SCIENTIFIC ABSTRACT VORONKOV, M.G. - VORONKOV, M.G.

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CIA-RDP86-00513R001860920004-1
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December 31, 1967
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SCIENTIFIC ABSTRACT
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USSR/Chemistry - Thiophenes, Phenyl 1 Mar 194-9 Chemistry - Synthesis "New Method of Synthesis of Phenylthiophenes and 'Their Homologs,",A. S.~Broun, M. G. Voronkov, Chem Faculty, Leningrad State U, 4 PP "Dok Akad Nauk SSSR, Nova Ser" Vol LIX, No 7 Authors showed in previous article that in heating alpha and beta~-dimethylstgrol or alpha, beta, betatrimethylstyrol with three equivalents of Bulfur:at 190-210 C until complete cessation of precipitation of hydrogen sulfides, smoothiformatic~n of betaphenylthiophene and beta-phenyl-betal-tbitolene results., Assuming that this reaction has general significance, they tried to syntheS12e ~be remaining two theoretically possible beta-phenylthiotolenes. Consequently,,jn realization of the reaction of sulfur with alpha-methyl-beta-ethylstyrol and betameth~-l-alpha- ethylstyrol,, obtained beta-phenylalpha-thiotolene and beta-phenyl;-alpha, thiolene heretofore unknown. Submitted by Academician A. N. Terenin, 5 Jan' 1948. PA 47T10 vcri=oV,- m.' I. 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Zhurrull 11"", YWffdi., jcp~qp VYP- 11) c- 1311-21. - "-ibliogr: 20 17;azv. SO: Letopis' ZhurnaltrUkh Statey, Vol. 50) Noskva, 1949 ~ 7- " , 5 - -- ~ -- - -- - -- - -- - - - - - ---- ----- --- ---- -- -10 - - ?a, .--- , v Cl -- - - --- -47 90) ~-4- . c O"j MON EEMMI-- Wit If RiH i 1. I v *.,10 tos, a a a 4 S or -W 4! 4 a 4t rv- A A-i? 1!j #06CJUOS AID OR MI-112, -1111" Ad"" a( allphoide Wwovuhaqui adjot to Wittyl Alkyl, go A others. Syndwwe so 1 71 wtyucgcidtilrat%~ I W44 Vo ow 'ZAN (). Gft. Cbmili.), 10. Ot.-CIll-C110-Alk writ titiotat gradually with the RM11 cont49- & tfMCV Of 11131434. cowing may too "erroeatry In WOW c"Co to subdue the orr.40kin, Alto' itanditiF ovenkht and wa%hing with kir-" so I so1n.,dwtu.ofthcml%ts.pve75-03" R as follows (Alk and R. resp,. CivA. El, U. b. 113.8 *0 0 5X,:lj* 0.9311, vV I-3W; Fit lit. Ifto 120 7 'R) it': 1) : ii 'EJ.' AUX) .39132 (xv I-3MMS. ov UMM) 1-304; 'H4' ow"G. IV, PO, lots Ago 1.400; Fit Bm. log OOA-70 4' 0 $XM2, 1.40W. Pp. J1j- Zoo ton's 65.6'. 0-100, I'M " b. *me. [in 66'. 0. Pr, M. tht (63.1 -40 44 -3.6" O.Vad ,. 5 1.4mi PF It, a. W MA'11% !I so o.qXM, 1.4108*. Do. Ate, boo fd.S*. 0.91%. 1.411M, Sol' 00 Ed. No 71.8'. UMUD. 1.4081'. it#-Ilx. Me, low W. OA170. 0 1.4(XK18. isa-Ho. Fj. loot W.2-7.5'. 0AWIS. I-Ift); 'to4 Aon Me. hot 1W.2-10.11", 0AW. 1.40617; G1114, .110:. goo hot i00-2", (1,9114. 1.4275. The Products may be jtu&~' soo yzed toy sol in a known val. o(0.1 N N1101t and backs zoo itration will", 11c1. Ker4oupo" , ! l too yes too t!0 9 two SITAtLUROKAL L11911#101 CLASSAPIKATICH beg 4111-11LA !4w 4: Mw ,,,a .r7 51 qat I 'Ross IT--4-T-T- . i' , V 5 IT It 4 0 rw i or a to a 'I ;I a v .0 to a x a 9 4 0 41 0 0 0 0 0 0 0 9 0 *0 0 0 0 0 0 0 gO 0 00 00 411see 0 0 0 A-* #1 9 0 0:41 o Co 0 so o 0 to * 0 Sulfur Jul 49 L gt,-ty of them Interaction of Sulfur. -WIth.Unmatu-m-~#4_ ~r~,=Pounds: III,, Synthesis of 0. Voronkov, A. S. Broun (deceazed), G. 0. Kar- B. L. Gol-'ahteyn., Chair of Org Chem, Im4tgraA ,ip U A. A. Zhdsia6v, 8j pp of Lenin, State. 41 01011hCh Mlbe XIX ~i;~r of z gu three ifsoiters- of, j)hww1butene-1j 1-ph~eU~ixi -put W-3), I-P1mk4-1butadi=c-1)3A and 1-7' ad a siwpl* mtbo& go t two proftc . i :w U= of tbp- itachavAsm of it s r6riation iaigbatic-aromatit-hydrocarbons..- SubmitteA 28 APr 48. 2/5M64 The mlqd~ of *A111w- WO "dwoma. IV. Pbowyl-embodbAW 3.2-Ad"o4-ddoom M. 0. Vocaukaw, A. S. Broun, and G. R. Kawko (IAHW-- I stato Vail.). J. Gem, Chem, (U.S'S.10 191 NO. 10, ;ii~110M)(Sntlbh tmostation).-Sw C.A. 44. a. C~ MISIV. lAldRVW), Zkor. PM. Kum, 38, 1 1 -cf. C.A. 0, MW- Tbe VIAM, r*k-4. by (Mblim (C.A. on re to that 1. mod VdIum ummill lwkr tbAft dttd.1 MrCH(OMv)# II.W. 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