SCIENTIFIC ABSTRACT VARSHAVSKIY, V.I. - VARSHAVSKIY, YA.M.
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96
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December 31, 1967
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SCIENTIFIC ABSTRACT
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CHALIKOV, Anatoliy Viktorovich;
GINTSBURG, V.I., ved.
[Fr(.grairming of design
proektn.vkh raschetov.
V;,JW-)llAUYlY, V.I.,, naul. red.;
red.
1~
calculations] ProgrammiA anie
I
Leningrad, Izd-vo 1114'edrai 1964 113 p.
(MIR ~17:7~
a) L.~r k 'Lc r ju
ACC NR,-AT6022684 SOURCE CODE- tM76-Ob676-67oo-o/-00070-1-5?-'/016-4-
AUTHOR: Varshavskly, V.-I Vorontmova, 1.
ORG: none
TITLE: The use of s!12hastic automatons of variable structure to solve.certain behavior
problems
SOURCE: Moscow. Institut avtomattki I tolemelchaniki. Samoobuchayuqhchiyesya
(8eff -JEF
avtomaticheskiye s StR6fin gautomatic systems). Moscow, Izd-vo Nauka, 1966,
ist
158-164
TOPIC TAGS: game theory, stochastic process, finite automaton
ABSTRACT: The authors analyze some behavior problems for variable -structure stochastic
automatons in game situations. The definitions and notation adopted in the paper are those of
M. L. Tsetlin (e.g., Konechnyye avtomaty I modelfrovanlye prosteyshikh form povedenkya.
--UMN, 1963, vol. XVIII, vyp. 4 (112)). The 2;ero-sum game of a variable -structure auto-
maton with a single opponent using one pure strategy Is considered In an effort to demonstrate
the conditions for asymptotic behavior optimality of such an automatic device in a stationary
random environment. The simplest stochastic automaton version is considered, i.e., the line
Card
L %f,)o6-67
ACC NRt AT60ZZ684
automaton without input. Expressions are derived for the mathematical win expectancy of such
an automaton (Ck). Games by t~o such Ck automatons are considered for pure strategies,
state diagrams are analyzed, and experimental data on Ck automaton assignment game behaviol
are presented. In the case of the nonstationary (random) environments (to which the problem
of inter-automaton gaming can ultimately be resolved) it Is not yet possible to formulate re-
quIrcments as the method of changing the state transitioif probabilities. It Is also shown that
a Ck automaton which has functioned for any extended period of time in one stationary medium
is very slow to retrain itself for operation in another environment. The elimination of this
defect is seen as the k~y to the design of an automaton capable of optimal behavior in nonsta-
tionary environments. The authors wish, in conclusion, to expres..i their sincere gratitude to
M. L. Tgetlin, I. I. aaktskly-Shapi o, V. Yu. Krylov. S. L. GInzburg, and V. A.Volk
for their willingness to take part in a discussion of the problems considered In this paper and
for their many helpful. suggestions. Orig. art. has.- 2 figures, 3 tables, and 9 formulas.
SUB CODE: 09,12/ SUBM DATE: 02Mar66/ ORIG REF: 008
5C2) SOV1153-2-3-20129
AUTHORS: Pozin, M. Ye., Kopyley, B. A., 7arshavskiy, V. L.
TITLE: The Flotability of Gypsum and of a Precipitate With Different
Reagents
PERIODICAL- Izvestiya vysshikh uchebnykb zavedeniy. Khimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, fir 3, PP 412-419 (USSR)
ABSTRACT: The authors investigated various enrichment reagante and reg-
ulators for the flotation or gypsum (CaSO 4' 2H20) and the
precipitate (CaHF0 4' 2H20) to achieve a separation of the two
substances by flotation. The investigations carried out showed
the following results: in the presence of oleic acid (consump-
tion.'750-1000 g/ton) and of IM-11 (consumption: 500-750 g/ton)
the precipitate and gypsum were practically completely floated
at pH 6-5-7. The flotability of the precipitate and gypsum by
oleic acid decreases rapidly with the decrease of the pH value
of the pulp. In the flotation with IM-11 a decrease of the p'[
value leads to a certain activation of the gypsum flotation
and to a considerable reduction of the flotation of the pre-
Card 1/4 cipitate. Thepe effects of the pH value are shown by fil-ure 2.
SOV/153-2-3-20/29
The Flotability of Gypsum and of a Precipitate With Different aeagents
The anion reagent aeroflot-25 proved to be the most efficient
among the flotation reagents investigated. In the presence of
aeroflot-25 the precipitate is strongly floated whereas gypsum
is hardly floated at all. The flotation of a precipitate-
gypsum mixture differs from the flotation of the individual
components since in the common presence of gypsum and pre-
cipitate in the liquid phase of the pulp a mutual inhibition
of the flotability occurs. It was found that a reduction of the
content of precipitate in the mixture leads to a considerable
reduction of the flotation which is due to the inhibiting ef-
fect of gypsum on the flotation of the precipitate. The use of
aeroflot-25 in the mixture with kerosene as collector for the
basic flotation-in the presence of copper salts and the pro-
cessing of the residues with reagent IM-11 in the presence of
trikresyl phosphate makes it possible to obtain a concentrate
containing 29-3(YA P205from the original mixture with a content
of approximately 17% P20 5* In this case 79-80~ of P205 are
again obtained. Purthermore it was found that the use of tri.-
Card 2/4 kresyl phosphate as peptizer in the processing of the residLLeS
SOV/153-2-3-20/29
The Flotability of Gypsum and of a Preciritate 'With Diffe-rent ReaFentB
of basic flotation makes it possible to obtain a concentzate
strongly enriched with P20 5' 2 tables show the results of flota-
tion of precipitate gypeum mixtures with contents of 21.5%
P205 (Table 1), and 17.2A F20 5 (Table 2), respectively, by Aero-
flot-25 in the presence of copper oulphate. Table 3 show's the
results of flotation of a precipitate gypium mixture with 17.2%
P205 by the addition of aeroflut-25 in 4 portions in the pre-
sence of kerosene and copper sulphate. Table 4 gives a survey
on the processing of the residues obtained in basic flotation
with the reagent U-11 in the presence of trikresyl phosphate.
Figure 6 shows a principal scheme of the separation of a pre-
cipitate-gypsum mixture bj, flotation with aeroflot-25 in the
presence of kerosene and by the reagent IM-11 in the presence of
trikresyl phosphate. There are 8 figures, 4 tables, and 4
Soviet references.
ASSOCIATION: Leningradskiy tekhnologicheskiy institut imeni Lensoveta
Kafedra tekhnologii neorganicheskikh veshchestv (LeninErad
Card 3/4 Technological Institute imeni Lensovet, Chair of Inorganic
SOV/153-2-3-20/29
The Flotability of Gypaum and of a Precipitate With Different Reagents
Substances)
SUBMITTEDt March 12, 1958
Card 4/4
VARSHAVSKIY, V.L.
--- Scientific conference on mineral fertilizors. Khim.prom. no.7:
5LL ii 162. (MIRA 15:9)
(Fertilizers and manures-Congresses)
POZIN, MJ4i.; KOPYLEV, B.A.; ,VARSHkVBKIYIV.L.
Various reagents for the floatability of gypsum and dicalcium
phosphate. Izv.vys.ucheb.2av.; khim.i khim.tekh. 2 no-3:
412-419 59. (MIRA 13:8)
1. Leningradekiy takhnologicheekiy Institut imeni Lensoveta,
kafectra, tekhnologii neorganicheakikh vashchestv.
(Gypsum) (Calcium phosphate) (Flotation)
POZINJ M.Ye.; KOPYLEV, B.A.; VARSHAVSKIY, V.L.; PINTERy I.
Crystallization of calcium sulfate in the reaction of monocalcium
phosphate with sulfuric acid in a phosphoric acid medium. Zhur.
prikl.khim. 34 no.11:2384-2390 N 161. .(MIRA 15:1)
1. Leningradskiy tekhnologicheakiy institut imeni Lensaveta.
- (Calcium sulfate)
VARSHAVSKIY V,L.
Interuniversity Scientific Conference devoted to the development
of the new methods of manufacturing mineral ferti4sers. Zhur.-
prikl.khim. 35 no.12t2805-2806 D 162. (MIRA 1625)
(Fertilizers and manures--CongreeBes)
TARS ASSM, V. LW
Interuniversity Scientific Conference of Departments of the
Technology of Inorganic Substances devoted to the development
of new methods of the production of mineral fertilizers.
Zhur. VKHO 8 no.23221,222. 163, (HIRA 16:4)
(Fertilizers and manures-Congreases)
ARNAUTOV, V.T.; BAIMOV, V.11.; MNSKOY, S.A.; PASTIO:HOV, A.1.; SMU111,01,P L.A.;
TOPSHILOV, Yu.V.; TFITIYAKOV, PDOVENKOP V.G.; FPEYI.TNZCJN, Ye.Z.;
SHGITIYJIIIIV, Yu.S.; Prinimli uchastiye: IAAKAYEV, 3,V.;
G.M.; NAGOVITSYN, D.F.; NOVOWDSHY, P.I.; VARSHAVS IY V.L.-
KOROGCDSKIY, V.G.; KLIBANOV, Ye.L.: MEDVEDRV~kiKll, Yu.; TAIANTSEVA,
T.I.; IRIBROV, N.F.; NEIMAN, SA.; TOPYCHKANOV, B.I.; CHAMISHNIMIJI,
O.A.; YMARITONCIV, Yu.A.
Developing and mastering the technology of converting vanadium
cast iron in oxygen-blown converters with a 100 ton (14g) capacity.
Stull 25 nn.(,:,jo/,_rn8 Je 165. (MIRA 18:6)
1. Nizhne-Tagi_Ll5kiy metallurgicheskiy komb-hiat (for Maksiyev,
niyets, Nagovitsyn, Novolodskiy, Varshavskiy, Korogodskiy,
Medvedevskikh, Talantseva 2. U, ral 1,3kiy nauc lrn-iss 1 gdv,-j;. 151,
institut chenykh tretallrv (for Ifubrov, Pzerriyayi, TopycI!kuw,;..,, --";a
nikov, Rharitonov),
ACCK-610N NP.: AP5CQ20231 UR/0069/6 5 AX~ 7 /004/05 93 /05 9f 72
541-18.046.8
AUTHORS: Fq_q~p, M. Yo.; Kopylev, B, ii. Yafr~2mov, -1. F. Varsh4vnkly, V.
!III-kovich,
TITLF: Cow!uiation proce*uea in tho manufacture of suporph s nte~
__ -7
7- SOURCE- Kolloidnyy zhurnal, v. 27, no. 4, 196', 593-597
IMPIC T'AGSi superphosphate, p-hosphorug comrrur5!d. fcr-Ilizer, in,i,
calcium sulfate
A-'-',')THA'C-: T-ie of potassi-xn su~fata dapo3itiun on apatitaq -~ranulos In
the manufacture of superphosDhate-g was
the particle sizej'or this pro'cess. '"he
other minerals 'r Ti- r 7~111,1
LJ. 1.
L 6
ACCESSIo?l jrR: A-P50202-31
r2nd for*T-, ,lo sl,,o
ro
UB !U TTE D 091.1,r64
Co-d 2/2
ZliGh
SITP CON-'! (,C,
M"i lllk;~v
7i
M.- i, T., x;_Ilf~~i i 2~_ _RR
MgOP ~2!,L ~ONA_ Ott
NIKITBINKO, M.D., inzh.; SURIN, P.P., inzh.; YARSH*IVSKIY, V.L -.,-inzh.
Manganese content of Ell, B12 and 313 electrical steel. Stall
21 no. 1.-30-31 A 161. Wu 14,1)
1. Alpayevskiy metallurgichaskiy kombinat.
(Manganese steel-.-Electric properties)
VARSHAVSKIY, V.L.. BEDRIKV I.A.
Rapid rp-inc of new hearthao Metal-lurg 8 no.5:13 W 163.
(MIRA 16:7)
1. Starshiy insh. tekbnicheskogo otdola Alapayevskogo meta-Uur-
gicheskogo kombinata (for Varshavokiy). 2. Starobiy master
Martenovsko o tsekba Alapayevskogo metanurgicheakogo koubinata
(for Bedrikl*
(open-hearth furnaose-Maintenance and repair)
,9/183/62/000/004/001/001
B117/3144
'AU'7HORS: Sigalp.M. 3., Varshavskiy, V. Ya. Koziorova, T. N.
TITLE: Determination of fiber-forming properties of new polymers
PERIODICAL: Khimicheskiye volokna, no. 4, 1962,.21 - 24
TEXT: The author's method and apparatus described earlier (nim. volokna,
no. 5, 29 (1959)) are superior to- those more recently reported (Man-Ylade
Text.,,3a, no. 439, 71 (1961)) in that they need a Minimum of oniy.1 g
polymer as against 25 g. The imoroved device allowed considerable varia_
tions in the conditions for fiber formation from the melt and otretching,
these processes being:conducted either continuously or individually. T',,,()
reliability and reproduceability of the method was checked with a standard
polycaprolactam fiber. The fiber-forming properties of some new polymers
-)roduced in the VNIIV, Institut elementoorganicheskikh soyedineniy AN SSSR
~Institute of Elemental Organic Compounds AS USSR) and other institutions
7tere determined. The best of these, yielding strong, elastic, and stretch-
able fibers, were: polyamide on the basis of n-amino-ethyl-phanyl acetic
'.d, copolymer of octamethylene diamine salt and hexahydro terephthalic
a
c J.
acid (72 %) containing 28 ~ canrolactam, a polyamide on the basis of non-
Card 1/2 ,
Determination Of fiber-fOrmina ...
amethylene diamine s
-it and hexahydro
Plasticized With o_o~
xydiphenyl
1 figure and 1 table. (10 %
ASSOCIITION;
SUB-~~ITT,-D:
December 12, 1961
S11831621000 v
/ 041GC,-,1cc,,
B117/BI44
terephthalic acid - ,
wnlcn is
Of the Polymer weight). There are
nard 2/2
VARSHAVSKIY., V,Ya,; SIGAL, M.B. .
Polyformaldehyde, a new raw material for synthetic fibers.
Xhim.volok. no.1:5-9 163. WM l6s2)
1. Voesoyuznyy naucbno-issledovatellskiy institut iskusetven-
nogo voloknao
(Formaldehyde) (Textile fibers, Synthetic)
SIGALf M.B.; SHABLYGINq M.V.; VARSIIAVSKIY, V.Ya.
Use of the infrared spectroscopy method for studying "polifen"
fibers. Kh1m. volok. no.2t25-27 165. (MIRA l8r6)
1. Vsesoyuznyy nauchno-issledovatellskiy institut iskusstvennogo
volokna.
0 40 0 0 0 0 0
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g;
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-
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P&LfISICS A.(- C'
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-00
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go*
Absorptim GP*Ctra of 11clutIOUS Of nitrophenots and -00
yaltr 46*12 in trater-ftes hydrazine. YA. M.
v
r
t
.0
i1 suit A. 1.
ht
(U.S.S.IRT22, 47&-W(I9-1X)(iv1
**Z I abstr. -The apectra are similar to thow in 0-10" N-VA01 I
i s Imt the mallma are shifted (oward the r4A hff m-nisro- 0
IS I - > 2 > P
phe a (12o mp) > 3.5- > 2.5- > '..4- > 0 00
0013 (43 niss). As these &Ulf xv 91ralct Own 1110-f in %its,
b
og
3 e -
..they piviawy are due to formAtiun of mol. comptis.
t
If th
l
4
001 c so
vvnt.
ey we
twern phenolate ;oo3 and the bm 00
Jut to ionic aunen., they would havr been baWkr if'
z
t. than NII.. An
N.M. which hwi a greater dielec. cons oo
00% app. for prcpg. buins. without contact with air is described.
llikcfmAn
d
lot"" 110,011VA
4.t
4-1 -T-1-
U IV 10 Is 0 pop,( X&%g Kan to,
0 a 0 0 0 0 0 0 0 0 0 0 0 0 0
:
0: 0 0 a 00 0 0 0 0 0 9 0 * 0
14.0
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=00
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-I 64_4;~v
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06*000060060606069::
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o 0-01"s 6 1 6 WIF IF or all
at- 7
A a Ali a A a -'a A -a.
10 It 11 1) 14 111 1. 1, M n M
I lip D D 11 6 A ;7 A L1, 11 141 1. t k I,
A I L-- ~a It_ _j_'j 1, 1 A* l# CC W If g 1 0 .I --i
004 0*
00 A on ppvctra of solutions of aromatic nitro c'. -00
Got ads savants INAM labile hy&c%en atoms. A*
Wellshtfln and Va. M. Varsh.Av"ll (K.Allitily Imol,
-linys.-Chicin., M'W.W). J. PAYI. cilt"t.
sea 22, cf. prrmling Anti. The lIyI%'thr%i%
AttriblAtinif the eulneal'on of fill f" A'llillid. UAIII. in '%*It,.
etC.. totraillitlex lurthalkal IA&%ic
I"Atir"166k"lifillned hydets, Ilivalwc1f.1 III U4 tier tildwrilts
so it
hilifing 10141C 11 1110"I'll. This litypollifills litecsitunts 69 lilt
,if reaellOr, of janovsky (Ilep. 24, g7lOWN)), The
(70
900 "-ctra of nitrated Phetluls In alk. acrione aft VfrY bill"J61
tit 1b,, ill 11.1*15 v %zolf. but the max. are ihitted 10-
a I'. in$ file the
ward the fed for 2.5-dinitrophenol (03 at%
lien hand,) > ol-filtrophenol > 3.5- > 2.03- > p - > 2,4. >
pkfic &Cj4j > 0-nilrophenol 06 mo). The spectra be- -,zoo
010,
lw"n 4511 And 681) Ina of a dinitroxylene ("I P. 90"), M. 500
toluene. atid 2.4-dinitrotinitde
dinitrobensent. 2.4-dinitro
in liquid \Ila and In 4).("15 N NaOli in ACC4101111! Are ~illli-
lAr, 1M~ AbSUrPti(MI MAx. of the Im, It whis are at 11:15 fill
X 57M,
(in &CTIO"r), SM and 5M, W and i 400
and II&I
and &30.,nd SM in#: the PMWOVI Of the IOAX~ Vilifies little
i"
but the illten&ity of cohniAlion dwiraws 4tronsly with
time (firs'). Hiltrrman
!.1 Ate-SLA -ITALLUOrKAL LIT101411"I CLASUPKAMM
to,, I
'if k4b
IS a AV to At I T -i -A
M $11 a If If of of ft it it 0 1 114 An 1 1 a 'W 0
0 0 0 a 0 0 0 0 0 0 * 0 * a 0 Anil
4 40 0 lllll~ 0 0 0 0 0 0 0
Determinallon of aroinatic hydrocarbons C. C, in
Ceacked peallue by absorption "tra. Va. %I. VAi0mv -
Tt IM." tow St.410 ulliv I lal-14.11's fah IS: IfIVIV,
!I(Ilm 1tv ii-Illd '.4111 .11A JAU A Im t"Ift jill.1
.4114) A, I-io MrIlb siw-l atiAv-4-- III so-o ki,l 0.1-holo, ""V
two ImIlml ; u.-Imm-Y It" C.1 1. %% it IIIII it ~4 1' ,; if hiri'll
1. 1.1--1 It'.. ..T.w I~ filit'llef I'alf IM41 Ow
MW 1, 12 "*, "ItIlt' (OF hlfkllt`~ It 11 It .30'. - III,
mvill."Y I,* II-t I'l."limal Iml-
G. %t.
, i- . . I
,
,.! ~111' , -~ . -! ~ , 1 t , ~ ~` , ~-, .
V,ilorofluoroetliane
Physicochemical constants of 1,2-chlorc-ficurrethanp,. 7hLL-. ob. khi=. 22 nG. 7, 1?--R
Monthly List of Russian Accessions, Library of Congress, November 1952. UnclassifieO.
VAPSHAVSKIY,, YA. M.
UBSR/Chemistry - Reaction, Kinetics 1 Jul 52
Denterium
"The Reaction Capacity of Some Aj-omatic Compoveds,"
A. I. Shatenshtein, Ya. M. Varshavskiy
"Dok Ak Nauk SSSR" Vol LXXXV, No 1, pp 157-160
A study of the reaction c4acity of org substances
as related to their constitution and the nature of
the reaction medium is conducted by measuring the
rate of isotopic exchange of hydrogen. In this
vork a systematic investigation of exchange reac-
t1ons of aromatic org,substances in acid medium :03
begun. The solvent used is d-eutorium bromide. For
the study in alk medium,, deuteroiumonia is used.
Presented by Acad A. N. Frumkin 7 May 52. 224T23
SIMONS, Joseph, 1897- Credaktorl; INUNYANVS, I.L., chlen-korresDondent tredaktorl;
VARSUVSKIY, Ya.M.. kandidat khimicheakikh nauk [redaktorl.
-------- --,- *,--,--,-
[Yluorine and its compounds] Itor i ego soedineniia. Tolum 1. Perevod
anglliukogo, pod red. I.L.Knuniantea i IA.M.Varshavokogo. Moskva, Izd-v*
inostrannot lit-ry, 1953- - (MM 6:8)
1. Akademiya nank SSSR (for Inunyants). (7luorine)
MBLWN, Melvin Guy, 189.1- (author]; ILI INAYA, A.A.; VARSHAVSKIY, Ya.M. [trans-
latorel; SHPOLISKIY. N.Y. Credaktor].
[Absorbtion spectroscopy; collection of articles] Aboorbtsionnaia spektro-
skopiia; abornik statei. Perevod a angliiskogo A.A.Illinoi i LL.M.Var-
shavskogo, pod red. B.B.Shpollskogo. Moskva, Izd-vo inostrannol lit-ry,
1953. 375 P. NLU 6:8)
(Spectrum analysis)
I 110,V-
fa. 1~1
~jy, -
:71 MR ~, L.
Investigation of the reactivity of aromatic compourls by the method of isotopic
exchange with deuterium bromide. V. R. Kali na(:he,.-jko, 'fn. M. Varchnv.91'.1,'~ nnd
A. I. Shatenshtcyn. DokladyARad. 11auh S.113.0'.11. 91, 577-VO, (1953); of. C. A.
46, 9395.
IMM)iqC UCRANOR Of WIDR60RH IM HYDROCARBONS
U~A 171 IMIDIUM or UTRJUVU FLUORMS. YAL
I APA A. Llb &I in. DoMmity Aka& 0
BAIL 14 Mild) -Mar. It. (in Russian)
NUclear SCiOnce Abstracts
.July 15, 1954- TU mankWass of the rats of V mmbwqe between D-
enrld ad Hr &W kydrocsbms was Investipled. D-
Onrick:od 117 wits pro&xfA by the Isotopic exchange
Chemistry wescUon of NIF uA kosvi water Isaoptc exchange was
measured b4tw~4n.Dlr mad the WidnxtrioDw bem!sne,
1"Ibnem- iAmyl Moll erjor, dLq2mjj&OWu~
napht Ad triphenyl
hustw, &M baptams. The rate of
exchasgs is explained by the #rot*bla genoralton of
lluarlao o3dde daring Via praiparatton of D-entiched Hr.
-2/
s
tj A 0-
AUDRIETH, Ludwig Prederick; OGG, Betty Ackerson; YAKOVLICVA, Ye.A.Etranalatorl;
,VARSHAVSKIT, Ya.H., redaktor; SAUTOVA, , H.V., rodaktor-, Popm, Y.r.,
;a-6J,--t-o-r-MMUFMVA, Ye.S., teanichaskiy rodaktor
(The chemistry of bvdra21UO. Translation from the Inglish] Khimiia
gidrazina. Perevod a angliiskogo B.A.IAkovlavoi. Pod red. IA.M.
Varshavskogo. Hoelcva, Izd-vo inostrannot lit-ry, 19_54. 237 P.
(Hydrazine) (MIRA Bt4)
Ni -J -F -
il IN I I fj 4,~ ill 1
Tj TJ -
Y39VA, YoY.A.
"Quantitative ultramicroanalysia.0 P.Kirk. Translated by
U.N.Varshavskii; I.P.Alimarin ad. Reviewed b7 Ia-.%Fentleva.
Usp.khim. 23 no.4:524-526 '54. (MA 7:7)
(Chemistr7, Analytical-Quantitative) (Kirk, Paul)
(Microchomistry)
;
AO
L
Ryawjin fi~fo~i flitercWj4 in ls~&owbons 14 4 liquid
VZ
K
M.VarshivskIfandA,j.:
-uterfurn fluoride medfurn.
.-;L,' Shatensbtcln. Dokkdy Akad. Naid: S.S.S,R. 93, 297-0
(1954).-Tbe effect was studilA of tfie diefec. cosuit. of the
mediutu on the mcchao~qtn 0 daub,e exclumse reactions,
Because of the high dit1te. cons(. of'JIF (176 at -78', 84 1
-Was'sckc A as ks-NI It!
IlDr 6 At - 80*),and was c%Iv.--ted to favor the ionization of
hydrocarbons, which was confirmed by Kilpatrick and
Luborsky (CA. 47, 7867s). The oily, of the isamples of
hydrocarbons (0.2 g. in 20 C. H F) wus tested, and beazene.
toluene, an thra"ne. an isole, and dim tthylauiline were sot. at
25 and 50" Whereas naplitbalelle, pheaunthrene, Ph'011,
MCH, MCI. Tetralln. Decaliu, cycloh"ane. hexane,
and heptane were either only partially sot. or insol. lie
D-exchange rate const. in beartne -.u a DF soln. Is an the
order of 104 greater than in 1113r. The 11 atoms in the tol-
tieric side-chala were not (idtaux,A for D fit 1000 firs.,
Whereas all the rintatoms W"e Cxcbanged in 15 min. at'25'.
BF$ addn. to DF accelerate-, the cxchajige, wi found with
cyclobexane, which exchanged its 11 atoms only slowly in the
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