SCIENTIFIC ABSTRACT VIKTOROVA, YE.A. - VIKULINA, E.K.

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CIA-RDP86-00513R001859810005-4
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November 2, 2016
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September 1, 2001
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December 31, 1967
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SCIENTIFIC ABSTRACT
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S/081/61/000/019/037/085 Contact catalytic transformation... B110/B1O1 oxide catalyst. The following data are given: reaction temperature in OC, yields of "H 07 111, o-(CH 3)2 C6H4- 1,2-dimethyl cyclohexane, 1,2-di- =ethyl-4-cyclohexanol, and 1,2-dimethyl 4-cyclohexanone: 150, traces, 1.8, 25, 29, 34.3, 7; 200, traces, 3.3, 17, 62.1, - -; 250 2.4, 22.3, 30.5, Reaction of Ib with (CH ) C--CHCH (Iva~ or (CH') CHCH=CH 3 2 3 3 2 2 (IVb) (at 1500C and 2 - 3 atm on 20% ZnCl 2180% Al203catalyst, the amount of the catalyst used being 10% of the weight of the reagents) yielded 40% 3-CH 3- 6-tert -C5H11 Ar (V) (and some 3-CH 3- 4-tert-C5 H11 Ar) (Ar - C 6H3OH). One isomer only, 4-CH 3- 2-tert-C5H11 Ar (VI), was obtained in 40% yield from Ic with IVa, IVb, or CH 20 C(CH 3)C2H5' In all experiments, the initial iso-l", 5H10 dimerized, forming C 10 H20' Under the same reaction conditions, 1-pentene and 2-pentene yielded 70% alkyl cresols. Reaction of Ic with 1-pentene yielded 2-HO-3-CH 3C 6H3CH(CH3)C3H 7in 65% yield. The data given for the alkylation products (obtained with C 5H10 and Ib or Ic) are b.~. in 0C/mm Hg, n 20 d20 , M.P. in 0C, and the m.p. of the Card 2 4 D? 4 S/081/61/000/019/037/085 Contact catalytic transformation... B110/B101 corresponding aryl glycolic acid in OC; V, 94 - 96/3, 142 - 143; VI, 125 - 125-5/9, -, -, 26-5 - 27, 126-5 3-CH3- 6-CH(CH3)(C3H7)Ar, 103 - 104/3, 1-5190, 0.9622, 3-CH3 -6-CH(C 2H5)2 Ar, 138 - 139/8, 1-5187, 0-9585, -, 147 - 148/8, 1-5148, 0.9693, -, 101. From Ib and piparylene 1-5193, 0.9626, 1271 981 3-CH 3-4-CH(C2H 5 2Ar, (20% ZnC12 on A1203 ), 70~ of an alkylate was obtained, which consisted of 3-CH 3-6-CH(CH3)-CH-ClICH 3Ar (VII) and 3-CH 3-4-CH(CH )CH=CHCH Ar (VIII) (90%), 3 3 and of 2,497-trimethyl chroma'n and 3~6-dimethy~-2-ethyl coumaran (10%). Reaotion of Ib with oyclopentadi ane0at 25 - 30 C yielded the dimer of the initial cyclopentadtene, and at go C 293-cyclopent6n-7-methyl-2,3-dihydro- benzofuran (IX). With H 3P04 at 0 C' 80% 3-methyl-6-(Oyolopenten-2-yl)phenoi (X) and 3-methyl-41(cyclopentene-2-.yl)pherLol (XI) were obtained. The alkylation products,obtained fr8m Ib by tre8tme~S with piperylene are characterized by their b.p. in C/mm. Hg' d4 and by the m.p. of the corresponding aryl glycolic acid in Ct VII, 136 137/9, 1-5312, 0-9847, Card 3/4 5/081/61/000/019/037/085 Contact catalytic transformation... BI1O/B1OI 108 - 108-5; VIII, 147 - 147-5/7, 1-5360, 0-9884, 118 - 118-5. The alkylation prodtacts obtained fr8m IIb by trlatme~8 with cycl8pentadiene are characterized by their b.p. in C/mm Hg, 0 9 ' d4_v m.p. in Cp and m.p. of the corresponding aryl glycolic acid in CS 118 120/3, -9 -v 69 - 70P 111 -'1121 XI, 129 - 132/3, 1-5655, 1.0666, 129; 3-methyl-6-cyclopentyl phenol, 113 - 115/3, 1-5495, 1.0087, -9 101 102; 3-methyl-4-cYolopentyl phenol, 123 - 195/3, 1-5549, 1.0498, -, 101 107; IX, 138 - 140, 1.5474, 1.0608, LAbstracter's note: Complete translation. Card 4/4 SHUYKIN, N.1,; VIKTOROVA, Ye*A.; POKROVSKAYAY I.Ye. Alkylation of phenols by compoundo with mixed functions. Report 1: Alkenylation of m-cresol with allyl alcohol* Izv#AH SSSR,Otd.khim.nauk no.6:1094,1098 Je 161. (KM l4j6) 1. Moskovskiy gosudarstvennyy universitet im. M.V.Lomonosoia. (Cresol) (Allyl alcohol) - N.I.; POPOVA, G.V. Contact calmlyluic cohv-rsions of ;hn-nols. Part 5: A - a - r' - lky3- tion of Y--cresol by Fiperylene. Vest. Mio~:k. im. Ser. 2: M-hir. 1,; nc.!.: 62-65 160. (I:I~A :L[,-2) 1. Kafedra khil!iii nefti Moskovs',oco wniversiteta. (Croool) (Eperylane) TMNTIYZV, A.P.;.TIKTOROVA, Ye.A.; TISELISON, B.M.; KOST, A.N.; YBRSHDV, T. . Inner complex compounds an contact insecticides. Zhur.ob. kbia. 30 no-7:2422-2427 JI 160. (MI" 11:7) 1. Moskovskiy gosudarstvennyy universitet. (Complex compounds) (Insecticides) YJJ~T~VA ~YA.; SHUYKIK, U.I.; POLYANSKAYA, B.I. Cycloalkanylation of phenol by 1,3-CYcloboxadiene. Izv. AU SSSR. Otd. khim. nauk no.11:2048-2049 N 060. (RU 13.11) 1. Mookovskiy gosudarstvannyy universitet im.M.Y.Lomonosova. (Cyclobezadiene) (Phenols) (Alkenylation) 8/074/60/029/010/002/004 13013/B075 AUTHORS: Shuykin, N. I, and Viktorova, Ye. A. TITLE: Catalytic Synthesis of Alkyl Phenols. Al PERIODICAL: Uopekhi khimil, 1960, Vol. 29, No. 10, pp. 1229-1259 TEXT: The authors give a survey of studies made on the catalytic synthesis of alkyl phenols. The available publications were systematized according to the character of the alkylating substances. Papers are mentioned re.. ferring to some catalysts, on the character of which the structure and the ratio of alkylation products are dependent. The subject of the first chapter is the alkylation of phenols with unsaturated hydrocarbons. The application of the following catalystslis described: Acids as alkylation catalysts (Refs. 32-108); metal chlorid'es in alkylating phenols with alkenes (Refs. 63, 109-128); borofluoride (Refs. 129-168). Data obtained show that sulfuric acid is the most freqrently used catalyst. It is pre- ferred due to its accessibility and its sufficiently high yields of alkyl phenols. Also alkylation in the presence of resin - ion exchangers seems to be promising. The use of borofluoride and of some of its molecular com- Card 1/3 Catalytic Synthesis of Alkyl Phenols S/074/60/029/010/002/004 B013/BO75 pounds requires further study~ The use of aluminum phenoxide seems to open new possibilities in the synthesis of o-alkyl phenols. The second chapter deals with the alkylation of phenols with alcohols (Refs. 36, 65, 80~ 81, 99, 173-277). As was proved by the mentioned data, the !jtruc-- ture and the yield of alkyl phonols are dependont on the reaction conditions. These, in turn, depend on the structure of the alcohols employed, on the temperature, as well as on the nature of the catalyst. In some cases, phase stateand pressure factor play an essential part, In spite of the high yields, alkylation of pbenols with alcohols is rather inexpedient for industrial purposes; in laboratory practice, however, it offers a number )f advantages. In the third chapter,alkylation of phenols with al- kyl halogens is discussel (Refs. 1091, 278-335).. Data available cn alkyla- tion with alkyl halogens show that the reaction in the presence of aluminum chloride is' most tForoukhly Investigated. However, It has to be taken into consideration that the isomerization of the radical entering into the phenol molecule does not always take place. Alkylation with ternary alkyl halogens in the presence of halogen hydracid is extremely easy, especial. 1y if the alkyl halogen forms during the synthesis. By this means, the possibility of using more easily accessible alkenes is given. Card 2/3 Catalytic Synthesis of Alkyl Phenols 3/074/6o/029/010/002/004 BO13/BO75 Yu. G. Mamedaliyev, V. N. Ipatlyev, V. I. Isagulyants, A. V. Topchiyev, I.Tsukervanik, V. Tambovtseva, B. M. Dubinin, A. Ye. Chichibabin, A. S. Abdurasuleva, N. G. Sidorova, Z. N. Nazarova, I. N. Samsonova, Z. P, Aleksandrova, A. B. Kuchkarev, and P. P. Bagryantseva are mentioned. There are 335 references: 40 Soviet, 166 US, I Austrian, 1 Belgian, 29 British, 1 Canadian, I Czechoslovakian, 1 Danish, I Dutch, 20 French, 38 German, 3 Italian, I Rumanian, 6 Japanese.and I Swiss. ASSOCIATION: Khimichaskiy fakulltet MOU im. M. V. Lomonoseva (Department of Chemistry of the Moscow State University imeni M. V. Lomonosov) Card 3/3 ACCF.5SIQNNR4- AP4015308 S/0280164/0001001/019610201 AUTHOR; Viktorov, Ye. D. (Leningrad) TITLE: Stabilizing a-control system by introducing & nonline4r correction SOURCE: AN SSSR. Izvestiya. Tekhnicheskaya kibernetika, no. 1. 1964. 196-201 JOPIC TAGS; automatic control, nonlinear o~orrectlon automatic control, alance 'adaptive filter correction, adaptive filter automatic control, harmonic b I method !A.BSTRACT: The control of a plant in coneddered whose transfer function has this ?form: S(P) - C (p) where &J, and Q. are real and proximate,, C (p) does not contain the co effi c lc nts of the fo r m (p I + (oil) I (p' + (41) with Wj a ufficie ntly clos a to i &jj,. The method of "frozen factors" is used in the investigation. a is proven that the stability cannot be ensured by any line" controller with constant !CWC"/2 I I - . - - . I . .-I 'ACCESSION NR: AP4015308 :parameters. Hence, an adaptive filter is suggested; its introduction results in 4 : stable self-oscillations. The harmonic balance method is used to investigate the 'behavior of the filter. The nonlinear correction in the controller can stabilize the above plant if the range of variation of W,, is known; the controller can be selected in such a way that I( to.) retains Its sign for all possible values of WL; here, I(co) is the imaginary part of K(ica) C(Lj) and X(p) is the transfer function of the controller. Orig. art. has: 3 f igureg and 37 forinulas. ASSOCIATION: none MMMITTED: 07j'&n63 IP'SUB CODE:' CG, IE DATE ACQ: 1ZMar64 NO REF SO'r. 002 ENCL: 00 OTHM 001 Card 2 / Z Slor /60/009/003/013/019/XX KON191 AUTHORS: Viktorova, Ye.N., ZhmyreVa, I.A.9_Kolobkov, V.P., and Saganenko5 A.A. TITLE: An Investigation of the Duration of Phosphorescence in Solutions of Organic Compoundsat --196 OC PERIODICAL: Optika i spektroskopiya, 1960, V~l 9) No 3, pp 349-3~2- TEXT: The effect of various external and internal molecular factors on the probability (r) of transitions of excited mole,-'.ales to a metastable state is related to the ratio (8) of the quantum yields of phosphorescence and fluorescence at low temperatures (e.g. -180 or -196 OC). For long wavelength phosphorescenoe + q, P e- where p is the probability of a fluorescent transition, It is the probability of emission of radiation on transition from the metastable state to the ground state, and q2 Is the probabilitj of cLuenching in the metastable state. The authors studied the duration of phosphor es cenc; e (Tphos.) in order to obtain info rma tio r). on enching in the metastable state at -.196 OC and to find to what Caraul/3 An Investigation of of Organic Compounds extent a change of the probability r. and 6 at The compounds dealt s/o51/6o/oo9/OO3/O13/O19/XX 9201/El9l the Duration of Phosphorescence in Solutions at --196 Oc 6 due to an external medium is reflected in Tables 1 and 2 list the values of -tphos -196 OC for 1-7 compounds in ZI solventa. with in Table 1 ares, (I) 3-acetylamino-N-methylph+,,halimideI (II) 4-acetylamino-N-methylphthalimide, (III) 316-diacetylamino-N-methylphthal,t~ideI (IV) 3-methylacety'Lamino-6-methylphthalimide. The compounds listed In Table 2 arw M 3-methylacetylamino-N-mothylphthallmideI M) 4--mothylacetylamino-N-methylphthal.imide, MI) 3-hydroxy-N-methyl.phthalim:Lde, (VIII) Li--hydroxy-N-.methylphthalimide, UX) 3-amino-6-nitro-N--methyl.phthal..imideI W 3-dimethylamino-(,-.-methylacetylamino-.N-methylphthalimide,, (XI) 3-dimethylamino-6-a(,-etylamino-N.-methyl.phtha.Limide, Card 2/.3 S/051/60/009/003/013/019/XX H201/E191 An Investigation of the Duration of Phosphorescence in Solutions of Organic Compounds at -196 OC (XII) 3-diphenylamino-N-mothylphthalimlde, (Xiii anthranilic acid, (XM paradimethylaminobenzoic acid, (XV) cL-naphthol, (XVI) 0-naphtholl (XVII) 0-naphthylamine. It was found that a change In the ratio 6 was a fairly accurate measure of a change in the probability of transitions of excited molecules to metastable states when the surrounding medium was altered. Acknowledgements are made to B.Ya. Sveshnikov and P.I. Kudryashov for loan of the apparatu-s--u-s-eU-Fo -measure the duration of pho-sphorescence. There are 2 tables and 21 references: 16 Soviet and 5 English. SUBMITTED: December 22, 1959 Card 3/3 VNTOROVA, lej. Certaln regularities In the nature of the quantum yield variation as related to the position of the fluorescence bando for a mmber of organic compounds. Opt. i spektr,, 10 tioW79-281 P 161. (MIRA 24:2) (Fluorescence) VIMPGROVA, Y0.1j.; Z1.1 T';Sj~rj, -,I.V. I, . Relaf.lon of nonradlixLilve deac".1va Lion to tl~c cimracterist-Ics oi* complex organic com-ound 1. Dokll. 91 S-""'R 1617, no.5:1033-10'6 D 165. op ('~',RA 19:1) 1. Subn'tted Anril 22, 1965. 7 60[UMj?C,,& opa: e -)"j- Zell 01je ,is On bLtwg 036 ell4racterlatl.en the -Probabljlt SOURCP Of AIT Y Of emisslo., Dokl Orgao"o cQVour~s '009 deactirat ad"* "'- -16.5.. J30. .5 Ion cOP'POund e3calted tate the Ansfiiial,9 grOuJid &t to -196.5., .10 9 Spectrum 33_.1036 A a 0 1 MAlber 01. 'a -P"r. 702COU"8013 Of 'Values 1, "'1048 sub.t,,,, or qufttum Values PrObab,11tle, f . JXI e14 aft ,,,,Cea P In a -varle emISSI0,,,, 0 chemIca.1 Of SOlVent as deact, tad acc0l-dIg ty a at C"00C, Vbere to the Vatlons exelted the Is aw of (q + M~u~tt'. . Pl*obab e in -leve.1 401*ftles ill luty Of the .P and - 7 'value a oxes"a.. )/-r a Is Is the ftde by state'rocess Of direct Vas Ob a effte durat 18 the eal be Of f"ftZlOa of the ProbablUty881022lesa ccqr rved between exe Of tr Mrsloll the lted ausfer to Of Card .1/,o BQuan 4w 'llus state 'value t4FA trste~ by 7b, a Metas tluor~~ceace and curves. C?Rwarle A dire(It Of The absolute Ion Ylelds Vere, Co,d L 1%).7-66 --j~cc Nn, '06W2417 measured according to a method., previously described by the authors (Optika i spectro- skopiya, 1. 5&$ 1956). using a FW-38 pbotonaltiplier in the capacity or a received of radiation. Tvas determined an a phase fluorometer at the W-titute or.1102M I-a-k2. Bioloor 9t tJ* AN SM, in L. A. TymnWls laboratory. The autbors conclude that the relation between the value of the barrier and the spectral characteristics in determined by the fact that both are functions of one and the same variable, the change of vhich characterizes the changes in the relative distribution of potential surfaces. - The authors thank L. A. Tvaerman for the possibility of conducting Wasure- Monte on the f1wrometer and A. N. Surova for carrying out the Measurements. Orlgo art- Me-. 7 fornibm and 4 figures. MM Cobn:', 07, WM. WM: OgApr 65/, OR-M MW: OU7/ 'OM 7W: OM Card 2/2"4Z e FIWP(J) RM -3700-5m6b---SWT(W)Z ACC NRi Ap6oiS593 SOURCE CODEs UR/0379/66/002/002/0227/0233 AUTHORt Iktorava, Ye. N.; Zelinskiy V. V. ORGI State 00tical Institute im. S. 1. Vivilovs Leningrad (Gosudarstvenrqy optiches- kiy institut) i TITLEI Study of the relationship between the probabilities of processes of nonradi- ative deactivation and the spectral characteristics of complex organic com- SOURCES Teoreticheskays. i eksperimentalInaya khimiya, v. 29 no. 2p 1966, 227-233 TOPIC TAGS1 nonradiative transitionp fluorescence spectrumij transition probability, ABSWCT: Tell probabilities of nonradiative deactivation of excited molecules on the singlet level in the fluorescence of a series of complex organic compounds were com- pared with the spectral charaotoriatics in various solvents at 206C. Values of these probabilities were calculated from the formula q t (q Ir where q is the probablUty of the process of diroct nonradiative conversion of excited 2 L 01274-66 EWT(1)/E'NT(m)/EPF(C)/EWP(J)/EWA(c) ACCESSIM NRs AP5021D783 ,21 AUTHCRs Viktorova, Ye* N.1 Zelinskiy, V. V. TITLEt Investigation of the,fluoreSc2ncjLyield (Reports,13th Conference on Luminesceno held in 1964] qq) eo S5 IJP(c)/RPL JN/" UR/0048/65/029/008/1278/1283 AR of some nitro-compound solutions Khar1kov 25 June to 1 July SOURCEt AN SSSR. Izvestiya, Seriya fizicheskaya, v. 291, no. 8. 19650 1278-1283 TOPIC TAGSs luminescence, solution propertyl, organic nitro compoundq lumin- escence spectrum, electron transition, activatTon W-energy ABSTRACTs The fluorescence yields of the following nitro-compounos in 14 different solvents were measured at ~OOC by a method that has been described elsewhere (V. V. Zelinskly and V. P. Kolobkovv Optika I spektroskopiyat I, 560p 1956): 4-amino-41!-nitrostilbene.1 4-dimethylamino-4'nitrostilbenot 41-amincl.- 41-nkrodiphenyly 4-dimethylamino-41-:hitrodiphenylg 4-dimethylaminobenzal-41- nitroanaline, metanitroanaline, meta-ni-tromethylanaline, meta-nitrodimethy. lanallne, meta-nitrodiphanylamine, and 5-nitro-l-aminonaphthaline. When the fluorescence yields were plotted against the frequency of the maximum of the fluorescence spectrum, the points for a single phosphor (in different solvents) Card 1/2 L 01274-66 ACCESSION NR: AP5020783 lay on a smooth curve which had a maxi==. The position and height of the maxim= varied from compound to compound. When the fluorescence yields were plotted against the Stokes shift, many points from all the phosphors lay close to a single common curve. The points that fell off this curve were those for solutions on the descending portion of the curve of yield versus frequency of the luminescence band. Similar results were obtained by plotting the proba- bility for radiationless deactivation against the Stokes shifts the deacti- vation probability was an exponential function of the Stokes shift. All the investigated phosphors in all the solvents had narrow luminescence bands of approximately the same width, and they all had approximately the same electron transition frequency. It is suggested that there is an activation energy for radiationless conversion which may be related to the electron transition frequency and the width of the luminescene spectrum, but which is largely inde- pendent of chemical composition as such. Orig. art. hass 3 formulas and 4 figures. ASSOCIATION: 00 SUBMITTED: 00 ENCL: 00 SUB CODEt GCj OP Cra-')40 REF SOV: 017 OTHER: 008 VIKTOROVA, Ye.N.; GOITUN, I.A. Fluorescent characteristics of' the --crien of rhodamino dyes. Zhur.fiz.~Jlim- 39 no.11:264'3-261,9 11 165. (!~'IRA 18:12) S/051/60/009/004/031/031+ B201/B191 AUTHORS: Viktogoa I Ye.N,, Kochemirovskiy. A.B., -Xfa-snitskaYi-,-W-.Mr;, and Reznikova, I.I. TITLE: New Examples of Pronounced Dependence of the Fluorescence Yield on Position in the Luminescence-, Spectrum p.I ON PERIODICAL: Optika I spektroskoplya2 1960, Vol 9, No 1+, pp 544-546 TEXT: Zelinskiy et al. (Ref 1) showed that in five phthalimide derivatives.there was.a.regular relationship between the absolute quantum yield of fluorescence (q) at 20 OC in various solvents and the frequency of the fluorescence spectrum maximum The present paper reports a similar dependence of q on in dimethylnaphtharhodine(dimetilnafteyrodin) (I), 2-aminoacridine (II) and cyclohexylaminomalainimide (III) at 20 OC (a figure on p 545). The fluorescence yields were measured using a.technique described earlier (Ref 10. The values of -0 (in lo3 cm-1) represent solutions in various solvents, such as ethyl alcohol, cyclohexanol. cyclohexanone2 and so on. For each compound (I, II and III) q'= f(,,)) was in the form of Card 1/2 S/051/60/009/004/031/034 9201/E191 Now Examples.of Pronounced Dependence of the Fluorescence Yield on Position in the Luminescence Spectrum suggesting two different processes of de-activation in the two groups of solvents represented by the two branches of A . The fluorescence yield is denoted by qpt and the fluorescence maximum by %)1;x in the figure on p 545; numbera in the figure (1-20) represent various solvents.. Acknowledgement is made to V.V. Zelinskiy who directed this work. There are I fl-gure and 7 references: 6 Soviet and 1 English. SUBMITTED: May 20, 1960 Card- 212- VIKTOROVA. Te.N. ; KOCHEMIROVSKIY. A.S.; KRUNITSKATA, N.D.; REZNIKOVA. I.I. New examples of the pronounced dependence of the f luoreecence yield on the position of the emission spectrum. Opt.i spektr. 9 no.4: 544-546 0 '60. (MMA 13;11) (Fluorescence) L 16128-66 1-mr, ( T-z)lwe(j) ACC NR: AP6004179 SOURCE CODE: Ult/007f)/66/0.10/0f)1/0094/0099 AUTHOBI-VMorova Ye. N. , Z a ko, N. F. Nczn, y ORG: none 13 TITLE: Effect of phenyl groups on the fluorescence yield of aminophthallmides~ SOURCE: Zhurnal fizicheskoy khimii, v. 40, no. 1, 1966, 94-99 TOPIC TAGS: fluorescence, quantum yield c)r ~Lvs'(! ABSTRACT: The effect of phenyl groups introduced Into the amino group of 4-amIno-N- methylphthalimide, 3-amino-N-methylphthalimide, 3-(Iiphenylamino-N-methylphtlialimide, 4-dipheiiylamino-N-metliylphthalimide, and 4- monophenyl amino-N-m ethyl pht hal imide on the fluorescence of these compounds was studied by determining the absorption spectra and quantum fluorescence yields In varlou.,i solvents at 20C, Tho e1ectron ripectra showed the presence of conjugation between the elec tron- acceptor phenyl group intrcx1twed into the amino group and the phthallmide ring, as Indicated ~v asubstantial bathochromic shift. Curves of the following relationships were plotted: V max versus solvent at 20C, quanf~m fluorescenco yields versus position of corresponding fluorescence spectra, and quantum fluorescence yields versus corresponding Stokes shifts. Orig. art. has: 3 figures. aCard 1/2 UDC: 543. 42 L 16128-66 ACC NR: AP6004179 SUB CODE: 07,N/ SUBM DATE: 23Sep64 ORIG REF: 013 OTH REF: 005 Card 212 ACC NR9 AT6000496 SOURCE CODE: Ult/0000/65/000/000/0266/0269 AUTHOR: Brekhovskikh, S. M ; Vfktorova Yu. N.; Zpientsov, V._V.; Zelentsova S. A. ORG: none TITLE: Effect of the chemical nature of cortalti elements on the radlation-optical re Istance of irradiated glass~,qj I r, Q I S E: VsesojTznoye soveshchan!vc Po st0doobramornu sostovanivu. 4 Leningqto, 1964. manlya, Leningrad, lz(l-vo Nauka, 1965, 266-269 TOPIC TAGS: optic property, glass property, gamma irradiation ABSTRACT: Ile dependence of the radiatton-optical resistance on the position of a variable element In the periodic system is studied in glasses of the system 4SiO2 * Na20 - 0.5ATeO (or 0. 25 Me20). As a rule two absorption. bands, at 400 - 4 50 and 600 - 650 mp, appear in the spectra as a result of y-radiation. The first band can bo ascribed to the F-center which represents a quasi-ion (Nle+ + _j]. The intensity of this band Is directly related to the position of Me In the periodic system. Ile smaller the electronegativity of Me, the greater the probability of the localization of a migrating secondary electron near it and the more intense Card 1/2 ACC NR, AT6000 496 the absorption bawl, All glasses containing elements of groups I and 11 as the third component have similar spectra, with smaller absorption at 400 rnu for glasses with Mg and Ca. The absorption in the 600 mp region Indicates, in all probability, the presence In the glass of oxygen vacancies and the formation of free oxygen atoms. Elements of group III differ appreciably more chemically than those of groups I and 11; therefore their spectra substantially differ from one another. For elements of group IV an increase of radiation -optical resistance is observed with a decrease of Ion radius only for the first three elements. For glasses containing clementj of group V the radiation-optical resistance increases by a factor of 3.3 on replacing SrO(4dO) by Zr02(4d2) and Nb205 (40), which is associated with a decrease of the ton radius from Sr to Nb. Glasses containing elements of group V1 are governed by the same rule. Orig. art. has: 3 figures. SUB CODE: 11, 18 SU13M DATE: 22May65 / ORIG REF. 002/ OTH REF: 001 2/2 I~t-~Illrl'r AtffliOP; Bre kh,.vski ki-,S 7-n 4,', V-I Sh_- No= EM MFM TI TL E Op~ I cr:Ll rad i it. i ~n t ~~b i 11 f 'i ftr~. 7 1,- F, i r r ~Ld i -it -jIga-=,t - r vq], i --is r Ie r '11, t; C' SOURCE: AN SSSF. Dakkady, v. '163, no . 1, 1965 , i 614- 1 6S TOPIC TAGS: optical radiail',ton stabil3ty, quartz glass, color center, F center, temperature dependence ! iAB~STRAC`T. The effect of temperature on the radiation-induced discoloration of Quar_IZ Iglasses KI and KRL has been studied in the virtual abssenr7e of literpture rn this :sUL,ject. The optical raiiatinn stability of the qlfuss stljl_`-d at room temperature. The rar',; cf the 11,zit, traLrmisFiori of the -irrarliate; P..~asr, to the initial tr,54~smiss::I.n ;r. tl'~- i %+A em r' vas determined fut p T~ETF. T tab Ii:,-'2_ -:J-I.Iubt 6t a - tffij: OFtS V i er closure r e 4t ures;: The- transmission _10 -th %h% '86C * 1)0 v takU -,but ofthe Devar, . a "-erce eatraena7--IrraAl-a -at--roo-m-, ite weran w empAr- were black-violet, and lthovne irradialc-d n~ 90K wr-re 11glit-emoky. ca--f-cf- I A NR AP5018091* [ACCI~;SIOH - The observed dependence of the discoloration on the temperature of irradiation can he explained by the shift of the dynamic equilibrium between the forn-ed F-:nd decaying T !color centers. It is assuw--a that the number of F--enters formed de-r,~ases vi'h de-r,-~!i.slng ~Pmperqture, whi1c. the rad'a~ :,-)n je.,'ri-fion !~*' th-z;,, r~-' depend -~ri the temperature. Phe , Fc after low doses (if irradlRti-)n -an b~- explained by a decrease in the effect of radiation annea-ling due to the iiminishing ,number (;f color centers and an increase i-n their-stability. Orig. art,. has: j2 tables, 1ASSOCIATION: none SUB CODE: Mr, N P iHO REF SOV: 001 OT"-R. 008 ATT) PPPSS-. 4056 Card P/ 4 Z-,, 5~ A C C E~,- 3 10 IRA P 0 PS at 1,00m tempemiture rradiation dose, r 'at COGO rd KI glass *T,k PC K R 1, g1 as 9 T,% PC n 1 n 2 92 04 104 9 (112 0 I L,2 92 10, 0 0 92 1 7, Light traimr-iii.7sion me~q~irpa on Card 3/4 MOSURE: 02 L 62-167-65 Ell r ~ACCE;SSIoN NFt:----A-P50l6691 Mperat-Ureiv- dose 10 r doge 10 4r KI 91 so, dose 106r YRL 91 rl,r.(Ii qtlon VI i7,llt % temperature# -- P Pr T, % T, OK 91 90 87 0.95 68 0 -'r 14 0.95 21 0.2 91 200 C12 0.02 BREKHOVSKIKH) S. M.; VIKTOROVA., Yu. N.; Z-VIENTSOV., V. V.; ZELENTSOVA., S. A. "Effect of some oxides on silicon-oxygen sceleton of oxygeneous glasses." report submitted for 4th '11-Union Conf on Structure of Glass,, Leningrad, 16-21 mar 64. S/058/63/000/001/067/120 A16o/Aioi AUTHORS: Ryabov, V. A., Nayman, 1. M., Borleova, 1. 1., Grinevetakeyap 86 N.0 Viktorova, Yu. N., 0ayevaya, L. A. TITLE: New light filters for the proteotion of the eyes during produeUon PERIODICAL: Referativnyy zhurnal, Fizika, no. 1, 1963, 83, abstract ID6W ("Steklo. Byul. Goa. n.-i. in-ta atekla", no. 1 (110), 1961, 72 81) T M A desoription is given of the technological process of producing neutral and selective light filters designed mainly for controlling metallurgical processes. The light filters are made by applying oxide films from metal salt* of the 4, 5 and 6th period of the periodic system of elements by the aerosolA method. Presented are the characteristics of the light filters with oxide lapre from cobalt, iron.,lead + antimony and lead + antimony + iron. Yu. Kutev [Abstracter's note: Complete translation) Card 1/1 VIKTOROVIC, D. Jamjicp T.; Viktoroyle, 2. "A Now Method For The Qualitative Separation of Basic Sulfides of the Second Analytical Group." p. 301 (GuSITIK, Vol. 18P No. 5o 1953, Beograd.) jmjlcm T. SO: '140atwx-LI-st of Easj gyj2pea AcceissionA, Vol. 3, No. 3,, Library of Congress March 19542 Uncl. KR&SIC, Sreten; VIXTOROVIC. Z.-, STOJANOVIC. D. Oas-stage colectony with ilootransvtrsootony for carcinoma of the right colon. Srpski arh. celok. Isk. 83 no.12:1481-1483 Doe 55. 1. Hirursko odelenjo Opste bolulce u Iragujevcu. Sef: prim. dr. Sreten Krasic. (COWN, neoplasms Ourg. colectomy with Ilmotransversostomy, one-stage. (Ser)) S/149/63/00,0/001/OOZ/008 A006IA101 AUTHORS: Listovskiy, D. I.,.Viktorovioh, 0. S., Malevskiy, A. Yu. TITLE: On the mechanism of interaction between the components of the Fe-Ni-O system in the solid phases 'PERIODICALs Izvestiya vysshikh uchebnykh tavedenly, Tavetnaya metallurglya, no. 1, 1963, 58 - 66 TEXT: In previous inve 'stigations the structure of the zone, formed between NiO and its reduction products and the part of oxygen diffusion was not revealed. The authors attempt to determine the basic features in the interac- tion of components-in the Fe-Ni-O slatem. Cylindrical specimens, 1.8 mm in diameter, were produced from pure iron and iron-nickel alloys. They we're pressed into chemically pure nickel oxide. The briquets obtained were quenched in a nitrogen filled closed space, at 1,0000C for 5 h. The chemical composition of the cylinders and the extension of the reaction zones is given in a table. The process of NiO reduction by iron was studied. The formation of nickel atoms takes place as a result of transition of Fe2+ ions into Fe3+. As a result of Card 1/4 S/149/63/000/001/00Z/008 On the mechanism.of interaction... A006/A101 Fe3+ and Ni2+ diffusion in opposite directions, a nickel ferrite layer is formed on the interface with NiO. Fe2+ and electron diffusion to a spinel layer causes the reduction of Ni-ions. These processes take place simultaneously. As a re- sult of reaction diffusion of metal ions and electrons in contact with wuestite, spinel must be formed which does not contain nickel (magnetite). In contact with NiO spinel may be present which does not contain Fe2+, i.e. nickel ferrite. In such a manner N12+ reduction by Fe2+ ions proceeds during the contrary dif- fusion of cations of both metals in the spinel layer, indicating the presence in the latter of metal phase inclusions. The thickness of the spinel layer is determined by the rate of iron transfer to its internal surface, The driving force in oxygen diffusion is the gradient of its chemical potential, which is supported over the layer of interaction products in the direction from NiO to the metallic cylinder. The oxygen can diffuse in electroneutral state over the ipterstices of the oxide phase lattice or pores, and also consecutively from one sublattioe to another one in the form of a negatively charged ion, The oxygen diffuses also through the metal phase. The penetration of oxygen into the depth of the alloy, accompanied by the formation of iron oxides along the grain boun- daries, and inside the grains, excludes the possibility of Ni diffusion, but Card 2/4 S/149/63/000/001/00P,/008 On the mechanism of Interaction... A006IA101 a~.-celerates Iron transfer. The general rate of oxidation Is increased in com- parison to the rate that could be expected when assuming that the process must be exclusively limited by mutual iron and nickel diffusion in the metallic phase. Investigating the effect of the composition of the alloy upon the composition of oxide phases and the structure of zones, it was established that the composition of the iniii~l fetal determines that of the oxides formed during their contact with the metal, and the structure of the internal reaction zone. If iron pre- vails in the initial alloy, wuestite formed in the internal reaction zone breaks the metal phase into finest metal particles. At a higher Ni content the wuestite particles in the alloy crystals ronain dissociated, but each grain is enveloped by an oxide film. Processes in the internal reaction zone are of a more general nature than those in the external reaction zone, where the structure of Indivi- dual layer depends little upon the composition of the initial alloy. T6 mech- anism of the former-processes does not depend upon the form of introducing the oxygen, and is also correct for oxidation of pure Iron and selective iron oxida- tion of Fe-Ni alloys by a gaseous medium. There are 2 figures aro- I table. ASSOCIATIONs MoBkovskiy institut stall I oplavov (Moscow Institute of Stool and Alloys) Kafedra metallurgii radioaktivnykh motallov I komplokanogo ispolizovaniya polimetallicheskikh rud (Department of Metallurgy of Radioactive Metals and the Complex Utilization of PolymetaWo Ores) C ard 3/4 s/149/63/0w/0DI/00Z/OO8 On the mechani3m of interaction... AO06/AIOI SUEMITTEDs October 1, 1962 Tabla- COMPOSVIon f cylinders,- EXtension of reaction zonesAu Specimen external Fe Ni internal viuastite spinel total layer laver a 100.0 - 100 320 10 430 b 78.9 21.1 170 190 15 375 c 60.9 '39.1 180 110 20 310 d .44.4 55.6 14o 60 25 225 e 22.9 77.1 25 - 40 65 Card 4/4 LISOVSKIY, D.I.; MALEVSKrY, A.Yu.; -UT WNW! mwm~ Interaction of the components of the system Fe - Ni - 0 in solid phases. Izv. vys. ucheb. zave; tavet* met. 5 no.6: 50-56 162. (MIRA 16:6) 1. Moskovukiy institut st&li i splavov, kafedra metallurgii komplakenogo i lizovaniya polimetal2icheskikh rud. 978tem,(Chemistry)) ~Phase rule and equi3ibrium) VIXTOROVICH, G.S.; LISOVSKIYj D.I.; MALEVSKIY, A.Yu. Studying the interaction of nickel oxide with iron in the solid phase. 10r. vys. ucheb, zav.; tavot. met. 5 no.406-94 162. (MM 160) 1. Moskovskiy institut stali, kafedra metallurgii i fisichaskoy khiadi tevetuykh metallov. (Nickel oxide) (Iron oxide) (Phase rule and equilibrium) VIKTOROVICH~ 108 Second year of new PDA arrangements. Neftian4k 6 no.717-8 n 161. (MM 14:7) (petrole= mini ) 1-1 VIKTOROVICH) Ye. flew working conditions at the Ukhta Combine. Reftianik 5 ne,.A.-26-27 Ag 160. (MIRA -14:8) (UkhU "glen . )."~~Jk%ffitvp-*nagement) Yel xrostproof acet-, ene Neftlnnik 0 (Gas weather condit-imi) EMM SUMATSKIY, A.; NIZHEGORODTSEV, P.; KARTYNOV., A.; VIKMROVICH v- - CHERTILIN., V.; BATIROV, R. In the oil regions of our country. 33 Ja. 162. industry) Neftiazilk 7 no.1:30- (KIRA 15:2) (Petroleum VIKTOROVICH, Ye. First in the Komi Republic. Neftianik 7 no.2:3-4 F 162.(YIRA 15:2) (Komi A.S.S.R.-Patroleum-Refilting) I VIXTOROVICH, Ta*Ya, In the brWes of communist labor. leftianik 3 no-10-7 Ja 6o. (KIRA 13:11) (Petroleum Industry) VIKTOROVICII Ye.Ya. our reserves. Neftianik 7 no.12j6 D 062. (XlkA l6s6) (Komi A.S.S.R.-Petrolonst Industry) VINTOROVICH, Ye.Ya. Gas field of communist labor., Meftiw4 ? no.?.26 J1 162. WIRA 16:3) i (Komi A.S.S~R.-Gas., Natural) IVRIOVA, T.I., prof.; VIKTOROVSKAYA, Ye.N., dotsent; LAFOVOY, I.D.; KRVMHEMA -Ve"-' .9 M. Use of albomycin in treating women with inflammatory diseases of the genitalia. Sov.med. no.3:M-122 162. (MIRA 15:5) 1. Iz kafedry akusherstva i ginekologii (zav. - prof. A.V. Anisimov) i kafedry mikrobiologii (zav. - prof. T.I. Ivanova) Stanislavskogo meditsinakogo instituta (dir. - dotsent G.A. Babenko). (GMWMTIVE ORGAFSj FaTALF.-DISMES) (ALBOMYCIN) F 'T IT USSR/Mathematics Integral curves qualitative theory FD-450 Card 1/1 : Pub. 64 - 2/11 Author : Viktorovskiy, Ye. Ye. (Kiev) Title : A generalization of the concept of integral curves for a discontinuous field of directions Periodical : Mat. sbor., 34 (76), 213-248, Mar/Apr 1954 Abstract : Introduces the concept of a generalized integral curve. Extends this new concept to systems of differential equations. Clarifies certain properties connected with the averaging the right part of dy/dx = f(x, y). Clarifies the qualitative properties of the set of such curves. Extends results here to certain nonlinear Volterra integral equations. Institution : Submitted : January 5, 1953 Name: VIKT(jRUVSKly Ye . Ye. Dissertation: Integral curves of disruptive field directions Degree: Cand Plqs-Math Sci b-w4S&�jL A* DA006660b6m: Min Higher Education UkSSR, Kiev Order of Lenin Polytechnic ?4"Jwn Inat DOCURM Date) Place: 195(a. Kiev Source: Knizhnaya Letopis', No 45, 1956 UM/Mathematics - Inequalities, Jul/Aug 52 Integral "A General Theorem Governing the Existence of So- lutions of Differential Equations Which Is Con- nected With a Consid6ration of Integral Inequalities," Te. Te. Viktorovskiy, Kiev "Natemat Sbor" Vol XX)a (73), No 1, ~p 27-33 Under conditions somewhat mo re &neral than thosc of Caratheodory, demonstrates an existence theorem vhich leads- to the =ax and =in integrals of the eq y I = f (x,y) on tbe basis' of a substitution of (strict) differeetial inequalities of Chaplygin and Perron by 29=72~_ (vesk-ewd) integrals. Until now, in the author's opinion, no one had succeeded in extending the method used by Perron to demonstrate existence of soins of y I - f (x,y) (essentially the'1~us a ian method devised by Chaplygin for approx integration) to the more general case of "Caratheodory's con- ditions." Submitted 4 Jan 52. _______22OT72 VIK-r Mathema,tical'keviews Vol-15 No. 3 March 1954 Analysis Viktorovsk--iILE. 19. On a generaUzation of the concept of intezrai ct,'We; for a discofiflnuous field of directions.Z_ Doklady Akad. Nauk SSSR (N.S.) 89, 593-596 (1953). (Russian) Let fi(x,yi, ---,y.) be measurable functions in an (n+l)-dimensional region G, such that Af (.V) - Sul) M, sup jfj(.V, Y1, is surnmable. A gencraliz"e'd solution of the systern yi'=fj through the initial point (xo, y1o, - - -, y.o) t G is a systern of n absolutely continuous functions u,(.v) defined in X: _IXG, Xo+al, ui(xo) =Yio, satisfying the followingcondition: Viktorovskiit E- E- (2) given e>0 and any se of n -measure U, there OF P1 measurable functions ii, (x) such that in X: i 4'i (1) MX, *if. - *0 are summable; lui(x) -*q(X) I