SCIENTIFIC ABSTRACT VANA, M. - VANAGS, G.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001858520006-6
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 31, 2001
• Sequence Number: 6
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

VANA)
man

404 VAM, L.ApIr.
Abdominal typhw in children. Geoko pediat. 12 no,8:693-700 5 Aug
57.
1. Infakeni oddeleni OUNZ v Uh. Hradisti, prednost MUDr R. Yana.
(THMOID FIV , in inf. & child
(CZ))

VANA, R.
"Jaroslav Svoboda, State Prize Winner." n. 21+1
"Orders of Labor Awarded on May 1, 1953.11 P. 242 (Prum-vsl Potravin, Vol. 4, no. 62
June 1953, Praha)
SO: Monthly List of Fast European fccessions, Vol. 3, no. 2, Library of Congress,
Feb. 1954, Uncl.

VAUA, V.; HAJOS, Z.
A delay-producing,, device for the Tm-1694 synchroscope. p.24. (Sdelovaci Technika. Vol. 5,
no. 1, Jan. 195~- Czechoslovakia.)
SO: Mlonthly List of East European Accession (EEAL) LC. Vol. 6, no. 7, July 1957. Uncl.

28 28 Ja ~,5
j~ In p r, ri
e., I r
dn-. .4T.. P.

MIKULA, Frantisek; ZAPLETAL, Bohuslav; VANA_,_Vaclav
Papilloma of the choroid plexus of the 4th cerebral ventricle.
Rozhl. chir. 41 no.6:432-437 Je '62.
1. Neurologicka klinika lekarske fakulty University Palackeho v Olo-
mouci, prednosta clen korespondent CSAV prof. dr. Jar. Hrbek, DrSc.
Neurochirurgicke oddeleni fakultni nemocnice v Olomouci, prednosta
MUDr, B. Zapletal.
(CHOROID PLEXUS neoplasms)
(BRAIN NEOPLASMS case reports)
(PAPILLO14A case reports)

YtNAp V.
Hypothezv.~s iA 6urge--7 of cerebrovascu7jar ma~12crmtIong.
RozhIl. oh--.. 431 no.lOa698-702 0 164.
1. NourocHrurgicke oddeler.1' -'ekareke fa~-,2ty Palaciceho
Univeralty v Olomouni, (vadouolt MUDr. B. flapietal).

RIUSM, K.; VAKA, V.
Protoporph7rin in blood calls, Pracoyni lek. 2 no.5:201-WQ 15
Nov 50. (UIAL 20:6)
1. Of the Clinic of the Industrial Institute, Prague (Head--Prof.
Taisinger,M.D.).

BAUM, T., KUDr; VANA, V., MUDr
fterapy of spoldneous panniculitis of Weber-Christian type, with
cortisone and ACTH. Oas. lek. cook, 93 no.46:1280-1281 12 NoT 54.
1. X chirurgickeho oddeloni OM VICaske Lips, prodnosta. KUDr
V. Fabian
(PAMCULITIS, ther&W
AGTE 8; cortisone)
(ACTH. ther. use
PAnniCUlitie)
(CCRTISONN. ther. use
panniculitim)

VARA, Vladimir, XUDr.
Chemicals in agriculture. Prakt. Isk., Praha 35 no.13:
3DI-303 5 July 55.
(YMILIZIMS
health aspects)
(INSBCTICIDES
in agriculture, health aspects)

VAM, Vladimir; LISKOVA, Blanka
Occupational diseases reported dnring 1958.,Pracavai lek. 11 no.8:
423-429 Oct 59.
1. Ministerstvo zdravotnictvi. Praha Ustav bygieny prace a chorob
z povolani, Praha.
(OCGUPATIONAL DISFASM, statist.)

um V1&d1m4r----.,.
A now awndmnt to the health legislation.
285-286 J1 160.
(PUBLIC HXAWH legiel.)
4
12 no. 6:
Pracarni, lek.
'I'I. %
AWLIL
.1.1.
I

q VANA, V.
Occupational diseaseq. Pracovni lek. 14 no.ls5-8 162-
(OCCUFATIONAL DISFASF-5)
i
I
i
,
i
k
.4-

VANAp V.
.1;8-10 162./
Health services for workers. Fraco'mi lek. 14 no
(jjIDLtSTpjAL II-EDICUIE) - '

L -31458-66
ACC NRj AP6023191 SOURCE CODE: CZ/0082/63 5 73
AUTHOR: Klqpetek, J.; Zapletal* B.; D~ak Z.; Vans, V.
ORG: Neurological Clinic/headed by'Dr. J. &.bg . DrSc/. Faculty of Medicine,, PUl
Olomouc (Neurolo cka klinika, lekarake fakulty PU); Neurological Section/headed
by Dr. B. Za at Faculty Hospital,, Olomouc (Neurologicke oddeleni fakultni
nemocnice).
TITLEt Electrocorticographic recording of an epileptic attack
SOURCE: Caskosloveneka, neurologie, v. 28, no. 5. 1965, 368-373
TOPIC TAGS., diagnostic instrument, nervous system disease, pathogenesis# cerebral
cortex, man
ABSTRAM Detailed description of two patientep female aged 29 and male aged 20
with epileptic attacks, the first being a Jacksoniazi And the second brought about
by stimulation of an epileptic focus. Electrocorticography ii considered very -
valuable for diagnootic and etiologic clAssification. Orig. :~. hasl 4 figures,
[Based on Eng. abst-1 [JPRS1
SUB CODE: 06 / SUBK DATS: none / ORM MW 1 001 OM REF: 013

VPI! A, V.
Contribution to the treatment of total paralysis of the res-
piratory muscles in neuromyelitis optical Devic. Cesk. neurol.
28 no.6:426-428 N 1 65.
1. Neurochirurgicke oddeleni fakultni nemocnice v Olomouci
(vedouci - doc. dr. B. Zapletal, CSc.

VANA, V.
Experiences -with the ad--inistration of glycerin in neurosurgery.
Rozhl. chir. " no.9:670-672 S 165.
1. Neurochirurgicke addeleni fakultni nemocnice v Olomouci
(vedouci doc. dr. B. Zapletal., CSc.).

XONTO, B.; VANA, V.; VOJACEK, K.
Contribution to pathology of the chlasm. Cesk. oftal. 22
no.lt68-75 la 1 66
1. Ocni klinika lekarske fakulty Pa2ackeho University v
Momcuci (prednosta - prof. dr. V. V'ejdovsky, D11c.) ,,
Neurochirurgicke oddeleni Fakultni nemocnice v Olomouci
(vedauoi: doe. dr. B. Zapletalp Mo.), Patologickoanatomicky
ustav lekarBke fakulty Palackeho 'University v Momouoi (pred-
nostat doe. dr. V. Valacb).

CZECHOSLOVAKIA
YARA. V.; KLAUS, E.; 11eurosurrrical Department, Faculty 111o3pital
(Neurochirur,-icke Oddeleni Fallcultni Nemocnice), Olomouc, Head
(Vedouci) Docent Dr B. ZAPLETAL; Neurolo,rrical Clinic, Nedical
Raculty, Palacky University (Nourologicka Klinika Lokarsko ?a-
kulty PU), Olomouc, He~d (Prednosta) Prof Dr J. HRBEK.
"Premedication with Neuroleptics and Analgesice in Gerebral Ar-
teriosraphy.11
4:1
Prague, Ceskoslovenska Neurolopie, Vol 29, No 5, Sep 66, pp
357 - 360
Abstract /Authors' English sirmnary _7: Application of neurolep-
ties and "Fnalgesics in cerebral arteriography was investigated
experimentally in the neurosuraical department of the University
Hospital at Olomouc. *The results of treatment of 68 patients
show that arteriography with prened-ication combined with local
filtration anesthesia of the site of the arterial puncture on the
neck is better than the usual methods of either local anesthesia
only or of general anesthesia. 6 Western, 1 Czech reference.

Free activity following intracerebral administration of bacterial toxins,
Opok. fysiol. 7 no-3:254-255 )%7 58.
f 14
1. Katedra farmakologie fakulty detakeho lekaretvi v Praze.
(STREPTOLYSIN, effects,
0, smooth ausc. activity after intracerebral admin. (Cz))
(WUCLW, eff. of drugs on,
streptol.voin 0, eff. of intracerebral admin. on smooth
muse. activity (Cz))

VARACM, J.; KREBS, V.; SCHEYM11A, 3.; BISIM, W.
Apparatus for intracerebral injections in mice. Cesk. fysiol. 8 no.3:
255 Apr 59.
1. Farmakologicks, kate&a fak. detskeho lek. Praha. Ustav pro kortikofis-
ceralni Datologii ,r Berline-Buchu, Prednesno na III. fy9iologickych dnech
v Brne den 15. 1959.
(BRAIN,
intracerebral inject. appar. (Cz))
(INJEGTIONS, appar. & instruments.
same)

Ao; 14AG3K, K-, ;Aar-ZK.
nobarmane. Ceak. fYGiO 1. 8 no.3;177-178
Reserpine-like actlOu of phe
Apr 59o predueseno na
1. Vy2kmmny ustav pro farmacii a biochemi'le Praha-
fysiologickych dnech v Brue dne 14. 1. 1959-
(RES33purs, rel. cPds- -ohenoharmue on 5-hYdrOxy J,,dole
renerpine-like actiOu Of
acetic acid metab. (Cz))
(UNDOISS, Off.
same)

VANA0111, Rudolf;STRYFAL, Frantisek
Massive osteolysis of Gorham--Stout. Acta chir. orthop. traum.
cech. 27 no.1:89-95 F 160
1. 1. klinika pro ortopedickou a detskou chirargii EU v Praze,
Prednosta Prof. MUDr. Miroolay Jaron N. patologickoanatomicky
ustav VJ v Praze, prednosta prof. MUDr. Vaclav Jedlicka
(EMWGIOKL compl. )
(ILIUM compl.)

USSR/Human and Animal Physiology - Blood Circulation. T-5
Abs Jour Ref Zhur - Blol.) 11o 1) 1958, 4o15
Author T.G& Vanadze,
Inst Academy of Sciences. Georgian SSR
Title On the Condition of Vascular Reactions and Mechanisms
of Their Changes in Patients with Hypertensive Disease.
Orig Pub Tr. In-t klinich. i eksperim. kardiol. AN OruzSSR., 1956
(1957), 4, 95-104
Abstract No abstract.
Card 1/1

VANACFAp VaolaV
egent state of typification and g1tandardization of equipment
r
P
for palletization, hnndlinp, 9f mAterials, and storage. Normalizace
3.2 no.L s 8 upplL P1/165- Pi/192 164.
1. KovotookuLa National Enterpriset Prague,

- - - ---
VAVADZINS.. Z.;.BRIVE2E, A. p red.
Sirmlda. Riga. Latvijas Valsto iz-,:-va, ll~-' . I -;.
, C,3
[In 5 languftes] (111,tA 17:6)

VPIIADZINS, Z.,
(Siguldai color photographs by Voldemars Upitis]
Sigulda; Voldemara Upisa krasu foto. Rigap Latvijas
Valsts izd-bas 1964. 1 v. (MIRA 18:1)

V.ANADZlNS Z - BRIVERE, A., red.
I
Riga. Riga, Latvijas Valsts izd-4a, 1964. 1 v.
(MIRA 17:8)

MAWLEVICA
t 'L1 L v
Ll e.
sma,
foW.;j

AVAKYAN, A.A.. VANAG, A. I.
Rapid. method of detecting Magri bodies with a phase contrast
microscope. Zhur.mikroblol. epid. i immm. no.6:90-96 Je '55.
(KLHA 8: 9)
1. Iz Instituta virusologii imeal. D.I.
(dir.-prof. P.N. Koeyakov)
(RAIM, pathology.
Negri bodies, detection with
scope)
(MICFDSCOPIC, PHM,
of Negri bodies)
Ivanovskogo AMR SSSR
phase contrast micro-

SIIUBLLDZE, A.K.; MAYEVSKAYA, T.M.; VANAG,, A.I.
Some features of different strains of herpes viruses. Report No.2:
Pathogenicity and morphological features of different strains of
herpso viruses. Vop.virus. 7 no.3:286-293 ~~-Je 161.
(MIRA 14:7)
1. Institut, virusologii imeni D.I.Ivanovskogo AM SSSRI Moskva.
(HERPES)

SHUBLADZE, A.K.; VANAG, A.I.j MAYEVSKAYA, T.M.
Some features of different strains of the herpes virus. Report No.
3: Role of erythrocy-tes in the pathogenesis of infection. Vop.virus.
7 no.3:293-299 My-Je 161. (MIIU 14:7)
1. Institut virusologii imeni D.I.Ivanovskogo AM SSSR, Moskva.
(HERPES) (ERYTHROGYTES)

SWBLADZE~ A.K.; BARINSHY, r.y.; B,-;3PROZiAN1NYY, D.K.; ANANIM, V.A.;
VANAC, A. I.
use of comr-firative virology mat~ods in atudying virus hepatite!;.
Report Nn.l: Study of v1i,.s accumulation dynarnics In t~e organs of
experimentally infected animals. Vope virus. 10 no.4.-2.67-.473 J1-
165, (MIRA 108
lo Institut virusologii imenI D.1.1vanovBkcgo AMN SSSR, Moskva.

BTCHKOVA, Ye.N,; SHENp R.M*IIVAINA02 A.I.
Virusso loolated from pnti.~nts with encephalcmyeliMa and multiple
acleronis. Repart N6.2* Stndy of the pathomorphology of expee-wn-
tal infection, Vop. virus. 10 no.51595-601 S-0 165.
(MIR& 'Isill)
1. Inistitut virufsologli tmeni D.I.1vanovskogo ILMN SS.I;Rp Moskva,

w ~ -- lu 3 ,~, J( ,
-, . t
I (-.;, pit- S.'at, c,
~ -- .., ~ ; ,
,; . ~ --I
. . f I
I I I

1. VAIN"AIG, G. W%NAG, Ye.
t
2. U30-H (600)
4. 0Y.:yphthalonomide
7. New isomer of nitroindandione, the J~r-osyphthalonimide. Dokl. 0 33-jh 90
No. 1, 1953.
9. Monthl List of Russian Accessions, Library of Congress, April 1-953, Uncl.

VANAG, E. V.
"Reaction of Nitroindanediol With Formaldehyde and With
Acetic Anhydride.#' Cand Chem Scis Latvian U, Riga,, 1954.
(RZhKhim, No 21v Nov 54)
Survey of Scientific and Technical Dissertations Defended at USSR
Higher Educational InatitutionB (32)
SOt Sum. No.521, 2 Jun 55

wit-u exc"s ~-Id, phtl .1aml
indan-dicne-2)[1, Va 00 plattlots. rn 25.3 (decm"pn.),
wai p,c;Ki. by boiling IV vnth. md Pznd Ill. The stability
Gi I i.; CXPW.-.Ed b7 pi es ~~-e of I or I intraraol. H bonds.
Andrew Dramuld-g

VANAG, E.; VANAG G.
--ammid
rl- complex Salts of /Y-oxyphthalonimide with polyiodides. 7bur.ob.khim.
24 no.11:1998-2001 N 154. (KWk 8:3)
1. Voronezbskir gosuiaretvennyy universitet.
(Phthalonimides) (iodiass)

VAHAO, E.-V.---- In Latvian
VANAG, E. V. -- "Reaction of Nitroindadione with Forkaldehyde and with Acetic Anhydride."
Latvian State U, 1954. In Latvian (Dissertation for the Degree of Candidate of
Chemical ScienceO
SO: Izvestiya Ak. Nauk kj&=skoy-SSR, No. 9, Sept., 1955

VAWq G**, VA6WsEs
Specific reaction for formaldehyde. Zhur.anal.khin. 10 noo'1:63-64
Ja-Ir '55 a' (YJAA 8:4)
1. Inatitut khimii AN Latv. SSR, Riga.
(Formaldehyde)

ZALUKAYEV,L.; VANAG,B
Preparation of ce--naphthyl-nitromethane and 4-nitro-emc-naphthyl-
nitromethane. Dokl. AN SSSR 103 no.4:619-621 Ag '55. (KLRA 8:11)
1. Institut khimii Akadenii nack Latviyskoy SSR. Predstavleno aka-
demikom I.R.Razarovym
(Hitromethy1naphtalene)

USSR/Organic Chemistry - Synthetic Crganic Chcmiatry E-2
Abs Jour Referat Zhur - Khimiya~ No 2, 1957, 4338
Author Zalukayev, L., Vanag B..
Title Preparation of Epha--Naphthy1nitromethane and Its
Derivatives
Orig Pub Zh. obshch. khimii, 1955, 26, No 2, 607-613
Abstract Alpha-naphthylnitrometlane (I), 4-nitro-I (a) and 4-bro-
M-I (III) were prepared by the previously developed me-
C_ h
tho7d (RZhKhiM, 1955,~ 21C8-). Reaction of alpha-nar thy-
lacetic acid (IV) with phthalic ahnydride (V) vas used to
prepare alpha-naph"u-hylidenephthalide (~rl) which on action
of CH ONa undergoes isomerization to 2-(alpha-naphthyll-
indan4iolle-1,3 (V11)- By nitration of VII was obtained'
2-nitro-2-(alpha-naphthyl)-iiidandione-1,3 (VIII),
Hydrolysis of VIII with kraGH gives I. On nitration of
VT there is formed 4-iLitro-ELlpha-iiaphthylidenephthalide
(IX) which is isornerize'd to 2-(4-nitro-alpha-naphthy1)-
Card 1/4 - 51 -

USSR/Orzanic Chemistry - Synthetic Organic Chemistry E-2
Abs Jour Referat Zhur - Khimiya, No 2) 1957, 4338
-indandiozie-1,3 M. By nitration of X followed by hydro-
lysis was prepared II, the structure of which is establis-
hed by -preparation of 4-nitro-alpha-naphthoic acid (XI),
by oxidation of IX and hydrolysis of II. III was synthes-
ized analogously from 4--brorao-alpha-naphthylidenephthalide
(XII), prepared by bromination of Vly followed by reducv'.
tion with Zn. Rixture of 81 g IV, 81 g V and 2-5 9
CH COONa is heated until crystals are formed, boiled
o
wNh a1c'hol, and VI is separated, yield of crude product
76%, MP IL77-1780 (from glacial CH COOH) 40 g VI and a
solution of CH ONa (from 6 g Na) E 275*ml CH OH is boiled
0.5 hour, di!Md with vater and acidified, Xld of crflk
de VII 88%, MP 205-2c60 (from cH 3COOH). To a solution of
3.25 g VII in glacial CH 3COCH is added a mixture of 4 ml
HN03 (d 1-52) and 8 ml CLacial CH COOH; on cooling VIII
is precipitated, yield 57%, MP 1590- Filtered solution
of 10.3 9 VIII in 300 ml of a 5% solution of NaOH is
Card 2/4 - 52 -

USSR/Organic Chemistry - Synthetic O;Tganic Chemistry E-2
Abs Jour Referat aqur - Khimiya, No 2, 1957, 4338
acidified with diluted CH COOH and I is separated, yield
of crude product 5,2 gl 10 71-7'20 (Trom glacial CH C00H)
To 15 g VI are added 90 nI HNO 3 (d 1-34) in glacial
CH3CCO", uixture is heated 5 minutes at 40-450, the
precipitate is boiled vith C6H 6-' and there are separated
9.8 g IX, MP 2570- IX is isomerized analogously to VI
to get X, yield 7* MP 203-2o4o (from glacial CII 3 CCCH).
From 19 g X after nitration ht:450 is obtained
2-nitio-2-(4-nitro-alpha-nayht~yl)-indandione-1,3 (XIII),
yi-e-ld 74%, mp L65-1660 (frcm CAf COCH), Hydrolysis of
xlil'(analogously to VIII, giye~ II, yield 66%, mp 1j.6-
11 r from alcohol). 0 .5 gr II and 5 ml 80% H2 S04 are
heated for 3C minutes ani diluted with water, precipital-e
is treated with a solution of.?TaHC03 , acidified and XI
is separated, MP 219-220") (from aqueous alcohol), To 2.3
g IX Llid 4.5 9 IIa2Cr207 in 60 r.1 glacial CH3COOH are
Card 3/4 - 53 --

USSR/Oreanic Chemistry .. Synthetic '~-r3anic Chemistry E-2
Abs Jour Referat Zhur - Kilnlya, No 2, 1957, 4338
added 5 ml concentrated 112S04) aiA after the usual treat-
Pient there is obtained X1, yield 25%. To a boiling uolu-
tion of 60 g VI in 1150 ELI CClh Exe added 24 ml Br2 in
CC14, boiling is continued for 18 hours, after which the
tribrom -derivative is scj~arated, yield 581P, MP -20G0.
65 g of the latter and 100 g Zn are boiled I hour in 600
ml glacial CH COCH XI_ is :,solated, yield of the crude
product 55%, i~ 223'-2210 (from CH CCOH or benzene).
From 15 g crude Yj1 is obtained t~ie isomeric diketone,
yield of crude product 14.5 g , MP 207-2G80 (from alco-
hol) 9-5 g diketone are nitrated as described above and
there is obtained the 2-i-.-itro-2-(4,-brono-alpha-naph-
thyl)-.ndandione-1,3, yield 45%, MP 147-1480 (fron
CH3COOW, which is hydrolyzed with a 10% solution of
Naoll to get III yield of crude product 90%,, ~T
91-920 (from alcchol~,
Card 4/4 - 54 -

K-pgp-n~,3 Z t.
~gq -~kqk
ZALUKAYEV. L.: VAILAG M.
5,ynthesis of ci-nitroathvi-f -nltrobenxens. '~'hlur.ob.Mjm.26
no.11:3115-3119 N 1560 Wax 10:1)
1e Inatitut khimij Akademii nauk LAtviyskoy SSR,
(Benzene)

pV-2-1
OX MRS Of
nzl t: -7 ~,E: CA
BAA. R.

PHASE I BDOK EXPLOITATION SOY/7435C
Soveshchanlye po kniall, tekhnologll I pr1nonenlyu pmjZw1nykh
pirldina I kn1rollne. Rio, 1957
4 Kh1mils, takhriologlys I prinenenLys Proilwodnrkh piriJims, I
kh1nolinal materilly soveahchwtya (Chemistry. Techhology
and U-1lizatlen of Pyridine anA qulnoline Z*rivatives.
Paterials of the Conference) RIga, ltd-vo Ali Latviyakoy
&U. 19W. 299 p. Errata slip inserted. 1.000 coplwA
printed.
3pwsorlj%g Agencies: Akademlya naUk LAtvLyskoy SSFk. Institat
kJ11-til VseVOjU2nOyq khlalaheskoye obshcheatvo.
34.s 3. Uzi-&rwvA: Tech. Xd.: A. la7lvlny&, Mtorial
IbArd. 7a. A. Bankovokly, Candidsts of Chemistry, K. V.
TRA"i, C"IdAte of Chemistry (Reap. Ed.). L. P. Zalukayer,
Doctor of Chemistry, " M. K. Kalnynl.
PUMSE. This book to intended for organic chemist* and
chfulds.1 ongivors.
COMRA-19t The collection contains 33 &rt1cles on methods
of synthesix1j*4 or producing Py-141ne, quirvollmo, and
tMe.'r derivatives from nataral ao.r-e3. So prr2onalltle3
A" ilentlOnGd. ~IS;W'eb, Uklolex. end rererenz*3 &-.omp&nl
tbe articles.
BAS,1) 0.11 PYRZD-~z A":) QJ:.%-Otxhx
In.3 3. A-7-v.
aynth.xta "r -- - (1~3tltuto for.
of
Phal.~ C'M ,It O~Ulat"Ork Of ?J,
=11hee
vonpe. 285
A- F" N- P. Tarjt,y,.jj
71,11-i0y"Mnyy Yj-
3XI), kl"O Qto-
-Tn-a-tl ~c 0 On
InatIt tejAlj-C,1~10r. pWtion picture Scientific R~
.sv'&r~'h
I'Mob"It' Of the Alkoxy (phenoxy) ,,up 1,
3#1te A'd " Selts 693~AlkW (PhsAoRY) Pyrid1m,
[.Wo
dr'L Org&-~Lehetk~y
lziNtliuta rybno~ Pr~yshlennostj-.
UznYy Pawhno-jssledo~atej.3,ty ~,hst~t~_,t
?0LhP SWR (D,,,t-ht Of Organic Che, "dukt,
latry
of the hcs&'Jw Inst1tat" for the Plsh-tng TnWitry; Al 1-1!nl,
Selentific fitv0ftr~rl Vistitute for 31
-14 1>1140, Kinistry or the Chemloal I mlflni.h~d Matt-rials
Uenzation If Alky'. Pyridines W1. ndtutry USSR)j Co,
Ke.
.0 )Wide* 203
(Ri-nalay meditainskly
Znst-Wt ')r6qj'LCh,.kOF1) -:.rtQ--A hkad,m_... r
LmtvlZskljr S&ij (R,,p Medl,.1
Organic 3yn'1w&1s.)j The LI.erhatItute; Znstlt~te or
Of SatUrat-d Nttmg.sn-
COnts.lnlr4 x*t*rO~ycljc CQIPIInds for Syntheals of Ge'n.11,
310csclng " Curiwir0ru Ubst&naes 207
zalukAyev, L. P. - m " , I
Lt,'-'Yskoy 6 -f~Xstitut kbimit
na'~A- UDA-.
344,demY Of- 3clencca Latyl SSR.TCZ;-"c&2 :not1tute of' the
aetlor's or it -x1tro~eth,j yak 78 33R)l Syn-hegis and Ft"-
Csrd 8/10 quInoines 223

AUTHORS: Zalukayev, L., Vanag, E. 79-12-22/43
TITLE.' The Nitration of Phalones (Hitrovaniyo ftalonov).
PERIODICAL: Zhurnal Obshchey Khimii, 1-957, Vol. 27, Nr 12., PP. 3278-3282 (USSR).
ABSTRACT: In earlier works the nitration process of qainophtalone and the hydro=
lytic --,learage of the nitration product in to 2-nitromethylquinoline
was de3cribed. Later the reaction with the homologs of quinaldine was
used and a useful method for the alcoholysis of nitroquinophtalone
to the esters of a-nitro- a - (2 - quinolyi)-acetophenone-o-carboxylic
acid ware worked out (see formulae). In the present work the general
application of this reaction with regard to phtalones of the 2-methyl-
pyridine and 2-methylbenzthiazol is shown. With convenient conditions
the authors obtained nitropyrophtalone (formula IV) and nitrobenzthia=
zophtalone (formula V). The compounds convert to alcohols when boiled
and with Alcohol influence they convert to the corresponding esters
of the a - nitro - a - - substituted acetophenone-o-carbon acids (for=
mula VI). In the case of a solution of nitrophtalones in alcalies with
subsequent acidification of alkaline solutions it was possible to se-
parate in both cases the correaponding nitromethanes with a heterocyc-
lic substituent (formula VIII). The structure of 2-nitromethylbenz-
Card 1/2 thiazol., which was obtained with a good yield and in the form of yel

~The Nitration of Phtalones.
79-12-22/43
low crystals, was proved by its conversion to benzthiazol - 2 - car-
boxylic acid by means of sulfuric acid according to the general conm
version of pri-mary nitro compounds.
There are 4 references, 3 of which are Slavic.
ASSOCIATION: Chemical Institute AN Latvian SSR (Institut khimii Akademii nauk
Latviyskoy IJSR).
SUBMITTED: October 24., 1956.
AVAILABLE.6 Library of Congress.
1. Phtalones - Nitration
Card 2/2

% , r, .
Y f r"4~
AUTHORS: Zalukayev, L., Vanag, S., 79-2 --.4/64
TITLE: Some Reactions of 2-Nitromethylquinoliiie (Nekotoryje rn-aktsii
2-nitrometilkhinolina) 1. The Salt -O'ormation and ~;ffect of Ha-
loids (Soleobrazovaniye i deystviye galoidov)
PERIODICAL: Zhurnal Obshchey Xhimii, 1958, Vol. 28, Hr 2, PP. 483-486
(USSR)
ABSTRACTs The mobility of the hydrogen atoms and the great re activity of
the methyl group in 2-iiitromethylquinoline admits an easy'salt
formation, a good solubility in lyes, as well as (at room' tein-
perature) an extremely simple substitution of the hydrogen atoms
of the side chain by chlorine and bromine. The formula
CHBrNO 2 is ascribed to the monobromide, since
the following reasons indicate that the halogen is aromatically
bound: the compound is easily soluble in lyes, here it in al-
ways separated unchanged after acidification. The bromine is
easily cleft off by the influence of benzolchloride. The ultra-
violet spectrum of monohalogen compounds is according to its
Card 1/2 character similar to that of 2-nitromethylquinoline. The power

Some Reactions of 2-Nitromethylquinoline. I. The Salt Yormation 79-2-4z./64
and Effect of Haloids.
of resistance against eyes must be especially pointed out. The
behaviour of chlorine- and dilialogen compounds is analogous and
the bonds to the carbon atom are also of aromatic character.
The introduction of halogen to the nitro group weakens to a great
extent the basic character of the quinoline ring. The halogen
comp-unds of the 2-nitromethylquinoline are very weak bases
which are not soluble in diluted acids. The preparation methods
for potassium and ammoniumsalt, the mono- and di~lalorllen deri-
vates as well as the chlorine-bromine substitution ard all spe-
cific data of the comoounds are given. There are 2 figires, and
2 Slavic ref~.-r,_~nceq.
ASSOCIATION: InstLtute of Chemistry AS Latvian SSH (Institat khimii Akade;aii
nauk Latviyskoy SSH)
SUBMITTED: January 14, 1957
AVAILABLE: Library of Congress
Card 2/2

5M
AUTHORS: Zalukayev, L., Vanagg E. SOV/79-29-5-49/75
TITLE: Nitration of Phthalones.11 (Nitrirovaniye ftalonov. Ii.)
PERIODICAL: Zhurnal obehohey khimii, 1959# Vol 29, Nr 3, pp 1639-1642
(USSR)
ABSTRACT: The present paper gives results obtained from experiments
made with the purpose of nitrating quinophthalones, that
are substituted at the pyridine ring by an alkyl radical and
that have the general formula:
As in the case of earlier
attempts of producing nitrophthalones (from p rophthalone,
benzthiazophthalone, quinophthalone, Refs 112~ also in the
present case the reaction ran smoothly and under mild condi-
tions. The derivatives of 2-nitro-2-substituted indandione-3
obtained undergo an alcoholysis on temperately heating in
alcohol and form eaters of a-nitro-a-alkyl quinolyl-2-aceto-
Card 1/2 phenone-o-carboxylic acid, wherein the radical of the alkoxy

Nitration of Phthalones.II
SOV/79-29-5-49/75
group norreaponda to the radical of the alcohol used.
Hydrolysis with sodium lye leads to a-nitromethyl-a-alkyl
quinoline. The experimental part describes the reactions
carried out and gives physical ane analYtic'92 data in the
compounds. There are 3 references, 2 of which are Soviet.
ASSOCIATIONt Institut khimii Akademii nauk Latviyokoy SSR (Chemical
Institute of the Academy of Sciences of the Latvian SSR)
SUBMITTED: April 16, 1958
Card 2/2

~
- _ YAN
,-- ---AGr6+Waga p E. ] (Fdga)
Interaction of 2-nitroindandione-1,3 vith formaldehyde. In Pqwsian.
Vestis Latv ak no.4:123-126 160. (EM 1W)
1. Akademiya nauk Latvi koi SSR, Institut khimii.
(NitroindandioneTB (Formaldehyde)

5. 610
AUTHORS: Zalukayev, L, 11. Vinap-, E. V.
TITLE: Soinc, Reri0Jotw oi'
Reaction WIth 0. , 'A] ed K~Aolv"."
PERIODICAL: Z11LIL-nal I(JILI)III, 19('-10, Vol ~7~0, NL' .1, f)[) 14'1~-
111'( (USSR)
ABSTRACT: 2-Nitr-omet11y1qLIlr)011ne was heated with chalcone, 2-
nitroinetiiyl-lt-tn(,-t;li,-.flqui.riolltic~ with cha.lr--one z-ind
acetone and derivativea'WI.th F-,enei~aj fOrITIL11a (III) vorece
obtained.
k' N02 Cliff
I-C, If-(1111-5CI12-colf'
Ito - 11, G'If,. It, - C11"
Card 1/3

Some Reactions of 2-Nitr t~ lquinollne.
,qrsie Ly
III Reaction With a,/
-~-Unsaturated Ketoner, sovIf zo - i -o/y8
The reaction is reversible. -Nitrobutyrophenones 'aith
bases (phenylhydrazine, p-nitropheny1hydrazine, aniline)
can eliminate elements of 2-nitt,omethylquinollne; a:3 a
result, a quinoline derivative and chalcone react with
amines independently from each othev. Spec Ificall:1,
phenylhydrazine with (III) for-tri3 1, 5,5-tvipheclylpyral-
ozidine.
C611"Cj1=Gj1GoCJ311r, + N 112N If-C,dir,
c"114C 11
N--C,11,
2-Nitromethylquinoline with p-nitropheny1hydrazine forrw3
the addition product (IV).
1-(;112-N02
N (IV)
Card 2/5

Some Reactions of 2-Nitrometnylquinoline. 't'll 7)0")
III:. Reaction With C, "~-Unsaturated Ketones SOV/'79-'Q-1--'zO1-(C'3
-Nitro- -"'-("-~7,.ethylquiriolyl-2)-i~
~,eacts 1-11 t vo -
but-roptionone w, 6alnerl Ln 90% 1 1 (11p
u i8o ly i 4-el)h b Lit -V ron'r-enon~,,,
n % Y161(1, P~1-152'
13-p i 1'/~ "110w Oryst", IL, Irp
(Y
150 1510; 4-4 of ~---riltr,om(--thyl-,I-inctiiyl(.Itil.t-toline wais'
t,ken as stat," i np, mat o- r L a I'Y - n i t ro -n - n L t Pophen I)-
i '~~o
phenylbuty'ODhenone (0.85 ~, colorless needles, mp il-
9- g of p-nitropheny1nItcomethane was taken as starting
P
material). There are 5 references, 2 Soviet, 2 U.S.,
1 German. The U.S. references are: E. Kohler, J. Am.
Chem. Soc., 41, 1738 (1924); C. Allen, M. Bridgess, llbl,."-~
51, 2153 (19129)~
ASSPCIATION: Voronezh Agricultural Institute and Institute of Chemlstry
Academy of Sciences of Latvian SSR (Voronezhskly 3el'-
skokhozyaystvennyy Institut I Institut khtmil Alk8dowil !j'-jkjj(
Card Latviyskoy SSR)
SUBMiTTED: JanuavY 5, 1959

5-5610 77880
010V/79 -70 -2 -1 Alp
AUTHORS Zalukaev, L
TITLE: Sol"" 01* 11. The
1-Uth i"clizoYt (;hjovld~~
PERIODICAL: ob;-,hch(2y lchimLi, 1)(J0, Vol 30, Nr 2,
Pp '--,00-,)10 (11sSR)
ABSTRACT: I wa.,, ficated wit-h benzoyl
chlor-1(1c. The p!,oduct, corve:srionding to formula II
brip 1'.6-151), walo obtaine(' in 601f, yield.
+1120
N~,
S, od I urn methoxide soiLition) reacts with II forming
methyl benzoatle and quinollne.
card 1/-~~

J)" qu Ltl(-) L110
11. The SOV/Y)
(j - 2 -
/*
12 j-NaC,1
IiJA NOC(W,11.
N
~Acid i!~ hy([L-Olyled With HC1 ai d
or'l dlotilllation. As a t,esult, the
~I.Cti',Cffl 01' b1-MZOYL ~' '1110PIde 'Alld '10diUM MOL11OXI(le prOcced~.'
...11th of' If2S04
t-eact,,~ w1th 11-he b(2n',,OY1ZitOd T)1'OdUCt, Corming a iavLre
DI'llount ol' ben,,~ol,-- acid Lffld a COMOOLInd (mp 1560) which,
accovclLnE to Its nitt-jEen content, cocresponds, to
ac Id ELL (mr) I dec Benzoyl
~!1110vlde L.O.,-IctL; with LI-~,)".t.,~o,,rietliylbenzothlazoI
ormIng, compounc' Ell (mr, -11~21-11~,~C))

Some Reactiont; Of 77880
Il. The Reaction With Berizoyl Chlorlde SOV/19-30-2-31/(81
1-C.0 N I I (I I 1 013 NOCOVolln
N
Jill) (I V)
Ni.tromethylquitiol trio li,,) wa:; reacte(j with acetyl
ehlovLdc (5' rnl) and compound VII was obtainc-d (0-45 g;
inp 146 - 1. 11,90) .
N
(N M
Thevo ave 5 veferences, 11 Soviet, I German.
ASSOCIATION: Voi,one/h AgriCUItLIP,'11 ln.,,,titutc and Institute of
Chemistry, Academy of' Sciences, Latvian SSR ( Voro-
sel lsko1(ho2:--.-jy.,,tvenriyy Institut I I.n,,;tltut
t1,11-1k 1,9tv1W',~40Y ",SR)
Card V'

YANAG. G.J.; WMICS, N.J.
Llebormann reaction for th* nitrome group. Zhur.*b.khim.26 ne.5:
14oo-14ol MY #56- (KLRA 9:9)
l.Latviyakiy gosudarstvauriy uidrarsitst.
(Lisbermann reaction) (Nitrove group)'

FAIR V W m
o 0
R o a foe

a I ill it Q if it if ill v 18
! Ji 10 31 U 0 ill A 1111i IT ill 19 X 41 44 44 0 45 0
t- a -IL I _,_ 11 -ii-A T I _M_ 0 -IM op J j
4
1-0 VIC-1111s. -
. 00
00
..AD 0
Tho forpstation at nitragett-subsilifultril phtWinUdiff.
Guootal, VAImp, 'I'i. I'llw. 1~jfr.jrov'sf, Am". I. is. as- 0
00 Sit. 4 No A kits C-,,csimu, 410, 2t; in Letti,h. 4""

' Ht P- 1-1,%, kj.
.00
(3. 1 S. 1. 7.4 S. plitUse osahyclsi& and 60 m
Aultic w.bfphl,t1vl% 1. Soon', hn1j.
ritflusird iu an air cuadymwt log 4,%-&) Min.
AcOll -11 It"liv, b."', 1 '141 .,flw follwlO,l. -00
00 .
slir Amid a 0.5 cc. samplc boded for I min, showomf & YvUow P-11111111111M. ftws, I, ll,Nt,*.Il,j*l,,

00 SI
It minfowticti),or in Xrc-vts%,,I,or w.1soxivil thr prs-mv of -1. %lilt 41111i'llill III A"(M;
; it. with 4.'40 .. ~ 11-11.
: ft.-m A,tlff. 0 0

* ln.,oxhl I., a 1."I .."A I)l.-mighl Ih, vuld of It.-IlI ...1141,111hirl.1
:r
:4 -k I I,
N I'll "a, III A-illf.
11
C ~It; fl,,Ill %,fill. ..
,
.
,
04 A ..... I d11,1111'. lit'l. f"." 1. 1-1-1- .. to, I......... .
till
%
41
1
11
.
1
1 I
1 0

phil.A. .%,q,N. ."d SO .
,
,
"
F ...
1
- 1g
.
1
.
to"".
%~11111 Ill mF I"I In ...... h
1
1".1.4 sttih L'ift, 117, 1. 1,11"IN111 1" A WAS . to,
.
l'
1
11
NC
a
V,mg ovillict im-th.4 V, iliv fidlustring 1'"11 P-
I
OL"ll
1l- I-AIIII-d P(Ill-VI'lk, Sim
A . it.
N It h lilt..

. it)
INS Hill) An't irdhow tiovill... All A.4111.
boom p . .....
00

l limm.d I-th plaf- I-m A01111; 1,9111"t
11-Al,,. ill 1, it off. 11, L~~Ji e
=00
00 Ar 1" 1,11 Ill aml A~t 111. Kfi~tsllltlg s-lh , (r,"ot EM)II
7 Mc, ln~jkl fr,K81 to I..rtc I
14

". .4 sit FtOll
2-1 fly )ph., Fly), b.-ill -01Y14111111w, ill. 13 t '
,
AcOlf. Fit,
0
00 And AcOll. 1,0111t4l I-,Ifg IIIAlt-4 F11111. 4-thyl.
7 fine nivll,-q m ill. .%,()1f; p.pf
11, %to
0 0
, " Floor. ~,t than lite
phenyl Isom p-, thimidust. fit. 17 .
m IA.;
boom 1 1441: 11. piti
#,I
o4-c"I.U. f,wcmd ~slkv it ... IS--- lovnit FlOlf sivul AcOll;
1,6'
1,4111"1
m
oi
ililin
f
t
l ,
(ImIldil 14( .1 ...... is to., 0
-
imit
.
v
i.
.
i
-I so, So,, 111111 li,till
'!V 400
filtill.
111411"; 411111t 1111`11111t 11% 1, ft-Ittl P-st
* .
I.fisti,111 II.,. ('"J" 1.1(ilt
tls%i
1~1, 1%1
.11-11mictlivIldseml.
IOLV,~,l it. 1,11111 Aml 10011 .
.
Nil,, .1, If I-Itill

ImIll o, Is, low, it, ~.4kf , ~11 Ali Al-Oll JIM -Iixhllv .

m. 1311 -fill
I'm lot"d in Al, -
s

-1 All F14 'it. )w%am"Ital plific, m PlOIL.

,
s
" .
I
1,
fit, ......
-
. :.
11-11 fit 11
,1 'i
lot 111"11tto.
JA%M it solIALLtIPGOICAL LIT1114144t CLASSIPICATICIF ill lot %,tllr. "%,Lj'.I,. s 00
F

t 11"J -IF J., 41.0
T
'
-T

o 0
EA uis A V W)
"t"I'DON an Ke K a it It at As, 5 At a 1 0
Ifis An It 1 0 Asof a '

l
0 0 0
Is 00009:00000 a
T
'
l

A
A
00
2
00
so Ar
of
0
00
00
00
00
0 W
0
00
-4V
It. 11 13 W li. 11 11, Is a
L A- A. Y a 11
--------
Seisgralke of iswis"ty. qectinifftry, and Tortlary Am-
Inc. Whit the Aid of 11hillalle Anhydride and 2-Nitra-
1.3-fallanedlesse. (In Russian.) G. Ys. Vans 7h1dr-
ltal Obohehei Khimii (Journal of
try), Y. 1709), Nov. 1947, p. 2080-2088.
~;ivrs drtails of a method claimed to be hiTrior
in some raiwa to previously described na-t s and
to tK' Just as OppliClIbIC to 41iPhMUC AN it) Aromatic
amlim-s. The method wait ronfirmM by xisplicntion
to typical mixtures. 15 ref.
S L ACTALLUVWCAL
LIMIATIAlf CLASUPOCATMOIN j
I
U is Aot 00 1 zi 411 ill OW Gov
- I Kitft% M A I "' 9 1 W a
o o o 0 o 0 0 0 : 0 1 0 000000 404,
!!r!Ooo 060*0 00000
o 0 * 0 o 0 0 o o 0 0 : 0 0 0 0 0 1: 0 0 0 0 U 0 0 * 0 0 0 :0_4 o 0 0
100
Vo
'00
196
109
V 0
*0
zoo
00
VO 0
!q0
too
to 0
too
If tool

Ultraviolej gthsor-69- appetra of 2-nitro-1,31-Indarldlone.
11 - Riduss. an-'SQi_"p. - Lotrijar PSR Zindinu
_'G. Vams
0
T
R
,,
WNo.
toe No.
w to c
-5), 21-10(keisslian
summary, 30-40)..-Absorption ipectra al' '_'nItro--J,34n-
CU, 0-" VqT dandione (1) unit its %alts were (Irttd. In many solvents. In
highly dil. aq. soln., the nitroindandlone ion Is the absorb-
ing agent, and can be relwnented as a m5a, ance hybrid of
3 out of a no. of possible valence Structures. III solvents of
low dielec. consts. such it-. ether and (Jim. ane. in which the
energy of shifting of thii citctions Is high, the tnol foTni
slowly tr4nifers Into the likoo fotni; the Wo of reaction lo
10tial to the diclev. const. In 110)4, the ab-
Is by a mol. forin of 1, characterized by it superpo-
=1
sition of 3 other electronic 3tructurei; this form Is an Inter-
mediate between the diketo and the enol forms. The
spectrum of the Et ester of the indandionecarboxylic acid had
-analogous form, but with the absorption max. shifted by
760 A. towards higher frequency, which can be explained by
structural considerations. Salts of I became colored on
storage, and the spectra Indicated that thizi Is cuused by Jet-
tramoll. shifts, A decrease in the Ionization potential of the
cation facilitates the formation of structures which absorb it'
the visible. The high ionization potential of IIg prevent,
formation of an ionic link and the salt of Ifg with I remains
g~zla
~
colorless. Arguments in favor of It bonding in I a' iv
'
'
' v
'-U
A. D.Vni
ks
~ 'W7

Condensation of 2-idtio-1.3 in4andulne with benshy.
drol. Vanal, V. 1. I'Latpittv, mid M. A. M,
t Ahift. I). C-ell- L111111 1 19,
1.15 g.
41) it 1011(") in L:. mi. jl~'Ifvs hr. Vvc
42-Sea' I-xdrv-.'4pi' fill;. $Is. lip-,
;."4)* (huln LIOJI); .1 31I.X% prIll is (lbulibird whril
Mull 6 tued for *Wvcnt alid iAHJIC I'll,C)IOLt .11*0 IUM11,
Olactal AcUll gives ill 5 lrfin~ 14V-; 4A a I,r(,dLbcl if). AIJI '.
The pr(Illuct is ustaflectect by but cmit'l. 1119J. unl'...
ChArring is lottlifitt'd; 1.2, libio. it.,& uldy A *light .1,
Cwtilig.camitatrcilux.
11 ith 2 g. PhNil, 3 his. gave I g. phthAlifill. fit.
fit (3g.) dksmAvesill 30 Till, of Nfe(JS4 lin Mcoil and
UP013 dilli. With 1110. LLIEV40011, and whin. ul IICI yield,
moomic, in, IM-4' thout litoll), a~ %tit as all
Imbilapste, its. CKI*. 'Allich ppts. ul-11 '11111. uf tile filtrate,
%itb 11,0 mid IICI, tile AIJK)Ve 11.11JIMI(XIIIIII011C JO-15 S-j,
tf`CJttd 'Aith %391111 5q MOUNd-SICOlt Until VPJIl. IlAfk
ptAcc and let stand ovemight g4ve the V%j i-sis. yellua
11MIRCS, 3,14. In HO'. 11 Ill is lxnlkt with 5'C' %IvON4--
MeOll 4 his. only a simill atia. 4 tile tl.&phtluNluuujuv
dCfiV. fUT11111 k.EIKI. As almvrl while A61311catioll t4 Ow
lituatc with IICI give% hhOlOhNih. tll~ G~Itl , INt
cr"td. frurn ht0li Aith A little IICI; rvpc4ted crybui. I
xi a pwc oduct, rus. 74)--l *. 'I fritment ul Ill %fit)
'ics
Se
aq. NAOFII until wiv. twcurs, follu%rd by diln~ and
addn. of IICI until give 4 g. 1.4f, Much "sill
HtOll g-AVC Ph,CIICII,Nlh, title tile Jjjsr..t,- jil.,n evji)jl.
and sublinlitivit gave ke~ductjull of
lllj.CJICJl,.NOl, by Za-AcOll yicl,ls the msno (w-pi-
detected by the vilAct 'VIor Il,.1 -ith bigild"'le. Nfih)
treatment of Ill with idti. ukill apj,,.ir% la
yield 0.1% C11 CH(Nol) COC.11, Will. which I'l-m J~ .'
cheesy solid oil avidilwAiun: howeva, fill vfy,tri. tFf
CvApfl. of its M.1m. tile A'i'l Ol'tri'tur valli'llu, .1ild (11.

mMMw%,,i us, oam

/ 01
C~4
itte condensation of I nitio.1.3 lnd&ndione wark brissny
drol. G. Va. V&nag, %*. 1. I'Lipicre. and NI. A Afat-kali-
Ov.1 tuivian SS.R., RiKA). J. Gen. Chem.
l*,.vs H. 19, IrP43 KIV49XIC1111. trilmlilimil, -Swe C.I.
44 lik-i"M It 1, %1
/?J-7

c
I at atructwe of Z-nitro-1,3-L-tdAwdious aad of its ults.
- - jeand E, Vu. Gisdrinictic (1-2tvian Stair Univ ,
t; Va. %~7
II-3(lq -
Riga?. Chem. US.S R. 19. 155 woXvsigi
tr.T%lati.n).-Sm C.A. 44. 112S-,a is: I... NI,
Id
/ 'Yn

2-toilo-2-altro-IJ-1adamillone. 0. Va. Vanag anif
M. hi Li n. PekWy Akad. 64,
M-459411m.repti. cot
which ranutit be pf"%I. anahWitisly to the Cl or tit derivs.,
was effected by the action of Iodine an the As salt od the
uilroderiv. It a dry raist. of thew cagnpoccuts Is wanned
in a scaled tube to 130' a strong explitism takes place with
fornmatim of ii-C41MCOW and. apparratir, As fultul.
"mile. If the ittlit-h"
i
i
p".. (1). oil. (IIINIS
C41 I), tthiAbLitile ill up to 701"; ithis; cycl, an execs, W
iodine falls to give tiame "AallZie t4mversion. I gives
yellow sollis. in roatit Orit. solvents atid Mimics Witte im
Vranning in it"In.; at 145' 1 turti% red affel CY64VTS itithlic, a
falter" millplele at 165". leAvial All hulille-ftrr lisairti-Il.
"4. In 1110 with am ItAt'llon. aplialrotly with fititlialion
o1 O-CJI,(COhO. nmtvrrtftl to the scid with If,(). daJ 01_
ninhydrin. Treatment tit I with sq. KI leads tofortualion
Ci huline in It quant. teaction, with the ratlical of the 13itro.
ituUndione formina tile K %Ali (U): the a1mve twcurs,mly
ill tit-"its for It. ctmml. aq. KI their Is Nnuril a ppt.
.If .14ok twe.itrit tit Li Amble "It. Us-Kl-h. of the Alit-ve K I
%alt with KI and ballne. I teActs with Nal.%()i with
evoititital 44 loditle tall, ill excess thlosulfate), VIA iaitLII
binding by the thimitUate of the p%cudolulklen Mdk-Al Of
the nitrointlandione. and only dier conlitkdoll 4 thit-
step dtles the umal 1-3-line-thk-wallate reaction take plaer.
Weak alludi also litwrates Wine train I and till Later Itt
ftil. its excess at the FrAscut. IttIlling I with 11.0 yiew.
nitrointLitullimme and 1101. The following prepts. of 1 6
more satisfactory thoss the seAltd-tube procedure. Cool-
In, a IK4n. of 3.4 g. and 2.& j.
Ag%*Ol In 0110 ml. 6AHnS jItO ykltb The Al Still, which
ppts. progressively In 3 col-xs- Yellow. arance. ovul finally
white (I he t4t I er tslcA.t stible, 1041t 411Y '.(I IW 3 (IN at
Its uw.1 ill lite prrIm, 1. VieLl 41r~, 4.1.1 111,
u3Ay Ik- frr-jvrr,,%I If,mis the u4n. tw4y. .1 %. I. I; tile .kit
salt itrrotnp. vismou-ty at fi-ttuaiij; motalli, Ag -.1
o-C#II,jCO)lO. The As -III tit 6 X.) awl U., It i-minir
are thormighly trituralr4l aml It-ft 1--g 5 IIAV. III A ch~'I
tesittilm. altef trtFilurat i.wl a lid fill I hrl a I '21day"ItItIl'i
ins (.~mupirle i-Laitlicatt,"O And rtia, ill, Imi C.11., tit. I..
is obtablol m miliag 73 ",;. 1. In. 1*-14*; 10,1111- mlltII
may Lie tibtaitted Inmn tile mAti. (U'ly. V, " its C.141. ThI,
C6114-111". lmmtii)fl citut'li"I 401ur marrActVil Ag Lill. r%
tractable by lu)t 160. and 14 4 K. AsL %I. K

VANAGS, G.; LIFH6NIS, X.
quantitative analysis of salts of 2-nitro-1,3-indandione. Kim. Irist,
ZinAtnisk, Raksti, Latvijae PSR Zin'atnu Akad. 1, 78-80-150.
1 (CA 47 no.19:9865 153)

; -l", ;---
hF.- - -
P Mlmtfll~ -0.& 1 a ~
~.. 01 % " 91 f
R ~i
I Mm
w i
-f .1,
111-1.1 MAIMIN, ~i
- - Oft. Im -". . ~~M
" N-09113"', mi-5m.
fwl

VANAOSP 0.

AlkylatInn of 2 V* V;uf-
Chemical Abstracts '
I.zl
tViatt vf, C.A. 42, 1,70h. -

Rw; 25, 1954 (1), F.C;t\- cr~qjkl, fimll dc fit.
*
'

Organic Chmmistry t,,J,,.ttt,j rt~-(-TY
~O~
1, Olhi~,,A
11*I. rellmilig 1, lira, -I ;I wit"T 1, till (I
Qqii4 .) 2-mititt"(1twmit: j Ill all'I 4 g, (2 , I M,-I ill
W g NIvOll, dilg. Isilk 1,24) ml~ $1;0, fill.fil)g It],'
flk,ukingit bilmillilg(lilti. 110'and wilb
MUM,
It lit MrOll. 1-1011, Atit(M.
CIICI!, NJ,-,CO, C41" 111-1 ght ill"lf-DII, I I/Ch, [off &.14,
(hydrol, iu-; lit I 12f)). 11aluixtulim"plifliol.,f Ir'll-lidn'.1
Yi',-Ifi it moll-NIt. ficriv. R4 lv;m 2 IMN, O"mi,10-
jr,wrrnr (111), ullt;tilwd ill 2.2-g. )-irld I,% ri (1116sil:
8 )ir,. list ;I ivatrr hath 2 g. ( I e(Iiiiv.) 11 ;md I g- (2 cfltdv~.]f
Ell lit S fill. abs. EAW1, browit crv,lal~ I'mm Ar., m. 79-
(1f,! fliqlar r;j[i(j 1 :2 (till not Vidd Ow t ~pi Ord di Ft fl, ri% 4
The compd. lit MeOll, Amf Yll, VI 0.
Ali,,-CO, CIICL,, WN, and gheial AcOll; Ki!f,f "ith I,i,,- i
.dow.- in gladal AMU it gave it Krtcti volor Oro itidii;,lt . .1
~ecoflllary amim,. 214S-eflt ohtai!z~-(j j!i
0.2-g. yield by Itnifing I lit. ('11 a wMer b.011 %vith [Ait%.
citruletised and later witifout a com(( tim r 0.3 g. Ill if% g.
Chits :till[ 2 g. AcCl, nt. 105" (from uk.j. lp,

g
W~ IV, I I
11 ~lq
wim"llim
't- I
, 1 -H ft
a

",roant few amines. .11 ~14~ ([Atviin
14MV. , r. Amt. Andl. 909M).
., U.
1 an~ ortoft&ry aMnalle Itrablo
-Contme, fonts, a PnM7
stoup pladuce a Lot" feart with 1111itflus ffillifflA. In'
toost cows the color b yellow or oranst. Aslisneousin4-
lWerbl, wood mn be used or, oh" is mom conytMent
paper. preferably newsprint. The rwilm is I"I rarritif.
out in dil. 110, glacial AeOlf, of an sk. solo. contil, a drop
u( cooM. 110. -Acyloted andurs do not give a pan. test.
III Sonne came I . phttlyfebedismints. i0mim can I*
diffematkUd irUt' the color diffmnev. Appro%. 1W
mmines, their specific color and limiting canto a listed.
iW rtefameh

A

0 IST A*V IND 1.0 AMC St.
PROC11116 Aso 010014119% *Dig

et
0 -4P 0
0 10 41
00
00 2959. QUALITATM TUT FOR ACMUPHTHM. -V Um P Go.. ra M and
ch
b
j
S
x
i
l
0
l
i
(
1
h
em.
. Ana
Ulukaeva,
. A.
z
. Am
.
, vo
.
m. (
', 195
. 5,
416 315-3181 abetr. in Chen. Ab4tr.p 1950, vol. ", 10605).

j!!~ Boiling a solution of 5-Aitroseenaphthens In glacial AcOH In the
si!~ presence of Fb powder prodixess a green fluorescence. This "if to
Z

e0
reaction, which has a giensitivit of It2,000p000, is used to detect OO
A
acnaphthene (I). To this end (If is nitrated with HNO or a mixture

rt
t
t
T
f h
I
d H
t
b
d
3
l
4
60
s o
a m
an
par
s.
wo pa
x
a are com
ine
ur
of HK0,%
2
4
00~ with l"part of H20 and the product in used for nitrating (I) in glacial too
Q

cOH or benzine. The nitration product is diluted with H 0, the pot
-90
formed is filtered off, dissolved in glacial AcOH, and bZed with
Fb powder. If there in no precipitate the nitration rroduct is ex-
J; tracted with benzine, the benzine is removed, and the test finia4" %0
3106
as before. Very small quantities of (1) are n1tratod preferably rn
benzine Anthracenel, naphthalon phenanthrone, fluoreno, biphoWl,
perylen;, A2--thy2naphtha2ene, 0:
I 6-dimethynaphthalene, diphenyZeno 500

~L SRTALLUP~XAL LOIN&TWE CLASWXATNW
flow 91"Raiv. Vj*M 60414,
t 141400 "to Ogg Ogg
" flital a" a-- set
U ig A, 0 Ll

,
Y
I
A FW I I a a I
A I I
44
-0 0 0 0 0 0 0 0 0 0 0 so 0 0

so
0

go 00
00 oxIder saphthalic acid anhydrido, #to. did not mict, Nor did other 00
400 derintives of (1) give this reaction. The presence of these hydr-o- 00
carbons severally or ombined did not Interfere Ath the test. Gon- 00
j did not Interfere, HN03 destroyed the fluor-
centrated HM and H2Wj
ba
itric
l
Onale
Lc
did t
d
H
0 00
0 0
e ser
nso
O
esconae as
o a
egree
# c
2-
,
,
2
tArtaric, and succinia acids did not Interfere. Glacial acetic acid 00
could be replaced by propionic, butyric, lactic, and monochloroacetic 0`0
acid. Di- and tri-chloroacatio acid vere unadt&ble. 00

to
*0 so
so o*
0 0 00
00

COM04" Sftft Of
NI'm. Acd- *i - ww"A
I kd' -T~R. 71. 4 ct. CA. 44.
tmlb -, A-Idn. of I-K1 soln. to an sq. Oak. 0 K deri".
of coth(COUCHNO
't (at).
Wt it Affen pkt pf. form. wkkk milify, kiwi
10 on czVouts to ⁢ drilm life vat"O Its VSVOW- of Is. the
prucluct a blark powiler with ire" luster. whh-b Ilmrs Is
c"1 walming, still Ila C'MOPH. Approllumiso
wIwfwAIsIb*Ktkt1v,ofl. TheNaderwollcoultin
be prvpd. sitaiLstly, but was prepd. by addis. of .11
Is to cofird. Iota. of Na defiv. of I followed by standrg 9~
h-. In -PP-mrance and Ittisavior It Is aintikr to the
abo". On stomilic In lik the empkz lam I atorn of I
fortning A4.K1.1j. The pmdon obtained by The action
tsf plestil. If apraimtes lho mnpa. A " I which on
mituding In air omts Asti. Sunilar Most. Xed Allah
A.-Cals,jls (where A Is the CA detiv. of 1) and the Nil:
10114109. All M11,1.51o (whirre A I% ibr Nil. detly. M 1)
rrmlts in analocom unstable lsoildo. the Nil. "v. dr-
111"T7". cqxnpkttly an esposure to air. *Idkng The NIA.
Ifm oil Adan. of vadow salt wins. to tbrw. complexes
'his;
w vlorvdalightlysol.pilu.1 thin, SO still# give a tkep.
y
violet IZIIWWb on IN# pilloslint Is emynird to life
VW* tiv. of 11. he sells give it 16ky bnmu W.;
byielliscimerrymcIM. Other catkwis fail tarivr ek-*O.v
defined pcodorts. Generally thr. nutst stable C01 at%"
am thcome tw-l-Irs 4, the I*Iklr of A "",41. ok. Itil,
at vtt- of ttw nwtAI iarrmwe. the itmitples twhility de.
Cline.. C.. 361. K-lapoll

1. MAGS. .; ZALUKAYEV, L.
2. USSR (600)
4. Indandione
7. Reduction products of 2-nitro-2-benzohydrylin-dandione-1, 3 and benzohydryinitro-
methane. Latv. PSR Zin. kkad. Vestis 5, 1951
9. Monthly List of Russian Accessions Library of Congress, January 953. Unclassified.
-1 1

1. VA?1013, G. - TAN-TT-3, '".
2. 7133R (600)
4. Indandione
7. Interaction of big-indandione with iodine. Latv. PSR Zia. Akad. Vestis, no. 7, 1951.
9. Monthl List of Russian Accessions, Library of Congress, April -1953, Uncl.

I
VaAGS, G. - ___71 -VS. L.
...- , 1--,
Products of reduction of 2-ni tro-2-benshydryl-1.3-i r-&md low axed ';-enzhYm:~-71-
aitromethane. Iatvijas PSR Zin7atnu Akad. 'Idatis '51, 753-6. (KiaA 5:io)
(CA 47 no.22:12332 153)

L I I 1~1 -
IC3- fff,,)O, - f -. 1--, IIJ-1;
IM', ; i_ - - --.X;0kN. aa. tal. ~f I- L-

kwla-M--.9 wIll
------- - ---- -- - - - -, - ,
I k "AN 'N - -,,
ll'o \f 1 3 1
. f,
I
.4

~~ * - --

W1,10,
ON F"t

, , . , -. 4
;, I , 7 . !, I'l , - . V, 111 , 1, 1, .
. , . , q f 1 "

N

1. YANAG, G. ; VANIAG, Ye.
2. U5311 (6oo)
4. Oxyphthalonomide
7. New isomer of nitroindandione, the Jy'-()sn~hthalonimide. Dokl. AN SS~~H 90
No. 1, 1953.
9. Monthl List of Russian Accessions, Library of Congress, April -1953, Uncl.

,~ ~ --- - -
i.' 1 11)

-CT 111 j 1, j,*
vi

VA .MI&S, C-r.
!Lsllmns! nxlnle tit
I 2-JAvo-1.3 ird i7irc
ii