SCIENTIFIC ABSTRACT VASILKOVA, I.V. - VASILKOVSKIY, D.N.

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SCIENTIFIC ABSTRACT
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t SOV/78-4-1-7/4E3 III. The Energetics of So-lid Uranium Oxyl~alidc-3 in the Light of the Substitation .Principle those of the solid chlorides and especially of the bromides (with the exception of UC1 2)i With regard to energetics and the exchange principle the situation of the oxychlorides has to be regarded as intermediary between halides and oxides. The com- parative proximity of the curves of the chlorides and~oxides as compared to the curves of the bromiden and oxidos can bo ex- plained by the fact that oxygen and chlorine have about the same oxidation properties. The formation enthalp-Jes of solid oxy- halides are higher thau those of the solid oxides and therefore the oxyhalides have more energy. The ex;hange energetics are determined by simple regillarities with regard to the theo::'y of chemical compounds. The greater condensation energy of oxy- chlorides shows that these compounds are more stable than oxides and that they show less dismutatio-i trend. There are 2 figures, 1 table, and 8 refererces, 5 of which are Soviet. SUBMITTED: August 6, 1957 Card 2/2 .r(,4), 21(l) OV/7 8 - 4 - I - ~5/9 AUTHORS: Shchukarev, S. A., Vasillko-za, I. V., Drozdova, V. M., Frantseva, K. Ye. TITLE: The Determination of the Formation Heat of UO 2 Cl 2aqu' UO2Br 2a,:g UO2Cl 2* H20, U02 Cl2 .3H2 0, UO2Br2 H 20 and UO 2Br 2- 3H20 (Opredeleraye teplot obrazovaniya UO 2Cl 2aq' UO2 Br 2aq' UO2Cl 2' H20, UO2 Cl 2'3H 20, U02Br 2-H20 i UO 2 Br 2-3H2 0) PERIODICAL: Zhurnal neorganicheskoy khimii, 1959, Vol 4, Nr 1, Pp 39-41 (USSR) ABSTRACT: The crystal hydrates of uranyl chloride and uranyl bromide were produced from anhydrous UO 2C12 and UO 2Br2 by treatment with inert gas containing steam at room temperature. The synthesized oompounds were nnalyzed by the determination of uranium according to th~. Va---adate .-.iethod. The chlorine and bromine content was determined. The determination of the solution heat of anhydrous uranyl chloride and uranyl bromide and their monohydrates and trihydrates in water at infinite Card 113 dilution was carried cut at 250. The results are 9hown in SOV/78-4-1-8/48 -The Determination of the Formation Heat of UO 2 Cl 2aau' U02 Br 2aqu' U02Ci 2'H 20, U02Cl 2'3H20, U0 2 Br 2'H20 and UO 23r 2d3H20 table 2. The followirg values wore given: AH U02 C1 2 ~ -23-86 + 0.13 kcal/moi AH UO2 C12 H20 _13.32 - 0.23 kcal/1"101 &H U02 Cl.2.3H20 -10.00 + 0.11 kcal/mol 4H U02 Br 2 ~ -33.28 + 0.32 kcal/mol &H U02 Br 2'H20 -24-42 + 0.08 kcal/mol AH U02 Br 2'3H20 -21-51 � 0.12 kcal/mol On account of the values of the solution heat the fo_-maiion heat of UO 2C1 2aa,-,' U02Br 2aqu' U02 Cl 2' H20, UO2C1 2'3H 20, U02Br 2'H2 0, and UO2 Br 2'3H2 0 was calculated and summed 1.zp in -table 3. The values of the formation heat of UO 2C1 2salid and U02Br 2solJ"dare as follows: 16H formation(2980K) U02Cl 2solid= -301.9 kcal/mol Card 2/3 AH formation(2980K) U02Br 2zolid ~ - 281.6 kcal/mol. SOV/78-4-1-8/48 The Determination of the Formation Heat of UO 2 Cl 2aqu' UO2 Br 2aqu' UO2C1 2'H20, UO2Cl 2-3H20, UO 2Br 2*H20 and UO 2Br 2-3H20 The dehydration heat of UO 2 Cl 2-3H20 was calculated according to the following equation: U02cl 2*3H2 0 = UO 2C12-H20 + 2H2Ogas- This value is in accordance with the value obtained by the tensimetric method (Ref 4). There are 3 tables and 6 references, 4 of which are Soviet. SUBMITTED: September 5, 1958 Card 3/3 B/054 60/000/02/14/021 B022YB,007 AUTHORS: Shukarev, S. A., Vasillkova, I. V., Sharupin, B. N. TITLE: The Investigation of the Halides of Molybdenu IV. The Determination of the Formation Saihalpy of Molybdenum Di- and Trichloride PERIODICAL: Vestnik Leningradskogo universiteta. Seriya fiziki i khimii, 1960, No. 2, pp. 112-120 1/3 TEXT: The present article comprises part of the material used in the 13 dissertation of B. N. Sharupin. It was found that in the oxydation of molybdenum di- and trioxide in oxygen a mixture of molybdenum trioxide and molybdenum dioxide is obtained, Table 1 gives the results obtained by analysis of the molybdenum- and chlorine content in MoCl and MoCl 3 21 which are compared with the data calculated according to theory. The calorimeter used for the determination of combustion ent-halpy was calibrated with metallic magnesium, which was obtained in spectroscopically pure state from the Veesoyuznyy alyuminiyevo-magniyevyy institut (All-Union Aluminum-Magnesium Institute). The results of calibration are given in Card 1/2 The Investigation of the Halides of Molybdenum. 3/054/60/000/02/14/021 IV. The Determination of the Formation Enthalpy B022/BO07 of Molybdenum Di- and Trichloride Table 2. Also the effect produced by various quantities of chlorine in the cylinder during combustion are investigated (Table 3). The enthalpy in the combustion of MoCl and MOC12 in oxygen at a pressure of 40 atmospheres and at 250C was determined. The combustion products were determined by dissolution in CCI in which M003 is not soluble and the oxychlorides are easily soluble. Thi results are given in Table 4. The total quantity of molybdenum and chlorine In the combustion products, as woll as the quantity of MoO3 was titrimetrically determined, and herefrom the percentual molybdenum- and chlorine content in oxychloride was calculated. The results are given in Tables 5 and 6. The thermograms of the preparations investigated (Fig.), the oombustion-enthalpy of MOC13 (Table 7) and MOC12 (Table 8) are given. The results obtained for the formation enthalpy of MoCl and MOC12 are compared with the data previously obtained (Ref. 5) by tL authors for MoCl and MoC14, as well an with the results obtained by Brewer (Ref. 1) (Table 9). The preliminary results calculated for the formation enthalpy of MoC13 and MOC12 are -93 � 4 kcal/mole and -69 � 5 kcal/mole. There are 1 figure, 9 tables, and 12 references, 5 of which are Soviet. Card 2/2 I A I I , , -/I I I V tt"~' i C- 0- VIT) 3/078/6 0/005/008/002/018 BO04/BO52 AUTHORS: Shchukarev, So Novikov Vasillkova, is Vol Suv0roVq Ae Vol An L GL Sharupin, B.-ff-., Bayev, T.- K. , I 'kI TITLE: The Thermodynamic Properties of Chlorides and Oxychlorides of nMEsten and Molybde ~1 _V1 PERIODICAL: Zhurnal neorganicheskoy khimii, 1960, Vol- 5, No- 8, pp. 1650-1654 TEXT: By applying various methods, Ithe authors wanted to check the formation heats, formation entropiesl\'and formation enthalpies in the case of Mo- and W chlorides, published in western papers (Refs. 1, 2). They investigated: WC1 6' MOC159 W0C1 4' MoCl4? W02Cl2 (obtained by a successive chlorination of WO 3 and MoO 3by means of CC1 4~ moo 2Cl2 (obtained by the reaction between Mo02 and C1 2); MOC13' WC14' WC15 (by the reduction of Mocl5 and WC1 6 by means of H 2) , and MOC121 WC12 (obtained by dispropor- Card 1/3 The Thermodynamic Properties of Chlorides S/078/60/005/008/002/016 and Oxyohlorides of Tungsten and Molybdenum B004/BO52 tion of MoCl 3 and WC1 49 and MOOC14 ). Two calorimetric methods were applied: 1) Comparison of the heat of solution of the investigated substance to the heat of solution of a substance whose heat of formation is known (Table 1). 2) Combustion in oxygen (Table 2). Furthermore, the vaporization, depolY-1 merization, dissociation, and disproportionation processes taking place in a state of equilibriumq were speotrophotometrioally and tensimetrioally investigated (Tables 3~ 4), The enthalpies of formationt ani partly also the standard entropies of formation were calculated from the experimental data. In Tables 5 (Mo compounds) and 6 (W compounds) they are compared with the data given in Ref. 2 which were adopted almost unchanged by the US National Bureau of Standards (Ref. 9),, The values determined by the authors are 1-4 - 1.7 times as high. Therefore, the dependence of the free energy of formation of temperature is different altogethera This is 0 graphically represented in Fig. 1 (comparison of determined AH and 6 F for tungsten compoundsp with the data of the National Bureau of Standards), and Fig. 2 (comparison of the A "form of Cr, Mo, and W chlorides, with the data of the National Bureau of Standards). There are 2 figures, 6 tables, and 9 references: 6 Sovietq 2 US, and I Dutch. Card 2/3 The Thermodynamic PropertJes of Chlorides B/078/60/005/006/002/018 and Oxychlorides of Tungsten and kolybdenum B004/B052 ASSOCIATION: Leningradakiy gosudarstvennyy universitet Khimicheskiy fakulltet (Leningrad State University Department of Chemistry) SUBMITTED: May 6, 1959 Card 313 SHCHUXAREV, S.A.; VASILINDTA, I.T.; SHARUPIN, B.N. Molybdenum halides. Part 4: Determining the mthalpy of for- mation of molybdenum dichloride and trichlorideo Yest.LGU 15 no.10:112-120 160. (MIRA 1315) (*3~vbdenum chloride) (Inthalpy) SHCHUKAREV# S9A,; SMIRROVA, YeA.; VASILIKOVAj I.V.; IAPFO, L.I. - -- ----- Inthalpies of formation of tantalum pentachloride and pentabronide. Vest. 1GU 13 no.16:113-119 160. (MIRA 13:8) (Tantalum chloride) (Tantalum bromide) (Ikthalpy) SHCHUKAREVP S.A.; Uajjt~~; OFJJISKAY.A, M.A. [deceased]; TSIN"MIUS, V.M.; SUBBGTDU, N.A. Determination of the enthalpy of vanadium tribromide formation. Vest LGU 16 no.16:125-129 161. (MIRA 14:8) (Vanadium chloride) (Enthalpy) PERFILOVAJ, I.L.; KOZLOVA, I.V.; SFiCIIUYARLV, S.A.; VAOSILIYOVI, I.V. Enthalpy of vanadium oxychloride formation. Vest ILU 16 no.16:130-135 t61. (MIRA 14:8) (Vanadium chloride) (Enthalp7) VASILIKOVIi, ~.,Vj_ZAYTSFjVA, N-.D;"-SVAIDVI.Yu.S. Molybdenum halideo. Determination of tYe ent-Alpy of dioxydibromide. Vent IGU 16 no.16jlI,0-1A..2 161. (MIRA 14:8) (Molybdenum bromide) (Enthalpy) SHCRUKARFV, S.A.; VASILIKOVA, I.V.; ZAITSEVA, N.D. Study of molybdenum halides, determination of the enthalpy of molybdenum tetrabromide formation. Vest LGU 16 no.22:127-129 ,61. (MURA 14: 11) (Molytdenum balides) (Heat of formation) SRCHUKAREV, S.A.; VASILIKOVA, I.V.; SHAWIN, B.N. i Molybdenum halides. Part 5; Thermodynamics of MoO2Cl and MoOZ 2* H20. Vest LOU 16 no.22:130-134 161. (KIRA t: 11 ) (Molybdenum halides) SHARUFINI B.N.; VASILIKOVA, I.V. Regularity in the enthalp7 of formation of oxides and hydroxy- chlorides. Zhur.ob.khIm. 31 no,6z2CY77-20178 Te 161. (MIRA 14:6) le Leningradskiy gosudarstvennyy universitet imeni A.A.Zhdanova. (Mtallic oxides) (Chlorides) (Enthalpy) S105411621CW1001 /010/01 B1 21 / B1 38 AUTHORS: Shchkarev, S. A., 11 Korolikov, D. V., Nikollskiy, S. S. Tl'.'L:;*: Thermodynamic study of molybdenum dibromide PERIODICAL: Lenin, rad. Universitet. Vestnik. Seriya fiziki J_ khir-iii, -no. .11 1.96Z, 1487153 -.. TEXT: The actual isobaric specific heat of solid molybdenum dibromide and the temperature dependence of entropy, enthalpy, and free enerCy of forma- tion of solid ;,',OBr2 were calculated. In addition the thermal stability of T.IoDr, was studied. 1.oBr2 was diluted, after bromination of metallic molytdonum in bromine vapor, with an inert gas at 600-7000C. The isobaric 3fiecific heat was deterz.-iined in a calorimetric apparatuo with a sensitivity of 0.000050C- When solid MoBr2 is heated to 6000C in a vacuum no meltin.rr occurs, and there is disproportionation which mainly follows the equation MoBr 2(solid) 113 Mo + Mo B r3 (c) 'The values for onthalpy, entropy, and free energy obtained in solid 1.1oBr2 formation are as follows: Card 1/3 S /0 5 4/6 2/C 00 /CC 1 /0 10/0 11 n Thermodyna.mic study of molybdenuz, ... B121/3136 IL -110 62.4 kcal/r-ole 293 formation L,oBr 2(solid) L S0 -31-4 e.u. 298 formation "'oBr2 AF0 -53.0 kcal/,mole. 298, lormation '11103r 2(solid) The temperature dependence of the specific heat of solid YoBr2 frOl' 298-77301: is expressed by the equation 7. ACO 41 ) = _51.80 + 30.2-10- 2T + o.63-105T-2 Cal/Mole.d.:& P -1103r 2, Ornation (.solid The temperature de7lenden.ce of the actual specific heat of some chemica2ly reSistant Classes such as -pyrex, pyre7 chemical resistant -lasz and the I ied and the chemicall'y resistant Rusoian -lacs 4'Yi?e TI -15 (P-1 5) st',"I I- valueo followin, obtaint:d: for ivrex Ci) - 0-174 + 3.60-10-4 cnliu of de,;rees t; for pyrex chemical re3i2tant glass LI - C-_ = 0.17a + 3 .13:10 -4 can! derrees t , and for P-1 5 I-lass C" = 0.161 + 2 .09 10-4 cal/,--deCrees t. There are 2 figures, tables, and 7 references: 3 Soviet and A. -ion-Soviet. The three referencez to Card 2/3 -'11054 62 C CO/o r, 1 /3,11 ClIc Thermodynamic study cf molyb'"'Jenum ... X j B1 -, B1 -38 En~:1i.5h-lanL-up-je publications read as follows: L. Brewer et al. , Chamistr and metallurLs-y of miscellaneous naterials. N. Y. Mc. Gra-a-11ill, 1 9C0. F. Rossini, D. 1.7aeman et al. 'Selected values of chemical thermodynamic properties, US Gov. print. office, '.'IashinL;ton, 27, 29~,-191-2. G. 14orey. The properties of L-Ilass. N. Y., Reinholdy 80, 276, 1954. SUB-ITT ---D: June 2"r, 1960 Card ~/3 S/054/62/000/CQ3/006/010 3101/B166 A L:T H ORS Vasillkova ~I. V~ Yefimov, A. I. TITLL: interaction in the system XoCl 3 - FeCl3 PLItIODMIL. Lenin-rad. Universitet. Vestnik. Seriya liziki i khimii, no. 3, 1)62, 98 - 1OCr T-*-XT: The fusibility curve for this system was plotted by thermographic investiL,itiorl ir the rangL: 20-3500C. The system forms a simple eutcetic, M.P. 18j0C, of the composition 93 mole~~U KoCl 7 moloi; FeCl In the 59 3' ranec 50-60 mole,P !ZoCj~-, the solidus line could be determined exactly ,Ihereas the liquidus line was inaccurate.* Tensimetric investigation -.-.-ith 0 0 ~;-~glass ze;:,.brane as a null Manometer in the range 20-300 C gave the dLagram p versus t. Down to liquidus temperature, the values obtained in Qp:oling agreed with those determined in heating. On further cooling an 61-evated residual pressure of 100-200 am Rg was observed due to gaseous chlorin7e formed on dissociation of 'J'OC'51 which, being poorly soluble in the solid phase, passes over into the gaseous phase on solidification. I Card 1/2 0/054/62/000/003/006/010 Interaction in the systLm ... B101/B186 The p-versus-t curve confirmed the complex composition of the gaseouB phase of the MoCl 5 -FeCl 3 systea. Gas pressure over a melt consistibg of 23-5 molO--) YoCl 5# 74.5 mole'713 FeC13, is only half the pressure over pure There are 3 figurvs. MOCI 5* SUBKITTiZ. June 27, 1961 Card 2/2 S/07 62/007/006/001/024 BI 24X51 38 AUTHORS: Shchukarev, S. A., Smirnoval Ye. K., Vasillkova, 1. V., Borovkova, N. 1. TITLE% Formation enthalpy of niobium pentabromide and oxytribromide PERIODICAL: Zhurnal neorganicheskoy khimii, v- 7, no. 6, 1962, 1213-1215 TEXT; This wasdetermined from their measured hydrolysis enthalpies for a newly developed method of separating niobium and tantalum by fractionating their bromine compounds. NbBr 5 free from oxybromide was produced by making niobium pentoxide react with CBr 5 in sealed ampoules evacuated with a forepump. A mixture of Nb 2051 NbOBr 31 and unreacted CBr4 was obtained by 18-20 hr heating at 200 0C. The ampoule was cooled# the gaseous reaction products were removed, the ampoule was sealed again and heated for 6-10 hr at 360-3600C. The reaction products CO, C0Br29 and Br 2 were drawn off with a forepump at 700C, The reaulting NbBr 5 was purified Card 1/2 S/076/62/007/006/001/024 Formation enthalpy of niobium ... B124/B138 from Nb 205by double sublimation in vacuo. NbOBr 3 ~ae produced by oxidation-of NbBr 5 at 150-1600C and bromination of Rb 205 with CBr4 at 190-2000C. The heat released during hydrolysis of the bromides was determined calorimetrically at 260C tc. be 66.3 � 0.9 kcal/mole (lIbBr 5) and 34-8 + 0.6 kcal/mole (NbOBr 3). The enthalpies calculatea on the basis L110 of published data were. RbBr5 135.2 + 1.2 kcal/mole and LH 0 -179.3 � 1.0 kcal/mole. There are 3 tables. The three most NbOBr 5 ~ important English-language references arei i. M. Alexander, F. Puibrother, J. Chem. Soc. (London), p. 223 (1949); F. Pairbrother, A. H. Cowley, N. Scottj J. of the Less. Common Metals, 1, 206 (1959); G. Z. Humpley, J. Amer. Chem. Soc. 76, 978 (1954). SUBMITTEDi July 14, 1961 Card 2/2 SHCHUKAREV, S.A.; SMIRNOVA., Ye.K.; VASILIKOVA, I.V.; BOROVKOVA, N.I. Enthalpy of formation of niobium pentabromide and oxytribromide. Zhur.neorg.khim. 7 no.6sl2l~-1215 JO 162. (MIRA 15%6) (Niobium bromides) (Heat of formation) SHCHUKAM,, S.A.; VASILIKOVA I.V., MFILOVA., I.L.; CHEI-I-IYKII, L.V. Enthalpy of vanadium trichloride formation. Zhur.neorg.khira. 7 uo.7: 1509-153-1 J1 162, (KM 16*,3) (Vanadium chloride) (Heat of formation) SHCRUKAREV, S.A.; VASILIKOVAp I.V.,-_,EROLIKOV., D.V.; NIKOLISKIY, S.S. Thermodynamic study of molybdenum dibromide. Vest. WU 17 no.4: 148-1,9Y 162. NM 15:3) (Molybdenum bromides-Thermal propertieb) VASIVKOVA, I.V.; YEF314OV, A.I. Interaction in the "stems molybdeGON with PentacblOridO - alicall metal chloride, Zhur.ob,khim, 32 no,8:2742-2743 Ag 62, MIRA i -15--9) (Molybdenum chloride) (AlAkli metal chlorides) S/08 62/035/007/002/013 D267YO307 T-,-70113: Shc-auharev, Vasil'l,:Ova, I.V. and Shaluicukhiua, ,U od,naaml c .1nalysis of the chlorination of molyb- T IT L - t.La aseous mixture of chlorine with sul C.~ J. oy no. 7, 1962, 7h %A rn al ,IODICAL: 145-9 -146k; -Lac with Sul- ic r ta -at of Cl was maoly~lates and cl-oLordeg begins W-1-11 c-'lc.L .. .. chlorides, Lae pro- ~.Iith 1:003 At about 160 .L.~t al c.rilorides of the corrz-,--, - -,.~ . -ind there- th, lrziar~~-- st C, WC - e cessos '-,WvoIved tT:)In v "-ac 5 Of entha- -eA - lis or -tion 6&- ,[)v tae ilo-,t probab'IQ I . -1 -1 - -arval 1-ics,,-"rea calculatea " t.,e Lnt b~IoC)4 and' --s.,Iczio~-- schemes oetween Ca~:o(; ".2 Sboo- !-or 072 POS-S I 41(0r pure C12)1 1, 0 e one *hainl. and a4-.:V'-es 0-2 012 wlt~" ~;2% k-O th Gard -J/060/C)2/035/007/002/013 T'I-LerrxdynL-m-:'c D267/-0307 ' on other. Most thesc :--~~-nctio:iL Qre eyoth:!n-.;ic; the analysis o.-ff t1i-lc. ob-41ne4 thei:--.,ocYnariic ma,,rnitud-a-- yiel",cl most probable rcact.ion schame-s 4ne. showed that the chlorinatio-.L with tile mixture of C;1,7 Ath &vlphUr chLoride-- is nor-- advantageous than chlorination -uith Cin 181 ohe "ThQ)-e i~ 1 figure and I table. I-D t4 7 29 1_961 02-rd 2.1/2 SHCHUKAREVv S.A.; VASILIKOVA,,Z.V.j KOROLOKOV, D.V. Interaction of *,tri-, and tetrabromides of titanium with the bromides of rubOlum and cesium. Zhure neorg. khim. 8 no.8:1933 1937 Ag 163. (MIRA 160) (Titanium bromides) (AlWlAetal brc*,des) VASILIKOVA, LV.; ZAYTSEVA, N.D.; SHAPKIN, P.S. Interaction of tungsten hexa- and pentachloride with oodium and potmnlum chloriden. Utir. n6org. kh1m. 8 no.10t-~.Vk- 2364 0 163- (MIRA 16t10) (Tungsten chlorides) (Alkali metal chlorides) VASILIKOVA,- I V.; ZAYTSEVA, N.D.; PETROVA, V.A. Systems RbC1 - WC1 . RbCl - WC1 CSCI - WC16 , and CsC1 - WC1, . Zhur. neorg. khim.68 no.10:2369-Myl 0 163. OEIRA 16:10~ (Tungsten chlorides) (Alkali metal chlorides) (systems (Chemistry)) SHCHUXAREV, S.A.; SMIRNOVA, Ye.K.; VASILIKOVA, I.V. Thermographic analysis of the system RbCl .. CbOC13 and CeCl - NbOCI 3& Vest. DGU. 18 no.16tl32-133 163. (MMA 16:11) SHCHUKAREV, S.A.; SMIRNOVA, Ye.K.; VASILIKOVA, I.V,; KOTGVA, M.S. Enthalpy of formation of Bodium and potaBeium chlorotanta- lates. Vest. LGU 18 no.221174-176 163. (MIRA 17:1) VASILIKOVA, IoV,; YEFIMOVj, A.I.; PITIRIMOV, B.Z. Enthalpy of the formation of Ks3CrCI6 , KJCTC16 , and K3Cr2Cl9 . Zhur. neorg. khim. 9 no.3.*754-755 Mr 164. (MM 17% 3) SMIRNOVA, Ye.K.; VASILIKOVA, I.V.; KUDRYASHOVA, N.F. Enthalpy of theformation of the chloronlobates and chlorotantalates of rubidium and cesium. Zhur. neorg. khim. 9 no.2:489-490 F164. (MM 17:2) VASIL'KOVA, I.V.; YEFIMOV., A.I.; PITIRIMOV, B.Z. Complex formation in the systems YbCl - CrC13 (Me- an allkaUne metal) Zhur.neorg.khim. 9 no.4:900-904. Ap 164. (MIRA 17:4) S"I 11 k SMIRNOVAp Ye.K.;-VASJ.L.IKQYA,. I.V. Oxychloroniobates of alkali metals of the composition Me IHbOU Vest. LGU 19 no.4:164..165 164. ~MIRA 1;'3) fllwa- as U,- ~ im mm,- - a m = a m 0 ~ I m - wom ~, UNION IIMIRNOVA~ Ye,K.; VASILIKOVA, I.V. a Chloroniobates (IV) of alkali 165. metals. Vest. LQU 20 no.10il6l-162 (ICRA 18; 7) Sh"'MrIvARE72 S A VAc fl,~,Ats of Gnzd-. iron, '--cpper, ii-ni.-I 20 MARTSOVA, N.S.; VASILIKOVA, T.V.; SUSAREV, M.P, -- ---- ------ -I.- -.- - Iyaluation of the concOntration region'of the locaticft of ternary eutectics in common eutectle systemo according to the data an binary outectics and components, VestOLGLY 20 no*22196-100 165# (MIRk 18312) KUDRYASHOVAP Z.P.; VASILIKOVA I.V.; SUBAREV, M.P. Application of differential equations of solid phase solubility isotherma in an ideal melt for evaluating the reliability of experimental data; system NH NO, KNO3 Pb(NO~)2- Zhur. prikl. khim. 38 no.l012252:4,,,57 0 165. (MIRA 18:12) 1. Submitted July 89 1963. VASIMKOVA, 1.V.; KR_'rk,'Ouz4,`Q-UA~ I.V.; SUSARF,'~o M.P.; Tol-KAcifl,"v, S-S. X-ray a tudy cf the xutlial ijolulmi Li tjr of :3ol id phu se n f ': y systems K'l- Na"I - Crill,, and K"I - !Jfa~l - vCi- ternar- %, 1 1; Vest. LGU 20 no.16:1~6-i_-,2 165.' -1 KRIVOUSOVA, I.V.; VPSILIXI~)-VA, I.V.; SUS!,lj~*-,V, 1111.1,0 Thermograpble study of the syntem Cl Var,11 - 101 Zhur. prlkl. khim. 37 no.11:2348-2353 It 164 3- (MTRA 18:1) ~71. , T l.' . ; ~" '.,' j -(_ I -~,C~Wji', , T .!~, . ; , t'j I . . . 4'.0 . i k . : o" *'I, 4,%e Ifacl - KCI - K I -, 3 7 r o . 10 : 2 1 c,'!-;'- 2- -2 G 3 0 164. 3"C'6' Z""r- Pr' " (IMIRA 17: -, j ) VASILfKOVA. K.I. Correction of scoliosts before fizing the spine. Ortop.travm. i protez. 17 no.6:91 N-D 156. (KISA 10:2) 1. Iz kafedz7 ortopedii i protezirovaniya (2aveduyushchiy - zaaluzbennyy dayatell nauki , professor H.I.Kuslik) Gosudarstvannogo Institute dlya usovershenstvovaniya vrachey i ortopedicheakogo otdelenlya (zaveduyushchiv - professor Ya.B.Tusevich) Ifiningradskogo nauchno-issledovateliskogo institute trdvmatologit i ortopedii (direktor - professor V.S.Balakina) (SPIMN-ABNcwrrIlS AND mwaKrrLw) VASILIKOVA, K.I., kand.med.nauk uw=lrmmzwra4x-~:]~I~z VredenIs "inhibition of flexors" in treating Bpastic paresis. Ortop.travm. i protez. 18 no.4:66 Jl-Ag '57. (gm 11:1) 1. Iz kafedry ortopedii i protezirovaniya (zav. - zasl. deyat6l' neuki prof. M.I.Kuslik) Gonuderetvennogo institute dlya usovershen- stvovaniya vrachey (dir. - prof. N.I.Blinov) i ortopedichesk-ogo otdaleniya (zav. - prof. Ya.S.Yusevich) Leningradskogo nauchno- iFialedovatellskogo institute travmatologii i ortopedii (dir. - prof. V.S.Balakina) (PARA LYS 13) VASIV Bone plastic surgery In,scoliosis following preliminary stretching. Xhirurgiia 34 no,7:93-98 J1 158 (MM 11: 9) 1. Ix ortopedicheakogo otdeleniya (sav; - prof. TaOSO' Tusevich) Laningradekogo institute, tralmatolo H i ortopedii (dir; - prof; V.B. Balan1na) i kafedry ortopedii fsave' - prof. X.T. luslik) Leningradskogo Gosudarstvennogo instituta dlia spetsializataii i usovershenstvovaniya Yrachey; (SCOLIOSIS, surgery plantic surg. after preliminary stretching, technic (Rae)) ~.VASILIXOVA, K.1, -A Determinatlon of the force for correcting moollests In ffplno traction. Trudy ron.gos.,nauch.-isol.inst.tr&Tu.I ortep. no.7-6 177-162 '58. (MM 13:6) (spin-ABNaDwas An mmRmiTims) VABIL'KOVA, K.I. Modification of the Wmann-Shants operation (transposition of the fibular and posterior tibial muscles in talipes equinus). Trudy Lon.goo.nanch.-isel.inst.travm.i ortop. no.7.'314-315 158. (MIRA 13:6) 1. 1z ortopedicheskogo otdoleniya LeriWadekogo gosudarstveuno- go nauchno-issledovatellskogo inatituta travmatologii i orto- pedii. (POOT-ABNORKTIZS AND DRYORKITIMS) VASILIKOVAt K.I.9 kand.meditainskik-h rAuk Late results of osteoplastic fixation of the spine in severe forrz of scoliosis. Ortop. travm. i protezp 21 no. 7:19-23 JI 160. (MIRA 13:10) 1. Iz Ortopedicheskoy kliniki (zav. kafedroy - zasluzhennyy devatel nauki prof, M.I. Kuslik) Lening-radskogo ordena Lenina Instituta usovershenstvovaniya vrachey (dir. prof. N.I. Blinov) i ortopedicheskogo otdeleniya (zav. prof. U.S. Yusevich) Leningradskogo instituta travmatologii i ortopedii (dir. - prof. V.S. Balakina). (SPII,'E--SbRGERY) VASILIKOVA K I Imnd. med. nauk,(Len'narad 101, Kronverkskaya u1, kv. 5 Apparatus for spinal refr-osemerit ;,.-r! ~I,tn travm. i protez. no.11-16-19 '61. 1. Iz kafedry ortopedii i protezirovaniya (zav. - zasluzh. deyatell nauki prof. M. I. Kuslik) Gosudaretvermogo ordena Lenina instituta usoverahanstvovaniya vrachey (dir. dotsent A. Ye. Kiselev) i ortopedicheskogo otdeleniya (zav. prof. Ya. S. Yusevich) LAnin- vradskogo nauchno-isaledovatellskogo inrtituta travmatologii i --ortopedii (dir. - prof. V. S. Balakina) (SPINE-- ABNORKITIES A14D DEFOWITIES) A~ S- I LKC) V A F.I., dotsent 4 C-steo-id osteo.-~ a-%, an ---,nusl.~&, site. Crtop., -ravm. - protez. nc.q: 80-081 162. my-, deyate 11 nauki i)ro:*. 7-11L.'~ 1;~;oversriens UVUVall.LYU VI'UCI'lt~y Prof. Ya.S. Len~n- --enlya- fmidokogo in-,tiLUta rravinatolov,-ji - ortopedii. VASILIKOVAP L.P.; Prinimal uchastiye SHALDEHKOV, I.P. Biochemical purification of the industrial waste waters from the production of vinyl acetate and the polymers based on it. Trudy VNIIT no.12:290-305 163. (MIRA 181l1) VASILIK07A. M.V., starehly nauchnyy cotrudnik Burning and sheMing vf leaves in fruit tress, Zashch. rast. ot vred. i bol. 7 nq.10133-34 0 162. (MIRA 16:6) L Nelitopol'skaya opytnaya stantsiya sadowdstva. (Plants, Iffict of chemicals on) r I VASILIKMVA, N.N.: TMIWSWA, A.G.; SWSKArik, Y.T. Tin deposits associated with subvolcanic bodies. Sov.guol. 2 no.10:81-97 0 1-409. (MIRA 13-4) 1. VaesoyuzzWy institut minerallnogo, eyrlya (VIMS). (Sikhote-Alint Range-Tin ores) 3(5) AU THO R: vasil,lcoval T I T L The Metastable Potassium Feldspar and Zeol-itUe in Ores of the Da1`.j,~i;ayezhnoye D,3posit (111ota5tabil'- nyy kaliye,7,j-v polevoy shpat i toeolit v rudakh Dal'~- netayezhnc,-,-o meot,-).,rczhdeniya) C3 PERIODICAL: Izvestiya Alkadenii nauh SSSR. Seriya geologich-ask-aya, 10 ,597 Nr 5, PP 1175-118 (USSR) ABSTRUCT: The suifite-~assiterite tin ores of the Dal'netayezh- noye depositz in the Primo:b'ye (the Soviet far eastei-n maritime region) were formed near the earth's sur- face and far from a ma-Matic hearth. Accordin to 4u-h=-, All-Union Instituue of Mineral Raw Materials MIA-), there is a close dependence of conditions of for- mation of --ulfide-cassiterite depositz on the depth of formation of intri-isive rocks. In consequence, all. such deposits are divided into three Groups 1) de.- Card l/ 5 posits territorially and genetically closely linked The stable PoIu-a.,;_zi,_u-_ Fold _-Pai- 7"-,o I-i to in Gr-_- f t Dal'netayczl,,ioye DepoSit. with Ac boaic,, -.)rc_t-on'U-l,,,~ not directly v.-itii a source, liavin- in th,-~ir li_:,itc uu~?eol~ of cop_'U="U-:.,,otazo- natic transfir-mationz i.-,ineral h reli oc,-.urin,!- -:dtli a-,-i incrcas-ir.,~ dista-mcc 2--on t'llcm; 0 deposits huvLa- neither diroct no2 indiroc~ lii-,',-.s L~ u with intrusive roc,11-3. De:)Osits to the firot two -r,-,u~,s -~~3rc under coi,_d]-tiono of s11--arp clian's'-'o o~L te:n~erature: initial tem- perature in th- procasc of c-otallizatioln oC oress and lower tcI-Li:pc_catuze duri2v- ore for:-_.atuion Iroceos. Th415 ex-lains, tIA10 occ-i-,reace of -Dccaliar riineral ftrvis a:Ld ncral as2ociat-onc, as observed L in t1ae Da'I..,.),~;ta-,-'s'--y:re de.-osits. Tlic-sc deposi -c _u u a coi7i-IJca4-e s-rstc= of --ina-ali7,--' crib` .,: _i. u Lk Zones in tI.Ic sa_rx-1~7'lonc-slatc stratui=,.. Card, 2/5 'I.!aCI-_-tic fcrinati.321's of thr- de-oos-its, ocnzist of The '.70I,,-a.,_-,tabIo in Oro~: D" ti, Da1,netayo.,:,hnQ-r,, large L) tes .?.nd Tile Ore" ill 1-1-ain ta's of 'Ancrali -,"q L i oil ar-cono-pyrill-in L 11 o a 2) a.lu,lar cta,--~~, -ion o~' lat;e pyrite a7vll Vic, authr,:- doccrib-~r~ e ao7(.,- ciation of _F-ld-par an zeolitc ~.u ~I - -"~ ca.-, .4 '1 SCritC 2.10'701' ID,_)fCI'0 arc tion t , * - -: ' - 4 a, t d 3 0 -Idr ho, 'i rE:t 0 a - -Lun f - ma-T J. .-Ath, ores; -ocond tIm later oz-clocn, quartz. Bot-h Z3c-noratuici-1.7 Izavo tical -ohysical , optiz-71 ~mrdl ot-her feature-. T'111,:~ 1'C,,- -ults of all n_aal-rsec -ire -ivor.. I - dine I:n tha aut'Llor, analy:-,ot-, ;-,hov: a relaLicn and thie s.~,.I-c~4- '--like I'Or:-, WhIiCh in t7ie pr,~,;e:-~- of cryotallization of orev-, io re- laard 3/5 pl!lced by -Alular. Tho san-,in- iZ, a tel:-Ineratlu-e 3OV11-50, -515-0, The 'Tetastable Potassiu,--i and Zeolite in Crec of -V-',,.e Dal'netayozlmoye De-posit variety of the orthoclase. Th.~. pottlascium zeoiite- leonlharl'~ite is t1le p-rincipal corlipoacnit o~ tl-he c--as- erite-zeolite fillir- one of -the vein of the Dal'netaYo,z1).noyc dopooit, land i_- fou-.i(1 in pockets in SodidTiUone of ~1opo,,AU!-,. Th~, zoolite in these orer, ic clooely ascociated -uith ,iuartz, caSsiterite, arse-_-io-pyrites ~-id calcium-containin;-,- minerals: act-Liolite, fluorite, , ini!;-o an,- i dotes. In re-ara to all tl,ese th,_- zool-ite is xenomorpl,ic, fillin: 'he spaces be-.-.,aan the grains or enclosi- th,:-)r-.-, li'Ke -oi'_~Jlite phenocry-ts. These associatuiono, as well as the rotastable varieties of potassitna feld-spar, are indicatoL?s o1L shar .1 - U .p charZe of tej:,perature durinr:- tll,:) ore foi,_ mation procozo. These chan--es are explai.-_1.,,-,r' by CLI d specific featuros of the Genesis of t.1110 Dal'netay- ezhnoye deposit-s, probably formed near the plu- 4_ Card 4/5 Uonic, magmatiG sourcoo, their up,-)r_-r part The -,.*otactable Potassium, Zo(--l_i'u-(' in Oress of tuc Dn I.- netayezl-Lioye Deposit-; near the eai2'u-h'*s szua~face. The follio-ui-ac scie-n-UiStS are ment-ioncd by ',;he autlio-,-: A.'fc. -eers:7-,an, e2 -arl- (;.A. Sirloreriko, Academician D 3 mid L.Folupaiio-va. are _--)' luables, 2 j~hoto.r-;r-apla-7, anll I r~2feiences$ '~' of are 3ovi-at" and 1 % - ~ "Li c r i -- a-,--. . .i*'L;-)'SOC 1AT I OIT: Vsesoyuzn~rj i-Lstitut -~,-in- eral'no-o syr'ya (the All-Unlon Sci-entifin Institute of Lateril, ;-JU3',.'ITTE?.D- ITIlly 15 1957 ~-t -lard 5/5 VASILIKOVA, 11.11.) KUZs,',IIN, V.J. ---- -------- Alteration of datolite bearing Tocks in the zone of hypogenesis. 1~ Geol.rud.mestoromi. no.6468-71 N-D 161. (YIRA 14:12) 1. Vsesoyuznyy muchno-issledovatel'skiy institut minerallnogo syr-ya. (Datollte) VA.SILIKOVA_,_N. Nl~ Sibirskite,, a new calcium borate. Zap. Vass, min. ob-m 91 no.4r 455-464 '62. (MMA 15: 10) 1. Voesoyuznyy institut minerallnogo syrIya (VW), Moskva. (Calcium borates) VASILfKOVA, Nina Nikitichna; SOLOVIKIIIA, Soflya Grigorlvevna; 19MOVA, !.Ye., ved. red.; ROZHKOVA, Ye.V., rauchn. red. [Typomorphic characteristics of fluorite and quartz; on the basis of a study of their physical and physicochemical properties) Tipomorfnye osobennosti fliuorita A kvartsa; na osnovanii izucheniia ikh fizicheskikh i fiziko-khimi- cheskikh svoistv. Moskva2 Nedra, 1965. 132 p. (MIRA 18:10) LCKONOSOY, Ivan Grigorlyevich, starshiy nauchnyy ootrudnik; ARYKIN, -Regins. Yavgenlyevich; ZHURXNKOV, Ivan Grigorlyavich;_YAS4~kQLA, Tevgeniy Aleksandrovich; F. Mh&~a Petrovich; OVCHIM- .. .6 KOVA, Dina Mikhaylovna; YUZVU. Vladimir Yefimovich. Prinimali uchastiye: ARNIN, I.G., starshiy nauchnyy sotradnik; rjzvuK, V.ye,, starshiy nauchnyy sotrudnik; LKBRM , M.P., starshiy nauchnyy sotradnik; OVCHINNIKOVA, D.M., mladshiy nauchnyy sotrudnik; T4SIL"KOV#t R.Te.' mladshiy nauchnyy sotrudnik; ZHURRNKOV, Ye.A.. mladshiy naucEyi-sotmd- nik. ZHURAVLEV, B.A., red.izd-va; PARAIMIU, N.L., takhn.red. [Album of designs of dams to be built on timber floating rivers] Allbom konstruktaii lasosplavnykh plotin. Moskva, GoBlesbusirdat. 1959. 212 P. (MIRA 1-3:7) 1. TSentrallnvy nauchno-issladovateliskiy institut lesosplava (for all, except Zhuravlev, Parakhina). (lumber--Transportation) (Dams) ~ACC.NR, AP6013819 (A) SOURCE C01i: UR~0356/65/000/012/0049/0051 AUTHOR: Mamuliya.-G* (Engineer); Vasillknva, Ye. (Engineer) ORG:_ State All-Union Scientific Resea Institute of Technology for Rtqnair nnA Onpvni-Ann in ManhinArv AnA Trnettme Nq vsesoyuznyy nauchn-o_-~~_iss-_e ovatellskiy tekhnologlobeskiy Institut .remonta i ekspluatatsii mashinno traktornogo parka) TITLE: Weld!IUof machine parts and assembliea'in carbon-dioxide gas SOURCE: Tekhni Y sellskom, khozyaystvat n6., 12, 19659 49-51 ,TOPIC TAGS: 'Waildin,ge-quipment, -repair welding, are welding, automatic~weldingj spot weldings W-elding technology /_A7-5;4~9-R4 .welding equipment,,A-537 welding equipmentt EZG-4 welding equipment _. 'V~ - - k ID ABSTRAM, Welding methods used- for repairing agricultural machines are- discus-sad. The most ef0sative method is a semi-automatio electric .arc welding witb~&-_barbon-dioxide gas-shielding.- The-equipment used for this kind of,welding is described. A welding device of A-547-R type is applied to thicknesses up to 3 mm while thicker paAs are welded by A-537 type. These devices consist of an are torch, electrode-wire feed mechanismf control panel, carbon-dioxide gas cylinder.. preheater, 1/2 UDC: 621,7916037:-661*97 Card L 28849-66 ACC NPh AP6013819, .reotifierp eta. A-537 type is equipped with a water-cooled torch* The A-547-R type arrangement is schematically illustratbd; A special arrangement for spot welding and electric riveting is designed by using an electrio-aro riveter of HZG-4 type6 The essential data on these three types of welding equipment is summed up in a tabled The rocom- mendedwelding data for various metal thicknesses are also tabulated. The welding technique applied to various machine and tractor parts is' briefly discussed-and some efficient methods,are recommended. Orig. art., has:,3 tables and 1 figure. .None SUB CODE:- 13./ StMA DATE: A 77'11- if c v TA 1 4 4 -Y I a a-ft a trl n.7 We a! ;,a,3 lo rn -on 7 L ' 1- -7 , - A"CV-5SION JR: AP501 ~372 carotenoids in the presence of ethyl alcohol wLth 6 decrfaae in the caroteno~d: ~!hlarn-,)hvl 1 rat in 7ho oriAlw1riv, tit i it &,in i n? cl~,-,m is, irnhq?,.1v tn m~ '~ .1 * , . , " P, .; f I v i qP Orig. art. has 2 tablee. ASSOCIATIONt Y-wdwvaki-T gosudaratrG=yT uairensitet im. K. V. Lomormsova Oloscow State Uaiversity) SUBMITTED, 23Jun6-14 FNCL! CO SUB OODEi L-Q NO REY SOY : OCY? jPFZ CO'd GUSEVY M.V.; VASILIKOVA, Ye.l. Changes in the composition and content of pigments of blue-gre-er algae in the presence of additional carbon and nitrogen sources. Mikrobiologiia 34 no.3:477-482 My-je 165. (MIRA 18:11) 1. Biologo-pochvennogo fakullteta Moskovskogo gosudarstvennogo universiteta imeni M.V.Lomoncsova. A FWV san no AC 4 SOURCE CODE: UR AP6017696 76226T657634T603 47?/0482 A .AUTHOR: Gusev, Ho if*; AIS14 -30 ORG: Soil Biolog Faculty, Moscow State University ime No' I* Lomonooov (Biologo. Z11tet Moskovskogo gosudar nnogo unIveraltata) pochvenzwy f& TITIEt Change in composition and pigment content of blue-green algae in the presence of additional sources of carbon and nitrogen SOURCEs AN MR, Mikrobiologiya,'v. 34, no- 3, 1963, 477-482 TOPIC TAGS: 'ale", chiorophyll, protein, plant chemistry, plant metabolism :, Phycoerythrin appeared in the cells of the blue-green alga aTa.variabilis grown an a medium with additional sources of carbon K L(glucose, ethanol# or acetate) and nitrogen (nitrate or ramtonium salts). This happened even at light Intensities which are Insufficient for the- production of this pigment in a mineral medium without additional sources of nitrogen and carbon. In a similar situation no changes were noted In :the composition of Hapalosiphon fontinalis pigments. When Mabacna varlabills and Hapalosiphon foatinalis were grown In the _--presence of 3dditlonal sources of carbon and nitrogen% the following changes'- ___ lace n en 'took p ___thd__ con tent -and -rat loo -of-the- pi Gm tilt---(I)-the content of ball pigments decreased in the presence of nitrate; (2) the con-tewt of-- !bIlichromproteins and chlorophyll A Increased In the. presence of ammonium L 27420-66 ACC NR* AP6017696 i-dfd--tkd--btlichfi6nfo&o--t--e-in-t - -chi o-roph-y-if _A'ra_~ o; _(j)i -ilie 6~i ek of achlorophyll A and bilichromoproteins Increased In the presence of addltlona1 ,carbon compounds as did the bilichromoprotains chlorophyll A ratio., I .%to carotenoldi chlorophyll A ratio decreased in the presince of ladditional carboq_compounds in Anabaena 0 0 3 ta a __SUB__CO1DEs____jW__/_ SM DATE: 22Ju164 CIRIG REFs 006 OTH REFt 003 _LSard 212 ")10 LEONTIYEVp M.N,; prinimali uctiastiye- BAKINAl K.V.1- KISELEVAp O.M.; KRAVETSt Ye.A.j KARIDVAt S.A.; DUBNOVA, S.S.; SEMENYAWt A.G.; ZAMORINAt Z.T.; MIIAMAp Te.F.; KOZELISKAYA, O.P.;- '- VASILIKOVAt -Z.I,"OTOVp S.N.; YEWIDVt A.I.; BEZLYUDNAYAq V.Vd; _-HAff Effo- B.A.-' ASHIKBMINAq V.M.; ASYAIMA9 A.N.; TROITSKAYA' B.I.1 SUNMVp A.V.t red.; LESHAJIOVp I.T.p tekhn. red.9 [The economy of Orlov Province; a~statiatical mamial] Narodnoe khoziaistvo Orlpvskoi oblasti; st4,tisticheeldi abornik. Orelt Goestatizdatq 1960. 281 p. (MIRA 14:5) 1. Orel(Provinpe) Statistich9skoye upravleniye. 2. Zamestitell nachallnika s~atisticheskogo upravleniya Orlovskoy oblasti (for Leontlyev). 3. Statisticheekoye itpravloniye Orlovskoy ob- lasti (for all except Lesbakov) 4. NpLchallnik statisticheekogo upravleniya Orlovskoy oblasti (for Skvortsov (Orlov Province-Statistics) ASHBE111) S.I., prof.; FOKROVSKAYA, E.A.; SOKOLOVA, V.G., kand.bJol.nauk; VASIL I 1111VAj kand.med.nauk Flffectiveness of oletetrin ti-batmont of Infectious inflamatO17 diseases of respiratory organs and intestines. Sov.med. 28 no.U:91-95 D 165. (MURA 18-.12) 1. Klinicheskiy otdel (zav. - prof. S.I.Ashbell) Gorlkcvskogo nitLi(tlino-is,.,~ledovatzllr;kogo Inntituta gipiyeny truda, i professio- nallRykh vabolovarOy i hfodra dat,skikh Inroktaly (zav. - dol,ment N.N.Fayerman) Gorikovskogo meditsinskogo instituta. SVMOV, M.S.; VASILIKOVICH, LA. Using lignin as a fu,el. Gidrolis i lesokhim.prom. 13 no-2:15-17 l6o, (MIRA 13:6) 1. Tavdinskiy gl4rolizuyy zavod. (Idgain) SMORKALOV, V.T., red.; KARDASH, F.G., st. varahchik, red.; IVANOVA.. V.Ya., red., OJDAKOVA, Yu., red.; VASILIKOVICH, L.A., red.; GETLING, Yu., red, [Plant of miraculous transfonnations; everyday work of the employees of the Tavda Hydrolysis Flant] Zavod ehu-- desnykh prevrashchen-ii; trudovye budni kollektiva Tavdin- skogo gidroliznogo zavoda. Sverdlovsk, Sredne-Urallskoe knizhnoe izd-vo, 1964. 50 i;- (MIRA 18:4) 1. DirpVtor Tavdinskogo pirirnli~tnoprl -qvndn TTrA-1 (fAr Kardash). '). Pred.-:--A-1--' zavodskogo komiteta Tavdirtokogo gidrol:Lznogo zavoda, Ural (for lvaviova), 3. Sakretar, Vessoyumnogo Leninakogo Koummiaticheekogo awfuza molodezhi (foT Sudakova). 4. Nachallnik planovcgo otdela Tavdinskogo gidro2iznogo zavoda, Ural (for Vasilikovich). BORISOVA, A.G.; BOCHANTSEV, V.P.; BUTKOV, A.Ya., dotsent; VASILIKOVSKAYA A.P.- . m ZLG;'~~ VVEWSKIY, A.I., doti3ent; GOLODKOVSKIY, V.L.; GONGM07 . . (deceased]; DROBOV. Y.P.. professor; KCRCTKOVA, fe.Te.; XOSTIUA, K.Y.; KUDRTASHEV, S.N. (deceased]; IAKHIAA, H.M.; LI$CEUSKIT.I.A.; HIRONOV, B.A. (deceased]; PAZIY. V.K.; POYARKOVA, A.I.; PROTOPOPOV, G.F.; SUHNEVICH, G.P. [deceased]; KHALIZOVA. K.P.; YUZXPCHUK, S.V.; KOROVIN, Ye.P.. professor. glavnyy redak;tvr,;,ZAKIROV,..cX.Z., professor. redaktor; SEIPUKHIN, A.Ta, redaktor izdatelstva [The glora of Uzbekistan] Flora Uzbekistana, Glav. reds R.P.Rorovin. Tashkent, Izd-vo Almdemii nauk UzSSR. Vol-3. 1955. 825 p. (MLRA 9:10) 1. Daystvitellnyy chlen AN UzSSR (for Korovin) (Uzbekistan--Botany) PISIMAN, I.I.; DALIN, M.A.; VASILIKOVSKAYA, G.V. Dimerization of ethylene on nickel and cobalt catalysts. Azerb. khIm. zhur. no.3:69-74 164. (~fflr?A 18:5) S11301611000100510031005 A006/AlOl AUTHORS: Sviridenko, F. F., Kazachkov, Ye. A., Vasillkovskaya, N. F., Lesm- ko, I. I. TITLE: Riser with an air gap in the wall PERIODICAL: Metallurg, no. 5, 1961, 15 - 18 TEXT: Risers used at "Azovatall" for delayed cooling of feed head metal, are lined with chamotte bricks. The lining is 120 mm thick.. Heat insulating conditions can be improved by employing insulated bricks, and the best means of insulation for this purpose is air. Investigations were-imade to use the heat insulating properties of an air gap in the lining of risers. The use of shaped bricks, which is the simplest method employed at the KMK, was not possible at Azovstall due to the lack of a ceramic shop. Therefore, standard brick dimensions and shapeshad to be employed. The existing design of risers was modified by two methods: 1. In the shell of a conventional riser, 8 - 10 mm thick steel sheets were inserted and fastendd by elec#ic welding process in such a manner, that an internal shell was formed that was separated from the external shell by a 70 mm wide gap. The gap was lined with chamotte bricks. 2) A special riser was employed with horizontal ribs in the center of the shell height, supporting Card 1/4 Riser with an air gap in the wall 31130e 1/000/005/003/005 A006/AIOI the bricks. Between the brick lining and the shell there was a 60 mm wide air gap. Heat balances were drawn up for conventional and experimental risers and for this purpose the distribution of temperature along the wall thickness of the risers was determined. Heat losses in the risers are characterized as follows: Total heat losses through the feed head at the end of ingot solidifying, in %: of which: losses to the surrounding medium ' absorbed by the refracto- ries of the risers absorbed by the riser shell 100 22 56 22 air gap 59 45 24 31 Card 2/4 3113016110001005100310()5' Riser with an air gap in the wall A006/AlOl Improved heat insulation reduces the metal volume in the feed head and increases the ingot weight. The upper section of the ingot which is most contaminated with non-metallic impurities, can thus by out off. Experimental'castings made with the new risers showed satisfactory results. However, their large-scale production was impeded by the low stability of the lining. Therefore, a new variant of the risers was designed,(Pigure -',) where th6 uniform suspension of the ingot over the whole perimeter of the mold and riser butt line, is assured by an excess of the cross section of the riser (885 x 790) over that of the mold (865 x 770). Grooves, 50 mm wide, in the riser shell prevent the falling out of the upper rows of the lining, and 50 mm - diameter apertures are provided in the walls for the elimina- tion of gases from Inter4al cavities. Experiments showed that risers lined with straight bricks were not less stable than those lined with shaped bricks. Their use will reduce rejects due to contaminations with non-metallic impurities. There are 3 figures. ASSOCIATION: Zavod "Azovstall" (Azovstal' Plant); Zhdanovskiy metallurgiches- kiy institut (Zhdanov Metallurgical Institute). card 3/ 4 3/13016 1 10W100510-1031005 Riser with an air gap In the wall Aoo6/Aioi Figure 3: Riser with an air gap in the wall card 4/4 Puc. 3. npuduabHan MSACTSSKA C 503AYMHbIM Sm- 30PON o cTeuxe VASILIKOVSKIYI A'...'A_.~ - Dissertation: "The Progpagation Thin-Wall Plate." Cand Phys-Math Zhurnal--Fizika--Moscow, Apr 54) and Absorption of Radiation in a Many-layer, Sci, Odessa State U, Odessa, 1953. (Rererativnyy SO: SUM 243, 19 Oct 1954 USSR/Physics Optics. Reflection Card 1/1 Pub- 153-22/28 Author : Vasilkovskiy A. A. Title : Theory of optic computation of multiple periodic laminae Periodical : Zhur. Tekh. Fiz., 25, No 7, 1326-1331, 1955 FD-3213 Abstract : Formulas are derived for amplitude coefficients of passing and reflection and their ratios, applicable to optic computation of multiple laminae, con- sisting of periodically recurrent laminae combinations. Ten references, including 4 foreign. Institution: -- Submitted : July 21, 195k VASILIKOVMUY, A.A. wwa 1 1 1, K- Calculation of a thin, moltilayer plate as effective refraction index, Opt. i spektr. (Refraction) one-layer plate with n9,2:229-235 7 157, (HLRA 10:3) AM-Wks--fi~625595 souRcE cd-F,,ViY/6~ -~ -666-6-- f3 1661 31ff]W603~1~, INVISTORS. Vaaillkovskiy, A. A.; Nechipurenko, V. V.) Sokolenko, V, L ORG; none TITW-: Multilayer film Hall emf,detoctor. Class 21, No. 163248 SOURCE: Izobrateniya, prorqshlennyye obraztey, tovarnyye znaki, no. 139 1966, 33 TOPIC TAGS: Hall effect, hf component AB:*;TRACT: This Author Certificate presents a multilayer film Hall emf detector according to Author Certificate No* 119556. To use the detector for measuring high frequency power, capaoitors deposited between the current electrodes of neighboring layers are connected in parallel relative to the controlling current in the loops joining the remaining layers of the detector (ace Fig. 1). -171 ~2 Fig. 1.1 1 - detect layerp;: g, -, cappoi or VASILIKOV.-KIT, D.N., GOROVITS, T.T., SHTM, T.K. Nethods of producing prittR of thin wires by the use of polystyrene and quartz. Trudy SAW no.148S23-26 159. (MITRA 13-.7) (Electric wire--Testing) A Ov Translation from: Referativnyy zhurnal, Khimiya, 1 0, No. 2t, p. j6 AUTHOR. Vasil'kovskly, D. N. 77EEf!f~~~ TITLE: The Determination of Grain Orientation in Cubic System --rystals From Chemical Etching Patterns in Microscopical inve-,4tigations PERIODICAL: Tr. Sredneaz. un-La, 1959, No. 148, pp. 29-44 TEXT: The proposed method Ls based on the utilizaticn oil the I e v 41 -,-a polar coordinate system. In case of a fa,-ecentered cubic :rystal directions [100.1, [010], [00!-], in,-tually o-thogonal are --JIG eOJ7'e~ of 'L"-O patterns), the method consists �n the superposition of the the axes < 100 > with the center of the c-)c*---1ir nuliere 1rt su& 7.~. 7-: the image plane of the microscope &.:)uld 7.,i !~h tl~.e ef - 11equatorial") sphere circle ard !.-.hr~ '--f with the sphere surface shvild be the :,ol,~, of reckoning tn-~ specified choice of the ~oordlnate syztr:m reduce!7 thn prob.!~~-i of r J7 crystallographic Indices of the basic cir~D~ plane To the cealc~)latjo~ Card 112 Az 5V A cl_-~ i The Determination of Grain Orientation In. Cubic System.Crystals F'-)m j Etching Patterns in Micro!~copical Investigations if latitudes" of the mutwally othogonal Interseqtion points cf' 1-11,-.,~ axe's < 100 > from their knov.,r. longitudes ),., K,;,, ~-,- 'Phe --ion-, - L tion of the "north pole" of the srihere I~h W , the point of ~ts Ir .-Tsection primary akis and the application of thie Imo-oin fom,-~Iar of leads to'the required reation: c03 Pi = y is J~ ctg where-i=113-XI'l are the angles het,-,reen thi.- projectiong of' 'h~ etchin~r natt.-Sr- edgez- orito the microscope image ancl ;,:-i ;zi-bi,,n-y 1,raig,-i-7 lina in (as aci example, the thread axis in th,~~ on ~f -,hin wir-, ar,~ the latitudes of the intersection pointz of the Ryf--S With rhQ -;,nere, lar, the crystallographic indices o~' ~h- -thread --i.xls car: b-~~ formulae: cos 1, = sin p. Cos A J, %,,hpL*- I an, tn,3 axis and the cry~tallographical axe he more having a bodycentered c!ijbl:~, lattice i.,-, ,.ccomplisheil by th-~ of the successive determination of the r) e c ~, I- on ~,i of r he, ~- dRa!~, I - I rhomododecahedral etching patterns and th- .Jro,jr--~tions of tii~,,- -I..-.-. 4-iuf~ > Nomographs are added for the act,-:all corr"putaticn ti,.e tneor(~-7'-~~ -ae; ",i.: thr question of errors at their utilization iz, Translator's note: This is the fuli, tranzla-,Ao~, ef the orlglna~ I~Oissi-ir. Card 2/2 21585 S/log/6o/005/010/008/031 (a2s~/ 1160.., 116V~ /2 rrs-) E24o/t4 35 AUTHORSs Azizov, U.V., Vasilukovskjy, D.N. and'Sultanov, V.M. TITLEs The Prepar,ation and Indexing-of Large Monocrystalline Tungsten Cathodes PERIODICAL: Rad-iotekhnika i elektronika, 19609 Vol.5, No-10, PPJ631-1635 TEXT% This paper was presented at the 9th Ail-Union Conference on Cathode Electronics in Moscow, October 1959. Methods are described for making large single --ry5tals of tungsten from which tan be made flat, spherical or cylindrical cathodes. Such cathodes are required for experimental work, as for example the measurement of work functions, heats of absorption and the study of surface diffusion, It was found that a fine-grained tungsten powder was necessary as a raw material, for beat results. The following process enabled powders with an average grain size of one micron to be preparedl industrial grades have mean grain sizes of several microns. A quantity of tungstic anhydride is reduced in a nickel boat, which Is drawn through a hydrogen tube furnace with a range of temperature increasing from 550 to 9000C. During Card 1/6 21585 s/log/60/005/010/008/031 The Preparation and Indexing E240/E435 this process an unspecified amount of the anhydride is reduced to 50 9 of tungsten. The tungsten powder is then pressed into rods, after sieving, which are then sintered for 5 hours at 800 to 900*C. Difficulties were experienced due to water vapour contamination of the furnace hydrogen supply, and an increase in temperature which occurred. It was found that the best crystals grew In the parts of the rods where the temperature gi-adient was greatest, i.e. at the ends. For this reason, the rods were shortened from 500 to 120- 220 mm. Their cross-sec*~ions ranged between 11.4 x 6~8 mm and 11.4 x 10.2 mm. To obtain the largest r-rystals, it was found necessary to increase the sintering time, while maintaining a slow rise In temperature. Details are then given of the next stage of the process in the course of which currents up to 3600 A are passed through the rods for 2 hours followed by cooling for 5 minutes. The reader is referred to earlier work (Ref.1) for a more detailed description of the technique, It was found that about 10% of the rods contained single crystals 2 to 5 cm in length, which occupied the whole cross-.section of the rod. In the majority of the remainder, smaller crystals were obtained, which were sometimes separated by fine-grained metal. No consistent Card 2/6 s/iog/60/005/010/008/031 The Preparation and Indexing ... r,240/E435 rules appeared to govern the orientations of the crystals within the rods. The crystals'can be picked out by the naked eye, after the surface has been etched. Some mosaic structure appears on the surfaces of the crystals, accompanied by a change in ! crystallographic orientation; however, this is less evident if' several microns of metal are first removed. The dimensions of the mosaic elements are of the order of three to seven microns. Pores were also discovered within the metal. The hoinogencity of the crystal may be judged by means of the Schottky effect. The specimen is inspected before and after heat-treatment; however., the appearance of a wavy structure on the surface may cause complications. A discussion then follows on the X*'-!ative stability of various facets of a crystal and reference is madc to the work of I.N.Stranski and R.Suhrmann (Ref.3) who postulated the additivity of interatomic forces, and that they decreased rapidly with distance. The surface energy of a facet, being a function of the number of broken bonds, will increase with any deviation in its orientation. The following expression for the surface energy density may be obtained: Card 3/ 6 C, )9/60/005/010/008/031 The Preparation and Indexing ~31"p S, sin( + 1cosp- ~.) Bill Bill P Gill (st M + E3 2 ~B)jj S, sin S- 1~11IS3 where p and X are the polar angle and width defining the inacro-orientation of the facet under consideration. The specific surface energies of the stable facets closest to it, with coordinates (0, 0), (S2, 0) and (S3, Sl), are correspondingly equal to El, E2 and E3- It is noted that the value of Ei, the interatomic force, does not affect the form of the equation. From this it is shown that it is theoretically possible for a stopped crystal structure to occur; but this is rarely found in practice. Further, it is argued that it is better to cut crystals' to the desired form, rather than to rely on existing facet surfaces. A method for producing large single crystal tungsten cathodes by mechanical working is described by S.T.Martin (Ref.4: Phys.Rev., 1939, Vol-56, 947). However, the authors found that electro- spark cutting, followed by polishing and electro-polishing, gives Card 4/6 21585 s/iog/60/005/Olo/oo8/031 The Preparation and Indexing E24O/E435 a far less laborious method of preparing cathodes. This method enabled'a I cm diameter hemispherical cathode to be made for the Martin projector in a few hours, as opposed to the 4- 5 weeks required for the mechanical machining method. A brief description is then given of various methods for determining the crystallographic orientation of a crystal. This can be done either by etching the cry tal ich given rise to clearly-visible marks bounded by the fac:t ~il'oj . By measuring the angles between these marks the spatial orientation can be defined (Ref.5). To find the tilo) facett a light-reflection method can be employed, while if the (100) facet is required, the cleavage of the crystal along this plane can be utilized., Such a fracture is readily distinguished from the conchoidal intercrystalline fracture. A suggested explanation of the fact that the crystal tends to break along the (.100) plane, rather than the (1101 plane, is then given. It woiLld be expected', from energetic considerations, that cleavage would occur preferentially along the latter. It can be shown that one dislocation with a Burger's vector of a r1001 is more stabl th n an equivalent pair of dislocations with a ~L) a vectors I and 1[11T] If it is postulated that a cleavage Card 5/6 21585 The Preparation and Indexing is the result of a series of from the above it is evident [100) plans, as it does. 2 Soviet and 3 non-Soviet. s/iog/60/005/010/008/031 ... B240/t435 similar linear dislocations, then that the fracture will occur in the rhere are 4 figures and 5 references: SUBMITTED: December 21, 1959 Card 6/6 0% 3/161/62/004/001/015/052 B125/B104 AUTHORSt Vasillkovskiy, D._N., and Tadzhiyeva, E. M. TITLE. The occurrence of a particular surface structure on wires annealed with direct current PERIODICALt Fizika tverdogo tela, v. 4, no. 1, 1962, 90 - 95 TEXTt According to Shmidt (G. N. Shuppe. Elektronnaya emissiya metallicheskikh kristallov - Electron emission of metal crystals - Izd. SAGU, Tashkent, 1959), there exists a relationship between the surface structure formed by vacuum annealing of drawn tungsten wires for 20 to 30 min at 20000K and the orientation of the original structure. The axis of the wire is a second-order axis of symmetry of the new structure. The size of the steps formed on the surface during annealing is dependent on the temperature of their formation. To investigate these phenomena more closely, pieces of tungsten wire of the type ISA-3 (VA-3) with an initial diameter of 1701b were electrically polished, and annealed at 2000 - 26000K for 10 - 300 hrs. Microscopic examination (magnification, 500 - 2000 times) of the surface of several dozen wires with the aid of a goniometric Card 1/4