- Nli: AP4010040 CH,FeC4fUC-H9 CjHoP",CK* + COisdHN(CH*)t- "Authors express deep apprepiation to A. N. Nesmeyanov for attention to the work and valuable advice." Orig. art. has: 10 Equations. ASSOOIATION: Institut elementoorganichaskikh soyedinenly Akademli nauk SSSR Moskovskiy gosudarstvenny*y universitet In. M. V.- Lomonosova (Institute of Organometallio Compounds, Academy of Sciences SSSR Moscow State University) SUBMITTED:,06Sep62 DATZ AOQ: 10064 ENOL: 00 SVB CODE: CH NR REF SOV: 006 OTHM: 005' A00ESSION XR: AP4010041 S/0062/64/000/001/0070/0073 AUTHORS: Usty*nyuk, Yu.A.; Porevalova, E.G.; Nesmeyanov, A.K. TYME: The reactive ability of compounds containing the ferrooonyl- methyl group Report-No,8# Wittig rearrangement in a series of forro-I cenylcarbinol ethers SOURCE: AN SSSR. Izveatlya. Ser. kh1m., no.i, 1964, 70-73 TOPIC TAGS: ferrocenylmeth~71 group, Wittig rearrangement, ferrocenyl"~i carbinol others, butyl lithiump lithium ether linkage, ether isomeri- : zation, anionic center stabilization, I phanyl 2 ferrocenylethanol, 2~, phenyl 1 ferrocenylethanol, 1,2 diferrocenylethanol, 1,2 diferrdoenyl-' ethylene ABSTRACT: In continuation of earlier work, this rearrangement was studied for the benzylferrocenylmethyl and bisforroconylmethyl others under the influence of butyllithium and tetrahydrofuran. During re- action with the first compound a 55% yield of i-phonyl-2-ferrooonyl- ethanol-~i was obtained without formation of its 2-phenyl-i-ferrooenyl Card T/2 ACCESSION XR: AP4010041 ethanol isomer, while reaction of the second yielded 1,2-diferrocenyl~ -ethanol. The latter rearrangement proceeded with less ease, with a yield of only 23% and a 27% residue of unchanged starter ether. The product of the second rearrangement was convertea into 1,2-diferro- cenylethylene by dehydration; this latter is a red crystalline aub- stance, m.p. 264-265, soluble in hot benzene, toluene and chloroform. The new data confirmed earlier findings, I.e., that the ferrocenyl nucleus will stabilize the adjoining carbonation center to a lesser degree than the benzene ring. The laboratory procedure, the products obtained, and their description and IR spectra are reported. "The authors wish to thank O.T. Hikitina for determining the molecular weight." Orig. art, has: 4 formulas. ASSOCIATION: Institut elementoorganicheakikh soedinenly Akademli nauk SSSR (Institute of Organoelemental Compoundsq:- --: Academy of Scien-: ces &SSR); Moskovskly gosudarstenyft univereltat Im, X*V# Lomo- nosova (K6soow State Univerrilty) SUBMITTED: 108op62 WE AOQ: 14pebA WOLt 00 SUB CODE: GH NR REP SOV: 004 OTEM: 004 Card ~/2 I NESMEYANOVP A.N.; PE.RFVALOVA, E.G.; LLON'r,YEVA, L.T.; USTYNYUK, Yu,A. Ferrocenylmethylthiol and metbyl(ferroceny1methyll vilfide. Izv. AN SSSR. Ser. khim. no.9:1696-1697 165. (MIRA 18j9) 1. Moskovsk'Ly gosudarstvennyy universitet. NESME-(ANOV, A.11. ; PEP-T;7ALOVA, EI.G. ; M- CIINT IYEVII, L. 1. ; Yu..A. Synthesis of 1,2-disubs4-4-utad ferrcc-~n--E. TZ-.-. I'; r- z"-... _?--. no.10:1882-188/+ 165. 0 CI. RA 18: 10) 1. vloskovskiy gcsudarstvenn~7 universitet. L 2M~~6 EWT(m)/EVIP(J) RM ACC NRI AP5027691 SOURCE CODE: UR/0062/6,5/000/019/1882/1884 AUTHOR: Neameyanov.*,A. N.; Ferevalova) E. G,;L~ontlyevas L. I.; Ustynyu ORG: Moscow State University.im. M. V. Lomonosova (Moskovskiy gosudarstvennyy universitet) TITLE: Synthesis of 1.*2-disubstituted ferrocenesq,jA-,-,- SOURCE; AN SSSR. Izvestiya. Seriya Ithimicheskayas no. 10s 1965, 1882-1864 TOPIC TAGS: ferrocene, chemical reactions desulfurization, chemical reduction ABSTRACT: The reduction of 1,2-(2t-thia-41-ketotetramethylone)ferrocene (I) was investigated in order to find suitable methods for the synthesis of homoannular disubstituted farrocenes, I was desulfurized with Raney nickel to form 122-methylethyl- and 112-mothylacelylferrocens. Reduction of I with lithium aluminum hydride gave l,2-(2'-thia-4'-hydrx>- xytetramethylene)ferrocone (II). Reduction of I in the presence-of aluminum chloride gave 1.,2-(21-thiatetramethylone)-ferroceneo a small amount of II, and methy1ferrocenes and in one Instances 112-(21-thia- 31,pl~f-dehydrotetramethylene)ferrocone, Orig. art. has: 2 equations. Card 1/2 UDC: 0 - -- - L 27456-66 - - -- I -L 2=44� EWP(J)/EWT(m)/T IJP(C) RM '___ACC NR. AP60.17364 SOURCE C_0__D_E_:__ URVO062/66/ 003/0558/0559 AUTHOR: Nesmeyanov,, A. U.; Perevalova, E. G.; Leonttyeva, L. .j.; Ust Yu. ORG: Moscow State University M. V. Lomonosov (Moskovsk-ly goeudar otvan nyy'' universitet) TITLE: Reactions of triferrocenylchloromethane hydrochloride -SOURCE: AN SSSR. Izvestiya. Seriya khimicheekaya, no# 3, 1966t 558-559 TOPIC TAGS* organoiron compound, chlorinated organic compound, organomagnesium compolmdo organosodium compoundo organolithium compound, chemical reaction ABSTRACT: T-riferrocenylchloromthane hydrochloride reacts with nucleophilic reagent~l (organomagnesium and organosodium compounds, lithium aluminohydride, sodium methylate and.sodium cyanide) to form the corresponding derivatives of triferroceny1methane. [JFRS1 SUB CODE. 07 SMI DATE: 22Ju165 ORIG PEN 002 OTH REFi 001 I Cord UDC: 542,91+541.49+546-72- L 26555-66 E;'IP(j WEVIT W/T TJN~' F~ACC'NR- Ar6o173631 SOURCE CODE: UR/00612/66/000/003/0556/0558 AUTHOR i N ancy. A. N. *. Pqrevalov,,t, E. ; Looribi UR~'ZnZu j YuA ORG: Moecmi State University im. M. V. Lomonosov (tfoskovokiy gosudarstvannyy univeraitet) TlTLE: Triferroceny1chloromethane hydrochloride SOURCE: AN SSSR. Izvestiya. Scriya khimicheskayd, no. 3, 1966, 556-558 TOPIC TAGS: organic sy~nthetic process, perchloric acidt perchlorate, hydrogen chloride, organoiron compound ABSTRACT: The ionic triferrocenylmethylperchlorate and triferroceny1chloromethane hydrochloride were synthesized by reaction of triferrocenylearbinol with perchloric acid in benzene and anhydrous HC1 in ether, respectively. HC104 (C5H5FeC04 )300H (C5H5FeC5H4)3CC'04 (C H FeC H ) ccl- Hol, iia- 5 4 3. In polar solutions triferrocenylchloromethane hydrochloride decomposes to'fom forrocenylfulvene. (JPRS1 SUB CODE., 07 SUBM DATE., 22jul65 ORIG REF: 003 OTTI REF: 002 IT-A el^ n-tA:ef-I In-LelL ?7n ACC NR, AP7011356 SOURCE CODEI UR/0062/66/000/010/1870/1871 smaynn AUTHOR: Nes ov, A. N.; Chapovskly, Yu. A.; Ustynyuk, Yu* At ORG: Institute of Hctero-Organic Compounds, Academy of Sciences USSR (Institut elementoorganicheskikh soyedineniy AN SSSR) TITIZ: Splittinp of the Fo-C bond in the exchange reaction of the carbonyl ligand of C5H5FQ(CO)CV(OC6H5)37d6H5 for triphenylphosphite SOURCE: AN SSSR. Izvestiya. Serlya khtmichaskaya, no. 10, 1966, 1870-1871 Topic TAGs: exchange reaction, carbon compound, nuclear magnetic resonance, maas spectroscopy, LZ spectroscopy SUB CODE: ABSTRUCT: The authors used nuclear magnetic resonance, infrar-ed and mass spectroscopy for studying the product of interaction between C5H5Fe(C0)(P(0CGHS)31C6H5 and triphenylphosphite under ultraviolet radia- tion. 7he results show a single cyclopentadienyl and two triphenylphosphite ligands per iron atom with no carbonyl ligands. This, together with the diamagnetism of the resultant compound indicate the dimer structure (CSH5Fe[?(OC6H5)312)2. However, data of x-ray analysis are needed for a final conclusion. EJPRS: * 40V35:17 Card I/ UDC: 541.57+542.957+547.2+547.241 ~ _- - - - 0 9, _q/ 17-3 7 0 0 0 0 0 0 0 0 0 0 0 0 0 1 a A A 1 9 If a IT is A a L. is U Is Is I, a 0 st, G 41 . . 00 9 MCC LVU4p I t I, #.C 00 00 of) 00 Prom. -00 of 3, 3. 3. x (1) The n1aictial wa, llualiall. -00 00 slightly fics.6-d. 6nwd ftsir 2 days. with atout 12% Cesit)II)s Un tbC Wiright uf the tiv4sx. washed and dtlitued with Ili- of tubite. Tanning fly v I life . tic-rat 4W IWU-V&t l f l l r U - i6 w usua s yrins, 460161 Ily l "Istutter invIl , thynig and finnbins, (2) The i1svtolt-valer W" heismsojil - ' , V i h 15 ( n. Clot Let M ;. WOIt!t, JIM n IIIII. in %vu l seseekeJ tur - .90 in 1111tc vat- with a gredually iturvailing trellis. In-III 21" 1 il 0 =4 :W. After me seluset dryielig pnkxl ths: timut to 2.5 (0 Xf 3 KU 4 f K O i i n ts n a ser n. o . l% S. n. 4 was ituntirfierd Im 3 w , ( =06 0* -( IGO). said (ben fit-lited with a *get. of If? in over 1. A. Istatilijis- ated 7 of. JIC1 j;rj 1 1110. Thr tissue sv- 40 Wel.turd, with an viumborts sel vin-niv still 0 vessel Stelos, wesed" *OKI mused. Ilse fust tallithis vat W., inadc oil eA K.C ". ailing 4, IICI 2~N Wo list) *k)7v; 99 the vervend of We, thiLloulAter, 6% IICI stivI '2101, Heil. '96 file Istissills; was ('44-wrti fly a er.ting tevfiml. lKilliffilit-4- fuen. dorroad, NOW list - hiltastipor. 41tvasne siml firib,hout .0 9 i ;IWACI 4 th.10111111, Ihah involual. wriv d d ti t W ~ L .4111,1111 f t s. o eour goo ty a qua i CANIVOW" opore of 4141 F. ovectilliz, Koalerisrsems4.1busmayu Prom. 13. UKI 7 - ( h ki i i 09 0 sul I) ec c t (I%M).--A detailed de-& pt ng swi" out by vatiestex 61m. its the Irallocr indulaty. iiii " is Sivvu "Vtd fly flue t1oraluisits lxdtlwr -Truxio hoe A.A. Ihs, hilloijile -:90 if J 9 4 1 er N . a p (1 1, , -1 a J to it nil It I les O 4 0 0000600 00 0 0 0 0 0 0 0 IN0 S 0 4,0 9 0 0 0 go 004 00 g 0 g g T O 0 do 000.4009 00 * to 0 0 0 0 a 06 0 0 ov 0 q 0 0 0 0 0 41 it 0 a 0 000 * 0 Si BRICHKDI, A.V.. USTYUGIN. Ye.I. Testing a toothed bore bit in perforator boring. Izv.AN Uzakh. SSR.Ser.gor.dela, met. i strnimat. no.11:36-41 '56. (KiRA loa) (Boring machiner7--Testing) USTYUGIN, 1. - FORTMTOV, V.I., rodaktor; TXZDOKOVA, H.L., redaktor - .- !2 ~zatel sty&; BMWV, A.Po, tekhaichaskly redaktore CBxperience of M.Khaklmov's brigate In high-speed mining] Offt raboty brigady N,.Xhmklmova po skorostuel prokhodke gornykh vyrabotok. Koskya, Gosenauchno-takhn.isd-vo lit-ry po ohernal I tevetnoi metallurgii, 1957. 43 p. (KIRA 10:6) (Mining engineering) S/081/62/000/002/034/107 B151/B108 AUTHORS: Gordiyevskiy, A. V., Ustyugov, G. 3- TITLE: Photometric determination of boron in magnesium alloys PERIODICAL: Referativnyy zhurnal. Khimiya, no. 2, 1962, 11)1, abotrac* 2D94 (Izv. vyssh. uchebn, zavedeniy. Khimiya i khim, tekhnol., v. 4, no. 31 i961, 366-369) TEXT: A photometric and fluorometric method has been developed for the determination of small quantities of B using the dye anthraquitione blue cBr SVG (I). Solutions of (I) in concentrated H 2so4 have a cherry red colour which changes to violet in the presence of B. The full development of the colour takes 20 min and the sensitivity of recording is 0.01 J&g of B. The weak fluorescence of a solution of (I) in concentrated H SO /mi 2 4 when irradiated with UV light becomes an intensely bright red in the presence of B,. The sensitivity is 0.001 ug/ml of B. Nith both methods the optimum H 2so4 concentration is 85 The fluorometric method is used for determining B in MA5 0115) alloy (Mg-Al-Zn). 0.1 g of the sample is Card 1/2 5/08!/62/000/002/0-14/-G"1 Photometric determination of boron in- B151/B108 introduced into a quartz flask contain 4nE 10 ml water, This IS connected to a reflux condenser and then concentrated H 2 so4is added slowly. Until the sample is dissolved 30 % H 10 solution is added to decompose the 2 2 carbides, The solution is boiled (to decompose the 11 202) and enough concentrated H 2s04 is added to bring the H 2 so4content of the final solution to 35 ~- It is then diluted further with 85 %-H 2so4 to 100 mi- To 5 ml of this solution 0.15 mi of a solution of (1) (0,,! g (I) in '0 m-. concentrated H 2so4) is added and after 20 minutes the intensity of fluorescence (excited by UV light) is measured with a vertical Pulfrish spectrophotometer. The mean error of determination is about 7 (Abstracter's note: Complete translation.j Card 2/2 s/137/61,/00o/012/043/149 A.oo6/Aioi AUTHORSj Kudryavtsev, A.A., Sedov, N.V,, Ustyugov, G.P., Hyabova, R.I, TITLE: On the separat-lcn of sulfur, selieniam and tellurium PERIODICAL: Referativnyy zhurTal. Metallurgiya, no, 12, 1961, 23, abst'ract 120166 ("Tr-. Moak. khim,-4A-khnol, in-ta im. D,I. Mendeleyeva". 1961, no. 35, 111 - '115) TEXT: Information Is given on methods of separating S, Se and Te. To check the possibility of separating S and Be by rectification, the ooncentrate oontaiDlng 70.5% Be (the rest S, low-volatile slid non-volatile substanees) was charged in a water-filled con-tainer &ni he&ted to 90OC-for 2 hours. For further refining, -the Be was placed in a crucible and heated during I hour at 2000C. Impurities emerging on 'the surface of the melt, were removed. Then Be was refined in a reolificaticn column, and a prcduct containing 99.99%-Se was Ob- tained. When separating Be and Te In the reatifioation column a-produc-. was ob- tained containing 99. 997 - 99.999% Be. There are also chemical methods of sepa- rating Be and Te2 a) a method based on the different volatility of Se02 ahd Te021 Card 1/2 On the separation of sulfur b) oxidation of the So _Te mixture, and their tion, by utilizing the different acidity of the of separating S, Se and T~e sl~ould be cher;kedi position, oxidation of the S, Se and To mixture reduction ofoxides. [Abstracter's notes Complete tramelation] Card 212 S/13?/61/000/012/043/149 A006/A101 aubsequent separation and reduc- medium. The following methods rectification, electrolytical de- with subsequent separation and L. Vorob'yeva It B/137/61/000/012/045/149 A006/AlOl AUTHORSs Kudryavtsev, A.A., Lekaye, V.M., Yelkin, L.N., Ustyugov, G.P. TITLE: Equipment and technology of developing the continuous thermal pro- cess of selenium and tellurium production PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 12, 1961, 24, abstract i2G168 ("Tr. Moak. khim.-tekhnol. in-te. im. D.I. Mendeleyevall, 1961, no. 35, 119 - 124) TEXT: On aocount of the complexity and expensiveness of chemical methods for extracting Se and Te from slurries of copper-melting, sulfuric acid and other plants, a continuous thermal method in suggested for the reprocessing of slurries containing Se and Te. The initial material is charged into an externally heated retort, and volatile components, such as 8, Se and Te, and some admixtures, are distilled. The vapors obtained are cleaned from dust and then supplied to the condenser. -The liquid mixtum of the aforementioned substances is separated in two (or more) rectification columns. In the first column 8 is distilled, and Se in the second one; the cubiD fosidue consists of To. To bring about the given soheme, equipment materials should be selected, since the materials to be re- Card 1/2 Equipm!nt and technology ... S/137/61/0oo/oi2/o45./14q Aoo6/AlOl processed are very aggreasive. Special steels and non-metallic materials should be tested. The.thermal me-thod for obtaining Se and Te has the following main advantages over.ohemical methodal -reduced number of r6processing stages; con- sumption of chemical reagents is not requiredi reduced cost price and investment costs; improved work conditionsi the possibility of mechanizing and automating the process. V. Oulyanitakiy [Abstracter's note, Complete translation] Card 2/2 KUDRY-AVTSZV, A.A.5 USTYUGOV, G.P. Determination of the saturated vapor preosura of selenium and tellurium. Trudy 16= no.38,-42-46 262. - (MM 16:7) (Selentlun) (Tellurium) (Vapor pressure) S GORDIEVSKIY, A.V.; USTYUGOV G.,II. Photometric-,determination of boron in nagnesi= alloys. Izv.vys. uchob.zav.;khim.i khim.tokh, I+ no.3:366-369 161. (14IRA 14: 10) 1. Mookovskiy Aiimiko-tekhnologicheskiy inatitut imeni Mendeleyeva., kafedra tekhnologii radioaktivnyMi i redkik7a elementov, Boron-Ana3qpip) 14agnooitan alloys) 1 2 2 o0 2Y527 B101/B147 AUTHORS: Kudryavtsev, A. A.,-Ustyugov, I'$'. P, TITLE: Determination of pressure of saturated telluric vapor PERIODICAL: Zhurnal neorganicheskoy khimii, v. 6, no. 11, 1961, 2421-2424 TEXT: The authors determined the pressure of saturated telluric vapor UP to 760 mm Hg as a function of temperatu:7e; the boilinE points at various pressures, and experimentally checked the normal boiling temperature of Te. They used the apparatus illustratea in Fig, 1. 30 - 40 g of tellurium (1) was filled into quartz container 5, The evacuated apparatus -,ias filled with argon, The pressure was read from manometer 15 (accuracy 0.2 Mm lig) With the aid of a magnifyinE glass. Furna-.e 4, controlled by an 311JI(ZPD) voltmeter, was maintained constant at the expected boiling temperature, Furnace 2 was quickly heated to 20 - 30 0C below boiling temperature, whereupon cock 16 was closed and I was made to boil, Quick motion of the Hg drop within capillary tube 13 indicated the boilit.1- point. The position of the drop between A (start of experiment) and B was pencil-indicated on paper-tape 19. Temperature was meas-~ired by thermocouple 9 movable Card 1/4 2)527 S/0'18/6!/006/01 11/()01,'0 15 Determination of pressure of- 13101 //B 147 within quartz tube 10 by aid ef screv. 8 The rem...'riing rictails concei-AnE Fig, I are: (3) asbestos intermediate layer; (6) condenser; (7) nut; (11) stainless steel cylinder; (12) HF container; (14) Hg collector; (1-1, (18) buffer capacities; (20) thermocouples; (a) water; (b) to vacuum pump; (c) argon, Control tests carried out with selenium showed good agreement '.vith thedataof~'~ S. Brooks (see below) and V V. Iliarionov, L, M. Lapina (DoU, AN SSSR~ 114, 1021 Tellurium was produced according to M- P. Smirnov, G. A, Bibenina (Tsvetnyye metally, no, !2~ !7 (1957)) and purified accoraing to A- A. Solovushkov. L. A. Soshnikova, Z, M, I'Jatveyeva (Chist~ye metally i poluproyodniki (Pure metals and, semiconductors) Tr, Pervoy mezhvuzovskoy konferentsii po chistym matallam, metallicheskim soyedineniyam i poluprovoinikovyrr. materialam, bietallur~;_zdal, 1959. p, 239). The following was found-, Card 2A, 29527 S/07a/61/C,06/011/001/013 Determination of pressure of... B101/B147 0 0 0 P, mm 11g. t' C p, mm Hg t' C P, Mm IIg t' C 13 646.0 68 761.o 250 872.7 20 672.0 90 781.8 330 901.0 30 700.5 115 803.0 450 932-3 38 717.5 150 825.5 6oo 64.0 50. 737.0 190 846.5 760 990.2 The following equation was derived from these data: log P -5960-5/T + 7.5992. kccordine to this 0 boiling Umperature of Te amounts to 990.1 � 1 .0 C, heat to 8H ev = 27.26 t 0.27 kcal/mole. There are 2 and 19 references: 6 Soviet and 13 non-Soviet. The references to English-lanCua&e publications read as J. Amer. Chem. Soo., 74, 227 (1952); A. L. Giorgi. (1957); R. Machol, F. viestrum. J. Amer. Chem. Soo., equation,the normal and the evaporation figures, 3 tables, three most recent follows: L. S. Brooks, Diss. Abstr., , 2166 85, 2950 (1951881. Card 3/4 29527, /07a/61/006/011/001/013 Determination of pressure of... BlOl/B147 SUBMITTED: October 2.0, '10/60 Fig. 1. Apparatus for determining the pressure of saturated telluric vapor. 4 Card 4/4 L 477117-A-5 E~a "m t )/r-:wp(- .ACCESSIOR NR: PP5010921 uR/o286/65/000/w71o1o4/oioL ;AUTHOR- Kudryaytsev, A. A.; Ryabova, R. I.; Uv-~,yugwv, 0. P.; Bartosevich. N. K.; vp~ r0 zov F. ; Zhiikov, P ~e ra--; mcv, tellurium. "la-S-S, 4,), !,o. i6q703 TITLE, - M(~thod of r(Ifining MUFM ByFulleten' izobreteniy i tovarnykh znakov, no. 7, 1965, 104 h tellurium TOPIC TACK14- tellurium, telluritm refining, h. e. pur-.;;y f-r 'Iur:;~ p ABSTRACT: This Author Certificate introduces metiad of refining ~j -,urity. C,-,nmmercial grade telluritm is 13urified by distil-Lation, firrt to 99.-1q---?Op in hydrogen at ~100C and then in a var-u~;:T, --' I r~r! H9- at a changing from 800C in the still to 500C in thf --ondencer. [A-! UMATIU1 none -ENCL: 'psur"M111=12, c t. 62 Ur 110 REF SOV: 000 )00 r CODE P44, ATD ppEss: 4005 -USTYMOVY M.; GARBARCRUK, M. News from schools, Prof .-tekh.obr. 19 no.10.-.32 0 162. (Vocational education) (MIRA 15:12) 1 1 I I I i S- -F - :-~ L k LUUGAUZ, Berngard Borisovich;. VqT)MGQV,.N.Ve, doktor i9tor. nauk, otvatst- vem3yy red.; TROITSKIT, S*X., red. izd-va; MARKOVICH, S.G., tekhn. red. [Rusian home market during the first half of the 18th centurY; based on Russian oustozas recordai Ocherki vnutrennego rynka Rossii pervoi'poloviny XVIII veka; po materialam vnutrennikh tamozhan. Moskva* lzd-vo Akad. nauk SSM4 1958. 353 p. (MIRA 1127) (Raseia-Gommerce) TATSUMIT, T.K., doktor istor. nauk, otv. red.; SKAZKIN, S.De, akmd*, red.; K=S, KhAh., red.; NIFONTOT, A.$., doktor istor. nauk, red.; -TWYUGOT, N.Y., doktor istor. nauk, red.; KAM9Yu-'Tu-, kand. istor. nau -re-a.; MAAKTAGi, T.A., kand. istor. nank, redo; ANFIROT, A.M.. kand. istor. nauk, red.; KUZOTLU, A.A., red. izd- va; RTLINA, Yu.T., tekhn.red. [Yearbook of the agrarian history of Eastern Europe, 19591 31%he- godnik po agrarnot istorii Vostochnoi Avropy 1959 g. Moskva, 1961. 457 P. (MIRA 14:5) 1. Akademiya nauk SUR. Inatitut istorii. 2. Chlen-korrespondent AN SSSR ( for Iraus) (Adrope, last,3rn-- Agriculture) HIRZON, Aleksandr TSezarevich, kand.:Lstor.nauk [doceasedj; TIKHONOV, Yuriy Aleksandrovich; 1QgMrAff,-1LJL"--dqktor istor.natxk, otv. red.; PODGOMONSKATA, TS.M., red.izd-va; HOVICHKOVA, N.D., takhn.red. (The market of the Great Ustyug; during the development of an all-Russian market In the 17th century] Rynok Ustiuga Velikogo; v period skladyvaniia Yeero,asiiskogo rynka (XVII vsk). Moskva, Izd-vo Akad.nank SSSR, 1960. 714 p. (MIRA 13:8) (Untyug-Commerce) KAMENTSEVAY Ye.I.; USTYUGOV, N.V.; LIPKINA, T.G., red. (Ftussian metrology) Russkaia metrologiia. Moskva. VyBshaia shkola? 1965. 254 P. NIRA 18:4) 4 % 4 f 4 f v tf U ti w Is 14 If jai a m a It u 0 bt a m m is 0 Q 4 m I I L K--r- 2 x-A tE J- A sd Of sxkgcd*a Q1 Udbt "ddlas We" to the TtM* Of KSMOMV*. A. Uum ru 0 U. S. S. A.) It, No. T-- 'V. Cks anj CAti". 041). CAM. zowr. 1943.1.1129--W'th an Rcid st-9th 0(4% and the PyTi- 00 -8j ding " AmmounflAff to 1.6% The saturattw fiquor is MUMUNd WM NMI ~ WOW -- The be*" wr srpd. by dista., =M of do NI& ~mItabo4istg, and acting to got .00 out dw fm~ me that a IRYW COWS. the Pyridirw bews a** wkb 10% 1%0 can be and. diewar. 01mrs C. Both 004 A =00 000 zoo 000 goo see i *0 0 It lk~oe 0e "TALLUMC&L UTINATufff CLAISWICATION see go Art L I v 'w 0 a u 0 it w U, a, 0 0 0 0'o 0 o o 00 0" 6 q o * 0 0 0 e 0 0 0 0 0 0 0 0 a 0 0 0 0 0 go* 010 0 o 0 * 0 0 oo 0 * 0 0 4 00000 of*** 000000 fill U-ST~U(,vVy t~A- PHASE I BOOK EXPLOITATION 1042 Ural'skiy zavod tyazhelogo mashinostroyeniya, Sverdlovsk Kovka I termicheskaya obrabotka (Forging a~d Heat Treatment) Moscow, MashgIz, 1958. 132 p. (Series: Its Sbornik statey, vYP 5) 6,000 copies printed. Ed.: Kvater, I.S., Engineer; Tech. Rd.: Dpgina, N.A.; Rd6 (Ural-Siberian Division, Mashgiz): Sustavov' M.I., Engineer-. PURPOSE: This book is intended for engineers and technicians working in the field of forging and heat-treating of metals. COVERAGE: The book presents material which reflects the achievements of Uralmashzavod (Ural Heavy Mach ine-build Ing Plant' imeni S. Ordzh,onikidze) In the field of forging and heat-treating of metals. Various Improvements in production methods, mechanization and automation of forging and heat-treating processes, application of various methods of Inspection of forgings and elimination of rejects are described. Specific information on improvements in Card 1/4 Forging and Heat Treatment 1042 forging and heat-treating of large parts such as turbine discs and rotors, cold-rolling-mill rolls, and crankshafts are presented. Descriptions are given of the results of new studies undertaken with a view to elimination of rejects and improvement of the quality of parts, determination of residual stresses at various cooling speeds, data on the efficiency of ultrasonic Inspection and the effect of degassing of molten steel on the quality of forgings. The book was prepared by the members of the plant organization of NTOmashprom in connection with the 25th anniversary of the Ural Heavy Machine-building Plant. TABLE OF CONTENTSt Kvater, I.S. Summary of Development or Forging and Heat-treating Production at the Ural Heavy Machine-building Plant Lebedev, A.V., andjLs~~ P.A. Welding Up of Internal Flaws,in Large Forgings 21 .Zlatkin, M.G. Improvement of Open-die Forging 34 Card 2A Forging and Heat Treatment 1042 Katkov, I.S. Xmprovement of Methods of Forging Turbine-diBcs 46 Kazarinovx.B.N. Comprehensive Mechanization of Press-forging Processes 50 Zaaotayev, S.P., Kvater, L.I., and Sklyuyev, P.V. Effect of Degassing Molten Steel on the Quality of Large-tized High- alloy Steel Forgings 59 Kamenskikh, V.N.j and Sklyuyev, P.V. Heat treatment and Quality of large Parts 73 Petrov, B.D., and Sklyvyev, P.V* Production of Rolls for Cold- rolling Mille 90 Mikullchik, A.V., and Kats, Sh. I. Schistose Type of Fracture in Chrome-nickel-nolybdenum Steel 103 Card 3/4 Forging and Heat Treatment 1042 Zabludovskiy, V.M. Effect of the Speed of Cooling of Cylindrical Parts on the Magnitude of Residual Stresses ill Zabludovskiy, V.M. Determination of Residual Stresses in Large Parts 115 Kozhevnikov, M.A. 'Investigation of Parts Rejected on Ultrasonic Inspection 123 Kuruklis, G.L., and Vereshchagina, W.G. Sulphidization-of Machine Parts 130 AVAILABLE: Library of Congress GO/ksv 1-7-59 Card 4/4 S/1','3/59/000/008/015/043 AOO4/AOO2 Translation from: Referativnyy zhurnal, Mashinostroyeniye, 1959, No. 8, P. 68, # 29048 AUTHORS: Lebedev, A. V., Ustyugov, P. A. faf Large-Size Forging TITLE: Weld4the Internal Defecti PERIODICAL: Sb. statev. Ural'skiy z-d tyazh. mashinostr. imeni S. Ordzhonikidz% 1958, No. 5, pp. 21-33 TEXT; Bibliographic entry Card 1/1 ILIBIDEV, A.V. -, USTrUGOV, P.A. Sealing-in internal defects in making large forgings. Bbor.st. UZTM no.5:21-33 '.58, (KIRA l1.-12) (Forging) (Metals--Defects) I'v 33 1 Asi--i V :3 to, -a i EIJI H S;P. A pffi"I W 0 "a 0 i1x; iv ~A V9 SO 0: d Ans MHz 5 AM V d!: 51 d :d d k1o Z"s I ---5 EJ . 34 .1J id Jill] 1 a- USTTUGOV, P.A. --l- ... -em" Maintenance of apartment-hollaes in Vidno7e, settlement of worbqrrs of the Moscow b7-product coking plant. Gor. khoz. Hook. 13 no-5: 32 Ky '59. (MIRA 12:7) (Vidnoye-Apartment houses-Raintenance and repair) /126t'6 / 10/01/015/019 S .IIIA303sc, 4 AVTHOR34- W.M I.dlubtk. I.I.. ..1-h... I.A., K.kh-v. W. and U-Y-Kcv. k.A. rrmjt; Lou or Us tontite on the Cold Short.... of Steaks ..4 Th-~ V-rd.~OZ in Plastic D.C-tt.., PgRtODtCAZ.,- 1960. V.1.10. Pa. 1. pp. 1.;2 - 130 TSXT.-s In" estimAttee, oc-a sort** of SL- shown that " a he'* -LEA-L%Lto.jj The ..th.r. Point not tb.t "rt to rormistion during COIA-shortn- t.atkot tb*-j)robsblo cause and that Itabtlity of aujtomitl~ stool. to r,saaart*nmjtg in plastic d.rornotion d.ponds an the position of th: 4 forma,ttom temperature relativo to the martansite point f 2) and tb. toap.retur. at hich and fr.. ...rgi.s are goal. Th.ir pr...., -Q,IL d..lt with th. C.11-twa .1.*I. I-1y.i. in T.bl, 11 '40GISKh%. 40CIBLhg %OQIBXh,'51.. AiOG18thV.48, %OClbLh%%'8V,,t30GI8. 50CIdth4. SOCISLM-~8y. the coop ... -o-ft-rav, W: O.ko - 0.53 C. 0-0.111 3 17.30-16.60 ".. 0-8.0 C'. *-ts.lz 141. C-4 1/4 SLIA/Z335 or D.fars-t... or X-t-it. !. th. Cold Sh,~,::n or Atistat,41,46 St*ei,! and.Tbekr Har4oning in Plamt&c Defom& 0-0.71 V. 0;.0;010 S. 0-0.067 P. 60 - lost pi- war. cut fr.. II x 12 - 9-4 The Plate- were h..t.d to LtSO 'C and ocalod In water. Ptagnatometric tests Als-ed no MArt*O.At* trans- t-tsom on c"14,ag to -196 C. 31and&rl notcjj#j test-pAv~*g 12.- deep natch,.1,mma red tu. * f.curwst-r:)U;:re used.rov., pact t. ,tu d J -.ttrox . t-p'r t ;.oAlph.-Ph se tins ) -- found with gr.., 'L ,L I t, .-S-at" --c-pt Lbilvty Mar 3) or aust-I I 3 9 . tho fracture region of impzx P..t- .." ;Wlr~: r,,.. .. th . at ....rd. r. a .-..d ..ris. or ;;p.rL..ftt. Ith"w -tsnLtic st**1% after ~JxvnahtnK fr,om 1150 C were raiiej at 2c-6oo oc to SI-. 30'~ d.f.rmati- J'Ags. L-) show the toughnOss or the various steals at functions if rest the ft.tt of the various b.1.1 br*Ugt&t *Ut; JaAXn:v..,:u;c.pt.bilItT :..f.nc ti... of test t-Prt.r. bat na fti r ,7 shown 1. F 4 end 5- FIS.. 6 and 7 show tl*, :f and.Fdtt;.8 the f'. , in c obt: d ri at-, Th do... of Card 2A ILL 11/1335 Imitl-. of 0 -.it.. or myt.~'lt. on the Cold 3hrt.... C a- - '. .:f: t at S I and Tkoxr H~d,djug in Plastic V*Corq!&tjoo 9~212* mtromIth. Yield Point. toughness and ftagn,tac suac&pt&bllffY .. d.f.tiaatL.. t-p.r.t-. is no" to Fig.. 9. 10. It .d 12. 4*"d -w 5QQ6 *test. .1-..d provi.--d old hich cmild be I.d.C.4 or ... pl.t.ly .1-..t.d by &44jtlogL&l da oling wktb chrOMLLLuft or "ck*l. Th* reason for the old skiirta"! A. d.f.ye-L.a.veart ... Lt. for-ti.n d.ring Los. tosep r.tojr. Lagp..t testing. Th. good rf.ct of lloyiiij; the ..1. .11b hreel". end ..Ck.1 is "PI.Ln.d by tn. L=reao*d aostouLto stability elth respect to plait tc-dofor~t ion L.A.C veartm-it. t r.roistio. of Ulh msm,tonait.% .0 th:d,-.o. I or th'. h.rd..g, of ..nK^n*so austenitic 9-t**Is Ln cold compared with 200-300 C PLOStLC d.Vor..t&- III :bl& m-etoultit ot#ol*. additionally 4110YOd With throa;avim and vil k*,. bor S.-& 1. old end .0.1-hpt vork-har4ani-A 1. pr:ct- L4^tly the .- There or. 12 table. .* d So L t *rt.f.r.- C." 3A ax9m IV126/60/010/02/013/019 BLIX/9135 Isinooewc* ~f Veforostion of morzensLto on tile Cold Shortness of A"tomitl. Steel. and Their H.rd.ni.11 to Plastic DoromAtion AMOCIATIM I"tltut Cialial ..tell*, A64 SSSR (1-tIt"t. f P in. S. Ordshonikid.. (U-1 2.111 ..... c Intent S. SUBMMM F.bm.ry 23, L960 C_-d 41/41 ACOMSION Xfts AP4010070 3/0129/64/000/001/'bO24/0027 AUTHORS: Gorbach, V.G.; Maly*shev, K.A.; Gc3s* A.T.; Ustyugov, P.A. TITLEt Effect of high temperature nonrearystallizing work hardening on the mechanical properties of precipitation hardened ateel,s*. SOURCE: Metallovedeniye I termicheskaya obrabotka metallov, no. 1. 1964, 24-27. TOPIC TAGS: precipitation hardened steel, austenitie steel, work hardening, aging, high temperature work hardening, vanadium contain- ing steel, brittleness, recrystallization, strength, impact strength ABSTRACT: A study of austanitic sl-eels (containing Cr-Ni-Mn, Cr-N1_ Dln-V and Cr-Vn-V) showed that high temperature work hardening affected their properties favorably after aging, Increasing strength and impact strength. The high temperature work hardening decreased the transcrystalline brittleness developed by precipitation harden- ing. The partial growth of recrystallization by the high tempera- ture ork hardening does not eliminate the possibility of getting Card ACCESSION NR: AP4olOOTO ~.higher mechanical properties (in comparison to properties of ~steels not subject to high temperature work hardening) by subse- quent precipitation hardening. Austenitic steel containing 1.5% vanadium, when subjected to a combination of high temperature work hardening and aging has high mechanical properties even by partial recrystallization during the high temperature deformation process. Orig. art. has: 2 tables and 4 figures. ASSOCIATION: None SUBMITTED: 00 DATE ACQ: 071~eb64 ENCL: 00 SUB CODE: ML NO REF SOV: 002 OTHER: 000 Card 2/2 ACC NRi AR6027503 SOURCE CODE: UR/0137/66/000/004/70'9/1019 AUTHOR: Belenkova, M. M.; Mikheyev, H. N.; Malyshev, K. A.; Sadovskiy, V. D.; TITLE: Phase transformations during the deformation and tempering of austenitic steel SOURCE: Ref. zh. Metallurgiya, Abs. 41127 IREF SOURCE: [Tr.) In-ta fiz. metallov. AN SSSR, vyp. 24, 1965,,54-58 TOPIC TAGS: metal deformation, austenite steel, martensitic transformation, grain size, magnetic susceptibility TRANSLATION: A study was made of the magnetic, electrical and mechanical properties i9f GOMMSM austenitic band steel subjected to deformations of 10, 25, 31, and 4-A 'after quenching from 10500C. For the same deformation conditions, a fuller decormposi- ,tion of austenite occurred in large-grained scnples as a result of the variation of the position of the martensitic point for a change of grain size (the point of the ini- al martensitic transformation of large-grained samples was located higher than 2:ine- ained). Under the effect of deformation in the steel, a much greater amount oi: a- ~piase formed than during tempering. A definite correlation was found between the nar ture of the magnetic and electrical property changes on the one hand and the mechanical ~praperties on the other, as a function of tempering temperature. Thus, a drop in a. UDC: 669.15126174124.781.017.3:621.785.78 Card 1/2 ACC NRs AR6027503 a of samples deformed at 200C was found beginning at 400-4500C; at these san, e tem- a ratures the lowering of electrical resistivity was initiated. Magnetic susceptibi 111!ity increased after 5000C, while * and a;,, decreased. It was concluded that the chang- ~ :es in mechanical properties were caused by processes associated with the formtion o.C a-phase during cold deformation. During tempering of the deformed samples, the a-phase iof the original deformation is dissolved and some quantities of the ferromagnetic phased jappear in separate portions owing to carbide formation* Is Tulupova. SUB CODE: 11,13 TAAPATOV. Lev Anatollyevich, inzhen r- USTYUGOV P.G., rednktor; TYURTAYEV, M.A., tekhuicheski; 'i [Experience of the Kirghiz Petroleum Trust with directionally drilled wells] Opyt naklonno-napravlennogo bureniia skvashin v "Kirgiznefti." Frunze, Kirgizakoe gos.izd-vo, 1957. 31 p (MIRA 1;:1l) 1. Kontorn bureniya Ro.1 "Kirgiznefti" (for Tarspatov). (Oil well drilling) GODWIENKO, Lyubov' Ilikolayevna, doyarka; USNUGOV, P.G., red.; BEYSIIENOV, A., tekhn. red. --K- - [Let us use loose housing of cows] Korov soderzhim bez pri- viazi. Frunze, Kirgizskoe gos. izd-vo, 1960. (MIRA 15:3) p..-, I 1. Sovkhoz "Dzhangi-Pakhta" (for Godumanko). (Dairy barns) ISAKOVI Dritriy Ivanovich; USTYUGOVj_P.G. red.; BEYSMOOV, A., tekhn. __j red. (I wi32 fatten a thousand swine a year] Otkormliu tysiachm evinei v god. Frun2e, Kirgizakoe gos. izd-vo, 1960. 30 (MIM 150~4 (Kirghizistan-Svine-Feoding and feeds) SKRIPAYEVA, I-Ijariya Vasillyma; USTYUGOV) P., red.; CIIOTIYEV, S-p tekhn, red. [For 150 eggs from each layer] Za 150 Jaits ot kazbdoi ku- ritsy-nesushki. Frunze, Kirgizskoe gos. izd-vo, 1960. 30 p. (MIRA 15:3) (Kalininskiy District-Poultry) PETRIYCHUKt Dmitriy Ignatlyevich; SIASHCHEVA,, Udiya Aleksoyevna,- - U�gj9ff,-E.*-Xed.; CHOTIYEV, S.., tekbn. red. [manganese and its importance In agriculture] Marganets I ego znachenie v sellskom. khoziaistva. Frunze,, Kirgizskoe gos I d- vo, 1960. 45 P. (MIRA 1;0~ (Manganese compounds) (Trace elements) (Agriculture) --Mmmm- O'll telthirL . red, red* I BOSO ar be9t Couibin"I Of sug largli%skoe GOI .0 jr')zlo 1 15%4) 'j.j the 0 0110JA014 00 for ilacre'LOIDI& bOty Sley.1 .,,bOnjj_s r8 56 P I.Cature. Pats. u",''- 1960. (kgr gos;,3 ild..qo (Gombi~6 ( jr b-6tel) KOSUOMMO, I.T.; MYTSINt I.P. I UW7UGO 'Tj P.G., red*; GCILOD# Mop red.t. UTWWOT, A.,, takhn.red. ELet's double the milk yields] Udyoim nadol moloks Jlrmza Kirgizekoe gos.Lsd-vo, 1960. 78 P. (LIRA 14:4~ 1, Predesdatell kolkhoza "Kirgiziya" Alamedinakogo rayons (for Kosyschanko), 2. Glavnyy zootakhnik kolkhoxa iment, Lenina Alamedinskogo rayons (for Hyteik). (Alamedin District-Dairying) USTYUGOVj-jA.,; DZHAYIIAKOVO A.D. j KOLICHENKOp V.V.,, red.; CHOTIYEV, S., - tekbn. red. (Youth on livestock fams] Molodezhl na femakh. Yrunzey Kirgizskoe goo, izd-vo, 1961- 52 p. (MIRA 15:3) (Kirghizietan--Stock and stockbreeding) KILOCREVSKIrs Afanasiy loontlyevichp doktor sellskokhoznauks, prof.; KU2WrsOV. Nikola7 Ivanoviobs, kand.sellskokhozonauk; USTrUGOV, P,,A,.,_red.; BEISMOV, A., takhn.red. (Corn oultivation in Kirghizistan] YozdelMnie kukuruzy v Kirgizii. Frunze, Kirgizakoe goo.izd-vos 1961s ?7 p. WU 15:5) (Kirghizistan --- Corn (Mmize)) OTTSELAY104, V.P., zootekhnik; POFOVy L.P., zootekhnikl USTYUGOVp P.G., red.; GOLOD, O.V., red.; BEYSMIOV, A., tekhn. re'd-. (More meat for the counti-fl Bollche biasa strane, FrunzeO Kir- gizskoe gos.izd-vo, 1961. 79 p, (MIRA 15:3) 1. Kolkhoz "I~liva" Kalininskogo rayona,, Kirgiz (for Otteelaynen). 2. Kolkhoz imeni Lenina Alamedinskogo rayonal Chuyskoy dolit7, Kirgiz (for Popov). (Chuya Valley-Meat) ALYBAYEV, Beyshen; DOROKBOV, Mikhail C-e-rasirovich; USTYIU,GOV. P.G.1 red.; B---YSMIOV, A., tekh.-j. red. (Storage of agricultural machinery] Khranenie sel'skokho- zial.stvepMkh mashin. Frunze, KIrgizgoaizdnt,, 1962. 29 p. (MIRA 17:2) USTYUGOV, Yuji. (Kirov) Rock salt boulder. Priroda 53 no-5:19 16/.. (MIRA 170) m UsTymn, 1. 1. Spinning Nachiner7 Economic advantages of using ring spinners in spinning cloth. rekst. prm. no. 5 (1952) 9. Monthly List of Russian Accessions, Library of Congress, August 1952 WUZ:~, Uncl. TURCHANINOV, A.A., Inzb.; Prinimali uchastiyez TORCHIN, Ya.G., ot.,irshiv z3c:tr,,Jn'~; nauchnyy soIrudnIk;_g_ IN I.I., atarskC~)r nauchny- y ALEKSEYEIIA, T.A*, mladshiv nauchny7 sotrudnik~ N.V., mladshiy nituchnyv sotrudnik; GORDON V.N., sta--shiy te khni k- -labo rant; SAVINA~ L.A., stArahiy tekhnik.-laborant; SOROKINA, A.I., atar-.5hly tekhnik-laborant Determining the iabor input for the manufpcture ,)f the ba-ic types of production in the woolen and woTsted industry. Imil.trudy TSNIISherati no.181185-248 163. "WRA 18-1) 1USTY'dVIN, 1 1 q ; I n2ho Econam!c officierc.7 of combining the processes of spinnlnj _r, slubbing end twisting on & spirmer-Niater, Hauch.--lasi. trudy TSNIIShergti no.1708-51 162. (MIRA 17j12) USTYUKHINP LI., insh.; STIMEVKOVA, A.I., inth, Labor productivitj in tke wool industry during the current seven- - year plan. Nauch.--isal. trudy TSNIISherati no.17tl02-112 162. (KMA l7t12) USTYUKJ,'I".',, T,[. st.arshiy nauchnyy sotrudnik I ~ ~ - 0. Development of progressive norms for raw material utilization in the woolen and worst,,,,d indU3try. Tekst. prom. 25 no.3; 6-8 Mr 16-5. (MIPA 18:5) 1. TSentra.Ltnyy nauchno-issledovatel'skly institut sherstyanoy promyshlennosti. i, -.- :T, , - Tl-;ZI,C,-,l y , U-SU(j,"I'll, b.V.- d, v.M. - I I I ~- ~ I Res-1.941-a.v-,E- c;-* iman tc 4-,-e an,:A4= cf of great frobl. kom. A,,'7'--'4 165. (,',CRA 18:9) UST'DaW A GOLOVIO. V Valuable cartographic publication. "Album of small river charts of the A.I. Okhotnikov and others. Reviewed by B. Ustiushanin., V.Golovko. Rech.transp. 15 no.5:32 My 156. (KLHA 9:8) (Rivers--Charts, maps. etc.) (Okhotnikov, A.I.) SHAYDO., N.M., inzh.; U3TYIJZHANIN, F.V., Jnzh. Reply to the article by V.R. Shchukin "Create a safety zone around waste disposal dumps. Bezop. truda v prom. 8 no.11: 49-50 N 164. (KIRA 28.2) 1. Gosudarstvennyy komitet pri Sovete Ministrov UkrSSH po nliazoru za bezopasnym vedeniyem rabot v prorryshlennosti i gornomu nadzoru. 1 'Y(! US Tyljilfl A N'114" F IV.,; ~SHAYTIO, N.M, , irzh. prevent'l-.re rw~--surci apalrn, lujldlon -;u~W-retq o, coFil. and gae. Bezop. '.7-,.1']1i v pr~.-,%, 8 no. L2 -, -6 ~j I 64. (MIRA 18! 3) y komitet pri Sovet,~ kllnt~trov UkrSEF pc nadzoru 1. zh tw~tzopttsnym vcdcniyem rabot. v prony-ilOrnnosti 11 go-;n,=-t nadzor%. AUTHORS: Tikhomirova--SJ.dorova, X. S., SOV/79-28-12-9/41 U!tyuzha 'to. TITLE: Amino Derivatives of 1,4-Anhydroxylite (Aminoproizvodnyye 1,4-angidroksilita) PERIODICALs Zhurnal obahchey khimii, 1958, Vol 28, Nr 12, pp 3210-3213 (USSR) ABSTRACT: The authors completed their earlier papers (Ref 1) by Bynthesizing the amino derivatives of xylitane starting from its chlorohydrin (5-chloro-1,4-anhydrox:ylite). The amino derivatives of xylite and xylitane have hitherto remained unknown. There is only few data available on the amination of the other multivalent alcohols. Thus, the 1,6-diamino mannite was obtained from diohloro-dimethylene mannite on heating in the autoclave with ammonia in methyl alcohol (Ref 2). Reactions of xylitane chlorohydrin with various amines were investigated and the follewing oompounds, hitherto unknown were synthesizedi 5-amino-1,4.-anhydroxylite M, 5-ethyl-amino- 1,4-anhydroxylite (II), 5-diethyl-amino-1,4-anhydroxylite (111)9 5-phenyl-amino-1,4-anhydroxylite (IV), and 5-piperidino-1,4- Card 1/3 anhydroxylite (V). The amines were characterized by their Amino Derivatives of 1,4--An~,ydroxylite SOV/79-28-12-9/41 tosyl derivatives which were used for the following syntheses. The action of p-taluenesulfonyl chloride is directed to the transformation of the alcohol groups into ester groups (VI to X) as well as to the amino groups for the primary amine (I) and the secondary amines (II, IV), with substituted sulfonamides (VI-VIII) being formed. C H-2--7 HCOTs HCOTs C TF34H j 6 TsOC H 1 H6- I- - nu Ts JH 2N I CH2R R-H(VI)'C 2H5(VII),C6 H5(VIII). R-N(C 2H5)2(,X) 'N(CH 3)5(x). Ts-O2SC6H4CH2-p Card 2/3 Amino Derivatives of '1,4-Anhydroxylite SOV/79-28-12-9/41 The conditions of the synthesis, the properties and analyses of the amino derivatives of xylitane are mentioned in table 1, their tosyl esters are mentioned in table 2. There are 2 tables and 2 references, 1 of which is Soviet. ASSOCIATION: Institut vysokomolokulyarnykh soyedineniy kkademii nauk SSSR (institute of High-Molecular Compounds, Academy of Sciences, USSR) SUBMITTED: January 20, 1-958 Card 3/3 DkNIWV, S.N.; TIKHOMIROVA-SIDOROVA., N.S.)_USTYUHANIV~ G.Ye.; YF,FIWVk, G.Ye.; KMN,, E.M. New data on the structure of xylitol dianhydride. Zlmr.ob. khim. 32 nc42:656-657 F 162. (MIRA 15:2) 1. Inatitut vysokomolekulyarnykh soyedineniy. (lylitol) - USTYI ZlVdl IN, G. Ye.; K'-',L'TS,,iV, A.l.,- TI.S.; DAIIILOV,S.&'.'. St-ructure. 0j, 9. ,:,.ur. rb. flitane (.Janhydro flite and acetal. khim. 34 no.12:3905-3907 D 16.~ (mlu Is, , 1. Iristitut vyi;okomolekulytrnykh -.,)ycdlreriiy t,'1 SS."OH. ,L 3552-66 Firf (m)/EPF(C)/EWP(J)/T RM I Ufl/0286/65/00 U . _910151008010()"r' AC ESSION NR.- AP502098 4 AUTHUH32 Daniiovf P* H*; zhanin,j.',. Ye.; Sidarova, N. S.; Logano M.) V. ~j TITLE: A method for obtaining epoxy reainn~' 'Class 39, 110- 1731105 SOURCE: Byulleten' izobreteniy i tovarnykii znakov, no- 15, 1965, 00 TOPIC TAGSt epoxyp resing alcohol, phenol ABSTRACT- This Author Certificate presents a method for obtaining epoxy resins by condensing epichlorhydrin of a polyatomic alcohol with biatonic phano!3 applicable to the production of epoxy resins (for in3tance, resorcin or dimi). The reaction is carried out in the presence of a base at a rising temperature) and solidification proceeds in the usual manner. To broaden the base of raw material by replacing the edible products with inedible ones, epiclUorhydrin of i xilitane-l,h-213-dianhydro-5-chlor-5-desoxyVlite is used as epichlorhydrin of a polyatomic alcohol. ASSOCIATIONt Institut vysokomolokulyarnykli soyedineniyj AN SSSH (Institute of High Molecular CoMeounds, AN i Lord 1/2 LA L 3552-66 ACCFSSION Wit AP502090 SUBMITTED: 1ONov63 No REF SOVt 000 ENCLs 00 SUB CODEt 000 CrTHERi 000 Card 2/2 ACC NRt AP7011821 AUTHOR: Tikhowirova-Sidorava, N. S.; ORG: none TITLE: Alcoholysis of uridine-21,31-cyclophosphate presence of pancreatic r1bonuclease SOURCEt Zhurnal obahchey khimii, v. SOURCE CODS1 UR/0079/66/03610'.-212219/2220 Ustyuzhanin, G. Ye.; Kogan, Z. M. with uridylic acid In the 36, no. 12, 1966, 2219-2220 TOPIC TAGSs paper chromatography, organic phosphate, hydrolysis, ribonucloic acid SUB CODE: 07 ABSTRACT: Alcoholysis of uridine-2'.3'-cyclopliorphate M v&s carried out in an 0-015 M phosphate buffer solution (pH 7-0) at 00. The reaction mixture with a total volume of 1 ml. contained 17 mg. pancreatic ribonucle86e, I in a concen- tration of 0.12 M, and uridylic acid in concentrations of 0.24-0-72 M. The re- action products were separated by paper chromatography. The reaction, as indi- cated by disappearance of I, was completed in 20 hrs. The yield of oligonucleotides I ~in all experiments was ~ 10%. In the-preaence of a 6-fold excess of uridylic acid,, uridylyl-(3',5')-uridine-31(2')-phosphate formed predominantly. Although hydrolyaii took..Dl8ce to a greater extent than alcoholysis, the reaction can be applied for Cmd 1! 2 UDCs 547.495.6+577.15 OOA9~~_ npyr'l