SCIENTIFIC ABSTRACT VINOGRADOVA, V.A. - VINOGRADOVA, V.S.

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• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 8
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

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V. A . ; RLP.'D~lt I K, B. V. ; SAL~Y`.,'TA, I- z:. ; - ~i !71 : ~, * - . !:. :.
ll (C6115)2 Gel2+ HgI2; 2Hgl2+ Gel 2 PGe14 + Ht;2,2'
The influence of the reaction conditions on the degree of arylation and on
the yield of organogermanium compounds was also studied. Quantitative
proportions and, above all, the sequence of combination of the reactants
affect both the yield and the degree of arylation. To achieve a predominam-
formation of Ar 2 Gel 2, Ar2Hg must be added in portions to a small Ge 12
excess. An attempt to alkylate Ar 3Gel completely by boiling for many hours
with the equimolecular amount of Ar 2Hg in absolute xylene failed. Ar 2Hg
reacted only with Ar 3Gel to form ArHgI. The simultaneous formation of
(Ar3Ge) 20 is probably caused by the oxidation of the ArGe radical by
atmospheric oxygen. Separation of the organogermanium iodides, especially
Ar3Gel and Ar 2Gel 2' is sometimes difficult owing to their similar
solubility, Thereforeg the reaction products, or the residues remaining
after the separation of.the principal amounts of iodides were hydrolyzed in
Card 3/1 V

33265
S/062/62/0u-0/001/004/015
Synthesis of aromatic germanium ... Bio6/BlOl
some cases from the mother liquors, and the resulting aryl germanium com-
pounds were separated in the form of oxides. The molecular weight of SoLrie
soluble diaryl germanium oxides was determined cryoscopically in benzene,
There are 1 table and 9 references: 1 Soviet and 8 non-Soviet. The three
most recent references to English-language publications read as follows:
0. H. Johnson, D. M. Harris, J. Amer. Chem. Soc- E., 5564 0950);
F. C. Whitmore, R. J. Sobatzki, J. Amer. Chem. Soc. 51, 1128 (1933);
J. K. Simons, E. 0. Wagner, J. H. YZL11er, J. Amer. Chem. Soo. 55, 3705
(1933)-
ASSOCIATIOH: Institut elementoorganicheskikh soyedineniy Akadem4.i nauk
SSSR (Institute of Elemental Organic Compeunds of the
Academy of Sciences USSR)
SUBMITTED: July 17, 1961
Table. Organic germanium compounds.
Legend: (1) substance; (2) m., OC; (3) obtained here; (4) acaording to
published data; (5) solvent for crystallization; (8) n-heptane;
Card 4/1 Y

VINOGRAMAI-VA,
(Katerials on experimental and clinical electrocardiography]
Materialy po eksperimentalino-klinicheakoi alektrokardiografii.
Moakva, W-vo Akad. Med. Nauk SSSR, 1953. 261 p. (MLRA 7:12)
(Blectrocardiography)

LNVIM, Mae; GODOVIKOVA, T.I.; VINOGRaOTA, V.N.
S7nthesIs of simple and compound ethers of l-c7cloP"nten-3-01-
VeRt*Mosk.uneSeromt., makh., astron., fiz., khim. 14 no,3:
171-175 '59. (KIRA 13 -.5 )
1. Kafedra organichaskoy kbimil Mookovskogo gosudarotvonnogo
universitata.
(Oyclopentenol)

VARDNIMMG, A.K., kasdidat tekhuichaskikh sank; FIL&GRITEVSKAYA, T.D., inzhszer
VINDGRADOVA, V.N., iashemer.
X_Wwjw_~-
%ber-emulsi9m insulating varnish. Toot.elektroprom.27 NO-1:55-59 JA
'56. (MI2A 9:6)
1.1auchme-imeledovatellskiy imstitut Hinisteretva alektropromyshlear
mosti.
(Electric insulators and insulation)

vII'I':0I*I']L*VI V. ii.
Y,C) th S
- _:r, in the farvily Pyralidae
13,;rLicularities in the venat.ion of 'uh.3 rear w:n,
V!nogradova. Ent. ob. 31, No. 3, 1~51-
9. Monthly List of Russian Accessions, Library of Congress, September -1951? Unclassified.

'51-' J 1/0 0 68052
5-+3# SOY/55-59-3-21/32
AUTRORSs Levina; it. Yu., Godovikovaq T. 1. 9, Vinogradova, V. " M.-
TITLEA On the Synthesis of Ethers and Eaters of Cyclopenteno-1-01-3
and Its Homologe
PERIODICALs Vestnik Moskovskogo universiteta. Seriya matematiki, mekhaniki,
astronomii, fiziki, khimii, 1959, Nr 3, PP 171 - 175 (USSR)
ABSTRACT: The present paper is a continuation of the investigation of
the.uoe of mono- and dichlorocyclopentenes in organic syn-
thesis, From 3-cyLl9penteneland potassium acetate the authors
obtained the ealer )---a7ceT-oxy-cyclopentene-1 with a 60% yield.
As the production of 3-ethoxy-.cyclopentene was not possible
with sodiu
n ethylate, the latter was caused to react with
,
1,2-dibromalvelopentane, and the hitherto not described
3-ethoxy-eyelopentene-1 was obtained with a 35% yield. For
the purpose of obtaining homologs of this compound, 1-methyl-
and i-ethyl cyclopentene-2 were produced by the action of
organomagnesium compounds upon 1-chla'='Yclopentene-2# after
whiph it was transformed into dibromid e and caused to react
Card 1/2 with sodium ethylate. As a result of allyl regrouping, a

SOV/55-59--3-21/32
On the Synthesis of Ethers and Eaters of Cyclopentene-.1-01-3 and Ito
Homologe
mixturs~of alkoxy-alkyl oyclopentenes was obtained, the
composition of whioh eould -be explained-by means of the
Raman spectra, recorded-by Ye. G. Treshchoras In the reaction'
of the etbyl,derivative 4MC-of 3-ethoxy-.I-ethyloyclopentene-I
and 57% of 1-ethoxy-l-ethyl cyclopentene-2 had been formed.
There are-5 refsrences,-4,of-which are Soviet. -
ASSOCIATIONs Kafedra organicheakay khimii.(Chair of Organic Chemistry)
SUBMITTEDt January 2, 1959
Card 2/2

VINOGRADOVA, V.N.
Materials on the study of vegetable and & P crop posts of
Tajlkistan. Trudy AN Tadzh.SSR 5:57-65 (KLRA 9:10)
O!ajikistan-Insects, Injurious and PO ra)(Vog tables-
V
i eases :nd pests)
-,"AIME 77 7-71-f-11

YEMEPYANOVA, L.I.; VINDGRAikVA, V.N.; IMAKAROVA, L.G.; NES14LEYjill,-jV, t.N.
--.- - - -- - -
Synthesis of aromatic compou-0s of germanium by the interaction of
diarylmercury with gerraniun dilodide. Izv. Ali SSSSR Otd.khin.na~;k
no.1:53-59 Ja 162. (MIRA 1-5:1)
1. Institut elementoorganicheskikh soyedineniy AN SSISR.
(Germanium organic c3mpoumls)

VINOGRADOVA, V.N.
USSR/Chemistry - Hydrocarbons I Jul 52
"Cyclo'pentadiene'ana Cyclohexadien~ ifi the Synthesis of Bicyclic Hydrocarbons,O
R. Ya. Levinas T. I. Tantsyrava., V. N. Vinogradova., Ye. G. Treshchova
"Dok Ak Nauk SSSR" Vol LXXXV, No 1, pp 107-3.10
The reaction between magnesium and the hydrogen chloride adducts of cyclopentadiene
and cyclohexadience-10 was used for the synthesis of 2,21 -dicyclopentenyl and
2.21-dLcyclohaxanyl, which were treated with mercuric acetate and then KC1 to
obtain the corresponding HgC1 derivs. Presented by Acad A. N. Nesmeyanov 30 Apr 52.
22hT15

AUTHORSt Kochetkov, N. K. and Vinogradova, V. N. 79-2-40/58
TITLEr Ketorinylation of Thiophenols (Ketovinilirovnniye tiofenolov)
M IODIGALt Zhurnal Obahchey Khimii, 1957, vol 27, No 2p pp. 460-464 (U.S.S.R.)
ABSTRACTs This report is devoted to the study of the first reaction between beta-
chlarovivyl ketones with thiophenols. A now method was developed for the
synthesis of hitherto unknown nryl-beta-acylvinyl sulfides which are do-
rived with high yields from the reaction of beta-chlorovinyl ketones with
thiophenols in an alkali medium. It was established that during the
ketovinylation of thiophenols, the actual reaction includes the sodium
thiaphenolate and is followed by nucleophilic substitution of the C1 atom
in the molecule of the beta-chloravinyl ketone under the effect of the
thiophanolate ion. A study of cartd n reactions of these compounds showed
a close similarity to other beta-substituted vinyl ketones. The aryl-beta-
acylvinylaulfides RCOCH = CHSAr obtained an a reBult of the reaction are
described an colorless solid bodies easily separated from the reaction
mirture by conventional means. All the synthesized sulfides showed good
Card 1/2 storage stability.

Ketovinylation of Thiophenola.
There are 13 references, of which 10 are Slavic
ASSOCIATT(Me Moscow State University
PRESWM BI t
BURCM? February 21, 1956
AVITLABIZi Library of Congress
Card 2/2
79-2-40/58

T7- -., r
KOOHITKOV, N.K.i. VIMORADOU, V*N,
S.rnthemis of arrl - ketones of vinrlsulfoces and arrl-
ketones of vinylaulloxi-des. Zhur.ob.khim. 27 no.10:2745-2750
0 157. (min U: 4)
1.Moskovskly goeudarotyenn" universitst.
(Ketones)

87125
110 61 -'bo c~ 1 12o 15 S/062 "(0 '-1o o1n2,,
- / ~ - ~j '
B027,/B064
AUTHORSt Neemeyanov, A. N., Ilaoig ~.; tlj~
,q9va and Makarova, L. G.
TITLE: Production of Aromatic Selenium Compounds 'Nith Aryl
Diazonium Boron Fluoridon
PERIODICALz Izvestiya Akademii nauk SSSR, Otdeleniye khimicheskikh
nauk, 1960, No. 9, pp. 1710-1711
TEXT: The authors report on the synthesis of aromatic selenium compounds
with boron fluorides of aryl diazonium. In the introduction, methods of
synthesis applied by Western authors (Refs. 2, 3 and 4) are mentioned. By
decomposing boron fluorides of aryl diazonium with zinc dust in the
presence of selenium tetrachloride, in acetone, diaryl selenides with the
following aryls were obtained: phenyl-, para-, and orthotolyl, parachloro
phenyl and paramethoxy phenyl. In the case of aryl phenyl a small amount
of diaryl diselenide was obtained. The yields were not large. Only in the
case of aryl phenyl the yield reached 35-40%. In other cases the yields
were smaller. Diaryl selenides were separated by vacuum distillation and
with vapor. They were identified by being passed over into bromides.
Card 1/2

87125
Production of Aromatic Selenium Compounds With S/062/60/O_r'C,/'_~-"O/S'j
Aryl Diazonium Boron Fluorides B023/Bo64
There are 12 references: 2 Soviet, 2 British, 1 French, 8 German, 1
Swedish, and 2 US.
ASSOCIATIONs Institut elementoorganicheakikh soyedineniy Akademii nauk
SSSR (Institute of Elemental-organic Compounds of the
Academy of Sciences USSR)
SUBMITTED: February 17, 1960
Card 2/2

VARDENBURG, A.K., kand.tekhn.nauk; VINOGWOVA,_Yk,,_,_jnzh.;
MUKHOVA) N.A., inzh.;-nLAM112VS-UYA-, T.D., inzh.
Problems concerning the automation and mechanization of saturation
and drying processes of tho wirAlings of electric machinary.
Vest. elektroprom. 31 no.8;4-9 Ag 160. (MIRA 15-5)
(Electric machinery-Windinga)
(Electric machinery-Drying)

ACCESSION R i AP500605-4 3/0139/65/000/D0l/00'7/9o6l
AUrHGR I Vi4qua
AOTM, V, N." Godnav. L. ff.
TITLE: On the applicability of the method of "progressing rigidity" to molecules
X( Hal n I Ight :4* the thz-%Ajr-y- -,f' -7harn - -rl, ol~l jpncl
SOURCE- IVUZ. Fizika, no. 1, 1965, 57-61
TIOPTC TACS! tetrahedral molecule, haltle. -hbr-~cteriqtlic frequency, 7r-,Mr T'l
AWTWTI: The method of "progresaina rli7ldltv" was first proposed by W. Tmrmevidie
r a ev ot~

94 MUM-

1 39412-65 -2-
),CCESSION NR I AP5006054 At the method of the 'pro-
jiterfAturp,
tc T.Clec-ules
T Cad-

VINOGRADOVA, V.N.; GODNEV, I.N.
I
Approximate computation of the noncharacteriSt4e CoeffjojenS Of
the frequency and form of vibtrations In tetrahedral moleculea'
and Ions of X(Hal) Opt. I spfktr. 17 no.6t838-841 D 164.
4* (MIRA 18.,3)

VINOOPADOIJAY V,N. GOONEV, I.N,
Applicability of the method of "prcgre3sirp. rigldityl to
molecules In the light oil the th'eory of characteristic 4
frequencies. Izv. vys. ucheb. zav.; fiz. 8 no.1:57-61 165.
(MIRA 1~-,3)
1. Ivanovskiy kh1miko-t,ekhncloF,1chv.9kiy Institut.

L 44155-6� EVITI /FCC; M/GD
ACC NAt AT6027228 SOURCE com un/oooo/66/000/000/0229/0255
AUTHOR: Vinogradav, P. A.; Vlnogradova, V. ff.
ORG: none
TITLE: Activity of the electrotelluric field
SOURCE: AN SSSR. Sibirskoye otdeleniye. Sibirskiy institut zemnogo magnetizma,
ionoafery i rasprostraneniya radiovoln. Issledovaniya po geomagnetizmu i aeronomii
(Studies in geomagnetism and aeronomy). Moscow Izd-vo Nauka, 1966, 229-255
TOPIC TAGS: geomagnetism, electrotelluric field, geomagnetic field, electrotelluric
activity
ABSTRACT: The results are presented of a statistical investigation of activity of
the electrotelluric field,YYbased on observational data from 1944-1959. Three-point
houri7y-c-haracteristies and hourly amplitudes of the eastern component are used as a
gage of the activity. Diurnal, annual, and cyclical changes of activity are analyze
and the distribution of disturbances of various intensities during the 24-hr period
are considered. The authors pr 19P. ent the results of the comparison of activities of
electrotelluric and Momagieti \fields, as well ae the results of the investigation
of activity, taking into account short-period oscillations. Some problems of
latitudinal distribution of activity are considered. Orig. art. has: 22 figures
and 12 tables.
SUB COIZ: 08/ SUBM DATE: 25Dec65/ ORIG REF: 019
C rd 1/1 hs

V

VINOGRANVA. V.P.
Conference on the geology of polyuet&la of Central Asia. 1xv.AX
SM.Ser.geol. 21 no.5;123-127 My 136. (NLRA 9: 8)
1. Ministerstvo geologii t okhrany nedr 8 M .
(Soviet Central Asia,-Ore deposits)

VINOGRADOVA, V.P.; RADZIYEVSKIY, V.V.
Acceleration of the satellites of Mars aM the stabilization of
the orbits of artificial earth satellites. Astron.zhur. 42
no.2:424-432 Mr-Ap 165. (MIRA 18:4)
1. Yaroslavskiy gosudarstvennyy pedagogicheskiy institut im. K.D.
Ushinskogo.

NABATOVA, K.A.; DYMSHITS, I.I.; DUBOV. A.F.; VIIIDGRADOVA, V.P.
Shot peening the transmission gears of the Hookvich antozobile.
Avt. i trakt. prom. no.6:29-31 J3 156. (114LRA 9:9)
1. Nauchno-issledovatellskle aytomotorz7y, institut i Mookovskiy,
zavod malolitrashnfth aytomobilay.
(Automobiles--Transmission devices) (Shot peening)

-- -- -------
AUTHOR:
TITLE:
38471
3/12 62/000/006/001/023
D234YD308
V
Distribution of angular momentum in the solar system
PERIODICAL: Referativnyy zhurnal, Nekhanika, no. 6, 1962, 4, ab-
stract 6A13 (Uch. zap. Yaroslavsk. tekhnol. in-ta,
1961, 7, 1-43-154)
TEXT: Ye. Epik (1961) and V. V. Radziyevskiy (1952) showed that a
rotating particle moving around the.su-n in its gravitational field
is subject to an additional reaction force co*nnected with aniso-
tropic re-radiation of incident solar radiatioxi by the particle.
This force increases the radius of the orbit of the particle in
the case of direct rotation and decreases it in the case of in-
verse rotation. Por sufficiently large, slowly rotating particles,
this effect can be much stronger-,than the well-known Poynting-Ro-
bertson radiation damping effect, which leads to a decrease of the
orbit. Using a general expression for the reaction force deduced
by V. V. Radziyevskiy, the author carries out an approximate calcu-
Card 1/2

S/1 2 62/000/00'6/-601-1'/023
Distr~bution of angular ... D234YD308
lation. of this force for particles and bodies of different sizes
2 5
f ro'M ~ 1'0`- to 10 cm) as well as their periods of rotation. Tables
are given for the velocity of variation of round-the-sun orbitraiiUq:
in case of simultaneous action of re-radiation anisotropy effect
and P..oynling-Robertson effect. Reasoning is given regarding the
possi'bility of redistribution of matter in a protoplanetary cloud
under the influence of-the above effects. 6 references. Z-Ab-
s,tracter's note: Complete translation..7
Card 2/2

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11' IAU10meric strut-tures, tsling outtissal (C..4. or 1A Is, an AV. 1, drVuGlows .4 1.1" G* I'll
so, ZIS.) With (mill slut of I -Y, flit I'M I hu., the 1..ra. Is.-F .0 0
I the V0111W VAJUr 14 Mll being 115.43
owed. front P of ('%le")OPOH), *AdSfACtU1`y alteeluCut Clasig) suit Ili usiril oil ilrbijiltly the 1411I.M.1k
.,figutration of thesw esters. 'flit diAlkyl PhIlsit'llit"
WAS oblainest bVilviI bleirml rul ,k-J. Values UP to the
v jvfI c-fliventionafly Iflan 11011 and KI., T
0 11111 flu toter. betrusud whicli a comt. de~~jion of w," vrrv he
0 e follomisims values of autfAve lessimen. ti.. mul to we" loss ro 0
-3 observed. Application of & 2,2 UW, for Wb C
0 berimul the 0-I.Mumn Iriv- sovilcwhAt better agrrmttfl(. for the weiof. Olfrol'I'llo, Ill. Wt.r? 5% .0. 37.21,
0 I~ (EW)WHO, b,, 75',
0
but such itisliblinS of t;jbjtnj,& staftiblyd p.C rvmclxm has '11114, mV 1.411:16;
go .3 11 no thrvielk-al Isissix. is, long A4 a 1.4401111; (PrOlsPilt). th. III W.21, 1 ONI. 1 11;`
I the rsivn -'am"I structure Of jejo-PPO),F110, b, (VA', W~W, OMWI, 1.4101m; 1 tfhfl,,:
10 % Rv1U tie,
I 11-honiled in, ,,w.
09 lurr 14 a*",. It. Jo- ii-A by Aftunyv. it. Ill. I C' PHO. th. 1116'. :0(.&[. O-WI 1ALM. 0
-.1,41, is, IRV. lr,.M. O.P71A. I.C110; I A, N I V.
thAl I letrolim it 81,1411-Ahle l" 4 ;!x 3m, I LLIA. P, I's Itir, 7'. :--1 M,
-11 V11 14 11 4 14 9 %gulf & m C likuLl *
414m"s lWv.Huj If f . ~? ~` ultit. lure C 4(,.fn 44 . I tt*42; 4 CAF1011,110, Is, ~AJ-2s. Ilzm,.
C Use of thi. limm-pt Xjvv. thr fjjjS~Ijll;rr gf,mjll valur I,* 1.44J). It is milmothy thAl a 1",,%. ,4 u,fA&r ittimspil
r%ists twt%tvn Ow Itu asul Aut rislots. lar)tmul ahuh wit- 0 0
Ix 0 if 0 Once tension nwis with Inarasips moL for. Tl:wfs,1l.,*tnx 0
z dialkyl phost,hites are irlmitted to new "'asilds.: (C.. 1*
M.O)dIllo. by juldn. of 6.7 1. PC4 to 15 1. CJI,,Oll
I~ with I" 11~`""Olt follost"I by -Cuatilut to frinove J10 Zoo
unit (lilt, 14 Isto,luct t12 N.) jig rdisla. 161fim'.
pliv. from it S~ 11cl, .11141 11A X. ov-coolell Cfff,Ajll.
followed by th4m. lot Pat (so (Yidd not of-41-10. (A.Vlah'. 0
8.1 1,4 OfflAttLINGKIL "JIN"'Af C&ASUPKADCO Pill), fivas PCI, still li-r-roolil CJI.A)II; fumn IC j.
Kls thm wa* ol-lained 19a. 1purvesicir,th IM-7".
ties
IWO,
00
~* ~js
U0 AV 10 is dw
W
0000 0 14 : *0 OW FA all 1 If 61 1 a lZX
0 is 0 0 0 0 0 0 0

V/ V/
AEBUZOV, B.A.; VONOGRADOVA. V.S.; POLN.HAYEVA. N.A.
Raters of -ketophosphinic acids. Report NO,3: Structure of products
of reaction of some haloketones with triethylphosphite and sodium
diethylphosphide. Xxv. IN SSSk. Otd.khim.nauk no.1:42,49 Ja 159.
(Min 12:4)
1* Nauchno-looledovateltakiy inatitut Im. A.M. Butlerova lazansko-
go goeudaretvannogo universiteta im. V.1. Ullyanova-Leniza.
(Ketones) (Phosphites) (Phosphides)

USSR/Ghemistry - ~,aracl~.ors
Che,-Astr.-., - E3ters
ftlarachors and the 3tructum :~f lhosr-,loric Pio~-~FYcrour; 'ici Thon-
Acid L'sters," 113. "--. Arbuzov, vjrof-r!jriova, "ej F,,en, in-st, i rnen ~u rov,
Kazan -"-'tat,:- U, 13
IlIzv Akad 11'aul- SSS7,, C"d Khim T,auk 1 N'O 5
Includes 0 ata on measurpmpnt~. cf 7-ararhcrs of !,'i of I csi
yhorous awl T-hosihinous acids, ur.0 c~mrurQ-- themwith Y-arachor- I,v
.umford and Fhillil-s and SarIllel MetbCCIIS Of 9-OUT
I.,
FA r,3T7

VINDMADOVA, V. S.
USSR/Chemistry - Phosphoric Acid, Dialk-yl Jan 1947
Chemistry - Parachors
"Parachor and Structure of Dialkylphoiphoric Acid," B. A. Arbuzov, V. S. Vinogradova,
Sci Res Chem Inst imeni A. M. Butlerov, Kazan State U, 2 pp
"Dok Akad Nauk ESSR, Nova Ser" Vol LV, No 1
Describgs experiments which produce data on parachors of dialkylphosphoric acid, fully
confirmin.:7 results on polymerizing ability of this acid in liquid condition.
PA 5PT11

69
am
011P I u am go m 1: u m 0 It 0 x It do 41 4i a As if Of At 6 71
c It IF
49 X L 0-
"21fLTN0f'.A- 13 1911VIIIIII 1.34-54nIIIJI. I SI S If
J[,ANXIH
J1w'lvw . " I-,q 'IAxnl !Orwc OIL'
ro.-.P
gap..(Kc 'Vim .91'er. 0, 'MCF1
lop I.V-991 Iq 11AWN !qt'tC uL 'OWtj
jp . V_Wl Iq 'JAin
12 !vrec fsj 'awl An'
OD VRO IN Ilido -Papicam an -nsuw
=10)A1 *(jl961t,lPf*ra,q%4"sPwv"!
3"Jis invld ilaqi ulivow snojwl tqmn 1-
.1's"1 Jail in MUAUMMWK-,)W)9 It lv*171
ul)(1moul-Ill, Its srsriva In
MTV' 'A
.4 all filts"JUJI)
-Jv 'Y 11 '114111104 P4P )e OPLIS248 FORD 1k
I I A In w i
It P4 (f P ~6 a it 41 it 1,
Ives
r 00
0

P
il v 00
60
0 *
00
00
00

V I I
1, it
0 0 0 0 0 0 0 00
a .3 T
t
0 * 0
'
0 09 0 0 * 0 90000

UNOGIADOVA 86 V. S.
Mr., Scientific Research Institute of Chenistry !m. Butlerov, Kazan State
University, -1946-
"On the Complements and the IStructure of the Ethers of boric Acid." Dok. AN,
55, No. 57, 1947

VINCORADri-VA, V. S.
USSR/Chemistry - Boric Acid
Chemistry - Esters
Oct llk7
"Parachor5 of Substituted Esters of Boric Acid," d. A. Arbuzov, V. S. Viriogradova,
Sci Res Inst imeni A. tA. LIutlerov,- Kazan State U imeni V. I, Lenin, 11 pp
I'Dok Akad Hauk SS,';I0 Val LVIII, No 1
Concludes from data that parachors show tho- structure of cst-ers of boric arid, wilich
is in complete a re,,Iment with data of electro organic research. Favora))I.e concurrence
found between caiculated and acLual si.-nificance of I:arachors.
PA 5Zrl5

0. 0. ON 811 oil oil ow it 4 41 41 a 4
at IL- I -a L l,-L- a _4 .I it --IL.A
.A r a L- L a 11,
4
F.ixfml A-0 reeffe"It.
00
oo
00
00 2
*o
410 A :V
0 ParmthOn And S&Wturee of Rwk Add Kdom (In
0
Russian.) B. A. Arbuzov and V. S. Vinowd
Kki." (Journal of Y111cat
:0 Chtmistry). Y. 21, War. 1948, p. 303-309.
Describes synthesis of three of the &bore esters
:0 not Previously reportecl. Gives data on molecular
parachorm Of six of Wait emten. and discusses
'00 structural considerations. 12 ref.
00
Q
IL
ai, still amt, sillil 09 ONT 1,11I
p it -r
1, . on 1 41 w 0 1 V, so 5 42 a 3 0
114 9 Aw W) is 't 't a I 1 114
a It K No a d1s
0 0 0,0 9 0 0 0 * * 0 0 0 0 0 0 0 0
0 9910906 -::0000 e0 0*0000::::::Oooooooooooooeooooooo
Oo
Vo
"so
vo
loo
41111110,
:100,
1101111,
Wo
411110
Igo
4Wo
FIS 0
too
w0 a
two

vrlTwiuajn~ V. ass
USSR/Chemistry - Boric Acid, Esters of Yar 1048
Chemistry - Parachors
"Parachors and Structure of the ""'sters of Boric Acid," B. A. Arbuzov, V. S.
Vinogradova, Chemi Sci Fes Inst, Kazan State U, 6 pp
HZhur Fiz Khimll Vol XXIIP No 3
Yeasures parachors of six esters of boric acid. Compare these values with values
calculated by the Gibling "group values" method. Vs~iation between the two does not
exceed 0.5%. Yake conclusions on the structure of boric acid esters on the basis of
the parachor findings. Submitted 16 Apr 1947.
PA 65T21

, ~ rr,
USSR/Chemistry- Orthofo=.7.:.c Ac-'4-, _-'sters of "-a,,- 1948
Cher,istri- Parachors
"Parachors and Structure of Orthofor::,ic Eot~3rs, Orthc-2axbonic and Orthoslllcic Acids,"
B. A. Arbuzov.. Corr Mem Acad Sci USST~J. V , Vino- alova$ Chem Inot imeni A. ~:. Dlutl-~rc-,,
Kazan State U imeni V. I. Ullyarlov-~~nir,*3i*pp
I
"Dok Ak Nauk SSSR Vol LY . No 5
In provious articles dealin:_ with nubject it wt~s statei that corrections were nacessary
for curve of' chains in a direction toward central atom as well as for i:-.torrelationzi-iip te-
tween componc,,nts. iLeports results of studies con--ucted to deter:.-.Ina vulue of parachors
of orthoformic enters with corrections 7zda on carbon atc.-, of-Mch chain, well as
re 0, tile carbQn atom. Submitted 15 '-',a-- 191,6.
corrections to parallel nau
FA 68T17

Pattlebtirs of cyclk serials. 14. A. AtImpoir aml V 14
niflitays (Nittests mlielle 1,111v I I toa fw Vabli
#W.4. Abjew ' %'.seek 1060 Zil A; c#. P.64wy 0
Mid Nask 58. M(194b. (.A . 41, 873&.
.'444h, 110iffilml.-Tise porwbar of 1,1~dkmmw (1) was
elvid. reiperi"writally to be 21A.21. that of dintakne
lolw IM 1. Thediffi-trnev.370.1m
%~ty lit thet Id,T cakd. %m Ow me-umptiown that Im..
,i,ijer few" a diia-membered to a Ave-treendirmi their shmAt
-kvmw the standard group pawbor of C111. 4211, by
AA. Con-equirestly, the ring conic Ion valid for twfx).
VV%,fir comrh. Is Appl"hip also to olvernalimt betmi.
rvv" '11w parachoet; eak,el. Ineret tho hirdl simppit.s.
, IKN-. Willi the currespuladine [WE cutirwililliq 110., 41141
Ile 4 few the sn- *red The fivie-ustrintwird this. it-wi, ) are
211.11 and 174.0. for I wid U. imp ' the devialJoes. av.
tim, is attributed to dic 1) atowas ;IA leadi; to Me irelm.
churtion of a come im of -3A ic; eseb 0 istom lea ibr
he(erm7chr ring' with Als com . alml the previ.
i"84Y "llibiwint ctirrmlowes for the Imlewlion twimm"
11w didir ritimin and Iled, time, AM lwlwvw" Iter Asir rhmim.
We It'd. misiclion atte lei very reit.1 agretiiiiiii f4lovidikso
:
,,, V.%cUlies 0.4%) Willi the! feelliewitig Valmduse"tally
detil.parachon: 4-nwthyl-l,3-dk)uurJ44.d; 2-nwthyl-
1,3-ilkaArer 2Q.3; 2-mirtIly1dicesslanc 207.0;
yklioxalarw .342.3; 2,4-diseetthyl-1,1-dioxane 2W.A.
1.4-dienstir 211A.4; 2-phrnvl-1.3~linxdoc, 37,14.7. Cf.
f"Itowmet 41.4r. N~ Mime

Pitimsbm qt tbe cyclic "sets ad subeigs, vallimrs".
MAI. H. A. Arlmum antl V. S. Vino-
111 StAte Vote.). Ismi.
=
Airl. Nksm. Nismk IM. 207-3)3: d. pre-
~Jing al"tt.-The extill. Value of the panwhm of
tthYknr SIMA I'Alt.111SAIC CIIA)CILX)CII, I-mm, IN in
t--- -- -j
'grrvownt 1within with the I-jil.9 raW. with
107.0 taken low the Weal 4mp pLmcbor of (C) E)COO(C).
the Littirr vislur in offlAftied Imm tIW uump pairsebor,
MAI. with the corevirtinno, -A.2 (4W tbg luteffacitoin of
C
Ainnis in(K - - 31 in C< and - 3.7 in < For.
their cto cc kxu aln-l"i me -3.4 for the fivv mber -
fine- Aml -41.00r the 20 atom in (be riag (d. prit"ding
isbatir.). My the marne procedurv, the parsrhor of irl-
awribylenr glycol curtiormte C11,01*0COMIJ, 6 cakti.
L -1
to lot within O-A% tit the tripti. 217.11, Rnit that of
6 cmkxt. to 204 U. within 0~2-r it
the rxpti. V4.4. Fur the ump (C)O~Ax)jC). th, W-I
Poop F4nwbtw h "tit. to tw 121.5,whwh. with the uiual
.1irtrvil-in. I'm file ring 'in-I iht- J 4) mattirn.. 614 the 1.10-
vhoro 4 CIIOk*X)CIlt frakA. INA, ritial. IN.1) Avul
.. j
i~Ak-d. inuf rtlill. =11 3). In a
604 goits way, the kind group pararinif of I(C)OI,v irl
fiv*108111d 11-111CM101-fird firiett 6C4k'I. talk' withth"
value, &nil the umul varlmlion-. the rali-d. jur."bur.
agree within brtler IhAn 0.9~' with t1w rupd. ~jlws-
L
I I N e XM' 4. N. Than

IlaraAars and structwo *( diatkytylsoffharous acids
11. A Adjustov ouil V. 'I Ybiouailsiva f % I I rems
State ['Dow.. KAMAO, V~N S R ), P14bbly Mitt Nook
A N S. R, 72, WIP N(19,ldl) (if thr .11-
11011.4 - 1-9, tile mean fit.A. Mih, J.'er." hio 1. f
Cill grimp is M 01, rkre W OW 1-flMll VAIII, 4)! :110 S. 'file
higher mrinficts have A - 40:." whwh III
chon P id the tmlcr III 41NP-71s). whetta. of thew hixlqr
Inembers were dimeriml. title %h,tuW esloert P 1-1(nt
154111 and A - 40.14-41.L Al-ni-e .,fa-ts. III * 1,
11011 W'J' ".11firtiletl I-Y rlytv-43'l'v its (*.Ill. III colIMI-1
Shtirlo, I W411,1101 1. ".-1 mid i. 111,11l'unv[jr .1111Y i's
vrev III .,lot I-imn thr . %pel I' - it$ 11 A Ow aught I,
itc4fly o"Ou'aurric fit,- gri"11, pamlwf A
0
I(C)01,1 , cuirceftif fur r%pAnsiiin, twit-lifts, and irill I.
,Action of the c1lains, is V17.3. Cnlnj~arimin ttl the P %-afurs
vulird. with this new group 1mravimr. with the ripti, P.
shows that onlythir "It"11wrl with of - S, 7, -.jn,I6_irr itimm.
merk. For the lower memlirrs, 'kVi4tions I.twern the
calrd. anti the expil. P bulirarr mvirn . hierri,ing "ith
dert'a.,ung 4. Oil the "thcr Lit"j. if fit,- gr'-ul,
o It
(C)NIP \P14 lie) to i- flit- 1"Iluiptio-11 "I
rrimpirle 'b"Irrizatio'n of it Is fou"'I
anti then curri;-ri~n t21 the vakil. and lite expil. /a
ind"fes inctrejAng ilbvictit. of the thriter tit mruliimer~ with
incre4sing I. The jwr crut deviatkin tx-t~,nirs crmit..
from oe - A top, which confirm% th.;t the mrostlwr%
with a - 6, 7, vind 8, are cornph:%cly mortam"w. oil thit
'N" mn lie rnuxhly v,l-l.
bilsis, lbegerrensr of motiomc, 3, .
to lie 65,. in (4i--BuO).MII. 70% in fDu0),POII. anti
40-f-- in (Prt)hPOII. The erpil. values e-f P fkr the (RO)1-
Will are: R a Mr. 4M.M; Ft. (140).3; 11r. 75A (); i-11r,
75511; Do, iWA, Wi-Bu, 11)(M.2; C.11, 121110). C,11u.
1372,0; Colla, 1-"' 0. N. TImu

V1140GRADO11A) 11. S.
"Parachor and Structure of Esters of Som Inorganic Acids,n Ucheniye Zapiski
Kazansk Ooo. Univ. im. V. 1. Ullyanov (Lenin), 110, No.9, pp. 5-82) 1950
Evaluation B 3p075,646 Translation in Librai-j

The i =4 of of
MI OW. 1I.A. and
State Univ.). lawd. Abad.
tyrVOROMO-Od'i Xkin, Meak MI, M-W; d. C.A.
42. =M-dju the buis of parsebor calcna. with correc-
lkw for chaW paralklill" Jef. CAbling. C-4. ". =11), it is
macludes! that the (RO).PO strwury involves a parallel
pooltimolallZRcisains. Tbethitipboaphates.(R04M,
po"M a similar sinarturt. llu"ver. phoWbites, (RO)sP,
problibly carry only 2 chains In parallel potit klu%, fndk&tW
the oteespity for a stron* pout tw,(PO or -08) to exteW
the structure of the ent nw. % (10 x ). 21) a. COHIl-
Mf. wed 13.4 g. pyridine in lOn mi. Pilo, with cooling. gave
().qm. as
7 g (ColiftO)sPiP, th IK7 M% nl* 1.4340
in 11, c a0beculed.
2*04 (dynr..'cm. i. 1P1 PO. In (with
wahse for 3 paralkichainsi, NmdArIT,ZJ1pg.CJfnOH.j0f.
PML. and 13.2 g. pyritline gave CJI,,O~J'O. bs 225-7
at" 1.4410. dj* 0 9", 1" 25P.M. iP) ltV4,-,: preM
PhNUn as the liCt-hinding agent g4ve an und liable
Addn. of 8 to (PrO).P gave (Pro 4PS, bw 323.5-
1.0177, xV 1.45M. -,m 2M.47. 1 P1 WA; lift
S20 g.) "Is 2.2 X. S to IM-2101o gavo (DoOVI
M
bo, IM-9 bu t 160- 1.5'. dj* O-W, 1, wV 1.4515. -Vu 28,36.
1P) W.2 HimsUrly were pr*pd- (CJ[uO'..PS. th., IRS-
11.5". dj* U-Mil, a460 1 4.w, 30,68, jfk 02.6. and
(C49nO)oPS. bsjw#-# Td+-O" (41M. at higbe ptewre
gives d 0 0.9M. W IAM2. -,* 29 It IPI
94. wW pyridine pre b%
121.5*,djO.91334 JAW.-102TV"P1619.6. siml-
lar ftaction With W.011 gave a mist. of 1weducts uhtch
after SYMtod dko. yielded (CJIO),P th 167-A-, dl-i
O.WW *V 14405 -em, 27.86, JPJ $0.5 liatermediate tw.
tweert i Ow i pwah~ .-I. structute); o( the ester
by biestiot 19.6 mi. C4IfwOH vrkb 7.3~j7.1T3i6).P and I
dr,3~~%M t 1.8). with dim. of the R H a
157-7.3", d:s 0.1081. wV I.Me~girA2.
JP) SM.] (Ywry elm to the Undure requirement for 2
parallel dAlcls). Similarly, (cgullouprej how K1.
b, 210'. dil OM36' SV 1. p IP110"J:
(intermediate value), wbik tk&t pcvpd. from (EtO).P. th
212-14'. djo OJW. *V 1.4473 -10 WOO save p) I=.&
(Tuy clog to 2-citain pool 01110),p
(IM' 'EM-P). b, 0-99N. OeV 1.4496. A
WX. gawl (Pi IAM (very clome to the requirement for I.
chain r4lk1l$M)' (C01111041" Pr"dL frum K4. b_
M'. 114. OAVA. *V LOW ill 20.76. gave JPJ I.W.7.
while the product from b, s 236.5-7.6'. dl* 0 SW.
*V 1.4613. ?w 29.99 !P I J330-2 (wa close to %vhajn
Parallelism). PINCIM11"'O' (mi.). I g. A, .0
36 0. _PkN&feo IS x. VPA CHo 0&0)~P. th 2M.9 da-
-10 41, t. IPJ not caled, 0, M. K.
LION, XV 1.8 ,

UM/Chemistry - organic Autimony Sep/Oct 51
Compounds
C
"Preparation of AntinonwAs ArA& . Ext9ris ky
c Re-eaterif ication Reaction, B - A. Arbuzov, V. S.
Vitogradova, Chem Sci Res Inst imeni A. M. Butlerov,
Kazan' U immi V. I. Ullyanov-Lenin
*Iz Ak Nauk SSSR, Otdel Khim lqauk* No 5, pp 551-553
Fa~a~ it possible to prep higher enters of anti-
wonoft acid by re-esterification of 3over esters of
antimoUous scil vith higher &Ica and distug off of
lover alcs. By this method prepd n-hexyl, n~-octyl,
195TI2
DW/Chemistry - Organic Antimony Sep/Oct 51
Compounds (Contd)
n-nonyl, n-decyl, benzyl, .8-phenylethyl, and cyclo-
helyl eaters of antinonous acid (none of these
described in the literature).
V;

7A
Chemical Abst.
Vol. 48 No. 9 C*t Q t Of OMS IAO ,QAWC 44148.-M.-A-.'Arl~-rov,
hay 10, 1954 1 , ~ V. 0 Acad. &i.
CAM. 15d. tran3fation).-See CA. 47,
organic Chemistry 4XIM. H.L.H.