SCIENTIFIC ABSTRACT VALTS, I.E. - VALU, L.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001858510017-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 17
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

I --- -- - - _- - - - -
VALITSv I.N.; VOLKOVA, I.B.
Progress in the compilation of the international dictionary on
coal potrology. lzv. AN SSSR. Ser. gaol. 23 no-7:127-128 J1 '60-
(MIRA 13ilO)
(Coal geolog7-Dictionaries)

GUDZHEDZHIAIII, B.I.; CHICIRJA, B.K.; PETROVSIaY, G p RVITIANI, G.A.;
AWEPARASHVILI, M.V.; AVAUSHVILI, E.Ye. tde* c; eased];
VIRZIASHVILI, T.1,1,.,- SHCMWAYOV., D.1%,, glav.red.; ARCHVADZE, Sh.H.,
red.; BOGOLYULIOVA, L.I., red.; VALITS 1-.E., red.; TAVADZE, F.117.,
red.; YABLOKOV, V.S., red.; PEVZNER, G.Xe., red.izd-va; MAXUNI,Ye.V.,
tekhn. red.
[Coal atlas of the Caucasus] Atlas uglei Kavkaza. By B.LCudzbefthiani
I. dr. Moskva,, Izd-vo Akad.nauk SM, 1961. 167 p. (MIRA 14:12)
1. Akademiya nauk Gruzinskoy SSR, Tiflis. Sovet po izucheniyu proiz-.;
voditellnykh sil.
(Caucasus-Coal geology)

VOLKOVA, I.B.; NALIVKIN, D.V.; SLATVINSKAYAj Ye.A.; BOGOMAZOV, V.M.;
GAVRILOVA, 0.1.; GUREVIGH, A.B.; MUDROV, A.M.; NIKOLISKIYt V.M.;
OSHUWWVA, M.V.; PETRENKO, A.A.; POGREBITSKIY, 'Ye.O.; RITENBERG,
M.I.; BOCHKOVSKIY, F.A.; KIM, N.G.; LUSHCHIKHIN, G.M.; LYUBER,
A.A.; MA~EDONTSOV, A.V.; SENDERZON, E,M.; SINITSYN, V.M.; SHORIN,
V.P.; BELYANKIN, L.F.; VLASOV, V.M.; ISHINA, T.A.;
KONIVETS, V.I.; MARKOVICH, Ye.M.; HOKRINSKIY, V.V.; PROSVIRYAKOVA,
Z.P.; RADCHENKO, O.A.; SEMERIKOV, A.A.; FADDEYEVA, Z.I.; BUTOVA,
Ye.P.; VERBITSKAYA, Z.I.; DZENS-LITOVSKAYA, O.A.; DUBARI, G.P.;
IVANOVp N.V.; KARPOV, N.F.; KOLESNIKOV Ch M NEFEDOYEV, L.P.;
POPOV,, G.G.; SHTEMPELI, B.M.; KIRYUKOV, V.~., lZROV) V.V.,-
SALINIKOV, B.A.; MDNAKHOVA, L.P.[deceased]; MURATIOV. M.V.,-
GORSKIY, I.I., glav. red.; GUSEV, A.I.,, red.; MOLCHANOV, I.I.,
red.; TYZHNOV, A.V., red.;,SHABAROV, N.V., red.; YAVORSKIY, V.I.,
red.; REYKHERT, L.A., red.izd-va; ZAMARAYEVA, R.A., takhn. red
(Atlas of maps of coal deposits of the U.S.S.R.]Atlas kart ugle-
nakopleniia na territorii SSSR. Glav. red. I.I.Gorskii. Zam.
glav. red. V.V.Mokrinakii. Chleny red. kollegii: F.A.Bochkovskiy
i dr. Moskva, Izd-vo Akad. nauk SSSR, 1962. 17 p.
(MIRA 16:3)
1. Akademiya nauk SSSR. Laboratoriya geologii uglya. 2. Chlen-
korrespondent Oademii nauk SSSR (for Muratov).
(Coal geology-Maps)

VALITSp LE" kand. geologo-miner. -nauk,, otv. red.; SUVOROV, 1.V., red.
SOROKINA, V.A., tekhn. red.
[Physical and chemical properties of coalal Fizicheskie i
khimichea3de svoistva iskopaemykh uglei. Moskva, Izd-vo Akad.nauk
SSSR;.,1962. 267 p. (Akademiia nauk SSSR. Laboratoriia geologii
uglia. Trudyp no.16.) (~gAk 15:6)
(Coal-Analysis)

BMDYUKOVA, M.D.; TIOSOVA~ K.T.- 1-911CIIETIKO, A.M.Weceaued);
KOLOME"IMEVit, A.K.; LIFSHITS, M.M.; PAZUKBINA, D.K.;
SHARAYEVA, L.N.; SHIROKOV, A.Z.; red.;
STRUM, M.I., red.; NIKOLAYFIJA, I.N., red.
(Atlas of the Lower Carboniferous coals of the Donets Basin]
Atlas uglei, nizhnego karbona Donetskogo bassaina. (By] M.-D.
Berdiukova I dr, Moskvap Naxika,, -119i:4. 101 p.
MIRA 18:4)

MOKRINSKIY, Vladimir Vladimirovich; VALITS estovna;
VLASOV, Vladimir Mikhaylovich;'_1SHINA, Tamara reyevna;
PROSVIfffAKOVA, Zoya Petrovna; LAVROV, V.V., doktor geol.-
miner. nauk, otv. red.
(Characteristics of the development and distribution of
Early Mesozoic coal accumulation in the Crimea, the
Caucasus, and the Caspian Sea region] Zakonomemosti
razvitiia i razmeshcheniia rannomezozoiskogo uglenakop-
leniia na territorii Krymaj Kavkaza i Prikaspiia. Mo-
skva, Nauka, 1965. 222 p. (MIRA 19:7)
1. Leningrad. Vaesoyuznyy nauchno-issledovatellskiy geolo-
gicheakiy institut.

VALITMTER, V.L.0 kand. tekhn. nauk: dote.1 ARTDIOVA, T.N.,
(Methods for the transformation of drawings] Sposoby
preobrazovaniia opiura. Moskva, Moak. inzheneimo-
fizichaskii in-t,, -.1963. 43 p. (MIRA 18:3)

VALITSIV, A.M.; KNOBLOXH, A.K., xtarshiy kalibrovshchik.
the productivity of the 330 mill b7 compl*to mochimizatles
and the us# of an afficient groove deeiga. Motallurg ne.7:24-27 J1
156. O"k 9:9)
1.Xramatorskijr matallurgichookiy zavod imeni Kuybywhava.
(Rolling Mills)

PONOXAM, P.U-,;-V.40,T3 HASOPOV, H.A.; HEMLDVA, Ye. S.; SAVCHWO,
A.S.; DUKHANIN, A.S.; AKHMSKIY, ~'. 1.
Rolling of square blanks made by continuous casting. Biul. TSIIIICHK
no. 8:43 158. (MIRA 11:7)
1. Kramatarskiy metallurgichookiy zavod im. Kuybyehava(for Ponomarev.
Vallteav, Hasonav, Merkulova, Snvchank* 2. TSentrallwy nauchno-
iseledovatell skiy institut chernoy metallurgit(for Dukhanin, Akhtyroki.V).
(Rolling(Retalwark))

VALITSEV, L., avarchchik (M,)skva)
A dispute wbich could have been avoided. Sov. profsoiuz7
17 no.24:14-17 D 161. (MIM 14:12)
(Moscow-Wages-14achine tool industry)
(Trade unions)

VALITSEV, V.B.
Activating effect of the exclusion of a continuous light stimulus
on the rhytbmic activity of the eye in the frog. Dokl. AN SSSR
135 no.2:49)-496 H 160. 1 (MIRA 13:11)
1. Institut vysshoy nervnoy deyatelinosti AN SSSR. Predstav-
leno ukademikom N.H.Semenovym.
(Vision)

I VALITSEV V.B.
Bioelectrical activity of the retina in the isolatedfrog eye
during simultaneous constant and rhythmic light stimulation.
Biofizika 7 n0-41433-441 162. (MIRA 15111)
1. Institut vysshey nervnoy deyatellnosti i neyi-ofiziologii All
SSSR, Moskva.
(ELECTRORETINGGRAPHY) (LIGHT--PHYSIOLOGIC"l EFFECT)

u A - I . . - I I. ..- -. -2 j. I -
f-,7~QL7ro bur L w Or it
yl -.-t Ir ru -a s (I --T-rT fl n
TUN- WMT

IvLvag- Pl, and d sh im -ad -te-ratin&-a
Wa t t aqua
,aubvu4rl%!;l): 3-01-lifir63 MUM, ----SUB
_qQDE#,.- LS
----- - - - -- ---------
WIN

M"
VALITSEV V.B-__.
Significance of the choIJI-reactive sstructurf!S c,f th-- fi-r".
synaptic layer for the bicelectric activity of the -retina in
frogs. Zhur. vys. nerv. deiat. 15 110-5-934-0/36 S-0 165.
("'IMP 18: 11)
1. Institut vysshey nervnoy deyatellnostui i neyrofizio-logii-
All SSSR, Moskva.

VALITSEV, V.I.; ARTAMONOVAq S.M.-, KRAMWO, L.Kh.
- Precipitation of elements from molten salts. Report No.2:
Precipitation of nitrates and nitrites of the alkali metals from
melts. Izv.Sib.otd.AN SSSR no.5:59-65 161. (MIRA 14:6)
1. Institut neorganicheskoy khimii Sibirskogo otdeleniya AN SSSR,
Navosibirak.
(Alkali metal salts)

k-
",-VALITSEV. V.K.; OZIASHVILI, Ye.D.
Distribution of rare earth elpAents in the hydrolsis of alloys of
their oxides with-aluminum '01-hiocyanate. Izv.Sib.otd.AX SSSR
no.6:59-64 160. (MIRA 13:9)
1. Inetitut neorganicheskoy Wmii Sibirskogo otdeleniya AN SSSR.
(Rare earths) (Aluminum alloys)

VALITSEY, Y.K.; KOVMINA, V.P.
Reaction of lanthanum oxide with ammonium nitrate and
sulfate. Izv. Sib. otd. AN SSSU no. 10:71-76 160.
(MIRA 13:12)
1. Institut neorganichaskoy khimii Sibirskogo otdolaniya
AN SSSR.
(Lanthanum oxide) (Ammonium salts)

22341
S/200/61/000/004/001/005
D228/D305
AUTHORS: Valltsev, V. K", Artamonova, S. M., Didora, N. F. and
'!Cr-avchenko, L. Kh.
TITLE: Precipitation of elements from fused salts. Report 1.
Precipitation of some elements from fused ammonium
nitrate
PERIODICAL: Akademiya nauk SSSR. Sibirskeye otdeleniye. Izvestiya,
no. 4, 1961, 38-42
TEXT., This article reports on an investigation into separating
rare earth metals by means of precipitation of their insoluble
compounds by different precipitants from fused ammonium nitrate.
It is known that rare earth oxides react with fused ammonium nitrate
f0rM3_n luble double nitrates as cited by L.-Ordit and Ya. Kleyn-
,& so
berg L Abstracter's note: Names taken from Russian_7 (Ref. 1: Nevo-
dnyye rastvoriteli (Non-aqueous Solvents) IL, M. 1955). At high
temperatures double rare earth nitrates react with ammonium sul-
phate at the formation of double rare earth sulphates, e.g. double
Card 115

22341
S/200/61/000/004/001/005
Precipitation of elements... D228/D305
lanthanum sulpahte at 3300C as cited by V. K. Valltsev and V. P.
Kovyrzina (Ref. 4: Izv. SO AN SSSRI No 10, 1960). The same reaction
in fused ammonium nitrate used as a solvent takes place at 1800C.
The use of fused ammonium nitrate allows work at lower temperatures,
mainly at 1800C. The following experiments were conducted: Rare
earth oxides previously ignited to 9000C - La203, Nd203, Er203,
DY203 and alkaline earth oxides - MgO, CaO, SrO, BaO, uranium nit-
rate and thorium nitrate, were dissolved in fused ammonium nitrate
at a temperature of 1800C concurrently with the formation of soluble
double nitrates. The solubility of double lanthanum nitrate is
60% by weight. The oxides do not react with fused NH4NO3. The
reactivity of uranium oxide with fused ammonium nitrate is very low.
The solution of Th and U was produced as follows: hydrated nitrates
of U and Th were fused with ammonium nitrate at 2500CI twice, to a
dry cake, a part of which (assumed to be double nitrates) was sol-
uble in fused solvent. A precipitant in the form of salt or dis-
solved in fused ammonium nitrate was then added to the solution of
metal nitrates. The precipitate formed was separated from the
C ard 2/5

22341
5/200/61/000/004/c-,01/905
Precipitation of elements ... D223/D305
mother-licpior by filtrati6n (centrifusion could be used
state the authors) and washed with a fused solvent JErom t-,lc c=CSO
.of preci,)itant, maintaining the tcm-perature of IUSOOC. The-a t1ric
precipitate was analyzed in tn,2 case of acnonium sulphatc ifor
ammonium ion and sulphatc ion. The reciultz oZ prcccipitanta
L
are given in tabulated form.
Legend: (1) Results Pe3yjtb-raTU XHMH4ecxoro AHUMU OCAAK05
of chemical analysis -cocra".
of precipitates;
pacc-11IT31111WA,
0
(2) Formula; (3) Con- .009MY.13

tent %; (4) Calaula- 2

S04
X"j
4*
S 2
04
XH+
ted; (5) Found
2Nd2(SO4)3 3 NH42SO4 37'.25 55,78 37,50 1 .55.401 7, 10

Er:(SOi)3 S(NH4)2so4
35,32
4.42
34.621
I 55,58 9.77

- ~A
2L82(SO,)s 3(Nff4)IS04 M,.19 1.%.54 7.07 136.97 54,90 8.12
Card 315

Precipitation oi elements...
2.2341
S/200~61/000/004/001/005
D228/ D305
TemDerature does.notalter tM reaction but it does change the
ratio x-and y in the double lanthanum sulphate - x La2 (S04)3
(*vIH4)2 S04. Ammonium oxalate precipitates La, Nd, Dy, Ca,-Mg,
Sr, Ba, Thorium. Double thorium oxalate is*soluble in.the excess
of precipitant. Uranium under.these conditions is not precipitated.
AlIcali oxalate can be used instead of ammonium oxalate vith exactly
the same results. Time of precipitation varies from immediate to
30 hours for differt'-.nt rare earth metals. The authors conclude that
on the basis of new ideas on 'the structure of solvents, it may be
suggested that this ratio varies also, depending on.the precipitant
concentration. The different behavior of rare earth metals during
precipitation by diff&rent precipitants opens up new possibilities
for tlieir separation. There is I table and 6 references: 3 joviet-
bloc and 3 non-'Joviet-blo6. The references to the :Inglisli-language
Dublications ravd..as follows: III. C. Vickery. 1. Chem. Ooe., 10,
~300 (1949), T. D~ -Aftandilian. Inor,r. I'Syntheses, 5, 37
(1957), D. E. Gruen. 1. Inorg. Nucl.. Chetti. Soc., 4, 1, 74 (1957)
,~SSCCI,UION: Institut neor-'anicheskoy !-.himii Jibirs%o-fo otdeleniya
carc! 4/5

22341
S/200/61/000/004/001/005
Precipitation of,elements... D228/D305
AN SSSR, Novosibirsk (Institute of Inor anic Chemistry,
Siberian Division, AS USSR, Novosibirski
SUBMITTED: July 19, 1960
Card 5/5

23631
S/200/61/000/006/003/004
D206/D303
AUTHORS: Valltsev, V.K., Avvakumov, Ye. G. and Pyr1yev, M.F.
TITLE: Distribution of lanthanoids in the fusion of ammonium
nitrate in the process of zoned crystallization
PERIODICAL: Akademiya nauk SSSR. Sibirskoye otdeleniye. Izvestiya,
no.~6, 1961, 71-74
TEXT: The purpose of this work was the study of the distribution
of the reaction products of rare-earth oxides (La, Fr, Nd, Sa, Er
and Y) with fused ammonium nitrate irt the process of zoned crystal-
lization. There appears to be little: published information concern-
ing the application of zoned crystallization for separating and
purifying rare-earth elements, although the method has been employed
by Sue et al (Ref. 1: P. Sue, 1. Pauly, Bull. Sac. Chim. de France,
No. 5, 593 (1958) for isolating other elements with similar chemical
properties, Further research by V. Val'tsev and V. Kovyrzina (Ref.
5: Izv. sibir. otdel. Akad Nauk SSSR, No. 10, 1960) resulted in the
development of a technique for obtaining the double nitrate of lan-
C ard 1/4

23631
S/200
,/61/000/006/003/004
Distribution of lanthanoids ... D206/D303
thanum, and in certain data regarding its solubility in fused ammon-
ium nitrate. The experimental procedure adopted by the authors com-
prises the initial solution of rare-earth oxides in molten ammonium
nitrate; the cooling of the melt in an aluminum boat, with the form-
ation of a semi-cylindrical slab having a length of 32 cm; the refu-
sion of the slab at 170 - 1900C in a molybdenum-glass tube by means
of a heater which is fitted with a thermocouple and rheostat to L/
ensure smooth temperature control and which is moved over the slab
at a speed of 0.82 cm/hr; the removal of the slab from the boat
after a period of 45 hours; and the subsequent dissection of the
slab into ten equal parts which are then analyzed for the rare-earths.
During the passage of the salt slab through the molten zone the
rare-earths are redistributdd in such a way that thcir concentration
at the end of the slab considerably exceeds the original value. The
distribution curves for the nitrates of Nd, Sa and Y are shown
graphically. The coefficient of enrichment (K) - necessary for com-
paring the behavior of elements in the process of zoned crystalliza-
tion - was calculated from the ratio of their inital to final con-
centration. After three slab runs through the fused zone the dis-
Card 2/4

23631
S/200/61/000/006/003/004
Distribution of lanthanoids ... D206/D303
tribution of elements at 'the end of the slab is in direct linear
relationship to their atomic weights (A): K a 0.063A - 7.33.
This relationship also holds for a slab of heterogeneous composition
prepared in a slightly different manner. Coefficients of separation
- the ratio of the enrichment coefficients for certain pairs of ele-
ments - were found in order to appraise the possibility of purifying
particular elements. They reach a maximum when nitrates are cryst-
allized in a heterogeneous slab, after no less than nine runs
through the fused zone. The pairs Sa - Y and Nd - Sa were therefore
subjected to zoned purification under these conditions which are
evidently the most favorable for purifying certain pairs of rare-
earth elements. A relatively pure separation is effected in the
case of samarin and yttrium: the yttrium content rises from 97.176
to 99.276, whi-le the samarin concentration falls from 2.976 to 0.8%.
The removal of neodymiuin from yttrium, however, was not successfully
ac'complished. This is believed to be due to the fact that the dis-
tribution of rather large amounts of rare-earths in ammonium nitrate
differs from the normal distribution specified by existing equations
(Ref. 6: Metody polucheniya. chi'stykh metallov (Methods of Obtaining
Card 3/4

23631
S/20OJ61/000/006/003/004
Distribution of lanthanoids... D206/D303
Pure Metals), Sb. perevodov (Collection of translations), IL, 1957)
which.are only applicable in the case of a low concentration of im-
purities in a slab in the process of zoned crystallization. The
authors conclude that their method is only suitable for separating
some elements of the yttrium and cerium groups; it is not recommend-
ed for purifying mixtures consisting of elements from other rare-
earth groups with very similar properties. There are 3 figures, 1
table and 6 references: 2 Soviet-bloc and 4 non-Soviet-bloc. The V/
references to the English-language publications read as follows:
J.K. Marsh, J. Chem. Soc. No. 1, 2051 (1946); R.C. Vickery, J. Chem.
Soc. No. 10, 2508 (1949); T. Meller, V. Aftandialian, J. Amer. Chem.
Soc. 76, 5249 (1954).
ASSOCIATION: Institut neorganicheskoy khimii Sibirskogo otdeleniya
-AN SSSR (Organic Chemistry Institute of the Siberian
Division, AS USSR) Novosibirsk
SUBMITTED: September 7, 1960
Card 4/4

S.21~m 1-i Liz lb67 t21"
27732
S/200/61/000/009/002/003
D219/D301
AUTHORSs Valltsev,V.K., and Kovyrzina,V.P.
- - - - -----------
TITLEs Thermographic investigation of the reaction of lanthanic
oxide with msleir~ innid
PERIODICALs Akademiya nauk SSSR. Sibirskoye otdeleniye, Izvestiya,
no. 9, 1961, 47-52
TEXT. Thermal methods of synthesizing the rare-earth maleates
have been little studiedg so the authors investigated this problem by
physico-chemical research on the reaction of La203 with maleic acid.The
analyses were carried out in accordance with V.S. Kurnakov's thermographic
method Abstracter's note: No reference given with supplementary volumetric,
crystallographic and chemical techniques. The experimental apparatus includ-
ed the pyrometer and recording buret, described by L.G. Berg (Ref.2: Termo-
grafiya (Thermography), Moscow, 1937; Ref. 31 Tr. Kaz. fil. AN SSSR, vyp- 3,
1956), and G.B. Bokiyls polarizing microscope (Ref. 4s Immercionnyy analiz
(Immersion analysis)q Moscow, 1951). It was first established that the
Card 1/4

27732
B/200/61/'000/009/002/003
D219/D301
Thermographic investigation of the reaction...
reaction between La.203 and maleic acid begins at 110? Next, mixtures con-
taining variable amounts of these compounds were heated for 20 minutes at
1300 and then analyzed crystallo-optically, when two products--termed A
and B--were detected. Their refractive indices are 10577 and 1,446, both
substances being soluble in water but insoluble in alcohol, acetone and ben-
zene. B, present in very small quantities, may be due either to A's reac-
tion with excess maleic acid or to Ala thermal decompcsition. Additional
tests, involving the a)ntinuous heating of samples to 3500and the use of CaH2
and P205 absorbers, indicated the dissociation of A first at 145', when wa-
ter is evolved, and then again at 1960; C02, however, is only given off at
temperatures of 2600 and above. It was further ascertained that A partly
decomposes at 1450 into B, which itself dissociates into water and C02 bet-
ween 1960 and 260? The maximum evolution of heat from the reaction is ob-
tained if the original materials are taken in strict stoichiometric pro-
portion: the greater the divergence from this ratio, the less likely the
decomposition of A. According to the results of the authors"chemical ana-
lyses A has the formulag La2(C404H2)3 . 1-23H4C404' Its aqueous solution
Card 2/4

27732
5/200/61/000/009/002/003
D219/D301
Thermographic investigation of the reaction...
gives a pH of 4 and intensely decolorizes permangmte. Conclusions.
1) The JAnthanin maleate thus synthesized differs from the usu4l neutral-
salts prepared from rare-earth oxides and ammonium compounds in that it is
a double salt--of La2(C4O4H2)3 and H4C404, 2) The thermal decomposition of
the double salt proceeds through the splitting-off of maleic acid, which
simultaneously breaks down into the anhydride and water, to the formation
of a new compound that also dissociates at higher temperatures; the nature
of this substance has yet to be determined. 3) The authors stress the impor-
tance of this reaction between rare-earth oxides and molten acid to form
new compounds with new properties: e.g. the solubility of these secondary
products is negligible in comparison with that of the primary products of
the interaction of rare-earth oxides with certain organic acida. There are
4 figures and 4 Soviet-bloc references.
ASSOCIATIONs Institut neorganicbeskoy khizii Sibirskogo otdeleniya
Akademii nauk SSSR, Novosibirsk (Institute of Inorganic
Chemistry, Siberian Section, Academy of Sciences of the
USSR.Novosibirsk)
Card 3/4

B12001621000100210021003
D204/D301
AUTHORS; Valt8ev, V.K.p Oziashvilip Ye.D.p and Solov'yev, L.K.
TITIE: Zone crystallization of lanthanon compounds from cer-
tain molten salts
PERIODICAM Akademiya nauk SSSR. Sibirskoye otdelaniyop lzveotiya~
no. 2, 1962, 53 - 57
TEXT: Description of an investiCation aimed at clarifying the ru-
les prevailment during the zone crystallization of complex systems
of lanthanon compounds from fused TTH4NO 3 and NH4 CNS (as oxideB) and
MgC12 and BaC12 (as chlorides). The following mixtures were tested
(1) La 2.5, Pr 8-11, Nd 86.84, Sm. 2-3, and (2) Pr 3.66# Sm 29.3
Eu 1.0, Gd 24.3, Dy 5.77v Ho 0.5, Eb 4.7, La, Tb, Yb 1, Y 25.2.
The melts were cas-u into rods which were then zone crystallized 6-9
times, passing the zone at 5 cm1hr. The experimental method for
chloride melts is indicated; for the other two the procedure was
that used earlier. Sections of rod were then analyzed spectrogra-
phically for the lanthanons. The results are tabulated and discus-

S1200162100010021002100311
Zone crystallization of lanthanon D204/D301
sed In N114NO3 the heavier elements tended in general to concentra-
te at the end of the bar and the same was observed for Sm (mixture
(1)) in the NH4CNS melt. 6imilar tendencies were observed for the
chloride melts although the results were only qualitative. It is
corcluded that (a) zone crystallization from NH 4 NO3or NH4CNS is
promising owing -Go the low temperature of the process. The chloride
nrocess is further made difficult due to the hygroscopic properties
of the lanthanon chlorides. (b) Concentration of the heavier ele-
raents at the end of the bar is probably due to their lower m.p.'s
although discrepancies to this rule were observed. (c) Relative
proportions of the lanthanons (mixture (1)) in NH 4NO3and NH4C"S
melts were relatively unaltered after zone crystallization, The dis-
tribution is probably affected rather more in the high temperature
chloride process, Analytical work was carried out by R.R. Shvangi-
radze. There are 3 tables and 5 references: 4 Soviet-bloc and 1 non-
Soviet-bloc. The reference to the Engliah-language publication
reads as follows: H. Reedp B.S. Hopkinsi J. Amer. Chem, Soc., 57,
1159t 1935.
Card 2/3

S/200/62/000/002/002/003
Zone crystallization of lanthanon D204/D301
ASSOCIATION: Institut neorganicheekoy khimii sibirskogo otdeleniya
AN SSSR Novosibirsk (Institute of Inorganic Chemistry
of the kberian Branch of the AS USSRt Novosibirsk)
SUBMITTED: September 30P 1960
Card 3/3

C:I: I tse,!, V. K. Arta:,~=Crv, Ye. V.. F.; Krev~henk-o., L. K-..
Se-,eratll-n of in nit-rate vith '-Ile 'ie-'-) 0' ZO--
SCURCE: All SS Sibirskoye otdeleniye. lzvestiya. SeriyaL khimic-heskikh nauk,
no. 1, 1963, 152-1554
TCPIC TAGS: zone crystellizatlori, La, Hd, Fx, Sm, M, Yt, lant-hanide se-parstion
ABSTRACT- The possibility of se.para~.ing La, Nd, Er, Sm, Gd, and Y4, ez lo,-,Iblem
suLfater, from E--=oni= nitrate melts b,. zone c-xrstal2~-zatlon
3eparetion -,ms indicated af:--r es c~f mclte-, zc-c ~1*:
us ng a=on~= sulfate as preclpitl~.--; tie lantha7iide double sujJfates sett-ed olit
i nthe central portion of the bar. nzalate ,--s a-so erfectf-.-e
,nrecipit-,nt. ) 7he elenent
ir'Tot;
a~nd Das3es '-- t.',ie er- I of
cr -en;~~n of -azses,
cone fl-n-,--r al".o n, etc.,, ',c '--e wrir,zi cut. a--'. has, 2 1 ~7 .
Card 1/a / Association: inst. of inorganic Cher-astry, Siber'an Dept., AN SSSR

KUPRIYANOVA, A,,K.; VAL'TSEV, V.K.; KA14kRZIN, A.A.
Precipitation from fused salts. Report Ifo.3i Precipitation of
neodymium and praaeodymium from molten potassium nitrate studJ*d
by the method of amperometric titration. Jzv. SO AN SSSR no.7
Ser.khim.nauk no.2:29-33 163. (MIRA 16-10)
1. Institut neorganichoskoy khimi:L Sibirskogo otdol6niya
AN SSSR, Novosibirsk.

3/709/60/025/001/005/009-
D040/Dllx
AUTHORS; Spivak, E.I., and Valltsev, V.V., Engineers
TITLE? Reheating furnaces with reels
SOURCE: Nauchno-.tekhnicheskoye obshchestvo chernoy metallurgii. Trudy,
v-.25, pt.l. Moscow, 1960. Raschaty, konstruirovaniy(- L
ekspluatatsiya nagrevatellnykh pechey; matorialy Vse,:,oyuzrLo6o
soveshchaniya, 358-365
TEXT; The paper describes two reheating furnac93 In operation since 1957
at the Novo-Lipetskiy metallurgicheskiy zavod (Novo-Lipetsk Piletallurgical
Plant). Designed by the Gipromez Institute, these were the first Soviet
reheating furnaces with a reel inside. The furnaces reheat metal in th-
rolling process on the finishing stand of a 1200 strip mill consisting of
two stands. Slabs,600-1000 mm wide, 100-140 mm thick, 2.0-2.3 m long an-j
weighing up to 2.5 t1are heated in a holding furnace and rolled in a rough
stand to 10-11 mm thickness. Strips of 2 mm thickness are rolled in tne
Card 1/3

S/70 60/025/001/00ri/006
Reheating furnaces D040YD113
-finishing stand in 5 passes, and a strip runs twice into each furnaoe;
strips thicker than 3 mm and narrow bands thicker than 2.5 mm tak,