SCIENTIFIC ABSTRACT VDOVIN, V.M. - VDOVIN, YU.A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001859210019-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 19
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

NAMETKIN, N.S.; VDOVIN, ZAVIYALOV, V.I.
Silicocyclobutane polymerization catalysts. Izv.AN ssc%R. Ser.khim.
no.1:203 Ja 164. (MIRA 17:4)
1. Institut neftakhimicheskogo sinteza im. A.V.Topchiyova AN SSSR.

VDOVIN, V.M.; NAMTKIN, N.S.; FINKELISHTEYN, Ye.Sh.; OPPENGIEYM, V.D.
Conversion of vinylbenzyl derivatives of silicon in the presence
of alkylation catalysts. Izv. AN SSSR. Ser.khim. no.3:459-464
mr 164. (AURA 17-4)
1. Institut neftekhimicheskogo sinteza im. A.V.Topchiyeva
AN SSSR.

r 1 1 T~,
I U
1. Inst-itut. rieftekh-imicheskcgo sinteza im. V.A. Topcliyeva
IIIN sssli.

ACPMSSION NR: A?40244,10
S/0204/64'/004/001/0137/0141
AUTHORS: Nametkin, N.A.; Berezkin, V.G.; Vanyukova, N.Ya.; VdovinV.140
TITLE: Gas-liquid chromatography of several silioohydrocarbons and
paraffins.
SOURCE: Nleftekliimiya, v. 4, no. 1, 1964, 137-141
TORIC TAGS: gas liquid chromatoSraphy, paraffin,- silicohydrocarbon,
elution characteristic, retention time, chromatographic analysis
ABSTR&OT: Me elution characteristics of hydrocarbons and of sili-'
cohydrocarbons i..rhich are structurally similar analogs of the hydro-
carbons were investigated in order to determine if mixtures of these
materials can be identified chromatographically. The relative reten-
tion time of certain silicohydrocarbons and of paraffins on two stat-
~ionary liquid phases of different (Dolymethylphenylsiloxane
(1) and polyethyleneglycol 15~0)la(rlilt)y) was determined at differ-
ent temperatures. The -following homologous series of hydrocarbons and.
silicohydrocarbons were studied
Card 1/5

~AOOESSIO'X NR: AP4024410
C112
'(CHS~ Si
~C
\C111
(Clij)a Sl (Cllj)'V Clio;
Clio (Clij)" Clio.
COMDarison of the retention time in Dhases I and II at 100 and 75d,
respectively, is shown in fig. 1: Til SI(CH2)n Si(CH3)
- U e (OH )
,type compounds can be identified in mixt0e; with paraffins Od other
silicohydrocarbons. By lowering the temperatures of the chromato-
graphic columns the selbcted phases I and II can be used to identify
the other series of compounds (fig. 2). It is recommended that the
elution characteristic be determined on the different stationary
phases at different temperatures and not at the same temperature.
The logarithm of the relative retention time of the silicohydrocarbons
can be represented as the sum of the partial values corresponding to
the specific bonds: (V.G. Berezkia and V.S. Kruglikova, Neftekhimiya,
N, 6, 845 (1962)):
Card 2/5

ACCESSION NP.: A?4,0244,10
Ig P'i - nj r,,,
where,,x = relative retention value of lgcK corresponding
1~s or.struotural .
to the hetermined combination of bon Ilements and n
= number of given structural elements in the molecule. The values
for the CH - CHO bond are practically the same for paraffins and
for the sHicohyarocarbons, and this is in agreement with the simi-
larity of the physical and chemical properties of the tetraorgano-
silicon com-nounds and of the structurally similar hydrocarbons. Orig.
art. has: 3 tables, 2 figures, 1 equation and 1 formula
ASSOCIATION: Institut neftelchimicheskogo sinteza AN SSSR im. A.V.
Topchiyeva (Institute of Pe.trochemioal Synthesis, AN SSSR)
SUBMITTED; 13'MaY63 DATE ACQ: 17Apr64 ENCL: 02
,.SUB CODE: CH ITR REP SOV: 009 OTHER: 003
Card 3/5,

1 A~
BNCLOSURZt 01
ACcFsslo*,i NR IAP4024410
Fig. 1
een the relative retention
Relationship betw
and paraffins
capacity of s ilicohydro carbons
on polymethylphenylailoxane oil ( -Xrat 1000;
and -polyethyleneglycol (aKrat 75C).
X--compounds of the series (CH3)3Si(CH2)n'
Si(CF-3)3;
0-- n-paraffins;
3)3S'(CH2)nCH3
ILI
-40 A--(CH3)2SiNCw
...Card 4/5

ACCESSIONINR:' AP4024410 ENCLOSURES 0 2
Fig. 2
Relationships between ocx at 75C and
cc at 50C.' Designations the same as in
'47 fig. 1.
qj -
V .4S. 47 49 C,
C=d 5/-5

ACCE,13SION NR: AP4012090 S/0020/64/154/002/0383/0386
AUTHORS: Nametkin, N.S. (corresponding member); Vdovin,.,,V,.JL;
Finkellshteyno Ye. Sh.; Arkhipova.' T.N.;'O~~geymjp V.D.
TITLE: Synthesis of 3,4-benzosilicocyclopentanes
SOURCE: AN SSSR. Doklady*,, v. 154, no. 2, 1964, 383-386
TOPIC TAGS: 3,4-benzosilicocyclopentahe, infra-re 'd spectrum,,ultra-
violet spectrump L',loromethylbenzyldichlorailane cyclization, 3.4-
benzosilicocyalopoix%ane synthesis, silicon containing indane
fABSTRACT: The siliaNn-containing analog of indanes 3#4-benzosill-
cocyalopentane and sent of its derivatives were synthes1zed and
characterized by theli-IR and u.v. spectra and physical properties.
ChloromethylbenzyldlolL'orailans was *yoljx*d with AM In b*nzone
Card

ACCESSION NR: AP4012090
to the 3.4-benzo-1,1-dichlorosilicocyclopentane:
i CICH AIC13
MIR Cu. ICIs +HCJ.
The latter was reduced with LiAlH4 to 3,4-benzo-1,1-dihydrosilico-
cyclopentane, alkylated with fUfjgBr to the oorrosponding 1.1-
dimethyl- and 1,1-dibutyl-derivatives, and reached with acetic
anhydride to fom the 3,4-benzo-1,1-diacetosilicocyclopentane.;~
H CH
UA111,
IC11 1H,
H/ V\CHS
,r,\
ICI, +RAIgBr IR,
V\C"I/
R - 013 " 4-cilf,
Icle + (013co~~ GCOCHAh
if,
Card 2/3

ACCESSION NR: Ap4ol2o9o
Orig. art. has:- 3 figures, 1 table, 2 equations and 2 formulas,
ASSOCIATION: Ins'titut haftekhimicheskogo sintoza.' Akademii nauk
SSSR (institute of Petrochemical Synthesis, Academy of Sciences
SSSR)
.SUBMITTED: 28SOP63. DATE AOQ:, 14pab64 EXMt 60
-SUB CODE: CH NO REP SOV: 005 OTHERt 001
C.,d 3/3

ACCESSION NR: AP403OT84 S/0020/64/155/004/0849/0852
AUTHOR: Hametkin, N. S. (Corresponding me er);-V,dov1.n., V. M.; Grimberg. P. L.
TITIE: Si3icacyclobutanee. Strength of the Si-C bond of the xilicacyclobutane
ring and synthesis of new derivatives of silicacyclobutanas.
SOURCE: AN SSSR. Doklady,*, v. 155.. no. 4., 1964., 849-852
TOPIC TAGS; silicacyclobutane., silicacyclopentane,, silicacyclohexane, silicon
carbon bond strengtho silicacyclobutane derivative, synthesis,, alkzvailica-
cyclobutanot acatoxysilicacylcobutane., amin silicacyclobutane
ABSTRACT: The investigation included an examination. of the strength of the Si-C
b=& of the silicacyclobutane ring,, of the specificity of reactions for the
"aLlicacyclobutane ring, and of the synthesis of new allicacyclobutane derivatives.
11-Reaction. was attempted between 1,1-d1methylsilicacyclobutane and haptyl alcohol,
acetic acid,, acetic anhydride., hydrochloric acid,, hydrogen chloride gas., watar
:-end-diethylsmine. Reactions with acids, alcohol., and vater proceeded according
-1--to-the equation

ACCMUSIM NR: AP4030784
CHI
CH SIC
~CH, R - S61-1,CH.CH, - H
D
6,
0
R=a, 0-C-ClIs, MlHwoy, OH
These reactions am specific for the Si-C bond of the silicacyclobutane rlng;
they
w= not proceed vith the 1,Ol-dizethylsilicacyclopentane or 4wxaw. Reactions
Vero attempted vith methylcblorosi3.icacyclobutare:
go"/ C11, C113
CHO S. R OC.11,-61.11) '11-"
CH~ 0u
c1f, CHI
+CH S
C 01, 10-IrIH *-.,.i
04 $4
CHO. CHI
all . ~ R.C,8: -79%)
%CH,* 0.
C
C11, CHO
C'HA "S," 0 (48%) UA
CHO' %0-e~~

Acassim im Ap4o3o784
Reactions 11a, T-lc,, and Ild are a memo of ayathesizing previously unknown alkoxy-j
acetoxy-., and Am-In allicacyclobutanes. Orig. art. bas; 2 tables and 2-equationso
ASSOCUMM: Institut, neftekbimicheskogo sinteza. Akademii nauk, SM (Lutitute
of-Petroch=ical SymthesI4,p AcademW of SciencesjSWR)
SUMZTEM 26oct63 DATE ACQ: 3OApr64, ENCL: tOO
SUB COM: 00 NO BEF SOV: 001 OTM: 005

1, 18222-6.5 /EEFF( c Pj-'.
ACC&SSION NR: AP4049139 S/002O/64/15q/bcjiAj146/01LQ
AUTHf,M), Narne. t k i n11. ~'-. I Ccrrps ponrl aiem~r Ajo ~-, F:'R ) ;' 7
j f ~cvln, V. M.
pova
TITLE: Attaching methylhydride silica' ..... nalkares qn,~ 'gir chaln anallogs
tc t2h-~-iene ;
SOURCE: All SS'SR. Doklady*, v. 159, no. 1, 10,64, 146-149
loroalknan-ee, -t-h,!.~yddr 1 do,, sJ I ioach aroalkarie, chemical
TOPIC TAGS: I-si icaqh - - III
activity, organic synthesis, hydride derivative, siliconhydride
ABSTR.ACT: This word is a part of a study on the influence of different radicals
(held Logether '-'~ C ~- i-H- ) on rra -''~n a :7 1, n~-; s
purpose of this ex-perime-,t -was '-he
a Live s iicac:-- --Za ,,-,,(-.sp er4c pre,3sure
Card 1/ 13

;TI 18222-65
ACGESSION NR. AF40419139
and 20-70C even in the presence of Pt charcoal (5'% Pt), which is a weaker catalyst
than platinum hydrochloric acid. It -was Ietarmirjed that the acLivity of 1-hy-
jy IL
drl~de-l-methyl-l-silicachlorcalkanes in the reaction with ethylene increases in
the following way:
This was concluded from a study of ethylene and methylhydride silicac,"loroalk-ane
as a twc-component sys-~a::~ anr, a2so '~iy i7vos+14Lrati-n -)*- !--Mppo-en~
reacli-,ns, as a-ovr. J,- -4,-. -)r, -,ne WBS aisC n e
I - - I . ~ -- - - ',na.
methy-'r.ya"r-fie -wer-a mr-re ac,.ive .nan -.:~e-ir ~-,--er criai:-,
Orig. ar". ha5. 3 -,abIes ar,,-'
ASSOCIATION: Institut neftekhimichaskogo sinteza Akademil nauk SSSR (Institute
of Petrochemical Synthesis, Acadenq of Sciences SSSR)
SUBMITTED: 17jun64
E14CL: 01
SUB CODE: OC 110 REF SOV: 004 OTHER: 002
Card 2/3

L IB222-65
ACCESSION NR: AF-4049139
R
Fig. 1. Chromatogram of a sample (after 2 hours) from an
experimnt of competing reactions
H(CH3)Sj1CH-)4 ~(A). -H('CH3)S1(C.til) SIM
at 4. (C:H&)(CH3)S1(CHi~j(Cq);
(C11 100 10i(clio'l (D)
1-2ict"CSURE: 01
.Card 313

7k F7 - ~--Z-
ALY114OR Nametkirl, S. cj, c;,,r - -
v valov, P.
TO Fr 1
gano s i 1 C 0
~.a

L 6164M5
ACCESSION NR: AP5015595
The structure- of the products obtained was identified by infrared analysis. The
presenc;~ bv --he
I, a S.
A, r. aly 'j LLUtlces'
SUBMI=D: 28Aug64 in CODE 0c
N R F

SOURCE!

. . . .. . . . . . .
NO REF SOV: uuu 1 K

7 1 e v o m i~ mp -,7- K i:-. -
SOURCE: A.11 SSSR.
IOPIC TAGS: c rg a nos
ABSTRACT: By directly reactinz s!_bstitu-ed ace-yienes XC_ _F CX' (where Xr H or P~-,
P h ) -d i A I ~i v.1 -1~
R Ch 3 an r, Cri 3 ar V, '7 n~ 3 rs re a re,- r cr 1: e f-,rs7 -me new tive-ne-m-
bered organocyclosilcxanes with vari ~ur; s,_,ts- a 1- the
FkRSi - CfIX - QfX' - MRS' - 0
where ( 1) X = X Ph 2) X = H X' Ph P = P (711 q 4 ) R = CH R C 2-4 5 . The
react i on t akes p lace i n a o I ven!- t-) ~enp i a ~j tmnsT,4-~ p r i - r-1- s s uvw! 3 r Z Y-, i n
Lj

ACCESSSICN NR: AP50i9770'
the catalyst according to the equation
XC~-CX'~ HR'TA-qf--O--SiRR'!f. XCH - CIIX
R'/
Ad 4 1 r-oduct s cf linear struc'ur-- :ire
A Q Q OCT A T TNI - n~a t tut
alemetitoorganir-hes~ikh scyedineni'j Akademii riauk SSSR (I, ti-

LEYTES, L, A. j FJNKS1.1 SEIM, Y-, Sh.), ~PQVIN
, N.S~
Ramap spectra of some orthc-zubstiluted beenze-ne deriva-Aves cc;ntalnir
~ ~ ~ gg
511tQon. Izv, All SSSR. Ser. khIm. no,7.-l.'l,05,-Jl'408 165. (M-IRA 180)
1. Institut organicheskoy kh-imii im. N.D.Zalhiskogo AN SSSR.

T 1 TLE: A met, hod f-,Dr ri~ -19
a.33
SOURCE: Bvu~leten' izcbmtemiv i t.-,vaT-nv'l-b znakovl no. 1165, 20
10 P I S 1 S i la:~ 7:: - I ar ~g ~nl- S I I
ABSTRACT: Th-is Author's Certificate i-~-roduces a rmeethod for producin2 '~r iS s
17,

L 17oo-66 -r1-!T(m)/FPF(c)/_EWP(J)/T RM
ACCESSION NR:_ AP5022932 uR/oo62/65/000/008/1448/1-453
546.287-542.952
.4+
I-AUTHOR: Nametkin, N. S.; Vdovin, V. 'M.; Zaviyalov, V. I
iTITLE: Polymerization 1,1-disubstituted Bilacyclobutanes
I -
ISOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 8, 1965, 1448-1453
ITOPIC TAGS: silane, polymerization
ABSTRACT: In an attempt to prepare heterochain silicohydrocarbon polymers, a
study has been made of the polymerization of 1,1-disubstituted silacyclobutanes
-(see formula below). The polymerization was carried out without catalysts at
150-200C at atmospheric pressure or in sealed ampuls. On the basis of IR data,
the.reaction was assumed to proceed thus:
R. Clio it.
CHk_ +~1CHLCH$CHr_1._
n It
Card_
R, CHI CHI H. CHO cgs 4"41
--afl-4 9H. CH-C CL QM QRS
I .H. CH 1C"1*_Cff2 [C-94U61 IT
.C
- I HII

L 17oo-66
ACCESSION XR: AP5022932
A regular structure was assigned to -the polymers on the basis of the crystal-line
structure revealed by x-ray analysis, IR spectroscopic data, and substantial ther-
mal-oxidative stability., The'polymers were solid, slightly elastic or rubber-like
materials, semitransparent or white in color, and, as a rule, soluble'in the commo
nj
organic solvents. Viscosity, molecular weight, melting point, and glass transition
1 temperature data as well as x-ray patterns and DTA curves are given for eome,.of the,
I
I polymers. Orig. art. has: 3 formulas, 5 figures, and 1 table. [SM1 :i
ASSOCIATION: Institut neftekhimicheskogo, sinteza im.A. V. Topchiyeva Akademii
nauk SSSR (Institute of Petrochemical Synthesis, Academy of SciengesiSss
SUBMITTED: 28jun63 ENCL: 00 SUB CODE~
NO REF SOV; 009 OTHER: 001 ATD PRESS:,qo?3
_gqrd 2/2
g
'420
a
n WMIN

L lh48-66 DIT .;m)/EPr- (c)/F.-[P(J)/T R14
JACCESSION NR: AP5022933 u-,q/oo62/65/ooO/Oo8/1453/l459
546-~87+542.952
IAUTHOR:' Nametkin, N. S.t Vdoyin V. M.; Pushchevaya, K. S.,,.Zaviyalov, V. I-.
TITLE: Po erizatioAr" 1,1-disubstituted silacyclo'entanes
iSOURCE: AN SSSR. Izvestiya. Seriya khimicheskaya, no. 8, 1965, 1453-1459
!TOPIC TAGS: silane, polymerization
! ABSTRACT: A study has been made of the catalytic polymerization of 1,1-disubstitut d
silacyclopentanes of the type
R, C113\
R>SI (,, wherewis the frequency
.on of high energies %,-, '- -11' c=l)
in the reg, ress of them-meson
.u,
of the ~-quant _, pnd.,, is the rest ek' with respect to the
For a nucleus that is ficbsolute1y bla
Card 1/2
Cntegory t USSR/Nuclorr Phynics - Nucloar Roactions C-5
Abs Jour i Ref Zhur - Fizika, No 3, 1957, No 6021
4--masons, and which hrs r. radius R, the cross section of the
process is
where is the "form factor" of the rr-meson, averaged over the
angles and over the energy. If we restrict ourselves to the
region of sprall angles between the nomentn of the -ji-mesons)
we can put 1, end then, assuming R;~l//', we have
L
+ Y1 r
where r,~ - gm2 2,
LIX/1.1 i.e., the cross section depends in this
case oh the frequency of they-qurnt=.
Also considered is the case of the semi-transpcrent nucleus.
A simple result is obteined under the assumption that the cb-
sorption coefficient.1k is independent of the energy of the
2
;r-meson. Then tTR in the formula for the cross section is
rcplpced by the expression (2 CY-K - r ), whore O~X- is the cross
section for the capture of a reaon'gth an absorption coefficient
-~r by a nucleus of redius R. It is expected that the above
mechanist- in bnsic at high energies.-
Card 212

PA - 2968
The ilroduction of Froton-AntiDroton Vairs bjr y-t2uanta of High L,'nergies~
everyffhere 11, - c = 1 is put, Xor_,the -,ross section of the process exa=ned
here d6- a 2ffLIM114(2T()--6dpl7,dkl.cik2lF+.-Ip applies, This expressio,,. contains
Yet anoiher additiona1L forafactor F+-, which is due'to the possible'non-
punctiformity of -the nucleons and depends'upon the invariant frequency
of the y-quantum in the system of rest of each nucleon. The interaction
of nucleons among one another is also contained in this form factor. Iii
the case of small angles between the momenta of,the produced'particle and
the momenta of the y- quantum the differential cros3 section attains hi.ffh
nuclear values. The results obtained for the "absolutely bLack nucleus"
can be generalized for ;,,ny laws of interaction of nucleons witn the nuc-
leus, (no ill.).
A~OOCIATION ~"oscow h:ngineering-Fhysic;.l Institute,
&E5r_.NTLM BY
tjUBMM 19.12.1955.
AVAIIABtt Library of Uongress.
Card 2/2

VDOVIN Yu.A ! V.V.; ZATSEPIN, KOPOBEYNIKOVA7 I.Ye.; MIKEEYEV,
k.; YANUS, R.I.
lf.!J.; TOMI-LOV (_S.: SHTURKIN, D.1 ,
RODIGIN, 'I - I - ~ " . I -
Discussion on ncndcf;'---i.,Ai',,-2 7-:E~tlhods. Defektc3ko;~-iia nO.1:90
165. (MIRA 18:6)

llr.OVIN, yu..A.; GALITSIKLY, V.!4.
14-.. .: - 1 - - I ~ ~ -17 ~. ; ~ r
,n of r -
1:1,r!,,n prc)f,agaLj.0II in ,;. ~*,,.,n.j;v~- U,17~ec~ - ~- -- .
6! klo, P. I I t co o . f " z . 4 8 r, o . 5 -, I " 5 2, .13 0" 5 M y 16 5 ,(,,.i j FA '!8:,1')*
1. Moskov~!kly inzhener-no-fizicheskiy institut.

L 267'z.,46 :-m (i) ijp(c)
ACCESSION UR: AP5021884 UR/0020/65/163/006/1344/1347
AUTHOR: Vdovin. Yu. A.
TITLEt Radiation from an excited molecul. in a resonant medium
SOURCE: AN SSSR. Doklady, v. 1632 no. 6., 19652 1344-1347 4/
TOPIC TAGSi Hamilton equation, wave functionj molecular spectrum, Fourier analysis,
ABSrRACT-. The study deals with radiation from initially excited molecules
distributed in identical but unexcited groupoof molecules. In the analyais,
resonance is assumed to be very sharp, with only two molecular levels having the
same transition frequency 6), for the molecules, For a low density system, the
Hamiltonian for a system of ? two-level molecules in a radiation field is given
~-with the wave runction
ce,M/2
(k. t) Ckk"' 0 > C1+ 0
kX
By using the Shroedinger equation and appropriate Fourier transformations,, the
distribution function n(W,t) for the photons at the moment t is calculated.
_Card 1 2

L2673-66
ACCESSION NRs AP5021864
The solution is then simplified for the two limiting cases Wr~ 1.
'For the former cased when t>>T n becomes
n(wh t)&k TV dcak -GXP Wt + t] Cos i2t
n A' + ITT2
P
The total probability of detecting excited molecules in the system is defined by
and for the case WT