SCIENTIFIC ABSTRACT VORONKOV, M.G. - VORONKOV, M.G.
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CIA-RDP86-00513R001860920004-1
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Publication Date:
December 31, 1967
Content Type:
SCIENTIFIC ABSTRACT
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USSR/Chemistry - Thiophenes, Phenyl 1 Mar 194-9
Chemistry - Synthesis
"New Method of Synthesis of Phenylthiophenes and 'Their Homologs,",A. S.~Broun,
M. G. Voronkov, Chem Faculty, Leningrad State U, 4 PP
"Dok Akad Nauk SSSR, Nova Ser" Vol LIX, No 7
Authors showed in previous article that in heating alpha and beta~-dimethylstgrol or
alpha, beta, betatrimethylstyrol with three equivalents of Bulfur:at 190-210 C
until complete cessation of precipitation of hydrogen sulfides, smoothiformatic~n
of betaphenylthiophene and beta-phenyl-betal-tbitolene results., Assuming that
this reaction has general significance, they tried to syntheS12e ~be remaining
two theoretically possible beta-phenylthiotolenes. Consequently,,jn realization of
the reaction of sulfur with alpha-methyl-beta-ethylstyrol and betameth~-l-alpha-
ethylstyrol,, obtained beta-phenylalpha-thiotolene and beta-phenyl;-alpha, thiolene
heretofore unknown. Submitted by Academician A. N. Terenin, 5 Jan' 1948.
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