SCIENTIFIC ABSTRACT YEREMENKO, V.N. - YEREMENKO, V.N.

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SCIENTIFIC ABSTRACT
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FESENKO, V.V.; YERM-IENKO V.N.; VASILIUo 14-10 lie solutions@ Part 2s Surface Surface tension of liquid metal ckel - copper* Zbur.fiz.khim. 35 tension of the system Di (14IRA 3-4:8) no.8;1750-:L751 Ag 161- 1. Institut mta.1-103ceramiki i spetsiallAYkh Oplavov AN USSR, Kiyevo (Nickel-Copper alloys) (Surface tension) NAYDICH., Yu. V.; YERFKNIIO, V~jl "large drq* method for the determination of the surface tension and density of molten metals at high temperatures. Fiz. meti metalloved. 11 no.6-.883-888 is 161. (MIU 14:6) 1. Institut metallokeramiki i spetsialInykh splavov AN USSR. (Surface tension) (Metals in high temporature) NATDICH9 Tu.V.; MMUMJ4, V..W.; FESENKO, V.V.; VASIIJUV M.I.; XMCFJ=p L.F. r 'r' F* Temperature dependence of the ourface te~vion of liquid cooper. Zhur. fiz. kbim. 35 no.3.1694,-695 Mr 161, (MM 34:3) 1. Institut zwtallokeramiki i tviallnAh splavov. sr (Copper) (Surface tension AUTHORS: TITLE: PERIODICAL: 24655 9/07 61/035/006/W7/013 WNB203 Yeremenko, V. N. and Nizhenko, V. I. Effect of titanium admixtures on the surface tension of nickel and cobalt and on their interfacial tension with aluminum oxide Zhurnal fizicheakoy khimiip v. 35, no. 6, ig6i, 1301-1306 TEXT: The present paper deals with the effect of titanium admixtures on the surface tension of Ni and Co, which metals are used in powder metal- lurgy as binding agents for titanium carbide, titanium nitride, or titanium boride. The surface tension is determined by the method of the drop lying on a horizontal base. For the alloys, 99.99 % pure Ni and Co, as vell as titanium iodide with less than 0.07 % impurities, were fused together in the aro furnace. The tables of Bashforth and Adams in a modified form were used to calculate the surface tension. Besides, a new table was compiled with the values ~ in direct dependence on x/z of the drop (Fig. 1) at if .600. The function was ~ -b2/p(2x)2. The surface tension a was calculated from a .~(2x)j qg. The error of measurement was Card Effect of titanium admixtures on... 61 S/076516 J~ 035/006/007/013 B127/B203 3-5 ~. in the system CooToIA120 31 the study was conducted in vacuum at 1.10-4 mm Hg and 16000C. The titanium content was 1.96 ~6. Titanium admixtures of 0.23 g-atom/l and more showed no effect on the surface tension. With 0-05 g-atom/l Ti, the inter5acial tension at the boundary Cc -A1203 dropped by more than 1000 erg1cm . The adhesive power increased simultaneously with the reduction of interfacial tension. Thus, a considerable interaction between alloy and A120 3base took place. In the system Ni,Ti, and A120 31 the same results were obtained as for Co. At a vacuum of 1-10-4 mm Hg, the specimen was always covered with a thin, but noticeable oxide layer during the experiment. The same phenomenon appeared in the case of BeO instead of A120 3 as a base; likewise, in higher vacuum obtained by freezing the vapors of the oil diffusion pump with liquid N2 . On addition of Ti, a reduction of the Ni surface tension was observed. All this changed abruptly if the experiments were made in H2 atmosphere. In this case, no activation by Ti on the interface Ni- gas was observed. The interfacial activity increased at the same time. The Card 2A -'~- S/07Pn/035/006/007/013"' Effect of titanium admixtdres on ... B127 11 203 same occurred by meltinC the specimen in In medium, and subsequent separa- 2 tion of H2 by evacuation. In the system Sn, Ti, Al2OY a high surface activity of titanium was observed at the Interface of the liquid Sn. This effect is explained .toy the adsorption of 02 Te.sAue~ from the vacuum by.*Ti. 0 causes the surface activity. Adsorption of Ti at the metal -Al 0 2 2 3 interface. In the Ni and Cc system, Ti develops higher interfacial activity due to high formation energy'of the loveat Ti oxide. With the use of the Gibbs adsorption equ&tion, the excessive Ti concentration at. the interface metal -Al 203 was calculated-(by graphical differentia-tion of the curve). Fig- 4 shows-the reaulto for Cc -Ti and Ni -Ti on A120 3 j ,In the maximum of the curve, the corresponding thickness of the adsorption layer is 2.7-10- a cm. It is assumed that the lattice nodes occupied by 0 ions are the active centers of adsorption of Ti atoms on the Al 2 03 sliTface. In maximum adsorption, every Ti is bound to an 0.' The authors mention joint papers by V. 'A". Yoremenko with Yu. V. Naydich and Card 3/4 1/ 24655 -9/076/.61/035/006/007/0'-13' Effect of titanium admixtures on... B127/13203 A. A. Nosonovich: Mektronika, no. 4, 136, 1959; Zh- fiz. khimii, 34 1186, 1960. There are 4 figures, 2 tables, and 11 references: 8 Soviet- bloc and 3 non-Soviet-bloc. The most recent referehee to the English- language publication.reade as follows: Kingery V. b., J. Amer. Ceram. Soc. 37, 42, 1954. ASSOCIATION: Institut metallokaramiki i spetsialInykh oplavov (In'htitute of Po--~,der Yetallurgy and Special Alloys) SUB'11TTED: September 25, 1959 Fig. 1: Diagram for'calculating the Ejurface tension from the form of the drop. x 4! Pard 4/0 S/076/61/035/008/005/016 3101/B218 AUTHORS: Fesenko, V. V., Yeremenkol V. N*j and Vasiliu, M. I. (Kiyev) TITLE: Study of the surface tension of liquid metal solutions. II Surface tension of alloys of the system nickel-copper PERIODICAL: Zhurnal fizicheskoy khimii, v- 35, no- 8, 1961, 1750-1751 TE(T: The authors attempted to check how far Cu-Ni alloys represent ideal systems and obey Raoult's law. For this purpose, the surface tension of Cu, Nil and their allo 9a was determined by measuring the maximum pressures in a gas bubble at 1550 C. Measurements were made in pure He or H Apparatus and method have already been described by the authors (Sb. IIS?royeniye veshcheetva i spektroakopiyall (Structure of substance and spectroscopy), 78, ig6o, Izd. AN SSSR). The total amount of impurities in the metals used was not higher than 0.1%. The alloys of different composition were molten in crucibles of pure A1203 in a high vacuum. Their composition was checked by chemical analysis. For the surface tension of Cu-Ni alloys at 15500C, the authors give the following values (rounded-off to 5 erg/CM2): Card 1/3 Study of the surface tension ... S1071"61103510081CO51016 B1017B216 atoms* of Cu erg/Om2 The data for nickel are in good agreement with those by W. D. Kingery, M. Humenik 0 10 1735 1655 (see below). The data for copper are much higher than those found byather scientists# 28 1545 as, e.g., Es E. Libman (see below). This 50, 1430 discrepancy is explained by the fact that 67 1370 the authors used high-purity copper (99-99% 79 1300 1269 and conducted the measurements under condi- 100 ti t i Th th t d d ti l on. am na e ons e con a exc u experimental data are in go od agreement with those calculated according to the Shiahkovokiy e quation. The constants of this equation were calculated according to A. A. Zhukhovi takiy (Zh, fiz. khimii, 18, 2141 1944). This agreement confirms that the system Cu-Ni is ideal at 1550OC- It fOllOws from the data that the copp er in Cu-Ni alloys is surface-active within the entire concentrati on range investigated. A paper by I. T. Sryvalin, 0. N. Yesin, Yu. P. Niki tin (Izv. vuzov, Tsvetnaya metallurgiyaf Ap 66, 1958) is mentioned. There are 1 figure, 1 table, and 9 references: 5 Soviet-bloc and 4 non-Boviet-b loc. The two references to English-language publications read as follows: W. D. Kin gery, M. Humenik, J. Phys. Chem., 51, 359, 1953; Card 2/3 S/076/61/035/008/005/016 Study of the surface tension ... B101IB218 E. E. Libman, Phya. Rev., 29, 911, 1927. ASSOCIATION: Akademiya nauk USSR, Institut metallokeramiki i spetsiallnykh splavov, g. Kiyev (Academy of Sciences UkrSSRf Institute of Powder Metallurgy and Special Alloys, Kiyev) SUBMITTED; November 23, 1955 PHASE I BOOK ELPLOITATION SOV/6101 Yeremenko, Valentin Hikiforovich. Mnogokomponentnyye splavy titana (Multicomponent Titanium Alloys) Kiyev, Izd-vo AN UkrSSR, 1962. 209 p. 2500 copies printed. Sponsoring Agency: Akademiya nauk Ukrainskoy SSR. Institut metallokeramiki i opetsiallnykh aplavov. Rasp. Ed.: I.. M. Fedorchenkot Academicians Academy of Sciences UkrSSR; Ed. of Publishing House: Z. S,. Pokrovskaya; Tech. Ed.s A. A. Matveychuk. PURPOSEt This book is intended for researchers in the field of metal science,and Por designers in the aircraft, shipbuilding, machine-building, and chemical Inaustries. It may also be useful to students specializing in these fields of*design. ' COVERAGE: The book., which constitutes the second part of the authMjs monograph "Titanium and Its Alloys" (published in 19553, reviews the structuress proper- ties, and applications of multicomponent titanium alloys which have btan Card 1/0 -'7 C-~ Multicomponent Titanium Alloys SOV/6101 investigated up'to the present time. The interaction between components is de- schbed and equilibrium diagrams of titanium-base systems are analyzed. Along with equilibrium datap information on technological, phyoicalp moohanicalt and other properties of titanium alloys in given. In addition, various heat-treat- ment methods applied to these alloys are discussed. In all, 122 ternary tita- nium-base systems and 52 quaternary and quinary systems are reviewed. Since these comprise all themulticomponent systems which have been investigated uptbUB rrptn-it time, the book., can serve as a comprehensive handbook in its field. No personalities are mentioned. The description of each titanium-base alloy is accompanied by Soviet and non-Soviet references. TABLE OF CONTENTS: Introduction 3 Ternary Systems 5 Ti- Ag - Al 6 Ti Al - B 9 Card 2/a ~2 PHASE I BOOK EXPLOITATION SOV/6032 Yer _u u-.,, Resp. Ed.; I. N. Frantsevich, 0. V. Samsonov, . M. Fedorchenk6, 0. S. Plearenko, V. Ve Grlgorlyevaj and V. I. Nizhenko, eds. Pov.erkhnostnyye yavleniya v metallakh i oplav&kh i ikh roll v protsessakh poroshkovoy metallurgii (Surface Phenomena in Metals and Alloys and Their Role in Powder-Metallurgy Pr;ocesses) Kiyev, Izd-vo AN USSR, 1961. 213 P. 1710 copies printed. Sponsoring Agency: Akademiya nauk Ukrainskoy SSR. Institut metal- lokeramiki i spetsiallnykh splavov. Ed., of,Publishing House: Z. S. Pokrovskaya; Tech. Ed.: A. M. Lisovets. PURPOSE:. This collection of articles is intended for scientific research workersengineers specializing in meta,ls,, and metal- lurgists. It may also be useful to advanced students at schools of higher education. Card 1/7 Surface Phenomena in Metals (Cont.) SOV/6032 coVERAOE: Articles of this collection discusi the role of surfaq~ phepomena in powder metallurgy processes and in processes of the strong bonding of various substances. Theoretical calculatione of the surface tension of some carbides and nitrides are pr!:~5--- The book also reviews modern methods for studying the surfac'r- pro~erties of metals at high temperatures and presents data on the surface tension :of refractory metals and of binary metals Particular attention is given to the effect of various addition6 the surface tension of metals and on the interphase tension at boundary between metals and various refractory compounds. Data -A the effect of thin metal coatings on the structural and mechanip.#,j properties of metals are also presented. No personalities are mentioned. Each article is accompanied by references, mostly Soviet. TABLE OF CONTENTSi Foreword 3 Card 2/7 Surface Phenomena in Metals (cont.) sov/6032 Yeremenko, 'V. N. Physic,ochevical Fundamentals of the Formation of a Cermet 5 Semenchepko., V.- K. -On the Relationship Between Volume and Surface Properties of Metals and Alloys 17 Bal'shin,, M. Yu.' On the Problem of the Relationship Between Surface Characteristics and the Interface Tension of Matetials and Their Deformability.in Creep and Sintering 26 Yepin, P. A. On the Isotherms of Surface Tension 33 Pugaichevich,- P. P.,and V. B. Lazarev. Surface Phenomena in Ternary Metal,Solutions 39 Fesenko, V. V., V. N. Yeremenko, and M. I. Vasiliu. Surface Tension of Copper-Nickel Alloys 48 Zadumkin, S. N. Approximate Calculation of the Surface Energy of Some Carbides and Nitrides with NaCl-Type Lattices 51 Card 31T Surface Phenomena In Metals (Cont,) SOV/6032 Yeremenko, V. N., Yu. N. Ivashchenko, and B. B. Bogatyrenko. Surface Tension of Pure Iron and Alloys of the Fe-C System Naydioh, Yu. V., V. N. Yeremenk4 V. V. Fesenko, M. I. Vasillu, and L. F. Kirichenko. Teippetature Dependence of the Surface Tension of Pure Copper Pugachevich, P. P., and V. I. Yashkichev. Determination of .the Surface Tension of Molten Metals at High Temperatures Timofeyevibheva, 0. A., and P. P. Pu'gachevioh. Temperature Dependence of Surface Tension of Indium Yeremenko, V. N., and V. I. Nizhenko. Effect of Titanium .and Titanium Carbide Additions on the Surface Tension of Nickel and Cobalt -Presnov, V. A., and A. P. Vyatkin. W13tting of Germanium by Indium and Fused Con,;acts Between Semiconductors and Metals Card 4/7. 56 02 85 91 Surface Phenomena in Metals (Cont.) SOV/6032 Yeremenko, V. N., and Yu. V. Naydich. Surface Activity of Oxygen in the Silver-Oxygen System 100 Perminov., A. A..p S. I. Popell,, and N. S. Smirnov. Adhesion of Molten Silicate to Iron and Its Alloys 10:1) Kuznetsov,, V. A. Investigatiod-of Surface T.ension and Electrocapillary Phenomena in Some Binary Metal Alloys Feoenko, V. V. On the Problem of Determining Surface Tension the Method of Maximum Pressure in the Gas Bubble 123 Vashchenko, K. I.,and A. P. Rudoy. Method and Unit for Determining the Surface Tension of.Cast Iron 130 Presnov, V. A. On the Physicochemical Nature of the Strong Bond Between Heterogeneous Substances 14o Tsarevskiy, V. B, and S. I. Popell. Adhesion 'of Binary Iron-Base Melts to Solid Aluminum Oxides 146 Card 5/7 Surface Phenomena ~n Metals (Ciont.). SOV16032 Yeremenko, V. N.Iand N. D. Lesink. Investigation of the Kinetics of the Impregnation of Porous Solids With Liquid Metals Yeremenko, V. N., and V. V. Fesenko. Rate of Impregnation of Titanium Carbide With Copper-Nickel Alloys Ge guzin, Ya. Ye., and N. N. Ovcharenko. On the Mechanism and Kinetics of the Prooess of High-Temperature Self-Healing of Defects on the Surface of Cr~stalline Solids Poryunov, Yu..V., N. V. Pertsov, P. A. Rebinder, and Ye. D. Shchukin. Effect of Thin Surface-Active Metal Coatings.on the Structural and Mechanical Properties of Single-Crystal and Polyarystal Metals 184 Xachanova, L. A., 1. A. Andreyeva, Ye. D. Shchukin,'and V. I. Likhtman. Surface Phenomena in the Processes of Brittle Fracture of Metal Crystals 194 Card 6/7 Surface Phenomena in Metals (Cont.) SOV/6032 Dekartova., N. V.,,and V. N. Rozhlanskiy. Investigation of ,Re*lative Surface Activity of Some Metals Toward Zinc by the Method of Internal Friction 202 Bal'shin, M. Yu. Some Remarks on the'Artiole "On the Prob- -lem'of the Theoretical Calculation of Surface Tension and of Some Other Characteriitice of Solids and Liquids" 209 1 1 .. Resolution of the Meeting of the Interinstitutional Seminar on Problems of Heat Resistance, and 'of the Interinstitutional. Colloquium on Surface Phenomena in Melts 212 AVAILABLE: Librao or Congress SUBJECT: Metals and Metallurgy DV/wpc/jw Card 7/7 5/10/62 IV, IZ5T AUTHORSt 1530 33752 S/021/62/000/002/007/010 D299/D304 YeromWIkP_,__YI_E_-, Trot Iyacheriko, L. 0. and Holubenko, TITLB: On the boundary of the ar'-phase in a tantalum-vanadium system PERIODICAL: Akademiya nauk UkrRSR. Dopovidi. no. 2, 19621 192-194 TEXT: The tantalum-vanadium alloys were prepared by t he method of Yeremenko et al. (Ref. 2: ZhNKhq 5, 22909 1960). Then they were annealed and tempered at 4 different regimes, ranging from tempe ratures of 1000 to 14000C, and lasting from 5 to 200 hours. The boundary of the T-phase was determined metallographically. The mi- crostructure was determined by means of various etchants, depend- ing on the composition of the alloy. A table shows the phase com- position of the alloys at various temperatures. Four types of mi- crostructure are shown in figures. The first shows the structure of a homogeneous 3-solid solution alloy; the grain boundaries are sharp and clean. Another figure shows the microstructure of the Card 1/3 33752 S/021/62/000/002/007/010 On the boundary of ... D299/D304 same alloy after low-temperature annealing; thereby small (f-phase formations are noted. Further, an alloy with a considerable amount of d-phaseis shown, and (lastly) the microstructure in the region of homogeneous ar-phase. The d-phase has very great hardness. The microhardnesst determined by means of the device NHT-3 (PMT-3) , of the T-phase in alloys containing 32.0 and 41.5 atom% Ta, ranged between 1070 - 1260 kg/mm2. The line digrams (of an X-ray picture) of a specimen containing 32.0 atom% Ta is shown. Nearly all the lines of the (r-phase were identified by the tetragonal lattice. Cal- culation of lattice parameters showed that the e-phase in alloys containing 32.0 atm% Ta has parameters a = 6.15 U and c = 8.85 kX. According to the data of W. Rostoker and A. Yamamoto ((Ref. 1: Trans. Amer. Soc. Metals, 46, 1136, 1954), these parameters are a = 6.104 U and c = 8.833 U. A state diagram of the Ta-V system is shown, us�ng data of Ref. 1 (Op.cit.) and the solidue-tempera- tures found in Ref. 2 (Op.cit.). There are 3 figures, 1 table and 3 references: 2 Soviet-bloc and 1 non-Soviet-bloo. The reference to the English-language publication reads as follows: W. Rostoker, A. Card 2/3 33752 S/021/62/000/002/007/010 On the boundary of D299/D304 Yamamoto, Trans. Amer. Soc. Metals, 46, 1136, 1954- ASSOCIATION: Instytut metalokeramiky i spetssplaviv AN UkrRSR (In- stitute of Powder Metals and Special Alloys of the AS UkrRSR) PRESENTBD: by Academician I. M. Fedorchenko of the AS UkrRSR SUBMITTED: July 15, 1961 Card 3/3 - ~ ~ -1 - - .--- ~ -1 . M -.1- - - - 1. -1- - -- - -- --- ---- ---- - - - - -- --- --- ---- -- - - - - - --- -- - --- - - . YEREMNKOP V.N.; HAYDICH, Yu.V.; LAVRMNKO, I.A. Studying compaction processes during sintering in presence of a liquid phase. Poroah.met. 2 no-4372-83 JI-Ag 162 iMIRA l5s8) 1. Listitut metallokeramiki i spetsiallnykh splavov AN UkrSSR. (Sintering) (Dilatometry) AUTHORS: Naydich, Yu. V., Yeremenko, TITLEs Surface tension and density aluminum system PERIODICAM Zhurnal neorganicheakoy khi,aii, 3)278 B/078/62/007/002/004/019 B119/B110 V. N. Kirichenko, L. F. of liquid alloys of the copper- v. 7, no. 2, 1962, 333 - 336 TEXTi Surface tensions and densities of Cu-kl alloys of varying mixing proportions were studied. The alloys were fused in cruciblesof pure over- burned and recrystallized aluminum oxide, in which also the further tests were made. Surface tension was measured by a method elaborated by the first two authors (Ref. 9: Fizika metallov i metallovedeniye, 110), 863 (1961)1 Ref. Ili Zmochuvannya ridkimi metallami poverkhent tugoplavkikh spoluk, Izd. AN USSR, Kiyev, 1958), in which particularly large and strict symmetrical drops of the test substance are usedl thus, the error in measurement is significantly reduced. The density of the melts was deter- mined from the volume of the drop (ascertained from the ratio d/2h, where d is the equatorial diameter and h the height of the drop on d, and with the aid of a table of F. Bashfort et al. (see below)) and from its weight. Card 1/3 33278 S/078/62/007/002/004/019 .Surface tension and density... B119/B11O Measurements were made in vacuo (1 - 2.10-5 mm Hg) between 700 and 12500C Resultai The temperature coefficient of the density of the alloys is strongly dependent on the Cu-Al mixing ratio (Maximum dQ/dT at , 951; by weight Al). The isotherm of the specific volumes of the alloys (measured at 11000C) shows that fusion of the components results in volume contrac- tion owing to chemical interaction. The surface tension of the alloys de- creases isothermally (measured at 1100 and 12500C) with increasing Al con- tent. (Surface tension of Cu at 'the temperatures indicated j1320 - 1350 erg/cm2'of Al 400 erg/cm2). In accordance with the sidehiometric pro- portion of CuAl 39 the isotherms of the alloys show a break after which the surface tension decreases very rapidly with increasing Al content. For the isotherm at 12500C the break becomes less sharp owing to the increasing dissociation of Cu 3Al at elevated temperatures. According to the classification of N. A. Trifonov (Ref. 141 V. Ya. Anosov, S. A. Pogodin. Oanovnyye nachala fiziko-khimioheskogo analiza. Izd-vo AN SSSR, 1947 (Principles of physicochemical analysis. Published by AS USSR, 1947))the isotherm of the surface tension of the Cu-Al system belongs to the third type, i. e., the Cu3Al compound formed is surface-active as to one Card 2/3 Surface tension and density... S~0372 62/007/002/004/019 B B119 B110 19P component (Cu), but surface-inactive as to the other (Al). The following papers are mentionedi Yu. A. Klyachko (Ref. 51 Zavodak. laboratoriya, ,j, 1376 (1937)); S- V. Sergeyev and T. I. Khomchenoveka (Raf. 6s Fiziko- kh1micheskiye avoystva metallovv Oborongiz, 1952); V. N. Yeremenko, V. I. Nizhenko, N. Levi, B. B. Bogatyrenko (Ref. 161 Ukr. khim, zhurn. (in print)). There are 4 figures and 16 references: 13 Soviet and 3 non- Soviet. The reference to the English-language publication reads as follows- F. Bashfort, I. Adams. An attempt to test theories capillary action, Cambridge, 1883. ASSOCIATIONi Institut metallokeramiki spetsiallnykh splayov Akademii nauk USSR (Institute of Powder Metallurgy and Special Alloys of the Academy of Sciences UkrSSR). Kiyevskiy gosudarstvennyy universitet (Kiev State University) SUBMITTEDs February 13, 1961 Card 3/3 FESENKOI V.V.; VASILIU, M-I-; yEREMFITKO, V.N. Surfuco Wrw'a.on of 3iqu,ld mcital Bolutlua.. Part 3. Zhur. ft. khim. 36 no.3:518-520 Mr 162. (MIRA 17-.8) 1, Institut motlillokermaiki i spetsialfriyU nplavov AN UkrSSII. 8/07 62/007/007/013/013 B119YBIOI AUTHORSt Yereumnkoj,V. N., Velikanova, T. Ya. 10 TITLE: Investigation of the system tin'...titanium within the range rich*in tin PERIODlCALs Zhurnal neorganicheskoy khimii-j -V 7, no- 7, 1962,.1750 -175-2 TEXTs The structure, of Sn - Ti alloys,containing'O - 34.6 0% by weight of Ti was studied. Re3ultsi Ti in concentrations of 0.008,;.20 % by-waight in the alloy lowers the crystallization point'of Sn (23 ) bv 1 200. All alloys. containing 0.008 - 16.98-A Ti show two phases only. Crystals in the intermetallie phase are evenly distributed through the mass of tin. The solubility of Ti in Sn in the solid state is 0.006 - 0.008 % Ti. In Sn - Ti alloyo with 5.3 - 34.6 % Ti a nonvariant conversion occurs at ,,.,7900C, the nature of which is not yet clarified. There are I figure eaid 2 tables. SUBMITTEDt November 1j 1961 Card 1/1 S/659/62/008/000/014/028 I048f1248 AUTHORS: Yeremenko, V.11., Tolmaeheva, Z.I., and Velikanova, T.Ya. I-- - TITTX: On the structure of titanium oarbide alloys with nickel,, chromium,, and molybdenum SOURCE: Akadeniya nauk -OSSR..Institut motallurgii, Isal.edovani-ya po zharoprochnym, aplavame v98* 1962o 95-102 TEXT: The systems Ti-C-Ni,, TI-C-Cr, and Ti-C-Mo were studied in an attempt to determine the true phase composition of cermets contain- ing iC with Ni, Cr, or Mo. The solubility of Ili in TiC at 1000- 120C is 0.7% by wt.; TiC-Ni alloys containing over 0*7% Ili are composed of two phases, the microhardness'of one of the phases being,/, 3000 kg./sq.cm. The section TIC-141i through the Ti-C-Ni s-ystem; as well as the TiC-Cr and TiC-1,1,o sections through the respective ter- .nary systems, are quasibinnry; the melting of.alloys containing over 5% Ni starts at 1280-13000C, In the system Ti-C-Cr. the form- ation of a now phase Cr C,, is observed when small amounts of TiC are added to Cr; the 0TiC28r 6alloy containing 20% Cr is composed of Card 1/2 1 S/659/62/008/000/014/028 1048/1248 on the structure of titanium... throo phases whose microhardnoss (300, 1000.. and 3000 kgoeq9ems) corresponds to that of solid solutions based on Cr, chromium car- bide, and TiC respectivnly. Til-Cr alloys containing 52,05 and v 63.0,~~ Cr are composed of two phases - Cr-based and TiC-based solid solutions. All alloys in the system Ti-C-Mo are composed of two phases, with microhardnossos of 300 and 2400 kg./sq.cm.; x-ray data reveals that these are Mo-based and TiC-based solid solutions., The experimental data for this system disagrees with the data of Albert and Norton (Planseeberichte fur Pulvermetallurgie, 4, 2, 1956)., according to which a Moe)C-based solid solution exists in the ays- tem. There are 7 figures and 1 table. Card 2/2 43064 0/073JS2/0n.0/004/001/004 I017fI217 AUT11OR: V.H. Yorimenko T T T Tr,, Surfriao tension of liquid metals PERIODICAL: Ukrainslocly lditrilchaskiy zhurnal, v.20p no*4,, 1962,, '427-440 TZXT: A wido critical slirvoy of Lhe known data Is mnde based on 76 ror(ironco3 thnt aro critically rovievied from point of view of the hn method employod. The surfnca tension of 63 o purlty of t lomonts nra tabulatnd. A serian of figruros ahow graphically the depondence of t1io aiirfaco tonalon of matals at their molting temperature (1) on; thn work of roleatio of the alectrona: 'on the inverse atomic vol-,, Umoj (3) on the atomic hosit of molting, (4) on the atomic heat -of -sublimation, (5) on the atomic volume and mnltin temperature, (a) on the modulity of diaplacoment and density and 17-8) the surface 'tonnion of the liquid motnls of the Up Illp ~Vj Vj VI and,VII groups.of the periodic av.8tem, It in shown that there is no justification to suppose,a proportion-' CaH 1/2 S/073162/OP,8/004/001/004 1017[1217 Surface tonsion of@.,., ality botw on the aurfaco tension of liquid metals anj: (1) the ratio. /f/re work of roloaan of the electrons, r square of the atomic radii)# (2) the inverse value of the atomic volume,,7 and (3) All,, tho inoleciilnr hent of maltinge The proportionality bet- ween the molar froo surface enorgy of liquid metals at melting tem- poratura and the hant or uublimation and molting Is justified. The known and,exparimontally obtnined valtios for the surface tonsion of metals confirm the applicabillty of tho periodical law on the aur- Thn moat probable valuou for-the face properties of the motals. surface tension of liquid metals,, including the rare onrths,, are %timatod and sutia,m Ized on the basis of the law of -periodical a ange of the sxtrface tension of the elements and oartain empirical- ly found rolationse There are 8 figiwas and 3 tableso AtSOCIATION: Institut metallokeramiki-i apetaialtnykh splavov AN USSR (Institute of Powder-Metallurgy ahd-Speelal Alloys AS Ukr SSR) SUBIAITTEDi February 28,, 1961' Card 2/2 MMMENY-Op V.No; LUMHENKO, G.M. Thermodynamio propertloo of Uquid solutiom in the wgnooi= - alumi= syeteme Ukrekbimoshw., ~24 no-4:462-466 162. (KM 150) le Institut metallokeramiU i apetsialltqkh splavov AN USSR. (ftnesium-alvaimm alloys) 5/073J62/028/004/004/00t 1017/1217 or( N.I., and ATITHORS: Y )monko, V.Neq Nizhonko, V.I.p Leviv -ro-gatyranko-p B,B& TrrLE: Surface tension of liquid alloys of binary metalic syd-. tems having maximum an the ILquldua curve PERIODICAM UkrainsLy khimiche-okly zhurnalp vP28, no*4i 1962, 500-505 TEXT., The surface tension and the density of liould alloys of nick-: el with aluninum at 16400C and nickel with berillum at 15000C were datermined. It was found that the formation of the alloys in the stiidied systoms, is accompanied by chemical Interaction which causes docroaoing, of volume and negative daviation of the isotherm of the specific volumes from the additive vnluese The analogy between the t1pe of dingramas surface tons ion/composit- Ion and the diagram of state is stated@ The compound NiBe its In- -active toward bothe the components of the aysteme, The compound NIAl slid 1/2 S/07Y62 1017 Z214028/004/004/004 Surface tension of liquid alloys ... Is surface active toward nickel and inactive toward aluminium. Re- sults -show that, malting alloys conserve,, Lm a -large degreep the Molecular groups corresponding to the composition of the intermetal- le phases existing In the ablid alloys* There are 4 figures and 1 table@ A ASSOCIATIONt Ins t itut meta I lokeramiki y apetaialnikh aplavov AN USSR (Institute of Powder Metallurgy nnd'Special Alloys AS Ukr SSR) SUBMITTEM: throh 2. 1961 Card 5/073/62/028/0005/002/005 1003/1203 AUTHORS: Yoromenko, VOL, and LukaBhonkop G.M. TITLEi Thermodynamic propert es of.magnesium-75nc liquid solutions ISMODICAL i Ukralnskiy kh1michoskiy zhurnal,v.-28)ao.S,570-574 TEXTt The thermal properties of the liquid niagnooium-zine system have boon little investigated despite the fact that this system is very interesting both as the basis for many commercial alloys and as a system with strongly reactive components. In order to define the thermodynamic properties of liquid M7.,-Zn alloyo the amf of the ,%soli 21~ - KC1 i-MCL Znliq dl 149 liq -1 - ~Ag- concentration cell was measured for 12 MS-Zn alloys containing from 10 to. 90 ai% of t%. The conclusion in reached that tho behaviour of Mg-Zn liquid alloys shows considerable deviation from that of perfect solutions. 'Min is duo to the 'strong reactions between magnonium and zinc which give r.so to a short-range order in the liquid Ug-Zn systems. 7ber8'are 4 figures and I table. Card 1/2 Thermodynamic proper-tieg... SV1073/6,?/028/OOo5/002/()05 1",03/1203 ASSOcIATJOJJ~ Inutitut motallokoramiki i spote.oplavo" Powder MOtallurgy and Spocial Alloye V AN USSR (Inatituto of ,,AS,UkrSSR) SUBMITTILDS April 29, 1961 Card 2/2 tlj VO AUTHORSs TITLEt PERIODICALs 3/()76/62/036/002f/004/011 B101/B108 Feaenko, V. V., Vasiliu, M. I., a-3d Yeremenko, V. N. (Kiyev) Study of the surface tension of liquid metal solutions. III. Surface tonston of cobalt-copper alloys Zhurnal fizicheskoy khimii, v. 36, no. 3, 1962, 518 - 520 TEXT: The surface tension of Cu, Co, and their alloys was determined at 15500C by means of the gas bubble maximum pressure method. The impurity content in the metals was not more than 0.01~. The alloys were molten in Al 0 crucibles in a vacuum or an H atmosphere. The measurements -more 2 3 2 Vr made with a beryllium oxide conical capillary (r - 0.247 cm) in H2 or He. Assuming that the solutions in the system Co-Cu are regular above the melting point the Co, the aotivity c4 of the Co in solution in Cu was cal- culated from the equilibrium diagramt logoc- -(T o-T)L/4-576TT0 + TSlog 11/f + (T - TS)log N/T, where T 0 is the melting point of the pure solvent, L its heat of fusion at T0 , No the atom percentage-at the solidus temperature T.1 Card 1/3 S/076/62/036/003/004/011 Study of the surface ... BIOI/B108 N the atom percentage at the liquidus temperature T., The activity of Cu was calculated from the Gibbs-Duhem equation. The values of the surface tension rounded to 5 erg/cm 2 are: C (atom-%) Ojerg/cm 2) CO 100'ro 1,845 96.5 1,775 89.5 1,600 83.0 1,440 76.8 1,430 49.0 1,325 32.0 1,320 0 1,265 These values are in good agreement with those calculated from the equations of A. A. Zhukhovitskiy (Zh. fiz. kbimii, 18, 2141 1944)s a- - o-Co + noRT ln(bCo/ae.); bCo/af~ a. Vn RT] , where iris the (aCo/ar~ )-exp [(a-cu Co 0 Cu Cu Card,2/3 .. ..... S10761621036100310041011 Study of the surface Biol/B108 surface tonsion of the alloy, b and b the activities of Cc and Cu in CO Cu the surface layer, a and a the activities inside the solution, *-C and Cc Cu 0 the surface tonniono of the pure metals, n the number of moles of the O;u 0 pure component per unit surface area, [the displacement coefficient equal to the ratio of the atomic volumes o f u and Co. Consequently, measurementa of the surface tonsion of alloys can be used as a criterion in the deter- mination of the thermodynamic properties of liquid alloys. There are 2 figures, 1 table, and 9 referencest 5 Soviet and 4 non-Soviet. The three preferences to English-language publications read as followss Metals Hand- book, 1948 ed.; P. Kazakevich, G. Urbain, J. Iron and Stool Inat.,.186, 167, 1957; B. G. Allen, W. D. Kingery, Trans. Metallurg. Boo. AIME, 30, 215, 195% ASS06IATIONs Akademiya nauk USSR, Institut, metallokeramiki i spetsiallnykh splavov (Academy of Sciences UkrSSR, Institute of Powder Metallurgy and Special Alloys) SUBMITTED: May 29, 1960 Card 3/3 111900 5/,-2-)/L,2/00U/0G4/0l0/012 IOU3/1203 yorvLxl~.W, V.i-., itaidich, Yu-V., LavrineWco, I.A. TIT"-: 1AV0Stij;Ut1014 Ul' thC CULPI'djuiun proceas auring sintering in the PrQs,w.CC Uf a liq..Ld jxhaze Pr~IUQDICAL; Porosh1wraya ictallurLiu, 11-0.4, iJ62, 72-3) 'The aintu~ Of LCtal powdera in tho present of a liquid phase ha3 so far bcc:i little in~estij;atcd. Thu .~LiLetic4 of .~uch,proceszc3 L~ay considerably difi,er fru- tiona vniul, take place dur.Lq; the sintering; of solid metal powders. Three, difl*orc,it Lecliai4iu~~z of sintcris"t, i;. tiie p4%;icixe 9f a'iiq:.Aid phase are conzidered: Ine kinetics of uintarix4, w-';u aid TiC-iti powders under tLe above conditiorus were irmcatidated by L,,-a;Ls of a u*iiatu,-atric ucvica. Thu density of the W-Cu, metal po,.:dcr ipereazer, sharply with the teaporature of sintoring and reaches a mazi-= value at 13000 - 1350'C- 12jLjs inc4"easo ii-, aeijity in gobably aue to tie increase ir. wotting of the tunguteia by coppor. A c(,Lplete couprejuion in Ue TiC-Ni Lietal powder in nuhieved wheu the content of tha liqaid phase is not less than ;e0-25 vol~96. Thure are 12 figures and 2 tables. 1/2 Card I ."/226/62/000/004/010/012 1003/1203 13avestigation of tho coLjprcj8Iw,#,-& AS-MIATIOm Inatit-Ut watalloker"i ;i i upeciyallnykh oplavov Ali WSR(Thu Institute of ketal Powders and Jpccial Alloys of tho AS UkrSSR) SUBAITTIZ: February -17, 19u2 WWI %11(~1k71'45A?W'M01UWr_aW L 27503-66 E1WT(n)/T/EWP(t)/ET1 lip(G) JD0010 ACC NRt IT661065 SOURCE COM UR/OOW/6 ~0071' 77. 1 AUMORSs Yoremenko. 11, N.., Sht2pa, T. D.,.' Gritsenko, go To,. ORGt none TITLE: Intermediate 2!jases in alloys of titanium with iridium and rhodium 19 2 X? SOURCE.- Soveshchaniye po metallokhimii., metallovu~niyu i primenaniyu titana i yego splavovi 6th. Novyye issledovaniya titanovykh splavov (New research on titaniun alloys); trudy soveshchaniya, Moscowp Izd-vo Naukas 1965,, 25-29 TOPIC TAGS-. titanium., iridiumy rhodium, alloy phase diagram . cryotal lattice ADSTRACT: The phase diagrams of the binary systems Ti--Ir. over the whole concentra- tion region, and Ti--Rh from hO--100 at* % Rh were determined (see Figs, I and 2)0 The diagrams were constructed on the basis of microstructural and x-ray analysi3 data. Photographs of alloy polished sections are presented. It was found that the system Ti--Ir exhibits three intermediate phasess and E. The crystal lattice of each intermediate phase was determined. The system Ti--Rh exhibits two intormodiato phases i and S. The latter phase, at an Rh content of 57 to 60 at.%, suffore a rearrangem nt., the rMture of which is not yet clear and which requires CardJ12 -1 -27503-66 ACC NRo AT6012365 Fig. lo ~Preliminary Ah rm r di h I PW#v Lot a ase ag p m of the syst fix : ISM zox 2OX single-phas alloys; 2 - fix IIJV two-phase IAV IAV 0 to alloys; 3 - t alloys which undergo a as jk IJL transformation ..... ..... ........... go i JO AV 10 in the solid state. Fig. 2. Preliminary phase diagram of the system Ti--Rh. I - single-phase alloys; 2 - two-phase alloys; 3 - alloys which undergo a transformation in the solid state* further study, Orig. art. haso figures* SUB CODE: n/ SUBM DATEI '02Deo65/ ON REF.1 002 C,rd 2/2 .0 .. . P. . 011k 4p t-e L ki 11 ej)ce p -194 '196 S 0.60 20f4S ,26 do 4* 5 ~optc 73 on 111ft ./00 0 0 titaq 7140st - a4d 04~ IVS2, Igo Coto C;a-hbjcj 20 1tif 7 (rbstltlit p e" -~Oj a 041J)d ej e Z jn7 oved, el"Aide 149 llolybdej7 ej) - i7a 17te 0 01i's 411 C Dial -tv, C 0, 7 20-1, 00 .1ge't J2 be ly.9ok 01. 0 ( e Q c"kPolo)d, jb 044cf.9). h-ere ect b thlee., er4p.., )to the 84M % lie) Prep!y k~h ko.1 02A k~!O~, at .18 ple 0-f 14. elled Ak'J' a Ybde dei7lo, 414 !!~. 3'7)Pe 9'J-7& 4d nift ye 21,1t -,bjn!p ztd J-VtQ J? 1.4 neo 'a .3 . hes P-1,01 % te 7 44d O1j-fe uko 7 libe or 0i. P% X 1 -2 t, lie 'genx~ 4'0 gec, og-l'. 4 No 47e te, " f -'175onc/ ekh - 4-ith .10 1 % aph-t 4 4,6 hr, .1 C ISO ir, 4 th Cellb a ~Y4 .1 a een A10 J29 ' ec de 00 elite Qt Ot .1 Ochi).j -911ea -4) Sol tic 200 8500 91je ' 8, the 2.it. e , -, -a? A. !mpl "g -to t 00L 0000C. el., e& 0 I't 410.1 of Fpyat 'IQ 7'he es -b Of A10 4-1.1.1 fo 0'r !P Pic e J) 2,16 ZQtj lind :Pgej) 1149-to C .1i) at on p the t "48 n .1)) the att-etv,.the A"eMot., Of el,,. , o~,% ed ec t., phe :tc to Ifo C t. eljt Qt Pe,, ec~ the ~Q- L'31873-66 ACC NRt AT6013564 tectic temperature is within the 3.5-4.5 mol % range a ':~ at 20000C it falls within the 2-2.5 mol % range. The temperature dependence of the ki,armodynamic activity (a0) of carbon in TiC and M02C is shown in figure 1. A phaseldiagram of the quasibinary Mo- -TJC system is also given. Orig. art, has: 6 trg-ums' 1 table. P SUB CODE: 1110/ SUBM DATE: 03Ju.165/ Fig. 1. ORIG REFs 003/ OTH REr., 003 Ir FO1 23 63 SOURDE COM UR AUTHORS: Yeremenko, I!. N.j Vel1kanovaj_jujW shahsMMO S. V. ORW none TITLE: Structure of certain alloys of the ternary-systesa 21-4to--C SOURCE2 Soveshlaniye po; me~ta1lokhimii, motallovedeniyu" i pr eneniyu titana i yego splayov, 6th. Novyye issladovaniya titanovykh splavov (Ntyw research on titanium al- loys)j trudy soveshchaniya. Moscowj Izd-vo Nauka, 1965, 11-19 TOPIC TAGS% titanium, mdlybdenum, carbon, alloy phase diagram p hardness .,lattice parameter . I ." ABSMACT: The p~iase relationships of the subsyptems -M02G - TiG, and X03C2 - TiC of the system Ti--Mo--G were studied. The study was carried out by means of microstruc- tural and x-ray analysis: The experimental results are swwiarizod in graphs " tables (see Figs. I and 2). The lattice parameters and hardness of the phases occurring in the system were determined. Above 200OCj the higher carbide of molybdenum and titaniur carbide form a continuous series of solid solutionso '.Card -1 /7 L 39780:~6 ACC NRs AT6012363 Ile I, 1 Fig. 1. Folytherude Mv section 1Mo2C - TiC. 7. oe si le-phase alloys loo, l or 2 - two- 0 phase alloys 3 - temperatures at 20 --- of 4 OF 0 f which the specimens are in the solid- 02 AV of liquid statej 4 a(t) 0 0 ej .t .4 temperature of 1 . solidus (obtained . 2200 after the method CO .0 000 of AlItertum- 0 109 Pirani) 0 MI'C' 20 to M 80 C, 1--- Tic/r;;:Le % Fig, 2, PolythermiC section - TiC (according to M03G2 data of data). I preliminary me C' to to f0- to Tic :J thexual analysis; 2 single- ' _ 3 two-phase phase alloysj V allOY84'. ig. art, haet tables and 10 filnirea BrTO~2't 2 2, ll./ SUBM DATEt ;~;ec651 ORIO IMS OD3/ OTH MWt 005 Mumma" NR1 AT6012364 SOURCE CODEt AUTHORS: YeremenkD, V. N. I Listovrdchib_y, Yee ORG: none TITLEi Phase diagram of the system Ti--P SOUICE: Soveshchaniye po metallokhimiis metallovedeniyu i primononiyu-titana i yego splavov, 6th. Novyye issledovaniya titanovykh splavov (New research on titanium alloys); trudy soveshchaniya. Moscow, Izd-vo Nauka,, 1965.. 20-2h TOPIC TAGS: titanium, phosphorus, alloy-phase diagramj x ray upoetroscopy j metal physical property , ABSTRACT: The phase diagram of the system Ti--P containing up to h5 at. % P was determined, The Investigation was initiated to test the hypothetical phase diagram for this system proposed by R. Vogel and B. Giessen (Arch, Bisonh"ttonwesen 959 u " I j 30, 565). The composition of the alloys was determinedj, after the method of 0. Popova and 0. Se2-aya (Analiz tugoplavkikh soyedineniy. Metallurgizdatj 1962, str, 226). On the basis of microstructural and x-ray analysis, a phase diagram for the system was constructed (see Fie. 1). The presence of the following phases was established., Ti3P) T~2pj Ti3P2p Tij1P 3, and TiP,, The regions of homogeneity and several physical properties, e.g., densityj crystal utructurop molting pointj microbardness, heat of formation, and specific electrical resistance of these phases ACC NRj AT6012364 (D 7 4-3 W dl ~11 o -f 0 0 - r W 4J (D b0 k YJ 0 0 -ft CL 0 P 4-5 r -P 4- J T (D 0 43 (D 9) t 0 0 w OJ -0 P4 b r4 Ir" 17 IIV 4 v 1 j99 0 4 were determined. The experime ntal reaults are tabulated*- It is concluded that the proposed phase diagram of Vogel and Giessen is wrong. Orig, art# hass I table and 2 figurese SUB CODEs l1/" SUBM DA M 02Doc65/ ORIG REFt 0031 OM PXF s OCLO C-,d 21V L-3ho84-66 &n(m)Zj1EWPWZETI IJP(c) JDN4 ACC RM- '-AF 25520 SOURCE CODE: UR/037 66 000 0192 AUTHOR: Yeremenkot V.__N._ (Kiev); Nizhe-nko, V. 1. (Kiev); onko, L. I. (Kiev) ORG: none 13 TITLE: Surface -tension d density of molten alloys of the system Ni-Ga and their miscibility with Al sub-%nO sub 3 SOURCE: AN SSSR. Izvestiya. Metally, no. 2, 1966, 188-192 TOPIC TAGS: surface tension, molten rrwtal, nickol alloy, gallium alloy, aluminum oxide, alloy phase diagram, metal property, specific density, opqcific vol 0 ABSTRACT: This report shows that o the otherm of free surface one (C ) of molten alloys of the systemq/1-AMhero is a clearly pronounced point of inflection corresponding-An composition to the congruently malt- ing intermetallide HiAl. Gallium lie an analog of aluminum and therefore it was of interest to study the surface properties of the MI-Ga systom and .to compare them with the phase diagram. The temperature and concentration relationships of the density of ;alloys in the Ni-G& system were determined. It wag established that .specific volumes of alloys both in the molten and in the solid states differ liharply from additive values. The temperature and concentration relationships of-the free surfaeG energy of molten alloys in the Ni-Ga system were studied. It was shown that the isothorm,pkq~ted from.expSrimental data pasnen L 34o84-66 ACC NRt AIP6025 120- considerably above that calculated for an ideal solution. This evidences the negative departure of the system examined from idoali~ty. The isotherm of a, f6r' the Ni-'Ga'a'ystem has a more flattened appear- .ance compared to the isotherm of d' for alloys in the Ni-Al systemg vhich js accounted for by the significant dissociation of intermetalliden in the ~nolten state in this system. The temperature dependence of the regional corner of miscibility ;vith alloys in the Ni-Ga system of polycrystalline specimens of aluminum ~oxide was studied. The presence of "threabholds of miscibilit-" on laiscibility polytherns is accounted for by the Intensified chemical re- action at the interface with increase in temperature. Orig. art. has: 6 figures, 4 formulas and 1 table. (JPRS: 36P7741 SUB COM 110 20 SUBH DATE: 1INov64 ORIG REFt 005 OTH HEN 002 L 4377h-66 _j~ ACC NR' AP6020963 (A) SOURM COr)V-' IJR/0226/66/000/006/0068/0072 AUTHOR: Yeremenko V. N.; Shte Sirotenko, V. G, pa, T. D. ORG: Institute for Problems in the Science of Materials,_ AN UkrSSR (Institut prob- lem materialoved;niya, AN UZSR) 1211 /0 TITLE- Intermediate n alloys of titanium with iridium, rhoejiuZLd osmium 11 1 SOURCE: Poroshkovaya metallurgiya, no. 6, 1966, 68-72 TOPIC TAGS: titanium alloy, rhodium alloy, osmium alloy, tridium alloy, -Ishi-a-z. monoclinal structure, intermediate phase,, 0"Sp- OOMPO-TMOA.) 4440)" ABSTRACT: The authors investigated the alloys TI-Ir, Ti-Rh, Ti-Os throughout the concentration range. The stfuctures and some properties of the Intermediate phases formed in these alloys were studied. The '6 -phase was found for the first time in the Ti-Rh alloy, and It has been shown as a monoclinal structure with ir~A 1/2 --------------------------------- L h3774-66 ACC IIR- AP6020963 the parameters ii-2X:t0.03 A,"b~-2,WL0,0S A,-c--3A'1:t0,02 A' and ~'P-W3~ Orig. art. has: 2 tables. [Based on authors' abstract) [AM]-' SUB CODE: 11/ SUBM DATE: 19Mar66/ ORIG REF; 002/ OTH REF: 00ri, 2 2 ACC NRs AP6020965 SOURCE CODE.: TIR/0226/1,'G/000/006/0077/0087 AUTHOR: Yeremenko, V. N.; Buyanov, Yu. 1. ; ]Lrirna, S. B. ORG: Institute for Problems in the Science of Materials, AN UkrSSR (Institut problem materialovedeniya AN USSR) TITLE: Structure of a phase diagram f a titantu -gD9par system 1~s 4 I$ ~? 2,7 SOURCE: Poroghkovaya metallurgiya, no. 6, 1966, 77-87 TOPIC TAGS: titanium phase diagram, - analysis dz+p_~ C,.'~ (D '_~k ABS~rhACT: Phafie diagrams of a titanium-copper system have been studied by metallographic, x-ray and microdurometric analyses at concentrations of 20 to 100 at 0/6 Cu. The results obtained and the data In the literature have enabled the authors to const~-uct a phase diagram of the Ti-Cu system. The system has six metalloides, of Which T'2 Cu, Ti Cu, and T! Cu4 form phases of variable CoMpoBi- tion with narrow regions of homogeneity. Orig. art. has; 3 tables and 2 figures. [Based on authors' abstract] [AM] SUB CODE.- - III SUBM DATE: 19Mar66/ ORIG REF: 002/ OTH REF: 014/ Card 1/111t L 43737-66 030766 (nil SOURCE CODE: UR/0363/66/002/009/1568/1573 AUTHOR: Tretlyachenko, L. A.; Yeremenko, V. N. ------------ ORG: Institute of Problems of Material Science, Academy of Scianc -esi UkrSSR (Institut problem materialovedeniya Akademii nauk UkrSSR) TITLE: Vanadium-carbon system SOURCE: AN SSA~ Izvest ya. Neorganichaskiye matoriely, v. 2, no. 9, .1966, 1568-1573 TOPIC TAGS: vanadium carbon system, vanadium carbon alloy, vanadium monocarbide, vanadium subcarbide 19440P 09AA-0~- 0Ajes56^jA4i-6.Y ABSTRACTs A series of vanadium-carbon alloys containing up to 58 atl carbon has been investigated. On the basis of obtained results,a phase diagr ~Off nadium aml f the va carbon system was plotted (see-Fig. 1). The solubility of carbon In vanad.i u m 4 at% at 1650 and drops rapidly with decreasing temperature. The homogeneity region of.V2C carbide extends from 30 to 33.3 at%C at 1650C and from 31.5 to 33.3 atZC at 1450C. The homogeneity region of VC carbide extends from 39 to 47.5 at%C at 2100C and from 42.5 to 47.5 at%C at 1450C. In alloys with 37-41 at%C, a C-phase was observed, the nature and structure of which was not determined. In the x-ray diffraction Pat-. 2 UDct 546.881+546.26 L 43737-66 ACC Nit, AP6030766 IBM* :Fig. 1. Phase diagram of the vanadiu*- carbon system. (L,- d4signated-liquid). IM IIL4vC Goo Go 0 /'L Ile 'IC NC vC4C IWO*% *"see* 0 08 Y#VIC 000 00 *"*see, C, terns of alloys containing more carbon than VCO go, some additional lipes were found, the nature of which also was not determined. ORg. art. has: 4 figures. ITD) 5UB CODE: 07, 11, 20/ SUBM DATE: 23Nov65/ ORIC RAF: 012/ OTH REF: 015/ ATD PRESS: 5076 Card 2/2 hs )4-66 E7dT(m)/EWP.')/B? NRt AP6025943 1j1P(c) JD/JG/JT SOURCE CODE: UR/0226/66/000/OOT/0084/0068 to AUTHOR: Tre yachenko, L. A.; Yeremenko, V.~ H. ORG: Institute of Problems in the Science of Materials AN UkrSSR (Instytut problem materia.loyeaeniya AN UkrSSR) TITLE: Structure and properties of alloys with respect to the TiC-VC 0'.901 TiC-V2C and TiC-V sections and in the TiC-VC 0.90 region of the Ti-V_C ternary system SOURCE: Foroshkovaya metallurgiya, no. 7, 1966, 84-88 TOPIC TAGS: vanadium containing alloy, titanium containing alloy, carbide, are furnace, stoicbiometric mixture, microhardening, metallographic examination, x ray diffraction analysisp 7'1E!#RA/Aje,-1 AAJ-0Y ABSTRACT: The alloys for the study were me ted In an are furnace, with a tungsten electrode/ ,~nd a water-cooled cooper hearth in a 400 00 mm Jig argon atmosphere* 4 The argo *as purified by melting a titani gette Carbothermic vanadium, (99.7% V, 0.23% C), titanitm iodide and spectrally pure graphite were used as start-, Ing materials. Titanium carbide with a stoichiometric composition and vanaditmi car--- bide containing approximately 40 at.% C were premelted and used for preparing the charge. The alloy ingots produced in the are furnace were cut on an electroerosion machine tool. These were annealed at various temperatures to a uniform composition (k) ACC NRt AP6025943 j P I in vacuum or in an inert atmosphere at.low temperatures in TGV-1 or MVP-3 M type ovens in molybdenum heater containers and quickly cooled. The alloys were studied by meta-_ lographic and x-ray diffraction analysis using the powder method on the URS-70 unit in the RKD camera with copper K-radiation. The Pirani-Altertum method was used for measuring microhardness,and determining the initial melting point. All alloys which contained more than 30 at.% C were chemically analyzed. The melting point and micro- hardness of titanium carbide solid solutions and carbon-Baturated vanadium monocar- bide were determined. The composition of these corresponds to the TiC-VC 0.90 section. It is found that the temperature of the eutectic formed by TiC-VC 0.90 solid solutions with graphite decreases from 2950 to 27500C with an increase in VC 0.90 from zero to 100 mol.%. The TiC-V2 C and TiC-V poly-thermic sections of the Ti-V-C system are plotted and the lattice constants and phase microhardness are determined for these alloys with respect to these sections. Beither of these sections is quasibinary. Orig. art. has: 5 figures, 3 tables. SUB CODE1 ll/ SUBM DATE: 15Apr66/ ORIG REF: oo4/ (YrH REF: 005 Card 2/2 mjS '4 cc NR, AiO3508 SOURCE COM IM/0137/66/000/009/t.007/AO07 AUTHOM Yeremenko, V, No; Nizhenko, V, Is; Sklyarenko, L, 1, TITLEs Surface properties of chrome-nickel alloys SOURCE: Refs zho Hetallurgiya, Abe. 9A44 REF* SOURCE: Sb. Poverkhnost. yavleniya v rasplayakh i vosnikoyushchikh iz nikh tverds fazakho Nallchlkg 1965l 297-301 TOPIC TAGS., surface property, surface tensiong michrome alloy, temperature dependence molten metal ABSTRACT. The surface tension a and the density of nichrome alloys were investigated by the large-drop method in a helium atmosphere as a function of the temperature and concentration, The chromium reduces the a of liquid Hi, especially when the chromium content exceeds 10 at.%. A minimum is observed on the isotherm of a at concentrations near 50 at.% Cr. A study was made of the temperature and time dependence of the con- tact angle when Al 0 is wetted by molten nickel or Cr-Ni. The beat adhesion charac- teristics in the Fr:h melt + Al 20 system is possessed by, nichromes containing up to 30 at.% chromium; with further inc;easa~of the chromium content$ the temperature at which the contact angle becomes minimal increases. Therefore nichromes containing up 1/2 uDc: 669.2412"54632.61 ACC NRs AR60354o8 to 30 at.% of chromium are the most suitable binders in cerueta of the'Me-Al 0 type FT2 up to 15500o 5 illustrationse Bibliography, 9 titleso A, Granoyakeya. r2slati of-abstract] SUB CODE: 20, 11 _YLVtkx TiL PMA 31593 (A) SOURCE CODEI AUTHOR: Tret'yachenko, L. A.; Yeremenko,.V. N. ORG: Institute of ?roblems in Material Science, Academy of Sciences.UkrSSR (Ins problem materialovedeniyal TITLE: Structure of some alloys of the titanium-vanadium-carbon system SOURCE: Poroahkovaya metallurgiya, no. 8, 1966, 33-38 TOPIC TAGS: titanium base alloy, vanadium containing allcy, system polythermal section, 4,14ey phase diagram)carbon containing alloy, titanium vanadium carbon system ABSTRACT: A series of titanium-vanadium-carbon alloys with a constant vanadium content of 66.7 or 84 atZ and alloys with a composition located along the Ti-VC and Ti-V2C sections of the composition triangle have been investigated and the respective polythermal sections of the ternary diagram have been plotted on the basis of data obtained by physicochemical analysis. It was found that for Ti-VC, the solubility of vanadium carbide in 0-titanium was leas than 1 mol% at temperaturei up to 1500C and about 4 mol% at 1600C. The maximum'microhardness of 'the metallic phase was at about 25% mol%VC. For Ti-V2C, the limit of solubility of V2C i"" $-titanium was about 3 mol% at 1600C; the limit of solubility of titaniuiritf 42C reached about 13 mol%. The microhardneas of the VZC-base phase decreaaes from Card 1/2 ACC NR- AP6034198 SOURCE CODE: UR/0369/66/002/005/0574/0577 AVrHOR: Yeremenko, V. N.; Natanzon, Ya. V. ,090, -Institute of Materials Science Problems, AN UkrSSR, Kiev (Institut problem ma- i-terialovedeniya- AN UkrSSR) ,TITIZ: Determination of the kinetics of dissolution of materials in liquid metals !SOURCE.~ Fiziko-khimidheskaya mekhanika materialov,.v. 2, no. 5~, 1966, 574-577 TOPIC TAGS: metal melting, metal physical property, solid dynamics, solid mechanics, solid'machanical property, physical diffusion ABSTRACT: A skhematic of the apparatus and the testing procedure is given for deter- ining the kinetics of dissolution of the solid materials immersed in molten metals. Among the basic features of the method are: operation at 1-2*10 5 mm Hg, continuou3 agitatton~of the metal, and a provision for continuous sample taking. The maximun ope- ration temperature of the apparatus is 1500-17000C. As an example, a kinetic curve is given for dissolution of copper in molten lead at 4850C. Orig. art. has: 1 formu- lai 2 figures. I SUB-CODE: 07,11/ SUBM DATE: 19Apr66/ ORIG REF: 007/ REr: on Card 1/1 ACC NRI AR7000858 SOURCE CODE: UR/0058/66/000/009/EO11/EOll AUTHOR: Yeremenko. V. N.; Nizhenko, V. N.; Sklyarenko, L. I. -_ -~. '.-- I TITLE: Temperature dependence of the free surface energy of molten iron SOURCE: Ref. zh. Fizika, Abs. 9E92 REP SOURCE: Sb. Poverkhnostn. yavleniya v rasplavakh i voznikayushchikh iz nikh tverd. fazakh. Nallchik, 1965, 287-292 TOPIC TAGS: temperature dependence, molten metal, carbonyl iron, free surface energy, surface energy ABSTRACT: The surface tension (a) of molten iron in the 1540-1750C tempera- ture range is measured by the lying-drop method. The object of the investigation was carbonyl iron, annealed in hydrogen at 1000-1200C and remelted in a 10-4 mm Hg vacuum. Consideration of all possible measurement errors leads to the expression cr_1&%*2,",23:!:0,Cd .(t -15A) The thermodynamic characteristics of the molten iron surface are com"puted from the data of o and (30/0 . A. Vertman. [Translation of abstract] [NT] SUB CODE: 20/ Card 1 / 1 1 ACC NRs AR7000857 AUTHOR - Ivashchenko., Khilya, G. P. SOURCE CODE: IJR/0058/66/000/009/EOII/EOll Yu. N. ; Yeremenko V. N. - Bogatyrenko, B. B. TITLE: Temperature dependence of free surface energy of liquid magnesium SOURCE: Ref. zh. Fizika, Abs. 9E91 REF SOURCE: Sb. Poverkhnostn. yavleniya v rasplavakh I voznikayushchikh iz nikh tverd. fazakh. Nallchik, 1965, 281-286 "141 f -j" TOPIC TAGS: temperature dependence, free energy, liquid heliumv surface tension, magnesium/MG-1 magnesium ABSTRACT: Measurements were made of the surface tension (a) of MG-1 f magnesium (99. 917o-pure) by the lying-drop method in a purified helium medium. The results fulfill the equation (Fr- 5K4:t1,2-:-0.192:t0.601 Y -660) . The critical temperature is evaluated as 3860 t 100C. A comparison is made of the results of previous determinations and it is shown that the most probable value of at 700C Is 580 mj/CM2. A. Vertman. [Translation of abstract] [NTJ SUB CODE: 20/ Card 1 / 1 I YHlEMENKO,-.V.N., otv. red.; FRANTSEVICH, I.N.., red.; SAMSONOV, G.V., red.; PISARENKO, G.S., red.; FEDCRCHRIKO, I.M.p red.; TRFSVYATSKIY, S.G., red.; IVAMEZUKO., ru.N.9 red.; POKROVSKAYA, Z.S., red.; RAKHLINA, W.Pej tekhns red* (Siu-face phenomena in melts and in prooIesseo of powder metallurgy) Poverkhnostnye iavleniia v rasplavakh i pro- tsessakh poroshkovoi, metallurgii. Kiev, Izd-vo All Ukr. SSRo 1963. 377 p. (MIRA 17:3) 1. Akademiya nauk URSR, Kiev. Instytut metalokeramiky i spetsiallrjykh splaviv. 2. Institut metal-16keramiki i spetoiallmykh splavov AN Ukr.SSR (for Yeremenko). i-fici.; rod.j G.V., red.; rcd.; FEMECHEMO, I.M0, red,j IRES7Y,'.T~;KJ7j IYA-SKME if-0, Tu.N., 1,I)KIROVI'MIYAP Z.N.p red. (Surface pheromena in mlt~ and pracezzes of powder metal- lural Poverkhnostnye lavlerilla v rosplavakh i protsessakh poroslikovol Le'~allurgli. K!t3v, lzd-vo T' U-SM, 1963. 456 (mllul, 18, 1) navk URI:Zlig n-.Iin. ' splaviv. ' Inoti-tut metallokeramiki I spe- taiallnykh splavov AN Ukr.-'!,3H (for Ivashchdnkof Yeremenko) A* loon-C, tae golubijitv of Ho irs TiC at the eutec-Tj C TeBEPerut" 'a 3~r Hol~" C T I jAn A f thp lif C.Cr i Card 1/2 rag Ac Ai HER card 2/2 yMMEIIKO, V.N. (Kiyev); NAYDICHx Yu-V- (Kiyev); VASILIU) M.I. (Kiyev) Surface tension of melts in the system cobalt.- tin. Izv. AN SSSR. Met. i gor. delo no.5:64-67 S-0 1630 (MIRA 1611l) YEREMENKO V.N.- NIZHENKO, V.I. R4o,-,,of surface phenomena in powder metallurgy proceBBese Porosh. met.".4, (MIRA 16:10) 4.3,'no.4t17-28 J1-A9 163. jC 1. Institut metallokeramiki i spetsialinykh splavov AN UkrSSR- (Powder metallurgy) kSurface chemistry) ~S/07QJ63/008/001/061/02'6 B1191BI86 AUTHORSs Yer~me!Rkq#-V..-N. Lukashenkop 04 MI, TITLEs Thermodynamic properties of higher zinc antimonide PERIODICALs Zhurnal neorganioheskoy khimiip v#'8# no. lt 1963p a 10 VEXTs The electromotive force (e.m.f.) and the temperature coefficient of, the eom.f. were measur 0d for galvanic chains according to the scheme Zo liqu IKC1 - N&CI - ZnO121 LZnSb + Bb) solid' The results were used to calculate the free energy of formation, the entropy, and the heat of forma- tion when ZnSb is formed from the elements. The measurements were made with Zu-Sb.alloys containing 15, 20, 25, 30v 37, and 43 % by weight of Zn at 420 - 50000. The measured values corrdsponded to the equation eemefs 0.0795 (t - 450).o.66-io-4 volts with an accuracy of +0-5 my. The free energy of formation for the production of solid ZaSb froj~ liquid Zn and solid Sb9 Az - -3670 + 3-04 (t - 450) cal/mole. The entropy of formation As - -3.04 cal/mole-deg. The heat of formation AH at 4500C -5870 oal/nkoi*.-.~ For the formation of solid ZrAb from solid Zn and SbtdHO 0 nSb -413 asVwle z i II I Card 1/2 S/OTS/63/008/001/001/026 Thermodynamic properties of... B119/BI86 0 .2065' Cal/g-atomi As ZnSb -0-53 Cal/mole.deg 7 -0e26 cal/g-stom-doge The standard quantities for the formation of ZnSb at 2980K could not be determined since neither the heat capacity of the compound nor the heat of phase transformation at 3000G,are known# There are 2 figures* The most important English-language references &rat 0. S~lvey, V& Lyonnst Vo- Silvestry. J. Electrochem. Soc., 108, 658, (1961)1 0. Kubasbhewskit J. Catterall. Thermochemical data of Alloyet Pergamon Press# 1956;. H. Belts, B. Dewitt. J. Amer. Chem* Boo., 61j 2594 0939), ASSOCIATIONi Inatitut metallokeramiki i opetemplavoy Akademii nauk USSR (Institute of Powder Metallurgy and Special Alloys of the Academy of Sciences UkrSSR) SUBMITTED$ March 28, 1962 Card 2/2 I YF REW, NKO A; NIMENKO, V.I. Surface properties of Ni-Au-A1203 liquid alloys. Zhur.neorg.khim. 8 no.9:2124-2127 S 163. (MIRA 16:10) 1. Institut metallokeramiki i spetsialtnykh splavov AN UkrSSR. ACCESSION NRt -AP3008085 S/0089/63/015/003/0266/0267 AUTHOR: none TITLE% Seminar on refractory metals, compounds, and alloys [Kiev, April 19631 SOURCE: Atdmnaya energiya, v.' 15, no. 3,.196*3, 266-267 !.TOPIC TAGS: refractory metal, refractory compound, refractory alloy; electron structure, crystal structure, electron beam welding, physical property, vanadium, niobium, molybdenum, single crystal growth, tung- sten, rhenium silicide,' nonmagnetic zirconium base-alloy, tantalum, nonmetallic element diffusion,*heat conductivity, electric conduc '.-tivity,.thermal diffusivity. ABSTRACT: In April 1963, a seminar on the extraction, physical prop- . ertieo, and electron structure of refractory metals was hold in Kiev. under the sponsorship of the Inst-ituto of Powder Metallurgy and Special Alloys, Academy of Sciences, Ukrainian SSR., Approximately 300 representatives of scientific research institutes attended the Card I ACCESSION NRt AP3008085 seminar, One hundred papers were presented. Among them were the following: I. Kornilov, The interaction between refra'ctory compounds in- volving the formation of binary', ternary,,and multicomponent solid solutions. G. V. Samsonov.' Classification of hydrides, nitrides, -and other compounds of.nonmetals with cloments of r~e periodfc table. V. N. Yeremenko,-Z. I. Tolmachev. The relationship between some proper tTe'-s'-"-a'_'n_`d-the elec'tron structure of transition metals and their interatitial'phases. G. V. Samaonov. The nature of the catalytic properties of transition metals. 1. A. Kedrinakiy, A. 1. Avguatinnik, Ye. A. Berkman. Experimental data on the catalytic activity of refractory metal electrodes in al,actro.chemicaVreactions, Card 2 /-14 TIT YEREMENKOJI V.N,; LUKASHENKO., G.M. Thermodynamic propertier rf liquid inlutiona of the magnesium - cadmium oystem. Ukr. khim. zhur. 29 no.10:1048-1052 163. (MIRA 17t 1) 1. Institut metallokeramiki i spetsiallnykh splavov AN UkrSSR. NIZRENKO V.I. YEBE)EMKOR Y-lu P -_ - Surface properties of nickpl-baaed liquid alloys. Part 1. Effect of silver-on the surface tension of nickel. Ukr. khim. zhur. 29 no.11:1157-1160 163. (MIRA 16:12) 1. Institut metallokeramiki i spetaialinykh splavov AN UkrSSR. ACCESSION NR: AT4030795 8/0000/63/000/000/0097/0109 AUTHOR: Yeremenko,,..Y.,#,~; Nizhanko, V. 1. TITLE: Surface properties of nickel based alloys SOURCE% AN UkrSSRS Institut metallokeramiki I spetsiallnyfth oplavov. Poverkhnostny*yel yavleniya, v rasplavakh I protsessakh poroehkovoy metallurgii (Sur- face phenomena in liquid metals and processes in powder metallurgy). Kiev, Tzd-vo AN UkrSSRp 1963, 97-109 TOPIC TAGS: surface propertyt nickel based alloy, powder metallurgy, infusible surface, nickel, aluminum oxide, surface tension# binary alloys copper containing alloy ABSTRACT: The results of the investigation were compared with diagrams of conditions for the same systems. The authors concluded that the isotherm of surface tension for alloys in a system with inorganic solubility in the solid, as well as the liquid state, was given by Zhukhovitskiys equation (A. A. Zhukhovitskiy, ZhM, vol. 18, 1944, p. 214) for an ideal solution (nickel-copper). In the binary liquid systems examined, the component with the least surface tension had an active surfacerela- tive to the second component. The lowering of the surface tension in these systems ractically ceased In a composition which corresponded to the monotectic point o%rd 1/2 F ACCESSION NR: AT4030795 coordinate (nickel-silver). Surface tension in a nickel-chromium system was studied and the isotherm of the surface tension showed a very slight deviation of the sur- face tension in alloys from the additive values. It was established that in systems with maxima on the fusibility curves corresponding to the congruently malting electron compounds having an electron concentration of 3:2, extreme points in form of a maximum (nickel-beryllium) or a point of bend (nickel-aluminum) were tected on the isotherms of surface tension. In the nickel-tin system, such poinz:s .were not detected although the isotherm in the region of the composition of the electron compound Ni3sn having an electron concentration of 1.75 had an abno-_,-., path. Orig. art. has: 12 figures. ASSOCIATION: Institut metallokeramiki i spetsiallny*kh splavov AN UIrSSR(Institutza of Powder Metallurgy'and Sp*0JA1*A11qysj' AN UkrSSR) SUB14ITTED; DATE ACQ: 16Apr64 23Bov63 ,SUB CODE: M NO REP SOV0. Ole OTHER: 008 21 ACCESSION NR: AT4030797 8/0000163/000/000/0119/0124 AUTHOR: Yeremenko, V.N.; Naydich, Yu.V.; Vasiliu, H.I. TITLE: Surface tension and density of liquid alloys of the Co-Sn system SOURCE: 'AN UkrSSR. Institut metallokeramiki i spetsiallny*kh splavov. ?overkhnos- ~ny*ye_ yavleniya v rasplavakh i protsessakh poroshkovoy metallurgii (surface phen- omena in liquid metals and processes in powder metallurgy). Kiev, Izd-vo AN UkrSSR, 1963, 119-124 TO PIG TAGS: surface tension, density, cobalt based alloy, tin containing alloy, aluminum oxide, high temperature ABSTRACT: The authois developed a method of determining the density of liquid metals at high temperatures. This work was done in an aluminum o~tide crucible heated to a maximum temperature of 19000. The results were presented in graphs and compared with published data. The accuracy of the density method was 0.3%. Density-of liquid alloys in the Co-Sn system was determined at a temperature of 15500C. The surface tension of the Co-Sn alloy system was measured. The isotherm of the surface tension of the Co-Sn system at 5500C had a continuous path. Orig. art. has: 4 figures, 2 Card 1/2 ACCESSION NR: AT4030797 tables, and 2 formulas. ASSOCIATION: Institut metallokeramiki i spetsial'ny*kh splavov AN UMSSR(Institute of Powder !-btallurar and Ppecial, Alloys of tho AN U