SCIENTIFIC ABSTRACT YAKOVLEVA, T. B. - YAKOVLEVA, T. V.

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• Collection: Scientific Abstracts
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• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT


YAKO'RZVAY T.B.,- PETROV, A.A.; STANDNICHUK, M.D.-
Vibration spectra and xtrucWre of enin sili6on hydrocarbons.
Opt. i spektr. 11 no.5:588-593 11 161. (MIRA 24:10)
(Silicon organic compounds)

AGEY.YANY T.A,; YAKOVLFVA,.T#D.
.. ......
Determining masses of rotating galaxies, Uch.tap.LGU no.3281139-245
165o (M'RA 18 110)

TANO LEVA,-Zatl-yana Fedorma; RYSTENKO, Anna Timofeyevna; LAVORKO,
P.K., insh., retsenient; RIKEERG, D.B., red.;
GORNOSTAYPOLISKAYA, H.S., takhn. red.
(Brief handbook on electroplating] Kratkii apravochnik po
gallvanichaskiid pokrytiiam. Moskva, Mashgllt~ 1963. 269 p.
(MIRA 160)
(Electi-oplating-Handbooks.. manuals, etc.)

13XOVLVVA, T*G*, kand, tekhn. nauk.
Determining the neosesary degree of soil coupactiin In railroad
embankmente, Tr~ MIT no,94.*3-20 157, (NBA 110)
(Railroads-3krthwork) (Soil stabilization)

Y~ __ VA T.G., kand. t9khn. nauk
ft
Carefttl maintenance of ditches. Pat' i put. khos. no.8.-34-35 Ag 159.
(MIRA 13:3)
(Railroads-Maintenance and repair)

-YA-KQ-VMM,-T-G..,kand. t ekhn. nauk
Determining the safety zone in planning control mea8ures
against karat formation. Trudy HIIT no.111:150-163 '60.
(MIRA 13:11)
(Railroad engineering) (Karat)
A,
jQ;~,~

YAICOVLEIIA, T.G.~ kand.tekhn-nauk
Some methods of romp-dial treatment of the roadbed. Put' i put.kho2.
6 no.3:47 Mr 162. (HURA 15 0)
(Ba3.1ast (Railroads)-maintenance and repair)

lmxid. Lekhii. nauk; IMMV, P.1".
Mar-ni ne f o:- r! fll'cre I In.,,, tr7ro a. id (;r,-fA-,hc cs.
Trudy KTIT no.2,77-.'147-104 163. --'7:10)

FRISIMI, 1-1-oisey Abramovich; XHOKHLOV, Ivan llikolayevich;
YAKOVLEEVA~-T~wy Tovna; SEPCEYEVA, A.!., red.
(Rail-road roadbed] ZeOlanue polotno zheleznykh dorog.
Moskvav Trarsportv 1964. 295 p. (MIRA 18:2)

CHIMIKOVg, P.O., kwW. tokhn. nauk;I T.0.0~- telchn. nauk
Basic prerequisites In the Wellng of embwiiment sagging.
Trudy NUT no.21WO-V 165. I:KTPA 1802)

YAKOVLEVA T.G. kand. tekhn. nauk; .'VANOV, D.I.
Centrifugal model.~,ng at the service of rallroader.s.(,put'll:pUt.
khoz. 9 no.lOs29-30 165. IRA 8 10)
1. Starshly inzh. putolopytateltnoy laboratoril MoskovBkogo
instituta inzhenerov zhele2nodorozhnogo transports, (for ivanov).

YAKOVIEVAi T-L, kand.toologo-mineralogicheakikh nauk; KALOVA, N.N., inzh.
Dptdrzination of coefficients of crushability. T~:-udy Inst.
ogneup. no.29:173-184 160- (MIRA 14:12)
(Refractory materials)

W
SUM
0 V VA T, X_
- 7r-4
7
7
-7
JI
4
*4"
Z, 87OM: 411W eatir. -4
r -m- ~~ I'M g!--,
-?A C AA
W% 014041*lth 21 .0 wt.; U ~T=i
-lag-ft tnlxt~&* 14,&-7- -0.5 hr~ gave Zplele
t0t and-Eirp f
cmtvtrgon.to the disulfims cb1ijrjdem,62Ar2,3*Ltm9v_
-!heating yltlds'it len pure prodet-- with, Sower mp, The:
product obtained is pure ob-~-
iained In 6217o -Yktd after quenchlag the mfit. in I?zQ;- -,The
--W comtsts Mainly of- the -sutfCnk
midtA mat
-The Srd sulfo.,group cannot b: introducedevea at reflux~
with CIS0111. , At 20' the 2.4-momcr Is wt. In 100 g. RIO
71C C, This dichloride (I g.) W14h I mi,
to thn extent of
30-6070 okum-in '. sealoA tute 4 h". at 189 yk Is with
C00JI JI It"!,;
d.
kfitoride
38';
antlOtul- ~ olc= and hes tint again 6.5 hr. at 14"9,
gave 5177 ttkhtmide, The tr It. tn. 157-9*, was
#Igo forrutd w% lieAtIng 2 g. -J-fcC.I(,SOjC.I wlO, 2 mi. 67%,
Mourn 4 b-9, t( 801, fohow'ed by the vbove trq &(mmt with;
CISOM. Nit 1, m. IG2* ff-orn AcOH, cf. Ma"i Per.,
307COl Li sot. In hot AtOli: MePh. C,11., CliC4,
(CII&Ci CISOall. Ilia &aly. in MIO al, 4'()* Ic 0,73 g.
Per 100 ff. "In.

RM
SFRYSKOV, A.A.; YAKOV13VA, T.I.
Stud7.of sulfonation. Part 35. Preparation of toluene di- arA trisulfo-
chlorides. Zhur.ob.khim. 25 no.4:783-786 AP 155. WaA 8:7)
1. Ivanovskiy khimiko-tekhnologicheskiy institut.
(Toluenesulfochloride) (sulfonation)

,A nt .-- ,-4 .- - I ,
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-- - I- -
- --- --m
911allmll

WHOM
d tl:~ L; V I-
484
AUTHCRS, Spryokov, A. A., and Yakovlevaj T. L
71 TIE: Orientation during Displacement in the Aromatic Series. Part 1.
Sulfonation of m-Toluenesulfonic Acid (K oriyentatsli pri Zame-
shchenii v aromaticheskom ryadu. 1. Sullfirovaniye m-toluolsull-
fokisloty)
M10DICAL: Zhurnal Obahchey Khimii, 1957, Vol. 27P No. lp pp. 2)9-244

ABSTRACT: It is known that the orientation of a newly incoming substitute
during the displacement in a benzene rinjv is affected by the reac-
tivity of the given compound and reactic. condition, i. e. tem-
perature, activity of attacking agsht am time of reaction.
The effect of these very factors on the orientation of a newly
incoming sulfo-group was investigated during m-toluene-sulfonic
acid sulfonation experiments. Instead of the anticipated 1,2,5-
and 1,3,5-toluenediaulfonic acids, the authors obtained a 1,3,5-
isomer (the wilfo-group is oriented in meta-position relative to
the methyl group) which was found to be a kinetically highly
stable isomer. The ortho-, para-orienting effect -of the methyl
Card 1/2

4%
Orientation during DizpUcement in the ArDVAtiC Series
group in toluene was seen to become weaker in m-toluenesulfonic
Acid as a result of the deactivation of the nucleus of the sulfo-
group. Sulfcnation of this acid results in the formation of a
more stable imta-isomer (1,3,5-toluenedisulfonic acid). Higher
temperature and activity of the sulfonating agent increase the
amount of the isomer. An increase in reaction period has the same
effect as temperature and activity increases. The results of
sulfonation with various agents ard at different tAmperature5 are
tabulated.
Six tables, 1 graph. There are 7 references, of uhich 2 are Slavic.
ASSOCIATION: The Ivanov Chemical-Technological Institute (Ivano,iskiy Khimiko-
Tekhnologicheskiy Institut)
PRESENTED HY:
SUHKITTED.-
AVAILABIE:
Card 2/2
January 30, 1956

(Satka--MWesite)

GULIN, Vasiliy Mikhaylovich; pmApoVA., Nina NikolVevna; YAKOVIEVA,
Tat~ya=_U ;.,IVAIIOVI F.P., red.PANXRATOV, 1.1-o.,
.'r'ed.
[mechanization of secondary and auxiliary operational
nizataila podsobno-vspozogatellrqkh rabot. Ivanovop :Evanovskoe
knizhnes 1?A-vo,, 1961, 1+6 p. (M:EU- .15:4)
(Textile industr7--Equipment and oUppliso)

pi K OXILS VA, T- L
J,
"Piodra and Pnuedopiedre.."
Vestnik vererologii i dermtola,-,ii (Fulletin of
Nlo Januar.,j-Febriar, 195h, k7f7mper), o c

Y~~O v VAJ
USSR/Zooparasitology Sporozoas P-1
Abs Jour Referat*ir-'.Y Zhurnal Biologii, No 16, i957, 70106
Author Yakovleva- T.L.
Inst Zdravookhr. T adzhkistann
Title Problem of Substitution of Sarrosporidia for Toxoplasma
in the Color Test for Taxoplasinosis
Orig Pub Zdravookhr. Tadzhkistam, 1956, No 5JV 13-16
Abstract 92 sera were stu6led by reaction with dye Sebin-Feleman's:
Goven healthy and 85 sLifft;rv*.,- from a variety of disea-
ses. In the latter group, five suspected of taxoplasmo-
sis. In place of live taxoplasma, sarcosporldia were
takun from heart inuscl..,s of horned cattle or from sheep,
Sarcosporidin were foond tinclittable for the ronxtion
for taxoplasmosin.
Card l/1 I

Y1qkoVLIEV19, T
USSR/Microbiology - Microorganisms Pathogenic to F-3
Humans and Animals
Abs Jour: Ref Zhur - Biol~j Na 18, 1958, 81613
Author Kenigsberg, L.M., Ya kovlova, T.L.
Inst
Title Tadzhikistan Piedra and Pseudopiedra.
Orig Pub: Izd. Otd. estestv. nauk AN TadzhSSR, 1957)
No. 18, 2Ll-231
Abstract: Cases of piedra disease which differ in their
clinical picture and in the nature of the cau-
sative agent (Trichosporum) from presently
known forms of piedra% American, European2
Japanese -- were observed in Tadzhikistan.
Characteristic symptoms of different Ibms of
piedra) mcrphological, and cultural features
of Trichosporum variants are tabulated. The
Card 1/3

USSR/Microbiology - Microorganisms Pathogenic to F-3
Humans and Animals
Abs Jour: Ref Zhur - Biol., No 18, 1958, 81613
disease is found in women with long and greasy
hair, In the mid-portion of the hair stony
nodules appear, of a greyish color, firmly
attached to the hair surface. The nodules
consist of mosaically arranged spores and small
granules retained in the first generation of
pure culture. The spores do not penetrate
inside the hair, the cuticle is undamaged at
the spot of attachment, the infected hair
retains its luster and sturdiness. For the
first time we succeeded in infecting cut human
hair by piedra by soaking it in a suspension
of the fungus culture in castor oil, which had
a characteristic granulosity in addition to
spores and mycelium. A disease is also des-
cribed clinically resembling piedral caused by
Card 2/3 46

Ii
USSR/Microbiology - Microorganisms Pathogenic to F-3
Humans and Animals
Abs Jour: Ref Z~ur - Biol,,, No 18, 1958t 61613
an actinomycete and named pseudoptedral in which
nodules of a brick-red color appear on long,
oily hair,, Pseudopiedra is found in Tadzhil;is-
tan, Vzbekistan, in the Urals and in the
I Ukraine. Bibl- 39 refs. -- M.I. Nakhimovskaya

YAKOVLEVA T M
PhosphataBes of leucocytes qatalyzi~g the hydrolysix of varioim
substrates at different pH valuea, TSitologiia 2 no.2;2M-218 Mr-
Ap 160. (141RA 14% 5)
1. Laboratoriya toito.logii Instituta morfologii zhivotnykh AN SSSR,
Mosk7a.
(fHOSPHATFZ)

TSARET, B.A.; GANNY'AN, V.V.; kARTYSH,
Uae of polyvinyl alcohol in photographic emulaions. frudy LIXI
no. 5t159-164 159. (MIRA 13,12)
1. Kafedra tekbnologii proizvodetva kinofotomaterialo-r.
Leningradskogo instituta kinoinzhenerov.
(Photographic emulsions) (Vinyl alcohol)

$UW
~EIMMI A.K.; FRIGORNEV, I.G. Brinimali uchastiyes YAKOVIEVA, T.P.;
VABILEVSKAYA, Ye.ye.
Obtaining tf-chloro-others from unsaturated hydrocarbons of vapor-
phaae cracking* Izv.vys.uchebsav.j neftli gaz 3 no.3163-68 160.
(MIU 14:10)
1e Groznenakiy heftianoy institut! Novogroznenskiy neftepererabaty-
vayushchiy zavods
(Ethers) (Cracking process)

V EV74
AVID01f, D.B., kand.med.nouk; BAIROV, G.A., kand.med.nauk; BUTIKOVA, N.I.,
dotsent, kand.med.nauk; BOIKOV, G.A., kand.md.nauk; VMBSHCIUGINA.
L.H., kand.med.nauk; GONCHAWYAP MiNs. prof., doktor med.nauk;
ZHOLOBOV, L.K., vrach; ZEKSKATA, A.G., kand.med.nouk; KAMRIYANTS,
G.A., dotsent, kand.md.nauk; XCLESOV, A.P., doktor med.nauko,
KOHMATIM, I.P., Imnd.med.nauk-, XORCHANOV, G.L. kand.med.nauk;
KUTUSM, F.Kh., kand.med.nauk; LZVIITA, O.Ta.. kand.med.nauk;
LYANDRES, Z.A., prof., doktor med.nauk; MOROZOVA, T.I., kand.med.nauk-,
MIRZOMA, I.I., kand.mod.nauk; PAIWMMIN, V.S., kand.modonsuk;
RASTORGUYEV, A.V., vrach; RUDAKOVA, T.A., Irand.med.nauk; SAVITSKAYA.
i'l ~Ye.V., kand.med.nauk; SVISMOV, N.I., vraca; CHIMOVICH, GoV.,
kand.med.nauk; TAKOVLEVA, T.S., vrach; MARGORIN, Yevgeniy Kikhaylovich.
prof., red.; 'red.; VSRXMCHAGINA, L.H., red.;
MJLXVA, K.S., takhn.red.
[Operative surgery an children] Operstimais khiruraiia detskogo
vozre-sta. Leningrad, Gon.izd-vo med.lit-ry Kedgiz, Laningr.otd-nis,
1960. 475 P. (MMA 13:12)
(CHILDRU-MMURY)

YLKOVLF.7A, T.S. (Imingrad., K-17.. Taroslavskiy pr., d.87.. k7.30)
Treatment of fistulons forso cf rectal and ar-al atresia. Test.
khir. 89 no.324119-125 X 162o (MIRA IW)
1. Iz kafedr7 khirurgii detskogo vosrasta (zavo - prof& GeAe
Bairov) laningradskogo pediatricheskogo maditainskogo instituta
(rp.';:tor - dotsent YeeP. Semenova).
(FISTULA., ANAL) (METUH-AMORKITIM AND DWOWITIM)
(BUS.,AMOWITIES AND DEFORMITIES)

LEMESHEV, M.Ya.; LAGUTIN, N.S.t GREKULOV, L.F.;IRASX0V, V.D.; IiRONIN'
A.A.; YAROVIZV&JY.; ANANIYEVA, L.F.; KOLDSOVA, Te.Ta.;
MURASfflC0-.Tu--.V.; GABIDULLIN, VA; POPOV, N.I.; POPOV, N.M.;
STUDENKOVA., N.M.; SMYSLOVA, A.S.; PANIN,-N.S.j red.;PANIN,N.S.,red.;
GERASIMOVA, Ye.S., tekhn.red.
(Methods f~r creating an abundance of agricultural products in
the U.S.S.R.] Puti sozdaniia i~obiliia sal'sk*khoziaiotvannykh
produktov v SSSR. Moskvat Ekonomizdatq 1963. 317 p. (MIRA 16:6)
1. Sektor ekonomichaskikh problem sellskWga khozyay6tva Nauckno-
iosladovatellskago okonomicheakogo inatituta Gosplana SSSR (for
all except Panin,N.S., Panin, N.S., Gernsimova).
(Farm produce)

UFOVLEVA, T. V.
Volkenshteinp M. V Nikitin, V. N. and lakovleval T.V. The reversible isomerism of
dienes., Pages 47i 477.
Inst. of High Molecular Compounds
Acad. of Si. USSR.
SO: Bulletin of the Academy of Sciences, Izvestia, (USSR) Vol. 149 No. 4.
(1950) Series on Physics

YAKOVUVA. T.
Physical Chemistry
.,Dissertation: *Depolarlzation of Lines of the Raman Spectra and zhe
INature of the Pouble C-C Bond.0 Cand Chem Sal, Inat of Bigh molecular
.compounds', Department of Chemical Sciences, Acad Scl Ubk'.'R, Oct-Dec 1953.
(Vestnik Akademii lauk, Moscow, Mar 54)
3016" ~SUX.213, 20 Sept 1954

Evil ----- ----- --

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YAICOVLBVA, T. V.
Spectrum analysis of solutions MrO, N;,.04 1~20. Zbur neorg.
kchim. .2 no,12:?782-2788 D 157. iMMA 11:2)
1. GomAaretvannyy institut prikladnoy khimli,
(711tric acid-Spectra) (Nitroeon oxides-Spectra)

v1j,
or for a Low 1rosJIM:
TITLE: A Current Rc.-,mill,_t--
tc)"u dlya wl~pj liz-"o -0 (~~vluniy"~.)
ca
PB,R!ODIC.4,-T--: r-;ri-borj ii Tclch~~ilrz~, 1957,
AB3pMV'JT 7A-~~ CJ-MU.1-1; Of (20--2-'5 A)
is shozm. ir~ FLr~ 1. 1!, 13 .0w) )14 ~,dl by
r e c 'u- I Zi c, 2., DAY"; - 10 0 - 5 1 - r -I "'l t h -:1 3: .0 J. 7~ L
0., r TIL v,
"Pli c of t h..,- ~t
t ud' c o b h - c; ur r rit -i o
Tlio slide is c-)ntrLAlc,~, by an
".V0 AiU 7 -il
�O
Thorc zil,o 2
I: r a
A330CIATIM:
I'diii-iii)
SUBIMITTED: January 25, 195?.
AVAIIABIE: T,V)T-cry of. Oan-,r-~ss
L
1. Mercur7 Lamps-Current-Control

AUTHORS: Vbvsi, B. A., Sharanin, Yu. A., SOV/156-58-2-33/48
Petrov, A. A.,.Kasliy, L. K., Yakovleva, 2. 7.
TITLE: 'The Action of Pho;phorus Pentachloridits on Vinyl Acetylene
and Isopropenyl Acetylene (Deystviye pyatikhloristogo foa-
fore, na vinilatsetilen i izopropenilateetilen)
PERIODICAL: Nauchnyye doklady vysahey shkoly. Khimiya i khimicheskaya
tekhnologiya, 1958, Nr 2, PP. 335 - 338 (USSR)
ABSTRACT: In previous reports (Refs 1-3) it was proved that the
sequence of the affiliation of various substances to the
vinyl acetylene hydrocarbons depends on the structure
of the latter and on the nature of the affiliated molecules.
It was interesting to compare the results thus obtained
to those concerning the-affiliation of compounds to the
vinyl acetylene hydrocarbons which react tinder a rupture
of the P.-halide-3-bondy above all of the phosphorus
pentachloride. A survey of publications follows. The authors
investigated the affiliation of PC1 5 to th-9 acetylene
mentioned in the title in a benzene- or CCI -medium. The

Card 1/4
reaction is accompanied by
a 1101-Beparation. In the case

The Action of Phosphorus Pentachlorides on.Vinyl sov/156-58-2-33/48
Acetylene and- Isopropenyl Acetylene
of vinyl acetylene exoess'and increased teoperature (350)
the reaction was limited-to the ch1crination of the
hydrocarbon (mostly tetrachlorides we,,e f03?med). At low
temperature phosphorio-producto are fo-.7med., The latter
are rather viscous,oile,which consolidate after longer
storage. They do not contain acetylene groupings, since
they do notiform acetylentdeB With A SilVe3! oxide solution.
Intensive frequencies of the double bonds (approximately
1650 cm-1) occur in.the.infrared spectra of the adducts.
Frequencies of the acetylene- and allene grouping are
lacking (Fig 1). The chlorine atoms connected with phosphorus
are exchanged easily with me-thoxyl groups ~.n the case of a
treatment with alcohol alkalis. The ether formed in this
case are liquids which are easily polymerized if they
are stored and heated. The analysis of the adducts shnwed that
they contain 4 chlorine atoms two of which are connected
with the carbon. The 1,3-diene character of-the investigated
substances made possible OWdetermination unobjectionable
of the position of one of those chlorine atoms. Several
Card 2/4 assumptions are made concerning the second. The chlorine

The Action of Phosphorus Pentachlorides on Vinyl SOY/156-58-2-33/48
Acetylene and Isopropenyl Acetylene
atoms are assumed to substitute to a great extent the
hydrogen atoms in the group GH2-CH-. This isIn agreement
with the fact that the mentioned substance forms in the
case of ozonization considerable quantities of formaldehyde.
The spectrum of the adduct which was obalned from iso-
propenyl acetylene is similar to the above mentioned. Thus
it was explained that PC15 is affiliated in vinyl- and
isopropenyl acetylene only to the acetylene bond. The
affiliation products differt however, from the expected
chlorine anhydrides-of the chlorine alkadiene phosphinia
acids by the presence of an additional chlorine atom the
position of which has not yet been determined. There are
1 figure, 1 table, and 8 references, ihich are Soviet.
ASSOCIATIOIT; Kafedra organicheskoy khimii Leningradukoffo tekhnologicheskogo
~nstituta im.Lensoveta jChair of.'Organic Chemistry of the lanin-
,grad Institute of Technology imeni Lenuovet)
Card 3/4

The Action of Phosphorus Pentach~orides on Vinyl
Acetylene and Isopropenyl Acetylene
SUBMITTED: November 26, 1957
SOV,1156-58-2-3.x/4,9

PETROV, A.A.; POEFIRIYEVA, Yu.I.; TAKOVLEVA, T.V,_;-MINGALEVA, K.S.
Conjugated systems. Part 42: Order of addition of iodine to vinyl
.' acetylene hydrocarbons. Zhur.ob.khim. 28 no.9:2320..2324 S 158.
(MIRA 11-.11)
1. LeningradekLy tekhnologicheskiy institut imeni Lensovets.
(Iodine) (Acetylene)

PASS, L.G.; RODIN, A.F.; SLUTSKIT, A.B.; TOPOROV. P.T.; FnIDXAN, L.G.;
YALIDKAN, D.A.; TUXAMNMT, X.S.; TMOTMA T.T.-, ISAXOT, T.I.,
~J- - ' -
red.; MORSKOY, K.L., red.izd-va; BOROYM. H 11-~'e I red.
Dvganizing machine accounting in the construction industry;
collection of articles] Organizataiia mekharizirovannogo uchata
v stroitelletva; sbornik statei. Moskva, Gos.izd-vo lit-ry po
stroit., arkhit. i stroit.materialam, 1959. 171 P- (MIRA 13:3)
(Machine accounting)

SOV161 -7 -2 -26/34
A%Utms Patrov, A -A. , Yaicovlova, T.V. and Kormer, V.A.
TI TIE i 'Infrarod Spectra of Certain Di-Substitutod Allens, Hydrocarbons
(Infrakrasnyya spektry nekotorykh dvuzameshchonnykh allonovykh
uglevodorodov)
PERIODICALs Optika i spektroskopiya, 1959, Vol 7, Nr 2, pp 267-271 (USSR)
ABSTRACTs The authors obtained the infrared transmission spectra of the following
nine alleness
haptadions-2,3 (curve 1 in a figure on p 268)j
nonadieno-2,3 (curve 2);
7-mothyloctadione-2,3 (curve 3);
6,6-dimethylheptadione-2,3 (curve 4);
octadione-3,4 (curve 5);
nonadions-3,4 (curve 6);
7-inothyloctadions-3,4 (curve 7);
docadione-3,4 (curve 8);
7,7-dimethylocta-diane-3,4 (curve 9).
The frequencies of the nine ccmpounds are listed in a table on pp 269-270.
These hydrocarbons were prepared by reaction of lithium alkyls and
Card 1/2 vinylalkylacatylenes. The spectra -were recorded by moans of an

infrared Spectra of Certain Di--Substituted Allene Hydrocarbong SOV/51-7-2-26/34
IKS-14 spectrophotometer using an N&Cl*priam up to 1800 cm-1 and an
LiF prism for higher vave numbers. The samples were in the form of
layers 0.03 = thick. The most chazacteristic and intense bands
observed in the spectra of all these hydrocarbons more the bands due
to the allans groux.) at 1960-1965 cm-3- and due to rLou-planar deformational
vibrations of the group C--=C-CH-- at 870-875 cm-1. Other absorption
bands are briefly discussed. Thera are 1 figure, 1 table and 4 references,
I of vhIch is Soviet, 1 translation fran English into Russian and 2 French.
SUBW TTEED z February 23, 1959.
Ca rd

is:, J /00
67159
S 07/15 1 -7 -6-20/38
AUTHORS: Petrov..i,.,A, and 'fakovlava. T.V.
dl i
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TITL9i one J
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On the Hy
rogen
y
FERIODICAL., Optika i spaktroskopiya, 1959, Vol 7, No 6, pli 817-81C.) (USSR)
ABSTPACT.- Hydrocarbons with an and acetylene group can readily exchange a hydrogen
atom for a metal, i.e. they behave liko acids (Ref 1). Ono would
expect also that compounds vith an end acetylene group mirht form.
complexes with maines. To chocic this the authors obtained tho Infrared
spectra of certain tortiary acatylani amines with the following general
formula: R.911-(GH2)n-G---CH (n = 1, 2 or 3). The spectra ware recorded
by means of an IKS-14 spectrometer with 1AF and NaCl priams. Some of
them are shown in a figure on p 818 wherei curvas 1-6 reprosent,
respectively: dimethylaminobutyno-3, diethyls.Eriinobutyna-",
diethylafainopentyne-4, piparldinobutyno-110, piporidinopentyna-4,
d1othylaminobuteno-1-butyna-3. The amines wore prepared #YnployinF,
the techniques described earlier (Ref3 4-6). In all ca,6eu tho authors
found a band characteristic of the) valAnce vibrations of the acetylene
kydrogen (3300 em-1) as vall a3 a broai 'usnd at 3210 cm--l (ef - fiVir5
on p 616, curves 1-5). The latter band la ascribed to the valan~*
Card 1/2 q,-,

67159
On the Hydrogen Boxyd in x'scet,ylqna .-U 1; 1 1110 5
'Vibrations of the acetyleno hydrotor- forTaing a hydrogen, bond wiul
nitrogen of the a;aino 'roup:
IT/R
H C=-- C---~G- (CH2) n-NR,~.
-C-0YI12)n--
%R
Dioplacea.,ont of the 3210 C!2-1 band -in Aretylon,, wftino.-, (w!lourt.lng to
90 am-1) is of the same order a-, that kno-An to b6 d4, to hydrogen-bcnd
formation in pri=ry and secondary saturate! a~ulnes (Ref 2)~ Th*
displacemeat Is larror In :soltztlona of tertirry butyl acetyleno Unj
1, rn
vinyl acetylene in triethyl amino (125 and 140 C'M .5partPfaly)~ 0111Y
a small proportion of the amine moleculas ftk,,,-z 1,9.rt In forvatio-I Cf
hydrcgon bonds since t1ho) r-ps3ctra a1ways izie3udej an intonse undisFlaco,3
band due to the va-leace CII-vibeationa of , frees 5oup. 11"ydro7,-3n
bond fornution wx6 also obaor-iewl botavoon of' ccrtiln oth~ir
acot5lene coulpouniiii with an on?, acotylono greup, o.e;, 1%, -71Lyl acotyinut
ketones and b#,,t,.,je5n molecul,)s of waino-alcohols, aurch a--~ otha=1
di-thylamine, 11r, evidence of the H-bond formution was fauni ir the Fpectr;,t
of propar5yl -,;LIdohydo and bvitynone, There are 1 fjg'.-IrC Mid 6
card 2/,2 -1 of which P-ro ~ovloi,, 1 ~,nd 1 ti-.n5latior.
SUBLITTI-M; April 14, 1959

7(3)10' 5M, 24M SOVY48-23-10-17/.')
AUTHORS: Petrov, A. A., Yakovleva~ T. V,
TITLE: Infrared Spectra and the Struoture of the P-roduota of th-3 Telo-
merization of Diene Hydrocarbons With Halogen Dorivativ'.-~,,'
PERIODICAL: Izvestiya Akademii nauk SSSR. Seriya fizicheskaya~, 19159,
Vol 23~ Nr 10; pp 1217-1218 (USSR)
ABSTRACT: The authors had'already previously found that diene-hydrocarbons]
react easily with halogen derivatives in the presence of Sn-.
Ti-, Zn?-, Fe- and other metal chlorides. This results in 1,2-
and 1,4 products, the structural determination of whioh meets
with certain difficulties. For the structural determination of
these telmors the authors used infrared spectra in that t1ley
determined the intensity of the bands of -ialence 'r!"
of short bonds, the corresponding deformation oacilinL,.iori L'ando
within the range' 800-1COO am -1 p and the valence oncilla-ion
bands (-C-H, 3030 Cm-1 or the harmonic vibrati3n with Pbout
6100 cm dW1 ). Inthe simplest cas-e two productij of the composition
C8H13 C1:were obtained in the telomerization of divinyl with
Card 1/2 its hydrochlorides, the st-ructure of which could be determined

SOV/48-23-10-17/39
Infrared Spectra and the Structure of the Products of the TelonErizatior, of
Diane Hydrocarbons With Halogen Derivatives
,as amounting to CH,-CH=CH-CH 2- on 2- CHCl-CH-CH2and
.10
CH 3- CH=CH-CH 2- CH 2- CH=CH-CH 2- Cl. In some cases, e.g. in the
telowerization of 2-chloropentene-3 with isoprene, pipE:-vls, and
chloroprene, 1j4-adducta ware obtained (yield 85-90%). In thr23c,
only the -CH=CH-groups could be distinctly identified. By means
of infrared spectroscopy the problem of the practical iden~i-
fication of telomers produced from allyl-isomers could be
solved; also in the analysis of telomer mixtures success could
be attained by the application of this method. There are
5 Soviet references.

24M, 5M, 7(3) SOV/48-23-10-21/,29
AUTHORS: Petrov, A. A.v Yakovleva.,,T" V
TITLE: The Infrared Spectra and the Structure of the Adlition Com-
pounds of Various Substances to Vinyl Acetylene Hydrocarbons
PERIODICAL: Izvestiya Akademii nauk SSSR* Seriya fizicheakayal 1959,
Vol 23, Nr 10p pp 1226-1227 (USSR)
ABSTRACT: Petrov et al. in a number of earlier papers already dealt with
investigations of addition reactions to vinyl acetylene hydro-
carbons in eleotrophiliet nucleophilic, and radical reagents
(Refs 1-8). The addition compounds were 1,3-diene-, acetylene-,
and allene-compoun-lo. They all had very characteristic bands
in the infrared spectrum: 1600 am-1, 2100 or 2200 cm-1 and
1960 cm-1. For the determination of structure, above all the
valence- and deformation vibrations of the CH group were used.
The addition reaction of bromine to non-substituted vinyl
acetylene furnished two addition compounds: one low-boiling
(1558 and 1621 cm-1 and 928 and 969 cm-') and one high-boiling
one (1960 cm-1). The structures of the two latter could be de-
termined as being CHBr=CBr-CH=CH2 and CHBr-C-CH-CH 2Br, a result
Card 1/2 that was confirmed by chemical methods. Also small quantities

BOV/48-23-10-21/39
The' Infrared Spectra and the Structure of the Addition Compounds of Various
Substanegs to Vinyl Acetylene Hydrocarbons
of the third possible isomer (3300 cm were founij which has
the structure CIF-C-CHBr-CH2Br. The addition of bromine in vinyl-
alkyl acetylene gave R-C-BiC-CHBr-CH2Br and R-CHBr-CH-C-CEBr. In
the following some further results obtained by earlier investi-
gations (Refs 4,6,7,8) are briefly discussed. Structures with
acetylene groups at their ends may b9 determined with particular
reliability by means of infrared speotra, because within the
range of CH-valence vibrations of this group (3300-cm- 1) no
other frequencies are found; an iderv.:ification of allene com-
pounds according to the frequency 1960 cm-1 is, however, very
difficult. Determination of 1,3-dieno compounds according to
the frequencies in the range of. 1..640-1720 cm-1 is also dif-
ficult because in this range there lie also the compounds which
arc characteristic of some,acelylene compounds. There are
10 Soviet references.
Card,2/2

COV/79-29- 2-20/71
'LUTHORS; Petrov, A. I.; Ballyan, Kh. Y., Yheruze, Yu. I. , Shvartg, Y,~. Yu~,

TITLE: On the question of the Structure of Citral, Obtained From the
Synthetic Geranyl Chloride (K voproau o stroyen'Li taitralya,
poluchennogo iz sintoticheskogo geranilkhlorida)
PERIODICAL: Zhurnal obshchey khimii, 1959, Vol 29, Hr 2, pp 445-450 (USSR)
ABSTRACT: In connection with the systematic investigations begun in their
laboratories in the field of teloraerization of diene hydro-
carbons Yrith halogen derivatives (Refs 1-3), K. V. Leets,
A. K. Shumeyko and collabor,,,tors achieved the oynthes.'s of
citral from t~soprene (Ref 4)~ The question arose obviously,
whether this citral differs from natural samples and especially
from citral, commercially obtained from coriander ol.l. According
to data _=W.ned in pUbliCUtiOnI3 (Refs 5-7) natural oitral
chiefly consitits of Pitral