SCIENTIFIC ABSTRACT VDOVENKO,K B. - VDOVENKO, N.V.

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SCIENTIFIC ABSTRACT
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VOLOKITIN, I.; VDOVENKO, B. Wings are strengthened in flight. Grazlid.av. 20 no.11:2 of cover 1-3 N 163. (NIRA 17:2) 1. Spetsiallnyye korrespondenty zhurnala "Grazhdanskaya aviatsiya". ADTHOR: Semenov, V. and Vdovenko, B. TITLE: Designers of Radio-Controlled Airplane Models Wonstruktory radioupravlyaemykh modeley) PERIODICAL: Radio, 1956,Nrl2, insert page (USSR) 107-12-1/46 ABSTRACT: Hundreds of young people, members of DOSAAF, construct radio-controlled flying models in their leisure hours. Petr VelichkOV8kiy from Alma-Ata has become the world champion when his model has flown for 3 hrs 6 min and 38 see. The photo shows him controlling on 28-29 me his model for 100 m against the wind and for 150 m. with the tail wind. Boris Kochetkov from Kuznetsk town, Pensa oblast , built a model that flew 2 km 400 m, in a straight-line route. The 1956 All-Union Contest of flying models attracted many amateur designers from Moscow, Leningrad, Alma-Ata, Sverdlovsk and other cities. Three photos show the designers and their models. In addition to the above mentioned, the outstanding designers were: N. Drozhzhin (Moscow), L. Teplov (Rhaftov), A. Erler (Leningrad), S. Malik (Moskva), Yu. Shchegolev (Sverdlovsk). AVAILABLE: Library of Congress Card 1/1 AUTHORS: Prokoflyev S., (text) Vdoven ko, B., (photos) 85-9-17 /33 TITLE: A Visit to the Promoters of the All-Union Competition of Aerolubs (U Initsiatorov sorevnovaniya aeroklubov) PERIODICAL: Kryllya Rodiny 1357, Nr 9, inserted colored sheet between pp. 16-17 (USSR ABSTRACT: 22 photos of the members of the Serpukhovskoy aeroclub at their routine exercises, showing also nome of the material equipment of the aeroclub. The text accompany- ing the photos offers brief and fragmentary Information on the members represented in the photos and comments on theIr activities. Stressed are; the strict discipline maintained at the aeroclub by its head S.M. Nefedov; the Importance the members of the club attach to the sports as a means of developing their physical condition ; and the fact that the members of the aeroclub'participate actively in the political work (obshchestvennaya rabota). AVAILABLE: Library of Congress Card 1/1 V C C Subject Card 1/1 Authors Title USBRAeronautics - Training (sports) AID P - 4457 Pub. 58 - 4/10 Vdovenko B., and M. Semenov A Primary Organization of the DOSAAF at Work Periodical Kryl. rod.., 1, 6-7, Ja 1956 Abstract The article describes the day-to-day work of a DOSAAF- sponsored Parachute Circle functioning at an unnamed machine-building plant, and contains some advice as to the organization of work in-such-Circles. Six photos. Institution None Submitted No date VDOVE,NKO, B. Watch in Arctic Region-4. Kryl.rod. 13 no.ltl6b-16e Ja f62. (MIRA 15:2) (Arctic regions) VDOMMO, B. 14. "Application of Radioactivity 14,-thods In Analytical Ghemlatry," a paper submitted at the Conference on the Application of Radioactive Tracers in Chemistry and in the Industry, Leningrad,30 Oct-1110V 56. SIM: 1345 P - 95 ACC NRi AT7006973 SOURCE CODE: U AUTHORS: Baydal, X. Xh.; Ydovenko2 G. N- ORGt none TITLE: Refinement of a computational miAhod for predicting rain on the basis of pressure maps SOURCE: Alma-Ata. Kazakliskiy nauelmo-issledovatellskiy gidrometeorologicheskiy institut. Trudy, no. 25, 1966. Voprosy moteorologii (Problems in meteorology)., 12 TOPIC TAGS: weather forecasting, atmospheric pressure., atmospheric temperature ABSTRACT: The authors have sought to refine a method for predicting rain proposed by them in 1963; application of the method to Frunze and the plains of Kazakhstan has also been considered. The method is based on daily changes in relative topography of pressure maps (300/500,, 500/700., 700/1000) and the dew-point deficit at the 700- millibar level. Improvement is introduced by considering advaction and the change 0 in dew-point deficit from the 700-millibar level to the 500- and 300-millibar le--'-. A good indicator of rain is a sharp decrease (more than .50) in the dew-poin. !-tacit from one level to the overlying level, but there must not be a reversal in going on to the next level. Several actual examples of observed dtta are consideredy and the results are encouraging. With consideration of this new modification, and on the ACC NR, AT7006973 basis of tests) 84-86% reliability is attainable,. if the procedure is strictly followed. Consideration of advection., in conjunction with the other refineaents) should provide'even better results, but radiosonde data are necessary, and those are too meager in the investigated area. If advection is weak, the sonde must be used at the site where prediction is desired. The authors conclude that their proposed refinements improve reliability., but that more refinement is possible and necessary. SUB CODEt 04/ WM DATEx none/ ORIG REFx 003 2/2 set eon go :40 saw ffl so v ;it 0 0 0000 0 - 0 0 0 0 1 4 r I I I ti a k a k v v 0 41 do U to 46 41 tj M U 01 U-1 It Is Mis 11111111 a It a L a a p 60 -00 The question of dm witter-mintral economy in acute *00 Artictsw theumadsm. R. V. Kavaikin awl !, I l. Vd.). venlro. rerap. Arkh. 16. 521 (VW-7e-,7,r-- -00 19" 1 11Y.I.-In tests on palient-I 41adcrinx frxQ .00 tnati4; In Which 11. 0( Water WA% Md1nh-,i%trTrtj jhrjiw~N - 4a reduction of the renAl and 0012f"RAl VICtriloll Of water 00 A" I in she I Wta which was suvanip2nicil by a lnwt.r "th vtk)ri nt I t t f A h ( Co t e ur en ne. i t e acute symptoms Ili--- At-Pea e red the renal excretion i"'rea-d at thc cxprnw (4 .00 the e%trarruAl rxcretkm, the chkWhir e."ttent i1wirm-hic No* at the game 11rur, M. 0. =00 2 U &I OD Ill; i it it i, A va a 0 0 0 0 0 a a a a 0 0 a 0 Oe Or COO ago, coo ago, goo see goo less -so fillil OAK UNT HI a o 0 2 " W M L S a 0 0 * 0 a 0 0 0 0 a 00 60 4j 50 we, 5W SOV/'i53-2--3-7/29 AUTHORS: Vdoven-ko, I. D., Kudraq 0. K. TITLE: On a New Method of Investigating Diffusion Processes PERIODICAL: Izvestiya vysshikh uchebnykh zavedeniy. Xhimiya i khimicheskaya tekhnologiya, 1959, Vol 2, Nr 3v PP 345-351 (USSR) ABSTRACT: The determination of diffusion coefficients according to the hitherto used methods, some of which are mentioned, still leads to considerable errors because the temperature can be kept sufficiently constant only with difficulties. For this reason the authors used for the determination according to Skobets and Kavetskiy (Ref 11) the current impulse which occurs in switching on the electrolysis. The electrolytes were solutions of CUSO4, ZnS04' C(L904 and AgNO, of differeAt concentration (Table). The current density and the period until the occurrence of the first cathode precipitation wire measured. A measuring device was developed which is shown by a-scheme (Fig 1)~ Formulas for the computation are deduced. Moreover, test series are carried out in which spherical instead of cylindrical cathodes are used. It could be proved that during Card 1/2 On a New Method of Investigating Diffusion Processes SOV/153-2-3-7/29 the first seconds of eleatrolysis the rule of the linear diffusion holds irrespective of the shape of the electrode. There are 2 figures, I tableg and 16 references, 6 of which are Soviet. ASSOCIATIONt Kiyevskiy politekhnioheskiy institut - Kafedra iizichaskoy i kolloidnoy khimii (Kiyev Polytechnic Institute - Chair of Physical and Colloid Chemistry.) SUBMITTED: March 19, 1958 Card 2/2 ~PQMKO, 1. D.; KUDRA, 0. K. Effect of the nature of the solvent an the diffusion of electrolytes. TJkr. khim. shur. 28 no.3;323-326 162. (MMA 15:10) 1. Kiyevskiy politekhnicheskiy institut. (Solvents) (Electrolyte solutions) VDOV~NKOY I.D.; BOGACHEVA, N.A. ce of indium-tin-thallil= allol* Investigating corrosion resistan 62. (wRA 15:9) l4ashinostroenie no.4t%_72 Ji-Ag 1. Akademiya nauR UkrSSR, Vin alloYs--G orro,ion) VDOVEIIKO, I.D.; KUDRA, O.K. Method of studying diffusion in electrode layers in the absence of a current. Ukr.khim.zhur. 26 no-1:36-40 16o. (MIRA 13:5) 1. Kiyevskiy ordena Lenina politekhnicheskiy Inatitut. (Diffusion) (Electrodes) VDMITTIKO, I. D. VDO::`ENr,O, I. D. -- "A New Llectrochemical Method of Irivt!~_f,4 -at i r p Solutions." Min Higher Education USSR. ' Kiev Ord--, of Lenl.ri --rlrteci-n.4c Inst. Chair of Physical and Colloid Chemistu. KJ ev, 1955. (Di,-zertation for -the Degree of Candidate in Chemical Sciences) SOURCE Knizhnaya Letopis', No 6 1956 VI~PYTNKO, I..D.; GRATSIANSKIY, N.N. Effect of organic additions on the corrosion of binary alloys of nonferrous and rare metals in aggressive media. Ukr. khim.zhur. 29 no.9:983-987 163. (MIRA 17:4) 1. Institut, obshchey i neorganicheskoy khimii AN UkrSSR. VDOVFIIKO,, N.V., kand.tekhn.nauk; VDOVENYO, J.D., kand.tekhn.nauk New method of chemical degreasing. Yashinostroenie no. 2: 66 Mr-Ap 164. (MIRA 17-5) (- KUDRA, 0,K, processes. jzv.vys.u-chob* New methode of i.vestigatiag diffusiOt' (MIRA 13:8) zav.; khim-i khim-tekh. 2 no-3:345-351 '59- 1 1. Xiy,,,kiy politekhalcheskiy Inatitut, kafedra fizicheskoy kolloldnoy khimii. (Diffusion) GRATSIANSKIY,'N.N.; VDOVENKO, I.D. Formation of a lead sulfate film on an In-Fb alloy during corrosion ift Sulfuric acid solutiono Zhur.fiz.khim,, 35 no,6zl2M-1211 Je 161. (MIRL 14:7) 1. Akademiya, nauk USSRj, Institut obshchW i neorqanicheskoy Ichimii. (Ind.limk-lead alloys-, Corrosion) (Lead sulfate) AUTHOR6; 2iTLE: PERIODICAL: 6/185/62/007/010/.011/020 D234/D308 11ratuians1kyy, I.I. V., Vdovenko, 1. 1). and Baturyns'ka, Formation and structure of corrosion 6urface layers in In-Pb and Fe-Ni alloys Ukrayinalkyy fizychnyy zhurnal, v. 7, no. 10, 1962, 1118-1123 TEXT: The layers were sludied by the x ray method, using charac- teristic Fe wavelen.-~'ths 1.9321 Xx and 1.7514 Kx, on both rotating 0 and fixed samples. Corrosion unstable in In-Pb has a layer of PbSO4 on the surface, a thin layer of.nea:rly pure Pb below it and finally a solid, Pb-enriched In-Pb solution. Up to the depth of 2 microns two cubic lattices are observed. Corrosion-stable Tn-Pb -possesses similar surface layers. in Fe-Ni alloys lattice parame- ters do not change and new lines do not appear: ~jtable alloys ex- hibit the Ni lattice and unstable alloys the Fe lattice. Thickness --and composition of the layers were studied in previous papers by Card 1/2 6/18;5/62/007/010/011/02 0 Formation and structure ... D234/D308 the first of the authors et al. '-Chere are 2 fi-ures and.2 tables. ASSOCIA'XION: 1natytut :~ahaliioyi ta neorhanichnoyi k1iii-Ayi AN ULU"', Xyyiv (Institute of General and Inorganic Chemistry JILS XLiev) SUBI,II12TED: March 31, 1962 Card 2/2 27679 S/07 61/027/005/003/004 0 1 B103YB101 AUTHOR: Vdovenko, I. D. TITLE: Investigation of the resistance to corrosion of indium - tin alloys PERIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 27, no. 5, 1961, 629-633 TEXT: The resistance to corrosion of the indium - tin system in different media was studied, since dataavailable on this subject are insufficient. The alloys ncs.1 - 10 were used, which were produced from pure metals and contained: 1,0; 3.0; 12.5; 25.0; 37.5; 50.0; 62-5; 80.0; 97.0, and 99.0 atom% of tin. They were molten under a layer of anhydrous glycerol. The samples were pressed to disks (diameter 16 mm, thickness 80 - 100p.), and then annealed. The purified samples were immersed in 500 ml of the corroding solution. The corrosion tests took 14 days at room temperature and with air supply without stirring. The following corroding solutions were used: chemically pure 1, 20, and 60% H2SO 4 solutions, 5% HC1, or 3~o NaCl. The resistance to corrosion was estimated from the loss in weight 2 of the samples in glem hr and from the change in appearance.. At the same Card 1/4 27679 S/073/61/027/005/003/004 Investigation of the... B103/B101 time, the potentials of the alloys were measured by the compensation meth- od with a TMTB_1 (PPTV-.l) potentiometer. The potentials of the alloys nos. 1 - 7 andthe potential of pure indium in I and 20% R2SO 4 were found to be more negative than those of pure tin and of alloys rich in tin. The poten- tial is shifted toward negative values with increasing acid concentration. In the afore-mentioned concentrations the potential drops at the beginning of corrosion (within 3 - 4 hr) in all alloyst and then remains nearly con- stant during the whole corrosion time. This is explained by the formation of an unsoluble film of corrosion products. The higher weight losses in 1T. H2SO4solution as compared with 20% solution may be due to the formation V~ of a permeable film in the former case. In 60/1) solution, the alloys are dissolved without any film formation. The course of the curves potential versus time of corrosion in the two other corroding media is analogous to that in H2SO4 solutions. In HN, the potential approaches that of a nobler metal owing to dissolution of the less resistant, and increased concentration of the more resistant component on the surface. In NaC1, the change of the potential in direction of that of a nobler metal is due to film formation. Corrosion losses largely depend on the physicochemical Card 27679 S/073/61/027/005/003/004 Investigation of the ... B103/B101 conditions of corrosion. In dilute 112S0 4 solutions, the corronion losses of the alloys depend only slightly on the composition. On the other hand, the curve of weight losses in 60,j', H2SO4 solution shows three abrupt breaks. They correspond (1) to the alloy with N3 atoW/1~1 of tin (due to increased corrosion), (2) to the alloy with N20 atorri-ja (decrease in corrosion), (3) to the alloy with 65 atoe/o (higher decrease in corrosion). (1) corresponds to alloys with a-Rhase, (2) to alloys with ~-phase, (3) to the range of existence of the I& + phase. Consequently, the limits of corrosion resistance correspond to the phase transformations in the alloys. Such a difference of the corrosion resistance depending on the composition of alloys is explained by their structural characteristics. The existence of different phases promotes the formation of sections of different electrochemical properties. The dissolution of In-Sn alloys. which is comparatively moderate in H 2S0 4solutions of mediujn concentration, markedly increases in H01 solutions, owing to the high corrosion activity of the chloride ion,. In analogy with the corrosion in 60% H2SO C a sharp limit of corrosion resistance is found in 5% HCl. It corresponds to the Card 3/4 27�79 S/07~/61/027/005/003/004 Investigation of the ... B103 B101 alloy with rJ70 atonfj'~' Sn. The weight losses in alloys with 0 - 70 atoej, Sn are located on a straight line parallel to the abscissa. The absolute values of these losses are equal to those of pure indium. Hence, the alloying of tin with 30% of indium highly increases the corrosion resist- ance of the former. The corrosion losses of the alloy in 3% NaCl solution are only fractions of those in HCl and H 2SO 4* Accordingly, corrosion processes largely depend on the nature of anions and cations. There are 8 figures, I table, and 5 non-Soviet references. The three most recent /Y references to English-language publications read as followst G, Colin, C. G. Pink et al., Trans. of Electrochem. Soc 12~ 463 (1939); C. G. Pink, E.. R. Jette et al. ibid.. 88, 229 6,945); F. Rhines, W. M. Urquchart and H, P. Home, Trans. Am.. Soc.. of Metals, J2 (1947)- ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN USSR (Institute of General and Inorganic Chemistry AS UkrSSR) SUBMITTED: September 28, 1960 Card 4/4 S/073/62/028/008/002/002 A057/A126 AUTHORS, Vdovenko, I. D., Gratsianskiy, N. N. TITLE: The effect of surface-active substances upon the corrosion of indiun tin, and Indium-tin alloys PERIODICAL: Ukrainskiy khimicheskiy zhurnal, v. 28, no. 8, 1962, 991.- 995 TEXT: The effect of adding small quantifies (0.094 resp. 0.265 g/1) of mixtures of heptyl and octyl amine, of decyl and dodecyl amine, and of octyl amine on the corrosion of indium, tin, and their alloys (50% In, or 20% in) was investigated In 60% sulfuric acid solutions by the method of cathodic and anodic polarization curves. These admixtures caused a shift of the cathodic polariza- tion curves towards negative potentials. The-shift of potentials is explained by a decrease In the rate of the cathodic reaction, i.e. an increase of th6 over_ voltage of the hydrogen ion discharge. This is due to the formation of dense .adsorbed layers of the surface-active organic compounds on the surface of the electrode. Corrosion inhibitors with a specific adsorption on the metal surface show the greatest effect when the potential of the electrochemical reaction is Card 1/? 3/073/62/028/008/002/002 The effect of surface-active substances upon... A057/A126 similar to the potential of the neutral point of the electrode metal. in the presence of amine decreases also the diffusion and self-dissolving current. This is apparently due to a barrier effect of the surface film formed. No ef- fect of the investigated admixtures was observed on the anodic process. Thus the examined corrosion process is generally controlled by cathodic reactions. There are 9 figures. ASSOCIATION: Institut obshchey i neorganicheskoy khimii AN USSR (Institute of General and Ihorganic Chemistry, AS UkrSSR) SUBMITTED: July 19, 1961 Card 2~2 ,9/r,73/62/028/009/005/01'. A057/A126 AUTHORS: Vdovenko, I. D., GratsiansRiy, I. N. TITLE; Corrosion resistance of indium, tin, and Indium-tin alloys In the presence of surface-active substances . PERIODICAL: Ukrainskiy 1rhimicheskiy zhurnal, v. 28, no. 9, 1962, 1069-- 1072 TEXT: At the Institut obshchey I neorganibheskoy khimii AN USSR (Insti- tute of General and Inorganic Chemistry AS UkrSSR) corrosion properties of in- dium, tin, and their alloys were studied at room temperature in 60% H2SOj, in the presence of the surface-active substances heptyl-octylamine, decyl-dodecylamine mixtures, or octadecylamine at various concentrations (0.094 and 0.265 g/1). A] - loys of the following composition were studied (in at%); 99.0, 97.0, 87.5, 75-C 62.5, 50.0, 37.5, 20.0, 1.0. The tests were carried out with disc shaped samples 80 - 100/ithick, measuring during 12 days the stationary potential, and the corrosion rate was determined gravimetrically. The electrode potentials shifted towards negative values after the addition of the amines, apparently due to the formation of an inhibiting film which aPfects the cathodic processes. The Card 1/2 S/073/62,/028/009/005/011 Corrosion resistance of indium,... A057/A126 gravimetric measurements showed a considerable inhibi'.-.on of the corrosion by the investigated amines, This effect increases with the..concentration of the amines. The change of the corrosion Irate of the alloys occurs with alternations of their structural state i.e. phase transitions. Minimal corrosion was observed in the region of '?- and ,--phases. The formation and structure of surface layers, formed during the corrosion process, depend an the concentration of the added inhibitors. An increase of the latter effects a drop of the relative content of tin or a rise of the indium content. Hence, surface active substances may in- fluence the formation of corrosion surface layers in dependence of the concen- tration and nature of these substances. There are 4 figures. ASSOCIATIO14: Institut obshchey i neorganicheskoy khimii A11 USSR (Institute of General and Inorganic Chemistry, AS UkrSSR) SUBMITTED: September 16, 1961 Card 2/2 4651 7 S/076/61/035/006/001/013 C/1 ~ 0 C, B127,/B20-3 AUTHORS: Gratsianskiy, N. N. and Vdovenko, I. D. TITLE: Formation of lead sulfate films on an In-Pb alloy during corronion in sulfuric acid solution PERIODICAL: Zhurnal fizicheskoy khimii, v. 35, no. 6, 1961, 1208 - 1211 Tl,,'XTt The authors describe the treatment of an In-Pb alloy with 1~- Sul- furic acid. The alloy was obtained from chemically puro lead and indium fused together in vacuum, the mixing ratio was 55 atom% lead : 45 at04 indium. A resistant layer was found to form on the alloy surface due to the deposition of poorly soluble corrosion products in the form of lead sulfate. The object of the present paper was a study of the formation process of this layer. The formation of the film was observed with the aid of S35 in Sul- furic acid (1120504 ). The activity of the film was measured with an MCT-MMST-17) Geiger counter. It was observed that the layer grew rapidly at the beginning, but the rate of growth decreased more and more until it Card 1/2 S/076/61/035/006/001/013 Formation of lead sulfate ... B127/B203 came to a standstill. The layer thickness was empirically found by the n equation: x = kt; x denotes the layer thickness, t is the time of corrosion, and k and n are constants equal to 0.018 and 1.5 so that the equation now reads: x1-5 . 0.018t. Tho layer thickness was equal to 0.5(4. The authors conclude that the stability of the In-Pb alloy is conditioned by the formation of a corrosion-resistant layer of poorly soluble corrosion products on the surface of noncorrodible layer consisting of lead atoms and the solid Pb-In solution concentrated with lead. There are 3 figures, 1 table,and 4 Sdviet-;bloc references. ASSOCIATION: nauk Institut obshchey i neorganicheskoy '0 khimii (Acadenly of Sciences UkrSSR, Institute of General and Inorganic Chemistry) SUBMITTED: August 3, 1959 Card 2/2 VDOVENKO', I.D.; BUSHIN, V.V. Gorroolon reolotance of irAluz-tvin allOYs In sulfuric acid. Ukr. kh1m, zhur. 29 no,ID1222-1223 163. (KIRA 16t12) 1. Institut obshchey I neorianicheakoy khimii AN Uki6SR. ACCESSION IM. AP4022108 B/00D/6k/03o/003/oe*7/oe52 AMHCIR: Vdovenko,, 1. D.j Kovalevskiy., V. 1. TITLE: Investigation of the corrosion of indiin-antizony alloys SOURCE: Mcrainskly khimicheskiy zburnal,, v. 30, nO- 3# 1964j, 247-252 TOPIC TAGS : indium antimony alloy., corrosion, corrosion activation, InSbj electric' potential, rate of solution, stable passive film, homogeneous allOyp electrochem- ical property. ABSMIACT: This study was conducted to accumulate experimental data regarding the behavior of In-ft alloys in aggressive media and to correlate this behavior to the chemical composition, structure and nature of the reagents. The corrosive behavior of In-Sb alloys was studied in acid (HC1 and H2604) and in alkaline (NAOH) media or different concentrations. The corrosion rate of in-rieb alloys Is greatest in HClL,, the chloride ions apparently activating the corrosion. The rate of solution of Ia-Sb alloys is in accord with the phase diagram., the most stable being the; homa- geneouB alloys containing the chemical compound luft. The minimum corrosion rate is shown by Sb-rich alloys. The potentials of several alloys were also measured. Card 1,12 Acassioff NR., AM221W As a rule good correlation is noted in acid media between the corrosive and the electrochemical properties. Improvement in the potential is accompanied by a decrease in the rate or solution of the alloys. In In-rich alloys the potential assumes a negative value and with increasing Sb content the potential becomes positive. The rate of solution in alkaline solutions is minimalr possibly due to the formation of stable passive films under the influence of atmospheric oxygen. Orig. art. bag: 7 figuree and 1 table. ASSOCIATION: InBtitut, obshchey I neorganicbeskoy khimii AkademijL nauk Ukr= Usti- :tute of General and Inorganic Chemistry,, Academy of Scienceq; Ukx6u) SURU=.- 1&%Y63 DATE ACQ-. 09Apr6k IBM: 00 SM CODE: ML We FdW. SOT: 005 002 Card 2/2 VDGVENKO, I.D. Automation of time determination in the electrocheatical measurement of the thickness of films on metals. Ukr. khim. zhur. 30 no.4t418-419 164. (MIRA 1716) 1. Institut obshchey i neorganicheskoy 1,11imii All LJk-.-SSR. _YWNKO, L.I.- ROYRV, L.M. Effect of surface-active agents on the evaporation velocity of drops of a solution and the condensation of water vapor on them. Trudy UkrNIGK no.47sl7-21 165. (MIRA 18:7) 1. KNIGINA, G.I.: ANTSELFNICH., V.I.: VDGVR:KO, I.S. 2. USSR (600) 4. Yuznetsk Basin - Building 'Materials 7. Building materials fmm burn ores of the Kuznetsk Basin. Ugoll 27 No. 10, 1/052. 9. Monthly List of Russian Accessions, Library of Congress, January 1953. Unclassified. 1. KNIGINA, G. I. - ANTS=ICH, V. I. : VDOVENYO, I. S. 2. USSP. (600) 1 4. Building Materials - Kuznetsk Basin 7. Bui-Idi-ng materials from bum ores of the Kuznetsk Basin. Ugoll 27 no. A, 1952 9. Monthly List of Russian Accessions, Library of Congress, J"Ijarg -1953. Unclassified. I MMRA, O.K.; VDOVENKO. I.D. Blectric timer method for the analysisof solutions. Ukr.khim. 2hur. 25 no.1:25-31 159 (MM 12:4) 1. Kiyevskiy ordena Lenina politekhnicheakiv. institute (Blectrochemical analysis) SMIRSHACHRYA, L.I.; VDOVENKO, K.G.; MUZYUKINA, T.K. Comparative evaluation of various methods for taking material to be tested for dysentery. lAb.delo 2 no.2:25-26 Xr-Ap 156. (MIRA 9:10) 1. Is baktariologichookogo otdela Kuybyehavokoy gorodakoy eanitarno- apidemiologichookoy stantaii. (DYSENTERY) Ge 0-0 0 0 0 0 0 0 -W 9 0 66066996911111 0 0 0 0 0 0 k) il u 1) 4 Id ON 1111111129 )d x loll 121) us ISOXWO&I "At "*'Be v I I I - . - - A 00 4 A40 LI!L el?(.Itt t's 0 PSOCISIrs A-0 PIN 10141 -W. goo sklwiu-mt of UM No. I BlUt-7maft at the X&CMINCOnk -00 Stalin MstaguxtW WorkL (). Pitrovskiv.M. N~lvvvnkov and A. Drvulsitt. (Stal, 1040, No. 10, 131). (fit- Itoodlan). A got tit;ie-tnblo isgiven oftho blowing-out provem which wasevirrit4l out itholit the addition of Anv Insterial to fill fill, eullit %. pl)"ter in the it. tho I'lirtimm turlinve its file lal"Ien wim ~%IIIIIIIIIIV411. vor Ishm ilia m' RM 11111111. IIIP Ilitildt-0 RRM lk-ing tilloued to e'tcapo to atinomplivre. Witter waA sluppliml thmigh water-pip-m welded into the. gam ontlet pilles to m)1 the thivat. Additional .00 0: Ell at* 0 Meant was supplied to the itust-catcbem. The (-wntial foaturo (if fill, blowing-ont olleration by thin mothmi is the""llfrol orthe throat. t inix-raturr, uhieh Amild not exm-d about W' C.. for Ivar of gas explosionli. Throat temperature W. contriulled by conlrolling roe the mto of supply of the cooling water and fill, blast, The latter thokilkl be MIUVOI to one half of the original sie ply t4mar-6 tit,- pill[ coo tif the operation. The stovk level "Illitilil Call tu 1-5.2 tit, stimm, 04014111 of tit %-bro level. The hlmvinv~out olm,rimim dem-rilloil timik I I lir. see 6:0U9 3 will. Go 1 see $00 ASS-SLA NITALLUX4KIL LITIOATUSt CLASSIOKATION .4, 1111111 1W a- All u is AV -a is An A 0 K 6 1 ill III s- All- 031 4 I* " ono sic wit few Oftern Ifill 34 0 0 *1* * 0 o 0 0 * 0 * * * 0 0 * 0 0 0 o 0 0 0 0 6 0!0 * 0 0 0 0 0 0 0 0 0 0 0 0 1111 RO 0 0 0 * 0 0 0 0 0 a o a 0 0 0 0 : 0 VDOVENF61 11. B. Dissertation: "Foraidniferal Fauna of the Vizey Stage of the Donets Basin arid Its Strati- graphic Significance." Gand Geol-llin Sci, Kiev State U, Kiev, 1953. Rteferativrrr Zh al-- y urr Geologiya, Geografiya, Hloscow, Jul 54. SO: SUM NO 356, 25 dan 1955 PASIAL, I.P.; BLMON, V.D.; VDOVENKO, H.I.; ONAYEV, I.A.; TONKONOGIY, A.V.; MGIYMO. V.7a. Cyclone smelting of polymetallic concentrates. Test. AN Kazakh. SSR 13 no.8:76-82 Ag 157. (ULRA 100) L. Akaaemiya'n -auk Kazakhakoy SSR (f or - Basina, - Mudon, Movenko. Onayev, Tonkonogiy). 2. Chimkentakiy svintsovyy zavod (for - (smelting) VDOVL,,NKO.. 111. 1. Dissertation. "Investigation of the Temperature Character3.stics of Asnes From Kazakhstan Coal Used in Power Plants." Cand Tech. Sci, Inst of Power Engineering, Alm-a-AlLa, 1953- Referativrrjy Zhurnal--Khimi:ya, Moscow,, No 13 Jul 54. SO: SbM 110. 35(), 25 Jan 1955 ll:~~Il --,- Z 1, -.- -- - - - , - -- - - - - - -- , - . .. - . I - - . - --- -- - - - -i- - - PI-I ?T r , 1, A~,/-."I TONKONOGIT, .A.V., kandidat tekhnicheskikh nauki BASINA. I.F.; VI)OIWW The cyclone process used in pyrometallurgy. TSvet.met. 30 no-1:30- 42 Ja '57. (MIRA 10:3) l.Akademiya neuk Kazakh koy SSR. (Smelting3 (Turboblowers) (Nonferrous metals--Metallurgy) BAYAKHUNOVY A. Ya.; VDOVENKO, M. I.; YERSHINA, L. M. Oxidation rate of copper sulfides, Izv. AN Kazakh. M. Ser. energo no.2x63-70 262. (MIRA 16:1) (copper sulfide) VDOTEPIKO, M.I., KOOIN, V-F. Crxidation of irr-~- sulfide. Izv. Ali Kazakh.SS.R. Ser.energ. no.1:51--58 160. (11URA 15:5) (Iron sulfides) S/031/61/000/002/002/003 A16i/Ai33 AUTHORS.- Vdovenko, M. I., Bayakhunov, A. Ya., Kondin, V. F. TITTIZ: Investigation of iron sulfide oxidation in suspension PERIODICAL: Vestaik. Akademil nauk Kazakhskoy SSR, no. 2, 1961, 52 - 61 TMT: The existing data on the mechanism and rate of iron sulfide oxidation were obtained in experiments where only the factors affecting the process rate were determined, but the present state of the theory and practice of roasting (in the "bociling layer") and melting /kin suspension and'in the cyclone) require studies In conditions close to the real process. The described Investigation was conducted in four stages: 1) determination of the reaction surface area; 2) of the travel- -he sulfide particles in the furnace; 3) of the reaction surface Ing speed of 4. temperature; 4) of roasting degree of sulfide. The iron sulfide powder was 80T'Ger-~d through a 200-micron meahscreen and introduced into the furnace in single particles. Thr. reaction surface was calculated assuming globular shape. Under the microscope the particles were polygonal. They turned into globules in t-hr, heat. The temperature of the moving burning particles was determined by a ph-oto- -pyrometric method based on comparison of the shadow densities on images with a Card 1/7 S/031/61/000/002/002/003 Investigation of... A16l/A133 reference picture with known temperatures. The particles were photographed by a high-speed camera using a color film, and the shadow density was measured with two filters - a red and a blue one. The ref,7rence Image was of the filament of an optis pyrometAr. The temperature and exposition time were. determin,.-~d gtapKloally and the degree of roasting by gas analysie as well as by chemical and X-ray analy- sis of the roasted particles. The test assembly is illustrated (Fig. 1). Sulfide was fed by an electromagnetic feeder (1) and a water-cooled motile pipe (2) lnlo vertical furnace (3). The roasted particles were collected in cooled receiver (4). Gas from the receiver was extracted through absorber bulbs (5) absorbing S02 ani Sc~, avid the quantity of burned sulfur was determined by titration with iodinf., oz- alkaly. Air was fed by pipe (2) after purifying and drying in vas2als (6). Th& air flow was kept constant and measured with flow meter (7). The syRtem re2lstancp wa3 m,~~asured with preasure gage (8), and the quantity of roasted sulfide by-ifitight, prior to and afte-" roasting. The temperature of the particles was measured from photog.-,raph5 taken through the bottom furnace window (11) with a "Zenit" cam9ra of single pax-f-Acles on the dark background. The speed of pax-ticles was dete"Mirv~l by the number of frames taken through both windows (11), top and bottom, with a "Klyev" cam;~ra (9) t-b--ough a mirror system in a tube (10). The test results are discuzsed gand illustrated In graphs and a table (Table 1). The table showa thre= Card 2/~ s/o3i/61/000/002/002/003 Investigation of... A161/A133 ranges with a characteristioal prevalence of certain reactions. It was not pos- sible to separate each reaction in pure form. Reactions dominating in high perature apparently will be present in lower ranges, and vice versa. No SO de- terminations were made, but it had been found in the iron sulfide oxidation prcc- less In a work carried out previously at the Ural'skiy filial Akademii nauk SSSR (The Ural Branch of the Academy of Sciences USSR). In a comparison the determ1r;ed temperature of particles agreed with the theorc*tical one up to 8000C in the medium (or 1,0500 on the particle surface), but from 8000C up~ the difference was con- siderable (the theoretical was-higher). This may indicate that the intermediate CO compound Is forming with much.lower heat liberation than in oxidation to C02 and SO3, and that further oxidation of SO goes on in a gaseous state and the liberating heat has no heating effect,on the pti-ticles. Conclusions: 1Y The new method roade it possible to determine the sulfide particle, temperature and the roaction :iurface area. 2) The.obtained data indicate three different stages In thin process at different temperatures:- forinatJon of higher sulfur oxides at low temperature, and low oxides at high temperature, up to 80, with a faster proc- ess rate in the third stage. 3) The kinetic-constants were determined for the summary process in separate temperature ranges. There are 5 figures, 2 tables and 5 Soviet-bloc references. Card 3/( inveztigation of... Table I S/031/61/000/002/OC)21*()03 A161A133 Tomp. oxidation Formation reactions of oxides 0(; reactions S03 S02 300-600- F,S+20,.Fe'04 FeSO,-FeO 4-SOs 2FeS +3 ,.50,j- e,Os+2SO, too - I o5plo 503-Fe,0,1+2SO2 2 SO... + 0, 2S03 2S0+ 2bO2 1050-11.1000 2FeS ~2:50.,-Fe3O3+-jbO Kinetic constants of summary process -E, cal/mo~] 1/spe Ko,- 4'270 , - 025 J! 1 17F0 is ;I 457410 Card 4/-( Investigation of ... Figure 1 S/031/61/000/002/002/003 A161/A133 ~ I Card 5/7 Investigation of... S10311611000100210CO- A161/A133 Figure 4: Dependence of the logarithm of the reactiori rate conbtant on the inverse value of absolute temperature 1-simmary process of sulfide oxidation, 2-oxidation of sulfide to sulphate, 3-oxidation of sulfide with formation of S02 Card Investigation of... Figure continued 44 I Al I I Card 7/7 s103116 1/OOU/002/OC)2/()03 A161/A133 TONKOROGIT, A.V.; BASINA, I.P.; VDOVMO, M.I.; KURRANGALIYEV, M.R. New method of metal extraction from sublimates. Izv. AN Irazakb. SSR. Ser.energ. no.1:110-114 159. (MIRA 12:11) (Nonferrous metals--Metallur&7) Bj-~Snllt~, K.R.; REZIlYi.-KOV, A.B.; TOIRCONOGIY, A.V. Ir-:-i ore treatnent .-flow sheet with the use of "he c7clore Izv, AIT Fazakh. SSR. Se-,.er-erp-*. no.2:97-101 '59. (ITIRA 12: 7) (Iron ores) (Sqparatoy6 (Machines)) 8(6) S07/1 I Z-59-4-6537 Translation from.: Referativay-y- zhurnal. Elektrotel-KE-iiiia, 19159, N'l- 4, p 19 !USSR) AUTHOR: Vdc-ver-k-3, M 1. , and Favorskiy, V. V. W TITLE: Temvex~~ture Characteri-stics of t-he Ashes of Sorne K~_z~_kL-_;3tan_ Coals PERIODICAL: V ab.: Isaled. fiz. os=ov. rabochego protsesea. i Alma-Ata, AS Kazakhskaya SSR, 1957, pp 279-284 ABSTRACT: The Pzwer-Engineering Institutpe, AS Kazakhok--ya SSR, haa stlzdlied the ViEC,:~g4+ 7 of slags cf typicall Kazzakhat'sn coalp. wlthLa ti - t3 ra-ge witlt the pu..rp,->se of findizzig t1lie connecti%in betweezt th--, temperatuxe characteriet'cs. A numbez, of hetexogeneo,:~s a solid-plLase con.tent of 30-50% !L-r%ve been stv~ffied. The solid plh~~-(! h-.Is been repy-esented by qtL--Ttz 6and, barite ore, or galenite w4.-.nh, the Enec:*Z;_c weights. .7 ?.i, 4. 3. and 6.6, respectIvely. The iiq~,_Od pl~_se lies beez i~e-pXesenzzd b-1) salut:' *onis of sugar in glycerine, colo'phonty, traixafornner mil, :,:,..ad. co).! tar. Tite followhig eemrii:vical relation between the ternp~ezaturc- -vhsc-,siy bl.en obtained: 61 = at--~L. The slags from Lenger, YayBan, _Ke11tc-.-na:3h2.t, anc: Card 112 SOV I I IZI -5-9 -4-6 5 37 Temperature Gharacteristics of the Ashes of Some Kazakhstan Cozz'13 Karaganda brown coals have been studied; these slags have a z,elat've!7 low ftzs-;on point. The empirical relation between the temperatuxe characteristic and viscosity for these slags in dimensionless quantities is Fa - ID-% where is the ratio of viscosity at any temperature to the viscoBi at the po-Int t2, 19 49 the ratio of the temperature at which the viscosity is sought to the temperature at the point t?, n is a constant (70 for the above experiments). The following conclusions are drawn: in Bthtd7ing viscosity characteristics of high-temperature complex systerns, a 'larity between them and the low-temperature heterogeneoza systems ca:a be used. Slags of some Kazakhsta--i power-producing coals at the temperature t? have the sam- e viscosIty, about 100,000 poise, zr;.d at the pol ' t3, about 33,000 poise. The viscosity-ternperature relation of the above slags ar-c! that i of cooll systems can be expressed, in dimens,10--less cco:-diza-tes, b-,r the same curve; thL5 fact points out that theTe is an approxannate B.JMLari-.'-,r --,n t'he effect of temperature on viscosity. S. M. sh. Card 2/2 1: H pig AKI Al 0 00 131 - 11-aul 11-11,11zi A: 0 oil vi 19i Ji, BASINA, I.P.; VDOVENKO, M.I.; KURMANGALIYEV, M.R. Principal results of the studies of cyclone processes of smelting and sublimation. Trudy Inst. energ. AN Kazakh. SSR 2:261-273 '60. (Mmk 15-.1) (Smelting) (Furnaces) (Copper) KOIOSOV, I.S.; VDOVCH211KOt --- ~ Certain problems of long term planning of emergency reserTe requirements of electric power systems- Obshch. energ. nO.l: MU 13:2) 43-51 '59- (Electric power production) TDOVENKO, M.V. Lower Vise Foraminifers. in the Donate Basim. Nauk.zap.Kviv.un. 16 no.14:115-123 157. NIRA 13:4) (Donets; Basin-Foraminifera, Fossil) "OVEIZOV M Comparison betveen the Foraminifera. found in lower Vise' sediments of the Donets Basin and the Foraminifera in the Bashkirian Mountains. Nauk zap. Kyiv. un. 15 no.2:53-57 '56. (MM 11:7) (Donets Basin--Foraminifer&, Fossil) (Bashkiria--Foraminifera, Fossil) ) ( , j-, - ~~ 6 , 1 2'1 VDOVKNKO,M.I.; FATEYXVA.Ye-T. Characteristics of some Kazakh coals for power. Izr.Aff 1.:azay-q.SSR Ser.energ. no-7:92-108 '54. (MIRA 8:12) (coal) VDOVWO,M.I.; FAVORSKIY,V.V. ~k---~_ Study of temperature characteristics of ashes from Xazakh in- dustrial coals. I2v.AN Kazakh.SSR.Ser.anarg.no.8:95-108 '55- (Ash (Technology)) (MIRA 8:12) 4 It is M a 1127 Dion xiix)9 ,1111 Wil JOA 1617 a A &-I I A ll Ait $1 ix W - ff P --k j Disturbance of the watvr basucl, And disolder 01 the liver In acute articut" rheumatism. 1. 1. Speramkit mutt 0 all -r ~ M. S. Vilovenko. Mix. Mfj. JU, S. S. it.) 16, -I 1939 1 44 t l1 ( . n a Cases t, . QV'4tc , Arliculan, theunlativill 4110tuda,itwe all the WAtet tlantV w"* 1-th in the febrile &last of the digeaw and 00 0 1 lot a long liflir Altrr tile lefelp. had game down, This djq- (Iffbant7v Consisted of 3 phasr%-. in the first the exclet lull of w2ter was insufficient. In the following 22nd phast it was :vaivr. r jaT Tba: teallst is regarded as deransenjent of tile at - Nl'aana- lie tjo 0 be 0 A a U --r -i' -T &A Kit 11 9 tn all 11" I if of 9 a- -Oi-i 4 -r- z, T" 15-57-5-5835 Translation from: Referativnyy zhurnal, Geologiya, 1957, Nr 5, p 17 (USSR) AUTHOR: Vdovenko, M. V. TITLE: A Comparisq'n of the Lower Visean Poraminiferal Fauna of the Donets Basin and the Mountainous Part of Bashkiria (Porivnyannya fauny foraminifer nyzhnlovizeyslkykh vidkladiv Donetalkol%o baseynu ta girstkoi,' Bashkiri in Ukrainian) PERIODICAL: Nauk. zap. Kiyivsfk. un-t, 1956, Vol 15, Nr 2, pp 53-57 ABSTRACT: The author notes the similarity in the foraminiferal and fusulinid groups from lower Visean deposits in the Kur-Krauk River section of the Southern Urals and in rocks of the same age in the Donbass. Archaediscus . . endothyrids of the group Endothyra uradyi, and, very rarely, quasiendothyrids appear for-ETTe--Tirst time in this group. Primitive forms of Eostafella and Para- stafella (Eostafella mediocris, E. prisca,' and -tFe-sub- Card 1/2 genus Eoparastafelia) are also present. A group of 15-57-5-5835 A Comparison of the Lower Visean Foraminiferal Fauna (Cont.-) foraminifers similar to those in the Kur-Krauk section is found in the lower Visean rocks along the Sikaza River (Southern Urals). Brunsia and Lituotubella occurin the Donets group but are almost absent at Kur-Krauk. Tetrataxis does not occur and Archaediscus is but poorly represented in the Donets assemblage. Thus, the Kur- Krauk rocks contain foraminifers only of upper lower-Visean age. The author suggests that a hidden unconformity occurs between the Tournaisian and the Visean rocks at Kur-Krauk and at other places in the Southern Urals (Sikaza River and elsewhere). Card 2/2 R. A. V. VDOVENKO, M.V. Some new Upper Visean and Lower Namurian species of Foraninifera in southwestern and central Kazakhstan. Paleont.zhur. no.1:41-46- 162. (MIRA 15:3) 1. Kiyevskiy gosudarstvennyy universitet imeni Shevchenko. (Kazakhstan--Foraminifera, Fossil) VWV-R-.KO, M. V. Evolution of t,:e series Eoparastaffella-Pseudoendothyra. Ti-,:,.I-,r Inst. geol. nauk AN MR Ser. strat. i paleont. no. 48tl6-,~C; .64 (MIRA 1!~~ ~ J ) EmORO, 0'" 1, pVv strutigmp4r of tho Lowor Carbmlforous of Us Belouty basin in oentna Kazakhaten., Sborr=whrmbNlov9unv nool#35-46 163. (MM 301n) VDOVEIIKO, M.V. Stratigraphic distribution of Lower Carboniferous Foraminifera in central Kazakhstan. Sbor.nauch.rab.Kiev.un. no.1:5Q-66 163- (YLIRA 18:11) BABK09 A.K.; VDO'VENK02 M.Y Effect of a solv6nt mixture campostion on the separation of som rare earths by paper chromatography. Zhur.a*al.khim. 17 no.72 820-M 0 162. (MU 15t12) 1. Institute of General and Inorganic Chemistryq leadewl of Sciences, Ukrainian S.S.R.# Kiev. (Rare earths.-Analysis) (Paper chromatography) 3TPY~NK - P~ M.,'Ye.. Effect of -tA-e composition of a mix-tuxe of esterB vith ke-t-meal and alcobols on 'Vhe separation of certain rare-earth elements by paper chromatography. Zhur. anal. khimo 18 no.9:1063-1070 S 163, (MIRA 16-11) 1. Instituts of General and Inorganic Chemistvy, Academy of Sciences, n-rainian S.S.R., Kiyev. 'o 14.Ye.; KOPAJS BABXOJP A.No; ~ ~o M.V. Direct photcmagtric d6twrmination of rare earth elements by paper chromatogmpby,_Zav. lab. 29 no.6.1645-649 163. (MIRA 16:6) 1. Insti-tut obshchey i neorganicheiskoy khimii AN UkrSSR. (Rare eimths.-Ahalysis) (Paper chromatograpby) VDGVENKO, M-Ye.; SPIVAKOVSKAYA, N.Ye. Trilon B in the determination of microquantities of lead in metallic cadmium. Zav.lab. 27 ni.8:963-964 161. (HIM 14-.7) 1. Institut obshchey i neorganicheskoy khimii AN USSR. (Lead--Analysis) (Cadmium--Analysis) _014;~6 ~9W 45/0619 IZMSSrMT-W-. AP3001521 STOAT 6~* &-;-Vdovenko., M.Ye.; Kopa., M. V. TITLE; Direct photometric determination of rare -earth-elements -by paper chromatography samm- zavodskaya laboratoriya., V, 290 noA 6, i963t 64s-649 iTOPIC TAGS: rare-earth chromatogram, rare-earth chxomstogrkphyj, lanthw=.,' neodymium., yttrium, reflection coefficient.. chromatographic spot, rare-earth ;,element, paper chromatography, reflected light ;ABSMCT-. The authors determined the color intensity of spots from rare earth i chromatograw In reflected light, using a,universal photometer with a light filter of 574 millimicron wave length. Using various concentrations of lanthe- num-1 neodymium-., and yttrium-nitrate., they found the reflection coefficient K to be in,~,erseiy proportional to the amount of substance in the chromatographic spot, Thus.. the problem was reduced to obtaining spots of the same size and shape. The experimental technique consisted in placing 0.001 ml of the rare metal nitrate solution on a chromatographic paper' strip., allowing it to stand for 30 minutes in a humidiWng chamber, followed by 5 hours of ascending chromatography Cord 1A L 12,?74-63 ACCESSION 'MR: AP3001521 ~Incylinders containing 50-ml-of a 1:2 ether-acetone mixture vith 0.4 gm ~thiocyanic acid. After dx"jing,, the chromatogram UM developed by spraying with a 0.4% alizarin solution containing 3% urotropin. The authors found that the ,spots were of a round shape when the drop of the experimental solution was ~placed15 cm. from the lower edge of the chromatographic paper strip., also when the ascendant flow van Elowed down either by rendering the solution more viscous :Iby dissolving photographic film in it or by nvmwina its access vith transverse cuts in the pgper strip. The technique proved accurate within ic~ on samples of. Loparib~j 143nazit~e, and Parisite., as coppared with the x-ray spectral and trilon microtitration procedures. Orig. art. hes: 4 figures and I table. ASSOCIATION: Institut obshchey i neorgenicheskoy khimii AN USSR (institute of ;General a~d Inorganic Chemistry,, Academy of Sciences USSR)* SUMaTTED: 00 DETE ACQ: 17jun63 ENCL. 00 SUB CODE: 00 NO REF SOV: 005 OTM: 001 -Card 2/2 2~351 r S/032/6'/027/006/001/018 52,"-0 B124/B203 AUTHORS: Marchenko, P. V., Vdovenko, M. Ye., Nabivanets, B. I., Obolonchik, 11, V. --a-R-U-5ff-i-al-o-Maya, V_ Ye. TITLE: Methods of determining impurities in metallic cadmium .) of high purity ~ERIODICALs Zavodskaya laboratoriya, v. 27, no. 6, 1961, 638 - 639 TEXT: The present paper describes a number of chemical methods for determining Fe, Cu, Ni, Sn, Sb, Tl, and As in high-purity cadmium; the determination of Zn had already been described in Ref. 1 (P. V. Marchenko. Zavodskaya laboratoriya, XXVI, 5, 532 (196o)), whereas the Pb determination will be described In Ref. 2 (M. Ye. Vdovenko, N. Ye. Spivakovskaya. Zavodskaya laboratoriya 'in Print)). For the corresponding determinations, the authors used semimicro-methods and only purified reagents and re- distilled water. Cadmium was dissolved in hydrochloric acid in a platinum Y vessel. Iron was determined colorimetrically with the aid of the ternary Fe-thiocyanate-diantipyrilmethane complex which can be extracted with chloroform. The disturbing Cu and Bi are precipitated with ZnS at PH - 4. Card 1/4 Methods of determining impirities-, Fe 3+ is reduced with ascorbic acid to Fe(OH)3' Copper is determined without 25351 S/032/61/027/006/00-1/018 B!24/B203 Fe 2+ to avoid losses by formation of seFaration from cadmium with diethy, ~~J_ dithiooaTbamatel the colored complex Is extracted from 40 - 45 ml of aqueous solution with 2 ml of CC1 49 and the color of the extract is compared with a standard series. Niokel is determined by extraction of its complex 4ith dimethyl glyoxime by means of ebl.oroform and subsequent evaporation of the chloroform under HC1, For the final determination of Ni, the authors used the formation of its complex with dimettiyl glyoxime in tne presence of ammonium persulfate. Tin is determined colorimetrically by extraction of its diethyl dithiocarbamate complex with chloroform, re-extraction with permanganate, and reaction with p-nitro-phenyl fluorone. For a quantitative extraction of tin in the presence of large Cd amounts, the extraction is repeated four times with new portions of a solution of diethyl dithiocarbamic acid in chloroform. Arsenic is determined colorimetrically in the form of arsenomolybdenum blue which can be ex- tracted with I ml of isoamyl alcohol. To concentrate the arsenic and sepa- rate it from Cd, the latter is distilled ofr in the form of arsenic hydride, the Card 2/4 25351 3/032/61/027/006/001/018 .Methods of determining impurities ... B124/B203 analyzea cadmium specimen being used instead of metallic zinc. Antimony and thallium are determined by the known extraction-colorimetric methods with the use of crystal violet from one weighed portion; the difference in the pH-values in the precipitation of their hyaroxy acids (Sb at 3+ PH - 5, TI at PH - 8 - 9, and Cd at PH - 7) is used for the cadmium separation. The following table was compiled on the basis of the. experi- ments made. There.are 1 table-and 11 Soviet-bloc references. ASSOCIATION: Institut obahchey i neorganicheskoy khimii Akademii nauk USSR (Institute of General and Inorganic Chemistry of the Academy of Sciences UkrSSR) YDOVENKO, M.Ye. . I., ... Fourth Republic Congress on Chemical Control of Production in Metal- lurg~ and Metalworking Industries. Ukr.khim.zhur. 24 no-5:695-697 1 58, (MIRA 12:1) (Metallurgy--Congresses) 5(2) SO V/32-25-4-1 2/71 AUTHORS: Vdovenko, K. Ye,, Spivakovskaya. N. Ye. TITLE: The Use of Trilon 3 in Determining Chromium in Steel (Primeneniye trilona B pri opredelenii khroma v stali) PERIODICAL: Zavodskaya Laboratoriya, 1950., Vol 25, Nr 4, PP 416-417 (USSR) ABSTRACT: The determination of chromium in steel can be made by an oxida- tion of tho chromium to bichromate and a ouboequezit iodonetric titration. Iron can be bound by trilon B (Ref 1), but some dif- ficulties will arise in the presence of vanadium.To overcome these, some hints have already been given (Refs 2,3) which are based on -- change of the redox potential with the pH. In the present paper it vias found out that at pH = 1.5 - 2.0 the bi- chromate is still reduced fast enough with potassium iodide (3 - 5 minutes) while the vanadate only reacts very slowly with potassium iodide. This knowledge forms the basis for the sug- Cested method of determination of chromium in steels with or without vanadium, also in the presence of wolfram. A table of analytic results by the described methods of analysis of dif- ferent standard samples is given (Table). There are 1 table Card 112 and 3 references. The Use of Trilon 3 in Deter:--ining Chromium in Steel SOV/ 32-25-4-12/71 ASSOCIATION: Institut obshchey i riecrE:anicheskoy- khinii ;kz-deniii US~;R (Institute of General and Iqoi-r--.qic ChemiL;try of the A.cademy of Sciences,Ukr3310 Card 2/2 ACC NR-.--AP6019226 ~A) SOU111CF, CODE: -AUTHOR: Babko, A. K.; Vdovenko,, M. Ye ORG: Institute of General and Inorganic Chomistry,01 Mcr"I'M (Inst-itut oibohc~.ey 'i neorganicheskoy khimii AN UkrSSR) TITLE: Comparison of reagents for direct photometric determination of rare-earth elements on chromatograms SOURCEt Ukrainakiy Ichimicheakiy zhurnal, V. 32, no. 2,, 1966, 209-212 TOPIC TAGS: rare earth element, photometric analysis, chromatographic analysis, spectrophotometric analysis,* light reflection coefficient 1,q.F.-nt0t9x_ 19cFwr ABSTRACT: Eight organic reagents ( methylthymol blue, pyrocatechol violet, glycine- thymol blue, alizarin, eriochromocyanine, xylenol orange resorcin, and peridylazo- and arsenazo-resorcin) were compared by studying the reflection spectra on paper cauzrd by the reaction of La with the reagent. The spectrophotometric charactoristics of the reagent and the products of reaction were used as criteria for selecting the =ost efficient reagent. The refleotion spectra of complexes and reagents on the paper were! taken with an SF-af apparatus containing a devire for measuring reflections. Water- alcohol and 1 x 10-3 M alcohol solutions of the reagents and 2.8 x 1o-2 1.1 La solu_ tions at PH 5 (urotropine buffer) were used in the experiments. Via I& solut ion Card 1/2 UDG; 543-5"+546.65 ACC NR: AP6019226 (0-05 ml) was applied on chromatographic paper Wl (East German) and dried in air. After applying 0*05 ml of reagent -solution, the paper was dried a4~ain aza t,2~e reflec- tion spectrum of the stain was taken in the SF-214 spoctrophotometer. The min'-=--s of the reflections of the complexes 01,bR) and reagents (AILt) , the displacements of the reflection band during complex formMon (AX), the minimal coefficients of the reflec- tions of complexes (K, ) and reagents (K, and their absolute (41 = K-in - ay and relative (A1014, ~~gifferences were de ormined for each reagent frora the raflectim spectra of coloredI s~"). The data obtained were tabulated and showed that mothyl- ~ thymol blue and alizarin were the best according to the intensity of reflections and!, the spectral displacement of the reflection band. It was found during the plotting I of the calibration ctrvo that the methylthymol blue yielded a considerably larger ra flection for the blank experiment. The advantages of alizarin over methylthy--ol were substantiated also by the followin observation. A certain arrount of blurring was seen' 9 during the formation of stains on paper. This was related to the chromatographic properties of the reagent solvent (alcohol and H20). Me blurring is objectionable in chromatograms with a large amount of separating elements. The solvent fraa of this effcat, i.e., one with an Rf of nearly zero for all rare-earth elements, was the one to be searched for. A study was made of solutions of methylthymol amd alizarim ia higher alcolhols and ketones. Only alizarin dissolved in butanol and ethanol. -1he use i;- of alizarin dissolved in butanol yielded well-coloredp distinct and uniform stains. The refleation spectra of the La with alizarin and the alizarin itself remained -un- changed. Orig. art. has: 2 fig. and 1 table. SUB COM OV SUBM DAT"Et OlDec64/ ORIG REF; 009/ OTH RZF; 004 Card 2/2 MARCHENKO, P.V.: VDOIJEIN(O M.Ye.; NABIVANETS, B.I.; OBOLONCHIK, N.V. 1-~ SPIVAKOVSWR~.- 5b."' -- Methods of dete- '"ina the impurities in high purity metallic cadmium. Zav.1aa. 27 no.6:638-639 161. (MIU 3.4:8) 1. Inst-1tut obshchey i neorganicheskoy khimii Ali USSR. (Cadmium-Analysis) S/075/62/017/007/002/006 B119/B166 AUTHORSs Babko, A. K., and Vdovenko, M. Ye. TITLE: Effect of the composition of solve-n-T mixtures on the paper chromatographic separation of some rare earths PERIODICAL: Zhurnal analiticheskoy khimii, Y. 17, no- 7, 1962, 820 - 824 TEXT: A physicochemical analysis was made'to' discover how the paper chromatographic separation of La, Nd, and Y is affected by different com- positions of mixtures of diethyl ether (E) with methanol (I), ethanol (H), propanol (III), butanol (IV), acetone M, methyl ethyl ketone (VI), or cyclohexanone (VII). The following mixtures were found to be optimumt EtI (Rf values in the order La, Ed, Yi 0.-25, 0.41, 0.60); E:II - 10 (Rf S 0.19, 0.35, 0.59); EMI - 1:9 (R f1 0.06, 0.16, 0-36)1 EjV - 1t2 (Rf s 0.06, 0.22, 0.61); EiVII - 1sq (R f: 0-03, 0-10, 0-30); pure VI (Rf 1 0..08, 0.27, 0-51)a The differentiating action of the solvent in-:-, creases with '~ts solubility in water. There are 7 figures and I table. Card 1/2 B/075/62/017/007/002/006 Effect of the composition of... B119/B186 The most important English-language reference iss F. Pollardp J. Mc. Omie, H. Stevenal J. Chem. Soc. 12, 4730 (1952). ASSOCIATIONt Institut obshchey i neorganichaskoy khimii AH USSR, Kiyev (Institute of General and Inorganic Chemistry AS UkrSSR, Kiyev) SUBMITTEDs October 31, 1961 Card 2/2 6 L 24826-6 MIJG ACC NR: AP6010834 SOURCE CODE: UR/0073/66/032/003/0284/0289 A0 jAUfHOR: Vdovenko M. Yei 3 ~ORG: Institute of General and Inorganic Chemistry, AN UkrSSR Inst*tut obshchey i khimii AN UkrSSR) tion of rare earth elements in tile fo ;TITLE: Mechanism of separa rm of thiocyanates :'by paper chromatography ISOURCE: Ukriinskiy khimicheskiy zhurnal, v. 32, no. 3, 1966, 284-289 !TOPIC TAGS: rare earth element, thiocyanate, paper chromatography, chemical separa--~, ition, partition coefficient 'ABSTRACT: In order to check the h othesis that the mechanism of separation of rare yp ;earth elements by paper chromatography is not identical when different solvent mix-i 'tures are used, -tile separation of rare earths in the form of thiocyanates was stud- !ied in different M-Ixtures of methyl acetate, ether, and butyl acetate with methanol 'or acetone. The partition coefficients Kpart of the rare earths were determined Rf values i(using yttrium as an example) at variou compositions of these mixtures. !Card 1/2 UDC: , 543,+ 546.65i; L 24826-66 ACC NR: AP6010834 .!were then calculated and compared with values obtained experimentally in a chroma-to..i 1graphic separation with the same mixtures. In order to determine KDart, it was necessary to know the volume of the organic phase; since for a mixtEre of solvents .!of which one is completely soluble in water the volume of the organic phase changesi, -unction of the composition of the mixture, the volume change of the organic as a f .!phase was determined in the following system of various compositions: saturated so_~ It was shown that in acetone Ilution of ammonium nitrate - mixture of solvents. !ester or acetone - ether mixtures the separation followed a simple partition mecha--;~ nism. In the case of methanol - ester or methanol - ether mixtures, the relation Detween Rf and Kpart is more complex. It is concluded that in the chromat 'ographic i separation of rare earth elements in the form of tbiocyanates, the maximum differen,-'L tial effect of the solvent mixture corresponds to a definite volume of the organic :phase. Orig. art. has: 6 figures. SUB CODE: 07 SUBM DATE: 1BNov64/ ORIG REF: 004/ OTH REF: 002 Card-, 2/2_1;;~ VDOVENKOo N. Y. USSR/Scientific Organization - Academy of Feb 53 Sciences USSR "Director of the Radium Institute imeni V. G. Xhlopin" Vest Akad Nauk No 2, 1953, P 53 Presidium has appointed N. M. Vdovenko, Dr Chem Sci, to be Dir of the Inst, subject to the approval of the General Assembly of the Acad. 271T97 SOKOLISKAYA, A.M.; YWVENKO, N.N. Hydrogenation of hydroxycodainone. Vest.AU Kazakh.SSIC 16 no.2:44-48 Ir 160. (MBA 13: 6) (Godeinone) (Hydrogenation) VDOVENKOY-.N.S.., inzh.; SHEVCHENKO, A.G. lArge-block ass6mb2,y of a composite banking unit. Mont. i 3p--ta. iabi v stroi. 24 no-90-8 S 1.62. (MIRA 15:9) 1. Soyuzprommekhanizatsiya. (Earthmoving machinery) OVCHARENKO, Fedor Danilovich, akademik; KUKOVSKIY, Yevgeniy Georgiyevich; NICHIPORENKO, Sergey Petrovich; VDOVENKO, Sergey Petrovich; TRET VDO~~ ~d;f asil!7 IMUK Vikentiy Yurlyesviah; 1WWWRMUW11, FAWASEVICH, Aleksandr Aleksandrovich; POKROVSKAYA, Z.S., red. izd-va; MONZHERAN,P.F., tekhn. red. [Colloid chemistry of palygorskite] Kolloidnaia khimiia paly- gorskita. Pod obshchei red. F.D.Oveharenko. Kiev, Izd-vo AN Ukr.SSR, 1963. 119 P. (MIRA 16:7) 1. AN Ukr.SSR (for Ovcharenko). (Palygorskite) (Colloids) VDOVENKO, N.V., kand.tekhr,.nauk; VDOVENFO, I.D., kand.tekhn.nauk New method o. ' chemical degreasing. Mashinostroenie no. 2: 66 Mr-Ap 164. WIRA 17:5) L 9 --1-: P (.1 AT6020589 -4 6 061 ACC NR: SOURCE WEE -I URT0606/ 000 077/0081 AUTHOR: Kolos-juk, R. G.; Vdovenko, 11. V.; Ishc uky juL_-ju- ORGI UkrINFIlgiproneft' f - TITLO-9 Structural and mechanical properties of oloopseudogels based on octadocylam- monium bentonite and palygorskito complexes SOURCE: Neftepererabotka i neftekhimiya (Petroleum refining and petroleum chemistry)~ Kiev, Naukova dumka, 1965, 77-81 TOPIC TAGS: clay, grease, rheologic property ABSTRACT: The Ukraine has rich deposits of Ca-bentonites and palygorskite; in this connection, the authors studied the possibility of using modified clays of Ukrainian deposits in the production of lubricating greasesif The modification of the surface oJ the clays was carried out by using octadecylamine (C18H37%). The lubricants 1-fore made by preparing a suspension of the organophilic clay and mineral oilp then homogen- izing the mixture in a laboratory paint mill. A quantitative evaluation of the rheo- logical properties of the bentonite oleopseudogels obtainad showeg that the most ef- fective of the thickening agents studied were the BK-0and Wh-Vlorganophilic benton- ites and a bentonite-palygorskite mixture. The results'leaT -to-the hypothesis that the nature of organomineral complexes (thickening agents) substantially affects the 1/2