SCIENTIFIC ABSTRACT YATSEMIRSKIY, K. B. - YATSIMIRSKIY, K. B.

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• Collection: Scientific Abstracts
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• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

PA 1PT91
YA,TSIMIRSKII, K. B.
MILY 1947
UM/Chomistry Utropy
chemistry 106
"The Standar& Entrop .i65 of Ions in the CrYstgllins
St4Lte K. B. jilLtaimirokii, Chemical-Technological
Inatitutej, IVILTLOVOP 2 pp
uZhur riz WWI Vol xxi, No 5
overed by S. H. G4,POn "I the
TAsis the Value's a8 diso - tion,
difterent valuos derive& by later experimenta
ftblishe& 17 D11c 1946.
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YATSIMIRSKIY, K.13.
Yatsemirckiy. K.B. and Zaslavskiy, I.I. "Classification of diagrams in
volumetric analysis of liquid double systems," (reference), Soobshch.
o nauch. rabotakh chlenov Vseso.-ruz. kbim. o-va im. Mendleyeva, 1948,
Issue 2, p. 2)
SO-., U-2888, Letopis Zhurnall.nykh Statey, No. 1, 1949

'~M/Chemlstry - Heat of Hydration, Of Ions Jul/Aug 48
Chemistry - Thermoohemistry
"Therwohemical Radii and Heats of Hydration of Ions,1F.,
iX. B. Yatsizol skiy, last Gen and Thorg Chem imeni N. S.
,MwnaXov, Acad Sot U=j, 71 pp
*1z Ak Nauk SSSR, Otdel Khim Nauk" No 4
iCalculates thermochemical radii and heats of formation
In the gaseous'state of t!Le 'Lana: JOS, BrO'3, CNO`;
C6R~(102)30' and ZC0(1qR3)5C17-
Calculates heats of hydration of the Ionst
] (1qO ) 0' Clo" b~~' NO, HCO
C
10'41 C6 0~'2~1~," alf -, CNO'
R5:'CO' 0 " I ~ CN,' 3~i(CH Uan cc( ?\43)5ci~**
Silovs; relation between heat ~PL;dratlcn and itude:
U /Cheml try Heat of Hydration, Of Ions Jul/Aug 48
(Contd)
or -mermochemical radiua. This relation for anions of.~'
the type RO-- -is SomewnaT, itai-It ~Qm-
anions. ii&; applicability of Xapustlnskiy"B~~
equation for calculating the entropies of R4 type
ions in aqueous solution. Presents heat
of solutican of sa.Lts as a I uaction of the ion radii
thich fox the particular salt. Establishes general
relationsb1p between alteration of heat of solutim &m&
ithe magnitude of the Icn radii. Submitted 11 Jun 1947..,~~.
AM- 8/49TI3

PA-ZI14
ili6R/Chemistry - TAnthanium Compounds Sep/oot 48.
Chemietry - Ionization, Potential of
"Calculation of the Potentiale -of Ionization for
Some Ianthanides by Means of Kapustinskly's
Equation," K. B. Yatsmirskly, Inst Gen and Inorg
Chem iment N. S. Karnakov, Arad Sci UMM, Ivanovo
7Chem Eng Inet, 2 pp
*Iz Ak Nauk-;SSSR, We 1 1him Nau k
.No5
a regular--inardase-In. the _Ionlz~tlon. potantid .
of the.lanthialde,serleo, Ce-37-1 ev, Pr-37.7.er,
Wd-38.2 e7, Sm-38.2 ev, and Er-40.0 ev. Submitted
5 Apr 43.
27/49T32
-vR

.19MIMemistry "Synthe;sie Navlbeo 48
Chemistry - FWW97, I&ttiCS, Of MOtMI Salts
"Me Iattice Energy of Metal Salts of Becordary
Groups in a Periodle System," X. M. Yati3izirskiy,,
i Inst Gen an& Inorg Chem imerd N. S. Kurnakvv,
-Azaa Sol UM, 11 pp
t
"I Nalik SSSR, Mel XbI- Nauk" No 6
7:108 conclensation of 2-farmoxTbu.tadi 2-
z
*othozybutadlens- and chlorolwene vith divInylke-
tones (5-metb7l-l34-hqxR~Iqn9-3-oaI= amdL 5-
'rwthyl-l,4-oota&I9n -3-onlxzi). Shows,that re-
actibn takes.place easily according to general
33/49T20
UM/Chandetz7 Syntheals. (C=td) No~~qc~ k8'
diagram Of &ie'ne syntheols vith fo=aticn cf
CM,respbnaing pair-substitu.ted derivatiTes of
cyclohexenylketones.' Submitted 10 Nov 47.
33/4*D'

-- - -- -
YATSIMIRSKIYI K. B. -PA-67/49740

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1ATgnmKil) K. B.
I. I. Zasiov--k-41i and K. B. Iatsirirskiil Unusur-IL ;oints rn V_e of'
perties of binary systeras Å vo]Jirietric analysis. n. 1755
Mathematical analysis has est7--blistled the following for 2-ccn~)oljnd systemz
by chemical reaction: The zL,x1mum devi!Aion of atomic concenta-Aion from the
average of calculated value QXA) is shifted in reEarcls to -U-.e devi~;tion
,e CUICIL110,ed value (bdl toward the component
of specific gr&vity from t~e avpr,,,[!
with the smaller Liver,,ge atomic weigl~t. T1,he uitixlmum AA i9 shifted in reg,,~rd
to the comuression mayimiu,; C to-w,,.;rd the comaxnent with the lDrgeft L.tornic con-
centration. The m_-ximumAd 1: 's s-ifted in regards to the :,-.axk.!M.; C tow--r6 the
component with the 1.,_rgest spacific gravity.
VChair of Inorganic Chemistry of the Ivanov Che.,Aco TeeMological Institute
July 17, 1947
SO: Journal of General Chemistry (USSR) 28, (80) No. 10 (19/,F3):

rakitairskii and L. L. Parikova, Tharma-chamintu of acido-1xintaarnwine salts
of cobalt. p. 2051.
The beat of reaction is determined with a 0.26 in solution of NA2 3 and from this
is calculated the hen -L of formation of 15 comr)ounds and tho heat of solution of 13 com-
pounds. The heat of formation is calculated for a sorles of complex aeLdo-ponta-anmino
colbalt-ions in a water solution. From this is calculated the heat of formation os%
certain salts.
Chair of Inorganic Ch!mistry of the
Ivanov Chemico-Technological
Institute
June 28, 1947
SO: Journal of General Chemistz7 (tSM) 28) (80) No. 12y(1948)

YATSIMUMIyo K.B.
29573
Ie istorii analitidhyeskoy Ichim ii v rOssii- Uspyekhi Khirnii,
1949, vyp.5, s-623-28. Bibliogr: s.628
4. Gyeologo-Gyearafichyeski.,(e Nauki
(Palyeontol6giya - Sm. r1, 5 B)
a. G,,yeologo-Gyeografichyesk:Lye Nauki b Tsyclom. Gyeologiya. Pyetrografiya.
14inyeralogiya. Kristallografiya.
SO: IZrOPISl NO. 40

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valite 90 kcal for the sublilliation beat of the lanthasides. as
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equation Lit - 31111 # 515/r, where r to in* Ion radius. by
using the material obtained In the present work. an Wims-
tion can be made of the heats of formation d various coo-
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s
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5, Kli
S
_,x N b~:"
MV
'WH
ti'R~'?-
;l XD
X lez

IR
,
~
- RP
RMAE

3
A. 9= J.S.R.
7
lei A
Tv 40(1647 V'Ro
381-3
leM Ulu U 2161W'-
ilics. -wh
066,
00
o
to st
b
0
f .
g
w
w 4 IWO bat o
execul, 10411
MA
I as
. do Ikv..
L: 5
I
Tr
06
4 md S
" M low w
v

-
4 '410,
',
Wcf
M gim
i
'e~
ON
k
POW-
cl~
f d m
bow o
(Was, vs I s ~

,
;
'
Z
l
.10
I
ust
1
M
9117

'
Ila tibe"
' 4
8
) 1"Mai"Z61140
-4 If
=

it
.
20 1 ~'
~O

F c
~;bt'jftf t of
- I 1
_~ M., j, &N. . 177
sky MIA Sve
w two(- i~Ad OR and the
the poem @g p
Ili jMm(gj4jC1616
How* by dw am (C A.
;me the is
t
b cc
wikb 423
Apo, TWO

i,T
ilm'z' ~j~
v
1. = ~7

Clandficadisse a diagrams to volum 0 anallyals; 1101 Ustiad
binary system$. K N' t-WIVIIIII Will 1. 1. lAtlavskif I
Ivanotis Owill-Ar, ObJ40,111 Nhim.
). (loss. Client.) JO, 3111 (11 I)IJIS141111 I'd this at,
1
camwit, .4 so* Willson 14 11M. foutills. still of 4 tylisrss: In
Wait SYSUITIS Of InglitittfAC(HIS liquids cif uischinging de..
am of ancwn . A fx a lusear function of the compn.. and
the deviation 3A frons whiltivity is zero throtithout. in
,system with me allened. voinflonent vililets, to Iselin.. dill-
omits. into ishispile units. the irurim of AA is Convirs to the
aslovetwit"', Anil 44 1. Always org. lnSptvCusWb'~ft
lbs, CCt4poesenjis focus chrus. turnpds., AA Is cosseave to the
axis of the t pn. In systems Lnvolvlbg both empd.
formation and dittovis. 4j(fmw or NO suiscil. components.
sm.
she AA cwvv 6 slightly micave 14 ilsouls of abaci
the 0!". vallift ON 4.4 Arv W*141i-ty km ADA the 0"..
44 sulty noll ciampood to the Aimulli; ' of Ilia WRIO.
Uslatallive fit Will Altate"14 sot fill-AVOKI Cifirctills
I
CI(rPblk, AvOllite-licollit, evillf-I'llel, 61IN-plime
CCI._C,IIjIrj. C.114-Calli'llri. etc.; for all
Pints W .1.4 Anil of the *11, sr. against The
thesse system ty
cossapts. in tno~ jr;&ctijus rr Ijjj,,,,r, althatict: the visivoij
LM*brflnsmnyxhawioniin-crantalL. ItnesurplottiolAA
may be found %W with %yittrult of AWW;I. but chemically
A** Subatalweii. .11 siattl IIC(1~11-ArOll.
lilers, slight derlationo limit 411ditivity, with re'n"ifte"tly
mg.4A
C11" C.11 Ure-C.%. Cillic-CS4. Ccit-Clich. C'IIW-Kt1O'
tfc~. verK Small . A;1 to found In Co-
JI.Drr-CJIC4 A 16-11 Dr. 2nil Ivrie. with dis-
tillidly Dec. AA. N extutplawd by C.11,;Ac()Il. CC[.--
MsPvCO.'CSr1%1tCO. StUr-AcOll. Phlite-AvOll. CCI.
PrOll. 1141PI-NI"CO. C&A'slOll. e1r.j vi.,mily I-..
thdilt"A oll Anv 44 1IlWW ov.1.11.6 U&A I to 0116t .
listo. or 4 artiss.. dild ale, rimiloquefilly."ir" inkool,
OtiVe MASS the AA pW*. In the 3rd tytw. ths: S.4
CurvT conililtz of 2 branches interilecting at the nA,..
depending on whether. along a branch. A Anil 4.1 arr
Syrubalic, antibiltic. or count., the, branch is cvnvjg to I*
axis of Colulln" reactive to it fir mlillarsir, Me %in&
Of pffilsince of wirtral Compla" thr Mill, I$ rNisdell, as in
IfClOr-IfjO, IfNOrIIO) fir-11,0, 11,4o,-ly), ll,PO,-
"I0, Neilip-HrO. 111.1kh1w.ric.
of the 4th fir, allowing a 6.41 ififlitw suAv.. A" Ohl'tr4trii
by PhOll- %If#, I6Ir.C(s-IjCCkII. C411AN(N), listill.,
tie. lot thil, -y-1,vus A,Iill 11,41,
AvOll, Illiolf-&IrWCO, the ru.sit. c.ott.posil. in so t,o~
Chissuscork f.4tla of IN- romlostivills Anil fit fill 11crinilt
compd. Ali S-shapcil AA etwvv, itsulting frotil the
dominance of the disimWa. of
Consfin comlsolletit a I
pan of the curve. Suld of pd. furmailoo alonS anothrr
rt. 6 exensplified by the Sysitems SW14-C.116. SbC1.
raphlicandSAICIO-Ciells wlwtr divAill. thr max. "Mir.
visnalls too sfolchiovnvtr~ raflo;4 llsectsuilKnicuts.
N. I'lunt
C,
jr.

MM
CA
4jands on as basis of imingy
lbe 191#1 (1 renew Clo-on. .'fsvh in 9, Invoil, Zhoor
"I M4.1m, (L Orn, Owns.) 20. 14111 711WO. 111
'flar rotrall "W, Ono Onvolry 14 14~"noollwf 11' Obt a r.11111.1p,4
gn the ufl~910 MIMI 1011 1111A Site 04W,Ml* A4161010.
1. F
Mo.") 11 cu"Ilmowil of VIKIrnsfalk. Mimi re'.
f'"virrify of Ott I*
'CAlent terms; specifically. it it Is the no. ol dontir-arreptur
envalcut bontit its the complex Ion. IV - I - xE - *D +
11. Own- I - total ionifiatintl potential.-A - electron
;affinity of The Addend, D - ettergy ut the toftkut 10)MI
between the teustral im and the addend, sjul V - reau-
MInM t1leffly Of 11141 gIVQm StrJdUFV, On thAt IMAJO, both
C= tral orkatients oand addevuls am be
e =rrits 4 Wo"Of (1) "clevirlsofAlle,"
chavacteorlsord by a kkk 0100. C1101tV. StnAll (Adifit P. 111411 8
dltk* 1"Coneost. relosuirvir low 1. tiall hi4h K: vitatuttles tot
mind "aams an AP ". Tit 1. Zoo 1. 1114 1. and at vidilcu.16.
P- IloO ROH. COt-- Bilb- (2) "covskill." clume-
444 i~ mo r I*.; E. io~ odectrostatic chscur,
ko(les; examples Wevotnal atoms are Au* 'fiff" Ph**
Hit+ TIO addends $A--, V CNS-, W. 6N.1l..
(5) elbooncterised 6 high 1, low fi, hi~,h
elm. chotitow and susbill P, vxAmpk% are Cob s. Pitt Rh -
loll. Cos' Cob"' and ills, adsessits Co.-- C.Ijo.--:
CN-. - (4 "inlr;vnediate," chamoctioml by tuedium
valurs of all onern chiractcristirs; examples am '41 # %
Znl* Coll, ve A4 * Cu 4L C4 a 0 and the addods
#e I
N
#h. olls(Alljo,
arlectivity In comims jumistim sisil dlffcftnm of soabitity
be lnlcqwttcd from th6 point
of complex inbas in soln.
can
of view, N. Tbon

torm4l niannulne nalts of
villsimirsoUr, Xhur
015shchef Xlill~n'"Icn
Min
.
.
.
-10.
'TTMMtI050).-'Fwo new conipk-x mitz.of Co(IlIF
were 5~nthrsixed. [COW113) 11COills M. f0d CrYstdl'J,
was 0 allied with a 057q yield,liVo-min. heating 5 g.
f C
hl
id
C
CI
ith 1
0
l
(N
Cl
c
or
o
m
.
o purpurcoc
0
e, l
L
s, w
J
of a Concd. Soln. of TIC01K collig" approx. all 8-fold
PXCC% Of HCOIX, $111KCQUCHt' WINIflif 131 file Cooked M:
-ioln. with An equttl vol, of Wit. KI, ond washing the prit.
'with Ict wu(cr, alf. n1c.. sitill filially Ud!(" RIC, With a
sitd, oln, of r4H,NO, instead at KI; a red prit. of (Co.
yield.
(,V]1,)j1JC0zj(JV0j)j (11) %%,is obtilned in a por,
I H 5oln. of Na,S at 25*
The licals of reactimt with a ().26
wtre detil., for 1, to be -3110c-al.,and for 11, to be -4W.
cal./mote. Iliebcstsoftoin.inlf.Ovt-crrdctd.tobel4780
and cal./mole, resp. Hence, and with the use of
tht th~rtnnchrm. data of Hichowsky, anti Rossini, the
standAt.1 he-als of fortriation 111: 1 the solid salts vere
"
kcal./mole, and ter the:~
calcd. to be 1 -261.2, 11 -334J
ion lCo(NITs)JIC0j ++ in aq. solri.. -219.7. kcal.imak.
For the gaseous ion [Co(NIII)SIlco-l". the beat of
formal ion wa5 calcd. to be 104 kcal./tnolc w-ith the aid or the
lCapust'iskil c(Ination for the lattice energy with the
i
A
If
u-iof the Ion assumed - 2.30
.
ence,
thernioclicin. rad
Ihr beat of-flit, n-action Co~~4 (g-
,%) + Will, Qas) +
-If CO.- fir.'s) - jCO(xjI1)&IIC4j~l -- (gas) + IV is x -
3r, kcal., where x - beat of formation of the gascous
Col-". Consequently, the thermalstabilRyof (lie gase.
ous [Co(NII.).IIC0xj ++ is greater Ilinit the stability of
-all other acidopentammitte C,)(111) ions, with the excep-
lion of jCo(N1Ij),N0.) ". The stability of these com-
Ions dr 11C01- 5 CNS- >
ple creases In the order N0j
I-, Cf- On

to 0 4) of a A) 'A as
D ItI ~C
A
T7 ~_.7_
1714
THR PRODUM Of SOLUSIU" OF COKPLgX SALIM.
K.B.'ralatutphY.
Using A 116001`011tal ANNUb 1110 Me led to The discovery of .100
tortam focAutuss in the solumuty at almle 10RIC coo-
poumb (Kap"Isaff OW Tatsiffilrow. ZME, Fla, KAI!L
06 1171(1941)), 1& sm"Is to made of familiumostat factors that
00 deformation the solmitility of complex oaks, "a., dissensions Ire 0
of low. their chiarges. WW the presence of pw" or hydro- =0*
philaws grave to their compositions. Regularities are a@.r
coo
Fo-smut-~ an mmeati. a wtersecon in 0. nowmilty
r* 0
certalm -of commimllow Sam, AW coadiumis are so
so It Conk um*W vbtcb difficultly suitable comwleassi can be ob-
talmoill. 11 can be stmed that in Gror to ounia a jwtmkly
AA"-Jt
*MUM@ compimmad of a givem Cosviox t0&, or, man peorally,
&&A
of a given large tm (r), I A). UOOAT WAMcloody largo Ion of
00-its 04M Sent With 4 maxissal Possible charge, mut be
"1008C tM 02" of both Kan&m in a certain o0imal Vote-
tiom to each other; the gives Ion sumat not contain hydrophilous 0
groLwo, vNio a well-esprtamod polarity writ2tin Uut too to too
AITALLU"ICAL UTINAt'WIN CLASISFICATWO
4*4 iw ov cat 211111 C" C.. It,
tL is AV i0 ml AV ew 0 Is 9 1 If If 0 At 0 3 1 T
at It It It It It a99 it ofn1W4
gi o0
00 00 0 0 00,00 Ato 0 41 0At 0000 0,411 000009 06 0 0 0
I 0i* a 0 0 9 S'"* 0 At 0 0. 0 0 0 0 41 It a 0 9 0 0 0 0 0
6-0000

14 V_1__:z5_TVf V1 TVDWX_T__ - - ----
_her~~Phemfg!7 tnplez wpounds with y1ene-
2,., X tof ~c
X. I . ~
L t.- V 1--Zhur, 0 Miz il"Whint"O
ChcM.) zo, 21491 0---ii)).-Caloritnetric me-awrellicutl lit
-M
25' gave for the heats,.)[ the reaction of the complex salts
"I t be followiali; values (cu - NIT,CII,CIT%M1I'):
[Cden,10, 4G.43; lCdcn,)Brs 3U.2; [Nien,10011%0
39.00; 114i e Irl 37.64; J!,ficollf, .15.41 kral./mole.
From _T1 (cryst.) +-GI1CJ,uq. -- NOI aq. 4-
q -,iq. + q,. and dettis. of the
3enHj++.nq.+15C[ .:tq.+2X
brats of soln, thi: licats of formation of the complexsalts in
the standard stat:e were calcd. to: fCd cn;JCIt 101
enilDr, 149.0, IM en,10t 10.1, (Nien,113r, 148.0. IM
ensjlillg.G,[Nif~u3]Clt.2ff:0300.7,[NienilBr2.2ilt0r)00.4
81.5 Itcod./ineir- The energir, AV, of biniiing of x~is
en by the gxwouii inual Ion At to form the gurom com.
plex Ion 11A ens) !!+, Is utd, fronj the lattice tnergy U of the
cryst. complex nalts, (11.1 cajjX2' (cryst.) - (Nf en,j
(gaseous) + 2X- (gaseou5) - U. whem U is calod. by
Kapastinskil's equation (CA, 38. 57051), with the thermo-
eficin. radii of all complex ions IM ens] 2.7 A. This
gives for IV NP + 3W Zn + 4 372, Co 4 + 372, Fe 3-12,
Cd+1"323kLj./jisolc. ~he order of the heats of bindingof
3 en by these font! is the same as that of the beats of binding
of 0 NHj; the Ilitter are lower by-B-13 kcal, From the
difference of the heats of formation of the anljyd. and the
hydrated salts. the beats of hydration am calcd to IN!
ensIC12.21110 10A1, jNICnjJBr2.2IJ:0 5.9, [Nientilt.21-IsO
3.6. The abuonital increase of the heats of hydration from
the iodide to thtt chloride cum be explihied by a_-unjing
hydration of the anion rather than the cation. N. 'r
r

olu "ill 01
43,
gm
-,i z,

OLI
Pies 060pow -40 my
its9*00 d ""I brou"VO). Kkim-
T hnAl 11" "
cinits. rv j last. AMU.
I 4MRW. 1Me h
Auk (C'A. 49.
I had. I low
s" of vivriout wor
F
D4 il~~~IMi,,-,,Itl~P,,~:"".~~,.-P"-.,~~WW'.1,-Yg.,~--~~-1,:-C-'f,- I
ar
-2,-, M 1111- IN I-&

Thanuccliernistry air tit* itoo." Infilsongs-K-,
U-41voluiv clstill- *i~
ollivilt Trelis I ,
A of, Saiak S~SA,R- 71. "Itil - 106 .1if ig it. 114'.Sl
of fticuolksom W llw hythmed Cis" I 1cm calammed to for
a v'j kcAl. l1rom the fro 0 energy, with give entratty
ej (be Ion in voln. tAked rtliml to Oro 40 Is-1 1 1), thr
f0knovinji heatol col Immakoo o( the insupt-i; Ion ill vvin,
froin tfw britAoir.1 vemi.sl im and adsictid) are cak-d.!
I
(11) MA:
41.7. 1co(SiloWlsol "t (IV)
~1-04CO(Nlloh-
(%'(N)sl* (VII M-0; lfl-jC(dNIfm),Chj* (VU) LUIA;
(VIIII A14: 1.6-1011 N110ANI Ist-
01' 031) 49-3i Is IXI 0111,
N,I19)t(SOp),I tXI) 47.11. lColl(NO0.1 (XIII
.11. Front thrlor dAla, the fir.At� Of 4fiAplU1V1lW1lt 14
,NO# toy V - 11. O.UP: VI - 11, -1).S; It - 1.
"IV. -0.0; IX His -7,0; XII - VI,
X1 - VI, +6.9; VI 1. -2A ". licuts of
=11hent of 1406 by 1120 are. V - T~ -7.3; U - IV,
8.1. ite-Atso(diigarvnwntoIN(hbyCIm.V-M,
-3.8; 11 - 111. - 11.4; IX - VU, -17J kcW. ifeats.
id dimspLarvuscut M Nits by Cl: U - IX, -3.8; 1 - M,
-W.2; III - Vlf. -9.7. Ill - VM, Mplacr.-
itsornt tit Nil If - X. -7.6; 1 - IV. -641.
.0 by Cl: X - IX, -4-3.7; IV - Ill
Illuxtrate 0W totommitAlity Li
thoortommilem. tunouiviovitt it thr trao. infiggentv, lot I 1W
caw of Co... coomPtroles. (IN soctirls 61 Mh' > sM,
11.0 > Cl-. The momelitrifity to Itatt- Indulonce tie.
riftswis in thAt order. Lt. i tie 11CAt CfICVC ~MVQTnpAfiyhlg the
MV1114til bY Milo, 1-"1WlW1 -11LA0 if It 1, -61p*11 I,y
Nits tit M0, Is"d ."usli-I ith Cl b$ Ifir lial't
In flis, ditislAvelliclil 44 2 Nt),.Ihe I !)~Snwl 111-2 it
with MI. is"Wirr with XI, Alld lord, with Nil, so giant
posilkwistoWN. 'The isvow ormi" Apply todilopkcrinmi of
Nita anti III, I lUl-, the br.41 11, ft let -gth NO, Ill
trunspositivoloolo ll'ot too than wi t.,4414m Witithat
position. This mier Is revrrmf in the dis-pla&awnt of
Nil# or 11#0 fly asid in the dillp6mgownt of Cl-
by any of the midcrids rignsWercil. Thome Licts can Iv
Intensirtell by asatiming Wt. of The two d-, one S-. 4n4
three f4milso tit the ortoshedgem the J4KNUIt Art (he ttKMt
siml dw P.IKM411 Mc lrl4,l StAbie, 141"1 that (he Iiff~frllt
trudrney appeAris its Avor.Lw Ill lite v4d,-j %ill-
11.0 > Cl*-. For NOy, the tosiml
depending on w1wother the NO, voulp is bouitol by 0- or
by al-boods; this diffetenco: is h-st lcoomrsmi fcw Sit.
and 140. mid scemol to ch-Apprar moupiclely for Cl .
TU% conclusion Is home out by the licuts wil folgrutsom
AU of crougetric: honvers. Czoceo4mis, with om NO,
group bKxmd by a p4md. the other by a d.lxmd. have A
Allibart davo-loca. with both -N0.xro:s-td-bmdo,%J.
lower
In the caft of pmw&- and vialro-sAlts. the trans immigia.
with the Cl- ions tossund by d-And p-bA.J., loaj, the higher
Ail. problibly loss A rs-Wo isf 11w ineoplovenie nature of the
N. Tlwvt

Thermochami3try of complux compo-,inds lzd-vo Akad-=il nauk
sssit, 1951. (mic P,3-P,4~ Collat'icri of thz original: 210 p.
I'Alicrofilm T-14

USSR/C~emistry Analytical Reactions JulAug 51
and Reagents
"Classification of Analytical Reactions and Rea-
_~t gents on the Basis of the Energy Characteristics
r-4 of Ions," K. B. Yatsimirskiy, Ivanovo Chem-Technol
2 inst
"Zhur Analit Xhim" Vol VI, No 4, pp 211-217
"Cuialent characteristic" of given ion, or tendency
of ion to form covalent bond (calcd as difference
betwen ion's.ionization potential and its beat of
hydration), electron charge, and ionic radius pro-
date for. classification of ions for analyt..
183T24
USSR/Chemistry 7-~'AnalyticELl Reactions IJ~jl/kug ~l
and Reagents (Contd)
Purposes. Gives tables Of above values for many
anions and. gen rules for prediction Of soly ~ten
larticular anion.and cation are present in soln.
P~:LC
Cn
E-4
"I
>1

Z;~ V -
Gdf Onic
roma
jqOLnj1 If -hli Voil- 0, f
80,
it hI 1' 0101 (J
Am and
ON
__Dt' 1~ "i" ItO
C,
21 All, cl (111)
It's) tv crKON,
of jI%C
pp - i .., I Ile C" 4
-witil Tile M Y j"C 11pts. it, llic -4)ly -
gave rot r ,fit ir gro"I" kle rulic-ll;
10I(p I int.1141(iction o
TIL Ow m
20' jN111 or C0,11 grqluv~ "cPII. Of 01114:;
011,
1.11 ") till: .401Y. IU11 the Co"11)" asible.
9,YCI
CINICC (,F( c0", ~ I
Ves Pill%. %y It,, I 'jjjf')jjt1r. Act(I - I)y titlell 111-11% Itilly be fl:
(C ff'CISOOSO Yullow" - I f,4)IY 5
At elff, N SOO', ye
C110W..1cy N11OW j(6jj[jjA1SOl)j'
GNSOOS. Y J~IKCONI"')t 5 tilro ant'109',11'44)
t 40 ; , Tile C 11 cis
t.20
I
3 ITO c
U all gmen.
IV p Wl INh dil
I r(. '01.).H611-ca in r.1'1"r .
Clio ; gives ppts. eve'.1,1", 11". galts .1 r yellow"
'01 le's Sol. r I SO,),
Yb= all F-ven '(CO(Nffl)al~
Y'
c1l Z11, C(I.
IC wit t d I salts %%Wt
it, ali 11 c
rly ar AI)Ut ar
enttollc

USSR/Chemistry Analytical Feb 51

"Problem of the Variation of Free Energy and
Entropy
.
in Reactions of Formation of Complexes," K. B. Yat-
slmirskiy, Chair of Analyt Chem, Chemicotech inst
j I'vanovo
-
"
Vol XXV, No 2, pp 221-223
Zhur Fiz Khim

Advances hypothesis, based on entropy data for R02-
CC2-, Moq-), that only thermocbem ra~
ions (i.e.
,
dius determined entropy of single-type complex ions
(i.e those having equal number of same groups com-
bined to cen ion). Shoiis difference between heat
effect and free energy to be const in single-type

184T33
.
USSR/Chemistry Analytical (Coutd) Feb 51.

complex formation. Arranges anions aud cations by
decreasing stability, latter assumed to be detd by
difference between ionization potential of cen atom
and heat of hydration of ion formet~.

4

184T33

VA

skbky sooftets $I I
i1oliouliskau mw= lost I"mm) Axr,
low.All. 47"INO.-Sairlier tbtw"W P"dictinto
(C.A. 49, 01 lq) CVWKVf1%IUS tbt rtiall" rAaIAMty of cum-
10 odn'sor"Wilbyr j,kod tallordrin,st
!11!~n w I I
4 ow stabl"N X, .On-
Movil. X, -- 11 -1 um
Theva K, - 1.15 X HO
1pbld. CN
wid Kt - 2Z .1 w aftled by mea C the vol o(
Tbc-lyo uct 07ib.
.4Aismhac4kd,:3.WXI0-v- Thevahm -0-514foul"I
Isy mrsswing the only. of P14CNAN In mq~ snl"s, td KCSS,
The WAY. pmfurt at 144CM0,14 2.1ki X 10-0. MAY, the
~fafilftr enmf. K' Pbflrs- Is r%cd. fmn the dam o( liunuge
CA, 20. 3Vr-,); it h approx. 2 x Ifol. vahms of K..
X and K , con6rru the thewy. %Ikbtf Houdart

Lz- -a.;
1-4
is&
rv--

Cant do with anions its gool "&lion Confols.
I'
Cb
l
)
I
rill..
lnn
rv
,
ntl.). P0.
77, m I is, r.1 I U,) I ),-Fxvsw a tile
Ifutl4l of thi rivitlrilt. if. Ittitil ('11140folf in mine.
ctlildhit"ll lot the I(dmAti.m Ill colmdes Ions Willi cathtn't at fit the te"Ch tiff atiAloptus romplelles V-11h .1.1~141 vallime
AlldeMill Wall AnIGHS A% tvillral alums life li,w election affmitv
1
h
b
h other than Ag",delits, weir ma,le ill t tic *-Iv, 411 C I, Its aq.
bof I
ONOA: sell" "1 (1.10 are
s
of I I
I
41111 *fill
of t
e *11
fIcVtFIln allillity of the lnAtioll. i.e. low
ill
And high icMiUtioln ImlitutiAls. resp.. III thr Cmrsimildilix ,
In
n
.
X
0,7210, 1.21M. itioleltIlflIvIl c. UP. flat,
Alonlv~ In aq, m4n., lilt drig. "vignitu,ir Is the Ijflr1rjU,r
4
t
l
I
1fi
i
1 14.5 M.S. 110.3, 149.0, 2091 tmiltinjut"/l lite C. lilt), The
indicitirs pirsener not oulY of list *
m III tilt sill
%t incir
f
l1
r
C17
hl" 4
lY Alil
flirli(V 41
mn-titiently.
Nvosr,ll A.Mcm). .111 1.- ealk-us *I Ito III'llf high rift'llut. i
a
y.
I)llt al%Lll)f Its,[ Ili ... is the .Iv. dau, lherquil rotitti.
41111111Y And tAllit Iwill-tilmiv Au'. A,- lilt' I
' air 4A '.K 10-11. Ills"11111"
Cd * I, Aml III) , I I It, .1"tNe %all% fis"Ild Ill lhe
A 0 rill,
I IllSol ' I 'I - 2, 1 X Ill I'All dirl 41IM1,11-rN III this (TIW
AW -AffINOt, A llt~AONO., ansl ASI-AgNt ),
'
tIll oft doutih; *111% vIttioultly J-11hell its lite Old Illetailler.
1
I
Ite florluldolvi 119#01h. 1A9,11(NAlp, JA9,110SM Im" 41
, ,
which should he fommLilctl IIIjJS X1. 10II4%IX 111
1 N
IAI,CIINO,. Vtosin t,.ta .I Itellit-IC f? 1,,
i0mv 1 18,SVICII. If . it,.
.
(CI04', 11, - .
I
1
mmill)(m thrv,ly.-,l As lmhdv~ tit ~,hmof Apl%'tl_
is, Imi Y rtimplell I-ltle, -itch 014 IIIIIIS
X.,
thete it" 1111
,
the 6-141"ittig -lud- tvum%, lie t,td.t IAK '[`if 'I :lAg,l purnill" of CO)IIII01tes with A r1plorol 114k r"Ital
().K X itv,'; IAX'jIjIIr-j!jAx,ItvIJ - a X 141 mons ire ill# Coniltill, drtivil-I fly I'Arck 00#1 ThIlitilli'l
'
JAs*IIjCI-IjjAsjCPj - ;.' X Thilis. the stabibly tilti, MiAll)(NONti, Itit-I
tier. 16, 243,1I(IM)), IAOIRN
'
l
(If the" rompir%ts hicreaws Willa 'ferreal'ing iv-plilmlil"I rmi- rho"
AsiM(NOP's. N.

Tho verlatill: flow of D. L mendelf1tv tud the stability of
Complex Compsivedg. A. A. Grintserl and K. IS, Vatsimir-
SU Is"u. Ak.14. Novi S.S.S.R.. Oskl.-KArK-1hWk
'I"i. 21 1-17,-The tendency to coniplex forination is chat.
SCIVIt"d iltill"litalively by The energics tot torniation of the
itasse" complex kme. anti by the Invishility cullst. K of the
cOMPION. the latter magnilt4d* actwdly express" the diiy,r.
Coco of The Stability, of the Complex Ion and Of
Ing aqua ion. From & theen,oc the Corre-
tvi. hem. cycle involving
rmaw" of a complex JM from %I" + xA.
the but 12 All - (IV, - IV*) 4, (,Ll - tj) + x(lj -- X,),
where IV# and Wive the criergirsill'Addri. of Holland of A.
MP" to
the Ofieou$ hill, It And 1. Arv tim heas of by.
dr.illonal MA.1"arld Mill.. matt 14 si"d At
the beat ~ cvapn.. of IIA) &ad of hydration of A. Yelp..
The tatter term being coast. for rexc6ons of one ty
ttle middle term approx. const'. .141 As W, - HIP". and
I ) + C
and R r in A: As - S (coast.). This
tiffs the re4tion betwera-lbe 2 of the lead.
rwy to Compka (ornuflon. Thfil rrliwn to veillied by
dAlA for 134 '4IIAJ'*.
2CO call Is. I ,,I, Carl * *
'arklizato)--
that the stability Of COMP14'sts lucte". from left to right in
the period anti &CMASti IMM top 40 b"itant In the grotips of
wimlic system. For tons with 1841ectron %bell$, the
the %inj At ~ no.
compitA stability ought to 110CMAW With InOrg
In The groaps if the band to pralamia4ittir lank; with Ple*
doodnwilly covalent bungling, 9tt'llctitt Of the "th Wind
Should form particularly stable complevs, As a result of
the 2 antAgo"Istic facto". the keat 01porumtAhtinam"mubt c4minus;
complex Was within a oibliroup -
flumple - M Ca 13 1. -
A are for complex ion*
Ali lift. An I&) kcal-frunle. NMI k-
Xn alut. Of 311. If 'd kcAl.1twile. The 14rat is found
fpr the fice-vieflY kInse Ar A, mr Ito K of fa-li- .4
, I the co-
comples loas in 4,71 JOI.. The ovate pr
vknt character 0 the bond, tilt "" '"Ark"d is the if-
crease of the stability (IF) of the complex Ion$ from top to
baltons; this Is Illu%truted by comparison of IF fair complez
chlorides, brumides, and intilles. the lAtter showing the
most mafked chance of IF froat Cu to All or from Zn to ifs..
c1do4les the Irist mArked. In ser" CJ complel
and the
8 with an laert.SAI structurv jWT the outer clectro" shelf.
but different charge grid fdjus. II;js leA,is 10 lons formed by central low with the sarae charge, but with
I he conclusion different naler-electron shell structures, the compka sLa.
--7
_0
'Rim
~t t~q '.; V-0101- -
9

YATSIMIRSKIY, K.B.; ASTASWA, A.A.
Slightly ar-luble complex compounds of thiourea and th-eir use in P-173is.
J. Anal. Chem. UwS-S-R- 7. 45-9 152 [Engl. translation].
(CA 47 no.19:9810 '53)

Monthl List of Russian Accessions. Library of Congress. November, 1952$ Unclassified,

S
ome "0 '1-1 Z. B.

G47 07,7m.-u-S. Oil
-
Mt f a Al.
gI translation); Zliar. Obibehel Khfix. 22, WWII
~2i.-Mien halitics of CII (1) mid Ag t1i,,mlye in solm. of
Chendcai Abst Th
lubiliti
f C
l
d (!
CN8 l
hi
fi

Vol ~ 48
No. 9 e so
es o
ct-tul
u
mi
it t
u
tte solim.
wcre measured at various temps, asid the ittabilily ci:,jj~tg.
~

May l0i 1954' were caled. Inr the remultant jCul$,Ojj,-- aml (Cu(Cj%8)
as 3.1 X 10-18 alid 13 x 10,11
On the
reop
Inorganic.Chemistrjr .
,
nagis of literature datit for the solubilities oF Ag ludigle-4 lit
*
thicicyanate and thiosulfate 1
0311m.. the following btability

corvits. were c.
-ded,: (Ag(CN.S).)---, 1.0 ~1:- O,A X 10-11,
-13; (AgClO,0,1--, 0.7~ X 10-10;
AgICNSJ 7.1 X 10
l
AgBrSzQ;]--,4.1 X 10-11; [Agl-'-Qjl-7,2.7 X 10-*.

Ch '141 Abst. Ov dj4,,,
V017~46 No. 1 9
MAY lot 1954 -1 - ..1 ~ 11: . I . '0 --
Gone it W t
ral and Physic ZOO;,,
;W IV. 17., L-54
al Chemistry 753 MO
47.10984,

YAT.Sil.IIRSKIYO K. B.
Compounds, Complex
"Thermochemistry of complex compounds."
Reviewed by 0. Ye. Zvyagintsev., Zhur. prikl.
khim., 25, No. 7. 1952.
Monthly List of Russian Accesi3ions, Library of Congress, November 1952, UTILASSIFIED.

USSR/Chemistry Cadmi= &Vd TenA Feb 52
"Entropy Changes During Formation of Complex Halides
in Aqueous Solutions," K. B. Yatsimirskiy, A. A.
Astasheva, Ivanovo Chem-Technol T-ust
"Zhur Piz Xhiza" Vol XM, No 2,, pp 239-243
Caled.eutropychanges occurring during formation of
some hallde and cyanide complexes as well as'std
MIZpjIe Il complex ions and mols in aq soln .
.: for
(2 Detd heats'of mixing of Cd(NO3)2 and
Pb(N03)2 solns with KI solas. On.the basis, of emptl
data, caled heat effects of formation of ions
=49
CdIk pbI4 CdI 3 in aq soin as well as contin-
gmt entropy changes. Showed that piblished re-
=1ts ion heaU of formtIon Of CdCl2 and PbX4' are
in:need of correction.,
~4 2=49
Z-4
34

I" cowiWIS, of bull,"
Nraw-2 WId =Tftrwr,(=
), ZA.". Pa. Kki.. 6~6912-1
7SM 1. M At 0 OW AI'O 8 1
WOU'v-1,1tt 1.05 1 1 1140i M, ;;~ I*.'wI WF(g(Nlolfk
at 26" is 118, 14 276,443, 661, M, 1290, and WIS X 10-1
Itat" the fast t- V, - be ITIwe-
5 OAN St/t T b= A, 1. WWI; C Is the
H amtpkttdbwu. being assumed. Tbala-
Clem UNI.Vecuumt beesplabstd by the lack strenath J
Of dK NOW- Of SbKr#&00*kh CAW WheltJ ft%WtW OWW- (ht
udxt%. 01 US(N%)s OW ~CO*)# at J - 6). As 3 cw-
tab" te"I" In 41/1 and Olt iincresse of S is due to foram.
'tions. Frow the abore stpotion
AT~ f';S=HA%. O.OWS; Asistbeso
7M , JIj. Product
X10-441stbeings itycow.
01HEIIII'loid s-1-77XIO-11theinstabifty-, of
Tits soly. was detd. in the wjW manner mid also
tiw;Wg Hg(NOA)s soins. with XI to opakwence.
MOMMU

ire nir-,l :11-
-v-i4
f~i tlv~ or ~Mltkl -fiel nf j,,,jj r,.,.;
Lt.

. .71 ~ , ~1- ,

YA T S 1041
f thit ebstnents.
St LbURY 4ekre
Ic -Wl-
i Lid Ne!:k
A 4
1 44
6'. 1, Ell-

ygT,)jMjRSKII$ K. B,

The ra of the so-callail >eighting effect." -K. D.
v
-
1
KO". 8, 3 4-2
00 ),-
fhe
pmd by Feigl (C.A. 19, 1108) according W which an lit-
crease in the mol. W,I t cases thesewnitivity of
MHR
~
t wictly true. The
,CA
reactluil LS It
the latter toward I ii
analysis outlined in C-4. 43, MAN and 45, Me is APPIW
here toorg. reagents. It 13 shown that sildn. of va"is grotipi
into an itmalytical reskent causes a thanse In the free energy
Vol. 1*8~ No- 4 !of Its lattice. Relilticenicht of it In a C-Tf group by bume
Feb. 257 1954 lother group causes a change In the log of soly. (a log 5) by
Analytical cbemistry approx. the same valite. For OH, a log S ~1,50 i.e. the soly,
!increases approx. 30 tintes. - For other groups a log S is for
ICut -0.60, CtIl, -2.1. Cl -0.4, Dr -0.5. and 1 -1.0.
Thn effect of added ClIj groups was studied on LI, Ca, and
134 fatty and salo. For these salts -A log SIn was calcd.
where n Istheno. of.CH3 groups. Each addid. C112 caused

f oma'ic
dda a,
(In. of aromatic,
h Ad
c 0 0 c ease by a" 0
I d -
g
,
~c - -
"a ' 10
hyroi
y
rt-11 -d
t
f It ;' but
d I t
--a- it to p
suly
Ph-bi go- -c s"
t hic I
it . y t _g,. w ca s
e he
ol a
t e ied
,

ns
h
to
tw
N

YATSIMIRSKIY, K.B.
1 Stability of compi,sx co--pounas in aqueous solutions. Uspekhi KhimaUp
7
4io-41P '53- (MLdA 6:4)
(CA 47 no.190841 153)

UTS114IRSKly, X.B.; GwOVA, Z-M-
..... .... - . jum complexes in water solution. zhur.ob.
Thermochemistry of 3upramxoon (MLRA 6:5)
uo.5:717-7:20 My '53,
khIm. 23
1. Ivanovskiy kh,milco-takhnologichookiy inatitut- y) (Compounds, 00mPIGIO
(Thermochomistr
E229~~~

W" ZIT--r1-r A -4-5. Mle -
f If cd 241J tl','l -101 11 , c;
711 k. V I
ml;, ac-.d. mci-d in 'L ,11us r, atre intcrvCat~imltc'
rt 25' !21ues rJ H F~ U to V111 are - WOO. - I 1 .11 i
-14SO, - 11.58. - 9.80, - 8 4A. and - 1.1.42 kcal , nvaLz.
~- V. %( usuced v-&(uts of the himt cd coin at 2V in I ol
~'.t knCl,.414,0. FtcLi' C-k-1, NMI Ml~c.
-j-,~ z'~i t& -. ~ -, - A " " -F
i rW. ~ I -.- k - x '' -11-,i,
Ix 17 rll-
~w r t- .1 11 Vill ha- 1h,
A ;. -.A. I . - A~ 4
wd627 1 kmi-Irnotc, r"p . sna Ks is t~. hirm
'j the An Anion. J. W. Loweberg. j I J.

r
3

USSR/qbemistry Cadmium, Palladium~ Oct., 53
Avd',Blgmutb~:Compounds,~-'

Themochemistry of Complex Thiourea Compounds
in,Aqueous,-Solutions,",'K. B. Tatsimirskij,--?~k. A.
An f,~~Ivanovo Chem-Technol Inst
tasheva.
Zhur Fiz KhIm, Vol 27, No 10, PP 1539~44-
Detd the heat of mixing of solns of the salts
AgN%, Hg(]M~)21 Cd(NOI)2, CdBr., 012, Pd (-NO )2Y.
ii
-
Bi("031 an CuCHS with thiourea solns of d
ferent conc-nr,. Detd the changes of enthalpy

272T12

and.entropy in connection with the formation Of,
complexIions from Ag+, Cu+, Cd2+, and Fb + with
thiourea. EstizMted the conjatant of Instsbility K of
~Akv (thioureaj41" to be 1.1 :k lo-33 o
[Hg n the basis.
'
data.
of thermochemical

272T12

KA"

r t
r

-j arge anions, R~id

4
VWy
"3l 2470.~The MeA lon was adaed to
PlIxIlhCHON (1)
I
tolm. of different anionq. I pptlt. Crl()?-- $04-- jPC-
-
4'-
;4
A
9(1.
, and I(Aidc. S'SISM
ty of th
, jI?tfCN).j
(CN~16
l
1- wcre plimagTitplit-t, A Af,
actions was letd. The cry%ta
~:In Mill of let
.
I.With StO~-- white dend ritei pptd. from c,)ncd.%oIns.(abovr.
stals.
Dill SoIns. gave cry A Af ICI solu. did not i
R. Ot-- but when a ICI,
_,jorrn a lipt. in solm. CoQtK.