SCIENTIFIC ABSTRACT VDOVENKO,K B. - VDOVENKO, N.V.
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CIA-RDP86-00513R001859210013-1
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S
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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Body:
VOLOKITIN, I.; VDOVENKO, B.
Wings are strengthened in flight. Grazlid.av. 20 no.11:2 of cover 1-3
N 163. (NIRA 17:2)
1. Spetsiallnyye korrespondenty zhurnala "Grazhdanskaya aviatsiya".
ADTHOR: Semenov, V. and Vdovenko, B.
TITLE: Designers of Radio-Controlled Airplane Models
Wonstruktory radioupravlyaemykh modeley)
PERIODICAL: Radio, 1956,Nrl2, insert page (USSR)
107-12-1/46
ABSTRACT: Hundreds of young people, members of DOSAAF, construct radio-controlled
flying models in their leisure hours. Petr VelichkOV8kiy from Alma-Ata
has become the world champion when his model has flown for 3 hrs 6 min
and 38 see. The photo shows him controlling on 28-29 me his model for
100 m against the wind and for 150 m. with the tail wind. Boris Kochetkov
from Kuznetsk town, Pensa oblast , built a model that flew 2 km 400 m,
in a straight-line route.
The 1956 All-Union Contest of flying models attracted many amateur designers
from Moscow, Leningrad, Alma-Ata, Sverdlovsk and other cities. Three photos
show the designers and their models. In addition to the above mentioned,
the outstanding designers were: N. Drozhzhin (Moscow), L. Teplov (Rhaftov),
A. Erler (Leningrad), S. Malik (Moskva), Yu. Shchegolev (Sverdlovsk).
AVAILABLE: Library of Congress
Card 1/1
AUTHORS: Prokoflyev S., (text) Vdoven ko, B., (photos) 85-9-17 /33
TITLE: A Visit to the Promoters of the All-Union Competition of
Aerolubs (U Initsiatorov sorevnovaniya aeroklubov)
PERIODICAL: Kryllya Rodiny 1357, Nr 9, inserted colored sheet between
pp. 16-17 (USSR
ABSTRACT: 22 photos of the members of the Serpukhovskoy aeroclub
at their routine exercises, showing also nome of the
material equipment of the aeroclub. The text accompany-
ing the photos offers brief and fragmentary Information
on the members represented in the photos and comments on
theIr activities. Stressed are; the strict discipline
maintained at the aeroclub by its head S.M. Nefedov; the
Importance the members of the club attach to the sports
as a means of developing their physical condition ; and
the fact that the members of the aeroclub'participate
actively in the political work (obshchestvennaya rabota).
AVAILABLE: Library of Congress
Card 1/1
V C C
Subject
Card 1/1
Authors
Title
USBRAeronautics - Training (sports) AID P - 4457
Pub. 58 - 4/10
Vdovenko B., and M. Semenov
A Primary Organization of the DOSAAF at Work
Periodical Kryl. rod.., 1, 6-7, Ja 1956
Abstract The article describes the day-to-day work of a DOSAAF-
sponsored Parachute Circle functioning at an unnamed
machine-building plant, and contains some advice as to
the organization of work in-such-Circles. Six photos.
Institution None
Submitted No date
VDOVE,NKO, B.
Watch in Arctic Region-4. Kryl.rod. 13 no.ltl6b-16e Ja f62.
(MIRA 15:2)
(Arctic regions)
VDOMMO, B. 14.
"Application of Radioactivity 14,-thods In Analytical Ghemlatry,"
a paper submitted at the Conference on the Application of Radioactive Tracers in
Chemistry and in the Industry, Leningrad,30 Oct-1110V 56.
SIM: 1345 P - 95
ACC NRi AT7006973
SOURCE CODE: U
AUTHORS: Baydal, X. Xh.; Ydovenko2 G. N-
ORGt none
TITLE: Refinement of a computational miAhod for predicting rain on the basis of
pressure maps
SOURCE: Alma-Ata. Kazakliskiy nauelmo-issledovatellskiy gidrometeorologicheskiy
institut. Trudy, no. 25, 1966. Voprosy moteorologii (Problems in meteorology)., 12
TOPIC TAGS: weather forecasting, atmospheric pressure., atmospheric temperature
ABSTRACT: The authors have sought to refine a method for predicting rain proposed
by them in 1963; application of the method to Frunze and the plains of Kazakhstan
has also been considered. The method is based on daily changes in relative topography
of pressure maps (300/500,, 500/700., 700/1000) and the dew-point deficit at the 700-
millibar level. Improvement is introduced by considering advaction and the change
0
in dew-point deficit from the 700-millibar level to the 500- and 300-millibar le--'-.
A good indicator of rain is a sharp decrease (more than .50) in the dew-poin. !-tacit
from one level to the overlying level, but there must not be a reversal in going on
to the next level. Several actual examples of observed dtta are consideredy and the
results are encouraging. With consideration of this new modification, and on the
ACC NR, AT7006973
basis of tests) 84-86% reliability is attainable,. if the procedure is strictly
followed. Consideration of advection., in conjunction with the other refineaents)
should provide'even better results, but radiosonde data are necessary, and those are
too meager in the investigated area. If advection is weak, the sonde must be used
at the site where prediction is desired. The authors conclude that their proposed
refinements improve reliability., but that more refinement is possible and necessary.
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5W SOV/'i53-2--3-7/29
AUTHORS: Vdoven-ko, I. D., Kudraq 0. K.
TITLE: On a New Method of Investigating Diffusion Processes
PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Xhimiya i khimicheskaya
tekhnologiya, 1959, Vol 2, Nr 3v PP 345-351 (USSR)
ABSTRACT: The determination of diffusion coefficients according to the
hitherto used methods, some of which are mentioned, still
leads to considerable errors because the temperature can be
kept sufficiently constant only with difficulties. For this
reason the authors used for the determination according to
Skobets and Kavetskiy (Ref 11) the current impulse which
occurs in switching on the electrolysis. The electrolytes were
solutions of CUSO4, ZnS04' C(L904 and AgNO, of differeAt concentration
(Table). The current density and the period until the
occurrence of the first cathode precipitation wire measured.
A measuring device was developed which is shown by a-scheme
(Fig 1)~ Formulas for the computation are deduced. Moreover,
test series are carried out in which spherical instead of
cylindrical cathodes are used. It could be proved that during
Card 1/2
On a New Method of Investigating Diffusion Processes SOV/153-2-3-7/29
the first seconds of eleatrolysis the rule of the linear
diffusion holds irrespective of the shape of the electrode.
There are 2 figures, I tableg and 16 references, 6 of which
are Soviet.
ASSOCIATIONt Kiyevskiy politekhnioheskiy institut - Kafedra iizichaskoy i
kolloidnoy khimii (Kiyev Polytechnic Institute - Chair of
Physical and Colloid Chemistry.)
SUBMITTED: March 19, 1958
Card 2/2
~PQMKO, 1. D.; KUDRA, 0. K.
Effect of the nature of the solvent an the diffusion of
electrolytes. TJkr. khim. shur. 28 no.3;323-326 162.
(MMA 15:10)
1. Kiyevskiy politekhnicheskiy institut.
(Solvents) (Electrolyte solutions)
VDOV~NKOY I.D.; BOGACHEVA, N.A.
ce of indium-tin-thallil= allol*
Investigating corrosion resistan 62. (wRA 15:9)
l4ashinostroenie no.4t%_72 Ji-Ag
1. Akademiya nauR UkrSSR, Vin alloYs--G orro,ion)
VDOVEIIKO, I.D.; KUDRA, O.K.
Method of studying diffusion in electrode layers in the absence
of a current. Ukr.khim.zhur. 26 no-1:36-40 16o. (MIRA 13:5)
1. Kiyevskiy ordena Lenina politekhnicheskiy Inatitut.
(Diffusion) (Electrodes)
VDMITTIKO, I. D.
VDO::`ENr,O, I. D. -- "A New Llectrochemical Method of Irivt!~_f,4 -at i r p
Solutions." Min Higher Education USSR. ' Kiev Ord--, of Lenl.ri --rlrteci-n.4c Inst.
Chair of Physical and Colloid Chemistu. KJ ev, 1955. (Di,-zertation for -the
Degree of Candidate in Chemical Sciences)
SOURCE Knizhnaya Letopis', No 6 1956
VI~PYTNKO, I..D.; GRATSIANSKIY, N.N.
Effect of organic additions on the corrosion of binary alloys of
nonferrous and rare metals in aggressive media. Ukr. khim.zhur.
29 no.9:983-987 163. (MIRA 17:4)
1. Institut, obshchey i neorganicheskoy khimii AN UkrSSR.
VDOVFIIKO,, N.V., kand.tekhn.nauk; VDOVENYO, J.D., kand.tekhn.nauk
New method of chemical degreasing. Yashinostroenie no. 2:
66 Mr-Ap 164. (MIRA 17-5)
(- KUDRA, 0,K, processes. jzv.vys.u-chob*
New methode of i.vestigatiag diffusiOt' (MIRA 13:8)
zav.; khim-i khim-tekh. 2 no-3:345-351 '59- 1
1. Xiy,,,kiy politekhalcheskiy Inatitut, kafedra fizicheskoy
kolloldnoy khimii. (Diffusion)
GRATSIANSKIY,'N.N.; VDOVENKO, I.D.
Formation of a lead sulfate film on an In-Fb alloy during corrosion
ift Sulfuric acid solutiono Zhur.fiz.khim,, 35 no,6zl2M-1211 Je 161.
(MIRL 14:7)
1. Akademiya, nauk USSRj, Institut obshchW i neorqanicheskoy Ichimii.
(Ind.limk-lead alloys-, Corrosion) (Lead sulfate)
AUTHOR6;
2iTLE:
PERIODICAL:
6/185/62/007/010/.011/020
D234/D308
11ratuians1kyy, I.I. V., Vdovenko, 1. 1). and Baturyns'ka,
Formation and structure of corrosion 6urface layers
in In-Pb and Fe-Ni alloys
Ukrayinalkyy fizychnyy zhurnal, v. 7, no. 10, 1962,
1118-1123
TEXT: The layers were sludied by the x ray method, using charac-
teristic Fe wavelen.-~'ths 1.9321 Xx and 1.7514 Kx, on both rotating
0
and fixed samples. Corrosion unstable in In-Pb has a layer of
PbSO4 on the surface, a thin layer of.nea:rly pure Pb below it and
finally a solid, Pb-enriched In-Pb solution. Up to the depth of 2
microns two cubic lattices are observed. Corrosion-stable Tn-Pb
-possesses similar surface layers. in Fe-Ni alloys lattice parame-
ters do not change and new lines do not appear: ~jtable alloys ex-
hibit the Ni lattice and unstable alloys the Fe lattice. Thickness
--and composition of the layers were studied in previous papers by
Card 1/2
6/18;5/62/007/010/011/02 0
Formation and structure ... D234/D308
the first of the authors et al. '-Chere are 2 fi-ures and.2 tables.
ASSOCIA'XION: 1natytut :~ahaliioyi ta neorhanichnoyi k1iii-Ayi AN ULU"',
Xyyiv (Institute of General and Inorganic Chemistry
JILS XLiev)
SUBI,II12TED: March 31, 1962
Card 2/2
27679
S/07 61/027/005/003/004
0 1 B103YB101
AUTHOR: Vdovenko, I. D.
TITLE: Investigation of the resistance to corrosion of indium - tin
alloys
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 27, no. 5, 1961, 629-633
TEXT: The resistance to corrosion of the indium - tin system in different
media was studied, since dataavailable on this subject are insufficient.
The alloys ncs.1 - 10 were used, which were produced from pure metals and
contained: 1,0; 3.0; 12.5; 25.0; 37.5; 50.0; 62-5; 80.0; 97.0, and 99.0
atom% of tin. They were molten under a layer of anhydrous glycerol. The
samples were pressed to disks (diameter 16 mm, thickness 80 - 100p.), and
then annealed. The purified samples were immersed in 500 ml of the
corroding solution. The corrosion tests took 14 days at room temperature
and with air supply without stirring. The following corroding solutions
were used: chemically pure 1, 20, and 60% H2SO 4 solutions, 5% HC1, or 3~o
NaCl. The resistance to corrosion was estimated from the loss in weight
2
of the samples in glem hr and from the change in appearance.. At the same
Card 1/4
27679
S/073/61/027/005/003/004
Investigation of the... B103/B101
time, the potentials of the alloys were measured by the compensation meth-
od with a TMTB_1 (PPTV-.l) potentiometer. The potentials of the alloys nos.
1 - 7 andthe potential of pure indium in I and 20% R2SO 4 were found to be
more negative than those of pure tin and of alloys rich in tin. The poten-
tial is shifted toward negative values with increasing acid concentration.
In the afore-mentioned concentrations the potential drops at the beginning
of corrosion (within 3 - 4 hr) in all alloyst and then remains nearly con-
stant during the whole corrosion time. This is explained by the formation
of an unsoluble film of corrosion products. The higher weight losses in
1T. H2SO4solution as compared with 20% solution may be due to the formation V~
of a permeable film in the former case. In 60/1) solution, the alloys are
dissolved without any film formation. The course of the curves potential
versus time of corrosion in the two other corroding media is analogous to
that in H2SO4 solutions. In HN, the potential approaches that of a
nobler metal owing to dissolution of the less resistant, and increased
concentration of the more resistant component on the surface. In NaC1,
the change of the potential in direction of that of a nobler metal is due
to film formation. Corrosion losses largely depend on the physicochemical
Card
27679
S/073/61/027/005/003/004
Investigation of the ... B103/B101
conditions of corrosion. In dilute 112S0 4 solutions, the corronion losses
of the alloys depend only slightly on the composition. On the other hand,
the curve of weight losses in 60,j', H2SO4 solution shows three abrupt
breaks. They correspond (1) to the alloy with N3 atoW/1~1 of tin (due to
increased corrosion), (2) to the alloy with N20 atorri-ja (decrease in
corrosion), (3) to the alloy with 65 atoe/o (higher decrease in corrosion).
(1) corresponds to alloys with a-Rhase, (2) to alloys with ~-phase, (3)
to the range of existence of the I& + phase. Consequently, the limits
of corrosion resistance correspond to the phase transformations in the
alloys. Such a difference of the corrosion resistance depending on the
composition of alloys is explained by their structural characteristics.
The existence of different phases promotes the formation of sections of
different electrochemical properties. The dissolution of In-Sn alloys.
which is comparatively moderate in H 2S0 4solutions of mediujn concentration,
markedly increases in H01 solutions, owing to the high corrosion activity
of the chloride ion,. In analogy with the corrosion in 60% H2SO C a sharp
limit of corrosion resistance is found in 5% HCl. It corresponds to the
Card 3/4
27�79
S/07~/61/027/005/003/004
Investigation of the ... B103 B101
alloy with rJ70 atonfj'~' Sn. The weight losses in alloys with 0 - 70 atoej,
Sn are located on a straight line parallel to the abscissa. The absolute
values of these losses are equal to those of pure indium. Hence, the
alloying of tin with 30% of indium highly increases the corrosion resist-
ance of the former. The corrosion losses of the alloy in 3% NaCl solution
are only fractions of those in HCl and H 2SO 4* Accordingly, corrosion
processes largely depend on the nature of anions and cations. There are
8 figures, I table, and 5 non-Soviet references. The three most recent /Y
references to English-language publications read as followst G, Colin,
C. G. Pink et al., Trans. of Electrochem. Soc 12~ 463 (1939);
C. G. Pink, E.. R. Jette et al. ibid.. 88, 229 6,945); F. Rhines,
W. M. Urquchart and H, P. Home, Trans. Am.. Soc.. of Metals, J2 (1947)-
ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN USSR (Institute
of General and Inorganic Chemistry AS UkrSSR)
SUBMITTED: September 28, 1960
Card 4/4
S/073/62/028/008/002/002
A057/A126
AUTHORS, Vdovenko, I. D., Gratsianskiy, N. N.
TITLE: The effect of surface-active substances upon the corrosion of indiun
tin, and Indium-tin alloys
PERIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 28, no. 8, 1962, 991.- 995
TEXT: The effect of adding small quantifies (0.094 resp. 0.265 g/1) of
mixtures of heptyl and octyl amine, of decyl and dodecyl amine, and of octyl
amine on the corrosion of indium, tin, and their alloys (50% In, or 20% in) was
investigated In 60% sulfuric acid solutions by the method of cathodic and anodic
polarization curves. These admixtures caused a shift of the cathodic polariza-
tion curves towards negative potentials. The-shift of potentials is explained
by a decrease In the rate of the cathodic reaction, i.e. an increase of th6 over_
voltage of the hydrogen ion discharge. This is due to the formation of dense
.adsorbed layers of the surface-active organic compounds on the surface of the
electrode. Corrosion inhibitors with a specific adsorption on the metal surface
show the greatest effect when the potential of the electrochemical reaction is
Card 1/?
3/073/62/028/008/002/002
The effect of surface-active substances upon... A057/A126
similar to the potential of the neutral point of the electrode metal. in the
presence of amine decreases also the diffusion and self-dissolving current.
This is apparently due to a barrier effect of the surface film formed. No ef-
fect of the investigated admixtures was observed on the anodic process. Thus
the examined corrosion process is generally controlled by cathodic reactions.
There are 9 figures.
ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN USSR (Institute of
General and Ihorganic Chemistry, AS UkrSSR)
SUBMITTED: July 19, 1961
Card 2~2
,9/r,73/62/028/009/005/01'.
A057/A126
AUTHORS: Vdovenko, I. D., GratsiansRiy, I. N.
TITLE; Corrosion resistance of indium, tin, and Indium-tin alloys In the
presence of surface-active substances .
PERIODICAL: Ukrainskiy 1rhimicheskiy zhurnal, v. 28, no. 9, 1962, 1069-- 1072
TEXT: At the Institut obshchey I neorganibheskoy khimii AN USSR (Insti-
tute of General and Inorganic Chemistry AS UkrSSR) corrosion properties of in-
dium, tin, and their alloys were studied at room temperature in 60% H2SOj, in the
presence of the surface-active substances heptyl-octylamine, decyl-dodecylamine
mixtures, or octadecylamine at various concentrations (0.094 and 0.265 g/1). A] -
loys of the following composition were studied (in at%); 99.0, 97.0, 87.5, 75-C
62.5, 50.0, 37.5, 20.0, 1.0. The tests were carried out with disc shaped
samples 80 - 100/ithick, measuring during 12 days the stationary potential, and
the corrosion rate was determined gravimetrically. The electrode potentials
shifted towards negative values after the addition of the amines, apparently due
to the formation of an inhibiting film which aPfects the cathodic processes. The
Card 1/2
S/073/62,/028/009/005/011
Corrosion resistance of indium,... A057/A126
gravimetric measurements showed a considerable inhibi'.-.on of the corrosion by
the investigated amines, This effect increases with the..concentration of the
amines. The change of the corrosion Irate of the alloys occurs with alternations
of their structural state i.e. phase transitions. Minimal corrosion was observed
in the region of '?- and ,--phases. The formation and structure of surface layers,
formed during the corrosion process, depend an the concentration of the added
inhibitors. An increase of the latter effects a drop of the relative content of
tin or a rise of the indium content. Hence, surface active substances may in-
fluence the formation of corrosion surface layers in dependence of the concen-
tration and nature of these substances. There are 4 figures.
ASSOCIATIO14: Institut obshchey i neorganicheskoy khimii A11 USSR (Institute of
General and Inorganic Chemistry, AS UkrSSR)
SUBMITTED: September 16, 1961
Card 2/2
4651
7
S/076/61/035/006/001/013
C/1 ~ 0 C, B127,/B20-3
AUTHORS: Gratsianskiy, N. N. and Vdovenko, I. D.
TITLE: Formation of lead sulfate films on an In-Pb alloy during
corronion in sulfuric acid solution
PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 6, 1961, 1208 - 1211
Tl,,'XTt The authors describe the treatment of an In-Pb alloy with 1~- Sul-
furic acid. The alloy was obtained from chemically puro lead and indium
fused together in vacuum, the mixing ratio was 55 atom% lead : 45 at04
indium. A resistant layer was found to form on the alloy surface due to the
deposition of poorly soluble corrosion products in the form of lead sulfate.
The object of the present paper was a study of the formation process of this
layer. The formation of the film was observed with the aid of S35 in Sul-
furic acid (1120504 ). The activity of the film was measured with an
MCT-MMST-17) Geiger counter. It was observed that the layer grew rapidly
at the beginning, but the rate of growth decreased more and more until it
Card 1/2
S/076/61/035/006/001/013
Formation of lead sulfate ... B127/B203
came to a standstill. The layer thickness was empirically found by the
n
equation: x = kt; x denotes the layer thickness, t is the time of
corrosion, and k and n are constants equal to 0.018 and 1.5 so that the
equation now reads: x1-5 . 0.018t. Tho layer thickness was equal to 0.5(4.
The authors conclude that the stability of the In-Pb alloy is conditioned
by the formation of a corrosion-resistant layer of poorly soluble corrosion
products on the surface of noncorrodible layer consisting of lead atoms and
the solid Pb-In solution concentrated with lead. There are 3 figures, 1
table,and 4 Sdviet-;bloc references.
ASSOCIATION: nauk Institut obshchey i neorganicheskoy
'0
khimii (Acadenly of Sciences UkrSSR, Institute of General and
Inorganic Chemistry)
SUBMITTED: August 3, 1959
Card 2/2
VDOVENKO', I.D.; BUSHIN, V.V.
Gorroolon reolotance of irAluz-tvin allOYs In sulfuric acid.
Ukr. kh1m, zhur. 29 no,ID1222-1223 163. (KIRA 16t12)
1. Institut obshchey I neorianicheakoy khimii AN Uki6SR.
ACCESSION IM. AP4022108 B/00D/6k/03o/003/oe*7/oe52
AMHCIR: Vdovenko,, 1. D.j Kovalevskiy., V. 1.
TITLE: Investigation of the corrosion of indiin-antizony alloys
SOURCE: Mcrainskly khimicheskiy zburnal,, v. 30, nO- 3# 1964j, 247-252
TOPIC TAGS : indium antimony alloy., corrosion, corrosion activation, InSbj electric'
potential, rate of solution, stable passive film, homogeneous allOyp electrochem-
ical property.
ABSMIACT: This study was conducted to accumulate experimental data regarding the
behavior of In-ft alloys in aggressive media and to correlate this behavior to the
chemical composition, structure and nature of the reagents. The corrosive behavior
of In-Sb alloys was studied in acid (HC1 and H2604) and in alkaline (NAOH) media or
different concentrations. The corrosion rate of in-rieb alloys Is greatest in HClL,,
the chloride ions apparently activating the corrosion. The rate of solution of
Ia-Sb alloys is in accord with the phase diagram., the most stable being the; homa-
geneouB alloys containing the chemical compound luft. The minimum corrosion rate
is shown by Sb-rich alloys. The potentials of several alloys were also measured.
Card 1,12
Acassioff NR., AM221W
As a rule good correlation is noted in acid media between the corrosive and the
electrochemical properties. Improvement in the potential is accompanied by a
decrease in the rate or solution of the alloys. In In-rich alloys the potential
assumes a negative value and with increasing Sb content the potential becomes
positive. The rate of solution in alkaline solutions is minimalr possibly due to
the formation of stable passive films under the influence of atmospheric oxygen.
Orig. art. bag: 7 figuree and 1 table.
ASSOCIATION: InBtitut, obshchey I neorganicbeskoy khimii AkademijL nauk Ukr= Usti-
:tute of General and Inorganic Chemistry,, Academy of Scienceq; Ukx6u)
SURU=.- 1&%Y63 DATE ACQ-. 09Apr6k IBM: 00
SM CODE: ML We FdW. SOT: 005 002
Card 2/2
VDGVENKO, I.D.
Automation of time determination in the electrocheatical
measurement of the thickness of films on metals. Ukr.
khim. zhur. 30 no.4t418-419 164. (MIRA 1716)
1. Institut obshchey i neorganicheskoy 1,11imii All LJk-.-SSR.
_YWNKO, L.I.- ROYRV, L.M.
Effect of surface-active agents on the evaporation velocity of drops
of a solution and the condensation of water vapor on them. Trudy UkrNIGK
no.47sl7-21 165. (MIRA 18:7)
1. KNIGINA, G.I.: ANTSELFNICH., V.I.: VDGVR:KO, I.S.
2. USSR (600)
4. Yuznetsk Basin - Building 'Materials
7. Building materials fmm burn ores of the Kuznetsk Basin.
Ugoll 27 No. 10, 1/052.
9. Monthly List of Russian Accessions, Library of Congress, January 1953. Unclassified.
1. KNIGINA, G. I. - ANTS=ICH, V. I. : VDOVENYO, I. S.
2. USSP. (600) 1
4. Building Materials - Kuznetsk Basin
7. Bui-Idi-ng materials from bum ores of the Kuznetsk Basin. Ugoll 27 no. A, 1952
9. Monthly List of Russian Accessions, Library of Congress, J"Ijarg -1953. Unclassified. I
MMRA, O.K.; VDOVENKO. I.D.
Blectric timer method for the analysisof solutions. Ukr.khim.
2hur. 25 no.1:25-31 159 (MM 12:4)
1. Kiyevskiy ordena Lenina politekhnicheakiv. institute
(Blectrochemical analysis)
SMIRSHACHRYA, L.I.; VDOVENKO, K.G.; MUZYUKINA, T.K.
Comparative evaluation of various methods for taking material to
be tested for dysentery. lAb.delo 2 no.2:25-26 Xr-Ap 156. (MIRA 9:10)
1. Is baktariologichookogo otdela Kuybyehavokoy gorodakoy eanitarno-
apidemiologichookoy stantaii.
(DYSENTERY)
Ge 0-0 0 0 0 0 0
0
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v I I I - . - - A
00 4 A40 LI!L el?(.Itt t's 0
PSOCISIrs A-0 PIN 10141 -W.
goo
sklwiu-mt of UM No. I BlUt-7maft at the X&CMINCOnk -00
Stalin MstaguxtW WorkL (). Pitrovskiv.M. N~lvvvnkov and A.
Drvulsitt. (Stal, 1040, No. 10, 131). (fit- Itoodlan). A
got tit;ie-tnblo isgiven oftho blowing-out provem which wasevirrit4l out
itholit the addition of Anv Insterial to fill fill, eullit %. pl)"ter in the
it. tho I'lirtimm
turlinve its file lal"Ien wim ~%IIIIIIIIIIV411. vor Ishm ilia m'
RM 11111111. IIIP Ilitildt-0 RRM lk-ing tilloued
to e'tcapo to atinomplivre. Witter waA sluppliml thmigh water-pip-m
welded into the. gam ontlet pilles to m)1 the thivat. Additional .00
0: Ell at* 0
Meant was supplied to the itust-catcbem. The (-wntial foaturo (if
fill, blowing-ont olleration by thin mothmi is the""llfrol orthe throat.
t inix-raturr, uhieh Amild not exm-d about W' C.. for Ivar of
gas explosionli. Throat temperature W. contriulled by conlrolling
roe
the mto of supply of the cooling water and fill, blast, The latter
thokilkl be MIUVOI to one half of the original sie ply t4mar-6 tit,- pill[ coo
tif the operation. The stovk level "Illitilil Call tu 1-5.2 tit, stimm, 04014111
of tit %-bro level. The hlmvinv~out olm,rimim dem-rilloil timik I I lir. see
6:0U9 3 will.
Go 1 see
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ASS-SLA NITALLUX4KIL LITIOATUSt CLASSIOKATION
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VDOVENF61 11. B.
Dissertation: "Foraidniferal Fauna of the Vizey Stage of the Donets Basin arid Its Strati-
graphic Significance." Gand Geol-llin Sci, Kiev State U, Kiev, 1953. Rteferativrrr Zh al--
y urr
Geologiya, Geografiya, Hloscow, Jul 54.
SO: SUM NO 356, 25 dan 1955
PASIAL, I.P.; BLMON, V.D.; VDOVENKO, H.I.; ONAYEV, I.A.; TONKONOGIY, A.V.;
MGIYMO. V.7a.
Cyclone smelting of polymetallic concentrates. Test. AN Kazakh.
SSR 13 no.8:76-82 Ag 157. (ULRA 100)
L. Akaaemiya'n -auk Kazakhakoy SSR (f or - Basina, - Mudon, Movenko.
Onayev, Tonkonogiy). 2. Chimkentakiy svintsovyy zavod (for -
(smelting)
VDOVL,,NKO.. 111. 1.
Dissertation. "Investigation of the Temperature Character3.stics of Asnes From Kazakhstan
Coal Used in Power Plants." Cand Tech. Sci, Inst of Power Engineering, Alm-a-AlLa, 1953-
Referativrrjy Zhurnal--Khimi:ya, Moscow,, No 13 Jul 54.
SO: SbM 110. 35(), 25 Jan 1955
ll:~~Il --,- Z 1,
-.- -- - - - , - -- - - - - - -- , - . .. - . I - - . - --- -- - - - -i- - -
PI-I
?T r
, 1, A~,/-."I
TONKONOGIT, .A.V., kandidat tekhnicheskikh nauki BASINA. I.F.; VI)OIWW
The cyclone process used in pyrometallurgy. TSvet.met. 30 no-1:30-
42 Ja '57. (MIRA 10:3)
l.Akademiya neuk Kazakh koy SSR.
(Smelting3 (Turboblowers)
(Nonferrous metals--Metallurgy)
BAYAKHUNOVY A. Ya.; VDOVENKO, M. I.; YERSHINA, L. M.
Oxidation rate of copper sulfides, Izv. AN Kazakh. M. Ser.
energo no.2x63-70 262. (MIRA 16:1)
(copper sulfide)
VDOTEPIKO, M.I., KOOIN, V-F.
Crxidation of irr-~- sulfide. Izv. Ali Kazakh.SS.R. Ser.energ.
no.1:51--58 160. (11URA 15:5)
(Iron sulfides)
S/031/61/000/002/002/003
A16i/Ai33
AUTHORS.- Vdovenko, M. I., Bayakhunov, A. Ya., Kondin, V. F.
TITTIZ: Investigation of iron sulfide oxidation in suspension
PERIODICAL: Vestaik. Akademil nauk Kazakhskoy SSR, no. 2, 1961, 52 - 61
TMT: The existing data on the mechanism and rate of iron sulfide oxidation
were obtained in experiments where only the factors affecting the process rate
were determined, but the present state of the theory and practice of roasting (in
the "bociling layer") and melting /kin suspension and'in the cyclone) require studies
In conditions close to the real process. The described Investigation was conducted
in four stages: 1) determination of the reaction surface area; 2) of the travel-
-he sulfide particles in the furnace; 3) of the reaction surface
Ing speed of 4.
temperature; 4) of roasting degree of sulfide. The iron sulfide powder was
80T'Ger-~d through a 200-micron meahscreen and introduced into the furnace in single
particles. Thr. reaction surface was calculated assuming globular shape. Under
the microscope the particles were polygonal. They turned into globules in t-hr,
heat. The temperature of the moving burning particles was determined by a ph-oto-
-pyrometric method based on comparison of the shadow densities on images with a
Card 1/7
S/031/61/000/002/002/003
Investigation of... A16l/A133
reference picture with known temperatures. The particles were photographed by a
high-speed camera using a color film, and the shadow density was measured with two
filters - a red and a blue one. The ref,7rence Image was of the filament of an
optis pyrometAr. The temperature and exposition time were. determin,.-~d gtapKloally
and the degree of roasting by gas analysie as well as by chemical and X-ray analy-
sis of the roasted particles. The test assembly is illustrated (Fig. 1). Sulfide
was fed by an electromagnetic feeder (1) and a water-cooled motile pipe (2) lnlo
vertical furnace (3). The roasted particles were collected in cooled receiver (4).
Gas from the receiver was extracted through absorber bulbs (5) absorbing S02 ani
Sc~, avid the quantity of burned sulfur was determined by titration with iodinf., oz-
alkaly. Air was fed by pipe (2) after purifying and drying in vas2als (6). Th&
air flow was kept constant and measured with flow meter (7). The syRtem re2lstancp
wa3 m,~~asured with preasure gage (8), and the quantity of roasted sulfide by-ifitight,
prior to and afte-" roasting. The temperature of the particles was measured from
photog.-,raph5 taken through the bottom furnace window (11) with a "Zenit" cam9ra of
single pax-f-Acles on the dark background. The speed of pax-ticles was dete"Mirv~l by
the number of frames taken through both windows (11), top and bottom, with a "Klyev"
cam;~ra (9) t-b--ough a mirror system in a tube (10). The test results are discuzsed
gand illustrated In graphs and a table (Table 1). The table showa thre=
Card 2/~
s/o3i/61/000/002/002/003
Investigation of... A161/A133
ranges with a characteristioal prevalence of certain reactions. It was not pos-
sible to separate each reaction in pure form. Reactions dominating in high
perature apparently will be present in lower ranges, and vice versa. No SO de-
terminations were made, but it had been found in the iron sulfide oxidation prcc-
less In a work carried out previously at the Ural'skiy filial Akademii nauk SSSR
(The Ural Branch of the Academy of Sciences USSR). In a comparison the determ1r;ed
temperature of particles agreed with the theorc*tical one up to 8000C in the medium
(or 1,0500 on the particle surface), but from 8000C up~ the difference was con-
siderable (the theoretical was-higher). This may indicate that the intermediate
CO compound Is forming with much.lower heat liberation than in oxidation to C02
and SO3, and that further oxidation of SO goes on in a gaseous state and the
liberating heat has no heating effect,on the pti-ticles. Conclusions: 1Y The new
method roade it possible to determine the sulfide particle, temperature and the
roaction :iurface area. 2) The.obtained data indicate three different stages In
thin process at different temperatures:- forinatJon of higher sulfur oxides at low
temperature, and low oxides at high temperature, up to 80, with a faster proc-
ess rate in the third stage. 3) The kinetic-constants were determined for the
summary process in separate temperature ranges. There are 5 figures, 2 tables
and 5 Soviet-bloc references.
Card 3/(
inveztigation of...
Table I
S/031/61/000/002/OC)21*()03
A161A133
Tomp. oxidation Formation reactions of oxides
0(; reactions S03 S02
300-600- F,S+20,.Fe'04 FeSO,-FeO 4-SOs 2FeS +3 ,.50,j- e,Os+2SO,
too - I o5plo
503-Fe,0,1+2SO2 2 SO... + 0, 2S03 2S0+ 2bO2
1050-11.1000 2FeS ~2:50.,-Fe3O3+-jbO
Kinetic constants of
summary process
-E, cal/mo~] 1/spe
Ko,-
4'270 , -
025 J!
1 17F0 is ;I
457410
Card 4/-(
Investigation of ...
Figure 1
S/031/61/000/002/002/003
A161/A133
~ I
Card 5/7
Investigation of...
S10311611000100210CO-
A161/A133
Figure 4: Dependence of the logarithm of the reactiori rate conbtant on the
inverse value of absolute temperature
1-simmary process of sulfide oxidation, 2-oxidation of sulfide to sulphate,
3-oxidation of sulfide with formation of S02
Card
Investigation of...
Figure continued
44
I Al I I
Card 7/7
s103116 1/OOU/002/OC)2/()03
A161/A133
TONKOROGIT, A.V.; BASINA, I.P.; VDOVMO, M.I.; KURRANGALIYEV, M.R.
New method of metal extraction from sublimates. Izv. AN Irazakb. SSR.
Ser.energ. no.1:110-114 159. (MIRA 12:11)
(Nonferrous metals--Metallur&7)
Bj-~Snllt~, K.R.; REZIlYi.-KOV, A.B.;
TOIRCONOGIY, A.V.
Ir-:-i ore treatnent .-flow sheet with the use of "he c7clore
Izv, AIT Fazakh. SSR. Se-,.er-erp-*. no.2:97-101 '59.
(ITIRA 12: 7)
(Iron ores) (Sqparatoy6 (Machines))
8(6) S07/1 I Z-59-4-6537
Translation from.: Referativay-y- zhurnal. Elektrotel-KE-iiiia, 19159, N'l- 4, p 19 !USSR)
AUTHOR: Vdc-ver-k-3, M 1. , and Favorskiy, V. V.
W
TITLE: Temvex~~ture Characteri-stics of t-he Ashes of Sorne K~_z~_kL-_;3tan_ Coals
PERIODICAL: V ab.: Isaled. fiz. os=ov. rabochego protsesea. i
Alma-Ata, AS Kazakhskaya SSR, 1957, pp 279-284
ABSTRACT: The Pzwer-Engineering Institutpe, AS Kazakhok--ya SSR, haa stlzdlied
the ViEC,:~g4+ 7 of slags cf typicall Kazzakhat'sn coalp. wlthLa ti - t3
ra-ge witlt the pu..rp,->se of findizzig t1lie connecti%in betweezt th--,
temperatuxe characteriet'cs. A numbez, of hetexogeneo,:~s a
solid-plLase con.tent of 30-50% !L-r%ve been stv~ffied. The solid plh~~-(! h-.Is been
repy-esented by qtL--Ttz 6and, barite ore, or galenite w4.-.nh, the Enec:*Z;_c weights.
.7
?.i, 4. 3. and 6.6, respectIvely. The iiq~,_Od pl~_se lies beez i~e-pXesenzzd b-1)
salut:' *onis of sugar in glycerine, colo'phonty, traixafornner mil, :,:,..ad. co).! tar. Tite
followhig eemrii:vical relation between the ternp~ezaturc- -vhsc-,siy bl.en
obtained: 61 = at--~L. The slags from Lenger, YayBan, _Ke11tc-.-na:3h2.t, anc:
Card 112
SOV I I IZI -5-9 -4-6 5 37
Temperature Gharacteristics of the Ashes of Some Kazakhstan Cozz'13
Karaganda brown coals have been studied; these slags have a z,elat've!7 low
ftzs-;on point. The empirical relation between the temperatuxe characteristic
and viscosity for these slags in dimensionless quantities is Fa - ID-% where
is the ratio of viscosity at any temperature to the viscoBi
at the po-Int t2, 19 49
the ratio of the temperature at which the viscosity is sought to the temperature
at the point t?, n is a constant (70 for the above experiments). The following
conclusions are drawn:
in Bthtd7ing viscosity characteristics of high-temperature complex systerns, a
'larity between them and the low-temperature heterogeneoza systems ca:a
be used. Slags of some Kazakhsta--i power-producing coals at the temperature
t? have the sam- e viscosIty, about 100,000 poise, zr;.d at the pol ' t3, about
33,000 poise. The viscosity-ternperature relation of the above slags ar-c! that
i
of cooll systems can be expressed, in dimens,10--less cco:-diza-tes, b-,r the same
curve; thL5 fact points out that theTe is an approxannate B.JMLari-.'-,r --,n t'he effect
of temperature on viscosity.
S. M. sh.
Card 2/2
1: H
pig
AKI
Al
0 00
131 -
11-aul 11-11,11zi A:
0 oil
vi
19i Ji,
BASINA, I.P.; VDOVENKO, M.I.; KURMANGALIYEV, M.R.
Principal results of the studies of cyclone processes of smelting and
sublimation. Trudy Inst. energ. AN Kazakh. SSR 2:261-273 '60.
(Mmk 15-.1)
(Smelting) (Furnaces) (Copper)
KOIOSOV, I.S.; VDOVCH211KOt --- ~
Certain problems of long term planning of emergency reserTe
requirements of electric power systems- Obshch. energ. nO.l:
MU 13:2)
43-51 '59-
(Electric power production)
TDOVENKO, M.V.
Lower Vise Foraminifers. in the Donate Basim. Nauk.zap.Kviv.un.
16 no.14:115-123 157. NIRA 13:4)
(Donets; Basin-Foraminifera, Fossil)
"OVEIZOV M
Comparison betveen the Foraminifera. found in lower Vise' sediments
of the Donets Basin and the Foraminifera in the Bashkirian Mountains.
Nauk zap. Kyiv. un. 15 no.2:53-57 '56. (MM 11:7)
(Donets Basin--Foraminifer&, Fossil) (Bashkiria--Foraminifera, Fossil)
) ( , j-, - ~~ 6 , 1 2'1
VDOVKNKO,M.I.; FATEYXVA.Ye-T.
Characteristics of some Kazakh coals for power. Izr.Aff 1.:azay-q.SSR
Ser.energ. no-7:92-108 '54. (MIRA 8:12)
(coal)
VDOVWO,M.I.; FAVORSKIY,V.V.
~k---~_
Study of temperature characteristics of ashes from Xazakh in-
dustrial coals. I2v.AN Kazakh.SSR.Ser.anarg.no.8:95-108 '55-
(Ash (Technology)) (MIRA 8:12)
4 It is M a 1127 Dion xiix)9 ,1111 Wil JOA 1617 a
A &-I I A ll Ait $1 ix W - ff P --k j
Disturbance of the watvr basucl, And disolder 01 the
liver In acute articut" rheumatism. 1. 1. Speramkit mutt
0 all -r
~ M. S. Vilovenko. Mix. Mfj. JU, S. S. it.) 16,
-I
1939
1
44 t
l1
(
.
n a
Cases t,
.
QV'4tc
,
Arliculan, theunlativill 4110tuda,itwe all the WAtet tlantV
w"* 1-th in the febrile &last of the digeaw and 00
0 1 lot a long liflir Altrr tile lefelp. had game down, This djq-
(Iffbant7v Consisted of 3 phasr%-. in the first the exclet lull
of w2ter was insufficient. In the following 22nd phast it was
:vaivr.
r jaT Tba: teallst is regarded as deransenjent of tile
at -
Nl'aana-
lie
tjo 0
be 0
A a
U --r -i' -T
&A Kit
11 9 tn all 11" I if of 9 a- -Oi-i 4 -r-
z,
T"
15-57-5-5835
Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 5,
p 17 (USSR)
AUTHOR: Vdovenko, M. V.
TITLE: A Comparisq'n of the Lower Visean Poraminiferal Fauna of
the Donets Basin and the Mountainous Part of Bashkiria
(Porivnyannya fauny foraminifer nyzhnlovizeyslkykh
vidkladiv Donetalkol%o baseynu ta girstkoi,' Bashkiri
in Ukrainian)
PERIODICAL: Nauk. zap. Kiyivsfk. un-t, 1956, Vol 15, Nr 2, pp 53-57
ABSTRACT: The author notes the similarity in the foraminiferal
and fusulinid groups from lower Visean deposits in the
Kur-Krauk River section of the Southern Urals and in
rocks of the same age in the Donbass. Archaediscus
.
.
endothyrids of the group Endothyra uradyi, and, very
rarely, quasiendothyrids appear for-ETTe--Tirst time in
this group. Primitive forms of Eostafella and Para-
stafella (Eostafella mediocris, E. prisca,' and -tFe-sub-
Card 1/2 genus Eoparastafelia) are also present. A group of
15-57-5-5835
A Comparison of the Lower Visean Foraminiferal Fauna (Cont.-)
foraminifers similar to those in the Kur-Krauk section is found in
the lower Visean rocks along the Sikaza River (Southern Urals).
Brunsia and Lituotubella occurin the Donets group but are almost
absent at Kur-Krauk. Tetrataxis does not occur and Archaediscus is
but poorly represented in the Donets assemblage. Thus, the Kur-
Krauk rocks contain foraminifers only of upper lower-Visean age. The
author suggests that a hidden unconformity occurs between the
Tournaisian and the Visean rocks at Kur-Krauk and at other places in
the Southern Urals (Sikaza River and elsewhere).
Card 2/2 R. A. V.
VDOVENKO, M.V.
Some new Upper Visean and Lower Namurian species of Foraninifera
in southwestern and central Kazakhstan. Paleont.zhur. no.1:41-46-
162. (MIRA 15:3)
1. Kiyevskiy gosudarstvennyy universitet imeni Shevchenko.
(Kazakhstan--Foraminifera, Fossil)
VWV-R-.KO, M. V.
Evolution of t,:e series Eoparastaffella-Pseudoendothyra. Ti-,:,.I-,r
Inst. geol. nauk AN MR Ser. strat. i paleont. no. 48tl6-,~C; .64
(MIRA 1!~~ ~ J )
EmORO, 0'" 1, pVv
strutigmp4r of tho Lowor Carbmlforous of Us Belouty
basin in oentna Kazakhaten., Sborr=whrmbNlov9unv
nool#35-46 163. (MM 301n)
VDOVEIIKO, M.V.
Stratigraphic distribution of Lower Carboniferous Foraminifera
in central Kazakhstan. Sbor.nauch.rab.Kiev.un. no.1:5Q-66 163-
(YLIRA 18:11)
BABK09 A.K.; VDO'VENK02 M.Y
Effect of a solv6nt mixture campostion on the separation of som
rare earths by paper chromatography. Zhur.a*al.khim. 17 no.72
820-M 0 162. (MU 15t12)
1. Institute of General and Inorganic Chemistryq leadewl of
Sciences, Ukrainian S.S.R.# Kiev.
(Rare earths.-Analysis)
(Paper chromatography)
3TPY~NK
- P~ M.,'Ye..
Effect of -tA-e composition of a mix-tuxe of esterB vith ke-t-meal
and alcobols on 'Vhe separation of certain rare-earth elements
by paper chromatography. Zhur. anal. khimo 18 no.9:1063-1070
S 163, (MIRA 16-11)
1. Instituts of General and Inorganic Chemistvy, Academy
of Sciences, n-rainian S.S.R., Kiyev.
'o 14.Ye.; KOPAJS
BABXOJP A.No; ~ ~o M.V.
Direct photcmagtric d6twrmination of rare earth elements by
paper chromatogmpby,_Zav. lab. 29 no.6.1645-649 163.
(MIRA 16:6)
1. Insti-tut obshchey i neorganicheiskoy khimii AN UkrSSR.
(Rare eimths.-Ahalysis)
(Paper chromatograpby)
VDGVENKO, M-Ye.; SPIVAKOVSKAYA, N.Ye.
Trilon B in the determination of microquantities of lead in
metallic cadmium. Zav.lab. 27 ni.8:963-964 161. (HIM 14-.7)
1. Institut obshchey i neorganicheskoy khimii AN USSR.
(Lead--Analysis) (Cadmium--Analysis)
_014;~6 ~9W 45/0619
IZMSSrMT-W-. AP3001521 STOAT 6~*
&-;-Vdovenko., M.Ye.; Kopa., M. V.
TITLE; Direct photometric determination of rare -earth-elements -by paper
chromatography
samm- zavodskaya laboratoriya., V, 290 noA 6, i963t 64s-649
iTOPIC TAGS: rare-earth chromatogram, rare-earth chxomstogrkphyj, lanthw=.,'
neodymium., yttrium, reflection coefficient.. chromatographic spot, rare-earth
;,element, paper chromatography, reflected light
;ABSMCT-. The authors determined the color intensity of spots from rare earth
i chromatograw In reflected light, using a,universal photometer with a light
filter of 574 millimicron wave length. Using various concentrations of lanthe-
num-1 neodymium-., and yttrium-nitrate., they found the reflection coefficient K
to be in,~,erseiy proportional to the amount of substance in the chromatographic
spot, Thus.. the problem was reduced to obtaining spots of the same size and
shape. The experimental technique consisted in placing 0.001 ml of the rare metal
nitrate solution on a chromatographic paper' strip., allowing it to stand for 30
minutes in a humidiWng chamber, followed by 5 hours of ascending chromatography
Cord 1A
L 12,?74-63
ACCESSION 'MR: AP3001521
~Incylinders containing 50-ml-of a 1:2 ether-acetone mixture vith 0.4 gm
~thiocyanic acid. After dx"jing,, the chromatogram UM developed by spraying with
a 0.4% alizarin solution containing 3% urotropin. The authors found that the
,spots were of a round shape when the drop of the experimental solution was
~placed15 cm. from the lower edge of the chromatographic paper strip., also when
the ascendant flow van Elowed down either by rendering the solution more viscous
:Iby dissolving photographic film in it or by nvmwina its access vith transverse
cuts in the pgper strip. The technique proved accurate within ic~ on
samples of. Loparib~j 143nazit~e, and Parisite., as coppared with the x-ray spectral
and trilon microtitration procedures. Orig. art. hes: 4 figures and I table.
ASSOCIATION: Institut obshchey i neorgenicheskoy khimii AN USSR (institute of
;General a~d Inorganic Chemistry,, Academy of Sciences USSR)*
SUMaTTED: 00 DETE ACQ: 17jun63 ENCL. 00
SUB CODE: 00 NO REF SOV: 005 OTM: 001
-Card 2/2
2~351
r S/032/6'/027/006/001/018
52,"-0 B124/B203
AUTHORS: Marchenko, P. V., Vdovenko, M. Ye., Nabivanets, B. I.,
Obolonchik, 11, V. --a-R-U-5ff-i-al-o-Maya, V_ Ye.
TITLE: Methods of determining impurities in metallic cadmium
.) of high purity
~ERIODICALs Zavodskaya laboratoriya, v. 27, no. 6, 1961, 638 - 639
TEXT: The present paper describes a number of chemical methods for
determining Fe, Cu, Ni, Sn, Sb, Tl, and As in high-purity cadmium; the
determination of Zn had already been described in Ref. 1 (P. V. Marchenko.
Zavodskaya laboratoriya, XXVI, 5, 532 (196o)), whereas the Pb determination
will be described In Ref. 2 (M. Ye. Vdovenko, N. Ye. Spivakovskaya.
Zavodskaya laboratoriya 'in Print)). For the corresponding determinations,
the authors used semimicro-methods and only purified reagents and re-
distilled water. Cadmium was dissolved in hydrochloric acid in a platinum Y
vessel. Iron was determined colorimetrically with the aid of the ternary
Fe-thiocyanate-diantipyrilmethane complex which can be extracted with
chloroform. The disturbing Cu and Bi are precipitated with ZnS at PH - 4.
Card 1/4
Methods of determining impirities-,
Fe 3+ is reduced with ascorbic acid to
Fe(OH)3' Copper is determined without
25351 S/032/61/027/006/00-1/018
B!24/B203
Fe 2+ to avoid losses by formation of
seFaration from cadmium with diethy, ~~J_
dithiooaTbamatel the colored complex Is extracted from 40 - 45 ml of
aqueous solution with 2 ml of CC1 49 and the color of the extract is compared
with a standard series. Niokel is determined by extraction of its complex
4ith dimethyl glyoxime by means of ebl.oroform and subsequent evaporation
of the chloroform under HC1, For the final determination of Ni, the authors
used the formation of its complex with dimettiyl glyoxime in tne presence
of ammonium persulfate. Tin is determined colorimetrically by extraction
of its diethyl dithiocarbamate complex with chloroform, re-extraction
with permanganate, and reaction with p-nitro-phenyl fluorone. For a
quantitative extraction of tin in the presence of large Cd amounts, the
extraction is repeated four times with new portions of a solution of
diethyl dithiocarbamic acid in chloroform. Arsenic is determined
colorimetrically in the form of arsenomolybdenum blue which can be ex-
tracted with I ml of isoamyl alcohol. To concentrate the arsenic and sepa-
rate it from Cd, the latter is distilled ofr in the form of arsenic hydride, the
Card 2/4
25351
3/032/61/027/006/001/018
.Methods of determining impurities ... B124/B203
analyzea cadmium specimen being used instead of metallic zinc. Antimony
and thallium are determined by the known extraction-colorimetric methods
with the use of crystal violet from one weighed portion; the difference
in the pH-values in the precipitation of their hyaroxy acids (Sb at
3+
PH - 5, TI at PH - 8 - 9, and Cd at PH - 7) is used for the cadmium
separation. The following table was compiled on the basis of the. experi-
ments made.
There.are 1 table-and 11 Soviet-bloc references.
ASSOCIATION: Institut obahchey i neorganicheskoy khimii Akademii nauk
USSR (Institute of General and Inorganic Chemistry of the
Academy of Sciences UkrSSR)
YDOVENKO, M.Ye.
. I., ...
Fourth Republic Congress on Chemical Control of Production in Metal-
lurg~ and Metalworking Industries. Ukr.khim.zhur. 24 no-5:695-697
1 58, (MIRA 12:1)
(Metallurgy--Congresses)
5(2) SO V/32-25-4-1 2/71
AUTHORS: Vdovenko, K. Ye,, Spivakovskaya. N. Ye.
TITLE: The Use of Trilon 3 in Determining Chromium in Steel
(Primeneniye trilona B pri opredelenii khroma v stali)
PERIODICAL: Zavodskaya Laboratoriya, 1950., Vol 25, Nr 4, PP 416-417 (USSR)
ABSTRACT: The determination of chromium in steel can be made by an oxida-
tion of tho chromium to bichromate and a ouboequezit iodonetric
titration. Iron can be bound by trilon B (Ref 1), but some dif-
ficulties will arise in the presence of vanadium.To overcome
these, some hints have already been given (Refs 2,3) which are
based on -- change of the redox potential with the pH. In the
present paper it vias found out that at pH = 1.5 - 2.0 the bi-
chromate is still reduced fast enough with potassium iodide
(3 - 5 minutes) while the vanadate only reacts very slowly with
potassium iodide. This knowledge forms the basis for the sug-
Cested method of determination of chromium in steels with or
without vanadium, also in the presence of wolfram. A table of
analytic results by the described methods of analysis of dif-
ferent standard samples is given (Table). There are 1 table
Card 112 and 3 references.
The Use of Trilon 3 in Deter:--ining Chromium in Steel SOV/ 32-25-4-12/71
ASSOCIATION: Institut obshchey i riecrE:anicheskoy- khinii ;kz-deniii US~;R
(Institute of General and Iqoi-r--.qic ChemiL;try of the A.cademy of
Sciences,Ukr3310
Card 2/2
ACC NR-.--AP6019226
~A) SOU111CF, CODE:
-AUTHOR: Babko, A. K.; Vdovenko,, M. Ye
ORG: Institute of General and Inorganic Chomistry,01 Mcr"I'M (Inst-itut oibohc~.ey 'i
neorganicheskoy khimii AN UkrSSR)
TITLE: Comparison of reagents for direct photometric determination of rare-earth
elements on chromatograms
SOURCEt Ukrainakiy Ichimicheakiy zhurnal, V. 32, no. 2,, 1966, 209-212
TOPIC TAGS: rare earth element, photometric analysis, chromatographic analysis,
spectrophotometric analysis,* light reflection coefficient 1,q.F.-nt0t9x_ 19cFwr
ABSTRACT: Eight organic reagents ( methylthymol blue, pyrocatechol violet, glycine-
thymol blue, alizarin, eriochromocyanine, xylenol orange resorcin, and peridylazo- and
arsenazo-resorcin) were compared by studying the reflection spectra on paper cauzrd
by the reaction of La with the reagent. The spectrophotometric charactoristics of the
reagent and the products of reaction were used as criteria for selecting the =ost
efficient reagent. The refleotion spectra of complexes and reagents on the paper were!
taken with an SF-af apparatus containing a devire for measuring reflections. Water-
alcohol and 1 x 10-3 M alcohol solutions of the reagents and 2.8 x 1o-2 1.1 La solu_
tions at PH 5 (urotropine buffer) were used in the experiments. Via I& solut ion
Card 1/2 UDG; 543-5"+546.65
ACC NR: AP6019226
(0-05 ml) was applied on chromatographic paper Wl (East German) and dried in air.
After applying 0*05 ml of reagent -solution, the paper was dried a4~ain aza t,2~e reflec-
tion spectrum of the stain was taken in the SF-214 spoctrophotometer. The min'-=--s of
the reflections of the complexes 01,bR) and reagents (AILt) , the displacements of the
reflection band during complex formMon (AX), the minimal coefficients of the reflec-
tions of complexes (K, ) and reagents (K, and their absolute (41 = K-in - ay
and relative (A1014, ~~gifferences were de ormined for each reagent frora the raflectim
spectra of coloredI s~"). The data obtained were tabulated and showed that mothyl- ~
thymol blue and alizarin were the best according to the intensity of reflections and!,
the spectral displacement of the reflection band. It was found during the plotting I
of the calibration ctrvo that the methylthymol blue yielded a considerably larger ra
flection for the blank experiment. The advantages of alizarin over methylthy--ol were
substantiated also by the followin observation. A certain arrount of blurring was seen'
9
during the formation of stains on paper. This was related to the chromatographic
properties of the reagent solvent (alcohol and H20). Me blurring is objectionable in
chromatograms with a large amount of separating elements. The solvent fraa of this
effcat, i.e., one with an Rf of nearly zero for all rare-earth elements, was the one
to be searched for. A study was made of solutions of methylthymol amd alizarim ia
higher alcolhols and ketones. Only alizarin dissolved in butanol and ethanol. -1he use i;-
of alizarin dissolved in butanol yielded well-coloredp distinct and uniform stains.
The refleation spectra of the La with alizarin and the alizarin itself remained -un-
changed. Orig. art. has: 2 fig. and 1 table.
SUB COM OV SUBM DAT"Et OlDec64/ ORIG REF; 009/ OTH RZF; 004
Card 2/2
MARCHENKO, P.V.: VDOIJEIN(O M.Ye.; NABIVANETS, B.I.; OBOLONCHIK, N.V.
1-~
SPIVAKOVSWR~.- 5b."' --
Methods of dete- '"ina the impurities in high purity metallic
cadmium. Zav.1aa. 27 no.6:638-639 161. (MIU 3.4:8)
1. Inst-1tut obshchey i neorganicheskoy khimii Ali USSR.
(Cadmium-Analysis)
S/075/62/017/007/002/006
B119/B166
AUTHORSs Babko, A. K., and Vdovenko, M. Ye.
TITLE: Effect of the composition of solve-n-T mixtures on the paper
chromatographic separation of some rare earths
PERIODICAL: Zhurnal analiticheskoy khimii, Y. 17, no- 7, 1962, 820 - 824
TEXT: A physicochemical analysis was made'to' discover how the paper
chromatographic separation of La, Nd, and Y is affected by different com-
positions of mixtures of diethyl ether (E) with methanol (I), ethanol (H),
propanol (III), butanol (IV), acetone M, methyl ethyl ketone (VI), or
cyclohexanone (VII). The following mixtures were found to be optimumt EtI
(Rf values in the order La, Ed, Yi 0.-25, 0.41, 0.60); E:II - 10
(Rf S 0.19, 0.35, 0.59); EMI - 1:9 (R f1 0.06, 0.16, 0-36)1 EjV - 1t2
(Rf s 0.06, 0.22, 0.61); EiVII - 1sq (R f: 0-03, 0-10, 0-30); pure VI
(Rf 1 0..08, 0.27, 0-51)a The differentiating action of the solvent in-:-,
creases with '~ts solubility in water. There are 7 figures and I table.
Card 1/2
B/075/62/017/007/002/006
Effect of the composition of... B119/B186
The most important English-language reference iss F. Pollardp J. Mc. Omie,
H. Stevenal J. Chem. Soc. 12, 4730 (1952).
ASSOCIATIONt Institut obshchey i neorganichaskoy khimii AH USSR, Kiyev
(Institute of General and Inorganic Chemistry AS UkrSSR,
Kiyev)
SUBMITTEDs October 31, 1961
Card 2/2
6
L 24826-6 MIJG
ACC NR: AP6010834 SOURCE CODE: UR/0073/66/032/003/0284/0289
A0
jAUfHOR: Vdovenko M. Yei
3
~ORG: Institute of General and Inorganic Chemistry, AN UkrSSR Inst*tut obshchey i
khimii AN UkrSSR)
tion of rare earth elements in tile fo
;TITLE: Mechanism of separa rm of thiocyanates
:'by paper chromatography
ISOURCE: Ukriinskiy khimicheskiy zhurnal, v. 32, no. 3, 1966, 284-289
!TOPIC TAGS: rare earth element, thiocyanate, paper chromatography, chemical separa--~,
ition, partition coefficient
'ABSTRACT: In order to check the h othesis that the mechanism of separation of rare
yp
;earth elements by paper chromatography is not identical when different solvent mix-i
'tures are used, -tile separation of rare earths in the form of thiocyanates was stud-
!ied in different M-Ixtures of methyl acetate, ether, and butyl acetate with methanol
'or acetone. The partition coefficients Kpart of the rare earths were determined
Rf values
i(using yttrium as an example) at variou compositions of these mixtures.
!Card 1/2 UDC: , 543,+ 546.65i;
L 24826-66
ACC NR: AP6010834
.!were then calculated and compared with values obtained experimentally in a chroma-to..i
1graphic separation with the same mixtures. In order to determine
KDart, it was
necessary to know the volume of the organic phase; since for a mixtEre of solvents
.!of which one is completely soluble in water the volume of the organic phase changesi,
-unction of the composition of the mixture, the volume change of the organic
as a f
.!phase was determined in the following system of various compositions: saturated so_~
It was shown that in acetone
Ilution of ammonium nitrate - mixture of solvents.
!ester or acetone - ether mixtures the separation followed a simple partition mecha--;~
nism. In the case of methanol - ester or methanol - ether mixtures, the relation
Detween Rf and Kpart is more complex. It is concluded that in the chromat 'ographic i
separation of rare earth elements in the form of tbiocyanates, the maximum differen,-'L
tial effect of the solvent mixture corresponds to a definite volume of the organic
:phase. Orig. art. has: 6 figures.
SUB CODE: 07 SUBM DATE: 1BNov64/ ORIG REF: 004/ OTH REF: 002
Card-, 2/2_1;;~
VDOVENKOo N. Y.
USSR/Scientific Organization - Academy of Feb 53
Sciences
USSR
"Director of the Radium Institute imeni V. G. Xhlopin"
Vest Akad Nauk No 2, 1953, P 53
Presidium has appointed N. M. Vdovenko, Dr Chem Sci,
to be Dir of the Inst, subject to the approval of
the General Assembly of the Acad.
271T97
SOKOLISKAYA, A.M.; YWVENKO, N.N.
Hydrogenation of hydroxycodainone. Vest.AU Kazakh.SSIC
16 no.2:44-48 Ir 160. (MBA 13: 6)
(Godeinone) (Hydrogenation)
VDOVENKOY-.N.S.., inzh.; SHEVCHENKO, A.G.
lArge-block ass6mb2,y of a composite banking unit. Mont. i 3p--ta.
iabi v stroi. 24 no-90-8 S 1.62. (MIRA 15:9)
1. Soyuzprommekhanizatsiya.
(Earthmoving machinery)
OVCHARENKO, Fedor Danilovich, akademik; KUKOVSKIY, Yevgeniy Georgiyevich;
NICHIPORENKO, Sergey Petrovich; VDOVENKO, Sergey Petrovich;
TRET
VDO~~ ~d;f asil!7 IMUK Vikentiy Yurlyesviah;
1WWWRMUW11, FAWASEVICH, Aleksandr
Aleksandrovich; POKROVSKAYA, Z.S., red. izd-va; MONZHERAN,P.F.,
tekhn. red.
[Colloid chemistry of palygorskite] Kolloidnaia khimiia paly-
gorskita. Pod obshchei red. F.D.Oveharenko. Kiev, Izd-vo AN
Ukr.SSR, 1963. 119 P. (MIRA 16:7)
1. AN Ukr.SSR (for Ovcharenko).
(Palygorskite) (Colloids)
VDOVENKO, N.V., kand.tekhr,.nauk; VDOVENFO, I.D., kand.tekhn.nauk
New method o. ' chemical degreasing. Mashinostroenie no. 2:
66 Mr-Ap 164. WIRA 17:5)
L 9 --1-: P (.1
AT6020589 -4 6 061
ACC NR: SOURCE WEE -I URT0606/ 000 077/0081
AUTHOR: Kolos-juk, R. G.; Vdovenko, 11. V.; Ishc uky juL_-ju-
ORGI UkrINFIlgiproneft'
f -
TITLO-9 Structural and mechanical properties of oloopseudogels based on octadocylam-
monium bentonite and palygorskito complexes
SOURCE: Neftepererabotka i neftekhimiya (Petroleum refining and petroleum chemistry)~
Kiev, Naukova dumka, 1965, 77-81
TOPIC TAGS: clay, grease, rheologic property
ABSTRACT: The Ukraine has rich deposits of Ca-bentonites and palygorskite; in this
connection, the authors studied the possibility of using modified clays of Ukrainian
deposits in the production of lubricating greasesif The modification of the surface oJ
the clays was carried out by using octadecylamine (C18H37%). The lubricants 1-fore
made by preparing a suspension of the organophilic clay and mineral oilp then homogen-
izing the mixture in a laboratory paint mill. A quantitative evaluation of the rheo-
logical properties of the bentonite oleopseudogels obtainad showeg that the most ef-
fective of the thickening agents studied were the BK-0and Wh-Vlorganophilic benton-
ites and a bentonite-palygorskite mixture. The results'leaT -to-the hypothesis that
the nature of organomineral complexes (thickening agents) substantially affects the
1/2