SCIENTIFIC ABSTRACT VENEVTSEV, YU.N. - VENEVTSEVA, N.K.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001859410008-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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L 22121-66
Acc m: AWx4921
300 Mcs by the coaxial-line method. Other specific properties of 13IFeO3 in addi-
tion to the large internal fields and large spontaneous polarization$ were a high
Curie temperature (850C), and the absence nf nonlinear properties at room tempera-
ture. An analysis of all the published data and the present resulto shown that in
spite of the fact that the spontaneous electric polarization of BiFeO3 is very
high, so that no dielectric IVsteresls loops could be obtained, this substance is
ferroclectric. Var i oua ''reasons for this conclusion P-re diaciissed. An rinaLysis of
the magnetic properties '~belov the Neel temperature (370C) also shows that BJFe03
has comp,~-ni-a-t-ed--f-erromagnetiso in addition to ferraelectricity. Orig. art. has:
5 figures.
SUB CODE: 20,,17/ SUBM DATE: 17Aug65/ ORIG REF: 022/ OTH REFi 002
Card 2/2 f".

L 01o52-67 Erw- (m)/T/EWP(t)/FTI TJP(c)- JD
ACC NR: AP603095G SOURCE CODE: UR/0181/66/008/009/2594/2597
AUTHOR: AKashlinskiy. A. 1. ; Chechernikoy, V. 1. ; Venevtsev, Yu. N.
ORG: Moscow State University im. M. V. Lomonosov(Moskovskiygosudarstvennyy
universitet)
TITLE : Investigation of electron resonance and magnetic properties in solid
solutions jof the system
1b
x
SOURCE: Fizika tverdogo tela, v. 8, no. 9, 1966, 2594-2597
TOPIC TAGS: electron spin resonance, electron spectrum, EPR spectrum, solid
solution, bismuth ferrate, barium titanate
ABSTRACT: The spectra of electronic resonance in solid solutions of the system
bismuth ferrate barium titanate have been investigated. The clearly defined
anomalies in the spectra are determined, corresponding to the dielectric and
magnetic transitions in solid solutions in conformity with tetragonal and rhombo-
hedral modifications. The data on changes in the EPR spectra are analyz*ed in
relation to the properties of solid solutions under study. Orig. art. has: 2 figures
[Based on authors' abstract', I NTI
SUB CODE: 20/ SUBM DATE: 14Jan66/ ORIG REF: 009/
Card 1 / I ,,, -- I-

Ver.cYL,5cy. ju. il.
ORG: none
TITLE: mossbauer effect in the ferroelectric )Fo &.1/2& /2)03
fF
SOURCE: Zhurnal eksperimental'noy i teoreticheAby llz4. Pis'ma v redaktsiyu.
Prilozheriiye, v. 3, no. 5, 1966, 212-216
TOPIC TAGS: ferroelectric matcriEil, Mcssbauer spectrum, miltiplet splittin4~~, critical
point, phase transition, Curie point, electron spin
ABSTIPACT: The purpose o~ the i.irvestigation war? to chock on the pi-azence of a minimixi
e1
of the probability of the Moss-bauer cL~."ect s.)n 5'n'19 i the investii!ated ~:n-mpnwvl,
n
sim,ilar to that observed fu: i~fferen. Ti/Sn rrtti-s) ~-j 7. A.
et al. (F?r v. 7, 1B8b, 15619 and elsewl.ere). Tt war, also desired to checr, on oLher
ningularities in the behavior of the quadrupole rplitting and of the PosItion of the
symmeti-j c-anter of the Mossbauer spectrum observed near the temperature 7c of the
ferroelectric phase transition. Tc) this end, the authors investigated the variation
of the parimeter of the Mossbauer absoyTtion spectrum of Fe 57 nuclei of the ferr-
'perature (TC - 1-"Jjc~ .Ihe absorbers
electric in question at the phase transition t:.M
were made by the usual ceramic technologi, using FeS7 03 (60~ Fe57). The source was
2
COS7 in stain-less steel. The appaxatus for the Mossbauer spectra is described by the
authors elsewhere (PTE No. 4, 43, 1964). The resiLlts corXirm the exAstence of the
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X~

L 24372-66
ACC NR; 0
singularitica in the vicinity of the Curie point T. 214C and a mini=n in the
1.4,ossbauer- effect probability. These singularities are apparently connected with the
fact that an anomalous decreassE. in the frequency of one of the transverGC OptiCal
branches of the lattice takes place an approaching the ferroelectric trans,Llon i.~oiDt
in crystals with perovsMte striicture. The decrease in the quadi-u-,))Ie si.lit~ing with
increase of temperature t-c- TC is- cormected with a decrease in the
ftI*Y7---,e-trV Of t"- line, which has a near T
Lc
Vo' M.,
.Dn
"ormat
transiti
'e.

ACC NRi AF?0o6214 SOURCE CODE1 ull/03")3/167/003/001/0,OCf-j/02C9
AUTHORS Shapiro, Z. I.; Fodulov, S. A.; Vanovtssov
ORG: Physicochomical Institute im. L. Ya. Karpov (FIz1Ro-j,,hi:mIchov1-iy Institut)
TITLE9 Determination of the Curio tomporaturo of the forroolectric LIN':~ 03
iSOURM AN SSSR. Izvostiya. Noorganichoskiyo natorialy, v. 3, no. 1967,
1 i
TOPIC TAGS; 0ario point, lithium compound, niobato, forrooloctric cr-fstal, dioloctric
constant
ABSTRAC":': In order to refine the Curio point of LiNbO3, temnorat,iro noasuro7.int's of
the dielectric constant were made on single crystals of both Li~-`o&-, an,1 a :;ol-1c
tion of 'the comDosition Li(,,Th0.qTaO.j)O3. The Curie ternDoraturn, fro-
dielectric constant maxi-ma, 1was found to be 1210:tlo*C for LtibO~ ind 1120+-101Z, for '-he
solid solution. In LVT60~, the dielectric constant along the po'!-ir axis '-s nuch 10~;3
than in the nex-)ondicular direction, as in the case of ba"riu:m t1tLnata
Some anomalies In the dieloct-ric constant Njore 1"ound in the 600-9.-",00C run;-,a. '.nerno-
graphic moasuromonts showad the molting point of UZ,`bC~ to he 124~150C. Uf all k;-,r,-.,r.
for'rcoloctrics, UNbO3 has the highest Curio point. The data obtainod on t.,v-) Cl-rlo
and neltin points of LiNo 6
9 93 are of najor ii-,portanco for the proparation of sn-'a-
ldc--ain sin.crle crystals with higher dielectric', optical and piezoelectric prope-:-tioz.
Card 1/2 UBCS 537.226-33

ACC NRs i,??oo6214
kuthor,~ aro gratofU to G. P. Kuznotzova, V. L. Farnhtendikur and R. M. ?ol-ch'Ln:k&ya
for assistanco in tho datormination of tho molting point. Orig. art. hast I fit,7uro.
SUB CODE: 20/ SUBM DXL-r-,: 13Apr66/ 01UG RZ-Ft 003/ OTH REFt 004
Card 2/2

L 31l7l-66 E4T(l)/E1dT(m)/T/E*dP(t) IJP(c) JD/GG
ACC NR: AP6006823 SOURCE CODE: UR/0181/66/008/002/0416/0423
4~7
AUTHOR: Viskov, A. S.- Yu. N.
j Venevtsev,
ORG: Pbysicochemical Scientific gS�Sa=h Institute Im. L. a. Karpov, Moscow
(Hauchno-issiedovatellskiy fiziko-khimicheskiy institut)
TITLE: Calculating the gradients of the Intracrystalline field In barium titanate
ferroelectric and in model cgstals based onthis salt
!SOURCE: Fizika tverdogo tela, v. 8, no. 2, 1966, 416-423
TOPIC TAGS: barium titanate, crystal theory, ferro-electric crystal
ABSTRACT: A method based on the ion model is proposed for calculating the gradients
of the intracrystalline field VE which act on the ions in the tetragonal modifica-
tion of ferroelectric barium titanate. The structural coefficients used in calcu-
lating the gradients were taken from experimental data in the literature. Curves
are given showing the difference in lattice parameters (c-a) as a function of tem-
perature. The affect which temperature has on spontaneous polarization, the intra-
:crystalline field and the gradients of the field is analyzed for the same modifl-
_Z_
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B, 31171-66
ACC NR: AP6006823
11~ation of barium titan'ate. The gradients are studied as a function of charge and
lpolarizability of A and B cations in AB03 crystals of the BaT103 type. The pro-
'posed method gives results which agree satisfactorily with the experimental data
!in the literature. The ion model is found to be highly effective for evaluating
;electric field intensities and gradients in ferroelectrics which are basically met-
[al oxides. The results of this paper may be useful for interpreting experimental
data on the Mdssbauer effect and -nuclear quadrupole resonance in isomorphic barium
titanate compounds as well as in solid solutions with a perovskite structure. The
authors thank G. S. Zhdanov and V. N. Lvubimov for useful consultation and Interest
in the work. Orig. art. has: 6 figures, 2 tables, 2 formulas.
SUB CODE: 20/ SUBM DATE: 2SApr65/ ORIG RM. oo8/ OTH REF: 010
lCard 2/2,.,/(

TOMASHPOLISKTY, Yu.Yaq VENEVTSEVt Yu.N.
Perromagnetiam in *he system Pb 2COW06 - BaTiO 30 Fiz. tver.
tela 7 no.10:3126-3128 0 165. (MIRA 18ill)
1. Nauchno-losledovatellskiy fiziko-khimicheakly Institut Imeri
Karpova, Moskva.

RNINWAYA,
c1 J: C~-.!
Karpiva,

I I 0i, IIV Yu Yfl - Yu.tf.; -At"PONCI, G.F.
p . 0 1 1 1
I r
Jr. tho zyotf~n PUF 213,`113'03
L~ 1 0
Zhur. EA-p. i teor. fiz. 49 no.2067-372 Ag 165. (1,JJi 18:9)
'I. R,,~i ko-kh J, -,i I che okly inzt I tut imen I Kflrf~ova.

VISKOV, A.S.; VE?IEVTSEV, Yu.N.; ZIMANOV, G.S.
New ferroelectric substances with the structure of perovskite and
pyrochlora. Dokl. AN SSSR 162 no.2:323-325 My 165. MRA 18S5)
1. Fiziko-khimiclieskiy institut im. L.Ya.Karpova. Submitted December
20 1964.

KAMM', A.G.; NOMSEV, TU.9,--
X-ray diffraction study of variatfous in the period of elementary
cells of (Ba. Pb)TiO3 solid solutions in the pAraelaotric region
as dependent an the composition. Kristallograftia 9 no.2t269-1270
Mr-Ap, 163. (KJRA 17t8)
1. Fizikc-khimicheskiy institut imeni Karpova.

1., all*
0 L I Y Y
F
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te.
Yarpovu,

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IM Imm, 4

ROG I 11S*KAYA , Yu . Ye VEN 1, 71 Yu. N.
O"ruci'llre and prrVjrt~'-c-s of Pb
. 4
"ZI-Ja 165.
If) no.3:31,1-345 8 -.7)
1. Fiziko-klilinicheskly institut, imani L.Ta. Kal-p-ova.

VER1
1 -66 /F-7-A 1w
2. ~,~T t wip L~ 1, -1
ACC N~l A P50245-tS
4 ~i. 7 3 6 5 3 7.
k~k A. S. %'Vnel, bt("-', Y
r1'rLJ`: StUdy Of thC Aructure and maimetir ;ind virctric pr..31wrtics of sojid ~4(ijwjj()ns In Int,
system BiF(!03 - "Sr(Snj/3N`1n2/V)-,3"
SOURCE: Kristallograftya, v. 10, no. 5, 1965, 644-649
TOPIC TAGS: solid solution, Nee, temperature, Curie point, antiferromagnetic material,
spontaneous magnetization, bismuth compound, iron compound, strontium compound, tin
compcund, TLnypi~i~~e compound
.D
ABSTILACT- Tho qarnplet- were prepared by the usual ceranitc- process from 13t,)03, SnO2,
SrC0,j. ;1nd NIII()" (firinz it 75 100C :it .4 -- 6 hr a nd -,i V;i i nM R,10 ir~ooc for
2 1 Aftvr- %wh firinv. tbp 'if 91c ~-i'ylfyh X- I;t
011fl- i( !~-r, I -1~1. I lil F.
2
exist In !'),I- filimilh, t-~
IfT~ ijO~.
penderce .)f spontancoub
om. s rn. i,
X101 I WO fert I ;,-neti it wnq found that in the systern studixii.1 :hcz

.. 1 -1
ACC ',P
qr)li(i s-lutions in which a magnetic and :in v.ectric (jipolt- ,;;tructurc e.Nist (;Nf,v
-I the-, ~.trijc-tiirrg, ind -I,.
r.i;i N,- diStinc! , ~ I- ~](;t
effort is made to clucida-te it. ' N~' f- tha [IN Y Y~' 'v'1 i'll -11", ! -
corrarients. Orig.--art. has. -4 fligures.
ASSOCIATION: Fiziko-khimteheskiyinstitutim.L. .1
SUBMITTFI): 10.Jun64 FN C 1, 00 SUB CODE: SS. E M
N(', 010
003
r

ROCilliSKAYAl yu.,yo.; VENEWSEV, Yu.N.; MDAINOV, G.S.
Structure aric: macnetin Properties of ferroe-lectr"c solid soDutions
f-n the system '--`b2GOWC6 Cd"'r. v. ". SSSR. Ser. fiz. 29 ro.6:
- 1 03- Iz "' -
165 ( 1.1, T 1~1, 18:6)
1022-102-5 Jf, - -

Stu(:y Cf V~p IiTaf
29 no.6;1047-1050 Jf!
1. Vsei3Gyu,,,nyy
reaktivov.

ROGINSK;~Y,";
r~t b ta!' I c P- -
1~14-1232 165.
'oullclino-iS 3je,J(p,,R
Y'. ,"'arpova, lloolkva.

r
L 198h-66 'F,-T(l ' /EaTTLOO/EF" I-
"XM21093 UIR/0056/65/()49/002/0367/0 2.
T
AUTHOB: Tomashpollskiyt Ya.~ Venevtsevt Yu. N.- Antonov G. N.
TITLE: Ferroelectrlc- magnet i c materials An he system FbFe,_/3W1/303--Fb2YbNbQs
SOURCE: tftui-r~d- -eksperimenta.1'noy i t'~rcticheakay fiziki, Y. 49, no. 2, r65,
376-372
TOPIC TAGS: 1ferroelectric material, antiferromagnetic material, lead'containing
alloy, iron')~oirtaining alloy, tungsten containing alloy, nioblum containing alloy,
solid aoluCi-o-n
ABSTRACT- New ferroelectric-magnetic naterials with perovskite structure were
prepared in polycrystalline form by firing the oxides WO3, Fe2031 M2051 and YbaO3
and the carbonate PbCO.3 at 700--1000C for 1--7 hcrurs. The techniques,used for the
crystal-structure measurements at high tem-paraturer and for the phase, "r, suremnts,
were described by the authors earlier (M v. 6, 2)9Z,3~)& Wid. iV--.1ab,---no-e--91
1112, 1961). The dielectric measurements were made by a standard bridge method,
and the magnetic measurements by the FaradAy method. The tests showed that several
solid solutions are Tormed in the FbFe2/3W1/303--Fb2Yb14bOG system, some of which
combine ferroelectric or arrtiferroelect~ric ropertles with ferrimagnetic ones over
a relatively wide range of concentrations and temperatures. Som resultg were ib-
Card 1/2

L 1984-66
ACCESSION HH: AP5021093
tained, which indicated a coupling betueen the electric and magnetic dipole stme-
goats may be of use in microwave
turen in the Investigated compositions. My
technology. "The authors thank G. S. Zhdan ~6r discuasing the reaults and B.A
Strukoy for help." ~~rig. art. lids: b figures.
#SSOCIATION's.-- Fiziko-khImIcheskiy institut in* L. Ya. K%rpov& (ftsicochemical
Xnatitute)
//V, S-1;I
SUBMWED: JO~W65" ENCti 00 SUB CODE1 Ss" M
HR MF S(W 1 010 OTHER.- 001
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JR 005 ;'3
_~_ACC-NRI--- -SOURCE CODE.-.- tjR/OO56j,'5/o4q/oO4/1O38/1O41
0
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AUMOR- Shvorneva, L. I._i_ Venev-tsev, Yu. ff.
. -8, - ..
z chskiy institut)I
ORG: Physicochemical Inatitute im. L. Ya. Karpo-7 (Fizlko-khimicheskiy institut)
i lko_khimi
TITLE: PerovskItes with ferroelectric properties
SOURCE: Zhurnal eksperimental'noy i t,-,)reticheskoy fiziki, v. 49, no. h, 1965,
1038-1041
TOPIC TAC,~7: ferroelectric mat_E,,-1q! , f. per~vskit~, Ine:)rganic
syntheuis fl
ABSTRACT: In view of the important practica-1 applications of ferrnel,~r~rt,~ compounIS
I Find of thF npceqsity f,-)r i q,ertfes,
s n t f"'s 1 117
PN70 lit, N
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~,e
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~ T~EV,.Yij.M.; SOLOVIYEV, S.F.; GCRBUIICJV, L.A.-
KAPYSHEV, A.G.;_Yjqju7
MI)ANOV, G.3. - - I
X-ray chambers for high-tempera-ture ewadies. Zav. lab. 3c no.!(-):
1271,1276 164. (KIRA 1PO
1. Nauchno-issledovateltakly fiziko-khimicheakty institut imeni
Karpova.

UA/ C048/ 65/ Uzv/ L'U tv, -.1 (i~ i
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Ya.ll.-, ROGR-'SKAYA. Yu.ye.; VISY07, A.S.; 17ANOVA, 7.7.:
IMISKIY, Yu.Ya.,-5IPAYHllHVA, L.I.i. KAFISWT, A.G.;
.,TEvTROVSKrl, A. Yu.; ZIMIJIOV, G.S*''
Few load-:!ontnir,-b.,g ol compIt-cc
4 "--0 r )-, ( m I F" ~* -I -, : ~, )
lc,n. Dokl. til SSSR 15P, 1 4'
l
1. Fiziko-kl.Lmi-f,e2'k-iy -4*n,-ii--' L. 'Ya.
staviono akadem--Ik,3,-i N.V. B--,hurym.

VENGEROVSKIY, I.S., prof. (Tomsk)
~-,- -,
Review of the book "Problems of pediatric surgery". Khirurgiia 39
no.11:141-145 N 163. (ICRA 17:11)

Zr

t~ VENEVTSEV, Yu. N.; LYUBIMOV, V. N.; SOLOVIYEV, S. P.; 711DANOV, G. S.-
~Calculation of internal electric fields and their gradients
in perovskite compounds with specific diel tric properties.
Izv. AN SSSR. Ser. fiz. 28 no. 4:630-635 IPTI 164.
(MIRA 17:5)

MITROFAIIOV, X.F.; VISKOV, A.S.; DRIKER, G.Ya.; PLOTNIKOVA, M.V.; FAM ZUJ MEN;
VERNTSEV, Yu.N.; SITINFLI, V.S.
Changes in the resonance absorption spectra of 2.1.8 Kev.
gama rays froir Snl19 during phase transitions in the system
BiFeO -Sr(Sn .3 Mn 213 )0 3' Zhur. eksper. i teor. fiz. 46
no.1:383-386 "J'a'64. (MITIA 17:2)
1. Institut yadernoy fizikl Poskovskogo gosudargtvennogo
universiteta i Fiziko-khimi,cheskiy institut imeni. Karpova.

TOMASH11OLtSKIY, Yu.Ya.; VENETI'6EV, Yu.N.; ZlfDANOV, G.S.
Electron diffraction otudy vf thn r-r-latAllinn.atruat,irrs of
BiFeO3. Dokl. AN SSSR 153 no.6:1313-1314 D 163.
(MIRA 17.1)
1. Fiziko-khimicheskiy institut im. L.Ya. Karpova. Prod-
stavleno akademikom N.V. Balovym.

SOLOVYEV, S. P.; LYUB!14)V, V. N.; UtMMEV, Yu. N.; ZHDANOV, G. S.
"The calculations of the internal electric fields and electric-field gradients
in the perovskite-type compounds with special dielectric proper-ties."
report submitted for 6th Gen Assembly, Intl Unionof CrystaLlogrkphy, Rome,
9 Sep 63-
Karpov Inst of Physical Chemistry, Moscow.

VENEVTSEV Yu. N.; VMANOV, G. S.; ROGINSKAYA,, Yu. Ye.; FEDULOV, S. A.; IVANOVA, V. V.
Investiption of some solid solutions based on the ferroelectric-antiferromiU,~etic
iFeO 3*
report submitted for 6th Gen Assembly, Intl Union of Crystallography, Rome,
9 Sep 63.
Karpav Inst of Physical Chemistry, Moscow.

FEDULOVY S.A.; LADYZHINSKIY, P.B.; PYATIGORSKAYA, L.I.; VENEVTSEV, YujN,
Complete phase diagram of the system PbT'03 - BiFeO3. Fiz. tver,
tela 6 no.2t475-478 F 164. (MIRA 17:2)
1. Vsesoyuznyy nauchno-issledovatellskiy institut khimicheakikh
reaktivov i osobo chistykh khimicheskikh veshchestv, Moskva.

SHAPIqO, Z.I.; FEDULOV, S.A.; VENEVTSKV, YU.N.
Curie temperature of the ferroelectric LiTaO3. Fiz. tver. tela 6
no.1:316-317 Ja 164. (1-aRA 17:2)
1. Vaesoyuznyy nauchno-issladovatellskly Ingtitut khimicheskikh
reAktivov i osobo ctiistykh khimichenkikh veshchestv, Moskva.

ACCESSION 11R: AP4012566 S/0056/64/046/001/0383/0386
AUTHORS: Mitrofanov, K. P.; Viskov, A. S.; Driker, G. Ya.,- Plo
S
nikovas M. V.; Fam, Zui Khiyen; Venevtsev, Yu. N.1 Shpinal', V
TITLE: Change in resonance absorption spectra of 23.8.kev gaz=a
i rays of Sn-119 during phase transitions in the system BiFeO
3
Sr(Sn Oy
1/3Mn2/,
SOURCE: Zhurnal eksper. i teoret. fiz., v. 46, no. 1, 1964, 383-386
TOPIC TAGS: resonance absorption, Mossbauer effect, recoilless
resonance absorption, ferroelectric antiferromagnetic compound,
ferroelectricity, ferro antiferromagnetism, group II stannate,
resonance absorption maximum, resonance absorption jump, Mossbauer
effect jump, magnetic hyperfine splitting
ABSTRACT: Tbis~is a continuation of an earlier investigation by
some'of the authors (ZhETF v. 44, 2182, 1963) and is aimed at im-
.JCard

ACCESSION NR% AP4012566
proving the earlier results and. finding the reason for the abrupt
'change in the relative counting rate at the absorption maximum (e).
The material used has properties similar to that of the earlier in-
I vestigation, and the addition of manganese made the samples practic-
ally single-phase and closer to equilibrium. The test procedure is
briefly described. The results indicate that the jump in the value
of the Mossbauer effect in solid solutions based on BiFeO is the re.,
3
sult of magnetid hyperfine splitting (but is not caused by change in
the probability of the effect), and is related to an antiferromag-
netic phase transition. This conclusion is supported by magnetic
.,-I'measurement results. Orig. art. has:-3 figures.
ASSOCIATION: Institut yadernoy fiziki Moskovskogo gosudarstvennogo
universiteta (Nuclear Physics Institute, Moscow State University);
Fiziko-khimicbeskiy institut..im. L. Ya. Karpova (Physicochemical In-
stitute)
i SUBMITTEDs 275ep,63.
DATE ACQ; 26Felb64
ENCL: 02
Card 2/dF 2-

ACCEMS"ON NO: AP4013507
5/018 1/64/006/002/0475/0478
AUTH01M Fedulov, S. A.1 Lady*xhinakiy, P. B.; PyatigorekayAp L. 1,1 _n
Yu. N.
TTTLEE: Complete phase diagram of the system PbT'03 BiFe0J
SOURCE; Fizika tverdogo tela, v. 6, no. 2, 1964, 475-478
TOPIC TAGS: phase diagram, FbTiO sub 3, BiFeO'sub 3, piezoelectric, phase transi-
tion, Curie point, morphotropic phase transition, polarization, ferroelectric,
ferromagnetic, Neel temperature, conductivity
ABS'iMCT: Uqing x-ray investigations and electrical and magnetio measurements, the
authors have constructed a complete phase diagram of the system FbTiO 3_BiFeO3:
This diagran is shoym in Fig. 1 on the Enclosure. It is seen that in the region of
the morphotropio phase transition the Curie point is very high (on the order of
7000, and it therefore seems suitable (in order to obtain high-temperature
piezoelectric material) to introduce other material into the system to decrease the
conductivity and to improve the conditiona of polarization. The authors suggest,
from this point of view, studies of the three-component systems PbTiO3_BiFeO 3-
P`bZr03 and 1'bT103-BiFeO 3-LaAlO 3- "The authors consider it their duty to express
Card 1/jj

ACCESSION NOt AP4013507
thanks to Yu. Ye. Roginskays, for her aid in the work." Orig. art. has: 5 figures-
ASSOCIATION: Vsosoyuzny*y nauohno-iseledovatellskiy inatitut khimichookikh
reaktivov i onobo chisty*kh khimfoheskikh Yeahchestv, Moooov (All-Union Scientific
Research Institute of Chemioal Reagents and E~ctra Pare Chemical Substances)
SUBIMITTED: 12Aug62 DATE ACQ; 0311&r64 ENCM 01
SUB CODF,- Pq NO R.EF 5011 009 arm: 001
Cord 2/5

ACCESSIT 11R: AP4011779
S/0182/64/oc)6/001/0316/0317
AUTHORSt Shapiro, Z. I.; Fedulov, S. A.; Veneftsey, Yu._ N.
TITLF: Curie roint of ferrooleatric lithium tantalate
SOURCEs FiziPA tverdogo telal v. 6# no, 1, 1964j 316-327
TOPIC TAGS: ferroelectric lithium tantalate, Curie point, dielectric property,
lithJum carbonate, tantrilum pentoxide, lattice parameter, hexagonal exis, rhombo-
hedral axis? dielectric peryneability, bridge ITP-300,, piezoelectric effect
ABSTRACT: An attempt was made to determine the dielectric properties In ceremic
specimens of lithium tantplate across a bropd temperature rpnge. Experifrental
specimens wer'a produced from lithium carbonate and tantalum pentoxide. They were
ptirified by two repented hentings (60 min ench), one atnooC and one at 1350C.
X-rpy analysis and subsequent calculations proved that the lattice paremeters of
lithium tantalAte were: on hexagonal axes -- a A; on
0 H - 5.153 1 and cH = 13.7?5
rhombohedral axes -- a.Rh = 5.4?0 A and d\Rh - 560121. Dielectric permeabilities
Card 1/2

ACCESSUN 11R: AP4011779
were measured with a bridge LTP-3DO at the frequency of 250 kilohertz. The curve of
F, = f(T) shoviad a sharp maximam at the temperature of about 6650. Dielectric
perineabillty ot room tempernture was 70g at the maximum it reached 1W. Above the
Oarie point Ue ch3nge in the dielectric permeability was calculated from the Curie-
Velss Inw. Tl~e sreclmons shoved a weak piezoelectric effect. These results dis-
prove the clFdm made by H. D. Vegave (Acts, Cryst., 7, 1910 1954; Ter-roelectri city
in cryst-ils, 11 p. 103, London, 195?), to the effect that lithium tantalate forms
sirple ryroolectrical crystnls. At the present time the authors Are undertn~rirFr. a
study of propertios exhibited by LiTaO and TANbo 3 and also of solid solutions
booed on thoso substances. Orig. Art. Lss I formula and I diagram.
ASSOCIATICNs Vnesoyuzny*v nauchno-issledovatellskiy Institut khImichaskikh
reaktivov I ocobo chisty*kh khirichoskikh veshchostv, Voscow (All-UnIon Scientific
Rrsearch Institute of Chemical Reactions and of Pure Cliemical Materials)
SUNITTEDt l,2A%w.63 DATE ACQ: VYeb64 ENCLs 00
SVB CODEt CH, PH N 0 FW S OV 1 000 OTHERt 002
Card 2/2

YU ZI, A.A.; VEBMSEV" IU.N.
Transition r6gion between the ferroelectric amd paraelectric
phases of the solid solutions fFb,, Ba) (Ti., Zr)Q,. Kristallo-
grafiia 8 no.3:454-456 My-Je 163* (MIRA 16:11)
1. Fiziko-khimicheslciy institut imeni, L.Ya. Karpova.

VEIXVTS.EVA, G. P.
,- -
AUAs of Irkutsk Province. Geed. i kart. no.6:58-61 Je 16~.
KRA 16:9)
(Irk-utsk 1~rcvince--Maps)

ACC NR. Ar60322~)59 GOLMCE CODE: UP 6 6 67ff r-6 a YX 5/677 1,"1, e Fff,
AUVOR: Tovu--bpol'okiy) Yu. Ya.; Venevtnev, Yu. N.
'(i-_'i;iko-khimiehcsk1y Institut)
ORG: Flaysicoclic,-Acal Institute Karpov
Crac'ion, and electric and maenctic inveatigation3 of a system co-,-
TITLE: X-ray dif.L
pri.,inC, a ferroclectric and a fcrronr~rignct
SOURCE: Kri&"allografiya) Y. 11, no. 5, .1!)66, 731-73~1
TOPIC TAGS; x ray difffraction, solid solution, ferroclectric material, ferromaenctic
material, elcctric property, magnetic propcrty, temperature dependence
L U A.
ABSTIViCT: The purpose of the investiCation war to check on the fecloibility of syn-
I thesizing co,:ipounds which exhibit rimultancousl~f ferroclectric anf ferromagnetic pro-
perties, which was demonstrated by the atithors in earlier inve.,tigations (MI v. 7.
no. 10, 31266j 1965), Test were made on the polycry.-tallinc syz;tcm-, - '* _' __ I
Sro.31ao.7""J10.3 (1) and Y0.5Bio.sT103 - Sro.3Iao.j!-,,n03 (TI) obtained by sinteriln,'--t-he
correspondirV,, -oxides. 7he properties and st-ructuxe of the sampler, were determined by
x-ray analysis. 7he dielectric constant was measured with a bridge circuit in a weak
...eld at 200 kcs, and the magnetic measurements were made b a procedure described
11 y
elsewhere (Kristallografiya v. 8, no. 4, 1963). The conductivity war; measured with a
bridge. Plots are presented of the concentration dependence of the unit-cell dimen-
sions on the logarithm of the conductivity, the temperature dependence of the dielec-
tric constant, and the temperature dependence of the spontaneous magnetic moment.
Card 1/2 UDC: 53T.226

AP6032959
Phase diagrans of the two sy.-tems are presented. 11he results show that the cox-poizids
remain fferromagnetic in almost the entire range of concentrations, and that corr2gunds
I and II have ferroalect-ric proper-ticG at 87 - 95 and 90 - 97 mol.% respective3,v.
Although the ferroclectricity and the ferroTaGnct ism combine onl,,f at low temperatures,
it is assumed that the temperature range can be extended by suitably choosing the
initial components. The authors thank V. P. Glushkov and A. I. Abramav for chemical
analysis. Orig. art. has: 5 figures.
SUB CODE: 20/ Sam DATE: L,~Yv65/ ORIG MF: 0051 "L REF: 002
Card

SEMOV, A.I., otv.red.; FIUPPOV, Yu.V., prof., doktor tekhn.nauk, red.;
BASHLAVIN, V.A., kand.tokbn.nailk, red.; VOYNOVA, Y.T., red.; GURARI,
Ye.L., kand.ekonom.nauk. red.; GURIEVICH, I.V., red.; T5117, I.S., red.;
ZARUTSl,--AYAj IsPel red.; ZAGLAVSKIT, I.I., red.; KOZLOV, P.M., red.;
NIKISHOV, M.I., kand.gpograf.nDuk. red.; &ADCHIKOV, S.F., red.;
TUMMIROV, D,I.i red.; TUTOCHKIIIA, V.A., red.; BALANTS3VA, I.A., red.
kart; BOGDANOVA, L.A., red.kart; BOCHAROVA, I.L., red.kart; VjTllNVTS9VA,
._~ red.kart; VOLKOVA, I.P., red.kart; GOSTEVA, N.A., red.ka-r"",--
YEFIYOVA, G.N., red.kart; ZHIV, D.I., red.kart; KRAVC1131TO, A.7., red.
kart; KIJBRIKOVA, IT.S., red.kart; KUZNATSOVA, N.A., red.kart; KITRSAKOVA,
I.V., red.1--art; LOBZOVA, N.A., red.k-art; 0WSAlkVA, L.M., red.kart;
MOSTICIN, S.L., red.kart; PAIIFILOVA, M.V., red.kart; 5DfsNQVA, V.D.,
red.kart; WIRNOTA, T.N., red.kart; TIM&ffOV.A, V.S., red.kart;
YEDOROVMLIYA, G.P., red.kart; "r. ISOVA, II.P., rod.kart; FILIGIJS. Z.Kh..
red.kart; SHAPIRO, Ye.M., red.lmrt; SHISUIN, Ye.A., red.kart; YASHIJ-
HICHKINA, Ye.G., red.kart. V razrabotke kart prinimali uchastlye:
ALISOV. B.A., prof.: BMUDIA, M.Ya.-, VASILMSKIY, L.I.; GAVRILOVA,
S.A., kand.gaoggraf.nauk; GINZBURG, G.A., kand.takhn.nauk.; DOBOSHIN:9:AYA,
I.B.; Yz-VSTICU3MA, A.I.; LAVRAWO, Ye.M., prof.; LOZINOVA, V.11., kand.
tekhn.nauk; MILANOVSKIY, Ye.Ye., kand.t;eolo,,Io--.iineral.nauk; MMUtYlkV,
A.A., prof., MYSITIN, Yo.P.; PUZANOVA, V.P., knnd.goograf.nank;
(Continued on next card)

34MOV, A.I.----(continued) Card 2.
ROZOV, N.H., prof.; SKIRKOV, D.I.; TAUSOV, A.P., TROFIMOVSL~TA,
Ye.A., kand.geograf.naijk; TUGOLESOV. D.A.,
nauk. ZININ, I.Y., tekhn.rad.
[Geographical atlas for secondary school tencharal Geograficheskii
atlas; dlia uchitelei sradnei shkoly. Izd.2. Moskva, Glav.upr.
geodezii i kartogrefii MVD SSSR, 1959. 191 P. (MIRA 12:11)
1. Predetavitall Nauchno-iculedovatel'skogo instituta motodov obu-
chnniya Akader3ii padagogichaskikh nank RffSR (for Zaslavskiy).
2. Predstavitall Upravlaniya shkol Ministerstva prosvyashcheniva
WSR (for Tutochkina). 3. Chleny-korrospondenty All SSSR (for La-freriko,
Mikhaylov).
(11aps)

GRINEV, A.N.;-VMVTSEVA, N.i.; kR,&NCWK, V.I.; TMENTITST, A.P.
quinonet.. Part 31: Sjrntbesis of tetrahydro-1,4-ondomethy-
leneanthraquinones. Zhur.ob.khim- 30 no.6:1911-1914
Je 160. (MIRh 13:6)
1. Moskovskly gosudaretvannyv universitet.
(Anthraquinone)

r
WhEY, A.N.; ZLYTSEY, TFMNTIYF.V, m.P.
(~ainonas, Part 32: trntbesis of substituted 2,5-bia(azlw)
-1,4-benzoquinones and 2-amino-,4-naptboqulnones. Zhursobs
kbim, 30 no.6*.1914-1918 Je 160. (MIRA 13;6)
1. Moskovskiv gosudarstvewWy universitet.
(Benzoquinons) (Naphthoquinone)

GRINEV, A.H.; VENEMEVA.. N.K.
Aminowthyl and amilwethyl derivatives of 5--methoxybenzofuran.
Zhur. ob. khim. 33 no.5:1436-lW My 163o (MIRA 16-.6)
1. Institut po izyBkaniyu novykh antibiottkoy AMN SSSR.
(Benzofuran) (Amino group)
~Illil -
4 ,

_ j N. 13,; 'El'ARAIll, P. A.; "HIN I ' T yj Z_
VOTEMIANOV, 1) .1 1, ~.- 1A-,Vz.,rj
ye
~OLTKARPOV, P. l.; BilliG, A. Yu..; BLEMIMAU, A. A. wA QBlQ-',N','K.(Y, V. Yc,.;
"Th, Car.-2 for Exploslon-P-.-Oof Eler-,trical In the 0--'-' and GaLI t re
report preEented at the All Uril~,n Scleritif-l- and Technil--ni Cor.,,Vercrice U.,. the
F,lcctrLc-:il Equipment in BuildIngs an(! 00,:~IdC Llahle to Ey. p I
siono, 14-19 April 1958, stalino
(Energet, Byulleten', 1958j, No. 7, PI) 2`9 33).

VEMPTSKIY, A.
...-M-Umm
3timaating action. Sove profsoiuzy 6 no.8:61 ii 158. (MIU, 11:9)
(Lvov--Trade unions)

13MY. M.7.; VMWSKIY, V.L.
-
C~tical properties of 7k -centers in Ionic metals. Yiz. ntor.
no,*3-*137-140 157, (xm 11: 8)
1. Institut fisiki ANUSSR.
(Ionic crystals--Optical properties)

VANIV, M.
Myositis ossificans eircumscripta neurotica. lbirarglia, Sofia 11
no.1:84-88 1958.
l..1% nevrokhirurgichnoto otdelenie pri Obohehoarmeiskata bolnitsa -
sofiift.
(KYOSITIS OBSUICAM,
circum cripts neurotica (BUM

VBNGLIUSKIY, I.Y. [VanUinelkylp Ia.]
-
Now &%ta on Spirialis from igiddle Miocene depouits of Trans-
carpathla, Geol,xhur, 18 no.5170-75 158. (HIRA 12:1)
(Transearpathia,--Pteropoda, Yossil)

VIRBITSKAYA, T.N.; ZHDANOT, G.S,-, VINWTSIV, Tu.N.; SOLOVOYNO S'p,
Mectrio testing and Z-ra7 diffraction examination of the
W103 - B&ZrO~ system. XrIstallograflia 3 no,'2:186-196 158.
(KU 11W
1, liziko-khisdahaskiy institut im. L.Ta. Karpova i lauohne-
iseledawatel Iskly Institut Kluieterutva radiotokhuieheskoy
provqBblennosti.
(Barium titanate)
(Barium ziroouate)

KiLPYSHIV, A.G.; SHLROV, Yu.Y.
X,ray analysis of the system PbT103-BaSnO3. Irlstallograflia 2 no.2:
233-238 '57.
1. Fiziko-khimicheskiy institut Im. L.Ta. Karpova.
(IAad titanates) (Barium stannate (X-ray crystallography)
N%

ZOMIOV, G,$,; SOIOOVIYNV. S,Pq VSHIMN, YU#N*
Strtwtural coefficients of Internal fields in seignetto-electric
substances vith parovskite-type structures. Krietallograflia 2
no,5:639-645 157. NIHA 11:1)
1. Yisiko-khimieheski.7 institut im. L.Ta. Karpova.
(Yerroolectric substances) (Crystal lattices)

I I / I : -I
USSR/ElelV4~~t ,y - Dielectr'i-cs G-2
Abs Jour ; Ref Zhur - Fizika, Ito 1, 1958, 1273
Author : Vnevtsev, Yu-N., adanov, G.S.
Inst
Title Crystal Chemistry of Ferroelectrics with the Perovskite
Structure.
Orig Pub Izv. Alt SSSR, ser. fiz., 1957, 21, No 2, 275-285
Abstract A classification is made o4' ferroelectric and antiferro-
electric substances of compcsition ABO, with a structure
of the type of perovskite, in accordance with the type
of the atomic displacements. The authors investigate al-
so the connection bttween -~~he structure and the character
of the spontaneous polarivition. It is shown that the
ferro~lectric or antiferroeltctric properties of the crys-
tal are due to tht ion tha'-. has a sufficient geometric
freedom of displaceLyrnt. within the confines of the crys-
talline cell. In the cellE, of the ferroelectrics
Card 1/3

USSR/Electricity - Lielectrics
Abs Jour Ref Zhur - Fizika, No 1, 1958, 1273
G-2
'When t ::- 1, it is cation B that is free within the confi-
nes of the cell, and when t < 1 it is cation A. For fer-
roelectrics one observes values of t that are both grea-
ter and less thaa 1, for antiferroelectrics t is always
less than 1. An investigation of the atomic displacements
has shown that cations A or B can shift along the second,
third, and fourth order axis and cause respectively mono-
clinic, rhombohedral, aid tttragonal deformation of the
cells, vhile the cells of the antiferroelectrics display
only a monoclinic deflormt-Ion. An investigation of the
with a
character of the chemical bond in comnounds AD03
structure of the perovskite type has shown tnat the cha-
racteristic bond for thes(i compounds is of the ionic type.
Biblio(gaphy, 46 titi~-G.
Card 3/3

p ~ I - ~ I !~ I . . ,
4 - I - - . - -, - -- -- - -- -- -- - - - .-
I ) t -, I . - - - - - ,
" 'i . . - - -

Vr--NEV-r'~5~-V
70-5-12/31
A-JTEORS: Zhdanov, U.S. SolovIyev, S.P. and V!neN~tL~ey-,-Yu.si.
,i.LTIZ: The Structural Coefficients of the fnter~,.al Field in Y~erro-
clectrics with the Perovskite-type Structure. (Strukturny"
koeffits4enty vimtrennego polya v segnetoelekti-&akh so
strukturoy tipa perovskita)
IIERIODICAL; Kristallografiya, 1957, Vol.2, VO-5, pp. 639-645 (USSR)
~~ISTRACT: Data published in the literature for the values of the
structural coefficients of the internal field in perovskite-
type crystals are critically exanined. Relations are set up
between the idealised cubic perovskite and the cases in which
there are dipoles in the C001] 1 [014 or C111] directions. The
structural coefficients are calculated for the tetragonal cell
of PbTiO at room temperature taking account of the ionic dis-
nlacemenh.
The field at the i-th ion is;
Bi = B + m
k ~-
4-m + Cik Pk
-3
where m is the number of sub-lattices each consisting of the
(;ardl/4 ions of the k-th sort, E is tLo external fieldl Pk is the

?0-5-12/31
The Structural Coefficients of the Internal Field in Ferroelectrics
with the Perovskite-type Structure.
dipole moment of the k-type of
coefficients. In the case whe:re
direction;
2-2 x2
Cik "jk 2j 11
(X~ +
3k jk +
ions, Cik are tLe structural
the dipoles are in the z-
Y~
-12 Jk )5/
-jk
where x Y k ZOK are the co-ordinates of the j-th
. I
dipole of the ~-thl sort relative to a
dipole of the i-th sort and su=ation is over each dipole of
the k-th sort. For the cubic cell, the Cik can be ex-oressed
in terms of two quantities P and Q . The values which
various authors find for these values are comi.-.ared, the best
values being P= - 15-04102/V and Q = 4.3338?/V as found by
1!cKechan (Phys. Rev. 43, 913, 1933 and 72, 78, 1947).
Card2/4

70---12/31
al_,;~ Structurcl Uoefficieiits of the Internal Field in Forroclectric-s-
..'.ii the Perovskite-type Structure.
Qik 0 0 -2Q. Tl!ere are 5 cub-lattices
0 0 -2P P P for -the ABO formula.
-2 -2P 0 Q Q 3
P Q 0 -20, aik are the values for the
Q P Q-2q 0 truly cubic cell.
Where the distortions of the cubic cell are spall (1%) the
aik are different from the CJ.k only by 2-3%. Even for
P7bTiO3 where the distortions are large, these do not differ by
in-ore than 20%. The actual values of tbe coefficients for
t-6ragonal PbTiO 3 where c/a = 1.064 are calculated and tabulated
-%'ith those of McKeehan (cubic, by Lev;aldls Pethod) and of
Hagendorn (BaTiO 3 with c/a = 1.010) (Zeit.f.Physik, 133,
394-421) 1952). There are 1 figure, 3 t,--*L)les and 14 references,
2 of which are Slavic.
ASSOCIATION: Karpov Physico -chr-m~ical Institute
(;ard 3/4 (Fiziko-khimicheskiy Institut im. L.Ya. Karpova)

in Y 70-5-12/31
The Structural Coefficients of the internal Field erroelectrics
with the Perovskite-type Structure.
bUBIKITTED: May 31, 195?.
AVAILAB12: Library of Congress
Card 414

v fizVTS 41-Q420
1
Using the dotted method to map branches of agriculture (practice
followed in making maps for the Agricultural Atlas of the
U.S.S.R.). Geod.i kart. no-4157-61 Ap(C'62. (MIRA 15s12)
(Agriculture-Hapa) artography)

VENEVTSEVA, G,F,
Using the dotted method to map branches of agriculture (practice
followed in making maps for the Agricultural Atlas of the
U.S.S.R.). Geod.i kart. no.4s57-61 Ap 162s (MIRA 15212)
(kgriculture.-Maps) (Cartography)

A Uri I o f-".." Gptny,.~v, A. H., 11. K., Ti---rentlyc,~, A. P.
TITLE: Irkve~;tlc'ation In the Rtobt ot, XXIX.
Azo Collplin,.; of
and
PERIODICAL: Diuvrial ob3hchey khiml.'L, W)l 30, I'll' 1, Pf) .183-185
(ussli)
AMTRACT: Azo couplin-i, of quirioncLi c,t~ior (-~Jectj'c)donor
subititAtecit.,3 wa~3 ;tudled.
V10.3 CC~UI)I(--d wll,h -,ome dia7onium
and
(111), -21,
(IV), anJ

1,41-ben,z.o(juluone (V) W(--Pf~ 0btZl,tf1t--d, in high yield.
Card 1/3

,I IV 7 7 37 6
xxix. SOV/79-30-1-37/78
0
Ar-,N ~N,
(C If 3)1 N
0 A r -
(v) Ar
ti
,D.Lazoniwn salts weve reacted with 2-dimethylanino-1,11-
naphtho(julnone, and Instedd of the expectod products
of azo coupling, of ',~-diiiietliyl~irrin~--)-1,11-riaphthoqttinonf2,
the der,lvative.,; of' 2-liycii,oxy-1,11-ri~-Lrht.IID-[Lllrtone were
obtaln~.,d
quInoric (VI) and
Card 2/3

XXJ
0
Oil
ASSOCIATION:
SUBMITTED:
Card 3/3
7~ '7
1.
(Vii) Ar
III Wai ObtZllried in 81 .3;-t" y1eld; IV, 38.6%; v, 65.9:'b;
vi, VII, 77.1%. There. lo I tabli; and 11
reforenct-;; 6 3 U.S., 1 Italian, I U.K. Tiw
U.S. an-1 U.K. m-e: D. J. Aul,
Chem. Soc., 56, 2478 (1934); L. Ficoer, ibid, 70, 320-,
(jqLj8); R, Raltzly, E. Lorz, ibid, 70, 8"A (19118); R.
Plimpton, J. ciiem. Soc., 37, 611"' (18"0).
Moscow State univers1ty (mDqkc)v:3k1y gosudarotvennyy
univeroitet)
JanuarY 5, 1959

GRIWLV, A.N.; VEMTfSEVA, N.K.
Mannich bases in the series of derivatives of 5-hydroxytenzofuran.
Zhur.ob.khlm. 33 no.31820--824 Mr 163. (MIRA 1613)
1. Inatitut po lzyskaniyu novykh antibiotikov AMN SSSR.
(ManTilch basea)
(Benzofuran)

r I.; . , I / ~ I , .
, - - .- - - - - .I
-TlBj2lTlTXY.-A*Y&---
............ ---,
(Wnonen. Part 14., The reaction of N -ben2oquinons with _~'-nitro-
and I -bromobanzoylacetic ostero. Zhur. ob. khim. 26 no.10:2933-
2934 0 156. (MIRA 11:3)
1. Hookovskiy Onsudaretvennyy universitet.
(Benzoquinans) (Acetic acid)

GRM4, A.H.; VEMOMA, TMNT"I:dV. A.P.
ResearA In the field of quincnas. Part 17: Reaction of 2,1
dichloroquinonA with benz,)71 acetic outer. Zhur. ob.
ni,4:1040-1091 Ap '5?, (ML,(A
1. Xoskovskiy gosudarstvennyy univer3itet.

S OV/7 2 8 - 7 - 2 6/64
AUT',*ORS: Grinev, 1%# Al"o qVenevtoeval N. K., '.11crent'.yev, ~.. P.
TITLE: The Alyklation-oT the Subotituted 'j-01xYben~ofurfurunes. The
Synthesis of the Now Plant Grorth Stimulators (Alkilirovaniye
zameshchennykh 5-oksibenzofuranov; eintez novykh st.-mulyatorov
rosta rasteniy)
PERIODICAL: Zhurnal obahchey khimii, 1956, Vol. 22, 7r 7, rT, 1951-0-1653
(USSR)
ABSTRACT: The authors succeeded in elaboratin- a m~~thoi of the rynthe::i-r-
of the substituted 5-oxybenzofurfuranezi by the condensation
of p-quinone with the esters of the 2-keto ccilf- 5),
which practically made accessible a series of 5-ozybenzofur-
furane derivatives. As a proof for the structure of the ob-
tained compounds papers already existed on the methylation
of some of these compounds with dimethyl sulfate, witii eit*aer
derivatives of the 5-methoxybenzofurfurane-3-carboxylic acido
(Refs 3, 5), or their esters having been obtained, depending
on the conditions prevailing (Ref 6). 'A'he compounds (1), (11),
(III), (IV) and (V) were synthtized by the authors by the
Card 1 /2 conversion of the 5-oxybenzofurfurane with limethylaulfate

SOV/79-28-7-26/64
The Alkylation of the Substituted 5-0x,,ibenzofurf~irinea. The rl'-irther".- o:
the New Plant Growth Stimulators
in alkaline medium in the presence of dioxane. rn. the h..,drc-
lysis of the esters (I), (III), (V) anti (VT) --ith r-lcoholate
'the furfpurane3 (VII), (VIII). (IX) ind (Z) i-,-ere obtained.
The acetic acids W) and (XII) vQre obtziined as final
products of the alkylation of th(-- alrendy earlier
synthetized oxi Acids of the ben,7,ofurfurane 2erip .3with r~hloro-
acetic acid Tl~e notassium oults of' the au (VIT)
proved to be highly effective plant grovith vtimul-itoru
was shown by the evidence obtained by It. -'t. BazilevFkayn in
the M. G. U. Botanical Garden. The results of the biological
experiments with these products will be published later.
There are 6 references, 6 of which are Soviet.
ASSOCIATION: Mookovskiy goaudarstvennyy universitet (Moscow State Univer.,,ity)
SUBMITTED: June 18, 1957
Card 2/2

SOV/7~-28-7-2 7/6z
AUTHORS: Grinev, A. N., Znytnev, 1. .11. , Venevt~:eva, !T.
Terentlycvp
VITLE: it New Method fort,ie "'ynthesis of Substituted Denzofurfurane-
and Indole From Esters of the Benzofurfurane- hnd Indole-Q-
Carboxylic Acids (,,'ovyy metod polucheniya zameshchennykh
benzofuranov i indolov iz efir ov bcnzofurati-I Wol-P-knr-
bonovykh kialot)
PERIODICAL: Zhurnal obahchey khimii, 1958, Vol. 28, Nr 7, PP, 1855-1855
(USSR)
ABSTRACT: In many cases the eaters of th e substituted benzofurfurane-
and indole-B-carboxylic acids were btter accessible than
the benzofur~uranesand indoles as such. The carboxyl - group
in these compounds is closely attached to them Po that their
cleavage demands strict condit i6n7 which lead to a great
lose in nubstance (Refo 1, 9). Tn the experiments carried
out to remove the carbox-1 , !-oup from such and similar ron-
pounds the authors either Diet with difficultie.s, or the
yields were too small (Refs ~., - 6). The synthesis of the
Card 1/3 N-alkyl- and N-aryl substit Ute d indoles with a free P-posi-

SOV,/79-26-7-27/64
A New Method of the Synthesia of Substituted Benzofurfurane- ani indole
From Enters of the Benzofurfurane- and Indole-p-Carboxylic Acids
tion could not be realized in these experiments at all. The
authors by means of nome examples suggent a convenient method
for the cleavage of the esters of the benzofurfurane- and
indole-o-cmboxylic acids by their heating with equimol,?cular
quantities of sulfuric or phosphoric acid in glacial acetic
acid solution. The reaction takes place according to the
mentioned scheme. Thus the authors by the oction of vulfuric
acid on the corresponding esters obtained the furfuranes (1),
(II), (III) and the indole (IV), vnd by the action of phos-
phoric acid the indoles (V) and (VI). The 2-phenyl-3-carboxy-
6,7-dichlorobenzofurfurane-5-oxyacetic acid was also oub-
jected to the cleavage of sulfuric acil, with the compound
(VII) having been obtained. There are 9 references, 6 of
which are Soviet.
ASSOCIATION: Moskovskiy gosudarstvennyy universitet
(Moscow State Univercity)
SUBMITTED: June 18, 1957
Card 2/3 1. Furan derivatives--Synthesis 2. Substitution reactions
3. Plants-Growth 4. Growth substances--Synthesis

A New Method forthe Synthacia of Subntituted Benz of firfurane- and Indole
From Enters of' the Benzofurfurane- and Indole-O-Carboxylic Acids
1. Furan deriyatiyee--Synthesis 2. Indoles--Synthesis 3. Carboxylic acid
esters--Chemidal reactions 4. Substitution reaotions 5. Carboxyl radicals
-4hdadcal effects
f~, rd 3,;

71-1-PP- - 7-263,~64
ri e v t s n v T% , Tpri-,ntlyev, A. F.
Investigations in the of '.uinouco (1s.-Ir-low-niya v
oblusti khinonov) (XII7. Tile Div,--stigution of the Conden-sation
of p-Denzoquinone r.nd 2,3-Dichloronuinone ':,'izh Acetic 2ster
'," -T'. T.,.licleni-~ kondeni3atrii p-benzo-
and Ito inalogs
I
khinona i 2,.7-dikh1orlhinona, o efirom i yegc

P~,:T'10--,,Ts:AL: '"hurnal obshchey khimii, 1959, Vol~ ?~A, r 7, prp- 1656-1864
OSSR)
In the present paper the, autho!lcl--rricad Out thE~-ondonsntion
of the p-benzoquirone with acetic ester at lo,,,,,Pr .enperatures
than the crize in their earlier narero (Refs 1 - 5" tht-
5
resultn deviated from tha.-e enrlier ou Pined. ;,t 80--S'; -;nd
"'t a low concentration of p-benzoqulnonn in the r,~acticn
MiXtUre mainly (at lox conc-ntrationseven Oxclusively) a
benzofurfurane derivative (formDla I) is obtained, --t ?i 45
at low concentra'ionri the entern, Qj) fend (IT!) are formed.
Card 113 7.1hen the reaction ttike!j TArce tit .~Wj onl,,,, the .7ubgti4.-u,,Pd

-07/79-28-7
-2816A
Investigations in the Field of ~~,jinones. Inv
fXTII. The cstiration of the
CondensEtion of p-Bf.-nzoquinone and 2,3-Dichloroquinone 77ith Acetic Eater
and Its Analogs
benzofurfurylacetio ester (II) is obtained without admixture
of (M). The substituted enter (I!) on boilini~ its solutions
in alcohol and other solvents er~cil,r converts to (III). When
the reaction is carried out at low tbmperatures it is Dos-
sible to separate also a product rith a melting point of
206,5 - 2070 besides (II) from the reaction products whe:.
the relative concentration of p-benzoquinone is increased;
according to the analysis and the qualitative reactions
carried out this product must be given the formula (IV). Frcm
the exDeriments carried out it..may be conclud-:4 that the one
or the other direction of the condensation of the quinones
with eoters of the e-keto acids, which may be Pasily controll'~d
by the comparison of the yields of the derivatives of benzo-
furfurane and benzodifurfurane, does not only depend on the
concentration of ouinone in the reaction mixture but also
to a considerable degree on temperature. Residep these factor8
mentioned also the nature of the reagent acting in the re--
action with the nuinones influences the yield of the derivatives
Card 2/3 of benzofurfurane and benzodifurfurane. There are 8 references-,

riv 1 -it ir on zi in "I ke 10. -_` -i In ~)nei The T I.- vpvt of the
zw' -P-Iicnzoauinorie ~:nl ',it_ Acetic Ester
~i nf! I ae) go
7 of are .'oviet.
ur, !,.tu
(Mooco-w Ct!-tte UnivAr.-.1ity)
june 2 1 195 7
1. Benzoquinones--Chemical reactions 2. Chloroquinone-Chemical
reactions 3. Condensation reactions 4. Acetic acid esters-Chemical
reactions
Card 31i-i