SCIENTIFIC ABSTRACT VOLKENSHTEIN, M.V. - VOLKENSTEYN, M.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001860510018-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 18
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

VCL I KII11S,11TEEIN, 14. V.
I
VOLIKENSETEDN', N. V. CA: '217-16j54/6
J. E;cFtl. Theoret. Fhys. (US"-:R) 211, 642-62 (1-041)
Intensities in vibration spectra oil polyatomic molecules.

VCK,nJ-!SH,T-F,INy F. V.
FRILEMAYEVA, E. I-, SYYPUXI~;', Ya. K. and VCLII~,-;:'SH~EJIN, I-'. V. cl:
i - --ll -
(Karpov Inst. FlivsIcal Chemistry, Voscow; State Univ., NAnsh)
Acta Physlocochim. URSS 14, 110-53 (1941) - in EnF~Iish
The Raman spectra of the halogen derivatIves of ethylene and the
electronic resonance.

111 0 0 0 0 0
0 a 0 0 0 111 0 0 0 0 111 0 0 4 ~66

L to I-,

V. v,,Iksa.

-.
"trin (C-Pl. rfotd. Acad. Sci. U.R.S.S..
-
-
1941. 00. 791
7
V
4
A
) -00
'emfemPidW method Is developed for the calcut&tion Gj
in
e
t
n
$
j
tk
s
--9
in infra-red and Raman spectra and the degr- O(depolaxisati.u of
Raman lines from data for the Kerr effe". intcrat. distance_
ylbration wr. Ca1c. and obtcrvod intensities for CII.Cl.
a
0
t
actorily.
",
0

00
00 _-w IF
00

00
.00
::)D 0

A S a L A jTAt,UPIKAL LITERATLAIE CLASSIFIC4TICH Cz

u it to to to w X it $1 12 PC t, rt t, 11, All A 1 8 Od 'I ar
tLo A a
0 0 0 0 0 0 0 0 a 0 0 0
0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 a - G - I
4 0.0 4 0 0 0 0 41; S 0 0
0 0 0

polar"bility of subcal" MW iniermaimew" form. m
V,UlkCn%ChtCiD (Coompl. r.-xd. Acad. Sti. U.ICS.S, 194). St.
IM).-Z-1-lithiMitical. Cnmideration of the effect of anharmovicitv
alid anhuArojy in electronic oscillators predicts chansces in moi.
con%ts. s4jkMLtml with the ani%otrolsy of the Itolartmbility t(tufter.
withoteChAng') in refrACtion. a* found rxpvrtmrntAtly (nr the KvtT
rtfe,ct and lopoku-ination of Rayleigh scattrring. ,the 1~
allfied to Iturnan inten.itiv-s. L J. j

1
VOLIY~EMSBTEIY, M." V.
VOL'KENSHTEIN, 11. V. CA: 37-1`267/0
(Karpov inst. of Physical "hemistry, Yoscow)
Acta Physicochim. LRISS 16, 120-2 (19/,2) - in -"n-r-rlish
Intensity of Raran lines and the nature of the chemical bond.

~~M -. - - . , I ~~ :1 ... - - - I - - 0~ - Eba , , -
VOL IKE N'SlITET1,1 I E. V.
SLOVIKHOTOVA, E. A., SYRTITI, -YA. Y. and
(Karp Inst. Physical gheruist_ry, ll';Oscow)
Compt. rend. acad. sci. URSS 2~, No. 1-5, 11j.6-8 (.191,2)
llprnn spectra of betaine.
1--. V. CA: 3-/--,A-55/'7
in Enj7liEh

-1,01i.111-MM - . - ~ff - ~ - I. . . . . . . . .- - NEU[
VOL'1MTSHT3YN11 V. V.
Physico-Chemical Institute imoni L. Ya. Yarpov, moscow (-1941-)
"Preliminary Reports - Intensity of the Raman Lines and the Nature -of the Chem-1cal Bond.1,
Zh-ar. -Fiz- Khim-, Vol. 17, No. 1, 1943
01-52059019
-1

& a
L L a
A ,L-
- I
AL-AL _f 9 -1 Q 90 it
t L it. A I S J,

Ise< 96111 09~.P#& ?4j

flos *I RAms Uses &ad the tonn
if T(hratio". W. A. IA yasbevich and M. V.
Vol tela. Compt. r&4. ac". sci. U. R. S. S. 41,
-F
nber theoretical stuslin
i
R
(I
b)
-00
.
n
a
u
ug
)
heo
of
l
it
ti
d b
i L
h
dditi

v
w
ca
e
t
t
e a
y sc
op
t
It is Concluded that the de-
(C. A. $7, ATj
-
;dI
don factor widual bonds may wary troca zoo
va Ce to 4/1 got I)ure
1eD
Nuall values f%
P
;:"
=
=
0
,
we wt"n
defamation vi
Iar
.
r%b
a
for vwkpu bonds in a no. at halageamed derivs. of CH. 0
awC*H4,MeSH,EWwWSOt. The form coasts. gener-
Zoo
ally referred to In the UtemWt usually have little to do
with ramut despite good agreement bttwev. calcd. and
l
owqwncim The form of vibration, mil kenew
maourod 1*0
the p values and Intensities. an t2trondy Wnillive to
Chang" in the force Consts. W. P"Ty

A I aI LA WrALLUVOCAL UTERATWIt rLASSWKATIGN E Z"

-
' 1

0 Al 10 10 L S 8 Ow 0

. 11 w A I at 5 4
It U
V
3

0 * *10 0 0 0 0 0 0 0 a 6 0 0

4w 15, _* 'OF 0 W* ; ;-; W* a V _WW w ip w
A- a _#t~ _A-A A,
IS? A
"OCC6116 A&P ONVOCOVA$ I.VFA M.T 0..0
14F
77
so. 1294 kNALYS! S OF L q-ID E~- T117" VJET'I~D V
*0 1 "A TI r 11 710X9 n~kk e, V and
kqkrA, I
.002 ihorygln P P (Trudy Vs-soyuz. Kon--erentsii' Manal. I
,~ 0 a -00
Yhiin., Akad. Nauk. _S.3.3.R. 1944, 3,, 90-104;,
Chem. Abst. 1944, 38, 5664). Data are~preoented
in tabular form on frequencies an*l intensitlea or
Oz
namar lines In the anaXy3is of various ty as of ego*
and
7aku ?etroleuin, cracked ig.-Itsoline (Groznyi~
cracked paraffins. Ihe Raman spectra affcrd =00
Ood
satisfactory qual. Informaticn and give promise
for qua-t. analysis by further improvement of E 0 a
technicues. ; a**
VV 11151'.
M.SLA- -litTALLMGICAL UTERATtAff CUWICATfQ*
via,"
SWICUO wit any Ogg IIJLtjll C49 GRY LS1
An t a II It I V0 9 op a
3 Al 1~'11, 0 4 . .
1 0 ty &to W.
0 0 0 0 0 0 0 We 0 0 0 a 0 4 0 0 0 0 010 0 0 a 0 0 0 0 0 4) 0 0 * 0 0 46 46 a a 0 0
00 00 00 00 go 40 0 g 0 0 IS 0. 0-0-1 4w 0 0 a0049 0 0 0, 41- 0 0 a 0 -0 46 Wo 00-0

10
041000000000000000 WNSIPWRIS M.- 06000000609
USYMNO W mr!
0 at*
41 4143
0 v x )9 1011 1111 Un
j si q n m is as

'A
ptal-ts -041
00 PC
L
1 VOC41tsts AMD eva -00
00 A,
4
00 ~
4 V.- V.
lourad rotation iAd 1.06
. Vol-ktusbttlu- Usp&Ui Xhimii 13.1 234-M(1944).- -04D
*0 i 66 at Atim" a" around sin& w4inks re-
R&ai
i-
ba
th
f=
-

00 .
e
to overcome
q
mouat I
certain a
e
b
d
= 00
j &
w
pW
t.ls3-10kg.-cmLper-- Forw-Unjts
t
t
dl
d -00
00 a fa
c
a
e
tmp. this barrier Is hur
6 higher. At room

o
-
faster then 10-6 am. Thomfoce for the
lvmr-p= ,
9 -00
00 a
ft
rotation may be coomidend ...
ftqm hmt. capacities. diclec.
an be obtained
b
j
h .0:

0 4p arr
er c
e
t
convenient for
and other peoperties of tbC m4b- Most
a
t no

00 r
this Purpose we Cja*onognWbk and Razaam-spec
n M&W confiSmAjon of hydrocarbons and
Tb
C ma
data.
the voW gate is the
tWr derimrs. In the liqluld as Well as in a**
00

0 trans One. Internal rotation Is of parav t importance
of "Kemization
the sp-d
ts
d
I
coo
00

3 e
.
t
for optkd actkvky-
and thetosgultakolopticajactivity. Rotationimonscrifffn x
00
. olno,
-
ISO
g &W of Ragaas.gpectz and -1 !UM--
with t&
l

00 len
The results we tabulat*d- 94 vefelme Sto 2 we*

1

- -
'
---
-
-
-
MATtAt CLASSWKAY"
LITI
A
-agTALL
L
UM
K
4 NO"Lnv
910.
-al v LS1

w 0 0
1 2 v
U f9&,100,61; w Cr
,
0
C, It
ow wit 9 0 IC a 01 Is 0
4
6
~1
~
~ 0 0

0
0
0
0
1 0-
ie-
!! 0.
0 0 a a 0 0 40 0 0 0 0 0
0000
,
!
'a
6
0
6 ::
0
0::: 0 0 0 a a 0 0 0 0 0 0

Them at isissidusis MA ramd"Gis in ftman 1900in M Wagat-
nh*UtRW swolliMm. M. V. Volkerschtein anti Nf. A. F.Iiawhr.
vitsch (Coops. rmd, Arad. Sri. .1944. 49. 51-A31).-The
theory revioull developed (A., 1943. 1. 116) is applied to C(A.,
CHO.IHIC1017.0 MeDr CH Ur CHBirs,andC11r, Theoriginal
theory_ d"na on ihe adaitfXy %f effects due to vatenq bondi.
but it& appruximation is not always valid. The polarisability of A
bond is not only a function of its length, but it also varies twith the
length of neighbouring bonds and with valency &aitte. ffnwcv~.
the theory gives satisfactory trment between observed a nd c-k-.
n.
vals. of intensity and polarna n. the agreement being betturrin Vic
caseofintensity. The cak. degree of depolarization of &(ormational
vibrations Is> observed vals. ThapOlAriSAbUity(*)oftheC.-Hbnitd
is small. but the vatiAtion of a with bond-length (r) is consideraWe
doldr, is the smaller the more ionic is the nature of the Nind,
A. 1. M.

4-,. // . -/ , ~ ~ - - ..I I -
almatro-opuce WOVKVWQ ot valemy oodusuous. %f. v.
uh~tc*- (COM t. read. Acad. Sci. U.R.S.S.. 1944. U. 332-331)
stithematicar Nl. St. II.--

a c
o
00
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00
00
064
00
0
0
. . -. a a -
I
tv . ip

lee
-00
Wft"O" M.V-
mi. U.N.S.S. 43. No.
lee
DZQ AjW Nook S-S-SJL 41 340-W(19")'
th F=-. d.&pd Am *0 ZWW -1 Pdwi-
or a amo"91 " - -k"
k
j
u
h
Li
ol
n
t
e
y
latim
mctim of is and I for ONO cam Of 0 sifrX"
tb lee
l,
mW mgt, itb 068 Wi
L-GrAs form g 'i if. 0. McCoun
.00

see

Lee
use
ILA ORTALLURGICAL LFTERATURE CLASSIVICATION
law !,ill mg Ov M
1430&0 ast ILI]ICht
An 1 9 Od 0 0 s 0 A Is 3 1 T KX.
4A
AT 00 JU 4 K i9 19 K 09 It. a n I M
G 0 0 0 0 0
o

*job 0 & 0 0 0 0 0 0 0 IS 0 * 0 0 a
1($ 0 0 0 0 0 0 0 0 0 0 0 0 0 0 !
14 j AG it At is
11 4j
Q w Etta A p
00 if rilwal L.-L -"4
00
.60
Intentity of walenty Wititilill"ll its lftfixr*d siptara -00
M. V. C-pl. ".J~ ...... 1. ~-., 1. 1
4S. 117-8( 19M., -'rllv 1-3 llit"? y
it, (or Ill.. illtrit'lly .4 a k"Illph. (cly NY111. -0 0
0 valvary vilmaii,ni of a grmil. of mmiLu bm.1, makitag -0
eqtIA1 wigh, with cacti wher. ill of Ills- rjt-c. 1114)1111-111,
of tile mol. &list imilvi'lltAt aml (lit- Itsmid h-141(th. -0
-0
atilt vi'lectitv AtIjAhAli-k 1'. aliti'vi'l,
",Ivc Ilgill, 1, 111'.
0 0
is 4900
a r 0
11.171`11PAIVAll CLASSIMATICIS
tm-
lot'll, -it OIV q1t k0 0
u is AV j An jj 0
It it Ell it ft fit it 19 It 9 tt tt 19 (1 KLO n 1 9 4'X"
0 0 0 0 0 0:0 0 0 0 0 If 0 If 0 0 0 0 0 0 0 o 0 0 0
0 000 0 0 0 0 0 4 0 0 0 0 0 so 0-0 0

0 0 0 0 0 0 0 0 00 * 0 0 *F?7TP'wPFPP'- 0 0 0
0 t 1) 11 If 0 14 14 Ito "AD fin 91144 11117MA'suil U13 MA 16 P ka"Al .1 di Is 64 13
A If a L A-A-P A - 1-1-M-04-Cr. m-
Q.
0.4
-00
00, -00
The"y of Lute"tiess and poLarization of vibration spectra
of molocules. M. A. M*Yashcvich land M. V. Vul'kt 1141 -
trill (State Optical Inst.). J. 11hp. (u.-i.s.R. i Q. im I
'O'0 f 194 5). - Nt ath. A th cory ul I hc'i it I cti,t t i- a it, I I h,IAT I z.& -
ts tin., f tile ilifr.Lred alld Rjullull ~jx.~-tra of I,
0 dcrived which 11 based (fur t1ke It'I,, aptir'nifilil wit) as thr
:0 "mulption of the additivity of bond ojijm~jc iliolnevit% aitot 10
E Polarizability tcnsors and their variati4m% with tile [vtogth
of the bond. The justifimti4m fim this A-tinaptum I, di-
cumed. Symmetry cu6rtfinatc., urr u%rd to smjt1if5 ilit. Azoo
zoo
=00
00 C
zoo
00 :4 mesmaildasi amd pakrimatim of vibration aptc-
it . 11. At. A. El'y"hervich and III. V.
00 P ='dh.'Jt. Phy,. (U.S.S.R.) 9. 326,41)(11145).- zoo
.r-ThiF-thik" developed in Pt. I (cf. C.A. 40, :Zoo
13954) is applied to the ca". of intensities and polariza- 'a
lion of vihmthas -im-tra of aijulx. of the for.. Xy', Xwom",
SIMI XY.. Frauk Cwt-t
61
Ate-SLA MJETALLURGKAL LITERATURE CLASSIPICATIOM C-z-,
".1010
ZOO
S.Aca" Cl.. C.C jjjj-I CwC7- I ~-j j aW C- S t
3 TA
S a1w 0 1 It : I a a 3 1 1 00
a AV M3 At . ,i. AnL
"-o
0 0 0 0 0 0 0 0 0 40 0 0 a 00 0 0 0 a a 0 0
0 0 0 0 00 0 6006*1910!
Ilb - * 0 _0 ~1'

WW WWWWWWW

* 0 e 0 0 4 W - - - - -v-
qP
0 0 0 a 0 A
1 it 11 44 It 16 1? to IV A it r; is A n A 11 W14 mill M11 ?rW .1 #1.. uto
A 5 L
L AA N [A LV t1t

Them of vibration spectra of polystornic mol*tW*s, 1.
*
'
: -00
&she.
1
General problems. M. V. Vol
kenshtchs, M. A. 1
h
S
S
Ad
Ph
Fa
S -00
op".
a
.
.
.
tepanov.
vich. and D. 1,
Oroc
7
114
Mi-42
Thmrd
M
1411
t
I U
S
R
) 1S
3
a
20
J
'00
-
.
.
.
.
.
.
7
.
ps.
.
;
,
N
(HP45)(Unglillh xtimmary).-Gencral review of probirmi .00
and applications of the th-ory of vibration s1wetra. 11.

1.00
I vibrallo"81 spectra of polystollill: Moto -
Theory at thi
100141nit Ill
IA
d
t
lfl
I

oo
44 9
#s an
ona
PO
n
cules. Ill. Theory of the
00 a! Raman spews of mothyl halides. hl, V. Vol Iro.h trill 0
ami M. A. Hl'yashtvich. J. Expil. Tho-twel. Ph7s.

00 1" 13.
(11,8.8.k.)
oo~ (,.J. 39. 20340. R: G. zoo
-;0 0
!m 0 00
0
:v
Of CLAMPKATK4
1 4 1 L A atTALLURGKAL U114*TC;
L%:;
It or 64 Or a it If K U is it at
0 0 0 '0 0 0 0 o 0 0 0 0 0 * 0 * 0 In a
0 0 ot
oooooo;oooooeeotoooeo0400:!~oog*oooooooeooeoeeoooot
zoo
zoo
1000
%-00
aoo
0
41,A)l 'I,
Joe
An L S 8 PW 0 4 6 1 if Of 5 AJ 0 1 IF
go n I ana
41 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0,
I

9 L M IF - A I I U Y. I I -T z PA 00 Cc LV U44 lo
w W1 Oloul..

The Wory of vibration tipactril of polystomic molecules.

A
1 IV. Spoefta of dauteriamethanes and electrol6pticai
p *a of vaknco vibrat"s. M. V. Vorke-olshtrin
=
r
:0 Opticaj Inst., Moscow). AC143 rkyliforhim..
(

L tr.R-V.S. ZO. W-50(11I-15).-The formuliv; olerived in
*0 S I previou-t papers (C.A. 40. 2711) are here u%ed to cale. the
vibiation lr%xiucnck~. their intrn~ittes. and the dr$,olari-
Ilitticon factarit in tile Raman ~J"tm Col Cit., Cit,[), Cl(J1111
Clll).,artdCD.- The ell". values are in notreetnent wit h -00
observed vidu" wit"ever the!or are available liorn,4~j-1.1%.
f
f --1110
Ranuon and in
tooons o
rared swtra. For the effective
charge of the C-li boud a value that is apiltot. O.We is 1*0
derived. C. C. Kir.44 ;06

VIVO
~00
-00
ZO*
tie 0
ties

A S A I L A AtTALLURGICALL ILM INATU01 CLAMPKAT110111

to
U &V too ?A I
10 w Cr ty of or K or

na,
0010 00 0 40 00

e 0 0 0 0 0 0 0 0 0 0 0
4

0 0 1111 0 1111 00 00 0 0

L10 0 0 0 0 0 0 0 0;
oil
0 & lit 0 * * :

I
so- Al
se,
Oslo
OO'd
4
00
00 13
00
90
Properties of f**1kft Ld U. N. _Vnlt!~
(state (Vtksl TWA.). COWPL rad. 4-d. Id.
40, lllt-1609")e-ft COMPSON dw tb"MWYnamic
functions of rotatift * . occomat should be takes
of thW vibratka heqw"gWeit the form of their votential
barrit", mW tho rub of the amts. of the bommen pftft..ftt.
ne estrojAm-ol 0-butow at 272AS' and at 21141.1 K.
were Wed. and eampowd with the vshm " @d by As-
can &ad Memmerlyfid. C.A. a#. 6111W). Vibration Ire-
qugucks 0 - - a ama. Swordbw to Wymehirvich And &CP-
awv (d. C.A. SP, Varlous- V'shm- of V4 hvm
3300 to 30,000 -1 - Imol Weil as Nemill it ifIctcut Values
of V, and Vs warm used. Tba natio, K - No._M..A. in
thaaqu9.sdxt.wa~UjkCnSAappM.l0. ILW-ObUtincd
from a rough YWW evaluation of the relative intensities
in the Itamm speam at ram temp. Frowthc2eentropy:
compmrimons, the Conclusion is reached that the pottntial
barrier V& - 30.OW c&L/=W., ZrIed by Aston and
M;=y (hv. ea.), may be too Ift P. R. Clark
.91ALLLMOKAL LIMILYW4 CkA%WKAISON
%som $114 11A
29"W "so OdV Got
R U rf ;ff _* -
to Ow 04 it wm ~ It - 4-41
O*A
0 0 0 t1o 0 0 a 49 0 0 a 41-40 0A
,If; A 9 4 ad a a a I Ar of 9 A a 3 4 V
0 0 e 0 0 0 0 0 0 0 0 0 0 0 0 0
t 0 _0 0 0 0 * 000004000 a * 41
-00
-00
.00
1*0
.0*
.00
go*
ZO*
go*
Gee
goo
goo
4

Volkenstein, reviewer Of KondratievIs book
in C 2:::, -3 ;-,a- Z
tructure cf at=tic cc m Z, n ;:;f nucl:_~-_`_-~,
--_eery e~` -~he r~!~c+rcne cover
Lc;~~, C _C+
4o Level :n, of enerZy in micecilles; e "I.,zi -.cfis -Int
e C t r 1~1 C:-
,Y
ti es r t -1na mc_,ncuir-
7.
SC cX he S. 3 R. C~f, :,.c:,-.ncz!:s
T- Stj
re -a _k a

,111 Oil 1 T
A
00
*0
00
00 A
0
00
00
00
so
0. 111, 011 114 oil
~v ~Tpvr~
-w, J~vn S~l ...
00~1&Lfl A.0 "100141vill WOES
his Mir Mled) 41 U43 m6:00
llp~ tt-- lsyol
-00
-00
-00
Th* 11414ts Of IsOmflutim of allphadc hydiocstbons see
dC Pt. read. aced. sci. u.R.s.s:
51 211-160M).-A = of the causes underlying =40
tile, greater stability of hydrumbons with an 1w)-structure 0
(Rovini effect, C.A. 34. 74"). It is concluded that a
certain part of the stability should be due to the possibility 00
of routtinnal Lsouserisim. With Lsobutane the Sivitter zoo
part. slid with tetrarnethyintethane cme-fifth of the Rcks-
000
sisd c(lect k explaincd by the clect-raw in the zrro-rk)int
Ciserssy (if tile vibrutil"116. A. S. Postman COO
Got
Me t.
u 0 AT so &%I it at
0 0 0 ; Ou
*Tee: :::::100 0 0 0 0 0 0 0 0 00
coo
is* 0
X99
=00
It -1 ~T --r.
2(w vc~lnv no 0
roe
4SMK
IF a ZA rm a m 0 IT lm a
42 A 00000 0 0 a 0 0
0 0 0 0 0 So 0 0 0 0 0

Title The z; t r -a c L7.3 --.-'iE: tZ 10 i- t:,
"ItT: Moc-C.Dw
Publishers llcus~. of tl~c Acad-i~n* n2 of tho, USSR
y
Date: 19h7
Avil-lable.- Fal-vard
Library of Conqc--m
cource- I
Monthly List of 11"usslian Lacecsionu
vol. 11'. ,io. o, p. ?26
Call Jo: QD466.v(,,5
!I-ewvtical.
C,
I ic, , Physic I - d
wv.bject-. 1. P'Accule-4. 2 (;yjem ur" a ell

09A
go 0,
00A
o08
00
go,'
00
*flu
*04
of rotation Iftows.
Unit. A. No. 2. 13-23(1947)
review of mtricted inner rotation
in its relation to Rayleigh peattrang of light and to the
Kerr egret. 11 references. N. Thnn
L"1017VNI Ct"WICATIM
-00
--::
n 600
zz 00
lee
,log
goo
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pal. tv two 11 6*111 $12063-4
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0 W 0 *-"Io * * * 0 * a * * 0 0 0 * *.& a 0 0 00

VOLtK!41SHTEYN,, M. V. Prof
U /Physics oct 48
Light - Dispersion
Light - Polarization
"Dispersion of Light," Prof M. V. Vollkenshteyn,
321 pp
"Priroda" No 10
Describes molecular dispersion of light in gases avd.
fluctuation of density; dispersion In liquid and
solid bodies; fluctuation of orientation and polarl-
sation of dispersed light; dispersion of light in
solid bodies an& theory of thermal capacity of solid
bodies.
I
alp 9A9TlO4
A 9/49TI04

-Usaphysics
Light, Dispersion
Folarization
."The Combined Dispersion of Light,," Prof M.V.
VolIkensliteyn, 16 pp
"Priroda" No 11
under following (mentioning
,Treats.subjec,
-scientists concerned): nature of phenomenort,
combined dispersion of light and chemical combi-
nation in poly~tomic molecules, analytical
propositions, intermolecular reaction.* theory of
molecular oscillations., aml theory of intentsities
and polarizatioas la combination dispersion.spectra.
23/49T102

VOLIM131ITM-4, M. V.
U.SSR/Physics
Polarization
Spectra - Analysis
Sep/Oct 48
"Polarization Of the 6pectral Lines of Combined Dispersion, II,11 Ya. S. Bobovich,
M. V. Vollkenshteyn, Stato Opt Inat, 7 pp
"Iz Ak Nauk SSSR., Ser Fiz" Vol XII, No 5
PA 19AMI

Polarizability and the Ftanck-Condon principle. Nt.
1'. Vol"Lemlitelts mul M. A, F1'rohr%ich (IxttinKra.1
VrCiv-1-. 'f::-ojf. Akad. Nauk S.S.S.R., Ser. Fsx. 12.
548 The 1W.J.161.46'.11 (,wtnttlA,lt
I'Llezrk 's"'I Mar".ju 1-.'jfel, 1935,
par. 14) o, derived: Ow inject.ify .,I lite U,jsjj-,ji u-.jjfr-
its% wmilsl 1w Irto it Ilse Frattvk-Cmidsm loottivildr wtrr .4
mo j Is*

."I'1 M.
Nauk F- IZ, tit Wim. A4s-pll -t I
lip is dcscribcd consL4ting of a %Iyct,t rogr'l ph It ith j 11-214 y
refractive polarixer in front L4 the Ait. Snwc the ImIArig-
Ing pri~:u iieparmic.%bothmniponentsof thecattered rAdLt-
It ... I III t turn, thells through 45". the Mulnin.1tor (1111
Lost 4) It :1 mitilml at A 45* 'Illsir ft.,iliect ti, thraiti.
4 X "r,011.1r, 'ill4tit. Ult, filitlid. fill. Isirth-MI girlillil. irs
.11 :1 U, Illtur'l. The If RAIII.All
CCI" C.II.. alld 1111%fr WA. Illea,ill!'141
I.. 'Ial ill li(rlisttuv~ Ilma Own Ill
(VI. I~ljm'r ."Ill. arr ill '11,41cf-tticill 4.1111 'L't
takril N.-daing It. .... ..I
I'VII'lille. m CO. 4 Ow 1.111"
1-11 st-itur"I: NittollIVIII'mr. list lilts.,
t"Its"w, it, .,-. p-iinruptics-1.
p-nilt-wiffinc. w-dinitrithenzeur. tOwtic. asittmmidt.
thak1w, atul 4ittit r." Pitt IwIctle. It i, '114mill that bpmp~
It, Jim., I-ition increlt.,te tile llxLkf vollit"Illent in tile m.-1

VOLIXENSHTEYU., M. V.
EA 41_rXU4
uswAnysics Jan 1948
Spectrum Analysis
Spectra, Electronic
"Blectron Spectra and Intensity of Combinaticn Dis-
persion in Spectra," M. V. Vollkenshteyu, 12 pp
"Zhur Eksper i Teoret Piz" Vol XVIII, No 1
alyzes formulas based on the association of' the
-An
intensities and polarizations of lines of combina-
tion dispersion with aspects -.-)f the basic and ex-
cited electron conditions of a molecule.
Igo UT104

Electronic spectra an's intensities to kaolso *I_l,tlA
M. V. Vol'irritlitt-to. Zku,, V'kq4I. t,r IM. 71
Critrtiott of InIvn'ttv atid t..Ltrfl~t-
tion of Raman fines, the Jeriv. of thr it ... 1. hctroute
polArizability with res1wct to the Slortu'll C-Momle, Call
Im rvj,rm-lltrI as it function of the I-Atrital-ifilit, , of tit,
individual VAICtloc fjoll.1, Alld tile Ivf%%N 1, a/ will%
respect to the txmtl LoOrthoate q. Oil the lux~i% of tht-
Krum"s-Ilei,etliterg formula. k%, aq call 1w hllk~l %ith
the properties of the grouod and ewitell r1cortmic, ~tjtv,
.)f the mol. In the c~sv of diat. Illot'. zlul of individoal
jjx)tj,j,j trmtni as tiLlt. twAs., the sheorv aevottot. fw th,
I . t~ll,ilv of Raman fill" .4 iollic 1-11.1% and their ill-
ZVI decreusing J,ourity. e.g. in tile -Tw, C C1.
c-iir. c-i. *rhe critcrino of I~rtd l.garitv &~jvm
from Raman spectra ciltineifl~% with the spectroc-opic
criteron of rranck. 11te theorv al,o aevount% for tile
high Ratoot-line Inten,itic, of conjoirmi-tiond atol u-
tuatic orst. tool-I.. i.e. Itt'd.. chittact'lizett hv ow-Witwitv
of Ix"O etirrul". N. Thoo

Polarizatwu of Raman lines. M.
le
lir V.11clit, "plical
uppicuientmg Phrick 's ridt . I. him wdy
validity but are I,r.,ctj,-.,jjv VA'sable
liad Immie Ina liv i'mulkiris,"i wiiij e,1,11,
I For Iny fully syminctric.sl purv d0firmAtIfin vilig,ijisin
f it IIWI if any -Irnisurtry gir-mils. I Iw b-icr, r 4
tion 0 - '~'. I,-,) Ftw a vibriatiot, if :I di.o."Ilic I'I'd. if
cliaracteri,fic vilw,,timi ,f an hitfivOu.si Ortiad. p I, cfin-
prs~llutwvvvs I/tign,141. CO U.-Irfully,Y111111"Itt-A vil,f.%-
twim sit my plaur in,,I,. of lite vininctry Mt. built up Is(
Id"Ilticil 0 its ,qu.41 .41341 IndviWII&I.1 "f the It... of
A) M a trueralirzttion of title 2. f.w Altv fully
pure valrmv vilwatim, -,f a I-w-I -r
W pleats. A lite 161.1"'r 1111sit .'r 0 1,

VOL'XINSHT M , M. V.
USSR/Chemistry Oils, Spectrography of A ug 4 8
Chemistry Asphalt
"Porphyrin Opectra. in Oils and Asphalts," Ye. A. Glebovskaya, 14. V. Volikinshteyn,
All-Union Sci Res Petroleum Geol Survey Inst and State Opt Inst, 12 pp
"Zhur Obshch Khimii" Vol XVIII (LXXX), No 8
Total of 24 samples, of bituminous substances, oils, shale constituents, etc.' from
vailous locations were dissolved in dioxane, alcohol, benzene, chloroform,
petroleum ether, or pyridine and subjected to spectrum analysis with a Beckmann
apparatus. Measurements were made every 2-5 main visible part of spectrum.
Presence of a porphyrin complex with vanadium, and possible with nickel was
established. Complexes may belong to mitbrial. from which oil originated. Submitted
17 Aug 47.
PA 19/49T26

Yi. r ~., I ~-1. . -, .
, t-l--.~-.,~~;,~Ii ~,-]L- , ,-; . -,- . 2UIxUj."Ov-LLIrI, F.I. A. wId 3~~Uvy B. -, .
"Molecular Vibrations: V.1. I.
"The Geometry and Mechanics of Molecular Vibrations"
State Publishing House of Technical and Theoretical
Literature: 14oscow-Leningrad, 1949.
Translation F-TS-7334-PEf

1~ VOLKENSHTEYNY M. V* I YEL'YASIEVICH, M. A., STEFANOV, B. I.
2. USSR (60C)
4. Physics and Mathematics
7. Oscillations of Molecules, M. V. Volkenshteyn, M. A. Yellyashevich,
B. I. Stepanov. (Moscow-Leningrad Stato Technical Press, 194.9). Reviewed
by V. M. Chulanovskiy, Sov. Kniga, No 10, 1950.
9. JWReport U-3081, 16 Jan. 1953, Unclassified.

1. - -,. i, 14 - , 1, , -~

lnv*suptm oz routional iww"rn by optical methodA.
St. V. Vol'Itensisteln, fzmr~J. Aka& Nauk S,S SJ( , Sr,,
Fis. 14,4W-,0(1950).- The i-wonicrswhu-.~e%tructurei%ift(ti.
~Y the rotation of mol. voups around A double bond
have vrry synall differencri its energy and nctiv~timj enerty
vul thrrtfore a (Ast mnvt-r~ion ~ that they catmot be de-
;mted Chemically. V. tile 'I'tection "Iethodl
-ks Rans-, t"tt~. ~I,N-tr~mic tr..nmtion jKvIf.i. And
Opt i".
tlf

Statationw Syntmetty Ot 41611011 'NJ ()j #;v1t,H(e1fJ
IN NiLitin. and T. V. %'AovIe%A Irt-t. 1kad. Xaki
3 1-7( IW The i"Itrimilic, of
S"- Fes. 14. 4 -0)
ruan lines of butadiene and i~oprrnc were investicatril m
60 to +715* (butadirrie) and -&) to +50" (isopfenrl
The cotnJmuism of the t4bulm"I Rarriall tin" with infrured
ab~wpti,ln lines. nicamuett It v other invvttijvator~. ~hoviq
thAt in liq"t InstAdi,tic th, tt.tti, f,.Yct (10,.i t, jwc-nt.
whor"i the girmearr tit the ci* Girm i-bitiltiful, The r-ult-
do not allow m3clu~iotvt oil the preel,4~ of 1.0b i-11j", it
rquil. in the caw of i-Aipretir. S. I'Ak,wer

C04
c 10
The wo ed L. A. ChoWev In the 9&4 of 711"y wdve
fompoe"s. M. . V.,VQirAtefn A M. lif
him a It ~---Restd eftnrrnc
K .10. 1 view; 49 rel
= of Chugaty. N. Thtm

F 19 T 9 1
USSR/Physics --Optics Apr 50
Polarization
"The Theory of Natural Optical Activity," M. V.
Vollkenshteyn, Leningrad State U, 5 PP -
"Zhur Eksper i Teoret Fiz" Vol XX, No 4
S
Classical theory of optical activity of anisotropic
media is made more precise. Shows Born's theory is
not applicable to case of anisotropic medium, and
that in this case it is necessary to consider elec-
trical quadrupole polarization besides electrical
and magnetic dipole polarizations. Submitted
15 Dec 49.
159T91

(~-'.,A
k Thl 11" Of the rty Me of the by-
bond . Vc=tmaxW9~Ufi
M. ciss. At A~ M'yahir~k-h.
AITpr
,.! 4, . .
Si4jmulav (I.AnIngirad State Univ.. Leningful).
Zhur, Fit. Kilisms. 24. 11 58-MOOM.-A crit.
Pistil W. llowrirt'jil

VOLIKENS11TEYN, M. V.
PA 1,65T90
USSR/Physics - Polarizability 21 Mar 50
-Optical Activity
"Theory of Polarizability, and Optical Activity,"
M ,-V. Vol-lkenshteyn, Leningrad State U imeni A. A.
Zhdanov
-Dok Ak Nauk SSSR- Vol LXXI, No 3, pp 447-450
Mathematic~LUy attempts to construct a molecular
theory of essential optical-activity-that-permits one
to' calculatexotating capacity of molecules purely on
basis of,other-1-uformation on their structure-. Valence-
optical scheme of optical activity. Subm:Ltted 26 Jan
50 by Acad A. N. Kolmogorov.
165T90

w4-11 is , -s" 6 Is to
It fa 1) 10 F0 so I to
A a It -A
A bevells
F,
044X811#6 Swo roarrat'll 0f#
792L Tba dim, at pmiwbnbft a"
)A. V. YW TdK -VoU, Ak4at
00 f Saak. $SSK'71'VVP. 4 RmdWL
(t
Q
9M -00
Rdda= Ij 'MW tQ S PMVMPA POW WW, .00
00 a 5754 (Mft TI id *Mdm&MW OW 00 *MY 01'
so a Wty,guecWdy. expkW An d4make -00
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*000001000060000roooo *0 00006660:*000 000
104;~ me 0 6 0';6 000 0 0 0 v 00 & 0 : 00,10 6 00 *be sees 0 0 0
000

Y1. V.
USSR/P4 Polariz 21 Apr 50
Combinairs-Dectra
"Polariza' the Spectra of Combination
-Scatteri Aromatic Nitro-Compounds," Ya. S.
Bobovich, M. V. VolIkenshteyn
"Dok Ak Nauk SSSR" Vol LXXI, No 6, pp 1o45-1049
PA 175TPO
Reports on some results of polarization measure-
ments an spectra of combination~scattering of aro-
matic compd (e.g., N02'0; W02*0* WH2; ' N02 .0-
C1; N02- O-Br; N02- 95 -OH; N02- 0 -CH 3; etc.). Addn
radicals are placed variously around benzene rad-
ical. Submitted 20 Feb 50 by Acad A. N. Terenin.
175T80

VOLtFXN8HPI'MI M. V.
11/5-
613.8
V9
Molekalyarnaya optika (molecular optics) Moskva, Gos., izd-vo tekhnikoteoreticheakoy
Literatury, 1951.
744 p. diagrs.
Cataloged from abstract.
FB 508050.
Monograph givei systematic account of molecular optica, related to the field
of physics. Spesial attention is paid to the leading role of Soviet reiiearchers in the de-
velopment of physics.

11A 197196
USSR/Nuclear Physics Optics, Molecular Oct 51
"Optically Active Molecules in External Fie.'.d,"
M. V. VolkenBhteyn, E. K. Byutner, LeningreZ
State U
"Zhur Eksper i Teoret Fiz" Vol XXI, No 10, pp
1132-1138
Discusses behavior of optically active gas or
soln in external field taking into account elec
dipole and quadripole and magnetic dipole of
polarizing medium (cf. M. V. Volkenshteyn, ibid.
20, 342, 1950, and "Molecular Optics" 1951). Au-
thors acknowledge A. T. Timorev's advice. Sub-
mitted 22 Nov 50.
LC 19,7T96

VOLKIENSHTEYN M. V.
USSR/Phyqics.- Molecular Spectra Apr 51
"Internal Molecular Interaction and Optics," M. V.
Volkenshteyn
"Uspekhi Fiz Nauk" Vol XLIII, No 4, pp 485-511
Discusses OPt phenomena disclosing interi-iol action.
Delocalization of electrons in case of strong elec-
tron action may be noticed in electronic spectra of
mols, in anisotropic diamagnetic susceptibility of
aromatic comps and particularly in-anoLialous inten-
sities of combined dispersion.

USSR/Phy'vica - CryfitanDgrapby I~ZW 5:L
"Optically Active Crystals," 14. V~ Volkenahteyn,
E- K. Byutner, Leningrad State U imen'. A. A.
Zhdanov.,
"Pok Ak Nauk SSSR" Vol'LXXVI, No 4, pp 5157-517
Only accurate theory of ratating crystals in
that of Born~ Expt! data 6n relation betmeen
crystallic spectrum and rotating capacity were
found by Samoylov, stulying uranyl acetate at
temp of "Liquid helium.. Submitted 20 Nov 50 by
Acad S. I., Vavilov.
178T107

USSII/Physics - Polymers, Linear 1 Jun 11
"Geonietry of Linear Polymers," M. V. Vol'kensh-
teyn, 0. B. Ptitsyn,
"Dok Ak Nauk SSSR" Vol LXXVIII, No 4, pp 657-660
Present-day phys of linear poAlymers proceeds
from representation of familiar freedom of rota-
tion of members of the polymer chain. Up to now
'no inethod has been described for solving prob-
lems of the geom of such chains. The most im-
portant formulas in the lit are given without
derivation. Here method is expounded which is
convenient for any potentials that brake int
18411102
USSR/Physics - Polymers, Linear 1 Jun 51
(Contd)
rotation. Also gives anal of existing computa-
tional formulas. Submitted 6 Apr 51 by Acad
A. F. Ioffe.
184T102
0

VOIKEITSHTEYN, M. V.
USSR/Physics - Molecular 11 Jun 51
"Linear Polymer as a Mixture of Rotational Isomersy"
M. V. Volkenshteyn, Inst High-Mol Compds, Acad Sci -
USSR
"Dok Ak Nauk SSSR" Vol LXXVIII, No 5, pp-879-882
Considers polymeric chain as equil state of rota-
tional isomers. Different equil states have dif-
ferent energy levels. Rotational isomerism of pol-
ymer may be studied by oscillatory spectra at var-
ious temps. Submitted by Acad A. F. Ioffe 6 Apr 51.
184T106
184T106

VOI,IU,TISI=- a, M. V.
"Molecular Optics," Sovetskaya ?taiga (Sioviet Books), 128 p., Pravda
1952.

VOLIT-CE:11-m-EV-11, 1r. V.
Cheacal Abrt.
Vol. 48 NO- 9
my lo,, 1954
Generaland Fhysical OhemiStry
ty f t ulose.
p ac" 0 rico Sci. U.S.S.R
V.; %W-2,1333-%~
f4 e on).---&e C.ii'
46. 1,

--- VOL31MNSHTEYN, M.V.; KOLODINA, N.S.
- - 7.-- - ~ -.. I - I
Electronic absorption spectra of polystyrene and its derivatives.
Izvest. Akad. Nauk S.S.S.R., Otdel Khim. Nauk 952, P.1-033-6.
(CA 47 no-13.6253 '53) (YT.,-RA 6:1)
1. High Polymer Inst., Aced. Sci. U.S.S.R., Moscow.

VOL
USSR/Physics - Dichroism. Nov 52
"Circular Dichroism in Crystals," M. V. Vol'kenshteyn
and E...K. Byutner, Leningrad Stute Univ
"Zhur Eksper i Teoret Fiz" Vol 23, No 5, PP 584-587
It is shown by means of a classicial. model of a system
of coupled oscillators with helical symmetry that
crystals in the plane of polarization may possess a
strong circular dichroism. Received 13 May 52.
F1 J-t- n o .6 G 8
236T85

VOL K E N S HTE A(N, M. V.
calcula. w
f Ii r- p9lpqer_s lion of 0.
01 "ne"'
I engih of the Cj I I ins, I-it
zhur. i'zz. A12,1111. Zrj, IVOL-1 It-I'
aWl in. A geller lictho:l is dt~
I .1th. A
V~Iopctl for citl,g. tlk(! ttv. quivIcAlic leogth of p4A),-ncri~l
ellailis oil thc b:L-'k, of a kinedc dicery in which is
soinewhat hindered r*tatioa about each of the, individu-0
C-C bosids. Liktf the 1-uhn equation the dcrived equa-
tion fails to take into account corrdailon between funre
distant rwations. XI. Rotallon-isomerism thcoey. N1. V.
Vol'kenshtela. Aid. 1072~Wj.-Thcorctical and niath. A
rofuttion-i~*mtrisrn theory is proposed for IL-scar p3lymers.
Amording to thbi theory the polyiner chain is an "uil.
mixt. of rutationnI isonicrs. Expd. values tire compamA for
nic, and 2-inethylimt-anc,
ethaue, propane. isobutane. isobuti:
r.. H.. Rathmann

. ---sprW
I VOL 'Kr1TS9T-,Ev.1T, M. V.
USSR/Chemistry - Polymers
Aug. 5 2
"The Geometry of Linear Polymers, IL The Rotation Isvijer Theory", M. 7. Vol
Inst of High Mol, compds, Aced Sci USSR, Leningrad
Zhur Fiz Mhim, Vol 26, No. 8, T)p 1-1072-1083
The rotation Isomer theory of linear polymers was pro2ceed, according tc which the
polyineric chnin represents an equil Axt of rotation isomers.
263 T 3

VOL t KF'-N'-)..T:1N M6-v.
~SW.vhygiics Osclllator7 Spectra I Feb 52
vDistrIbution of Intemalt6v In the 08CdllP-tm7 SP&Ctra Of Ulm" Ch9An9#*
L. 1. Vidrox B. 1. Stepanov
flDok Ak Raa SSW." Vol T-Y=v No 4. pp 557-560
Calmlates the IntAnsitlea of Infrared &rA =binational lime for 2 simplest
mod*2,o - 11mear chains, usirg the valent-optical s of M. V6 Vollkenobtoyn
and ff. -Aw Yellyaskavl" Conal"re a 91WIe 11mear ch"n cansiating of Zin.
1 -4
idwAd ha bonds; ckwuladgea the helpftl v3sista: ce of Frof M. V.
Vollkerwhte7z4 SW=Itted ILy Acad A. R. Terenin 4 Doe 51.
PA 213T112

USSR/Physics - Electron Spectra, 1 Aug 52
Aromatic Com:
pounds
Mlectron Spectra of Aromatic Compounds," M.V. Vol
kenshteyn, L.A. Borovinskiy, Leningrad State U
imeni Zhdanov, and Novgorod Teachers I Inst of
City of Borovichi
"DOk Ak Nauk SSSR" Vol 85, No 4, PP 737-74o
States that aromatic compds represent systems with
especially considerable interaction of pi-electrons
Notes that the properties of t1hese systems can be
understood only by proceeding from,the profound
ideas of "averaged" mutual influence of atoms,
227T73
which were expressed for -Hie lst time by Butlerav
and Markovnikov in 18701s. Proposes that a semi-
quant theory of electron spectra of aromatic comj&
can be constructed on the basis of a model of po-
tential well just as in quantum mech. Submitted,
by Acad A.N. Terenin 10 Jun 52.
no. 207 J3)
227T73

LISSR/Physics - Susceptibility 11 Aug r-2
,r
"Anisotropy of Diamagnetic Susceptibility of Benzol,
Naphthalene, and Anthracene," M, V. Vol'keziahteyn and
L. A. Borovinskly; Leningrad State U and _~~,ovgorod
Teachers Inst, Borovichi
"DAN SSSR" Voi 85, No 5, PP 977-980
Derive new calcne based on the application of an ele-
mentary phys model of an electron in a potential well,,
which is a graphic visual method. State that in
future computations it will be necessary to take into
consideration the nonequivalence of all the bon" in
condensation aromatic compds. Submitted by Acad
A.-N. Terenin 13 MaY 52. 239T94

%LKC-WShnYN) M.V.

U S S R IVII-A, YOUT-L
539.132
ok . Ak"
Nauk SS.~R, 9!~ No. 6, 1743-6 (1952) In Runian.
See alsso Abstr. 5627 (1953). Derim expressions
for intensities of the C-C bond vibrations in the
Rarnan spectra of linear polymers; for sonic C.H.+ 2
hydrocarbons the expitWon is in qualitative agroo-
Inent with experimental results obtained for tbj:ir
Raman, spMUa. F. LAM"S

*rll--~~i*:i~--Igxr - Mr -A-O~ N 19W
--A&izp 4r-7. giff mwmkm~jl 4
0 M-- V.
K60,3tlmyr
V
U S S R
Iling. Dirnmiions of the rtal a ilnt4r .'
Zgir
jyjagcs in soluilowi AVD
k:SNY9 -SC4%'4Tji(V
493-6 (1952) In Russlim. ' I'- ".'; - 1 7 1-0..
A simph: melhod i~ pinp6ldAr ii-n qt~
tipproxini
evillualloll of thr. hillualec of tho voll1mr, 1.11f,"I'li OA
thr dimensions or ttie piilyffxr niolcculm: 'Itic floal
formula shu-.%s that, when Volume CITO;(A aw, I&CA
into account, thd'valuc ~/fil (It bcing ~the violsabld
chain Icngtli) variLs as NO!I(not as W'~)Iand thuflp.
tcrnpcranire ilL~crdclfce ii Irss pronourl-~a that.
visium.-d prcv;OLLsly.
7-

VOLIKENISHT-EYN, M. V. and PTITSYII, 0. B.
tI 71,
"Rotational-Isomerile 71heory of Fusion of Cryst-all.-Lie Polyr-emil- DAI; S-E-S-3- 7!~il 86,
No 4, pp 677-80, 1252. Inst. of High-141olecular CorTds.
Attempts to prove on basis of rotational isomeric theoi-j that the temp of cryst
fusion and the elasticity modulus should rise with increasing stretching of the molecular
chain of the pol3mier. This theory permits direct connection between phys properties of
polymers and their chem, structure. Presented by Acad A.F.Ioffe 28 Jul 52
252T91

2AMU-999SIM-Of tW* FilmnAl Vollenghtelts itticl
.19
Sh.1 I dFakwMAL Bull. Acad.
1 .53,,8 gi. Emnslation).-Sce C.A. 47. 62S4h.
It. L.

VOLIMSEWSYllp H.V.; FOJUIOVSKlY, Te.I.
R-g-n spectra of two silan6s. Isvest. Akad. lauk S.S.S.R., Otdel
Khim. Rank 153, P. 177. Oaak 6~3)
(CA 47 n0-13.-6254 '53)
1. High Polymer Inst., Acad. Sci. U.S.S.R., Moscow.

rN
USSH/Physics - Molecular Spectra Sep/Oct 53
"Computations of Oscillatory Spectra of Molecules
Containing the Carbonyl Group and Their Compara-
tive Characteristics," L. M. Sverdlov, Saratov
State Unix im Chernyshevskiy
Zz Ak Naukj Ser F1z, Vol 17., No 5s PP 567-573
The oscillatory spectra are calculated by method
of Me Ve Volkenshteyn,, M. A. Yellyashevich, B. I.
Stepanov (Kolebaniya Molekul (Oscillations of
Molecules) 1949) and L. S. Mayants (Dissertation,,
Trudy FTI.N,, v. V (1950) for compds contg car-
bonyl group: formaldehyde, acetaldehyde, acetone,
acetyl chloride., monomers of formic and acetic
acids and dimers of formic acid. Results are
tabulated. Indebted to M. A. Kovner
274T86
A

A

M. V

of ilte W
Zf4iQTlics of 6=4)zdary
blivyl alctibil!, flicithyl- aadahyi-'Vi~,Yl (narbinob, in the
h-ght of lh~ awlic,,r's ih:wry (19N). (n
ck,-w- phys., S. 4,79-91 (Jz-,c. 19)7)L
It Ls (,curd that a tecund appown--lian bur the
gyracc.-ar., or matcmU.- cormunt of op,ji,.al ACUMV
bc tak-n consAcraliun Ea~-F
bct"c4n ariJ
atsio predwf~ a numLcr of ottv--i kiwwn
fncls~ c !. Thal lia"wral-d cArb!nol, 'O.'att lll~ 0;%cw
of pilaliz~', ;~~(
sil"e.ac" Wixft.y

Theory of the relavkdo 11 0pectrunt of 9k pulymerfe a,iLi,
Va, Va. Gotlib wid bl. V. Vol'iccushtela. Zhut-.
Pi:. the tmsW of the niodel of
Kargin (C.A. 43, 7201r) the dynarnic behavlor cl a high
polymer in snin. wug calcd. PalydiatmrNion cutwx un ex-
panslon and change in fohn of the distributlon futiction of
rcla=60" UNIC, Wlltrta3 the GAVIALM IlbtribUtIOZI Of Inol.
ffip. has prwfimdly no effect. 49 referesices. A,

. . . . . . . . . . .
1 V OL Tn-r nH T- F YN
2. ussR (6oo)
It. Adsorption
7. Theory of activated adsorption, Part 1) Tnur.fiz.khim. 27 no. 2, 1953.
9. Monthly List of Russian Accessions, Library of Congress, APRIL 1953. Unclassified

4 -ON--,W-4
at em Merv. M.
et vorkm=h-
aud 0 ffizt-R-~-~W t
pd-j., Acad. Sci. USSA, Leninu-4d). Zhu, i1i,
q Khim. 27, 76-W 1953). d. C.A. 46, 21; 48, 1.1140d; 49
-The V ~d as un equil'
2162c. polymer chnin Is coru etL
mixt. of rotatioual isowAn.- Chain is crized by
t4e degree of convahition, or the thermodyn2inic flexiblUty,
and the kinetic flembility. The degree of convolution is
the ratio of the max. length of the chain to the L-iWh of the
convoluted chain. A method is given for the eaten. of this
ratld and it is applied to a* series of polymers. A study of
the proptrties of thtse mols~ shows the relation between
the flexibility of (be mols. and their them. structure.

VOLOY.-UISHTEYN, M. V.
USSR/Physics - Polymers
Apr 53
"Statistical Physics of a Linear Polymeric Chain," M. V. VolIkenshteyn and 0. B. F-titsin
Usp Fiz Nauk, Vol 49, No 4, pp 501-568
First part of a review that will be continued. Analysis of statistical theory of an
isolated chain mol. Discusses possibility of predicting the phys properties of
polymers from their chem structure. Assumes the polymer to possess considerable
number of degrees of freedom, which is responsible for its great elasticity. Also
Discusses the rotating isomeric theory of linear polymers and statistics of real
polymeric -mols. Lists 125 references, 35 Soviet.
267T90

VOLII(ZNSHTEYN, M. V.
259T87
USSR/Physics - Ultrasonic Absorption 11 Apr 53
"Absorption of Ultrasound in Solutions of Polymers,"
Yu. Ya. Gotlib and'.M. V. Vollkenshteyn
DAN sssR, Vol 89, No 5, pp 821-824
Derivation and soln of the eqs describing_,the
Kargin-Slonimskiy model-IV. A. Kargin and.'G. L.
Slonimskiy, DAN SSSR,, Vol 62, No 2, 239 (1948);
Zhur Piz Khimii, 23, 5, 563 (142)) of a net-like
high polymer i rsed in a soln as a sequence of
sphere-segments connected by quasi-elastic forces
of a statistical character. Presented by Acad A. N.
Terenin 13 Feb 53.
259r87

VOL I KZ-NMT ---YN if. V.
USSR/Fayeicz - Molecular I/--ngths 21 AL-r 53-
"Length of the-Molecular Chain in Cis- and Trs3as-
Polydienes," A. A. Chistorazum, In-st, of High-
Molecular Compals, Acad Sci WSR
DAN SSSR, voi 89, No 6, pp 999-1002
Calculations of mean square distances in chains with
alternating double bonds and different valence
angles in the case of the polymers polybutadiene,
polyisoprene-, and polydimethylbutadiene are given.
Acknovledges the int-erest and assi6tance of 14. V.
Vol'kenshteyn and 0. B. Ptitsyn, vho developeiL the
259T97
~'59T97
formulas for the mean square distance between ends
of a chain having N identical bond-, taking into ac-
count extent of hindrance of rotation aroun,! each
bond (DAN SSSR, 78, 879 (1951))i Presented by Acad
A. F. Ioffe 21 Feb 53.

USSR/Physics - Polymer Chains 21 Aug
"Stretching of Polymer Chains," M. V. Vol'kenshteyn
and-0. B, Ptitsyn,'-Inst of High Molecular Compds,
Acad Sci TISSR
DAN SSSR, Vol ql,, No _S, P- 1313-1-~a6
Conclude that for s911 extensions (disregarding
torms of the orrl,~r x~)th;- "onergetic' elastic force
fl and the "entropic" elastic force Q COD"ected
with the transition of convoluted isomers into trans-
ir---rs comnensate each other; consequently,fbrsmall.
extensions this transition does not change the free
275T95
energy of the chain and the recovering force bears
a purely entropic character. For large extensions
the above-indicated compensation will not hold.
Propose that a one-dimensional model in the main
correctly gives the dependence of stretching of
polymer chains upon their flexibility and external
force. Presented by Acad A. F. loffe 22 Jun 5-1.

KITATOORODSKIY, A.I.; VOLIXICNSHTEYN, H.V., redalctor-, BELOVA, V.I.,
~ It.
redaktor; ASTAY-1-y-SM- G. 'te Icheskiy redektor.
[Order and confusion in the world of atoms] Foriadok i bes-
poriadok v mire atomov. Mosirva, 12d-vo Akad. nauk SSSR,
1954. 69 p. (MLRA 7:12)
(Atoms) (Crystallography)

Vo 4'iF A/ -5 IV 7,5
GRINBERG, A.A. (Leningrad); BABAYEVA, A.V.(Moscow); YATSIMIRSKIY. K.B.
(Ivanovo); GOREMYKIN, V.I. (Moscow); BOLIY, G.3. (Moscow): FIAL-
KOV. Ya.A- (Kiyer); YAKSHIN, M.M. (Moscow); KZDROV, B.M. (Kosccr,01
GZLIMIN, A.D. (Moscow); FEWROT, I.A. (Moscow); MAKSIMYUK, Ye.,L.
(Leningrad); VOL' KENSHT3YN,,-,,M-, V. (Leningrad); ZHDANOY,,G.S. (Moscow);
PTITSYN, A.V. (Kishinev); VOIIM=, L.H.
(Dnepropetrovsk); TROITSKAYA, A.D. (Kazan); KIC-CHKO, M.A. (Moscow);
3ABAYXVk, A.V.; TRONEV, V.G. (Moscow); RUBINSHTZYN. A.M.(Moscow)
CIEUZNYATEV, I.I.; GRINBM, A.A.; TANARAYZV., I.V.
Nkplanation of the transeffect. Izv.Sakt.plat.i blag.met. no.28:
56-126 '54. (MLRA 7:9)
(Compounds, Complex) (Platinum)

VM/ Chemistry. Physical chemistry
Card 1/1 Pub. 147 18125
Authors Bazhenov, N. M.., and Vollkenahteyn., M. V.
Title I Cptical activity and reversible isomerization
Pdriodical : Zhur. fiz. khim. 28/7, 1299 1309., July 1954
Abstract : The quantitative connection between the magnitude of optical activity
and the nature and orientation of atoms and bonds in the molecule, is
explained theoretically. The differences in energies (also entropy)
of reversible isomeral were determined on the basis of the thermal
process of the optical activity-of many substances. A new ultraviolet
polarometric method for the study of the thermal rotation process
and the dispersion of the optical activity of tested isomers,, is
described. Twenty-one references: 8 USA; 1 German; 11 USSR and
1 English (1902 - 195-1). Tables; graph; illustrationis; drawing.
institution : Acad. of Se. USSR, Institute of Highmolecular Compounds., Leningrad
Svbmitted : November 30, 1953

HEM]= mmuwak . . . . .
110L I mt, ~Irmy
USSRI Chemistry* Physical chemistr7
1/1 Pub. 147 19125
Authors t Bazhenov, N. M.9 Vollkenshteyns M. V.3 and Bybreviah,.T. V.
Title optical activity of gaseous methylviny1carbinol
Periodical Zhur. fiz. khim. 28/7, 1310 - 1312, JulY 1954
Abstract A method of measuring the thermal process of optical activity in gaseous
of the spa----',;ram,
developed. The
Institution
was
phases in the ultraviolet. zone
optical activity of gaseous metbylvinylcarbinol and the molecular
constants of reversible isomers of this compound, were investigated
and the results are given in tables. Two references: 1 USA and
1 USSR (1925 and 1954). Drawing.
: Acad. of Se. USSR, Institute of High Molecular Compourids., Leningrad
Submitted : November 30, 1953

VOL M11"11
USsn/ Chemistry Physical chemistry
1/1 - 20/25
Card Pub. 147
Autbors I Volikenshteyn., M. V., and Brebdo_, V. 1.
Tit le t Effect of intermolecular reactions on reversible isomerization
Pori.odical
A"antract
Institution
Submitted
j Zhur.~ fiz. khim. 28/7, 1313 - 131B., July 19514
t The differences in energies of intermolecular reactions of convolute
and trans-isomers of 1.2-dichloroethane and 1,,2-dibromoethane, were
estimated quantitatively. It was foundthat an orientational reaction,,
between molecule.s. balances the energies of revers:U)le isomers in
liquids. The effect of intermolecular reactiormi, on the relative
stability of reversible isomers, is explained. Eleven references:
4 Japanese; 3 USSR and 4USA (1939 - 1953). Tables..
Acad. of Sc,, USSR, Institute of High Molecular Compounds, Leningrad
-..November 30, 1953

'Physics
Card: 1/l Pub. 22 14/63
Authors a Gotlib, Yu. Ya.; Vollkensh_toyn., M-.B.; and Byutner, E.K.
-'Utle t Anisotropy of the Polarizability of chain molecules
Periodical I Dok. AN SSSR 99/6, 935-938, Dec 21i 1954
Abstract t An analytical derivatiQn of the polarizability of a chain molecule
containing a number of equal links characterized by A symmetrical
voltage of the inner rotation (V(T )=v(-s , is presented. The matrix
and tensor method was used for the computaplons. Five references;
3-USSR (1942-1953). Table.
Institutions: The Leningrad State Pedagogical Institue im. A.I. Gertsen; The Institute
of the Figh Mfolecular Compounds of,the Acad. of Scs. of the USSR
Presented by: Academician A.F. Ioffe, September 18, 1954

VOLIMISHMN, 14.V.; SOKOLOV, H.D professor, redaktor; BSFKLN, Tu.A.
re a,' o IRNOTA4A.T., tekhaicheakiy redaktor.
Nolecules and their structure] Molak-uly i Ikh stroanis. Moskva,
12d-vo Akademii nauk SSSR, 1955. 229 p. (MLRA 8:12)
(Molecules)

1a
i
VInternal rotation in and the PhYM I
0
-
I- Of polymer Ch a in S.
Pro 6 OL H. 40. .
t
,
.
d 0. B. Ptitsyn, ~ Zhur. Tekh. St.
-Cf. The av.
and averages of the squares of the distances between and
among the &ain ends. of polymer chains are caled. when
e
they are under th action of an external force f, and these
averages in their most general expression are presented as a
series offilkT., where I is the length of one link of the chain. f
The equations aresolved for one-dimensional and two-di-
~Meniiou-rd models on the basis of the theory of rotation
Mmery, and the various mechanisms of chain elongation

are discussed. The findings on these models can b
C applied
freely to linked chains with long statistical elements, this
Is Aetd. from the congruence of the max. length ~a av.
square oUthe length of such model with the coff6potiding
dimension of the true chain. The diffusion analogy cannot,
be applied to such a chain, which is under the influence of an j
external force. - IH. The change of the -internal energy of
polymer chains upon elongation. Ibid. 662-70.-Math.
.,0a, elongation of the, polymer chain with impede4l interr6d
rotation, there is generated in such, chain not. only an enE
tions th
tropy, but also an energy form At small dongai
force is compe=ted by an addul. entropy energy thatj$ riot Ix
taken into account in ilia ordinary theory. Theelongatioll
i
l
n a block is d
of the polymer
scumd, and thus an expr".9'
of. rubber Is-obtal
--------- - -- - sion far the inadnJus of elasticity 14 that-~
is,:based upon the grid theory. The energy effects that
-
-
-
I
i
)
~:ocl-
ur on clang
ation of the p
ywrr
n a block are discussed
also; - the t;p- beat of the polymer chain changes 6pou,
dollaution. Averm

Al
Category USSR/Optics , Ftysical K-
Ab a Jour Ref Zhur - Fizika, -1jo 2, 1,;,~77. 'qo 49
-9,)
Author Blazhenov, N,M~ . V0 M.,V., ~'Yolotina, T,.A.
Title Optical Activi;.y 8nd Vit-Lt-fi--r-tion. -
Orig-Pub Zl--. . t,~-.kbn. fiziki, No 11, 1661 -186,,-
Abstract Investigation of 'the tempf~r6tux~ vax,laticn of tht~ rotation of the
pl&ae of polarization In rosin. The curve ~A~T) dispi.a.ye a break P--+~
the rosin vitrification temp,~~r-atux-e T -:::: 2V. Th-- tr-~-.k at the same
o-
amperature is- observr~d on thf~ cum. gn an r.. is th,~~ index
t
of refraction and,? t.--,i dt-nF-i+--y), K wtere K is a con-
stant, and g is tb-e moj~~-iula--, rotation constant 7,gyration). Using
the Lorentz--Lorenz F Uation th-,~; authoT3 deriv-~ &r, exp7za.5AIon
2.-
-n
? 6~7- 7 r
Esttmating the individuel 14~.zma of tbi- -quq+ion frcn. obtained exp~ri-
I I A~ , .-
mr!:ntg-l data, the autlaora obtairl --..,o..04 6,nd show that thFt
tempe-rature iraxiatior I.), t~,.fjd th-- br,:ak in "-be df/dT Sit
Card 1/2

Category : USSR/Optic& - Ptysic-H-! or-tj.:.z~
Abs Jour : R -7
F,.t &nlr F:L z i ka , 27C. -'n 4990
T ars dst,~rmined no' C).r.7l.y !;y th~-- clne.~-g-~ i-n d OITP b-.-,.t ~13o by th6
A:.ect change i- g, in dg/ir-P, RiLe quantity '-,/g; Ag/dT'i chang-i
i n th,-7 case. of
9
'd
quantity '1/ /dT --b.- ~utj,_oj:S ladiCa":i,
t'~ + r in -., f-at i gat ion
O.L tbi,~: t C-Mpe bF7:~,5,vlor of t-~iF- cip-lical &-:ti,~ity glu-6 a nev sensi-
tive method f or s t.-LLdyir.,_;x -~, 4m' rl +-, if i c at ion , mki rig it PoS c~ -tr) in
vestigat,~-~ Separat-ly tt- '-ha in t.h-r. MILF,.-
cul.e, p;mking --trwriatlon of dlf~/-It) r~rd vitli th,~ t7-. + i t
g* CF _~je
intaraction of dg/dT'
Card 2/2

V k_, L.- I ~ V_ r1 Y
Category USSR/Atomic and. Molecilla Physics - Physics of W4;h-molecular substance D-9
Abs Jour Ref Zhur - Fizika,~No 1, 1957~No 1019
Author Nikitin, V.N., Vol" kenskteyn, 14-V._, Volchek, B.Z.
Title Investigation o?_tE_e_STr_etcbing of Polymers in Polarized Infrared Light
Orig Pub Zh. tekhn. fizil-A, 1955, 25, No 14, 2486-2491
Abstract The authors derived an equation for the ratio of the coefficient of ab-
sorption of two bands at various degrees of tension (Kfl/K'2): (Kill/K"2),
vhere the indices 1 and 2 pertain to bands %) and V and the indices -~ and
1 2
J3 pertain to the first and second stretchings. This ratio is unity if the
content of the-rotation isomers does not change with st:retching. The
stretchlug of polyethylene and. polyvinyl acetate was investigated. It is
s6wn that at elongations of 1,000~.b and more, the content of the rotation
isomers changes. The stopping of the growth of dichroism. at 100% elongation
indicates the absence of further orientation.
Card 1/1

VOLIKHNSHTSYN, H.V.; PTITSYN, O.B.
~ 1' 1.
Relaxation theory of vitrification. Dokl.AN SSSR 103 no.5:795-79a
Ag '55. (MI,'HA 9: 1)
l.Inatitut vyaokomolekulyaLrnykh soyedineniy Akademii nauk SSSR.
Predstavlano alkademikom A.F.Ioffe.
(Vitreous state)

VOLIZENSMYff, N.V.. TLZYKGVA, S.M.
Intensities in vibration spectra and the 'metalliew model of the
molecule. Dokl. AS SSSR 104 no.6:834-836 0 155. qniL 9:3)
1. Institut vysokonolskulyarufth soyedinenly Akademll nauk SM
i Irizicheakiy institut imeni P.R. Lebedev& Ak-adenii nauk SSSR.
Fredstavleno akadealkon G.S. Landubergom.
(Raman effect) (Spectrum, Molecular)

VOL'KENSHTEVI, M. V. . and PTITSYN, 0. B.
Introduction by M. V. Vollkenshteyn and 0. B. Ptitsyn, XMb
lemy Sov'remennoy Fiziki, Vol 81 14o 12, Dec 56, PP 3-5
This issue of the periodical Problemy Sov-remennoy Fiziki, which
publishes translated axticles illustrating progress in various fields
of physics outside the USSR, represents a collection of non-USSR articles
on the physics of polymers. The tran lations contained. in this issue
have been edited by M. V. Vollkenshteyn. Vollkenshteyn and Ptitsyn
comment as follows on five articles published as a separate section
(PP 173-222) under the heading "'!he Action of Nuclear Radiation on Poly-
mers":
'!The last, sixth section of the collection of articles conssists of
papers that deal with the action of nuclear radiation on polymers. This
field is of great interest from both the physical and -the chemical stand-
point, because the processes which take place in polymers under the
action of radiation (cross-linking, etc.) lead to the formation of sub-
stances which have new and valuable Frcperties. Investigation of the
processes and characteristics involved is also of importance for nuclear
technology, in which some higb-polymer materials are applied."

USSR / Optics K
Abs Jour: Referat Zhur-Fizika, 1957, No 4, 10353
Author : Bazhenov, N.M., VolIkenshteyn, M.V., Gotlib, Yu.Ya., Rosen-
Inst : Not Given ------ shtcyn. L.D.
Title : Photoeleastic Effect in Polystyrol and 1+.5 Halogen Derivatives
Orig Pub: Zh. tekhn. fiziki, 1956, 26, No 8, 1730-3-737
Abstract: The photoelastic effect (PE) was measured in poly-tyrol (I)
dichlo~rclstyzro_!
(130000), poly-Darachlorosty-,cl (II) poly- 2-5
(iii) (6oooo), polyorthochlorostyrol 'IV) 180200), poly-,~.LL
dichlorostyrol (V) (300001)., pCly0_rthoIodos~,,,rr_ol (VI) (20000)
and polyparaiodostyrol (VII) (-312000). The nun_ibers i-n the
parentheses represent the molecular weights. The PE was st-l..1dieed
in tension of thin film by constant load and at temperatures
above the vitrif ication temperature - With the aid of a setup
with a polarization microscope, sin3_1,~,aneous measlaxements were
made of the elongation,6.1/6 , the birefringence,A a, and the true
load The PE in vitrified films was measured. ir. a priol;oelect-ric
Card 1/3

US~R / Optics
Abs Jour: Referat Zhur-Fizika., 1957, No 4, 103553
K
setup. The time dependences of zA n, and. -the ph:)toelast ic
coefficient c-Ir = A n/(S' were obtained. The tension curves have a
characteristic S-Shape for!r with a relative satur-ation, this being
due to the presence of a labile lattice in the block linear poly-
mer. The step-like character of the tension of I discloses the
damage to the lattice structure and form tion of new labile nodes.
,f rapidly reaches its no iTmim value and diminishes only sli ghtly
upon further tension. cc_max is practically indeper. ent of 6- -+
over a wide range of 6-init (for 11: 2 -- 18 x log dyne/cm~~"The
average values of E max were used to find the effective anisotropic
polarizabilities of the chain,6c>~ (Treloire, L. PhysicA of Elasti-
city of Rubber , IL, 195j): I -- 140, 11 -- 210, 111 --- 170, IV --
130, V -- 340 x jo-25 cm . In accordance with the theory (Got 'lib
Yu. Ya.., Volkenshteyn, M.V., Byutnor, E.K., Dokl AN SSSR, 195~,
99, No 6, 935), the known value of-e) (the average cosine of the
angle of internal rotation about the bona C-c in I) and the value
of were used to determine_,.A, = cos2 is the angle of
Card 2/3

US~R / Optics
Abs Jour: Referat Zhur-Fizika, 1957, No L, 3-0353
K
rotation of the phenyl ring), after which these values lf_,.Li and,,,
were used to calculate6o( for II -- VII. Satisfactory agreement
w-ith experiment was obtained for II and V. whi&.L indicates a si-
milarity in the conditions of internal rotation in 1, 11, aDd V.
For II and IV, which contain chlorine in the ortho Dcsition, the
calculated values of Aco, are greater than those dlbsey.~'~ed, this
being due to the greater resistance to rotation of the suspended
-weight.
Card 3/3

V Y-, F- N ~5 14 TV4, V
SUBJECT USSR / EHYSICS CARD 2 PA - 1561
AUTHOR WOL1XENSTEJN,1M.V., PTICYN~O~B~
TITLE The Relaxation Theory of the Formation of Glass~
I. Solution of the Basic Equation and its Examination
PERIODICAL Lrn.techn.fis,26, fasc.10, 2204-2222 "Or,')
Issued. 11 / 1T56 ~ .1 - ID I
Proceeding from the most general molecular-kinet4o ideas the basic laws of
glass formation and of softening are here derived, The theory found must then
be suited for all obJects from which glass is formed. Relaxation processes are
here dealt with by an equation which describes the transition of kineti,:. units
.Lrom one energy state to another. The spectrum of relaxation times is on this
occasion neglected. Reaction may be of the first or second order someri-
zation" or I'd-1merization" respectively). The influence exercised by reactions
of a higher order may be neglected, In the case of a reaction of the first
order the elementary acts of transition from the nonexcited state (state ') to
the excited state (state 2) take place with the participation of only one
kinetic unit The reaction of the second order consists in the production and
dissociation of the bindings among the kinetic units. On the occasion of the
investigation of such relaxation processes which are connected with only
little deviations from equilibrium the equation of the first order may always
be used. Here only reactions of the first order are investigated- Reactions
of the second order are studied later,
At first- an expression for the solution of the basi-- equation is givens On thi3

V
Zurn.techn.fis,26jasc 10,2204-2222 (1956) CARD 2 / 2 P1. 5 6 1
4
occasion the dependein-ce of the turansition probability on the st~----iccture of take
liquid is neglected. At first the most simple proccess is investigated -~:r which
the exterior parametere of the system do not depend or, time "Text the --ase -'s
investigated in which the temperature of the system changes with oons-.Ant or
variable --,relocity. Tl-,o solutions found for the share V of the kine-tic units
which are in an exci,*.ed state are written down, There follows the Mathematioal
discussion of the aolution obtained.
Forming of glass and softening. Every -3yatem natiBfy:lng the above conditions
is suited for the formation of glass in connection with cooling and for
softening durIng heating Furthermore, equations are obtained which f;onnect
the temperature of glass formation TI and cf the softening T with the para-
9
meters Df the system and with the modification velocity Ifl,071ith increasinC
dalso T and TI increase. Next, the solutions of the basic equation for the
9 9
vitrification interval and for the domains above and below the vitrification
interval are discussed, Among others, V does not depend on temperature
with-in the range below the vitrifi,~ation interval. 4-e- the structure of the
liquid is frz)zen.
INSTITUTIOBT. Institute for Hlg].,~Iy Molecular Compounds of the AcELdeny of
Soien~.,~ -.n the USSR.

tTvplttjqf cnpntahl~lm Po my"fi.
1 he
equAtioLi ui~~ w c"Ic-
cl~ La 11- :it t1l;-zii y f." -wr,
'16 zclup A-d a~ - f'A7',,!i:-e-iil-4,ll.,-,4. frtqs-tc-~,:i.
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Matek&27 X Vacaryd-Inogo oo7oahchani7a po spektroakopi-l. t.
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Molekulyarna7a spektroak,piya. (Papers of the 10th All-Unio
Conference an Spectriacopj. Vol. 1% Molecular Sp6ctrosoopy)
(Llvovl Izd-vo L-vovakogo univ-ta, 195T. 499 p. 4 COO copies
printed. (Sarlsai !tot Pizychnyy zbirn7k, v7p.
Additional Sponsoring A-gencyt Akademiya nauk SSSH. Konisaiya p0
spektrookopil. Ed.i Jazer, S.L.; Tech. Ed.: Sarartyuk, T.V.;
Editorial Board: Landaterg, G.S.. Academician (Reap. Ed., Deaeao*4),
Neporent, B.S., Doctor of Physical " Mathematical Sciences,
?Abellnakiy, I.L., Dootor or Physical and Mathematical Sollonce&,
Fabrlkavt, V.A.. Doctor of Physical and Mathematical Sciences,
K0173111RUJ4, V.Q., CaMidata of Tao~=Ioal Science&, Rayokly, S.K.,
Candidate of PhIsica-1 an4 Mathematical Sciences, falnovakiy, L.K.,
Candldate or Pbja4.oal aznd Mathematical Sciencess MillyanchuXt V.S,
Candidate of Plqsioal Pund MatharAtical Sciences and Glauberuan,
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A. Ys, Candidate of Physical an
Card 1/30
nkitizi. Va.. B.Z. volchak, and-N.V. Vol-kanshteys.
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Usina Infrared Polarized Light
1
tbA Orientation of Polymra
-
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and O.B. Ptitayn. Behavlor or
NY
d"ZOA Bonds During Vitrification
43T

Lazarev, A.H. Vibrational spectra Of Orthoaniol.110
Acid Eaters and Their Relation to SLI.Ioata Spectra 440
LOtkOvs, Z-H-, V-V- ObUkhov-Denisov, N.N. Sobolov,
and V.P. Charom-4sinov. Raman Speatrus, of V1t-ou*
Boric Anhydride "5
fild0rov. T.A.. and N.N. Sobolov. Infrared Spectra
and ths Structure of Phosphorous, Phosphoric and
Boric Anhrdr1des 448
BObovieh, Ya. S., and T.P. Tulub. RavAn Spectra or
Double-oomplex ailjogt* (11,,
gea 455
30v*h6nk4
N,
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, and V.A. F2orLnak&yjL. Reflection
,j
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and ast Lon Spectra of Various Modifications
or Ulica 1A th* Wave LAngth Range From T to 24
)doronjp

"'ale zat of, -pre so 7~tcd at I'a -_-'c-.
on the Chemistr",;- anu-, of Polyi--ers, 2C Jzj7-.-2
B - 3 3

"St-rQtc;,.E:d films of in rclarlz~,-(! ir-f-rarc-d
inst., Acaa. sci-.,
Chomist,.y P--ySics of PC,
1~ mers, 2~ Jon-2 Yo'b
B - 3 , OF

"Synthesis properties of sorme stece-o-Isomocric pol,,amide:i oi.,.! pol-~c".-.erz
a poper presented at the ConL;ros-z ontl-ie a., "! Fl "sics -f H-11~1,
2P- Jan-2 -'Web 57, Moscov, ko-ly:11-icr ;-cs'.3orcit ins".

1~ y 011--,
"The phcbelostic effc!ct u-nil tlic froo rc~ition o-C lirk~2ar
-C of 14-1-1 Polymers,
paper presented at the 'nti, Congress on The Chemistry pli-31.
28 Jar-2 fob '17, 7..Ic)scc;,,;, Ins".
, 195
B-30-4 ~)~

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at the ~ttla Con.-n-ess oi-I tl.-~c Cliemistr, - ond F SJ Cs of lial P,:~ly-z!~,rs 2c, jv'----2
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VOLn'175TEMI M. V. J, ond PITT'Mll;~ u ~ V .., - LJ - . . a-'
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W-,,>,,,,
"Theory of Elongation of Pal-mer Choins and v -pw~er
submitted at -tlie Iriternational 6yMosiu-:, on Vacromoleculor Y
9-15 Sep 1957, Fr3gue.