SCIENTIFIC ABSTRACT YENIKOLOPOV, N.S. - YENIKOLOPYAN, N.S.

• Document Type: CREST
• Collection: Scientific Abstracts
• Document Number (FOIA) /ESDN (CREST): CIA-RDP86-00513R001962710004-1
• Release Decision: RIF
• Original Classification: S
• Document Page Count: 100
• Document Creation Date: November 2, 2016
• Document Release Date: September 1, 2001
• Sequence Number: 4
• Publication Date: December 31, 1967
• Content Type: SCIENTIFIC ABSTRACT

KOMU I C.~ , Yur I y I q UB LIA NSKAY.A , I., ! Lr" In OVnIq Y." NI)
SGf Iya mikfsZtJc-,,rna; SlRGIY'--'NKO, Ly-uJudla -!-ridreyeirnat
Moi~,aywma, -SHAGly-T, Vallentim
Factorowin: YlMKOLOf,()V,-N.:,.2 doktrr khJ?L. ntuYp
M LI-OL7.0rA
(Fo2yfornutldohyde] Pollformalldegid. Kiev; Tekhnika,
196,4.. 90 P. (milu m--i)

28437-66 1JP(G) WW/RM
ACC- NRt AP6017976 SOURCE CODE: UR/04l3/66/ooo/olo/oo7q/oo7q
1WERTOR, enikolopoy, S. S.; Karmilova$ L. V.; Konareva.-G. P.; Plechoya, 0. A.;
i--e-- -y' - -
lollfson, S. A.; Br k nsElem, A._A. 3q
ORG: none
TITIZ: Preparative method for heat-resistan0co22L=ei:s1of trioxane. Class 39p
NO. 181808
SOURM Izobreteniya, promyshlennyye obr&ztay, tovarnyye znaki, no. 10, 1966, 79
TOPIC TAGS: heat resistant copolymer, trioxane, cyclic etherj copolymer
---ABSTRACT--- -An--Aixtho--r----Ce-rtif icate has preparative-method for
-beenissued for a
--heat-resistant copolymers~--of-+,Ao
xane and cyclic ethers sucb-sa I -trioxacyc-lo~-
--octenei--i-13-i7--triz=ycl-o-deda-n-e-,-o-r--l-, ioxacyclododecane. The method involves
~,bulk copolymerization of the monomers in the presence of cationic catalysts, first
below the m~ andllthen.aboVe the mp of the monomers. IBO)
~SUB CODE: 07,11/ SUBM DATE: 02jun64/ ATD PRESS: o 6
Card

"The Occurrence of Anor-heles Malcullpennis in Uninhabited Floodlands of the Sulak
River and Data on Seasonal Changes in the Number of Mosquitoes in Dagestan", Med. Faraz.,
i Faraz. Bolez., Vol. 17, No. 2, pp 168-70,, 1948.

UNIKOLOPOV, S.K.
Behavior characteristics of Anopheles hyrcanus pall. Ned.parax.
i P&raz.bol. no-1:31-33 J&-Mr 154. (kLRA 7:3)
1. Is Dagestanskogo institute. apidemiologii i mikrobiologii
(direktor Inatituta Te.Te.Zhadkovich). (Mosquitoes)

GRUSINOT,I.P.. skodamik, oty.red.; ANTIPOV-XARATAYXY, I.N., alcadeusik,
oiv.red.; MWIKOT, K,,Kho, dotsent# oty,nd,j TANOT# T~,N,,g
starshiy nauchnyy- isotradniko otirerade'; GAMAt T~V# p ~ red*;
?MR, 1J., red.; K4TUN, P.I. , red.ixd-ira; KAKTJNIj
tokhn.red.
[SoiIle of Bulgaria] Pochvy Bolprii. Nookys, 1959o 30 pe
(KM 12:6)
I.. Akademlya nauk.S.SSR. PochvenW Institut In. T.T.Dokucbayevs.
2.-Aff Tadxhikmkoy SSR (for Antipoy-Karatayev).
(Bulgaria-Soils)

USSR/Chemistry - Fuels
Combustion Aug 52
"Periodic Combustion Flashes in Mixtures of Car-
bon Monoxile and Oxygenp" X. S. Yenikolopyan and
A. B. Nalbandyan
"DAN SSSR" Vol 85, No 6, PP 1309-133.2
A quant description of the combustion observed
in a mixt of CO and Q2 vhen a small amount of H
is added by diffusion is vorked out on the basis
of the reaction mechanism and the consts of ele-
mentary reactions calcd from previous vark.
238TA
When the pressure of the H on the membrane is
decreased and its rate of entry to the mixt is
decreased, the time betveen explosioas is in-
creased. By means of eqs derived from the mecb-
inism of the reaction, the article explains why
the combustion flz only a flash and not a com- -
plete burning of the entire mixt~. Presented by
Acad N. X. Semenov 14 Jun 52
2-38~14

TENIKOWFrAN, N. S.
Theory of degenerate branching chains. Part 1. Kinetic equations-
or reactions with degenerate chain branching (with Inglish summary
In insert). Zhur.fis.khim. 30 no.4:,769-783 Apr. 156. NLRA 9:9)
1. Akademiya nauk SSSR, Institut khtmicheakoy fisiti, Moskva.
(Chemical reaction, Rate of)

A -IA-1- j CI? -i..

";

TANIKOWFYANO Wes*
I,- - ~...
Dlommelon. Probl. kin, I kat, 9;133-137 '57. (Kin 11-.3)
(Oxidation) (methane)

sf-
- . . - . C . ~ -
,- . : 11 -% ., , "
: .. .~ "I- 'it 1, - . ..
1. 4

USSWRiyoical Chemistz~.r - Kinetics., C4=0nation., Explosiona,. Topo-
chemistry, CatAlYsis- B-9
Abs Jour: Pafezat. Zhurnal Ehimi7s., No 3, 1958, 7184-
Author H.S. Yenikolopyan., G.V. Kozrolev~r G.P. Savushkina.
inst.
Title, Upon the MarJmm Conce:.traticms of Stable Interwdi&rj Pro-
duets in CrAoposite Chisin Rftctions.
Orig Pub; 2h. fiz. lrhimii.. I.M., 33L., no 4,, 865-873.
Abstract: It is shown for coemposits ^-..ain reactions of the type A-> B-) C
;)rocassding in two stages (chain fon2atiou of a stable intermediary
prrduct B from the initial substanies A and chain eapendit",we of
B vith the formtion of ftzj,%l substances C) that there is a pro-
portionality ni - rA ja (1) among the conceutrations (n) of all
active centers (AC) in:L ae reaction system; in thin equation,x
does not depend on the rates of AC generatim. (W), of tbAir
fication (a) and of their destructioa (g). Shoild a clavly re-
Card. 21/3 -1-

USW-physical Chemistry - Kinetics., Combuaticm,, Eolosiais, Topo-
chemistry., Catalysis. B-9
Abs Yourt Referat. Zhurnal Dimlya., No 3,, 1958, 7184-
acting AC gpontaneously generate., the eqwtion (1) vauld bee rigat
only in the case of long enough chain . It :19 shown that the sta-
tionaxy concentration of B does not depend on AC concentration
in the reaction system., i.e. that it does nort depend on W., a and
g. It was revealed at the oxidation of C94 (vhich proceeda fol-
lowing the conposite chain mechanism CH4-*,~CH20 -4 final oubstan-
ces) at 462 to 5250 &--d the ymsvixe of 53 nd of mere- c01- in
the mixture CH4:2D that varying the comlitions influencing W and
g (concentration 4 the hcmg. initiator N02,, vessel 41-
lution of the mixture 8 time with Np) different cbesd cal treat-
ment of the vessel walls) results in great changes of C4 oxida-
tion rate (v), vb1ch in the criterion of AC concentration in the
.reaction systemj but does not practically.influence the stationary
CH20 concentration. -The experiments were carried out under static
co&itiona, v was measured nLuometrical3,y,, and C920 concentration
Card v2/3 -2-
&-MItration of CROO rt Of the reactticn.
(the activation
Is 46 kmi mergy L? Is 16.6 kses v'th tha taVe4rata:,_-,e
Per m3le. ]?e-- mole). L? of V(,,,)
Card 313

:fwg-pzw~ Way allcu WM-MlRi filn.,th thA -~L-

V -1 - . IC I , - , ~ r- 3
pn-vy F--m--O V-U J-1 T~ -
1j
AUTBORt SAYASOVIYU o3 YERIKOLOPYAN,N.S. A - 2919
TITLEs Note on the Liffusion of Active contras In the Case of a
quadratic Stripping of Chains In the Volume. (0 diffusii aktiTUYkb
tsentrov pri kyadratichnom obryye tospey Y oblyesep Russian)
PERIODICALe Deklady Akademli Nauk SSSR, 1957, Vol 113, Nr 1, PP 130 133
(U.S.S.R.)
Receiveds 5 / 1957 Rtyievedt 6 1957
ABSTRAM The present paper furnishes a solution of the problem of the
spatial steady distribution of tho forming heterogeneous active
centers on the assumption, that they are destroyed in the case
of mutual collisions on the surface and in the iAterior (i.9. in
the case of quadzetto stripping of the chains). 'his problem
arises *.g. in the came of a mixture of hydrogen with chlorine
without admixtures of oxygen. Lot the velocity of heterogeneous
generation bf much greater than the velocity of the homogeneous
generation. he roaotion is assumed to take place in a container
4th plans-p6rallel walls with a distance of 21'betwoon the walls
(on*-d1m*zsion&1 problom)olu that case the spatial distribution
o*~ the active o*nten in described by the differential equation
Z(41./dx2) - k (M)a2 - 0. Here n(,/OK3) denotes the 9oncentration
P 6/800)
of the active centers, k p (as the coefficient of recombination,
Card.1/3 (M) (I/OR3) the total concentration of the mixture and of the pro-

NoteIon the Diffusion of Active Contres in the PA - 2919
Can* of a Quadratic Stripping of Chains In the Volume.
dustag x(cm) - ~ht coordinate measured from the-cen%er of the
container, D(cm /sea) - the Uffusion coefficient of the active
centers. The boundary conditions are also given.
The solution of this differential equation can be represents& by
the elliptic function of WEIMSTRABSt a =,fo (u). in the case
of small velocities of the heterogeneous generation only few
chains form at the wallop and therefore the probability of an
interaction in the volume is small* Subsequently the equilibrium
of the process oigeuvration and dectruction of thit-aotive centers
is determined. Up however, a griat number of chains form at
the walls in unit time,.W is determined from the *quality of the
velocity of generation and destruction of the active centers in
unit volume of the container* urthermore the case is investigated
in which the concentration a of the active centers-varies con-
siderably in the interior of the contalLere 'With fte help of the
method of the WNUMSTRLSS function described here, ~the diffusion
of the active centers for different conditions can be investigated
(in which case the quadratic stripping of chains plays an important
part. 0 Illustration)
Card 2/3

PA - 2919
Note on the Diffusion of Active Centers in the Case of a quadratic
Stripping of Chains in the Volume.
ASSOCIATIONt Institute for Physical Chemistry of the Academy of Science
of the U.S.S.R.
PRESEWED M V.N.KOJ[DRAT'YEV, Member of the Academy
SUBMITTEDs ie.ioo956
ATAILABLEt Library of Congress
Card 3/3

ANISONYAII, A.A.; GUDKOV, S.F.; IVANOV, A.K.; YEHOLOPYAH, N.S.;
HARKETICH, A.M.; HALBAMAK, A.B. ;-
Results of the operation of an experimental apparatus for
the manufacture of formlin from natural gas. Trudy VMIGAZ
no*3:130-142 '58. (MIRL U: 8)
(Natural gas) (formaldehyde)

GOV/76-32-9-45/46
AUTHORSt Yanikolopyen, N. S., Polyak, S. S., Shtern, V. Ya.
TITLEt On the Nature of the old Plame" Phenomenon (0 prirode
kholodnoplamennogo yavleniya)
PERIODICALt Zhurnal fizicheakoy khimii, 1958, Vol 32, Nr 9, pp 2224-2226
(USM)
ABS)TRACTs Two viewe are represented in publications on the oxidation of
hydrocarbons in regard to the nature of the "cold flame"
phenomenon. M. B. Neyman (Ref 1) explains this phenomenon in
terms of the explosive decomposition of organic peroxides,
while Pease (Ref 2) and Norrish (Refs 3 and 4) explain it as a
result of the thermal instability of the reacting system. The
authors suggest a new mechanism, He holds that the peroxide
radical reacts in one of two possible ways: either with the
initial hydrocarbon (RO; + RH -ROOH + R*), or through molec-
ular decomposition (RO; --RICHO + RIIO*). The second reaction
becomes predominant with an increase in temperature. To explain
this phenomenon an idea of N. N. Semenov (Ref 5) was used. This
Card 1/2 is the so-called "degenerated branching"s RICOH + R02 --"-

On the Nature of the "Cold Flame" Phenomenon SOY/76-32-9-45/46
.---a-RO* + O'H + RICO*. Because of the action of the above-
mentioned mechanisms there is a temperature range in which the
optimal conditions for "branching" exist. There are 12 ref-
erences, 8 of which are Soviet.
ASSOCIATIONt Akademiya. nauk SSSR, Institut khimicheskoy fiziki, Moskva (AS
USSR, Moscow institute of Chemical Physics)
SUBMITTEDi January 31, 1958
Card 2/2' ~

AUTHORS: -Yenikolopyan, N. S., Korolev, G. V. 20-2:18-6-25/43
TITLE: Formaldehyde and Acetaldehyde Yields in the Oxidation of
Ethane at High Temperatures (0 vykhodakh formalidegida i
atsetalidegida pri vysokotemperaturnom okislenii etana)
PERIODICAL: Doklady Akademii Nauk SSSR, 1957, Vol- 118, Nr 6, pp. 1138-1141
(USSR)
ABSTRAPT:~ The conceptions which in complicated chain reactions lead to
the existence of extreme yields of stable intermediate products
iKere verified at the example of the oxidation of methane. is
4ample for the further verification of these conceptions the
next more complicated representative of thv homologous series
!of-paraffin hydrocarbons, i.e. othanop was chosen. '.rho
behavior of the yields of formaldehyde and acetaldehyde was
investigated in the case of variation of the conditions of
oxidation of C H at high temperatures. The apparatus and the
2 6
method were described already earlier. The experiments were
carried out in two quartz reaction containers with a diameter
Card 1/3 of 45 mm and avolume of 250 m1p the walls of which were

Formaldehyde and Acetaldehyde Yields in the Oxidation of Ethane 20-118-6-25/43
at High Temperatures
treated as follows: 1) by washing with K 2P2 (H2F2-container)
and 2) by washing with a one percent solution of K 2B40 7
(K,B 07- containerl The results of these experiments
at&lgw pressures (25 mm of mercury column) are illustrated &n
a diagram for mixtures relatively rich in oxygen (C R -20
The addition of an initiator for the radicals (No 2)2~g~ 2
the dilution of the reaction mixture with a rare gas (N 2)
increase the concentration of the active centres in the
reaction mixture to a great extent. The yield of CH 0 and
CH3CHO here remains practically unchanged, i.e. it goes not
differ from the extreme yields. The same experiments were
repeated at a pressure of 53 mm torr. The yield of CH 0
remains unchanged as before in the case of a modificaKon of
the concentration of the active centres. However, the velocity
of the accumulation of CH 3CHO increases considerably in the
Card 2/3 very last moments of transformation. The concentration reaches

e -U8-6-25/43
Formaldehyde and Acetaldehyde Yields in the Oxidation of Ethan 20
at High Temperatures
its maximum if the transformation velocity already equals
zero with respect to b6p. Then the extreme yields of the
stable intermediate product are investigated in a complicated
chain reaction. The maximum yield of CH3CHO suffers no
systematic modification in the case of concentration changes
of the acti7q centres in the reaction system. In the case
of the mixture 2C H the yield of CH 0 becomes a function
2 6:02 2
of the reaction conditions: the conditions leading to the
concentration increase of the active oentree in the system
increase the yield of CH20.
There are 4 figures and 2 references which are Soviet
ASSOCIATION: Institut khimicheakoy fiziki Akademii nauk SSSR
(Institute of Chemical PhysicsIS USSR)
PRESENTED: July 30, by N. N. Semenov, Member, Academy of Sciences USSR
SUBMITTED: July 27, 1957
Card 3/3

20-11$-5-30/59
AUTHORSt Yenikolopyan,_No S. , Korolev, G. V.
TITLEt Formaldohyde Yields on Methane Oxidation, as Dependent Upon
the Homogeneous Initiator Concentration, Inert Gas Admixtures
and the Condition of the Reaction Vessel Walls (Zavisimost,
vykhodov formalldegida pri okialenii metana ot kontsentratsii
gomogennoeo initBiatora, dobavok inartnogo graza i ot nontoy-
aniya atonok reaktoionnogo uouda)
PERIODICAL: Doklady Akadomii Nauk SSSR, 1958, Vol- 118, Nr 5, PP-983-986
(USSR)
ABSTRACTs The apparatus and the method of the measurings were described
by thesame authors already earlier (Ref 1). Experiments on
the not initidL-d oxidation of CH were carried out i43huartz
reaction containers of the same hameter (45 mm) the surface
of which was processed in different wayt 1) No special pro-
cessing ("pure" container); 2) washed out by means of bydro-
fluoric acid (H 2 F2container); 3) washed out by means of a
Card 1/4 0
container). The results of
0
1 ~6 solution of K2B
(K2B
7
7
4
4

20-118-~-38/59
Formaldehyde Yields on Methane Oxidation, as Dependent Upon the Homogencous
Initiator Concentration, Inert Gas Admixtures and the Condition of the Re-
action Vessel Walls
these experimenta are illustrated on a diagram and demonstrate
that the yield of C1120 depends on the state of the surface
of tho motion containor. Thoroforep yield of C11 20 tit given
conditions of the oxidation of C11 has no maximum, i.e. ve-
locity of molecular consumption Of CH 0 is of the same order
of magnitude as with the consumption In the chain reaction.
The dependence of the yield of CH 20 on the nature of the
surface of the reaction container observed here may have two
reasonst 1) Destruction of the active centers on the surface
of the reaction container takes place in the kinetic or dif-
fusion-kinetic range. 2) Heterogeneous reaction of the con-
sumption of CH 20 takes place in the kinetic or diffusion-ki-
netic range. A dilution of the reaction compound with nitro-
gen renders difficult the diffusion of the radicals and
CH20 molecules to the wall and therefore is bound to increase
the yield of CH 20. The admixture of materials which can
produce active centers to the reaction compound is equally
bound to increase the yield of CH 0. A diagram illustrates
the results of tbeexperiments on ihe oxidation of methane
Card 2/4 under the presence of different amounts of NO 2' Thus, e.g.

20-116-5-3s159
Formaldehyde Yields on Methane Oxidation, as Dependent Upon the Homogeneous
Initiator Concent-ration, Inert Gas Admixtures and the Condition of the Re-
action Vessel Walla
ASSOCIATIONs
Card 3/4
an increase of the 140 -content in the compound from 0 to
0,2 - 0,3 % increases the yield of CH20 by 4 to 8 times. At
the same time a strong increase of oxidation velocity is
observed. With sufficiently high concentration of the active
centers in the reaction system the yield of the stable in-
termediary product reaches the maximum value. Variation of
the concentration of the initiator exerts strong influence
on the oxidation velocity, however, practically does not in-
fluence at all the yield of CH20- All results found here
show among others the followings In the case of a not in-
itiated oxidation of methane formaldehyde is consumed mole-
cularly and the velocity of this consumption has the same
order of magnitude as consumption in chain reaction. There
are 4 figures and I reference, I of which is Soviet.
Inatitut khimicheakoy fiziki Akademii nauk SSSR (Institute fcr
Physical Chemistry AS USSR)

20-118-3__V/59
Formaldehyde Yields on MethAne Oxidationg as Dependent Upon the Homogeneous
Initiator Concentration, Inert Gas Admixtures and t
action Vessel W-alls he Condition Of the Re-
PRESENTEDs Jul-Y 30, 1957, by it. N. Semenovy Membe r, Academy of Sciences,
USSR
SUBMITTED: JulY 30, 1957
Card 4/4

AUTHORs 2o-119-3-35/65
FTITLE% On the Negative Temperature Coefficient in the Oxidation of
Hydrocarbons (Ob otritsatellnom temperaturnom koeffitsiyante
pri okislenii uglevodorodov)
PERIODICAL: Doklady Akademii Nauk SSSR, 1958, Vol- 119, fir 3, Pp. 520-522
(USSR)
ABSTRACT: I oharacteristical peculiarity of the,oxidation of the hydro-
carbons is the so eglled negative temperature coefficient in
a certain temperature range. This negative temperature range
has a strong influence upon the kinetics of the slow oxidat-
ion and upon the character of the self-ignition of the hydro-
carbons. The present theories (references 6112,13,14) actually
do not explain the phenomena of the negative temperature co-
efficient. This work investigates on the basis of the theory
of the degenerate ramification by N. N. Semenov the negative
temperature coefficient as a result of the competition of the
elementary processes, which are participating in a composed
chain reaction. At low temperatures the Qxidation of the hy-
drocarbons goes on passing through superoxide radicals, which
form after the reaction R + 02 --;%l ROO. This process has a low
Card 1A steric factor (1o-3 to lo-4) and a low activation energy

On the Negative Temperature Coefficient in the Oxidation of 2o-119-3-35/65
Eydroop.rbons
(2 to 4 great calories/mol). The elementary process of the
d~generate'ramification can be represented, after B. Llyuis
and G. Ellbe (reference 13) as well as after V. V. Voyevodskiy
and V. I. Vedeneyev(reforence 16), as result of the interact-
ion of the superoxide radical with a stable intermediary pro-
duct (a. g. with aldehyde) t ROO + R' CHO ----) HO + OR + R, Co.
By this reaction 3 new active centers form from a radical.The
reaction ROO RI CHO + R"O takes place with previous ino-
merization of the superoxide radical and therefore It has a
high activation energy (2o great oalories/mol). The competit-
ion of the two above given reactions causes the maximum in the
dependence of the reaction velocity on the temperature. At
low temperatures the superoxide radical must react according
to the bimolecular reaction. From a certain temperature pn-
wards, however, the monomolecular continuation reaction, which
above is given in the second place, predominates, by which
the oxidation velocity is decreased. The destruction of the
active centers essentially depends on the destruction of the
radicals R. With increasing temperature the probability of the
ramification decreases and on the other aide the steady con-
centration of the radicals ROO deoreaeoef so that the limiting
Card 2/4 process is the retLotion R + 02 -4 ROO. Therofore the oxidation

On the Negative Temperature Coefficient in the Oxidation of 2o-119-3-35/65
Hydrocarbons
velocity of the hydrocarbons rapidly decreases with increasing
temperature. On the base .f this simplified oxidation scheme
an expression for the re4ution velocity is written down. The
velocity of the oxidation of a hydrocarbon passes a maximum
with increasing temperature. The author also solved the foll-
owing inversion problemi Given are the values of the ratio of
certain parameters and of the difference of the activation
energy of the elementary reactions. The steric factor of
the reaction R + 02 -4 ROO is to be computed, so that the re-
action velocity has its maximum at the temperature of 400OC-
The concerning numerical data are given here. The generalized
scheme of the oxidation of the hydrocarbons, suggested here,
thus leads to a maximum of the reaction velocity with regard to
the temperature. In case of further increase of the temper-
ature the consideration of the reaction RCHO + 02 -4 RCO +
+ 1102leads to an increase of the reaction velocity.
There aro 2 figures and 2o references, 11 of which are Soviet.
ASSOCIATION: Institut khimicheskoy fiziki Akademii nauk SSSR (Institute of
Card 3/4

On the Negative Temperature Coefficient in the Oxidation of 2o-119-3-35/65
Hydrocarbons
Chemical Physics 7AS USSR)
PRESENTED: September 14o 1957 by V. N. Kondratlyev, Member Academy of
Sciences, USSR
SUBMITTED: Septemb6r-11, 1957
AVAILABLEt Library of Congress
Card 4/4

N I Ko ~_D PY/9 IV, Is
5(3) PHASE I WOK EXPLOrTATION SOV/3198
Nalbandyan, Aram Bagratwdch, a4d flikoalay S-.-,rg-,~,evIch Yenikolopyan
Formalldegid - materlal day% pla6t'~aas (Formaldahyde: Raw Material for
Plastics) Moscow, AN SSSR, 1959. 68 p. (Series: Akademiya nauk SSSR.
Hauchno-poVa1yv.r-wt7ja strlra) 17,000 coples printed.
Resp. Ed.: V.N. Kcnrlratlyev, AQa&-m1.,-1an; Ed. of Publishing House:
V.N. Vyazemtsev; Tech. Ed.: A.P. Ouseva.
Sponsoring Agency: Akt4tmlya rv!,~* SSSR. Redkolleglyn naucbno-populyarnoy
literatury.
FURPME; This book Is lntene,~!i for ohemists interested in plastics production,
students of 6rgr%n.l,:~ chc-mialvry, and ly--rsons interested in the theory and
practice of sywLhAia ma:bi;riAls prc.A..w;tion.
COVERAGE- The booklst Aleiscri'tvts the netare of forpaldehyde, its principal
properties, mtthOs Vr its pro&uc~tion, and its most important chemical
reactions vith other s-etstaw!es -to pro-3,1ce synthetic resins and -plastics.
Card 1/2

Raw Materl&l (Cont.) SOV13198
Also, some propertles Of' p:-oduats, and their Industrial and
dmestie uses aTe T'=~V`i-~%111:~,t. 1-to pe-rraotmlltleG are mentionel. There are
10 SovIet
TAKE OF' M11TEMS-
Introd4otion 3
Ch. 1. Forwaldxthyd!- %n1j. Its prap--~I,tj,~tj 5
Ch. 11. The Production of Pormaldehyd.-? 9
Ch. III. Some Fomia.1dehyd,-3 Pol~msrs 19
Ch, IV. Phenal-formaldehyd- Resins 31
Ch. V. Urea-formaldehyde. -md- Some Other Resins 50
Bibliography 609
AVAIIABLE: Libraxy of Congress TM/jb
Card 2/2 2-24-6o

50) SOVIBO-32-4-38147
AUTHORSt Yenikolopyan, N,S!, Kleymenov, N.A.,.Karmilova, L.V., Markevich, A.M.
an Nalbandyan, A.B.
TITLEt The Preparation of Formaldehyde in a Jet Apparatno by Means of the
Oxidation of Methane Catalyzed by Nitrogen Oxides (Polucheniye formal'-
degida na struyevoy ustanovke putem okieleniya metana, katalizirovannogo
okislami azota)
PERIODICAL: Zhurnal prikladnoy Xhimii, 1959, Vol 32, Nr 4, PP 913-919 (USSR)
KBSTRACT: The problem ol'methane oxidation, very important in view of chemical
utilization of natural gases, was dealt with in many investigations,
-
including those of Medvedev ZR
efs 25, 2f and D.M. Rudkovskiy. The*
present article describes some results of laboratory studies in ob-
taining formaldehyde by means of methane oxidation.catalyzed by nitro-
gen oxides. The following research workers of the VNIIGAZ M3F parti-
cipated in individual phases of these studies: S.A. Antsonyan, S.Ya.
Beyder, and N.I. Vinnikovap and of the Giprokauchuk MXhPt A.S.Zhadayev,
N.N. Chernov and M.N. Shendrik. The methane oxidation was carried out
under jet conditions at a pressure of the gas mixture near the atmo-
spheric one and at temperatures of 600 to 8000C. Various conditions of
experimentation were tried out in order to find the optimum ones, and
Card 1/2 the results were as follows: 1. The treatment of the inner surface of

The Preparation of Formaldehyde in a jet Apparatus by Means of the Oxidation of
Methane Catalyzed by Nitrogen Oxides
a vesselt in which reactions take placep with K2B407 increases and
stabilizes the yield of formaldehyde and reduces the reaction tempera-
ture by 80 or 100OC; 2. The relative yield of formaldehyde (CH20 : NO)
amounts to 10 to 12 molecules per one molecule of the catalyst; 3. The
optimum composition of the methane-air mixture was found to be 1 : 2;
4. The optimum temperature of the reaction is about 1000 C; 5. The stable
run of the reaction is possible in metal vessels; 6. The laboratory
results were confirmed by experiments carried out in a pilot instal-
lation with a capacity of 13 m3/hr of gas-air mixture. There are 7
graphs and 35 references, 16 of which are Soviet, 14 English , 2 German,
I Swiss, I French and 1 Japanese.
SUBMITTEDt September 30, 1957
Card 2/2

5 SO11/80-32-5-35/52
AUTHORS: ,,O for initiation by the "law of chance". The
Card 1/2

3/190/62/004/C.06/013/026
Initiating mechanism iyi the ... BIOI/Blic
uncertainty in the case n - 0 can be eliminated by adding an inhibitor
The kinetics of degradation of polyformaldehyde (at 2220C in 112) and of
polyformaldehyde treated with acetic anhydride was investigated
experimentally. In both caseaq a linear decrease of K was observed with
increasing No (increasing,rb) according to initiation by the law of
terminal groups. There are 2 figures and 2 tables. The mosit important
English-language reference,,io: H. H. G. Jellinek, Degradation of vinyl
polymers, N. Y., 1955-
ASSOCIATION: Institut khimicheskoy fiziki Ali SSSR (Institute of
Chemical Physics AS USSR)
SUBMITTED; April 0, 1961
Card 2/2

MIAMI
S11901621004100810091016
B1011B140
1,UTHORS: Bellgovskiy, I. M., Yenikolopyan, N. S., Sakhonenko, L. S.
MIT"LL: Determination of the molecular weight of polyformaldehyde by'
light scattering
IJERIODICAL: V7aok6molekulyarnyye aoyedineniya) v. 4,* no. 8$ 1962,
1197-1203
TEXT: -An apparatus is described for measuring the Intensity of the'light:
acattered by solutions of polyformaldehyde-in dimethyl formamide. one
ray of a direc3 beam and one daflocted through 900 in thd diah containing.
the solution are photomultiplied and then compared by dn alactronic
coopeneating circuit. -'With a thormostat allows, ter4peratures up fo 200'C
can be used. A differential refractometor in also described for
determining the increment at temperatures up to 200 0
C- At 1500C density
06845 g/om j iefraoiive index ng - 1.390; Rayleigh constani
u -6 -1
R90 -.(44-.0+1-5).-10 . cm .-Light scattering incieased linearly with
Polyformaldehyde concentration. Themolecular weight was determined,
Card -1/?,

S1190162100410b~WI0091016'
Determination.of the molecular.weight B101/B160
viocosimetrioldlly.as,a function of the intrinsic viscosity:.
44M 0.66 ' 4hi weights b.etween 89-10
oh yielded moleoular 3
4.4-10 and
3
285-10 . The molecular weights determined by light scattering y;ere not
consistent with the viscosimetric values. Light sPaittering only yields
a weight - average mole6ular weight. Thore are 10 figures and 2 tables.
The iiont important Englich-language reference is: T. A. Kocho ?I E.
Lindvig, J..Polymer Sci., 1, 9, 164, 1959-
ASSOCIATION: Institut khimicheskoy fiziki Alf SSSR (Institute of
Chemical Physics of the AS USSR)
SUBMITTED" May 12,-1961
Card 2/2

6/19 62/004/012/002/015
B101Y2166
,AUTHORS., 3kuratov, S. It., Ye
-- lli-tkolvp~~n, Bonetskaya, A. K.f
Voyevodskiy, V. T.
'~TITLE* Mechaninm of lactam polymerization
PERIODICAL: Vyaokomolekulyarryyv soyedineniya, v. 4, no. 12, 1962,
1770-1778
TEXT: In continuation of papers of 1952-54 (last publication Dokl. A14 SSSR,
95, 1017, 1954), the polymerization of E-caprolactam and f-enantholactam was
studied in the presence of water, water and aci.d, and water and alkali at
231-50C. A slightly modified reaction scheme is proposed on the basis of
experimental results concerning induction pprio'd, maximum reaction rate,
time before maximum reaction rate is reached, degj~ee of conversion, heat
kI k
effect of the reaction: (1) B + H20 -1 AH; (2) AH + AH -~4 P + H 20;
k1
k 1 k k
(3)~AH + P LL* P + 11 20; (4) AH + B + X -:~L P + X 5 13 + P P
Card 1/3

S/190/62/004/012,"OC)2/01'/
Mechanism of laotam... Biol/BI66
k k
(6) B + H20 + X AH i X; (7 AH + X " B + H 20 + X; where B - lactam.
AH - amigo acid, P - polyamide, X - catalyst. The probable cour-se of these
reactions under diff erent conditions is discussed, and the following
equations are derived for the rate of polymerization, w: (A) for polymeriza-
tion of f--caprolactam in the presence of H2 0; w - alp 20][B1 ([Bol 2 _ [B11),
where W - k k /2k (b) for polymerization of I-enantholactam in the
4 6 7;
presence of water: w = aj[H20] [B) j [Bo] 2 _ (B 12 ;where a' - kO-5kO-5k6A3;
5 2
(C) for polymerization of E-caprolactam in the presence of H 0 and H PO
2 3 4
W 014 2 2
[AcH ) [B] V (B 0 (B] , where 01 - (k4 k5k6LH201/k7)0.5, and
AcH = acid; (D) for polymerization-of t-enantholactam in the presence of
4 _ [B12
0 and H PO : w = at rL_AcHJfB] [B where
2 2 4 012
at ~ k0.25kO.75kO.5[H 0]0-5 AO -~5; (e) in the polymerization of E-capro-
2 5 6 2 3
lactam and ~-enantholactam in the presence of H 20 and NaOH, the presence of
Card 213

S/190/62/004/012/002/015
Mechanism of lactam... BIOIIB186
NaOH,only reduces the induction period without affecting the polymerization
kinetics proper. All the experimental results ar~e' satisfactorily explained
by these equations. There are 3 tables.
ASSOCIATION: Moskovskiy Cosudarstvennyy univernitet im. M. V. Lomonosova
(Moscow State University imeni M. V.- Lomonosov)
SUBMITTED: June 24, 1962
Card 3/3

5/190/62/004/012/003/015
Bioi/BW
AUTHORS: Yenikolopyan, N. S., Bonetskaya, A. K., Skuratov, S. M.
TITLE* Induction period of E-caprolactam and I-enantholactam
polymerization under various conditions
PERIODICAL: Vysokomolekulyarnyye soyedineniya,,V. 4, no. 12, 1962,
1779-1783
TiXT: A set of reaction equations was drawn up in a previous paper-
(Vys6komolek. soyed., 4, 1770, 1962) for the polymerization of F--capro
lactam and t-enantholactam in the presence of water, water and acid, and
ki k
water and alkali: ( 1 ) B + H 0 V=--' AH - ( 2 ) AH + AH "::4- P + H 0
k 2 ki k 2 k
(3) All + P -:~- P + It 0; (4) AH + B + X -':-4- P + X1 (5) B + P P;
k 2 k
(6) B + H 0 + X 6 All + X; (7) AH + X -::Z. B + H 0 + X1 where B - lactam,
2 2
Aff - amino acid, P - polyamidot X - catalyst, whose functioning groups are
either the end-Croups of P, i!n the case of polymerization with water, or
Card .1/3

S/1',90/62/004/012/003/'O 15
Induction period of... 1310-1/13186
If 0 ion in the caso of polymerization in the preaqnce of acid. In the
present caper, the experimental data are uned for deriving oyintionn for
the induction period as dependent on the amount of H 0 added. Reaction (1)
2 k'
catalyzed by the amino acid riv~es iise to: B + H 0 + AH AH + AH.. The
2
induction period t - (1/y) ln W/U; where w - U09t , a - k5lk,LBI/k;, and
k
IN reement with the experimbat, the induction period is
, ['q2() In ac
inversely proportional to'the-amount of water added. The induction period
decreases with an increased addition of NrtOH. In this case, the cooperation
of the hydroxyl ion must be taken into account besides reaction (1) and the
k -11 -
catalysia by the amino acid: 3 + H 20 + OH AH + OH . Hence,
t a (1/y)(in w - 1n a), where Y,- W13)(H 0], a - k;k'-(Bj(OH-]/k,'.
2 2 1
Consequently, the kinetica of polymorizittion propooed Inturproto the
reaction co'urses cox-rectly. There are 2 figures and I tab19.
Card-2/3

5/19 62/004/012/003/015
Induction period of ... BIOIYB186
ASSOCIATION: Moskovskiy gosudarstvennyy univeraitet im. M. V. Lomonosovs,
(Moecow State University Imeni M. V. Lomonosov)
SUBMITTED: June 24, 1961
r

L 12438!41 EWP(J)/EPF(c)/EWT(m)/B])S ASD Fc-h/Pr-4 RHIWW
C 16 " "NR: AP30OU59 S10190163100310061086lloa67
N
L___k.___Y_A~_olopyan, N. S.
-AUT11ORi---Dudina in
TITLEt Thermal and thermo-oxidativeldegrad.ation, or Eoly malde de. 1. Order
of the thermal degradation reaction
SOURCEs Vy*sokomolekulyarny*ye voyedinonlya, v. 5, no. 6, 861467
TOPIC TAGS% I thermal degradation, thermo-oxidative dagradation,~ degradation reac-
tion, polyformaidehyde, activation anorgy
'-ABSTRACTs-~--Th6-~6!yit-ors-ii4dizi the study were prepared by-polymorization of
--formaldehyde -in -toluene. -using -calcium -stearate as initiator. A part of the
polymer was stabilized by beating at 100C for three hours with acetic anhydride.
;The molecular weights of the -nonstabilized polymers were 2.57X10 suP-5-and 3.16x],o
-sup -5,, -and -1.3&dO -svp- 5 --for the stabilized polymer. Thermal destruction was con-
ducted in-a vacuum installation at 10 sup -4 = residual pressure, at temperatures
varying from 120 to 346C, and the volume of liberated gas was detemined by pres-
sure cbange, Such a method is applicable where t?2e sole gaseous product is a
monomer, and the authors were able to show that it fitted their case by obtaining
pressure readings almost matching theoretical ones. The semilogarithmic
Card 1/2
.................... ..................

'ACCESSION NR% AP3001139
anamorp oses of kinetic decomposition curves of alpha-polyipxymethylene and the non-
stabilized p63,yformaldebyde are carved, while.those. of the stabilized polymer form
a straight line, indicating that in the latterinstance the decomposition of the
polyaer follows a first order course. It implioa that haro the activation energy
of active center destruction in leas than- the activation onorgy of monomer elinim-
tion. A psLrt of the experlment was conducted by 0. M. Koz Iminy*kh, Orig, art.
haot 15 formulas, 3 charts, and 1 table.
ASSOCIATION.- Institut khimicheakoy fiziki AN SSSR (Institute of Chemical Physics,
Madewl.of Octences WSR)
SUMUMM .1ONov61 DATs Am t ol-,xd63 ENCLt 00
SUB COES: 00 NO REF SOVt 004 OTHERs 004
!Cad 2/2

SEMEBOV., N, N., akademik (Moskva); YENIKOLOPYAN-,,,,.N&,,$,.(Moskva)
GOLIDANSIKIY) V. I. (MoBkva7
On'the problem of polymerization at low temperaturee,
Rev chimie 7 no. Is 5M-511 16~.
1, Institut khimicheskoy fiziki AN SSSR, Moskv~L.

36055
-"/U6.3/62/007/0(J2/007/U 14
AO 57/A 126
solo
AUTHOUS: ~~~~.Doctor of Chemical Sciences, Vatdanyan, M.S.
TITLE: The production of polyformaldehyde
PERIODICAL: Zhurnal vsesoyuznogo khimicheskogo obshchestva imeni D.I.
Mendeleyeva, v. 7, no. 2, 1962, 194 - 200
TEXT: Properties, the produation, and the mechanism of polymerization
of pulyi*Oi-,,ialdehyda ive discussed and some experimental vasults are prerented.
A great part ot' the presented information is apparently taken from the Symposium
on Macrochernistry in Canada, 1961. Polymers of formaldehyde are known since thadr
discovery by A.M. Butlerov. Two types - polyoxialdehydes and polyoximethyleries
can be noted. Ifigh molecular weight polyoximethylene, i.e., poly t'ormaldchydo,
shows some outstanding physical and. chemical properties, thus being oi' interest
"or various purposes. Monomer forffaldehyde used as initial material can be pre-
patcd: i) As low-molecular compound., para- formaldehyde andX-polyoximethylene;
2) nz ccerai-acetal; or 3) by partial condensation. The monomer should contain
les:i than u.uulrlj admixtures. Preliminary polymerization, or filtration through
molecular Cilters allows to remove tIx impurities below v.001%. The purified
Ca rd l /3

S106316 21U0 7/01J 2/U07/0 14
.The production ol . ..... AU57/A126
monomer can be polymerized in two ways In the presence of various catalysts.
The latter is not con*umed during polymerization, i.e., active centers ave not
lost. Tiie effect of H20, CH
I CH30H, HCOOH, _3COOH, (CH3CO)20, CO, C02. and other
substances on rate and degree of polymerization was investigated expericXrtally.
In contrast to the OH ions the HCO3 and HCOO ions do not influence the polyme-
rization of formaldehyde. thus, in principle, a regulation of the process and
reproduction of polyformaldehyde with any desired molecular weight is possible.
The stability of para- formaldehyde against heat and oxidation depends only on the
nature of the end-group of the chain. The present authors demonstrate that at
thermal destruction also processes of chain transfer to the polymv are of im-
portance as well as to the evolving monomer formaldehyde, simultaneously with
.generation, growth and rupture of chains. Studies of the kinetics of thermal
destruction of polymers with CH and OCOCH3 end-radicals showed that the different
rato of doatruction depends upon tho difforont activation anargy. It Vinn pro.."Id
experim,ntally that oxygen increasea sharply the destruction rate, rind decivnser,
even more the molecular weight. However, the molecular weight of acetylized
polymer decreases much slower than !that of the non-stabilized polymer. This In-
dicates that oxygen does not attack directly the middle of the) chii1n, Oxyjron
oppnivritly (loan not attnok dlivotly tho polymal, ollain, bul, Uld ovolved monolwir
Card 2/3

S/063/62/007/002/007/014
The production of .... A057/A126
formaldehyde. The observed greater mutual effect of oxygen and formic acid Is
not explained yet. An efficient mixture of a stabilizer should be able to bind
the evolving formaldehyde (limiting thus its further oxidation), also the
evolving Cormic acid, rind contain radical inhibitors ivtaining the chain PVocOW3
of destruction. There are 9figures.
Card 3/3

KOZIDVO P.V., otv. red.; ANDRIANOV, K.A., red.; DOGADKIN, B.A., red.;
DOLGOPLDSKP V.A., red.1 red.; KARGIN,
V.A., red.; KOLESNIKOV, G.S., red.; KOROTIOV, A.A., red.;
KOBSHAK., V.V., red.; LAZURKIN, Yu.S., red.; MOVEDEV, S.S.,
red.; MIKHAYLOV, N.V., red.; PASYNSKIY, A.G., red.;
SLONIMSKIY, G,L., red.; alIRNOV, V.S., red.; TSVETKOVV.N.,
red.; FREYM-iKRUPENSKIT, D.A., tekhri. red.
[Adhesion of polymers] Adgaziia polimerov; sbornik statei.
Moskva, Izd-vo AN SSSR, 1963. 142 p. (MIRA 16:10)
(Polymers) (Adhesion)

KOLESNIKOV, G.S., otv. red.; ANDRIANOV, K.A., red.; DOGADKIN, B.A.p
red.; DOIMPIDSK, B.A.j, red.; YENIKOIDPYAB, red.;
KARGIN, V.A... red.; YOnCV, PAr.-,,"?id-.;!'TOR=OV, A.A.$
red ; KORSHAKp V.V., red.; LAZURKIN, lu.S... red.; MEDVEEDIEV,
S.S... red.; MIKHAYIDN', N.V.j, red.; PASYNSKIY, A.G., red.;
SLONIMSKIY, G.L.) reei.; SMIFINOV, V.S., red.; TSVETKOV, V.N.,
red.; FREYMAN-KRUPENSKIY, D.A., tekhn. red.
[Feterochain high-molecular weight compounds] Geterotsoppye
vysokomolokuliarnye i3oedlnoniiaj obornik otatei. Moskva,
lzd-vo "Nauka," 1963. 2,46 p. (MIRA 17:3)

KOLESN1KOV, G.S., otv. red.; ANDRIANOV, K.A.p red.; DOGADKIN, B.A.t
red.; DOLGOPLOSK, B.A., red.; YENIKOLOFYAN,. N.S.1, red.;
KARGIDI, V.A., red.; KOZIOV, PST,-~;a.'-; *'kOROTKOVY A.A.p
red.; KORSHAK, V.V., red.; LAZURKIN, Yu.S., red.; MOVEDEV,
S.S., red.; MIKHAYLOV, N.V., red.; PASYNSKIY, A.G., red.;
SLONIIISKIYI G.L.p red.; SMIRNOV, V.S., red.; TSVETKOV, V.N.j
red.; FREYVAN-KRUPENSKIT, K.A.p tokhn, red.
(Carbochain high-molecular weight compounds) Karbotsepnye
vysokomolekuliarriye soedineniia; abornik statei. Moskva,
Izd-vo All SSSRp 1963. 287 p. (MIRA 17;1)

ACCESSION NR: AT4020701 S/0000/63/000/000/0100/0106
AUTHOR: Bellgovskly, 1. M.: Kravchuk, 1. P--, Nikol'skly, V. G.: Yonikolopyan.
N.- S.
TITLE: Low-temperature radiation-induced polymerization of isobutylene
SOURCE: Karbotsepny.:ye vy*sokomolekulyarny*ye soyedinenlya (Carbon-chain macro-
molecular compounds); sbornik statey. Moscow, lzd-vo AN SSSR, 1963, 100-106
TOPIC TAGS: polymerization, radiation polymerization, Iso'butylene, low-temperature
polymerization
ABSTRACT: In order to clarify the degree to which the reaction proceeds via an
ionic mechanism, the kinetics of thet radiation polymerization of isobutylene over
a temperature range of -40 to -196C were investigated. With respect to low-
t (F~erature radiation polymerization, the following conclusions could be drawn:
The independence of the polymerization yield of the Intensity of the dose indi-
cates a linear relationship between the polymerization rate and the radiation in-
tensity. The polymerization of isobuty-lene In the liquid phase is accelerated by
a decrease in temperature down to the freezing point of the monomer. The reaction
rate has an activation energy of 2.5 kcal/mol. in the solid phase, the reaction
rate has a normal temperature dependence with an aliparent activation energy of
Cord 112

ACCESSION NR'. AT4020701
+1.88 kcallmol. The maximum rate of polymerization Is obtained In the initial
stage of Irradiation and the process shows a tendency to become saturated as the
dose of radicition is increased. The molecular weight of the product-has a maxi-
mum value during the initial stage of irradiation, after which it drops rapidly
to a value of 15,000-20,000; thereafter it ' is essentially Independent of the dose.'
Orig. art. has: 5 formulas and 5 figures.
ASSOCIATION: Institut khimicheskoy fiziki AN SSSR (institute of Chemical Physics,:
AN SSSR.)
SUBMITTED: 26Apr62 DATE*ACQ:' 20Mar64' ENCL: 00
SUB CODE: OC NO -,IREF"SOV: 005 OTHER: 005
Card 2/2

NIKOLOPYANI, N.S.; SHILOV, A.Ye.
"Chemical kinetica and catalyuisO b7 G.H.FanchenkoT.
:V.P.Ioebe&va. Reviewed b7 N.S.Emi lopian, A.E.Shikov.
Kin.i kat. 4 no 4:322-P25 Mr-Ap 163. (MIRA 1635)
(Chemical reabtion, Rate of)(Catalysio)
(Panchenko'v., G.M.) (Lebedev, V.P.)

DUDINA, L.A.;. PTIRWYAN. N.S.
Thermal and thermal oxidation degradation of polyformaldehyde.
Part 1s Order of the-thermal degradation reaction. Vysokom.soed.
5 no.6:861-867 je 163. (MIRA 16:9)
1, Institut khimichookoy fiziki AN SSSR,
(Formaldehyde) (Degradation)

ACCESSICK NR: AP3003787 Slol-90163100510071096610993
AUTHORS t Dudinas L. A.; Yonikolopyan 11. S.
TITLE: Thermal and thermooxidative degradation of polyformaldehyde. 2* On
temperature dependence of thermal dogriuLation rate
SOURCE: Vy*sokomolelculyarny*ye soyedira)niyas v. 52 rio. 4 19639 W-993
TOPIG TAGSs thermal dissociations dissociation rate, unstabili2ed polyformal-
idehyde, activation energyp true activation enorgys chemical reactions' reaction rate,'
constant
ABSTRACT: The thermal dissociation of polymers upon heating was investigated,
using the method described by the authors in (Vy*sokomoleks ooyed. 50 8619 1963)0
,The polymer specimen was in the-form of a tablet with heat being applied from its
base. At high temperatures (above 26w.) the dissociation rate of unstabilized
polyformaldehyde (PFA) was found to be independent of the temperature, In the
temperature range 190-260C the dissociation activation energy of PFA in the 0.02 gm;
specimen yielled a value of 17 + 1 kcal,fmolp and for the 0.05 gm, specimen, 13 * 1
kcal/wl. An analytic method has been developed to determine the true activation

ACCESSION NRt AP30037.87*
energy in the chemical reaction when the limiting factor in the heat treatment is
the intbrnal conductivity of the specimen. The effective reaction rate constant ig
eipressed by
7.
00 IfiT'j"
whore X - thermal conductivityp P densityp S cross-sectional area, E -
activation onorgyp ko - constant in heat source tam
WMT
The effective activation rate constant is then plotted against the inverse specimer
,Weight. It is shown that when the apparent rate constant is inversely proportional
to the sample) the true activation energy is twice that of the experimontaX value.
The activation energy of the stabilized polymer terminated with the hydroxyl group
iyiclds a value of 26 kcal/mol and with acetylene, E - 32 kcal/rolo "The authors
;express their gratitude to A. S, Komparwyets for evaluating the worke" Orig. art@
';hast 13 equations and 3 figures,
IASSOCIATICHt InsItitut khimioheskoy fisilti AN SSSR (Inatitute of Chamd"I Physios
;AX SSSR)
[Card 21A

V-25%08--63
i.~~.~'SIO19016310651008ln3511139
~4pC= ON ffl~ sAP3004699
OPY4
TITLE i Thermal'ind thermooxidative decompo'sit 6n'of ~pojyformaldEh in
Zde 3. Cha
tranafer reaction in thermal discomoosition
SOURCEI iY*30komo1sku1yarny*ye aoyedineniyaj`,-v*- 50-1 _n0.-. 00 1963t 1135-1139
ITOPIC TAGSs fomaldehyde polyner, alpha-ooly6xy~ethylena, thermal decomposition,
chain-transfer,,:stabilization
ABSTRACT t -This report is a-continuation of earlier studies by the authors on
ithermal decompo3ition of formaldehyde polymers' -An 'explanation was sought for
the deviat4nn of the decomposition rate from tLt of a first order reaction. The
method ust:d was described in an earlier publication 4y the authors (Vy*sokorolak.
15, 986t 1963), the kinetics of the reaction being evaluated on the basis of gas
rate evolution from polyforr-aldehyde samples at 130-20W in a closed system. It
vias found that the rate of monomeric HCOH evolution in nonstabilized specimens
tapered off within 5 to 10 minutes, a phenomenon not observed in control tests
1
1nan atmosphere of nitrogen.1 hus excluding.pressure as a potential factor of

LL126o',
A.00F, MON I - - /005/008/110/464
lilt t0300 70) -A 90163
/71
AUTHOASt Dudina. Le A g Karmilova, Yertikolo H&_S'
m L _-V MEN - - ;;
TITLE t Thermal and thermookidative decomposition of,polyformaldehydes 4, Kinetics
of the thermooxidative reaction
SOURCE; Vy*sokomolokulyarny*ye soyedineniyal vo 5, no 8P-1963p 1160-3264
TOPIC TAGM formaldehyde,.pR~i~formaldoh-vde. thermooxidative decompositi autor-
catalysis.Latabi-lizatidn
ABSTRACT: The polymer (0.382 gm.3) was placed-in' a'glass dish attached to a
quartz spiral suspended inside a glass cylinder, -Through this a stream of oxygen,
was passed at temperatures' rangilig from 165-2200, Tho.changes in weight of the
sample were followed by recording the extension of the spiral. Tho gaseous do-
' I :n means of condenuation at temperatures down to
00 iti products, trapped by
Mpo or analyzed for monr)mer formaldehyde, organic peroxides, hydrogen
-twe, and formic acid. The viscosities of the samples were determined by
perox,
'Ubbelhodets method in dimethylror-mamide solution at 150C ar from it the molea-
id
ular weights were calculated, It was found that We oxidative decomposition of
/2

4CCEMION N4
tabilized-polyforma,ldehyde pi-oceeds -at- &-rate.n w'ly 50 tia
I
-nons as greater than
purely thermal-,decompositionlin an atmosphere of aygonp formaldehyde being the
only decomposition products Also, in the oxidative prdqeas the molecular weight.
lof the residual polyformaldehyde-shows-aogear3.y instant drop in molecular weight
~to 2 6#103 from an initial figure of 3-1 j while in an atmosphere of argon the
!molecular woight is affected only slightly'#' Experiments with polyformaldihyde
Istabilized by means of acetic anhydride revealed a rapid slowing of the decom-
1position reaction and an insignificant drop in molecular weight,, It is suggested
Ithat the polyformaldehyde dec9mposition process possesses autocatelytic character-
I istics. Orig, art. hass 6 charts~,j
ASSWIATIONt Institut khimichaskay fiziki, AN SSSR (Institute of Physical Chemist
-lkcademy of 66ioncesp, SM)
SU EMITTED; 05Jan62'.
UTE ACqt 2SAug63-
EMLs 00
ISUB COM CH W W SOV# .005 OITM 1 002
Card

-.EPR/EWP(J)/EPP(C)/EWT.(fl)/BDS--"-'--A-31)'- Ps-4/pc-4/
L -1560143
T--~47 - ;_ffiVW-T/Jt-
ACOFMION-URv:03004710- 8/0190/63/005/008/1245/V
-L, V.; Yenikolopyanp No So
AUTHORSt DuAina,- L. A,,- Aiyantsp L,-Aol Karmilovat
TITLEt Thermal and tharmiJA& qf.oolyfo maldehydeC_/_'5. The
t1yA dncompa&iti4
role of formic acid in the thernooxidative reaction
-1249
SOURCEs Vy*sokom~11kulyarny*ye soyedine ya., v# 1963, 1245
rma
TOPIC TAGSt thermal decomposition, therwooxidative decomposition, polyfo 1-
dehyde, formic acid, stabilization
ABSrRACTs- Experiments were conduo ted using 0-382 gm of acetylated polyformal-
dehyde having a molecular weight of 0 .7*102, which was subjected to vapors of
85% formic acid in a current of oxygen or argon, or to the acid alone. The
kinetins of polyformaldehyde decomposition were recorded in an earlier paper by
.. At Dudinap L. V. Karmilova, No S. Yonikolopyan (Vy*sokomo1ek. soed., 5, 1160,
1963). It was found that at 220C tho rate oC thermooxidative decomposition of
polyformaldehyde in argon increases in proportion to the formic acid gas content
and that an almost double rate and volume of destruction take place in the prea-
once- of oxygen. Where samples of polyformaldehyde were reacted with liquid 65%
-rard V2.

..Card

PROSHLYAKOVA, N.F.; SANAYA, I.F.; 'YFNIKOLOPYAN _N.S._-
Polymerization of formald'.ehldo. Part 1: Order of the reaction in
anionic polymeri2ation. Vyiokom.goad. 5 no.llsl632-1637 N 163.
()URA 17.- 1)
1. Institut khimichaskoy fiziki AN SSSR.

IRZHAK, V.I.; ROMANOV, L.M.; I~NIIL
PLO
Polymerization of formald-ohyde. Part 2,. Effect of a monomer on
the mean degree and rate of polymerization. Vysokom.soed. 5
no.lltl638-1640 N 163. (MIRA 17il)
Institut khimicheskoy fiziki AN SSSR.

BOBXOVA, L.P.; XORSAKOV, V.S.; ROMANCY, L.M.; YENIKOLOPYAN, N.S.
Pol*rization'of formaldehyde. Pa rt 3t Effect of active addition
agents on the polymeriuLtion of formaldehyde in solutions.
Vynokqi~.soed- 5 no.Ili:1653-1657 N 163. (MIRA 111r1)
I.Institut khimicheskoy fiziki, AN SSSR.

FROSHLYAKOVA, N.F.; SANAYA, I.F.; YEN1KOLOPTAN,,.-Nt-SV1,
Polymerization of formaldehyde. Part 41 Change in molecular
weight of polyformaldehyda in the courva of polymorization*
Vysokom. soed. 5 no.'L2:1776-1779 D 163, (MIRA 17q)
1. Institut khimicheakoy fiziki, AN SSSR.

BOBKOVA, L.P.; KORSAKCV, V.S,j ROMANOV, L.M.; YENIKOL4)PYANp H.S.
Polymerization of formaldehyde. Part 5t Effect of water,
metbyl. alcohol, acetic acid, and acetic anhydride on the
polymerization of formaldehyde in solutions. Vysokom. soed.
5 no.22:1780-1784 D 163. (MIRA 17:1)
1, Institut khimicheakoy fiziki AN SSSR.

FF BDS--ASD
2 i-6 Y-Pr-,4---%IWW----
'AUTHORO.' Dudinap- L. A.;'Karmilovas 11, V.;, Yeni~lo atn U. S.
py
Oxidat
TITU ive destruotion - of. polyfo=aIdebyde
"ROM 1501 no. 2# 1963 3 v-312
I E: AN SSSR4'_.~Dok1adyp:v. b9
--TOPIC- TAGS: --thermal- oxidative--destruotion polyformildehyde --depolymerization
~ftctiv
ation energy,, reaction rate
-destriiotid-n- OolyforvAldeb7d*--,W-ith---hydroxyl or with-
1ADSTRACT-t ' Thermal -oxidative -of-,
-acetylenlic end-groups was-carried~-cyutat-180-185 degrees; -condensed products were
n~~Iy c Liected and analyzed. Regardles6 of the end group,, main products
contir 0
--were --monomeric - formaldeEy with- traces- of-__T_
6 thers i - but to ~ peroxides. The coux-se- of- the 0-initiated depolymerizAtion and pr&_,ti-
tal absence of.oxidation reaction %res studied. Activation energies and reaction
rates were calculated for proposed reactions where the molecule can disintegrate as
-,,shown in -equation (1) of anolbsure,l or it cAnadd amolecule of 0 an shown in
--anclosure-1, then gmbsequent, looTmerizo., However.,,-perokides -were -
Ilot detected: - either they were rot formed according to proposed reactionss or P-ddi-
tional -reactions, not calculated hewain, are imrolved. Also none of the proposed
reactions explains the formation of' formic acid. Further study is reco=onded.
J'Card 1/11_", ociatlon:- Charitcal. Physics, -kciLderq Of Sciences SSSR

~.-121 ~J5_6 MIEW -J)YtPF(c)AW AFFMIAsD
SA-026/6j/150/003/0
~~4CCSSSIOVM-AP3000753 0 cSO/0583
AUTHOR t -A-0-1-Berlin .-Al. A3.0 Urmilova U'Le, V.; Yenl)colopyan, N. S.
the,
-da'structlo I c `polyfomaldehyd
TITLE:' Changing molecula r weight, -oiddativie n ;6-
--SOURCE:- 'AN SSSR. -DaklacLy, vo. 130 j nji. 3,1063o 580-583
TOPIC TAG~t oxidative'destruction, p6lyformaldehyde
.~In, coikt --and-
Unuation of
-~=9;-7s;--Tehikol:opyan-(DAN.1--150-~,~,-,iio L.2 il& tudY-va 0 made to determine. whether
JQ L- 3)
the--0- initiated- de6ompos f _-_poiit6z%i1d6h7de- ik(kik - indeed -go -a to-the - -
_ffie enol9sure. _. ZVorimentaniv a i rp, rop. in mo e ar -weight
equation,shown in 3ha d
was found, -such L that. its dependence on the degree of conversion is representative
of the formation of two, stable fragneints- iTon decomposition of the Molecule.
These fra Igments could be fomed either because the 0 inhibits decomposition of the
-active contor.in addition to initiating destruotion of the polymer or because of
acidolysia of the polymer by the acid - from -the oxidation process. CalcdationB
also indicated that the above-proposed reaction does not account for the drop in
molecular -weight. Orig. art. has: I.figuro and 28 equations.
Card 1
.......... .

OOLUMKrY, V-1-P TROFDOVA, O.K.,
RadUtion-irAiced so]JA-state polywrlsation.
ParUieftlywrisation of sarylotitftlee~*
;-4 P&AM.Polywrization of vigwl asetal4a
Variou kiab of pelpwrisaUen ratA tw*sratmms ft"nismads.

ra
AND)f1i)L-3/Wr Mx
~CCK~STON Ui kM-"152 3/01190/64/006/001/oWe/000
--IIA-kiv- V. T.. Yeni-kolopyan, H.
Terakha", 5-.-
Ui5TRA(7: The radiaLion tne 9olid phase of morm-nom was Lnves-
volmPri7-aLion rate
ua
=z alzo ue--4. Th# talorimat-r-le determirmv~

I pim rv . ne-
--- , VP
93 M SM* M-1
omm, Cab I

ff~g_-,m
u -L
/F c -ill
,pw(c n)
n
L
rra,l

L .~F. 71y -.t L~
i I , -, I T ~; 11 .. . A , ! , ~ 4 )(4 1 , 1
. - . - . , -t,
..xi . - .; , ul
Iq
i . i-. . f
,e I
I
.. --U 7), - _.,r_ -

fu-, t t. 0, -j a 1, C, "L..2 t u f,- E f,