SCIENTIFIC ABSTRACT VOYEVODSKIY, V.V. - VOYEYKOV, V.V.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001861110020-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: August 9, 2001
• Sequence Number: 20
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

Application of the analysis ...
S/051/62/012/001/005/020
E075/E436
6 H -(Z --T
exper V
and is determined by the width Allb of unresolved hyperfine
structure or by the width 6141 of Individual component. For
most aromatic radicals 1111i is not greater titan I to 2 Oe.
In that case, A Hb is given by
LHb = L - (2)
Vr-2-(-n
where n is the number of protons interacting with unpaired
electron and to a factor depending on the length of the spectrum.
The results of the measurements of component number and line width
and also determinations of the number of units in which the
delocalizations are small in relation to the molecular dimensions.
Examination of anions I and II in the table shows that the presence
of one conjugated system does not always give high frequencies of
delocalization in a molecule. The frequency of delocalization of
an unpai ed electron in a polymer molecule, which is not in
Card 2/ f '~

S/051/62/012/001/005/020
Application of the analysis ... E075/E436
conjunction in the main chain is less than 3.07-1/sec. For soire
polymers, however, there are high frequencies of exchange. In
the spectrum of the polystilbene anion m.vL. 1300 and for some
samples of polysterene there is a narrow central line, which may be
connected with the appearance iniseparate molecules of high exchan,-p
frequencies. This niay.bQ a consequence of the formation in these
polymers of some ordered arrangement of polymeric units. There
are 2 figures, I table and 7 references: 5 Soviet-bloc and
2 non-Soviet-bloc. The two references to English language
publications read as follows: Ref.4': H.M.McConnell. Chem. Phys.,
v..33, 1960, 115; Ref-5: H.M.McConnell. Chem. Phys. v.35, 1961, 508.
SUBMITTED: November 23, 1960
Card 34

38129
S/020/62/144/003/C26/030
B124/B101
S-,
AUTHORS: Shelimov, B. N., Fok, N. V., and Voyevodskiy, V. V.9
Corresponding'Xiember of the As US�1F- -
TlTLE: The benzene-photosensitized low-temperature decomposition
of hydrocarbons
FERIODICAL: A-kademiya nauk SSSR. Doklady, v. 144, no. 3, 1962, 5906-599
TEXT: As has been shown earlier, the product from photochemical decompo-
sition of benzene (1), irradiated by ultraviolet light at 77 OK in trans-
parent organic glasses is a substituted hexatriene (II)
H2C-CH-CH-CH-CH.CH-R (HR being the hydrocarbon medium in which photolysis
is performed), and alkyl radicals are formed in addition. As the forma-
tion of alkyl radicals cannot be explained by the reactions hitherto
assumed, this and the formation of gaseous products was studied from the
epr spectra. Solid-phase reactions of I in mathyl cyclahexane (III) and
3:-methyl pentane (IV). were studied with concentrations ranging from
1.8-10-3 to 2.1.10-k mole/liter. The mercury vapor lampITP'4-7 (PRK-7)
was used as the radiation source. After irradiation, the solution was
Card 113

S/020 62/14..,/003/0206/030
The benzene-photosensitized B124 3101
Y3
defrosted, then recooled to 770Y, the gas pressure measured and the gas
collected for mass-spectrometric analysis. The irradiated solution was
subsequently diluted with n-pentane (V) and the amount of Ii fo=ed by
radiation was measured spectrophotometrically at 275 mp. The epr spectra
of the irradiated solutions of I in III were found to be identical to
that of the methyl cyclohexyl radical obtained by radiati= of frozen (III)
with fast electrons. The spectrum of solutions of I in IV consists of -4 1/
6 high-resolution, hyperfine structure components with a uniform pattern
splitting of about 24 oerst which is probably due to the
CH3
CH 3- OH2_~ - CH2_CH3radical formed by splitting off one,H atom from the
tertiary C atom of IV. When I is irradiated in IV, H forms-, in addition
to the R-substituted II, while C 6D6 yields small amounts of HD in addition
to H2 in the same hydrocarbon. The simultaneous formation of alkyl radi-
cals is obviously due to-the decomposition of the hydrocarbon photosen-
sitized by 1. The'most important feature of the reaction is that the
:~n-z.z;ry rf the light quantum absorbed by 1 (112 kcal/mole) is transferred,
ef ~_:i ,art, to the hydrocarbon molecule, which results in splittir-
Card 2/3

S/02 62/144/003/026/030
The benzene-photo3ensitized ... B124Y3101
off one C-H bond, whilst the I molecule returns from its excited to the
original unexcited state. Neither C6H 5';(C6D5') in the epr spectra nor
diphenyl in the reaction products could be detected. Thus, the reaction
due to ultraviolet radiation proceeds in two steps: (1) formation of
Substituted II, and (2) the I-photosensitized decomposition of the
hydrocarbon leading to the formation of hydrocarbon radicals and Of i12-
The yields of Il and 2radicals are maximum with I or C 6D6 concentrations of
1.6-10-1 and 6.o.lo- moles/liter, respectively. The yield of II' increases;,,),/
4 2-fold, when the concentration of I is increased frcm 1.a.jo-3 to
1:0.10-1 moles/litery,while the increase of yield of radicals is only
1.2-fold; with C6D61 the relative increase is 2-3 and 1.1 fold. There are
3 figures &Lnd I table.
ASSOCIATION: Moskovskiy gosudarstvennyy universitat im. M. V. Lomonosova
(Yoscow state University imoni 114. V. Lomonosov)j Institut
kinatiki i goraniya Sibirskogo otdoleniya Akademii nauk SSSP,
(Institute of Kinetics and Combustion of the Siberian
Department of the Academy of Sciences USSR)
SUBIIITTP.D: February 24, 1962
Card 3 3

SOLODOVNIKOV, Stanislav Panteleymonovich; VOYEVODSKIY, V.V., otv. red.;
TARASENKO, VJI,.., red.izd-va; GUS red.
[signals from the microcosm; magnetic resonance] Signaly Iz
mikromira; magnitnyi rezonans. Moskvap Izd-No AN SSSR. 1963.
84 P. (MIRA 17:2)
1. Chlon-korrespondent AN SSSR (for Voyevodakiy),

SHELIMOV# B.H.; FOXO N.V.; VOYEVUDSKIY V.V. -
Photochemical decomposition of alcohols at 1-ow te=peratures.
Kinetics of mathyl alcohol decomposition, Kin. i kat, 4 no.
4:539-548 JI-Ag 163. (MIRA 16:11)
1. ~bskovskiy gosudarstvennyy universitet imeni M.V.Lotonosova,
khimicheskiy fakulftet i Institut khimicheskoy fiziki AN SSSR.

MOLINp Yu,N.; CMIDZE, I.I.; KAPLAN.. Ye.P.; BUBENj, N.Ya.; VUX~&-
VODSKIYP V.V'
Formation of radicals in the radiolyvis of solid organic
substances. Part 2: Yield of radicals in benzene and biphenyl
derivatives, Kin. i kat. 4 no.4057-560 JI-Ag 163. OURA 16:1:0
1. Institut khWcheskoy fiziki AN SSSR, Institut khImichoskoy
organicheskoy khimii All SSSR.

LEBEDEV, U.S.; TSVETKOVO
Free radical reactiona in irradiated pol7tetrafluoroetb7lene.
Part 4: Reactions of fluoroalkyl radicals with molecules
from the gaseous phase. Vyaokom. voed. 5 no,10:1500-1506
0 163. (MIRA 17:1)
1. Institut khimicheskoy- fiziki AN SSSR i Institut khimi-
cheskoy kinetiki i goreniya Sibirskogo otdoloniya AN SS.SR.

LEBEDEVP Ya.S.; TSVETKOV, ru.D.; VOYEVODSKIYp V.V.
Free radical reactions in irradiated polytetrafluoroethylene.
Part 5s Discussion of the reaction meehanism. Vysokom.soed. 5
no.11:1608-1614 N 163. (MIRA 17:1)
1. Institut khimicheskoy fiziki AN SSSR i Institut khimicheskoy
kinetiki i goreniya SibirBkogo, otdoloniya AN SSSR.

FOK, N.V., SHELIMOV., B.N.9 VOYEVODSKIY.,- V.V.
"On the photosensitized decomposition of hydrocarbons by benzene and
its derivatives at low temperature-*
Report submitted to the Sixth Intl- SYMP- on Free Radicals,
Cambridgeg England 2-5 July 1963

VoyEVowKir, Vladislav Vladislavovich
*Application of the electronspix resonance method in heterogeneous
catalysis"*.
Report to be submitted at the Third International Congress on Catalysisj
(IUPAC),, Amsterdam, Netherlands,, 20-25 jul 64-

VOYEVODSKIY, V. V.; SOWUKHIN, R. 1.
"On the mechanism and explosion limits of hydrogen and oxygen chain mlf-lgnition
in shock waves."
report presented at the 10th Intl Combustion Symp, Cambridge, UK) 17-21 Aug 64.
Novosibirsk Univ.

VOYWODSXIY, Vladislav Vladislavovich
"Application of the electron-spin resonance method in heterogeneous catalysis."
report Bubmitted to 3rd Intl Cong on Catalysis, Amsterdam, 20-25 Jul 64.

BLYUMENFELID, L.A.; ~OYE~VQq5KTY,j,.V..; SOLODOVNIKOV, S.P.
Nature of ion radicals formed during interaction of potassium and
sodium with some aromatic hydrocarbons. Izv.AN SSSR. Ser.khim.
no.ltl58-160 J& 064. (MIRA 17:4)
1. Institut khimicheskoy fiziki AN SSSR.

VINOGRkDOVA, V.G.; SHELIMOV, B.N.; FOK,N.V.; VOYFVODSKIY, V.V.
Law temperature decomposition of hydrocarbons photonensibllized
by some benzene derivatives. Dokl. AN SSSR 154 no.1:188-190
Ja'64. (MIRA 17:2)
1. Moskovskiy gosudarstvennyy universitet im. M.V. Lomonosova i
Institut khimicheskoy fiziki AN SSSR. 2. Chlen-korrespondent
AN SSSR (for Voyevodskiy).

VOYEVDDSKIY., V.V.
Inhibition of paraffin cracking in the gas phase. Kin. i kat. 5 no.4:
603-608 il-Ag 164. (MTRA 17:11)
1. Institut khImicheakoy kinatiki i goreni~u Sibirskogo otdcleniya
AN -OSSR.

Ty, V.V,
VOYETODSK.L
Chemical transformations at low temperatures. Vest. AN SSSR
34 no. 2;56-62 F 164. (MIRA 17:5)
1. Chlen-korrespondent AN SSSR.

BUBNOV, N.N.; BAZHINp N.M.; VOYEVOWSKEY Vj.
photosensitized decomposition ~! saturated bydrocarbcna
and alcohols in the oollde phaa-,, Kin, i kat. 5 w3.2057
Mr-Ap 164. (MIRA 17t8)
1. Institut khimicheskoy kinatiki i goTeniya Sibirskogo
otdbleniya AN SSSR.

BAKH, M. A.; VOYEVODSKIY,, V. V.; GOLDANSKIY,. V. I.; SHMN; A. S.
"Use of powerful radiation sources in cnemical invest igat ions."
report submitted for 3rd Intl Conf~ Peaceful Uses of Atomic Energy, Geneva,
31 kig-9 Sep 64.

7-) YVI'ili. [ji L001 1W-1
8/0190
ACCESSION NR. AP4=76i. S/0020/64/154/001/018
AUTHOR: Vinogradova, V. G.,~ Sholimov,, B; Noj Vokp N. V.; Voyovod-
slciy, V. V. (Corresponding 'member)
TITLE: Photosensitization decomposition of hydrocarbons at low
temperatures by benzene derivatives I
SOURCE: AN SSSR*, Doklady, v. 154, no, 1, 1964, 188-19o
TOPIC TAGS: benzene derivative , hydrocarbon.,, aromatic hydrocarbon.,,
hydrocarbon decomposition.. photosensitized decompoaltion, toluene,
ethylbenzene, iso-propylbenzene, pxylene. dipheny1methaney chlorobeenzene,
triphenylmethane, fluorobenzene, acetophenone,
ultraviolet light, o xjvlene., m xylene
ABSTRACT: Diluted solutions of benzene derivatives, such as toluene,
ethylbenzene, iso-propylbenzeneo ol m and p-xylene, diphenylmethane,
triphenylmethane, fluorobenzene, chlorobqnzene and acetophenone in 3-
methyl pentane and deuterium-containing 3-mothyi pentane were sub-
jected to ultraviolet light at 77 C- Hydrogen was icolated and 3-
Card -1/3

L J
ACCESSION NR; AP4010761
ASSOCIATION: Moakovskiy gosudarstvonny,*y univeraitat im. II.V,,Lomo-
nosovs. (Moscow State Univernity), Institut Ichimichookoy fizikio All
SSSR (Institute of Chemical Phynies, AN BSSR)
SUBMITTED: 033ep63 DATE ACQ: 10rbb64 ENCL: 00
SUB CODE: 0C NR REF SOV: 004 OTHER: 011'
Card 3/3

ACCESSION NR: AP010761
methylpentyl radicals were formed in all cases except in C 11 F
4 J'
C6H5C1 and C.6H COCII solutions. The initial rate of H ev21~Lion was
measured and r2lated to the concentration of the tripyet stz- *"e oC aro-
matic molecules. The data agrees with the assumption that molecules
of aromatic compounds in the triplet stat,e' participate in the photo-
sensitization reaction. The energy of the triplet levels of the aro-
matic compounds is not higher than 78-85,kcai/m-ole. The relationship
between the rate of the formation of hydrogen and alIqjl radicals for
toluene and benzene solutions depending on light intensity is in-
vestigated and the data are tabulatedO The longer life of aromatic
molecules in the excited triplet state makes it possible to absorb
one more light quantum while passing to the higher triplet level, and
owing to the eneq;y excess (as compared to the energy needed to rup-
Uure the CH links) causes the photos en si tizati on decomposition of the
solvent molecules; Origo arts hass I table*
Card 2/3

ODINTSOVA, S.P.; SHELIMOV, B.N.; FOK, N.V.; Vq VODSKIY, V.V.
Temperature dependence of the rates of benzene photochemical
reactions in hydrocarbon solutions. Izv. AN SSSR. Ser.khIm.
no.31572-574 Mr 164. (MIRA 17s4)
1. Hookovskiy gosudarstvannyy universitet im. M.V.Lomonoscrva I
Institut khimicheskoy fiziki AN SSSR.

ACCESSION NR; A~40259o6 S1003016VOO0100-21005610062
.AUTHOR: Voyevodskiy,'V. V, (Corresponding member)
TITLE: Chemical transformations at lau tomeraturos
;SOUPCE: AN SSSR. Vastpik, no. 2, 1964, 56-62
1 '20PIC chemcal transformationA low tekooraturej solid phase, storeospeci-!
ficity, radiation polymerization, frozen monomer, free radical
AB91'RACT t This brief review deals mainly with radiation-chenical trLsf.ormations
and the reactions of free radicals in the solid phase at low te;,r?eratu.-e3. An
essential role in the revival of interest in Ivr temperature reactions is due to
the observation that polymers obtained at those low ter;peratures possess storoo-
spacific~ty) as. exemplified by the formaldehyde and acotaldehydo polymors, tho
:r.,,eltinc, points of which are -117 and -'2.",C respectively. In the field of radiation
polymerization of frozen monomers, it was auggested-l"hat the extremely rapid onsat.:
of the polymerization process was duo to some kind of broachinm of the strictly
a o r. e 4,j
-rically oriented molecules of the monomer by an initially formod,active~
;center. The mobility of components of solid frozen organic compounds,, such as the
Cdrd
--- - - - - - - - - - - - - - - - - - - -

-7- :-7~
ACCESSION IM: APLO25906
'rotation of Mothyl ~roupss was revealed by the electron paramagnetic resonance i
technique at the terVerature of liq04,nitrogen~'. The molecule of cyclohexane
15 Knovm to undergo rotation around -.,!,.roe main, axes at -87C. The dopondence of
t-he reaction rato on'the frequency tl-* intrxiiolecular sliifts.,~n tho solid atate
is stressed, and the role of the mas of the factor o-,PJ/RT is omphaz
Its sianificanco, , however, disappeaw.,; vhore ionizing radiation is brought in,
Q
The cleavage p,j1_cA9mica1 bonds and the formation of free radicals are now becoming
of prime L~p"ortancea 'The formation of molecular hydrogen is an invariable conse-
in radiochemical transformations of most solid hydrowbons, The free
,radicals, in turn, can undergo a series of transformations and may also bring about
;a kind of cros.s linkaGe, causing the so-callcd radiation vulcanizatidns a process
,,already used by industry~ By a proper:application of low temperatures it is
to "freeze" theprocoos at a desired level, without permitting secondary
,reactions to take place., At the Institut k1iimicheskoy fizild Akade=.** nauk SWR
(Iistitute of Chemical Physics, Academy of Sciences SSSR), a special spectronTotor
1was constructed which permits determination of the structure of froo,radicas and
concentration during the process of irradiation with fast electrons. The
!technique reveal& that the saturated hydrocarb.ons are 20-30 times less 4esistant
V3
Ccud ----- --

ACCESSION NR: AP4o25qo6
to tho'effoctl., ioni!zzing 'radiation than benzenn, while the ter-phenylz
and some other highly conjugated systerLs, are 2~-20 times more resistant..
Insic;ht has boon gained into the nechanism of the interactidn of the huge
lquantums of radiant energy with the molecules of the irradiatod substrate. it was
-found that the excitation energyis actually capable of being transported within a
.Solid phase, not only within a single molecule but also between neighboring
inolecules. The author describes a ki.rd of collective state of excitation (exciton
!in irradiated materials, involving a large number of bonds. Electron transport
1presumablylalso occurs In irradiated solid systems. The possibility of stabili-
Izatt.ion and accumulation of free radicals in systems at low temperatures has been
4 the atoms of hydrogen in a hydrocarbon attain such high
.verified. At 7T mobility
tI,at they react instantineously with radicals or other hydrogen atoms. The con-
stants of rate and activation energy of free radicals in irradiated systems a'. low
te:miperatures hum beea determin d.
tZSCCTITION: none I
SUB101 VM: 00 DkT---;' ACQ- O8Apr64
ZMICOD-*: CH NO Ra SOV:L 000
03 1
Ca-rd
ENCL: 00
OTHER: 000

I ~
-, I , I I I I I I I

. m
-,. I ~ I ~ ~. .,- . ~ _-,_ . L - : -z , . ~l (T-- I .: - - ; - E;- :--, -7,=~ Z--, -- -; - L.- - -Z. :, - I I

-,-, -I - ": -,,, ia
I, ~ ,
~ ~ w~ ;, ---
I

VOYEVODSXIY, ~L. V.; SOLUKHIN, R. L
"On the mechanism and explosion limits of hydrogen and oxygen chain self-Ignition
in shock waves."
.report submit ted to 10th Intl Symp on Combustion) Cambridge, UK) 17-21 Aug 64.
Novouibirok Univ.

Vw
i MM"
- M.M.
-M ItS

~'~v ; - "i--i At ,
, ~~ -
n 2.~ - -
~: " ".2 ~, ~.!

Pi "I

E-L-L-10827 -66---ZWT(m)ZEWP(JJ,"; n't WitAWRK
ACC NR, ATS023443 SOURCE-CODE; UR/J)000/65/000/000/0249/02S3
AUTHOR: Shelimov, B. X.-' Fok N. Ve; Voyevodskly, V. V.1
ORG: none
TITLE: Benzene and its derivatives Lit photosensitizttd hydrocarbon dec )ositio at
low temperatures
SOURCE: SJADozium vo elementarnym protsessam khimit vysokikh anargiy"t Moscow# 1963
El -23-kh energ
ementarnyye protsessy khImii Vyso fy- (Mementary processes or the chemis
try of high energies); trudy simpoziuma. Moscow, 1965, 2413-253
TOPIC TAGS: hydrogen, alkane, aromatic hydrocarbon, UV irradiation, EPR
ABSTRACT: Initial rates of formation of hexatriene, I radical
and hydrogen were
studied at 770K %a a function of CGHG and C6D6 concentrations In 3-methylpentane. The
dependence-of-iRrmation rates of hexatriene and hydrogen upon temperature was studied
in various solvents using a 2.10-2 moles/l benzene concentration. All samples were
UV irradiated at 770K. Free radicals were monitored by the EPR technique. The ob-
ject was to elucidate the mechanism of the simultaneous formation of alkyl radicals
and hydrogen during UV irradiation of benzene solutions at 7710K. The hexatriene
formation and the photosensLtization were not found to be Interrelated. The UV irra-
diatlon of CrH5CD3 In 3-methylpoutdne at 770K results In formation of 94% H2 and 6%
Card 1/2

ACC NRo ATS023445
HD; hydrogen Is the sole product when o-D- and p-D-toluene in am
subjected to UY Irradiation; H2, HDO and D2 resulted from W irradiation of C6HSCH3
in 3-wthylpentane. A photasonsitized decomposition of hydrocarbons according to the
following scheme
CAW, + RH substituted hexatriene
CNXWO + Rif (RD) qIW4 + R + H 0*
occurs in thecase of toluene. Results obtained with
ICJT6C6*+RH+hv.
system revealed that the rate of formation Of C6H$Cf12 radical Is 10-12 times smaller
than the rate of formation of alkyl radicals, It was condluded that photosensitized
decomposition of hydrocarbons at 770K also occurs In ethylbenzene, cumene, o-, M-,
and p-xylenes. diphanyl- and triphanyimethane and other compounds. Orig. art. has:
1 formula*
SUB CODE: 07/ SUBM DATE3 23Feb65/ ORIG RErs --003/---- --OTH -IMr:- 005
CoM: 2/2-

APS02 pp)e)/Z"WP(j
6607
U 7
4 U 7710.q:
fe.
Afolla r4. Arqq-0 C2-
'YjO
g; 1~~fj 'rO If
77 ifte AwWij , tVO062"16
777,
841.0k 6100
fail 0 1
ZVI )1~4r /009/
04,W .67
C4 re Y
0 lk
k. I solov,
SOU roe #'J'z-
C-V. a. k.
. ANftn. ztv'est~Y4' OttraIcs Sludy Of the keto
'Pop, rAGq.. '0401 op
/Ails?.,, 41, OPectroaco.. ~Ilft 0'3-4
Icheekaya
/
AC,p.. 'UAM D's no. 9, 19
p"
PrOPVI~ 3 'P NAM 65 1566.16
.P"'W-2- 0 .1,80but ectra 0 64
We.. Per4,,_, yl. ?Of the foil
ve
torzfts 4100 re 'Qv '180pro Owing coa~po
If
02
cor 0 U4ds
c0 - fts detex-d0d * 7be *Pool Pil -
aton of ;~l with 44 ra wera 44d 3.8 were Stu
C-Ccaroo,50z~'
Cb 8-sucli ftd. 49-2 'akM ;q'yt-~4-butYl Wed' 3
!Pftiz OrT48 ,4110'14, V-~CfrOV4. ftetyjzoeto~ -aloth,,,
Vith br OfYI40et,, ter (60 '1 J1VAf-3 jash,4,ne, sac, 3
At eth
'"Od 0"80 0)49.%, &180 2
r jrtu'M V1114 I" Uabr~cb
fteutuents eat (40 Afc) ~Zlsoplr":'
'be kato 280- 4ad lb
(8-1,00 no, ed 8,tbst,ue a cozl,eat aoa2~
46 proj:wz' lwa ftraft Witij aff Wer of
04Y1400 a
ka ch ~hDIZ
84d to
Jjft;ft'Q'd d4ta

L "64-66
-ACCESSION NRt AP5026507'
lacatone) are almost pure ketows. The slight enolization of these substances does not
permit the classification of the enil form in the pJA or trjV# series on the basis of the
NMR method alone. "Measurements with the 01 Instrbibent were made'st the Tsentrall
myy institut khtmit Vengerskoy Akademti nauk (Central Chemls!q Institute of the
Hungarian Academy of ScIencpsayo the direct participation of Dr. h,_RAAq_hL*_whom
the authors expresetheir gvatf di.11 Orig. art. has: 5 figures and 2 tables."'
ASSOCIATION: Institut elementoorganicheskikh soyofte* Adadewil n&A WSR 91~ulltutq
of Organometallic Compowula. AcadgM of Sciencegg R)j butitut khtmiabasimy Qw-UHT
gorentya Sibiralwgo otdolenlys, Adadetall nauk SM (InstiWA of Chemical klietics and
Oombution, Siberian BrwAh, Academy of Sole",89R-),
W45~'
SUBJUTTED: 04;u163 ENCL:' 00 SUB OODM OC, MP
OTHZRs 014
NO RZF Bovi 000

TYUrESH, F.] KENDEf L; EMZHNYKH, T.; SOLODOVNIXOV, S.P,; VOYEVODSKIY V.V.
-
Radicals as intermediate products in the inhibition of radical poljr-
merization reaction. Kin. i kat.,6 no.W03-211 mr-Ap 165. (MIRA 18:7)
1. Tgentrallnyy nauchno-issledovateliskiy institut khimii AN Venger-
skoy Narodnoy Respubliki I Institut khizicheskoy fiziki AN SSSR.

SHMMOV, B.H.; FOK, N.V.; -V9X4V
.-,QDSK1Y,.,,Vj?,_
Photo3,vsis of ethyl alcohol solutions at 770K. Kin.i kat. 5
no.6:1008-1013 N-D 164. (MIRA 18:3)
. I
1. Moskovskiy gosudarstvannyy universitet imeni Lomonosova,
khimichoskdy fakulftet i Institut khimichtskoy fiziki kH SSSR.

1P

. N "
I~p
- .It~
X.~V ~,
, " 7,-,, ~; 1; V
, =ZA-,
iM

AUTTIOR I Voyevodmkiv- u ti I.-
'11~-
ig

... I . ~ . ., , i I . 1 4
-4~
it ~: ~ : - -r ", , - -
-- I I -,, - ~zf- '-' - - -.- - T. " -, , , -
, 'i - .", '-'; ~, ~~ lx m - -
?~'r .~, , -I. - . i. .6i

VO MODSM, V. I., alkademik
Hbtaroly-tic fomation of fr6e radicali In the radlolysis of
solid organic vubstances. D&1. PIT SI~M 159 no.4s87&-8?8
D 164 (MIRA 1841.)
1. Institut. khImicheskoy kinetiki i goreniya Sibirskogo ot-
deleniya MI SSSR, NovosJbirDk.

B ubno v. V-2MY ~'"Cl -~L-12-2
~q

3,A

WBNOVP N.N.; BA711-JIN, VOYEVODSKIY, Ui.
-
Fnrmation of alkyl radicals in the phototransfer of electron3.
u
Kin. 1 Mt. 5 no.3:568 W-je f64. (,%IFJ~ 17:111)
1. Institut khimichekoy kinatiki I goroniya Sibirskogo otdeleniya
AN

B AZ R I NN V, C I I T B R 11: T11 r.,v OD.,; m Yvv
Some types of polyrzra 'With conjugated bonds studied b7 means of
electron paramagnetic reaonance. Vysolccm. zoed. 6 no.8:1478-1482
Ag 164o (MIRA 17!10)
1. Inatitut ~Jiirniahuskoy kinetlkl i gorenlya.

M~4^al ftln-+i~a nA ~qfl AU q-q-CM'l

1~-00927--J66_ ]~~/i~~w/EPF("
-WDIG WIDIP (J)/T/EWP (t)/RiP (b)/VdA (c) IJP(c)/RPL
D57M) W%,TwAtm.
ACCESSIOD OR: AP5020982 __7 __Ufl/0l95/65/0O6/0Wo5!7/o~64_
543-878:546, 11-123:542.5
AUTHOR: -Panfilov, V. N.; Voyevodskiy, V. V.
TITLE: The reaction-of hydrogen atoms with molecules -of some compounds in the-zone
of a rarefied-hyAEc, en.flame
SOURCE:
Kinetiks, i ka aliz, v. 6, no. 4, 1965; 577-584
W
TOPIC V catalytic combustion, combustion theQry, c0 ustion kinel
;icsq COM-
bustion mechanism, hydrogen atont-reaction, hydrogen fuel free radical chain
reaction, chain termination, controlled kfnefies, co ion activation energy,
short lived moiety, kinetic flame control
ABSTRACT: The reactions of hydrogen atoms-with molecules of saturated, unsaturatedi
and aromatic hydrocarbons as well as with molecules. of monohydric alcohols were
stadied. Electron jaramagnetic resonance measurements made it possib*le to observe
the concentration of hydrogen atoms In rarefied hydrogen flames, and thus determine!-7
the effect of the above additives. Activation energies were calculated convention!
ally fror. plots of rate constants vs time. A convenient parameter, a, was intro-
duced, representing the dffectiveness of a given molecule in the repetitive "cYcle"17-7,
Card 1/2

-------------SOMICE-coDEi--mi/goi-z-/67-/OoO-/052/OOOVGOok--
ACC NRAN7005951
AUTHOR: none
ORG: none
TITLE: Death of Academician V, V. V oyevodskly
SOURCE: Pravdap no. 52, 21 Feb 67o P- 40 001- 8
TOPIC TAGS: scientific personnel, chemical personnel
ABSTRACT: Academician V, V. Voyevodakiy died at 50. He was a well-known sp*cialist
in chemical physics. (NC]
!SIM CODE: 05/ SUBM DATE: none/ ATD, P111ESSI 5115
Card

BAZHIN 0 H*M. I LIMIACITEVA, N.M. I BUENOV, N.11. I VOYMD6Kly 7j,
Rflaotlans involvjnl a hydrogen atom In the ayntem H20 +Nsfw~114.
Raction with h+ a KIns i kats 6 no, 01105~-1108 N-V 165
(MIRA 3.90.)
I, 3hotitut khimicbeakoy kinetW i goraniya Sibiral(op ot-
delaniya AN SSSR. Outmitted Saptamber Up 1964s,

!~.",L J VA 11XJ/ Aj,M
ACC Nli AP60-67M SOURCE 6 1607661 f6
AUTIfOR: Bazhin, N. M.; Kuznetsov, E. V.; 1Lubncvj_N. N.; !MvodsklX, V. V.
ORG: Institute of Chemical Kinetics and C mbustion 90 All ich;skoy!
_,S~p~~(Jnstitut kh1n
kinetiki, i goreniya SO AN SSSR)
TITLE;, Reactions of hydrogen atoms in the system, water-sulfuric acid-ferrous sulfate.1
11. Reactions with pnsaturated7l3iiFounds
Kinet16
SOURCE.,
-i kataliz, v. 7, no. 1, 1966, 161-165
TOPIC TAGS: -hydrogen, free radical,_free radical reaction, unsaturated hydrocarbon
ABSTRACT:- Previous work has shown that UV irradiation of FeS04 solutions in dilute
sulfuric acid at 77K leads to the formation of hydrogen atoms, which are stable at
this temperature. In this workthe reactions of such hydrogen atoms at 90K and 120K
with acetzlen .1 ethylen .1propylene, allyl alcohol and carbon monoxide were studied.
The concentrations of hydrogen atoms and of the reaction products were measured by
observing the EPR spectra of the samples. Except for acetylene, all EPR measurementsi
were made at 77K. Hydrogen atoms add to acetylene to form vinyl radicals whose
hyperfine structure is similar to that obtained by other workers in the photolysis of,
HL in-the presence of acetylene at liquid helium temperatures. In discussing the
mode of addition, the authors compare their observations with other work on the addi-_
tion of hydrogen atoms to deuterated acetylene. Addition of hydrogen atoms to
UDC: 541.141:546.7221226-145.2

L_ 17952-M
ACC--NRs--AP6007776 ------ -
propylene leads almos.t-exclusively to-the formation of-Isopropyl radicals. It was
observed that ethyl and isopropyl radicals do not decompose under the influence of
UV or visible light under experimental conditions. The spectrum of the reaction
product obtained from allyl alcohol is very similar to those of hydrocarbon radicali
RCH2N2 and therefore can be ascribed to the radical tH2CH2CH 2011. Since a protonated
N e
form af allyl alcohol is involved,-the radical in this case must bc 2CI12CH20 12-
The energy decrease due to the Increased separation of the unpaired electron and the
charge on the hydroxyl group must be sufficient to offset the energy increase of
localization of the unpaired electron on a primary rather than on a secondary carbon
atom. Addition of a hydrogen atom to Co yields a product whose spectrum consists of
a doublet with a separation of approximately 132 e. and can be ascribed to the rad-
ical 00. The radical decomposes under the influence of light, probably to H and CO.
'The authors conclude that under the above conditions hydrogen atoms can react with
unsaturated compounds by adding to double or triple bonds, or to unshared electron
pairs. Useful quan titative data concerning unsaturated compounds can be obtained in
this manner. Orig. art. has: -2 figures. (VSI
SUB CODE: 07 SUBH DATE: 143un65/ ORIG REF: 005/ OM REIF: 006/ ATD rRESS:
Card 2j?a___11

-e./awri
J i/rja A% hi I rjvv At Ij an/ V M/ %A%Z/ An
ACC NRi AP6013381 SOURCE CODE: UR/0195/66/007/002/0230/0236
AUTHOR: Chkheldze, 1. 1.; Molin Yu. M.; Mfivnov V. F.: Chermysh*v, To. A.; B2!mn,
N. Ya 1 VqevodskiX, V. V.
ORG: Institute of Chemical Physics AN SSSR (Institut kh1micheskoy fisiki AN SSSR)
Instituie-of Kinetics and Combustion SO AN SSSR (institut kinstiki i gorenlya SO
SSSR); Institute of 25anic Chemlstry, In. N. D. Zelinskly, AN LSSSR (Institut organi-
cheskoy kfiUli AN SSSR)
TITLEt rormation of radicals during the radfolysis of organic solids. Part 3t EPR
spectra and radiation YTe_1ds of rndicals In certain orgenoollicon compounds
SOURCE: Kin tika i k1taliz, v. 7, no. 2, 1966, 230-236
TOPIC TAGS: free r-adical, organosilicon compound, irr .adiation effect, EPR spectrum
ABSTRACT: The EPRLMethod was used to investigate the radical processes involved in
the low-temperature radiolysis of certain organosilicon compounds with a view to de-
temining the effect of the silicon atom entering into the aliphatic chain on the ef-
fectiveness and direction of primary radloc.hemical processes. The radiation yields
of the radicals.(GR) formed by irradiating the compounds with fast electrons at tem-
paratures from -130 to -2800C were determined by the EP21method. It was found that
0. for saturated and aromatic substituted dsrivati"s of tetrimethyls I lane did not
UDC1 541.IS-16
-Card _ 1/2

ACC NRi AP6013381
differ from G'R for hydrocarbons of siallar structure and amounted to 4-5 1/100 ey and
0.2-0.6 1/100 ev, respectively. ror compounds of the general formula (CH3)3SI(CH2)
CHzC112 (n x 0, 1, 2), the radiation yield Is 0Ra 1 1/100 ev, which Is approximateig
4 times less than for hydrocarb*ns with double bond. Analysis of the EPR spectra .
showed that the introduction of a silicon atom in the aliphatic chain 4oes not produce
any appriciable changes In the rViolysle mchanism, Orig, art, hast 7 figures# 2
tableog 5 fonulasi
SUB COW t 07;'2o/ Stu DATEs i2svo/ ono uro ooe/ On nri on
2/2

'776-66
AUTHOR:
1FAPJ)/E7WT(M) M/JW
P6030704 SOURCE *CODE: UR/0195/66/007/004/073270734
.3
Bazhin, N. M.; Kuznetsor, E. V.; Bubnov, N. N.; Voyevodski It. V.
ORG: Institute of Chemical Kinetics and Combustion,SO AN SSSR (Institut khimicbeskoy
kinctiki I gorenlya SO AN SSSR)
TITLE: Reaction of the hydrogen atom In the system H2O+H2SO4+FeSO4. 11L Reaction with
saturated organic compounds
SOURCE: Kinetika I kataliz, v. 7, no. 4, 1966, 732-734
TOPIC TAGS: hydrogen atom reaction, methanol, ethanol, Isopropyl. alcohol, ethylene glycol,
Isobutyric acid, malonic acid, acetone, free radical
ABSTRACT: Atomic hydrogen obtained by the action of UV light on frozen 1j20+H2S04+FeS04
at 77K was previously shown to react with unsaturated organic compotmds. In the present
paper the authoTs studied the reaction with a series of saturated compounds having weak C-H
ondsf c -1d
(moth -0111 ethanolJ sopropyl alcohol, ethylene glyc Isobutyric acid, malonic a
an , I
and a etone). The reactions were carried out with 0. 1 M solutions of the organic reagents at
90 and 120K, and the products were Identified from the EPR spectra. It was found that the
reaction between H and methanol, ethanol, Isopropyl alcohol, malonic acid, and isobutyric

L h5776-66
ACC NRi AP6030704
acid resulted In the following radicals.-
~112011, CH3611011, 1131-CH3, HOOC-C-COOH and H3C- C113, respectively. In the
case of methanol, the 6H2011 was further broken down to IICO, but no 6113 could be detected,
With acetone, the reaction yielded C112- -CH3 Instead of H3C- ~-C]13, while In the case of
~H Oil
ethylene glycol, Only 6112- 9-H and no 6H20H could be detected. The mechanism by which
atomic H at approximately 90K can capture bydrogen from alcobols, organic acids, and
ketones Is discussed. Orig. art. has: 5 formulas and I figure. (261
SUB CODE: 07/ SUBM DATE: O8Oct65/ ORG REF: 004 1 ATD PRESS: 5084

TOVBIM, M.V.; VOIIVUDSK&U, Z.L.
Autoadoorption process. Part 1. Surface tension of salt solutions,
Ukr.kbim.shur. 22 no.2,.173-179 136. (WAL q.-
1. Kiyevskiy gosudaretvanW universitet imeni T.G. Shavchanko.
(Surface tension) (Salts)

Z. z
USSRI Physical Chemistry Surface phenomena. Adsorption. Chromatography. B-13
Ion exchange
Abe Jour : Referat Zhur Xhimiya, No 4) 1957, 1-1387
Author : Tovbin M.B., Voyevudskaya, Z.L.
Title Concerning the PFo-e-es-s--o-f-S-elT-Adsorption, 1. Surface Tension of
Salt Solutions
Orig Pub Ukr. khim. zh., 1956, 22, No 2, 173-179
Abstract The assumption is made of the existence of a phenomenon of self-adsorption
which consists in an accumulation of molecules of an individual aubstance
or solvent at the surface of liquid phase-air interface. On thq b5aic- of
this assumption and.thermodynamic considerations a correlatict hae b';~an
tablished between surface tension ((5 ) and vapor tension '(P) of s3clutions
of non-volatile surface-active substances. In particular, as,a rtault of
dissolution of electrolytes in water self-adsorption of water vapor at tht
surface of the solution causes a decrease of p over t4e solution and am in-
-crease of a of the solution, as compared with p and 6 of pure water. At
temperatures of 25, 35 and 450measurements were made of (~ of r-4teous solu-
tions of NaCl, KC-1, MgC121 BaC'21 KII Na2804 and it was sho**m that in the
1/2

USSR/ Physical Chemistry Surface phanoarmrta. Adsorption. Chromtography. B-13
Ion exchange
Abe Jour Referat Zhur Khimiya,, Ito 4, 1957Y 11387
case of pure vater and of all thq solutions of the abova-statr-d .1&1tP_, ri:-
gardleas of the nature of dissolved surface-6ctive substancE.3,6 d.'-p~t:'ids
in an uniquely defined maxner on p. 7ais correlation is lin-59.r sLzA cn. ita
basis vu calculated the value of self-adsorption of vz;,tir 'WL. I Ch i e
(in 10-"j mole/cm2): 14'.58 at 250, 16.32 at 350, 19.26 at kio. on- dia6o-
lution of surfac ~_- -active substances the effect of self-adao.-ptict. in iup-
pressed by adsorption of the solute, resulting in decr,.-~&Ps'of
2/2

KARACEAN, B.P.; VOTIVUDSKIY, B.M.
Valves of a new t]rpe for large diameter sewers. Yod. i san.
tekhn. no.10:35-36 0 158. (MIRA 11110)
(Sewers, Concrete) (Valves)

.KOICIIAN, B.?~t-!OT-MSK1Y,,.1..B.H-.
Chemically a.table plastic materials. Strot. promo 36 no- 7:42-43
J1 158 - (MIRA 11:8)
MsStiCB)
I

j,,v4.adshiy naucblw BotpWziik
KARLSEX.. G.G... kand.biolog.nauk;.VOMXOV, AIB
Working out a method for investigating the vorking quaUties of horses.
Trudy VNIIK no.17.-65-82 149. (MIRA 16;3)
(Draft horses)

I VOYEYWYI-~~abhiy .nauchW sotrudnik
Improving horsel harrteses. Trudy VNIIK no,17:83-89 149. (MIRA 16:3)
(Harness)

TARLSIN, G.G.. kand~biolog.naukj VOTMOT, A.B., nauchnyy sotrudnik;
KOBMN, B., red.; TMCffOT;-R-.,-Te-k1inr-9-r.
[Using horses In agriculture] Ispollsovanis loshadel v sel'skom
khosiaistva.- Moskva, Mosk.rabochii, 1947. 118 P. (MIRA 13:9)
1. Zaveduyushchiy otdolom konsiopolizovaniya Vsesoyuznogo nauchno-
iseledovateliskogo instituta konevedetva (for larlsen). 2. Vse-
soyusnyy nauchno-ionledovateliskly Institut konevodstva (for
(Voyeykov).
(Draft horses)

ijoyzr,!0v, A. 13.
24163 A. B. Usov-rsherstvo,:,L-d%-k,, 'zonsko~, u-prcliahl. Trudy Vst~soyuz- ','auch,
r,~ C:r%
issled. D'-TA konevolstva, 17, 19~19, S. b3-9-
SO: Lotopis, islo. 32, lg:i-?.

!- VOMKOVO A.P.
Automation and mechanization of the processes of the
chemical heat treatment of steel parts. Avt. prca. 29 no.8:
34-36 Ag 163. (14IRA 1611l)
1. Moskovskiy avtozavod imeni Likhachava.

17,Oymiri,07, A. V.
24160 v 1xv 'k - V. K razrabotRo .-,ct0d0v ispytanny rabochilli kachestv loohadoy.
Trudy Vscso~luz, in-ta 1:onevo-l-st.,a, MP. 17, 1910, S. 65-C-51.
SO: Letoplo, No- 32, 1910-

a

&2z&a. xilt 'Lt kT I
;SjTj
Ig
1 UIP 1'43 p 9 t~c

c Viiij giv
ct ;j prorAr tYpe hirmice f0t it %IKCI,.Il
I
~
c
h-,; tn f"
TjjC ctwIptcr drall with 11"'14
i1 tv m d0m,"r, de.
pUrpo'c'
l
c
c i1tvO
Two Cha"414 ftr,r Iwalofy ilat-a
vc!
A
re
sctjptl~jj of cruribl 1111
fill 111fir
' T'I'mcd-AK.
t
t
f
o
-c
)
oil the rt
re-

-110 AND Jim o4offs
M of I CH 41$S I I.) Jb)ILVOJL I I IV NO H a '--F -5Y
fTA" U. S. S. R, Pat. 29,M3, A I
inner layer Is made C4 a high-Srule t-
resistant basic or neutral matesLal; while the outer er i4.
PrePIrtd from m refractory material which fus -;it scient'
mechanical strength but wk;ch ii attacked by the Mag.

I
rors of attematers. j,
. I ,Iskiro.arlazi 11 no-2:28-
(Ilsetric resistors) (X'aA .101-3)

SOV/120-59-4-23/50
AUTHOR: V, 1'7,4
.
TITLE: A Balanced Hall-Effect blagnetometer with a Thermostatted
Detector
PERIODICAL: Pribory i tekhnika eksperimenta, 1959, Nr 4, pp 100-102
(USSR)
ABSTRACT: The unit is meant for use in fields of strength 100-
16 000 oersted. The first part of the paper presents the
theory. The detector is a piece of n-type germanium 2.7 x
2.7 x 0.4 mm, of specific resistance 2-3 ohm-cm. Fig 2 shows
thebridge system used to measure the Hall e.m.f. (here
10 IiV /oersted at a working current of 10 mA at 1000 c1s).
Fig 4 shows the thermostat system (the bottom pair of wires
go to the detector, while the top pair go to a thermistor).
Fig 5 shows a general view of the complete unit. The det-
ector is designed to work at "-50C; the excursions do not
exceed 1.5 OC at the thermistor, which is near the heater,
and are only about 0.2500 at the detector, which is ther-
mally insulated. The heater power can be adjusted in nine
Card 112

SOV/120-59-4-23/50
A Balanced Hall-Effect Magnetometer with a Thermostatted Detector
steps to suit atmospheric temperati-Lres from -30 to +500C.
The paper contains 5 figures and 6 references,, 2 of which
are Soviet and 4 English.
SUBMITTED: May 14, 1958.
Card 2/2

31828
S/194/61/000/010/036/082
9, 3 D256/D301
AUTHOR; Voyeykov, D.D.
TITLE: Some problems of Hall emf-element construction
PERIODICAL: Referativnyy zhurnal. Avtomatika i radioelelctronika,
no. 10, 1961, 10, abstract 10 V85 (Izv. Leningr.
elektrotelchn. in-ta, 1960, no. 43, 157-162)
TEXT: Optimum admixture of ingredients for producing Hall
emf-elements was investigated. The dependence upon the composition
of the following characteristics of the Hall emf-elements is dis-
cussed: Temperature behavior of the emf; the resistivity and Hall-
coefficient changes in strong fields; sensitivity in terms of volt-
age and power; equilibrium instability due to temperature effects.
A comparison between elements prepared of different materials
shows that for high ohmic loads and for strong fields most suitable
are elements composed of Si and Ge; for weak fields and low ohmic
loads at any field - elements of .InAs and In(As 0.8P0,2 Elements
Card 1/2

i
31828
S/194/61/000/010/036/082
Some problems of.Hall ... D256/ "301
prepared of InSb are suitable only for relative measurements or for
instruments working at low temperatures. 10 references. Z-Abstrac-
ter's note. Complete translation_.7
x
Card 2/2

1,,OXEYKOV,.,.D4trlY.,4.iitriy.evichj GERTSIGER, Leopolld Naumovich;
KNYAaV, Xonsti~konztantinovich; LIVSHITS, Il'7a
Aronovich; ESSENSMI, Allbert Yakovlevich; KPOV, K-K-pred.
[Design of low-frequency enerators] Konstruirovanie nizko-
chastotrWkh generatorov, TBy) D.D.Voeikov i dr. Moskva
Izd-vo mftergiia," 1964. 225 P. (MIRA 1701

Vn-1k"- D. 1). UMNO 'MAGNEIRTS IN XILKS FUSING,
COPPI11? IN T-101 4 4411W VVQPJET X I
PIRY,
we 5 (71, Vk;')--48 (MU).-I'lie ai ege of mative-
!site over Dina% brietc. clay, and quartz Is Its resistance to,
buleslairinfa-,inn. Tt was used with success for walli and,
!archc% In kiln- rchtting copper. Its weak points are Its
sensitivity In irm-,temuire changes avid dilatao(m. DiIA-'
Atation of marticsite occum In a continuatis manner but
only during cooling. The apcrture% must thcrefoce be:
ca-rclullybitceland (fickilmrriviltil slowly when work eeaws-,
1 Aut4Wg', rnt was made. to.combine mapesite with Vinas'
4
=71(ervening Laytt of chromite was found tItI-11
necMa to a-Luim stretigth. the kiln wall* wat slightly
Inclined: The thickneqs of the walls was equal to two
brick: a m2gilc-,ite brkk In the InArrivir, thets a half Dings.
brick, and a hall clay brick.

or
Itrid Ili-
I,v ;4 ti-w for .1 %I'trili
It . ,,,I !U-ir
, 'J. 10. hi,,-
A 1, dr,
s y
Mil-V

For jigjp4a tIGNIFITAROUS
MIT,
R 3 p A KOM
and
of lillflilcei
it
c pttr
'Opcr type af furl,,,Icr for a "P"141
eusics h()'W to Oat it r Pt'r &-als WWI ItA4 and"'helf
J.-he :~~rdld CIIIA j* ~11.tajjrrl de-
purpo"O.- t1juptcts at'. (Ifv(~tcli to 0
Tlwo
'nIt'u.tMTI- Iry fornace.1t,
Cc, reverbet"tc 3nd tlltlr
r-rip"oll of mcOlods 0
on the ttfractlIry
44 (J.
i.T. -I t_57 7`7
HEM

D. D.

IST AMD JAV LITTIN
t1x%
Alm ClIattl CF!C
AUTHOR NOR It
1"19

m

nonrim- 12
ZAL& U. S. S. R. Pat, 29,503, April 26,
i1nner layer is aude of a high-gr de It" I
"Sistant busic or neutral materl2l; "bile the outer er 1;
prep2red from it refractory inateriat which line
mechanical strength but which It altatted by the Ait,
A

S20~wr. T)- . U,%jNn MAGNISITY; IN KILNS FUSIM3,
lij~ f(kiij-pi ~Jvau).--Iht advantage a
~xltc ov" Pir%'A' briek, CUY' and quqfti is Its felblance to*
basic slat In fir,inn. It wa4 tvw4 with mcceii for wall i Rnd
tarche-4 In kiln- t(Atting cWper. Its weak points art Its
sen-m vify P~ hmprrmire changes and dilatation. Dila-'
Jafian of rrvivic~itc fwrvrq in a cmilnumm inarintr but
only dttrinK cryttirig. I he apcrtum~. must. Ocrdmt be
cartfully lisicif and thr Wit c:~ul 4owly when work ctaqti
i An a;paiment -mai mix1r. to cninbine magntsite with Dinas;
layer of chromite wat found ud-'
necmary. To"i-mure Ortrigib.. the kiln wall,; we" slightly
T as equal to two
Inclined. he ihkknc.!t of the walb w,
brick: a magne-qite brick In IN Interior, then a half Dinjis
~.brick, anti a half clay brick.
1111 lip

VOYEMV, D.D.
Methods of increasing balance stability in Hall effect-devices. Zhur,
tekh,flz. 28 no.10:2248-2254 0 158. (mmi xx:n)
(flail effect)

VOYEIBOV, D. D. , Cand Tech Sci -- (diss) "Construction of gaussaieters
of increased precision, employing the Hall effect." Leningrad, 1960.
15 pp; (Ministry of Higher and Secondary Specialist Education RZ-FSR,
Leningrad Inot of Aviation Instrument-Building); 20C copies; price
not given; (KL, 26-60, 135)

24(3)
AUTHORs Voyeykov, D.D. SOV/57-25-10-21/40

TITLEt Methods of Increasing the Balance Stability of a Hall
Transmitter Netody povyaheniya stabillnosti uravnovashivaniya
datchikov Kholla)
PERIODICAL: Zhurnal tekhnichaskey fiziki,V,).L 23) lir 10, pp 2248-2254 033R)
ABSTRACT; This is an investigation. of some of the causes of the balance
instability of instruments used in engineering, the operation
of which is based on the Hell- (Kholl) effect. The temperature
instability during balancing is one of the principal obstacles
to the utilization of such t--ansmitters in precision instruments.
As, however, the compensation of this instability in a wide
temperature range proves to be difficult it is more convenient
to study the causes leading to such instabilities and to examine
the possibilities'*of eliminating them already in the production
of the transmitters. In a simplified form a Hall transmitter can
be represented by a bridge circuit, the Hall generator being
ganged into one of the diagonals. It J- a shown that the instrument
error due to the unbalance of the Hall transmitter is inversely
proportional to the field strength and to the stability co-t
Card 1/3 efficient K of the transmitter. K represents the ratio of the

Methods of Increasing the Balance Stability of SOV571-29-10-21/40
a Hall -Transmitter
sensitivity to half the ioltage aczoss the current terminals of
the Hall transmitter. The larger K, the smaller will be the in-
fluence of unbalance of the transmitter upon the instrument
error. Thus a stability coefficient as high as possible is one
of the basic requirementq placed upon the design of a Hall trans-
mitter. The influence of tha shape of the transmitter and of the
carrier mobility upon the Ptability coefficient is investigated.
The formula (4) deduced forY 1,isds to the following conclusionss
1) In order to Increase K an" the balance stability the ratio
1 , 2, which was recommended by Kjhrt (Kurt) (Ref 1), must be
a
abandoned in favor of a value keeping within the limits of 1* 0,5,
a 1, (and d) denoting the dimensions of the transmitter.
21 Apart from an increa3e in K th'is choi_-e of dimenvions leads to
a saving in semiconductor material.
3) X varies as the mobility at otherwise equal dimensions of the
transmitter. Transmitters of InSb and InAs are to be preferred
to such of n-Ge for measuring weak fields. It is demonstrated
Card 213 that the principal causes for the temperature instability in

Methods of Increasing the Balance Stability of SOV/57-OB-10-21/40
a Hall Transmitter
balancing Hall transmitters are to be found in the heterogeneities
of the crystal lattice of the transmitter material, in the recti-
fying effects and the insufficient equipotential level of the Hall
contacts. If the design is chosen in an effective manner and a
corresponding method of production is selected the temperature
stability in balancing the transmitters can be considerably in-
creased. A.P. Kalmykov assisted with the production of the samples
of Hall transmitters. There are 4 figures, 1 -table, and 3 refer-
ences, 0 of which is Soviet.
SUBMITTEDs February 13, 1958
Card 3/3

VOYMOV, IoDo
, " ---
Aleksandr rvana7icb Toeikov; peraoaal recollections. Keteor. i gi&-ol.
no.12:15-22 D 158. (XM 12:2)
(Voeikov, Aleksandr Ivano7ichp 1842-1916)

3(0) SOV/50-58-12-3/20
:AMORi
TIM: Aleksandr Ivanovich Voyeykov (Aleksandr Ivanovich Voyeykov)
Personal Reminiscences (Lichnyye vospominaniya)
MRIODICAL: Meteorologiya i gidrologiya, 1958,, Nr 12, pp 15-22 (USSR)
ABSTRACT: Pis article contains the reminiscences about his uncle of a
nephew of the above-mentioned famous Russian geographer
(1842-1916).
Card 1/1

VOYIYIOV, I.G.. master.
Organizing and mechanizing the work of repairing secondary comstuta-
tion. Inergatlk 2 no.10:1?-19 0 154. (KLRA 7:10)
(Ilectric switchgear)

VOYe,Y1