SCIENTIFIC ABSTRACT VINOGRADOVA, V.S. - VINOGRADOVA, YE.

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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Chemical Abets
Vol. 48 No. 9
May 10p 1954
Organic Chemistry
VlacovIty and p(hicture bf
A, S
Ix. Ed al. translation).;
Ste -C.A._47t.43.4d.

VINOGIRGOVA., V. S.
Chemical Abut.
V01- 48 No- 8
Apr. 25v 1954
Org3nic Chemistry
v1scoalty acd vnKMM of teen
fit, an
St UZ v an an dd.
a u ac .
Me JC11 r -translation). See
47, ln%e.

T-r NOGRADOVA V S
Chemi0al Abet.;
Vol. 48 go. 8
Apr. 25#,1954
Orginic Ohemist-7
and Ovif parachors, A.
Bun. acad, JCT
sit giql. tranxlAtfon~.
See ,C.A. ~7, iwm.h. If. L. 11.

ARBUZOV,B.A.; V.IHOGRADOVA, V.S.
Viscosity and structuro of estors of phosphorous, phosphoric, and thio-
phosphoric acids and boric acid. Izvost. Akad. Nank S.S.S.R., Otdel. Khim.
Nauk 132, 863-74.
(CA, 47 no.20:10458 '53)
1. Kazan St&t* Univ.

ARBUZOV, B.A.; VINOGRADOVA, V.S.
Boterm of alkylphosphonic acids and their parachors. Izvest. Akad. lauk
S.S.S.R.,.Otdol. Khim. Nauk '52, 882-93. (MLRA 5:11)
(CA 47 no.20 ,:10464 153)
1. Xazan State Univ.

ITY V.
USSR/Chemistry - Cetyl Eaters MaY/Jun 52
"Cetyl Esters of Some Inorganic Acids,"
B. A. Arbuzov, V. S. Vinogradova, Sci
Res Chem Inst imeni A. M. Butlerov,
Kazan' State U imeni V. 1. Ulyanov-Lenin
"Iz Ak Nauk, Otdel Khim Nauk" No 3, PP 505,506
By re-esterification with cetyl alc of ethyl eaters
the following products were obtained: tricetylpho-
sphite and tetracetylorthosilicate. Tricetyl
borate-was obtained by the action of cetyl alc on
boric acid. All esters obtained can be distilled
in vacuum without decompg.
a2ori6

USSR/Cbemistry, - Organo-Phosphorus may/Jun 5P-
Compounds
"Me Viscosity and Structure of Dialkyl-
phosphorous Acids," B. A. Arbuzov, V. S.
Vinogradova, Sci Fee Chem Inst imani A. M.
Butlerov, Kazan State U imeni V. I. Ulyanov-
Lenin
"1z Ak Nauk, Mel Khim. Nauk" No 3, PP 507-511
Detn of the viscosity of dialkylphospho-
rous acids in dild solns of carbon tetra.-
chloride or benzene sholred that according
to the given values of `Y equiv they are in
the monn?n ric state. The following compds
Pqffr]2
were synthesized for the let time by re-asterifi-
cation of diethylphosphorous acid with the corre-
sponding ale: dinonylphosphorous, didecylphospho-
rous, decetylpho~~phorous, di-0-phenylethylphospho-
rous, ethylhexyll)hosphorous and ethyloctylphospho-
rous acids.
22OT17

USSR/Chemistry - Organophosphorus I Mar 51d
Compounds
"Preparation of Higher Dialkylphosphorous Acids
by the Reaction of Re-esterification," B. A. Ar-
buzov, Corr Mem, Acad Sci USSR, V. S. Vinogra-
dova, Sci Res Inst imeni A. M. Butlerov, Kazan
State U imeni V. I. Ul'yanov-Lenin
"Dok Ak Nauk SSSR" Vol 83, No 1, PP 79, 80
Two moles of the appropriate ale were reacted
with one mole of diethylphospborous acid in the
presence of a few drops of coned phosphoric
234T2
acid catalyst to form ';he following dial.%ylphos-
phorous acids, which were isolated: dihexyl,
dioctyl, dionyl, didecyl, dicetyl, and di-beta-
phanylethyl. Hexylethyl and octylethyl phos-
phorous acids were obtained by using only one
mole of the ale. Re-esterification can also be
carried out with the fol.lowing ales: ethylene
glycol, cycolhexanol, benzylalc, and octanol-2.
However, distn caused the products to decompose,
so that isolation of esters of this group was
unsuccessful.
234T2

VJ!'Oorm"A' 7.. S.
OW/ Cheadstry Physical chemistry
Card 1 1/1 Pub. 40 - 7/27
Autbore t Arbuzov., B. A., and Vinogradova, V. So
Title I Paraeboro of mono-estere; of othylphosphinous acid
Parlodical r Izv. AN SSSR. Otd. kh1m. nauk 4, 622 - 626, July - August 1954
Abstr~At t Data on the parachors of many mono-eaters of ethylphoaphinous acid and
the constants of these esters, are presented. Excellent conformity
between the found and conputed parachor values was observed during the
reaction of the aster chains of the different molecules. The parachor
and molecular weights data, which were determined aryoscopically,
indicate the monomerism rather than the association of the investigated
esters. Thirteen references; 6 USSR and 5 USA (1942 - 1953). Tables.
Institution t The V, 1, Lenin State-University, The A. M. Butleroy Scientific
Reseanh Institute of Chemistry, Kazan
Oubmitt,~d I Jam 19.9'1953

VIDOGI~;'.,'~--DO"A, V. 53
OW/ Chemistry
Card 1A
Physical chemistry
Pub. 40 - 8/26
Autbon Arbutov, B. A,'s, and Vinogradova., V, S,
Title Parachors of certain dibutylcarbinol eaters
Perlodical Ity. AN MR. Otd. khim. nauk It, 627 - 630, JulY - Auvat 1954
Abstract Now hitherto unknown esters of dibutylcarbinol carbonic., malonic, boric
and orthosilicic acida, were synthesized and their parachor values
determined, The necessity of introducing correctionm for-the parallel-
ism of main and side chains, was established on the basis of the
coRputed parachor values, The introduced corrections are eh'own in
tables. Thirteen references: 8 USSR; 4 USA and I French (1907 - 1954).
Institution i The V. I. Lenin State University, The A. M, Butleroy Scientific
Research Institute of CherAstry, Katan
Submitted June 19, 1953

ARBINOV, B.A., akademik; VINOGRADOVA,___IS
Synthesis of esters of certain -katophosphinte acids. Dokl. AN
SSSR 99 no.1:85-87 N 154. (MIRA 8:2)
1. Nauchno-ionledovatellskiy khimtoheokiy institut im. A.M.Butlerova
pri Xazanakem gosudaretvennom univereltets in. MAJ11yanova-Lenina
(Phosphinic aolQ

Q-R~
zr

ARBUZOT, B.A.; VINOGRAWYA, VPS.
Parachors of mothyltriaDqlsilanes. Izv.AN SSSR Otd.khim.sauk 86 n0.6:
1031-1036 my 155. (MLRA g14)
l.Khimichookiar institut imeni A.M.Datlereva, Kazanskoge gesudarstvan-
noge universiteta. imeni M.Ullyanova-Lenika.
(Silans) (Paracher)

V
ARBUZOV, B.A. (Kazan); VIKOGRADOVA, V.S. (Kazanl)
Kato-enol tautomerism of some phosphorus organic compounds. Uch.zap.
Kas.un. 115 no.10:36-37 155. (KLRA 10:5)
(Phosphorus organic compounds)
(Tal4tomerism) -

VTTIOG-i"VA, V- S- and ARBUZOV, B. A.
"Esters of Ketophosphonic Acids and Some of Meir Properties"
paper presented at lln First Conference on Phosphorous Compounds, Kazan,
8-10 Dec 56
SO: B-3,084,841

"Eaters of Beta-Ketophosphonic Acids, Communication 1. Phospho-
acetic Ester, Phosphonacetone, and Their Homologs," by B. A.
Arbuzov and V. S. Vinogradova, Chemical Institute imeni A. M.
Butlerov, Kazan State University imeni V. 1. Lenin, Izvestiya
Akademii Nauk SSSR, Otdeleniye Khimicheskikh Nauk, No 1, Jan
5Z, pp 54-63
This article outlines material indicating an analogy betveen carbox-
ylic acids and beta-keto and beta-carbalkoxy derivatives of phosphonic
acid eaters. The phosphonacetic and methYl phosphonacetic esters do not
contain noticeable amounts of the enol form. Both phosphonacetone and
methyl phosphonacetone contain small amounts of the enol form, ae deter-
-mined bromine titration. Considemble enolization was found to take place
In an alkaline medium. Esters of beta-ketophosphonic acids as prepared
by Arbuzov's rearrangement have properties differing from those as pre-
.pared vith dietbylph"phate,

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: Y- , -1-1115- 1
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C". k o"
11SCR/ Chfnaistry
Card 1/1 Pub. 22 - 24/154
Authors I Arbuzov) D. A., Academician, and Vino-rtdova, V, S.
Title Beta-ketophosphinic acid ester investl6ated by the bromine titration
method
Veri'Odic&l I Dok. AN SSSR 106/2, 263-266$ Jan 11, 1956
Abstract t Numerous beta-phosphinic acid esters were synthesized and inveatigated
to deterriine the existence of anol forms of these esters and to estab-
lish the effect of the carboxyl atA phosphonium groups on the formation
of enol forms. It was found that the results obtained by the application
of the bromine titration method do not allow the problem concerning
the existence of enal forms or their nim1ber in esters of various beta-
phosphinic acids to be solved. FLu,ther study of these acids by physico-
chemical methods is recmmended. Light references: 6 USM and 2 Germ.
(1911-1955). Tables.
Instibition Scient. Re.s. Inst.-in. A.- M. Butlerov at the Kazan University im. V. I.
Lenin
Submitted September 24, 1955

UltrAylolot obsorptlan spectra of qi0ra gf_~f, .01,9
-,Pbgt--
1
I

phooli: acids. 11. A. Arbuzov and ~
j.
41",
(V I
)(HIn,117 "I"
r
ii, 4,4ao. 0~ at. y A
N~ak S.S.S.R. 106, 4 ze6emwtim,, of ultra-
violet abwq2ti~,j sp-ctra ar,? givtit farculivi, c-f s~vcral t~(cr4
of keto phaqp1wine aci,li mid of their alktnyl plinq[ALAte
(1,.'tO)l O)CII,Ac in
N
MtOH tia, a ~prvtru- %isillar to that J A
fjCOjl1,t iii
.
fj,O, Indicating %,try.little cmiL form; ill
sotri. Olere is a inav. at 2.100 A., indleative of
concii. of enolate iorii; giv('s it ihnij.q
Spectrum which is similar to Outt of J3uSOCIIjAc (cf,
and Cqrrnack, CA. 43, 4215j). SIC011, firmne, Ur 11,0 us
solvents give subtao im:i fly ilia &imestittArilm of(VJO,~P(O)-
Cfi,Ae (1). The sp~trtiw of n
Possible coutainin mt 4A thc tibovitt sh,3w,-i Ek mix. 2500
A, In the l(KAtion in which I has it ruht.; MtOIN,t turrely
-enhances ilia 2,W) liand. The atiove results wcre cli.tained
frotzi I pircrid, !rum ()-,'tO),P alvi XCII,Ac. I prelA. frian
(L'tO),PON4aiill WC11,Ac ijawtiltr
and Lickv ilia m-tx. at 2-1W A.; ill MeON" th
sptcln"n
YA A. 't o (,,!Ac,
a1-0 liag the Mlldte LaUktl at - (E I-Viv.\
'-prelml. frotm Wtu_~.~IONA, lja~ le'l tilml -"'6 fltcf~ will, 11r,
"lad ILI ub~orptiwt hlKorlull 11"I ulaq. lit 2:kX) A.
unciiinged by MIcONTa. pirpit
:
front (14,10),11. givt~ I-Wh C"):,r t%,,t lind V1,1113jim U31
S.Itd. lluaerLil WS hJACUUM ill NIL011 (JUj)Hk`a.XQ:1 IfiAt. Of

RR buz oy 13,9,
A01h;
):11"'lly' fill") I-,()-A.
;,,,f Utrr flit. j, lpe j talc
the 2Xro-A
All
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rw C110ati"rl.
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071114, (it
1119 Y i1 4rawfl
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M, , - i - ~ L ~ A 1 .1
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1'e.- - I ~ I . - - -- .: z " 1 ~ . . I -'~, ..
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V I G."I I J` V '- i~. ; . , A
YOVII.- 11 "Y"P-W, (ChaLr of
10,
rganic i'hemistry and NTT of Cf-.emisLry im. A.M. Butlero-.r of Kazan State University
im. V.I. nlyanov-1--nin)
"Intermediate Products br
, the Arbuzov Rearrangomc-nt" (Promezhutochnyye produkty
pri peregnippirovke Arbuzova)
,ar,cr.),1,io,zphorous Compoundr,
-chemistry and U--cs of or(-
(Khimiya i primeneniye j-,jz4L'cr,-)rganichca1:i1'Jt s,.,yedneniy).*
Trudy of First Confcrencoy F,.10 December 19551 Kazany
pp. Published by Yazan AfTil- ki USSRy 1957
62-75,
Report discussed by: B.Ya. Teytellbaum (Chem. Inst. lm. Ac-lkd. A.Ye. Arbuzov, Kazan
Aff. AS USSR), M.I. Kabachnik (Inst. Elementary Organic Compounds AE~ TJS-IR), and V.S.
4bramov (Kazan Chem. Technological Inst. im. S.M. Kirov). E~fnrlments wpntloned by
V%-S, Abramov were conducted by A.I. Bol'shakova.

Vjt-.IOGRADt^,VA, V.3., AR3LEL07, B.,I. ( Chen. Inst. irr.. lk.11-1. Bu~Uerov under the Kazan
V.1-Ullvanov-Lenin)
state--vrdvgrstty Im.
"Esters of Beta-Ketophosphinic Acids and Soiw of the Their Properties" (Fxiry
Beta-ketofosfinovykh k-islot i nekotoryye ikh svoystva)
Cheniatry and U:~cs Of 0-r[-,an0Pho:-phoro,js CQET~ounds
(Kh:Lmiya i prilaeneniye: !;-,-Yednr-rjiy),
Trudy of First Crnfererx(~-, Dece., '
,ber 1555, Kezar,
PP. Publi~;hcd by F-azan Af l'il-. X~ LISSR, 19J7
176-184,
Report discussed by A.W. Pudovik (Chem. Inst. !Lm. Acad. A.Ye. Arbuzov, Kazan Affil.
AS USSR) and M.I. Kabachnik (Ifist. Slem. Organ. Compounds AS USSR, Moscow)

- - - - - - -i-7
AR -!"R -
N, R
-E P

rl. W7R T-
,t&~

V,~
AUTHCHS: Arbuzov., B. A., and Vinogradova, V. S. 62.1-8/21
TITLEt Esters of Beta-Ketophosphinic Acids (Beta-Ketophosphinates) Part 1.
Phosphonacetic Esters Phosphonacetone and their Homologues (Efiry
beta-katofosfinovykh kislot, Soobshchaniye 1. Fosfonuksusnyy efir,
fosfonatseton i ikh gomologi)
PERIODICALs Izvestiya Akademii Nauk SSSRs Otdoleniye Khimicbeskikh Nauk, 1957,
No. 1. pp, 54-64 (U*S*S*Ra)
AB67RACTi Date are presented on t~a synthesis of certain substituted derivatives
of phosphonacetic ester, phosphonacetone arul -'.ts methql derivatives and
the results obtained during the titration of these compounds with bromine,
The three methods employed in the synthesis of these compounds are : A,
reaction of alpha-balogeno-carbonyl compounds with phosphorous acid
esters (the A. Ye. Arbuzov regrouping); B, reaction of dialkylphosphites
vrith alphs-halogeno-carbonyl compounds (Michael's-Becker reaction);
and C, alkylation of the metallic derivatives of beta-phosphoncarbonyl
compounds with alkyl halides. The constants and properties of the
compounds obtained by the three different methods uere found to be
quite different. It was found that the amount of phosphoric ester
Card 113

62-1-8/21
Eaters of Beta-Ketophosphinic Acids (Beta-Katophosphinates) Part 1.
Phosphonacetic Ester, Phosphonacetone and their Homologues
obtainable depends upon the reaction teqvrature and nature of the
halide., high temperature aids the formation of ketophospbinic acid
ester, lower temperature promotes formation of phosphoric ester.
The chloro-derivatives sometimes yield an unsaturated phosphoric
ester; the formation of unsaturated phosphoric acid esters explains
the abnormal case of unsaturation in the di-substituted compounds.
The enol content in the phosphonacetic and mothylphosphonacetic esters,
determined by the bromine titration method, is explained by the presence
of hardly-separable small amounts of unsaturated phosphoric acid ester.
Considerable enolization taki--s place in alkali media.
Cawd 2/3 Tables, graphs. There are 24 references., of wtdch 10 are Slavic.

62-1-8/23.
Esters of Beta-Katophosphinic Acids (Beta-Ketophosphinates) Part 1.
Phosphonacetic Ester, Phosphonacetone and their FlcrolcV.)es
ANOCIATIDN t The Kazan' State University imni V. I. Ullyanov-Lenin, Institute
of Chemistry imenj A. M. Butlerov.
PRMNTRD BYt
SUMMI January 12, 1956
AVA31AM: Llbr=7 of Cbzgmss
0" 3/3

AUTHORS: Arbuzov, B. A., Member, Academy of SOV/2o-121-4-19/54
Sciences, USSR, Vinogradova, V. S., Polezhayeva, N. A.
TITLE: On the Structure of the Products of the Interaction Between
Some a-Haloid Ketones of the Carbocyclio Series and Tri-
ethyl Phosphite and Sodium Diethyl Phosphite (0 stroyenii
produktov vzaimodoystviya Rokotorykh a-galoidoketonov karbo-
taikliclieskogo ryada o trietilfosfitom i dietilfoeforistym
natriyez)
PERIODICAL: Doklady Akademii nauk SSSR, 1958, Vol- 121, Nr 4,
pp. 641 - 643 (USSR)
ABSTRACT: In the course of the past years the authors found that
the reaction of regrouping according to Arbuzov of tri-
ethyl phosphite with a halide ketones proceeds in a very
complicated way in the production of P-ketophosphinic acid
others. Apart 11rom the mentioned ethers mixed phosphoric
others are formed (Ref 2). Thus the investigation of the
first mentioned ethers was rendered more difficult and some
deviations of their chemical and physical properties were
Card 1/4 explainedt,(Rof 3). It proved true that the reaction according

On the Structure of the Products of the Interaction SOV/2o-121-4-19/54
Between Some a-Haloid Ketones of the Carbocyclic Series and Triethyl
Phoophite and Sodium Diethyl Phosphite
to Mikhaelis-Bekkir In the case of the interaction between
sodium diethyl phosphite and a-haloid ketones proceeds also
in a complicated way and that it also leads to the formation
of epoxy phosphinio acid ethers apart from the expected
others (Ref 4). In this paper the structure mentioned in the
title is shown. The ketones are: a-chloro-cyclohexanone,
a-ohloro-a-methyl oyclohexanone, a-ohloro-oyolopentanone
and others of bromine pyruvio &aid. The investigation of the
product of interaction between a-chloro-cyolohexanone and
sodium diethyl phosphite revealed (in contrast to Ref 6)
that it is neither an unsaturated ether of phosphoric acid
nor a phosphonium, cyclohexanone other. Its spectrum of
combination light dispersion does not contain the frequency
of the carbonyl group. These and other data show that this
product has the structure of a diethyl ether of epoxy cyclo-
hexane phosphinic acid. This assumption was proved by the
synthesis carried out by the authors (Ref 4). Thus it was
proved that the last mentioned ether was concerned and no
Card 2/4 a-phosphonium oyclohexanone. Somehow surprising was the

On the Structure of the Products of the Interaction S0V12o-12',-4-1()/')4
Between Some a-Haloid Ketones of the Carbocyclic Serles and Triet-,-1-i
Phosphite and Sodium Diethyl PhoSDhite
similarity between the constants and the spectra of the
combination light dispersion of the products of the two
phosphites mentioned in the title acting upon a-chloro-
a-methylcyclohexanone. The mentioned findings show the
complicated process taken by this reaction. It leads to
the formation of unsaturated phosphoric acid ethers, ethers
of epoxy phosphinic acids, in some cases, however, even
of.0-ketophosphinic ethers /Ref 4); this depends on the
nature of the haloid,, the conditions of reaction and the
substituting alkyl radicals6 There are 5 references, 5 of
which are Soviet.
ASSOCIATION: Nauchno-isaledovateltskiy khimicheakiy inatitut im-A 11.
Butlerova pri Kazans.kom gosudaretvennom universitete im.
V.I.Ulf yanova-Lenina (Scientific Chemical Research Institute
imeni A.M.Butlerov, State University imeni~V.I.Ullyanov-Lenin,
Card 3/4 Kazan')

5(3) SOV/62-501-1-7/30
AUTHORS: Arbuzov, B. A., 7inogra~ova, V. S., _Folezhayeva, N.
TITLE: Esters of P-Ketophosphinic Acids (EfiiY ~-ketofosfinovykh
kislot) Com~-nunication III. On the Structure of Products
Resulting From Interaction Between Certain Halojer Ketones
With Triethyl Phosphite and Sodium Diethyl Phoophite (Soob-
nhcheniYe 3- 0 stroyenii prodiiktov vzaimodeystviya nel~otorykh
galoidoketonov n trietilfoafitom i dictilfosforisty--i natriyeft.)
PERTODICAL: Izvectiya Akademii nauk SS37M. Otdoleniye khi~michenkikh nauk,
1959, Nr I I pp 41 - 49 (USSR)
A133TVACT: In the preceding papers (Refs 1-3) the authors found that
the enters of 0-katophosphinic acid synthesized in variniic
ways differ considerably as to their physical constants
as well as to their behavior towards dinitro-phenyl hydr,,.-
zine. The differences are particularly evident in'ultra-
violet spectra. The causes for these differences, however,
have not yet been made clear. In order to obtain preparations
as pure as possible the authors of this paper distilled pre-
parations earlier obtained as well as new ones in rectifica-
Card 1/3 tion columns with an efficiency of 17 theoretical plates.

Esters of P-Ketophosphinic Ac4ds. Co=,Iunication Ill. SOV/62-59-1-7/36
On the Structure of Products Resulting Prom interaction Bet-,rqen Certnln
Halogen Ketones With Triethyl Phosphite and Sodium Diethyl Phosphit,
The constants of the pure preparations are given in table
Ultraviolet absorption spectra were recorded by means of
the spectrometer SF-4 in riethyl alcohol solution. Ra,ian
spectra were recorded by means of the thr--e-prism spectro-
graph ISP-51. The investi,-ations carried out lj~Lve shown
the following data: on the effect of triethyl phosphite
on chloro and bromo acetone (beside isopropyl enter of the
diethyl phosphoric acid) as well as on bromoethyl ketone
esters of corresponding P-ketophoophinic acids are formod.
Products of potassium derivatives of phosphonium acetone
and methyl-phoqphonium acetone, rhich were synthesized by
methylation with metl-lyl iodide, possess the structure of
esters of the p-ketophosphinic acid. On the effect of
sodium diethyl phosphite on chloro and bromo acetone as
well as on bromo-a-brono-ethyl ketone esters of the epoxy
phosphinic acid are formed. Their strticture Yjas confirmed
by a synthesis carried out in anotber ray and by Raman
spectra. Contrary to Kreutzkamp's and Kayser's data, not
Card 2/3 the unsaturated isopropyl enter of pho.3phoric acid is

Esters of P-Ketophosphinic Acids. Com-:=ication 111. 50V/6.1-r,9-1-7/3,6
On the Structure of Products ReBulting From Interaction -`stv.~en Certsin
Halogen Ketones With Triethyl Phosphite and Sodium Diethyl ?hofphittc
produced on the effect of~ sodium diethyl phoophite on chloro
and bromo acetone, but the ethyl eater of epoxy-propyl
phosphinic acid as well a3 phoophonium acetone. The product
synthesized by the interaction of methyl-y - chloro-propyl
ketone with sodium dialkyl phosphite possesses the structure
of the ester of 1-methyl-tetrahydrofuran phosphinic-l-acid.
There are 1 figure, 2 tables, and 13 references, 8 of
which are Soviet.
ASSOCIATION: Nauchno-issledovatellskiy institut im. A. M. Butlerova
Kazanskoeo gosudarstvennogo universiteta im. V. I. Ullyanova-
Lenina (Scientific Research Institute imeni A. M. Butlarov
of the Kazan' State University imeni V. 1. Ullyanov-Lenin)
SUBMITTED: May 11, 1957
Card 3/3

50)
AUTHORS: Arbuzov, B. A.# Academician, SOV120-128-1-21156
Vinogradova, V. S., Polezhayeva, N. A.
TITLE:- Diethyl Ester of Cyclohexanone-2-Phosphinic Acid
PERIODICAL: Doklady Akademii nauk SSSR, 1959, Vol 128, Nr 1, PP 81-84
(USSR)
ABSTRACT: In the present paper the authors synthesized the diethyl
aster of cyclohexanone-2-phosphinic acid on the basis of
a,d'-dibromo cyclohexanone. By reaction of triethyl phosphite
upon a,al-dibromo cyclohexanone the diethyl phosphinic ester
of the enol form of. cyclohexanone-2-phosphinic ester (III) was
obtained with the following constants: boiling point
172-5 - 1730/2-5 mm; d 20 1.1885; n20 1-4652. This compound
0 0
was converted into the diethyl ester of cyclohexanone-2-phos-
phi~nic acid by means of ethyl alcohol. The molecular refract-
ion of cyclohexanone phosphinic ester is placed between the
values which were computed for the ketone- (IV) (57-06) and
for the enol form M (58.1l)- Figure I shows its ultraviolet
absorption spectra in aqueous solution (curve 1) in methyl
Card 1/2 alcohol solution (Curve 2) and in isooctane (curve 3). Figure 2

Diethyl Ester of Cyclohexanone-2-Phosphinic Acid SOV/20-128-1-21/58
gives the ultraviolet absorption spectrum in methyl alcohol
solution with content of sodium methylate. With the example
of the diethyl cater of cyclohexanone-2-phosphinic acid it
was demonstrated that a ketoenol tautomerism may occur in
phosphinic eaters containing a group of ketones in P-position
within the hydrocarbon radical present in phosphorus. There
are 2 figures and 8 references, 3 of which are Soviet.
ASSOC.IATION: Nauchno-iseledovatellskiy institut im. A. 11. Butlerova
Kazanskogo gosudarstvennogo universiteta im. V. I. Ullyanova-
Lenina (Scientific Research Institute imeni As M. Butlerov
of the Kazan State University imeni V. I. Ullyanov-Lenin)
SUBMITTED: June 5, 1959
Card 2/2

02
JA
u
I
is
IL
vo
is

ARWZOV, B.A.t'-TWGRJ%DOVA, T.S.; POLUUYNTA. N-A-
Isters of ketophosphonic &cids, Report No.53 Structure of
the ~ - to-of the interaction between certain mr-halo ketones
of the carbocyclic series, trietbyl phosphite, and sodium diethyl
phosphite. Isy,AN SSSR Otd.khim.nauk no-53832-841
My l6o. (MINA 13s6)
1. Xhimicheskiy institut ineni A.M. Butlerova Kazanskogo
gosudarstvannogo univereitet&.
(Ketones) (Phosphorous siaid)

84852
5"-'W>0 QT0 S/062/60/000/olo/oo5/018
B015/BO64
AUTHORS; Arbuzov, B. A., Vinogradova,.V.-.S.t and Zvereva, Lt. A.
TITLE: Esters of O-Ketophoophinic AcidP4 Information 6. Products of
the Reaction of Chloro- an Bromo AoetoneslWith the Diethyl
Eater of Ethyl Phoophintus Acid and With the Sodium Salt of
the Monoethyl Ester of Ethyl Phosphinous Acid
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 10, PP. 1772-1778
TEXT: The investigations mentioned in the title were carried out to
,-Ietermine the effect of an exchange of an ethyl radical directly bound to
phosphorus for the ethoxyl radical in triethyl phosphite, or in diethyl
phosphorous sodium. The reaction between chloroacetone and the diethyl
ester of ethyl phosphinous acid led to the mixed ethyl isopropenyl ester
of ethyl ph08phinouB acid:
Card 1

84852
Estero of P-Ketophosphinic Acids. Information S/062/60/000/010/005/018
6. Products of the Reaction of Chloro- and B015/BO64
Bromo Acetones With the Diethyl Ester of
Ethyl Phosphinous Acid and With the Sodium
Salt of the Monoethyl Ester of Ethyl
Phosphinous Acid
0 OCH
if/ - 1-12
C2 H5 F CH3 (1). Two products resulted from the reaction of
\0 - C2H 5
bromo acetone with the diethyl ester of ethyl phosphinous acid, and it
was found that one of them corresponded to ester (I), and the other
product was a mixture yielding two substances after distillation, one
representing the ethyl ester of ethyl acetonyl phosphinic acid,
0
C H I "1', 0 C2H5
2 5 - P ---CH C11 (II), and the other following one of the two
2 3
0
formulas:
Card 2

8h852
Eaters of P-Ketophosphinic Acids. Information S/062/60/000/010/005/018
6. Products of the Reaction of Chloro- and B015/BO64
Bromo Acetones With the Diethyl Ester of
Ethyl Phosphinous Acid and With the Sodium
Salt of the Monoethyl Ester of Ethyl
PhOBphinous Acid
0 0
0C2H5 0C2H5
2 5-P O-C CH2 (IV) or C2H5-F 0 C C HB r M.
CH2Br ___1 CH3
It is, however, necessary to carry out further investigations to verify
one of the two last-mentioned formulae. The reaction between chloro
acetone and the sodium salt of the monoethyl ester of ethyl phosphinous
acid leads to the ethyl ester of ethyl epoxy isopropyl phosphinic acid:
0C H CH
3
C2H 5-P-C-CH2 (VI). The Raman spectra (obtained from an Ocn -51
6 \~
Card 31AYV

84652
Eaters of P-Ketophosphinic Acids. Information S/062/60/000/010/005/018
6. Products of the Reaction of Chloro- and BO15/BO64
Brome Acetones With the Diethyl Eater of
Ethyl Phosphinous Acid and With the Sodium
Salt of the Monoethyl Eater of Ethyl
Phosphinous Acid
(ISP-51) spectrograph) and the ultraviolet absorption spectra (obtained
from an 0 -41~(SF-4) quartz spectrophotometer) of the substances obtainedv
which =ve hitherto not been described in the literature, and correspondin
steps of preparation are given. It is stated that the reactions
investigated by the authors proceed in the same directions as those of
triethyl phosphite and diethyl phosphorous sodium (Ref. 1). There are 2 gl
figures and 9 references: 5 Soviet, 2 US, 1 British, and 1 German.
ASSOCIATION; Nauchno-iseledovatellokiy inatitut ime A* Me Butlerova
Kazanskogo gosudarstvennogo universitsta (Scientific
-Research 14stitute M,__Butlerov of Kazan' State
Univerp_ity). Khimicheskiy inst~Gt ime A.' i-e-. Arbuzova
Kazanskogo filiala Akademii nauk SSSR (Chemical Institute
imen
Sciences USSR

ARBUWV, B.A.; VOOGRADOVA, V.S.; UKUWA, M.A.
Eaters of f-keto pbosFbouic aclds. Report SO.7: Products of the
reaction of co,-cblorocyblobe-ran ne vith dietbyl ester of ethylphos-
phonous acid and the sodium salt of the monoethyl ester of
ethylphosphonous acid. Izv. AN SSSR.Otd. khim. nauk no.11:1981-
1984 N 160. (MIRA 13:11)
1. Khimicheskiy institut Kazanskogo filiala AU SSSR t Khimicheekiy
institut im. A.M.Butlerova, Kazanskogo universiteta im. V.I.Ullyanova-
Lenina.
(Cyclohexanone) (Phoophonous acid)

r2495 3/020/61/137/004/019/031
610 zzoq 1157, 1) B1031B208
.AUTHORS9 Arbuzov, B.A., toademicianp V inogradoval V..S. and
Polezhayevap N.A.
TITLEa Diethyl aster of I-athoxy-oyolohaxone-l-phosphinic-2-acid
PERIODICALs Doklady Akademii nauk SSSR, ve 137, no- 4P 19611 855 - 858
TEXTs The authors prepared the diethyl eater of 1-ethoxy-cyclohexene-1-
-phosphinic-2-acid (X) in an indirect way, having previously (Ref. 1, DAN,
1219 641P 1958) proved that the eaters of cyolohexanone-2-phosphinic acid
could neither be obtained by the Arbuzov rearrangement nor by the Micha-
elis-tooker reaction (neither of these reactions is discribed). Therefore,
they used the diethyl phosphoric ester of the enol form of cyclohexanone-
-2-phosphinic ester (III) whose radicals were interchanged by ethanol
(Ref. 2t DANr 2-8v 81P 1959)- A comparatively low yield of the phosphoric
ester of cyclohexenol phosphinic acid, and a poor reproducibility of the
experiment induced the authors to study the causes of these results, and
to find better methods of preparing the latter ester. The reaction bet-
Card 1/4

Diethyl ester of ...
IU95
8/02 61/137/004/019/031
B103YZ208
wean dibromo-cyclohexanone and triethyl phosphite (Ref, 2) is complicated.
Conformation of the initial dibromo-oyclohexanons might be one of the causes
of thts complicated course of reaction. The authors therefore studied the
effect of triethyl phosphite and sodium diethyl phosphite on cis- and trans-
-2,6-dibromo- and on 296-dichloro-eyelohexanones. The following attempts
of synthesizing (III) failedt a) bromination of diethyl-cyclohexenyl
phosphate by bromosuccinimidet in which the resultant monobromide was trea-
ted with triethyl phosphite; b) Br
_OCOCH 3 OCOCH3
bromosuccinimide. (C H 0)3P
1 -2 5 e%
M 0
(c2R, 50)2 P-0 H 0
OCOCH 3- 2 1 ~(c 2E50)2 Th e main product was
(VII) (IV)
Cari 2/4

1119
2 5
9/071
S/020/61/137/004/01
Diethyl ester of ... B103/B208
diethyl-cyclohexenyl phosphate (I). ,1.F. Lutsenko and K~~
DAN
9 128, 89, 1959) reported the possibility of preparing ~'phosphone al-
dehydea~and ketones by adding pentavalent phosphorus to enol acetate. The
authors-have so far not been able tolfind suitable conditions foi this
reaction in the case of cyclohexanon~6 enol acetate. However, they rjyn-
thouized,M in an analogous waYi prbcooding from 1-ethoxy-cyclofiexene
(VIII) (see Scheme)
OC21 1, OCjH5 *j OC1111
1/.c
PCI.C-11,011
_-P
+PCI, PCIV PCIS 0
0-
(Vill) OX)
6 011 0 0
/CC2H3 . 1 11 P
(OC.-H,). -P (Oui~)'
rl\')-p (OCeHl)' tl.ql 0 H
0'
(XI jXI)
Card 3/4,

1.3/020/61/137/004JO19/031
Diethyl ester of ... B103/3208
By-addisig PC1 5 to (VIII), and by treating the resultant complex with 302?
they ob ained the acid chloride.(IX). Esterification of (IX) yielded the
end prott M. Saponification of (X) with acidified water. gave the
diethyl ester of cyclohexanone-2-phosphinic acid (XI). Raman, infrared CIR),
and ultraviolet spectra were taken for (IX) - (XI). The IR and R-azian
spectra of (XI) were in agreement with those of the ester obt&ined by the
authors by ester interchange of.(III) (Ref. 2). The authors conclude
from a comparison of the spectra of the resultant esters that equilibrium
is considerably shifted toward the enol form (XI) in their solutions in
hexane. They do not exclude the participation of*tI;e P-- 0 group in the
formation of an intramolecule-r hydrogen bond. There are A figures and 5
referenceat 4 Soviet-bloc and 1 non-Soviet-bloo.
ASSOCIATIONt Nauchno-issledovatel'skiy khimicheskiy institut imag A.X.
Butlerova pri Kazanskem gosudarstvennom universitate
(scientific Research In3titute of Chemistry imeni A.M.
Butlerov of Kazan,' Stqte University)
SUBMITTEDs December 16, 1960:.
Card 4/4

ACCESSION NR: AR4033714
S/0081/64/000/003/PO27/PO27
SOURCE: Referativny*y zhurnal. Khimiya, Abs. 31`216
AUTHOR: Vinogradovs, V, S,; Kofman, L. S.; Lukashine, V* M.
TITLE: Separation, desiccation and purification of C4 and CS hydrocarbons by
molecular sieves
CiTgD SOURCE: Tr. po khImli I khIm. tekhnol. fGorIkIR, no. 2, 1962, 268-276
TOPIq TAGS: hydrocarbon, hydrocarbon fractionation, molecular sieve; zeolite,
column chromatography, hydrocarbon drying, Isopentane, isobutene
ABSTRACT: Tests were conducted in 20-50 ml cylinders, 12-15 mm in diameter, fill-~
ed with synthetic zeo)ites. Separation of isopentane-pentane mixtures was Inves-
tigated at a material charge rate of 1.5 liters/hr. and a sorption temperature of
60-70C. All the varieties of SaA sieves quaranteedthe separation of pure isopen-
tane. From a 1-butene-isobutene mixture, pure isobutene was obtained but hydro-
carbon isomerization on the adsorbent was observed. The molecular sieves showed
high efficiency In monomer desiccation: the water content dropped to 0.0001%.
DATE ACQ: O2Apr64 SUB CODE: CH ENCL: 00
Card

(M it --I
--io-u-lic-li-C-O-D-E-:--~i/-6-0-0-0-"/--65-/-O-0,0--/O-0-0--/-0-268/0274
ACC NRI AT6M7558 (A)
AUTHOR: Uxbpg. G. V.; Vinogradova, V. S.; Komaroya, V. N. Kofman, L. S.
ORG: none
TITLE: Thorough removal of sulfur compounds from CA -C,-alkane
SOURCE: VBesoyuznoye soveshchanlye po tscolitam. 2d, Leningrad, 1964. Taeollty, ikh
sintez, svoystva I primenenlye (Zeolltg I, their synthesis, properties. and application);
materialy soveshchanlya. Moscow. Izd-Yo Nauka, 1965, 268-274
TOPIC TAGS: desulfurization, alkane, zeollto, adsorption Wkr-'t'COL~~N,
ABSTRACT: The report covers feasibilitieB of exploiting the unique sorption properties of
synthetic zeolites to develop an industrial process for the desulfurization Of C4-C6 Alkanes
and cycloalkanes used as source materials In the manufacture of high polymers. Emphasis
was placed on the removal of more Lptans%nd_~~hen~A isotherms for adsorption of various
substances, hydrocarbons, and sulfurous compounds by various types of zeolites were obtained
experltr.entally and processed graphically. Values for affinity factors, peak adsorption volume,
and other needed constants were calculated by employing equations which dencribo the volumet-J
ric filling of pores. Coadsorption of sulfurous compounds and Isopentane from the liquid phase
Card 1/2

L
ACC NRs AT6017558
was analyzed for ethyl mercaptan and their relative capacity for adsorption vvas determIned.
The coadsorption of ethyl mercaptan and cyclopentadienellwas studied in a dynamic environmelat~,
It was estabUshed that successive adsorption by NaA and NaCI zeolites represent a promising
method for simultaneous deep drying and fine desulfurization. of alkanes and cyclohexane. The
authors formulated zeolite regeneration factors and evolved an equation to doscribe the specif-
Ic consumption of displacer gas at various proem parRmetern. Orig. art. has: 11 figures
and I table.
SUB CODE: 07#11/ SUBM DATE: 290ot65/ ORIG REF: 007
C,,,d 2/2

L -06599-67 - Ewp (DAW (m)-----RMI(G ----------
ACC NRz AT6017557 SOURCE CODE: UR/0000/65/000/000/0259/0268
;AUTHOR: Vinogradova, V. S.; Kofman, L. S~
iORG: none
I
r,
iTITLE: Separation and fine purificat* n of h drocarbons used in the high polymer in-
dustry by means of synthetic geolites Or
~~Pa er lp~resented at the All-Union Conference on
Zeolites held in Leningrad, 2n , in 19 h
,SOURCE: Vsesoyuznoye soveshchanlye po tseolitam. 2d, Leningrad, 19G4. Tseolity, ikh
sintei, svoystva i primeneniye (Zeolites, their synthesis, properties, and applica-
Ition); materialy soveshchaniya. Moscow, Izd-vo Nauka, 1965, 259-268
TOPIC TAGS; hydrocarbon, molecular sieve, adsorption, desulfurization, ethylene, pro- I
pylene
1ABSTRACT: Separation of mixtures of unsaturated hydrocarbons and selective removal
lof sulfur compounds (hydrogen sulfide, ethyl mercaptane, CS2, thiophene), and water
frim olefinic feedstocks by dynamic adsorption on synthetic zeolites KA, NaA, CaA,
band NaX was studied. The separations and purifications were conducted in liquid as
well as in vapor phases. The saturated zeolites were regenerated with steam, nitrogen
l
or hydrocarbon vapors. Among the feedstocks studied were; commercial ethylene d pro
lene~jstreams as well as artificial blends containing butanes and butene isome , bu-
"je:
-itffad , isopentane, cyclohexane, and benzene. The adsorption isotherms we" measured
Card 1/2

L 06599-67
ACC NRI AT6017557
at 20-1000C. The experimental data were correlated using an empirical equation for
dynamic adsorption. It was found that, in general, separations and purifications were~
not due t(> the "sieve effect" of the zeolites but due to the difference in the polari-
zations and the polarizabilities of various molecules. It was found that proper con-
ditions for separations of the unsaturated hydrocarbons with different structures can
be worked out. It was also found that various sulfur compounds and water can be remov
ed from hydrocarbons stream down to only a few parts per million level. The possibi-
lity of such a fine purification is explained in tems of the great affinity of the
sulfur compounds and water to the polar zeolite surface. Orig. art. has: 7 figures,
7 'tables, 6 famulas.
SUB CODE: 07/
SUBM DATE: 290ct65/ ORIG REF: 012/ OTH REF: 002
2

-66 EWP(J)/EWT(m) WA
ACC NRt AP6012034 SOURCE CODE: UR766i6/6-5/16 /6~f/66~~J-0-10-21
AUTHOR: Arbuzov, V. A. (Academician); Dianova, E. N.; V-inogradova, V. S.; -
Shamsutffn- K-. 3 ;?.
ORG: Chemical Institute im. A. M. Butlerov, Kazan' State University ime ve is Ultyan
Lenin (Khindcheskiy institut pri KazaEs-kom gosudarstvennom universitete)
TITLE: Reactions of tri-(alphanynnoicouroal.) Phouhitel, othyl-di-tert-(beta Ibeta,
beta-trichlorobutyl) ~-hosphlte, and tri-kbeta,beta,beta-t,richlorooetliyl) phosphit-3
with chlcral
SOURCE: AN SSSR. Doklady, v. 160, no. 1, 'J!j~5, 99-102
TOPIG TAGS: orgaqc phos4oro2s coM~ound~tnh'lorine compound, ester, chemical reacti
ABSTRACT: Tri-(alpha-cyanoisopropyl) phoqphite'wac found to react with
chloral at room temperature, forming the di-alpha-cyanoiBopropyl ester of alpha-
hydroxy-(bota,beta,beta-trichlorcothyl)-phosphinic acid, splitting off methacryl-
onitrile. The reaction between chloral and tri-ter-(beta,beta,beta-trichlorobutyl)
phosphite produced di-ter-(beta,beta,bota-tr4-chlorobutyl)-Pllospl,,orous acid, which
in turn reacted with chloral to give the di-~ter-(beta,beta,beta-trichlorobutyl)
ester of alpha-hydroxy-beta,beta,beta-trichloreoth_vlphosphinic acid. The reaction
of chloral with mixed di-ter-(betatbeta,beta-trichlorobutyl)-ethyl phosphite pro-
duced the di-ter-(beta,beta.beta-trichlorobutyl) ester of alpha-hydroxy-beta,beta,
beta-trichloreoethylphosphinic acid and di-ter-(beta,beta,beta-trichlorobutyl)-
(beta,bota,-dichlorovinyl).phosphate. Another complete phosphite with electro-
negative groups in the ester radicals, tri-(beta,beta,beta-trichloroothyl)

L 2M773-56
ACd NR, AP6oi2O34
.. phosphite, reacted with chloral at room temperature to give the di-beta,beta,beta-
,'trichloroethyl eater of alpha-bydroxy-betapbota,beta-trichlorootbylphosphinic acid.
The reaction machaniona and infrared spectra of the reaction products are discussed.
ri I - . . I - 4 es.
g. art. has: f ig-u-r - [JFRS1 . -
0
SUB CODE: 07 / SUBM DATE: UJun64 / ORIG FEF: 005 / OTH REF: 003
e7,

ARBUZOV, B.A.; DJANOVP, E.N.; Vj~NOGRU_QYA,_V.,S,; SJWBUTDINOVAp A.K.
Nature of di-iX-cyanoisopropyl eater of phosphorous acid.
Izv. AN SSSR. Ser. khim. no.8:1389-1396 165.
(MIRA 18:9)
1. Khimicheskly institut im. A.M. Butlerova Kazanskogo
gosudarstvennogo universiteta.

T
V. I. v
V
black u dc- (m!ssllat e~pliode.-J after i05 years~.
g
I (MIRA 18:6)
;As-y~rL. 3 no.22.55 160-
(rachallnik - karid.mad. nauk
Klyev.

ARBUZOV, B.A.; POLEZHAYEVA, N.A.; VINOGRADOVA, V.S.; SHAMSUTDINOVA, A.K.
Prodncts of interaction of chloroacetone and 4)-bromoacetophenone
with diphenylphosphinic acid esters. Izv. All SSSR. Ser. khim. no.4.-
669-678 165. (MIRA 18:5)
1. Khimicheskiy institut, im. A.M.Butlerova, Kazanskogo gosudarstven-
nogo universiteta im. V.I.Ullyanova-Tenina.

~'-. ~ I -'! , - ~ ~ , 7 " r -,,

". . , ;. ";~,f ~', , '-. % . I . .
g- i

L U29-66 (IV)EWT.(l)IW~m)I-EPF(a)IrWP(J)I-r,,iA-(b)-21Y,4A(c) . RPL . ZdILWIROIRM - .
ACCESSION NRi AP5022930 UR/0057/65/000/009/1389/1396
661.718.1
4 kV
AUTHORt Arbuzov, B. A.-, Dianova, E. N.; Vinogradova. V. S..; Shamsutdinovag A. K.
TITLE; The nature of di-a p C
.yl.ester of phosphorous a id 4
SOURCE: AN SSSR. Izvestiya. Seriya khimicheakaya no, 8. 1965, 1389-1396
4~1
TOPIC TAGS: eater, phosphorous acid, IR spectrum
ABSTRACTs The structure of di-a-cyanisopropyl
C11% 0
C-O-P-Oll
/ \ H
Olffill
and tri-a-cyanl9opropyl esters of phospborous acid were invastleateC by TR spectrn-:
scopy. The TR spectra were taken using a fligler H-800 spcctrophotometcr. Tha 2000-
-3500 C;M-l ramge was investigated with an IKS-3.4 spectroptotometer. The IR opcctr-lum
LC.,,d lL3L-

L 1129-66
ACCESSION NR: APS022930
of di-a-cyanisopropyl ester of phosphorous acid is shown in fig.1 of the Enclo-
sure. To verify the structure, these spectra were compared with the spectra of
products from hydrolysis of the chloroanhydride of di-c-cyanisopropyl phosphoric
acid. It was found that di-a-eyanisopropyl as well as tri--ct-cyanisopropyl esters
of phosphoric acid contain an atom of pentavalent phosphorous. Orig. art. has:
5 figures, 1 -formula.
ASSOCIATION: Khimichaskiy institut im. A. M. Butlerova Kazanskogo gosudarstvennogo
universiteta (Chemical Institute, Kazan State University)
SUBMITTED: 24Jun63 ENCL: 01 SUR CODE: GC, OC
NO REF SOV: 003 OTHER, 007
Card, 2/3
VIM,-

L U2 9-66
ACCESSION XR: AP5022930-
EN CLOSURE f, 01
Fig. Is'
77

ARFWOV, V.A., akademik; DIANOVA, E.N.; VINOGRIBOVA, V.S.; SHAMSUTDINOVA, A.K.
Reactions of "z,i-(( 11
/,r-c~anoisoprcj:y~) phoFphite, ethyl-JI-tert-
( p I p , A -trichlorobutyl) phosph,lte, and trl-( A , g, -trichlo-
roethyl) phosphite with chloral. Dokl. AN SSSR 160 no.1:99-102
Ja 165. (MIRA 16.2)
1. Khimicheskiy lngtJtl,- Jr. A.M. Butlerova pTI Kazamkom gosu-
darstvennom univeraltote im. V.I. 1111yanova-Lenina.

L; -,rr I c
r a 0 Tia
7
sna--.E;u t d i nova, A
-I rn v ho s h,
Fe ac I
nc. 1 57- 4")
A.?; S-SSP. Doklad-
d;l FA i' la, i n
Abotract: -ille e a c t ton o", 0 d i 11-,. with 1, 2-(ill i o~~t; c 0 -
7 1) ne wr-~ n wt. 1 -'n It 1 'j r- r v a ive-5 1-,r.,
i 3C
Card 112

ACCESSION NR; AP5
5001947
compounds obtained in the reaction of dibromocyclahexane with dl~--
thylphoaphide proved tG bC the GQrC C-' 8 thOlge fOr' hcl teACt L(3n 3f R ~lm
dipthylphospliLde with t~rnm;np
i AT Naucano-issic-dovatel'skly 41natitut Im. A. M, Ntlerovn
Research Institlitml: Kazsrnkuzo znn,:~,. -
SUBM METED: ~)QKaq64 EVC L.- 00 SUB CODE: OC, GC
NO REF SOV: 005 OTHER. 007 JPRS
Card 2/2

ARBUZOV, B.A.; VINOGRADOVA, V.S.; POLFZHAYEVA, N.A.; SHAMSUTDINOVA, A.K.
Esters of 4 -ketophosphinic acids. Report I(o.12: St-ructuree of
the products of interaction of some armatic 0( -halo ketones with
triethyl, phosphite and sodium diethyl. phosphite. Izv.AN SSSR.
Ser.khim. no.8:1380-1389 Ag 163. (MIRA 16:9)
1. Nauchno-issledovatellskiy khimicheakiy inatitut Im. A.M.Butlerova
Kazanskogo gosudarstvennogo universiteta im. M.Ullyanova&-tanina.
(Ketones) (Phosphorous acid)

ARBUZOV,j &A.; YINOGRADOVA, V.S.; I-XJJXMAYLVA, N.A.; aIlAK3UTDINGVA, AA&
Estern oft-ketophoopw-nic acids. Report No,I.J: Action of didomethane (in
die'thyl e ro of acotyl- and benzoylphuphinto acids. Izv SSSR.
Ou"k-bi uk no.4:675-683 Ap 163. (141 016 t 3)
1. Khimiche*Vy institut im. A..-LWtlerova Kazangkogo gosudardt~enno&o
universiteta Im. V.I.Ullyawvap-Lenina.
(Phosphinic acid) (149thal2e)

'AT, Rj
V; TV
PHASE I BOOK MCPWITATION SOV/6246
Soveshchaniye po tsoolitam. lot, Lenlngmdj 2961.
Sintetiohookiye toeolity; polucheniye, iseledovanlye i primeneniye
(Synthetic Zeolitest Production, Investigationsand Use). Mos-
cow, Izd-vo AN SSSR, 1962. 286 p. %,(Seriess Itai Doklady)
Errata slip inserted. 2500 copies printed.
Sponsoring Agency: Akademiya nauk SSSR.\\ Otdolenlye khimichookikh
nauk. Komdolya po tooolitam. .,\
Resp. Zds.t X. M.~'Dublnln, Academician and\V. V. 3orpinakly, Doctor
of Chadcal-Solenoool Bd. t Ye. 0. Zhukove4yaj Tech. Xd. t S. F.
Golub'. 1~
PURPOSX: This book Is intended for scientists and~,~neors eagaged
in the production of synthetic sooliten (molecular sleves),-and
for chemists In general.
Card I/JW 41

Synthetic Zoolltess (Cont.) SOV/6246
COVERAGEt The book In a oolleotion of reports presented at the First
Conference on Zeolites, held In Leningrad 16 through 19 )kroh 1961
at the'Leningrad Technological Institute imeni Lensovet, and is
purportedly the first monograph on this subject. The reports are
grouped Into 3 subject areas: 1) theoretical problem of adsorp-
tion on various types of zoolites and nothods for their Investi-
gation, 2) the production of z9olites, and 3) application Of
zeolites. No personalities "a mentioned. References follow In-
dividual articles.
TABLB OF CONTZNTSs
Foreword 3
Dubinin, X. N. Introduction, 5
Card 2/4*

Synthetic Zeolites: (Cort.) 30V/6246
--)d L. 8. Kofttt,.-n. 1, of
,Vinogradova, V. S., J
ay-n ll-he+ Zoolites 99
Mirskiy,, Ya. V. The -.,f Wjittwlrig of Zeclitea 103
e
FIRODVI,~TION OF ZBOL-17"M
Zhdanovy S. P., and N. N. of the
Hydrothemal Syntlies-'s Condif-fons a.-ijdl of
Sodium Zeo--,'Ltea 105
Tsitsishvili, G. V., and T. G. And::,onlke.Ahv:.,A. Synthesis
and Some Adsorption Pr,-.ipert!.a!~ of Zeolites 117
Iru, P., 0. and 14. -and
Properties of 129
Card 6-742L *

Synthetic Zoolitest (Cont.) SMA246
Tonkonog, L. 0.0 K. V. Chmutov. Separation of Mixture*
of Ithyl and Methyl Alcohols on Synthetio Zoolites
_ 230
;~eeyeva. Application of Syn-
Vollf, N* B.P ~Al~ceeyeva.

Sol a
thetio C&A Zool a g Hydrocarbon Nixtur*~
,

33
YAtrofanov, M. 0., and Ya. V. Mirekly. Separation of
Petroleum Fractions on Synthetic Uolitee 236
Kelltsev, N. V., A. F. Starovoytova, and N. S. Torochosh-
n1kov. The Adsorption Method of Purifying Isopentane
From Admixtures of n-Pentane 239
Vino V. 3 and L. 3. Kofman. Application of Syn-
hatio Z*o as In Sopaftting and Purifying 3ynthetis
Rubber Monomers 245
Card APOAW-

VINOGRADOVA., V.S., POLEZHLYEVA, NA.
"Diethyl eater of cyclohexanone-2-phosphinic acid " its tautomerism."
aooUcatlur of 'f~
u-A., by irlazir -~Iz
Collectiun of *,he
(.~crristry of "orux)ljrl:iI

B/08IJ62/000/018/017/059
B144/B186
AUTHORSj Kofmanp L. 5.p Vinogrkdova_L V. S# Mitrofanova, V. B.
TITLEs Method of determining mioroquantities of dimethyl formamide
and dimethyl amine inhydrocarbons
PERIODICALt Referativnyy zhurnal. Khimiyat no. lap 1962, 127, abstract
18D173 (Vestn. tekhn.' i ekon. ififorfa. N.-i. in-t tekhn.-ekon.
issled. Gos. kom-ta Sov. 11in..SSSR po khimii, 1961, no. 11,
21 - 26)~
TEXTs A photometric method for the direct quantitative determination of
dimethyl formamide Wimpurities in hydrocarbons (HC.) is based on the
3+-
color reaction of hydroxamic acids with Fe ions. On reaction with
alkaline solution of hydroVl amine (II)p I forms hydroxamic acid (AA).
d'from HC by an alkaline solution of II.
Dimethyl formamide is extracte
To ensure a good contact between the HO and the shifill volume of extrac-
tive a special apparatus (shown diagrammatically)lia used in which the
HC vapors bubble continuously through a layer of II solution. To 2 ml of
II hydrochloride solution-in the apparatus 2 ml 30 N NaOH or KOH solu-
Card 1/3

S/081/62/000/018/017/059
Method of d6termining.e. B144/Ble6
tion and the HC sample contAining 0.3 - 1 mg Lare added, The mixture is'
kept for 40,min at 400C a~d. is then rapidly cooledi, whereupon 2 ml of
N HNO and.2 ml saturated solution of ferric-amm, onium sulfate are added
3
to it. The colored bottoi'layer is separated from"the HC layer and
'The mean error in the determination of I is
photometrically measured.,'
15%. To aitermine dimetfiyl amine (III) in HC the color reaction of III
with furfural (IV) is used?. III is extracted frod'HC with 0.1 N solution
of the acid, and 2.5 ml 0-1 N KOH solution with 1.5 ml of 25A solution of
IV in ethanol are added to 1-5 ml of the acid layer, then photometrically
measured for 30 min. The mean error of III determination is 5 - 10~6-
An indirect method of determining I is also desaribedl this is based on
I hydrolysis by acid and on determination of the III formed- 5 - 100 ml
HC is kept in the above-mlentioned apparatus with 5 ml of 10/9 B230 4 at
600C for I hr. The content of the apparatus is cooled, the acid layer is
drained off into an.apparatus for the distillation of III (figure is
shown), the.HC layer is washed with water and added to the acid solution
of 111, 20% KOH solution is added until the mixture turns alkaline, III
is distilled by air into &.container with 0.1 N-acid and photometrically
Card 2/3

S/001,/62/000/018/017/059
Method of determining... B144/BI86
determined as described above. The mean error in the determination of I
is 15 - 20~. For the separate determination of I and III in HC, III is
determined in one HC sample and the I+III content in another sample.
Content I is calculated from the difference. (Abstracter's notet Com-
plete translation
r. n
Card 3/3 ac

AK-UZOV, B.A.; VINJOIRAA)VA, V.S.; POLEZ11AYLVA, N A.
Esters of r -ketopbosphinic acids. Report ho.10: Diethyl ester of
2 _ -j anone-l-phosphinic acid. Izv. AN SSSR Oto.khim.nauk
no.l.:71-78 Ja '62. (MILU 15:1)
1. Nauchno-issledovatel'skiy khimicheskiy institut im. A.M.Butlerova
Kazanskogo rosudarstvennogo universiteta im. V.I.Ullyanova-Lenina.
(Phosphinic acid)

ARBUZOV, B.A.;-VINOGRADOVA, V,Ss; POLEZHAYEVA, N.A.
Esters of f -ketophosphinic acids. Report Ilo.8: Reaction of
2,6-dibromocyclohexanone with triethyl phosphite. Izv.AN SSSR.-
Otd.khim.nau), no.11:2013-2020 14 161. (MIRA 14:11)
1. Rhimicheskiy institut im. A.M.Butlerova Kazanskogo gosudar5tven-
nogo universiteta.
(Gyclohexanone) (Phosphorous acid)

ARBUZOV, B.A.; VINOGRADOVA, V.S.; POLEZHAYEVA, N.A.
Esters of ~-ketophosphinic acids. Report Ko.9: Reaction of
2,6-dibromo- and 2,6-dichlorocyclohexanone with one and two moles
of triethyl phosphite. Izv.AN SSSR.Otdkhim.nauk no.11:2020-2028
N 61. (MIRA 14-11)
1. Kbimicheskiy institut im. A.M.Butlerova Kazanskogo gosudarstven-
nogo universiteta.
(Cyclohexanone) (Phosphorous acid)

KOROTNIMA, D.Sh.,,- VINOGRADOVA, V.V,; KAREUMAj, G.G*
Copolymerization of unsaturated orgamphosphoruo compounds.
Kauch.i rez. 21 no./+:1-3 Ap 162. OMA 1534)
1, Voeooyuznyy nauchno-isoledovatellokiy institut sinteticheskogo
kauchuka.
(Phosphorus organic compourAs) (Polymerization)

BORISOV, S.N.; VINOGRADOVA, V.V - LYASHKTO, I.N.; NAM-ETKIN, N.S.;
CHMIYSHEVA, . .
Addition of cyclic siloxanes containing Si-H bonds to unsatumted
compounds. Izv. AN SSSR Ser. khim. no.12:2230-2232 D 164
(MIRA 18;1)
1. Institut neftekhimicheskogo sinteza imeni A.V. Topchiyeva
AN SSSR i Vsesoyuznyy nauclmo-issledavateltakiy institut sin-
teticheakago kauchuka.

3/081J63/000/004/018/051
B166JB186
AUTRORSs Kalabinat A. V., Filippovat A. Kh., Akeerienko, R. A.,
Latishevay Fjo:S.t Yjno~~~~ # ZhIdyayevap L. M.
TITLEt Studies in the field of synthesis and conversions of vinylaryl
eaters. No. 22. Synthesis and certain cc-aversions of vinyl
eaters and acetals of bromophenols
PERIODICALs Referativnyy zhurnal. Khimiya, no. 4, 1965, 238 - 239, alt-
stract 4ZhI23 (Izv. Fiz.-khim. n.-i. in-ta pri Irkutskom un-te,
Y. 5, no- it 1961, 120 - 130)
TEXTs Vinylation of 2-bromophenol (I) and 4-bromophenol (II) by the Favor-
skiy - Shostakovskiy method (initial pressure *of acetylene 18 - 28 atm
210 - 2200C9 30 - 45 min) in the preaence of a large quantity of KOH or RaOH
and with high dilution of the reaction mixture with water (sometimes with
dioxane added) made possible the synthesis of the vinyl eater of I,yj.eld
40%, b.p. 93 - 940C18 mm, Hg, n20D 1.5676, d 420 1-4379, and the virtyl uster
of II ~III), yield 12 - 52%, b.p. 215 - 2160C/728 mm Hg, 109 - 1100C/11 mm,
98t n2 D 1-5685, d 420 1-4366. The addition of I - II to aliphatic and
Card -1/3

3/081/63/000/004/018/051
Studies in the field of synthesis... BWAW
aromatic vinyl esters (with thorough stirring in the presence of 2 - 4 drops
concentrated HCO gave a series of CH CH(OR)ORI acetale (IV). Below
ate givens the initial' vinyl ether, quantity in moles, the initial phenoll
quantity.in moles# reaction temp. in 00 and the reaction time in hre, R and
RI in IV# yield ~q bepe in OC/mm Hgp n20 D and d 420 8 vinylethyl ether (:V),
0-430t 1, 0-300t 85 - 90, 1.5, G2H 5P O-BrC6H 4' 40t 135/15, 1.5223, 1-3208;
Vt 0.120, No 0-058, 70 - 75, 1-5, C2H V n-Br06114(Ilia), 124 - 125/8, 1.5308,
1-3463; vinylbutyl ether, 0.679, 11, 0-5799 75 - e6, i, c 4H9p n-BrC6H4 (M),
38, 155 - 156/17, 1.5051, 1.2364; vinylphenyl ether, 0.167, 11, o.167, 70 -
80, 2t C6H5' n-BrC6114 1 47.1, 171 - 173/6, 1-5631, 1.3784; 111, 0-115, 11,
0-104, 70 - 60, 2, n-BrC 6H 4 ('Vc)t 55t 216 - 217/8, m-P. 460Ct 1.6025,
A study was made of substitution of the Dr atom in III and IV by ethyl a d
ethoxyl groups. Experiments to hydrolyze III and IV with dilute alkali to
the respective vinyl esters of the phanols (in an autoolave, 220 - 3000C, in
the presence of Cu2cl2 and Cu shavings) were unoucceseful. To 5~ mmoles
Wa in 20 ml oryoscopic C696 were added 0.08 moles C,H 5Br and 0.13 Moles Na,
Card 2/3

5/08 1/631000100410181051
Studies in the field of synthesis ...
which was thoroughly stirred for 2 hre at 60 650C and then left to stand
for ,j 12 hre, whereupon it was filtered through glass wool and distille,i,
to give IV (R - C29 9 RO. n-C 2H506H4) (IVd)q'yield 60%, b.p. 93 - 940C/16 mm
Hg, n 20 D 1.10060
.F d4 0 0-9851- 5 g IVd and 20 ml 20% H 2s04 were heated Tor
3 hre at~jIOOOC to give 4-ethylphenol (VI)j yield ea%, b.p. 93 - 95OC/7 mm
Hg, n2oD 1-5240. In the optimum experiment 0 '-054 moles IVbp 0-079 mcleis
C2H5Br and 0.13 moles Na in 200 ml C6H6 were heated for 2 hrs at 800C and,
as stated above, IV were separated (R - C 4H9p R1 - C2 H5C6H4), yield 8%, b.p.
140 - 1420C/17 mm Hg, n 20 D 1.496o, d420 0.9275- Under similar conditions
(85_- 900C, 2.5 hre) the vinyl eater of VI was produced, yield 10%. b.p.
92 930C/18 mm Hg, n20D 1.5148. A mixture of 0.077 molea 111, 0.117 moles
dry C H oNat 10 ml C H and 50 9 Cu filings was kept at 3300C for 6 hrs;; it
2 5 6 6
Was then washed with 10% alkali and 4-ethoxyphenol vinyl eater was separated
by distillations Yield 40, b.p. 101 - 1021C/3 mm Hgj n20D 1,5232. See
abetraot 4Zh122, [Abotracter's notet Complete tranolation.]
Card 3/3

;~4 22 30 22'
L!, L
TIT LF~ Arld tion of c v 7, r~ f o n ds o I-I Tj s 'ii
T)n I; r, ds
SO 1-1
lo n in III T',i' ~C dUC-f
synthe s i s
(-ard

A C C ESSIC) N P
0 rig -art I
ASSOC 1 AT 110
Card 2/2

gyA
_UNpg~W
VOROBIYEVAp O.V., kand. takhn. nauki J__jjyt,_j~2h*
metal oxide films on glass with unif0m and variable
resistance. Stek. i k-,. 20 no.8sl3-15 Ag 163 ZMIRA 16t11)
1. Gosudar5tvennyy institut oteklao

311175
S11 38/6' 2/000/-'04 /Go I /C~-
AOIji/M26
11,2-91-9
AUTHORS: Korotkina, D.Sh.; Vinogradova, V.V.; Karelina, G.G.
TITLE: Copolymerization of unsaturated phosphor-organic compounds
PERIODICAL. Kauchuk i rezina, no. 4, 1962, 1 - 3
TEXT: The effect of the phosphorous atom on polymer properties waz in-
vestigated and a comparison was made of the sodium-butadiene and acryl rubter
properties with those of similar polymers containing phosphorous in the side
chain. Me ethers of allyl-, butadiene-, isoprene -styrene -phosphene acids viere
used as the phosphorous- containing monomers in the experiments. 7he 03H- L!
(FEK-M) photocolorimeter was used to determine the phosphorous content in -.he
initial products and polymers. Me introduction of the phosphorous atom into the
polymer chain of the sodium-butadiene rubber was found, in most cases, to Improve
considerably the physico-mechanical properties of the vulcanizates at low Temper-
atures, as compared to the sodium-butadiene rubber produced by the emulsion mth-
od. The properties of the acryl polymer were considerably improved at low ternper-
atures upon introducing 1% of phosphorous into the polymer. 11,e following con-
clusions could be drawn: the ethers of the unsaturated phosphene acids ccpolyrer-
Card 1/2

Copolymerization of .....
S/138/62/000/004/001/CZ8
A051/A126
ize with the butadiene and butylacrylate, forming rubber-liko and liquid poly-
mers. The introduction of the phosphorous atom into the polyner chains of the
sodium-butadiene and butylacrylate rubbers improves their properties at low
temperatures, increases the resistance to various solvents and, in some cases,
increases the physico-mechanical indices of the rubbers. There ara 3 tables.
The reference to the most recent English-language publication reads as follows-.
3.M.C.Cormack, Pat. USA 2671078, 2671079, C.A., 48, 6738 (1954).
ASSOCIATION: Vsesoyuznyy nauchno-issledovatel'skiy institut sintoticheskogo
kauchuka (All-union Scientific-Re search Institute of Syntheti2
Rubber)
Card 2/2

MIN IR
L17466---Q Fiip (q) I Fw-, 1~ /Bx-A Fq- -h WH
ACCESSION NRt AP3004689 S/0072/63A00/008/0013/0015
AUTHORSt Voroblyeva, 0. V. (Candidate of technical sciences);,.~fino-
_gradova, V, V, (Engineer)
TITLE: Metallic oxide-coatingB on glaaskith uniformly-alternating
:resistances K I
_00
__.___._S0U.RCE#.______Steklo i_keramIka._,___no.---8,, lq63P_13_l5_-_________
TOPIC TAGS: metallic oxide glass coating, tin dioxide, antimcny
'ABSTRACT: Authors studied samples of SnOq filma.modified by snall
.admixtures of Sb. The films were deposited on VVS1-'tlass. The film_
forming solution was sprayed on. The treatmerff--d-onditions of the
'glass, amount of fi2m-forming substance applied In a unit of time
and other conditions were identical for all test samples. X-ray
analysis revealed that the interplanar distances of the analyzEd sub-
stance coincide with the corresponding values for SnO2. The relative
4ntensity of the diffraction lines is identical for all samples In
the X-ray picture. Authors conclude on the basis of these hndings
that the primary orientation of the SnOj crystals is identical in all
Card 1/2

L 17466-63
ACCESSION M - AP3oo4689 ing jei.
samples and does not depend upon the angle of the film-form
,Determination of the electrical parameters of the samples showed that
ithe specjf.~c resistance of the coating rises in proportion to the in-
:crease in angle of slope of the jet. Measurement of the thlclne3S Of
the coatings bore out the assumption that change in resistance L3 de-
pendent upon the varied thickness of the coatings. The film thick-
,ness is decreased in proportion to the fncrease In the slope of the
:Jet. The transparency is also reduced in this case. Authors con-
!elude that it is not always advantageous to use slanted jets to ob-
Itain a coating with uniformly-alternating resistance. Orig. art.
:has: I figure and I table.
.ASSOCIATION: Institut stekla (olass institute)
:!SUBMITTED: 00 DATE ACq: 28Aug63 ENCL: 00
SUB CODE: MA NO REP SOV.-, 000' OTHER 1 000
Card

V I t4 Cj 6, $2, A - 0 Q '~ I-A ~) Y2
VINOGRADOVA, Te., insh.
,a . W WAWN-NOW
Leather tochnolog7w b7 IU.P.Zybin [profJ Reviewed by I.Vinogradova.
Leg.prom. 16 no.10:52-53 0 156. (KrRA 10:12)
(Leather industry) (Zybin, ru.p.)

V1,110GIU0,11A. Y~.
"The Action of Diazobenzene on Alkoylacetylacetic
Esters as a Wans of Obt-E-ining the Freny1hydra zones
of -Ketonic and -Amino Acids" Part II. "The
Synthesis of Phenylallanine," Zhur. Obshch. IlChim, 10,
No 31 1940. Laboratory of Albumen, Academy of Science
W,'.R. Received 29 August 1939.
Report U-1526, 24 Oct. 52.

VINGGRADOVA, Y-S,
"The Synthesia of the Phenylhydrazone of
Phenylpruvic Acid from Dmzylmalonic and
Benzlcyanacetic Esters" Flart. 1:1. Zhur.
Obsch. Khim, 10, No 3p 1940. Laboratory of
Albtunen, Academy of Scinces U&~R. Roceived
29 August 19391
Report U-1526, 24 Oct 52.

VIROGRADOVA, Ye.
Metody Opralelenita KontzentrRtzil Vodaro4ykh Tonov 04thods for DetermirAng
Concentrations of Hydrogen Ions) (?aper edition)
119 P. 600
SO: 7our Continent Book List, April 1954

- I--------
--- VINWTZADOKA~jt. ~--FMFILAKTOV, - V. - --- -
"The Synthesis of the Phenylhydrazone of Phenylpyruvic Acid from BenzylMlonLc
and Benzylcyanacetic EBtera" Part IV. Zhur. ~%sch. Khim,, 10, No. 3, 1940.
Laborator7 of Albumen, AcadeaW of Sciences USSR. Received 29 August 1939.
IM Report U-1526, 24 Oct 52