SCIENTIFIC ABSTRACT YAKUBOVICH, A. YA. - YAKUBOVICH, I. A.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962010016-5
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 17, 2001
• Sequence Number: 16
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

:,A120,11,21 It, ;~/C~03/0 17/02 7
Aty-PROPS1 Vaknrov, S. P., Bhj;-,)njkJj, V- A~, Ginaburp. *1 A-
Fil,itoy, A, S., Ynrtjn~;-,ii, L. I,
V,, Golovnnt:vi, A. F., ond. YO~ubuvich, A. Tn.
TITLEt Roaetlorv~ of polyfluorinated nitrot;o-n1krinni vith unnoturatod
'compounds
PERIODICLU Akademiya nauk 335R. Doklndy, Y~ 142, vo. 3, 1,)62, 596 - 5))
TEXTs Trifluoronttrono methane In Lapel no tizi exmnpl-, of nonf, riqr.!i,3nn of
polyfluarinoted nitroao-ilkanes with unsaturated ronpoundq, lh,~nn -idditttn
reactiona take plac*t Pasily (in an autriclove fit -70 to ODC). 14.ini~v,-rn %nd
polymors contnining I mole or nttrooo rompound. j,~,r olefin nole. fcrli.
Styreno and trifldoronitro3o methane alao forra a compound vith thq
ratio I 1 2 which decomposes Into I mole of nitrono compnt.n,l,
and the corresponding imino when hented to '10 0100C. Thoir-for., it
the Btruaturv C 11 C11- 92 Trifluoronitrono methano td,.a to dir-henyl
6 51 f
CF a
0 H-Ce
Card 3

lb 1 '027
Reactions or polyfluorInated- B106/1MO
ketone even more easily under Lite foru-ition of (C H )2C-CO wh 101
6
O-NC?
d
ecompouea when heated to JOOQ(; milnly forming. trifluoromOltyl isoayanate
BP. 330C, yield 35~) and trace3 of,trifl,ioronitrago n(:thnn,.,. Thn latter
also reacto with R FC~_CX alkines (X Cl, Br; it CF3t Cr WCl, CFC12) at
room temperature In an autoclave. 14,F forma on herttlitF frifluoro-
3
nitrone methane with azodicarbonia said eaters to too - IiOOI,
under
pressure. Diazomothano and trifluoranitrono mothene renct at -700C to
give a polymeric nitron (CF 3U(O)Cll~jn un,ler nitrogon naparation.
Phouphnzinen and trifluoronitrouo mrt~anc rvart violintly At 700C
following the scheme (C 6if 5)3?'=l'_lf-_J"ll2 f CF31"O -)ell20
+ k'C 12 _Y(C It ) P-I;CF Tito product of thin reaction
I t 6 1 3 _:L___ ~6 5 3 3'
also forma from trlph"nyl phosphin" nod trifluorompthyl itzid" under the
same conditions Trifluoronitroso miAlinno anl Dinthyt io)-jinitto ro4l7t
C
A.

Reactioun of polyfludrinatod...
vigorously when heated to 25'C in tin nutoPlave to form -11;CP 5. Which-
decomponea into trifluartnated dimethyl carbodiinido and Licthyl
inocyannte whiAn heated to 550 - 40000 In vacua. Theac re).i(tionn de'ron-
Strate the pre-it tondcncy-n~ thr 11.0 groupf) of trifluoronProan mnthnnn
to addition renctionn rith nucloophilic and elootrophilto nompoundn, For
comparison, some additions similar to the above rertations il:rn conducted
with polyfluorInated r( zomethinams CF 11_rv, (11P. -330C) ant Cr3N-CFG1
(Bp. -500). In nll casea, the additivity of the C.11 groupi of theor com-
pounds woo much lower. on reaction of CY 3If-CP2ivlth diphenyl keteno
(nutoolnvod'for 12 hre at 10000), not addition, but dimerizittion of the
initial substance took place. The dimer also formed in a]-iont quantitative
yields by reaction between CP 311-CF2 and pyridine at -70 - 500C. With
aniline, the dimer orinvorts Into the antlide of the monomvr, when aub-
jectlod to pyrolysis (>50000) It dinnoointon into the monomer (Cr 5N-Cpd.
Unlike the polyfluorinated szomethinco above, difluaro fo.-mimine easily
Card 3/6

4R;MIW IFM~
5/02qJ62/142,1003/017/027
B106/B1 I()
polyfluicirinstOd-
ReaCtiong of H ) GcO-2CF2"'1.
it (CIS 5 2
form the adduc
,to with diph anyl kotono to chlorid6i end scrourto
re n flu~rjijnt hy
with hydroilc
Addition reactio
th
Uoride folIO"Ing, a-
Pf
m0, 10 (7
Us,
in queatiOn-
ited o7lomOthin" a to adition
the polyfluorilif an
chvirricturistiO for tea oubatencos with double bol
Ciro very ollowal far th-
Me todunny or polyriuorina, decrea"VO a13 f eynt
q I t1jorofor, of the COVIPOund"
i t holeCins conotaint' at nnd a non-
Tabl, i nhosO the Phy"001 a and 12 reforoncc-. 4 Sov',ag, Vublicitions
ftere are I tabl ' to Frigil6h-1,08 11
fir,L timO- T' it refevencco Cheri. Soc., 1959t
Soviet. The throo moot recCr eldind, Froc-
followel F. F. Griffin B. H, 11"a Uaosoldinot I Chem- Soo-$
'jig6o)-
read a 11551 c E Griffin, 11- N 145, 26,
860, M
3691 19 Grawfordp ;OIYM. sci.9
jg6o, 13981
card 4/6

f K,
:j/o?o/6:1/'42/oo3/01?/027
B106/B I to
ctiong Of,pollfluorinated,
Rea
Academician
pjjE~rFIITFDi june j, 1561j by M. Kaboohnik,
SUBMITTEDs may 5o, iq6i
Tabie 1. Compounds syntheatz-A for the first title.
Lc ondi (a) Com d (b) ~p Qp.), Oc/rm, (c) dotermineill %I
10,101 FP, k P;n-419tIllnbl-9 yellov, all I v4 molecular -
(al calculated, %,
weight (in noetio A014) idetermined 560, onicut4ted ror Lit pontamer 565,
Card 514

SUIRNOY, X. M.; - GINSURG., , T, A.; , YAPMOVICH v A. Ya. ,
.-I C--~Vw
Reaction of fluoroacetjrlene vith mercury, salts@ Zhur. VKHO 8
no.21231-232 '63. (XMA 1614)
(Acet.rlene) (Mercury, salts)

yAKnOVICH, A.Ya.; SMTWV, N-I.; LEBEDEVA, I.v.; YAKI[BOVICHj V.S.
I itriled. Zhur-ne"Ohimo
Now method of Bynthesis of polyphosphon (MIRA 160)
8 no.2:534 F -163. .
1. Fiziko-441~cheskiy institut imeni L.YR.Karpova.
(Phosphonitrile chlo-Ao)

and IT formuUm~
ASS=ATIONs nwao

SUBMrTm.1 l6seP62 23A',63 , 00
INCL
s
SUB OMES CH
so mw SIM 001
CTHERo 010

. . . . . . ..........

ZAYTSEVA, Ye. L.; BRAZ, G. I.; YAKUBOVICH, A. Ya.; BAZOV, V. P.
Syntheses in the Berieo of 1,,3.,5-triazine. Part 2.' Arepam-
tion of mixed 2,4,6-trialkyl-1,3,5-triazines from imino ethers.
Zhur. ob. khim. 33 no.13199-202 163. (MIRA 16il)
1. Fiziko-khimicheskiy institut imeni, L. Ya. Karpova.
(Triazine) (Ethers)

BRAZ, G.I.; MYASNIYOVA, G.V.; YAKU13OVICII, A.Ya.; BAZOV., V.P.;
SAKODYNSKIY, K.I.
Simultaneous trimerization of acetonitrile and trichloroacetonitrile.
Zhur.ob.khlm. 33 no.6:1939-1941 Jo 163. (MIRA 160)
4 .
1. Fiziko4~chsskiy institut imeni. L.Ya.Kar-pova.
(Acetonitrile) (Polymerination)

4611F,73 .;i~ t~!. "A Y ~? ! ~ ~~, .
. -1 '~t
SHVETSOV, N.I.; ITUIUDZIIANYAN, K.A.; YAKUBOVICII, A,Ya.; .SUKIIOVt F.F.
Chemistry of phosphazenes. Derivatives of 21~96j6-tetra-';-dl-
methylaminocyclotriphosphonitrile. Zhur.ob.k.Um. 33 no.12:3936-
3941 D 163. (MIRA 17:3)
1. Fiziko-khimicheskiy institut imeni Karpova.
0

4, bh563
S102 63/148/001/024/032
B i o.6yB i s6
0.
AUTHORS: Motearev, G. V.,_Yakubovich, Ai Ya.,, Rozenbergj V. R.
TITLE: Production and properties of hexachloro cyclohexyl
chloroeilanes
PERIODICAL. Akademiya nauk SSSR.. Doklady, v. 148, no. 1, 1963, 116-117
TEXT: The addition 6f chlorine to phenyl trichlorosil.ane (I) and phenyl
Under the
methyl dichloro'silanq (II) was studied for the first time.
action of chlorine at O-2*C in diffuse daylight, both compounds yield
ixcliiaively the addition products hexachloro c clohexZrl trichlorosilane
~MI)f(20.9~.' yield) and hexachloro cyclobexyi(Ymetbyl) dichlorovilane (IV)
0.41' yield). Ultraviolet light considerably increa:3ea yield and
N
renctio'n rate. The yield of addition products decrea3es with incren sing
reaction temperature, nnd aubatitution occurs. Substitution occurs
exclusively at 1200C (compound I) and 500C (compound II). Additive.
chlorination of aromatic chlorosilanee, eopedially of compound IIJ,
roceeds much more readily,than chlorination of benzene. This in
p
explained by the-fact that the el'ectrophilic silyl chloride group dis-
turbo the symmetry of the n-&Iectron cloud of the benzene ring, and
Card 1/3

S102 6",/148/001/0,-4/032
6ya 1
Production and properties of BIO c;6
deactivates the phenyl radical for substitution reactions. Compouni II,
the silicon atom of which is leas electrophilic, undergoes additive
chlorination more readily than compound I. Therefore, there is a
relationship between the electrophilic effect of the substituents and
the rate of additive chlorination of substituted aromatic compounds.
Compounds III and IV are colorless, viscous liquids which fume slightly
in air, are soluble in organic solvents, and crystallize when standing
for-a long time (m.p. 90-93 OC). Their wide bo'iling ranges (Table 1) are
due to the existence of stereoisomeric mixtures. Unddr the action of
water, they are hydrolyzed to siloxanea; in lyes, the hexachloro
cyclohexyl radical is split'off, and goes over into triohlorobenzene
with separation of hydrogen chloride. III and IV react with ethanol to
give hexacbloro cyclohexyl ethoxy silanes (Table 1). Taere Is 1 table.
-PRESENTED: April 12, 1962, by 1. L. Knunyants, Academician
SUBMITTED: April 4, 1962
Card 2/3

GINSBURGP V.A.; WASOVAP Ye,S.; VASILIYEVA, M.N.j MIRZABEKOVAO N.S,.;
MAKAROV, S.Pq SHCHEXOTIKIfIN, A.I.; -YA,K-.UBOVICH, A.Ya.
Photoreaction of hemafluoroazomethane with unsaturated compounds.
Dokl.AN SSSR 149 no.1397-99 Mr 163. (KIRA 16:2)
1. Predstavleno akademikom M.I.Kabachnikon.
(kzomethane) (Photochemistry) (Unsaturated compounds)

GINSBURG. V DUBOV, S.S.; MEDVEDEV, A.N.; MRTYNOVA, L.L.; TETELIBAUK, B.I.;
VASILITWA, M.N.; !STTOIIM,,A.Ya!~n:'
Structure of the inclusion complexes of trifluo-onitrosomethane with
unsaturated compounds and the mechanism of thei-.~ formation. Dokl.
AN SSSR 152 no.5glIO4-1107 0 163. NJRA 16:12)
L Predstavleno akaderaikom I.L.Knunyantsom.

ACCESSION Us AP4037281 S/0190/64/006/005/0838/A2
AUTTIORst Yakubovich. A. Yao; Rozantseirp Go Go; BraZq Go lei Bazovj V* Po
TITLEs Fluorinated polybenzimidazoles
OURCE: Vy*vokomolekulyarn" soyedineniyap ve 6,, nos 5a 19649 638-842
,TOPIC TAGSj polybenzimidazole,, fluorinated polybenzimidazolo,, diaminobenzidine
~perfluoroglutarate.polycondensationg diaminobenzidine dipherVrl perfluoroglut-aratoo
polyperfluorotrimethylenedibemimidazole
ABSTRACT: Low-molecular poly-2,21-(perfluorotrimethvlene)-5,51-dibenzimidazole
(PPD) was synthesized by meltir4,- 0-5 gm 301-diaminobenzidiry) with 0*92 gm
diphenylperrluorogluturate at 160C in an atmosphere of argon, Within 30 minutes
'the temperature was raised to 19OCj and the heating was contLnued for another 30
minutes at 1*5 m pressureo After grinding tho reaction mav;i to a powder the
heating was continued for 3 hours at the same pressure, with the temperature
gradually increased to 220G, This procedure yielded polymer I@ Polymer T1 wair ob-~
tained by allowing the process to run the last three hours at 190G and 093 mm
pressure, When the last stage was continued for hours at 190G and 0*04 pressure#
Card 3-/2

ACCESSION NR: AP4037281
;the resulting compound was labeled polymer III. The yield or polymers Is 1-1, and
III averaged 59%. They were dissolved in m-cresol from which they were procipita-,
by etherv The products were then analyzed and studied by infrared spectroscoFV.
ific v::3cosities of 0.2% oolutiorw of polymers I and III in cresol were round
Spec
;to be 0.0.35 and 0-055 respectively# while polymor II did not show any noticeable I
!viscosity. 11oating at 220-230C in an atmosphere of argon brought about the
,decomposition of the PPD polymer,, with the liberation or fluorine. Orig. art. hass!
:2 tablesj 2 fomulasj and 1 charte
'IASS6GIATION:
Fiziko-khimicheakiy inatitut in. Ls The Karpoya (Physicochemical
!Institute)
iSUBMITTED3 03jun631 DATE ACQs 09Jun64 ENCM 00
SUB COM ;a NO. W SOVI -003.- OTHERs 004
-1 Card, 2/2

KARAPETIYAN, S.S.; YAKUBOVI-"Il, A.Ya.; WUNYANTS, I.L.
.....
Polyesters and mixed polyesters of 2j2-bis-(4,-h)-droxyphe-nyl) ~exa-
. fluoropj~opane and aromatic dicarbo-Aylic acids. Vysokon.aoeed. 6 no.
9:15~~1554 S 164- 1 (MIRA 17:10)

CHELOBOVY F.N.; DUBOV, S.S.; TIKHOMIROV, M.V.; GITELI, P.O.; YAKUBOVICH, A.Ya.
Ionization and di4sociation during an alactroni Impact of dL-fluoro
nitriles with a groving alkyl chain. Zhur.ob.khim. 34 no.2:571-575
F 164. r (MIRA 170)
4

M
z-
2
P
1 7.1 1__r_ f=--,P0
f-" 1.
NR:
ACOM10,14,
~y
OrIch
AUT-11OR! Karopety~
tars, 6d mixed polyeswrs a'
'Irstav
djC=bWUc; acids
and k .- ~ ';' M64
arc
- )r - - .. . .- 4 1550.
i 9 196
Vo
diliw
YaCL add,
so
Ster, nAxed polyester, coiPolyrhertz P.I.Osior meclialacal
TOPICTAGS; P61ye Orrapane
I-- widt ~ydrwwpheuylkwxa- ulor
a b~nl_ie -- 11 ~ __ - .
[property hen OtIMP
Ti
so
-act
sfor -Of 1 i 74 1" IMPact tou
The homo- or mixed 6 Ljor. telup.
i' A W-3TRACT. farn1l. 2GIC.. destMO . ft CT_ . (-. - D
auc actuAS011---w -0=0- &Av~ . mp. .37613-f IM-77FT71-
2) :pr., IC AGSIZi_
M 2-24413 t6rov, M84A and
_jh tCr,5phthvftC_ L-:-Jd ~na w:ih isophth-
r wi Oprop
1 hex BE, , hydr, ny4hex 'Wu&wsFt7- 11, both
p. 379C, imPac aughness 4.
2. teTn 131,
Paot 22-0-22,iC. destr-
"e. - 377 C I tra )act b
L"'r. tf!Tnpj
terd~Aiuni~d;c 1;~ f - 25-22160C, 1,408'-r-
ar-ids (soft- t"T )jjthajj,, Exid'tgoft- t"nT' 2 1 both
propaMS wltj-l b')tk -Pberrfrl propane with .4,,xYPherQ J)propan'O with
uref"'!"t
12.
_jj;pact tougbnefsf,
temps. 3"10C,
cold 1/2
M::i 1 1141-
W14j'A -T - M IS
0
11 741 9 " P i " a. "I;

BAY, L.I.; YAKUBOVICHp A.Ya.; MULER, L.Ie
i
S~ynthesis of oC -substituted st3renes. 2Diur. ob. khim. 34 no.Ut
3690--3697 11 "64 (MIRA 18a1)
I

ZAYISEVA, Ye.L.; YAKUBOVICH, A. Ya.; BRAZ, G.I.j BAZOV, V-P-
Enters of bisimlnopdipic and -terephthalic acids. Zhur. ob.
khIm. 34 non 0.3709-3713 N 164 (MIRA 18:1)
1. Fiziko-khimicheskiy Inatitut imani L. Ya. Kirpova,

0 ~4 ivl~iipil -wily. I' I~Zrr42v~ r-MRMV

YAKUBOVICII, A.Ya.; SERGefL','p A.1).
--l' -.1. , .1 .1
A 0 -d"ifluoroacrylic.acid and Its derivative-s. Zhur.
I olY. kh1m. 35 no.34411-475 Mr 165. (MIRA 18,4)

MOTSAREV , G. V. ; YAK! '4*GVTCII, A.Ya.; POIIOMPdNK(, V.A.; SNEGOVA, A.D.;
I M. - - -
Subtitit-tition chlorination of phenyltrichloroill lane. Zhur. ob. khIm.
35 no.4:756-'157 Ap 165. (MIRA 18: 5)

YANUBOVICH ZAYTSEVA, Ye.L.; DAZOV, V.P.
Synthesis of MioIrinated aliphatic aromatic diketones. Zh-jr. ob.
khim. 35 no.5s848-850 My t65. (MIRA 18:6)
1, Fiziko-khlmichenkly institut Imeni Karpova, Moskva.
. Ii 17 -~ V i~~, ~111

rj.'N.qbfJR'j,, V.A,; Mt-PTYN'OVA, L.1 .-, DCRIV, TE.'1141110M, B.T.;
y
YPFUBC,'V'.'CH, A,Ya.
- , --- - -111
1 1.
';truc4-nre of adducts of trifliic~rcnitreiio ric-ts-sne With unsat-uraved.
corq,our.do. Znhurz. ob. )rhlm. 35 no.5-,851-857 Itj 165.
(M!RA 1846)

WiTFAREV, G.V.;, 'IAKI'J',WVICH, A.Ya.
. I z I:-, j- - ~
Halogenation of a,romatle allanes. Part 16: Cartain featurea of
the reaction of phenyltrichlorosilane with Jodine chlorides.
Zhur. ob. khim. 35 noo6,.,,1056-1057 Je 165. (MITRA 18:6)
1

ENGLIN, M.A.; XAfU~BOVICHDUA.Ya,.; MAKAROV, S.P.; NIKD'OROVA, T.Ya.;
LYSENKO, V.V.; DU S.S.
Heterogeneous fluorination with 'elementary fluorine. Part 7t
Fluorination of hydrochlorides of aliphatic amines. Zhur. ob.
khim. 35 no.71ll67-1171 '71 165. (MIRA 18:8)

MDTSAREV, G.V.;_jVM.UQH,-.A.,Ya,; ROZENBFRG, V.R.; FILIPPOV, M.T.;
DZHAGATSPANY AN,' R.V.; BARDENSHTEYN, S.B.; KOLBASOV, V.I.;
ZETKIN, V.I.
Halogenation of ar~omatic silanes. Part 17: Additign of chlorine
to phenyl-4richlorosildne. Preparation of hexaohlorocycloh".yl-
trichlorosilane and the mechanism of its fonna.tion. Zhur. ob.
khim. 35 no.7;1178-1183 J1 165. (MIPA 18:8)

ENGLIN# M.A.; MAKAROV, S.P.; DUBOV, S.S.; YAKUN)VICH, A.Ya.
Heterogtneous fluorination by elementar
y fluorine. Part 5:
Fluorination of silver and potassium thiocyanaten. Zhur,
kbim. 35 no.81l,412-1415 Ag 165.
Heterogeneous fluorination ty elementary fluorine. Part 61
Fluorination of cyAnuric Ohloride, 1W.-A416-1418
(MIRA 180)

G' lt: ~ " ~
V.A.; L ~~ , , - f, -
Electrrm
~Jechanifim w
ri
Ob. klilm. ~
WIRA

YAKUBOVII-11 A VEA i"V J~ P
Synthesis of 1-4 o~-xa f 1u oz-r,,d
thyInitrogen oxide. Dok-',.
1. Siubmitted December 8,
mf~- t hy Ihy- ne
IN, -1~3.SR If'.'O
T
J, r~
1964.
m

YAKUBIOIJICII, A.Ya.; SFRGEYEV, A.P.; EFLYAYF.VA) I.N.
Direct fluorovinliaUon. Dokl. AN SSSIR 161 no.6:1362-136,1. An) 165.
~M7:, I
1. Submitted October 26, 1964. 1 -~. I-R;5)

it 63~5-61-0T- - 6-- 0-67 -1
J)/r 6 066/ 2276
~CNRM SOURCE COM U7 6 Z6~6
(A~
I
AUTHORSi Yakubovich, V. S,; Lebe-deva., 1, V, ~akubo-.Ich, L, _Yas j Shvetsov.N. 11
ORG: none ey C?
TITLE: A mothod for obtaining polyphoophonitryl chlo idesl Class 39J No, 176412
Ca,nuounced by Scientific Research Physicochemical Institute iffie L9 Yas Karpov
N chno-issledovateliskiy fiziko-khimichuskiy instiLut
SOURCE: Byul-letesn' izobreteniy i tovarnykh znakov, no. 22, 1955, 6o
7XVIC, IZA033 phosphorus compound) pul3rmer, polycondariantion
ABSTRAM This Author Certificate presci%3 a method for obtaining polyphosphonitryl
h1orides based on phouphonitryl chlorides. To produce a thermally stable awl uniform
polymer of a high molecular wuight~ monohydroxy derivatives of polychlorophosphazine-
phosphohydroxy dichlorides or their doil.vativwj such as alkoxy dorivativosp arc used
as phosphonitryl chlorides. These substances are subjected to polycondenuation.
SUB CODES 07/ SUB14 DATEs 25Feb63
UDGI 678-745-3173

L 15326-66 EwT(M)/EWP~j)/T/wC(M)-6
ACC NRI AP6000990 -TAT --C`6DE':- -576 ~16 566/ 22[6661165~ii
Shvetgov
AUTHOM, Yakubovioll, V. S.; ljghodRXIL~l. jakubovich,
Al
ORG t none
TITLEs A method for obtaining 0l phosphonitrile chlorides.! G:i.aos 39, ko. IL6416'
~a 0 cod by Scientific Rooearoh Phynico-Chomical Inntituto im, L. Ya. Karp9j,
fiziko-khimichoBkJv inst!G-T
SOURCE:' Byulloten, izo
,),;woteniy J tovarnykh znnkov, no. 22, 196,,,, 61
TOPIC.TAGSj Polne polycondensation, organic phonphorus compound, phoophonitrile,
monomer
ABSTRACT: This Author Certif~cate presents a method forlobtainimp, polyphopphonitrile
chlorides by ko lonsatAjo'lof phoophonitrile chlorideitnonomera. To increage the
lycqndL,T j I rN; monomers used are-'chloromorio
variety of thermostable pol_~~e ifiee- I - Or poly(dichloro-
phoophaaen)-phosphooxide dichlorides or mlko3WI derivatives of iba lattijr.
SUBCODE.: 1l/ SUBM DATE: 25Feb63
0Y,
TTW.. 47A -'7AC X #171

MOMA REV G. V. - ()VICH, kaft.; V.A.; A.D.,
3 -,--X~KUB -, In - i G A
TVA,','OV,',, T.M.
Substitution chlorinatIon of pheanyltrichlorosilane. Zhur.ob,khir-
35 no.Pi2167-2176 D 165, (MTRA 39;1)
1. Submitted July 8, 1964.

42:66 EnW/EWP(J)/T VdIX-417.4.
NRt AP60063131 ~bu= CODE: UR/0413/66/000/002/0027/0027
INVENTOR: Yakubovich, A. Ya.; Gitellj Po Oo; Solovovag Ov P*
K
ri.9i none If%
TITLE: Preparative method for.fluoroaromatic c
No. 177886 Cla3s 12,
SOURCE: Izobreteniya, promyshlennyye obraztsy, tovarnyye z3aki, -no. 2, 1966, -27
TOPIC TAGS:, phosphorus compoundt nitrogen compound, fluori-ae compound, fluorinated
organic compound.
.-ABSTRACT; An.Author Certificate has been issued for a preparative method for fluoro-
aromatic cyclophosphonitrilates. The method involves the r,eaction of sodium or potas,
sium fluorophenolate with phonphonitrile chloride on heating in an inert solvent,
such as tetrahydrofuran. ISH]
UB CODE: 07/ SUBM DATEi 29Oct64/ ATD PRESS:
-558oloO7.
Cuid iji~ UDC: 5470

12926-66,
ALA-1, NKj AP6006981 rAr) 50(iRCE Mgt (JR/0190/66/008/002/0272/0277
AUTHOR: Braz, G. I Kardash, 1. Ye.; Yakubovich, V. S.; My G. V.;
psnikova
,Ardashnikov, A. Ya., Oleyn1k, A. F.; Pravednikov, A. N.; Yakuborich A. Y&.
ORG; Physical Chemistry Institute im. L. Ya. Karpov (Fiziko-kh,i.imi7cheaki~vy~inistitut)
101' '%.
TITLE: Polybenzoxazoles: preparation and thermal degradationR4
SOURCE: Vysokomolckulyarnyye soyedineniya, v. 8, no. 2, 1966, 272-277
SOIL*
TOM TAGSt host resistant polymer, polyoxamlde, polybenzoxa
ABSTRACT: New high-thermal-atabilit polybenzoxazoles have been prepared which
withstand temperatures up to_52Om__-_-_53 C in vacuum. Polyoxamidel:.ntermediate products.
(1, a-e) were prepared by low-temperature (1%, OC) polycondensaf-on of 3, 3'-dihydro:qp-
benzidine with isophthaloyl,-terephthaloyl, 2,5-furandicarbon,pl, 3,5-pyridine.
dicarbonyl, and fumacyl chlorides in dimethylacetamide. The polyoxamLdea were con-
verted to the polybenzoxazoles (11, a-e) by thermal cyclodehydration. In addition,
polycondensation of bis(4-hydroxy-3-aminophenyl) sulfone with iiiophthloyl chloride
proditcedpclyoxamide 117 which was converted to polybenzoxazole IV.

ACC NRg AP6006981
no on
0
0
A-I-: -10
where a').*
relf-cm-
Ito
Oil
0 0-
MH
[H
60.
01
IV
All the polyoxasides except III were colored materials, and all were vol'iblg In
cone. H2SO 4 and in some amide solvents. Polybensoxasoles Ila and Ilb are solubl
in conc. 11.804 and insoluble in amide. solvents, even in the prusence of UClj
II c-e are Insoluble in conc. H2SO4, apparently owing to.cross--linking. The po: Y-
Card 2/3

AP6006981
benzoxazoles show bright luminescence. Structures were confirmed by IR spectro-
Orig, art. has: 3 tables, 3 figures, and 4 formu-
scopy and elemental analyzing, ism)
lag.
SUB CODEI 1l/ SUBM DATE: 13Mar6,5/ ORIG REF: 001/ OU REN 009/ ATD PRESS:

At-k- NKi 6019549 (A SOURCE CODE: - UR/O.'LgO/66/008/006/1137/1137
AUTHOR: Yakubovich, A. Ya.; Gitina, R. H.
ORG: none.
TITLE: Preparati .on of fluorinated polyamideslby low temperattirelpolycondensation?in
amide solvents
SOURCE: Vysokomolekulyarnyye soyedineniya, v. 8, no. 6, 1966, 1137
TOPIC TAGS: polyamide, fluorinated organic compound, polycondensation, polymerization'
kinetics
ABSTRACT: Preparation of polyfluoroglutamides by reacting dichloroglutanides of the
perfluoroglutaric acid with 3,31-dioxybenzidine in diamethylacetamide in dry argon at-
mosphere at -100 to OOC is reported. The viscosity of a solution of 0.5 g polymer ifi
100 ml dimethy1fluoroamide at 250C was: (n I ^. 0.10-0.15. The structure of the
log
polyfluoroglutamides was confirmed by IR spectroscopy. The success of this prepara-
tion procedure is explained in terms of the high rate of interaction of the dimethyl-
acetamide solvent with both the starting dichloroanhydride of the perfluoroglutaric
acid and the active terminal chloroanhydride groups of the macromolecules; the latter
interaction leads to chain termination. In order to establish the ratio of the rates I
of growth and cleavage of the polymer molecules, subsequent wrntheses were based on
Car~ 1/2
U DC: 541.64+678.675

L 01039-67
ACC NRi-AP6019549
(1) the less reactive dichloroanhydrides of the iso- and terephthalic acids and (2) th.4
dihydrazide of perfluoroglutaric acid instead of diamide. In this case, the polycon-
densation of an equimolar mixture of the starting components in N-methylpyrrolidone at
OOC led to the previously unreported high molecular fluorinated p`61yFydraz1des-.rj7PC51'V-
-1-isophthalyl-2-perfluoroglutarylhyd--azide and poly-l-terephthalyl-2-perfluorotlu-
tarylhydrazide. The viscosi~j of these polymers in dimethylfomamide is:
In log I = 0.6-0.7.
SUB CODE: 07/ SUBM DATE: OlFeb66/ ORIG REF: 002/ OTH REF: 002
awm
Card 2/2

ACC NRt AP7011030:
SOURCE CODEt UR/C079/66/036?010/1861/1861
AUTHORs Filatoval, 1. M.; Zaytsevs, Ye. L.; Y&kuboYich;.jA-t--Ya.*'-.,.
ORG: Physicoche-vical Institute Imeni L. Yes Karpov (Fittko-khimichoskiy
institut)
TITLE: New type of rearrangement of esters of the phosphazene series
SOURM Zhurnal obahchey khimil, Y, 36, not 109 19669 1861
TOPIC TAGSt aster, organic phosphorus compound, organic nitrogen compound,
Isomerization
SUB CODE: 07
ABSTRACT: The authors succeeded in observing a rearraneement for phosphazenes
gement. It vat; proposed that the nev
differing from the normal phosphazene rearran
rearrangement be called the phoophazenephosphoxide rearrangement. The isomerization
OR III I It, Oil
Ho--V N-~=O
I I k
on
Card 1/2 UDI;t 547.261118
- -------------------------- Z7

ACC NR- AP7011830
was studied for an eater In which R RO x C2H5- T he icomerizatlon could be con-
ducted In both directions; in the pre oration of compound (;.) at temperatures above
850P a mixture of the..eeters M and M) was obtained. ~rjlj* arts hass I formula,
cj-PRSs 4093
Card 2/ 2
Vv:

rX L ~4122-66.- (MVEVNIVT IJP(c) RM
LL NXI AF0025541 SOURCE CODE:
AUZIM: XaMmIch, Al Tae; -gAtell. Pj Oe; Lagutina,, Z. Not, Cholobov" F. He
ORG: none
TIM% Unusual adduat of ronitrosomthanel thylen i w-A
t-r*l-uo .1 totrafluoroi
phosphorus tric1ilorido I
SOURCOs Diurnal obsbohey khimii, vo 36, no* 1, 1966, 163-16~
TOPIC TAGS: phosphorus chloride, chemical coripoundo molecular weight, solvent action
copolymorization, mass spectrum, spectrum analysis
ABS!DIACT: The reaction of 'trifluoronitrosomothane with tetrafliio'roothylone-~
in the presence of phosphorus trichlorido yielded an unusual three-component
adduot with the composition C 2F2'PC'3 -2CF3NO. This adduct 13 thermally
-atable and behaves as an individual compound, with a distinct boiling point
and molecular woight; it dissolves in a number of organic solvents without
change, does not react with oxidizing agents (halogens), and does not
liberate molecular iodine from an acidified solution of KI. It rea'cts
readily with nucloophi3io agents such a .a water, alcohols, anti amines. When
the adduct is treated with methanol in the cold, a product vith composition
.2CF 110-C F P(OCH ) is isolated. The chemical properties o:?.' the adduct
-.3 2 4 3 3
Card 112 UDC

L 34129-66
ACC NR: AP60255U
'contradict theIhypothesis of a radical mechanism of the copalymerizationlof
-CF NO with C?4 in the presence of My supporting the idea of a unique
3
tertaination of th`0 'Copolymerization, occurring at the very baginning of the'
process and accompanied by oxidation of trivalont phosphorus to tho
,pontavalent form. A complete reaction mechanism and structure of tha &dduct
..are proposed. The chemical data on the structure of the adduct are con-
..firmed by the results of mass spectral- measuremonts. fJPRS.- .3~, 998J
SUB COM 07, 20 SUMI DkVst O8ju165 ORIG REF: 001 001 REF: 003
Card 2/2,!2- 0

YA-;TIJB(.',I,"CH, A. Ya.; DZICAM-9, L.N.; GINSFURG, V.A.
Fluorinated p-divinylbenzimes. Zhur. VY110 10 nc. 6:705--X6
t65 (MI-RA 19.1)
1. SlUbnItted April 20, 1965.
I-

wT(m)/EPF(6)/Ewp(j)/D1A(c-) APj-
AWESSION NR: APS020084 _UR/0079/6Si6i5/008 i418/1422
546.161:547,122:547.414.7,
_,TAUTHOR: -Ginsburg, V, A.,. Medvedevs~A. N.; Lebedeva, M..F.;_Dubovj S6 S,;
Ya1mbovich, A. Ya."-/-
TITLE: Electron transfer in nitroso-compound reactions. 1. Mechanism.,.of, tri-
is portionation
fluoranitrosometh2pe
tSOURCE:- Zhtirnal obhskhey,khimli, v. 35, no. 8, 1965, 1418-14'!2
TOPIC TAGS*. electron transition, reaction mechanism, EPR speatrum, organic nitroso
compound, aliphatic fluoronitro compound, methane
-.7.-ABSTRACT., The mechanism of trifluoronitrosomethane dispropoe.-ionation was studied
-in
--vari6us--orgclnic.and-.aqueous alkaline solvents-in.the-tempe,~ature-range from
.:-l200,_to.,200C,,~11A detailed examination of the EPR spectra indIcated that in the ab-
sence of a reducing.agent,,the-first stage-of trifluoronitros,methane dispropor-
tio 'ati
n on -in-an. eous,alkaline solution 1CF3NO+ (C2HSO)+ 203 aqueous NaO111 is as
0 o0s__~-
F3N-O- CFIN--*
CPSNO,+OH- (1 0 -0FNO + 0-H
-Y"
1/3
- LCFSMq�__iq_

A fI.f
137-58-5-8800
Translation from: Referativnyy zhurnal, Metallurgiya, 1958, Nr 5, p 10 (USSR)
AUTHOR: Yakubovich, A. Ya.
TITLE: Ceramic Rakers for Herreshoff Furnaces (Keramicheskiye greb-
ki dlya pechey Geresgofa)
PERIODICAL: Byul. Tsentr. in-t inform. M-va tsvetn. metallurgii SSSR,
1957, Nr 1, pp 14-16
ABSTRACT: The building-materials laboratory of the Norillsk Kombinat
has developed a design and a manufacturing technology for the
production of ceramic rakers employed in roasting furnaces.
In their design the rakers are characterized by reinforced hori-
zontal surface and a stronger blade. Tae chemical composition
of the ceramic material is given together with the results of tests
performed on the rakers.
A.Sh.
1. Furnaces--Operation 2. Ceramic materials--Applications
Card 1/1

137-58-6-11383
Translation fr6m: Referativnyy zhurnal, Metallurgiya, 19513, Nr 6, p 19 (USSR)
AUTHOR: Yakubovich, A.Ya.
TITLE: Fuel for Shaft Furnaces from By-products of the Coke-chem-
ical Industry (Polucheniye topliva dlya shakhtrtykh pechey iz
otkhodov ko~so-khimicheskogo proizvodstva)
PERIODICAL: Byul. tsvetn. metallurgii, 1957, Nr 11-12, pp 57-59
ABSTRACT: A discussion is offered of methods for briquetting coke
breeze (K) (with tar and a mineral binder - Portland cement)
and the results of production tests of the briquettes (B). The
physical chemical properties of the K are presented, also the
chemical composition and physical mechanical indices of the
Portland cement, the characteristics of the tar, the composi-
tion of the mix going to the preparation of B by pressing with an
organic binder, the results of tests of B strength, of physical
chennical analysis of an average B specimen z.nd of local (Noril'-
sk Kombinat) coke, and also of the composition of the mix, the
physical mechanical indices and physical chernical analyses of
B made with cement binder. It is shown that :he briquetting of
coku-chemical industry wastes may serve as a supplementary
Card 1/ 1 source of supply for industrial shaft furnaces. N. B.
1. Coke--Properties 2. Fuels--Sources

ZATFSEVA, Ye.L.; GITINA, YAKUf3O*,,rlGlf, A.Yu.; IJRAZ, G.I.; PIE"PlIOVA, L.G.;
BAZOV, V.P.
Synthesis and some properties of minoperflu:)ro,-,-arboxylic acid
eaters. Zhur. ob. khim. 34 no.8:2816 Ag 16 -',. (!*.!If?.A 17:9)

BRAZ) G.I.; MYASNIKOVA, B.V.; YAKUBOVICH, A.Ya.; BAZOV, V.P.
Syntheses in the 1,3,5-triazJ-re scries. Fart I.: Carhpethcxy~-
substituted triazines. Zhur. ob. khim. 31, no.9:2980-2987
s 64, (MIRA 17:11)
1. Fiziko-khimicheskiy institut imeni. L.Ya. Kurpova.

ZAYTSEVA, Yc.L.; YAKUBOVICII, A.Ya.; BRAZ, G.I.; DAZOV, V.P.
Synthesis in the 1,3,5-trlazine series. Part -1:
L, ,a-
kyltriazines. Zhur. ob. khim. 34 no.9:2976-29't9 S 164.
(MIRA 17:11)
1. Fiziko-khimicheskiy institut imeni L.Ya. &trpova.

ROZAN'i"hV? (;.(;.; G.J.; YAi(.Ij!;()Vl(Al, t.
0 It Ya.
Phenyl eatc-ni ef perfluoroaliphatic -mcno ard ilicarbcxv2ic
Zhur. ob. khl:n.. 34' nc-).9:2974-2976 -'; t64.
(MIRA 17:11)
1. Ffziko-khJ.mJcheskiy In3titut imeni L.Ya. Karpova.

BANIT, Feofan Gavrilovich; YAKUBOVICH, Boris Isayevich.;
., retsenzent; VYBORlrfY,
VOUIYAJISKIY,
K.H., inzh., rateenzent,- KRIZHANOVSXIY, G.S... inzh.,
retsenzent; ZAYCHIKOVA, E.A., red.; GOLIBERG, T.M.,
tekhn. redi
[Operating, repairing, and assembling equipm)nt In build-
ing materials plants] Ekspluatateiiaj remont I montazh oboru-
dovaniia zavodov stroitollnykh materialov. Moskva., Stroiiz-
dat, 1964. 234 P. (V11RA 17:3)

YAKUDOVICHI B-
pawatka po, ekspluatatsii trelevochnoeo traktora KT-12 (Ijandbook on the use
of the KT-12 skidding tractoi.2 by) IT. V. Yurin i B:.14. Yakubovich. MosIrwa)
Hashgiz, 1951.
142 p. illus-
Cataloged from abstract
FB 520089
SO: 14/5
743.281
A96

1. YMMOVICH, D. Min. Eng.
2. ussR 6oo
)$. Shaft Sinking
7- Sinking a shaft by the method of freezing, Mast. ugl-j Ij No. 101 1952.
9. Monthly List of Russian Accessions, Library of Congres.-i, April 1953, Unel.

Aerosol spraying of paints and varnishes. Mn. nauka i prom. 2
no.3:399 157. (KLRA NO)
1, TSentrallnava nauchno-lealedavatellskaya laboratoriyu Tzesoyar-
noy kontory "lakokraspokrytiye."
I . (Paint)

YA.KUBOVICH, D.SI.; GROZINSKAYA, Z.P.; SANZHAROVSKIYj A.T.; ZUBOV) P.I.
Studying the physicomechanical properties of polyurethan coatings.
Lakokras.matJ ik4 priii. no.6:32-37 162. (MM 16:1)
(Protective coatings-Testing) (Ethyl cartamate)

YAKUB(XICH. D.S.
Physical roceosev occurring during the dryinf and aging of paint
coatings Mom "Official Digesto" 33 no.439, 1961). Lakokrao.mat. i ikb
prim. no.2-M-77 163. (ML~A 1634)
(United Stata--Paint-TestIng)

YAKUBOVICH, D.S.; SANZHAROVSKIY, A.T.; ZUBOV, P.I.
Studying the effect of the copper base structure on the adhesion
to it of polyurethane coatings. Lakokras.-mat. i ikh prim.
no.5:30-33 163. (MIRA 16:11)

YAKUBOVICH, D.V.. inzh.
"In"ektoll".. a new preparation (from "BIO i metau niezelazne,00
no.7, 1961). Shakht. Atroi. 6 no.1003,32 0 162. (WF-A 14:9)
.(Poland-Cement)

KOH011) V.F., inzh.; YAKI-MOVIC-11 -D.V., 'inzh.
r9jA;,
Plueging holes in rock salt at the Solotvin f~j_p
a ~ht. s troi.
8 no.6:24-26 Jo 164. ("d.:IA 17:10)
1. Slolotvirskiy roleru,4jdk (for &'~orop). 2. TsI-Ilgorosusheniye (for
Y.-%,tbovich).

U915
S/191/62/000/011/009/019
Bloi/BiB6
AUTHORS: Li, P. Z., Lukovenko, T. it., Yakubovich, V.-I., Shagova,
E. A., Markovich, V. E.
TITLE: Determination of the linear expansion coeffioient of glass
plastics
PERIODICAL: Plastiche8kiye massy, no. 11,.1962, 36-40
TEXT: The linear expansion coefficient a of a glass textolite from
phenol formaldehyde resin reinforced by 65-70% glass fabric was determined
in the temperature range 20-4000C. The resin 6ombinp-tions of 70% 3A-6
(ED-6) epoxy resin and 30% phenol formaldehyde-resin, phenol formaldehyde
resin with polyvinyl butyral 1:1, or of phdnol formaldehydo~ resin witb
furfural acetone resin 1:1, tested for comparison, showed no essential
difforences. The relative elongation 61/10 of glasa textoliten was not
-found to be a linear function of tompera)ure. a for 30316 resin content
liea near the a for glass fiber (1-15-10-VOC), it approaches that of iron
for 45-55% resin content, and that of aluminum for 711% resin content,
whereas a for pure resin is rvOO,10-010C. Glass tex-,olite shaped in
Card 1/2

S/1 91/62/000/011/009/019
Determination of the linear B101/BI86
vacuo and molded glass textolite differ in that the LI/i 0-versus-tempera-
ture curve for the latter shows irregularities above !OOPC, due to
after-hardening of the resin and loss of volatile components (the loss
in weight being greater than with vacuum-shaped textolite). Therefore
vacuum-shaped glass textolite offers higher heat resistance and
mechanical strength. Glass textolite heated to 3000C and cooled in the
exaiccator ahowed conatant relative elongation owing to the elimination
of moisture. The bending strength of vacuum-shaped glass textolite after
heating to23000C rose by 15,A io 2000 kg/cm2 9 at 3500C by Iqa to
1900 Ikg/cm . The bending strength decreas.-ii above 4000C. There are
6 figures and 3 tables.
Card 2/2

AUTHOR- 1.0
eased 6
14., C0070t6va K. bi~ akubod6,~--
7.
wtis
JZO poxy 0 0 Ili- -:tiedi
glass ~ro aft ed.-.p dat ci--epo"-reo a -a n v ~ak -ri -6--EN a,
rc
t~efj ap, eg
~-usinisl-phlenol!)~4 t" I e'-~restwL4a- ng, agent-:-
V"'A)f

TAKUBOVICg, P.,,propoaav4tall
The "21citude of our party Inspires us. SoV,ProfsoinsY 7
no.91:26 N 059. (KIRA 12:12)
1. BrIgada immunisticheskogo trod& teekha Jk,-3 sayoda
(Turning-Technological Innovationti)

YAKUDOVICII, Fedor Fedorovichl VIURASHEVA, 0.1., red.;KI.IIIINA, Ye.l., tekhn.
reas
[Manufacturing kwass] Proizvodstvo khlebnogo Imatia. Mookval Pi-
shohoprorr,izdat, 1961. 91 p ~Kvass) (MIRA IJ, 111)

SR 0 M
SHAKINI I.A.; jAkUjppy~qp,,Jt~~; ADAMSON, N.F..* otvs za vypusk;
MIKHAYIDVA, G.A., otv. za vyp.; MA"MVA, Ye.S.0 tekhn.
red.
(Malted corn extract) Kukuruzno-solodovyi ekstrakt. Mo-
skva, Tsentr. in-t nauchno-fokhn. informatsii pishchevoi
promyshl., 1963. 20 p. (MIIA 17:3)

--- --------
PROSVETOTA, G.I.; TUKAYEVA, S.A.; YAKUBOVICH, F.S.
Eff ectiveness of homonal preparations in the combined treat,
ment of Botkin's disease. Zdrav. Kazakh. 23 no.2:44-49163.
(MIRA 16:10)
1. Iz kafedry infektsionnykh bolezney Karagandinakogo medi-
tsinsko o instituta.
NPATITIS, IMCTIOU.9) (ADRWOCORTICAL HOIDIMIES)
(ACTII)

AUTHORS: Kondrat I Yev., A?_YAb4M1_Ch_z_i- Engineers SM/84-58-8-27/59
TITLE: The An-10 Hydraulic System (Sarolet An-10 - Gidravlicheakaya sistemr-)
PERIODICAL: Grazhdanskaya aviatsiya, 1958\