SCIENTIFIC ABSTRACT VOLKOVA, L.A. - VOLKOVA, L.M.

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SCIENTIFIC ABSTRACT
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A060_29_ig~ fidk. _66 66- U.-Ri. /6--b~67C6ro(56/6657oo-L4/0-61-7 AUTHOR: Volksy�,_ L. A.; Yushkin, G. V. ORG: Orenburg O~i-a~ci--Sanitary-EpidemiologicnI Stntion (Orenburgaknya oblastnaya sanitarno-epi emiologisheskaya stanLsiya) TITLE: Tulare-rda4in Oronburgsknyn ObInat, 1. SOURCE: Zhurnal mikrobiologil, epidemiologli iImunoblologli, no. 5, 1966, 14-17 TOPIC TAGS: tularemia, epidemiology, pathololij, rodent, disease incidence ASTRACT: On the basis of a study conducted between 1960 and 1962, ,the 4uthora ooncluded that tho boundaries of the natural focus of ,-tularemia in Orenburgslcaya Oblast (a floodplain rnramp) have tended ito exuand since the disease was first reported in this area In 1928o In 19~0, six cultures of F. tularensis were isolated from Arvicola Iterrestris L., CrIcetus cricetua L., Apodomus sylvaticus, and Citellual, !maximum, Tho number of rodents caught in enzootle and nonenzootic I,regions was about the same, but the tularemia pathogen was not loo- ,lated from any of the rodents caught in the nonenzootio regionse 'The pathologi.oal changes characteristic of tularouls were found Imainly 14 the watp;X.yolent e.g,, en3.sXApmept_of..~1Wq..2;MPh 1~?dpW-_ of'ifie liver and marked spleno-me-galy. Orig. art. has: -_ 2 tables. 1JPRSt 36p9321 SUB COM 06 / SUBM DATEt 15Jun64 / ORIG REF: 002 card 111 /,0 1- UDC: - L 40072-66 EWT(m)/EWP(J)/T ACC NRI AP6C12417 IVS AN fiI)SSR IJP(c) Rm SOUCE CODE: UR/0183/65/000/006/0022/0026 'HOR: Sorokin, A. Ya.; Andreyeva~ N. A.; Vollkoya. L. A.; rp;Ltsov_, A. I.; akov, A. -F.; Pyrkov L, M.; Frenkell, S_ Ya '7 ITLE: Corre- 'ation of structural and mechanical characteristics of olvvinyl alcohol fibers 15,Investigation of supermolecular arrangement n chemleal fibers and means of increasing their strength,,,/ OURCE: Khimicheskiye volokna, no. 6, 1965, 22-26 OPIC TAGS: polyvinyl alcohol, synthetic fiber, polymer structure, longation, rupture strength, correlation function, NMR, X ray analysis ABSTRACT: The structural and mechanical properties of polyvinyl alcohol fibers were investigated using the range of thermoplasticized stretch as the controllable variable. Correlation between these properties was shown. Linear correlation was established between the overall orientation of the machromolecules in the fiber and orientation of the crystallites; between rupture strength and maximum relaxation stress, anc also between these values and the reciprocal half-width reflection UDC: 677-744-72 " ~Vv C-00 ACC NRI AP6()12417 and the amount of elongation (up to 450% elongation tested). It was shown that the parameter(~jljtdescribes the previous history of the samples with respect to macromolecular orientation. NMR studies showed the basic conformation of the polyvinyl alcohol fiber macromolecules is flat trans-zigzag. A combination of different analytical methods (NMRP X-ray, isothermal beating) can be used to study in succession the structure formation processes at different stages of fiber formation, Orig. art. has: 4 equations, 8 figures and 2 tables. SUB CODE: 07,11/ SUBM DATE: 09Jun64/ ORIG MF: Oll/ OTH REF: 003 [card 2/2 l1b M L 2?1.16--66 MT(l)/T JK FA-CC NRI AP60C ,4869 SOURCE CODE: UR/0402/65/00 /005/0613/0614 AUTHOR: Noskov, F. S.; Boldasov, V. Golldin, R. B.; N.V.; VoTEO-Vap LeAe ORG: Military Medical Academy im. S. M. Kirov, Order of Lenin Leningrad (Voyennomeditsinskaya ordena Lenina. skad TITLE: Contrast medium for Immunofluoresoent detect4of adenoviruses in Coll cultureslof guinea pig kidneys SOURCE: Voprosy virusologii, no. 5, 1965, 613-614 TOPIC TAGS: virus disease, animal disease., experiment animelo ABSTRACT: Bovine serum albumin labeled with sulforhodomine B fluoride was tested as a contrast medium for adeovirus type 4 Infected guinea pig kidney cells stained with fluorescein. The Infected cells were exposed to th3 specific rabbit immune globulin, then added with fluorescein isotbiocyanate at a rate of,10 mg fluoroebrome per 1 g protein. The phosphate buffered serum albumin was first conjugated with freshly synthesized sulforbodamine B fluoride in an alkaline medium,, then -purified. Th.e fixated adenovirus preparations were treated Card 1/2 .ACC NRs AP6004869 W'itb the mixture of conjugates for 20 minuteas then studied.under the luminescent microscope. *Normal cells'were brick red, the protoplasm :fighter than the nucleus; the Infected nuclei bad a specific green color with bright green sparkling enclosures. Upon single step processing of the preparations, the specific interaction of virus antigen-antibody was not inhibited by the presence of the labeled albumin',, The -?bysicocbemical absorption of labeled albumin on calls i led t0 nonspooffio staining of the backgroud (cells containing no virusJ antibodies) which did not depress specific fluorescence. This method also permits the detection of single infected calls, Its use is recommended. "The sulforhodamine B fluoride was plaood at our disposal by Prof. I. S. Ioffe whom we wish to thank for his courtesy", Orig~ art. has: none. SUB CODE: 06/ SUBM DATE: 26Nov64/.,OTH REF: 006 2/2 Y\- o \/F1L PHASE I BOOK EXPLOITATION 1043 Ural'skiy 2-.avod tyazhelogo mashinostroyeniya, Sverdlovsk Proizvodstvo atali (Steel Production) Moscow, Machgiz, 1958. 154 p. (series: Its Sbornik statey, vyp. 3) 4,000 copies printed. Ed.: Zamotayev, S.P., Engineer; Tech. Ed.; Dugina, N.A.; E)mcutive Ed.(Ural-Siberian Division, Mashgiz): Kaletina, A-V., Engineer. PURP099: This book, published on the 25th anniversary of the Uralmashzavod (Ural Heavy Machine-building Plant imeni S. Ordzhonikidze) Is intended for engineer.3, technicians and scientific workers concerned with the production of steel. COVERAGE: The basic stages in the development of steel making during the 25 years of the e;dstence of the Ural Heavy Machine -building Plant are described. The following achievements in the field of steel making technology are described: vacuum pouring, resulting in an improved quality of steel; production of Ingots in a variety of special shapes; steel making in open-hearth and electric fuxnaces. Research work done by the central laboratory of the plant, including a study of the causes of the formation of internal cracks in heat-resistant steel ingots Card 1/3 Steel Production 1043 and a study of non tallic inclusions, macrostructure and intracrystalline liquatim in large ingots, is also discussed. TABLE OF CO'_MNTS: Zamotayev, 113.P. - Production of Steel at the Ural Heavy Machine Building Plant 3 Zamotayev, 113-P.; Bogorodskiy, A.L.; and Mikullchik, A.V. - Improvement of the Quality of Steel in Vacuum Casting , 17 Demakov, A.Ye. - Technological Process of Steel Making in the Open-hearth Furnaces of the Ural Heavy Machine-building Plant 36 Malkin, I.P.; Volkova, L.A.; and Razhitskiy, V.I. - Making of Stainless and Heat -re s istant-Sfeies - a~e Ural Heavy Machine -building Plant 52 Bogorodskiy, A.L. - Influence of the Casting Mold Design on the Quality of Ingots 62 Bogorodskiy,, A.L. and Mikullchik, A-V. - A Study of a Massive Ingot 76 Bogorodakiy., A.L. and Blinov, V.V. - Causes of the Formation of Internal Cracks in lk!at-resistant Steel Ingots and Thermal Effect of the Mold on the Ingot 101 Mikullchik, A-V. and Golubina, O.P. - Nonmetallic Inclusions in Acid Chromium-ni(:kel-molybdenum,Steel n6 Card 2/3 Steel Production 1043 Bron, V.A.; Bogordskiy, A.L.; and Semavina, K.P. - Wear Characteristics and Experience Gained in Improving the Life of an Open-hearth Furnace Bottom Popov, A.A.; Mirmel'shtein, V.A.; Fedorov, A.B.; and Shcherbakov, A.P. - -Macrostructure Characteristics of Cast Steel Popov, A.A.,; Ferminov, P.P.; and BogorodBkiy, A.L. - Intracrystalline Liquation oX Carbon Along the Height and Cross Section of a 36-ton Chromium- nickel-molybdenlim Structural Steel Ingot AVAIUMZ: Library of Congress 128 139 150 Ca:rd 3/3 GO/fal 1-8-59 VOLKOVAp Lyudmila Andreyevna; VOLPYANSKIY, L.M.,, inzh., red.j 4~-~UGM ",-X.T-te-Uh. red, [fetal ia.elting in induction fumacoo) P:Lavka inotalla v In- duktsiomiykh pechakh. Pod red. L.M.Volpianskogo. Moskva, Mashgiz, 1961. 99 p. (Hatchno-populiarnaia biblioteka rabo- chego-liteishchika, no.17) (MIRA 15:3) (Electric furnaces) (Foundries-Equipment and supplies) XLENKOVA, N.I.; KULAKOVA, O.M.; VOLKOVA, L.A. Determination of the density and other,proper"Ies of cellulose fibers characteristic of their structure in r6lation to reactivity. Zhu~.- prikl.khim. 36 no.1:166-~176 Ja 163. (MIRA 16:5) L Institut vysokonolekulyarnykh s4ledinenly AN SSSR. (Cellulose) A*K,;.V.LMVA L.A.; MAKAROVA, V.N. SMMNOVAJ~ A.V.; XWNOVAP P.. am. Methods for the exposure and determination of the grain size ofaustenits in steel. Standartizataiia 27 no.5;23-28 163. (Austanita-Metallcarapby) (MMA 16:61 PETROFAVI,CVI~;KIY, G.A.; VASILIMA, G.G.; VOLKOVA, L.A. Determiration of structure changes in cellulose at thc 'nitial 0:3terificaLion stages by X-ray diffraction analysis. Z.-.ur. pi,IkI. khIm. 37 no.9:2008-2016 S 164. 17:210) KJIENF--,'V--A , . ; , )~'% ; , ~-A. rr.ara,~trzr--3 c-*- %,e a I,. j.y a v~ -x-c=9 AP lbar a ac rel a tr, " P-ir . li,h . :, -?' . ' ~ 4 - - r~ . 3'.,' no.1):,"f)23-2029 S 164. 11: ~ I ~~ . 1. 1 - : I 'D i7 I . ln3titutl noypfilnenly All SCS!". -VQ:I,-KCVr'. , L.A.; KCI, ITSOV, A . ~ . ; ' SOROKIN A.Ya.; ANMYEVA, N.A.; ~ : t A, ~P. ; FYRY,91, L.M. ; rFF!,Mf!.L I, S Y;i, CorrelatIon of the structurid aM mechunical rX polyvinyl alcohol fibprs. Kh1m, volok. ro.6-22-26 165. O'n!~A 1,, InstI.Lut vysokomo1ekv.IyarnyVh soyedlneriiy AN SISSR. SuIrLitted June 9, 196,1. nEN.xovA,. N.J.; KULAKOVA, O.M.; MATVEYEVA, N.A.; VOLKOVA, L.A.; IS3YJ,RA, N.D. Effect of methylamine in various media on the structure and reactivity of cotton fibers. Zhur. prikl. khim. 38 no-531077- I My 165. (MIRA 18:11) ..084 Institut vyBokomolskulyarnykh soyedineni-y AN SSSR, SOKOLISKIYII D.V.; VOLKOVA, L.D. Hydrogenation of mesityl nxide in mixed solvents. Izv.;N XazaYb 2W. Ser. tekh.1 khim.nauk . u6-.1 3-7 ,163. WRA 17:3, SOKOLISKIY, D.V.; VOIXO~! JJ~, - - :t Hydrogenation of acr7lonitrile in mixed solycnts on. a ';A,- skeletal catalyst. Izv. AN Kazakh. SSR, Ser. khAm. nauk 14 (MTRA 18:31 no.1:69-74 Ja-Mr 164. VOLKOVA, L.D.; SOXCLISKIY, D.V. 1--- Hydrogenation of nitri-les with conjugated bonds in mixed solvents. Izir. All Kazakh. SSR. Ser. khim. naul, 15 no.1:52-57 Ja-Mr 165. (MMA 18:12) 1. Submitted Nov. 11, 1964. Z~V il ,U~ W0903-66 EWT (m) /KWIA (d)/EVIP (j WT RM ACCF UR/0WA5/66O/o66/bo' 4 b61 SSION NRs AP50.20205 ~X~ 665-3/35:661-185-1 .nat G* (Engineer); Volkovaj'L. D. (Engineer) AUTHORSt Moskvi wdery cleansing agents.on the basis of alkyloulfateal obtained by so ITLEs Po air tt T oulfation of nonsaponifiables - II alcohols. Communication 3 SOURCEs Maclozbirovaya promyshlonnootlp no, 8y 1965Y 14-17 TOPIC TAM detergentp alkyloulfatei sulfationt cleaning compound (Maslozhir 1965p 6), the ABSTRAM In their previous paper ovaya, promyshlennost'# authors noted the dependence of properties of the nonnaponifiables-II alcohols on the boiling point. In this present workr the effect of inorganic salts on the clewising abiliiy and surface-active$iroperties of alkylaulfateolderived from the 00 was determinei ,,.-nonsaponifiable-II fraction of alcohdls boiling at 350, 375p and14 C The composition of the cleansing agents studied is given in Table I onthe Enolosurel The cleansing atility was tooted on wool# ailki oapron# and cotton fabriost and was compared with the performance of detergents "Novost"I and "Progress@" It was foundi- that cleansing ability increases with the boiling,point of the nocksoponifiable-II alcohol fraOUOV.. Orig. art. has' 5 tables. 7 -7-= J,00903-66 ACCESSION M AP5020205 ASSOCIATIONs Volgodonakiy filial VNIISINZha (Volgodoft Branoh of VNIISINZh) SUBMrfMt . SUB CODEs 0 00 ENCLt 01 NO 9u, sov 1,: 005 OTMI 000 jCcrd----2/3 A B C D E COACPAS r-011"IMM, Tom VIOMU.321- COACPIKSVINC "144 CY11h. K* SA;*At ~JU A to#- STOJ "SIOULK AD Pus, % PCRTYPbl, 350 34.75 1.7 4.89 2.30 315 34.00 1.14 3.35 2,32 A~ 400 XOD 0,70 2.06 2.00 A Alkylen1fates from alcohols of the nonsaponifiable-Il fraction boiling at the tempera tureq C, B AlkylmLlfate contentf 0 - Nonsultated 'Compounds content, " D - K* - r!Ltio, of, the nonsulfated substances to the active oubstanoop J E - Sodiuwaulfate content$ L 53751-6 Dn ACCESSI61 11P. AP50,12828 0/0360/65/0"/001/0052/0057 AUTHOR. Volkova, L. D. Sokol'skiy, D- V. 4 ated bo ds n mixed solvents i TITLE: Hydrosenationj'61r-nitriles 'with ccgjug~a n N XazSSR, Izvestiya. Seriya kbimicheskikh nauk, no. 1, 1965, 52-57 iTOPIC.TAGI;:, mthaerylonitrile, a cryi66ft ABSTRACT- The-authors studied the hydrogenation of methacrylonitrile and acrylo- nitrile n Pd and Pt*bla me ck and of th 'acrylofiitrile on Raney nickel in n-butyl alcohol, ditnethylformamidei and mixtures of thd two. Three to five portions of thel compound studied were hydrogenated in successim on the same batch of catalyst. Ki-j etic ane. p n otentiometric.curves show that the hydrogenation of m3thacrylonitrile in n- butyl eacohol, proceeds at -a gradually decreasing' rate, and the reaction is first order. I n dimethylformamide, the reaction -is considerably slower, and the jorder- Changes - --In mixtures the rate of hydrogenation decreases with rising di- i- zethyl:foii;~amide - content;- this Js- thought .-to-be --caused.-by.- ~the _polar properties of this so1rent. The activation energy of the-by&,~gonatio-.q-ii3creas,es-frbta n-butyl,----,--,____ alcohol -to d-imethvlformamide, on Pd blacks botli nitriles are ccn-.rerted to saturated..- C~m in~ N ; ~ ~ 'i i C'a 2/2 A AW. -Ar of -The 06 System so. am I& field of omtkimotts N%S%, a of UsSO, aod Ll and of the compdo.L .2N&,S% 11 ,Na . a ad LAI IM* 3 PW t"Wactic t3. --A-MMIJO-0 SOV/ 137-58-8-16613 Translation from: Rcferativnyy zhu rnal, Metallu rgiya, 1958, Nr 8, p 53 (USSR) AUTHORS: Volkova, L., Dausheva, M. TITLE: C'emEn ~aion 7of Ce'rtain Metals from Their Carbonates by a Sodium Amalgam (Tsementatsiya nekotorykh metallov iz ikh karbonatov amallgamoy natriya) PERIODICAL: Byul. nauchn. stud. o-va. Kazakhsk. un-t, 1957, Nr 7, pp 14-16 ABSTRACT: Qualitative experiments were made in the displacement of a number of metals from their carbonates by an Na amalgam (A). The experiments were run as follows- 5 cc 10/6 Na A was shaken in a separating funnel for 5 min with suspensions of 0.5 milli- equivalents of carbonates of various metals in 5 cc of distilled water. The A was then separated from the solution. The solu- tion was examined for content of the corresponding cation. The A was washed with water and treated successively by HG1 and a solution of mercurous nitrate, the metal going into the A being separated out of solution. In terms of their ratio to the Na A, the metal carbonates may be divided into 3 groups-, viz., Card I/;'. a) carbonates the metals of which undergo complete SOVI 137-58-8-16613 Cementation of Certain Metals from Their Carbonates (cont.) cementation with formation of A, these being the carbonates of Ag, Cu, Pb, and Zn; b) carbonates the metals of which undergo partial cementation, these being the carbonates of Ni, Co, and Mn, and c) carbonates the metals of which do not undergo cementation, these being the carbonates of Mg, Ba, Sr, and.Ca. G.S. 1. Metals--Separa,tion 2. Sodium alloys--Chemical reactions 3. f-letvl carbonates--Chemical reactions Card 2/2 VOIXOVA, L.P. Sulfate-carbonate exchange in alkali metal fusions. Izv. Sib. otd. AN SSSR no-3:60-64 158. (MIRA 11:8) I.Irkutskiy sellekokhoz7aystvannyy inatitut. (Alkali metal sulfatei) (Alkali metal carbonates) (Fusion) VOLKOVA, L.P. 0 nary system Of lithium, sodium and potassium carbonates. ItT. Sib. otd. AN SSSR no-7:33-35 158. (MIRA 11:9) 1.1rkutsk1y sel'skokhozyaystvenn" institut. (Alkali metal carbonates) (Fusion) ACL;--f'Sz;10;4 121 A.A010618 S10210163100010111020610113 AUTHORSt Poplavskaya, L, N,; Volkova) L. F9j..Zhukj,-,F* D. TITLE: 3eismicity of the Far'Last for 1961 SOURCE; Geolo-iya i -10ofizika,, no. 21, 1963,1 106-13j Co W TOPIC TAGS: sois-Acity., Fdr 6ast.' epicenter, deep focus, earthquake,, deep focus earthquake ABIMRACTi This paper is a summary of instrumental and macroseismic data for earthquakes in the.Far East during 1961. Epicenters were located by the methods ccxioidered nost effective for that region: I average liness 2 - equal disWnces from stations, 3 - intersections for t and master curves for isochrons of t P and S-P. The first was'most commonly gjs'ed in combination with the third. The accuracy of locating epicenters was Generally within 20-25 km. The epicenter of deep-focus earthquakes was easily located by one of the above methods. The depth of focus was generally found by difference in the S-F and 0-112 phases, but diffi- culties were encountered because, firstly, the S-P travel-time curves for the depth 20-50 kn- within the epicentral interval 1.5-150 were difficult to distinguish and,, Card 1/2 ACCESSIOU NW: AP4010878 secondly, Lho nc-daration of the sP phase on saismograms of Kurile -Kamchatka earthquakes was Crequently impossible. Depth was therefore generally determined by data from near (up to 100 km) and distant (over 15M km) stations. Wrin the indicated period (1961) 6 earthquakes of [:roup 11 were recorded > H > 6b 18 5;' of group 111 (4 86 ol: group IV (516 > H), 41) , and 132 of , group V Seismicity for 1~a In the Kamchatka region was .considerably lower than in pro- ceding years. All earthquakes with a scale reading greater than 5 are shown in a table. The two largest were: 1 - the earthquake of 12 February,, with 14 7, on the island of Shikotan; 80 aftershocks with 3j,(G H . There are 4 6 4 6 7 ?,' 6 5 2 35 2 Y figures, 1 table. and referenceE, I of wgich is Soviet. ASSOCIATION: Institut elementoorgarich,~sklkh sc-yedinenfy Akademii nank SSSR (Instlklut of Elemental-Organic Compoun4sAS USSR) SUBMITTED, Janiary 28, 19917 Card 21e VOLKOVAY L. 11. L. I.I. Volkora, K. A. Andrianov, G. Ye. Golubkov, L. N. Makarova) and V. A. Odinets, "The introduction of Polar Groups into Organic Radical at the Silicon Am." Report presEnted at the Svcond All-UnLon Conferknce on the Gaemistry and Practical Application of Silicon-Organic Gompounds held in Leningrad from 25-27 Septei4ber 1958. Zhurnal Prikladnoy khimii, 1959, Ur 1, pp 23P-240 (USSR) 50) SOV/62-59-2-15/40 AUTHORS: Andrianov, K. A~I/Volkova, L. M. TITLE: On the Reaction of-a-Chloro-methyl Ethoxy-ailane3 With Lmines (0 reaktsii a-khlormetiletoksisilanov s aminami) PERIODICAL: Izvestiya Akademii nauk SSSR, Otdeleniyo khimicheskikh nauk, 1959, Nr 2, pp 278-282 (USSR) ABSTRACT: In the present paper the relative reactivity of chlorine in a-chloro-methyl ethoxy-silanes with various amines was investi- gated. In contrast with the data hitherto published it was found that chlorine in chloro-methyl ethoxy-silanea is substi- tuted by various amines of the aliphatic and aromatic series at 200. When ethyl amine is acting on a-chloro-methyl-dimethyl othoxy-silane and a-chloro-methyl-mothyl diethoxy-siliine,oand aniline on a-chloro-methyl-methyl diethoxy-silane, at 20 , ac- cordingly, ethyl-amino methyl dimethyl ethoxy-silane (65;,o'), ethyl-amino methyl-methyl diethoxy-silane (56%) and phenyl- amino methyl-mothyl diethoxy-silane (13.5%), as well as hydro- chloric acid, ethyl-amine and aniline were obtained. The first two compounds are new. It was found that the reaction of amines 'Card 1/2 with a-chloro-methyl ethoxy-silanes at 200 proceeds with dif- SOV/62-59-2-1 5/40 On the Reaction of' a-Chloro-mothyl Ethoxy-silanes With Amines ferent velocity, according to the nature of the &mine. Au to their reactivity the amines investigated rank in the following order: HOC 2H4NH 2 -> (CH3) 3sioc 211 4fill 2') C2H 5NH 2 >(C2H5 )2 f1H> C6H5NH 2 > > (C 2H5 )(C6 H5 ) fili. As to their reaction rate with amines the a-chloro-methyl ethoxy-silanes rank in the following order: CICH 2(CH3)2S'oC 2H 5'> CICH 2 CH3 Si(OC 2 H5)2> CICH 2S'(OC2115 There are ~ figurer, and 7 references, 4 of which are Soviet. ASSOCIATION: Institut elementoorEanicheakikh soyedineniy Akademii nauk SSSR (Institute of Elemental-Organic Compounds of the Academy of Sciences, USSR) SUBMITTED: May 23, 1957 Card 2/2 TERENTIYEW, A.P.; GRACIIEVA, R.A.; PREOBRAZIIENSKAYA, U.N.; VOLKOVA, L.M. Synthesis of furan analogs of tobacco alkaloids based on chrilcones. Zhur.ob.khim. 33 no.12:4006-4011 D 163. (141RA 17:3) 1 1. 14oskovskiy gosudarstvennyy univeraitet, imeni Lomonosova. ANDRIANOV, K.A.; VOLKOVA, L.M.; TALANOV, V.N. .. ww **ftwk"w," Ammmolysis reaction of AIW -dichlorodi-methylsilaxane. Izv. All SSSR. Ser. khIm. no.11:2045-2047 N 163. (YJRA 171l) 1. Institut elementoorganicheskikh soyedineniy AN SSSR. -,SOURCEI Vy'*GokoMolekulyarny*ye soyedinentya. v. 6. no. 9, 19649 .1662-1667 TOPIC TACSt. silicone, sil_oxane, dimethylsitoxans, potysitoxaneg dicyclic.polysiloxans ABSTRACT,t- -'A -a tudy, - has beets. conducted of the synthesis.of branched polyorganodimethylsiloxanes containing sitsesquioxane groups at regular Intervals in the backbone by catatytLe polymerizaticu of dLcyclic-dimethytailoxene otigomerst Ottgomers of the formula ACCESSION JfRi AP4045433 .containing-a large number (n) of dimethylelloxane unLte-lbetween the brings (n w 130 322 669-1459 -170~ 198i 224,-or-270) were prepared 1 by condene,ition of ao w-dihydroxypolydimethylsitoxanes with hepta- mathylchlo'cocyclotatraoLloxene. Study of the polymerLzatLon of these oligomers revealed that in the presence-of KOH they polymerize much more readily than octamethylcyclotetrasiloxanot A kinetic sttidy of the polymerization at 70C in the presence of 0.5% Koff catalyst showed that with increasing nt the reaction rate and degree of cross link- ing decrease. All the polymers were t 'ransparent products which Polymers with n - 12 or swelled readily in bsnzenf,~ and toluene* 66 were brittle gals; those with n - 170 or over were very elastic -materials-0, A thermomechanical study showed that the polymers differ! considerably from Linear polydimethylailaxanes - their Rlass-tran- sition--temperature# Is -90C.9-as compared to -58C frr the polydi- methylsLlaxanese Studies are being conducted to explain this sharp J7. orqu Las --and-5--figures Cord 2/3 VOLKOVA,___-I.M..- A.NDRIANOV., K.A.; OBUSHEVA, M.S. Bicyclic dimethylsiloxane oligomers. Izv. AN SSSR. Ser. Min. no.11:1986-1989 H 163. (HIRA 17:1) 1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni M.11. Lomonosova. VOLKOVA, -".M.; DEVYATM, A.M. Datermining the effective excitation cros8 sectiona of rannwince lines of potassium atoms. Izv. AN SSSR. Ser. fiz. 27 no.S11052- 1055 Ag 163. (MIRA 16-.10) 1. Kafedra elektroniki Fizichoskogo fakuliteta Moskovskago gosudarstvennogo universiteta Im. M.V,Lomonosova, ANDMANOV, K.A. , akade.T.U; Synthesia and spact'ra c-P 1. Institut -AFi?TC/AM/SSD - ~Pa_4 lwwljDljo4l NH: AP'1004499 3/0048/63/027/008/IC ACCESSXON t'AUTHOR: Volkova. M Devyatov,A.M. TITLE: Determina,:ion of.the excitation crosa sectlonefor the resonance lines of atomic.potassium Xffeport presented at the,Sepond All-Union Conference on the Phys- 1, 'Acs of. Electronic-ana Atomic.Collinions hold in Uzhgorod 2-9 Oc~ 19~2/ /1963, 1052-1055 SOURCE: AN SSSA_ Izvestiyt, ser.fiz.,v~.27 no.8. ..TOPIC TAGS: excitation cross section electron impact excitation,spectrum line ABSTRACT: To ditto there have been only two experimental studies (1,6veridge quoted 1, by R.B.Prode, Rvvi.11od.Phys.,5,257, and Y.A.Fabrikant, Doklady AN SSSR,25,664,1939)i: and wstheoretical investigation - (R.Damburg and V,Kravchonkoi Izv.AN LatvSSR,No.; on 73,1960) devoted to evaluation of the excitation cross sections for the resonance I lines 'o% potass:lumi. The experimental results disagree, possibly because Loveridie faile4;'to take Into account absorption. The authors'used the photographic photome-' try technique to determine the electron-enorFy dependences and values of the oxci- 7698, j tatioh,brosq sections for the lines of the resonance doublet of K,(7665 and 21nesl. The measurements were per;omed in g special tube at a-votassi vapor Card z o6 ACCESSION NR; M004499 pressure of 2 n 10-6 mm Uc. The values arrived at for the ex6itation cross sqct:bl~g, are q, it 10 OT= 0.85 and qm&X a 0.90 for the 7665 R line (42SI42--42P transi- J~2 tion)~,'nnd qio w a 0.40 and qMAX w 0,42 for the 7698 It line (4 112-4 1 tr*ansi' ~2 tion)'*. The onorgy dependence of q.is shown in rUg.1 of the enclosure, T a rola-A The sum of the crons qec,~-: tive error in -the above values is estimated to be 35%. 1 tions.'agrees ransonably well with the results of Fabrikant and the theoretical cil-I I' culationsof D=burg and Kravchanko; it also agrees with the authors' calaulations by means of a3orn approximation formula adduced by LA,Vaynshtayn (Optika i SP04-,. troskopiya, l1,.301, 1961). Orig.art.has:-7 formulae, 5 figures and 1 table. ASSOCIATIOM. Xafedra elektroniki Fizicheskogotakultteta Moskovskogo gos.uniterst-,. tota:Im.M.V.Lozonosova (Chair of Electronics, Dept. of,Physics, Moscow State.Uni MMITTED, 00 DATE ACQ-. 2SAug63 ENCL- 01 SUB CODE: PH NO REF 8OV~ 004' MER: 002 Card 2/11~~/ _~OLIKOVA, . M. Deterninatton of the effective excitation cross sectients of tho are Unes of potansiun. Opt. i spektr. 13 no 6:84c D 162a (MIRA i6::L) (Potaissium-Spectra) (Quantum theory) KIABUNOVSKIY, Ye.I.; AGRONOI-OV) A;Ye.; VOLKOVA, L.M.; BALANDIN, A.A. Adsorption of racenic and (-t-) -isomers of 2-butanol OL stereospecific, silica gels. Izv.AN SSSR.Otd.W-Lm.nauk no.21 X 2,'!8-234 F 163. 16W 1. Institut organicheskoy khJmJi, im. N.D.Zelinskogo AN SSSR i Moskavskiy gosudarstvennyy universitet im. H.V.Lomonosova. (Butanol) (Adsorption) (silica) ANDRIANOV., K.A.; OLKOVAI L.M.; CHUMAYMM, N.A. YLbrational spectra of organic compounds contaiving -,%~ elements of the I7-group (Sig Go, Sn). Report 14o,72 Infrared absorption ajpctra of substituted aminamethylailoxanes and the frequencies 404 bond stretching vibrations. Izv.kN SSSR. Otd.khim.nauk 1~4U&1959-1964 1 262. (MIRA 1502) I. rhatitut elementoorganicheakikh soyedineniy AN SSSR. (Silo=nes--Spectra) (Hydrogen bonding) B140166 AUTHORS i Andrianov, K. A., Volkova, Lora M., and Tartakov3kaya, L. M. T IT 1, E: "ynthenin of' dimethyl cycloolloxanus containing functional S e,roup!3 In thc-ring PERIODICALs Akad&miya nauk SSER. Izve3tiya. Otdeleniye khimicheskikh nauk, no. 2, IQ~63, 294 - 298 TEXT i Dimathyl cyclosiloxines with a funcLional group at the Si atom were aynLhenized by quantitative decomposition or dibagic -,sQdJum sult-4 of a,ics-dioxy-no thy 1 ailoxtinus with methyl trichloronilane (1) or methyl- butoxy-dichlorosilane (11). The dimethyl cyclosiluxunes obtained differed in the numbers of 31 and 0 atoms in their rings and were separated by fractionation. Reacting 1,5-dis;odium-oxy-hexanethyl trisiloxane with I yielded hr-ptainethyl chloro-cyclotetrasiloxane (b.p. 05.5 - a6-50C, yield 15"t), p entaire thy 1 -chl oro-cyc lot ris 11 oxane (b.p. 47 - 500C, d201.0265, 20 4 nD 1-4050t yield 2.6;4), and nonntrie thy 1-ch I o ro -cy clopentas i loxn ne (III) (b.p. 129 - 1320c, d20 1.0410, n20 1.4063, yield Reacting it with II 4 D yielded heptame thy I -butoxy -cycl o tetras I laxane (b.p. 94 - 960C, yield 13-9/0, Card 1/q '-J/C-62/6-,/C,r,'C~/'CC,2/r,13/G2Ci Synthesis of dimethyl ... B 144/B 106 P(-ntai-.iethyl-t-utoxy-cyclotrimiloxzine (b.p. 67 - 710c, d 20 0.9653, n 20 1 - 4044 4 D yield 2.1~,), noiiiirctityl-butoxy-cyclopt~ritusiloxniif, (b.i). 134 - 137oc, d20 0.97979 it 20 1-4110, Yield 4-8-,4), nna undef-,,.iiiipthyl-butoxy-cyclohexa- 4 D 20 20 siloxane (b.p. 200-5 - 203-50C, d' 0-9857, n 1.4135, yield 5-4~j,). All 4 D these compounds dis.,3olv(td reneily in benzeno, toluene, acetone and ethyl ether. Their structure Wa3 d(!rived from tile TR spectra . Subutituting 11H 2 for the Cl group in III g3ve nonanc thy I -nit; i no -cy clopentar, 11 oxan e (b.p. 134 - 1370C, d20 1.0160, n 20 1.4115, Yield 32.2~). There are 1 figure and 4 D 1 table. ASSOCIATIONs Institut tonkoy khimicheskoy tekhnolo,-,,Yii im. M. V. Lomonosova I ns Litute of' Fine Chemical Technology imeni M. V. Lomonosov) SUBIATTTED: May 21, 1962 Card 2/2 . -ANDRIANOVI X.A.; VOLKOVA, I.Cra M.; TARTAKOVSKAYA, L.M. Synthesis of dimethyleyclosiloxanes containing functional graipa in a cycle. Izv.AN SSSR.Otd.khim.nauk no.2:294-298 F 163. (MIRA 16:4) 1. Institut tonkoy khimicheskoy tekhnoloeil im. M.V.Lomonoaova. -" I (Siloxanes) S/o51/62/013/ooVoil/027 E032/P-314 AUTHOR: Vollcova, L.1M. TITLE: )Ctcrmination of the effective excitation cross- sections for the arc lines of potassium PERIODICAL: Optika i spelctroskopiya, v. 15, no. 6, 1962, 849 - 850 TEXT: These cross-sections were determined by comparing the intensities of the lines with the continuous spectrum of a tungsten strip lamp (,P%-8-200 (S'[-8-200). The experimental apparatus has been described in a previous paper (the author, Opt. i spelctr., 6, 273, 1959). The cross-sections were 'calculated from the formula Ir i I'd kXSol1t') 2 qil_ - cm M i F n- h Ili t '~)i k where d is the diameter of the beam of' the excited gas in cm, 2 Ic the spectral luminance of the tungsten lamp in erg/sec-steradjun, -Card 1/3 Determination or S/051/62/oi3/oo6/oiI/027 P,032/F,311, s - snectrograph slit width in cm, D- the linear dispersion of the silectrograph in cm/cm, n- the concentration of potassium a t atoms in the ground state in cm i- electron current . tile receiver in A-, e -electronic charge in coulombs, F 21 FI- focal lengths of the chamber and collimator lenses of the spectrograph in cm, I I are tile intensities of tile potassium and tun-sten- 0 0 lamp specl~a 5nd t. t t, - the corresponding exposure times in sec. The maximum possible 'error in the cross-sections is estimated as 351% and the numerical values for this quantity re tabulated I'or 19 potassium lines between 4863.66 and 5831.67 R at an electron- .,,excitation beam energy of 5 eV. The varia ion in the.excitation cross-section with energy for the 6938-89 k, 58o1.86 A and 5339.9 ~ lines is shown in the figure (the ordinates of curve I should be multiplied by 6 to obtain the correct scale). There are I figure and I tab] e. SUB,',,IITTED: November 18, 1961 Card 2/3 Determinntiort of .... rigure S/051/62/013/Oo6/oil/027 E032/E314 J 3 & 5R 7 8 .9 V is zely Card 3/3 3/06 62/000/011/004/021 BlOlYD144 AUTHORSo J,ndrianov, K. A., Volkova, L. M., and Chumayevskiyo N. A. ---------------------- - TITLEs Vibration spectra of organic compounds containing elements of group IV (Si, Ge, Sn). Communication 7- Infrared ab- vorption spectra of substituted amino-methyl siloxanes and stretching vibration frequencies of C-H bonds FERIODICAM likademiya-nauk-55M lzyeetiye; Otdeleniye khinicheakikh nauk, no. 11, 1962, 1958 - 1964 TEXT: The IR absorption spectra of the.followieg compounds were studied$ C H NHCH (CHjSi(OC H ) , b.p. . 130 - 1320C/5 mm H9f n 20 1.4975; 6 5 2 3 2 5 2 D C H NHCH (CH i0c H b.p. 140 - 1440C/20'MM Hg, n20 1-51111 2 3)2S 6 5 1 2 50 20 C 11 NHCH (CH ) SiOSi(C H b.p. 1C9 - 109-50C/0-5 D Hg, d 0.9402, 6 5 2 3 2 2 5)31 am 4 '20 nD 1i4927; (C 2H5) 3SiOSi(CH3)(CH2?1HC6H5)OSi(C2H5)30 b-P- 159 - 1610c/1 maNg, d20 0-9514, n20 1-4619; (C H ) SiOSi(CH )LCH2N(C H 4 D 2 5 3 5 2 5)2)05'(C2H5)3 Card 1/3 S/062/62/000/Oil/004/021 Vibration spectra of organic ... B100144 1, 20 20 b. 02 - 1WWO-5 as Hg, d 4 0.6882, "D 1-4410; CH CH (C29 ) SiOSi(CjI )(CH 2N O)OSi(c 2H5)3, b*p. 129 - 13100/1 mm' HgF 5 3 5 \CH2CH2/ d 20 0-9425, n 21) 1.4525; 06 H5 NHCH 2(C"3)2S'OS' (CH b.p. 123-128OC/I M2 4 D 3)2C6H5 20 20 Hg, d 4 1.0047t nD 1.5310; C6H 5(CH 3)2S'OS '(CH3 )(CH2NHC6H 5)OSi(CH 5)2C6R5' b.p. 187 - 196OC/I an Hg, d 20 1.0534, 20 1.5381; 4 nD C 6H5NHCH2 (CH 3)2S'OS'(C 2H 5)205 i(CH ) CH NHC H b.p. 173 - 1750C/0-5 an HS, 3 2 2 6 5p d 20 1.023, n 20 1-52181 (C H ) SiOSi(CH )(CH NHC H CI)OSi(C H )3t b.p. 4 D 2 5 3 20 3 2 6 4 2.5 a RO 1 . 000, n 1,4885, and 153 - 1570C/0'5 zm H9, 1 4 D oc/7 = Hg, d 20 0.9238, (C2H 50)2S'(CH.IIi )CH2KHOCH 2)6NH2' 'o-p- 144 - 147 4 20 nD 1.4450- The results confirm the conclusions drawn by N. A. Chu~yevskiy (Optika i spektroskopiyat v. X, no.,1, 1961, p. 69) concerning the Card 2/3 /62/000/011/PO4/021 3/062 Vibration spectra of organic... B101/3144 frequencies of Si-O-Si, Si-O-C, Si-CH 3' S'_C2H5' and Si.-C bonds. In the present paper the frequencies-of the C-H bonds in the Si-CH and Si-C 2H5 groups were identified, using data from the earlier paper. The following ,interpre tation of frequencies is suggesteds v a(CH2) 2870 2880 es -1 Qas (CH2 ) 292!i 2940 cm- vs(CH 3) 2900 - 29 10 cu-1, and v AG(CA 3.) 2956 - 2970 ca- . There are 4 figures-and tables. ASSOCIATIONs Inatitut elementoorganicheakikh soyedineniy Akademii nauk SSSR (institute of Elemental Organic Compounds of the Acadezy of Sciences USSR) SUBMITTEDt March 23, 1962 Card 3/3 ANDRIANOV, K.A.; VOLKOVA, Lora, M.; SOKOLOVAp N.V. Synthesis and polymerization of oc. - and ,4 -cyano derivatives of dimethylcycloolloxanes. Vysokom.sood. 4 no.3:403-408 mr 162. (MIM 15:3) 1. Moskovskiy institut tonkoy khimicheskoy tekhnologii imeni Lcmonosova. (Siloxanes) VOLKOVAp L.M. Effective aross sectionD of excitatiOnB of certain Bpectral -1) linea of sodiun. Opt. i spektr. 11 no.6:775-771 D 161. (MIF2, 14:.L (Sodium-Spectra) ANDRIANOV, K.A.; VOLKOVA, L.M. Re;!ctions of amines with bis-(chloromethyl)-tetramethyldisiloxane an~, its derivatives. Izv. A SSSR Otd.khim.nauk no.1:8-7-96 Vla ,6,,!. (MIRA 1-11:1) - 1. Institut elementoorganicheskikh soyedinenly AN SSSR. (Amines) (Silicon organic compounds) ANDRIANCV, K.A.; VOLKOVA, Lora M. Synthesis and polymerization of beptamethylalkoxycycl6tatra- siloxanes. Vysokom.soed. 3 no.10:1580-1583 0 161. (14M 14:9) 1. Moskovskiy institut tonkoy khimichoskoy tekhnologii imeni 14.V. Lomonosova. (Cyclo'tetrasilcxane) TEMITIYEV, A.P.; GRACHEVA, R.A.; VOLKOVA, L.M. Synthesis of substituted pyrrolidinecarboxylic acids via furan derivatives. Dokl. All SSSR 140 no.3:6ir,-613 S '61. (MIR,~ 14:9) 1. 14oskovskiy gosudarstvennyy universitet Im. 14N.Lomonasova. 2. Cblen-korrespondent AN SSSR (for Terentlyev), (Pyrrolidinecarboxylic acid) (Furan) ~ ~Fz Pa.