SCIENTIFIC ABSTRACT YEMELYANCHIKOV, A.N - YEMELYANENKO, O.V.
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SCIENTIFIC ABSTRACT
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YEIELIYAICHIKOV) A.N.1 kand.tekhn.nauk; PATRANIIIAp O.Pe, inzh.
IDireasing the output of ski blanks in the Vologda Fumiture
Factory. Der.prom. 3.1 no-41l7-19 AP :62. OMIMA 15:4)
1, Arkhangeltakiy lesotekhnichookiy irwtitut im. V.V.Kuybysheva.
(Vologdar-Skis and skiing)
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-dertrode frons dq. tolds. of thetr "ti with varifju ralnus
vw r-tudied for the purpose of elu6lathig the nature of sec.
ftd W-rntials; (Kudra, 7'ru:iy PA Vies". Kj
reewel. i P,iklad. Ek*,AWn.. Akad. JV-s6 Mr.
104D, 47-432). The animts were: SO.--, NO.-, Cl-. 1-.
ctfmcot-. M---. csil,04- -1 C.114()7---.
and The wrmspooding ,~l and salts -re
ad-L-d sts anit'bry clectroly". The- patru "i of tile. 7mi
wi-Am (swond pottntitl) In all cams wa4 attritAitable not to
.the -ib-charge of cornpl~ metal ",5 but ~fh--r to the evulu-
tinnoll-I(-I-SvAnacklmedium, -2, in-till.r.in
the C.Se of flltmt~, reductio. 0( l" oot-j. q..la. .
alc , or f(na=midc, thc wcond pottonti-N of (u Cd, Ag.
and NN .,,r ilj~ to t~ Vf,itlutm to ., ~1-1-4
ch2ml stw .1 the au. ili.,, - -1-o
the rr~lts -t--J-A f , K.d-
second potenimh to M~ roluction cA ~imjj,rx tom c;f Itic
MCA. flowli
C-T
Le r,
?
of
Effed of temossture on Me rata of i-fe-Cirod
Y, jit" Vv
from Std hurid G. A. e i j a Ms It ~v
Mauh 3=, 0.0014, WININKIII-I
temp. cia-the electrolysls of weakly acid .0, solutions, e.g.. the
increase of polarization at temp. above 30*, are explained in term:4
bf chemical clianges occurring on the surface of the Cu cathodo--
for=tion of oxide. hydroxide, or basic Cu safts. TWL is sup-
ported by experiatents which showod that no Yeductlon in the
rate of Cu deposition occurred in a strongly acid solution, also
that, when the e1cctrodcs wtnc immersed in a CUSO' at 40 or 60'
a" then tested for polarization at 15 or 30'. ley gave polarization
COMIS as It the me4surements were being made at 40 or 60'.
Cuffent/potulzation curves arv given for 0-IN-CUSO, at t(!MP.
from 15 to 631 and the correiponding log i- I / I.curves are platted.
1: W KIPmIlpirm.
USSR ectrochemistry B-12
~O /El
Abs Jour : Ref Zhur - Xhimiya, No 8, 1957, 263o6
Author : G.A. Yemellyweako., V.P. Galushko
Title : Nonsteeu!~Woc=ssesi at Electrolysis of Copper and Nickel So-
lutioas.
Orig,Pub : Zh. fiz. khimii) 1956, 30, No 8, 1710-1717
Abstract : The importance of studying the time dependences*of the elec-
trode potential (~ ) and the current density (L ) was dis-
cussed in reference to the, kinetics of electron processes,
and the changes of q and L in time (t ) was studied at a con-
stant voltage on the electrolizer at the electro-deposition of
Cu. and Ki. Cu, was deposited from a solution of 0.1 a.,of CuSO4
+ 0.5 n. of H2SO4 at 20 to 220. It was shown in.the case of
electrodeposition of Cu, that i has a great magaitude at the
beginning of the electrolysis (two secondo after switching
in) and that it decreases~with time, to which the rise of the
negative P in time corresponds-and which is explained by the
considerably great magnitude of the concentration polarization.
If some gelatin was added to the Cu electrolyte (0-01 g per
lit), the magaitude of the initial current at a low electrolizer
Card 1/3
USSR/F.lectrochemistry B-12
Abs Jour : Ref Zhur - Xhlmiyao No 8, 1957, 263o6
voltage (up to 0.16 - 0.17v) decreases in comparison with the
solution without the addition, and, besides, the current
strongly decreases with time, which indicates a strong re-
tardation of the process; a slow rise of the negative Y cor-
responds to it. -A considerably high increase of the current
takes place at greater voltages, which in the opinion of the
authors is caused by the potential of gelatin desorption
having been reached. It is shown on an example with Cu that
it is possible to estimate the applicability of either me-
thod of surface preparation by the method of curves (io t) and
~0 t). Ni was deposited from a solution of 0-5 n. Of NiSO4 +
NH4)2804 (12 9 Per Lit) + NaCl (5 g per lit) (pH - 4.8) ~Lt
n to 220. The curves (i, t) in case of Ni are characterized
by a little initial decrease of i with a following sharp rice
of the current, to which not a decrease, but an increase of
the negative Y of the electrode corresponds. The cuiwee (i, t)
are of the same character in the same solution without NiSO4-
The anode's rides shafply at the beginning and, after thAt,
drops. The opinion is expressed that V is redistrJbuted be-
tween the cathode and the anode, in consequence of which k and
Card 2/3 1
USSR/Electrochemistry B-12
Abs Jour : Ref My, - Rhimiya, No 8, 1957, 263o6
i rise on the cathode. In solutiqns free of NaCl) or if the
Ni anodes were replaced with graphite ones, the abnormal
course of the cat-bde curves (i., t) and (ff, t) is eliminated.
The authors explain the initial retardation at the electrode-
position of Ni by the retardation of the activation of Ni-anodes
by Cl- ions. The cathodeprocess accelerates together with
*be activation of the Ni-anodes in consequence of the greater
falling on the cathode.
Card 3/3
TMV YANMNM,- ~ OA.
The choice of a system oPsigne-fat.the e, m.- f~-ard-farthe
elw6tr
(I= 10:4)
1, Dnepropetrovski7 gosudarstvanny7 universitet.
(Alectronotive for3e) (311actrodem)
nMLIYAIiZfKO, G,A#; GALUSHED, V,P*
Iffect of sulfuric acid solutions on metallic copper at various
tonporatures. Zhar. neorg. khIn. 2 no.12:2834-2837 D 157.
(Copper sulfate) (Copper oxides) (9M 1110
AUTHOR: Emellyanenko G.A.
73-2-17/22
TITLE: Causes of the anomalous course of the dependence of
electric precipitation of copper on the temperature.
(Prichiny anomallnogo khoda zavisimosti skorosti
elektroosazhdeniya medi ot temperatury).
PERIODICAL: "Ukrainskiy Khimicheskiy Zhurnal" (Ukrainian Journal
of Ch=emstry)g Vol.239 1q0-.2, March-April, 1957,
pp.243-250'-,'(USSR).
ABSTRACT: The inveS%4gation of the influence of the temperature
on the veloc.~,y of the electrochemical process procures
additional da"z\% on the mechanism of the process. Syste-
matic investig,,, ions were recently carried out by
S V.Gorbachev k al (ref.2-5). They concluded that the
tLrmal method Yould be used for determining the charac-
ter of pola alion. The basic.-criteria were the course
3u
of the depe ~i se of the log of the current density (lg i)
on the inversie ragnitude of the al,.)polute temperature( I
at constant pol~7isation of the el&l-trode, the value of
the so-called eftective energy of ao,%ivation of the pro-
cess W and its, qeEpn4ence on the pc'Q.a:~Isation of the
Card 1/3 electrode. ,V.GorbanhoT s,tatOd -,~t both the
73-2-17/22
Causes of the anomalous course of the dependence of
electric precipitation of copper on the temperature.
(Cont.)
concentrational and the chemical polarisation are pharac-
terised by a linear course of dependence lg i on ~:. . But
T
for the concentrational polarisation w has a value of
the order of a few calories and is practically independent
from the electrode polarisation, value. The chemical pol-
arisation is in a defined relation to the electrode polar-
isation and w reaches 2 figure values of calories (kh.
cal'. ) To clarify the part of chemical transfozmations
during increased temperatures the author investigated the
influence of the temperature on the velocity of electric
precipitation of copper from sulphuric acid solutions. The
anomalous course of the dependence of the velocity of
electro-precipitation of copper on the temperature was
found to be caused by chemical transformations occurring
on the "metal-liquid" boundary line at increased tempera-
tures. Tile formation of oxidesp their hydrates or basic
Card 2/3 metal salts can be related to such chemical transformat-
ions. The maxima of the curves of the dependence of the
log of the current density on the inverse value of the
73-2-17/22
Causes of the anomalous course of the dependence of
electric precipitation of copper on the temperature.
(Cont.)
absolute temperature are explained. (Diagrams 3, 59 89 9
and 10)'. The polarisation curves for various temperat-
ures and different concentrations of CuSO 4 are shown in
Diagrams 2, 41 6 and 7.
There are 9 diagrams, 1 table and 1 drawing There are
7 Slavic references.
ASSOCIATION: Dnepropetrovsk State University (Dnepropetrovskiy
Gosudarstvennyy Universitet).
SUBMITTED: October 24, 1955. (f irst) , September 10, 1956 (f i.nal)
AVAILABLE: Library of Congress
Oard 3/3
~-Wm
-.1-1 4-- 1 . -
I . f
AUTHOR j
TITLEs
Yemellyanenko, G. A. SOV/76-32-9-26/46
--Oi~ ~nomal~ous Temperature Dependence of the Electrodeposi-
tion Rate of' Copper (Ob anomallnoy zavisimosti skorosti elek-
troesazhdeniya medi ot temperatury)
PERTODICAL: Zhurnal fizicheekoy khimii, 1958, Vol 32, Nr 9, pp 2119-2122
-(USSR)
ABSTRACT: The author investigated 0,1 n CuSO 4 solution. In the first
series of experiments the dissolved oxygen from the air was
driven out with hydrogen, while in the second series it was
allowed to remain in solution. A platinum electrode was used,
and a compact copper layer was allowed to separate out onto it
under a high current density. The current density (i) and the
potential of the eloctrodes wars moacured at difforent tem-
peratures. The results are represented in two graphs as a func-
tion of lg i and 1 (reciprocal of the absolute temperature) at
different potentiLs.
The results so obtained suffice to show that the anomalies
arise through chemical changes on the copper-solution boundary
Card 1/2 under increases in temperature. There the following redox re-
SOV/76-52-9-26/46
On the Anomalous Temperature Dependence of -the Blectrodeposition Rate of
Copper
action takes place to a small extenti Cu + Cu 24, *-A 2 Cu"' . Cu*
hydrolyses and forms a yellow coating of cuproas (I) oxide,
which is transformed into a red coating. The composition of
this coating was analyzed quantitatively and qualitatively
and was found to be practically pure Cu 20. There are 2 figures
and 12 references, 12 of which are Soviet.
ASSOCIATIONs Dnepropetrovskiy gosudarstvennyy universitet (Dnepropetrovsk
State University)
SUBM ITT ED i April 12, 1957
Card 2/2
5W
AUTHOR: Yemellyanon SOV/76-32-11-2/32
TITLE: The Role of Cuprous Oxi0c in the Development of an
"Anomalous" Dependence of the Velocity of Electro-
deposition of Copper on Te-?~raoture (Rollzalkisi medi
v vozniknovenii llanon~Lllnoyll zavisimosti skorosti
cloktroosaz'h,,,1eniya medi ot tomporatury)
PERIODICAL: Zhurnal fizicheskoy khimii, 1959, Vol 32, lir 11,
pp 2479 - 2482 (USSR)
ABSTRACT: The formation0f%oon a copper electrode at
increased temperature was already pointed out
.(Refs 1,2). Together with V.G.Govorukh the author
carried out measurements of the averaje formation
velocity of the Cu 20 deposition on the Cu electrode
in a copper sulfate solution at different temperatures.
The Cu 0 coating was noparated, from the electrode
2 ?
by means of a hot 15,/j ITH Cl solution and determined
gravinmetrically. The autior used CuSO 4 and CuSO 4' 5H20
Card 1/4 solutions. At 40 Cibe velocity of the Cu 20 deposition
The Role of Cuprous Oxide in tbe DevelopMent of an S011/76-32-111-2/"42
"Anomalous" Dependence of the Velocity of Electrodeposition of Copper
on Tomperature
is low, it increase&j however, rapidly with
temperature. According to the de~;rcc of accumulation
of the reaction products the formation velocity of
Cu20 decreases. Thi3 is explained by a partial
oxidation of Cu 20 by the oxy-en dicsolved in the
ell-ctrolyte. The crystalline CU20 layer firmly fixed
to the surface leads to the paszivation of the
corresponding part of the surface. To investijate the
velocity of activation -pascivation of the electrode
surface the elect.ode polarization 6T was measured
at different current densities Yith respect to time.
The electrolysis took place in sulfuric acid solutions
at different temperatures. It was found that the
mininum of t-:e value AT io, with the increase of the
current density, displaced to hiaher' tenperature
values, which is explained by a reduction of the
copper ion content of the layer near the cathode.
The formation of an "anomalouall course of the
Card 2/4 dependence of the rate of --lectrodeposition of
The Role of Cuprous Oxile in the Development of an SOV176-32-11-2171,2
"AnomLlous" Dependence of t,,e yelr)city of Electrodepozit'lLin r~r
on Temperature
copper on temperature is not explained by a phase
polarization but by a complete p.,asivation of the
surface parts of the electrode by CU 20. The increase
in temperature promotes two opposite effects. On
the one hand, the addition of the Cu 0 ions to the
electrode surface is intensified, ang on the other,
the passivation of the electrode surface by the
CU 0 fornation is accelerated. In the first case the
v2ocity of electrolysis increases with temperature, in
the-second it decreases. The increase of e ion
concentration in the solution to prevent the Cu 20
formation and thus to remove the "anomalousif
influence of temperature upon the electrodepocition
of copper was already pointed out (Ref 1). There
are 2 tables and 4 Soviet references.
Card 3/4
The Role of Cuprous Oxide in the Developncnt of an ZOII/76-32-11-2/32
4-
"Anomalous" Dependence of the Velocity of Electrodeposi.ion of Copper
on Temperature
ASSOCIATION: Dnepropetrovskiy gosuda.-stvennyy.iiniversitet im-300-letiya
vossoyedineniya Ukrainy s Rossiyey (Dnepropetrovsk
State University imeni 300th Anniversary of the
Unification of t*-e Ukraine With Russia)
SUBMITTED: March 30, 1957
Card 4/4
oil
iRIGULIM, II.S.,
GA-; SMEMKi V-I-
Zinic-p2ating frm.an emmonts alsetrOlYte., Ukr.khim.shur,,
27 no.6:'828-430 163.. (KMA 34:n)
I'S Dnepropetmvokiy v*ivermitat.
U-MLIYAMIKO) G.A.
Effect of temperature on the rate of the electrodeposition of
zinc from sulfate solutions. Zhurz. fiz.-khim. 35 no.2:393-
400 F 761, (NIRA 16:7)
1. Dnepropetrovskiy gosudarstvennyy universitet.
(Zinc plating)
S/122/62/000/007/oo4/oo6
D262/D308
iUTHORSt Semeryuk, V.Is, Engineer; Yemellyanenkof G.A.,
Candidate of Chemical Sciences ---------
TITLEs Acid electrolyte for cadnium.plating of complex
details
PERIODICALa Yestnik mashinostroyeniya, noe 7P 1962v 42 43
TEXT: The article describes the experiments conducted
with the electrolyte (50 g/litre CdS04 - 8/3 B20 and 56 g/litre
H2SO4) containing additions of si!lfurated naphtalene
(30 mixture
of concentrated sulfurio acid and naphtalene),.galAin and hide glue.-
The results show that these additions improve the diffusing power of
the electrolyte and have considerable positive influence on polarize-
tion and the size of cadmium crystals. This electrolyte is recommen-
ded as a replacement for the cyanide electrolyte. There are 1 figure
and 1 table.
Card 1/1
YFMLIYANWO, G.A.; BAYIIAROVA,, Ye.Ya.
Else trodeposi tion of zizc and lead at given high current densittep.
Ukr,khimozhur, 28 no.7:8'j9-911 162* (HaRL 15M)
1* Dnepropetrovskiy gosudarstvennyy upiveroitete
(Zino platinr) (Lead plating)
Y&ELItANEEKOP G.A,; T..-'*
Effect of t,,-imT;o-rat?iru ;,n thij, eluctrcdepo:~!t-tf),.' of eadm'Aum
fraii riu2fate ""hur. f Iv. khim. 36 no.3:50P-512
Mr 162. (MIPA 17:8)
1. Dnepropetrow-Oldv gosudsrstvonnyy univerviti%t.
AUTHORS: Yemellyanenko,* G. A.,
TITLE: Effect of temperature
metals.
PERIODICAL: Zhurnal fizicheskoy khimii,
S/07 62/036/007/008/010
B101%138
and Alekseyova# Yea Ps
on the electrodeposition of some
v- 369 no. 7, 1962, 1532 - 1536
TEXT: To find the opt:~= temperatures for the electrodeposition of Cuq
Zn,.and Ag from various electrolytes, the curves log i versus 1/T were
plotted. The folloving electrolytes were useds 1~-5 6v/1 CuSO -5H 0
4 2
+ 2.5 9/1 H2 so 4 (1); 200 g11 CuSO 4-5H20 + 50 g/l.H 2S6 4 (11); 450 g11.
ZnSO 0 + 30 9/1 Al (36 ) -18H 0 (111); 17 g1l AgNO (IV), and 40 9/1-
4* 7H2 2 4 3 2 3
~ 200
AgCl g/1 K 4 Pe (CN)6 J-3H 20 + 20 gll--K 2CO3 (V)o-, A deviation from-~-,
linearity was observed for the function log i - f(.I/T). It occurred at
certain polarizations and temperatures and was more distinct at high
polarization. It lies at 40 mv, 40-500C, for electrolyte 1; at 50 mv,
50-600C, or 100 mv, 40 0C, for 11; at 50 mvt 30-40 0C0 for IIII at 10'mv,
Card .1/2
3/076/62/036/007/008/01.0
Effect of temoerature ... B101/B138
400C, or 20 mv, 35 0C, for IV; and-at 30 mv, 350C or 100'mv, 45 0C, for-V.
The activation energy '.'/ for electrolytes I-IV is much lower above than
below the bend in the curve, whereas V shows the opposite behavior to W.
The deviation from linearity and the drop in W for I-IV are attributed
tu transition from chemical to concentfation polarization.- The deviation
of V is attributed to the fact that Ag ions are discharged at low polari-
zation, but complex silver ions at high polarization. Conclusions This
transition from chemical to concentration polarization must be allowed
for when d6ciding the optimum temperature. Optimum temperatures for a
rapid and irreversible process with 0prevailing chemical polarization aret
for I (no data)j II 60'mv, up to 40 C; 111 50 mv, 18-250CI IV (no data);
V 250 mv, 60-80 C. There are 5 figures and 2 tables.
ASZ001ATION; Dnepropetrovskiy goeudaratvennyy universitet (Dnepropetrovsk
State University)
SUBMITTED: May 29, 1961
Card 2/2
YEMIYANENKO G.A.1 SDMJNS G.G,;
1
Blectrodepositim-of copper
high cmTent densities. Ukr.
163.
BAYBAROVAj le.Yao
.1
from sulfuric acid molutions at
khIm. shur. 29 no 4:404-406
iMIRA l6t 6)
1. Dmpropetrovskiy osudarstvennyy universitet,
Popper plating)
IPMLOYANENKO, G.A.j BAYBAROVA, Ye.Ya.j SIHULIN, G.G.
.
Cathodic deposition of zinc and lead at high current densities. Ukr.
khim.zhur. 29 no.5:515-518 163. (HIM 16:9)
1, Dmprtpetrovskiy gosudarotvennyy universitet,
YENELIYAIENKO, G.A.; SDIULIII, G.G.
... - ~ - ~ ".-I.-I.-
Electrodepooitlon of copper from amonia liquors at high
current denaities. Ukr. khim. zhur. 29 no.7t727-730 163,
(MIRA 16t8)
1. Dnepropotrovskiy gosudarstven.W universitet.
(Copper plating)
3/07 65/037/005/015/020
B1 01YI32 15
AUTHORS: Yemollyanenko, G. As, Afanaaenkog Ve I#
TITLE: Effect of temperature on the electrodeposition of chromium
PERIODICAL: Zhurnal "izioheakoy khimli, v. 37, no. 3, 1963, 680-682
TEXT: The effect of temperature on the electrolysis of a solution of
180 g11 CrO 2 + 1.8 g11 H 2so4 was studied between 10 and 600C at constant
polarization of the cathode. The curves log i varsus 105/T show that
the rate of deposition at 20 - 30 0C passes a maximum. This is explained
by thermal and electrical activation of the reducing substance acting
aC,ainst elootrodepoBition, and by inhibited deposition by reaction between
deposited Cr and the cathodic layer whose thickness and properties are
changed by temperature. There are I figure and 2 tables.
ASSOCIATION:% Dnepro~etrovski~ univer3itet (I)nepropetrovsk University)
SUBMITTED: May 25, 1962
Card 1/1
YEWLIYANENKOp G.A.; AFANASEMKO, v.r.
Kinetics of the electrolysis of a chromium electrolyte at
various temperatures. Zhur. fiz. khIn. 37 no-4:915-918 Ap 163.
(MIRA 17M
1. Dnepropetrovskiy gosudarstvennyy universitet.
YEHEL'YANENKO, G.A.; AFANASENKO, V.I.
Anomalous affect of temperature on the rate of electrodeposition
of chromium. Zhur.fiz.khim.., 37 no.8:1854-1857. Ag 163.
(MIRA 160)
1. Dnepropetrovskiy gosudarstvennyy universitet.
(Chromium plating)
YE,%%LIYANTNKO, G.A4; Sit-111,111; G.G.
Oscillographic determination of the transport numberq of ions
in electrolyte solutions. Zhur. 'Liz. khim. 38 no.12.3004-1100'
D 164. (~qRA 18:2)
1. Dnepropetrovskiy gusudarstvennyy universitet.
YEIMIYAIIENKO. G.A.; SIMULIN), G.G.
Causes for the forr,-,Iicn of some loose metal deposit.3 OTI the cathode at
high current densities. Dok2. All SSSR 158 no.5t1186-1189 0 164~
(MIRA 17:10)
1. Dnepropetrovskiy gosudarstvennyy univeraltet. Predstavleno akademi-
kom A.N.Frumkinym.
TEMELIMENKOP, C.A.1 ~IMULIN, G.G.
Oacillographic study of nickel eleotrodopoB.ItIon at bIgh
current densities. tlektrokhtmiia I no.11:1384-1388 N 165.
(MIRA M11)
1. Dnepropetravokly gosudAretvennyy univereltet.
YEW,LIYANENKO, G.A.1 BAYBAROVA, Ye.Ya.
~' ~ .: ~_ ....... ~.-, 11 ~~ - -
Electrodeposition of silver at high current densities. Ukr. khim.
zhur. 31 no.107-41 165. (MIRA 18s5)
1. Dnepropetrovskiy gosudarstvennyy universitot.
-r -A M
'UT.M 400
-ic.afilfatp srolutte-.ni of
KI RP M Of COPPIr 010-Ctr(Aepositfort frcl~ %i,, 4
MOM,filillant cop"r at hign clirrant daroft~wi. m
khtm. zhur. 31
-no.61 581,~-587 165. (MRA 18,s7)
1. Dimpropstrarakly gosiidarstverzi.~ry' unIverultat.
TrYMLIYATRO.,_G. A..) AFANA5FNY,(), V.I.
-hrr
lemrerbture der-ardence of the rat. of o~ .1alun electrodeposition at
iianatant polarization'of t'he cathode. -Zhur. fiz. khljn. 39 no.3t631-
633 W 165. (MIRA 18:7)
1. Dnepropertrovskly-- venrqy universitet.
~sudarst
, '4
- ~ ..!. .. A
L. i ~ - --- - - -- --
, . i J~l ,
YF,MLIYANFNKO G A., SIMULIff, G.G.
on kinetics of cobalt at high current densities.
Electrodepositi (KIRA 18:8)
Zhur. fiz. khIm. 39 no.5$1077-1081 My 165.
1. Dnepropetrovskiy gosudarstvennyy universitet.
YEMLITANENKO, G.A.; SIMLIN, G.G.
Zhur.
.ation of' the transiticn time fer elan
Determir
fiz.'khim. 39 no.-7:3.7301-Wa i1 165.
1. Dnepropotrovsk:V gosudarstvenn-yy ivilverriiiato
YEMEL'yAlIENKO, G.A.2, AFANASENKO, V.I.
Effect of the temperature on the electrodeposition of
chromium. Zhur. fiz. khim. 39 no.4:850-854 'Ap 165.
(MIRA 19:1)
1. Dnepropetrovskiy gosudarstvennyy universitet. Submitted
July 1, 1963.
YEMELIYANFAIKOP G.A.; SDMIN, G.G.
Electrodeposition of copper from thioemifate solutions of
cuprous oxide. Ukr.Wiln.zhur, 31 no.5t4nF8-480 165-
(MIRA 18:12)
1. Dnepropetrovskiy goaudarstvennyy universitet. Submitted
Sept. 25, 1963.
S/080/.62/035/009/008/014
D204/D307
AUTITORS: Yemel'ygnenko,,_G_,_&!'j Baybarova, Ye.Ya.., and Semeryukt
TITIE: The electrodeposition of cadmium,in the presence of
hide lue (A), gelatine (B), aiid oulphonated.naphtha-
lene
,PIMIODICAL: *Zhurnal prikladnoy khimii,-v'. 35j no. 9p 1962p
2007 - 2011
TEXT: The effects of A, Bp and 0 on the electrodeposition of Cd
from a solution containing 50 g CdSO 4. 8/3 E20 and 50 9 H2SO4 per li-
ter were studied at room iemperature, in an effort to improve the
properties of electrolytic cadmium used as anticorrosive coatihgo
on Fe. The cathodic polarization, A ,f t was measured at arious cur-
rent densities, with and without additivesp using a 1 eJ flat catho-
de and a large Cd anode. The greatest increases'in Acp (5NeIOO mV)
were obsbrved with simultaneous additions of A and C or B and C.
/a'c? increased with i (0-4 - 2.0 a/dm2) and passed through maxima
Card 1/2
S/013 62/035/009/008/014
The electrodeposition of cadmium ... D204YD307
with increasing concentration of the additives; e.g. with 1 g IL/litr-,r
A cp ;~as maximum at ev5 g C/l, whilst with 10 g A/1 the polariza-
tion was greatest when 2 - 5 g of C ,,iere added. These effects are
ascribed to the formation of strong adsorption layers of the additi-
ves on the surface of Cd; the layers viere stronger when C was added
to a solution containing 10 g11 of A or B, than when C was added to
those containing only 1gll of either Aor Bo The eventual lowering
of Ay at high concentrations of C is explained by a relative ex-
cess of this additive in the adsorbed layer, over A or Do The ad-
sorbed layers increased the energy barrier for the discharge and
dehydration of Cd ions and facilitated the production of dense,
fine-grain deposits of the metal. There are 3 figures and 2 tables.
SUBMITTED: June 5, 1961
'Card 2/2
YIDMIL'YAIIENKO, G-0- 111"llianenko, H,H,I, kAnd,filon.nAuk, dOtdo
1117ttia. 9 no.4:6-9
t book about the trutb of life
grea (HIR& 12:7)
Ap 159. (Lqnint Vladimir Illich, 1870-i924)'
(Dialectical "aterialiam)
YEMELIYAIMIKO, odavatell
Practice In related jobs is a valuable training wthod. Prof.-takh.obr.
15 no.9-.16 S"58. OGRA 11:11)
Is Lyublinakiy industriallny7 tokbnikum.
(Ityublino-Technical, education)
TEMITAIMIKO, G.G. kand.filoo.nauk, d3ta.
The founder of scientific communism. Hauka i zhyttia 8 no.5:
1-5 1~, '58. (MIRA 13:4)
(Marx, Xarl, 1818-1883)
YMMETIYANWOO I., prepodavatell poikhologii i pedagogiki
I I -
Letts improve pedagogical traini . Frof.-tekh, obr, 20 no.3:19 Hr 163.
(MIRA 16:3)
1. Lyublinskiy industriallnyy tekbnilalm.
(Vocutional education) (Teachers, Training of)
65=� IJP(c) WN/RM
AR6016566 SOURCE CODE: UR/0196/65/0
JAUTHOR: Yemeltyanenkoy L. D.; Tsvetkov, V. He
TITLE: Investigation of properties of translucent and light-diffusing
glass-reinforced_plasticsi~
l
SOURCE: Ref. zh. Elektrotekhnika i energetika, Abso 12V214
REF SOURCE: Sb. Fizika. Dokl. k XXIII Nauchn. konforentaii Leningr. inzh.
stroit, in-t.a, L., 1965, 89-90
TOPIC TAGS: light diffusion coefficientq reinforced plastic# glass
reinforced plastic, translucence coefficient, colored glass reinforced
plastic
ABSTRACT: The measurement results are given of the translucence and
light-diffusion coefficients of 10 types of achromatic and colored RInm
reinforced n1antics manufactured in the USSR to justify their use no
_tganspajelt tructural parts in building constructions Thd -ori .g.' arto,
-has: 1 tab140% G. Vvina. [Translation of abstract]' tAMI
SUB CODE: ll/ SUBM DATE: 00
Card
.EW(e)/E74T(m)/&qP(j)/T IJP(c) 'Ard/RMM1
5017560 SOURCE CODE: UR/0196/66/000/001/BO14/BO14
'AUTHOR: Yemellyanenko,.j.-D.; Obcrin, L. A.-,- Tsvetkov, V. N.
REr SOURCE: Sb. Mika. Dokl. k XXIII Nauchn. konferentsii Leningr. inzh.-stroit.3
in-ta. Le, 1965, 83-86
TITLE: Investigation of certain physical properties of domestic fiber glass
SOURCE: Ref. zh. Elektrotekhnika i energetika, Abe. IB02
TOPIC TAGS: fiber glass, temperature coefficient
TRANSLATION: Thermal, optical and acgustical PrVerties of f~,Pt and corrugated poly-
ester fiber glass based on PH-1 resinPand ZhS-04NIass fibarql%re analyzed. The co-
efficients of,heat transfer (X) and emperature conductivity M for two batches of
specimens (30 x 30 cm) were calculated using the V. S. VolkenshtLe~ method. The aver-
age values for the first batch were a=7.4-10-8 M2js_e'E~,_X_-(F._77 i~jmodeg, and for the
second batch a=6.8*10 8 M2/sec; A=0.2 w/m-deg. 1 figure, 2 references. V. Kostyukov.
SUB CODE: ll/ S
UDC: 621.315.619
Card 1/1 fv
ACC "R' AR6031873
SOURCE CODE: UR/0058/66/000/006/I)093/1)003
Yemellyane
AUTHOR: _nko, 1. D.
TITLZ: Methods of evaluating the optical properties of polyester glass reinforc4
plastics
SOURCE: Ref. zh. Fizika, Abe. 6D755
REF SOURCE: Sb. Issled. po matem. I eksperim. fiz. I mekhan. L., 1965,
164-171
TOPIC TAGS: optics, optical property, polyester, glass reinforced plastic
ABSTRACT: The coefficient of directional light transmission and the coefficient
of reflection and diffuse reflection were measured for samples of industrial glass
reinforced plastics. /A study was made of the effect of temperature, moisture and
ultraviolet radiatioalon the optical properties. It was shown that glass reinforced
plastic is a dispersive medium with a high degree of nonuniformity to which it is
difficult to apply the existing analytical relationships. E. Glazunov. [Translation
of abstract)
SUB CODE: 20/
P11ASE I BOOK MWITATION SOT/5544
Tomashov.. N. D.j. Doctor of Chemical Sciences., Professorp ed.
Korroziya i zashchits. konstruktsionriykh metallicheskikh materialov; sbornik
Statey (Corrosion and Protection of Constructional Metals; Collection of
Articles) Moscow., Mashgiz) 1961. 258 P, Errata slip inserted, 10.,000
copies printed,
Ed. of Publishing Howe: N.P. Yevotaflyeva; Tech. Ed.: ON. Smirnova;
Managing Ed. for Literature on Chemical and Textile Machine Building:
V.I. Rybakova., Engineer.
FURPM: This collection of articles is intended for scientific and technical
personnel concerned with the corrosion and protection of metals.
COVERAGE: The collection deals with problems of the corrosion of constructional
retals in various environments and conditions. Articles discuss new methods
for the investigation and testing of corrosion and give results of recent
research condneted on the corrosion and protection of metal constructions.
The corrosion of some new alloys is allo considered. The collection includes
Card 1/7
Corrosion and Protection (Cont.) SOV/5544
articles generalizing the results of research conducted during the last 2-3
years in the Department for Corrosion of Metals of the Moskovskiy institut
stali (Moscov Steel Institute). Some of the articles were written in
cooperation with the laboratory staffs of the "Berp I molot" Plant and
Khimicheskiy zavod im. M.I. Kalinina (Chemical Plant, imeni~'RZKalinin) and
are based on Investigations condacted at these plants. No personalities are
mentioned, There are 21-9 referencesj, Soviet and non-Soviet. References
accompany each article.
TANZ OF CORIMIrS
Foreword 3
Tomashov.. N. D, [Doctor of Technical Sciences]. The [Process]
Controlling Factorb and the Protection of Metals Against Corrosion 5
GAS CORROSION DURING TEO ERAT TREATH10T OF ALLOYS
Abramor., 0. V. [Engineer]., and N. P. Zhuk (Candidate of Chemical
Sciences]. Oxidation of Some Alloys During Beat Treatment in Gas
and Electric Furnaces 19
Card 2/
Corrosion and Protecti6n (Cont.) SOV/5544
Zhuk, N. P,, and L, P. Yeme11YanenkQ'1x-D&O9i3. The Effect of the
Carbon Content in--th-e-Er on the Gas corrosion of Carbon Steels 40
PICIaMIG OF SOME: MRALS AND AUM
Kuznetsov., G. G. [Engineer), N. P, Zbuk, and B. E, Lyubinskiy
(Candidate of Technical Sciences]. Electrolytic Pickling of
,011gh-Alloy Metals 53
K~avchenko, T. G. (Engineer]., M. A. Vedeneyeva [Candidate of
Technical Sciences],, and F. S. Rakhovskaya (Engineer]. Pickling
of Austenitic-Ferritic EI811 Steel 72
Markovich, L. A. (Engimerl, and ff., P. Zhuk. The Effect of Raloid
Ions on the Corrosive Behavior of UM18N9T Steel Daring Pickling
in Sulfuric Acid 93
Card )/7
Corrosion and Protection (Cont.) 607/5544
CORROSION RESISTANCE OF CHROMIUM-NMXEL STEELS
Vedeneyeva, M. A., and N, D. Tomashave Corrosion of lKh18Nq Steel 108
in Sulfuric-Acid Solution of CuS04
Vedeneyeva, M. A.., and F. D. Tomashov. Effect of Deformation on the
Tntergramlar Disintegration of Chromium-Nickel Steel 1!6
CORROSION RESISTANCE OF TITANIM AND ITS ALLOYS
Tomashov, N. D.,, and L. A. Andreyev [Engineer]. High-Temperature
Oxidation of Titanium 127
Tomashcrr., X. D.,, and M. G. Milividakiy (Engineer]. Pickling of
Titanium in Acid Solutions and in Alkaline 14elts 133
Tomashov, N. D.0 R. M. AlItarskiy [Engineerlp A. V. Prosvirin
(Engineer]., and R. D. Shamgwwa (Candidate of Chemical Sciences]&
Corrosion of Titanium and Its Alloys in Sulfuric Acid 151
Card 4/T
Corrosion and Protection (cont.) SOV/5544
Tomashov, N. D.,. R. M. Al'tovs1dy., and V. B. Vladimirov [Engineer].
Investigation of Corrosion of Titanium and Its Alloys in Bromine
Solutions in Methyl Alcohol 164
,, H. D,j, R, M, Al'tovski-y., d.P~4hqZwva [Candidate'of
Tomanbov
Chemical Sciences], and A, D, Arteyev (Engineer]. Corrosion Resistance
ef Titanium Alloyed With Mlybdemxm.0 Chromium, and Palladium 173
CORROSION AND PROTECTION OF SOME WTAIS
AND AMMS IN ACZDS AT EMATED MMERATMM
Titav, V. A. [Candidate of Technical Sciences]., 0, 1. Agapov (Engineer].,
and N. D. Tomashov. The C~rrosion of Tantalum, Niobium, and Their Alloys
in Sulfuric Acid at Elevated Temperatures 187
Tomashov, H. D., and P. V. Strekalov [Engineer]. Investigating the
Corrosion Rate of Iron-Carbon Alloys in Acids at Elevated Temperatures 196
Card 5/7
Corrosion and Protection (Cont.) SCV/5544
Titoy, V. A.y 1. M. Balandin [Engineer], and N. D. Tomashov.
Investigq.ting the Effectiveness of Various Metal-Protection
Methods in Solutions of Sulfuric and Phosphoric Acids at
Elevated Temperatures 200
CORROSTON ENDURAME CF STEEL
Titov,, V. A,, and.N. D, Tomashm. Imestigating the Endurance
of Card Wire 215
Titoy., V. A.0 and Yia. M. Korovin [EngLneerl. The Effect of
Hydrogenation on the Enaars=a of Steel 223
Titov., V, A,., and V, V. Belnunova (Engineer]. Corrosion of
Steel in Contact With Copper 230
CCOOSION AND PRMMION IN CEUAIN
NWICHES OF THE CHEMICAL IWMTRY
Millvidoldy., M, G., Z. 1. Ignatova [Enginleer),, M, A. Vedeneyevaj,
V. A. Titov., and V. A. KUmt (Engineer]. The Usq of Urotropine to
Retard Corrosion of the Steel Apparatus Used in the Production of
Amionium. Chloride 245
Car& 6/T
Corrosion and Protection (Cont.) SOV/5544
1
Titovj V. Aep.Le A. MarkcvIch (Engineer]., and A. V. Prosvirin.
Investigating the Corrosion Resistance of Certain Meta3z and
Alloys In Hexachloran Production 254
AVAILAME: Library of Congress (TA462.T64)
Card 7/7 VK/wrc/mas
1o-5-61
8/137~61/000/011/098/123
A060/AlOl
AUTHORS: Zhuk, N. P., Yemel'
TITLE: Influence of carbon content upon the gas corrosion of carbon steels
In air
PERIODICAL: Referativnyy zhurnal, Metallurgiya, no. 11, 1961, 43, abstract
111291 (V sb. "Korroziya I zarhchita konstrukts. metallich. mate-
rialov", Moscow, Mashgiz, 1961, 4o-52)
TEXr: A study was made of the Influence of the carbon content (0.06 - 1.34
%) upon the gas corrosion of carbon steels from experimental heats in air at
0
500 1,100 C. The method was used of periodically weighing the specimens withcut
extraction from the reaction zone of the furnace., the determination of the weight
losses of the specimens after oxidation and scale removal, measuring the micro-
hardness and studying.metallographically the transverse sections of the specimens
after oxidation. The scale growth on all steels at all the temperatures investi-
gated proceeds according to the parabolic law A gn . kr, whose exponent n varies
between rather wide limits (from 4 to 1-5) as function of the testing temperature.
The law of variation of n as a function of the temperature for ever7 steel Is
Card 1/2
Influence of carbon content ...
S/137/61/000/011/098/123
Ao6o/Alol
violated,*as- a rule, in the region of temperatures corresponding to changes
occurring in the steel and in the adjacent scale layer: the formation of wustite
in the scale, eutectoid, magnetic and allotropic transformations in the steel,
strong dissociation of the oxide Z - Fe203. The temperature dependence of the
oxidation rate K of steel in air has the shape of a broken straight line In the
coordinates log K versus-l/T, and the breaks in the straight line, accompanied
by corresponding changes In the activation-energy Q of the activation process,
take place in the region of temperatures corresponding to the abovementioned
transformations: the appearance of wustite in the scale is accompanied by a
rise of Q, eutectold and magnetic transformations cause a rise of Q, an allo-
tropic transformation causes a drop of Q. The depth of the apparent and the real
decarbonization of carbon steels increases as the temperature rises, and decreases
with an increase of the C content In the steel. The decarbonization process of
carbon steels leads to a reduction of their oxidation. rate in air. The oxidation
rate jDf bteels is lowered as their C content is raised, and this effect becomes
more pronounced with increasing temperature.
[Abstracter's note: Complete translation]
V. Tarisova
Card 2/2
8 81/62/000/001/033/067
B151/B101
AUTHORS: Zhuk, N. P.,-Yomellyanenko, L. P.
T IT Lf S - The effect of carbon content on the gas corrosion of
carbon steels in air
PERIODICAL: Referativnyy zhurnal. Khimiya, no. 1, 1962, 306,
abstract 11183 (Sb. "Korroziya I zashohita konstrukta.
metallich. materialoy". M., Maeligiz, 1961, 40-52)
TEXTt A study of the effect of the carbon content on the gas corrosion
of carbon steels (oxidation and decarbonization) In air is described,
using periodic weighing without removing the nample from the furnace, at
temperatures from 500 - 10000C. At.high temperatures (850 - 110000 the
rat
e of oxidation of carbon steels decrease3 with increasing C content.
At temperatures from 700 - 80000 the oxidation process is complexp showing
varying rates of oxidation. In the temperature region 500 - 6500C the C
shows an insignificant effect on the rate of oxidation of carbon steels.
The scale growth in all the steels, at the temperatures studied, follows
Card 1/2
S/081/62/000/001/033/067
.The effect of carbon ... B1510101
n
the law Ag kt~ . The rate of oxidation of the steels decreases with
increasing Gcontent. This effect increases with increasing temperature.
[Abstracteria notes Complete translation.]
Card 2/2
22032
3/177/61/000/001/008/010
D211/D306
AUTHORSs Oksengendler, G.I.9 Captain of Medical Services,
Aralov, S.S.# Senior Engineer-Lieutenant, and
Yemej~Zanenko, M.I.j Major of Medical Services
TITLE3 An apparatus for studying the stability of attentive-
ness
PERIODICAL: Voyenno-meditainakiy zhurnal, no. 1) 1961v 74 - 76
TEXTs The proposed apparatus permits the automatic recording of the
above-mentioned test. It consists of a panel with nos. 1 - 25 not
given in sequence. Undor each number there is an electric contact;
the airman undergoing the test-touche8 the contact with a connect-
ing rod and closes the circuit; only when he touches the correct
consecutive number are the results registered on a tape recorder
and the graphs obtained show the times needed to find individual
numbers as well as the total time taken during the test. A schema-
Card 1/4
An apparatus for studying
tic diagram of the apparatus is given.
requires an alternating current of 220
direct current of.24V. In the author's
be used for studying the psycho-phy8ioLogical
flyi.ag personnel. There are 3 figures.
SUBMITTED; April, 1960
Card 2/4
22032
3)1177/61/000/001/008/010
D211/11306
The automatic tape recorder
volts and the stepfinder a
opinion this apparatus may
characteristics of
22032
S/177/61/000/001/008/010
An apparatus.for studying 3)211/D306
15
Fig. 2.
0 0 0 o 0l
0 0 0 0.0
0 0 0 0 0
,%~o 0
0
0 0 0
2
5 6 131
00
Card 3/4. ~4 8
22032
S/177/61/000/001/008/010
An apparatus for studying ... D211/D306
Pig.-2. (cont'd)
Legends I - Numbered panel; 2 - stepfinder ATS (Dial Telephone
System); 3 - relay of the stepfinder; 4 - contacts of the signal
system; 5 - 6 - lamps; 7 - recorder; 8 - recording tape moving
at a constant speed of 15 cm/min; 9 - Warren's electric motor;-
10 - contact rod; 11 - device for exchanging number panels;
12 - key for changing no. sequences; 13 - switches to the general
current supply; 14 - button which puts the stepfinder into a new
working position; 15 signal lamps.
"',iJor of the f-'cdIc;,jj 13
. -rvica, --A. SLmf-le Yet~od of
of the Blo,7d Vessel. wall. OKSEEGENDLER, G. I.
Voyenno-Y6ditsimskiy Ahurnal. No. 11, 1961, Pr
YEHELIYANEHKO, M.1 , mayor meditsini3koy aluahby; OKSENQMIDIER, G.I.,
kapitan meclitsinskoy pluzhby
Simple method for determining the permeability of the vascular
wall. Voen.-med. zhur. no.3-I.-?9 11 161. WIRA 15:6)
(BLOOD'VESSEIZ--PEMIEABILITY)
) -a. a - . # - ---- --- ____ - - _------ ------
Stellar Astronomy, Kinematics and Dynamcis of Stellar Systems (1743)
Paremennyye Zvezdy, Vol 9, No 4, 1953, pp 266-270
YEKM I YANENKO, - M. T, and HATVEYEV, 1. V.
"An Investigation of Irregular and Semiregular Variables" Part III; "Several
Properties of the Visual Distribution of Irregular and Semiregular Variables"
As a result of their studies, the authors succeeded in-dividing 75% of the
stars they examined into 28 groups, which occupy. 4.6% of the area of the celestial
sphers. The article contains a map and list of the~;e groups.
SO: Referativnyy Zhurnal--Abtronomiya i Geodeziya, No 1, Jan 54;(W-30785, 28 July 1954.)
CHMPASHCHUX, A.; YEHELoyMmt M~T., nauchnyY rukOvOditell
Photometric observations of the total lunar eclipse on YAY 13-14#
1957. Uch.zap-Nuib.goo.ped-inst. no.37210-16 162. (KM '1631)
1 (Ealipsest Lunar)
CU"ANOVA, Ye-P- , T ~Q,_j", NESTEMO, A.D.
Ampaiykakoye iron ore dePosit- Sov* geole 3 no-7tl22-123 Jl
'6o. (MIRL 13:8)
1. Ampal-ykakaya ge ologorazvedochnaya partiya-
(Kuznetsk Basin--Iron ores)
0
S1135161100010ohlOlOI012
A006/A101
AUTHORS: Andrianov, K. I., Supereko, 0. D., Ilikolayeva, L. I., Kudryavtscv,
K. V. Yemel;yanenko, N. L., Engineers
TITIE: Ceramic Noz?les of the A-547r Semi-Autonatic lHachine for Welding
in Carbon Dioxide
PERIODICAL: Svarochnoyc proizvodstvo, 1961, No. h) pp. 37 - 38
TEXT - ~Aslding in carbon dioxide with consumable electrode is used at
the Chelyabinsk Tractor Plant for Joining tractor parts on the A-5h7r semi-auto-
matic machinep where the gas flow is directed by a chromplated brass nozzle
(Fig. 1)3 placed on the rubber housir.F of the burn(-,r tip. The use of this nozzle
presents hovever, a series of deficiencies, such as short-circuits of the weld-
ing current; sticking of metal splashings to the internal nozzle nurface, and
short service life of the nozzle. The laboratory of mineral zer3mics at the
Plant developed ceramic nozzles to replace the chrome-plated brass nozzles, pre-
pared in a metallic mold by press-forming from a ceramic mass of 12 - lhp" mois-
ture. The conponents of the ceramic mat,7-ri,:1 were dried, crushed, screened,
and mixed during 8 h. The material was then wetted with water to 28 - 30% for
3/135/61/rOO/001j/01,0/03.2
AW6/AlOl
Ceramic Nozzles of the A-547r Seni-Auto;-tatic 11-lachIne for Welding in Carbon Dl.,~x-
ide
saven days and then molded. The molded noz-,Ias mro dried at room tonTYvittire
and roasted in an electric furnace. Ceramic nozzles of the following composi-
tiona were -anufactured by the described technology:
Designation of mat~,rials of the mass
I ii I IIII IV
Talcum chlorite 7o 6o - -
Refractory clay 20 30 LO 15 20
Quartz - - - 20 15
Fluorspar - - 30 25
Porcelain waste - - 10 35
Kaolin - - 25 5
Card 2/h
S/135/61/000/ooli/010/012
A006/AlOl
Ceramic 11ozzles of the A-547r Sen-d-Auto.,i4tlc ~Iachino for *Ueldin- in Carlbon Diox-
ide
Talcum-chlorite containing nozzles were roasted according, to graph 3. Torts p4~,r-
formed with experimtental ceramic nozzles proved satisfactory. The rcplacin~7 of
brass nozzles by the new ccranic ones presents the following advantaocs: the
possibility of a contact between the nozzle and the part to be welded is excluded
the durability of nozzles is raised by a factor of 1b - 16; scare chronie-plbed
brass is replaced by cheap ceramic materi3l; labor consixiing proccoses of manu-
facturir4g, the nozzles are siibstlltuted by advanced press forming methods, elininat-
ing subsequent m4chanical treatment; the time 6f exchanging and cleaning ths.
nozzles from metal splashings is considerably reduced. There are I table and 4
figures.
ASSOCIATIM: Chelyabinskiy traKtornyy zavod (Chelyabinsk Tractor Plant)
Card 313
ANDRIUDVr K.I.p inzb.; SUPEREKO# O.D.f lnzh.; NIKOIAYEVA, L,Lp~ln2h.j
-KUDRYAVTSEVp X.V., inzh.; UNKLOYABENKOp N.L., inzh.
~Ceramic noxzles for A-54? r semiautomatic machines for veling in an
-,.atmosphere of carbon dioxide. Svar. proizT. no.4:37-38 Ap 161.
(MIRA 14:3)
l.- Chelyabinskiy traktornyy zavod.
(Electric velding-Equipment and supplies)
(Protective atmosphereer)
Ti
38363
S/058/W000/005/090/119
7 ),o
AUTHORS: Moldovanova, M., Yemelyanenko, 0.
TITLE: Comprehensive investigation of carrier equilibrium in InSb ana GaAs
PERIODICAL: Referativnyj zhurnal, Fizika, no. 5, 1962, 33, abstract 5E259
("Godishnik Sofiysk. un-t. Fiz.-matem. fak.,' 1959-1960 (1961),
v. 54, no. 2, 1-9,'Bulgarian; English summary)
TEXT: A comprehensive Investigation has been conducted on conductivity,
the Hall coefficient, the coefficient of the transverse thermomagnetic effect,
and the thermoremf on the same p-type InSb and GaAs s ecimens at temperatures
between 86 and 4240K for InSb, and between 86 and 550 8K for GaAs. The hole
concentration for 1n3b was 4.3 * 1015 cm-3. The impurities were completely
ionized in the temperature ranges Investigated. The entrainment. of carriers by
phonons was observed below 110 K. Above this temperature, the carriar mobility
in the impurity zone obeyed the laur u "-T-1-5 and in the zone of intrinsic
conductivity it obeyed the law un --~T21-4. Above room temperature, the electron
gas became partly degenerate. The consideration of degeneracy led to the values
of the effective masses: mp - 0.174 mo, % 0.045 mo; in fhe opposite case:.
Card 1#0,
S/058/62/000/005/090/119
comprehensive investigation of carrier equilibrium... Ao6l/Aloi-
nip - 0.167 mo, mn - 0.043 mo. b - 10 was found for the ratio of carrier mrbilitim
For GaAs, the hole concentration at temperatures above 770X. was 4.5. , 1016 cm-3.
The electron gas started becoming degenerate at 250 0K. The carriers were
scattered partly by the impurity, and partly by the lattice (the latter scatter-
ing prevailed at high temperatures). The effective mass was mp,* 0.5 Mo.
I MenbAyeva.
(Abstracter's note: Complete translation]
S/194,/62/000/007/075/160
D295/D308
AUTHORS: J4oldovanova,*M.# and Y4gjelyanenko, 0.,
TITLE; Complex investigations of InSb and GaAs at equilibrium
carrier concentration
PERIODICAL: Referativnyy zhurn4l. Avtomatika i radioelektronika,
no. 7, 1962, abstract 7-4-27 sh (Godishnik Sofiysk,
un-t Fiz.-matem. fak.0 v.-54# no, 2, 1959-1960 (1961)
15;tl.; summary in Eng.1)
TBXT: Complex investigations of R, d, a and..Q in p-type,monocry-
sthle of InSb and Ga4s have been carried out in tomperature ranges,'
of,86 - 4240K for IzAb and 86-5760K for G6.As. It has been shorm
that the Hall coeffibient and carrier concentration in type-InSb'
in the 8,6-1340K ranger are constant and equal to 1700 em3/-coulomb E~ad
4.3 x 1015 cm-3
respectively, It was found that carrier nobility
follows the law U ~, T-1.5-in the impurity'region and the law U
p P "k
T-1*4 in the intrinsic-*conductivity region. At 3240K the p-car-%
rier mobility was 1700 cm2/V see. and the n-carrier mobility to
Card 1/2
B/194/62/000/007/075/160
Complex investigations of InSb ... I D295/D308
4 2 C
5.1 x 10 cm /V sec. The width ok the forbidden band at absolute
zero, A E0, was found to be equal::to 0.268 eV. The effective mass
of the p and n-carriers corresporided to 0.174 and 0.45 m0 (allowing
for the fact that ~he oloctron gas above room temperature In par-
tially degenerate). In p-type GaAsp in the impurity region 86-20003;
the carrier concentration was equal to 4.5 x 1018 cm-3, and the ef-
fective mass was m 0-5 m 16 references. [Abstracter's note:
p
Complete translation.]
Card 2/2
AUTHORS s Yeraellyanenkot 0. V.) Nasledov, D, if. 57-25-6-8/34
. . . ............
TITLE: The Electrical Properties of UaAs at Low Temperatures
(Blaktrichookiye svoy3tva GaAs pri nizkikh touperaturakh)
PERIODICALs Zhurnal Tokhnichookoy Flziki, 1958, Vol. 20, Nr 6,
Pp- 1177-1187 (MR)
ABSTRAM Gajl~Lum arsenide is a semiconductor compound of the type
AjJ1 B-Y- . The electrical properties of AM BY are similar
to those of germanium and silicon and are, in most casec,
explained by means of the theory of atomic semiconductors.
The characteristic feature of numerous compounds of the
'M B2 is the small effective mass of the conduction
type A
electrons m n Thus for InSb M n , 0,013 m and for InAs m. n
= 0,064 m (m mass of free electrons). In the present
paper full independence of conductivity and of the Hall 0
constant (Kholl) of temperature in the interval 1,5 -4- NO K
was obtained for the n-samplea of GaAs. Analogous results
Card 113 have formerly been obtained for the n-samples of InSb and
__TEe__'2l7e_ctr cal Properties of GaAs at Low Temperatures 57-28-6-0/34
InAs. Analys-is of these data shoved that the
semiconductors mentioned are in the metal state at the
respep.tive concentrations of the donor impurities
(N(10;~1017 -_ 1018 cm-3). The activation energy of thA
Impurities in their case is equal to zero. The concentration
of current carriers is steady. The carrier gas is highly
degenerated. An important part is played in connection
with the metallization of these matprinlo by the small
effective mass of the electrons, The non-dependence of
carrier' mobility upon temperature is explained qu!%litatively
by the function of those processes of dispersion the effect-
tive cross section of vhieh does not.immediately depend upon
temperature. In the analysis of reau.L~~.j Lue term
"temperature of semi-ionization of admixtures was
introduced. This term is of general validity for
semiconductor3 with high concentrations of admixtures, and
with its help it is possible to determine especially the
fact of the metallization of the semiconductor (J6-E 0)
pr.
aft,er measuring R at not too low temperatures (e. g.
Card 2/3 temperature of liquid nitrogen). More detailed information
The Electrical Properties of GaAs at Low Temper'aturee 57-28-6~4/34
concerning the structure of the energy spectrum in
metallized semiconductors and the kinetics of conductivity
must be obtained by measurements of the thermoelectromotive
force as well as of R and cewithin a larger concentration-
and ?emperature interval. it may also be hoped that this
will also explain the nature of the reduction of the
resistance of n-samples of GaAs in the magnetic field,
which was discovered in the course of this work. The
authors thank 0. 1. Averkiyera, V. S. Grigorlyeva, T. S.
Sukhanova and N. U. Reynov for their cooperation. There are
6 figures, 3 tables, and 14 references, 3 of which are
Soviet.
ASSOCIATIONs Leningradskiy fiziko-takhnichaskiy institut,AN SSSR
(Leningrad Physical-Techn'Lcal-Inatitute,AS USSR)
SUBMITTEM! October 1, 101;'?
1. Ga1lium arBenides-Blectricil-properties 2, Galli'um
Card 3/3 arsenides-Temperature factors 3. Semiconductors-Analysis
4. Semiconductors-Magnetic factors
~XTPORS: Averkiyeva, G. K., YemellyanAnko, 0. V.
T -n the Electric
Efflact"'6C, rit
tff 0
Impu
JYL':':
(71 iy a n i Y eprimesey na olektrichoski.Vc :--oyntvn
i~IODICAL: Zhurral finiki, 1958/Vol 282-OP- V 15-1917 (U`))
9, 9q,
T iAC, T '1'h~~- ixvt~sent article presents information on ex!e-iPenlus In
%shich a number of elements of the c?lns I - VI were in"ro-
dw,ed into a compound of the type A- B , that ir, to say
gallium arsenide. "itcl- a ritudy nny bc oxivectcd to yield
eviderce~ bearIng on tho I effect.--o of elcments of various
groups upon the olictric tf,:.,~ of GLAs &nd upon the
entlir admixturec. 'Ale "Ie
,.czt effective donor and acc .3
-were produced by an im.-rediate joint melting of the conT)onents
in evactated tightly sol(lored quartz amroules. The evidence
ob-thined leads to t6 folloviing statenen*ts: 1) The elements
of the H column, Zr and Cd act in GaAs as acceptrirs, t1houe
calurar:, 2, So and To ao donorc jw3t cis thef do :n
of' tile YJ I I
Other A-' -TII commotin.1a. 2) Coppor Jv an acceptor, thiv result
.-!ilh that found by 'Y'zairous (.Shmirouv) 1) for
compl,
("ard 1/4 GaJb. 3) 'fh-, elLments of the 1II,- V.coluvin, N, 'A, ..'n,
on the -1:*1sctr--c of rsen-~-Ira
-b do not form active centers in GaLs. 4) Yhe of
c-lectrons .-nd of ',,olea 1.9 only little de,,Tjidon~,, i-non thc
oC tinI unon thQ concentration of th,: vdmi~--t-oren.
1,o ..nf1u!.-r.Qe of the i:-.iniritien iroon the .9trength of G;,.'..n coti],,'
as ~,ret bc- 'J~uni, as only --in a few cases it Oossible
to mc:,cure the microutrength of the excess phas~~a. r: -I
ited a strongth coincidLiv t'! t.,4,tt
"tj ir,,, 'Irition exhib,
of nu.ve indiuvi j)1'Od11CeS Ln excess p!i,.-,,e .-hich e:,---
I
hib-ita rt zhole Suectrurl of nicrostrongth valuco, w1hich could
1),~ idu;~tjfiod -,,Iith such of the solid Ga xIn 1-X I.- "Olutiono.
lih,-, elements of the 11r. column, zinc in particuLar, rtre
gallium arsenide than the el,!.-aents of the
~;ubter -;nluble in r
'i'l. crilumn. Zinc proved to be the most effectiv,3 accentor
!tdrfl.7~:!iro und aelanium its tho motit a:factivo do~ior ivlni..tuve.
p3taln fort,1011 by uto-,mlov with Ln- and )*o tidmil-,tuvon
hrrl Uj.,i somo flime naions ae thono without adiiix-turej. "I"hen
Vie acceptor elements Cu and Cd were introduced, into a n-ty;...-
material P. ~iigh --utual compensation of acceptc-,-r? and donors
w~,,v found. This occurred more frequently thav, -, coul.' "Oe
.Effect on tile- ct-"ic L ic-3 01, 5;-,'
r.,;"cted frcm thc~ -iremiiia thut the flormi, and thr: accc;,tcr 1* m -
Independently in GuAo-. Vl~--.,,:
'ji_jAr!VC.. t;lat t'le disoolvln
'q 0i, the 'oc c-e!) t Or r
ff.Ici_littoted by thi.! c-,dutunce '-ed
(10,nor certer.,;. N. -iuvledov and fl. A. Oor-tinw.,
with tile authors. ~. D. 't*t!,.,C)v rlnoiuted -_ir. he
pre-m-ratim o. Une .9a;,o)1ec wid in thc~ t.re-uration rinfl, Vrw
study '.o_`1' the Polished section2. There. are I t,a'uic _-nI
coo, I of vhich in ;;ov.iet.
'notitut .',N 59.2"R
A .TIOU: LenLngradski,,r fiziXo-t-.?k1,ni(,hoskiy
awj 'PechnictA Inotitute i.'CS.__A)
T) ril 10 10',7,1
YINELITAIMIMD Q.V,.., NASLIDOV. D.R.
=*Xitl
Irernst-IttingshBussn, affect in gallium arsenide. Yiz- tvare tela
1 no.6:985-988 Js '59. (KIRA 12:10)
I1.-Leningradskiy fiziko-takhnicheekiy ingtitut AN.SSSR.
I (Gallium arsenide-Blectric proPotties)
69086
.29,71 oo S/12o/6o/oo/ol/027/051
E19�/#382
AUTHORS: Yomellyanenko, O.V. and Trishi
TITLE: 77nstrume2it-"ror-tha Investigation of the Kinetic
Effects in Semiconductors
PERIODICAL: Pribory i tekhnika eksperimenta, 1960, Nr 1,
pp 98 - 99 (USSR)
ABSTRACT: The device described is a laboratory instrument suitable
for the measurement of the.electrical conduct vity,
the Hall effectV Nernst-Ettingsliausen-effect~tnd the
Be
thermal e V in 3miconductor samples at temperatures
ranging frMlo-ho - 900 OK. The diagram of the instrument
is shown in the figure on p 99. The investigated sample
5 is placed between two graphite blocks 1 which clamp
the sample due to the tension of the spring 4 . The
blocks are furnished with side grooves. 2 and centre
holes. Porcelain tubes are placed in these holes in
order to accommodate the thermocouples 6 . The probes
for the measurement of the electrical conductivity and
the Hall and Nernst-Ettingshausen effects are made of
tungsten wire, having a diameter of 0.1 mm and are
Cardl/3 situated in the grooves of the upper block. The probe and
69086
5/12o/60/000/01/027/051
An Instrument for the Investigation of thE012MEOM' Effects in
Semiconductors
the thermocouple wires are insulated by means of quartz
capillary tubes 11. The upper block is fixed to a glars
stem by means of a fine steel tube 8 . The glass stem
contains all the output wires. Before the measurements,
the device is evacuated and then filled with an inert gas.
The blocks and the sample are heated or cooled externally.
For this purpose, the instrument is inserted into a two-
section tubular oven. Each section (A and B) heats
one of the blocks. If it is necessary -to carry the
measurements at low temperatures, the instrument, together
w:Lth the oven,is placed into the stream of evaporatIng
nitrogen. The outer diameter of the device is 12.5 mm,
the diameter of the blocks being 10 mm. The investigated
samples can have dimensions ranging from
I x 2.5 x 6 mm3 to 4 x 6 x 30 mm3. The instrument reaches
a thermal equilibrium in about 20 to 30 min. The samples
can easily be removed by taking out~the lower block. The
Card2/3 measurements are carried out as follows. The "heateril a
69o86
S/12o/60/000/01/027/051
Ej9?4E3Rfnet1c Effects in
An Instrument for the Investigation 0 e
Semiconductors
the "refrigerator" of the device produce a temperature
difference along the sample. This is determined by the
thermocouples. The thermal emf can also be determined
by means of the thermocouples. In order to deterihine
the Hall effect, the instrument should be placed in a
magnetic field. The authors thank D,N. Nasledov for
his interest in this work. There are I figure and
3 Soviet references.
ASSOCIATION: Fizilto-teldinicheskiy institut AN SSSR (Physics-
engineering Institute of the Ac.se., USSR)
SUBMITTED: January 2, 1959
Card 3/3
YEMBLOYAIENKO, O.,V.; LAGUNOVAy T.S.; IIABLEDO'Vp D*N.
rs in strongly degenerated gallium 8)
Scattering of current Arrie 2-197 F 160. (miRA 14:
ars'enide. Fiz. tvaro tela 2 no.2:19
1. Fiziko-tekhnichooki-Y inotitut AN SSSRI Loningrad,
(Gallium arsenide)
L ~14 4,) rol o V
r-) (0 0 0
AUTHORS:
TITLE:
PERIODICAL:
825hl
s/iai/60/002/007/017/042
B006/BO7O
Yemellyanenko, 0. V., Kesamanly, F. P.
The Problem of Methodology of quick Precision
Measurement of the Thermo-emf of Semiconductors
Fizika tverdogo tela, 1960, Vol, 2, No- 7P PP- 1494-1496
TEXT: The authors describe an apparatus with the help of which it is
possible to measure the thermo-emf in a short time. The method is based
on the application of thermocouples with controlled heating. The two
'thermocouples are surrounded by a heater which is in the immediate
neighborhood of the mcaouring junction (Fig. 1). One of the junctions of
couple I is in contact with the object, while one junction of couple II
is separated from it by a small gap. The second couple controls the
heating. With this comparison instrument a very exact measurement of
temperatures is possible. Applying this method of measuring temperature,
the authors oonstructed a simple apparatus for measuring the differential
thermo-emf of semiconductors of arbitrary forms of samples in the
Card 1/3
825hi
The Problem of Methodology of Quick Precision B/181/60/002/007/017/042
Measurement of the Thermo-emf of Semiconductors B006/13070
temperature range 25 1* 1500C. The apparatus has a high degree of accuracy
and rapidity of measurement. It is shown diagrammatically in Fig. 2. For
the purpose of meaauringg the sample is placed at the ends of two
L-shaped copper blocks, the other ends of these blocks being In containers
filled with ice. The sample is heated, and the thermocouple is brought
manually to the points between which the thermo-emf is to be measured.
The temperatures of these two points Wre measured. The heating of the
thermocouples is reacrded by two potentiometers. The thermo-omf of thA
semiconductor and the thermocouple were measured by a potentiometer of
the type nCITIB-1 (PPTV-1) and galvanometer of the typeti-21/1 (M-21/1).
The temperature is measured with an accuracy of 0.10C, that is, of about
2-3% between 7-100C. The junctions of the thermocouple had a diameter of
0.4 - 0-5 mm, and the contact diameters were not larger than 0.02 - 0.03
mm. The method requires 10 - 15 minutes for one measurement. To determine
the temperature dependence of the thermo-emf of a sample between
25 - 1500C for 10 - 15 points of measurement, 2 - 3 hours are required.
The accuracy of measurement of the thermo-emf is t(2-3)%. Fig. 3 gives an
example of a measurement of the temperature dependence of the thermo-emf
Card 2/3
825hi
The Problem of Methodology of Quick Precision 311811601002100710171042
Measurement of the Thermo-emf of Semiconductors B006/BO70
of gallium arsenide. The authors thank Professor D. N. Nasledov for
discussions. There are 2 figures and 3 Soviet references.
ASSOCIATION: Fiziko-tekhnicheskly institut All SSSR Leningrad
(Institute of Physics and Technology of the AS USSR.
Leningrad)
SUBMITTED: November 20, 1959
Card 3/3
LI, -7 700 t/ q3 S_C7)
6 'C;2 WID-0
00Y4
8/181/60/002/010/016/051
B019/BO56
AUTHORS: Yemell enka. 0. V., Nasledov, D. N.9 and Petrov, R. V.
TITLE: The jernst-Ettingohausen Effe p-Type Gallium.ArsenideV
PERIODICAL: Fizika tverdogo tela, 1960, Vol. 2, No. 10, pp. 2455-2457
TEXT: In an earlier paper (Ref. 1) the authors investigated the Nernst-
Ettingshausen effect in n-type gallium arsenide. The coefficient Q, of
the transverse Nernst-Ettingshausen effect in p-type gallium arsenide is
graphically represented as a function of temperature. As it turned out,
Q+ is considerably lower for p-type gallium arsenide than for n-type
gallium arsenide. This is due to a lower mobility of the holes as J~
compared to the electrons. At temperatures below room temperature, Q
is negative, which may be explained by the scattering of carriers by
impurity ions. This explanation agrees with measured results of the
Hall-mobility of holes. Above 350 to 4500K, e becomes positive. This
convinces the authors of the fact that at these temperatures the PK
acoustic vibrations are the main scattering centers. The mixed conductance
Card 1/2
84594
The Nernst-Ettingshausen Effect in p-Type
Gallium Arsenide
S/181/60/002/010/016/051
B019/BO56
beginning at 600 - 8000K again makes e negative. Finally it is pointed
out that the results obtained here may be explained by the modern theory
of thermomagnetio effects. Furthermore, the results obtained make it
possible to estimate the part played by acoustic vibrations of the
lattice in scattering processes. There are 1 figure, 1 table, and 3
references; 2 Soviet and 1 US.
ASSOCIATION: Fiziko-tekhnicheskiy institut AN SSSR Leningrad (Institute
of Physics and TechnoloKv of the AS USSR. LeninKrad)
SUBMITTED: April 4, 1960
Card 2/2