SCIENTIFIC ABSTRACT VIKTOROVA, YE.A. - VIKULINA, E.K.
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CIA-RDP86-00513R001859810005-4
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RIF
Original Classification:
S
Document Page Count:
100
Document Creation Date:
November 2, 2016
Document Release Date:
September 1, 2001
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5
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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S/081/61/000/019/037/085
Contact catalytic transformation... B110/B1O1
oxide catalyst. The following data are given: reaction temperature in OC,
yields of "H 07 111, o-(CH 3)2 C6H4- 1,2-dimethyl cyclohexane, 1,2-di-
=ethyl-4-cyclohexanol, and 1,2-dimethyl 4-cyclohexanone: 150, traces,
1.8, 25, 29, 34.3, 7; 200, traces, 3.3, 17, 62.1, - -; 250 2.4, 22.3,
30.5, Reaction of Ib with (CH ) C--CHCH (Iva~ or (CH') CHCH=CH
3 2 3 3 2 2
(IVb) (at 1500C and 2 - 3 atm on 20% ZnCl 2180% Al203catalyst, the
amount of the catalyst used being 10% of the weight of the reagents)
yielded 40% 3-CH 3- 6-tert -C5H11 Ar (V) (and some 3-CH 3- 4-tert-C5 H11 Ar)
(Ar - C 6H3OH). One isomer only, 4-CH 3- 2-tert-C5H11 Ar (VI), was obtained
in 40% yield from Ic with IVa, IVb, or CH 20 C(CH 3)C2H5' In all experiments,
the initial iso-l", 5H10 dimerized, forming C 10 H20' Under the same reaction
conditions, 1-pentene and 2-pentene yielded 70% alkyl cresols. Reaction
of Ic with 1-pentene yielded 2-HO-3-CH 3C 6H3CH(CH3)C3H 7in 65% yield. The
data given for the alkylation products (obtained with C 5H10 and Ib or Ic)
are b.~. in 0C/mm Hg, n 20 d20 , M.P. in 0C, and the m.p. of the
Card 2 4 D? 4
S/081/61/000/019/037/085
Contact catalytic transformation... B110/B101
corresponding aryl glycolic acid in OC; V, 94 - 96/3,
142 - 143; VI, 125 - 125-5/9, -, -, 26-5 - 27, 126-5
3-CH3- 6-CH(CH3)(C3H7)Ar, 103 - 104/3, 1-5190, 0.9622,
3-CH3 -6-CH(C 2H5)2 Ar, 138 - 139/8, 1-5187, 0-9585, -,
147 - 148/8, 1-5148, 0.9693, -, 101. From Ib and piparylene
1-5193, 0.9626,
1271
981
3-CH 3-4-CH(C2H 5 2Ar,
(20% ZnC12 on
A1203 ), 70~ of an alkylate was obtained, which consisted of
3-CH 3-6-CH(CH3)-CH-ClICH 3Ar (VII) and 3-CH 3-4-CH(CH )CH=CHCH Ar (VIII) (90%),
3 3
and of 2,497-trimethyl chroma'n and 3~6-dimethy~-2-ethyl coumaran (10%).
Reaotion of Ib with oyclopentadi ane0at 25 - 30 C yielded the dimer of the
initial cyclopentadtene, and at go C 293-cyclopent6n-7-methyl-2,3-dihydro-
benzofuran (IX). With H 3P04 at 0 C' 80% 3-methyl-6-(Oyolopenten-2-yl)phenoi
(X) and 3-methyl-41(cyclopentene-2-.yl)pherLol (XI) were obtained. The
alkylation products,obtained fr8m Ib by tre8tme~S with piperylene are
characterized by their b.p. in C/mm. Hg' d4 and by the m.p. of the
corresponding aryl glycolic acid in Ct VII, 136 137/9, 1-5312, 0-9847,
Card 3/4
5/081/61/000/019/037/085
Contact catalytic transformation... BI1O/B1OI
108 - 108-5; VIII, 147 - 147-5/7, 1-5360, 0-9884, 118 - 118-5. The
alkylation prodtacts obtained fr8m IIb by trlatme~8 with cycl8pentadiene are
characterized by their b.p. in C/mm Hg, 0 9 ' d4_v m.p. in Cp and m.p. of
the corresponding aryl glycolic acid in CS 118 120/3, -9 -v 69 - 70P
111 -'1121 XI, 129 - 132/3, 1-5655, 1.0666, 129; 3-methyl-6-cyclopentyl
phenol, 113 - 115/3, 1-5495, 1.0087, -9 101 102; 3-methyl-4-cYolopentyl
phenol, 123 - 195/3, 1-5549, 1.0498, -, 101 107; IX, 138 - 140, 1.5474,
1.0608, LAbstracter's note: Complete translation.
Card 4/4
SHUYKIN, N.1,; VIKTOROVA, Ye*A.; POKROVSKAYAY I.Ye.
Alkylation of phenols by compoundo with mixed functions.
Report 1: Alkenylation of m-cresol with allyl alcohol* Izv#AH
SSSR,Otd.khim.nauk no.6:1094,1098 Je 161. (KM l4j6)
1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosoia.
(Cresol) (Allyl alcohol)
- N.I.; POPOVA, G.V.
Contact calmlyluic cohv-rsions of ;hn-nols. Part 5: A - a
- r' - lky3- tion of
Y--cresol by Fiperylene. Vest. Mio~:k. im. Ser. 2: M-hir. 1,; nc.!.:
62-65 160. (I:I~A :L[,-2)
1. Kafedra khil!iii nefti Moskovs',oco wniversiteta.
(Croool) (Eperylane)
TMNTIYZV, A.P.;.TIKTOROVA, Ye.A.; TISELISON, B.M.; KOST, A.N.;
YBRSHDV, T. .
Inner complex compounds an contact insecticides. Zhur.ob.
kbia. 30 no-7:2422-2427 JI 160. (MI" 11:7)
1. Moskovskiy gosudarstvennyy universitet.
(Complex compounds) (Insecticides)
YJJ~T~VA ~YA.; SHUYKIK, U.I.; POLYANSKAYA, B.I.
Cycloalkanylation of phenol by 1,3-CYcloboxadiene. Izv. AU SSSR.
Otd. khim. nauk no.11:2048-2049 N 060. (RU 13.11)
1. Mookovskiy gosudarstvannyy universitet im.M.Y.Lomonosova.
(Cyclobezadiene) (Phenols) (Alkenylation)
8/074/60/029/010/002/004
13013/B075
AUTHORS: Shuykin, N. I, and Viktorova, Ye. A.
TITLE: Catalytic Synthesis of Alkyl Phenols. Al
PERIODICAL: Uopekhi khimil, 1960, Vol. 29, No. 10, pp. 1229-1259
TEXT: The authors give a survey of studies made on the catalytic synthesis
of alkyl phenols. The available publications were systematized according
to the character of the alkylating substances. Papers are mentioned re..
ferring to some catalysts, on the character of which the structure and the
ratio of alkylation products are dependent. The subject of the first
chapter is the alkylation of phenols with unsaturated hydrocarbons. The
application of the following catalystslis described: Acids as alkylation
catalysts (Refs. 32-108); metal chlorid'es in alkylating phenols with
alkenes (Refs. 63, 109-128); borofluoride (Refs. 129-168). Data obtained
show that sulfuric acid is the most freqrently used catalyst. It is pre-
ferred due to its accessibility and its sufficiently high yields of alkyl
phenols. Also alkylation in the presence of resin - ion exchangers seems
to be promising. The use of borofluoride and of some of its molecular com-
Card 1/3
Catalytic Synthesis of Alkyl Phenols S/074/60/029/010/002/004
B013/BO75
pounds requires further study~ The use of aluminum phenoxide seems to
open new possibilities in the synthesis of o-alkyl phenols. The second
chapter deals with the alkylation of phenols with alcohols (Refs. 36,
65, 80~ 81, 99, 173-277). As was proved by the mentioned data, the !jtruc--
ture and the yield of alkyl phonols are dependont on the reaction conditions.
These, in turn, depend on the structure of the alcohols employed, on the
temperature, as well as on the nature of the catalyst. In some cases,
phase stateand pressure factor play an essential part, In spite of the
high yields, alkylation of pbenols with alcohols is rather inexpedient
for industrial purposes; in laboratory practice, however, it offers a
number )f advantages. In the third chapter,alkylation of phenols with al-
kyl halogens is discussel (Refs. 1091, 278-335).. Data available cn alkyla-
tion with alkyl halogens show that the reaction in the presence of aluminum
chloride is' most tForoukhly Investigated. However, It has to be taken into
consideration that the isomerization of the radical entering into the
phenol molecule does not always take place. Alkylation with ternary alkyl
halogens in the presence of halogen hydracid is extremely easy, especial.
1y if the alkyl halogen forms during the synthesis. By this means, the
possibility of using more easily accessible alkenes is given.
Card 2/3
Catalytic Synthesis of Alkyl Phenols 3/074/6o/029/010/002/004
BO13/BO75
Yu. G. Mamedaliyev, V. N. Ipatlyev, V. I. Isagulyants, A. V. Topchiyev,
I.Tsukervanik, V. Tambovtseva, B. M. Dubinin, A. Ye. Chichibabin, A. S.
Abdurasuleva, N. G. Sidorova, Z. N. Nazarova, I. N. Samsonova, Z. P,
Aleksandrova, A. B. Kuchkarev, and P. P. Bagryantseva are mentioned.
There are 335 references: 40 Soviet, 166 US, I Austrian, 1 Belgian,
29 British, 1 Canadian, I Czechoslovakian, 1 Danish, I Dutch, 20 French,
38 German, 3 Italian, I Rumanian, 6 Japanese.and I Swiss.
ASSOCIATION: Khimichaskiy fakulltet MOU im. M. V. Lomonoseva
(Department of Chemistry of the Moscow State University
imeni M. V. Lomonosov)
Card 3/3
ACCF.5SIQNNR4- AP4015308 S/0280164/0001001/019610201
AUTHOR; Viktorov, Ye. D. (Leningrad)
TITLE: Stabilizing a-control system by introducing & nonline4r correction
SOURCE: AN SSSR. Izvestiya. Tekhnicheskaya kibernetika, no. 1. 1964. 196-201
JOPIC TAGS; automatic control, nonlinear o~orrectlon automatic control,
alance
'adaptive filter correction, adaptive filter automatic control, harmonic b
I method
!A.BSTRACT: The control of a plant in coneddered whose transfer function has this
?form: S(P) - C (p) where &J, and Q. are real and proximate,, C (p) does not
contain the co effi c lc nts of the fo r m (p I + (oil) I (p' + (41) with Wj a ufficie ntly clos a to
i &jj,. The method of "frozen factors" is used in the investigation. a is proven
that the stability cannot be ensured by any line" controller with constant
!CWC"/2
I I - . - - . I . .-I
'ACCESSION NR: AP4015308
:parameters. Hence, an adaptive filter is suggested; its introduction results in
4
: stable self-oscillations. The harmonic balance method is used to investigate the
'behavior of the filter. The nonlinear correction in the controller can stabilize
the above plant if the range of variation of W,, is known; the controller can be
selected in such a way that I( to.) retains Its sign for all possible values of WL;
here, I(co) is the imaginary part of K(ica) C(Lj) and X(p) is the transfer function
of the controller. Orig. art. has: 3 f igureg and 37 forinulas.
ASSOCIATION: none
MMMITTED: 07j'&n63
IP'SUB CODE:' CG, IE
DATE ACQ: 1ZMar64
NO REF SO'r. 002
ENCL: 00
OTHM 001
Card 2 / Z
Slor /60/009/003/013/019/XX
KON191
AUTHORS: Viktorova, Ye.N., ZhmyreVa, I.A.9_Kolobkov, V.P.,
and Saganenko5 A.A.
TITLE: An Investigation of the Duration of Phosphorescence
in Solutions of Organic Compoundsat --196 OC
PERIODICAL: Optika i spektroskopiya, 1960, V~l 9) No 3, pp 349-3~2-
TEXT: The effect of various external and internal molecular
factors on the probability (r) of transitions of excited mole,-'.ales
to a metastable state is related to the ratio (8) of the quantum
yields of phosphorescence and fluorescence at low temperatures
(e.g. -180 or -196 OC). For long wavelength phosphorescenoe
+ q,
P e-
where p is the probability of a fluorescent transition, It is
the probability of emission of radiation on transition from the
metastable state to the ground state, and q2 Is the probabilitj
of cLuenching in the metastable state. The authors studied the
duration of phosphor es cenc; e (Tphos.) in order to obtain info rma tio r).
on enching in the metastable state at -.196 OC and to find to what
Caraul/3
An Investigation of
of Organic Compounds
extent a change of
the probability r.
and 6 at
The compounds dealt
s/o51/6o/oo9/OO3/O13/O19/XX
9201/El9l
the Duration of Phosphorescence in Solutions
at --196 Oc
6 due to an external medium is reflected in
Tables 1 and 2 list the values of -tphos
-196 OC for 1-7 compounds in ZI solventa.
with in Table 1 ares,
(I) 3-acetylamino-N-methylph+,,halimideI
(II) 4-acetylamino-N-methylphthalimide,
(III) 316-diacetylamino-N-methylphthal,t~ideI
(IV) 3-methylacety'Lamino-6-methylphthalimide.
The compounds listed In Table 2 arw
M 3-methylacetylamino-N-mothylphthallmideI
M) 4--mothylacetylamino-N-methylphthal.imide,
MI) 3-hydroxy-N-methyl.phthalim:Lde,
(VIII) Li--hydroxy-N-.methylphthalimide,
UX) 3-amino-6-nitro-N--methyl.phthal..imideI
W 3-dimethylamino-(,-.-methylacetylamino-.N-methylphthalimide,,
(XI) 3-dimethylamino-6-a(,-etylamino-N.-methyl.phtha.Limide,
Card 2/.3
S/051/60/009/003/013/019/XX
H201/E191
An Investigation of the Duration of Phosphorescence in Solutions
of Organic Compounds at -196 OC
(XII) 3-diphenylamino-N-mothylphthalimlde,
(Xiii anthranilic acid,
(XM paradimethylaminobenzoic acid,
(XV) cL-naphthol,
(XVI) 0-naphtholl
(XVII) 0-naphthylamine.
It was found that a change In the ratio 6 was a fairly accurate
measure of a change in the probability of transitions of excited
molecules to metastable states when the surrounding medium was
altered. Acknowledgements are made to B.Ya. Sveshnikov and
P.I. Kudryashov for loan of the apparatu-s--u-s-eU-Fo -measure the
duration of pho-sphorescence.
There are 2 tables and 21 references: 16 Soviet and 5 English.
SUBMITTED: December 22, 1959
Card 3/3
VNTOROVA, lej.
Certaln regularities In the nature of the quantum yield variation
as related to the position of the fluorescence bando for a mmber
of organic compounds. Opt. i spektr,, 10 tioW79-281 P 161.
(MIRA 24:2)
(Fluorescence)
VIMPGROVA, Y0.1j.; Z1.1 T';Sj~rj, -,I.V.
I, .
Relaf.lon of nonradlixLilve deac".1va Lion to tl~c
cimracterist-Ics oi* complex organic com-ound 1. Dokll.
91 S-""'R 1617, no.5:1033-10'6 D 165.
op
('~',RA 19:1)
1. Subn'tted Anril 22, 1965.
7
60[UMj?C,,&
opa:
e -)"j- Zell
01je
,is
On bLtwg 036
ell4racterlatl.en the -Probabljlt
SOURCP Of
AIT Y Of emisslo.,
Dokl
Orgao"o cQVour~s '009 deactirat
ad"* "'- -16.5.. J30. .5 Ion
cOP'POund e3calted tate the
Ansfiiial,9 grOuJid &t to -196.5., .10
9 Spectrum 33_.1036
A a 0 1
MAlber 01.
'a -P"r. 702COU"8013 Of 'Values
1, "'1048 sub.t,,,, or qufttum
Values PrObab,11tle, f . JXI e14
aft ,,,,Cea P In a -varle emISSI0,,,, 0 chemIca.1
Of SOlVent as deact,
tad acc0l-dIg ty a at C"00C,
Vbere to
the Vatlons
exelted the Is aw of
(q + M~u~tt'. .
Pl*obab e in
-leve.1 401*ftles ill luty Of the
.P and - 7
'value a oxes"a.. )/-r
a Is Is the
ftde by state'rocess Of direct
Vas Ob a effte durat 18 the eal
be Of f"ftZlOa of the ProbablUty881022lesa ccqr
rved between exe Of tr Mrsloll
the lted ausfer to
Of
Card .1/,o BQuan 4w 'llus state
'value t4FA trste~ by 7b, a Metas
tluor~~ceace and curves. C?Rwarle
A dire(It Of
The absolute Ion
Ylelds Vere,
Co,d
L 1%).7-66
--j~cc Nn, '06W2417
measured according to a method., previously described by the authors (Optika i spectro-
skopiya, 1. 5&$ 1956). using a FW-38 pbotonaltiplier in the capacity or a received
of radiation. Tvas determined an a phase fluorometer at the W-titute or.1102M I-a-k2.
Bioloor 9t tJ* AN SM, in L. A. TymnWls laboratory. The autbors conclude that the
relation between the value of the barrier and the spectral characteristics in
determined by the fact that both are functions of one and the same variable, the
change of vhich characterizes the changes in the relative distribution of potential
surfaces. - The authors thank L. A. Tvaerman for the possibility of conducting Wasure-
Monte on the f1wrometer and A. N. Surova for carrying out the Measurements. Orlgo
art- Me-. 7 fornibm and 4 figures.
MM Cobn:', 07,
WM. WM: OgApr 65/, OR-M MW: OU7/ 'OM 7W: OM
Card 2/2"4Z
e FIWP(J) RM
-3700-5m6b---SWT(W)Z
ACC NRi Ap6oiS593 SOURCE CODEs UR/0379/66/002/002/0227/0233
AUTHORt Iktorava, Ye. N.; Zelinskiy V. V.
ORGI State 00tical Institute im. S. 1. Vivilovs Leningrad (Gosudarstvenrqy optiches-
kiy institut) i
TITLEI Study of the relationship between the probabilities of processes of nonradi-
ative deactivation and the spectral characteristics of complex organic com-
SOURCES Teoreticheskays. i eksperimentalInaya khimiya, v. 29 no. 2p 1966, 227-233
TOPIC TAGS1 nonradiative transitionp fluorescence spectrumij transition probability,
ABSWCT: Tell probabilities of nonradiative deactivation of excited molecules on the
singlet level in the fluorescence of a series of complex organic compounds were com-
pared with the spectral charaotoriatics in various solvents at 206C. Values of these
probabilities were calculated from the formula
q t
(q Ir
where q is the probablUty of the process of diroct nonradiative conversion of excited
2
L 01274-66 EWT(1)/E'NT(m)/EPF(C)/EWP(J)/EWA(c)
ACCESSIM NRs AP5021D783
,21
AUTHCRs Viktorova, Ye* N.1 Zelinskiy, V. V.
TITLEt Investigation of the,fluoreSc2ncjLyield
(Reports,13th Conference on Luminesceno held in
1964] qq) eo S5
IJP(c)/RPL JN/"
UR/0048/65/029/008/1278/1283
AR
of some nitro-compound solutions
Khar1kov 25 June to 1 July
SOURCEt AN SSSR. Izvestiya, Seriya fizicheskaya, v. 291, no. 8. 19650 1278-1283
TOPIC TAGSs luminescence, solution propertyl, organic nitro compoundq lumin-
escence spectrum, electron transition, activatTon W-energy
ABSTRACTs The fluorescence yields of the following nitro-compounos in 14
different solvents were measured at ~OOC by a method that has been described
elsewhere (V. V. Zelinskly and V. P. Kolobkovv Optika I spektroskopiyat I, 560p
1956): 4-amino-41!-nitrostilbene.1 4-dimethylamino-4'nitrostilbenot 41-amincl.-
41-nkrodiphenyly 4-dimethylamino-41-:hitrodiphenylg 4-dimethylaminobenzal-41-
nitroanaline, metanitroanaline, meta-ni-tromethylanaline, meta-nitrodimethy.
lanallne, meta-nitrodiphanylamine, and 5-nitro-l-aminonaphthaline. When the
fluorescence yields were plotted against the frequency of the maximum of the
fluorescence spectrum, the points for a single phosphor (in different solvents)
Card 1/2
L 01274-66
ACCESSION NR: AP5020783
lay on a smooth curve which had a maxi==. The position and height of the
maxim= varied from compound to compound. When the fluorescence yields were
plotted against the Stokes shift, many points from all the phosphors lay close
to a single common curve. The points that fell off this curve were those for
solutions on the descending portion of the curve of yield versus frequency of
the luminescence band. Similar results were obtained by plotting the proba-
bility for radiationless deactivation against the Stokes shifts the deacti-
vation probability was an exponential function of the Stokes shift. All the
investigated phosphors in all the solvents had narrow luminescence bands of
approximately the same width, and they all had approximately the same electron
transition frequency. It is suggested that there is an activation energy for
radiationless conversion which may be related to the electron transition
frequency and the width of the luminescene spectrum, but which is largely inde-
pendent of chemical composition as such. Orig. art. hass 3 formulas and 4
figures.
ASSOCIATION: 00
SUBMITTED: 00 ENCL: 00 SUB CODEt GCj OP
Cra-')40 REF SOV: 017 OTHER: 008
VIKTOROVA, Ye.N.; GOITUN, I.A.
Fluorescent characteristics of' the --crien of rhodamino
dyes. Zhur.fiz.~Jlim- 39 no.11:264'3-261,9 11 165.
(!~'IRA 18:12)
S/051/60/009/004/031/031+
B201/B191
AUTHORS: Viktogoa I Ye.N,, Kochemirovskiy. A.B.,
-Xfa-snitskaYi-,-W-.Mr;, and Reznikova, I.I.
TITLE: New Examples of Pronounced Dependence of the
Fluorescence Yield on Position in the Luminescence-,
Spectrum p.I ON
PERIODICAL: Optika I spektroskoplya2 1960, Vol 9, No 1+, pp 544-546
TEXT: Zelinskiy et al. (Ref 1) showed that in five
phthalimide derivatives.there was.a.regular relationship between
the absolute quantum yield of fluorescence (q) at 20 OC in various
solvents and the frequency of the fluorescence spectrum maximum
The present paper reports a similar dependence of q on
in dimethylnaphtharhodine(dimetilnafteyrodin) (I),
2-aminoacridine (II) and cyclohexylaminomalainimide (III) at 20 OC
(a figure on p 545). The fluorescence yields were measured
using a.technique described earlier (Ref 10. The values of -0
(in lo3 cm-1) represent solutions in various solvents, such as
ethyl alcohol, cyclohexanol. cyclohexanone2 and so on. For each
compound (I, II and III) q'= f(,,)) was in the form of
Card 1/2
S/051/60/009/004/031/034
9201/E191
Now Examples.of Pronounced Dependence of the Fluorescence Yield
on Position in the Luminescence Spectrum
suggesting two different processes of de-activation in the two
groups of solvents represented by the two branches of A .
The fluorescence yield is denoted by qpt and the fluorescence
maximum by %)1;x in the figure on p 545; numbera in the figure
(1-20) represent various solvents.. Acknowledgement is made to
V.V. Zelinskiy who directed this work.
There are I fl-gure and 7 references: 6 Soviet and 1 English.
SUBMITTED: May 20, 1960
Card- 212-
VIKTOROVA. Te.N. ; KOCHEMIROVSKIY. A.S.; KRUNITSKATA, N.D.; REZNIKOVA. I.I.
New examples of the pronounced dependence of the f luoreecence yield
on the position of the emission spectrum. Opt.i spektr. 9 no.4:
544-546 0 '60. (MMA 13;11)
(Fluorescence)
L 16128-66 1-mr, ( T-z)lwe(j)
ACC NR: AP6004179 SOURCE CODE: Ult/007f)/66/0.10/0f)1/0094/0099
AUTHOBI-VMorova Ye. N. , Z a ko, N. F.
Nczn, y
ORG: none 13
TITLE: Effect of phenyl groups on the fluorescence yield of aminophthallmides~
SOURCE: Zhurnal fizicheskoy khimii, v. 40, no. 1, 1966, 94-99
TOPIC TAGS: fluorescence, quantum yield c)r ~Lvs'(!
ABSTRACT: The effect of phenyl groups introduced Into the amino group of 4-amIno-N-
methylphthalimide, 3-amino-N-methylphthalimide, 3-(Iiphenylamino-N-methylphtlialimide,
4-dipheiiylamino-N-metliylphthalimide, and 4- monophenyl amino-N-m ethyl pht hal imide
on the fluorescence of these compounds was studied by determining the absorption spectra
and quantum fluorescence yields In varlou.,i solvents at 20C, Tho e1ectron ripectra showed
the presence of conjugation between the elec tron- acceptor phenyl group intrcx1twed into
the amino group and the phthallmide ring, as Indicated ~v asubstantial bathochromic shift.
Curves of the following relationships were plotted: V max versus solvent at 20C, quanf~m
fluorescenco yields versus position of corresponding fluorescence spectra, and quantum
fluorescence yields versus corresponding Stokes shifts. Orig. art. has: 3 figures.
aCard 1/2 UDC: 543. 42
L 16128-66
ACC NR: AP6004179
SUB CODE: 07,N/ SUBM DATE: 23Sep64 ORIG REF: 013 OTH REF: 005
Card 212
ACC NR9 AT6000496 SOURCE CODE: Ult/0000/65/000/000/0266/0269
AUTHOR: Brekhovskikh, S. M ; Vfktorova Yu. N.; Zpientsov, V._V.; Zelentsova S. A.
ORG: none
TITLE: Effect of the chemical nature of cortalti elements on the radlation-optical re Istance
of irradiated glass~,qj
I r, Q I
S E: VsesojTznoye soveshchan!vc Po st0doobramornu sostovanivu. 4 Leningqto, 1964.
manlya, Leningrad, lz(l-vo Nauka,
1965, 266-269
TOPIC TAGS: optic property, glass property, gamma irradiation
ABSTRACT: Ile dependence of the radiatton-optical resistance on the position of a variable
element In the periodic system is studied in glasses of the system 4SiO2 * Na20 - 0.5ATeO
(or 0. 25 Me20). As a rule two absorption. bands, at 400 - 4 50 and 600 - 650 mp, appear in
the spectra as a result of y-radiation. The first band can bo ascribed to the F-center which
represents a quasi-ion (Nle+ + _j]. The intensity of this band Is directly related to the position
of Me In the periodic system. Ile smaller the electronegativity of Me, the greater the
probability of the localization of a migrating secondary electron near it and the more intense
Card 1/2
ACC NR, AT6000 496
the absorption bawl, All glasses containing elements of groups I and 11 as the third component
have similar spectra, with smaller absorption at 400 rnu for glasses with Mg and Ca. The
absorption in the 600 mp region Indicates, in all probability, the presence In the glass of oxygen
vacancies and the formation of free oxygen atoms. Elements of group III differ appreciably
more chemically than those of groups I and 11; therefore their spectra substantially differ from
one another. For elements of group IV an increase of radiation -optical resistance is observed
with a decrease of Ion radius only for the first three elements. For glasses containing clementj
of group V the radiation-optical resistance increases by a factor of 3.3 on replacing SrO(4dO)
by Zr02(4d2) and Nb205 (40), which is associated with a decrease of the ton radius from Sr to
Nb. Glasses containing elements of group V1 are governed by the same rule. Orig. art. has:
3 figures.
SUB CODE: 11, 18 SU13M DATE: 22May65 / ORIG REF. 002/ OTH REF: 001
2/2
I~t-~Illrl'r
AtffliOP; Bre kh,.vski ki-,S 7-n 4,', V-I Sh_-
No=
EM
MFM
TI TL E Op~ I cr:Ll rad i it. i ~n t ~~b i 11 f 'i ftr~. 7 1,- F, i r r ~Ld i -it -jIga-=,t - r
vq], i --is r Ie r '11, t; C'
SOURCE: AN SSSF. Dakkady, v. '163, no . 1, 1965 , i 614- 1 6S
TOPIC TAGS: optical radiail',ton stabil3ty, quartz glass, color center, F center,
temperature dependence
!
iAB~STRAC`T. The effect of temperature on the radiation-induced discoloration of Quar_IZ
Iglasses KI and KRL has been studied in the virtual abssenr7e of literpture rn this
:sUL,ject. The optical raiiatinn stability of the qlfuss stljl_`-d
at room temperature. The rar',; cf the 11,zit, traLrmisFiori of the -irrarliate; P..~asr, to
the initial tr,54~smiss::I.n ;r. tl'~- i
%+A em r'
vas determined fut p T~ETF. T
tab Ii:,-'2_ -:J-I.Iubt 6t a - tffij: OFtS V i er
closure r e 4t
ures;: The- transmission
_10 -th
%h% '86C
* 1)0 v takU -,but ofthe Devar, .
a "-erce eatraena7--IrraAl-a -at--roo-m-,
ite weran w empAr-
were black-violet, and lthovne irradialc-d n~ 90K wr-re
11glit-emoky.
ca--f-cf- I A
NR AP5018091*
[ACCI~;SIOH
-
The observed dependence of the discoloration on the temperature of irradiation can
he explained by the shift of the dynamic equilibrium between the forn-ed F-:nd decaying
T
!color centers. It is assuw--a that the number of F--enters formed de-r,~ases vi'h
de-r,-~!i.slng ~Pmperqture, whi1c. the rad'a~ :,-)n je.,'ri-fion !~*' th-z;,, r~-'
depend -~ri the temperature. Phe , Fc after low doses (if irradlRti-)n -an b~-
explained by a decrease in the effect of radiation annea-ling due to the iiminishing
,number (;f color centers and an increase i-n their-stability. Orig. art,. has:
j2 tables,
1ASSOCIATION: none
SUB CODE: Mr, N P
iHO REF SOV: 001
OT"-R. 008
ATT) PPPSS-. 4056
Card P/ 4
Z-,, 5~
A C C E~,- 3 10 IRA P
0 PS at 1,00m tempemiture
rradiation dose, r
'at
COGO
rd KI glass
*T,k PC K R 1, g1 as 9
T,% PC
n 1
n
2 92
04
104 9 (112
0 I L,2 92
10, 0 0 92 1
7, Light traimr-iii.7sion me~q~irpa on
Card 3/4
MOSURE: 02
L 62-167-65 Ell r
~ACCE;SSIoN NFt:----A-P50l6691
Mperat-Ureiv-
dose 10 r
doge 10 4r KI 91 so, dose 106r YRL 91
rl,r.(Ii qtlon VI i7,llt %
temperature# -- P Pr
T, % T,
OK
91
90 87 0.95 68 0 -'r 14
0.95 21 0.2 91
200 C12
0.02
BREKHOVSKIKH) S. M.; VIKTOROVA., Yu. N.; Z-VIENTSOV., V. V.; ZELENTSOVA., S. A.
"Effect of some oxides on silicon-oxygen sceleton of oxygeneous glasses."
report submitted for 4th '11-Union Conf on Structure of Glass,, Leningrad,
16-21 mar 64.
S/058/63/000/001/067/120
A16o/Aioi
AUTHORS: Ryabov, V. A., Nayman, 1. M., Borleova, 1. 1., Grinevetakeyap 86 N.0
Viktorova, Yu. N., 0ayevaya, L. A.
TITLE: New light filters for the proteotion of the eyes during produeUon
PERIODICAL: Referativnyy zhurnal, Fizika, no. 1, 1963, 83, abstract ID6W
("Steklo. Byul. Goa. n.-i. in-ta atekla", no. 1 (110), 1961, 72
81)
T M A desoription is given of the technological process of producing
neutral and selective light filters designed mainly for controlling metallurgical
processes. The light filters are made by applying oxide films from metal salt*
of the 4, 5 and 6th period of the periodic system of elements by the aerosolA
method. Presented are the characteristics of the light filters with oxide lapre
from cobalt, iron.,lead + antimony and lead + antimony + iron.
Yu. Kutev
[Abstracter's note: Complete translation)
Card 1/1
VIKTOROVIC, D.
Jamjicp T.; Viktoroyle, 2.
"A Now Method For The Qualitative Separation of Basic Sulfides of the Second
Analytical Group." p. 301 (GuSITIK,
Vol. 18P No. 5o 1953, Beograd.)
jmjlcm T.
SO: '140atwx-LI-st of Easj gyj2pea AcceissionA, Vol. 3, No. 3,, Library of Congress
March 19542 Uncl.
KR&SIC, Sreten; VIXTOROVIC. Z.-, STOJANOVIC. D.
Oas-stage colectony with ilootransvtrsootony for carcinoma of
the right colon. Srpski arh. celok. Isk. 83 no.12:1481-1483
Doe 55.
1. Hirursko odelenjo Opste bolulce u Iragujevcu. Sef: prim. dr.
Sreten Krasic.
(COWN, neoplasms
Ourg. colectomy with Ilmotransversostomy, one-stage.
(Ser))
S/149/63/00,0/001/OOZ/008
A006IA101
AUTHORS: Listovskiy, D. I.,.Viktorovioh, 0. S., Malevskiy, A. Yu.
TITLE: On the mechanism of interaction between the components of the
Fe-Ni-O system in the solid phases
'PERIODICALs Izvestiya vysshikh uchebnykh tavedenly, Tavetnaya metallurglya,
no. 1, 1963, 58 - 66
TEXT: In previous inve 'stigations the structure of the zone, formed
between NiO and its reduction products and the part of oxygen diffusion was not
revealed. The authors attempt to determine the basic features in the interac-
tion of components-in the Fe-Ni-O slatem. Cylindrical specimens, 1.8 mm in
diameter, were produced from pure iron and iron-nickel alloys. They we're pressed
into chemically pure nickel oxide. The briquets obtained were quenched in a
nitrogen filled closed space, at 1,0000C for 5 h. The chemical composition of
the cylinders and the extension of the reaction zones is given in a table. The
process of NiO reduction by iron was studied. The formation of nickel atoms
takes place as a result of transition of Fe2+ ions into Fe3+. As a result of
Card 1/4
S/149/63/000/001/00Z/008
On the mechanism.of interaction... A006/A101
Fe3+ and Ni2+ diffusion in opposite directions, a nickel ferrite layer is formed
on the interface with NiO. Fe2+ and electron diffusion to a spinel layer causes
the reduction of Ni-ions. These processes take place simultaneously. As a re-
sult of reaction diffusion of metal ions and electrons in contact with wuestite,
spinel must be formed which does not contain nickel (magnetite). In contact
with NiO spinel may be present which does not contain Fe2+, i.e. nickel ferrite.
In such a manner N12+ reduction by Fe2+ ions proceeds during the contrary dif-
fusion of cations of both metals in the spinel layer, indicating the presence
in the latter of metal phase inclusions. The thickness of the spinel layer is
determined by the rate of iron transfer to its internal surface, The driving
force in oxygen diffusion is the gradient of its chemical potential, which is
supported over the layer of interaction products in the direction from NiO to
the metallic cylinder. The oxygen can diffuse in electroneutral state over the
ipterstices of the oxide phase lattice or pores, and also consecutively from one
sublattioe to another one in the form of a negatively charged ion, The oxygen
diffuses also through the metal phase. The penetration of oxygen into the depth
of the alloy, accompanied by the formation of iron oxides along the grain boun-
daries, and inside the grains, excludes the possibility of Ni diffusion, but
Card 2/4
S/149/63/000/001/00P,/008
On the mechanism of Interaction... A006IA101
a~.-celerates Iron transfer. The general rate of oxidation Is increased in com-
parison to the rate that could be expected when assuming that the process must
be exclusively limited by mutual iron and nickel diffusion in the metallic phase.
Investigating the effect of the composition of the alloy upon the composition of
oxide phases and the structure of zones, it was established that the composition
of the iniii~l fetal determines that of the oxides formed during their contact
with the metal, and the structure of the internal reaction zone. If iron pre-
vails in the initial alloy, wuestite formed in the internal reaction zone breaks
the metal phase into finest metal particles. At a higher Ni content the wuestite
particles in the alloy crystals ronain dissociated, but each grain is enveloped
by an oxide film. Processes in the internal reaction zone are of a more general
nature than those in the external reaction zone, where the structure of Indivi-
dual layer depends little upon the composition of the initial alloy. T6 mech-
anism of the former-processes does not depend upon the form of introducing the
oxygen, and is also correct for oxidation of pure Iron and selective iron oxida-
tion of Fe-Ni alloys by a gaseous medium. There are 2 figures aro- I table.
ASSOCIATIONs MoBkovskiy institut stall I oplavov (Moscow Institute of Stool and
Alloys) Kafedra metallurgii radioaktivnykh motallov I komplokanogo
ispolizovaniya polimetallicheskikh rud (Department of Metallurgy of
Radioactive Metals and the Complex Utilization of PolymetaWo Ores)
C
ard 3/4
s/149/63/0w/0DI/00Z/OO8
On the mechani3m of interaction... AO06/AIOI
SUEMITTEDs October 1, 1962
Tabla-
COMPOSVIon f cylinders,- EXtension of reaction zonesAu
Specimen external
Fe Ni internal viuastite spinel total
layer laver
a 100.0 - 100 320 10 430
b 78.9 21.1 170 190 15 375
c 60.9 '39.1 180 110 20 310
d .44.4 55.6 14o 60 25 225
e 22.9 77.1 25 - 40 65
Card 4/4
LISOVSKIY, D.I.; MALEVSKrY, A.Yu.; -UT WNW!
mwm~
Interaction of the components of the system Fe - Ni - 0 in
solid phases. Izv. vys. ucheb. zave; tavet* met. 5 no.6:
50-56 162. (MIRA 16:6)
1. Moskovukiy institut st&li i splavov, kafedra metallurgii
komplakenogo i lizovaniya polimetal2icheskikh rud.
978tem,(Chemistry))
~Phase rule and equi3ibrium)
VIXTOROVICH, G.S.; LISOVSKIYj D.I.; MALEVSKIY, A.Yu.
Studying the interaction of nickel oxide with iron in the solid
phase. 10r. vys. ucheb, zav.; tavot. met. 5 no.406-94 162.
(MM 160)
1. Moskovskiy institut stali, kafedra metallurgii i fisichaskoy
khiadi tevetuykh metallov.
(Nickel oxide) (Iron oxide) (Phase rule and equilibrium)
VIKTOROVICH~ 108
Second year of new PDA arrangements. Neftian4k 6 no.717-8 n 161.
(MM 14:7)
(petrole= mini )
1-1
VIKTOROVICH) Ye.
flew working conditions at the Ukhta Combine. Reftianik 5
ne,.A.-26-27 Ag 160. (MIRA -14:8)
(UkhU "glen . )."~~Jk%ffitvp-*nagement)
Yel
xrostproof acet-, ene Neftlnnik
0
(Gas weather condit-imi)
EMM
SUMATSKIY, A.; NIZHEGORODTSEV, P.; KARTYNOV., A.; VIKMROVICH v- -
CHERTILIN., V.; BATIROV, R.
In the oil regions of our country.
33 Ja. 162.
industry)
Neftiazilk 7 no.1:30-
(KIRA 15:2)
(Petroleum
VIKTOROVICH, Ye.
First in the Komi Republic. Neftianik 7 no.2:3-4 F 162.(YIRA 15:2)
(Komi A.S.S.R.-Patroleum-Refilting)
I
VIXTOROVICH, Ta*Ya,
In the brWes of communist labor. leftianik 3 no-10-7 Ja 6o.
(KIRA 13:11)
(Petroleum Industry)
VIKTOROVICII Ye.Ya.
our reserves. Neftianik 7 no.12j6 D 062. (XlkA l6s6)
(Komi A.S.S.R.-Petrolonst Industry)
VINTOROVICH, Ye.Ya.
Gas field of communist labor., Meftiw4 ? no.?.26 J1 162. WIRA 16:3)
i (Komi A.S.S~R.-Gas., Natural)
IVRIOVA, T.I., prof.; VIKTOROVSKAYA, Ye.N., dotsent; LAFOVOY, I.D.;
KRVMHEMA -Ve"-'
.9 M.
Use of albomycin in treating women with inflammatory diseases
of the genitalia. Sov.med. no.3:M-122 162. (MIRA 15:5)
1. Iz kafedry akusherstva i ginekologii (zav. - prof. A.V.
Anisimov) i kafedry mikrobiologii (zav. - prof. T.I. Ivanova)
Stanislavskogo meditsinakogo instituta (dir. - dotsent G.A.
Babenko).
(GMWMTIVE ORGAFSj FaTALF.-DISMES)
(ALBOMYCIN)
F 'T IT
USSR/Mathematics Integral curves qualitative theory FD-450
Card 1/1 : Pub. 64 - 2/11
Author : Viktorovskiy, Ye. Ye. (Kiev)
Title : A generalization of the concept of integral curves for a discontinuous
field of directions
Periodical : Mat. sbor., 34 (76), 213-248, Mar/Apr 1954
Abstract : Introduces the concept of a generalized integral curve. Extends this
new concept to systems of differential equations. Clarifies certain
properties connected with the averaging the right part of dy/dx =
f(x, y). Clarifies the qualitative properties of the set of such
curves. Extends results here to certain nonlinear Volterra integral
equations.
Institution :
Submitted : January 5, 1953
Name: VIKT(jRUVSKly
Ye . Ye.
Dissertation: Integral curves of disruptive field directions
Degree: Cand Plqs-Math Sci
b-w4S&�jL A*
DA006660b6m: Min Higher Education UkSSR, Kiev Order of Lenin Polytechnic
?4"Jwn Inat
DOCURM Date) Place: 195(a. Kiev
Source: Knizhnaya Letopis', No 45, 1956
UM/Mathematics - Inequalities, Jul/Aug 52
Integral
"A General Theorem Governing the Existence of So-
lutions of Differential Equations Which Is Con-
nected With a Consid6ration of Integral Inequalities,"
Te. Te. Viktorovskiy, Kiev
"Natemat Sbor" Vol XX)a (73), No 1, ~p 27-33
Under conditions somewhat mo re &neral than thosc of
Caratheodory, demonstrates an existence theorem vhich
leads- to the =ax and =in integrals of the eq y I = f
(x,y) on tbe basis' of a substitution of (strict)
differeetial inequalities of Chaplygin and Perron by
29=72~_
(vesk-ewd) integrals. Until now, in the author's
opinion, no one had succeeded in extending the
method used by Perron to demonstrate existence of
soins of y I - f (x,y) (essentially the'1~us a ian
method devised by Chaplygin for approx integration)
to the more general case of "Caratheodory's con-
ditions." Submitted 4 Jan 52.
_______22OT72
VIK-r
Mathema,tical'keviews
Vol-15 No. 3
March 1954
Analysis
Viktorovsk--iILE. 19. On a generaUzation of the concept of
intezrai ct,'We; for a discofiflnuous field of directions.Z_
Doklady Akad. Nauk SSSR (N.S.) 89, 593-596 (1953).
(Russian)
Let fi(x,yi, ---,y.) be measurable functions in an
(n+l)-dimensional region G, such that
Af (.V) - Sul) M, sup jfj(.V, Y1,
is surnmable. A gencraliz"e'd solution of the systern yi'=fj
through the initial point (xo, y1o, - - -, y.o) t G is a systern
of n absolutely continuous functions u,(.v) defined in X:
_IXG, Xo+al, ui(xo) =Yio, satisfying the followingcondition:
Viktorovskiit E- E- (2)
given e>0 and any se of n -measure U, there OF
P1 measurable functions ii, (x) such that in X:
i 4'i
(1) MX, *if. - *0
are summable;
lui(x) -*q(X) I