SCIENTIFIC ABSTRACT VISHNEVSKIY, K.P. - VISHNEVSKIY, N.N.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001860030009-4
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 99
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 9
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

VISHNEVSKIY, K.P., inzh.
Using computer techniques to calculate cyclic water-stknply systems.
Nov. tekh.zhil.-kom.khoz.; Vod. i kan. no.2s4-14 163. (MIRA 17 19)

VISHNEVSKIYP K.P., inzh.
Calculating water ha;mmer using electronic com-puters. Yod. i san.
tekh. no.9:1-5 S 164. (MIRA 17:11)

B 1 WEI 80
.1
AUTHORSt Antipin, L. M., Vishnevskiy, L. D., Zhigach, A. F.,
Popov, A. F.
TITLEt Chemical activation of aluminum powder by triisobutyl
aluminum
PERIODICALs PlaBticheskiye massy, no. 1, 1963, 73
TEXTs The effect of activation conditions on the conversion of rAIC-3
(PAK-3) aluminum powder was studied, as also on the productivity of the
direct synthesis of triisobutyl aluminum (TIBA). The test conditions
weret Al:TIBA 0-45-0-48; activation tLt -30,t4O atm for 3 hre; synthesis it
150,1600C and 120-80 atm until complete qonversion of the aluminum.
Maxiluium productivity of the synthesis was reached at 1950C, the yield
decreasing with a further temperature rise up to 2300C. The synthesis is
improved by longer activation. The synthesis time,depends on the
ADTIBA ratio. Optimum activation conditions are: 160-1950C, 10 hre,
30 atm, in which case, the synthesi -can be carried out at reduced
pressure (60-45 atm). The method is-Bimple and requires no special appa-
ratue and can be used to produce reactive alum#um industrially.
C;ird 1/1
9/191/63/000/001/016/017

ZHIGACH., A.F.; POPOV, A.F.; VISHMSKIY, L.D.; ANTIPIN, L.M.
Direct sy'~theais of triloobutyl abmi-m. Khim.prox. no.1:24-26
ja 162. (NIRA .15:1)
(Aluminum orgenic compounds)

"CV11---3-' --,I ~
U.~
1. T _7 0 F Izmaillskiy, V.A., Vishnev3k-iy, L.D.
Aboor-tion. j t) 4
Ac'.1 en Vol III, I'
C) U
kBSTRLCT: Varicus structures with chromophoric systems have becn in-
ve3tik;ated. The anilide of the 9-acridinic-propionic acid and
the n-anisidide of the same acid are only slightly differ-
entiated in the spectrum. With the transition to acridinic
oalts the coloring becomes more intensive. The ethyliod'-da
of thu anilide is intensively yellow, but the ethyliodid'~ of
n-unisidide is dark red. The color may become violet or biLe
in some cases, if the electron supply is increased.
There are 2 graphs and 6 references, 5 of which are Soviet anl
Car-1 '11112 1 Amorican.

Spe(-,tra of AbuorFt4cn and Rceflection of Anilide.,3 of the
Acid
P. Poter-kina
ASSOCIATIOV: 'j,',oskovskiy Ped:L`O;'-i(;,`,eokiy inotitut imeni V
PcdcgoCic In3titute Imeni V.P. Potemkin)
SUBMITTED: Arril 25, 1958
Card 2/2

33440
2 2 0 9 S/064/62/000/001/003/008
B110/B138
AUTHORS: Zhigach, A. F., Popov, A. F., Vishnevskiy, L. Antipin,
L. M.
TITLE- Direct synthesis of triisobutyl aluminum
PERIODICAL: Xhimicheskaya'promyshlennost', no. 1p 1962, 24 - 26
TEXT: Triisobutyl aluminum (1) was directly synthesized according to
Al + 2A1(i-CHj3 + 111,11, ~ Mff(l-qH~),
3A1H(1-Q4),-F3CH,=CH(CH3)j 3A1(J-C4H$)3
A1+ p/jHj+3G1%=G1(CHJj AI(I-rH,),
As isobutylene hardly reacts with I, the reaction can take place in one
stage. It has been achieved by L. I. Zakharkin, 0. Yu. Okhlubystin and
V. V. Gavrilenko (Ref- 4t Izv. AN SSSR, OKhN, 100, (1957)) at 130 - 1400C
and 150 atm with almost quantitative Al conversion and by other
investigators at variorus temperatures and with lower yield. The authors
studied the effect of pressure and temperature on Al conversion, output,
Card 1/,0,-

33440
S/064/62/000/001/003/008
Direct synthesis of triiso'butyl... B110/B138
and optimum reaction conditions. They,used Al powder type 7;-~-3 (PAK-3)
(-,.)-T5194-50 (cOST 5194-50)) ground for 50 hrs in an r-10 (14-10) vibratory
mill, isobutylene (11) (0.001-'-; by weight of aldehyde, 0.045','b by wei ht of
isobutyl alcohol), and rubber solvent spirit ['~"-443-56 (GOUP'443-Z' An
Al solvent spirit suspension, I, and 110were synthesized in a rotating
(2 rpm) 2.5-liter autoclave at 80 - 165 C with H 2passing through, until
the pressure ceased to drop. Al conversion increased with the temperature.
At low temperatures, the synthesis took 1-5 - 3.5 hrs with Al conversion
-50j'3. Al conversion increased from 33.2 to 71.0';o with H2pressure rising
from 31 to 60 ati.,, reaction time 6ecreased from 10 - 3-3 hrs, ahd the output
increnued from 7.4 to 78.3 g/kg-hr. Further pressure increase caused no
more changes; so 50 - 60 atm is taken as the optimum. 0.41 - 0.57 kg of
finely dispersed, active, ground Al in the solvent, 0.35 - 0.36 kg of I
dissolved in 1 - 2 kg of solvent, and 3 - 4 kg of 11 Were put into 0
autoclave 3 and stirred under an H2 pressure of 40 - 60 atm at 1,110 - 150 G.
'Jaximu.m R'2absoiption (4 liter/min) cas obscrv~-!! after I br. .'.ft-ar
absorption, resi:Iual H and II 7ere passed throuL-,h 1, an,!- II
Card 2/1 )> 2

33440
S/064/62/000/001/003/008
Direct synthesis of triisobutyl... B110/B138
The reaction mass was passed into centrifuge 6 via 5. Average Al
conversion was 81.9~6, and the consumption of raw material somewhat exceeded
stoichiometric amounts. There are 2 figures, 3 tables, and 9 references:
5 Soviet-bloc and 4 non-Soviet-bloc.
Fig. 1. Flow sheet for tiiii3obutyl aliminum
Legend: vibra mill; (2) and (5~
vessel; ~41~ coolerto'76) centrifuge; (7)
solution; (a) nitrogen; (b) aluminum;
transferring medium; M isobutylene;
isobutylene solution; (k) isobutylene.
production.
portable vessels; (3) reaction
collector for triisobutyl aluminum
~c~ benzine; (d) hydrogen; (e) beat-
kg) ammonia; ~h) slime; (i)
Card 3/0

VISHIIT,NSKIY, L.D., kand.khim. nauk
.
I Conference dedicated to organoaluminum compounds. Zhur. VKHO 8 no.6:
691-692 163. (MIRA l7t2)

VISHNEVSKIY, L. D.
Cand Chem Sci - (diss) "Spectra of absorption of sal-c of 2-
phenylquinoline and acridine and their molecular complexes
with amines." Moscow, /-Pub. Academy of Sciences USSR7, 10,61.
20 pp; (Moscow Order of Lenin Chemical Technology Inst imeni
D. I. Mendeleyev); 245 copies; free; (KL, ?-61 sup, 221)

ZHIGACH, A.F.; POPOV, A.F.; VISHNEVSKIY, W Yb
a - _ ~..D. 1.. 1. KOI E 'V, N. 11.
Direct synthesis of triethylalumimm* Khimeprom. no-4.-249-253
Ap 16L, (KUu- 14:4)
(Aluminum)

s/o64/6i/000/004/002/003
B110/B207
AUTHORS: Zhigach., A. F., Popov, A. F., Vishnevskiy, L. D.,
Korneyev, N. N.