SCIENTIFIC ABSTRACT YANOVSKAYA, G.N. - YANOVSKAYA, L.M.

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• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962110015-5
• Release Decision: RIF
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• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 15
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

5/05-1/63/014/001/004/031
E039/E.120
;AUTHORS:
Be.rezins I.A.9 and N.
TITLE: A study of the excitatioxi of iodine in a hollow cathode,
PERIODICAL: Optika i spektroskopiya, v.14, no.1, 1963, 23-28
';TEXT-. The dependence of the intensity of the spectral lines
of iodine on the composition of'the gas sustaining the discharge,*
the gas pressure, the current intensity.and the presence of an
impurity with a lower excitation potential, is investigated. The,
sensitivity for determining iodine in an atmosphere of noon is one
order higher than for argon, while in helium it is two orders
higher than for noon (10 mm Hg gas.pre.ssuie, 250 mA). Standards
containing 101,u iodine were used with A and Ne, and 0.1~~ iodine with
lie. The subsequent measurements were 6arried out in He. At
pressures less than 5 mm and. more than 20 nun the condition 6f the
discharge in the hollow cathode deteriorated, hence the pressure
-over the range
dependence of the iodine lines was determined;,
.7.5 to 17 mm. As the pressure was increased the intensity of tixe-:
majority of the lines either decreased or r~ma'ined constanti only
few increased in intensita 138-19 and 5407-36
1, in particular~5.
Card 1/2
IN
L
3

OEM
S/051/63/Oi4/ool/004/031
-A study of the excitation'-of iodine...
E039/E120
As the current was increasdd, so did the inionsity of all the
lines. 'The majority incrbdsed linearly with the current, but for
Y.:
tile 5338. 19 and 5407.36 X-' lines the intensit ' depended approximately
on the square'of the curri~A.. With increasing concentration of
sodiumi which has a low exclitation potentia-1,;.the intensity of all
the iodine.lines decreasedluniformly. In dadItion, the intensities
of the spectral lines of lddine,.chlorine, bromine and sulphur'in a
hollow cathode-are cosnparbd with line intensities for the same
elements in a Slow dischargd. -The results are explained on the---,-:
basis of_coll-is ion-proc eases.,-
There are 2-figures apd 3 tables.
SUBMITTED:*.November 27, 1961
Card 2/2
24 F-1 4;
VE~

UNOVSKAYA 0. T
lood of copepods and their lary" In the Black Sea. !frudy (iidrobiol.
ob-T& 7:163-172 '56. (KM 10:2)
(Black Sea--Copepoda)

LCATA, E.D.; YAVOVSKATA9 G-Ta-
MOIIDTJEUY-BOLTovSKOY, F.D.; MORDUKUY-BOLTOVS
Rybinsk Reservoir. Trudy Biol, eta, "Borokg
Shore-vater fauna Of (MIRA 11:9)
n0-3:142-194 '58- -water fauna)
(Rybinsk Reservoir-7resh
P
tlz
63 -
3~v
INU
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A
,I*C
A. -7 0 44.30731
Ad 5 mli 4 W= 9.1

yA SKAYA I_L &. ~A usuifonation of N-sub3tittted PYrroles)" vestnik mosk. wl-ta,
Yanovalrayal L. A. - 1948, 1.10. 11, p. 123-31
So: 'U-3566i 15 March 53j (Letopis 'Zhurnal nykh stateyy No. 13, 1949)
:jt, 14 aop
4,
M,
~A
T,

1.rl"111'ry
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l
difi
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YANOVSKAYA-~-L-~o-A-.
t'Sulfonation in the F-Yrrole and Indole Series." Thesis for degree of Cand.
Chemical Sci. Sub. 8 Jun 49.. Moscow order of Lenin State U imeni. Ml. V. Lozonosov.
FDD Swmary 82, 18 Dec 52, Dissertations Presented For Degrees In Science arri
Fngineering in Moscow in 1949. 11-om Vechernyaya, Moskva, Jan-Dec 1949.

Unk/chamistry - Sulfonatica Mir 49
:C
bamistry - PyrrOld
k
E-4
"SUIfonation and SulfoacIds of Acidopho'bic Cam-
3:11, Sulfanation of Pyrrcle and Its
CQ pounds:
ifo Hariologues," A. P. Terentlyev, L. A. Yaacrviffkaya,
lab, of Org Cbem, Hoo cow State U, 5 1/2 pp
"Ebur Obahch Mum" Vol =, So 3
PrOpared pyrrole-2-sulfonic acid,, 1-metb71pMole
2-julftaitc- acid, 2-metbylpyrrole-5-sulfcialc acid
2 4-4I=tby1py=ole-5 -gulf onic acid, an& I-o-
Z41pyrrole-2-sulfonic acid by sulfonation, of
Wvrole and Its h- logues by pyridlne-sulr=
62/4W14
UM/C~smietry - Sulfonatica (Contd) mgr,49~~
ta4oxifle in a dichloroetbane solution. Eveh:at
15P9 C, 215-d*tbylpy=ole was not sulfonatad.
Su'=Itted 3 Nov 47.
62/49TJ~'

.I; J
e--'i r, try Fy-.r--Ic Jull JC,
"Sulfonation Sulfo Acids of Acids phobic C~,mpound--,: VI, Sulfonation of
Alpha-tLpha'-Substituted lviomoloLues of Pyrrol.c," A. P. Terentlyev, L. A.
Yanovs~aya, lab of Gr6 Cheu~, 'V'oo~,,cow State U bi(mi I.'. Ii. Lomonnsov, 1, -p
I'Zhur Obohch Kbi.,-;" Vol XIX, NO 7
Sulfonated 2,5-dimethylpyrrole, 1, 2, 5-triretbylpyrrole, Pn,.' 2, 3p
5-trimethylpyrrole with pyridinesulfotrioxide. Then, preparer!
, of: nci, , 2, 5-M-rpthylp rrolc,,dJ-
sal tr
sulfanic-(3,4) acid:,, 1 2, tri i-,,e Unyl. pyrrolema Con I c- (3, u c -1 1-1, 1,215-1,rj,-
r.ethylp~-rroledisulf onic- (11, 14)acid, and 2, 31, 115--trine thy]. y...,rrrol esul f onic- (4)
acid. `~,ulxrdtted 21 1,'rIX 48.
FA 2/5CT63

Sultonstion and culfank acids of scidophobic sub- c
stances. Ix. Solimutlon of I- and I-scetylpyrrolt.
A. P. Trrrrjt'cv and L. A. Vanovskaya (XIWO34 State
Vniv.). ZAXP. O!oJkAWr-Kii-W.'-Tj;-r'Tn. Chesil.) 10,
21114, 22(IV19); el, CA, 44, I(VU,
yryole (1) (1.3 jj in 23 nil. 6% oltunt, liourrd Into
li,(), neutralized with lt*CO,, fillefed, and coned. gave
I
7670 1k 2-attlyl-4-p7rroksuffismate, PA. in 110). giving
HAS(h with Dr water and CA nil boiling with lbefe IICIj
Vibile uxklation witfi CrO, gave sulfoinalcansw a61,r,
isolated as the Its 6411. A (IM 9.) strut 4.777
g. pyridinir-SO, lit (CHICO, in 8 firs. at 100". then .1 firs.
at 12")", give on evoilin. and ricutralizalim with
PaCO,, 1.2 K. di-#,j 2~uelyt.1,5.pyrratedisuffaft,sto iftinn-
lit, f."folf), while the "lather ltqllnf Yields the Illosso..
eldfollate (fes-rilsell UIW)Vr ((?.', V.). I-Aertyllpyrrole 11.5
g.) and So X. joyritlint-,W), in WHIC111 in 5 firs. ifit 11,111,
'$(111 1) firs. lit 110-210* give 4.2 dily1famitirl. appire"OY the
.5- ond evLjtvl at the Ba jaks by fr.wlimml
ppirs. filmn Ild, Fjf)jI: Oxidation lly elf), gaive 8-dertyl.
malriluidr, tn. W, G. M.

Die 19.
kki PON'
Us
fe

1-,d
li-,07
Suffatimiap md sulfank acids d &OoAlibit sub
scam". X1. AMAkatioci of the loathing inothod to tho
InIZO of "liciatka "ucts of pyrfole, A 11
Ir. ~-L and V. fl~ V44imi-kil
L~ILMKVW K41M. 0. C."'c
client.) 20. 510-130950); %f. C.A. 43, 74,15s; 41.
in
-V X OX4 0,
"I.
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h it gifil, vilts
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h it ja~ 1,
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taken up:u McOll I tilrAll. Willi rad.f.im.4 0 1..
with 0.1 x XASCIC4 lphthAlCut; Ilk' f-jjlj~
vh"ktd CJj.O,.V.S'),Ba. tftuAlt (LAV, 9 ') ~Itikefl 2
hrm. with 35 mi. -q- B-ItOll (2;3 by vol.) tivr a ~jfd
As. at Wattil au allqUot Of Itic voln.
Whik The aliquot Vul. WAS trpl4mf by affcquil "Vi. td
%;ln, j4 the Saint CtAnpii., JIM t1w JW(XV%S w4, fr1w.41rd I
(jinel; tbt 601Y. Of the MAIJ PhASC, LC,, ON! C01111111, -If Of
undissolved salt. reminal the L-tine. The samv pimr.
duze med on the unpuri&d H,% "t obtAinvil by pyrilinc-
SLh sultmation Of PYITOIC CAVV A "infilAlly ClOn.l. ft~011,
thus showing the 110MOVOCRY d tht �UlI(IUAIkXl friCtim-o
licu,luct. RIVA4.11.41
X

Adophobic CO-
th -
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i'
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Ate
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01 tho yisht I.-, I
I still 10 tito
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LA
U. I'tudy SI't p)(OpIrsulf.01c acids by (Saidativo polso.j
I ctewcv. 1, A Vm,.% 4 It I . ..... 1 11. A
V.4 I Mo. 11.4iIdy
I4.1d 'Nat. I S S"'i R. Ia. 09 if I Pegp~ 43,
44, lAP,#:,i m 19,11111-1
droppilig-Ifs me 1. oftly '10,11trA m
'old giving Ji.liful .111*#. I'll,,
-mulb., Ikoloatul Iva, llwaolfr.f "lilt 4 0,41,4110 0"
mul All, 'A KCI ; the t-t
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1.111-VIAW *fill,- I if,
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Use of diolane dibrom!40,1,. Wominago" I Organic
.y.
is_,j V.1
compoundii. 1- I)ALOY Al", - ,
I Valiv M,
'I. tv .. . -141W.,ilm, iii,
S
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2.5 9- 1 '"t$ g
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of thr F-40 I
andryall". It"'111111,11. , .41, -11,11il'it"
1, lit
, .11-thill, "fill lift
'Itt.liblill-11C. i I,." I
I4.40119411111(il
It It t It W IV I Ill 13 9.11 1141i,,im "Y
ill. At Willi th,: Atilt -
'I'liv. i. Ili lit -it, arti. "Old M.-I'll %3%.
2- .. it I to feal.i. bill Allillfai'vil,
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It, Went jr-tvc
Ablelly-l- 'kild krILY111,
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lit I
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aw
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ir.
ERR A?,
"'N N1151 M:R, RM

Sall'o"tift of fildithy-doot and betoutim. A. 11 reircit't i,
41111 L. A. YxnrvAjv 1. V. Immwumpv "itale
? 11, 1 fQ73r.-(APX.,k S.S.S R. TS, i~M 'I wdi.
-Aghla. of art iihichrile ew horteirw With oftivift i-thrig ca
olknmir-lWh ill (ClItCDo. killps oitaml ovirvitithl. Irrainirnt
fifth HaVCh. fritri, vifth bM 11,0, o"d rj.tn 4 the
4,41flol. rit ~ with FoOll-Iflo) g4ve 114 *Alto 1.1 Im"l- w ill
-Illfonlk, Porkil, d"OuIllis 4m The follks 14 rVASir"I. 10-1
fiw A, Ph, of[ Ittitiltri g.4tor all. If.% milf.m4l", immliv
ak Al III ctltfrhyflr% thr J"lv. .4 .11611
ol,o mitr At As teilrifur tro, tmto-v 1,,Mitim m-lit , I"If site
-4.0 Willi fit. 1101-SI, mhl it.. Ilia ('11111 SmIlIr'. plovml
., w . I h, "I *if I~ I I " "
Is. I'v -NI I.. 1w . 14,
('.. 11.4 ..11.v J.j. vicM. glvrlf)
mo#,41,14 31, all't 4044IJ MI; Ni'lloo
Pff,110 wommool #11 mod jiaid 79: ifo-lallip
7.5. ion-flool110 --trid N, monoteki IM-i
("Ib.01f) MaRralid fill, Coi&CHO momooftif 43. A"'I all.
dl#J 31; 114711,M(P ~~*J [,',: "Imm(O A:J,
land ji'lild blo). pp'llf sk",W,,Vujj Alt. 411*1 diviod
1"'Co too; A(PA molomffid ill);
M~*M�CiJ 94. (NOIC 117 9111thOM. Aftrf COMPI~lllmk Of fht*
.,.k gh"r Apf~.Fnl III, rrjM1rj 1.1 Tiller and Allierl (t',-#
04mit. owrtivis ~imit.r plirv- 1.:1. .0h I.**-
thfirproll In 111#14110,1

P mi, 6
Abl~ pumbr;;Skit.
a,d A-. At gave OW
So Fos.. mS I,"
,,,,j a a 023 T
onil Ic ~; sullo rip
Wave th =tl-d of t icKd I if
as I linuting lUe jar the otbowaves COO 'Oulfonk.
w beence a' ted 1109ten I C the
(t the It llydrotc"- c0 I~Akat a
I own- gave lifell, ! ". pour"*
It . I I xt.IU04 Imelsulloole r;,~fntlall
oshfis L4hyj-jl-buW ilb hall.wavluied by tht
at urle CAW 2 Vraves h fi"t Was CM k"wn at
ra probably, I e her being It" id
.10 ocl~ c4 the Ot ac
thohutadimcVlIf*nk with
I~Wlfonk "Ii 'he' 1 Wave . .
Yho 211-dlm' pbY gave HOW
,his One' cl;.~71- POWOCra 0 be the 1-$u
oxidAt~- gave tw. 0 017 V. Obo"Winsgiltvt "t ith ha
hal4ravc poters ., c K.,dAPOff
cyowentadictlesulloubc CO.
wave tw 0.016
'MER -0 -:g.
KZ A MNAVP, t
VO RTM-0

YANOVMYAO L. A. ------
USWChemistry - Sulfonation Feb 51
"Bulfonation and Sulfonic Acids of Acidophobic-Compounds. XIV. Sulfonation of 2-
Chloropyrrole and 2-Benzolazopyrrole," A. P. "erentlyev,, L. A. Yanovskaya.. Lab Org
Chem,, Moseov State U
"Zhur Obahch Khim" Vol XXI, No 21 pp 281-284
Pyridine-aulfotrioxide can be used for sulfonation of 2-chloropMole and 2-benzeneazopyrrole
Obtained for let time 2-chloropyrroleoulfonic-5and 2-benzoneazopyrrolesulfonic-5 acids
in form of their barium salts.
PA 177T16
%,7
j ~i~ T"
a-z' .4 .5mF-A -1 P]$~

y,la,OVSKAYA, L. A-
NI 5
sulfonation
USsA/ChemistrY
Onic Acids of AcidopIldbIc-
ji-Aole
11sulfonation and Sull Certai~
y onatiOn Of A. yanovsWas
Compounds. VT.. sulf L.
res,,A. p. Terentlyevi
Derivati~ ) state U
'heM ~JOSCOW
lab ors C No 7, pp 1295-1297
"Zhur O'bs-nca V.01 1011,
table sulfOvAting
pyridine~-Sulfur tri0xide is sui and
agent for indole derivs. Prepd for 1st time -
.p,,,ylindolP,Bul
Ba salts 2, indo-
isolated in form 0;,indolylacetic 3-acetYl cids.
-.3 2~-bulfo-3-- 'ulfonic-2.a
fonic 1j.-2, and I acetylindole.
esulfon

,ad 14111C O'j' Lsse'4'jO?MbA'c subsUAC*s
P,
swonation jW* of derlwAttv"'Ch" R. 21. 14 1
Y.V1. SUVO" G". C 4 1" R'
and L. A Set
Mm -M-MV

Dipsk tummeoft of "f Me dwivillves. V, N, ( lise'vAn.
,va t. ~, VemwAmim tind A, 11 Trivnt'rv I
z4ff. AS. X6110. IS. We Ail
IS Of PYrMk drfiVX- LU C4114 MAIL A
198O.-Impals tuatnen
The miults (in bcb)v units) ve: 2,3-
25* we nwasured
2.03; 1.2h4rimethylp)Trule 2.08; 1-
yrrok
y * A-ciftwithOpyrfak 1 .90;
no ylpt"We 2.50:~ 2.4-dimethylpyrrole 1. 5: I-phrnyt-
.Yrrule 1.61; I-Afflylpi,frok 2.M. 3-rdtikylpvffole
I-phirnyl-2-rarthylp)-mile I W. Tbu-, In th, joymile riots.
the dipak has the ctimflon (N-cing) n,Ixwi1r w thAt in
Amines. Alma. the circtruncliativity of C at-mi* let N-0-
%tituted pyffok derin. Is Lirgff thin lit pyrrole It-If
This explains s=e cbetu. propertiri of pyrrok drriv,
(Covrtcv and Pairtinstan. C.A. 28, 9d'. Dhont anti Wshitit.
r-4. 38. =M). Michel lkvdltt
N IV- t,
T

Tj
try,:--;, Sulfonati6n.
and Sulfonic Acids of Acidophobic',com-
Oounds -XIX.
Polarographic Investl
gation of P.
'sulforLic Acids," A,P. Terentlyev,~-'
'L. A. Yanovska7ft
"'Y
e~ A Terentlyeva
_-Org Chem,Lab, Moscow State
Zbiir Obshch M2im, Vol 22, No -865
5, PP 859
e.g.,.l and.2-acetylpyrrole and 1-
~Phenylpy=ole, can be sulfonated with.pyridine aul-
fotrioxide to form&- azA.0-sulfonic acids. Tb:e
'-metbod of oxidative polarography can be used to~ deta
~:tW,pos~ition of the sulfo group in pyrrole sulfonic
acids...-Separate
-polarographic. determination ofo(-, and
Pyrrolft SUlfo C aa:Ue in a MiXt U'LPOS
ni Kible.
'L63T35
t
~21

-Y MY, 52::
USSR/Chemisti SU2fo=tiCM::.
."Sultonation and Sulfonic Acids Of AcIdophoble Cdin-
pounds, XX. Polarographic Investigation of Idole"
Sulfonic Acids," A. P. Terentlyev~~. A. Yanovs",,
m Lab, Moscov State U
g~'Cjje
Zhur:(Ybshch Xhim, Vol 22P No 5., PP 866-87o
Pyii4ine aulfotrioxide was used to prepare indole
acid. The oxidative polarographic method
..,van.be used to det the position of the sulfo group
in'indole sulfortic acids.
2
61W
16

232T24
U~SR/Chemistry Bromination Se-P 52
"Bromination With Dioxane-Dibromide. 1. Bromina-
tion of Phenols," L. A. Yanovskaya, A. P. Terent'
yev, L. 1. Belenlkiy, Moscow State U
"Zbur Obshch Xhim" Vol 22., No 9, PP 1594-1598%
Authors propose a convenient new method for brom-
initing phenols, naphthols, and oxyanthraquinones
in vhich the addn product of bromine to dioxane,
i.e., dioxane-dibromide, is used.
232V4

A.
232TP5
U
8
M
tr
Mudet-17 Bromination
y
S~~P 52
"B
r
0
n
Itd0
n
W
'tBromination With Dioxame-Dibromide. Bromi-
na
ti
n of
Ald
nation of Aldehydes and Ketone,5 A. YaLnovqkaya,
A. P. Terentlyev
Ap- Terento ye,
-v Moscow State U
"Zhur Obahch Xhj
"Zhur Obshch Xhim" Vol 22 1 NO 9, PP 1598-1602
A Fhode b
t r i
u 'a cr 3
Authors dencribe a new method of brominating alde-
hydes and etone
hydes and ketones under use of dioxane-dibromicle...
232T25
4
M
R~
M
MM 4,

polymel's and PolLnierization
New refractorj pol,~,mers. Px-iroda 1;1, no. 2, 1952.
1952
9. Monthly List of Russian Accessions, Library of Congress, LYMP Unclassified.

I- YANOVSKAYAP- L*. A-.'*
2. US,--,R (600)
4. Compounds, RAcemic
7* A new method for separating racemic COMPOunds, Priroda, 41, 110. 10 , 1952.
9.
List Of Russian Accessionst Library Of Congress,
---fttnLa-'X-1953. Unclassified.
Ev"
N~
-H BN
"M M
P -R.4 -R-
W

(Iss,
45
CCIJ,C\ 111frCu.,clut
c -.0-4 (vIIj.' p A,Or,
_CO ~t j )
N
Of (Vill)
above even Pyridi SchI e_ Ill
,tt ISO. ne.-
- I ), Antl
boll,ogencou. . so, .'a
tr3rljp,,,,lt I. .. Wit t
re'lal I W
'rill, with h I
* .1lutu"I
M ((-11
Pyrialifle-1,sa, :C1,-l c2vc IS 1.
me-sr), under (c pr, ,d f V, Ill u t
uct3 SIt lie "). .'Y 11 ill s;
11,; , " 0 to
t1i': y
in f lj~
forn (ad
9, 21141 c ,
70; IV (C'fi,f), '., ! re
V 4.2 11 .!.- ;mt.1 4
(11j'Ant I T. 2.q.
- Vf1 u4n
.21i.o a
4
.1th have fr 'It.,
0
1. 1 3 nt.,
*uter- th,Tllr,Ac of I 1~'d Etl)31" fc'P- All 8
VE- Uni is (it the . I "OT hYdrol a gait,
10 , 'dfs Ill alk Infes hydr", jyz, 1. 60. efe
du!ds very 'a ofus to ff Yzed fil boil. 'Unig
read Ve
Wi~ We 11,()
11~1; he lnonlOarid
.h the greateg The thazz
the pure state. care, the Aalu "QuId be Oh tain", 94v(
1`11 ,, I *i on
L SO 4(c
'b

~,j
YANOVSKIYA, L. A,
Sullonation and #Wfbnlc acids of aci I
lanhobic substance!
XXIH. BAUU"UO of a arl(f k4
V I
an v
at,
11178b,' 49, 4420a.--As a result of expis. with vArlous wil-
fonating agents (SO3 In (CHIC01, Pyr ille-,
tnatllne,wl, pyrid
~=s, dloxant-SOJ, it was shown for iulloilailon of
s! Aldehydes dioun"Os is most sultAble, while for ketonej,
all the lbove agents except pyridine-SO, can be employed.
To 5.6 g. AcH In 10 ml. (CHICI~ wu3 added with cooling
diome-840, frota Off g. SQj 4a 25 id. (CIIICI~ with ex-
ceu dloxane;. after 12 brs. at W ud ututralizatlun. with a
telispension of BaCOj, an &q. ext. of the evapd. mixt, suve
'04 jt~_Da actialdehydasuffonaU hydral#,'(C%11jOjS)jBa.1W
!,groin 4 . RtOll-gtfo). Addn, of 9.8 g. AeFf to it suspen-
11 . ott of! 31oxane-90~ from 25-C. 501 In (CHICI)i at 0' give -
AL(tu 12 bts. 100 Ba d(sulfonW, CtHjOt&B4.HiO. SIMI-
'~Ufly 5.8,g. Rtff& In (CHaClh treated with 8 g. 50j in 20
I rid, (C11jCIh with cooling and then Immediately with Ba-
LCO* gave 7 it. (CS1A04S)*Ba.HO (1); 8.5 g. HtCHO treated
ivin cooling- with WNne-2SOO, from 24 Idl e-SO3
sad 12 g $0, 2 hl gave 12.5 jr, C"NA"a, Et-
Ipx~T~~j ynder similar conditions give 64% 1.

L.A., kandidat khimicheakikh nauk.
Polarographic method of analyRia. F~riroda 42 no.12:90-94 D '53.
(HLRA 6:11)
(Polarograph and Polarography)

19,
AID P - 1120
Subject USSR/Chemistry
Card 1/1 Pub. 119 - 3/5
Authors Terentlyev, A. P. and Yanovskaya, L. A. (Moscow)
Title Methods of synthesizing compounds of the pyrrole series
Periodical Usp. khim., 23, no. 6, 697-736, 1954
Abstract An extensive review on the preparation of pyrrole com-
pounds by condensation and cyclization of aliphatic com-
pounds and by conversion of heterocyclic compounds is
given. The review is based principally on non-Russian
sources. 346 references (51 Russian: 1884-1953).
Institution : None
Submitted : No date

lk J

M. PhOli '3 (-CI, tfrAVA
ti, milt

UM/Biology -Botany
Card 1A. t Pub 86 - 14/46
-.Autbore i Yanovskaya, L,, A,,, Cand. Chem. Sol.
'-Z4---fo- f rubber in plants
Perlodlcdl Friroda- 43/9p 83-85s So 1954
P
Abstract The.author states thecheipical formula for rubber and recounts the
efforts of various scientists to reproduce in the laboratory the
process of the formation of rubber which takes place in certain
plants. It is shown how the efforts to transfom isoprene into
rubber led to the conclusion that polimerization is the result of
the rearranging of the atoms. The series of steps in this process
is given. One German reference, three English and four Russian
(1948-1952).

DZE-Ye--.G-.,reda or;
RODIONOV, emik, redaktor [deaceased]; KAZAITSKIY, B.A.,
akademik, redaktor; KNMANTS, I.L. akademik, redaktor;
SHEMYAKIN, M.K., redaktor; MEV ITRW prof, re4aktor;
LURIYE, H.S., tekhnicheakiy redaktor.
(Polarographic analysis in organic chemistry] Poliarograficheskil
method v organi6heskoi khimii. Moskva, Goa. nauchno - tekhn. izdv
vo khim. lit-ry, 1957. 388 p. (Reaktaii i metody isoledovaniia
organicheskikh soodineniio vol-5) (MIRA 10:10)
l.Chlen-korrespondent AN SSSR (for Shemyakin).
(Polarography) (Chemistry, Organic)

TIRMIYET, A.P.1 2YAN50VBU
Using halogen-containing ocapounds for substitution halogenation
of organic substposse R#akt~*org.sosd,6t?-342 157. (XnU W12)
(Halocanation)"'i-, (Substitution (Chemistry)) (Organic oospounds)
Y~z It "E
R4`1 " Rt

20-2-27/60
AUTHORSt Nazarovs I* No , Memb- r of the Academy,
Gusev, B. P. I Yufit, So So I Gunar, Vo I., Smit, V. A-.'
TITLEt The Synthesis of ]Aethylheptenone and Methylheptadienone
(Sintez metilgeptenona i metilgeptadiyenona)
PERIODICAL: Doklady Akademii Nauk SSSR, 1957, Vol- 114, Nr 2, PP. 331-334
(USSR)
ABSTRACT: The two substances mentionedAn the title of the paper under
review are of importance foi! the syntbEsis of the natural
scenting substances of the isoprenoid type. The authors of
the present paper investigated the production of the former
on basis dimethylvinylcarbinol or isoprene with the aid of
three different methods t(l) by condensation.of prenylhalo-
genids by aceto-ethylacetate; (2) by interaction between di-
methylvinylcarbinol and the same other; and (3) by pyrolysis
,of the same ether of dimethylvinyloarbinol. As was shown in
a previously published noientffic paper originating in the
same laboratory, there are produced at influence by hydrogen
Card 1/4 halides on dimethylvinyloarbinol corresponding prenylhalides

The Synthesis of Methylheptanone and Methylheptadienone
20-2-27/60
with high'yields. They can be easily condensed by sodium-ace-
to-ethylacetate and at a subsequent saponification they yield
methylheptenone. The second m8thod of synthesis takes place
at a temperature of 160 - 170 a--.! yields 60 - 70 ~ methYl-
heptenone in addition to an almost theoretical amount of
ethanol and CO.# The reaction must be carried out under pres-
sure or by using high-boiling Vaseline oil. The remainder
after distillation is aceto-ethylacetate of dimethylvinyl-
carbinol. At 160 - 1700 this is subjected to a pyrolysis,
and here methylheptenone and CO 2 are produced. This supports
the reactions mechanism as illustrated in the paper under
review. The pyrolysis of pure dimethylvinylcarbinol-aceto-
acetate was investigated further. It is produced with a yie3d
of 90 %, when diketone affects dimethylvinyloarbinol in pre-
sence of small amounts of pyridine, best at a temperature bet-
0
ween 145 and 160 . During this process, rm thylheptenone is
produced (65 - 70 %). The pyrolysis has also a lateral di-
rection and leads to isoprene, acetone and C02' Sometimes
this lateral direction predominates. The authors of the pr---
sent paper studied in detail the production methods of methyl-
Card 2/4 heptadienone both by interaction between dimethylethinylear-

The Synthesis of Methylheptenone and Methyl' ptadienone 20-2-27/660
binol and aceto-ethylacetate, and also by pyrolysis of pure
dimethylat .hinylearbinol-acetoacetate with a yield of go ~by
influence of diketone on pure dimethylethi;iyl in presence of
triethylamine. The reaction takes place only at 170 - 1800.
Below 160 0the initial products are obtained again, because
no interaction takes place. In the gaseous phase the reaction
takes place only at 250-300~ There the yield is low (15-20
Inert diluting agents, acids, salts and metallic oxides do
not favor the reaction, but rather frequently lead to a com-
plete resinification of the substance. Here again lateral
processes take place, with isopropenylacetylene and acetone
being produced. The experimental part of the paper under re-
view contains a detailed description of the production meth-
ods together with constants and yields. There are 5 referen-
ces, I of which is 56viet
Card 3/4

20-2-27/60
The Synthesis of Methylheptenone and Methylheptadienone
ASSOCIATION: Institute ..oF Organic Chemistry imeni N. D. Zelinskiy, AS
USSR
(Institut organioheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR)
SUBMITTEDt JanuarY 7, 1957
AVAILABLE: Library of Congress
Card 4/4

20-5-31/60
AUTHOR 11AZAROV I.N., member of the Academy, ';.0 :714
N.O
X1-fA
GTJ
A
P
V
B
P
d
b
.
YA
VS
.
S
.0 an
,L.L
)

TITLE FAZAR07A) 1. 1.
The Synthesis of Geranglacetonet 3-Methylgeranylaootone,
Pseudoionon and Pseudoiron.
(Sintez geramiiataetona~ 3-metil'gerarilatsetonap
psevlolonona i peovdoirona.- huasianj
PERIODICAL Doklady Akademy Nauk SSSR 1957, Vol 114 Hr 5,
pp 1029-1032 (U.S.S.R.)
ABSTRACT In the course of eyetematio work on the synthesis of
i3opranoidoompounds a paper by Carrol attracted the
attention of the author. That author reports that with
the heating of linalool with acetoacetio etherp in the
presence of a small amount of sodium alooholatep gerany-
laoetone with a 40-45 % yield develops. Kimel and Cope
obtained 61 % linalylacetoacetate from interaction of
linalool with diketone, in the presence of metallic.
sodium. Its pyrolysis at 170-235 % Yielded 76 % ger"Y-
lacetone. The authors thoroughly examined both synthesis
varieties on linalool and 3-methyllin-ilool, in order to
work out a produotion method for geranylaoetane and
3-methylgeranylacetone. It was found out that roaction
proaveds best at 160-1800C without any oatalystas
CARD 1/4

20-5-31/60
The Synthesis of Geranylacetone, 3-Mothylgeranylaootoneg
Pseuddonon and Peoudoirono
90-95% of the theoretical CO 2-amount precipitata, and
an almost theoretical amount of alcohol (with admixture
of acetone) is distilled. Sines the latt-3r ;)rooeae is
terminated considerably earlier than the C02- elimina-
tiong it may be assumed that the reaOtion paGaes Vho
acatoaoetete-stage. A system is given. This moobaniam
was proved by the authors for the reLation between
dimethylvinyloarbinol and acetoaostio other. From a
study of the second variety of synthesis the authors
found that the aoylation of linalool and mothylinalool
with diketone may best be performed in the presence of
pyridine or triethylamine, and not of metallic ooaium.
Based upon the results obtained, the authors decided
to investigate both varieties dn dehydrol1nalool and
3-methyl dehydrolinaloolp in order to w6rk out synthesis
methods for poeudooionon and pseudoiron. Sometime during
the beginning of this work a paper by Lacey was
published demonstrating the possibility of a synthesis
of dienones on most simple othinylcarbinole according
to a general system mentioned here. The second half of the
reaction the pyrolysis of acetoacetate, was performed by
Lacey in the presence of small amounts of p-toluolaulfonio
CARD 2/4 acid. This kind of dienone synthesis was thoroughly
Ii.
~E'f '~~ Z- 1
T
?Y

20-5-31/69
The Synthesis of Geranylacetone, 3-Methylgeranylaoetoneg
Pneudoionon and Pseudoiron.
studied in the laboratory of the authors. During the work
the paper by Haven of the same topio was published, He
also described a production method for 3-methylpseudoiron
from 3-mothyld,ehydrolinalool and a-methyl acetoacetio
ethpr. Recently Preobrazhenskiy and collaborators wrote
on this topic, The authors studied b6th synthesis varieties
and found that the roaotion between dehydrolihalool or
3-methyl dehydrQlinalool and acatoaoetic ether proceeds
best at 110-1800C The yield of pseudoionon and pseudoiron
amounts to abou.t ;5 ~. The aoylation of dehydrolinalool or
3-)R8thyldehyd:rolIiialooI by dikotone-prooeede best in the
presence of pyridihe or triethylamine. The pyrolysis of
the two mentioned w4betance's thus obtained was performed
at 185-195 0 C.-In tbie connection about 80 ~ of the'
theoretical 00 -amdunt.is obtained. The yield of pseudo-
ionon and paeuioiron amounted to 50-55 ~, of the initial
materials. The cyolization of'the thus obtained pseudionon
with a mixture of sulfur- and ioe-aoetio acid gave'ionon
CAR]) 3/4
-g
g

20-5-31/60
The Synthesis of Geranylaoetonat 3-Methylgeranylacetoneg
Pseudoiojon and Pseudoiron.
yield. Experimental part with the usual data.
with a 65
(2 siavic-ref.erenoes)
1111,D.IZUTZINSKyo, institute for organio ohemistry of the
Aoademy of Scienocaof the U-65R.
(Inl3titUt OrgaUicheskoy khimii im.11-D. Zelinekogo Akademi
nauk SSSR)
"FISENTED BYZ -
fMB=TTED: 74-57
AVAITABLE: Library of Congress.
CARD 4/4
J i~' C.-I
N

AUT11ORSt Nazarov, I. N.(Deceased), Yanovskaya, L. A. 74-27-3-1/7
(filoscow) *~_
TITLI~: Achievements in the Field of the Synthesis of Carotenoids
and Vitamin A (Uspekhi v oblasti sinteza karotinoidov i
vitamins, A)
241-276 (USSR)
PERIODICAL: Uspekhi Khimiio 1958, Vol. 27~ Nr 3, pp.
ABSTRACTt
In the course of the last years great success was made in
the field of the ab,ove synthesis. Synthetic vitamin A and
P -carotene are produced in industrial scale already in
sona 'V-4'e,3tern countries. At the beginning the author reports
on th~- results of the structural investigation of the caro-
tcnioi'-':s Thich already in 193o had found the most important
results. At present there exist more than 70 so-called in=
dividual carotenoids. Following, the methods of synthesis
are described. Already in 1952 Undon elaborated a new
method acc6rding to which a yield of 14% could be obtai-
ned (formulae IV). Karrer and Inhoffen (References 5,6)
worked with magnesium oreanic compounds (see formulae I
and II.) and obtained tetraol with a yield of 6o 70~-

Achioveni~nta in th,-~ Field of the Synthesis 74-27-'A-1/7
of Carotenoids and Vitamin A
According to this method only a small percentage of
(1-carotene could be synthesized, In the course of a series
of intensive investigations Inhoffen succeeded in elabora=
ting 3 further possibilities of synthesis. One of them is
equally based on the principle C 16+C8+Cl6"4o" Qn further
methods see formulas V-I - VII, The methods of synthesis.
of ketone C 18 are sufficiently elaborated to day, For its
synthesis(~-ionons condenses with the cater of the Vbromo
carotenic acid (according to Reformatskiy). Yarrer used
the same method of synthesis (sec formulas IX - XIII)-
ilaisman suggested another variant of the scheme of synthe=
jis (ketone.-Cl.) according to Maylas. It was found that
the reaction of simultaneous dehydration and saponifica=
tion of the oxy ester io accompanied by an allyl re.-rou=
ping. As the :result/ the acid Cjr, forLin With a yield of
97-99%. (See formulae IX, XIV, XIII) The schcm,( of syn=
:~Ui"' 2/4 (~.-caroi:onf' to
T~l

.Lchiev(;--ents in the 'e'ield of S.:,nthc3is of
Carotenoids and Vita-.An A
2 19 = C4o is the most favourable. A descri-)tion
C19 + 0 + C
follows of the raothods of zjnthcais of the aldehyde C 19
(formulas XX - XXV and X7XIII - XXXV).
Conclusion: Prom 1950 to 1957, 6 different principles of
synthesis of(~-carotene rere elaborated (see p. 232).
Vitamin A: The first successful synthesis was baued on the
aldehyde C 14' The greatest achievement Liade during 1951 -
1957 was the regrouping of allyl in the dehydration of
~-ionol alcohols discovered by Oroshnik and I'luioman (,qefs.
113 - 115). It was ncLmod'Iretro-ionylidene-rogroupin-311
with retro compounds as products. A detailed description
of work carried out in the field of synthesis of vitamin
A, of the 'Huisuan investigations of the transition of the
retro iOllylidCnO f1trUcturoo into lonylidone follows (for.
mulae 0,'~ - U5). Vurthor viorks in the fields of -iitanin A
synthesis Coveloped into two directions: elaboration of
ne-a schemes of synthesis -,,hich exclude a retro ionylidene
Card 3/4 rcgroupinG and imathods to find out possibilities of rc-

Achievement in the Field of the Sjnthesis of 74-27-3-1/7
Carotenoids and Vitamin A
grouping of the retro ionylidene structures into the -.;an=
ted ionylidene structure. Also other variants are found 'in
patent publications which were not described in this Da.)er.
There are 151 references, 5 of which are Soviet.
1. Carotenoids--Synthesis 2. Vitamin A--Synthesis
Ca,_ d

5(3)
AUTRORs Yanovskayal L. A# SOV/74-28-6-3/6
TITLE: Some New Methods for the Synthesis of Isoprenoid Chains
(Nekotoryye novyye metody sinteza izoprenoidnykh teepey)
PERIODICALs Uspekhi khimii, 1959t Vol 28# Nr 8# PP 948-969 (USSR)
ABSTRACT-z In recent years isoprenoid chemistry has greatly developed.
Numerous compounds which until recently could be obtained from
natural raw materials only can now be produoei synthetically.
The present survey deals with the most promising reactions by
which it has become possible to solve a number of extremely
difficult questions with regard to the structure of the iso-
prenoid chain. These questions are (1) the synthesis of ketones
by the pyrolysis of the acetoacetates of the A-, r-unsaturated
alcohols, and (2) the synthesis of polyane aldehyies and
ketones by an interaction of acetals and ketals on the one
hand and vinyl ethers on the other. The Vittig and Norman
reactions were already dealt with in detail in references I and
2. The former of the above reactions was discovered by Carrol
(Refs 3-5) in 1940. However, it was used in practice for the
Card 1/3 first time in 1953-54, after publication of references 9 and 10p
777

Some Now Methods for the Synthesis of Inoprenoid Chains SOV/74-28-8-3/6
on a large scale In organic synthesis as a =ethod of producing
unsaturated ketones. Thin is proved by the numerous patents
obtained in the different countries of the world (Refa 11-64)-
Most frequent is the synthesis of isoprenoid dienes by the
pyrolysis of acetoacetates of the ethynylcarbinols. In the
Investigation of the pyrolysis meabaniam an interesting
regrouping was discovered (Refe 65, 66) by which the possibility
of the formation of allene structures In the pyrolysis of
ethynyloarbinol enters was proved. Possibilities of an
expansion of the application of the Carrol reaction are shown
up in references 67-69. The possibility of adding acetals to
vinyl ether in the presence of Friedel-Craft catalysts was
mentioned as early as 1939 (Ref 70). But it was not before 1949
(Ref 71) that it was shown that the reactions between acetals
and vinyl ethers follow the general pattern. The role of the
catalyst consists in the formation of an active complex with
the aadtal, which ensures the formation of a carbonium ion
reacting with the double bond of the vinyl ether. Such a
mechafiism matches entl:r'e'ly with modern concepts of the role of
the catalyst in elactrophilic reactions taking place via a
Card 2/3 carbonium ion. The addition of ketals to vinyl ethers is a

Soto New Methoda for the Synthesis of Isoprenoid Chains SOV/74-28-8-3/6
sphere rather insufficiently investigated so fare Besides
acetals, free aldehydes can Yeact with vipyl ethers as well
(Refs 134, 135, 136). In recent times this variant is being
used to,a higher and higher degree in organic synthesis. It was
shown recently (Refs 137* 138) that this reaction follows a
general pattern. All kinds of catalysts may be used. The reaction
velocity depends on the nature of the reagents and catalysts.
It was found (Ref 139) that the yields are much higher in
reactions with aldehydes than in reactions with aoetals. The
condensation mechanism with free aldehydes has not yet been
completely cleared up. There are 139 referencest 41 of which
are Soviet.
ASSOCIATIONs In-t organicheskoy khimii AN SSSR Im. N. D. Zelinskogo
(Institute of Organic Chemistry AS USSR imeni N.D* Zelinskiy)
Card 3/3
"D Mi
W
x ,4,

flit I

YANOVSKAYAO L.A.
possible we," of synthesizing compounds oi-Ila to vitamin~-A-
Izv.AN SSSR Otd.khi-.nauk no.8:1435~-1439 Ag 160. (MM 15:5)
1, Institut organicheskoy kchildi im. N.D.Zelinakogo AN SSSR.
(Vitamins-A)
R,
w
-W,
7i
p

S106216010001008102910331xx
B013/BO55
AUTHORS: Kucherov, V. F., Kovalev, B. G., Nazarova, 1. 1., and
TITLE: Application of the Wittig Reaction for the Synthesis of
a,p.-Unsaturated- and Polyene Acids
PERIODICAL: Izvestiya Akademii nauk SSSR. Otdeleniye khimicheskikh nauk,
1960, No. 8, pp. 1512-1514
TEXT: This is a short communication on the investigation of the reaction
of-carboe.thoxymethylene triphenyl phosphorane (I) with various aldehydes.
This investigation was undertaken with the purpose of synthesizing diffe-
rent polyene acids. It was found that (I) reacts readily with saturated,
unsaturated, aromatic and heterocyclic aldehydes giving the corresponding
ethyl enters of a,p-unsaturated acids in high yields, Particularly good
results were obtained with polyenals, polyene acid eaters being formed
in yields of over 80%. By hydrolysis of these eaters with sodium hydroxide
in aqueous methanol, the polyene acids, up to now difficultly accessible
substances, were obtained In satisfactory yields. Owing to the simplicity
of execution, general applicability,,, high Yields and purity of reaction
Card 1/2

Application of the Wittig Reaction for the B/062/60/000/008/029/033/XX
Synthesis of a,P-Uneaturated- and Polyene B013/BO55
Acids
pr oductsq'the Wittig reaction surpasses many of the better-known prepara-
tion methods. It Is undoubtedly one- of the most convenient methods to
prepare polyene acids and their eaters. There are 1 table and 10
references: 1 Soviet, 1 US, 2 French, 5 German, and 2 Swisa,
ASSOCIATION: Institut organicheskoy khimii im. N. D. Zelinskogo Akademii
nauk SSSR
(Institute of Organic Chemistry Imeni ff. D. Zelinakiy of the
Academy of Sciences USSR)
SUBMITTED: January 15~ 1960
Card 2/2

KYANOVSKATA, I.A. IUCMMV, V.F.
tbemlstr7 of acetals. Report go. 3: Reactions of tetraethyl
acetals of malonle and methylmalonic dialdeb7des with vin7l etbryl
and propeWl ether. rzv. AN SSSEt.Otd. khIm. mauk no.12:2184-2192
D l6o. (MIRA 13:12)
1. Institut organicheakoy khimit im.N*D.Zelinakogo AN SSSR-
(Acetala) (Ethers)

W
81861
5102016011331021331068
Z-' J X3 B0161BO60
1,57 a L/00
AUTHORSs Xucherov, V. F.0 YanovskaZap L. A., Kovalev, B. G.
TITLEs Saponi ication of Tetraeth* Acetals of the A-Dicarbonyl Com-_
pound2nd Some Ways of Utilizing the Compoundo Formed
Thereby-.
PERIODICAM Doklady Akademii nauk SSSR, ig6op vol. 133, Ro. 2,
PP. 370-373
TEXTt The saponification of tetraethyl acetals (I) with an equivalent
of water in the presence of p-toluene sulfonic acid was bound to be a
general method of synthesizing the P-formyl-vinyl ethers'~(Ref. 3). The
further saponification of the latter ds to the substituted derivatives
of malonic acid dialdehy A(III) (in accordanoe with Ref. 4). IR spoctra
of the 0-formyl-vinyl ethers produced by the authors confirm their
structure as at,A-unsaturated aldehydes. However, they contain a slight
admixture of saturated aldehydes. On the sa onification of tetraethyl
acetals of P-ethoxy glutaric dialdehyde (IV5 with an equivalent amount
of water there is a cyclization, with 2,496-triethoxy tetrahydropyrans
Card 1/3

81861
Saponification of Tetraothyl Acetals of the
A-Dicarbonyl Compounds and Some Ways of
Utilizing the Compounds Formed Thereby
S102016011331021331068
BW/Bo6o
M forming as the main products. Here as well, the IR spectra confirm
their structure. As the authors had proven earlier (Rof. 2), only corre-
sponding ethoxy aldehydes (VII) result on the saponification of ethoxy
tetraethyl acetals of the type (VI) with an excess of water. The
saponification of tetraethyl acetal of acetoacetic aldehyde and its
derivatives (VIII) with a water equivalent has a peculiar course, inas-
much as only diethyl acetals of the type (IX) are formed here, All of
the compounds formed in this connection do not yield any Fehling reac-
tion, and the IR spectrum shows them to possess a free keto group. The
dialdehydes of the type (III) and (VII) were found to react readily
under the conditions of the Wittig reaction with carbethoxy methylene
triphenyl phosphoran (X). In this connection they form corresponding
diethyl esters of the unsaturated dicarboxylic acids (XI) and (XII).
Also several A-formyl vinyl ethers are capable of undergoing this
reaction. Thus, P-formyl-o-methyl vinyl other benzoate (XIII) yields
1-carbethoxy;4-meth 1 5-benzyl oxypentadiene-2,4 (XIV) on the reaction
with phospho ane (X~--Therefrom, 2,4-dinitro phenyl hydrazone of the
corresponding aldehyde ester (XV) was obtained in turn. O-Keto acetals
Card 2/3
V

81861
Saponification of Tetraethyl Acetals of the S102016011331021331068
O-Dicarbonyl Compounds and Some Ways of BW/Bo6o
Utilizing the Compounds Formed Thereby
(IX) do not react with carbethoxy methylene triphenyl phosphorane. Still,
they easily enter the acetylene synthesis reaction with the lithium
cyclohexene-1-yl-aoetylenide and form acetylene alcohols of the type
(XVI) with a good yield. Saponification and dehydration of the latter
yield unsaturated aldehydes (XVII). All of the conversions investigated
here open up great possibilities for the synthesis of several polyene
compounds which are related to the natural ones. This constitutes the
subject of further studies made by the authors. There are 5 referencess
2 Soviet, 1 German, and 1 Swiss.
ASSOCIATION% Inntitut organicheskoy khimii im. 1q. D. Zelinakogo Akademil
nauk SSSR (Institute of Organic Chemistry imeni 11, D.
Zelinskiy of the Academy of Sciences, USSR)
PRESERTBDi January 16, 1960, by M. M. Shemyakin, Academician
SUBMITTED: January 7, 1960
Card 3/3

NAZAROT, Ivan Nik olayevich Eigo6-19571; TORGOT# I.T., doktor khim.naldl-Cs
otv.red.; MORMT, YA, kand.khim.nauk, red.; GURYICSP I.A,,
kand.khim.nauk, red.; SH 9 N.J., kand.khim.nauk, red.;
YAIJ,Q-T=TA,-~.,,,,kand.khim.naukq red.; MMIKO, Y.A., red.izd-va;
POLYAKOTA, T.T.... takhn.red.
[Se,1-dated works] lzbranuye trudy. Hoskva, Izd-vo Akad.nauk SSSR.
1961. 690 p. (HIRA 14:4)
(Chemistry, Organic)
-M
-12 "P4
~4

YANOVSKAYA, L.A.; KUHMOV, V-F-
Chemistry of acetals. leport N'o-7: Polarorraphic study of Exre
products of the hydrolysir of tetraethylacetalE of nalonic and
Z-.ethoxyglutaric dialdehydes. Izv. All SSSR. Otd.khim.nauk
.9:1650-1657 5 '61. (MIRA 14:9)
1. Institut organicheskoy khimii im. N.D-Zelinakogo Ali SSSR.
(Mlalonaldehyde) (Glutaraldehyde)
Jz

YANOVSKAYA, L.As; KUCHEROVj V.F.,
Chemistry of acetals. Report No.8: Grignard reaction with
tetraethylacetal of malonic dialdehyde, 1, 1, 3, 5, 7, 7-
hexaetboxyheptane, and 1, 1, 3, 5, 7, 2, 9-heptaethoVnonane.
Izv.AN SSSR.O%-Mkhim.nauk no.10:1830-1834 0 161. (MIRA 14:10)
1. Institut organicheskoy khimil im. N.D#Zelinskogo AN SSSR,
(Acetal) (Grignard feagents)

YANOVSKAYA, L. A.
Wittig roaction. U;jf).khl.m. 30 no.7;813-8/#5 JI 1610 (VIRA 14:8)
lo Institut organicileskoy khimii AN SSSR imieni. P.D. Zelinskogo.
(Wittig'reaction)
,
IV:

KUCHEROV, V.F.; KOVALEV, B.G.; KOGAN, G.A.; YANOVSKAYA L. A
synthesis and geometric configuration of diethyl eateris of 2.. 41 6;
8, 10-Wecapontaane-l) 12-dioic and 2p 4~. 60 Sl 100 12, 14-
hexadecaheptaene-lp 16-dioic acids. Dok3.;" MR 138 no*5tl325-
M7 je 161. (ML 14t6)
I., Institut orge-aichookoy kbimli im...-NAjiblinskogo AN SSSR.
Predstavleno akademikom B,A,Kazawkim,
(Dodecapentaenedioic acid) (Hexadecahaptasnedioic acid)
R7
S',
5~gjg;M
PIT 41-;z
w N F

YANOVSKAYA L.A.; KUCHEROV, V.F.
Chemistry of acetals. Report No.10: Hydrolysis of te-traethylacetals
of malonic and methvlmalonic dialdehydes. Izv.AN SSSR Otd.khim.-
nauk iao.4t667-674 Ap '62. (MIRA 15W
1. Institut organicheskoy khimil im. N.D.Zelinskogo All SSSR.
(Malonaldehyde) (Acetals) (Hydrolysis)
.1,!;, v
ig.

In
YANOVSKAYA, L.A.; KUCHEROV, V.i.; KOVALEV, B.G.
Chemistry of acetals. Re t N *11: Certain reactions of
/~-ethoxyacrolein and -e hoxj-,ropionaldehyde. Izv.AN SSSR
Otd.khim.nauk tio.4: -681 Ap 162. (MIRA 15:4)
1. Institut organicheskoy khimil im. N.D.Zelinskogo AN SSSR.
(Acrolein) (Propionaldehyde)
4~',w
-,7

MOVAUVI B.G.j YANOVSKAYAXLA2~_; KUCHFMV$ V.F.
Synthesis of iBoprenoid acids from isoprenold ketorles by the action
of diethyl ester of carbethoxymethylphoBphinic acid, Izv. AN SSSR.
Otd.khim.na:uk no.10:1876-1877 0 162. (14M 15:10)
1,* Inotitut orgaicheakoy khimii im. N.D.Zelinakogo AN SSSR
(Isoprenaids) (Phosphinic acid)

YANCV,.-,~'AKY-A
Bmild-ap of carb:;.n b.1 the interaction of acetals and
ketals with vinyl ethers (synthesis of unsaturated aldehydes
and ketones). Reakt.org.soed 11:231-284 162, (MIRA 15:6)
(Acetals) (Vinyl compounds) (Chemistry, Organic-Synthesis)

YANOVSKAXA.. L, A.; OCEMV, V. F.; RUDMOO B. A.
Chemistry of acetals. Report No. 122 Application of the method
of gas-liquid chromatography for the analysis of the products
of the reaefton of orthoestere with vito%O-ethers. Izve AN
SSM Otd. khim. nauk no. 12:23.82-2189 D- '162. (MIRA 16%1)
1. Institut organicheskoy khimii im. N. D. Zelinskogo AN SSSR.
(Acetals) (Ethers) (Gas chromatography)
~7 iz Z.~-
v-

TANGVSE ~UDFAO, B. A.1 KUCHEROV, V. F.; STEPANOVA, R. 11.1
Is G. A.
Chemistry of acqtals. Report No. 13: Hydrolysis of nome
diacetals fftudied by meanig of gas-liquid chromatograpby.
Izv. AN SSSR Otd. khim. nauk no.12t2.189-2196 D 162.
(MMA 16:3.)
1. Inatitut organichookoy khlmii im. 9. D. Zolin8kogo AN SSSR.
(AcetalB) (Hydrolysio) (Gas chromatog'raphy)
R
v

KOVALEVp B. G.; YAROVSKAY L A
; KUCHEROV, V. F.; KOGAN, G. A.
Chemistry of polyene and polyacetylene compounds. Feport
No. 8: Paths in the Bynthesis of polyene dicarboxy1ic acids
with an even number of double bonds and polyene dicarboxylie
acids. Izy. AN SSSR. Otd. khim. nauk n0-11145-152 1 3.
(MMA 16:1~
1. InBtitut organicheskoy khimil im. N. D. Zelinakogo AN SSSR.
iAcids,_Organic) (Unsaturated compounds)
(Chemical borlds)
91

4 ", - '. '. z . ~~
tZ
"MW
HEM
YANOVSKAYA, L.A.; STEPANOVA, R.N.; KOGAN, G.A.; KUCHEROV, V.F.
Chemistry of acetals. Report No.14t Preparation of eaters of
polyenic aldehyde acids, their acetals ald symmetric and asymmetric
dicarboxylic acids. Izv.AN SSSR Otd.khim~nauk no.5:857-865 My
163. (WRA 1618)
1. Institut organicheskoy khimii im. N.D.Zelinskogo AN SSSR.
(Acetals) (Acids, Organic) (Unsaturated compounds)

YANOVSKAYA L.A.
Synthesis of unaatm-ated-ketones by the condensation of
-unsaturated alcohols with esters of 0 -keto acids or by
pyrolysis of aoetoacetates of /Jv;1-unsaturated alcohols
(Carrol-Kimel reaction). Reakts. org. soed. 12:259-308 163-
(MMA 16-7)
(Chemistry, Organic-Synthesis)
Ketones)
j79
42

TERENTIYEV, Aleksandr Petrovich; YANOVSKAYA, Lyudmila Aleksandrovna;
RABBOVICH, F.V., red
(Chemical literature and its use] Khimicheskaia literatura
i polIzovanie eiu. Moskva, Khirdial 1964. 318 p.
(MIRA 17:8)
mit
iA Ai.
Ilk
IV
W-
N, 3R.

,~EUTOV, Gleg Alekdandrovich; YAINVSKAYA, L.A., red.
ITheoretical principles of organic chemistry] Teoreti-
cheskie osnovy organichaskoi khimii. Moskva, Jzd-vo
Mosk. univ., 1964. 697 p. (MIRA 17:8)
U,

I I t, W ~! I
NAZAROVA, I.I.;jA!iQV44AYA,-I.A.;,.,-KUCHEROV, V.F.
Chemistry of acetals. Report No.15: Selective hydrolysis of 1.
1.,3-triethoxy-4-hexenet-and some reactions of 3-ethoxy-4-hexenal.
Izv. AN SSSR Ser. khim no.7:1245-1249 J1 164 jMIRA 17:8)
1. Institut orgahicheskoy khimii.imeni Zelinskogo AN SSSR.

W -6i, ~!l

lHgapp'

Zj
~17e-~*Ili~,~ "'K NMI

K7,W,
A Cl- 1. 0,ili 4 iilj
TT
ON
4g
PA
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ACC NR. AR6025768 swpr-E com UR/0058/66/000/6-04-/66!~-67t65-6
AUIHOR: Mogan, G. A.; Ivanova, T. M.; YAnovskaya, L. A.; Yjacherov, V. F.; POPOV0,
Ye. M.
TITLE: Vibrational and electronic spectra of ethers of polyene c acids
SOURCE: Ref. zh. Fizika, Abs. 0426
REF. SOURCE: Tr. AN $SR, t. 3, vyp. 1, 1964, 113-124
TOPIC TAGS: ir spectrum, Pzw.-An spectrum, uv spectrum, carboxylic acid, electron
spectrm, vibration spectrum, conjugate bond systm
ABMAM: In order to study the mutual influence of functional groups of atonis
through a system of cqniuqated bonds,1the authors investigated the frequencies and
integral intensities of the IR, Raman, and UV bands of polyene cmTourx1s of the type
X (C"-~) nCOOC2"5 (X = CH3, 0C2H5 01 CM r M2 , and COOC 2H5; n = 1 - 5). On the basis
of an analysis of the obtained data, the authors explain the causes of variations of
these parameters and of the spectra of the ocrpounds in the ground and excited state-,
[Translation of abstract).
SUB OODE: 20
Card Mj a
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YANOVSKAYA, L.A.; KOIIAIFIV, B.G.; KUCHEROV, V.F.
Chemistry of acetals. Report No.16s Ways of synthesizing sym-
metric and asymmetric difunctional polyene compounds. Izv. AN
SSSR. Ser. khim. no.4s684-688 165. (MIRA 18:5)
1. Institut organicheskoy khinil Im. N.D.Zelinskogo AN SSSR.

- - ---- -----
KOGANO G,A.; YANOVSKAYAp L.A.; STEPANOVA, R.N.; KUCHEROV, V.F.
Infrared spectra of functionally substituted linear polyenes.
Teoret. i eksper. khim. l.no.3s411-414. My-Je,.165.
Certain features of electronic absorption.spectra of.functional
substituted linear polyenes. Ibid.-.4V,-417
(MIRA 18j9)
1, Institut organicheskoy khimii imeni N.D. Zelinskogo AN
SSSR, Moskva.
H.

YANOVSKAYA,I.-.I,.-h.. IIF-I~IKOV, V.M.
Che.--t,~try of acetals. Rr-Port. No.-I?s Pate t;f hydrolyalz of r~;rc-
rionc-and dincetals. Izv. AN SSSR. S(sr. khim. no.8.-1363-1369 165.
(MIU 18:9)
1. Institut organicheskoy k1drali im. N.D. Zolinskogo All SSSR.

'YANOVSKAYA L.A. STYPANOVA, R.N.-
Chemfstr-f of ece"I-II3. Repcz`,
of various type diacetaln 17 ga5--'"qujd rhr3ma'~ographye Izv,
All SSSR. Ser. k-him. no.8gI416-IL24 '65.
1. Inatitut organicheak,:;y kh~lmi-f im. N.D. Zej~ljj!3kogo All SSSR.
j

YANOVSKkYA L.-A-. KUCHFROV V -.F
Stereochemisti7 of the Wittig reaction withd-ionone. Izv.
All SSSR. Ser. khim. no.8s1504,1506 165. (MIRA 18:9)
1. Institut organicheskoy khimii Im. N.D. Zelinskogo AN SSSR.
M,
g t
4
,4P. m
A
u
ER
W
4" %
;,r ta-

YANOVSKAYA- LOA.----T',,PA?T(T,"A -R.N.; KUCTFROV, V4Fs-
Reaction of acetone-7-anohydrin with trans-,4-dirmethorylmten-
2-al. Izv. AN SSSR. Ser. khim. no.8;1509 165. (MMA 18:9)
1. Institut organicherikoy khimit im. N.D. Zelinskogo AN SSSR.
-7~ k~
all
4. N
:1
V-

YANOVSKAYA L.A.
Chemistry of acetals. Report 19: St'ructure of acetals and their
reactivity toward. vlnyl ethyl ether. Izv. AN SSSR. Ser. khim.
no.9:1638-1644 165. (MIRA 18tg)
1. Inatitut organicheskoy kh1mii Im. N.D. Zelinskogo All SSSR.
i~g -,g i ""I
"POIK,
V

YANOVSKAYAI_~.A!; KUCIIFROV~ V.~'.
Ccmparative rea~!tivfty of" diacel'-&-la of %Ic f~::,,fni-j ~,?fx - k
4 , , ~.
2 - < 7: . , &
t7pe. Izv. AN Ser. khIr. rio.9-1657-1058 165. (ITTA 18-,g)
1. InstiLut organinfieskq UimIJI. ~m. N.D. Zphnskogo All SESR.

Y A IjOVSK A Y' '2 3.4~
tho~bj&,,% r," WTRA ISPID)
:1,
~j

TANOVSKAYA, L.H;ALTHAUSEN, B.L,
'~-e 7?72~,77:r- ~- -V,~a -~ -.
Iffect, of vitamin D. in pulmonary tuberculosis. Probl. tuberk.,
Noskva no.4:59-62 ZIF-Aug. 1950- (CLKL 20:1)
1. Of the Institute of Skin Tuberculosis (Director -- Prof. F. V.
Shebanov; Scientific Director Frofo N. Lo Rossiyanskiy).
V,;j

Kedicine
Physical condition and treatment, of the- 'Uubcr-cular patient. Medgiz, 11051?
2
9. Monthly List of Russian Accessions, Library of Congress, October -19M. Unclassified.
-;'V IU
All,
NY,
1-5 -M
i"M -I~t-
-'I
it ii

YANOVSKATA, L. M.
[What should be the behavior of a person in the family of a tubercular patient]
Kak dolzhen vesti sebia chlen aemli tuber)mlesnogo bollnogo. Koskva, Kedgiz,
1952. 10 p. (MLRA 6:8)
(Tuberculosis--Prevention)
L
-N

1. YANOVSKAYA, L. K.
2. USSR (600)
4. Tuberculosis - Prevention
7. Hygiene education in tuberculosis control. Probl. tub. no. 5, 1952.
9. Monthly List of Russian Accessions, Library of Congress, February -1953, Unclassified.
-N
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